# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2010


data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182

_publ_contact_author_name        'Luo, Fang'
_publ_contact_author_email       luof746@nenu.edu.cn

_publ_section_title              
;
Design Synthesis and Photocatalytic Activity of a Novel
Lilac-like Silver-Vanadate Hybrid Solid Based on Dicyclic
Rings of [V4O12]4- with Argentophilic {Ag7}7+ Cluster
;
_publ_author_name                'Fang Luo'

# Attachment '- h.cif'

data_h
_database_code_depnum_ccdc_archive 'CCDC 759774'
#TrackingRef '- h.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C40 H56 Ag7 N16 O24 V8,C10 H14 Ag N4, 2(H2 O)'
_chemical_formula_sum            'C50 H74 Ag8 N20 O26 V8'
_chemical_formula_weight         2641.78

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.107(5)
_cell_length_b                   12.154(5)
_cell_length_c                   15.078(5)
_cell_angle_alpha                83.821(5)
_cell_angle_beta                 68.816(5)
_cell_angle_gamma                68.176(5)
_cell_volume                     1919.6(13)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6762
_cell_measurement_theta_min      2.12
_cell_measurement_theta_max      25.00

_exptl_crystal_description       block
_exptl_crystal_colour            green
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.21
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.285
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1282
_exptl_absorpt_coefficient_mu    2.997
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.442
_exptl_absorpt_correction_T_max  0.533
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\w scans'
_diffrn_detector_area_resol_mean 0.01
_diffrn_standards_number         0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_decay_%        none
_diffrn_reflns_number            9721
_diffrn_reflns_av_R_equivalents  0.0189
_diffrn_reflns_av_sigmaI/netI    0.0376
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.12
_diffrn_reflns_theta_max         25.00
_reflns_number_total             6762
_reflns_number_gt                5839
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
During the refinement, the command 'isor' was used to restrain the non-H
atoms with ADP and NPD problems. These atoms are as follows:
c4 n2
These refinement led to the restraint number of 12.
all the non-H atoms are refined anisotropically.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0436P)^2^+16.1941P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00026(5)
_refine_ls_number_reflns         6685
_refine_ls_number_parameters     508
_refine_ls_number_restraints     12
_refine_ls_R_factor_all          0.0598
_refine_ls_R_factor_gt           0.0523
_refine_ls_wR_factor_ref         0.1320
_refine_ls_wR_factor_gt          0.1279
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_restrained_S_all      1.100
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.0000 0.0000 0.0000 0.0432(2) Uani 1 2 d S . .
Ag2 Ag 1.04194(6) -0.26284(6) -0.01235(4) 0.04122(18) Uani 1 1 d . . .
Ag3 Ag 0.75908(7) 0.61516(7) 0.37187(6) 0.0575(2) Uani 1 1 d . . .
Ag4 Ag 0.5000 0.5000 0.5000 0.0691(4) Uani 1 2 d S . .
Ag5 Ag 0.90576(6) -0.40042(7) 0.13291(5) 0.0510(2) Uani 1 1 d . . .
C22 C 1.1636(9) -0.6139(9) 0.1021(7) 0.054(2) Uani 1 1 d . . .
H22A H 1.1325 -0.6691 0.0922 0.065 Uiso 1 1 calc R . .
C21 C 1.1782(8) -0.4512(8) 0.1257(6) 0.0410(19) Uani 1 1 d . . .
H21A H 1.1603 -0.3712 0.1352 0.049 Uiso 1 1 calc R . .
C11 C 1.0292(9) 0.5757(8) 0.3716(7) 0.049(2) Uani 1 1 d . . .
H11A H 1.0070 0.6562 0.3825 0.059 Uiso 1 1 calc R . .
C23 C 1.2802(8) -0.6386(8) 0.1042(7) 0.046(2) Uani 1 1 d . . .
H23A H 1.3432 -0.7134 0.0965 0.056 Uiso 1 1 calc R . .
C24 C 1.3979(8) -0.5195(8) 0.1311(6) 0.0399(19) Uani 1 1 d . . .
H24A H 1.4222 -0.5718 0.1796 0.048 Uiso 1 1 calc R . .
