# Electronic Supplementary Material (ESI) for Chemical Communications # This journal is © The Royal Society of Chemistry 2011 data_global _journal_name_full Chem.Commun. _journal_coden_cambridge 0182 _journal_year ? _journal_volume ? _journal_page_first ? loop_ _publ_author_name 'Jianzhuang Jiang' 'Hailong Wang' 'Kang Wang' 'Yongzhong Bian' N.Kobayashi _publ_contact_author_name Xiaolongz _publ_contact_author_email xiaolongz@126.com data_1 _database_code_depnum_ccdc_archive 'CCDC 795366' #TrackingRef 'complex.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C144 H78 Cd Cl16 Eu2 N28 O' _chemical_formula_weight 3199.85 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cd Cd 0.1185 4.6533 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 21/n' _symmetry_space_group_name_Hall '-P 2yn' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 15.20600(10) _cell_length_b 29.7187(2) _cell_length_c 28.7031(3) _cell_angle_alpha 90.00 _cell_angle_beta 103.5440(10) _cell_angle_gamma 90.00 _cell_volume 12610.28(18) _cell_formula_units_Z 4 _cell_measurement_temperature 100(2) _cell_measurement_reflns_used 16396 _cell_measurement_theta_min 1.58 _cell_measurement_theta_max 30.46 _exptl_crystal_description block _exptl_crystal_colour black _exptl_crystal_size_max 0.2 _exptl_crystal_size_mid 0.15 _exptl_crystal_size_min 0.1 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.684 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 6360 _exptl_absorpt_coefficient_mu 12.037 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.172 _exptl_absorpt_correction_T_max 0.30 _exptl_absorpt_process_details ; CrysAlisPro, Oxford Diffraction Ltd., Version 1.171.34.40 (release 27-08-2010 CrysAlis171 .NET) (compiled Aug 27 2010,11:50:40) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm. ; _exptl_special_details ; ? ; _diffrn_ambient_temperature 100(2) _diffrn_radiation_wavelength 1.54184 _diffrn_radiation_type CuK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Xcalibur, Eos, Gemini' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean 0 _diffrn_standards_number 0 _diffrn_standards_interval_count 0 _diffrn_standards_interval_time 0 _diffrn_standards_decay_% ? _diffrn_reflns_number 38354 _diffrn_reflns_av_R_equivalents 0.0368 _diffrn_reflns_av_sigmaI/netI 0.0551 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_h_max 17 _diffrn_reflns_limit_k_min -31 _diffrn_reflns_limit_k_max 33 _diffrn_reflns_limit_l_min -32 _diffrn_reflns_limit_l_max 26 _diffrn_reflns_theta_min 3.17 _diffrn_reflns_theta_max 61.00 _reflns_number_total 18900 _reflns_number_gt 15430 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0892P)^2^+95.3198P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 18900 _refine_ls_number_parameters 1733 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0740 _refine_ls_R_factor_gt 0.0586 _refine_ls_wR_factor_ref 0.1658 _refine_ls_wR_factor_gt 0.1539 _refine_ls_goodness_of_fit_ref 0.977 _refine_ls_restrained_S_all 0.977 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Cd1 Cd 0.67872(3) 0.672340(16) 0.648356(16) 0.01592(13) Uani 1 1 d . . . Eu1 Eu 0.76831(3) 0.777066(14) 0.680362(15) 0.01524(12) Uani 1 1 d . . . Eu2 Eu 0.59398(3) 0.571315(14) 0.610567(15) 0.01421(12) Uani 1 1 d . . . Cl10 Cl 0.3413(2) 0.39748(11) 0.82156(12) 0.0713(8) Uani 1 1 d . . . N15 N 0.5280(4) 0.6506(2) 0.5890(2) 0.0166(13) Uani 1 1 d . . . Cl15 Cl 0.0881(2) 0.35832(11) 0.66893(11) 0.0659(8) Uani 1 1 d . . . N21 N 0.6865(4) 0.51269(19) 0.5910(2) 0.0171(13) Uani 1 1 d . . . N9 N 0.5315(4) 0.7690(2) 0.5983(2) 0.0215(14) Uani 1 1 d . . . C53 C 0.8631(5) 0.7064(2) 0.6109(2) 0.0159(15) Uani 1 1 d . . . C92 C 0.4851(5) 0.6369(3) 0.6798(3) 0.0224(17) Uani 1 1 d . . . C16 C 0.9245(5) 0.7799(2) 0.7852(3) 0.0201(16) Uani 1 1 d . . . C45 C 0.6004(5) 0.7603(2) 0.5776(3) 0.0193(16) Uani 1 1 d . . . C61 C 0.8389(5) 0.6773(2) 0.7505(2) 0.0180(16) Uani 1 1 d . . . C101 C 0.6630(5) 0.6431(2) 0.5331(3) 0.0179(16) Uani 1 1 d . . . N11 N 0.9092(4) 0.6709(2) 0.7309(2) 0.0176(13) Uani 1 1 d . . . C46 C 0.5968(5) 0.7716(2) 0.5285(3) 0.0216(17) Uani 1 1 d . . . C93 C 0.4504(5) 0.6634(2) 0.6015(3) 0.0186(16) Uani 1 1 d . . . N24 N 0.5415(4) 0.5524(2) 0.5278(2) 0.0200(14) Uani 1 1 d . . . N10 N 0.8161(4) 0.7234(2) 0.5699(2) 0.0195(14) Uani 1 1 d . . . N27 N 0.3850(4) 0.5765(2) 0.5164(2) 0.0235(14) Uani 1 1 d . . . C108 C 0.7851(5) 0.6116(2) 0.5818(3) 0.0185(16) Uani 1 1 d . . . N1 N 0.7592(4) 0.8365(2) 0.6213(2) 0.0199(14) Uani 1 1 d . . . N8 N 0.6034(4) 0.7358(2) 0.6751(2) 0.0187(13) Uani 1 1 d . . . N7 N 0.7577(4) 0.6974(2) 0.7294(2) 0.0186(13) Uani 1 1 d . . . C68 C 0.7056(5) 0.6967(2) 0.7631(3) 0.0203(16) Uani 1 1 d . . . N3 N 0.8397(4) 0.7933(2) 0.7623(2) 0.0179(13) Uani 1 1 d . . . C100 C 0.5213(5) 0.6649(2) 0.5421(2) 0.0168(15) Uani 1 1 d . . . C19 C 0.7911(5) 0.7986(2) 0.7970(3) 0.0186(16) Uani 1 1 d . . . C1 C 0.6541(5) 0.8362(2) 0.7473(3) 0.0178(16) Uani 1 1 d . . . C15 C 0.9973(5) 0.7741(2) 0.7633(3) 0.0191(16) Uani 1 1 d . . . C20 C 0.7042(5) 0.8179(2) 0.7900(3) 0.0176(15) Uani 1 1 d . . . C76 C 0.5347(5) 0.7578(2) 0.6435(3) 0.0200(16) Uani 1 1 d . . . N20 N 0.5818(4) 0.6605(2) 0.5163(2) 0.0188(13) Uani 1 1 d . . . C4 C 0.6142(5) 0.8612(3) 0.6731(3) 0.0235(17) Uani 1 1 d . . . N5 N 0.6819(4) 0.7403(2) 0.5988(2) 0.0187(13) Uani 1 1 d . . . N12 N 0.6221(4) 0.7128(2) 0.7579(2) 0.0207(14) Uani 1 1 d . . . N4 N 0.6766(4) 0.8351(2) 0.7034(2) 0.0203(14) Uani 1 1 d . . . N2 N 0.9220(4) 0.7967(2) 0.6804(2) 0.0215(14) Uani 1 1 d . . . N16 N 0.6979(4) 0.62680(19) 0.5798(2) 0.0163(13) Uani 1 1 d . . . N19 N 0.4289(4) 0.6573(2) 0.6435(2) 0.0211(14) Uani 1 1 d . . . C60 C 0.9069(5) 0.6827(2) 0.6854(2) 0.0167(15) Uani 1 1 d . . . N23 N 0.4396(4) 0.5500(2) 0.5982(2) 0.0199(14) Uani 1 1 d . . . N22 N 0.5863(4) 0.5092(2) 0.6623(2) 0.0208(14) Uani 1 1 d . . . C69 C 0.5760(5) 0.7315(3) 0.7174(3) 0.0210(17) Uani 1 1 d . . . N6 N 0.8360(4) 0.7014(2) 0.6531(2) 0.0186(13) Uani 1 1 d . . . C70 C 0.4873(5) 0.7512(3) 0.7134(3) 0.0227(17) Uani 1 1 d . . . C133 C 0.4612(5) 0.5693(2) 0.5012(3) 0.0203(16) Uani 1 1 d . . . N25 N 0.7373(4) 0.4776(2) 0.6691(2) 0.0210(14) Uani 1 1 d . . . C77 C 0.8213(5) 0.5870(2) 0.6609(3) 0.0204(16) Uani 1 1 d . . . N18 N 0.6837(4) 0.5841(2) 0.7442(2) 0.0219(14) Uani 1 1 d . . . C84 C 0.7474(5) 0.5809(2) 0.7190(3) 0.0201(16) Uani 1 1 d . . . C51 C 0.6796(5) 0.7574(2) 0.5195(3) 0.0214(16) Uani 1 1 d . . . C2 C 0.5735(5) 0.8633(3) 0.7435(3) 0.0228(17) Uani 1 1 d . . . H2 H 0.5435 0.8691 0.7684 0.027 Uiso 1 1 calc R . . C75 C 0.4610(5) 0.7681(3) 0.6666(3) 0.0235(17) Uani 1 1 d . . . C67 C 0.7560(5) 0.6756(3) 0.8072(3) 0.0224(17) Uani 1 1 d . . . C59 C 0.9842(5) 0.6766(3) 0.6644(3) 0.0215(16) Uani 1 1 d . . . C33 C 1.0863(5) 0.7593(3) 0.7948(3) 0.0236(17) Uani 1 1 d . . . C8 C 0.7663(6) 0.8637(3) 0.5474(3) 0.0300(19) Uani 1 1 d . . . H8 H 0.7882 0.8694 0.5195 0.036 Uiso 1 1 calc R . . C9 C 0.8126(5) 0.8392(3) 0.5890(3) 0.0220(17) Uani 1 1 d . . . N13 N 0.7402(4) 0.59497(19) 0.6719(2) 0.0172(13) Uani 1 1 d . . . C117 C 0.6610(5) 0.4841(2) 0.6841(3) 0.0193(16) Uani 1 1 d . . . C13 C 1.0760(5) 0.7829(3) 0.6961(3) 0.0238(17) Uani 1 1 d . . . H13 H 1.1353 0.7740 0.7124 0.029 Uiso 1 1 calc R . . N14 N 0.5706(4) 0.6193(2) 0.6815(2) 0.0196(13) Uani 1 1 d . . . C18 C 0.8471(5) 0.7861(3) 0.8427(2) 0.0201(16) Uani 1 1 d . . . H18 H 0.8297 0.7858 0.8725 0.024 Uiso 1 1 calc R . . C52 C 0.7318(5) 0.7385(2) 0.5644(3) 0.0216(17) Uani 1 1 d . . . C102 C 0.7297(5) 0.6373(2) 0.5049(3) 0.0201(16) Uani 1 1 d . . . C17 C 0.9288(5) 0.7749(3) 0.8356(3) 0.0236(17) Uani 1 1 d . . . H17 H 0.9799 0.7655 0.8594 0.028 Uiso 1 1 calc R . . C39 C 0.6665(5) 0.8203(3) 0.8342(3) 0.0195(16) Uani 1 1 d . . . C40 C 0.6225(5) 0.7833(3) 0.8477(3) 0.0253(18) Uani 1 1 d . . . H40 H 0.6146 0.7567 0.8288 0.030 Uiso 1 1 calc R . . C54 C 0.9558(5) 0.6916(2) 0.6172(2) 0.0195(16) Uani 1 1 d . . . C10 C 0.9038(6) 0.8242(3) 0.5975(3) 0.0254(18) Uani 1 1 d . . . C58 C 1.0709(5) 0.6596(3) 0.6814(3) 0.0258(18) Uani 1 1 d . . . H58 H 1.0898 0.6486 0.7133 0.031 Uiso 1 1 calc R . . C44 C 0.6778(5) 0.8586(3) 0.8618(3) 0.0235(17) Uani 1 1 d . . . H44 H 0.7067 0.8842 0.8522 0.028 Uiso 1 1 calc R . . C99 C 0.4338(5) 0.6876(3) 0.5244(3) 0.0218(17) Uani 1 1 d . . . C95 C 0.3080(5) 0.7093(3) 0.5583(3) 0.0271(18) Uani 1 1 d . . . H95 H 0.2789 0.7100 0.5842 0.033 Uiso 1 1 calc R . . C85 C 0.6043(5) 0.6031(3) 0.7269(3) 0.0220(17) Uani 1 1 d . . . C55 C 1.0138(5) 0.6901(3) 0.5861(3) 0.0287(19) Uani 1 1 d . . . H55 H 0.9941 0.6995 0.5538 0.034 Uiso 1 1 calc R . . C94 C 0.3910(5) 0.6875(2) 0.5621(3) 0.0204(16) Uani 1 1 d . . . C12 C 1.0497(5) 0.7969(3) 0.6506(3) 0.0260(18) Uani 1 1 d . . . H12 H 1.0874 0.8002 0.6287 0.031 Uiso 1 1 calc R . . C107 C 0.8055(5) 0.6174(2) 0.5353(3) 0.0200(16) Uani 1 1 d . . . C6 C 0.6830(6) 0.8610(3) 0.6020(3) 0.0241(17) Uani 1 1 d . . . C3 C 0.5489(5) 0.8788(3) 0.6982(3) 0.0256(17) Uani 1 1 d . . . H3 H 0.4987 0.8976 0.6852 0.031 Uiso 1 1 calc R . . C83 C 0.8366(5) 0.5610(3) 0.7376(3) 0.0229(17) Uani 1 1 d . . . C5 C 0.6131(5) 0.8720(3) 0.6247(3) 0.0250(17) Uani 1 1 d . . . C78 C 0.8833(5) 0.5658(3) 0.7015(3) 0.0240(17) Uani 1 1 d . . . N17 N 0.8424(4) 0.5939(2) 0.6190(2) 0.0194(13) Uani 1 1 d . . . N28 N 0.6814(4) 0.5300(2) 0.5077(2) 0.0214(14) Uani 1 1 d . . . N26 N 0.4348(4) 0.5168(2) 0.6750(2) 0.0242(15) Uani 1 1 d . . . C63 C 0.9033(5) 0.6414(3) 0.8337(3) 0.0248(18) Uani 1 1 d . . . H63 H 0.9600 0.6327 0.8281 0.030 Uiso 1 1 calc R . . C86 C 0.5378(6) 0.6096(3) 0.7553(3) 0.0292(19) Uani 1 1 d . . . C103 C 0.7264(6) 0.6463(3) 0.4570(3) 0.0256(18) Uani 1 1 d . . . H10 H 0.6753 0.6601 0.4366 0.031 Uiso 1 1 calc R . . C115 C 0.8297(5) 0.4808(3) 0.6101(3) 0.0229(17) Uani 1 1 d . . . C109 C 0.7202(5) 0.5137(2) 0.5510(3) 0.0192(16) Uani 1 1 d . . . C43 C 0.6472(5) 0.8602(3) 0.9037(3) 0.0248(18) Uani 1 1 d . . . H43 H 0.6563 0.8863 0.9234 0.030 Uiso 1 1 calc R . . C126 C 0.3010(5) 0.5465(3) 0.6171(3) 0.0299(19) Uani 1 1 d . . . C11 C 0.9548(5) 0.8061(3) 0.6409(3) 0.0214(17) Uani 1 1 d . . . C134 C 0.4674(6) 0.5777(3) 0.4523(3) 0.0259(18) Uani 1 1 d . . . C72 C 0.3497(6) 0.7769(3) 0.7292(3) 0.036(2) Uani 1 1 d . . . H72 H 0.3108 0.7806 0.7504 0.043 Uiso 1 1 calc R . . C139 C 0.5530(5) 0.5629(2) 0.4494(3) 0.0219(17) Uani 1 1 d . . . C123 C 0.5561(6) 0.4736(3) 0.7281(3) 0.0271(18) Uani 1 1 d . . . C62 C 0.8398(5) 0.6640(3) 0.7990(3) 0.0199(16) Uani 1 1 d . . . C104 C 0.8016(6) 0.6338(3) 0.4406(3) 0.034(2) Uani 1 1 d . . . H10A H 0.8021 0.6396 0.4081 0.040 Uiso 1 1 calc R . . C21 C 0.5383(6) 0.9006(3) 0.5970(3) 0.0316(19) Uani 1 1 d . . . C82 C 0.8762(6) 0.5413(3) 0.7809(3) 0.032(2) Uani 1 1 d . . . H82 H 0.8437 0.5379 0.8052 0.038 Uiso 1 1 calc R . . C116 C 0.7481(5) 0.4907(2) 0.6261(3) 0.0169(15) Uani 1 1 d . . . C7 C 0.6881(6) 0.8767(3) 0.5548(3) 0.0294(19) Uani 1 1 d . . . H7 H 0.6431 0.8935 0.5332 0.035 Uiso 1 1 calc R . . C98 C 0.3954(5) 0.7073(3) 0.4804(3) 0.0272(18) Uani 1 1 d . . . H98 H 0.4238 0.7060 0.4543 0.033 Uiso 1 1 calc R . . C132 C 0.3753(5) 0.5651(2) 0.5601(3) 0.0226(17) Uani 1 1 d . . . C110 C 0.8122(5) 0.4952(2) 0.5621(3) 0.0204(16) Uani 1 1 d . . . C79 C 0.9739(5) 0.5517(3) 0.7087(3) 0.0289(19) Uani 1 1 d . . . H79 H 1.0069 0.5552 0.6846 0.035 Uiso 1 1 calc R . . C140 C 0.5973(5) 0.5465(2) 0.4972(3) 0.0208(16) Uani 1 1 d . . . C118 C 0.6443(6) 0.4623(2) 0.7262(3) 0.0238(17) Uani 1 1 d . . . C66 C 0.7339(6) 0.6668(3) 0.8509(3) 0.0309(19) Uani 1 1 d . . . H66 H 0.6777 0.6759 0.8570 0.037 Uiso 1 1 calc R . . C34 C 1.1494(6) 0.7907(3) 0.8176(3) 0.033(2) Uani 1 1 d . . . H34 H 1.1349 0.8218 0.8155 0.040 Uiso 1 1 calc R . . C125 C 0.3980(5) 0.5372(2) 0.6336(3) 0.0243(18) Uani 1 1 d . . . C105 C 0.8764(6) 0.6132(3) 0.4702(3) 0.035(2) Uani 1 1 d . . . H10B H 0.9258 0.6043 0.4572 0.042 Uiso 1 1 calc R . . C37 C 1.1919(6) 0.6994(3) 0.8260(3) 0.034(2) Uani 1 1 d . . . H37 H 1.2061 0.6683 0.8294 0.041 Uiso 1 1 calc R . . C64 C 0.8813(6) 0.6318(3) 0.8768(3) 0.0311(19) Uani 1 1 d . . . H64 H 0.9240 0.6166 0.9012 0.037 Uiso 1 1 calc R . . C73 C 0.3225(6) 0.7935(3) 0.6816(3) 0.037(2) Uani 1 1 d . . . H73 H 0.2650 0.8075 0.6714 0.044 Uiso 1 1 calc R . . C14 C 0.9967(5) 0.7838(3) 0.7155(3) 0.0213(16) Uani 