# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2011
data_global
_journal_name_full               Chem.Commun.
_journal_coden_cambridge         0182
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_name        'Ennio Zangrando'
_publ_contact_author_email       ezangrando@units.it
loop_
_publ_author_name
'Enzo Alessio'
'Elisabetta Iengo'

data_2
_database_code_depnum_ccdc_archive 'CCDC 785342'
#TrackingRef 'Comp_2.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C260 H160 Cl8 N36 O8 Ru4 Zn4, C H Cl3'
_chemical_formula_sum            'C261 H161 Cl11 N36 O8 Ru4 Zn4'
_chemical_formula_weight         4984.97

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0074 0.0035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0136 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0227 0.0128 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.2413 0.3112 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn -0.3198 2.5638 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -0.5010 1.5477 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   20.743(4)
_cell_length_b                   20.688(4)
_cell_length_c                   21.045(3)
_cell_angle_alpha                70.59(2)
_cell_angle_beta                 70.86(2)
_cell_angle_gamma                66.84(3)
_cell_volume                     7626(2)
_cell_formula_units_Z            1
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.085
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2526
_exptl_absorpt_coefficient_mu    1.563
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_correction_T_min  0.3695
_exptl_absorpt_correction_T_max  0.8134
_exptl_absorpt_process_details   
;
Parkin S,Moezzi B & Hope H, (1995) J. Appl. Cryst. 28, 53-56
Quadratic fit to sin(theta)/lambda - 18 parameters
;

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.00000
_diffrn_radiation_type           synchrotron
_diffrn_radiation_source         'Elettra Synchrotron, Trieste (Italy)'
_diffrn_radiation_monochromator  Si111
_diffrn_measurement_device_type  'CCD MarResearch'
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            32030
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_sigmaI/netI    0.0485
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.80
_diffrn_reflns_theta_max         27.11
_reflns_number_total             10433
_reflns_number_gt                8769
_reflns_threshold_expression     >2\s(I)

_computing_data_collection       ?
_computing_cell_refinement       'Denzo (Otwinowski & Minor 1997)'
_computing_data_reduction        'Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_structure_solution    'SHELX97 (Sheldrick, 1998)'
_computing_structure_refinement  'SHELX97 (Sheldrick, 1998)'
_computing_molecular_graphics    'Ortep3/windows (Farrugia,1997)'
_computing_publication_material  'Wingx 1.80.05 (Farrugia, 1999)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2\s(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1725P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0040(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_number_reflns         10433
_refine_ls_number_parameters     1478
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0733
_refine_ls_R_factor_gt           0.0670
_refine_ls_wR_factor_ref         0.2035
_refine_ls_wR_factor_gt          0.1920
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.002

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.24162(4) 0.55288(3) -0.03331(3) 0.0878(4) Uani 1 1 d . . .
Ru2 Ru 0.54656(4) 0.73531(3) 0.36194(3) 0.0811(4) Uani 1 1 d . . .
Cl1 Cl 0.17316(14) 0.67817(13) -0.04864(15) 0.1209(9) Uani 1 1 d . . .
Cl2 Cl 0.31002(14) 0.42767(11) -0.01207(12) 0.1078(8) Uani 1 1 d . . .
Cl3 Cl 0.46360(13) 0.85203(10) 0.32838(11) 0.0965(7) Uani 1 1 d . . .
Cl4 Cl 0.62387(13) 0.61621(12) 0.39778(13) 0.1079(8) Uani 1 1 d . . .
C1R C 0.2535(7) 0.5573(7) -0.1245(7) 0.144(4) Uani 1 1 d . . .
O1 O 0.2699(7) 0.5611(7) -0.1839(6) 0.220(5) Uani 1 1 d . . .
C2R C 0.1608(7) 0.5295(6) -0.0164(6) 0.120(3) Uani 1 1 d . . .
O2 O 0.1085(5) 0.5137(5) -0.0037(5) 0.170(3) Uani 1 1 d . . .
C3R C 0.6156(6) 0.7794(5) 0.3434(5) 0.103(3) Uani 1 1 d . . .
O3 O 0.6546(5) 0.8098(5) 0.3322(5) 0.165(3) Uani 1 1 d . . .
C4R C 0.5181(5) 0.7471(5) 0.4514(5) 0.096(3) Uani 1 1 d . . .
O4 O 0.4994(4) 0.7569(5) 0.5062(4) 0.144(3) Uani 1 1 d . . .
Zn1 Zn 0.46628(4) 0.37186(4) 0.30748(4) 0.0629(4) Uani 1 1 d . . .
Zn2 Zn 0.36113(4) 0.88267(4) 0.01038(4) 0.0620(4) Uani 1 1 d . . .
N1 N 0.4288(3) 0.3480(3) 0.2410(3) 0.0630(15) Uani 1 1 d . . .
N2 N 0.4094(3) 0.4797(3) 0.2746(3) 0.0638(15) Uani 1 1 d . . .
N3 N 0.5255(3) 0.4042(3) 0.3448(3) 0.0681(16) Uani 1 1 d . . .
N4 N 0.5435(3) 0.2728(3) 0.3118(3) 0.0626(15) Uani 1 1 d . . .
N5 N 0.3213(3) 0.9905(3) -0.0354(3) 0.0665(15) Uani 1 1 d . . .
N6 N 0.3348(3) 0.8579(3) -0.0631(3) 0.0683(16) Uani 1 1 d . . .
N7 N 0.4306(3) 0.7775(3) 0.0294(3) 0.0591(14) Uani 1 1 d . . .
N8 N 0.4137(3) 0.9096(3) 0.0610(3) 0.0627(15) Uani 1 1 d . . .
C1 C 0.4956(4) 0.2185(4) 0.2576(4) 0.0669(19) Uani 1 1 d . . .
C2 C 0.4415(4) 0.2804(4) 0.2350(4) 0.070(2) Uani 1 1 d . . .
C3 C 0.3885(4) 0.2820(5) 0.2026(4) 0.080(2) Uani 1 1 d . . .
H3 H 0.3842 0.2417 0.1942 0.096 Uiso 1 1 calc R . .
C4 C 0.3469(4) 0.3514(4) 0.1868(4) 0.077(2) Uani 1 1 d . . .
H4 H 0.3088 0.3700 0.1635 0.093 Uiso 1 1 calc R . .
C5 C 0.3714(4) 0.3912(4) 0.2121(3) 0.0648(19) Uani 1 1 d . . .
C6 C 0.3410(4) 0.4674(4) 0.2067(4) 0.072(2) Uani 1 1 d . . .
C7 C 0.3626(4) 0.5077(4) 0.2338(4) 0.0620(18) Uani 1 1 d . . .
C8 C 0.3350(4) 0.5846(4) 0.2231(4) 0.079(2) Uani 1 1 d . . .
H8 H 0.3024 0.6171 0.1948 0.095 Uiso 1 1 calc R . .
C9 C 0.3649(5) 0.6019(4) 0.2618(4) 0.083(2) Uani 1 1 d . . .
H9 H 0.3563 0.6489 0.2665 0.100 Uiso 1 1 calc R . .
C10 C 0.4111(4) 0.5362(4) 0.2935(4) 0.068(2) Uani 1 1 d . . .
C11 C 0.4505(4) 0.5301(4) 0.3406(4) 0.070(2) Uani 1 1 d . . .
C12 C 0.5040(4) 0.4683(4) 0.3640(4) 0.069(2) Uani 1 1 d . . .
C13 C 0.5466(5) 0.4638(4) 0.4059(4) 0.085(2) Uani 1 1 d . . .
H13 H 0.5410 0.5006 0.4266 0.102 Uiso 1 1 calc R . .
C14 C 0.5972(5) 0.3975(5) 0.4117(4) 0.095(3) Uani 1 1 d . . .
H14 H 0.6342 0.3795 0.4363 0.114 Uiso 1 1 calc R . .
C15 C 0.5841(5) 0.3597(4) 0.3737(4) 0.076(2) Uani 1 1 d . . .
C16 C 0.6227(4) 0.2876(4) 0.3680(4) 0.080(2) Uani 1 1 d . . .
C17 C 0.6032(4) 0.2489(4) 0.3376(4) 0.074(2) Uani 1 1 d . . .
C18 C 0.6454(4) 0.1751(4) 0.3317(4) 0.084(2) Uani 1 1 d . . .
H18 H 0.6898 0.1468 0.3448 0.101 Uiso 1 1 calc R . .
C19 C 0.6075(4) 0.1551(4) 0.3031(4) 0.082(2) Uani 1 1 d . . .
H19 H 0.6196 0.1091 0.2944 0.099 Uiso 1 1 calc R . .
C20 C 0.5459(4) 0.2172(4) 0.2889(4) 0.070(2) Uani 1 1 d . . .
C21 C 0.3575(4) 1.0428(4) 0.0329(4) 0.073(2) Uani 1 1 d . . .
C22 C 0.3258(4) 1.0476(4) -0.0189(4) 0.070(2) Uani 1 1 d . . .
C23 C 0.2982(5) 1.1137(4) -0.0666(5) 0.095(2) Uani 1 1 d . . .
H23 H 0.2955 1.1607 -0.0671 0.114 Uiso 1 1 calc R . .
C24 C 0.2763(5) 1.0958(4) -0.1115(4) 0.099(3) Uani 1 1 d . . .
H24 H 0.2546 1.1281 -0.1485 0.118 Uiso 1 1 calc R . .
C25 C 0.2925(4) 1.0190(4) -0.0918(4) 0.0687(19) Uani 1 1 d . . .
C26 C 0.2785(4) 0.9818(4) -0.1261(4) 0.075(2) Uani 1 1 d . . .
C27 C 0.2956(4) 0.9048(5) -0.1096(4) 0.079(2) Uani 1 1 d . . .
C28 C 0.2808(4) 0.8664(4) -0.1462(4) 0.080(2) Uani 1 1 d . . .
H28 H 0.2544 0.8871 -0.1813 0.096 Uiso 1 1 calc R . .
C29 C 0.3120(4) 0.7948(4) -0.1206(4) 0.080(2) Uani 1 1 d . . .
H29 H 0.3116 0.7557 -0.1345 0.096 Uiso 1 1 calc R . .
C30 C 0.3458(4) 0.7896(4) -0.0686(4) 0.070(2) Uani 1 1 d . . .
C31 C 0.3887(4) 0.7256(4) -0.0337(4) 0.0631(18) Uani 1 1 d . . .
C32 C 0.4285(4) 0.7206(4) 0.0116(4) 0.0643(18) Uani 1 1 d . . .
C33 C 0.4713(5) 0.6543(4) 0.0485(4) 0.086(2) Uani 1 1 d . . .
H33 H 0.4781 0.6069 0.0460 0.103 Uiso 1 1 calc R . .
C34 C 0.5003(4) 0.6711(4) 0.0872(4) 0.075(2) Uani 1 1 d . . .
H34 H 0.5319 0.6384 0.1163 0.091 Uiso 1 1 calc R . .
C35 C 0.4737(4) 0.7482(4) 0.0757(4) 0.0644(19) Uani 1 1 d . . .
C36 C 0.4916(4) 0.7880(4) 0.1067(3) 0.0650(19) Uani 1 1 d . . .
C37 C 0.4621(4) 0.8636(4) 0.1004(4) 0.0668(19) Uani 1 1 d . . .
C38 C 0.4792(5) 0.9043(5) 0.1320(4) 0.082(2) Uani 1 1 d . . .
H38 H 0.5133 0.8857 0.1599 0.098 Uiso 1 1 calc R . .
C39 C 0.4385(4) 0.9735(4) 0.1150(4) 0.077(2) Uani 1 1 d . . .
H39 H 0.4361 1.0125 0.1308 0.092 Uiso 1 1 calc R . .
C40 C 0.3998(4) 0.9774(4) 0.0691(4) 0.0651(19) Uani 1 1 d . . .
N9 N 0.0031(4) 0.2481(3) 0.7582(3) 0.0840(19) Uani 1 1 d . . .
H9A H 0.0228 0.2501 0.7139 0.101 Uiso 1 1 calc R . .
N10 N 0.1224(4) 0.2958(3) 0.6593(4) 0.0812(17) Uani 1 1 d . . .
N11 N 0.1101(4) 0.2399(4) 0.5551(4) 0.0910(19) Uani 1 1 d . . .
H11 H 0.0873 0.2421 0.5981 0.109 Uiso 1 1 calc R . .
N12 N -0.0091(4) 0.1925(4) 0.6538(4) 0.094(2) Uani 1 1 d . . .
C41 C -0.0834(5) 0.1924(4) 0.7719(5) 0.082(2) Uani 1 1 d . . .
C42 C -0.0515(5) 0.2210(4) 0.7955(5) 0.081(2) Uani 1 1 d . . .
C43 C -0.0659(5) 0.2288(5) 0.8658(4) 0.095(2) Uani 1 1 d . . .
H43 H -0.1017 0.2144 0.9036 0.114 Uiso 1 1 calc R . .
C44 C -0.0227(5) 0.2583(5) 0.8693(5) 0.089(2) Uani 1 1 d . . .
H44 H -0.0210 0.2692 0.9091 0.107 Uiso 1 1 calc R . .
C45 C 0.0230(5) 0.2716(4) 0.7998(5) 0.081(2) Uani 1 1 d . . .
C46 C 0.0775(5) 0.3017(4) 0.7815(5) 0.081(2) Uani 1 1 d . . .
C47 C 0.1225(5) 0.3136(4) 0.7156(5) 0.082(2) Uani 1 1 d . . .
