# Supplementary Material (ESI) for Chemical Communications
# This journal is (c) The Royal Society of Chemistry 2011
data_global
_journal_name_full               Chem.Commun.
_journal_coden_cambridge         0182
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_address     
;
Universita' di Firenze
LAMM Laboratory for Molecular Magnetism
c/o Dipartimento di Chimica
Via della Lastruccia 3, 50019 Sesto Fiorentino
Firenze, Italy
;
_publ_contact_author_email       roberta.sessoli@unifi.it
_publ_contact_author_phone       +390554573268
_publ_contact_author_name        'Roberta Sessoli'
loop_
_publ_author_name
P.-E.Car
M.Perfetti
M.Mannini
A.Favre
A.Caneschi
R.Sessoli

data_DyDota
_database_code_depnum_ccdc_archive 'CCDC 795879'
#TrackingRef '- CCDC 795879.cif'

_audit_creation_method           SHELXL-97
_audit_author_name               'Pierre-Emmanuel Car'
_audit_author_address            
;
Universita' di Firenze
LAMM Laboratory for Molecular Magnetism
c/o Dipartimento di Chimica
Via della Lastruccia 3, 50019 Sesto Fiorentino
Firenze, Italy
;
_audit_contact_author_email      pierre.emmanuel.car@gmail.com
_chemical_formula_moiety         
'(C16 O8 N4 H24 -4)1, (Dy 3+), (Na 1+), (H2 O)5'
_chemical_formula_sum            'C16 H34 Dy N4 Na O13'
_chemical_formula_weight         675.96
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   ' P-1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.7190(10)
_cell_length_b                   9.0790(10)
_cell_length_c                   15.6370(10)
_cell_angle_alpha                82.962(5)
_cell_angle_beta                 85.824(5)
_cell_angle_gamma                81.637(5)
_cell_volume                     1213.5(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    3840
_cell_measurement_theta_min      4.2737
_cell_measurement_theta_max      29.0079

_exptl_crystal_description       prismatic
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.28
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.844
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             674
_exptl_absorpt_coefficient_mu    3.168
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.46138
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       '\w scans'
_diffrn_detector_area_resol_mean 16.4547
_diffrn_standards_interval_count 25
_diffrn_standards_decay_%        0
_diffrn_reflns_number            13345
_diffrn_reflns_av_R_equivalents  0.0716
_diffrn_reflns_av_sigmaI/netI    0.1268
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         4.28
_diffrn_reflns_theta_max         29.08
_diffrn_measurement_details      
;
#__ type_ start__ end____ width___ exp.time_
1 omega -71.00 -40.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- -21.0487 179.0000 0.0000 31

#__ type_ start__ end____ width___ exp.time_
2 omega -94.00 -60.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- -21.0487 151.0000 -49.0000 34

#__ type_ start__ end____ width___ exp.time_
3 omega -89.00 -32.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- -21.0487 179.0000 30.0000 57

#__ type_ start__ end____ width___ exp.time_
4 omega -46.00 54.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- 22.1424 -38.0000 -30.0000 100

#__ type_ start__ end____ width___ exp.time_
5 omega -5.00 81.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- 22.1424 -123.0000 -111.0000 86

#__ type_ start__ end____ width___ exp.time_
6 omega -49.00 51.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- 22.1424 -38.0000 -120.0000 100

#__ type_ start__ end____ width___ exp.time_
7 omega -11.00 72.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- 22.1424 77.0000 -120.0000 83

