# Supplementary Material (ESI) for Chemical Communications # This journal is (c) The Royal Society of Chemistry 2010 data_publication_text _journal_name_full Chem.Commun. _journal_coden_cambridge 0182 _publ_contact_author_name 'Stefan Kaskel' _publ_contact_author_address ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; _publ_contact_author_email Stefan.Kaskel@chemie.tu-dresden.de _publ_contact_author_phone '00490351/46334885 ' _publ_contact_author_fax (+49)035146337287 loop_ _publ_author_name _publ_author_address R.Gruenker ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; I.Senkovska ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; R.Biedermann ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; K.Nicole ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; M.R.Lohe ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; ; P.Mueller ; ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; S.Kaskel ;Department of Inorganic Chemistry University of Technology Dresden Mommsenstrasse 6 D-01069 Dresden Germany ; _publ_section_title ; A highly porous Metal-Organic Framework with flexible corundum topology ; _publ_section_abstract ; A flexible Metal-Organic Framework Zn4O(BenzTB)3/2 (DUT 13) was obtained by combination of a tetratopic linker and Zn4O6+ as connector. The material has a corundum topology and shows the highest pore volume among flexible MOFs. ; data_Zn4O(BenzTB)1.5 _database_code_depnum_ccdc_archive 'CCDC 784971' #TrackingRef '- Zn4O(BenzTB)1.5 - new.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; Zn4O(BenzTB)1.5 ; _chemical_name_common Zn4O(BenzTB)1.5 _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C60 H36 N3 O13 Zn4' _chemical_formula_weight 1268.40 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting hexagonal _symmetry_space_group_name_H-M R-3C loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-y, x-y, z' '-x+y, -x, z' 'y, x, -z+1/2' 'x-y, -y, -z+1/2' '-x, -x+y, -z+1/2' 'x+2/3, y+1/3, z+1/3' '-y+2/3, x-y+1/3, z+1/3' '-x+y+2/3, -x+1/3, z+1/3' 'y+2/3, x+1/3, -z+5/6' 'x-y+2/3, -y+1/3, -z+5/6' '-x+2/3, -x+y+1/3, -z+5/6' 'x+1/3, y+2/3, z+2/3' '-y+1/3, x-y+2/3, z+2/3' '-x+y+1/3, -x+2/3, z+2/3' 'y+1/3, x+2/3, -z+7/6' 'x-y+1/3, -y+2/3, -z+7/6' '-x+1/3, -x+y+2/3, -z+7/6' '-x, -y, -z' 'y, -x+y, -z' 'x-y, x, -z' '-y, -x, z-1/2' '-x+y, y, z-1/2' 'x, x-y, z-1/2' '-x+2/3, -y+1/3, -z+1/3' 'y+2/3, -x+y+1/3, -z+1/3' 'x-y+2/3, x+1/3, -z+1/3' '-y+2/3, -x+1/3, z-1/6' '-x+y+2/3, y+1/3, z-1/6' 'x+2/3, x-y+1/3, z-1/6' '-x+1/3, -y+2/3, -z+2/3' 'y+1/3, -x+y+2/3, -z+2/3' 'x-y+1/3, x+2/3, -z+2/3' '-y+1/3, -x+2/3, z+1/6' '-x+y+1/3, y+2/3, z+1/6' 'x+1/3, x-y+2/3, z+1/6' _cell_length_a 25.682(4) _cell_length_b 25.682(4) _cell_length_c 