C48 C 0.1774(5) 0.3444(5) 0.6997(5) 0.099(3) Uani 1 1 d . . .
H48 H 0.1877 0.3626 0.7299 0.119 Uiso 1 1 calc R . .
C49 C 0.2138(5) 0.3429(5) 0.6306(5) 0.102(3) Uani 1 1 d . . .
H49 H 0.2539 0.3591 0.6048 0.122 Uiso 1 1 calc R . .
C50 C 0.1772(5) 0.3114(4) 0.6067(5) 0.082(2) Uani 1 1 d . . .
C51 C 0.1974(5) 0.2973(4) 0.5426(5) 0.086(2) Uani 1 1 d . . .
C52 C 0.1658(5) 0.2649(5) 0.5185(5) 0.087(2) Uani 1 1 d . . .
C53 C 0.1873(6) 0.2519(6) 0.4500(5) 0.117(3) Uani 1 1 d . . .
H53 H 0.2257 0.2634 0.4137 0.140 Uiso 1 1 calc R . .
C54 C 0.1420(6) 0.2198(6) 0.4471(5) 0.118(3) Uani 1 1 d . . .
H54 H 0.1418 0.2063 0.4082 0.142 Uiso 1 1 calc R . .
C55 C 0.0945(6) 0.2106(5) 0.5151(5) 0.092(3) Uani 1 1 d . . .
C56 C 0.0437(6) 0.1798(6) 0.5322(5) 0.101(3) Uani 1 1 d . . .
C57 C -0.0040(5) 0.1709(5) 0.5969(6) 0.105(3) Uani 1 1 d . . .
C58 C -0.0590(7) 0.1398(7) 0.6150(6) 0.137(4) Uani 1 1 d . . .
H58 H -0.0669 0.1180 0.5862 0.165 Uiso 1 1 calc R . .
C59 C -0.1007(6) 0.1457(6) 0.6826(6) 0.124(3) Uani 1 1 d . . .
H59 H -0.1423 0.1316 0.7067 0.149 Uiso 1 1 calc R . .
C60 C -0.0655(5) 0.1781(5) 0.7062(6) 0.097(3) Uani 1 1 d . . .
N1A N 0.4640(4) 0.6889(3) 0.3794(3) 0.0703(17) Uani 1 1 d . . .
C1A C 0.3965(6) 0.7184(5) 0.4109(4) 0.084(2) Uani 1 1 d . . .
H1A H 0.3843 0.7620 0.4243 0.101 Uiso 1 1 calc R . .
C2A C 0.3431(5) 0.6880(5) 0.4249(4) 0.092(2) Uani 1 1 d . . .
H2A H 0.2956 0.7080 0.4499 0.111 Uiso 1 1 calc R . .
C3A C 0.3626(5) 0.6265(5) 0.4004(4) 0.092(2) Uani 1 1 d . . .
H3A H 0.3272 0.6046 0.4081 0.110 Uiso 1 1 calc R . .
C4A C 0.4316(5) 0.5966(4) 0.3655(4) 0.073(2) Uani 1 1 d . . .
C5A C 0.4815(4) 0.6296(4) 0.3560(4) 0.071(2) Uani 1 1 d . . .
H5A H 0.5297 0.6099 0.3321 0.085 Uiso 1 1 calc R . .
N1B N 0.3391(4) 0.5789(3) -0.0545(3) 0.0730(16) Uani 1 1 d . . .
C1B C 0.4029(6) 0.5411(4) -0.0863(4) 0.087(3) Uani 1 1 d . . .
H1B H 0.4055 0.4998 -0.0987 0.105 Uiso 1 1 calc R . .
C2B C 0.4657(5) 0.5575(5) -0.1027(4) 0.091(2) Uani 1 1 d . . .
H2B H 0.5100 0.5291 -0.1260 0.109 Uiso 1 1 calc R . .
C3B C 0.4611(5) 0.6167(5) -0.0837(4) 0.087(2) Uani 1 1 d . . .
H3B H 0.5034 0.6293 -0.0939 0.104 Uiso 1 1 calc R . .
C4B C 0.3960(5) 0.6589(4) -0.0499(4) 0.070(2) Uani 1 1 d . . .
C5B C 0.3377(5) 0.6358(4) -0.0364(4) 0.070(2) Uani 1 1 d . . .
H5B H 0.2928 0.6625 -0.0123 0.084 Uiso 1 1 calc R . .
N1C N 0.2300(4) 0.5483(3) 0.0724(3) 0.0736(16) Uani 1 1 d . . .
C1C C 0.1647(5) 0.5811(5) 0.1114(5) 0.093(2) Uani 1 1 d . . .
H1C H 0.1245 0.6049 0.0906 0.111 Uiso 1 1 calc R . .
C2C C 0.1554(5) 0.5809(5) 0.1759(6) 0.110(3) Uani 1 1 d . . .
H2C H 0.1098 0.6066 0.2000 0.132 Uiso 1 1 calc R . .
C3C C 0.2123(5) 0.5431(5) 0.2099(5) 0.095(3) Uani 1 1 d . . .
H3C H 0.2050 0.5413 0.2573 0.114 Uiso 1 1 calc R . .
C4C C 0.2800(4) 0.5078(4) 0.1726(4) 0.072(2) Uani 1 1 d . . .
C5C C 0.2834(5) 0.5130(4) 0.1038(4) 0.073(2) Uani 1 1 d . . .
H5C H 0.3283 0.4888 0.0775 0.088 Uiso 1 1 calc R . .
N1D N 0.5776(4) 0.7210(3) 0.2580(3) 0.0761(17) Uani 1 1 d . . .
C1D C 0.6438(6) 0.6840(5) 0.2303(6) 0.098(3) Uani 1 1 d . . .
H1D H 0.6783 0.6616 0.2581 0.118 Uiso 1 1 calc R . .
C2D C 0.6652(5) 0.6763(5) 0.1629(5) 0.105(3) Uani 1 1 d . . .
H2D H 0.7131 0.6491 0.1450 0.126 Uiso 1 1 calc R . .
C3D C 0.6151(5) 0.7094(5) 0.1220(4) 0.087(2) Uani 1 1 d . . .
H3D H 0.6284 0.7051 0.0755 0.104 Uiso 1 1 calc R . .
C4D C 0.5465(4) 0.7482(4) 0.1490(4) 0.072(2) Uani 1 1 d . . .
C5D C 0.5299(4) 0.7506(4) 0.2183(4) 0.075(2) Uani 1 1 d . . .
H5D H 0.4816 0.7747 0.2383 0.090 Uiso 1 1 calc R . .
N1E N 0.3819(3) 0.3481(4) 0.3953(3) 0.0706(15) Uani 1 1 d . . .
C1E C 0.3240(6) 0.3993(5) 0.4173(5) 0.090(2) Uani 1 1 d . . .
H1E H 0.3238 0.4480 0.3994 0.108 Uiso 1 1 calc R . .
C2E C 0.2630(6) 0.3864(5) 0.4652(5) 0.106(3) Uani 1 1 d . . .
H2E H 0.2226 0.4256 0.4787 0.127 Uiso 1 1 calc R . .
C3E C 0.2615(5) 0.3149(5) 0.4935(4) 0.083(2) Uani 1 1 d . . .
C4E C 0.3251(5) 0.2607(5) 0.4694(4) 0.085(2) Uani 1 1 d . . .
H4E H 0.3279 0.2112 0.4860 0.102 Uiso 1 1 calc R . .
C5E C 0.3814(5) 0.2795(5) 0.4229(4) 0.077(2) Uani 1 1 d . . .
H5E H 0.4233 0.2418 0.4088 0.093 Uiso 1 1 calc R . .
C1F C 0.0893(5) 0.3246(5) 0.8375(4) 0.092(2) Uani 1 1 d . . .
C2F C 0.1298(7) 0.2773(7) 0.8827(7) 0.142(4) Uani 1 1 d . . .
H2F H 0.1502 0.2282 0.8799 0.170 Uiso 1 1 calc R . .
C3F C 0.1431(8) 0.2964(9) 0.9323(7) 0.171(6) Uani 1 1 d . . .
H3F H 0.1733 0.2614 0.9618 0.205 Uiso 1 1 calc R . .
C4F C 0.1133(9) 0.3645(12) 0.9388(7) 0.161(5) Uani 1 1 d . . .
H4F H 0.1206 0.3784 0.9740 0.193 Uiso 1 1 calc R . .
C5F C 0.0739(10) 0.4118(9) 0.8961(10) 0.188(6) Uani 1 1 d . . .
H5F H 0.0543 0.4607 0.8999 0.225 Uiso 1 1 calc R . .
C6F C 0.0591(8) 0.3940(7) 0.8451(8) 0.157(5) Uani 1 1 d . . .
H6F H 0.0286 0.4297 0.8161 0.189 Uiso 1 1 calc R . .
C1G C 0.6864(5) 0.2504(5) 0.3983(5) 0.098(3) Uani 1 1 d . . .
C2G C 0.6887(6) 0.1912(6) 0.4523(6) 0.110(3) Uani 1 1 d . . .
H2G H 0.6483 0.1744 0.4706 0.132 Uiso 1 1 calc R . .
C3G C 0.7507(9) 0.1534(7) 0.4823(7) 0.155(5) Uani 1 1 d . . .
H3G H 0.7528 0.1115 0.5193 0.186 Uiso 1 1 calc R . .
C4G C 0.8084(9) 0.1826(9) 0.4531(9) 0.155(5) Uani 1 1 d . . .
H4G H 0.8509 0.1586 0.4705 0.186 Uiso 1 1 calc R . .
C5G C 0.8056(7) 0.2408(10) 0.4038(11) 0.170(5) Uani 1 1 d . . .
H5G H 0.8448 0.2593 0.3885 0.204 Uiso 1 1 calc R . .
C6G C 0.7444(6) 0.2792(6) 0.3708(7) 0.130(3) Uani 1 1 d . . .
H6G H 0.7436 0.3207 0.3335 0.156 Uiso 1 1 calc R . .
C1H C 0.5025(4) 0.1478(4) 0.2464(4) 0.075(2) Uani 1 1 d . . .
C2H C 0.5173(4) 0.1383(4) 0.1796(4) 0.080(2) Uani 1 1 d . . .
H2H H 0.5227 0.1769 0.1403 0.096 Uiso 1 1 calc R . .
C3H C 0.5242(5) 0.0706(5) 0.1716(5) 0.094(2) Uani 1 1 d . . .
H3H H 0.5334 0.0636 0.1267 0.113 Uiso 1 1 calc R . .
C4H C 0.5178(5) 0.0159(5) 0.2275(7) 0.107(3) Uani 1 1 d . . .
H4H H 0.5241 -0.0297 0.2209 0.128 Uiso 1 1 calc R . .
C5H C 0.5027(6) 0.0236(5) 0.2926(6) 0.122(3) Uani 1 1 d . . .
H5H H 0.4983 -0.0161 0.3309 0.147 Uiso 1 1 calc R . .
C6H C 0.4936(5) 0.0898(5) 0.3032(5) 0.104(3) Uani 1 1 d . . .
H6H H 0.4813 0.0959 0.3490 0.125 Uiso 1 1 calc R . .
N1I N 0.2693(3) 0.8630(4) 0.0892(3) 0.0696(15) Uani 1 1 d . . .
C1I C 0.2055(7) 0.9093(6) 0.0917(6) 0.128(4) Uani 1 1 d . . .
H1I H 0.2005 0.9562 0.0620 0.154 Uiso 1 1 calc R . .
C2I C 0.1421(7) 0.8942(7) 0.1364(7) 0.144(4) Uani 1 1 d . . .
H2I H 0.0965 0.9303 0.1349 0.173 Uiso 1 1 calc R . .
C3I C 0.1460(6) 0.8290(5) 0.1809(5) 0.088(3) Uani 1 1 d . . .
C4I C 0.2150(8) 0.7835(6) 0.1772(6) 0.136(4) Uani 1 1 d . . .
H4I H 0.2231 0.7367 0.2075 0.163 Uiso 1 1 calc R . .
C5I C 0.2729(6) 0.8017(6) 0.1321(6) 0.124(3) Uani 1 1 d . . .
H5I H 0.3191 0.7665 0.1325 0.149 Uiso 1 1 calc R . .
C1J C 0.2405(6) 1.0240(4) -0.1838(6) 0.095(3) Uani 1 1 d . . .
C2J C 0.1647(7) 1.0420(7) -0.1693(7) 0.157(5) Uani 1 1 d . . .
H2J H 0.1372 1.0289 -0.1240 0.189 Uiso 1 1 calc R . .
C3J C 0.1307(11) 1.0826(10) -0.2290(12) 0.188(7) Uani 1 1 d . . .
H3J H 0.0801 1.0947 -0.2222 0.226 Uiso 1 1 calc R . .
C4J C 0.1662(14) 1.1008(8) -0.2866(12) 0.180(8) Uani 1 1 d . . .
H4J H 0.1411 1.1284 -0.3224 0.216 Uiso 1 1 calc R . .
C5J C 0.2415(12) 1.0840(8) -0.3042(7) 0.164(5) Uani 1 1 d . . .
H5J H 0.2663 1.0999 -0.3500 0.197 Uiso 1 1 calc R . .
C6J C 0.2807(8) 1.0401(6) -0.2480(7) 0.133(4) Uani 1 1 d . . .
H6J H 0.3318 1.0243 -0.2570 0.160 Uiso 1 1 calc R . .