#__ type_ start__ end____ width___ exp.time_
8 omega -11.00 95.00 1.0000 2.6500
omega____ theta____ kappa____ phi______ frames
- 22.1424 77.0000 0.0000 106
;
_reflns_number_total             5578
_reflns_number_gt                3855
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
;
_computing_cell_refinement       
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
;
_computing_data_reduction        
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
(compiled May 6 2009,17:20:42)
;
_computing_structure_solution    'Sir-97 (Cascarano, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0321P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5578
_refine_ls_number_parameters     316
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0782
_refine_ls_R_factor_gt           0.0457
_refine_ls_wR_factor_ref         0.0919
_refine_ls_wR_factor_gt          0.0857
_refine_ls_goodness_of_fit_ref   0.910
_refine_ls_restrained_S_all      0.910
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.59456(3) 0.25259(3) 0.30644(2) 0.02453(10) Uani 1 1 d . . .
Na1 Na 0.3728(3) -0.1804(3) 0.40061(17) 0.0442(7) Uani 1 1 d . . .
N1 N 0.8478(5) 0.0580(5) 0.3029(3) 0.0266(11) Uani 1 1 d . . .
N2 N 0.6408(5) 0.4577(5) 0.1760(3) 0.0268(11) Uani 1 1 d . . .
N3 N 0.8436(5) 0.3795(5) 0.3221(3) 0.0264(11) Uani 1 1 d . . .
N4 N 0.6462(5) 0.1377(5) 0.1563(3) 0.0273(11) Uani 1 1 d . . .
O1 O 0.5109(4) 0.0199(4) 0.3104(3) 0.0308(10) Uani 1 1 d . . .
O2 O 0.3753(4) 0.3277(5) 0.2278(3) 0.0336(10) Uani 1 1 d . . .
O3 O 0.6039(5) 0.6662(5) 0.4282(3) 0.0384(11) Uani 1 1 d . . .
O4 O 0.7980(4) -0.0139(5) 0.5361(3) 0.0344(10) Uani 1 1 d . . .
O5 O 0.5398(4) 0.4824(4) 0.3623(3) 0.0304(10) Uani 1 1 d . . .
O6 O 0.6838(4) 0.1654(4) 0.4435(3) 0.0287(9) Uani 1 1 d . . .
O7 O 0.2421(5) 0.4725(5) 0.1244(3) 0.0483(13) Uani 1 1 d . . .
O8 O 0.3861(5) -0.1300(5) 0.2463(3) 0.0441(12) Uani 1 1 d . . .
C1 C 0.8506(6) -0.0367(6) 0.3878(4) 0.0288(14) Uani 1 1 d . . .
H1A H 0.9577 -0.0732 0.4003 0.035 Uiso 1 1 calc R . .
H1B H 0.7989 -0.1230 0.3837 0.035 Uiso 1 1 calc R . .
C2 C 0.7741(6) 0.0444(7) 0.4609(4) 0.0261(14) Uani 1 1 d . . .
C3 C 0.7067(7) 0.3882(7) 0.0985(4) 0.0318(15) Uani 1 1 d . . .
H3A H 0.8166 0.3555 0.1049 0.038 Uiso 1 1 calc R . .
H3B H 0.6964 0.4633 0.0488 0.038 Uiso 1 1 calc R . .
C4 C 0.7406(6) 0.5628(6) 0.1989(4) 0.0304(14) Uani 1 1 d . . .
