# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               Chem.Commun.

_journal_coden_Cambridge         0182
_journal_volume                  ?
_journal_page_first              ?
_journal_year                    ?

_publ_contact_author_name        'Dr Jian Zhou'
_publ_contact_author_email       jianzhou888888@yahoo.com.cn

_publ_section_title              
;
One unprecedented 1-D europium thioindate-thioantimonate
based on heterometallic mixed nitro-thioclusters with luminescent properties

;
loop_
_publ_author_name
Author
Names:
J.Zhou

# Attachment '- 1.CIF'

data_x
_database_code_depnum_ccdc_archive 'CCDC 844289'
#TrackingRef '- 1.CIF'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'4(C8 H23 Eu In4 N5 S9),4(C16 H48 Eu2 N10 O S3 Sb),C8 H23 N5'
_chemical_formula_sum            'C104 H307 Eu12 In16 N65 O4 S48 Sb4'
_chemical_formula_weight         8219.53

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P21/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   15.167(3)
_cell_length_b                   28.929(6)
_cell_length_c                   15.709(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 111.35(3)
_cell_angle_gamma                90.00
_cell_volume                     6420(2)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      1.41
_cell_measurement_theta_max      25.60

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.124
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3922
_exptl_absorpt_coefficient_mu    5.135
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5549
_exptl_absorpt_correction_T_max  0.6841
_exptl_absorpt_process_details   'Jacobson, R. (1998) Private communication'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       \w
_diffrn_detector_area_resol_mean 7.31
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            39589
_diffrn_reflns_av_R_equivalents  0.11
_diffrn_reflns_av_sigmaI/netI    0.4818
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.41
_diffrn_reflns_theta_max         25.60
_reflns_number_total             11700
_reflns_number_gt                3621
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11700
_refine_ls_number_parameters     604
_refine_ls_number_restraints     1307
_refine_ls_R_factor_all          0.1464
_refine_ls_R_factor_gt           0.0843
_refine_ls_wR_factor_ref         0.1718
_refine_ls_wR_factor_gt          0.1641
_refine_ls_goodness_of_fit_ref   0.830
_refine_ls_restrained_S_all      0.807
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.05155(12) 0.03058(6) 0.10901(12) 0.0510(6) Uani 1 1 d . . .
Eu1 Eu 0.69639(8) 0.16631(5) 0.81986(10) 0.0510(4) Uani 1 1 d . . .
Eu2 Eu 0.23490(8) 0.09822(4) 0.28797(9) 0.0388(4) Uani 1 1 d . . .
Eu3 Eu 0.23080(8) 0.10098(4) 0.03312(9) 0.0386(4) Uani 1 1 d . . .
In1 In 0.26524(10) 0.20048(6) 0.67890(12) 0.0379(5) Uani 1 1 d . . .
In2 In 0.44841(11) 0.10783(6) 0.75224(12) 0.0405(5) Uani 1 1 d . . .
In3 In 0.49443(11) 0.22592(6) 0.87624(12) 0.0367(5) Uani 1 1 d . . .
In4 In 0.48721(10) 0.21642(6) 0.61900(12) 0.0355(5) Uani 1 1 d . . .
S1 S 0.0920(4) 0.2179(3) 0.6166(5) 0.061(2) Uani 1 1 d . . .
S2 S 0.2811(4) 0.1183(2) 0.7191(5) 0.049(2) Uani 1 1 d . . .
S3 S 0.3164(4) 0.2254(2) 0.5513(5) 0.0458(19) Uani 1 1 d . . .
S4 S 0.3267(4) 0.2440(2) 0.8212(4) 0.048(2) Uani 1 1 d . . .
S5 S 0.4792(6) 0.0225(3) 0.7669(6) 0.096(3) Uani 1 1 d . . .
S6 S 0.5199(4) 0.1320(2) 0.6423(4) 0.0449(19) Uani 1 1 d . . .
S7 S 0.5434(4) 0.1435(2) 0.8981(4) 0.0430(19) Uani 1 1 d . . .
S8 S 0.5785(4) 0.2594(2) 1.0253(5) 0.049(2) Uani 1 1 d . . .
S9 S 0.5672(4) 0.2542(2) 0.7669(5) 0.0461(19) Uani 1 1 d . . .
S10 S 0.0519(5) 0.0576(3) 0.2508(5) 0.066(2) Uani 1 1 d . . .
S11 S 0.2222(4) 0.0252(2) 0.1552(5) 0.0472(19) Uani 1 1 d . . .
S12 S 0.0398(5) 0.1002(2) 0.0205(5) 0.063(2) Uani 1 1 d . . .
O1 O 0.2874(9) 0.1308(5) 0.1786(10) 0.051(5) Uani 1 1 d . . .
N1 N 0.1303(12) 0.1668(6) 0.2374(12) 0.062(4) Uani 1 1 d DU . .
H1C H 0.1574 0.1848 0.2070 0.075 Uiso 1 1 calc R . .
H1D H 0.0761 0.1563 0.1953 0.075 Uiso 1 1 calc R . .
N2 N 0.1722(13) 0.1360(6) 0.4090(13) 0.065(4) Uani 1 1 d DU . .
H2C H 0.2180 0.1557 0.4437 0.078 Uiso 1 1 calc R . .
N3 N 0.2576(13) 0.0464(7) 0.4282(13) 0.072(4) Uani 1 1 d DU . .
H3C H 0.2109 0.0248 0.4105 0.087 Uiso 1 1 calc R . .
N4 N 0.3968(12) 0.0551(6) 0.3462(13) 0.054(4) Uani 1 1 d DU . .
H4C H 0.4112 0.0487 0.2960 0.065 Uiso 1 1 calc R . .
N5 N 0.3758(11) 0.1448(6) 0.3913(13) 0.055(4) Uani 1 1 d DU . .
H5C H 0.3657 0.1749 0.3772 0.066 Uiso 1 1 calc R . .
H5D H 0.3809 0.1411 0.4497 0.066 Uiso 1 1 calc R . .
N6 N 0.1597(12) 0.1821(6) -0.0104(13) 0.062(4) Uani 1 1 d DU . .
H6C H 0.1087 0.1848 0.0056 0.074 Uiso 1 1 calc R . .
H6D H 0.2025 0.2033 0.0215 0.074 Uiso 1 1 calc R . .
N7 N 0.1526(13) 0.1148(7) -0.1364(14) 0.067(4) Uani 1 1 d DU . .
H7C H 0.2019 0.1206 -0.1548 0.081 Uiso 1 1 calc R . .
N8 N 0.2113(13) 0.0275(7) -0.0701(13) 0.073(4) Uani 1 1 d DU . .
H8C H 0.1653 0.0111 -0.0591 0.088 Uiso 1 1 calc R . .