C1L C 0.3432(5) 1.1115(4) 0.0510(4) 0.072(2) Uani 1 1 d . . .
C2L C 0.2748(6) 1.1522(5) 0.0726(5) 0.099(3) Uani 1 1 d . . .
H2L H 0.2359 1.1354 0.0794 0.118 Uiso 1 1 calc R . .
C3L C 0.2614(6) 1.2194(6) 0.0849(6) 0.124(3) Uani 1 1 d . . .
H3L H 0.2131 1.2496 0.0967 0.149 Uiso 1 1 calc R . .
C4L C 0.3150(9) 1.2415(5) 0.0805(5) 0.110(3) Uani 1 1 d . . .
H4L H 0.3045 1.2855 0.0926 0.132 Uiso 1 1 calc R . .
C5L C 0.3838(7) 1.2028(6) 0.0592(4) 0.097(3) Uani 1 1 d . . .
H5L H 0.4220 1.2197 0.0545 0.116 Uiso 1 1 calc R . .
C6L C 0.3981(5) 1.1366(5) 0.0440(4) 0.087(2) Uani 1 1 d . . .
H6L H 0.4466 1.1088 0.0286 0.104 Uiso 1 1 calc R . .
C1M C 0.0398(6) 0.1428(9) 0.4817(6) 0.123(4) Uani 1 1 d . . .
C2M C 0.0113(7) 0.1863(10) 0.4264(9) 0.179(6) Uani 1 1 d . . .
H2M H -0.0063 0.2374 0.4198 0.215 Uiso 1 1 calc R . .
C3M C 0.0085(8) 0.1502(11) 0.3755(7) 0.170(5) Uani 1 1 d . . .
H3M H -0.0121 0.1766 0.3364 0.203 Uiso 1 1 calc R . .
C4M C 0.0369(11) 0.0796(13) 0.3902(11) 0.191(6) Uani 1 1 d U . .
H4M H 0.0321 0.0570 0.3602 0.229 Uiso 1 1 calc R . .
C5M C 0.0734(12) 0.0305(12) 0.4423(11) 0.229(8) Uani 1 1 d . . .
H5M H 0.0965 -0.0198 0.4454 0.274 Uiso 1 1 calc R . .
C6M C 0.0701(11) 0.0688(11) 0.4897(9) 0.208(8) Uani 1 1 d . . .
H6M H 0.0900 0.0415 0.5290 0.249 Uiso 1 1 calc R . .
C1S C 0.2861(11) 0.8994(14) 0.2741(10) 0.113(6) Uani 0.50 1 d P . .
H1S H 0.3307 0.9085 0.2720 0.136 Uiso 0.50 1 calc PR . .
Cl1S Cl 0.2478(7) 0.9668(8) 0.2206(6) 0.263(5) Uani 0.50 1 d P . .
Cl2S Cl 0.2431(8) 0.8969(10) 0.3507(8) 0.317(7) Uani 0.50 1 d P . .
Cl3S Cl 0.3130(6) 0.8286(8) 0.2545(7) 0.248(5) Uani 0.50 1 d P . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ru1 0.1138(6) 0.0717(5) 0.1014(6) -0.0257(4) -0.0475(5) -0.0302(4)
Ru2 0.1127(6) 0.0670(5) 0.0889(5) -0.0095(3) -0.0432(4) -0.0451(4)
Cl1 0.1294(19) 0.0840(15) 0.159(2) -0.0152(14) -0.0796(18) -0.0162(13)
Cl2 0.145(2) 0.0683(13) 0.1218(17) -0.0380(12) -0.0271(15) -0.0362(13)
Cl3 0.1352(18) 0.0632(12) 0.1044(14) -0.0202(11) -0.0366(13) -0.0371(12)
Cl4 0.1260(19) 0.0828(15) 0.1381(19) 0.0075(13) -0.0748(16) -0.0480(13)
C1R 0.193(12) 0.157(10) 0.116(8) -0.050(7) -0.078(8) -0.041(8)
O1 0.268(12) 0.268(13) 0.151(8) -0.053(8) -0.094(8) -0.074(10)
C2R 0.124(9) 0.137(9) 0.141(8) -0.062(7) -0.052(7) -0.042(7)
O2 0.153(7) 0.188(9) 0.218(9) -0.080(7) -0.053(7) -0.069(6)
C3R 0.130(8) 0.087(6) 0.124(7) -0.017(5) -0.047(6) -0.059(6)
O3 0.174(8) 0.137(7) 0.234(9) -0.028(6) -0.073(7) -0.093(6)
C4R 0.138(8) 0.105(7) 0.077(6) -0.030(5) -0.022(5) -0.065(6)
O4 0.174(7) 0.190(8) 0.109(5) -0.044(5) -0.039(5) -0.085(6)
Zn1 0.0749(7) 0.0546(6) 0.0675(6) -0.0150(4) -0.0144(5) -0.0298(5)
Zn2 0.0705(6) 0.0507(6) 0.0642(6) -0.0164(4) -0.0100(5) -0.0206(4)
N1 0.080(4) 0.049(4) 0.072(4) -0.015(3) -0.019(3) -0.030(3)
N2 0.077(4) 0.053(4) 0.072(4) -0.015(3) -0.018(4) -0.031(3)
N3 0.073(4) 0.065(4) 0.074(4) -0.015(3) -0.014(4) -0.033(3)
N4 0.070(4) 0.055(4) 0.075(4) -0.023(3) -0.018(3) -0.025(3)
N5 0.078(4) 0.055(4) 0.069(4) -0.014(3) -0.018(3) -0.021(3)
N6 0.087(4) 0.055(4) 0.067(4) -0.016(3) -0.023(4) -0.020(3)
N7 0.065(4) 0.045(4) 0.070(4) -0.019(3) -0.016(3) -0.014(3)
N8 0.062(4) 0.056(4) 0.070(4) -0.025(3) -0.001(3) -0.021(3)
C1 0.079(5) 0.060(6) 0.070(4) -0.018(4) -0.012(4) -0.033(5)
C2 0.088(6) 0.058(6) 0.070(4) -0.012(4) -0.023(4) -0.028(5)
C3 0.089(6) 0.076(7) 0.091(5) -0.018(4) -0.025(5) -0.039(5)
C4 0.081(5) 0.066(6) 0.100(5) -0.021(4) -0.031(5) -0.028(5)
C5 0.078(5) 0.055(5) 0.067(4) -0.017(4) -0.012(4) -0.029(5)
C6 0.081(6) 0.069(6) 0.069(4) -0.019(4) -0.016(4) -0.026(5)
C7 0.069(5) 0.058(6) 0.066(4) -0.016(4) -0.016(4) -0.025(4)
C8 0.096(6) 0.059(6) 0.090(5) -0.014(4) -0.034(5) -0.025(4)
C9 0.114(6) 0.048(5) 0.093(5) -0.017(4) -0.033(5) -0.024(5)
C10 0.085(5) 0.047(5) 0.077(5) -0.011(4) -0.017(5) -0.032(4)
C11 0.083(5) 0.062(6) 0.080(5) -0.019(4) -0.023(5) -0.035(5)
C12 0.080(5) 0.062(6) 0.081(5) -0.019(4) -0.027(5) -0.031(5)
C13 0.112(6) 0.054(6) 0.103(6) -0.020(4) -0.043(5) -0.024(5)
C14 0.120(7) 0.089(7) 0.107(6) -0.016(5) -0.057(6) -0.043(6)
C15 0.088(6) 0.062(6) 0.082(5) -0.013(4) -0.028(5) -0.026(5)
C16 0.088(6) 0.073(6) 0.087(5) -0.021(4) -0.025(5) -0.030(5)
C17 0.083(6) 0.067(6) 0.082(5) -0.025(4) -0.019(5) -0.026(5)
C18 0.091(6) 0.071(6) 0.095(5) -0.032(4) -0.030(5) -0.014(5)
C19 0.097(6) 0.064(5) 0.088(5) -0.022(4) -0.024(5) -0.023(5)
C20 0.070(6) 0.069(6) 0.071(4) -0.014(4) -0.011(4) -0.028(5)
C21 0.085(5) 0.067(6) 0.073(5) -0.023(4) -0.012(5) -0.030(5)
C22 0.091(5) 0.043(5) 0.072(5) -0.015(4) -0.022(4) -0.014(4)
C23 0.123(7) 0.057(6) 0.108(6) -0.019(5) -0.037(6) -0.023(5)
C24 0.146(8) 0.058(6) 0.098(6) -0.009(5) -0.058(6) -0.021(5)
C25 0.076(5) 0.056(6) 0.078(5) -0.021(4) -0.018(4) -0.019(4)
C26 0.099(6) 0.055(6) 0.068(5) -0.014(4) -0.028(4) -0.014(4)
C27 0.095(6) 0.071(7) 0.072(5) -0.027(5) -0.023(5) -0.015(5)
C28 0.097(6) 0.070(6) 0.084(5) -0.020(5) -0.032(5) -0.026(5)
C29 0.092(6) 0.070(7) 0.088(5) -0.024(4) -0.028(5) -0.025(5)
C30 0.088(5) 0.057(6) 0.069(5) -0.024(4) -0.016(5) -0.023(4)
C31 0.075(5) 0.048(5) 0.068(4) -0.019(4) -0.012(4) -0.019(4)
C32 0.072(5) 0.049(5) 0.069(4) -0.016(4) -0.016(4) -0.014(4)
C33 0.106(6) 0.047(5) 0.094(5) -0.019(4) -0.023(5) -0.011(5)
C34 0.082(5) 0.064(6) 0.090(5) -0.023(4) -0.029(4) -0.020(4)
C35 0.072(5) 0.060(6) 0.061(4) -0.016(4) -0.006(4) -0.026(4)
C36 0.067(5) 0.061(6) 0.061(4) -0.011(4) -0.013(4) -0.019(4)
C37 0.078(5) 0.056(6) 0.071(4) -0.013(4) -0.023(4) -0.022(4)
C38 0.100(6) 0.077(7) 0.083(5) -0.009(4) -0.031(5) -0.041(5)
C39 0.101(6) 0.051(6) 0.081(5) -0.011(4) -0.026(5) -0.026(5)
C40 0.074(5) 0.059(6) 0.067(4) -0.015(4) -0.014(4) -0.027(4)
N9 0.094(6) 0.084(4) 0.073(4) -0.028(4) -0.011(4) -0.026(4)
N10 0.087(5) 0.088(5) 0.070(4) -0.029(4) -0.002(4) -0.033(4)
N11 0.091(6) 0.107(5) 0.073(4) -0.025(4) -0.004(5) -0.039(4)
N12 0.095(6) 0.110(5) 0.095(5) -0.038(4) -0.012(5) -0.047(4)
C41 0.065(6) 0.095(6) 0.080(6) -0.021(5) 0.021(5) -0.049(5)
C42 0.063(6) 0.082(5) 0.099(7) -0.022(5) 0.006(6) -0.042(5)
C43 0.094(7) 0.098(6) 0.081(7) -0.027(5) -0.003(5) -0.028(5)
C44 0.079(6) 0.096(6) 0.100(8) -0.036(5) -0.005(6) -0.036(5)
C45 0.076(7) 0.075(5) 0.081(6) -0.017(4) -0.006(6) -0.024(5)
C46 0.074(7) 0.078(5) 0.095(7) -0.029(5) -0.011(6) -0.026(5)
C47 0.061(6) 0.082(6) 0.097(8) -0.027(5) 0.006(6) -0.031(4)
C48 0.095(7) 0.113(7) 0.097(7) -0.036(5) 0.001(6) -0.050(6)
C49 0.095(7) 0.101(7) 0.122(8) -0.038(6) -0.011(6) -0.046(5)
C50 0.084(7) 0.087(6) 0.073(6) -0.017(5) -0.005(6) -0.039(5)
C51 0.080(7) 0.087(6) 0.089(7) -0.015(5) -0.007(6) -0.040(5)
C52 0.079(7) 0.105(6) 0.078(6) -0.018(5) 0.006(6) -0.052(5)
C53 0.100(7) 0.172(10) 0.096(8) -0.039(6) 0.014(6) -0.083(7)
C54 0.117(8) 0.161(10) 0.097(8) -0.043(6) -0.006(7) -0.071(7)
C55 0.083(8) 0.128(7) 0.079(7) -0.027(5) 0.008(7) -0.067(6)
C56 0.079(8) 0.153(9) 0.079(7) -0.040(6) 0.019(7) -0.065(7)
C57 0.060(7) 0.132(8) 0.145(11) -0.034(7) -0.003(8) -0.069(6)
C58 0.129(10) 0.200(12) 0.097(8) -0.063(7) -0.004(7) -0.062(9)
C59 0.108(8) 0.166(10) 0.130(9) -0.049(7) 0.006(7) -0.092(7)
C60 0.073(7) 0.117(7) 0.103(7) -0.023(6) 0.006(7) -0.056(5)
N1A 0.101(6) 0.057(4) 0.078(4) -0.013(3) -0.034(4) -0.041(4)
C1A 0.096(7) 0.082(6) 0.094(6) -0.030(5) -0.026(6) -0.039(6)
C2A 0.107(7) 0.084(6) 0.098(6) -0.041(5) -0.018(5) -0.030(5)
C3A 0.106(8) 0.088(6) 0.102(6) -0.020(5) -0.025(6) -0.053(6)
C4A 0.072(6) 0.073(5) 0.080(5) -0.027(4) -0.014(5) -0.024(5)
C5A 0.087(6) 0.062(5) 0.076(5) -0.009(4) -0.028(4) -0.034(4)