H24B H 1.3728 -0.4385 0.1526 0.048 Uiso 1 1 calc R . .
C13 C 1.2420(12) 0.2698(11) 0.3218(9) 0.078(3) Uani 1 1 d . . .
H13A H 1.2235 0.2185 0.2885 0.094 Uiso 1 1 calc R . .
H13B H 1.3215 0.2781 0.2818 0.094 Uiso 1 1 calc R . .
C15 C 1.3520(13) 0.0871(11) 0.3920(9) 0.088(4) Uani 1 1 d . . .
H15A H 1.3348 0.0416 0.3529 0.106 Uiso 1 1 calc R . .
H15B H 1.4376 0.0867 0.3605 0.106 Uiso 1 1 calc R . .
C14 C 1.2511(14) 0.2203(12) 0.4096(9) 0.086(4) Uani 1 1 d . . .
H14A H 1.1687 0.2204 0.4518 0.103 Uiso 1 1 calc R . .
H14B H 1.2773 0.2680 0.4396 0.103 Uiso 1 1 calc R . .
C8 C 0.9342(11) 0.1628(9) 0.5427(9) 0.067(3) Uani 1 1 d . . .
H8A H 0.9663 0.1497 0.5948 0.080 Uiso 1 1 calc R . .
H8B H 0.9914 0.1893 0.4891 0.080 Uiso 1 1 calc R . .
C4 C 0.3370(14) 1.0370(13) 0.4873(11) 0.102(5) Uani 1 1 d U . .
H4A H 0.2482 1.0500 0.5223 0.122 Uiso 1 1 calc R . .
H4B H 0.3664 1.0755 0.5225 0.122 Uiso 1 1 calc R . .
C25 C 1.5114(7) -0.5455(7) 0.0388(6) 0.0373(18) Uani 1 1 d . . .
H25A H 1.5314 -0.6240 0.0146 0.045 Uiso 1 1 calc R . .
H25B H 1.5843 -0.5460 0.0519 0.045 Uiso 1 1 calc R . .
C1 C 0.5195(10) 0.8414(11) 0.4094(10) 0.089(5) Uani 1 1 d . . .
H1A H 0.5517 0.8654 0.3477 0.107 Uiso 1 1 calc R . .
N1 N 0.5729(7) 0.7384(6) 0.4420(5) 0.0439(17) Uani 1 1 d . . .
C3 C 0.3939(10) 0.8468(9) 0.5528(9) 0.073(4) Uani 1 1 d . . .
H3A H 0.3248 0.8696 0.6093 0.087 Uiso 1 1 calc R . .
N5 N 0.8093(8) 0.2552(7) 0.5712(6) 0.053(2) Uani 1 1 d . . .
C19 C 0.4527(9) -0.0346(8) 0.1351(7) 0.052(2) Uani 1 1 d . . .
H19A H 0.4776 0.0235 0.1544 0.062 Uiso 1 1 calc R . .
H19B H 0.3706 -0.0301 0.1811 0.062 Uiso 1 1 calc R . .
C7 C 0.7219(12) 0.2836(11) 0.6606(8) 0.075(3) Uani 1 1 d . . .
H7A H 0.7326 0.2498 0.7167 0.089 Uiso 1 1 calc R . .
C18 C 0.5275(8) -0.2567(7) 0.1324(6) 0.0412(19) Uani 1 1 d . . .
H18A H 0.4560 -0.2649 0.1284 0.049 Uiso 1 1 calc R . .
C20 C 0.4406(8) -0.0042(7) 0.0381(7) 0.045(2) Uani 1 1 d . . .
H20A H 0.4186 -0.0642 0.0181 0.054 Uiso 1 1 calc R . .
H20B H 0.3714 0.0710 0.0436 0.054 Uiso 1 1 calc R . .
C16 C 0.6637(8) -0.1824(8) 0.1368(7) 0.047(2) Uani 1 1 d . . .
H16A H 0.7004 -0.1273 0.1367 0.057 Uiso 1 1 calc R . .
C17 C 0.6336(8) -0.3439(8) 0.1358(7) 0.047(2) Uani 1 1 d . . .