N9 N 0.3899(11) 0.0592(6) 0.0639(13) 0.059(4) Uani 1 1 d DU . .
H9C H 0.4048 0.0432 0.1171 0.071 Uiso 1 1 calc R . .
N10 N 0.3632(12) 0.1481(7) 0.0151(14) 0.068(4) Uani 1 1 d DU . .
H10C H 0.3665 0.1431 -0.0402 0.082 Uiso 1 1 calc R . .
H10D H 0.3531 0.1785 0.0204 0.082 Uiso 1 1 calc R . .
N11 N 0.7978(18) 0.1114(9) 0.9617(17) 0.120(6) Uani 1 1 d DU . .
H11C H 0.7691 0.0837 0.9563 0.144 Uiso 1 1 calc R . .
H11D H 0.8559 0.1068 0.9602 0.144 Uiso 1 1 calc R . .
N12 N 0.7791(17) 0.2035(9) 0.9904(17) 0.109(5) Uani 1 1 d DU . .
H12C H 0.7291 0.2084 1.0083 0.130 Uiso 1 1 calc R . .
N13 N 0.8061(16) 0.2411(8) 0.8272(15) 0.102(5) Uani 1 1 d DU . .
H13C H 0.7632 0.2644 0.8165 0.122 Uiso 1 1 calc R . .
N14 N 0.7649(15) 0.1821(8) 0.6781(16) 0.090(5) Uani 1 1 d DU . .
H14C H 0.7270 0.2005 0.6325 0.108 Uiso 1 1 calc R . .
N15 N 0.7453(18) 0.0881(8) 0.7619(18) 0.119(6) Uani 1 1 d DU . .
H15C H 0.7789 0.0708 0.8104 0.143 Uiso 1 1 calc R . .
H15D H 0.6927 0.0723 0.7294 0.143 Uiso 1 1 calc R . .
C1 C 0.1019(18) 0.1980(6) 0.2957(16) 0.076(5) Uani 1 1 d DU . .
H1A H 0.1509 0.2203 0.3266 0.091 Uiso 1 1 calc R . .
H1B H 0.0432 0.2139 0.2623 0.091 Uiso 1 1 calc R . .
C2 C 0.0905(15) 0.1641(8) 0.3569(14) 0.070(5) Uani 1 1 d DU . .
H2A H 0.0404 0.1433 0.3217 0.084 Uiso 1 1 calc R . .
H2B H 0.0688 0.1798 0.4001 0.084 Uiso 1 1 calc R . .
C3 C 0.1582(14) 0.1016(7) 0.4707(15) 0.059(4) Uani 1 1 d DU . .
H3A H 0.1506 0.1163 0.5231 0.071 Uiso 1 1 calc R . .
H3B H 0.1028 0.0828 0.4396 0.071 Uiso 1 1 calc R . .
C4 C 0.2422(15) 0.0741(8) 0.4982(14) 0.067(4) Uani 1 1 d DU . .
H4A H 0.2411 0.0535 0.5466 0.081 Uiso 1 1 calc R . .
H4B H 0.2961 0.0945 0.5241 0.081 Uiso 1 1 calc R . .
C5 C 0.3470(14) 0.0218(8) 0.4543(14) 0.065(4) Uani 1 1 d DU . .
H5A H 0.3951 0.0402 0.4993 0.078 Uiso 1 1 calc R . .
H5B H 0.3409 -0.0069 0.4837 0.078 Uiso 1 1 calc R . .
C6 C 0.3796(18) 0.0110(7) 0.3817(15) 0.067(5) Uani 1 1 d DU . .
H6A H 0.3321 -0.0066 0.3342 0.081 Uiso 1 1 calc R . .
H6B H 0.4374 -0.0071 0.4045 0.081 Uiso 1 1 calc R . .
C7 C 0.4741(14) 0.0827(7) 0.4065(15) 0.056(4) Uani 1 1 d DU . .
H7A H 0.4765 0.0793 0.4688 0.067 Uiso 1 1 calc R . .
H7B H 0.5333 0.0714 0.4042 0.067 Uiso 1 1 calc R . .
C8 C 0.4639(13) 0.1307(7) 0.3821(17) 0.057(5) Uani 1 1 d DU . .
H8A H 0.4607 0.1349 0.3198 0.068 Uiso 1 1 calc R . .
H8B H 0.5167 0.1484 0.4228 0.068 Uiso 1 1 calc R . .
C9 C 0.1321(17) 0.1918(9) -0.1072(13) 0.078(5) Uani 1 1 d DU . .
H9A H 0.0871 0.2172 -0.1222 0.094 Uiso 1 1 calc R . .
H9B H 0.1876 0.2025 -0.1182 0.094 Uiso 1 1 calc R . .
C10 C 0.0911(16) 0.1546(7) -0.1689(17) 0.073(5) Uani 1 1 d DU . .
H10A H 0.0864 0.1628 -0.2303 0.088 Uiso 1 1 calc R . .
H10B H 0.0281 0.1478 -0.1700 0.088 Uiso 1 1 calc R . .
C11 C 0.1058(16) 0.0753(7) -0.1909(17) 0.078(5) Uani 1 1 d DU . .
H11A H 0.0491 0.0678 -0.1788 0.093 Uiso 1 1 calc R . .
H11B H 0.0875 0.0825 -0.2553 0.093 Uiso 1 1 calc R . .
C12 C 0.1696(15) 0.0370(9) -0.1677(14) 0.072(5) Uani 1 1 d DU . .
H12A H 0.2201 0.0429 -0.1903 0.086 Uiso 1 1 calc R . .
H12B H 0.1359 0.0097 -0.1986 0.086 Uiso 1 1 calc R . .
C13 C 0.2939(13) -0.0022(8) -0.033(2) 0.091(5) Uani 1 1 d DU . .
H13A H 0.2929 -0.0184 0.0202 0.110 Uiso 1 1 calc R . .
H13B H 0.2943 -0.0249 -0.0788 0.110 Uiso 1 1 calc R . .
C14 C 0.3761(15) 0.0263(8) -0.0099(16) 0.076(5) Uani 1 1 d DU . .
H14A H 0.3733 0.0434 -0.0640 0.091 Uiso 1 1 calc R . .
H14B H 0.4313 0.0064 0.0068 0.091 Uiso 1 1 calc R . .
C15 C 0.4709(15) 0.0873(7) 0.069(2) 0.085(5) Uani 1 1 d DU . .
H15A H 0.5273 0.0762 0.1176 0.102 Uiso 1 1 calc R . .
H15B H 0.4815 0.0857 0.0118 0.102 Uiso 1 1 calc R . .
C16 C 0.4508(14) 0.1337(8) 0.0868(15) 0.079(5) Uani 1 1 d DU . .