N1B 0.104(6) 0.047(4) 0.081(4) -0.022(3) -0.025(4) -0.027(4)
C1B 0.125(8) 0.054(5) 0.087(5) -0.032(4) -0.025(6) -0.019(6)
C2B 0.090(7) 0.082(7) 0.101(6) -0.034(5) 0.001(5) -0.036(5)
C3B 0.099(7) 0.073(6) 0.091(5) -0.018(5) -0.011(5) -0.041(5)
C4B 0.072(6) 0.068(5) 0.061(4) -0.018(4) -0.007(4) -0.017(5)
C5B 0.077(6) 0.065(5) 0.069(5) -0.023(4) -0.012(4) -0.022(4)
N1C 0.086(5) 0.060(4) 0.085(4) -0.026(3) -0.031(5) -0.018(3)
C1C 0.103(8) 0.090(6) 0.089(6) -0.026(5) -0.035(6) -0.020(5)
C2C 0.090(7) 0.112(7) 0.126(9) -0.051(6) -0.027(6) -0.008(6)
C3C 0.091(7) 0.114(7) 0.090(6) -0.046(5) -0.017(6) -0.030(6)
C4C 0.076(6) 0.062(5) 0.083(6) -0.024(4) -0.015(5) -0.025(4)
C5C 0.089(6) 0.060(5) 0.077(6) -0.021(4) -0.027(5) -0.020(4)
N1D 0.086(5) 0.058(4) 0.091(4) -0.008(3) -0.040(5) -0.020(4)
C1D 0.088(7) 0.082(6) 0.134(9) -0.018(6) -0.053(6) -0.019(6)
C2D 0.090(7) 0.107(7) 0.109(7) -0.041(6) -0.025(6) -0.009(5)
C3D 0.081(6) 0.089(6) 0.093(6) -0.023(5) -0.024(6) -0.025(5)
C4D 0.075(6) 0.062(5) 0.080(6) -0.019(4) -0.016(5) -0.022(5)
C5D 0.086(6) 0.059(5) 0.087(6) -0.019(4) -0.022(5) -0.025(4)
N1E 0.080(5) 0.065(5) 0.069(4) -0.020(4) -0.006(3) -0.031(4)
C1E 0.090(7) 0.073(6) 0.096(6) -0.020(5) 0.012(6) -0.042(6)
C2E 0.114(9) 0.080(7) 0.111(7) -0.024(5) -0.008(7) -0.032(5)
C3E 0.096(7) 0.080(6) 0.081(5) -0.017(5) -0.012(6) -0.043(6)
C4E 0.089(7) 0.077(6) 0.084(5) -0.010(5) -0.001(5) -0.042(6)
C5E 0.081(6) 0.067(6) 0.079(5) -0.015(4) -0.008(5) -0.029(4)
C1F 0.092(6) 0.093(7) 0.086(6) -0.030(5) 0.004(5) -0.038(5)
C2F 0.157(10) 0.119(9) 0.154(10) -0.050(8) -0.070(9) -0.005(8)
C3F 0.213(14) 0.161(13) 0.167(12) -0.072(10) -0.100(11) -0.014(11)
C4F 0.172(13) 0.238(19) 0.121(10) -0.083(12) -0.017(9) -0.093(13)
C5F 0.255(18) 0.146(13) 0.215(15) -0.096(12) -0.096(14) -0.038(12)
C6F 0.194(12) 0.105(10) 0.190(12) -0.054(8) -0.084(10) -0.016(8)
C1G 0.107(8) 0.070(6) 0.123(7) -0.038(6) -0.041(7) -0.010(6)
C2G 0.119(8) 0.098(8) 0.120(7) -0.038(7) -0.055(7) -0.009(6)
C3G 0.198(14) 0.116(9) 0.142(10) -0.058(8) -0.072(11) 0.010(10)
C4G 0.164(14) 0.138(12) 0.190(14) -0.024(10) -0.084(12) -0.052(11)
C5G 0.124(11) 0.167(14) 0.251(18) -0.080(13) -0.069(12) -0.032(10)
C6G 0.107(8) 0.119(8) 0.179(10) -0.039(7) -0.049(8) -0.033(7)
C1H 0.080(5) 0.068(6) 0.089(6) -0.023(5) -0.022(4) -0.029(4)
C2H 0.080(5) 0.075(6) 0.097(6) -0.032(4) -0.008(4) -0.035(4)
C3H 0.095(6) 0.088(7) 0.114(7) -0.049(7) -0.008(5) -0.036(5)
C4H 0.131(8) 0.072(7) 0.135(9) -0.039(7) -0.040(7) -0.030(5)
C5H 0.194(11) 0.069(7) 0.125(9) 0.011(6) -0.067(7) -0.066(6)
C6H 0.159(9) 0.068(6) 0.097(6) -0.009(5) -0.041(6) -0.046(5)
N1I 0.068(5) 0.053(4) 0.076(4) -0.006(4) -0.006(3) -0.024(4)
C1I 0.099(9) 0.091(7) 0.139(9) 0.010(6) -0.013(8) -0.015(8)
C2I 0.090(9) 0.106(9) 0.169(10) 0.011(8) -0.008(9) -0.017(6)
C3I 0.092(8) 0.076(6) 0.098(7) -0.034(6) -0.013(6) -0.026(6)
C4I 0.105(9) 0.087(7) 0.144(9) 0.009(6) 0.023(8) -0.031(8)
C5I 0.081(8) 0.092(8) 0.140(8) 0.005(7) 0.004(7) -0.016(6)
C1J 0.124(9) 0.067(5) 0.103(8) -0.021(5) -0.041(7) -0.025(6)
C2J 0.123(10) 0.160(11) 0.156(10) -0.044(9) -0.055(9) 0.013(8)
C3J 0.155(15) 0.165(14) 0.222(17) -0.008(13) -0.108(16) -0.005(11)
C4J 0.23(2) 0.114(10) 0.189(17) 0.036(11) -0.113(19) -0.056(12)
C5J 0.241(18) 0.172(13) 0.120(10) -0.007(9) -0.047(13) -0.126(13)
C6J 0.186(12) 0.133(9) 0.112(9) 0.012(7) -0.071(10) -0.087(8)
C1L 0.086(6) 0.057(5) 0.081(5) -0.024(4) -0.016(5) -0.026(5)
C2L 0.118(8) 0.069(6) 0.122(7) -0.042(5) -0.037(6) -0.020(6)
C3L 0.123(9) 0.099(8) 0.164(10) -0.064(7) -0.053(8) -0.007(7)
C4L 0.165(11) 0.073(6) 0.104(7) -0.031(5) -0.041(7) -0.032(8)
C5L 0.130(9) 0.084(7) 0.085(6) -0.011(5) -0.022(6) -0.053(7)
C6L 0.111(7) 0.069(6) 0.077(5) -0.018(4) -0.006(5) -0.037(5)
C1M 0.099(8) 0.191(13) 0.100(8) -0.053(9) 0.012(7) -0.079(8)
C2M 0.135(11) 0.245(18) 0.182(14) -0.096(14) -0.034(10) -0.052(11)
C3M 0.155(12) 0.232(18) 0.143(10) -0.060(12) -0.032(9) -0.072(12)
C4M 0.193(10) 0.217(11) 0.200(10) -0.069(9) -0.042(8) -0.090(8)
C5M 0.29(2) 0.206(19) 0.221(17) -0.102(16) -0.027(17) -0.091(17)
C6M 0.32(2) 0.184(17) 0.175(13) -0.082(13) -0.052(14) -0.105(16)
C1S 0.105(14) 0.16(2) 0.093(13) -0.050(14) -0.028(12) -0.037(13)
Cl1S 0.236(11) 0.321(16) 0.233(10) -0.035(10) -0.027(9) -0.137(11)
Cl2S 0.284(14) 0.41(2) 0.277(14) -0.114(14) -0.124(12) -0.048(14)
Cl3S 0.203(9) 0.296(15) 0.258(11) -0.047(10) -0.070(8) -0.093(10)

_geom_special_details            
;
All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell s.u.'s are taken
into account individually in the estimation of s.u.'s in distances, angles
and torsion angles; correlations between s.u.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C2R 1.817(13) . ?
Ru1 C1R 1.828(12) . ?
Ru1 N1C 2.130(6) . ?
Ru1 N1B 2.164(6) . ?
Ru1 Cl2 2.383(2) . ?
Ru1 Cl1 2.385(3) . ?
Ru2 C4R 1.848(10) . ?
Ru2 C3R 1.860(10) . ?
Ru2 N1A 2.153(6) . ?
Ru2 N1D 2.154(6) . ?
Ru2 Cl4 2.379(2) . ?
Ru2 Cl3 2.385(2) . ?
C1R O1 1.166(13) . ?
C2R O2 1.179(11) . ?
C3R O3 1.133(10) . ?
C4R O4 1.149(9) . ?
Zn1 N4 2.041(6) . ?
Zn1 N3 2.051(6) . ?
Zn1 N1 2.069(5) . ?
Zn1 N2 2.070(6) . ?
Zn1 N1E 2.161(6) . ?
Zn2 N5 2.057(6) . ?
Zn2 N6 2.062(5) . ?
Zn2 N8 2.065(5) . ?
Zn2 N7 2.075(5) . ?
Zn2 N1I 2.153(6) . ?
N1 C2 1.357(9) . ?
N1 C5 1.366(9) . ?
N2 C7 1.338(8) . ?
N2 C10 1.369(8) . ?
N3 C12 1.376(9) . ?
N3 C15 1.387(9) . ?
N4 C17 1.361(9) . ?
N4 C20 1.366(9) . ?
N5 C25 1.355(8) . ?
N5 C22 1.381(8) . ?
N6 C27 1.352(9) . ?
N6 C30 1.380(9) . ?
N7 C35 1.366(8) . ?
N7 C32 1.368(8) . ?
N8 C37 1.368(9) . ?
N8 C40 1.374(8) . ?
C1 C20 1.392(10) . ?
C1 C2 1.394(10) . ?
C1 C1H 1.504(10) . ?
C2 C3 1.457(10) . ?
C3 C4 1.346(10) . ?
C4 C5 1.420(9) . ?
C5 C6 1.429(10) . ?
C6 C7 1.412(10) . ?
C6 C4C 1.477(10) . ?
C7 C8 1.428(10) . ?
C8 C9 1.372(10) . ?
C9 C10 1.416(10) . ?
C10 C11 1.426(10) . ?
C11 C12 1.391(10) . ?
C11 C4A 1.497(10) . ?
C12 C13 1.398(10) . ?
C13 C14 1.356(11) . ?
C14 C15 1.432(10) . ?
C15 C16 1.413(11) . ?
C16 C17 1.406(10) . ?
C16 C1G 1.474(12) . ?
C17 C18 1.454(10) . ?
C18 C19 1.371(10) . ?
C19 C20 1.441(10) . ?
C21 C22 1.406(10) . ?
C21 C40 1.414(10) . ?
C21 C1L 1.485(10) . ?
C22 C23 1.434(10) . ?
C23 C24 1.372(11) . ?
C24 C25 1.428(10) . ?
C25 C26 1.372(10) . ?
C26 C27 1.433(11) . ?
C26 C1J 1.497(12) . ?
C27 C28 1.439(10) . ?
C28 C29 1.359(10) . ?
C29 C30 1.438(10) . ?
C30 C31 1.393(10) . ?
C31 C32 1.409(9) . ?
C31 C4B 1.468(10) . ?
C32 C33 1.435(10) . ?
C33 C34 1.350(10) . ?
C34 C35 1.431(10) . ?
C35 C36 1.414(9) . ?
C36 C37 1.413(10) . ?
C36 C4D 1.486(10) . ?
C37 C38 1.429(10) . ?
C38 C39 1.341(10) . ?
C39 C40 1.411(10) . ?
N9 C42 1.357(10) . ?
N9 C45 1.361(10) . ?
N10 C47 1.353(10) . ?
N10 C50 1.359(10) . ?
N11 C52 1.350(10) . ?
N11 C55 1.359(10) . ?
N12 C57 1.372(11) . ?
N12 C60 1.373(11) . ?
C41 C42 1.323(11) . ?
C41 C60 1.409(12) . ?
C41 C3I 1.478(12) 2_566 ?
C42 C43 1.463(11) . ?
C43 C44 1.298(11) . ?
C44 C45 1.462(11) . ?
C45 C46 1.387(11) . ?
C46 C47 1.401(11) . ?
C46 C1F 1.523(11) . ?
C47 C48 1.412(11) . ?
C48 C49 1.408(12) . ?
C49 C50 1.451(11) . ?
C50 C51 1.370(11) . ?
C51 C52 1.388(11) . ?
C51 C3E 1.482(11) . ?
C52 C53 1.446(12) . ?
C53 C54 1.371(12) . ?
C54 C55 1.448(12) . ?
C55 C56 1.331(12) . ?
C56 C57 1.400(13) . ?
C56 C1M 1.538(14) . ?
C57 C58 1.410(13) . ?
C58 C59 1.418(13) . ?
C59 C60 1.440(12) . ?
N1A C1A 1.327(10) . ?
N1A C5A 1.346(9) . ?
C1A C2A 1.386(11) . ?
C2A C3A 1.393(11) . ?
C3A C4A 1.373(11) . ?
C4A C5A 1.382(10) . ?
N1B C1B 1.328(11) . ?
N1B C5B 1.339(9) . ?
C1B C2B 1.381(11) . ?
C2B C3B 1.369(11) . ?