H4A H 0.6825 0.6292 0.2375 0.036 Uiso 1 1 calc R . .
H4B H 0.7732 0.6235 0.1472 0.036 Uiso 1 1 calc R . .
C5 C 0.8833(6) 0.4770(7) 0.2427(4) 0.0318(15) Uani 1 1 d . . .
H5A H 0.9440 0.4157 0.2023 0.038 Uiso 1 1 calc R . .
H5B H 0.9472 0.5483 0.2573 0.038 Uiso 1 1 calc R . .
C6 C 0.8041(6) 0.4704(7) 0.3940(4) 0.0310(15) Uani 1 1 d . . .
H6A H 0.8737 0.5455 0.3901 0.037 Uiso 1 1 calc R . .
H6B H 0.8204 0.4065 0.4479 0.037 Uiso 1 1 calc R . .
C7 C 0.8478(7) -0.0399(7) 0.2333(4) 0.0371(16) Uani 1 1 d . . .
H7A H 0.7757 -0.1116 0.2502 0.045 Uiso 1 1 calc R . .
H7B H 0.9506 -0.0954 0.2252 0.045 Uiso 1 1 calc R . .
C8 C 0.9805(6) 0.2637(7) 0.3435(4) 0.0300(14) Uani 1 1 d . . .
H8A H 0.9721 0.2258 0.4042 0.036 Uiso 1 1 calc R . .
H8B H 1.0752 0.3091 0.3329 0.036 Uiso 1 1 calc R . .
C9 C 0.3563(7) 0.4394(7) 0.1705(4) 0.0335(15) Uani 1 1 d . . .
C10 C 0.6313(7) 0.2568(7) 0.0817(4) 0.0328(15) Uani 1 1 d . . .
H10A H 0.5224 0.2893 0.0720 0.039 Uiso 1 1 calc R . .
H10B H 0.6802 0.2168 0.0301 0.039 Uiso 1 1 calc R . .
C11 C 0.4827(6) 0.5416(7) 0.1585(4) 0.0331(15) Uani 1 1 d . . .
H11A H 0.4842 0.5907 0.0998 0.040 Uiso 1 1 calc R . .
H11B H 0.4580 0.6186 0.1971 0.040 Uiso 1 1 calc R . .
C12 C 0.5242(7) 0.0400(7) 0.1562(4) 0.0361(16) Uani 1 1 d . . .
H12A H 0.5629 -0.0399 0.1210 0.043 Uiso 1 1 calc R . .
H12B H 0.4348 0.0984 0.1290 0.043 Uiso 1 1 calc R . .
C13 C 0.6376(7) 0.5482(7) 0.3953(4) 0.0299(14) Uani 1 1 d . . .
C14 C 0.8019(6) 0.0508(7) 0.1494(4) 0.0348(16) Uani 1 1 d . . .
H14A H 0.8771 0.1190 0.1313 0.042 Uiso 1 1 calc R . .
H14B H 0.8042 -0.0161 0.1054 0.042 Uiso 1 1 calc R . .
C15 C 0.9883(6) 0.1354(7) 0.2893(4) 0.0329(15) Uani 1 1 d . . .
H15A H 1.0004 0.1735 0.2288 0.040 Uiso 1 1 calc R . .
H15B H 1.0790 0.0633 0.3032 0.040 Uiso 1 1 calc R . .
C16 C 0.4715(7) -0.0290(7) 0.2438(4) 0.0304(14) Uani 1 1 d . . .
OW1 O 0.3651(4) 0.2561(4) 0.4085(3) 0.0331(10) Uani 1 1 d . . .
OW2 O 0.2031(6) 0.9342(6) 0.1015(4) 0.0654(15) Uani 1 1 d . . .
OW3 O 0.0320(5) 0.7189(5) 0.0759(3) 0.0541(13) Uani 1 1 d . . .
OW4 O 0.2231(5) -0.3775(6) 0.3744(4) 0.0676(16) Uani 1 1 d . . .
OW5 O 0.1452(7) 1.2375(6) 0.0643(4) 0.093(2) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.02346(15) 0.02693(16) 0.02306(17) -0.00338(12) -0.00359(10) -0.00143(10)
Na1 0.0411(15) 0.0501(17) 0.0375(17) -0.0023(14) 0.0022(12) 0.0019(12)
N1 0.025(3) 0.031(3) 0.024(3) -0.006(2) -0.003(2) -0.003(2)