H16C H 0.5023 0.1539 0.0878 0.094 Uiso 1 1 calc R . .
H16D H 0.4442 0.1355 0.1459 0.094 Uiso 1 1 calc R . .
C17 C 0.806(2) 0.1322(11) 1.0488(19) 0.120(7) Uani 1 1 d DU . .
H17A H 0.7441 0.1328 1.0526 0.144 Uiso 1 1 calc R . .
H17B H 0.8458 0.1121 1.0972 0.144 Uiso 1 1 calc R . .
C18 C 0.845(2) 0.1778(10) 1.066(2) 0.123(6) Uani 1 1 d DU . .
H18A H 0.9086 0.1788 1.0656 0.148 Uiso 1 1 calc R . .
H18B H 0.8457 0.1894 1.1245 0.148 Uiso 1 1 calc R . .
C19 C 0.815(2) 0.2500(9) 0.987(2) 0.099(6) Uani 1 1 d DU . .
H19A H 0.7633 0.2721 0.9675 0.118 Uiso 1 1 calc R . .
H19B H 0.8588 0.2591 1.0473 0.118 Uiso 1 1 calc R . .
C20 C 0.8618(19) 0.2478(11) 0.9236(16) 0.114(6) Uani 1 1 d DU . .
H20A H 0.9077 0.2230 0.9426 0.137 Uiso 1 1 calc R . .
H20B H 0.8972 0.2763 0.9291 0.137 Uiso 1 1 calc R . .
C21 C 0.835(2) 0.2455(9) 0.7495(19) 0.111(6) Uani 1 1 d DU . .
H21A H 0.7848 0.2590 0.6982 0.133 Uiso 1 1 calc R . .
H21B H 0.8903 0.2656 0.7649 0.133 Uiso 1 1 calc R . .
C22 C 0.8582(16) 0.2007(9) 0.7257(18) 0.096(5) Uani 1 1 d DU . .
H22A H 0.8928 0.1826 0.7795 0.115 Uiso 1 1 calc R . .
H22B H 0.8946 0.2025 0.6863 0.115 Uiso 1 1 calc R . .
C23 C 0.778(2) 0.1360(8) 0.649(2) 0.104(6) Uani 1 1 d DU . .
H23A H 0.7191 0.1286 0.5987 0.125 Uiso 1 1 calc R . .
H23B H 0.8259 0.1386 0.6221 0.125 Uiso 1 1 calc R . .
C24 C 0.801(2) 0.0960(10) 0.706(2) 0.108(6) Uani 1 1 d DU . .
H24A H 0.8671 0.0982 0.7453 0.130 Uiso 1 1 calc R . .
H24B H 0.7950 0.0691 0.6669 0.130 Uiso 1 1 calc R . .
N16 N 0.700(3) 0.1470(14) 0.262(3) 0.105(11) Uani 0.50 1 d PDU . .
H16A H 0.6948 0.1608 0.2095 0.157 Uiso 0.50 1 d PR . .
H16E H 0.6438 0.1367 0.2585 0.157 Uiso 0.50 1 d PR . .
N17 N 0.859(3) 0.0798(11) 0.406(3) 0.129(11) Uani 0.50 1 d PDU . .
H17C H 0.9027 0.0996 0.4336 0.154 Uiso 0.50 1 calc PR . .
N18 N 1.027(2) 0.0217(9) 0.498(5) 0.128(12) Uani 0.25 1 d PDU . .
H18C H 1.0461 0.0500 0.5213 0.154 Uiso 0.25 1 d PR . .
C25 C 0.765(4) 0.1086(19) 0.278(2) 0.127(11) Uani 0.50 1 d PDU . .
H25A H 0.7427 0.0848 0.2314 0.152 Uiso 0.50 1 calc PR . .
H25B H 0.8284 0.1183 0.2833 0.152 Uiso 0.50 1 calc PR . .
C26 C 0.762(3) 0.0942(16) 0.364(3) 0.133(11) Uani 0.50 1 d PDU . .
H26A H 0.7178 0.0689 0.3570 0.160 Uiso 0.50 1 calc PR . .
H26B H 0.7462 0.1195 0.3963 0.160 Uiso 0.50 1 calc PR . .
C27 C 0.884(3) 0.0314(15) 0.401(3) 0.128(11) Uani 0.50 1 d PDU . .
H27A H 0.8283 0.0120 0.3745 0.154 Uiso 0.50 1 calc PR . .
H27B H 0.9262 0.0272 0.3677 0.154 Uiso 0.50 1 calc PR . .
C28 C 0.930(3) 0.0245(18) 0.498(3) 0.136(11) Uani 0.50 1 d PDU . .
H28A H 0.9216 0.0502 0.5325 0.163 Uiso 0.50 1 d PR . .