C3B C4B 1.396(11) . ?
C4B C5B 1.383(10) . ?
N1C C5C 1.313(9) . ?
N1C C1C 1.373(10) . ?
C1C C2C 1.306(12) . ?
C2C C3C 1.404(12) . ?
C3C C4C 1.406(11) . ?
C4C C5C 1.396(10) . ?
N1D C1D 1.325(11) . ?
N1D C5D 1.335(9) . ?
C1D C2D 1.384(12) . ?
C2D C3D 1.387(11) . ?
C3D C4D 1.365(10) . ?
C4D C5D 1.397(10) . ?
N1E C1E 1.320(10) . ?
N1E C5E 1.347(9) . ?
C1E C2E 1.392(12) . ?
C2E C3E 1.407(12) . ?
C3E C4E 1.425(12) . ?
C4E C5E 1.351(10) . ?
C1F C2F 1.352(13) . ?
C1F C6F 1.364(14) . ?
C2F C3F 1.367(15) . ?
C3F C4F 1.331(19) . ?
C4F C5F 1.306(19) . ?
C5F C6F 1.396(18) . ?
C1G C2G 1.364(13) . ?
C1G C6G 1.419(13) . ?
C2G C3G 1.442(15) . ?
C3G C4G 1.420(18) . ?
C4G C5G 1.298(18) . ?
C5G C6G 1.463(17) . ?
C1H C2H 1.400(10) . ?
C1H C6H 1.407(11) . ?
C2H C3H 1.414(11) . ?
C3H C4H 1.346(12) . ?
C4H C5H 1.351(13) . ?
C5H C6H 1.391(12) . ?
N1I C5I 1.279(11) . ?
N1I C1I 1.290(12) . ?
C1I C2I 1.425(14) . ?
C2I C3I 1.350(13) . ?
C3I C4I 1.362(14) . ?
C3I C41 1.478(12) 2_566 ?
C4I C5I 1.363(13) . ?
C1J C6J 1.347(14) . ?
C1J C2J 1.416(14) . ?
C2J C3J 1.481(19) . ?
C3J C4J 1.22(2) . ?
C4J C5J 1.41(2) . ?
C5J C6J 1.491(18) . ?
C1L C2L 1.350(11) . ?
C1L C6L 1.377(11) . ?
C2L C3L 1.402(12) . ?
C3L C4L 1.325(14) . ?
C4L C5L 1.341(13) . ?
C5L C6L 1.405(12) . ?
C1M C2M 1.361(18) . ?
C1M C6M 1.38(2) . ?
C2M C3M 1.522(19) . ?
C3M C4M 1.31(2) . ?
C4M C5M 1.42(2) . ?
C5M C6M 1.44(2) . ?
C1S Cl3S 1.49(2) . ?
C1S Cl2S 1.56(2) . ?
C1S Cl1S 1.59(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2R Ru1 C1R 87.4(5) . . ?
C2R Ru1 N1C 93.9(4) . . ?
C1R Ru1 N1C 178.7(4) . . ?
C2R Ru1 N1B 178.8(4) . . ?
C1R Ru1 N1B 92.0(4) . . ?
N1C Ru1 N1B 86.7(2) . . ?
C2R Ru1 Cl2 89.8(3) . . ?
C1R Ru1 Cl2 91.8(4) . . ?
N1C Ru1 Cl2 88.19(18) . . ?
N1B Ru1 Cl2 89.22(18) . . ?
C2R Ru1 Cl1 90.7(3) . . ?
C1R Ru1 Cl1 91.2(4) . . ?
N1C Ru1 Cl1 88.84(18) . . ?
N1B Ru1 Cl1 90.24(18) . . ?
Cl2 Ru1 Cl1 177.01(8) . . ?
C4R Ru2 C3R 88.9(4) . . ?
C4R Ru2 N1A 92.5(3) . . ?
C3R Ru2 N1A 177.0(3) . . ?
C4R Ru2 N1D 178.8(3) . . ?
C3R Ru2 N1D 92.3(3) . . ?
N1A Ru2 N1D 86.3(2) . . ?
C4R Ru2 Cl4 90.5(3) . . ?
C3R Ru2 Cl4 94.7(3) . . ?
N1A Ru2 Cl4 87.98(19) . . ?
N1D Ru2 Cl4 89.70(19) . . ?
C4R Ru2 Cl3 89.0(3) . . ?
C3R Ru2 Cl3 88.5(3) . . ?
N1A Ru2 Cl3 88.88(19) . . ?
N1D Ru2 Cl3 90.74(19) . . ?
Cl4 Ru2 Cl3 176.80(7) . . ?
O1 C1R Ru1 170.9(12) . . ?
O2 C2R Ru1 178.4(11) . . ?
O3 C3R Ru2 176.1(9) . . ?
O4 C4R Ru2 177.6(9) . . ?
N4 Zn1 N3 89.5(2) . . ?
N4 Zn1 N1 88.2(2) . . ?
N3 Zn1 N1 161.9(2) . . ?
N4 Zn1 N2 162.4(2) . . ?
N3 Zn1 N2 88.5(3) . . ?
N1 Zn1 N2 88.4(2) . . ?
N4 Zn1 N1E 101.5(2) . . ?
N3 Zn1 N1E 105.0(2) . . ?
N1 Zn1 N1E 93.1(2) . . ?
N2 Zn1 N1E 95.8(2) . . ?
N5 Zn2 N6 88.7(2) . . ?
N5 Zn2 N8 89.1(2) . . ?
N6 Zn2 N8 163.2(2) . . ?
N5 Zn2 N7 160.7(2) . . ?
N6 Zn2 N7 88.2(2) . . ?
N8 Zn2 N7 88.4(2) . . ?
N5 Zn2 N1I 102.5(3) . . ?
N6 Zn2 N1I 93.3(2) . . ?
N8 Zn2 N1I 103.5(2) . . ?
N7 Zn2 N1I 96.6(2) . . ?
C2 N1 C5 105.6(5) . . ?
C2 N1 Zn1 125.2(5) . . ?
C5 N1 Zn1 126.4(5) . . ?
C7 N2 C10 106.8(6) . . ?
C7 N2 Zn1 127.7(5) . . ?
C10 N2 Zn1 125.4(5) . . ?
C12 N3 C15 105.4(6) . . ?
C12 N3 Zn1 126.1(5) . . ?
C15 N3 Zn1 126.2(5) . . ?
C17 N4 C20 106.2(6) . . ?
C17 N4 Zn1 127.0(5) . . ?
C20 N4 Zn1 126.8(5) . . ?
C25 N5 C22 106.4(5) . . ?
C25 N5 Zn2 127.1(5) . . ?
C22 N5 Zn2 126.2(5) . . ?
C27 N6 C30 106.3(6) . . ?
C27 N6 Zn2 126.8(5) . . ?
C30 N6 Zn2 126.4(5) . . ?
C35 N7 C32 106.3(5) . . ?
C35 N7 Zn2 126.4(5) . . ?
C32 N7 Zn2 125.5(5) . . ?
C37 N8 C40 105.8(5) . . ?
C37 N8 Zn2 127.6(5) . . ?
C40 N8 Zn2 126.2(5) . . ?
C20 C1 C2 124.5(6) . . ?
C20 C1 C1H 116.6(7) . . ?
C2 C1 C1H 118.8(6) . . ?
N1 C2 C1 125.7(7) . . ?
N1 C2 C3 109.5(7) . . ?
C1 C2 C3 124.8(7) . . ?
C4 C3 C2 107.0(6) . . ?
C3 C4 C5 106.1(6) . . ?
N1 C5 C4 111.7(6) . . ?
N1 C5 C6 123.8(6) . . ?
C4 C5 C6 124.5(7) . . ?
C7 C6 C5 125.5(7) . . ?
C7 C6 C4C 116.4(7) . . ?
C5 C6 C4C 118.0(6) . . ?
N2 C7 C6 125.3(7) . . ?
N2 C7 C8 110.5(6) . . ?
C6 C7 C8 124.1(7) . . ?
C9 C8 C7 106.1(6) . . ?
C8 C9 C10 106.6(6) . . ?
N2 C10 C9 109.9(6) . . ?
N2 C10 C11 125.6(7) . . ?
C9 C10 C11 124.5(7) . . ?
C12 C11 C10 125.2(6) . . ?
C12 C11 C4A 118.9(6) . . ?
C10 C11 C4A 115.9(7) . . ?
N3 C12 C11 123.9(6) . . ?
N3 C12 C13 110.6(7) . . ?
C11 C12 C13 125.3(7) . . ?
C14 C13 C12 107.9(7) . . ?
C13 C14 C15 106.7(7) . . ?
N3 C15 C16 124.8(7) . . ?
N3 C15 C14 109.3(7) . . ?
C16 C15 C14 125.9(8) . . ?
C17 C16 C15 124.6(7) . . ?
C17 C16 C1G 118.5(7) . . ?
C15 C16 C1G 116.9(7) . . ?
N4 C17 C16 126.3(7) . . ?
N4 C17 C18 110.9(6) . . ?
C16 C17 C18 122.7(8) . . ?
C19 C18 C17 105.4(7) . . ?
C18 C19 C20 107.1(7) . . ?
N4 C20 C1 125.7(7) . . ?
N4 C20 C19 110.3(6) . . ?
C1 C20 C19 123.9(7) . . ?
C22 C21 C40 124.3(6) . . ?
C22 C21 C1L 116.6(7) . . ?
C40 C21 C1L 119.1(7) . . ?
N5 C22 C21 126.3(6) . . ?
N5 C22 C23 109.6(6) . . ?
C21 C22 C23 123.9(7) . . ?
C24 C23 C22 106.6(7) . . ?
C23 C24 C25 106.6(7) . . ?
N5 C25 C26 126.5(6) . . ?
N5 C25 C24 110.7(6) . . ?
C26 C25 C24 122.8(7) . . ?
C25 C26 C27 124.9(7) . . ?
C25 C26 C1J 118.4(7) . . ?
C27 C26 C1J 116.7(7) . . ?
N6 C27 C26 124.7(7) . . ?
N6 C27 C28 110.6(7) . . ?
C26 C27 C28 124.3(7) . . ?
C29 C28 C27 106.6(6) . . ?
C28 C29 C30 106.8(6) . . ?
N6 C30 C31 125.0(6) . . ?
N6 C30 C29 109.7(6) . . ?
C31 C30 C29 125.0(7) . . ?
C30 C31 C32 125.4(6) . . ?
C30 C31 C4B 116.0(6) . . ?
C32 C31 C4B 118.4(6) . . ?
N7 C32 C31 125.8(6) . . ?
N7 C32 C33 109.2(6) . . ?
C31 C32 C33 124.9(7) . . ?
C34 C33 C32 107.8(7) . . ?
C33 C34 C35 106.1(6) . . ?
N7 C35 C36 125.2(6) . . ?
N7 C35 C34 110.5(6) . . ?
C36 C35 C34 124.2(7) . . ?
C37 C36 C35 125.4(6) . . ?
C37 C36 C4D 116.4(6) . . ?
C35 C36 C4D 118.1(6) . . ?
N8 C37 C36 124.8(6) . . ?
N8 C37 C38 109.2(6) . . ?
C36 C37 C38 126.0(7) . . ?
C39 C38 C37 107.6(6) . . ?
C38 C39 C40 107.0(6) . . ?
N8 C40 C39 110.3(6) . . ?
N8 C40 C21 125.5(6) . . ?
C39 C40 C21 124.0(7) . . ?
C42 N9 C45 109.5(7) . . ?
C47 N10 C50 108.8(7) . . ?
C52 N11 C55 109.4(7) . . ?
C57 N12 C60 110.7(7) . . ?
C42 C41 C60 128.7(9) . . ?
C42 C41 C3I 118.1(8) . 2_566 ?
C60 C41 C3I 113.2(9) . 2_566 ?
C41 C42 N9 126.0(9) . . ?
C41 C42 C43 128.2(10) . . ?
N9 C42 C43 105.8(8) . . ?
C44 C43 C42 110.3(9) . . ?
C43 C44 C45 106.4(8) . . ?
N9 C45 C46 127.1(8) . . ?
N9 C45 C44 108.0(8) . . ?
C46 C45 C44 124.9(9) . . ?
C45 C46 C47 125.5(8) . . ?
C45 C46 C1F 117.5(8) . . ?
C47 C46 C1F 117.0(8) . . ?
N10 C47 C46 126.6(8) . . ?
N10 C47 C48 110.2(7) . . ?
C46 C47 C48 123.2(9) . . ?
C49 C48 C47 106.6(8) . . ?
C48 C49 C50 105.7(8) . . ?
N10 C50 C51 126.4(8) . . ?
N10 C50 C49 108.6(8) . . ?
C51 C50 C49 124.9(10) . . ?
C50 C51 C52 126.9(9) . . ?
C50 C51 C3E 118.1(8) . . ?
C52 C51 C3E 114.9(8) . . ?
N11 C52 C51 125.8(8) . . ?
N11 C52 C53 108.4(8) . . ?
C51 C52 C53 125.8(10) . . ?
C54 C53 C52 107.2(9) . . ?
C53 C54 C55 106.4(9) . . ?
C56 C55 N11 128.0(9) . . ?
C56 C55 C54 123.5(9) . . ?
N11 C55 C54 108.5(8) . . ?
C55 C56 C57 125.3(9) . . ?
C55 C56 C1M 119.9(8) . . ?
C57 C56 C1M 114.5(9) . . ?
N12 C57 C56 127.9(8) . . ?