114.90(2) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 120.00 _cell_volume 65630(18) _cell_formula_units_Z 12 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 3000 _cell_measurement_theta_min 1.22 _cell_measurement_theta_max 35.92 _exptl_crystal_description diamond _exptl_crystal_colour colorless _exptl_crystal_size_max 0.1 _exptl_crystal_size_mid 0.05 _exptl_crystal_size_min 0.02 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 0.385 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 7692 _exptl_absorpt_coefficient_mu 0.450 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_absorpt_process_details ? _exptl_special_details ; Absorption cooefficient is given for the solvent free framework, data is partially incomplete because the diffractometer is for protein cystals. Detector distance was at machine minimum for measurement. Resolution could not be increased any further. ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.88561 _diffrn_radiation_type Synchrotron _diffrn_radiation_source 'BESSY BL MX 14.2' _diffrn_radiation_monochromator 'Si-111 crystal' _diffrn_measurement_device_type 'MX-225 CCD' _diffrn_measurement_method '\D\f scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 167128 _diffrn_reflns_av_R_equivalents 0.0480 _diffrn_reflns_av_sigmaI/netI 0.0280 _diffrn_reflns_limit_h_min -33 _diffrn_reflns_limit_h_max 33 _diffrn_reflns_limit_k_min -31 _diffrn_reflns_limit_k_max 31 _diffrn_reflns_limit_l_min -150 _diffrn_reflns_limit_l_max 146 _diffrn_reflns_theta_min 1.22 _diffrn_reflns_theta_max 35.92 _reflns_number_total 16481 _reflns_number_gt 8988 _reflns_threshold_expression >2\s(I) _computing_data_collection 'marCCD 1994-2002' _computing_cell_refinement XDS _computing_data_reduction XDSCONV _computing_structure_solution 'SUPERFLIP (Palatinus, 2007)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Diamond 3.1' _computing_publication_material WinGX _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2\s(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0926P)^2^+0.1000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary heavy _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 16481 _refine_ls_number_parameters 241 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.1006 _refine_ls_R_factor_gt 0.0542 _refine_ls_wR_factor_ref 0.1644 _refine_ls_wR_factor_gt 0.1494 _refine_ls_goodness_of_fit_ref 1.007 _refine_ls_restrained_S_all 1.007 _refine_ls_shift/su_max 0.039 _refine_ls_shift/su_mean 0.003 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group C1 C 0.10891(12) -0.00500(11) 0.354742(18) 0.1009(6) Uani 1 1 d . . . C2 C 0.14969(11) -0.02090(11) 0.360411(17) 0.1034(7) Uani 1 1 d . . . C3 C 0.14333(12) -0.03692(12) 