H17A H 0.6463 -0.4243 0.1368 0.057 Uiso 1 1 calc R . .
C9 C 0.9338(11) 0.0481(8) 0.5155(8) 0.062(3) Uani 1 1 d . . .
H9A H 0.9009 0.0611 0.4638 0.074 Uiso 1 1 calc R . .
H9B H 0.8776 0.0209 0.5693 0.074 Uiso 1 1 calc R . .
C10 C 1.0226(9) 0.4100(9) 0.3406(7) 0.055(2) Uani 1 1 d . . .
H10A H 0.9945 0.3530 0.3295 0.066 Uiso 1 1 calc R . .
C12 C 1.1400(11) 0.4903(9) 0.3681(8) 0.065(3) Uani 1 1 d . . .
H12A H 1.2058 0.4999 0.3806 0.077 Uiso 1 1 calc R . .
C6 C 0.6167(11) 0.3703(11) 0.6527(7) 0.065(3) Uani 1 1 d . . .
H6A H 0.5416 0.4058 0.7027 0.078 Uiso 1 1 calc R . .
C5 C 0.7549(9) 0.3262(8) 0.5129(6) 0.047(2) Uani 1 1 d . . .
H5A H 0.7943 0.3258 0.4473 0.057 Uiso 1 1 calc R . .
N3 N 0.9541(7) 0.5234(6) 0.3561(5) 0.0456(17) Uani 1 1 d . . .
N7 N 1.0963(7) -0.4920(7) 0.1173(5) 0.0445(17) Uani 1 1 d . . .
N8 N 1.2900(6) -0.5357(6) 0.1194(5) 0.0365(15) Uani 1 1 d . . .
N4 N 1.1380(8) 0.3878(7) 0.3429(7) 0.065(2) Uani 1 1 d . . .
N2 N 0.4128(8) 0.9073(8) 0.4762(8) 0.078(3) Uani 1 1 d U . .
N10 N 0.5463(6) -0.1539(6) 0.1361(5) 0.0376(15) Uani 1 1 d . . .
C2 C 0.4945(10) 0.7443(9) 0.5344(7) 0.055(2) Uani 1 1 d . . .
H2A H 0.5086 0.6858 0.5784 0.066 Uiso 1 1 calc R . .
N9 N 0.7212(6) -0.2982(6) 0.1376(5) 0.0394(16) Uani 1 1 d . . .
N6 N 0.6392(8) 0.3967(7) 0.5597(5) 0.0491(18) Uani 1 1 d . . .
O1 O 0.5462(5) 0.1911(5) 0.1522(5) 0.0482(15) Uani 1 1 d . . .
O2 O 0.6688(5) 0.2883(5) 0.2287(4) 0.0412(13) Uani 1 1 d . . .
O3 O 0.8928(6) 0.2337(5) 0.2812(4) 0.0418(14) Uani 1 1 d . . .
O4 O 0.9600(7) -0.0266(5) 0.2653(5) 0.0550(17) Uani 1 1 d . . .
O5 O 0.7262(5) 0.0295(5) 0.2235(4) 0.0433(14) Uani 1 1 d . . .
O6 O 0.7917(5) 0.1569(5) 0.0551(4) 0.0456(14) Uani 1 1 d . . .
O7 O 1.0610(7) 0.1049(6) 0.1116(4) 0.0630(19) Uani 1 1 d . . .
O8 O 0.8323(6) -0.1854(5) 0.2988(5) 0.0550(17) Uani 1 1 d . . .
O9 O 0.9519(5) -0.1481(5) 0.1170(4) 0.0441(14) Uani 1 1 d . . .
O10 O 0.8560(6) 0.3905(5) 0.1334(4) 0.0407(13) Uani 1 1 d . . .
O11 O 1.1354(6) 0.0725(7) 0.2624(5) 0.066(2) Uani 1 1 d . . .
O12 O 0.7039(5) 0.4585(5) 0.3155(4) 0.0433(14) Uani 1 1 d . . .
V1 V 0.77998(12) 0.34627(10) 0.23867(9) 0.0288(3) Uani 1 1 d . . .