1 1 d . . . C96 C 0.2705(5) 0.7298(3) 0.5145(3) 0.032(2) Uani 1 1 d . . . H96 H 0.2140 0.7448 0.5103 0.038 Uiso 1 1 calc R . . C27 C 0.9532(5) 0.8307(3) 0.5585(3) 0.0264(18) Uani 1 1 d . . . C38 C 1.1072(5) 0.7137(3) 0.7996(3) 0.0257(18) Uani 1 1 d . . . H38 H 1.0635 0.6921 0.7848 0.031 Uiso 1 1 calc R . . C131 C 0.2889(5) 0.5652(3) 0.5719(3) 0.0279(19) Uani 1 1 d . . . C56 C 1.1009(5) 0.6744(3) 0.6040(3) 0.033(2) Uani 1 1 d . . . H56 H 1.1424 0.6740 0.5838 0.039 Uiso 1 1 calc R . . C106 C 0.8802(6) 0.6054(3) 0.5176(3) 0.0267(18) Uani 1 1 d . . . H10C H 0.9322 0.5922 0.5379 0.032 Uiso 1 1 calc R . . C74 C 0.3769(5) 0.7898(3) 0.6500(3) 0.0277(18) Uani 1 1 d . . . H74 H 0.3589 0.8013 0.6183 0.033 Uiso 1 1 calc R . . C57 C 1.1287(5) 0.6591(3) 0.6510(3) 0.032(2) Uani 1 1 d . . . H57 H 1.1886 0.6482 0.6623 0.039 Uiso 1 1 calc R . . C91 C 0.4643(5) 0.6309(3) 0.7261(3) 0.0268(18) Uani 1 1 d . . . C119 C 0.6967(6) 0.4328(3) 0.7589(3) 0.032(2) Uani 1 1 d . . . H11 H 0.7569 0.4254 0.7576 0.038 Uiso 1 1 calc R . . Cl16 Cl 0.2547(2) 0.41048(13) 0.68498(13) 0.0802(9) Uani 1 1 d . . . Cl14 Cl 0.1148(2) 0.43417(12) 0.73311(13) 0.0785(9) Uani 1 1 d . . . Cl8 Cl 0.3919(3) 0.47808(13) 0.87718(16) 0.1002(12) Uani 1 1 d . . . Cl9 Cl 0.2082(3) 0.44285(15) 0.86236(17) 0.1066(14) Uani 1 1 d . . . C138 C 0.5835(6) 0.5682(3) 0.4076(3) 0.0260(18) Uani 1 1 d . . . H13A H 0.6416 0.5580 0.4055 0.031 Uiso 1 1 calc R . . C124 C 0.5209(5) 0.5023(2) 0.6868(3) 0.0213(17) Uani 1 1 d . . . C41 C 0.5902(6) 0.7854(3) 0.8891(3) 0.0287(19) Uani 1 1 d . . . H41 H 0.5589 0.7605 0.8983 0.034 Uiso 1 1 calc R . . C49 C 0.6335(6) 0.7820(3) 0.4395(3) 0.035(2) Uani 1 1 d . . . H49 H 0.6445 0.7857 0.4084 0.042 Uiso 1 1 calc R . . C111 C 0.8777(5) 0.4928(3) 0.5354(3) 0.0277(18) Uani 1 1 d . . . H11A H 0.8655 0.5024 0.5030 0.033 Uiso 1 1 calc R . . C136 C 0.4394(6) 0.6030(3) 0.3723(3) 0.033(2) Uani 1 1 d . . . H13B H 0.4007 0.6167 0.3452 0.039 Uiso 1 1 calc R . . C42 C 0.6035(5) 0.8232(3) 0.9163(3) 0.0238(17) Uani 1 1 d . . . C135 C 0.4093(6) 0.5977(3) 0.4129(3) 0.0288(19) Uani 1 1 d . . . H13C H 0.3504 0.6073 0.4144 0.035 Uiso 1 1 calc R . . C35 C 1.2349(6) 0.7762(3) 0.8439(3) 0.034(2) Uani 1 1 d . . . H35 H 1.2785 0.7976 0.8594 0.041 Uiso 1 1 calc R . . C48 C 0.5505(6) 0.7965(3) 0.4481(3) 0.034(2) Uani 1 1 d . . . H48 H 0.5068 0.8100 0.4228 0.041 Uiso 1 1 calc R . . C47 C 0.5313(6) 0.7915(3) 0.4926(3) 0.0276(18) Uani 1 1 d . . . H47 H 0.4754 0.8014 0.4983 0.033 Uiso 1 1 calc R . . C26 C 0.4594(6) 0.8809(3) 0.5713(3) 0.039(2) Uani 1 1 d . . . H26 H 0.4522 0.8492 0.5726 0.047 Uiso 1 1 calc R . . C81 C 0.9645(7) 0.5269(3) 0.7879(3) 0.040(2) Uani 1 1 d . . . H81 H 0.9931 0.5127 0.8172 0.048 Uiso 1 1 calc R . . C112 C 0.9619(6) 0.4756(3) 0.5584(3) 0.034(2) Uani 1 1 d . . . H11B H 1.0080 0.4729 0.5412 0.040 Uiso 1 1 calc R . . C50 C 0.6988(6) 0.7627(3) 0.4751(3) 0.0296(19) Uani 1 1 d . . . H50 H 0.7551 0.7534 0.4694 0.036 Uiso 1 1 calc R . . C137 C 0.5253(6) 0.5891(3) 0.3693(3) 0.031(2) Uani 1 1 d . . . H13D H 0.5444 0.5940 0.3404 0.037 Uiso 1 1 calc R . . C114 C 0.9138(5) 0.4638(3) 0.6322(3) 0.0247(17) Uani 1 1 d . . . H11C H 0.9262 0.4535 0.6644 0.030 Uiso 1 1 calc R . . C113 C 0.9794(5) 0.4623(3) 0.6060(3) 0.0302(19) Uani 1 1 d . . . H11D H 1.0382 0.4518 0.6211 0.036 Uiso 1 1 calc R . . C122 C 0.5159(6) 0.4548(3) 0.7626(3) 0.037(2) Uani 1 1 d . . . H12A H 0.4555 0.4619 0.7637 0.044 Uiso 1 1 calc R . . C97 C 0.3130(6) 0.7288(3) 0.4768(3) 0.034(2) Uani 1 1 d . . . H97 H 0.2851 0.7434 0.4476 0.041 Uiso 1 1 calc R . . C71 C 0.4317(5) 0.7557(3) 0.7450(3) 0.0302(19) Uani 1 1 d . . . H71 H 0.4495 0.7443 0.7767 0.036 Uiso 1 1 calc R . . C90 C 0.3887(6) 0.6429(4) 0.7431(3) 0.046(3) Uani 1 1 d . . . H90 H 0.3380 0.6576 0.7232 0.056 Uiso 1 1 calc R . . C65 C 0.7982(6) 0.6441(3) 0.8851(3) 0.035(2) Uani 1 1 d . . . H65 H 0.7851 0.6368 0.9149 0.042 Uiso 1 1 calc R . . C32 C 0.9528(6) 0.7965(3) 0.5256(3) 0.033(2) Uani 1 1 d . . . H32 H 0.9174 0.7703 0.5262 0.039 Uiso 1 1 calc R . . C36 C 1.2546(6) 0.7316(3) 0.8469(3) 0.037(2) Uani 1 1 d . . . C80 C 1.0124(6) 0.5328(3) 0.7524(3) 0.041(2) Uani 1 1 d . . . H80 H 1.0738 0.5234 0.7586 0.049 Uiso 1 1 calc R . . C28 C 1.0027(7) 0.8691(3) 0.5559(3) 0.045(3) Uani 1 1 d . . . H28 H 1.0019 0.8932 0.5776 0.054 Uiso 1 1 calc R . . C127 C 0.2275(6) 0.5391(3) 0.6376(4) 0.045(2) Uani 1 1 d . . . H12B H 0.2349 0.5257 0.6683 0.054 Uiso 1 1 calc R . . C121 C 0.5677(7) 0.4256(3) 0.7950(3) 0.045(2) Uani 1 1 d . . . H12C H 0.5424 0.4124 0.8190 0.053 Uiso 1 1 calc R . . C31 C 1.0042(6) 0.8008(3) 0.4919(3) 0.036(2) Uani 1 1 d . . . H31 H 1.0051 0.7771 0.4697 0.043 Uiso 1 1 calc R . . C130 C 0.2040(6) 0.5785(3) 0.5460(4) 0.042(2) Uani 1 1 d . . . H13E H 0.1964 0.5923 0.5154 0.051 Uiso 1 1 calc R . . C30 C 1.0529(7) 0.8385(4) 0.4904(3) 0.042(2) Uani 1 1 d . . . C87 C 0.5407(6) 0.6001(4) 0.8034(3) 0.049(3) Uani 1 1 d . . . H87 H 0.5916 0.5860 0.8237 0.059 Uiso 1 1 calc R . . C129 C 0.1309(7) 0.5713(4) 0.5661(4) 0.061(3) Uani 1 1 d . . . H12D H 0.0720 0.5797 0.5488 0.073 Uiso 1 1 calc R . . C23 C 0.4791(10) 0.9727(4) 0.5675(5) 0.079(4) Uani 1 1 d . . . H23 H 0.4850 1.0044 0.5662 0.095 Uiso 1 1 calc R . . C128 C 0.1427(7) 0.5523(4) 0.6106(5) 0.060(3) Uani 1 1 d . . . H12E H 0.0913 0.5479 0.6236 0.072 Uiso 1 1 calc R . . C89 C 0.3912(7) 0.6324(6) 0.7905(4) 0.077(5) Uani 1 1 d . . . H89 H 0.3403 0.6392 0.8031 0.092 Uiso 1 1 calc R . . C120 C 0.6571(7) 0.4147(3) 0.7933(3) 0.043(2) Uani 1 1 d . . . H12F H 0.6908 0.3946 0.8164 0.052 Uiso 1 1 calc R . . C88 C 0.4659(8) 0.6123(5) 0.8199(4) 0.074(4) Uani 1 1 d . . . H88 H 0.4657 0.6066 0.8525 0.088 Uiso 1 1 calc R . . C29 C 1.0538(8) 0.8727(4) 0.5218(4) 0.060(3) Uani 1 1 d . . . H29 H 1.0890 0.8988 0.5205 0.072 Uiso 1 1 calc R . . C22 C 0.5479(8) 0.9472(4) 0.5949(4) 0.062(3) Uani 1 1 d . . . H22 H 0.6017 0.9613 0.6122 0.074 Uiso 1 1 calc R . . C25 C 0.3917(8) 0.9064(4) 0.5440(4) 0.056(3) Uani 1 1 d . . . H25 H 0.3377 0.8926 0.5264 0.067 Uiso 1 1 calc R . . C24 C 0.4029(9) 0.9522(5) 0.5425(4) 0.066(3) Uani 1 1 d . . . C142 C 0.3016(10) 0.4505(5) 0.8371(6) 0.087(4) Uani 1 1 d . . . H14C H 0.2825 0.4691 0.8074 0.104 Uiso 1 1 calc R . . C144 C 0.1652(9) 0.3896(4) 0.7107(4) 0.067(3) Uani 1 1 d . . . H14 H 0.1928 0.3694 0.7381 0.080 Uiso 1 1 calc R . . Cl1 Cl 0.3167(3) 0.98615(14) 0.50743(13) 0.1025(14) Uani 1 1 d . . . Cl4 Cl 0.56459(14) 0.82522(7) 0.96914(7) 0.0353(5) Uani 1 1 d . . . Cl3 Cl 1.35986(17) 0.71446(10) 0.88049(11) 0.0636(8) Uani 1 1 d . . . Cl2 Cl 1.1198(2) 0.84220(12) 0.44819(11) 0.0747(9) Uani 1 1 d . . . Cl11 Cl 0.1439(3) 0.59777(14) 0.92053(15) 0.0940(11) Uani 1 1 d . . . Cl13 Cl 0.2161(4) 0.56649(13) 0.84200(13) 0.1066(14) Uani 1 1 d . . . C143 C 0.2304(9) 0.5682(5) 0.9045(5) 0.075(4) Uani 1 1 d . . . H14B H 0.2315 0.5368 0.9170 0.090 Uiso 1 1 calc R . . Cl5 Cl 0.6629(3) 0.45572(12) 0.91697(15) 0.1020(13) Uani 1 1 d . . . Cl6 Cl 0.5809(4) 0.54268(16) 0.92119(17) 0.1147(15) Uani 1 1 d . . . Cl7 Cl 0.7273(4) 0.5332(2) 0.8756(2) 0.153(2) Uani 1 1 d . . . C141 C 0.6304(12) 0.5058(5) 0.8869(6) 0.093(5) Uani 1 1 d . . . H14A H 0.5864 0.4994 0.8558 0.112 Uiso 1 1 calc R . . O1 O 0.303(2) 0.4948(16) 0.7301(13) 0.108(6) Uani 0.343(19) 1 d P A 1 O2 O 0.3339(12) 0.5240(8) 0.7562(6) 0.108(6) Uani 0.657(19) 1 d P A 2 Cl12 Cl 0.3344(3) 0.59415(18) 0.92924(15) 0.1145(17) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Cd1 0.0186(3) 0.0151(3) 0.0153(3) -0.00353(19) 0.00657(19) -0.0021(2) Eu1 0.0190(2) 0.0151(2) 0.0130(2) -0.00334(17) 0.00636(17) -0.00250(17) Eu2 0.0159(2) 0.0123(2) 0.0155(2) -0.00110(17) 0.00584(17) -0.00004(17) Cl10 0.0721(19) 0.0591(18) 0.085(2) 0.0079(16) 0.0238(16) 0.0031(15) N15 0.016(3) 0.017(3) 0.019(3) -0.001(3) 0.006(2) 0.002(2) Cl15 0.0661(18) 0.0723(19) 0.0635(18) 0.0044(15) 0.0239(14) 0.0086(15) N21 0.018(3) 0.011(3) 0.023(3) 0.002(3) 0.006(3) 0.002(2) N9 0.023(3) 0.020(3) 0.021(3) -0.002(3) 0.005(3) -0.003(3) C53 0.019(4) 0.015(4) 0.015(4) -0.006(3) 0.008(3) -0.006(3) C92 0.025(4) 0.020(4) 0.027(4) -0.010(3) 0.015(3) -0.008(3) C16 0.025(4) 0.019(4) 0.018(4) -0.008(3) 0.009(3) -0.006(3) C45 0.022(4) 0.015(4) 0.021(4) -0.005(3) 0.005(3) -0.002(3) C61 0.025(4) 0.016(4) 0.013(4) -0.004(3) 0.004(3) -0.008(3) C101 0.020(4) 0.013(4) 0.021(4) -0.003(3) 0.004(3) -0.001(3) N11 0.018(3) 0.016(3) 0.019(3) -0.003(3) 0.005(3) 0.001(3) C46 0.027(4) 0.013(4) 0.023(4) -0.002(3) 0.002(3) -0.006(3) C93 0.019(4) 0.011(3) 0.028(4) -0.005(3) 0.008(3) -0.006(3) N24 0.023(3) 0.018(3) 0.019(3) -0.004(3) 0.003(3) 0.002(3) N10 0.021(3) 0.024(3) 0.014(3) -0.002(3) 0.005(3) -0.004(3) N27 0.023(3) 0.016(3) 0.030(4) -0.008(3) 0.003(3) 0.001(3) C108 0.019(4) 0.018(4) 0.021(4) -0.004(3) 0.010(3) -0.007(3) N1 0.027(3) 0.016(3) 0.018(3) -0.003(3) 0.007(3) -0.007(3) N8 0.021(3) 0.016(3) 0.020(3) -0.003(3) 0.008(3) -0.003(3) N7 0.022(3) 0.021(3) 0.015(3) -0.003(3) 0.008(3) 0.000(3) C68 0.028(4) 0.019(4) 0.015(4) -0.008(3) 0.007(3) -0.007(3) N3 0.020(3) 0.018(3) 0.018(3) -0.005(3) 0.009(3) 0.000(3) C100 0.017(4) 0.013(4) 0.018(4) -0.004(3) -0.001(3) -0.001(3) C19 0.026(4) 0.013(4) 0.020(4) -0.003(3) 0.011(3) -0.007(3) C1 0.018(4) 0.020(4) 0.018(4) -0.007(3) 0.009(3) -0.007(3) C15 0.019(4) 0.019(4) 0.019(4) -0.003(3) 0.005(3) -0.006(3) C20 0.020(4) 0.016(4) 0.020(4) -0.002(3) 0.011(3) -0.001(3) C76 0.020(4) 0.017(4) 0.024(4) -0.005(3) 0.008(3) -0.003(3) N20 0.021(3) 0.017(3) 0.019(3) -0.005(3) 0.007(3) -0.001(3) C4 0.028(4) 0.018(4) 0.023(4) -0.005(3) 0.003(3) 0.000(3) N5 0.019(3) 0.023(3) 0.017(3) -0.004(3) 0.010(3) -0.004(3) N12 0.021(3) 0.023(3) 0.022(3) -0.007(3) 0.011(3) -0.010(3) N4 0.027(3) 0.016(3) 0.020(3) -0.005(3) 0.008(3) -0.003(3) N2 0.031(4) 0.016(3) 0.019(3) -0.006(3) 0.011(3) -0.005(3) N16 0.019(3) 0.012(3) 0.017(3) -0.004(2) 0.004(2) -0.001(2) N19 0.021(3) 0.019(3) 0.026(4) -0.005(3) 0.010(3) 0.000(3) C60 0.017(4) 0.015(4) 0.017(4) -0.004(3) 0.003(3) -0.005(3) N23 0.022(3) 0.012(3) 0.027(3) -0.006(3) 0.009(3) -0.001(3) N22 0.027(3) 0.017(3) 0.021(3) -0.005(3) 0.009(3) -0.002(3) C69 0.025(4) 0.022(4) 0.018(4) -0.005(3) 0.010(3) -0.007(3) N6 0.018(3) 0.022(3) 0.018(3) -0.002(3) 0.009(3) -0.002(3) C70 0.024(4) 0.025(4) 0.020(4) -0.012(3) 0.008(3) -0.006(3) C133 0.026(4) 0.010(4) 0.023(4) -0.004(3) 0.002(3) 0.001(3) N25 0.023(3) 0.018(3) 0.022(3) -0.004(3) 0.005(3) -0.003(3) C77 0.025(4) 0.018(4) 0.020(4) -0.003(3) 0.009(3) -0.001(3) N18 0.028(4) 0.022(3) 0.015(3) -0.003(3) 0.004(3) -0.009(3) C84 0.030(4) 0.013(4) 0.015(4) -0.003(3) -0.001(3) -0.006(3) C51 0.033(4) 0.015(4) 0.017(4) -0.004(3) 0.007(3) -0.006(3) C2 0.026(4) 0.023(4) 0.020(4) -0.006(3) 0.006(3) 0.000(3) C75 0.019(4) 0.022(4) 0.029(4) -0.009(3) 0.007(3) -0.003(3) C67 0.027(4) 0.022(4) 0.021(4) -0.011(3) 0.010(3) -0.010(3) C59 0.020(4) 0.023(4) 0.022(4) -0.006(3) 0.006(3) -0.003(3) C33 0.025(4) 0.033(5) 0.016(4) -0.005(3) 0.010(3) 0.000(4) C8 0.034(5) 0.032(5) 0.029(5) 0.003(4) 0.017(4) -0.005(4) C9 0.028(4) 0.022(4) 0.017(4) -0.001(3) 0.009(3) -0.007(3) N13 0.019(3) 0.014(3) 0.019(3) 0.003(3) 0.006(3) -0.002(3) C117 0.026(4) 0.011(4) 0.024(4) -0.006(3) 0.011(3) -0.002(3) C13 0.024(4) 0.025(4) 0.024(4) -0.012(3) 0.011(3) -0.007(3) N14 0.024(3) 0.016(3) 0.019(3) -0.002(3) 0.005(3) 0.000(3) C18 0.026(4) 0.023(4) 0.011(3) -0.003(3) 0.005(3) -0.002(3) C52 0.029(4) 0.017(4) 0.021(4) -0.006(3) 0.009(3) -0.008(3) C102 0.027(4) 0.016(4) 0.020(4) -0.004(3) 0.012(3) -0.002(3) C17 0.025(4) 0.028(4) 0.018(4) -0.002(3) 0.006(3) -0.002(3) C39 0.016(4) 0.023(4) 0.020(4) -0.001(3) 0.005(3) 0.001(3) C40 0.026(4) 0.028(4) 0.025(4) -0.006(3) 0.012(3) -0.002(3) C54 0.025(4) 0.018(4) 0.015(4) -0.006(3) 0.004(3) -0.005(3) C10 0.034(5) 0.021(4) 0.023(4) -0.003(3) 0.011(4) -0.007(4) C58 0.017(4) 0.031(5) 0.029(4) -0.007(4) 0.003(3) 0.002(3) C44 0.023(4) 0.024(4) 0.025(4) 0.000(3) 0.007(3) -0.004(3) C99 0.022(4) 0.019(4) 0.023(4) -0.003(3) 0.002(3) 0.000(3) C95 0.020(4) 0.022(4) 0.040(5) -0.009(4) 0.008(4) -0.002(3) C85 0.026(4) 0.019(4) 0.022(4) -0.003(3) 0.008(3) -0.007(3) C55 0.028(4) 0.035(5) 0.026(4) -0.003(4) 0.013(4) -0.003(4) C94 0.018(4) 0.016(4) 0.028(4) -0.007(3) 0.006(3) -0.002(3) C12 0.028(4) 0.029(4) 0.026(4) -0.005(4) 0.017(3) -0.007(4) C107 0.021(4) 0.016(4) 