0.372242(17) 0.1155(8) Uani 1 1 d . . . H3 H 0.1139 -0.0353 0.3767 0.139 Uiso 1 1 calc R . . C4 C 0.18006(12) -0.05502(12) 0.377366(17) 0.1229(9) Uani 1 1 d . . . H4 H 0.1755 -0.0647 0.3852 0.147 Uiso 1 1 calc R . . C5 C 0.19422(13) -0.02440(14) 0.354256(19) 0.1283(9) Uani 1 1 d . . . H5 H 0.1995 -0.0141 0.3464 0.154 Uiso 1 1 calc R . . C6 C 0.22304(12) -0.05894(12) 0.371083(17) 0.1161(8) Uani 1 1 d . . . C7 C -0.27310(12) -0.10883(14) 0.30312(2) 0.1427(11) Uani 1 1 d . . . H7 H -0.3051 -0.1480 0.3025 0.171 Uiso 1 1 calc R . . C8 C -0.27475(11) -0.06229(13) 0.297554(18) 0.1239(9) Uani 1 1 d . . . C9 C -0.22708(13) -0.00591(15) 0.29846(3) 0.1593(13) Uani 1 1 d . . . H9 H -0.2274 0.0252 0.2944 0.191 Uiso 1 1 calc R . . C10 C -0.17815(12) 0.00647(14) 0.30532(3) 0.1502(12) Uani 1 1 d . . . H10 H -0.1468 0.0458 0.3061 0.180 Uiso 1 1 calc R . . C11 C -0.22274(13) -0.09631(14) 0.30965(2) 0.1325(9) Uani 1 1 d . . . H11 H -0.2208 -0.1277 0.3132 0.159 Uiso 1 1 calc R . . C12 C -0.17571(11) -0.03863(14) 0.310934(19) 0.1194(8) Uani 1 1 d . . . C13 C 0.27851(12) -0.07012(13) 0.387685(18) 0.1190(8) Uani 1 1 d . . . C14 C 0.29884(13) -0.01458(12) 0.392594(18) 0.1290(9) Uani 1 1 d . . . H14 H 0.2987 0.0159 0.3883 0.155 Uiso 1 1 calc R . . C15 C 0.23031(13) -0.04235(14) 0.35929(2) 0.1380(10) Uani 1 1 d . . . H15 H 0.2601 -0.0437 0.3549 0.166 Uiso 1 1 calc R . . C16 C 0.27850(15) -0.11469(13) 0.39429(2) 0.1469(11) Uani 1 1 d . . . H16 H 0.2637 -0.1530 0.3912 0.176 Uiso 1 1 calc R . . C17 C 0.30048(15) -0.10264(12) 0.40558(2) 0.1423(11) Uani 1 1 d . . . H17 H 0.3011 -0.1330 0.4099 0.171 Uiso 1 1 calc R . . C18 C 0.32132(11) -0.04720(10) 0.410600(17) 0.1082(7) Uani 1 1 d . . . C19 C 0.31957(13) -0.00362(12) 0.403964(18) 0.1309(9) Uani 1 1 d . . . H19 H 0.3326 0.0342 0.4072 0.157 Uiso 1 1 calc R . . C20 C -0.12276(13) -0.02788(18) 0.31795(2) 0.1271(9) Uani 1 1 d . . . N1 N 0.25970(11) -0.08077(11) 0.375857(15) 0.1354(8) Uani 1 1 d . . . O1 O 0.0000 0.0000 0.336640(16) 0.0803(5) Uani 1 3 d S . . O2 O 0.06507(7) -0.00911(7) 0.360266(13) 0.1027(4) Uani 1 1 d . . . O3 O 0.12291(9) 0.01556(10) 0.344315(14) 0.1438(7) Uani 1 1 d . . . O4 O -0.02710(12) -0.11373(12) 0.32086(2) 0.1718(10) Uani 1 1 d . . . O5 O -0.11890(9) -0.07228(11) 0.321271(17) 0.1422(7) Uani 1 1 d . . . Zn1 Zn 0.0000 0.0000 0.353516(3) 0.08153(13) Uani 1 3 d S . . Zn2 Zn -0.060499(12) -0.078922(12) 0.331015(2) 0.09559(12) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 C1 0.1169(17) 0.1318(18) 0.0716(12) -0.0108(12) -0.0157(12) 0.0754(15) C2 0.1292(18) 0.1330(18) 0.0726(11) -0.0207(11) -0.0245(12) 0.0840(16) C3 0.149(2) 0.174(2) 0.0681(11) -0.0252(13) -0.0216(12) 0.1150(19) C4 0.177(2) 0.181(2) 0.0620(11) -0.0293(13) -0.0310(13) 