V2 V 0.68183(11) 0.16727(11) 0.16249(9) 0.0289(3) Uani 1 1 d . . .
V3 V 0.86944(12) -0.08621(10) 0.22603(9) 0.0285(3) Uani 1 1 d . . .
V4 V 1.01702(13) 0.09523(12) 0.22781(10) 0.0373(3) Uani 1 1 d . . .
O1W O 0.7589(6) 0.1985(6) 0.8760(5) 0.0549(17) Uani 1 1 d . . .
H1W H 0.8290 0.1543 0.8373 0.066 Uiso 1 1 d R . .
H2W H 0.7612 0.1840 0.9319 0.066 Uiso 1 1 d R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.0458(5) 0.0278(4) 0.0389(5) 0.0023(4) -0.0048(4) -0.0046(4)
Ag2 0.0530(4) 0.0360(3) 0.0294(3) -0.0056(2) -0.0050(3) -0.0174(3)
Ag3 0.0434(4) 0.0432(4) 0.0738(5) -0.0119(4) -0.0189(4) 0.0000(3)
Ag4 0.0770(8) 0.0705(8) 0.0854(9) 0.0257(7) -0.0584(7) -0.0315(7)
Ag5 0.0328(3) 0.0659(5) 0.0569(4) 0.0269(4) -0.0222(3) -0.0212(3)
C22 0.047(5) 0.066(7) 0.058(6) 0.003(5) -0.015(5) -0.034(5)
C21 0.033(4) 0.039(5) 0.042(5) 0.009(4) -0.006(4) -0.012(4)
C11 0.053(5) 0.030(5) 0.060(6) -0.008(4) -0.018(5) -0.008(4)
C23 0.042(5) 0.033(5) 0.062(6) -0.001(4) -0.014(4) -0.014(4)
C24 0.038(4) 0.049(5) 0.039(4) 0.006(4) -0.016(4) -0.021(4)
C13 0.070(8) 0.070(8) 0.071(8) -0.008(6) -0.013(6) -0.008(6)
C15 0.091(9) 0.076(8) 0.064(7) -0.013(6) -0.038(7) 0.021(7)
C14 0.104(10) 0.087(9) 0.077(8) 0.018(7) -0.042(8) -0.039(8)
C8 0.069(7) 0.050(6) 0.091(8) 0.003(6) -0.051(6) -0.010(5)
C4 0.077(7) 0.092(8) 0.113(8) 0.010(7) -0.019(6) -0.022(6)
C25 0.029(4) 0.036(4) 0.052(5) 0.005(4) -0.021(4) -0.013(3)
C1 0.049(6) 0.077(8) 0.090(9) 0.041(7) 0.000(6) 0.000(6)
N1 0.042(4) 0.021(3) 0.059(5) 0.004(3) -0.017(4) -0.002(3)
C3 0.055(6) 0.050(6) 0.091(9) -0.032(6) 0.012(6) -0.021(5)
N5 0.067(5) 0.054(5) 0.053(5) 0.010(4) -0.038(4) -0.024(4)
C19 0.048(5) 0.040(5) 0.068(6) -0.006(4) -0.023(5) -0.012(4)
C7 0.099(9) 0.094(9) 0.047(6) 0.024(6) -0.045(6) -0.039(8)
C18 0.045(5) 0.036(5) 0.052(5) 0.013(4) -0.024(4) -0.021(4)
C20 0.037(4) 0.029(4) 0.075(6) 0.004(4) -0.032(4) -0.007(4)
C16 0.046(5) 0.041(5) 0.067(6) 0.001(4) -0.030(5) -0.020(4)
C17 0.046(5) 0.039(5) 0.070(6) 0.023(4) -0.031(5) -0.024(4)
C9 0.093(8) 0.039(5) 0.075(7) 0.015(5) -0.053(7) -0.027(5)
C10 0.038(5) 0.045(5) 0.072(7) -0.004(5) -0.015(5) -0.008(4)
C12 0.067(7) 0.052(6) 0.085(8) -0.002(6) -0.039(6) -0.020(5)