0.024(4) -0.002(3) 0.007(3) -0.004(3) C6 0.038(5) 0.016(4) 0.018(4) 0.001(3) 0.005(3) 0.000(3) C3 0.023(4) 0.024(4) 0.028(4) -0.002(3) 0.004(3) 0.005(3) C83 0.029(4) 0.015(4) 0.022(4) -0.006(3) 0.003(3) -0.003(3) C5 0.033(4) 0.018(4) 0.023(4) 0.004(3) 0.006(3) 0.005(3) C78 0.026(4) 0.018(4) 0.027(4) -0.007(3) 0.004(3) -0.006(3) N17 0.015(3) 0.016(3) 0.025(3) 0.000(3) 0.001(3) -0.003(3) N28 0.029(4) 0.016(3) 0.022(3) -0.001(3) 0.012(3) -0.002(3) N26 0.031(4) 0.013(3) 0.033(4) -0.002(3) 0.016(3) 0.002(3) C63 0.024(4) 0.028(4) 0.021(4) -0.004(3) 0.002(3) -0.008(3) C86 0.036(5) 0.036(5) 0.020(4) -0.009(4) 0.015(4) -0.017(4) C103 0.036(5) 0.016(4) 0.026(4) -0.001(3) 0.010(4) -0.002(3) C115 0.027(4) 0.019(4) 0.026(4) -0.004(3) 0.011(3) -0.003(3) C109 0.026(4) 0.014(4) 0.021(4) 0.000(3) 0.012(3) 0.000(3) C43 0.036(5) 0.023(4) 0.018(4) -0.004(3) 0.010(3) 0.003(4) C126 0.022(4) 0.021(4) 0.050(5) -0.011(4) 0.014(4) -0.005(3) C11 0.025(4) 0.019(4) 0.022(4) -0.011(3) 0.011(3) -0.009(3) C134 0.034(5) 0.016(4) 0.025(4) -0.005(3) 0.003(4) -0.004(3) C72 0.022(4) 0.051(6) 0.040(5) -0.021(4) 0.015(4) -0.002(4) C139 0.028(4) 0.015(4) 0.021(4) -0.003(3) 0.001(3) -0.001(3) C123 0.037(5) 0.016(4) 0.030(4) -0.005(3) 0.011(4) -0.003(3) C62 0.019(4) 0.022(4) 0.017(4) -0.006(3) 0.002(3) -0.008(3) C104 0.050(6) 0.029(5) 0.029(5) 0.001(4) 0.025(4) -0.001(4) C21 0.038(5) 0.029(5) 0.028(4) -0.001(4) 0.008(4) 0.009(4) C82 0.044(5) 0.023(4) 0.025(4) -0.001(4) 0.002(4) 0.001(4) C116 0.021(4) 0.008(3) 0.024(4) -0.002(3) 0.010(3) -0.005(3) C7 0.043(5) 0.026(4) 0.018(4) 0.008(3) 0.004(4) -0.003(4) C98 0.020(4) 0.027(4) 0.031(4) -0.001(4) -0.002(3) 0.003(3) C132 0.019(4) 0.012(4) 0.034(5) -0.005(3) 0.003(3) 0.001(3) C110 0.021(4) 0.015(4) 0.028(4) -0.002(3) 0.012(3) 0.000(3) C79 0.023(4) 0.027(4) 0.033(5) -0.003(4) -0.002(4) 0.000(4) C140 0.026(4) 0.013(4) 0.024(4) -0.005(3) 0.008(3) -0.002(3) C118 0.038(5) 0.015(4) 0.022(4) 0.002(3) 0.014(4) -0.002(3) C66 0.036(5) 0.036(5) 0.022(4) -0.009(4) 0.011(4) -0.006(4) C34 0.035(5) 0.023(4) 0.041(5) -0.007(4) 0.008(4) -0.002(4) C125 0.024(4) 0.015(4) 0.039(5) -0.002(4) 0.018(4) 0.000(3) C105 0.046(5) 0.026(5) 0.045(5) -0.001(4) 0.036(5) 0.001(4) C37 0.030(5) 0.033(5) 0.039(5) -0.002(4) 0.009(4) 0.010(4) C64 0.033(5) 0.037(5) 0.021(4) 0.001(4) 0.001(4) -0.005(4) C73 0.025(4) 0.043(5) 0.045(6) -0.010(4) 0.012(4) 0.008(4) C14 0.021(4) 0.022(4) 0.021(4) -0.008(3) 0.005(3) -0.004(3) C96 0.019(4) 0.025(4) 0.047(5) -0.001(4) -0.003(4) 0.005(3) C27 0.029(4) 0.032(5) 0.021(4) 0.001(4) 0.011(3) -0.004(4) C38 0.029(4) 0.024(4) 0.025(4) -0.005(3) 0.010(3) 0.000(3) C131 0.027(4) 0.025(4) 0.033(5) -0.014(4) 0.007(4) 0.000(3) C56 0.023(4) 0.045(5) 0.035(5) -0.006(4) 0.016(4) 0.000(4) C106 0.028(4) 0.022(4) 0.034(5) -0.005(4) 0.015(4) 0.002(3) C74 0.019(4) 0.029(4) 0.034(5) -0.009(4) 0.004(3) -0.001(3) C57 0.018(4) 0.045(5) 0.033(5) -0.013(4) 0.005(4) 0.002(4) C91 0.026(4) 0.031(5) 0.026(4) -0.009(4) 0.011(4) -0.007(4) C119 0.037(5) 0.032(5) 0.029(5) 0.006(4) 0.016(4) 0.009(4) Cl16 0.0638(19) 0.090(2) 0.095(2) -0.0071(19) 0.0356(18) -0.0061(17) Cl14 0.0680(19) 0.086(2) 0.085(2) -0.0176(18) 0.0263(17) -0.0005(17) Cl8 0.110(3) 0.070(2) 0.120(3) -0.007(2) 0.028(3) 0.004(2) Cl9 0.103(3) 0.106(3) 0.131(3) -0.016(3) 0.067(3) -0.019(2) C138 0.041(5) 0.017(4) 0.021(4) -0.006(3) 0.007(4) -0.002(3) C124 0.029(4) 0.015(4) 0.023(4) -0.004(3) 0.011(3) -0.003(3) C41 0.033(5) 0.033(5) 0.023(4) 0.000(4) 0.012(4) -0.009(4) C49 0.055(6) 0.037(5) 0.015(4) 0.006(4) 0.010(4) 0.003(4) C111 0.033(5) 0.020(4) 0.035(5) -0.001(4) 0.017(4) 0.003(4) C136 0.049(6) 0.019(4) 0.023(4) 0.002(3) -0.007(4) -0.003(4) C42 0.027(4) 0.029(4) 0.020(4) -0.005(3) 0.015(3) 0.005(3) C135 0.040(5) 0.020(4) 0.022(4) -0.004(3) -0.001(4) 0.004(4) C35 0.027(5) 0.039(5) 0.031(5) -0.005(4) 0.000(4) -0.007(4) C48 0.049(5) 0.032(5) 0.019(4) 0.003(4) 0.004(4) 0.007(4) C47 0.032(5) 0.027(4) 0.024(4) -0.008(4) 0.006(4) -0.001(4) C26 0.039(5) 0.045(6) 0.033(5) -0.004(4) 0.005(4) 0.008(4) C81 0.051(6) 0.033(5) 0.029(5) 0.000(4) -0.004(4) 0.008(4) C112 0.032(5) 0.030(5) 0.045(5) 0.004(4) 0.021(4) 0.008(4) C50 0.035(5) 0.031(5) 0.025(4) -0.001(4) 0.012(4) 0.000(4) C137 0.054(6) 0.017(4) 0.020(4) 0.000(3) 0.003(4) -0.008(4) C114 0.022(4) 0.018(4) 0.034(4) 0.006(3) 0.007(3) 0.007(3) C113 0.015(4) 0.027(4) 0.048(5) 0.006(4) 0.005(4) 0.003(3) C122 0.047(5) 0.036(5) 0.035(5) 0.010(4) 0.025(4) 0.008(4) C97 0.029(5) 0.033(5) 0.036(5) 0.007(4) -0.002(4) 0.002(4) C71 0.024(4) 0.042(5) 0.027(4) -0.006(4) 0.011(3) -0.001(4) C90 0.026(5) 0.086(8) 0.031(5) -0.014(5) 0.015(4) -0.007(5) C65 0.040(5) 0.051(6) 0.015(4) 0.007(4) 0.008(4) -0.002(4) C32 0.040(5) 0.035(5) 0.028(5) -0.003(4) 0.019(4) -0.001(4) C36 0.032(5) 0.051(6) 0.028(5) -0.006(4) 0.009(4) 0.009(4) C80 0.031(5) 0.046(6) 0.039(5) -0.009(4) -0.007(4) 0.011(4) C28 0.070(7) 0.035(5) 0.040(5) -0.008(4) 0.033(5) -0.016(5) C127 0.034(5) 0.046(6) 0.063(7) -0.018(5) 0.027(5) -0.001(4) C121 0.050(6) 0.051(6) 0.040(5) 0.018(5) 0.026(5) 0.004(5) C31 0.033(5) 0.054(6) 0.021(4) -0.007(4) 0.007(4) 0.001(4) C130 0.023(5) 0.053(6) 0.049(6) -0.018(5) 0.004(4) 0.011(4) C30 0.048(6) 0.057(6) 0.030(5) 0.001(5) 0.027(4) -0.005(5) C87 0.035(5) 0.088(8) 0.023(5) 0.001(5) 0.006(4) -0.019(5) C129 0.028(5) 0.089(9) 0.063(8) -0.027(7) 0.007(5) 0.012(5) C23 0.108(11) 0.043(7) 0.074(9) 0.025(6) -0.005(8) 0.028(7) C128 0.030(6) 0.078(8) 0.080(9) -0.028(7) 0.029(6) -0.001(5) C89 0.033(6) 0.168(15) 0.032(6) -0.005(7) 0.015(5) 0.000(7) C120 0.059(6) 0.038(5) 0.036(5) 0.018(4) 0.019(5) 0.018(5) C88 0.054(7) 0.148(13) 0.027(5) 0.002(7) 0.026(5) -0.002(8) C29 0.072(8) 0.061(7) 0.060(7) -0.002(6) 0.040(6) -0.026(6) C22 0.072(8) 0.041(6) 0.061(7) 0.007(5) -0.007(6) 0.008(6) C25 0.052(6) 0.069(8) 0.041(6) -0.011(5) -0.005(5) 0.019(6) C24 0.074(8) 0.075(9) 0.035(6) 0.003(6) -0.013(6) 0.026(7) C142 0.082(10) 0.070(9) 0.114(12) -0.003(9) 0.034(9) 0.005(8) C144 0.087(9) 0.062(8) 0.057(7) 0.020(6) 0.027(7) 0.020(7) Cl1 0.114(3) 0.104(3) 0.069(2) 0.005(2) -0.020(2) 0.066(2) Cl4 0.0417(12) 0.0464(12) 0.0238(10) -0.0015(9) 0.0199(9) 0.0039(10) Cl3 0.0336(13) 0.0758(19) 0.0689(18) -0.0112(15) -0.0131(12) 0.0156(13) Cl2 0.085(2) 0.100(2) 0.0588(17) -0.0003(16) 0.0568(17) -0.0151(18) Cl11 0.082(2) 0.093(3) 0.109(3) -0.009(2) 0.028(2) 0.023(2) Cl13 0.175(4) 0.077(2) 0.059(2) -0.0035(18) 0.011(2) -0.018(3) C143 0.077(9) 0.074(9) 0.075(9) -0.023(7) 0.022(7) -0.005(7) Cl5 0.140(4) 0.062(2) 0.090(3) 0.0064(19) 0.000(2) -0.004(2) Cl6 0.139(4) 0.101(3) 0.103(3) -0.001(3) 0.026(3) 0.029(3) Cl7 0.120(4) 0.187(6) 0.158(5) 0.085(4) 0.046(4) 0.009(4) C141 0.119(13) 0.059(9) 0.095(11) 0.001(8) 0.011(10) 0.003(8) O1 0.081(11) 0.17(2) 0.074(12) 0.037(11) 0.024(9) -0.009(11) O2 0.081(11) 0.17(2) 0.074(12) 0.037(11) 0.024(9) -0.009(11) Cl12 0.085(2) 0.171(4) 0.101(3) -0.074(3) 0.047(2) -0.044(3) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Cd1 N8 2.421(6) . ? Cd1 N16 2.462(6) . ? Cd1 N7 2.470(6) . ? Cd1 N5 2.476(6) . ? Cd1 N13 2.514(6) . ? Cd1 N6 2.516(6) . ? Cd1 N15 2.597(6) . ? Cd1 N14 2.614(6) . ? Cd1 Eu2 3.3461(6) . ? Cd1 Eu1 3.4351(6) . ? Eu1 N3 2.398(6) . ? Eu1 N4 2.405(6) . ? Eu1 N2 2.409(6) . ? Eu1 N1 2.428(6) . ? Eu1 N5 2.638(6) . ? Eu1 N6 2.665(6) . ? Eu1 N8 2.763(6) . ? Eu1 N7 2.779(6) . ? Eu2 N23 2.377(6) . ? Eu2 N21 2.387(6) . ? Eu2 N24 2.389(6) . ? Eu2 N22 2.389(6) . ? Eu2 N14 2.578(6) . ? Eu2 N15 2.579(6) . ? Eu2 N16 2.579(6) . ? Eu2 N13 2.589(6) . ? Cl10 C142 1.782(14) . ? N15 C93 1.366(9) . ? N15 C100 1.393(9) . ? Cl15 C144 1.739(14) . ? N21 C109 1.364(9) . ? N21 C116 1.369(9) . ? N9 C76 1.331(10) . ? N9 C45 1.345(10) . ? C53 N10 1.324(9) . ? C53 N6 1.377(9) . ? C53 C54 1.447(10) . ? C92 N19 1.329(10) . ? C92 N14 1.392(10) . ? C92 C91 1.446(11) . ? C16 N3 1.364(10) . ? C16 C15 1.404(10) . ? C16 C17 1.439(10) . ? C45 N5 1.381(10) . ? C45 C46 1.437(11) . ? C61 N11 1.333(9) . ? C61 N7 1.379(10) . ? C61 C62 1.445(10) . ? C101 N20 1.320(9) . ? C101 N16 1.407(9) . ? C101 C102 1.449(10) . ? N11 C60 1.343(9) . ? C46 C47 1.387(11) . ? C46 C51 1.408(11) . ? C93 N19 1.332(10) . ? C93 C94 1.461(11) . ? N24 C140 1.368(9) . ? N24 C133 1.375(10) . ? N10 C52 1.332(10) . ? N27 C132 1.340(10) . ? N27 C133 1.349(10) . ? C108 N17 1.319(10) . ? C108 N16 1.389(9) . ? C108 C107 1.448(10) . ? N1 C6 1.371(10) . ? N1 C9 1.373(9) . ? N8 C76 1.377(10) . ? N8 C69 1.381(9) . ? N7 C68 1.385(9) . ? C68 N12 1.332(10) . ? C68 C67 1.459(11) . ? N3 C19 1.380(9) . ? C100 N20 1.316(9) . ? C100 C99 1.472(10) . ? C19 C20 1.411(11) . ? C19 C18 1.435(10) . ? C1 N4 1.381(9) . ? C1 C20 1.393(10) . ? C1 C2 1.449(11) . ? C15 C14 1.400(11) . ? C15 C33 1.507(11) . ? C20 C39 1.513(10) . ? C76 C75 1.463(10) . ? C4 N4 1.369(10) . ? C4 C5 1.421(11) . ? C4 C3 1.453(11) . ? N5 C52 1.382(9) . ? N12 C69 1.331(10) . ? N2 C11 1.370(9) . ? N2 C14 1.384(10) . ? C60 N6 1.365(9) . ? C60 C59 1.453(10) . ? N23 C132 1.362(10) . ? N23 C125 1.369(10) . ? N22 C124 1.361(10) . ? N22 C117 1.380(10) . ? C69 C70 1.451(11) . ? C70 C71 1.382(11) . ? C70 C75 1.402(11) . ? C133 C134 1.451(11) . ? N25 C116 1.342(9) . ? N25 C117 1.343(9) . ? C77 N17 1.331(9) . ? C77 N13 1.364(9) . ? C77 C78 1.458(11) . ? N18 C85 1.320(10) . ? N18 C84 1.341(10) . ? C84 N13 1.395(9) . ? C84 C83 1.461(11) . ? C51 C50 1.383(11) . ? C51 C52 1.458(11) . ? C2 C3 1.348(11) . ? C2 H2 0.9500 . ? C75 C74 1.410(11) . ? C67 C62 1.392(11) . ? C67 C66 1.398(11) . ? C59 C58 1.389(11) . ? C59 C54 1.394(10) . ? C33 C34 1.388(12) . ? C33 C38 1.389(11) . ? C8 C7 1.315(12) . ? C8 C9 1.433(11) . ? C8 H8 0.9500 . ? C9 C10 1.422(11) . ? C117 C118 1.446(10) . ? C13 C12 1.341(11) . ? C13 C14 1.442(11) . ? C13 H13 0.9500 . ? N14 C85 1.369(10) . ? C18 C17 1.349(11) . ? C18 H18 0.9500 . ? C102 C103 1.390(11) . ? C102 C107 1.404(11) . ? C17 H17 0.9500 . ? C39 C44 1.376(11) . ? C39 C40 1.388(11) . ? C40 C41 1.390(11) . ? C40 H40 0.9500 . ? C54 C55 1.393(11) . ? C10 C11 1.410(11) . ? C10 C27 1.501(11) . ? C58 C57 1.378(11) . ? C58 H58 0.9500 . ? C44 C43 1.388(11) . ? C44 H44 0.9500 . ? C99 C94 1.388(11) . ? C99 C98 1.388(11) . ? C95 C96 1.394(12) . ? C95 C94 1.399(11) . ? C95 H95 0.9500 . ? C85 C86 1.455(11) . ? C55 C56 1.385(12) . ? C55 H55 0.9500 . ? C12 C11 1.430(11) . ? C12 H12 0.9500 . ? C107 C106 1.394(11) . ? C6 C5 1.408(11) . ? C6 C7 1.454(11) . ? C3 H3 0.9500 . ? C83 C82 1.379(11) . ? C83 C78 1.394(11) . ? C5 C21 1.492(11) . ? C78 C79 1.409(11) . ? N28 C109 1.336(10) . ? N28 C140 1.336(10) . ? N26 C125 1.335(10) . ? N26 C124 1.344(10) . ? C63 C64 1.382(11) . ? C63 C62 1.388(11) . ? C63 H63 0.9500 . ? C86 C91 1.384(12) . ? C86 C87 1.400(12) . ? C103 C104 1.385(12) . ? C103 H10 0.9500 . ? C115 C114 1.384(11) . ? C115 C110 1.406(11) . ? C115 C116 1.450(10) . ? C109 C110 1.468(11) . ? C43 C42 1.374(11) . ? C43 H43 0.9500 . ? C126 C131 1.384(12) . ? C126 C127 1.397(12) . ? C126 C125 1.466(11) . ? C134 C139 1.394(11) . ? C134 C135 1.395(11) . ? C72 C71 1.376(12) . ? C72 C73 1.419(13) . ? C72 H72 0.9500 . ? C139 C138 1.393(11) . ? C139 C140 1.463(11) . ? C123 C118 1.395(12) . ? C123 C122 1.395(11) . ? C123 C124 1.458(11) . ? C104 C105 1.394(13) . ? C104 H10A 0.9500 . ? C21 C26 1.383(13) . ? C21 C22 1.395(14) . ? C82 C81 1.380(13) . ? C82 H82 0.9500 . ? C7 H7 0.9500 . ? C98 C97 1.389(12) . ? C98 H98 0.9500 . ? C132 C131 1.430(11) . ? C110 C111 1.393(11) . ? C79 C80 1.373(12) . ? C79 H79 0.9500 . ? C118 C119 1.391(11) . ? C66 C65 1.387(12) . ? C66 H66 0.9500 . ? C34 C35 1.408(12) . ? C34 H34 0.9500 . ? C105 C106 1.370(12) . ? C105 H10B 0.9500 . ? C37 C36 1.384(13) . ? C37 C38 1.399(12) . ? C37 H37 0.9500 . ? C64 C65 1.388(12) . ? C64 H64 0.9500 . ? C73 C74 1.368(12) . ? C73 H73 0.9500 . ? C96 C97 1.384(13) . ? C96 H96 0.9500 . ? C27 C28 1.378(12) . ? C27 C32 1.386(12) . ? C38 H38 0.9500 . ? C131 C130 1.388(12) . ? C56 C57 1.392(12) . ? C56 H56 0.9500 . ? C106 H10C 0.9500 . ? C74 H74 0.9500 . ? C57 H57 0.9500 . ? C91 C90 1.397(12) . ? C119 C120 1.380(12) . ? C119 H11 0.9500 . ? Cl16 C144 1.802(13) . ? Cl14 C144 1.727(12) . ? Cl8 C142 1.772(16) . ? Cl9 C142 1.753(15) . ? C138 C137 1.388(12) . ? C138 H13A 0.9500 . ? C41 C42 1.356(11) . ? C41 H41 0.9500 . ? C49 C50 1.372(12) . ? C49 C48 1.409(13) . ? C49 H49 0.9500 . ? C111 