0.128(2) C5 0.163(2) 0.205(3) 0.0717(12) -0.0046(15) -0.0057(14) 0.133(2) C6 0.160(2) 0.171(2) 0.0685(11) -0.0427(13) -0.0416(13) 0.1212(19) C7 0.1093(18) 0.156(2) 0.1186(18) 0.0487(17) -0.0228(15) 0.0331(17) C8 0.0907(15) 0.168(2) 0.0807(13) 0.0574(14) 0.0012(11) 0.0409(16) C9 0.1112(19) 0.169(3) 0.144(2) 0.085(2) -0.0193(17) 0.0292(19) C10 0.1034(18) 0.160(2) 0.144(2) 0.073(2) -0.0241(16) 0.0335(17) C11 0.124(2) 0.156(2) 0.1096(18) 0.0348(16) -0.0247(15) 0.064(2) C12 0.0925(16) 0.155(2) 0.0848(13) 0.0374(14) -0.0048(11) 0.0424(17) C13 0.170(2) 0.160(2) 0.0773(12) -0.0466(14) -0.0546(13) 0.120(2) C14 0.212(3) 0.142(2) 0.0802(12) -0.0355(13) -0.0617(15) 0.124(2) C15 0.173(2) 0.231(3) 0.0820(14) -0.0296(16) -0.0267(15) 0.155(2) C16 0.234(3) 0.147(2) 0.1043(17) -0.0588(16) -0.078(2) 0.129(2) C17 0.238(3) 0.129(2) 0.0965(15) -0.0385(14) -0.0702(19) 0.119(2) C18 0.1509(19) 0.1165(16) 0.0780(12) -0.0255(11) -0.0467(12) 0.0825(15) C19 0.216(3) 0.1344(19) 0.0792(12) -0.0372(13) -0.0627(15) 0.115(2) C20 0.108(2) 0.162(3) 0.0881(15) 0.0277(16) -0.0193(13) 0.051(2) N1 0.196(2) 0.208(2) 0.0788(10) -0.0647(12) -0.0619(12) 0.1585(19) O1 0.0932(8) 0.0932(8) 0.0545(10) 0.000 0.000 0.0466(4) O2 0.1118(11) 0.1293(12) 0.0811(9) 0.0007(8) -0.0082(8) 0.0709(10) O3 0.1552(16) 0.234(2) 0.0843(10) 0.0189(12) -0.0032(10) 0.1294(16) O4 0.185(2) 0.229(2) 0.1603(19) -0.1042(17) -0.0640(16) 0.148(2) O5 0.1491(16) 0.193(2) 0.1094(13) -0.0108(13) -0.0384(11) 0.1041(15) Zn1 0.09540(18) 0.09540(18) 0.05380(18) 0.000 0.000 0.04770(9) Zn2 0.1032(2) 0.1160(2) 0.06170(14) -0.00320(11) -0.00216(11) 0.05040(15) _geom_special_details ; All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag C1 O2 1.250(3) . ? C1 O3 1.286(3) . ? C1 C2 1.454(3) . ? C2 C5 1.385(3) . ? C2 C3 1.406(3) . ? C3 C4 1.375(3) . ? C3 H3 0.9300 . ? C4 C6 1.364(3) . ? C4 H4 0.9300 . ? C5 C15 1.354(3) . ? C5 H5 0.9300 . ? C6 C15 1.405(3) . ? C6 N1 1.425(3) . ? C7 C8 1.375(4) . ? C7 C11 1.387(3) . ? C7 H7 0.9300 . ? C8 C9 1.354(4) . ? C8 N1 1.430(3) 33_445 ? C9 C10 1.379(3) . ? C9 H9 0.9300 . ? C10 C12 1.354(3) . ? C10 H10 0.9300 . ? C11 C12 1.373(3) . ? C11 H11 0.9300 . ? C12 C20 1.484(3) . ? C13 C14 1.371(3) . ? C13 C16 1.373(3) . ? C13 N1 1.422(2) . ? C14 C19 1.385(3) . ? C14 H14 0.9300 . ? C15 H15 0.9300 . ? C16 C17 1.386(3) . ? C16 H16 0.9300 . ? C17 C18 1.373(3) . ? C17 H17 0.9300 . ? C18 C19 1.374(3) . ? C18 C18 1.493(3) 12 ? C19 H19 0.9300 . ? C20 O5 1.252(3) . ? C20 O4 1.287(4) 3 ? N1 C8 1.431(3) 32_545 ? O1 Zn1 1.9391(19) . ? O1 Zn2 1.9470(7) 3 ? O1 Zn2 1.9470(7) 2 ? O1 Zn2 1.9470(7) . ? O2 Zn1 1.9597(15) . ? O3 Zn2 1.9235(16) 2 ? O4 C20 1.287(4) 2 ? O4 Zn2 1.914(2) . ? O5 Zn2 1.9462(18) . ? Zn1 O2 1.9597(15) 2 ? Zn1 