H28B H 0.9105 -0.0036 0.5181 0.163 Uiso 0.50 1 d PR . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Sb1 0.0699(13) 0.0464(14) 0.0499(14) -0.0114(11) 0.0374(11) -0.0214(10)
Eu1 0.0419(8) 0.0667(12) 0.0496(11) -0.0044(9) 0.0228(7) 0.0008(7)
Eu2 0.0480(8) 0.0350(9) 0.0409(9) -0.0033(8) 0.0252(7) -0.0028(6)
Eu3 0.0445(8) 0.0362(10) 0.0449(10) 0.0029(8) 0.0279(7) -0.0012(6)
In1 0.0385(10) 0.0394(13) 0.0423(13) -0.0032(10) 0.0225(9) -0.0011(8)
In2 0.0519(11) 0.0332(13) 0.0477(13) 0.0004(10) 0.0315(10) 0.0013(9)
In3 0.0359(10) 0.0443(14) 0.0358(13) -0.0052(10) 0.0202(9) 0.0004(8)
In4 0.0361(10) 0.0410(13) 0.0352(12) 0.0022(10) 0.0201(9) -0.0020(8)
S1 0.043(4) 0.082(6) 0.056(6) -0.001(5) 0.014(4) 0.005(4)
S2 0.054(4) 0.047(5) 0.051(5) 0.009(4) 0.026(4) 0.004(3)
S3 0.036(4) 0.052(5) 0.048(5) 0.010(4) 0.013(3) -0.001(3)
S4 0.036(4) 0.068(6) 0.046(5) -0.024(4) 0.024(4) -0.004(3)
S5 0.133(8) 0.077(7) 0.103(8) 0.021(6) 0.071(7) 0.031(5)
S6 0.055(4) 0.041(5) 0.049(5) 0.012(4) 0.031(4) 0.006(3)
S7 0.047(4) 0.065(5) 0.021(4) 0.008(4) 0.017(3) 0.014(3)
S8 0.043(4) 0.064(6) 0.047(5) -0.020(4) 0.024(4) 0.003(3)
S9 0.039(4) 0.064(5) 0.044(5) 0.005(4) 0.026(4) -0.003(3)
S10 0.070(5) 0.090(7) 0.054(5) -0.031(5) 0.043(4) -0.037(4)
S11 0.069(5) 0.029(5) 0.054(5) -0.011(4) 0.035(4) -0.007(3)
S12 0.069(5) 0.048(5) 0.092(7) 0.012(5) 0.053(5) -0.006(4)
O1 0.039(10) 0.072(13) 0.057(12) 0.001(10) 0.034(9) 0.022(8)
N1 0.073(9) 0.064(10) 0.079(10) 0.011(8) 0.062(7) 0.006(8)
N2 0.074(8) 0.063(9) 0.078(9) -0.003(7) 0.053(7) 0.012(7)
N3 0.086(8) 0.051(8) 0.077(9) -0.005(7) 0.026(7) 0.014(7)
N4 0.073(8) 0.037(9) 0.060(9) -0.004(8) 0.032(7) 0.003(7)
N5 0.068(7) 0.042(8) 0.067(8) -0.004(7) 0.040(6) 0.008(6)
N6 0.058(8) 0.079(10) 0.071(10) 0.011(9) 0.050(8) 0.009(8)
N7 0.068(8) 0.078(9) 0.068(9) 0.016(8) 0.039(7) 0.004(7)
N8 0.070(8) 0.086(9) 0.079(9) 0.021(8) 0.047(7) -0.006(7)
N9 0.057(6) 0.076(7) 0.077(7) 0.012(6) 0.064(6) 0.014(6)
N10 0.058(8) 0.070(9) 0.086(9) 0.021(8) 0.037(7) 0.016(7)
N11 0.132(12) 0.108(13) 0.110(13) -0.003(11) 0.033(11) 0.019(10)
N12 0.116(11) 0.108(12) 0.110(12) -0.013(10) 0.051(9) 0.009(9)
N13 0.112(10) 0.105(11) 0.104(11) -0.010(10) 0.059(9) -0.002(9)
N14 0.110(10) 0.093(11) 0.098(11) -0.009(9) 0.076(9) 0.011(9)
N15 0.147(12) 0.105(12) 0.112(13) -0.019(10) 0.054(10) 0.007(10)
C1 0.075(10) 0.056(11) 0.098(11) 0.006(10) 0.034(9) 0.019(9)
C2 0.079(9) 0.055(10) 0.088(10) -0.018(9) 0.045(8) 0.029(8)
C3 0.069(8) 0.060(10) 0.076(9) -0.007(8) 0.058(7) 0.009(8)
C4 0.082(8) 0.058(9) 0.072(9) -0.013(8) 0.039(7) 0.016(7)
C5 0.076(8) 0.059(9) 0.073(9) 0.000(8) 0.043(7) -0.009(7)
C6 0.086(9) 0.056(10) 0.067(10) -0.013(9) 0.035(8) 0.009(8)
C7 0.072(9) 0.051(9) 0.061(9) 0.000(8) 0.044(7) -0.002(8)
C8 0.072(10) 0.035(10) 0.060(10) -0.021(10) 0.019(9) 0.009(9)
C9 0.070(9) 0.076(11) 0.084(10) 0.022(10) 0.023(9) 0.001(8)
C10 0.071(9) 0.087(11) 0.073(10) 0.010(9) 0.041(8) 0.001(8)
C11 0.069(9) 0.089(10) 0.079(10) 0.015(9) 0.031(8) -0.009(8)
C12 0.072(9) 0.092(10) 0.071(9) 0.001(9) 0.050(8) -0.009(8)
C13 0.079(9) 0.091(10) 0.100(10) 0.002(9) 0.029(9) -0.003(8)
C14 0.066(8) 0.087(9) 0.091(9) 0.012(8) 0.047(7) 0.013(7)
C15 0.069(9) 0.082(10) 0.104(10) 0.018(9) 0.031(9) 0.006(9)
C16 0.075(9) 0.078(11) 0.091(10) 0.011(10) 0.040(9) -0.002(9)
C17 0.125(12) 0.109(14) 0.119(13) -0.007(12) 0.037(11) 0.022(11)
C18 0.125(12) 0.112(13) 0.122(13) -0.005(11) 0.031(11) 0.013(11)
C19 0.110(11) 0.112(13) 0.100(12) -0.020(11) 0.068(10) 0.015(10)
C20 0.119(11) 0.115(12) 0.118(12) -0.008(11) 0.055(10) 0.002(10)
C21 0.124(11) 0.106(12) 0.112(12) -0.003(11) 0.053(10) 0.009(10)
C22 0.117(11) 0.111(12) 0.096(11) -0.007(10) 0.082(9) 0.010(10)
C23 0.134(11) 0.116(13) 0.098(12) -0.001(10) 0.083(10) 0.011(11)
C24 0.128(12) 0.101(13) 0.113(13) -0.004(11) 0.064(11) 0.006(11)
N16 0.104(13) 0.110(13) 0.107(13) -0.004(9) 0.046(9) 0.000(9)
N17 0.130(12) 0.135(12) 0.130(12) -0.004(7) 0.056(7) 0.002(7)
N18 0.130(13) 0.132(14) 0.128(14) 0.002(8) 0.053(8) -0.004(8)
C25 0.128(13) 0.133(13) 0.125(13) 0.000(8) 0.053(8) -0.007(8)
C26 0.134(12) 0.136(12) 0.131(12) 0.002(7) 0.050(8) -0.011(7)
C27 0.131(12) 0.131(12) 0.128(12) 0.005(7) 0.054(7) -0.009(7)
C28 0.137(13) 0.137(13) 0.134(13) 0.000(7) 0.049(8) -0.003(7)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 S10 2.359(6) . ?
Sb1 S12 2.417(7) . ?
Sb1 S11 2.425(6) . ?
Sb1 Eu2 3.711(2) . ?
Eu1 N15 2.64(2) . ?
Eu1 N13 2.71(2) . ?
Eu1 N11 2.71(2) . ?
Eu1 N12 2.73(3) . ?
Eu1 N14 2.817(19) . ?
Eu1 S7 3.067(5) . ?
Eu1 S9 3.132(7) . ?
Eu1 S6 3.240(7) . ?
Eu1 In4 3.852(3) . ?
Eu1 In3 3.8880(19) . ?
Eu1 In2 3.902(2) . ?
Eu2 O1 2.338(13) . ?
Eu2 N1 2.484(18) . ?
Eu2 N5 2.547(18) . ?
Eu2 N3 2.582(19) . ?
Eu2 N4 2.604(17) . ?