C112 1.392(12) . ? C111 H11A 0.9500 . ? C136 C135 1.357(12) . ? C136 C137 1.393(13) . ? C136 H13B 0.9500 . ? C42 Cl4 1.754(7) . ? C135 H13C 0.9500 . ? C35 C36 1.359(13) . ? C35 H35 0.9500 . ? C48 C47 1.382(11) . ? C48 H48 0.9500 . ? C47 H47 0.9500 . ? C26 C25 1.368(14) . ? C26 H26 0.9500 . ? C81 C80 1.396(14) . ? C81 H81 0.9500 . ? C112 C113 1.389(12) . ? C112 H11B 0.9500 . ? C50 H50 0.9500 . ? C137 H13D 0.9500 . ? C114 C113 1.383(11) . ? C114 H11C 0.9500 . ? C113 H11D 0.9500 . ? C122 C121 1.377(13) . ? C122 H12A 0.9500 . ? C97 H97 0.9500 . ? C71 H71 0.9500 . ? C90 C89 1.389(14) . ? C90 H90 0.9500 . ? C65 H65 0.9500 . ? C32 C31 1.385(12) . ? C32 H32 0.9500 . ? C36 Cl3 1.741(9) . ? C80 H80 0.9500 . ? C28 C29 1.390(13) . ? C28 H28 0.9500 . ? C127 C128 1.396(15) . ? C127 H12B 0.9500 . ? C121 C120 1.409(14) . ? C121 H12C 0.9500 . ? C31 C30 1.351(13) . ? C31 H31 0.9500 . ? C130 C129 1.383(15) . ? C130 H13E 0.9500 . ? C30 C29 1.356(15) . ? C30 Cl2 1.758(8) . ? C87 C88 1.379(15) . ? C87 H87 0.9500 . ? C129 C128 1.372(17) . ? C129 H12D 0.9500 . ? C23 C24 1.355(18) . ? C23 C22 1.379(16) . ? C23 H23 0.9500 . ? C128 H12E 0.9500 . ? C89 C88 1.382(17) . ? C89 H89 0.9500 . ? C120 H12F 0.9500 . ? C88 H88 0.9500 . ? C29 H29 0.9500 . ? C22 H22 0.9500 . ? C25 C24 1.374(18) . ? C25 H25 0.9500 . ? C24 Cl1 1.770(11) . ? C142 H14C 1.0000 . ? C144 H14 1.0000 . ? Cl11 C143 1.731(13) . ? Cl13 C143 1.756(14) . ? C143 Cl12 1.753(14) . ? C143 H14B 1.0000 . ? Cl5 C141 1.734(15) . ? Cl6 C141 1.755(16) . ? Cl7 C141 1.778(17) . ? C141 H14A 1.0000 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N8 Cd1 N16 146.6(2) . . ? N8 Cd1 N7 68.2(2) . . ? N16 Cd1 N7 142.79(19) . . ? N8 Cd1 N5 67.73(19) . . ? N16 Cd1 N5 88.14(19) . . ? N7 Cd1 N5 103.0(2) . . ? N8 Cd1 N13 143.19(19) . . ? N16 Cd1 N13 66.77(19) . . ? N7 Cd1 N13 87.4(2) . . ? N5 Cd1 N13 147.55(19) . . ? N8 Cd1 N6 103.3(2) . . ? N16 Cd1 N6 86.74(19) . . ? N7 Cd1 N6 66.37(19) . . ? N5 Cd1 N6 66.7(2) . . ? N13 Cd1 N6 90.60(19) . . ? N8 Cd1 N15 89.51(19) . . ? N16 Cd1 N15 65.81(18) . . ? N7 Cd1 N15 148.50(18) . . ? N5 Cd1 N15 87.66(19) . . ? N13 Cd1 N15 99.44(19) . . ? N6 Cd1 N15 143.37(18) . . ? N8 Cd1 N14 88.29(19) . . ? N16 Cd1 N14 99.33(19) . . ? N7 Cd1 N14 92.70(19) . . ? N5 Cd1 N14 143.11(19) . . ? N13 Cd1 N14 64.93(18) . . ? N6 Cd1 N14 149.13(19) . . ? N15 Cd1 N14 63.59(18) . . ? N8 Cd1 Eu2 128.79(14) . . ? N16 Cd1 Eu2 49.93(13) . . ? N7 Cd1 Eu2 129.88(14) . . ? N5 Cd1 Eu2 127.11(14) . . ? N13 Cd1 Eu2 49.99(14) . . ? N6 Cd1 Eu2 127.92(14) . . ? N15 Cd1 Eu2 49.49(13) . . ? N14 Cd1 Eu2 49.41(13) . . ? N8 Cd1 Eu1 52.93(14) . . ? N16 Cd1 Eu1 126.73(14) . . ? N7 Cd1 Eu1 53.14(14) . . ? N5 Cd1 Eu1 49.83(14) . . ? N13 Cd1 Eu1 131.12(14) . . ? N6 Cd1 Eu1 50.36(14) . . ? N15 Cd1 Eu1 129.40(13) . . ? N14 Cd1 Eu1 133.88(13) . . ? Eu2 Cd1 Eu1 176.498(18) . . ? N3 Eu1 N4 75.2(2) . . ? N3 Eu1 N2 74.6(2) . . ? N4 Eu1 N2 116.8(2) . . ? N3 Eu1 N1 118.5(2) . . ? N4 Eu1 N1 74.3(2) . . ? N2 Eu1 N1 73.8(2) . . ? N3 Eu1 N5 166.1(2) . . ? N4 Eu1 N5 109.9(2) . . ? N2 Eu1 N5 112.49(18) . . ? N1 Eu1 N5 75.36(19) . . ? N3 Eu1 N6 109.93(19) . . ? N4 Eu1 N6 166.85(19) . . ? N2 Eu1 N6 76.30(19) . . ? N1 Eu1 N6 111.82(19) . . ? N5 Eu1 N6 62.38(18) . . ? N3 Eu1 N8 109.86(18) . . ? N4 Eu1 N8 75.89(19) . . ? N2 Eu1 N8 167.25(19) . . ? N1 Eu1 N8 112.44(19) . . ? N5 Eu1 N8 60.67(17) . . ? N6 Eu1 N8 90.96(18) . . ? N3 Eu1 N7 75.00(19) . . ? N4 Eu1 N7 111.40(19) . . ? N2 Eu1 N7 112.19(19) . . ? N1 Eu1 N7 166.53(18) . . ? N5 Eu1 N7 91.18(18) . . ? N6 Eu1 N7 60.14(17) . . ? N8 Eu1 N7 59.32(18) . . ? N3 Eu1 Cd1 120.33(14) . . ? N4 Eu1 Cd1 120.24(15) . . ? N2 Eu1 Cd1 122.93(14) . . ? N1 Eu1 Cd1 121.20(14) . . ? N5 Eu1 Cd1 45.84(13) . . ? N6 Eu1 Cd1 46.63(13) . . ? N8 Eu1 Cd1 44.36(12) . . ? N7 Eu1 Cd1 45.34(12) . . ? N23 Eu2 N21 112.7(2) . . ? N23 Eu2 N24 72.6(2) . . ? N21 Eu2 N24 70.9(2) . . ? N23 Eu2 N22 72.3(2) . . ? N21 Eu2 N22 72.5(2) . . ? N24 Eu2 N22 112.5(2) . . ? N23 Eu2 N14 87.19(19) . . ? N21 Eu2 N14 141.9(2) . . ? N24 Eu2 N14 147.1(2) . . ? N22 Eu2 N14 84.29(19) . . ? N23 Eu2 N15 83.88(19) . . ? N21 Eu2 N15 145.88(19) . . ? N24 Eu2 N15 87.47(19) . . ? N22 Eu2 N15 141.49(19) . . ? N14 Eu2 N15 64.34(18) . . ? N23 Eu2 N16 141.5(2) . . ? N21 Eu2 N16 86.79(19) . . ? N24 Eu2 N16 84.2(2) . . ? N22 Eu2 N16 146.1(2) . . ? N14 Eu2 N16 97.26(18) . . ? N15 Eu2 N16 64.45(18) . . ? N23 Eu2 N13 146.58(19) . . ? N21 Eu2 N13 84.17(19) . . ? N24 Eu2 N13 140.67(19) . . ? N22 Eu2 N13 87.0(2) . . ? N14 Eu2 N13 64.42(19) . . ? N15 Eu2 N13 97.99(18) . . ? N16 Eu2 N13 64.00(18) . . ? N23 Eu2 Cd1 125.44(14) . . ? N21 Eu2 Cd1 121.85(14) . . ? N24 Eu2 Cd1 123.18(15) . . ? N22 Eu2 Cd1 124.29(14) . . ? N14 Eu2 Cd1 50.34(13) . . ? N15 Eu2 Cd1 49.96(13) . . ? N16 Eu2 Cd1 46.92(12) . . ? N13 Eu2 Cd1 48.07(13) . . ? C93 N15 C100 107.3(6) . . ? C93 N15 Eu2 120.1(4) . . ? C100 N15 Eu2 116.6(4) . . ? C93 N15 Cd1 116.2(4) . . ? C100 N15 Cd1 114.3(4) . . ? Eu2 N15 Cd1 80.55(17) . . ? C109 N21 C116 107.6(6) . . ? C109 N21 Eu2 122.7(5) . . ? C116 N21 Eu2 121.0(4) . . ? C76 N9 C45 121.8(7) . . ? N10 C53 N6 127.7(6) . . ? N10 C53 C54 122.3(6) . . ? N6 C53 C54 110.0(6) . . ? N19 C92 N14 128.5(6) . . ? N19 C92 C91 122.5(7) . . ? N14 C92 C91 109.0(7) . . ? N3 C16 C15 125.2(7) . . ? N3 C16 C17 109.2(6) . . ? C15 C16 C17 125.6(7) . . ? N9 C45 N5 126.9(7) . . ? N9 C45 C46 122.2(7) . . ? N5 C45 C46 111.0(6) . . ? N11 C61 N7 126.9(6) . . ? N11 C61 C62 122.8(7) . . ? N7 C61 C62 110.3(6) . . ? N20 C101 N16 126.6(6) . . ? N20 C101 C102 123.9(7) . . ? N16 C101 C102 109.5(6) . . ? C61 N11 C60 122.2(6) . . ? C47 C46 C51 120.5(7) . . ? C47 C46 C45 133.3(7) . . ? C51 C46 C45 106.2(6) . . ? N19 C93 N15 127.6(7) . . ? N19 C93 C94 122.0(6) . . ? N15 C93 C94 110.3(6) . . ? C140 N24 C133 107.1(6) . . ? C140 N24 Eu2 123.8(5) . . ? C133 N24 Eu2 120.9(5) . . ? C53 N10 C52 122.7(6) . . ? C132 N27 C133 123.7(7) . . ? N17 C108 N16 127.3(6) . . ? N17 C108 C107 123.4(7) . . ? N16 C108 C107 109.4(6) . . ? C6 N1 C9 105.9(6) . . ? C6 N1 Eu1 124.9(5) . . ? C9 N1 Eu1 124.7(5) . . ? C76 N8 C69 106.5(6) . . ? C76 N8 Cd1 120.2(4) . . ? C69 N8 Cd1 118.0(5) . . ? C76 N8 Eu1 111.4(4) . . ? C69 N8 Eu1 116.7(4) . . ? Cd1 N8 Eu1 82.71(17) . . ? C61 N7 C68 106.7(6) . . ? C61 N7 Cd1 118.1(4) . . ? C68 N7 Cd1 114.9(4) . . ? C61 N7 Eu1 116.1(4) . . ? C68 N7 Eu1 118.4(5) . . ? Cd1 N7 Eu1 81.52(17) . . ? N12 C68 N7 127.1(7) . . ? N12 C68 C67 122.9(6) . . ? N7 C68 C67 110.0(6) . . ? C16 N3 C19 106.9(6) . . ? C16 N3 Eu1 125.0(4) . . ? C19 N3 Eu1 122.4(5) . . ? N20 C100 N15 127.7(6) . . ? N20 C100 C99 123.1(7) . . ? N15 C100 C99 109.2(6) . . ? N3 C19 C20 125.8(7) . . ? N3 C19 C18 109.1(6) . . ? C20 C19 C18 124.8(6) . . ? N4 C1 C20 126.3(7) . . ? N4 C1 C2 109.3(6) . . ? C20 C1 C2 124.2(6) . . ? C14 C15 C16 126.0(7) . . ? C14 C15 C33 116.6(6) . . ? C16 C15 C33 117.3(6) . . ? C1 C20 C19 125.8(6) . . ? C1 C20 C39 118.9(6) . . ? C19 C20 C39 115.2(6) . . ? N9 C76 N8 127.6(7) . . ? N9 C76 C75 122.1(7) . . ? N8 C76 C75 110.3(6) . . ? C100 N20 C101 123.3(6) . . ? N4 C4 C5 126.6(7) . . ? N4 C4 C3 110.0(6) . . ? C5 C4 C3 123.4(7) . . ? C45 N5 C52 106.7(6) . . ? C45 N5 Cd1 117.9(4) . . ? C52 N5 Cd1 117.8(5) . . ? C45 N5 Eu1 115.0(4) . . ? C52 N5 Eu1 114.1(4) . . ? Cd1 N5 Eu1 84.33(18) . . ? C69 N12 C68 122.7(6) . . ? C4 N4 C1 106.4(6) . . ? C4 N4 Eu1 126.3(5) . . ? C1 N4 Eu1 123.5(5) . . ? C11 N2 C14 105.3(6) . . ? C11 N2 Eu1 126.1(5) . . ? C14 N2 Eu1 124.3(5) . . ? C108 N16 C101 107.2(6) . . ? C108 N16 Cd1 115.8(4) . . ? C101 N16 Cd1 118.9(4) . . ? C108 N16 Eu2 115.7(4) . . ? C101 N16 Eu2 114.9(4) . . ? Cd1 N16 Eu2 83.15(17) . . ? C92 N19 C93 121.5(6) . . ? N11 C60 N6 127.0(6) . . ? N11 C60 C59 122.1(6) . . ? N6 C60 C59 110.9(6) . . ? C132 N23 C125 108.4(6) . . ? C132 N23 Eu2 122.0(5) . . ? C125 N23 Eu2 125.2(5) . . ? C124 N22 C117 107.9(6) . . ? C124 N22 Eu2 125.8(5) . . ? C117 N22 Eu2 123.0(5) . . ? N12 C69 N8 127.0(7) . . ? N12 C69 C70 121.9(6) . . ? N8 C69 C70 111.1(7) . . ? C60 N6 C53 106.8(6) . . ? C60 N6 Cd1 119.2(4) . . ? C53 N6 Cd1 117.8(4) . . ? C60 N6 Eu1 116.3(4) . . ? C53 N6 Eu1 112.6(4) . . ? Cd1 N6 Eu1 83.01(17) . . ? C71 C70 C75 120.9(7) . . ? C71 C70 C69 133.4(7) . . ? C75 C70 C69 105.8(6) . . ? N27 C133 N24 126.6(7) . . ? N27 C133 C134 122.9(7) . . ? N24 C133 C134 110.5(7) . . ? C116 N25 C117 123.6(6) . . ? N17 C77 N13 127.2(7) . . ? N17 C77 C78 122.8(7) . . ? N13 C77 C78 109.9(6) . . ? C85 N18 C84 122.7(6) . . ? N18 C84 N13 126.8(7) . . ? N18 C84 C83 123.9(7) . . ? N13 C84 C83 109.3(6) . . ? C50 C51 C46 121.7(7) . . ? C50 C51 C52 132.0(7) . . ? C46 C51 C52 106.2(6) . . ? C3 C2 C1 107.6(7) . . ? C3 C2 H2 126.2 . . ? C1 C2 H2 126.2 . . ? C70 C75 C74 121.3(7) . . ? C70 C75 C76 106.4(7) . . ? C74 C75 C76 132.3(7) . . ? C62 C67 C66 121.7(8) . . ? C62 C67 C68 106.0(6) . . ? C66 C67 C68 132.2(7) . . ? C58 C59 C54 120.7(7) . . ? C58 C59 C60 133.7(7) . . ? C54 C59 C60 105.5(6) . . ? C34 C33 C38 119.5(8) . . ? C34 C33 C15 120.6(7) . . ? C38 C33 C15 119.9(7) . . ? C7 C8 C9 107.6(7) . . ? C7 C8 H8 126.2 . . ? C9 C8 H8 126.2 . . ? N1 C9 C10 124.9(7) . . ? N1 C9 C8 109.9(7) . . ? C10 C9 C8 124.9(7) . . ? C77 N13 C84 107.6(6) . . ? C77 N13 Cd1 113.3(4) . . ? C84 N13 Cd1 118.3(4) . . ? C77 N13 Eu2 118.4(4) . . ? C84 N13 Eu2 115.9(4) . . ? Cd1 N13 Eu2 81.94(17) . . ? N25 C117 N22 127.9(7) . . ? N25 C117 C118 122.5(7) . . ? N22 C117 C118 109.6(6) . . ? C12 C13 C14 106.5(7) . . ? C12 C13 H13 126.7 . . ? C14 C13 H13 126.7 . . ? C85 N14 C92 107.8(6) . . ? C85 N14 Eu2 117.8(5) . . ? C92 N14 Eu2 118.7(4) . . ? C85 N14 Cd1 115.5(5) . . ? C92 N14 Cd1 115.0(5) . . ? Eu2 N14 Cd1 80.25(17) . . ? C17 C18 C19 107.1(6) . . ? C17 C18 H18 126.4 . . ? C19 C18 H18 126.4 . . ? N10 C52 N5 127.0(7) . . ? N10 C52 C51 123.1(7) . . ? N5 C52 C51 109.9(7) . . ? C103 C102 C107 122.1(7) . . ? C103 C102 C101 131.4(7) . . ? C107 C102 C101 106.4(6) . . ? C18 C17 C16 107.5(7) . . ? C18 C17 H17 126.2 . . ? C16 C17 H17 126.2 . . ? C44 C39 C40 119.9(7) . . ? C44 C39 C20 120.1(7) . . ? C40 C39 C20 119.9(7) . . ? C39 C40 C41 119.5(7) . . ? C39 C40 H40 120.2 . . ? C41 C40 H40 120.2 . . ? C55 C54 C59 120.9(7) . . ? C55 C54 C53 132.3(7) . . ? C59 C54 C53 106.8(6) . . ? C11 C10 C9 125.8(7) . . ? C11 C10 C27 116.1(7) . . ? C9 C10 C27 117.9(7) . . ? C57 C58 C59 118.3(8) . . ? C57 C58 H58 120.9 . . ? C59 C58 H58 120.9 . . ? C39 C44 C43 120.3(7) . . ? C39 C44 H44 119.8 . . ? C43 C44 H44 119.8 . . ? C94 C99 C98 122.3(7) . . ? C94 C99 C100 106.3(6) . . ? C98 C99 C100 131.3(7) . . ? C96 C95 C94 116.4(8) . . ? C96 C95 H95 121.8 . . ? C94 C95 H95 121.8 . . ? N18 C85 N14 127.9(7) . . ? N18 C85 C86 122.7(7) . . ? N14 C85 C86 109.4(7) . . ? C56 C55 C54 117.9(8) . . ? C56 C55 H55 121.0 . . ? C54 C55 H55 121.0 . . ? C99 C94 C95 121.1(7) . . ? C99 C94 C93 106.7(6) . . ? C95 C94 C93 132.1(7) . . ? C13 C12 C11 107.9(7) . . ? C13 C12 H12 126.1 . . ? C11 C12 H12 126.1 . . ? C106 C107 C102 120.1(7) . . ? C106 C107 C108 132.3(7) . . ? C102 C107 C108 107.5(6) . . ? N1 C6 C5 126.4(7) . . ? N1 C6 C7 108.8(7) . . ? C5 C6 C7 124.6(7) . . ? C2 C3 C4 106.7(7) . . ? C2 C3 H3 126.6 . . ? C4 C3 H3 126.6 . . ? C82 C83 C78 121.6(8) . . ? C82 C83 C84 132.2(7) . . ? C78 C83 C84 106.1(7) . . ? C6 C5 C4 124.2(7) . . ? C6 C5 C21 116.7(7) . . ? C4 C5 C21 118.8(7) . . ? C83 C78 C79 120.7(7) . . ? C83 C78 C77 107.0(7) . . ? C79 C78 C77 132.3(7) . . ? C108 N17 C77 122.7(6) . . ? C109 N28 C140 122.1(6) . . ? C125 N26 C124 123.4(6) . . ? C64 C63 C62 117.9(8) . . ? C64 C63 H63 121.1 . . ? C62 C63 H63 121.1 . . ? C91 C86 C87 121.6(8) . . ? C91 C86 C85 106.8(7) . . ? C87 C86 C85 131.4(9) . . ? C104 C103 C102 116.4(8) . . ? C104 C103 H10 121.8 . . ? C102 C103 H10 121.8 . . ? C114 C115 C110 120.1(7) . . ? C114 C115 C116 134.2(7) . . ? C110 C115 C116 105.6(7) . . ? N28 C109 N21 128.5(7) . . ? N28 C109 C110 121.9(6) . . ? N21 C109 C110 109.6(6) . . ? C42 C43 C44 118.8(7) . . ? C42 C43 H43 120.6 . . ? C44 C43 H43 120.6 . . ? C131 C126 C127 121.0(8) . . ? C131 C126 C125 106.3(7) . . ? C127 C126 C125 132.7(9) . . ? N2 C11 C10 125.3(7) . . ? N2 C11 C12 110.2(7) . . ? C10 C11 C12 124.5(7) . . ? C139 C134 C135 120.7(8) . . ? C139 C134 C133 106.0(7) . . ? C135 C134 C133 133.2(8) . . ? C71 C72 C73 120.9(8) . . ? C71 C72 H72 