C6 0.063(7) 0.089(8) 0.040(5) 0.013(5) -0.019(5) -0.026(6)
C5 0.063(6) 0.046(5) 0.039(5) 0.006(4) -0.029(4) -0.017(5)
N3 0.045(4) 0.035(4) 0.051(4) 0.001(3) -0.014(3) -0.010(3)
N7 0.036(4) 0.060(5) 0.041(4) 0.010(3) -0.012(3) -0.024(4)
N8 0.031(3) 0.038(4) 0.040(4) 0.002(3) -0.012(3) -0.012(3)
N4 0.043(5) 0.032(4) 0.109(8) -0.004(4) -0.026(5) 0.000(3)
N2 0.039(4) 0.048(5) 0.116(7) 0.008(5) -0.002(4) -0.007(4)
N10 0.039(4) 0.041(4) 0.040(4) 0.003(3) -0.018(3) -0.018(3)
C2 0.062(6) 0.046(6) 0.054(6) -0.002(4) -0.017(5) -0.019(5)
N9 0.035(4) 0.039(4) 0.051(4) 0.012(3) -0.023(3) -0.016(3)
N6 0.058(5) 0.057(5) 0.040(4) 0.013(4) -0.027(4) -0.023(4)
O1 0.034(3) 0.044(3) 0.076(4) 0.008(3) -0.030(3) -0.016(3)
O2 0.040(3) 0.038(3) 0.042(3) -0.010(3) -0.006(3) -0.016(3)
O3 0.050(3) 0.030(3) 0.037(3) -0.006(2) -0.018(3) 0.000(3)
O4 0.078(5) 0.037(3) 0.071(4) 0.001(3) -0.052(4) -0.018(3)
O5 0.029(3) 0.038(3) 0.049(3) 0.003(3) -0.010(3) 0.001(2)
O6 0.041(3) 0.046(3) 0.038(3) -0.005(3) -0.005(3) -0.008(3)
O7 0.067(4) 0.057(4) 0.035(3) -0.015(3) -0.013(3) 0.009(3)
O8 0.059(4) 0.030(3) 0.055(4) 0.012(3) -0.005(3) -0.010(3)
O9 0.043(3) 0.039(3) 0.037(3) -0.012(3) -0.008(3) -0.003(3)
O10 0.053(4) 0.025(3) 0.036(3) -0.002(2) -0.005(3) -0.015(3)
O11 0.039(4) 0.090(5) 0.072(5) -0.002(4) -0.032(3) -0.014(4)
O12 0.048(3) 0.030(3) 0.038(3) -0.016(2) -0.008(3) -0.001(3)
V1 0.0364(7) 0.0212(6) 0.0262(6) -0.0023(5) -0.0092(5) -0.0083(5)
V2 0.0249(6) 0.0255(6) 0.0358(7) -0.0007(5) -0.0123(5) -0.0063(5)
V3 0.0313(7) 0.0208(6) 0.0273(6) 0.0006(5) -0.0086(5) -0.0041(5)
V4 0.0340(7) 0.0341(7) 0.0420(8) -0.0064(6) -0.0216(6) 0.0000(6)
O1W 0.045(4) 0.056(4) 0.052(4) -0.005(3) -0.026(3) 0.005(3)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O6 2.437(6) 2_755 ?
Ag1 O6 2.437(6) . ?
Ag1 O9 2.459(6) . ?
Ag1 O9 2.459(6) 2_755 ?
Ag1 Ag2 3.0580(14) 2_755 ?
Ag2 O10 2.195(5) 2_755 ?
Ag2 O9 2.204(5) . ?
Ag2 O7 2.536(7) 2_755 ?
Ag3 N1 2.133(7) . ?
Ag3 N3 2.138(7) . ?
Ag3 O12 2.549(6) . ?
Ag4 N6 2.123(7) . ?
Ag4 N6 2.123(7) 2_666 ?
Ag5 N7 2.091(7) . ?
Ag5 N9 2.094(7) . ?
C22 C23 1.341(13) . ?
C22 N7 1.398(13) . ?
C21 N7 1.309(11) . ?
C21 N8 1.338(10) . ?
C11 C12 1.343(14) . ?