Eu2 N2 2.651(16) . ?
Eu2 S10 2.871(6) . ?
Eu2 S11 2.924(6) . ?
Eu2 Eu3 3.9821(19) . ?
Eu3 O1 2.297(15) . ?
Eu3 N7 2.52(2) . ?
Eu3 N10 2.527(17) . ?
Eu3 N6 2.570(18) . ?
Eu3 N9 2.582(16) . ?
Eu3 N8 2.62(2) . ?
Eu3 S12 2.831(6) . ?
Eu3 S11 2.947(6) . ?
In1 S4 2.436(6) . ?
In1 S2 2.448(7) . ?
In1 S1 2.499(6) . ?
In1 S3 2.504(6) . ?
In2 S2 2.417(6) . ?
In2 S7 2.448(7) . ?
In2 S6 2.452(5) . ?
In2 S5 2.506(9) . ?
In3 S8 2.423(7) . ?
In3 S4 2.427(6) . ?
In3 S7 2.482(7) . ?
In3 S9 2.493(5) . ?
In4 S3 2.430(6) . ?
In4 S9 2.453(7) . ?
In4 S8 2.461(5) 4_565 ?
In4 S6 2.491(7) . ?
S8 In4 2.461(5) 4_566 ?
N1 C1 1.457(8) . ?
N1 H1C 0.9000 . ?
N1 H1D 0.9000 . ?
N2 C3 1.458(8) . ?
N2 C2 1.458(8) . ?
N2 H2C 0.9100 . ?
N3 C4 1.446(8) . ?
N3 C5 1.453(8) . ?
N3 H3C 0.9100 . ?
N4 C7 1.450(9) . ?
N4 C6 1.455(9) . ?
N4 H4C 0.9100 . ?
N5 C8 1.453(8) . ?
N5 H5C 0.9000 . ?
N5 H5D 0.9000 . ?
N6 C9 1.451(8) . ?
N6 H6C 0.9000 . ?
N6 H6D 0.9000 . ?
N7 C11 1.450(9) . ?
N7 C10 1.453(8) . ?
N7 H7C 0.9100 . ?
N8 C13 1.453(9) . ?
N8 C12 1.457(8) . ?
N8 H8C 0.9100 . ?
N9 C15 1.449(8) . ?
N9 C14 1.455(8) . ?
N9 H9C 0.9100 . ?
N10 C16 1.455(9) . ?
N10 H10C 0.9000 . ?
N10 H10D 0.9000 . ?
N11 C17 1.454(9) . ?
N11 H11C 0.9000 . ?
N11 H11D 0.9000 . ?
N12 C18 1.451(9) . ?
N12 C19 1.457(9) . ?
N12 H12C 0.9100 . ?
N13 C21 1.449(9) . ?
N13 C20 1.453(9) . ?
N13 H13C 0.9100 . ?
N14 C22 1.442(9) . ?
N14 C23 1.445(9) . ?
N14 H14C 0.9100 . ?
N15 C24 1.448(9) . ?
N15 H15C 0.9000 . ?
N15 H15D 0.9000 . ?
C1 C2 1.428(11) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.428(11) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.434(11) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.432(11) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.430(11) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.429(11) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.427(11) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.428(11) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 H16C 0.9700 . ?
C16 H16D 0.9700 . ?
C17 C18 1.429(11) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C20 1.427(11) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.425(11) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.427(11) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
N16 C25 1.448(9) . ?
N16 H16A 0.8900 . ?
N16 H16E 0.8900 . ?
N17 C26 1.448(9) . ?
N17 C27 1.457(9) . ?
N17 H17C 0.8600 . ?
N18 C28 1.470(9) . ?
N18 C28 1.476(9) 3_756 ?
N18 N18 1.51(3) 3_756 ?
N18 H18C 0.8998 . ?
C25 C26 1.429(11) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.440(11) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 N18 1.476(9) 3_756 ?
C28 H28A 0.9599 . ?
C28 H28B 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S10 Sb1 S12 103.9(3) . . ?
S10 Sb1 S11 95.9(2) . . ?
S12 Sb1 S11 94.2(2) . . ?
S10 Sb1 Eu2 50.66(15) . . ?
S12 Sb1 Eu2 82.78(19) . . ?
S11 Sb1 Eu2 51.91(15) . . ?
N15 Eu1 N13 117.0(7) . . ?
N15 Eu1 N11 68.6(8) . . ?
N13 Eu1 N11 106.1(8) . . ?
N15 Eu1 N12 126.1(8) . . ?
N13 Eu1 N12 65.7(7) . . ?
N11 Eu1 N12 60.3(7) . . ?
N15 Eu1 N14 68.6(6) . . ?
N13 Eu1 N14 60.4(6) . . ?
N11 Eu1 N14 118.8(7) . . ?
N12 Eu1 N14 122.8(7) . . ?
N15 Eu1 S7 107.6(5) . . ?
N13 Eu1 S7 134.3(5) . . ?
N11 Eu1 S7 80.2(5) . . ?
N12 Eu1 S7 80.5(5) . . ?
N14 Eu1 S7 154.5(5) . . ?
N15 Eu1 S9 146.1(6) . . ?
N13 Eu1 S9 71.2(5) . . ?
N11 Eu1 S9 143.7(5) . . ?
N12 Eu1 S9 87.7(5) . . ?
N14 Eu1 S9 92.0(5) . . ?
S7 Eu1 S9 77.83(15) . . ?
N15 Eu1 S6 71.9(6) . . ?
N13 Eu1 S6 125.7(5) . . ?
N11 Eu1 S6 124.9(6) . . ?
N12 Eu1 S6 154.9(5) . . ?
N14 Eu1 S6 78.2(5) . . ?
S7 Eu1 S6 76.75(15) . . ?
S9 Eu1 S6 77.23(17) . . ?
N15 Eu1 In4 106.9(6) . . ?
N13 Eu1 In4 92.6(5) . . ?
N11 Eu1 In4 160.9(6) . . ?
N12 Eu1 In4 127.0(5) . . ?
N14 Eu1 In4 73.9(5) . . ?
S7 Eu1 In4 83.76(12) . . ?
S9 Eu1 In4 39.45(13) . . ?
S6 Eu1 In4 39.97(12) . . ?
N15 Eu1 In3 143.2(5) . . ?
N13 Eu1 In3 99.2(5) . . ?
N11 Eu1 In3 109.3(5) . . ?
N12 Eu1 In3 73.7(5) . . ?
N14 Eu1 In3 131.0(5) . . ?
S7 Eu1 In3 39.66(12) . . ?
S9 Eu1 In3 39.80(10) . . ?
S6 Eu1 In3 81.91(10) . . ?
In4 Eu1 In3 62.44(4) . . ?