N2 0.024(3) 0.028(3) 0.027(3) -0.001(2) 0.000(2) -0.002(2)
N3 0.022(2) 0.029(3) 0.028(3) -0.007(2) -0.006(2) 0.001(2)
N4 0.025(3) 0.032(3) 0.024(3) -0.005(2) 0.000(2) 0.001(2)
O1 0.034(2) 0.029(2) 0.030(3) -0.007(2) -0.0023(19) -0.0039(18)
O2 0.030(2) 0.041(3) 0.031(3) 0.004(2) -0.0123(19) -0.0080(19)
O3 0.047(3) 0.029(3) 0.041(3) -0.020(2) -0.002(2) 0.004(2)
O4 0.037(2) 0.043(3) 0.022(3) 0.005(2) -0.0032(19) -0.005(2)
O5 0.030(2) 0.027(2) 0.036(3) -0.007(2) -0.0085(19) -0.0061(18)
O6 0.031(2) 0.028(2) 0.024(2) -0.0025(19) -0.0032(17) 0.0055(18)
O7 0.035(3) 0.052(3) 0.057(4) 0.004(3) -0.027(2) 0.000(2)
O8 0.054(3) 0.044(3) 0.041(3) -0.006(2) -0.007(2) -0.026(2)
C1 0.028(3) 0.025(3) 0.031(4) 0.000(3) -0.005(3) 0.002(3)
C2 0.026(3) 0.031(4) 0.022(4) 0.002(3) -0.004(3) -0.011(3)
C3 0.038(4) 0.037(4) 0.019(4) 0.000(3) 0.005(3) -0.007(3)
C4 0.035(3) 0.026(3) 0.030(4) 0.000(3) -0.002(3) -0.003(3)
C5 0.031(3) 0.034(4) 0.031(4) -0.003(3) 0.000(3) -0.010(3)
C6 0.026(3) 0.035(4) 0.033(4) -0.009(3) -0.002(3) -0.007(3)
C7 0.043(4) 0.035(4) 0.032(4) -0.009(3) 0.002(3) 0.004(3)
C8 0.025(3) 0.034(4) 0.031(4) -0.004(3) -0.009(3) -0.002(3)
C9 0.037(4) 0.036(4) 0.027(4) -0.006(3) -0.007(3) 0.001(3)
C10 0.034(3) 0.040(4) 0.023(4) -0.004(3) 0.002(3) -0.004(3)
C11 0.036(4) 0.032(4) 0.031(4) -0.003(3) -0.008(3) 0.000(3)
C12 0.038(4) 0.040(4) 0.035(4) -0.013(3) -0.005(3) -0.011(3)
C13 0.036(4) 0.028(4) 0.026(4) -0.002(3) 0.000(3) -0.004(3)
C14 0.036(4) 0.042(4) 0.025(4) -0.015(3) -0.001(3) 0.007(3)
C15 0.031(3) 0.031(4) 0.033(4) 0.002(3) 0.000(3) 0.002(3)
C16 0.030(3) 0.030(4) 0.032(4) -0.008(3) 0.003(3) -0.004(3)
OW1 0.032(2) 0.038(3) 0.029(3) -0.003(2) -0.0028(18) -0.0056(19)
OW2 0.059(3) 0.074(4) 0.069(4) -0.016(3) -0.018(3) -0.012(3)
OW3 0.046(3) 0.049(3) 0.064(4) 0.001(3) -0.009(2) 0.000(2)
OW4 0.045(3) 0.068(4) 0.090(5) -0.018(3) 0.008(3) -0.008(3)
OW5 0.138(6) 0.040(3) 0.105(6) 0.007(3) -0.054(4) -0.010(3)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O2 2.321(4) . ?
Dy1 O1 2.326(4) . ?
Dy1 O5 2.333(4) . ?
Dy1 O6 2.340(4) . ?
Dy1 OW1 2.466(4) . ?
Dy1 N1 2.621(4) . ?
Dy1 N2 2.639(5) . ?
Dy1 N3 2.641(4) . ?
Dy1 N4 2.667(5) . ?
Na1 O3 2.313(5) 1_545 ?
Na1 O8 2.398(5) . ?
Na1 O4 2.399(5) 2_656 ?
Na1 OW4 2.452(6) . ?
Na1 O6 2.468(5) 2_656 ?
Na1 O1 2.551(5) . ?
Na1 C2 2.765(7) 2_656 ?
Na1 C16 2.802(7) . ?
Na1 C13 3.127(6) 1_545 ?
N1 C7 1.488(7) . ?
N1 C15 1.488(7) . ?