N12 C57 C58 106.4(9) . . ?
C56 C57 C58 125.7(10) . . ?
C57 C58 C59 110.1(10) . . ?
C58 C59 C60 104.2(9) . . ?
N12 C60 C41 124.1(8) . . ?
N12 C60 C59 108.6(9) . . ?
C41 C60 C59 127.3(10) . . ?
C1A N1A C5A 119.7(6) . . ?
C1A N1A Ru2 121.6(5) . . ?
C5A N1A Ru2 118.7(6) . . ?
N1A C1A C2A 122.6(7) . . ?
C1A C2A C3A 116.6(8) . . ?
C4A C3A C2A 121.7(7) . . ?
C3A C4A C5A 117.3(7) . . ?
C3A C4A C11 120.1(7) . . ?
C5A C4A C11 122.6(7) . . ?
N1A C5A C4A 122.0(7) . . ?
C1B N1B C5B 116.0(7) . . ?
C1B N1B Ru1 123.1(6) . . ?
C5B N1B Ru1 120.8(6) . . ?
N1B C1B C2B 124.7(7) . . ?
C3B C2B C1B 116.9(8) . . ?
C2B C3B C4B 121.7(8) . . ?
C5B C4B C3B 115.0(7) . . ?
C5B C4B C31 122.2(7) . . ?
C3B C4B C31 122.7(8) . . ?
N1B C5B C4B 125.6(7) . . ?
C5C N1C C1C 116.8(6) . . ?
C5C N1C Ru1 122.3(5) . . ?
C1C N1C Ru1 120.8(6) . . ?
C2C C1C N1C 123.0(8) . . ?
C1C C2C C3C 120.5(9) . . ?
C2C C3C C4C 118.9(8) . . ?
C5C C4C C3C 115.2(7) . . ?
C5C C4C C6 124.5(7) . . ?
C3C C4C C6 120.3(7) . . ?
N1C C5C C4C 125.6(7) . . ?
C1D N1D C5D 116.9(7) . . ?
C1D N1D Ru2 122.7(6) . . ?
C5D N1D Ru2 120.4(6) . . ?
N1D C1D C2D 123.4(7) . . ?
C1D C2D C3D 118.4(8) . . ?
C4D C3D C2D 119.6(8) . . ?
C3D C4D C5D 117.3(7) . . ?
C3D C4D C36 122.1(7) . . ?
C5D C4D C36 120.6(7) . . ?
N1D C5D C4D 124.2(7) . . ?
C1E N1E C5E 116.7(7) . . ?
C1E N1E Zn1 122.3(6) . . ?
C5E N1E Zn1 120.2(6) . . ?
N1E C1E C2E 124.0(8) . . ?
C1E C2E C3E 119.6(9) . . ?
C2E C3E C4E 115.2(9) . . ?
C2E C3E C51 122.5(9) . . ?
C4E C3E C51 122.3(8) . . ?
C5E C4E C3E 120.2(8) . . ?
N1E C5E C4E 124.3(7) . . ?
C2F C1F C6F 116.1(10) . . ?
C2F C1F C46 122.1(9) . . ?
C6F C1F C46 121.8(10) . . ?
C1F C2F C3F 123.6(11) . . ?
C4F C3F C2F 119.4(13) . . ?
C5F C4F C3F 118.8(13) . . ?
C4F C5F C6F 123.1(14) . . ?
C1F C6F C5F 118.9(12) . . ?
C2G C1G C6G 121.1(9) . . ?
C2G C1G C16 120.8(10) . . ?
C6G C1G C16 118.1(9) . . ?
C1G C2G C3G 121.9(12) . . ?
C4G C3G C2G 115.8(13) . . ?
C5G C4G C3G 122.8(15) . . ?
C4G C5G C6G 122.7(15) . . ?
C1G C6G C5G 115.6(12) . . ?
C2H C1H C6H 118.8(7) . . ?
C2H C1H C1 120.9(7) . . ?
C6H C1H C1 120.3(7) . . ?
C1H C2H C3H 118.9(8) . . ?
C4H C3H C2H 120.2(8) . . ?
C3H C4H C5H 122.3(8) . . ?
C4H C5H C6H 119.7(9) . . ?
C5H C6H C1H 120.1(8) . . ?
C5I N1I C1I 115.2(9) . . ?
C5I N1I Zn2 122.1(7) . . ?
C1I N1I Zn2 122.2(7) . . ?
N1I C1I C2I 123.7(9) . . ?
C3I C2I C1I 120.8(10) . . ?
C2I C3I C4I 112.6(11) . . ?
C2I C3I C41 124.8(10) . 2_566 ?
C4I C3I C41 122.6(10) . 2_566 ?
C3I C4I C5I 123.1(10) . . ?
N1I C5I C4I 124.5(9) . . ?
C6J C1J C2J 123.0(10) . . ?
C6J C1J C26 118.0(9) . . ?
C2J C1J C26 118.9(10) . . ?
C1J C2J C3J 116.1(13) . . ?
C4J C3J C2J 121(2) . . ?
C3J C4J C5J 125(2) . . ?
C4J C5J C6J 117.4(14) . . ?
C1J C6J C5J 116.9(13) . . ?
C2L C1L C6L 118.3(7) . . ?
C2L C1L C21 120.0(8) . . ?
C6L C1L C21 121.7(8) . . ?
C1L C2L C3L 119.6(9) . . ?
C4L C3L C2L 121.1(10) . . ?
C3L C4L C5L 121.1(9) . . ?
C4L C5L C6L 118.4(9) . . ?
C1L C6L C5L 121.2(8) . . ?
C2M C1M C6M 122.0(13) . . ?
C2M C1M C56 117.3(14) . . ?
C6M C1M C56 120.5(12) . . ?
C1M C2M C3M 117.7(16) . . ?
C4M C3M C2M 114.1(16) . . ?
C3M C4M C5M 132.3(19) . . ?
C4M C5M C6M 109.4(19) . . ?
C1M C6M C5M 124.0(18) . . ?
Cl3S C1S Cl2S 114.0(18) . . ?
Cl3S C1S Cl1S 114.9(13) . . ?
Cl2S C1S Cl1S 113.2(15) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2R Ru1 C1R O1 -172(8) . . . . ?
N1C Ru1 C1R O1 8(26) . . . . ?
N1B Ru1 C1R O1 7(8) . . . . ?
Cl2 Ru1 C1R O1 -82(8) . . . . ?
Cl1 Ru1 C1R O1 98(8) . . . . ?
C1R Ru1 C2R O2 162(34) . . . . ?
N1C Ru1 C2R O2 -18(34) . . . . ?
N1B Ru1 C2R O2 106(37) . . . . ?
Cl2 Ru1 C2R O2 71(34) . . . . ?
Cl1 Ru1 C2R O2 -106(34) . . . . ?
C4R Ru2 C3R O3 -71(13) . . . . ?
N1A Ru2 C3R O3 46(18) . . . . ?
N1D Ru2 C3R O3 108(13) . . . . ?
Cl4 Ru2 C3R O3 -162(13) . . . . ?
Cl3 Ru2 C3R O3 18(13) . . . . ?
C3R Ru2 C4R O4 72(20) . . . . ?
N1A Ru2 C4R O4 -106(20) . . . . ?
N1D Ru2 C4R O4 -95(24) . . . . ?
Cl4 Ru2 C4R O4 166(20) . . . . ?
Cl3 Ru2 C4R O4 -17(20) . . . . ?
N4 Zn1 N1 C2 20.8(6) . . . . ?
N3 Zn1 N1 C2 103.6(9) . . . . ?
N2 Zn1 N1 C2 -176.4(6) . . . . ?
N1E Zn1 N1 C2 -80.7(6) . . . . ?
N4 Zn1 N1 C5 179.2(6) . . . . ?
N3 Zn1 N1 C5 -98.0(9) . . . . ?
N2 Zn1 N1 C5 -18.0(6) . . . . ?
N1E Zn1 N1 C5 77.7(6) . . . . ?
N4 Zn1 N2 C7 86.4(9) . . . . ?
N3 Zn1 N2 C7 170.0(6) . . . . ?
N1 Zn1 N2 C7 7.8(6) . . . . ?
N1E Zn1 N2 C7 -85.1(6) . . . . ?
N4 Zn1 N2 C10 -96.3(9) . . . . ?
N3 Zn1 N2 C10 -12.7(5) . . . . ?
N1 Zn1 N2 C10 -174.9(6) . . . . ?
N1E Zn1 N2 C10 92.2(5) . . . . ?
N4 Zn1 N3 C12 -173.0(5) . . . . ?
N1 Zn1 N3 C12 104.4(9) . . . . ?
N2 Zn1 N3 C12 24.5(5) . . . . ?
N1E Zn1 N3 C12 -71.2(6) . . . . ?
N4 Zn1 N3 C15 -12.6(6) . . . . ?
N1 Zn1 N3 C15 -95.2(9) . . . . ?
N2 Zn1 N3 C15 -175.1(6) . . . . ?
N1E Zn1 N3 C15 89.3(6) . . . . ?
N3 Zn1 N4 C17 4.7(6) . . . . ?
N1 Zn1 N4 C17 166.8(6) . . . . ?
N2 Zn1 N4 C17 88.2(9) . . . . ?
N1E Zn1 N4 C17 -100.5(6) . . . . ?
N3 Zn1 N4 C20 -174.8(5) . . . . ?
N1 Zn1 N4 C20 -12.7(5) . . . . ?
N2 Zn1 N4 C20 -91.3(9) . . . . ?
N1E Zn1 N4 C20 80.0(5) . . . . ?
N6 Zn2 N5 C25 -0.4(6) . . . . ?
N8 Zn2 N5 C25 162.9(5) . . . . ?
N7 Zn2 N5 C25 80.4(9) . . . . ?
N1I Zn2 N5 C25 -93.5(5) . . . . ?
N6 Zn2 N5 C22 -173.0(6) . . . . ?
N8 Zn2 N5 C22 -9.6(6) . . . . ?
N7 Zn2 N5 C22 -92.1(9) . . . . ?
N1I Zn2 N5 C22 94.0(6) . . . . ?
N5 Zn2 N6 C27 -9.2(6) . . . . ?
N8 Zn2 N6 C27 -91.8(10) . . . . ?
N7 Zn2 N6 C27 -170.2(6) . . . . ?
N1I Zn2 N6 C27 93.2(6) . . . . ?
N5 Zn2 N6 C30 179.7(6) . . . . ?
N8 Zn2 N6 C30 97.2(10) . . . . ?
N7 Zn2 N6 C30 18.7(6) . . . . ?
N1I Zn2 N6 C30 -77.8(6) . . . . ?
N5 Zn2 N7 C35 98.1(8) . . . . ?
N6 Zn2 N7 C35 179.0(5) . . . . ?
N8 Zn2 N7 C35 15.5(5) . . . . ?
N1I Zn2 N7 C35 -87.9(5) . . . . ?
N5 Zn2 N7 C32 -99.5(8) . . . . ?
N6 Zn2 N7 C32 -18.6(5) . . . . ?
N8 Zn2 N7 C32 177.8(5) . . . . ?
N1I Zn2 N7 C32 74.4(5) . . . . ?
N5 Zn2 N8 C37 -172.7(5) . . . . ?
N6 Zn2 N8 C37 -90.3(10) . . . . ?
N7 Zn2 N8 C37 -11.8(5) . . . . ?
N1I Zn2 N8 C37 84.6(6) . . . . ?
N5 Zn2 N8 C40 16.4(5) . . . . ?
N6 Zn2 N8 C40 98.8(9) . . . . ?
N7 Zn2 N8 C40 177.3(5) . . . . ?
N1I Zn2 N8 C40 -86.3(5) . . . . ?
C5 N1 C2 C1 179.9(7) . . . . ?
Zn1 N1 C2 C1 -18.0(10) . . . . ?
C5 N1 C2 C3 -1.4(8) . . . . ?
Zn1 N1 C2 C3 160.7(5) . . . . ?
C20 C1 C2 N1 -1.2(12) . . . . ?
C1H C1 C2 N1 -179.6(6) . . . . ?
C20 C1 C2 C3 -179.6(7) . . . . ?
C1H C1 C2 C3 2.0(11) . . . . ?
N1 C2 C3 C4 2.7(8) . . . . ?
C1 C2 C3 C4 -178.6(7) . . . . ?
C2 C3 C4 C5 -2.8(8) . . . . ?
C2 N1 C5 C4 -0.3(8) . . . . ?
Zn1 N1 C5 C4 -162.2(5) . . . . ?
C2 N1 C5 C6 -178.9(6) . . . . ?
Zn1 N1 C5 C6 19.3(10) . . . . ?
C3 C4 C5 N1 2.1(8) . . . . ?
C3 C4 C5 C6 -179.4(7) . . . . ?
N1 C5 C6 C7 -4.2(11) . . . . ?
C4 C5 C6 C7 177.4(7) . . . . ?
N1 C5 C6 C4C 178.4(6) . . . . ?
C4 C5 C6 C4C 0.0(10) . . . . ?
C10 N2 C7 C6 -175.4(7) . . . . ?
Zn1 N2 C7 C6 2.3(10) . . . . ?
C10 N2 C7 C8 2.4(8) . . . . ?
Zn1 N2 C7 C8 -179.9(4) . . . . ?
C5 C6 C7 N2 -7.3(11) . . . . ?
C4C C6 C7 N2 170.1(7) . . . . ?
C5 C6 C7 C8 175.1(7) . . . . ?