N15 Eu1 In2 84.2(5) . . ?
N13 Eu1 In2 151.1(5) . . ?
N11 Eu1 In2 99.9(6) . . ?
N12 Eu1 In2 119.4(5) . . ?
N14 Eu1 In2 116.8(5) . . ?
S7 Eu1 In2 38.84(12) . . ?
S9 Eu1 In2 80.32(11) . . ?
S6 Eu1 In2 38.78(10) . . ?
In4 Eu1 In2 61.01(4) . . ?
In3 Eu1 In2 59.54(4) . . ?
O1 Eu2 N1 78.0(4) . . ?
O1 Eu2 N5 79.9(5) . . ?
N1 Eu2 N5 94.1(6) . . ?
O1 Eu2 N3 152.3(5) . . ?
N1 Eu2 N3 127.4(5) . . ?
N5 Eu2 N3 86.7(6) . . ?
O1 Eu2 N4 85.5(5) . . ?
N1 Eu2 N4 154.9(6) . . ?
N5 Eu2 N4 64.2(5) . . ?
N3 Eu2 N4 66.8(5) . . ?
O1 Eu2 N2 131.9(5) . . ?
N1 Eu2 N2 63.0(5) . . ?
N5 Eu2 N2 76.2(6) . . ?
N3 Eu2 N2 66.3(5) . . ?
N4 Eu2 N2 118.9(6) . . ?
O1 Eu2 S10 125.3(4) . . ?
N1 Eu2 S10 78.7(4) . . ?
N5 Eu2 S10 150.5(4) . . ?
N3 Eu2 S10 75.8(5) . . ?
N4 Eu2 S10 126.4(4) . . ?
N2 Eu2 S10 75.0(5) . . ?
O1 Eu2 S11 73.7(4) . . ?
N1 Eu2 S11 118.7(5) . . ?
N5 Eu2 S11 131.2(3) . . ?
N3 Eu2 S11 98.2(4) . . ?
N4 Eu2 S11 73.4(4) . . ?
N2 Eu2 S11 149.4(4) . . ?
S10 Eu2 S11 75.62(17) . . ?
O1 Eu2 Sb1 91.0(4) . . ?
N1 Eu2 Sb1 87.9(5) . . ?
N5 Eu2 Sb1 170.0(4) . . ?
N3 Eu2 Sb1 99.8(5) . . ?
N4 Eu2 Sb1 111.4(4) . . ?
N2 Eu2 Sb1 113.3(4) . . ?
S10 Eu2 Sb1 39.46(13) . . ?
S11 Eu2 Sb1 40.75(12) . . ?
O1 Eu2 Eu3 30.5(4) . . ?
N1 Eu2 Eu3 83.6(4) . . ?
N5 Eu2 Eu3 109.4(4) . . ?
N3 Eu2 Eu3 144.9(4) . . ?
N4 Eu2 Eu3 91.7(4) . . ?
N2 Eu2 Eu3 146.5(4) . . ?
S10 Eu2 Eu3 98.25(14) . . ?
S11 Eu2 Eu3 47.53(12) . . ?
Sb1 Eu2 Eu3 61.04(4) . . ?
O1 Eu3 N7 148.5(6) . . ?
O1 Eu3 N10 83.4(6) . . ?
N7 Eu3 N10 83.3(6) . . ?
O1 Eu3 N6 83.7(6) . . ?
N7 Eu3 N6 65.4(6) . . ?
N10 Eu3 N6 75.6(5) . . ?
O1 Eu3 N9 90.2(5) . . ?
N7 Eu3 N9 108.7(6) . . ?
N10 Eu3 N9 63.0(5) . . ?
N6 Eu3 N9 138.6(5) . . ?
O1 Eu3 N8 146.7(6) . . ?
N7 Eu3 N8 64.7(6) . . ?
N10 Eu3 N8 106.5(6) . . ?
N6 Eu3 N8 129.4(6) . . ?
N9 Eu3 N8 67.9(6) . . ?
O1 Eu3 S12 94.3(3) . . ?
N7 Eu3 S12 81.5(4) . . ?
N10 Eu3 S12 146.2(4) . . ?
N6 Eu3 S12 70.7(4) . . ?
N9 Eu3 S12 150.7(4) . . ?
N8 Eu3 S12 93.9(4) . . ?
O1 Eu3 S11 73.8(4) . . ?
N7 Eu3 S11 133.7(5) . . ?
N10 Eu3 S11 134.4(4) . . ?
N6 Eu3 S11 137.6(3) . . ?
N9 Eu3 S11 77.9(4) . . ?
N8 Eu3 S11 77.1(4) . . ?
S12 Eu3 S11 75.70(19) . . ?
O1 Eu3 Eu2 31.1(3) . . ?
N7 Eu3 Eu2 153.4(4) . . ?
N10 Eu3 Eu2 113.6(5) . . ?
N6 Eu3 Eu2 97.9(4) . . ?
N9 Eu3 Eu2 97.5(4) . . ?
N8 Eu3 Eu2 124.2(4) . . ?
S12 Eu3 Eu2 73.22(16) . . ?
S11 Eu3 Eu2 47.06(12) . . ?
S4 In1 S2 107.2(2) . . ?
S4 In1 S1 104.6(2) . . ?
S2 In1 S1 106.7(2) . . ?
S4 In1 S3 117.3(2) . . ?
S2 In1 S3 117.1(2) . . ?
S1 In1 S3 102.5(2) . . ?
S2 In2 S7 111.3(2) . . ?
S2 In2 S6 120.7(2) . . ?
S7 In2 S6 106.2(2) . . ?
S2 In2 S5 106.8(3) . . ?
S7 In2 S5 107.7(3) . . ?
S6 In2 S5 103.3(2) . . ?
S2 In2 Eu1 146.78(17) . . ?
S7 In2 Eu1 51.79(12) . . ?
S6 In2 Eu1 55.85(16) . . ?
S5 In2 Eu1 105.8(2) . . ?
S8 In3 S4 111.88(19) . . ?
S8 In3 S7 103.0(2) . . ?
S4 In3 S7 118.6(2) . . ?
S8 In3 S9 109.0(2) . . ?
S4 In3 S9 110.7(2) . . ?
S7 In3 S9 103.00(19) . . ?
S8 In3 Eu1 102.50(14) . . ?
S4 In3 Eu1 145.58(15) . . ?
S7 In3 Eu1 52.03(12) . . ?
S9 In3 Eu1 53.53(15) . . ?
S3 In4 S9 116.6(2) . . ?
S3 In4 S8 116.7(2) . 4_565 ?
S9 In4 S8 104.4(2) . 4_565 ?
S3 In4 S6 107.0(2) . . ?
S9 In4 S6 107.1(2) . . ?