119.5 . . ? C73 C72 H72 119.5 . . ? C138 C139 C134 121.2(7) . . ? C138 C139 C140 132.3(7) . . ? C134 C139 C140 106.4(7) . . ? C118 C123 C122 121.1(8) . . ? C118 C123 C124 106.4(7) . . ? C122 C123 C124 132.2(8) . . ? C63 C62 C67 120.7(7) . . ? C63 C62 C61 132.2(7) . . ? C67 C62 C61 107.0(7) . . ? C103 C104 C105 122.1(8) . . ? C103 C104 H10A 118.9 . . ? C105 C104 H10A 118.9 . . ? C26 C21 C22 118.9(9) . . ? C26 C21 C5 120.1(8) . . ? C22 C21 C5 121.0(9) . . ? C83 C82 C81 117.8(8) . . ? C83 C82 H82 121.1 . . ? C81 C82 H82 121.1 . . ? N25 C116 N21 127.2(6) . . ? N25 C116 C115 122.0(7) . . ? N21 C116 C115 110.7(6) . . ? C8 C7 C6 107.7(7) . . ? C8 C7 H7 126.1 . . ? C6 C7 H7 126.1 . . ? C99 C98 C97 116.3(8) . . ? C99 C98 H98 121.9 . . ? C97 C98 H98 121.9 . . ? N27 C132 N23 128.2(7) . . ? N27 C132 C131 121.9(7) . . ? N23 C132 C131 109.8(7) . . ? C111 C110 C115 121.8(7) . . ? C111 C110 C109 131.9(7) . . ? C115 C110 C109 106.2(6) . . ? C80 C79 C78 116.8(8) . . ? C80 C79 H79 121.6 . . ? C78 C79 H79 121.6 . . ? N28 C140 N24 127.5(7) . . ? N28 C140 C139 122.6(7) . . ? N24 C140 C139 109.9(6) . . ? C119 C118 C123 122.0(7) . . ? C119 C118 C117 131.4(7) . . ? C123 C118 C117 106.4(7) . . ? C65 C66 C67 116.6(8) . . ? C65 C66 H66 121.7 . . ? C67 C66 H66 121.7 . . ? C33 C34 C35 119.8(8) . . ? C33 C34 H34 120.1 . . ? C35 C34 H34 120.1 . . ? N26 C125 N23 127.9(7) . . ? N26 C125 C126 123.6(7) . . ? N23 C125 C126 108.3(7) . . ? C106 C105 C104 121.2(8) . . ? C106 C105 H10B 119.4 . . ? C104 C105 H10B 119.4 . . ? C36 C37 C38 118.5(8) . . ? C36 C37 H37 120.7 . . ? C38 C37 H37 120.7 . . ? C63 C64 C65 121.3(8) . . ? C63 C64 H64 119.4 . . ? C65 C64 H64 119.4 . . ? C74 C73 C72 121.7(8) . . ? C74 C73 H73 119.2 . . ? C72 C73 H73 119.2 . . ? N2 C14 C15 125.9(7) . . ? N2 C14 C13 110.0(6) . . ? C15 C14 C13 124.1(7) . . ? C97 C96 C95 121.9(8) . . ? C97 C96 H96 119.1 . . ? C95 C96 H96 119.1 . . ? C28 C27 C32 119.1(7) . . ? C28 C27 C10 121.4(7) . . ? C32 C27 C10 119.4(7) . . ? C33 C38 C37 120.7(8) . . ? C33 C38 H38 119.7 . . ? C37 C38 H38 119.7 . . ? C126 C131 C130 121.3(8) . . ? C126 C131 C132 107.0(7) . . ? C130 C131 C132 131.7(8) . . ? C55 C56 C57 121.0(7) . . ? C55 C56 H56 119.5 . . ? C57 C56 H56 119.5 . . ? C105 C106 C107 118.1(8) . . ? C105 C106 H10C 120.9 . . ? C107 C106 H10C 120.9 . . ? C73 C74 C75 117.0(8) . . ? C73 C74 H74 121.5 . . ? C75 C74 H74 121.5 . . ? C58 C57 C56 121.2(8) . . ? C58 C57 H57 119.4 . . ? C56 C57 H57 119.4 . . ? C86 C91 C90 121.3(8) . . ? C86 C91 C92 107.1(7) . . ? C90 C91 C92 131.7(8) . . ? C120 C119 C118 116.7(8) . . ? C120 C119 H11 121.6 . . ? C118 C119 H11 121.6 . . ? C137 C138 C139 117.1(8) . . ? C137 C138 H13A 121.4 . . ? C139 C138 H13A 121.4 . . ? N26 C124 N22 127.4(7) . . ? N26 C124 C123 122.9(7) . . ? N22 C124 C123 109.6(7) . . ? C42 C41 C40 119.6(8) . . ? C42 C41 H41 120.2 . . ? C40 C41 H41 120.2 . . ? C50 C49 C48 121.3(8) . . ? C50 C49 H49 119.4 . . ? C48 C49 H49 119.4 . . ? C112 C111 C110 117.1(8) . . ? C112 C111 H11A 121.4 . . ? C110 C111 H11A 121.4 . . ? C135 C136 C137 122.0(8) . . ? C135 C136 H13B 119.0 . . ? C137 C136 H13B 119.0 . . ? C41 C42 C43 121.9(7) . . ? C41 C42 Cl4 119.3(6) . . ? C43 C42 Cl4 118.8(6) . . ? C136 C135 C134 117.9(8) . . ? C136 C135 H13C 121.0 . . ? C134 C135 H13C 121.0 . . ? C36 C35 C34 119.6(8) . . ? C36 C35 H35 120.2 . . ? C34 C35 H35 120.2 . . ? C47 C48 C49 121.4(8) . . ? C47 C48 H48 119.3 . . ? C49 C48 H48 119.3 . . ? C48 C47 C46 117.6(8) . . ? C48 C47 H47 121.2 . . ? C46 C47 H47 121.2 . . ? C25 C26 C21 120.9(10) . . ? C25 C26 H26 119.5 . . ? C21 C26 H26 119.5 . . ? C82 C81 C80 120.8(8) . . ? C82 C81 H81 119.6 . . ? C80 C81 H81 119.6 . . ? C113 C112 C111 120.8(8) . . ? C113 C112 H11B 119.6 . . ? C111 C112 H11B 119.6 . . ? C49 C50 C51 117.5(8) . . ? C49 C50 H50 121.2 . . ? C51 C50 H50 121.2 . . ? C138 C137 C136 121.1(8) . . ? C138 C137 H13D 119.5 . . ? C136 C137 H13D 119.5 . . ? C113 C114 C115 118.0(7) . . ? C113 C114 H11C 121.0 . . ? C115 C114 H11C 121.0 . . ? C114 C113 C112 122.0(7) . . ? C114 C113 H11D 119.0 . . ? C112 C113 H11D 119.0 . . ? C121 C122 C123 117.0(8) . . ? C121 C122 H12A 121.5 . . ? C123 C122 H12A 121.5 . . ? C96 C97 C98 121.9(8) . . ? C96 C97 H97 119.0 . . ? C98 C97 H97 119.0 . . ? C72 C71 C70 118.3(8) . . ? C72 C71 H71 120.9 . . ? C70 C71 H71 120.9 . . ? C89 C90 C91 116.7(10) . . ? C89 C90 H90 121.7 . . ? C91 C90 H90 121.7 . . ? C66 C65 C64 121.8(7) . . ? C66 C65 H65 119.1 . . ? C64 C65 H65 119.1 . . ? C31 C32 C27 119.8(8) . . ? C31 C32 H32 120.1 . . ? C27 C32 H32 120.1 . . ? C35 C36 C37 121.9(8) . . ? C35 C36 Cl3 118.8(7) . . ? C37 C36 Cl3 119.3(7) . . ? C79 C80 C81 122.3(8) . . ? C79 C80 H80 118.9 . . ? C81 C80 H80 118.9 . . ? C27 C28 C29 120.1(9) . . ? C27 C28 H28 119.9 . . ? C29 C28 H28 119.9 . . ? C128 C127 C126 116.6(10) . . ? C128 C127 H12B 121.7 . . ? C126 C127 H12B 121.7 . . ? C122 C121 C120 121.7(8) . . ? C122 C121 H12C 119.1 . . ? C120 C121 H12C 119.1 . . ? C30 C31 C32 120.1(9) . . ? C30 C31 H31 120.0 . . ? C32 C31 H31 120.0 . . ? C129 C130 C131 118.0(10) . . ? C129 C130 H13E 121.0 . . ? C131 C130 H13E 121.0 . . ? C31 C30 C29 121.4(8) . . ? C31 C30 Cl2 119.0(7) . . ? C29 C30 Cl2 119.6(8) . . ? C88 C87 C86 116.6(10) . . ? C88 C87 H87 121.7 . . ? C86 C87 H87 121.7 . . ? C128 C129 C130 120.7(10) . . ? C128 C129 H12D 119.7 . . ? C130 C129 H12D 119.7 . . ? C24 C23 C22 119.7(12) . . ? C24 C23 H23 120.2 . . ? C22 C23 H23 120.2 . . ? C129 C128 C127 122.3(10) . . ? C129 C128 H12E 118.8 . . ? C127 C128 H12E 118.8 . . ? C88 C89 C90 121.7(10) . . ? C88 C89 H89 119.1 . . ? C90 C89 H89 119.1 . . ? C119 C120 C121 121.5(8) . . ? C119 C120 H12F 119.3 . . ? C121 C120 H12F 119.3 . . ? C87 C88 C89 122.0(9) . . ? C87 C88 H88 119.0 . . ? C89 C88 H88 119.0 . . ? C30 C29 C28 119.5(10) . . ? C30 C29 H29 120.3 . . ? C28 C29 H29 120.3 . . ? C23 C22 C21 119.8(11) . . ? C23 C22 H22 120.1 . . ? C21 C22 H22 120.1 . . ? C26 C25 C24 119.0(11) . . ? C26 C25 H25 120.5 . . ? C24 C25 H25 120.5 . . ? C23 C24 C25 121.7(10) . . ? C23 C24 Cl1 118.2(10) . . ? C25 C24 Cl1 120.1(10) . . ? Cl9 C142 Cl8 111.8(9) . . ? Cl9 C142 Cl10 110.1(8) . . ? Cl8 C142 Cl10 108.3(8) . . ? Cl9 C142 H14C 108.9 . . ? Cl8 C142 H14C 108.9 . . ? Cl10 C142 H14C 108.9 . . ? Cl14 C144 Cl15 112.3(7) . . ? Cl14 C144 Cl16 109.4(7) . . ? Cl15 C144 Cl16 110.7(6) . . ? Cl14 C144 H14 108.1 . . ? Cl15 C144 H14 108.1 . . ? Cl16 C144 H14 108.1 . . ? Cl11 C143 Cl12 109.8(7) . . ? Cl11 C143 Cl13 111.5(8) . . ? Cl12 C143 Cl13 108.1(8) . . ? Cl11 C143 H14B 109.1 . . ? Cl12 C143 H14B 109.1 . . ? Cl13 C143 H14B 109.1 . . ? Cl5 C141 Cl6 111.5(9) . . ? Cl5 C141 Cl7 109.4(9) . . ? Cl6 C141 Cl7 107.5(9) . . ? Cl5 C141 H14A 109.5 . . ? Cl6 C141 H14A 109.5 . . ? Cl7 C141 H14A 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N8 Cd1 Eu1 N3 88.0(2) . . . . ? N16 Cd1 Eu1 N3 -134.2(2) . . . . ? N7 Cd1 Eu1 N3 -1.1(2) . . . . ? N5 Cd1 Eu1 N3 178.9(2) . . . . ? N13 Cd1 Eu1 N3 -44.3(2) . . . . ? N6 Cd1 Eu1 N3 -89.5(2) . . . . ? N15 Cd1 Eu1 N3 138.6(2) . . . . ? N14 Cd1 Eu1 N3 49.1(2) . . . . ? Eu2 Cd1 Eu1 N3 -151.4(3) . . . . ? N8 Cd1 Eu1 N4 -1.9(2) . . . . ? N16 Cd1 Eu1 N4 135.9(2) . . . . ? N7 Cd1 Eu1 N4 -91.0(2) . . . . ? N5 Cd1 Eu1 N4 89.0(2) . . . . ? N13 Cd1 Eu1 N4 -134.2(2) . . . . ? N6 Cd1 Eu1 N4 -179.3(2) . . . . ? N15 Cd1 Eu1 N4 48.7(2) . . . . ? N14 Cd1 Eu1 N4 -40.8(2) . . . . ? Eu2 Cd1 Eu1 N4 118.8(4) . . . . ? N8 Cd1 Eu1 N2 178.7(2) . . . . ? N16 Cd1 Eu1 N2 -43.5(2) . . . . ? N7 Cd1 Eu1 N2 89.6(2) . . . . ? N5 Cd1 Eu1 N2 -90.4(2) . . . . ? N13 Cd1 Eu1 N2 46.4(2) . . . . ? N6 Cd1 Eu1 N2 1.3(2) . . . . ? N15 Cd1 Eu1 N2 -130.7(2) . . . . ? N14 Cd1 Eu1 N2 139.8(3) . . . . ? Eu2 Cd1 Eu1 N2 -60.6(4) . . . . ? N8 Cd1 Eu1 N1 -91.1(2) . . . . ? N16 Cd1 Eu1 N1 46.8(2) . . . . ? N7 Cd1 Eu1 N1 179.8(2) . . . . ? N5 Cd1 Eu1 N1 -0.2(2) . . . . ? N13 Cd1 Eu1 N1 136.6(2) . . . . ? N6 Cd1 Eu1 N1 91.5(2) . . . . ? N15 Cd1 Eu1 N1 -40.4(2) . . . . ? N14 Cd1 Eu1 N1 -130.0(3) . . . . ? Eu2 Cd1 Eu1 N1 29.6(4) . . . . ? N8 Cd1 Eu1 N5 -90.9(2) . . . . ? N16 Cd1 Eu1 N5 46.9(2) . . . . ? N7 Cd1 Eu1 N5 179.9(2) . . . . ? N13 Cd1 Eu1 N5 136.8(2) . . . . ? N6 Cd1 Eu1 N5 91.6(2) . . . . ? N15 Cd1 Eu1 N5 -40.3(2) . . . . ? N14 Cd1 Eu1 N5 -129.8(3) . . . . ? Eu2 Cd1 Eu1 N5 29.7(4) . . . . ? N8 Cd1 Eu1 N6 177.4(2) . . . . ? N16 Cd1 Eu1 N6 -44.7(2) . . . . ? N7 Cd1 Eu1 N6 88.3(2) . . . . ? N5 Cd1 Eu1 N6 -91.6(2) . . . . ? N13 Cd1 Eu1 N6 45.2(2) . . . . ? N15 Cd1 Eu1 N6 -131.9(2) . . . . ? N14 Cd1 Eu1 N6 138.6(3) . . . . ? Eu2 Cd1 Eu1 N6 -61.9(4) . . . . ? N16 Cd1 Eu1 N8 137.8(2) . . . . ? N7 Cd1 Eu1 N8 -89.1(2) . . . . ? N5 Cd1 Eu1 N8 90.9(2) . . . . ? N13 Cd1 Eu1 N8 -132.3(2) . . . . ? N6 Cd1 Eu1 N8 -177.4(2) . . . . ? N15 Cd1 Eu1 N8 50.6(2) . . . . ? N14 Cd1 Eu1 N8 -38.9(3) . . . . ? Eu2 Cd1 Eu1 N8 120.7(4) . . . . ? N8 Cd1 Eu1 N7 89.1(2) . . . . ? N16 Cd1 Eu1 N7 -133.0(2) . . . . ? N5 Cd1 Eu1 N7 -179.9(2) . . . . ? N13 Cd1 Eu1 N7 -43.1(2) . . . . ? N6 Cd1 Eu1 N7 -88.3(2) . . . . ? N15 Cd1 Eu1 N7 139.8(2) . . . . ? N14 Cd1 Eu1 N7 50.2(2) . . . . ? Eu2 Cd1 Eu1 N7 -150.2(4) . . . . ? N8 Cd1 Eu2 N23 5.8(3) . . . . ? N16 Cd1 Eu2 N23 -130.6(3) . . . . ? N7 Cd1 Eu2 N23 98.7(3) . . . . ? N5 Cd1 Eu2 N23 -84.2(2) . . . . ? N13 Cd1 Eu2 N23 137.5(2) . . . . ? N6 Cd1 Eu2 N23 -172.0(3) . . . . ? N15 Cd1 Eu2 N23 -39.7(2) . . . . ? N14 Cd1 Eu2 N23 48.1(3) . . . . ? Eu1 Cd1 Eu2 N23 -112.5(4) . . . . ? N8 Cd1 Eu2 N21 -175.8(2) . . . . ? N16 Cd1 Eu2 N21 47.9(2) . . . . ? N7 Cd1 Eu2 N21 -82.9(2) . . . . ? N5 Cd1 Eu2 N21 94.2(2) . . . . ? N13 Cd1 Eu2 N21 -44.0(2) . . . . ? N6 Cd1 Eu2 N21 6.4(2) . . . . ? N15 Cd1 Eu2 N21 138.7(2) . . . . ? N14 Cd1 Eu2 N21 -133.5(2) . . . . ? Eu1 Cd1 Eu2 N21 65.9(4) . . . . ? N8 Cd1 Eu2 N24 97.3(3) . . . . ? N16 Cd1 Eu2 N24 -39.0(2) . . . . ? N7 Cd1 Eu2 N24 -169.8(2) . . . . ? N5 Cd1 Eu2 N24 7.4(2) . . . . ? N13 Cd1 Eu2 N24 -130.9(2) . . . . ? N6 Cd1 Eu2 N24 -80.4(2) . . . . ? N15 Cd1 Eu2 N24 51.8(2) . . . . ? N14 Cd1 Eu2 N24 139.6(2) . . . . ? Eu1 Cd1 Eu2 N24 -21.0(4) . . . . ? N8 Cd1 Eu2 N22 -86.1(3) . . . . ? N16 Cd1 Eu2 N22 137.6(3) . . . . ? N7 Cd1 Eu2 N22 6.8(2) . . . . ? N5 Cd1 Eu2 N22 -176.0(2) . . . . ? N13 Cd1 Eu2 N22 45.7(2) . . . . ? N6 Cd1 Eu2 N22 96.1(2) . . . . ? N15 Cd1 Eu2 N22 -131.6(2) . . . . ? N14 Cd1 Eu2 N22 -43.8(2) . . . . ? Eu1 Cd1 Eu2 N22 155.6(4) . . . . ? N8 Cd1 Eu2 N14 -42.3(3) . . . . ? N16 Cd1 Eu2 N14 -178.6(2) . . . . ? N7 Cd1 Eu2 N14 50.6(2) . . . . ? N5 Cd1 Eu2 N14 -132.3(2) . . . . ? N13 Cd1 Eu2 N14 89.5(2) . . . . ? N6 Cd1 Eu2 N14 139.9(2) . . . . ? N15 Cd1 Eu2 N14 -87.8(2) . . . . ? Eu1 Cd1 Eu2 N14 -160.6(4) . . . . ? N8 Cd1 Eu2 N15 45.5(2) . . . . ? N16 Cd1 Eu2 N15 -90.8(2) . . . . ? N7 Cd1 Eu2 N15 138.4(2) . . . . ? N5 Cd1 Eu2 N15 -44.4(2) . . . . ? N13 Cd1 Eu2 N15 177.3(2) . . . . ? N6 Cd1 Eu2 N15 -132.3(2) . . . . ? N14 Cd1 Eu2 N15 87.8(2) . . . . ? Eu1 Cd1 Eu2 N15 -72.8(4) . . . . ? N8 Cd1 Eu2 N16 136.3(3) . . . . ? N7 Cd1 Eu2 N16 -130.8(2) . . . . ? N5 Cd1 Eu2 N16 46.4(2) . . . . ? N13 Cd1 Eu2 N16 -91.9(2) . . . . ? N6 Cd1 Eu2 N16 -41.4(2) . . . . ? N15 Cd1 Eu2 N16 90.8(2) . . . . ? N14 Cd1 Eu2 N16 178.6(2) . . . . ? Eu1 Cd1 Eu2 N16 18.0(4) . . . . ? N8 Cd1 Eu2 N13 -131.8(3) . . . . ? N16 Cd1 Eu2 N13 91.9(2) . . . . ? N7 Cd1 Eu2 N13 -38.9(2) . . . . ? N5 Cd1 Eu2 N13 138.3(2) . . . . ? N6 Cd1 Eu2 N13 50.5(2) . . . . ? N15 Cd1 Eu2 N13 -177.3(2) . . . . ? N14 Cd1 Eu2 N13 -89.5(2) . . . . ? Eu1 Cd1 Eu2 N13 109.9(4) . . . . ? N23 Eu2 N15 C93 33.5(5) . . . . ? N21 Eu2 N15 C93 155.8(5) . . . . ? N24 Eu2 N15 C93 106.3(5) . . . . ? N22 Eu2 N15 C93 -17.7(7) . . . . ? N14 Eu2 N15 C93 -56.3(5) . . . . ? N16 Eu2 N15 C93 -169.0(6) . . . . ? N13 Eu2 N15 C93 -112.9(5) . . . . ? Cd1 Eu2 N15 C93 -114.9(5) . . . . ? N23 Eu2 N15 C100 -99.1(5) . . . . ? N21 Eu2 N15 C100 23.2(7) . . . . ? N24 Eu2 N15 C100 -26.3(5) . . . . ? N22 Eu2 N15 C100 -150.2(4) . . . . ? N14 Eu2 N15 C100 171.1(5) . . . . ? N16 Eu2 N15 C100 58.5(5) . . . . ? N13 Eu2 N15 C100 114.6(5) . . . . ? Cd1 Eu2 N15 C100 112.5(5) . . . . ? N23 Eu2 N15 Cd1 148.42(19) . . . . ? N21 Eu2 N15 Cd1 -89.3(3) . . . . ? N24 Eu2 N15 Cd1 -138.82(18) . . . . ? N22 Eu2 N15 Cd1 97.2(3) . . . . ? N14 Eu2 N15 Cd1 58.59(17) . . . . ? N16 Eu2 N15 Cd1 -54.05(16) . . . . ? N13 Eu2 N15 Cd1 2.05(17) . . . . ? N8 