C4C C6 C7 C8 -7.4(10) . . . . ?
N2 C7 C8 C9 -2.5(8) . . . . ?
C6 C7 C8 C9 175.3(7) . . . . ?
C7 C8 C9 C10 1.5(8) . . . . ?
C7 N2 C10 C9 -1.4(8) . . . . ?
Zn1 N2 C10 C9 -179.2(5) . . . . ?
C7 N2 C10 C11 175.7(7) . . . . ?
Zn1 N2 C10 C11 -2.1(10) . . . . ?
C8 C9 C10 N2 -0.1(8) . . . . ?
C8 C9 C10 C11 -177.3(7) . . . . ?
N2 C10 C11 C12 13.4(11) . . . . ?
C9 C10 C11 C12 -169.8(7) . . . . ?
N2 C10 C11 C4A -166.8(7) . . . . ?
C9 C10 C11 C4A 9.9(10) . . . . ?
C15 N3 C12 C11 174.1(7) . . . . ?
Zn1 N3 C12 C11 -22.2(10) . . . . ?
C15 N3 C12 C13 -1.8(8) . . . . ?
Zn1 N3 C12 C13 161.9(5) . . . . ?
C10 C11 C12 N3 -0.5(11) . . . . ?
C4A C11 C12 N3 179.7(6) . . . . ?
C10 C11 C12 C13 174.8(7) . . . . ?
C4A C11 C12 C13 -5.0(11) . . . . ?
N3 C12 C13 C14 2.1(9) . . . . ?
C11 C12 C13 C14 -173.8(8) . . . . ?
C12 C13 C14 C15 -1.5(9) . . . . ?
C12 N3 C15 C16 178.9(7) . . . . ?
Zn1 N3 C15 C16 15.3(10) . . . . ?
C12 N3 C15 C14 0.9(8) . . . . ?
Zn1 N3 C15 C14 -162.8(5) . . . . ?
C13 C14 C15 N3 0.4(9) . . . . ?
C13 C14 C15 C16 -177.7(8) . . . . ?
N3 C15 C16 C17 -6.0(12) . . . . ?
C14 C15 C16 C17 171.7(8) . . . . ?
N3 C15 C16 C1G 176.0(8) . . . . ?
C14 C15 C16 C1G -6.2(12) . . . . ?
C20 N4 C17 C16 -178.9(7) . . . . ?
Zn1 N4 C17 C16 1.5(11) . . . . ?
C20 N4 C17 C18 -0.5(8) . . . . ?
Zn1 N4 C17 C18 179.9(5) . . . . ?
C15 C16 C17 N4 -2.9(13) . . . . ?
C1G C16 C17 N4 175.0(8) . . . . ?
C15 C16 C17 C18 178.8(7) . . . . ?
C1G C16 C17 C18 -3.3(12) . . . . ?
N4 C17 C18 C19 -1.7(9) . . . . ?
C16 C17 C18 C19 176.8(7) . . . . ?
C17 C18 C19 C20 3.0(8) . . . . ?
C17 N4 C20 C1 -179.1(7) . . . . ?
Zn1 N4 C20 C1 0.5(10) . . . . ?
C17 N4 C20 C19 2.4(8) . . . . ?
Zn1 N4 C20 C19 -178.0(5) . . . . ?
C2 C1 C20 N4 10.7(12) . . . . ?
C1H C1 C20 N4 -170.8(6) . . . . ?
C2 C1 C20 C19 -170.9(7) . . . . ?
C1H C1 C20 C19 7.5(11) . . . . ?
C18 C19 C20 N4 -3.5(9) . . . . ?
C18 C19 C20 C1 177.9(7) . . . . ?
C25 N5 C22 C21 -174.7(7) . . . . ?
Zn2 N5 C22 C21 -0.9(10) . . . . ?
C25 N5 C22 C23 0.5(8) . . . . ?
Zn2 N5 C22 C23 174.3(5) . . . . ?
C40 C21 C22 N5 10.3(11) . . . . ?
C1L C21 C22 N5 -168.0(7) . . . . ?
C40 C21 C22 C23 -164.3(7) . . . . ?
C1L C21 C22 C23 17.4(11) . . . . ?
N5 C22 C23 C24 0.7(9) . . . . ?
C21 C22 C23 C24 176.0(7) . . . . ?
C22 C23 C24 C25 -1.5(9) . . . . ?
C22 N5 C25 C26 179.9(7) . . . . ?
Zn2 N5 C25 C26 6.2(10) . . . . ?
C22 N5 C25 C24 -1.5(8) . . . . ?
Zn2 N5 C25 C24 -175.2(5) . . . . ?
C23 C24 C25 N5 1.9(9) . . . . ?
C23 C24 C25 C26 -179.4(8) . . . . ?
N5 C25 C26 C27 -3.4(12) . . . . ?
C24 C25 C26 C27 178.1(8) . . . . ?
N5 C25 C26 C1J 174.7(8) . . . . ?
C24 C25 C26 C1J -3.8(12) . . . . ?
C30 N6 C27 C26 -173.2(7) . . . . ?
Zn2 N6 C27 C26 14.4(10) . . . . ?
C30 N6 C27 C28 -0.1(8) . . . . ?
Zn2 N6 C27 C28 -172.6(5) . . . . ?
C25 C26 C27 N6 -7.6(12) . . . . ?
C1J C26 C27 N6 174.3(8) . . . . ?
C25 C26 C27 C28 -179.7(8) . . . . ?
C1J C26 C27 C28 2.2(12) . . . . ?
N6 C27 C28 C29 0.1(9) . . . . ?
C26 C27 C28 C29 173.2(7) . . . . ?
C27 C28 C29 C30 0.0(8) . . . . ?
C27 N6 C30 C31 174.6(7) . . . . ?
Zn2 N6 C30 C31 -12.9(10) . . . . ?
C27 N6 C30 C29 0.1(8) . . . . ?
Zn2 N6 C30 C29 172.6(5) . . . . ?
C28 C29 C30 N6 0.0(8) . . . . ?
C28 C29 C30 C31 -174.6(7) . . . . ?
N6 C30 C31 C32 -1.2(11) . . . . ?
C29 C30 C31 C32 172.5(7) . . . . ?
N6 C30 C31 C4B -176.9(7) . . . . ?
C29 C30 C31 C4B -3.2(10) . . . . ?
C35 N7 C32 C31 178.2(7) . . . . ?
Zn2 N7 C32 C31 12.9(9) . . . . ?
C35 N7 C32 C33 0.4(7) . . . . ?
Zn2 N7 C32 C33 -164.9(5) . . . . ?
C30 C31 C32 N7 1.1(11) . . . . ?
C4B C31 C32 N7 176.7(6) . . . . ?
C30 C31 C32 C33 178.6(7) . . . . ?
C4B C31 C32 C33 -5.8(10) . . . . ?
N7 C32 C33 C34 -1.2(8) . . . . ?
C31 C32 C33 C34 -179.1(7) . . . . ?
C32 C33 C34 C35 1.5(8) . . . . ?
C32 N7 C35 C36 178.9(6) . . . . ?
Zn2 N7 C35 C36 -16.0(9) . . . . ?
C32 N7 C35 C34 0.6(7) . . . . ?
Zn2 N7 C35 C34 165.7(4) . . . . ?
C33 C34 C35 N7 -1.3(8) . . . . ?
C33 C34 C35 C36 -179.7(7) . . . . ?
N7 C35 C36 C37 6.8(11) . . . . ?
C34 C35 C36 C37 -175.0(6) . . . . ?
N7 C35 C36 C4D -172.3(6) . . . . ?
C34 C35 C36 C4D 5.8(10) . . . . ?
C40 N8 C37 C36 -179.6(6) . . . . ?
Zn2 N8 C37 C36 8.0(9) . . . . ?
C40 N8 C37 C38 -1.2(8) . . . . ?
Zn2 N8 C37 C38 -173.6(5) . . . . ?
C35 C36 C37 N8 -2.5(11) . . . . ?
C4D C36 C37 N8 176.7(6) . . . . ?
C35 C36 C37 C38 179.4(7) . . . . ?
C4D C36 C37 C38 -1.5(10) . . . . ?
N8 C37 C38 C39 3.4(8) . . . . ?
C36 C37 C38 C39 -178.2(7) . . . . ?
C37 C38 C39 C40 -4.1(8) . . . . ?
C37 N8 C40 C39 -1.3(8) . . . . ?
Zn2 N8 C40 C39 171.2(5) . . . . ?
C37 N8 C40 C21 174.0(6) . . . . ?
Zn2 N8 C40 C21 -13.5(9) . . . . ?
C38 C39 C40 N8 3.5(8) . . . . ?
C38 C39 C40 C21 -171.9(7) . . . . ?
C22 C21 C40 N8 -2.5(11) . . . . ?
C1L C21 C40 N8 175.8(6) . . . . ?
C22 C21 C40 C39 172.1(7) . . . . ?
C1L C21 C40 C39 -9.6(11) . . . . ?
C60 C41 C42 N9 5.5(14) . . . . ?
C3I C41 C42 N9 -175.2(7) 2_566 . . . ?
C60 C41 C42 C43 -173.1(8) . . . . ?
C3I C41 C42 C43 6.2(13) 2_566 . . . ?
C45 N9 C42 C41 -178.9(8) . . . . ?
C45 N9 C42 C43 -0.1(8) . . . . ?
C41 C42 C43 C44 178.8(9) . . . . ?
N9 C42 C43 C44 0.0(9) . . . . ?
C42 C43 C44 C45 0.1(9) . . . . ?
C42 N9 C45 C46 178.9(7) . . . . ?
C42 N9 C45 C44 0.1(8) . . . . ?
C43 C44 C45 N9 -0.1(9) . . . . ?
C43 C44 C45 C46 -178.9(8) . . . . ?
N9 C45 C46 C47 0.2(13) . . . . ?
C44 C45 C46 C47 178.8(7) . . . . ?
N9 C45 C46 C1F 179.6(8) . . . . ?
C44 C45 C46 C1F -1.9(11) . . . . ?
C50 N10 C47 C46 -175.7(7) . . . . ?
C50 N10 C47 C48 2.1(9) . . . . ?
C45 C46 C47 N10 -2.4(13) . . . . ?
C1F C46 C47 N10 178.2(8) . . . . ?
C45 C46 C47 C48 -179.9(8) . . . . ?
C1F C46 C47 C48 0.7(11) . . . . ?
N10 C47 C48 C49 -2.0(9) . . . . ?
C46 C47 C48 C49 176.0(7) . . . . ?
C47 C48 C49 C50 1.0(9) . . . . ?
C47 N10 C50 C51 175.9(8) . . . . ?
C47 N10 C50 C49 -1.4(9) . . . . ?
C48 C49 C50 N10 0.2(9) . . . . ?
C48 C49 C50 C51 -177.2(8) . . . . ?
N10 C50 C51 C52 0.5(14) . . . . ?
C49 C50 C51 C52 177.4(8) . . . . ?
N10 C50 C51 C3E -176.6(7) . . . . ?
C49 C50 C51 C3E 0.3(12) . . . . ?
C55 N11 C52 C51 -179.0(8) . . . . ?
C55 N11 C52 C53 0.7(10) . . . . ?
C50 C51 C52 N11 -1.7(14) . . . . ?
C3E C51 C52 N11 175.5(8) . . . . ?
C50 C51 C52 C53 178.7(9) . . . . ?
C3E C51 C52 C53 -4.2(13) . . . . ?
N11 C52 C53 C54 1.0(11) . . . . ?
C51 C52 C53 C54 -179.3(9) . . . . ?
C52 C53 C54 C55 -2.2(11) . . . . ?
C52 N11 C55 C56 179.5(9) . . . . ?
C52 N11 C55 C54 -2.1(10) . . . . ?
C53 C54 C55 C56 -178.8(10) . . . . ?
C53 C54 C55 N11 2.7(11) . . . . ?
N11 C55 C56 C57 -0.8(16) . . . . ?
C54 C55 C56 C57 -178.9(9) . . . . ?
N11 C55 C56 C1M -173.6(10) . . . . ?
C54 C55 C56 C1M 8.2(15) . . . . ?
C60 N12 C57 C56 176.3(9) . . . . ?
C60 N12 C57 C58 -1.5(11) . . . . ?
C55 C56 C57 N12 1.2(16) . . . . ?
C1M C56 C57 N12 174.4(10) . . . . ?
C55 C56 C57 C58 178.6(10) . . . . ?
C1M C56 C57 C58 -8.2(15) . . . . ?
N12 C57 C58 C59 3.1(12) . . . . ?
C56 C57 C58 C59 -174.7(10) . . . . ?
C57 C58 C59 C60 -3.4(12) . . . . ?
C57 N12 C60 C41 178.4(8) . . . . ?
C57 N12 C60 C59 -0.7(11) . . . . ?
C42 C41 C60 N12 0.0(15) . . . . ?
C3I C41 C60 N12 -179.4(8) 2_566 . . . ?
C42 C41 C60 C59 178.9(10) . . . . ?
C3I C41 C60 C59 -0.5(13) 2_566 . . . ?
C58 C59 C60 N12 2.5(11) . . . . ?
C58 C59 C60 C41 -176.5(10) . . . . ?
C4R Ru2 N1A C1A 46.2(6) . . . . ?
C3R Ru2 N1A C1A -71(7) . . . . ?
N1D Ru2 N1A C1A -133.6(6) . . . . ?
Cl4 Ru2 N1A C1A 136.6(5) . . . . ?