S8 In4 S6 104.0(2) 4_565 . ?
S3 In4 Eu1 145.88(16) . . ?
S9 In4 Eu1 54.24(16) . . ?
S8 In4 Eu1 97.01(16) 4_565 . ?
S6 In4 Eu1 56.67(16) . . ?
In2 S2 In1 100.0(2) . . ?
In4 S3 In1 102.2(2) . . ?
In3 S4 In1 102.53(19) . . ?
In2 S6 In4 105.5(2) . . ?
In2 S6 Eu1 85.37(19) . . ?
In4 S6 Eu1 83.36(19) . . ?
In2 S7 In3 103.4(2) . . ?
In2 S7 Eu1 89.37(16) . . ?
In3 S7 Eu1 88.31(18) . . ?
In3 S8 In4 118.6(2) . 4_566 ?
In4 S9 In3 108.4(2) . . ?
In4 S9 Eu1 86.31(19) . . ?
In3 S9 Eu1 86.67(19) . . ?
Sb1 S10 Eu2 89.88(16) . . ?
Sb1 S11 Eu2 87.33(17) . . ?
Sb1 S11 Eu3 93.0(2) . . ?
Eu2 S11 Eu3 85.41(16) . . ?
Sb1 S12 Eu3 96.1(2) . . ?
Eu3 O1 Eu2 118.4(6) . . ?
C1 N1 Eu2 126.4(13) . . ?
C1 N1 H1C 105.7 . . ?
Eu2 N1 H1C 105.7 . . ?
C1 N1 H1D 105.7 . . ?
Eu2 N1 H1D 105.7 . . ?
H1C N1 H1D 106.2 . . ?
C3 N2 C2 117.0(16) . . ?
C3 N2 Eu2 111.9(12) . . ?
C2 N2 Eu2 106.3(12) . . ?
C3 N2 H2C 107.1 . . ?
C2 N2 H2C 107.1 . . ?
Eu2 N2 H2C 107.1 . . ?
C4 N3 C5 116.7(17) . . ?
C4 N3 Eu2 108.6(14) . . ?
C5 N3 Eu2 110.3(13) . . ?
C4 N3 H3C 106.9 . . ?
C5 N3 H3C 106.9 . . ?
Eu2 N3 H3C 106.9 . . ?
C7 N4 C6 116.6(19) . . ?
C7 N4 Eu2 113.6(13) . . ?
C6 N4 Eu2 106.1(13) . . ?
C7 N4 H4C 106.6 . . ?
C6 N4 H4C 106.6 . . ?
Eu2 N4 H4C 106.6 . . ?
C8 N5 Eu2 112.2(13) . . ?
C8 N5 H5C 109.2 . . ?
Eu2 N5 H5C 109.2 . . ?
C8 N5 H5D 109.2 . . ?
Eu2 N5 H5D 109.2 . . ?
H5C N5 H5D 107.9 . . ?
C9 N6 Eu3 112.8(14) . . ?
C9 N6 H6C 109.0 . . ?
Eu3 N6 H6C 109.0 . . ?
C9 N6 H6D 109.0 . . ?
Eu3 N6 H6D 109.0 . . ?
H6C N6 H6D 107.8 . . ?
C11 N7 C10 107.6(19) . . ?
C11 N7 Eu3 116.1(15) . . ?
C10 N7 Eu3 119.5(15) . . ?
C11 N7 H7C 103.9 . . ?
C10 N7 H7C 103.9 . . ?
Eu3 N7 H7C 103.9 . . ?
C13 N8 C12 121(2) . . ?
C13 N8 Eu3 110.3(16) . . ?
C12 N8 Eu3 113.9(15) . . ?
C13 N8 H8C 103.2 . . ?
C12 N8 H8C 103.2 . . ?
Eu3 N8 H8C 103.2 . . ?
C15 N9 C14 106.5(15) . . ?
C15 N9 Eu3 117.7(14) . . ?
C14 N9 Eu3 107.6(14) . . ?
C15 N9 H9C 108.2 . . ?
C14 N9 H9C 108.2 . . ?
Eu3 N9 H9C 108.2 . . ?
C16 N10 Eu3 107.3(14) . . ?
C16 N10 H10C 110.2 . . ?
Eu3 N10 H10C 110.2 . . ?
C16 N10 H10D 110.2 . . ?
Eu3 N10 H10D 110.2 . . ?
H10C N10 H10D 108.5 . . ?
C17 N11 Eu1 111.2(19) . . ?
C17 N11 H11C 109.4 . . ?
Eu1 N11 H11C 109.4 . . ?
C17 N11 H11D 109.4 . . ?
Eu1 N11 H11D 109.4 . . ?
H11C N11 H11D 108.0 . . ?
C18 N12 C19 110(3) . . ?
C18 N12 Eu1 122.4(19) . . ?
C19 N12 Eu1 112.0(18) . . ?
C18 N12 H12C 103.2 . . ?
C19 N12 H12C 103.2 . . ?
Eu1 N12 H12C 103.2 . . ?
C21 N13 C20 129(2) . . ?
C21 N13 Eu1 114.0(18) . . ?
C20 N13 Eu1 105.5(17) . . ?
C21 N13 H13C 101.4 . . ?
C20 N13 H13C 101.4 . . ?
Eu1 N13 H13C 101.4 . . ?
C22 N14 C23 107(2) . . ?
C22 N14 Eu1 103.0(14) . . ?
C23 N14 Eu1 103.5(15) . . ?
C22 N14 H14C 114.1 . . ?
C23 N14 H14C 114.1 . . ?
Eu1 N14 H14C 114.1 . . ?
C24 N15 Eu1 112.1(17) . . ?
C24 N15 H15C 109.2 . . ?
Eu1 N15 H15C 109.2 . . ?
C24 N15 H15D 109.2 . . ?
Eu1 N15 H15D 109.2 . . ?
H15C N15 H15D 107.9 . . ?
C2 C1 N1 97.7(12) . . ?
C2 C1 H1A 112.2 . . ?
N1 C1 H1A 112.2 . . ?
C2 C1 H1B 112.2 . . ?
N1 C1 H1B 112.2 . . ?
H1A C1 H1B 109.8 . . ?
C1 C2 N2 118.3(19) . . ?
C1 C2 H2A 107.7 . . ?
N2 C2 H2A 107.7 . . ?
C1 C2 H2B 107.7 . . ?
N2 C2 H2B 107.7 . . ?
H2A C2 H2B 107.1 . . ?
C4 C3 N2 104.6(16) . . ?
C4 C3 H3A 110.8 . . ?
N2 C3 H3A 110.8 . . ?
C4 C3 H3B 110.8 . . ?
N2 C3 H3B 110.8 . . ?
H3A C3 H3B 108.9 . . ?