O2 1.9597(15) 3 ? Zn2 O3 1.9235(16) 3 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag O2 C1 O3 124.2(2) . . ? O2 C1 C2 119.6(2) . . ? O3 C1 C2 116.1(2) . . ? C5 C2 C3 117.0(2) . . ? C5 C2 C1 121.6(2) . . ? C3 C2 C1 121.4(2) . . ? C4 C3 C2 120.9(2) . . ? C4 C3 H3 119.5 . . ? C2 C3 H3 119.5 . . ? C6 C4 C3 121.0(2) . . ? C6 C4 H4 119.5 . . ? C3 C4 H4 119.5 . . ? C15 C5 C2 122.1(2) . . ? C15 C5 H5 118.9 . . ? C2 C5 H5 118.9 . . ? C4 C6 C15 118.5(2) . . ? C4 C6 N1 122.9(2) . . ? C15 C6 N1 118.5(2) . . ? C8 C7 C11 118.7(3) . . ? C8 C7 H7 120.6 . . ? C11 C7 H7 120.6 . . ? C9 C8 C7 119.3(2) . . ? C9 C8 N1 120.6(2) . 33_445 ? C7 C8 N1 120.1(2) . 33_445 ? C8 C9 C10 121.5(3) . . ? C8 C9 H9 119.2 . . ? C10 C9 H9 119.2 . . ? C12 C10 C9 120.1(3) . . ? C12 C10 H10 120.0 . . ? C9 C10 H10 120.0 . . ? C12 C11 C7 121.6(3) . . ? C12 C11 H11 119.2 . . ? C7 C11 H11 119.2 . . ? C10 C12 C11 118.7(2) . . ? C10 C12 C20 122.0(3) . . ? C11 C12 C20 119.3(3) . . ? C14 C13 C16 118.75(19) . . ? C14 C13 N1 120.6(2) . . ? C16 C13 N1 120.6(2) . . ? C13 C14 C19 120.5(2) . . ? C13 C14 H14 119.8 . . ? C19 C14 H14 119.8 . . ? C5 C15 C6 120.4(2) . . ? C5 C15 H15 119.8 . . ? C6 C15 H15 119.8 . . ? C13 C16 C17 120.0(2) . . ? C13 C16 H16 120.0 . . ? C17 C16 H16 120.0 . . ? C18 C17 C16 121.9(2) . . ? C18 C17 H17 119.0 . . ? C16 C17 H17 119.0 . . ? C17 C18 C19 117.20(18) . . ? C17 C18 C18 120.90(13) . 12 ? C19 C18 C18 121.90(13) . 12 ? C18 C19 C14 121.6(2) . . ? C18 C19 H19 119.2 . . ? C14 C19 H19 119.2 . . ? O5 C20 O4 125.3(2) . 3 ? O5 C20 C12 118.6(3) . . ? O4 C20 C12 115.9(3) 3 . ? C13 N1 C6 121.32(17) . . ? C13 N1 C8 118.98(18) . 32_545 ? C6 N1 C8 119.16(16) . 32_545 ? Zn1 O1 Zn2 109.39(5) . 3 ? Zn1 O1 Zn2 109.39(5) . 2 ? Zn2 O1 Zn2 109.56(5) 3 2 ? Zn1 O1 Zn2 109.39(5) . . ? Zn2 O1 Zn2 109.56(5) 3 . ? Zn2 O1 Zn2 109.56(5) 2 . ? C1 O2 Zn1 125.09(14) . . ? C1 O3 Zn2 134.99(18) . 2 ? C20 O4 Zn2 130.2(2) 2 . ? C20 O5 Zn2 132.1(2) . . ? O1 Zn1 O2 113.31(5) . . ? O1 Zn1 O2 113.31(5) . 2 ? O2 Zn1 O2 105.37(5) . 2 ? O1 Zn1 O2 113.31(5) . 3 ? O2 Zn1 O2 105.37(5) . 3 ? O2 Zn1 O2 105.37(5) 2 3 ? O4 Zn2 O3 120.32(12) . 3 ? O4 Zn2 O5 103.60(9) . . ? O3 Zn2 O5 103.03(10) 3 . ? O4 Zn2 O1 112.20(9) . . ? O3 Zn2 O1 106.67(8) 3 . ? O5 Zn2 O1 110.40(7) . . ? _diffrn_measured_fraction_theta_max 0.927 _diffrn_reflns_theta_full 35.92 _diffrn_measured_fraction_theta_full 0.927 _refine_diff_density_max 0.458 _refine_diff_density_min -0.522 _refine_diff_density_rms 0.048 loop_ _platon_squeeze_void_nr _platon_squeeze_void_average_x _platon_squeeze_void_average_y _platon_squeeze_void_average_z _platon_squeeze_void_volume _platon_squeeze_void_count_electrons _platon_squeeze_void_content 1 -0.022 -0.015 0.000 53995 22952 ' '