C11 N3 1.378(12) . ?
C23 N8 1.350(11) . ?
C24 N8 1.464(10) . ?
C24 C25 1.522(11) . ?
C13 C14 1.418(16) . ?
C13 N4 1.487(13) . ?
C15 C4 1.474(18) 1_645 ?
C15 C14 1.604(17) . ?
C8 N5 1.450(13) . ?
C8 C9 1.498(14) . ?
C4 C15 1.474(18) 1_465 ?
C4 N2 1.491(16) . ?
C25 C25 1.548(15) 2_845 ?
C1 N1 1.312(12) . ?
C1 N2 1.338(14) . ?
N1 C2 1.365(12) . ?
C3 N2 1.296(15) . ?
C3 C2 1.347(14) . ?
N5 C5 1.335(11) . ?
N5 C7 1.362(14) . ?
C19 N10 1.474(11) . ?
C19 C20 1.516(13) . ?
C7 C6 1.353(16) . ?
C18 C17 1.341(12) . ?
C18 N10 1.361(10) . ?
C20 C20 1.513(18) 2_655 ?
C16 N9 1.319(11) . ?
C16 N10 1.336(11) . ?
C17 N9 1.377(10) . ?
C9 C9 1.53(2) 2_756 ?
C10 N3 1.312(11) . ?
C10 N4 1.334(12) . ?
C12 N4 1.351(13) . ?
C6 N6 1.355(12) . ?
C5 N6 1.311(12) . ?
O1 V2 1.620(5) . ?
O2 V1 1.791(6) . ?
O2 V2 1.793(5) . ?
O3 V1 1.789(6) . ?
O3 V4 1.810(5) . ?
O4 V3 1.797(6) . ?
O4 V4 1.812(7) . ?
O5 V3 1.791(5) . ?
O5 V2 1.815(6) . ?
O6 V2 1.664(6) . ?
O7 V4 1.642(6) . ?
O7 Ag2 2.536(7) 2_755 ?
O8 V3 1.619(6) . ?
O9 V3 1.669(5) . ?
O10 V1 1.669(5) . ?
O10 Ag2 2.195(5) 2_755 ?
O11 V4 1.618(6) . ?
O12 V1 1.639(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Ag1 O6 180.0(2) 2_755 . ?
O6 Ag1 O9 82.30(19) 2_755 . ?
O6 Ag1 O9 97.70(19) . . ?
O6 Ag1 O9 97.70(19) 2_755 2_755 ?
O6 Ag1 O9 82.30(19) . 2_755 ?
O9 Ag1 O9 180.0(3) . 2_755 ?
O6 Ag1 Ag2 124.05(15) 2_755 2_755 ?
O6 Ag1 Ag2 55.95(15) . 2_755 ?
O9 Ag1 Ag2 134.49(13) . 2_755 ?
O9 Ag1 Ag2 45.51(13) 2_755 2_755 ?
O10 Ag2 O9 174.0(2) 2_755 . ?
O10 Ag2 O7 91.6(2) 2_755 2_755 ?
O9 Ag2 O7 94.3(2) . 2_755 ?
N1 Ag3 N3 153.0(3) . . ?
N1 Ag3 O12 99.9(2) . . ?
N3 Ag3 O12 102.4(2) . . ?
N6 Ag4 N6 180.000(1) . 2_666 ?
N7 Ag5 N9 174.3(3) . . ?
C23 C22 N7 109.2(8) . . ?
N7 C21 N8 113.6(8) . . ?
C12 C11 N3 108.3(8) . . ?
C22 C23 N8 107.9(8) . . ?
N8 C24 C25 111.8(7) . . ?
C14 C13 N4 107.8(10) . . ?
C4 C15 C14 105.6(10) 1_645 . ?
C13 C14 C15 110.0(11) . . ?
N5 C8 C9 112.9(9) . . ?
C15 C4 N2 108.7(12) 1_465 . ?
C24 C25 C25 113.2(8) . 2_845 ?
N1 C1 N2 111.3(10) . . ?
C1 N1 C2 103.4(8) . . ?
C1 N1 Ag3 125.4(7) . . ?