N1 C1 1.489(7) . ?
N2 C4 1.471(7) . ?
N2 C3 1.474(7) . ?
N2 C11 1.501(7) . ?
N3 C6 1.467(7) . ?
N3 C5 1.484(7) . ?
N3 C8 1.500(7) . ?
N4 C14 1.471(7) . ?
N4 C12 1.482(7) . ?
N4 C10 1.490(7) . ?
O1 C16 1.269(7) . ?
O2 C9 1.269(7) . ?
O3 C13 1.233(7) . ?
O3 Na1 2.313(5) 1_565 ?
O4 C2 1.248(7) . ?
O4 Na1 2.399(5) 2_656 ?
O5 C13 1.280(7) . ?
O6 C2 1.268(6) . ?
O6 Na1 2.467(5) 2_656 ?
O7 C9 1.251(7) . ?
O8 C16 1.258(7) . ?
C1 C2 1.499(8) . ?
C2 Na1 2.765(7) 2_656 ?
C3 C10 1.502(8) . ?
C4 C5 1.528(8) . ?
C6 C13 1.519(8) . ?
C7 C14 1.509(8) . ?
C8 C15 1.514(8) . ?
C9 C11 1.528(8) . ?
C12 C16 1.505(8) . ?
C13 Na1 3.127(6) 1_565 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Dy1 O1 81.77(14) . . ?
O2 Dy1 O5 86.68(14) . . ?
O1 Dy1 O5 143.12(14) . . ?
O2 Dy1 O6 144.75(14) . . ?
O1 Dy1 O6 85.66(14) . . ?
O5 Dy1 O6 83.91(14) . . ?
O2 Dy1 OW1 72.07(14) . . ?
O1 Dy1 OW1 73.84(13) . . ?
O5 Dy1 OW1 69.28(13) . . ?
O6 Dy1 OW1 72.82(13) . . ?
O2 Dy1 N1 138.77(15) . . ?
O1 Dy1 N1 74.38(14) . . ?
O5 Dy1 N1 131.57(14) . . ?
O6 Dy1 N1 66.69(14) . . ?
OW1 Dy1 N1 129.59(14) . . ?
O2 Dy1 N2 67.68(14) . . ?
O1 Dy1 N2 131.00(15) . . ?
O5 Dy1 N2 74.16(14) . . ?
O6 Dy1 N2 140.07(14) . . ?
OW1 Dy1 N2 126.21(13) . . ?
N1 Dy1 N2 104.18(14) . . ?
O2 Dy1 N3 132.64(14) . . ?
O1 Dy1 N3 142.14(14) . . ?
O5 Dy1 N3 66.30(13) . . ?
O6 Dy1 N3 72.91(14) . . ?
OW1 Dy1 N3 125.67(14) . . ?
N1 Dy1 N3 68.59(14) . . ?
N2 Dy1 N3 67.83(14) . . ?
O2 Dy1 N4 72.17(14) . . ?
O1 Dy1 N4 66.96(14) . . ?
O5 Dy1 N4 141.00(15) . . ?
O6 Dy1 N4 131.50(14) . . ?
OW1 Dy1 N4 129.64(13) . . ?
N1 Dy1 N4 67.70(14) . . ?
N2 Dy1 N4 67.63(15) . . ?
N3 Dy1 N4 104.63(14) . . ?
O3 Na1 O8 103.00(18) 1_545 . ?
O3 Na1 O4 139.01(19) 1_545 2_656 ?
O8 Na1 O4 110.56(18) . 2_656 ?
O3 Na1 OW4 97.10(18) 1_545 . ?
O8 Na1 OW4 83.80(19) . . ?
O4 Na1 OW4 109.05(17) 2_656 . ?
O3 Na1 O6 90.59(16) 1_545 2_656 ?
O8 Na1 O6 164.56(18) . 2_656 ?
O4 Na1 O6 54.07(14) 2_656 2_656 ?
OW4 Na1 O6 101.96(18) . 2_656 ?
O3 Na1 O1 92.51(16) 1_545 . ?
O8 Na1 O1 53.42(14) . . ?
O4 Na1 O1 89.17(16) 2_656 . ?
OW4 Na1 O1 137.2(2) . . ?
O6 Na1 O1 119.58(17) 2_656 . ?
O3 Na1 C2 115.67(19) 1_545 2_656 ?
O8 Na1 C2 137.33(19) . 2_656 ?
O4 Na1 C2 26.78(15) 2_656 2_656 ?
OW4 Na1 C2 107.45(19) . 2_656 ?
O6 Na1 C2 27.29(14) 2_656 2_656 ?
O1 Na1 C2 105.48(17) . 2_656 ?
O3 Na1 C16 97.54(18) 1_545 . ?
O8 Na1 C16 26.57(15) . . ?
O4 Na1 C16 102.00(18) 2_656 . ?