Cd1 N15 C93 -27.2(5) . . . . ? N16 Cd1 N15 C93 176.1(5) . . . . ? N7 Cd1 N15 C93 16.4(7) . . . . ? N5 Cd1 N15 C93 -94.9(5) . . . . ? N13 Cd1 N15 C93 116.9(5) . . . . ? N6 Cd1 N15 C93 -139.1(5) . . . . ? N14 Cd1 N15 C93 61.1(5) . . . . ? Eu2 Cd1 N15 C93 119.1(5) . . . . ? Eu1 Cd1 N15 C93 -65.3(5) . . . . ? N8 Cd1 N15 C100 98.7(5) . . . . ? N16 Cd1 N15 C100 -58.0(4) . . . . ? N7 Cd1 N15 C100 142.3(5) . . . . ? N5 Cd1 N15 C100 31.0(5) . . . . ? N13 Cd1 N15 C100 -117.2(5) . . . . ? N6 Cd1 N15 C100 -13.2(6) . . . . ? N14 Cd1 N15 C100 -173.0(5) . . . . ? Eu2 Cd1 N15 C100 -115.0(5) . . . . ? Eu1 Cd1 N15 C100 60.6(5) . . . . ? N8 Cd1 N15 Eu2 -146.24(18) . . . . ? N16 Cd1 N15 Eu2 57.02(17) . . . . ? N7 Cd1 N15 Eu2 -102.7(3) . . . . ? N5 Cd1 N15 Eu2 146.03(17) . . . . ? N13 Cd1 N15 Eu2 -2.12(18) . . . . ? N6 Cd1 N15 Eu2 101.9(3) . . . . ? N14 Cd1 N15 Eu2 -57.91(17) . . . . ? Eu1 Cd1 N15 Eu2 175.67(3) . . . . ? N23 Eu2 N21 C109 106.9(6) . . . . ? N24 Eu2 N21 C109 46.1(5) . . . . ? N22 Eu2 N21 C109 168.3(6) . . . . ? N14 Eu2 N21 C109 -136.5(5) . . . . ? N15 Eu2 N21 C109 -7.4(7) . . . . ? N16 Eu2 N21 C109 -38.9(6) . . . . ? N13 Eu2 N21 C109 -103.0(6) . . . . ? Cd1 Eu2 N21 C109 -71.7(6) . . . . ? N23 Eu2 N21 C116 -109.6(5) . . . . ? N24 Eu2 N21 C116 -170.4(5) . . . . ? N22 Eu2 N21 C116 -48.1(5) . . . . ? N14 Eu2 N21 C116 7.0(7) . . . . ? N15 Eu2 N21 C116 136.2(5) . . . . ? N16 Eu2 N21 C116 104.7(5) . . . . ? N13 Eu2 N21 C116 40.5(5) . . . . ? Cd1 Eu2 N21 C116 71.8(5) . . . . ? C76 N9 C45 N5 -1.4(11) . . . . ? C76 N9 C45 C46 178.9(7) . . . . ? N7 C61 N11 C60 -2.6(11) . . . . ? C62 C61 N11 C60 178.7(7) . . . . ? N9 C45 C46 C47 -0.6(13) . . . . ? N5 C45 C46 C47 179.6(8) . . . . ? N9 C45 C46 C51 -179.7(7) . . . . ? N5 C45 C46 C51 0.6(8) . . . . ? C100 N15 C93 N19 -178.6(7) . . . . ? Eu2 N15 C93 N19 45.0(9) . . . . ? Cd1 N15 C93 N19 -49.3(9) . . . . ? C100 N15 C93 C94 -0.8(8) . . . . ? Eu2 N15 C93 C94 -137.2(5) . . . . ? Cd1 N15 C93 C94 128.5(5) . . . . ? N23 Eu2 N24 C140 -167.9(6) . . . . ? N21 Eu2 N24 C140 -45.5(5) . . . . ? N22 Eu2 N24 C140 -106.3(6) . . . . ? N14 Eu2 N24 C140 137.5(5) . . . . ? N15 Eu2 N24 C140 107.7(6) . . . . ? N16 Eu2 N24 C140 43.1(6) . . . . ? N13 Eu2 N24 C140 8.2(7) . . . . ? Cd1 Eu2 N24 C140 70.7(6) . . . . ? N23 Eu2 N24 C133 47.9(5) . . . . ? N21 Eu2 N24 C133 170.3(6) . . . . ? N22 Eu2 N24 C133 109.5(5) . . . . ? N14 Eu2 N24 C133 -6.7(8) . . . . ? N15 Eu2 N24 C133 -36.5(5) . . . . ? N16 Eu2 N24 C133 -101.1(6) . . . . ? N13 Eu2 N24 C133 -136.0(5) . . . . ? Cd1 Eu2 N24 C133 -73.5(6) . . . . ? N6 C53 N10 C52 -0.2(11) . . . . ? C54 C53 N10 C52 -177.6(7) . . . . ? N3 Eu1 N1 C6 -103.0(6) . . . . ? N4 Eu1 N1 C6 -40.0(5) . . . . ? N2 Eu1 N1 C6 -164.8(6) . . . . ? N5 Eu1 N1 C6 76.0(6) . . . . ? N6 Eu1 N1 C6 127.6(5) . . . . ? N8 Eu1 N1 C6 27.0(6) . . . . ? N7 Eu1 N1 C6 76.8(10) . . . . ? Cd1 Eu1 N1 C6 76.1(6) . . . . ? N3 Eu1 N1 C9 104.2(6) . . . . ? N4 Eu1 N1 C9 167.1(6) . . . . ? N2 Eu1 N1 C9 42.4(5) . . . . ? N5 Eu1 N1 C9 -76.8(6) . . . . ? N6 Eu1 N1 C9 -25.2(6) . . . . ? N8 Eu1 N1 C9 -125.8(5) . . . . ? N7 Eu1 N1 C9 -76.1(10) . . . . ? Cd1 Eu1 N1 C9 -76.7(6) . . . . ? N16 Cd1 N8 C76 8.0(7) . . . . ? N7 Cd1 N8 C76 170.0(6) . . . . ? N5 Cd1 N8 C76 54.9(5) . . . . ? N13 Cd1 N8 C76 -138.0(5) . . . . ? N6 Cd1 N8 C76 112.5(5) . . . . ? N15 Cd1 N8 C76 -32.8(5) . . . . ? N14 Cd1 N8 C76 -96.4(5) . . . . ? Eu2 Cd1 N8 C76 -65.6(5) . . . . ? Eu1 Cd1 N8 C76 110.5(5) . . . . ? N16 Cd1 N8 C69 141.0(5) . . . . ? N7 Cd1 N8 C69 -57.0(5) . . . . ? N5 Cd1 N8 C69 -172.1(6) . . . . ? N13 Cd1 N8 C69 -5.0(7) . . . . ? N6 Cd1 N8 C69 -114.4(5) . . . . ? N15 Cd1 N8 C69 100.2(5) . . . . ? N14 Cd1 N8 C69 36.6(5) . . . . ? Eu2 Cd1 N8 C69 67.4(5) . . . . ? Eu1 Cd1 N8 C69 -116.5(5) . . . . ? N16 Cd1 N8 Eu1 -102.5(3) . . . . ? N7 Cd1 N8 Eu1 59.50(17) . . . . ? N5 Cd1 N8 Eu1 -55.64(17) . . . . ? N13 Cd1 N8 Eu1 111.5(3) . . . . ? N6 Cd1 N8 Eu1 2.0(2) . . . . ? N15 Cd1 N8 Eu1 -143.31(17) . . . . ? N14 Cd1 N8 Eu1 153.09(17) . . . . ? Eu2 Cd1 N8 Eu1 -176.13(3) . . . . ? N3 Eu1 N8 C76 126.8(5) . . . . ? N4 Eu1 N8 C76 58.6(5) . . . . ? N2 Eu1 N8 C76 -124.6(9) . . . . ? N1 Eu1 N8 C76 -7.4(5) . . . . ? N5 Eu1 N8 C76 -64.3(5) . . . . ? N6 Eu1 N8 C76 -121.6(5) . . . . ? N7 Eu1 N8 C76 -175.5(5) . . . . ? Cd1 Eu1 N8 C76 -119.7(5) . . . . ? N3 Eu1 N8 C69 4.3(6) . . . . ? N4 Eu1 N8 C69 -63.9(5) . . . . ? N2 Eu1 N8 C69 112.8(9) . . . . ? N1 Eu1 N8 C69 -130.0(5) . . . . ? N5 Eu1 N8 C69 173.1(6) . . . . ? N6 Eu1 N8 C69 115.9(5) . . . . ? N7 Eu1 N8 C69 62.0(5) . . . . ? Cd1 Eu1 N8 C69 117.8(6) . . . . ? N3 Eu1 N8 Cd1 -113.49(19) . . . . ? N4 Eu1 N8 Cd1 178.3(2) . . . . ? N2 Eu1 N8 Cd1 -4.9(9) . . . . ? N1 Eu1 N8 Cd1 112.29(19) . . . . ? N5 Eu1 N8 Cd1 55.37(19) . . . . ? N6 Eu1 N8 Cd1 -1.86(18) . . . . ? N7 Eu1 N8 Cd1 -55.78(17) . . . . ? N11 C61 N7 C68 -179.7(7) . . . . ? C62 C61 N7 C68 -0.9(8) . . . . ? N11 C61 N7 Cd1 49.0(9) . . . . ? C62 C61 N7 Cd1 -132.1(5) . . . . ? N11 C61 N7 Eu1 -45.3(9) . . . . ? C62 C61 N7 Eu1 133.6(5) . . . . ? N8 Cd1 N7 C61 -174.3(5) . . . . ? N16 Cd1 N7 C61 -10.7(7) . . . . ? N5 Cd1 N7 C61 -115.0(5) . . . . ? N13 Cd1 N7 C61 33.9(5) . . . . ? N6 Cd1 N7 C61 -57.9(5) . . . . ? N15 Cd1 N7 C61 137.8(5) . . . . ? N14 Cd1 N7 C61 98.6(5) . . . . ? Eu2 Cd1 N7 C61 62.6(5) . . . . ? Eu1 Cd1 N7 C61 -115.1(5) . . . . ? N8 Cd1 N7 C68 58.3(5) . . . . ? N16 Cd1 N7 C68 -138.1(5) . . . . ? N5 Cd1 N7 C68 117.5(5) . . . . ? N13 Cd1 N7 C68 -93.5(5) . . . . ? N6 Cd1 N7 C68 174.7(6) . . . . ? N15 Cd1 N7 C68 10.4(7) . . . . ? N14 Cd1 N7 C68 -28.8(5) . . . . ? Eu2 Cd1 N7 C68 -64.8(5) . . . . ? Eu1 Cd1 N7 C68 117.5(5) . . . . ? N8 Cd1 N7 Eu1 -59.24(17) . . . . ? N16 Cd1 N7 Eu1 104.4(3) . . . . ? N5 Cd1 N7 Eu1 0.04(19) . . . . ? N13 Cd1 N7 Eu1 148.96(17) . . . . ? N6 Cd1 N7 Eu1 57.16(17) . . . . ? N15 Cd1 N7 Eu1 -107.1(3) . . . . ? N14 Cd1 N7 Eu1 -146.31(16) . . . . ? Eu2 Cd1 N7 Eu1 177.73(3) . . . . ? N3 Eu1 N7 C61 -63.8(5) . . . . ? N4 Eu1 N7 C61 -130.9(5) . . . . ? N2 Eu1 N7 C61 2.2(5) . . . . ? N1 Eu1 N7 C61 116.4(8) . . . . ? N5 Eu1 N7 C61 117.1(5) . . . . ? N6 Eu1 N7 C61 60.3(5) . . . . ? N8 Eu1 N7 C61 171.6(5) . . . . ? Cd1 Eu1 N7 C61 117.2(5) . . . . ? N3 Eu1 N7 C68 65.2(5) . . . . ? N4 Eu1 N7 C68 -1.9(5) . . . . ? N2 Eu1 N7 C68 131.2(5) . . . . ? N1 Eu1 N7 C68 -114.6(8) . . . . ? N5 Eu1 N7 C68 -113.9(5) . . . . ? N6 Eu1 N7 C68 -170.7(6) . . . . ? N8 Eu1 N7 C68 -59.5(5) . . . . ? Cd1 Eu1 N7 C68 -113.8(5) . . . . ? N3 Eu1 N7 Cd1 179.0(2) . . . . ? N4 Eu1 N7 Cd1 111.91(19) . . . . ? N2 Eu1 N7 Cd1 -114.97(18) . . . . ? N1 Eu1 N7 Cd1 -0.8(9) . . . . ? N5 Eu1 N7 Cd1 -0.04(17) . . . . ? N6 Eu1 N7 Cd1 -56.92(18) . . . . ? N8 Eu1 N7 Cd1 54.38(17) . . . . ? C61 N7 C68 N12 179.8(7) . . . . ? Cd1 N7 C68 N12 -47.2(9) . . . . ? Eu1 N7 C68 N12 46.6(9) . . . . ? C61 N7 C68 C67 0.3(8) . . . . ? Cd1 N7 C68 C67 133.3(5) . . . . ? Eu1 N7 C68 C67 -132.9(5) . . . . ? C15 C16 N3 C19 -174.7(7) . . . . ? C17 C16 N3 C19 2.1(8) . . . . ? C15 C16 N3 Eu1 31.7(10) . . . . ? C17 C16 N3 Eu1 -151.5(5) . . . . ? N4 Eu1 N3 C16 -166.0(6) . . . . ? N2 Eu1 N3 C16 -42.2(6) . . . . ? N1 Eu1 N3 C16 -103.6(6) . . . . ? N5 Eu1 N3 C16 80.6(10) . . . . ? N6 Eu1 N3 C16 26.7(6) . . . . ? N8 Eu1 N3 C16 125.3(6) . . . . ? N7 Eu1 N3 C16 76.5(6) . . . . ? Cd1 Eu1 N3 C16 77.3(6) . . . . ? N4 Eu1 N3 C19 44.2(5) . . . . ? N2 Eu1 N3 C19 168.1(6) . . . . ? N1 Eu1 N3 C19 106.6(5) . . . . ? N5 Eu1 N3 C19 -69.2(10) . . . . ? N6 Eu1 N3 C19 -123.1(5) . . . . ? N8 Eu1 N3 C19 -24.5(6) . . . . ? N7 Eu1 N3 C19 -73.3(5) . . . . ? Cd1 Eu1 N3 C19 -72.5(5) . . . . ? C93 N15 C100 N20 178.4(7) . . . . ? Eu2 N15 C100 N20 -43.4(9) . . . . ? Cd1 N15 C100 N20 48.0(9) . . . . ? C93 N15 C100 C99 -0.6(8) . . . . ? Eu2 N15 C100 C99 137.6(5) . . . . ? Cd1 N15 C100 C99 -131.0(5) . . . . ? C16 N3 C19 C20 171.0(7) . . . . ? Eu1 N3 C19 C20 -34.5(9) . . . . ? C16 N3 C19 C18 -2.5(8) . . . . ? Eu1 N3 C19 C18 152.0(5) . . . . ? N3 C16 C15 C14 4.1(12) . . . . ? C17 C16 C15 C14 -172.1(7) . . . . ? N3 C16 C15 C33 179.7(7) . . . . ? C17 C16 C15 C33 3.4(11) . . . . ? N4 C1 C20 C19 6.4(12) . . . . ? C2 C1 C20 C19 -167.5(7) . . . . ? N4 C1 C20 C39 -176.9(7) . . . . ? C2 C1 C20 C39 9.2(11) . . . . ? N3 C19 C20 C1 -2.4(12) . . . . ? C18 C19 C20 C1 170.1(7) . . . . ? N3 C19 C20 C39 -179.2(7) . . . . ? C18 C19 C20 C39 -6.6(10) . . . . ? C45 N9 C76 N8 -1.5(12) . . . . ? C45 N9 C76 C75 178.4(7) . . . . ? C69 N8 C76 N9 -179.7(7) . . . . ? Cd1 N8 C76 N9 -42.0(9) . . . . ? Eu1 N8 C76 N9 52.0(9) . . . . ? C69 N8 C76 C75 0.3(8) . . . . ? Cd1 N8 C76 C75 138.0(5) . . . . ? Eu1 N8 C76 C75 -127.9(5) . . . . ? N15 C100 N20 C101 -3.9(11) . . . . ? C99 C100 N20 C101 174.9(7) . . . . ? N16 C101 N20 C100 0.1(11) . . . . ? C102 C101 N20 C100 178.9(7) . . . . ? N9 C45 N5 C52 -179.6(7) . . . . ? C46 C45 N5 C52 0.2(8) . . . . ? N9 C45 N5 Cd1 45.1(9) . . . . ? C46 C45 N5 Cd1 -135.1(5) . . . . ? N9 C45 N5 Eu1 -52.0(9) . . . . ? C46 C45 N5 Eu1 127.8(5) . . . . ? N8 Cd1 N5 C45 -55.7(5) . . . . ? N16 Cd1 N5 C45 100.5(5) . . . . ? N7 Cd1 N5 C45 -115.3(5) . . . . ? N13 Cd1 N5 C45 138.7(5) . . . . ? N6 Cd1 N5 C45 -172.2(5) . . . . ? N15 Cd1 N5 C45 34.7(5) . . . . ? N14 Cd1 N5 C45 -2.6(6) . . . . ? Eu2 Cd1 N5 C45 66.9(5) . . . . ? Eu1 Cd1 N5 C45 -115.3(5) . . . . ? N8 Cd1 N5 C52 173.9(6) . . . . ? N16 Cd1 N5 C52 -29.9(5) . . . . ? N7 Cd1 N5 C52 114.3(5) . . . . ? N13 Cd1 N5 C52 8.3(7) . . . . ? N6 Cd1 N5 C52 57.4(5) . . . . ? N15 Cd1 N5 C52 -95.7(5) . . . . ? N14 Cd1 N5 C52 -133.0(5) . . . . ? Eu2 Cd1 N5 C52 -63.5(5) . . . . ? Eu1 Cd1 N5 C52 114.3(5) . . . . ? N8 Cd1 N5 Eu1 59.55(18) . . . . ? N16 Cd1 N5 Eu1 -144.16(18) . . . . ? N7 Cd1 N5 Eu1 0.0(2) . . . . ? N13 Cd1 N5 Eu1 -106.0(3) . . . . ? N6 Cd1 N5 Eu1 -56.91(17) . . . . ? N15 Cd1 N5 Eu1 149.99(17) . . . . ? N14 Cd1 N5 Eu1 112.7(3) . . . . ? Eu2 Cd1 N5 Eu1 -177.82(3) . . . . ? N3 Eu1 N5 C45 114.3(8) . . . . ? N4 Eu1 N5 C45 5.0(5) . . . . ? N2 Eu1 N5 C45 -127.1(5) . . . . ? N1 Eu1 N5 C45 -61.9(5) . . . . ? N6 Eu1 N5 C45 173.3(5) . . . . ? N8 Eu1 N5 C45 64.9(5) . . . . ? N7 Eu1 N5 C45 118.3(5) . . . . ? Cd1 Eu1 N5 C45 118.2(5) . . . . ? N3 Eu1 N5 C52 -121.9(8) . . . . ? N4 Eu1 N5 C52 128.7(5) . . . . ? N2 Eu1 N5 C52 -3.3(6) . . . . ? N1 Eu1 N5 C52 61.8(5) . . . . ? N6 Eu1 N5 C52 -62.9(5) . . . . ? N8 Eu1 N5 C52 -171.3(6) . . . . ? N7 Eu1 N5 C52 -118.0(5) . . . . ? Cd1 Eu1 N5 C52 -118.0(6) . . . . ? N3 Eu1 N5 Cd1 -3.9(9) . . . . ? N4 Eu1 N5 Cd1 -113.26(19) . . . . ? N2 Eu1 N5 Cd1 114.71(19) . . . . ? N1 Eu1 N5 Cd1 179.9(2) . . . . ? N6 Eu1 N5 Cd1 55.09(17) . . . . ? N8 Eu1 N5 Cd1 -53.31(17) . . . . ? N7 Eu1 N5 Cd1 0.04(17) . . . . ? N7 C68 N12 C69 1.5(12) . . . . ? C67 C68 N12 C69 -179.1(7) . . . . ? C5 C4 N4 C1 176.4(7) . . . . ? C3 C4 N4 C1 -1.2(8) . . . . ? C5 C4 N4 Eu1 -25.0(11) . . . . ? C3 C4 N4 Eu1 157.4(5) . . . . ? C20 C1 N4 C4 -173.3(7) . . . . ? C2 C1 N4 C4 1.4(8) . . . . ? C20 C1 N4 Eu1 27.3(10) . . . . ? C2 C1 N4 Eu1 -158.0(5) . . . . ? N3 Eu1 N4 C4 163.6(6) . . . . ? N2 Eu1 N4 C4 99.8(6) . . . . ? N1 Eu1 N4 C4 37.7(6) . . . . ? N5 Eu1 N4 C4 -29.9(6) . . . . ? N6 Eu1 N4 C4 -81.8(11) . . . . ? N8 Eu1 N4 C4 -81.0(6) . . . . ? N7 Eu1 N4 C4 -129.4(6) . . . . ? Cd1 Eu1 N4 C4 -79.6(6) . . . . ? N3 Eu1 N4 C1 -41.2(5) . . . . ? N2 Eu1 N4 C1 -104.9(5) . . . . ? N1 Eu1 N4 C1 -167.1(6) . . . . ? N5 Eu1 N4 C1 125.3(5) . . . . ? N6 Eu1 N4 C1 73.5(11) . . . . ? N8 Eu1 N4 C1 74.3(5) . . . . ? N7 Eu1 N4 C1 25.8(6) . . . . ? Cd1 Eu1 N4 C1 75.6(6) . . . . ? N3 Eu1 N2 C11 -167.2(6) . . . . ? N4 Eu1 N2 C11 -103.1(6) . . . . ? N1 Eu1 N2 C11 -40.7(6) . . . . ? N5 Eu1 N2 C11 25.4(6) . . . . ? N6 Eu1 N2 C11 77.3(6) . . . . ? N8 Eu1 N2 C11 80.5(11) . . . . ? N7 Eu1 N2 C11 126.6(6) . . . . ? Cd1 Eu1 N2 C11 76.4(6) . . . . ? N3 Eu1 N2 C14 39.4(5) . . . . ? N4 Eu1 N2 C14 103.5(6) . . . . ? N1 Eu1 N2 C14 165.9(6) . . . . ? N5 Eu1 N2 C14 -128.0(5) . . . . ? N6 Eu1 N2 C14 -76.1(6) . . . . ? N8 Eu1 N2 C14 -72.9(11) . . . . ? N7 Eu1 N2 C14 -26.8(6) . . . . ? Cd1 Eu1 N2 C14 -77.0(6) . . . . ? N17 C108 N16 C101 179.6(7) . . . . ? C107 C108 N16 C101 -1.3(8) . . . . ? N17 C108 N16 Cd1 44.3(9) . . . . ? C107 C108 N16 Cd1 -136.6(5) . . . . ? N17 C108 N16 Eu2 -50.7(9) . . . . ? C107 C108 N16 Eu2 128.4(5) . . . . ? N20 C101 N16 C108 179.9(7) . . . . ? C102 C101 