Cl3 Ru2 N1A C1A -42.7(5) . . . . ?
C4R Ru2 N1A C5A -135.6(5) . . . . ?
C3R Ru2 N1A C5A 107(7) . . . . ?
N1D Ru2 N1A C5A 44.6(5) . . . . ?
Cl4 Ru2 N1A C5A -45.2(5) . . . . ?
Cl3 Ru2 N1A C5A 135.4(5) . . . . ?
C5A N1A C1A C2A 4.2(11) . . . . ?
Ru2 N1A C1A C2A -177.6(6) . . . . ?
N1A C1A C2A C3A -3.8(12) . . . . ?
C1A C2A C3A C4A 1.3(12) . . . . ?
C2A C3A C4A C5A 0.6(11) . . . . ?
C2A C3A C4A C11 179.5(7) . . . . ?
C12 C11 C4A C3A -120.7(8) . . . . ?
C10 C11 C4A C3A 59.6(9) . . . . ?
C12 C11 C4A C5A 58.1(10) . . . . ?
C10 C11 C4A C5A -121.6(7) . . . . ?
C1A N1A C5A C4A -2.1(10) . . . . ?
Ru2 N1A C5A C4A 179.7(5) . . . . ?
C3A C4A C5A N1A -0.3(10) . . . . ?
C11 C4A C5A N1A -179.1(6) . . . . ?
C2R Ru1 N1B C1B 1(20) . . . . ?
C1R Ru1 N1B C1B -55.5(7) . . . . ?
N1C Ru1 N1B C1B 124.5(6) . . . . ?
Cl2 Ru1 N1B C1B 36.2(6) . . . . ?
Cl1 Ru1 N1B C1B -146.7(6) . . . . ?
C2R Ru1 N1B C5B 180(100) . . . . ?
C1R Ru1 N1B C5B 123.6(6) . . . . ?
N1C Ru1 N1B C5B -56.4(5) . . . . ?
Cl2 Ru1 N1B C5B -144.7(5) . . . . ?
Cl1 Ru1 N1B C5B 32.4(5) . . . . ?
C5B N1B C1B C2B -1.4(11) . . . . ?
Ru1 N1B C1B C2B 177.8(6) . . . . ?
N1B C1B C2B C3B 0.7(12) . . . . ?
C1B C2B C3B C4B -0.5(12) . . . . ?
C2B C3B C4B C5B 1.0(11) . . . . ?
C2B C3B C4B C31 -175.4(7) . . . . ?
C30 C31 C4B C5B -62.7(9) . . . . ?
C32 C31 C4B C5B 121.3(7) . . . . ?
C30 C31 C4B C3B 113.4(8) . . . . ?
C32 C31 C4B C3B -62.6(9) . . . . ?
C1B N1B C5B C4B 2.0(10) . . . . ?
Ru1 N1B C5B C4B -177.2(5) . . . . ?
C3B C4B C5B N1B -1.8(10) . . . . ?
C31 C4B C5B N1B 174.6(6) . . . . ?
C2R Ru1 N1C C5C 131.7(6) . . . . ?
C1R Ru1 N1C C5C -48(20) . . . . ?
N1B Ru1 N1C C5C -47.4(6) . . . . ?
Cl2 Ru1 N1C C5C 42.0(5) . . . . ?
Cl1 Ru1 N1C C5C -137.7(5) . . . . ?
C2R Ru1 N1C C1C -46.5(7) . . . . ?
C1R Ru1 N1C C1C 134(20) . . . . ?
N1B Ru1 N1C C1C 134.5(6) . . . . ?
Cl2 Ru1 N1C C1C -136.2(6) . . . . ?
Cl1 Ru1 N1C C1C 44.2(6) . . . . ?
C5C N1C C1C C2C 3.2(12) . . . . ?
Ru1 N1C C1C C2C -178.6(7) . . . . ?
N1C C1C C2C C3C -3.4(15) . . . . ?
C1C C2C C3C C4C 2.5(14) . . . . ?
C2C C3C C4C C5C -1.4(12) . . . . ?
C2C C3C C4C C6 -179.9(8) . . . . ?
C7 C6 C4C C5C 120.8(7) . . . . ?
C5 C6 C4C C5C -61.6(10) . . . . ?
C7 C6 C4C C3C -60.8(10) . . . . ?
C5 C6 C4C C3C 116.8(8) . . . . ?
C1C N1C C5C C4C -2.1(11) . . . . ?
Ru1 N1C C5C C4C 179.7(5) . . . . ?
C3C C4C C5C N1C 1.3(11) . . . . ?
C6 C4C C5C N1C 179.8(7) . . . . ?
C4R Ru2 N1D C1D -135(16) . . . . ?
C3R Ru2 N1D C1D 58.5(7) . . . . ?
N1A Ru2 N1D C1D -124.1(6) . . . . ?
Cl4 Ru2 N1D C1D -36.1(6) . . . . ?
Cl3 Ru2 N1D C1D 147.1(6) . . . . ?
C4R Ru2 N1D C5D 46(16) . . . . ?
C3R Ru2 N1D C5D -120.7(6) . . . . ?
N1A Ru2 N1D C5D 56.6(5) . . . . ?
Cl4 Ru2 N1D C5D 144.6(5) . . . . ?
Cl3 Ru2 N1D C5D -32.2(5) . . . . ?
C5D N1D C1D C2D 1.5(12) . . . . ?
Ru2 N1D C1D C2D -177.8(7) . . . . ?
N1D C1D C2D C3D 0.4(14) . . . . ?
C1D C2D C3D C4D -0.2(13) . . . . ?
C2D C3D C4D C5D -1.9(12) . . . . ?
C2D C3D C4D C36 176.7(8) . . . . ?
C37 C36 C4D C3D -119.9(8) . . . . ?
C35 C36 C4D C3D 59.3(10) . . . . ?
C37 C36 C4D C5D 58.5(9) . . . . ?
C35 C36 C4D C5D -122.3(7) . . . . ?
C1D N1D C5D C4D -3.8(11) . . . . ?
Ru2 N1D C5D C4D 175.6(5) . . . . ?
C3D C4D C5D N1D 4.0(11) . . . . ?
C36 C4D C5D N1D -174.5(6) . . . . ?
N4 Zn1 N1E C1E 171.7(6) . . . . ?
N3 Zn1 N1E C1E 79.0(6) . . . . ?
N1 Zn1 N1E C1E -99.6(6) . . . . ?
N2 Zn1 N1E C1E -10.9(6) . . . . ?
N4 Zn1 N1E C5E -19.0(5) . . . . ?
N3 Zn1 N1E C5E -111.6(5) . . . . ?
N1 Zn1 N1E C5E 69.8(5) . . . . ?
N2 Zn1 N1E C5E 158.4(5) . . . . ?
C5E N1E C1E C2E -1.7(12) . . . . ?
Zn1 N1E C1E C2E 168.0(6) . . . . ?
N1E C1E C2E C3E 0.8(13) . . . . ?
C1E C2E C3E C4E -0.1(12) . . . . ?
C1E C2E C3E C51 -177.5(8) . . . . ?
C50 C51 C3E C2E -66.8(11) . . . . ?
C52 C51 C3E C2E 115.8(9) . . . . ?
C50 C51 C3E C4E 115.9(9) . . . . ?
C52 C51 C3E C4E -61.5(10) . . . . ?
C2E C3E C4E C5E 0.4(11) . . . . ?
C51 C3E C4E C5E 177.8(7) . . . . ?
C1E N1E C5E C4E 2.0(11) . . . . ?
Zn1 N1E C5E C4E -167.9(6) . . . . ?
C3E C4E C5E N1E -1.4(11) . . . . ?
C45 C46 C1F C2F 84.1(11) . . . . ?
C47 C46 C1F C2F -96.4(11) . . . . ?
C45 C46 C1F C6F -95.6(11) . . . . ?
C47 C46 C1F C6F 83.9(11) . . . . ?
C6F C1F C2F C3F -2.2(19) . . . . ?
C46 C1F C2F C3F 178.1(12) . . . . ?
C1F C2F C3F C4F 2(2) . . . . ?
C2F C3F C4F C5F -2(2) . . . . ?
C3F C4F C5F C6F 2(3) . . . . ?
C2F C1F C6F C5F 2.2(19) . . . . ?
C46 C1F C6F C5F -178.1(12) . . . . ?
C4F C5F C6F C1F -2(2) . . . . ?
C17 C16 C1G C2G -61.9(11) . . . . ?
C15 C16 C1G C2G 116.2(9) . . . . ?
C17 C16 C1G C6G 119.7(9) . . . . ?
C15 C16 C1G C6G -62.2(11) . . . . ?
C6G C1G C2G C3G -2.4(14) . . . . ?
C16 C1G C2G C3G 179.2(8) . . . . ?
C1G C2G C3G C4G 1.3(15) . . . . ?
C2G C3G C4G C5G 2(2) . . . . ?
C3G C4G C5G C6G -4(2) . . . . ?
C2G C1G C6G C5G 0.5(14) . . . . ?
C16 C1G C6G C5G 178.9(9) . . . . ?
C4G C5G C6G C1G 3(2) . . . . ?
C20 C1 C1H C2H -117.0(8) . . . . ?
C2 C1 C1H C2H 61.5(10) . . . . ?
C20 C1 C1H C6H 63.4(10) . . . . ?
C2 C1 C1H C6H -118.1(9) . . . . ?
C6H C1H C2H C3H -1.2(11) . . . . ?
C1 C1H C2H C3H 179.2(7) . . . . ?
C1H C2H C3H C4H -1.1(12) . . . . ?
C2H C3H C4H C5H 1.9(15) . . . . ?
C3H C4H C5H C6H -0.3(16) . . . . ?
C4H C5H C6H C1H -2.2(15) . . . . ?
C2H C1H C6H C5H 2.9(13) . . . . ?
C1 C1H C6H C5H -177.5(8) . . . . ?
N5 Zn2 N1I C5I -176.8(7) . . . . ?
N6 Zn2 N1I C5I 93.9(8) . . . . ?
N8 Zn2 N1I C5I -84.7(8) . . . . ?
N7 Zn2 N1I C5I 5.3(8) . . . . ?
N5 Zn2 N1I C1I 11.0(8) . . . . ?
N6 Zn2 N1I C1I -78.4(8) . . . . ?
N8 Zn2 N1I C1I 103.1(8) . . . . ?
N7 Zn2 N1I C1I -166.9(8) . . . . ?
C5I N1I C1I C2I -2.4(16) . . . . ?
Zn2 N1I C1I C2I 170.3(9) . . . . ?
N1I C1I C2I C3I 1.6(19) . . . . ?
C1I C2I C3I C4I 0.4(17) . . . . ?
C1I C2I C3I C41 -178.5(10) . . . 2_566 ?
C2I C3I C4I C5I -1.5(17) . . . . ?
C41 C3I C4I C5I 177.4(10) 2_566 . . . ?
C1I N1I C5I C4I 1.3(16) . . . . ?
Zn2 N1I C5I C4I -171.5(9) . . . . ?
C3I C4I C5I N1I 0.8(19) . . . . ?
C25 C26 C1J C6J 88.7(10) . . . . ?
C27 C26 C1J C6J -93.1(10) . . . . ?
C25 C26 C1J C2J -94.4(10) . . . . ?
C27 C26 C1J C2J 83.9(10) . . . . ?
C6J C1J C2J C3J -2.1(17) . . . . ?
C26 C1J C2J C3J -178.9(11) . . . . ?
C1J C2J C3J C4J -2(3) . . . . ?
C2J C3J C4J C5J 3(3) . . . . ?
C3J C4J C5J C6J 0(3) . . . . ?
C2J C1J C6J C5J 4.8(15) . . . . ?
C26 C1J C6J C5J -178.3(9) . . . . ?
C4J C5J C6J C1J -4.1(18) . . . . ?
C22 C21 C1L C2L 57.5(10) . . . . ?
C40 C21 C1L C2L -120.9(8) . . . . ?
C22 C21 C1L C6L -120.2(8) . . . . ?
C40 C21 C1L C6L 61.4(10) . . . . ?
C6L C1L C2L C3L 2.2(12) . . . . ?
C21 C1L C2L C3L -175.6(8) . . . . ?
C1L C2L C3L C4L -4.9(15) . . . . ?
C2L C3L C4L C5L 4.9(16) . . . . ?
C3L C4L C5L C6L -2.2(14) . . . . ?
C2L C1L C6L C5L 0.3(11) . . . . ?
C21 C1L C6L C5L 178.1(7) . . . . ?
C4L C5L C6L C1L -0.4(12) . . . . ?
C55 C56 C1M C2M -76.8(13) . . . . ?
C57 C56 C1M C2M 109.6(11) . . . . ?
C55 C56 C1M C6M 97.7(14) . . . . ?
C57 C56 C1M C6M -75.9(14) . . . . ?
C6M C1M C2M C3M 5(2) . . . . ?
C56 C1M C2M C3M 178.9(10) . . . . ?
C1M C2M C3M C4M -2(2) . . . . ?
C2M C3M C4M C5M -4(3) . . . . ?
C3M C4M C5M C6M 7(3) . . . . ?
C2M C1M C6M C5M -1(2) . . . . ?
C56 C1M C6M C5M -175.4(14) . . . . ?
C4M C5M C6M C1M -4(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.864
_diffrn_reflns_theta_full        27.11
_diffrn_measured_fraction_theta_full 0.864
_refine_diff_density_max         0.615
_refine_diff_density_min         -0.617
_refine_diff_density_rms         0.085