OW4 Na1 C16 110.3(2) . . ?
O6 Na1 C16 145.31(19) 2_656 . ?
O1 Na1 C16 26.90(15) . . ?
C2 Na1 C16 125.1(2) 2_656 . ?
O3 Na1 C13 19.83(15) 1_545 1_545 ?
O8 Na1 C13 91.76(18) . 1_545 ?
O4 Na1 C13 156.52(19) 2_656 1_545 ?
OW4 Na1 C13 79.65(17) . 1_545 ?
O6 Na1 C13 103.32(16) 2_656 1_545 ?
O1 Na1 C13 98.96(16) . 1_545 ?
C2 Na1 C13 130.36(19) 2_656 1_545 ?
C16 Na1 C13 94.81(18) . 1_545 ?
C7 N1 C15 108.9(5) . . ?
C7 N1 C1 108.8(5) . . ?
C15 N1 C1 109.8(4) . . ?
C7 N1 Dy1 111.2(3) . . ?
C15 N1 Dy1 110.8(3) . . ?
C1 N1 Dy1 107.1(3) . . ?
C4 N2 C3 110.7(4) . . ?
C4 N2 C11 109.0(4) . . ?
C3 N2 C11 109.3(5) . . ?
C4 N2 Dy1 111.3(3) . . ?
C3 N2 Dy1 111.2(3) . . ?
C11 N2 Dy1 105.2(3) . . ?
C6 N3 C5 109.6(5) . . ?
C6 N3 C8 109.3(4) . . ?
C5 N3 C8 109.3(4) . . ?
C6 N3 Dy1 105.5(3) . . ?
C5 N3 Dy1 111.9(3) . . ?
C8 N3 Dy1 111.0(3) . . ?
C14 N4 C12 110.9(5) . . ?
C14 N4 C10 108.3(4) . . ?
C12 N4 C10 109.9(4) . . ?
C14 N4 Dy1 111.5(3) . . ?
C12 N4 Dy1 104.5(3) . . ?
C10 N4 Dy1 111.7(3) . . ?
C16 O1 Dy1 122.8(4) . . ?
C16 O1 Na1 87.7(4) . . ?
Dy1 O1 Na1 145.90(19) . . ?
C9 O2 Dy1 125.8(4) . . ?
C13 O3 Na1 120.7(4) . 1_565 ?
C2 O4 Na1 93.2(4) . 2_656 ?
C13 O5 Dy1 125.6(4) . . ?
C2 O6 Dy1 124.3(4) . . ?
C2 O6 Na1 89.5(3) . 2_656 ?
Dy1 O6 Na1 143.90(17) . 2_656 ?
C16 O8 Na1 94.9(4) . . ?
N1 C1 C2 113.5(5) . . ?
O4 C2 O6 123.2(6) . . ?
O4 C2 C1 118.1(5) . . ?
O6 C2 C1 118.6(5) . . ?
O4 C2 Na1 60.0(3) . 2_656 ?
O6 C2 Na1 63.2(3) . 2_656 ?
C1 C2 Na1 177.1(4) . 2_656 ?
N2 C3 C10 114.0(5) . . ?
N2 C4 C5 110.3(5) . . ?
N3 C5 C4 113.1(5) . . ?
N3 C6 C13 113.1(5) . . ?
N1 C7 C14 111.2(5) . . ?
N3 C8 C15 110.6(5) . . ?
O7 C9 O2 125.1(6) . . ?
O7 C9 C11 118.2(6) . . ?
O2 C9 C11 116.7(5) . . ?
N4 C10 C3 110.5(5) . . ?
N2 C11 C9 112.5(5) . . ?
N4 C12 C16 115.0(5) . . ?
O3 C13 O5 124.2(5) . . ?
O3 C13 C6 119.8(5) . . ?
O5 C13 C6 116.0(5) . . ?
O3 C13 Na1 39.5(3) . 1_565 ?
O5 C13 Na1 86.1(3) . 1_565 ?
C6 C13 Na1 155.9(4) . 1_565 ?
N4 C14 C7 112.6(5) . . ?
N1 C15 C8 112.8(5) . . ?
O8 C16 O1 123.8(6) . . ?
O8 C16 C12 117.2(6) . . ?
O1 C16 C12 119.0(5) . . ?
O8 C16 Na1 58.5(3) . . ?
O1 C16 Na1 65.4(3) . . ?
C12 C16 Na1 175.0(4) . . ?

_diffrn_measured_fraction_theta_max 0.859
_diffrn_reflns_theta_full        29.08
_diffrn_measured_fraction_theta_full 0.859
_refine_diff_density_max         1.310
_refine_diff_density_min         -1.093
_refine_diff_density_rms         0.160