N16 C108 1.0(8) . . . . ? N20 C101 N16 Cd1 -46.3(9) . . . . ? C102 C101 N16 Cd1 134.7(5) . . . . ? N20 C101 N16 Eu2 49.8(8) . . . . ? C102 C101 N16 Eu2 -129.2(5) . . . . ? N8 Cd1 N16 C108 142.4(5) . . . . ? N7 Cd1 N16 C108 -9.2(6) . . . . ? N5 Cd1 N16 C108 100.0(5) . . . . ? N13 Cd1 N16 C108 -58.9(5) . . . . ? N6 Cd1 N16 C108 33.1(5) . . . . ? N15 Cd1 N16 C108 -171.8(5) . . . . ? N14 Cd1 N16 C108 -116.4(5) . . . . ? Eu2 Cd1 N16 C108 -115.3(5) . . . . ? Eu1 Cd1 N16 C108 66.0(5) . . . . ? N8 Cd1 N16 C101 12.5(7) . . . . ? N7 Cd1 N16 C101 -139.1(5) . . . . ? N5 Cd1 N16 C101 -30.0(5) . . . . ? N13 Cd1 N16 C101 171.2(5) . . . . ? N6 Cd1 N16 C101 -96.8(5) . . . . ? N15 Cd1 N16 C101 58.3(5) . . . . ? N14 Cd1 N16 C101 113.7(5) . . . . ? Eu2 Cd1 N16 C101 114.8(5) . . . . ? Eu1 Cd1 N16 C101 -63.9(5) . . . . ? N8 Cd1 N16 Eu2 -102.2(3) . . . . ? N7 Cd1 N16 Eu2 106.1(3) . . . . ? N5 Cd1 N16 Eu2 -144.71(18) . . . . ? N13 Cd1 N16 Eu2 56.42(17) . . . . ? N6 Cd1 N16 Eu2 148.48(18) . . . . ? N15 Cd1 N16 Eu2 -56.45(17) . . . . ? N14 Cd1 N16 Eu2 -1.05(19) . . . . ? Eu1 Cd1 N16 Eu2 -178.65(3) . . . . ? N23 Eu2 N16 C108 -148.9(4) . . . . ? N21 Eu2 N16 C108 -25.5(5) . . . . ? N24 Eu2 N16 C108 -96.5(5) . . . . ? N22 Eu2 N16 C108 25.9(6) . . . . ? N14 Eu2 N16 C108 116.5(5) . . . . ? N15 Eu2 N16 C108 173.5(5) . . . . ? N13 Eu2 N16 C108 59.6(5) . . . . ? Cd1 Eu2 N16 C108 115.4(5) . . . . ? N23 Eu2 N16 C101 -23.0(6) . . . . ? N21 Eu2 N16 C101 100.4(5) . . . . ? N24 Eu2 N16 C101 29.3(5) . . . . ? N22 Eu2 N16 C101 151.8(4) . . . . ? N14 Eu2 N16 C101 -117.6(5) . . . . ? N15 Eu2 N16 C101 -60.7(4) . . . . ? N13 Eu2 N16 C101 -174.5(5) . . . . ? Cd1 Eu2 N16 C101 -118.7(5) . . . . ? N23 Eu2 N16 Cd1 95.7(3) . . . . ? N21 Eu2 N16 Cd1 -140.89(19) . . . . ? N24 Eu2 N16 Cd1 148.0(2) . . . . ? N22 Eu2 N16 Cd1 -89.5(3) . . . . ? N14 Eu2 N16 Cd1 1.06(19) . . . . ? N15 Eu2 N16 Cd1 58.05(17) . . . . ? N13 Eu2 N16 Cd1 -55.82(17) . . . . ? N14 C92 N19 C93 0.1(12) . . . . ? C91 C92 N19 C93 178.3(7) . . . . ? N15 C93 N19 C92 0.4(11) . . . . ? C94 C93 N19 C92 -177.2(7) . . . . ? C61 N11 C60 N6 -1.0(11) . . . . ? C61 N11 C60 C59 178.8(7) . . . . ? N21 Eu2 N23 C132 -104.8(5) . . . . ? N24 Eu2 N23 C132 -45.0(5) . . . . ? N22 Eu2 N23 C132 -166.4(6) . . . . ? N14 Eu2 N23 C132 108.7(5) . . . . ? N15 Eu2 N23 C132 44.3(5) . . . . ? N16 Eu2 N23 C132 10.6(7) . . . . ? N13 Eu2 N23 C132 139.5(5) . . . . ? Cd1 Eu2 N23 C132 73.7(6) . . . . ? N21 Eu2 N23 C125 101.5(6) . . . . ? N24 Eu2 N23 C125 161.3(6) . . . . ? N22 Eu2 N23 C125 39.9(5) . . . . ? N14 Eu2 N23 C125 -45.0(6) . . . . ? N15 Eu2 N23 C125 -109.5(6) . . . . ? N16 Eu2 N23 C125 -143.1(5) . . . . ? N13 Eu2 N23 C125 -14.2(8) . . . . ? Cd1 Eu2 N23 C125 -80.0(6) . . . . ? N23 Eu2 N22 C124 -39.0(6) . . . . ? N21 Eu2 N22 C124 -160.7(6) . . . . ? N24 Eu2 N22 C124 -100.8(6) . . . . ? N14 Eu2 N22 C124 49.9(6) . . . . ? N15 Eu2 N22 C124 15.5(7) . . . . ? N16 Eu2 N22 C124 144.4(5) . . . . ? N13 Eu2 N22 C124 114.5(6) . . . . ? Cd1 Eu2 N22 C124 82.3(6) . . . . ? N23 Eu2 N22 C117 164.1(6) . . . . ? N21 Eu2 N22 C117 42.4(5) . . . . ? N24 Eu2 N22 C117 102.3(5) . . . . ? N14 Eu2 N22 C117 -107.0(5) . . . . ? N15 Eu2 N22 C117 -141.5(5) . . . . ? N16 Eu2 N22 C117 -12.5(7) . . . . ? N13 Eu2 N22 C117 -42.4(5) . . . . ? Cd1 Eu2 N22 C117 -74.6(5) . . . . ? C68 N12 C69 N8 2.7(12) . . . . ? C68 N12 C69 C70 -176.2(7) . . . . ? C76 N8 C69 N12 -179.1(7) . . . . ? Cd1 N8 C69 N12 42.1(9) . . . . ? Eu1 N8 C69 N12 -54.0(9) . . . . ? C76 N8 C69 C70 -0.1(8) . . . . ? Cd1 N8 C69 C70 -138.9(5) . . . . ? Eu1 N8 C69 C70 125.0(5) . . . . ? N11 C60 N6 C53 -178.1(7) . . . . ? C59 C60 N6 C53 2.0(8) . . . . ? N11 C60 N6 Cd1 -41.6(9) . . . . ? C59 C60 N6 Cd1 138.6(5) . . . . ? N11 C60 N6 Eu1 55.3(8) . . . . ? C59 C60 N6 Eu1 -124.6(5) . . . . ? N10 C53 N6 C60 -179.6(7) . . . . ? C54 C53 N6 C60 -1.9(8) . . . . ? N10 C53 N6 Cd1 43.2(9) . . . . ? C54 C53 N6 Cd1 -139.1(5) . . . . ? N10 C53 N6 Eu1 -50.8(8) . . . . ? C54 C53 N6 Eu1 126.8(5) . . . . ? N8 Cd1 N6 C60 114.1(5) . . . . ? N16 Cd1 N6 C60 -98.1(5) . . . . ? N7 Cd1 N6 C60 55.4(5) . . . . ? N5 Cd1 N6 C60 172.5(5) . . . . ? N13 Cd1 N6 C60 -31.5(5) . . . . ? N15 Cd1 N6 C60 -138.3(5) . . . . ? N14 Cd1 N6 C60 4.6(7) . . . . ? Eu2 Cd1 N6 C60 -67.7(5) . . . . ? Eu1 Cd1 N6 C60 116.2(5) . . . . ? N8 Cd1 N6 C53 -114.0(5) . . . . ? N16 Cd1 N6 C53 33.7(5) . . . . ? N7 Cd1 N6 C53 -172.7(6) . . . . ? N5 Cd1 N6 C53 -55.6(5) . . . . ? N13 Cd1 N6 C53 100.4(5) . . . . ? N15 Cd1 N6 C53 -6.4(7) . . . . ? N14 Cd1 N6 C53 136.5(5) . . . . ? Eu2 Cd1 N6 C53 64.2(5) . . . . ? Eu1 Cd1 N6 C53 -111.9(5) . . . . ? N8 Cd1 N6 Eu1 -2.1(2) . . . . ? N16 Cd1 N6 Eu1 145.60(18) . . . . ? N7 Cd1 N6 Eu1 -60.81(18) . . . . ? N5 Cd1 N6 Eu1 56.23(17) . . . . ? N13 Cd1 N6 Eu1 -147.70(17) . . . . ? N15 Cd1 N6 Eu1 105.5(3) . . . . ? N14 Cd1 N6 Eu1 -111.6(3) . . . . ? Eu2 Cd1 N6 Eu1 176.08(3) . . . . ? N3 Eu1 N6 C60 -5.8(5) . . . . ? N4 Eu1 N6 C60 -116.6(9) . . . . ? N2 Eu1 N6 C60 62.0(5) . . . . ? N1 Eu1 N6 C60 128.0(5) . . . . ? N5 Eu1 N6 C60 -173.2(5) . . . . ? N8 Eu1 N6 C60 -117.3(5) . . . . ? N7 Eu1 N6 C60 -64.1(5) . . . . ? Cd1 Eu1 N6 C60 -119.1(5) . . . . ? N3 Eu1 N6 C53 -129.4(5) . . . . ? N4 Eu1 N6 C53 119.8(8) . . . . ? N2 Eu1 N6 C53 -61.7(5) . . . . ? N1 Eu1 N6 C53 4.3(5) . . . . ? N5 Eu1 N6 C53 63.2(5) . . . . ? N8 Eu1 N6 C53 119.0(5) . . . . ? N7 Eu1 N6 C53 172.3(5) . . . . ? Cd1 Eu1 N6 C53 117.2(5) . . . . ? N3 Eu1 N6 Cd1 113.36(18) . . . . ? N4 Eu1 N6 Cd1 2.6(9) . . . . ? N2 Eu1 N6 Cd1 -178.9(2) . . . . ? N1 Eu1 N6 Cd1 -112.91(19) . . . . ? N5 Eu1 N6 Cd1 -54.03(17) . . . . ? N8 Eu1 N6 Cd1 1.79(17) . . . . ? N7 Eu1 N6 Cd1 55.07(17) . . . . ? N12 C69 C70 C71 -0.8(13) . . . . ? N8 C69 C70 C71 -179.8(8) . . . . ? N12 C69 C70 C75 178.8(7) . . . . ? N8 C69 C70 C75 -0.2(8) . . . . ? C132 N27 C133 N24 -4.6(11) . . . . ? C132 N27 C133 C134 173.6(7) . . . . ? C140 N24 C133 N27 174.1(7) . . . . ? Eu2 N24 C133 N27 -36.4(9) . . . . ? C140 N24 C133 C134 -4.3(8) . . . . ? Eu2 N24 C133 C134 145.1(5) . . . . ? C85 N18 C84 N13 -2.2(11) . . . . ? C85 N18 C84 C83 178.5(7) . . . . ? C47 C46 C51 C50 0.1(11) . . . . ? C45 C46 C51 C50 179.3(7) . . . . ? C47 C46 C51 C52 179.8(7) . . . . ? C45 C46 C51 C52 -1.0(8) . . . . ? N4 C1 C2 C3 -1.0(9) . . . . ? C20 C1 C2 C3 173.8(7) . . . . ? C71 C70 C75 C74 -0.6(12) . . . . ? C69 C70 C75 C74 179.8(7) . . . . ? C71 C70 C75 C76 -180.0(7) . . . . ? C69 C70 C75 C76 0.4(8) . . . . ? N9 C76 C75 C70 179.6(7) . . . . ? N8 C76 C75 C70 -0.4(8) . . . . ? N9 C76 C75 C74 0.3(13) . . . . ? N8 C76 C75 C74 -179.7(8) . . . . ? N12 C68 C67 C62 -179.1(7) . . . . ? N7 C68 C67 C62 0.4(8) . . . . ? N12 C68 C67 C66 0.8(13) . . . . ? N7 C68 C67 C66 -179.7(8) . . . . ? N11 C60 C59 C58 -0.2(13) . . . . ? N6 C60 C59 C58 179.6(8) . . . . ? N11 C60 C59 C54 178.8(6) . . . . ? N6 C60 C59 C54 -1.4(8) . . . . ? C14 C15 C33 C34 85.5(9) . . . . ? C16 C15 C33 C34 -90.4(9) . . . . ? C14 C15 C33 C38 -91.7(9) . . . . ? C16 C15 C33 C38 92.4(9) . . . . ? C6 N1 C9 C10 170.4(7) . . . . ? Eu1 N1 C9 C10 -32.5(10) . . . . ? C6 N1 C9 C8 -3.5(8) . . . . ? Eu1 N1 C9 C8 153.6(5) . . . . ? C7 C8 C9 N1 1.9(9) . . . . ? C7 C8 C9 C10 -172.0(8) . . . . ? N17 C77 N13 C84 177.3(7) . . . . ? C78 C77 N13 C84 1.7(8) . . . . ? N17 C77 N13 Cd1 -50.0(9) . . . . ? C78 C77 N13 Cd1 134.4(5) . . . . ? N17 C77 N13 Eu2 43.4(9) . . . . ? C78 C77 N13 Eu2 -132.1(5) . . . . ? N18 C84 N13 C77 177.7(7) . . . . ? C83 C84 N13 C77 -2.9(8) . . . . ? N18 C84 N13 Cd1 47.7(9) . . . . ? C83 C84 N13 Cd1 -133.0(5) . . . . ? N18 C84 N13 Eu2 -47.2(9) . . . . ? C83 C84 N13 Eu2 132.2(5) . . . . ? N8 Cd1 N13 C77 -138.4(5) . . . . ? N16 Cd1 N13 C77 61.2(5) . . . . ? N7 Cd1 N13 C77 -91.3(5) . . . . ? N5 Cd1 N13 C77 19.0(7) . . . . ? N6 Cd1 N13 C77 -25.0(5) . . . . ? N15 Cd1 N13 C77 119.6(5) . . . . ? N14 Cd1 N13 C77 174.5(5) . . . . ? Eu2 Cd1 N13 C77 117.5(5) . . . . ? Eu1 Cd1 N13 C77 -58.1(5) . . . . ? N8 Cd1 N13 C84 -11.1(7) . . . . ? N16 Cd1 N13 C84 -171.5(5) . . . . ? N7 Cd1 N13 C84 36.0(5) . . . . ? N5 Cd1 N13 C84 146.3(5) . . . . ? N6 Cd1 N13 C84 102.3(5) . . . . ? N15 Cd1 N13 C84 -113.1(5) . . . . ? N14 Cd1 N13 C84 -58.2(5) . . . . ? Eu2 Cd1 N13 C84 -115.2(5) . . . . ? Eu1 Cd1 N13 C84 69.2(5) . . . . ? N8 Cd1 N13 Eu2 104.1(3) . . . . ? N16 Cd1 N13 Eu2 -56.33(17) . . . . ? N7 Cd1 N13 Eu2 151.16(18) . . . . ? N5 Cd1 N13 Eu2 -98.5(3) . . . . ? N6 Cd1 N13 Eu2 -142.52(17) . . . . ? N15 Cd1 N13 Eu2 2.10(18) . . . . ? N14 Cd1 N13 Eu2 56.96(17) . . . . ? Eu1 Cd1 N13 Eu2 -175.63(3) . . . . ? N23 Eu2 N13 C77 154.7(5) . . . . ? N21 Eu2 N13 C77 31.4(5) . . . . ? N24 Eu2 N13 C77 -18.5(7) . . . . ? N22 Eu2 N13 C77 104.1(5) . . . . ? N14 Eu2 N13 C77 -170.8(6) . . . . ? N15 Eu2 N13 C77 -114.3(5) . . . . ? N16 Eu2 N13 C77 -57.9(5) . . . . ? Cd1 Eu2 N13 C77 -112.2(5) . . . . ? N23 Eu2 N13 C84 24.6(7) . . . . ? N21 Eu2 N13 C84 -98.8(5) . . . . ? N24 Eu2 N13 C84 -148.7(5) . . . . ? N22 Eu2 N13 C84 -26.1(5) . . . . ? N14 Eu2 N13 C84 59.1(5) . . . . ? N15 Eu2 N13 C84 115.5(5) . . . . ? N16 Eu2 N13 C84 172.0(5) . . . . ? Cd1 Eu2 N13 C84 117.6(5) . . . . ? N23 Eu2 N13 Cd1 -93.1(3) . . . . ? N21 Eu2 N13 Cd1 143.58(19) . . . . ? N24 Eu2 N13 Cd1 93.7(3) . . . . ? N22 Eu2 N13 Cd1 -143.72(18) . . . . ? N14 Eu2 N13 Cd1 -58.60(18) . . . . ? N15 Eu2 N13 Cd1 -2.11(18) . . . . ? N16 Eu2 N13 Cd1 54.32(17) . . . . ? C116 N25 C117 N22 -8.6(11) . . . . ? C116 N25 C117 C118 167.5(7) . . . . ? C124 N22 C117 N25 173.1(7) . . . . ? Eu2 N22 C117 N25 -26.4(10) . . . . ? C124 N22 C117 C118 -3.4(8) . . . . ? Eu2 N22 C117 C118 157.1(5) . . . . ? N19 C92 N14 C85 177.8(7) . . . . ? C91 C92 N14 C85 -0.7(8) . . . . ? N19 C92 N14 Eu2 -45.0(10) . . . . ? C91 C92 N14 Eu2 136.5(5) . . . . ? N19 C92 N14 Cd1 47.4(9) . . . . ? C91 C92 N14 Cd1 -131.0(5) . . . . ? N23 Eu2 N14 C85 103.6(5) . . . . ? N21 Eu2 N14 C85 -20.7(7) . . . . ? N24 Eu2 N14 C85 154.7(5) . . . . ? N22 Eu2 N14 C85 31.2(5) . . . . ? N15 Eu2 N14 C85 -171.9(6) . . . . ? N16 Eu2 N14 C85 -114.8(5) . . . . ? N13 Eu2 N14 C85 -58.2(5) . . . . ? Cd1 Eu2 N14 C85 -113.8(5) . . . . ? N23 Eu2 N14 C92 -29.4(5) . . . . ? N21 Eu2 N14 C92 -153.7(5) . . . . ? N24 Eu2 N14 C92 21.7(7) . . . . ? N22 Eu2 N14 C92 -101.8(5) . . . . ? N15 Eu2 N14 C92 55.2(5) . . . . ? N16 Eu2 N14 C92 112.2(5) . . . . ? N13 Eu2 N14 C92 168.8(6) . . . . ? Cd1 Eu2 N14 C92 113.2(5) . . . . ? N23 Eu2 N14 Cd1 -142.63(19) . . . . ? N21 Eu2 N14 Cd1 93.1(3) . . . . ? N24 Eu2 N14 Cd1 -91.5(4) . . . . ? N22 Eu2 N14 Cd1 144.93(19) . . . . ? N15 Eu2 N14 Cd1 -58.08(17) . . . . ? N16 Eu2 N14 Cd1 -1.01(18) . . . . ? N13 Eu2 N14 Cd1 55.57(17) . . . . ? N8 Cd1 N14 C85 -95.4(5) . . . . ? N16 Cd1 N14 C85 117.3(5) . . . . ? N7 Cd1 N14 C85 -27.4(5) . . . . ? N5 Cd1 N14 C85 -143.3(5) . . . . ? N13 Cd1 N14 C85 58.5(5) . . . . ? N6 Cd1 N14 C85 18.0(7) . . . . ? N15 Cd1 N14 C85 174.3(6) . . . . ? Eu2 Cd1 N14 C85 116.2(5) . . . . ? Eu1 Cd1 N14 C85 -65.4(5) . . . . ? N8 Cd1 N14 C92 31.1(5) . . . . ? N16 Cd1 N14 C92 -116.2(5) . . . . ? N7 Cd1 N14 C92 99.1(5) . . . . ? N5 Cd1 N14 C92 -16.8(6) . . . . ? N13 Cd1 N14 C92 -175.0(5) . . . . ? N6 Cd1 N14 C92 144.5(5) . . . . ? N15 Cd1 N14 C92 -59.2(5) . . . . ? Eu2 Cd1 N14 C92 -117.3(5) . . . . ? Eu1 Cd1 N14 C92 61.1(5) . . . . ? N8 Cd1 N14 Eu2 148.32(19) . . . . ? N16 Cd1 N14 Eu2 1.06(19) . . . . ? N7 Cd1 N14 Eu2 -143.60(18) . . . . ? N5 Cd1 N14 Eu2 100.5(3) . . . . ? N13 Cd1 N14 Eu2 -57.74(18) . . . . ? N6 Cd1 N14 Eu2 -98.3(3) . . . . ? N15 Cd1 N14 Eu2 58.02(17) . . . . ? Eu1 Cd1 N14 Eu2 178.39(3) . . . . ? N3 C19 C18 C17 1.9(8) . . . . ? C20 C19 C18 C17 -171.7(7) . . . . ? C53 N10 C52 N5 2.0(12) . . . . ? C53 N10 C52 C51 179.7(7) . . . . ? C45 N5 C52 N10 177.1(7) . . . . ? Cd1 N5 C52 N10 -47.5(9) . . . . ? Eu1 N5 C52 N10 49.0(9) . . . . ? C45 N5 C52 C51 -0.8(8) . . . . ? Cd1 N5 C52 C51 134.5(5) . . . . ? Eu1 N5 C52 C51 -128.9(5) . . . . ? C50 C51 C52 N10 2.8(13) . . . . ? C46 C51 C52 N10 -176.9(7) . . . . ? C50 C51 C52 N5 -179.1(8) . . . . ? C46 C51 C52 N5 1.2(8) . . . . ? N20 C101 C102 C103 -2.0(13) . . . . ? N16 C101 C102 C103 177.0(7) . . . . ? N20 C101 C102 C107 -179.2(7) . . . . ? N16 C101 C102 C107 -0.2(8) . . . . ? C19 C18 C17 C16 -0.6(8) . . . . ? N3 C16 C17 C18 -1.0(9) . . . . ? C15 C16 C17 C18 175.8(7) . . . . ? C1 C20 C39 C44 -83.1(9) . . . . ? C19 C20 C39 C44 93.9(8) . . . . ? C1 C20 C39 C40 98.6(9) . . . . ? C19 C20 C39 C40 -84.4(9) . . . . ? C44 C39 C40 C41 0.1(12) . . . . ? C20 C39 C40 C41 178.3(7) . . . . ? C58 C59 C54 C55 -0.2(11) . . . . ? C60 C59 C54 C55 -179.4(7) . . . . ? C58 C59 C54 C53 179.3(7) . . . . ? C60 C59 C54 C53 0.2(8) . . . . ? N10 C53 C54 C55 -1.6(13) . . . . ? N6 C53 C54 C55 -179.4(8) . . . . ? N10 C53 C54 C59 178.9(7) . . . . ? N6 C53 C54 C59 1.1(8) . . . . ? N1 C9 C10 C11 -3.0(12) . . . . ? C8 C9 C10 C11 170.0(8) . . . . ? N1 C9 C10 C27 -178.6(7) . . . . ? C8 C9 C10 C27 -5.6(12) . . . . ? C54 C59 C58 C57 1.7(12) . . . . ? C60 C59 C58 C57 -179.4(8) . . . . ? C40 C39 C44 C43 1.4(12) . . . . ? C20 C39 C44 C43 -176.8(7) . . . . ? N20 C100 C99 C94 -177.2(7) . . . . ? N15 C100 C99 C94 1.8(8) . . . . ? N20 C100 C99 C98 1.5(13) . . . . ? N15 C100 C99 C98 -179.5(8) . . . . ? C84 N18 C85 N14 5.0(12) . . . . ? C84 N18 C85 C86 -175.3(7) . . . . ? C92 N14 C85 N18 -179.1(7) . . . . ? Eu2 N14 C85 N18 43.2(10) . . . . ? Cd1 N14 C85 N18 -49.0(9) . . . . ? C92 N14 C85 C86 1.2(8) . . . . ? Eu2 N14 C85 C86 -136.5(5) . . . . ? Cd1 N14 C85 C86 131.2(5) . . . . ? C59 C54 C55 C56 -1.7(12) . . . . ? C53 C54 C55 C56 178.9(8) . . . . ? C98 C99 C94 C95 -3.1(12) . . . . ? C100 C99 C94 C95 175.7(7) . . . . ? C98 C99 C94 C93 179.0(7) . . . . ? C100 C99 C94 C93 -2.2(8) . . . . ? C96 C95 C94 C99 1.6(11) . . . . ? C96 C95 C94 C93 179.0(7) . . . . ? N19 C93 C94 C99 179.9(7) . . . . ? N15 C93 C94 C99 2.0(8) . . . . ? N19 C93 C94 C95 2.3(12) . . . . ? N15 C93 C94 C95 -175.6(8) . . . . ? C14 C13 C12 C11 -0.9(9) . . . . ? C103 C102 C107 C106 -0.9(11) . . . . ? C101 C102 C107 C106 176.7(7) . . . . ? C103 C102 C107 C108 -178.1(7) . . . . ? C101 C102 C107 C108 -0.6(8) . . . . ? N17 C108 C107 C106 3.5(13) . . . . ? N16 C108 C107 C106 -175.6(8) . . . . ? N17 C108 C107 C102 -179.7(7) . . . . ? N16 C108 C107 C102 1.2(8) . . . . ? C9 N1 C6 C5 -172.6(8) . . . . ? Eu1 N1 C6 C5 30.4(10) . . . . ? C9 N1 C6 C7 3.7(8) . . . . ? Eu1 N1 C6 C7 -153.3(5) . . . . ? C1 C2 C3 C4 0.3(9) . . . . ? N4 C4 C3 C2 0.6(9) . . . . ? C5 C4 C3 C2 -177.1(7) . . . . ? N18 C84 C83 C82 1.2(13) . . . . ? N13 C84 C83 C82 -178.2(8) . . . . ? N18 C84 C83 C78 -177.6(7) . . . . ? N13 C84 C83 C78 3.1(8) . . . . ? N1 C6 C5 C4 4.1(13) . . . . ? C7 C6 C5 C4 -171.6(8) . . . . ? N1 C6 C5 C21 177.8(7) . . . . ? C7 C6 C5 C21 2.1(12) . . . . ? N4 C4 C5 C6 -7.4(13) . . . . ? C3 C4 C5 C6 170.0(8) . . . . ? N4 C4 C5 C21 179.0(7) . . . . ? C3 C4 C5 C21 -3.6(12) . . . . ? C82 C83 C78 C79 -1.7(12) . . . . ? C84 C83 C78 C79 177.2(7) . . . . ? C82 C83 C78 C77 179.1(7) . . . . ? C84 C83 C78 C77 -2.0(8) . . . . ? N17 C77 C78 C83 -175.6(7) . . . . ? N13 C77 C78 C83 0.3(8) . . . . ? N17 C77 C78 C79 5.4(13) . . . . ? N13 C77 C78 C79 -178.7(8) . . . . ? N16 C108 N17 C77 2.0(11) . . . . ? C107 C108 N17 C77 -177.0(7) . . . . ? N13 C77 N17 C108 2.5(12) . . . . ? C78 C77 N17 C108 177.5(7) . . . . ? N18 C85 C86 C91 179.0(7) . . . . ? N14 C85 C86 C91 -1.2(9) . . . . ? N18 C85 C86 C87 2.3(14) . . . . ? N14 C85 C86 C87 -177.9(9) . . . . ? C107 C102 C103 C104 0.9(11) . . . . ? C101 C102 C103 C104 -175.9(8) . . . . ? C140 N28 C109 N21 -3.3(12) . . . . ? C140 N28 C109 C110 179.2(7) . . . . ? C116 N21 C109 N28 176.8(7) . . . . ? Eu2 N21 C109 N28 -35.5(10) . . . . ? C116 N21 C109 C110 -5.5(8) . . . . ? Eu2 N21 C109 C110 142.2(5) . . . . ? C39 C44 C43 C42 -1.7(12) . . . . ? C14 N2 C11 C10 -174.3(7) . . . . ? Eu1 N2 C11 C10 28.3(10) . . . . ? C14 N2 C11 C12 2.8(8) . . . . ? Eu1 N2 C11 C12 -154.7(5) . . . . ? C9 C10 C11 N2 5.7(12) . . . . ? C27 C10 C11 N2 -178.7(7) . . . . ? C9 C10 C11 C12 -171.0(7) . . . . ? C27 C10 C11 C12 4.7(11) . . . . ? C13 C12 C11 N2 -1.2(9) . . . . ? C13 C12 C11 C10 175.9(7) . . . . ? N27 C133 C134 C139 -175.2(7) . . . . ? N24 C133 C134 C139 3.3(8) . . . . ? N27 C133 C134 C135 7.7(13) . . . . ? N24 C133 C134 C135 -173.8(8) . . . . ? C135 C134 C139 C138 1.0(11) . . . . ? C133 C134 C139 C138 -176.5(7) . . . . ? C135 C134 C139 C140 176.5(7) . . . . ? C133 C134 C139 C140 -0.9(8) . . . . ? C64 C63 C62 C67 -1.5(11) . . . . ? C64 C63 C62 C61 -177.0(8) . . . . ? C66 C67 C62 C63 2.7(11) . . . . ? C68 C67 C62 C63 -177.4(7) . . . . ? C66 C67 C62 C61 179.2(7) . . . . ? C68 C67 C62 C61 -0.9(8) . . . . ? N11 C61 C62 C63 -4.0(13) . . . . ? N7 C61 C62 C63 177.1(8) . . . . ? N11 C61 C62 C67 -180.0(7) . . . . ? N7 C61 C62 C67 1.1(8) . . . . ? C102 C103 C104 C105 0.5(12) . . . . ? C6 C5 C21 C26 96.3(10) . . . . ? C4 C5 C21 C26 -89.7(10) . . . . ? C6 C5 C21 C22 -81.0(11) . . . . ? C4 C5 C21 C22 93.0(11) . . . . ? C78 C83 C82 C81 0.7(12) . . . . ? C84 C83 C82 C81 -177.9(8) . . . . ? C117 N25 C116 N21 0.9(11) . . . . ? C117 N25 C116 C115 -176.4(7) . . . . ? C109 N21 C116 N25 -171.6(7) . . . . ? Eu2 N21 C116 N25 40.1(9) . . . . ? C109 N21 C116 C115 6.0(8) . . . . ? Eu2 N21 C116 C115 -142.4(5) . . . . ? C114 C115 C116 N25 -10.0(13) . . . . ? C110 C115 C116 N25 173.7(6) . . . . ? C114 C115 C116 N21 172.3(8) . . . . ? C110 C115 C116 N21 -4.0(8) . . . . ? C9 C8 C7 C6 0.4(9) . . . . ? N1 C6 C7 C8 -2.6(9) . . . . ? C5 C6 C7 C8 173.7(8) . . . . ? C94 C99 C98 C97 3.0(12) . . . . ? C100 C99 C98 C97 -175.6(8) . . . . ? C133 N27 C132 N23 8.6(12) . . . . ? C133 N27 C132 C131 -167.6(7) . . . . ? C125 N23 C132 N27 -172.7(7) . . . . ? Eu2 N23 C132 N27 29.8(10) . . . . ? C125 N23 C132 C131 4.0(8) . . . . ? Eu2 N23 C132 C131 -153.6(5) . . . . ? C114 C115 C110 C111 0.2(11) . . . . ? C116 C115 C110 C111 177.1(7) . . . . ? C114 C115 C110 C109 -176.4(7) . . . . ? C116 C115 C110 C109 0.5(8) . . . . ? N28 C109 C110 C111 4.8(13) . . . . ? N21 C109 C110 C111 -173.0(8) . . . . ? N28 C109 C110 C115 -179.1(7) . . . . ? N21 C109 C110 C115 3.1(8) . . . . ? C83 C78 C79 C80 0.9(12) . . . . ? C77 C78 C79 C80 179.7(8) . . . . ? C109 N28 C140 N24 4.9(12) . . . . ? C109 N28 C140 C139 -177.7(7) . . . . ? C133 N24 C140 N28 -178.7(7) . . . . ? Eu2 N24 C140 N28 33.0(10) . . . . ? C133 N24 C140 C139 3.6(8) . . . . ? Eu2 N24 C140 C139 -144.7(5) . . . . ? C138 C139 C140 N28 -4.6(13) . . . . ? C134 C139 C140 N28 -179.4(7) . . . . ? C138 C139 C140 N24 173.2(8) . . . . ? C134 C139 C140 N24 -1.6(8) . . . . ? C122 C123 C118 C119 -1.4(12) . . . . ? C124 C123 C118 C119 -176.1(7) . . . . ? C122 C123 C118 C117 174.8(7) . . . . ? C124 C123 C118 C117 0.0(8) . . . . ? N25 C117 C118 C119 1.0(13) . . . . ? N22 C117 C118 C119 177.7(8) . . . . ? N25 C117 C118 C123 -174.7(7) . . . . ? N22 C117 C118 C123 2.1(8) . . . . ? C62 C67 C66 C65 -2.7(12) . . . . ? C68 C67 C66 C65 177.4(8) . . . . ? C38 C33 C34 C35 2.1(12) . . . . ? C15 C33 C34 C35 -175.1(7) . . . . ? C124 N26 C125 N23 -5.3(12) . . . . ? C124 N26 C125 C126 169.6(7) . . . . ? C132 N23 C125 N26 173.4(7) . . . . ? Eu2 N23 C125 N26 -29.9(10) . . . . ? C132 N23 C125 C126 -2.1(8) . . . . ? Eu2 N23 C125 C126 154.6(5) . . . . ? C131 C126 C125 N26 -176.4(7) . . . . ? C127 C126 C125 N26 2.2(14) . . . . ? C131 C126 C125 N23 -0.6(8) . . . . ? C127 C126 C125 N23 177.9(9) . . . . ? C103 C104 C105 C106 -2.1(13) . . . . ? C62 C63 C64 C65 0.5(12) . . . . ? C71 C72 C73 C74 -1.3(14) . . . . ? C11 N2 C14 C15 175.2(7) . . . . ? Eu1 N2 C14 C15 -26.9(10) . . . . ? C11 N2 C14 C13 -3.3(8) . . . . ? Eu1 N2 C14 C13 154.6(5) . . . . ? C16 C15 C14 N2 -6.5(12) . . . . ? C33 C15 C14 N2 178.0(7) . . . . ? C16 C15 C14 C13 171.8(7) . . . . ? C33 C15 C14 C13 -3.7(11) . . . . ? C12 C13 C14 N2 2.7(9) . . . . ? C12 C13 C14 C15 -175.8(7) . . . . ? C94 C95 C96 C97 -0.3(12) . . . . ? C11 C10 C27 C28 -85.4(11) . . . . ? C9 C10 C27 C28 90.6(10) . . . . ? C11 C10 C27 C32 91.4(9) . . . . ? C9 C10 C27 C32 -92.6(10) . . . . ? C34 C33 C38 C37 -1.7(12) . . . . ? C15 C33 C38 C37 175.5(7) . . . . ? C36 C37 C38 C33 -0.5(12) . . . . ? C127 C126 C131 C130 2.1(13) . . . . ? C125 C126 C131 C130 -179.1(8) . . . . ? C127 C126 C131 C132 -175.8(8) . . . . ? C125 C126 C131 C132 3.0(8) . . . . ? N27 C132 C131 C126 172.5(7) . . . . ? N23 C132 C131 C126 -4.4(9) . . . . ? N27 C132 C131 C130 -5.1(14) . . . . ? N23 C132 C131 C130 178.0(9) . . . . ? C54 C55 C56 C57 2.2(13) . . . . ? C104 C105 C106 C107 2.1(12) . . . . ? C102 C107 C106 C105 -0.7(11) . . . . ? C108 C107 C106 C105 175.8(8) . . . . ? C72 C73 C74 C75 0.9(13) . . . . ? C70 C75 C74 C73 0.0(12) . . . . ? C76 C75 C74 C73 179.2(8) . . . . ? C59 C58 C57 C56 -1.2(13) . . . . ? C55 C56 C57 C58 -0.7(14) . . . . ? C87 C86 C91 C90 -1.5(13) . . . . ? C85 C86 C91 C90 -178.7(8) . . . . ? C87 C86 C91 C92 177.9(8) . . . . ? C85 C86 C91 C92 0.8(9) . . . . ? N19 C92 C91 C86 -178.6(7) . . . . ? N14 C92 C91 C86 -0.1(9) . . . . ? N19 C92 C91 C90 0.7(14) . . . . ? N14 C92 C91 C90 179.3(9) . . . . ? C123 C118 C119 C120 0.5(13) . . . . ? C117 C118 C119 C120 -174.5(9) . . . . ? C134 C139 C138 C137 0.5(11) . . . . ? C140 C139 C138 C137 -173.8(8) . . . . ? C125 N26 C124 N22 6.8(12) . . . . ? C125 N26 C124 C123 -169.4(7) . . . . ? C117 N22 C124 N26 -173.2(7) . . . . ? Eu2 N22 C124 N26 27.0(10) . . . . ? C117 N22 C124 C123 3.5(8) . . . . ? Eu2 N22 C124 C123 -156.3(5) . . . . ? C118 C123 C124 N26 174.7(7) . . . . ? C122 C123 C124 N26 0.8(13) . . . . ? C118 C123 C124 N22 -2.2(8) . . . . ? C122 C123 C124 N22 -176.1(8) . . . . ? C39 C40 C41 C42 -1.3(12) . . . . ? C115 C110 C111 C112 -0.2(11) . . . . ? C109 C110 C111 C112 175.4(8) . . . . ? C40 C41 C42 C43 1.1(13) . . . . ? C40 C41 C42 Cl4 -178.7(6) . . . . ? C44 C43 C42 C41 0.4(12) . . . . ? C44 C43 C42 Cl4 -179.8(6) . . . . ? C137 C136 C135 C134 0.1(12) . . . . ? C139 C134 C135 C136 -1.3(11) . . . . ? C133 C134 C135 C136 175.4(8) . . . . ? C33 C34 C35 C36 -0.4(13) . . . . ? C50 C49 C48 C47 -0.5(14) . . . . ? C49 C48 C47 C46 -0.2(13) . . . . ? C51 C46 C47 C48 0.3(11) . . . . ? C45 C46 C47 C48 -178.6(8) . . . . ? C22 C21 C26 C25 0.2(14) . . . . ? C5 C21 C26 C25 -177.2(8) . . . . ? C83 C82 C81 C80 1.1(13) . . . . ? C110 C111 C112 C113 -1.1(12) . . . . ? C48 C49 C50 C51 0.9(13) . . . . ? C46 C51 C50 C49 -0.7(12) . . . . ? C52 C51 C50 C49 179.7(8) . . . . ? C139 C138 C137 C136 -1.6(11) . . . . ? C135 C136 C137 C138 1.3(12) . . . . ? C110 C115 C114 C113 1.1(11) . . . . ? C116 C115 C114 C113 -174.8(8) . . . . ? C115 C114 C113 C112 -2.4(12) . . . . ? C111 C112 C113 C114 2.5(13) . . . . ? C118 C123 C122 C121 1.3(13) . . . . ? C124 C123 C122 C121 174.4(9) . . . . ? C95 C96 C97 C98 0.3(13) . . . . ? C99 C98 C97 C96 -1.6(12) . . . . ? C73 C72 C71 C70 0.7(13) . . . . ? C75 C70 C71 C72 0.2(12) . . . . ? C69 C70 C71 C72 179.8(8) . . . . ? C86 C91 C90 C89 0.0(15) . . . . ? C92 C91 C90 C89 -179.3(10) . . . . ? C67 C66 C65 C64 1.7(13) . . . . ? C63 C64 C65 C66 -0.7(14) . . . . ? C28 C27 C32 C31 2.1(13) . . . . ? C10 C27 C32 C31 -174.8(8) . . . . ? C34 C35 C36 C37 -1.9(14) . . . . ? C34 C35 C36 Cl3 -178.8(7) . . . . ? C38 C37 C36 C35 2.4(13) . . . . ? C38 C37 C36 Cl3 179.2(6) . . . . ? C78 C79 C80 C81 1.0(13) . . . . ? C82 C81 C80 C79 -2.0(14) . . . . ? C32 C27 C28 C29 -2.1(15) . . . . ? C10 C27 C28 C29 174.7(10) . . . . ? C131 C126 C127 C128 -1.3(13) . . . . ? C125 C126 C127 C128 -179.6(9) . . . . ? C123 C122 C121 C120 -0.4(15) . . . . ? C27 C32 C31 C30 -1.4(14) . . . . ? C126 C131 C130 C129 -2.1(13) . . . . ? C132 C131 C130 C129 175.3(9) . . . . ? C32 C31 C30 C29 0.7(16) . . . . ? C32 C31 C30 Cl2 178.3(7) . . . . ? C91 C86 C87 C88 1.2(15) . . . . ? C85 C86 C87 C88 177.5(10) . . . . ? C131 C130 C129 C128 1.2(16) . . . . ? C130 C129 C128 C127 -0.5(18) . . . . ? C126 C127 C128 C129 0.5(16) . . . . ? C91 C90 C89 C88 2(2) . . . . ? C118 C119 C120 C121 0.3(14) . . . . ? C122 C121 C120 C119 -0.4(16) . . . . ? C86 C87 C88 C89 1(2) . . . . ? C90 C89 C88 C87 -2(2) . . . . ? C31 C30 C29 C28 -0.8(18) . . . . ? Cl2 C30 C29 C28 -178.3(9) . . . . ? C27 C28 C29 C30 1.5(18) . . . . ? C24 C23 C22 C21 -1(2) . . . . ? C26 C21 C22 C23 0.2(17) . . . . ? C5 C21 C22 C23 177.5(11) . . . . ? C21 C26 C25 C24 -0.1(15) . . . . ? C22 C23 C24 C25 1(2) . . . . ? C22 C23 C24 Cl1 -179.4(11) . . . . ? C26 C25 C24 C23 -0.4(19) . . . . ? C26 C25 C24 Cl1 179.8(8) . . . . ? _diffrn_measured_fraction_theta_max 0.980 _diffrn_reflns_theta_full 61.00 _diffrn_measured_fraction_theta_full 0.980 _refine_diff_density_max 2.063 _refine_diff_density_min -1.481 _refine_diff_density_rms 0.134