C2 N1 Ag3 129.9(6) . . ?
N2 C3 C2 106.2(10) . . ?
C5 N5 C7 106.2(9) . . ?
C5 N5 C8 126.1(9) . . ?
C7 N5 C8 127.7(9) . . ?
N10 C19 C20 112.6(7) . . ?
C6 C7 N5 107.2(9) . . ?
C17 C18 N10 105.6(7) . . ?
C20 C20 C19 114.1(9) 2_655 . ?
N9 C16 N10 111.6(7) . . ?
C18 C17 N9 110.8(8) . . ?
C8 C9 C9 112.3(11) . 2_756 ?
N3 C10 N4 110.6(9) . . ?
C11 C12 N4 107.1(9) . . ?
C7 C6 N6 108.6(10) . . ?
N6 C5 N5 111.6(8) . . ?
C10 N3 C11 106.2(8) . . ?
C10 N3 Ag3 129.6(7) . . ?
C11 N3 Ag3 123.9(6) . . ?
C21 N7 C22 103.5(7) . . ?
C21 N7 Ag5 128.8(6) . . ?
C22 N7 Ag5 127.5(6) . . ?
C21 N8 C23 105.8(7) . . ?
C21 N8 C24 126.7(7) . . ?
C23 N8 C24 127.5(7) . . ?
C10 N4 C12 107.5(8) . . ?
C10 N4 C13 124.4(9) . . ?
C12 N4 C13 128.1(10) . . ?
C3 N2 C1 108.6(9) . . ?
C3 N2 C4 116.2(11) . . ?
C1 N2 C4 133.0(11) . . ?
C16 N10 C18 107.7(7) . . ?
C16 N10 C19 127.9(7) . . ?
C18 N10 C19 124.3(7) . . ?
C3 C2 N1 110.4(10) . . ?
C16 N9 C17 104.3(7) . . ?
C16 N9 Ag5 131.0(6) . . ?
C17 N9 Ag5 124.6(6) . . ?
C5 N6 C6 106.4(8) . . ?
C5 N6 Ag4 126.4(6) . . ?
C6 N6 Ag4 125.7(7) . . ?
V1 O2 V2 134.4(3) . . ?
V1 O3 V4 132.2(3) . . ?
V3 O4 V4 133.9(4) . . ?
V3 O5 V2 137.6(3) . . ?
V2 O6 Ag1 125.4(3) . . ?
V4 O7 Ag2 129.2(3) . 2_755 ?
V3 O9 Ag2 166.3(4) . . ?
V3 O9 Ag1 111.1(3) . . ?
Ag2 O9 Ag1 81.77(19) . . ?
V1 O10 Ag2 118.7(3) . 2_755 ?
V1 O12 Ag3 136.1(3) . . ?
O12 V1 O10 109.7(3) . . ?
O12 V1 O3 108.7(3) . . ?
O10 V1 O3 109.4(3) . . ?
O12 V1 O2 109.1(3) . . ?
O10 V1 O2 110.7(3) . . ?
O3 V1 O2 109.3(3) . . ?
O1 V2 O6 109.7(3) . . ?
O1 V2 O2 109.3(3) . . ?
O6 V2 O2 109.1(3) . . ?
O1 V2 O5 108.8(3) . . ?
O6 V2 O5 109.5(3) . . ?
O2 V2 O5 110.4(3) . . ?
O8 V3 O9 109.0(3) . . ?
O8 V3 O5 108.6(3) . . ?
O9 V3 O5 108.5(3) . . ?
O8 V3 O4 109.7(3) . . ?
O9 V3 O4 111.0(3) . . ?
O5 V3 O4 110.0(3) . . ?
O11 V4 O7 110.3(4) . . ?
O11 V4 O3 108.9(3) . . ?
O7 V4 O3 108.5(3) . . ?
O11 V4 O4 108.7(4) . . ?
O7 V4 O4 110.1(3) . . ?
O3 V4 O4 110.3(3) . . ?

_diffrn_measured_fraction_theta_max 0.989
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.989
_refine_diff_density_max         1.244
_refine_diff_density_min         -1.203
_refine_diff_density_rms         0.135