C3 C4 N3 116.8(18) . . ?
C3 C4 H4A 108.1 . . ?
N3 C4 H4A 108.1 . . ?
C3 C4 H4B 108.1 . . ?
N3 C4 H4B 108.1 . . ?
H4A C4 H4B 107.3 . . ?
C6 C5 N3 116.1(18) . . ?
C6 C5 H5A 108.3 . . ?
N3 C5 H5A 108.3 . . ?
C6 C5 H5B 108.3 . . ?
N3 C5 H5B 108.3 . . ?
H5A C5 H5B 107.4 . . ?
C5 C6 N4 106.0(17) . . ?
C5 C6 H6A 110.5 . . ?
N4 C6 H6A 110.5 . . ?
C5 C6 H6B 110.5 . . ?
N4 C6 H6B 110.5 . . ?
H6A C6 H6B 108.7 . . ?
C8 C7 N4 112.1(19) . . ?
C8 C7 H7A 109.2 . . ?
N4 C7 H7A 109.2 . . ?
C8 C7 H7B 109.2 . . ?
N4 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
C7 C8 N5 105.0(17) . . ?
C7 C8 H8A 110.8 . . ?
N5 C8 H8A 110.8 . . ?
C7 C8 H8B 110.8 . . ?
N5 C8 H8B 110.8 . . ?
H8A C8 H8B 108.8 . . ?
C10 C9 N6 117(2) . . ?
C10 C9 H9A 108.1 . . ?
N6 C9 H9A 108.1 . . ?
C10 C9 H9B 108.1 . . ?
N6 C9 H9B 108.1 . . ?
H9A C9 H9B 107.3 . . ?
C9 C10 N7 107(2) . . ?
C9 C10 H10A 110.3 . . ?
N7 C10 H10A 110.3 . . ?
C9 C10 H10B 110.3 . . ?
N7 C10 H10B 110.3 . . ?
H10A C10 H10B 108.6 . . ?
C12 C11 N7 109(2) . . ?
C12 C11 H11A 110.0 . . ?
N7 C11 H11A 110.0 . . ?
C12 C11 H11B 110.0 . . ?
N7 C11 H11B 110.0 . . ?
H11A C11 H11B 108.3 . . ?
C11 C12 N8 114(2) . . ?
C11 C12 H12A 108.7 . . ?
N8 C12 H12A 108.7 . . ?
C11 C12 H12B 108.7 . . ?
N8 C12 H12B 108.7 . . ?
H12A C12 H12B 107.6 . . ?
C14 C13 N8 108(2) . . ?
C14 C13 H13A 110.1 . . ?
N8 C13 H13A 110.1 . . ?
C14 C13 H13B 110.1 . . ?
N8 C13 H13B 110.1 . . ?
H13A C13 H13B 108.4 . . ?
C13 C14 N9 116.3(19) . . ?
C13 C14 H14A 108.2 . . ?
N9 C14 H14A 108.2 . . ?
C13 C14 H14B 108.2 . . ?
N9 C14 H14B 108.2 . . ?
H14A C14 H14B 107.4 . . ?
C16 C15 N9 107.5(19) . . ?
C16 C15 H15A 110.2 . . ?
N9 C15 H15A 110.2 . . ?
C16 C15 H15B 110.2 . . ?
N9 C15 H15B 110.2 . . ?
H15A C15 H15B 108.5 . . ?
C15 C16 N10 108(2) . . ?
C15 C16 H16C 110.0 . . ?
N10 C16 H16C 110.0 . . ?
C15 C16 H16D 110.0 . . ?
N10 C16 H16D 110.0 . . ?
H16C C16 H16D 108.4 . . ?
C18 C17 N11 117(3) . . ?
C18 C17 H17A 108.1 . . ?
N11 C17 H17A 108.1 . . ?
C18 C17 H17B 108.1 . . ?
N11 C17 H17B 108.1 . . ?
H17A C17 H17B 107.3 . . ?
C17 C18 N12 102(3) . . ?
C17 C18 H18A 111.4 . . ?
N12 C18 H18A 111.4 . . ?
C17 C18 H18B 111.4 . . ?
N12 C18 H18B 111.4 . . ?
H18A C18 H18B 109.3 . . ?
C20 C19 N12 106(2) . . ?
C20 C19 H19A 110.6 . . ?
N12 C19 H19A 110.6 . . ?
C20 C19 H19B 110.6 . . ?
N12 C19 H19B 110.6 . . ?
H19A C19 H19B 108.7 . . ?
C19 C20 N13 119(2) . . ?
C19 C20 H20A 107.5 . . ?
N13 C20 H20A 107.5 . . ?
C19 C20 H20B 107.5 . . ?
N13 C20 H20B 107.5 . . ?
H20A C20 H20B 107.0 . . ?
C22 C21 N13 109(2) . . ?
C22 C21 H21A 110.0 . . ?
N13 C21 H21A 110.0 . . ?
C22 C21 H21B 110.0 . . ?
N13 C21 H21B 110.0 . . ?
H21A C21 H21B 108.4 . . ?
C21 C22 N14 101(2) . . ?
C21 C22 H22A 111.6 . . ?
N14 C22 H22A 111.6 . . ?
C21 C22 H22B 111.6 . . ?
N14 C22 H22B 111.6 . . ?
H22A C22 H22B 109.4 . . ?
C24 C23 N14 125(3) . . ?
C24 C23 H23A 106.0 . . ?
N14 C23 H23A 106.0 . . ?
C24 C23 H23B 106.0 . . ?
N14 C23 H23B 106.0 . . ?
H23A C23 H23B 106.3 . . ?
C23 C24 N15 116(2) . . ?
C23 C24 H24A 108.3 . . ?
N15 C24 H24A 108.3 . . ?
C23 C24 H24B 108.3 . . ?
N15 C24 H24B 108.3 . . ?
H24A C24 H24B 107.4 . . ?
C25 N16 H16A 109.5 . . ?
C25 N16 H16E 109.5 . . ?
H16A N16 H16E 109.5 . . ?
C26 N17 C27 119.2(12) . . ?
C26 N17 H17C 120.4 . . ?
C27 N17 H17C 120.4 . . ?
C28 N18 C28 118.3(12) . 3_756 ?
C28 N18 N18 59.4(7) . 3_756 ?
C28 N18 N18 58.9(7) 3_756 3_756 ?
C28 N18 H18C 97.1 . . ?
C28 N18 H18C 137.4 3_756 . ?
N18 N18 H18C 147.1 3_756 . ?
C26 C25 N16 97.4(13) . . ?
C26 C25 H25A 112.3 . . ?
N16 C25 H25A 112.3 . . ?
C26 C25 H25B 112.3 . . ?
N16 C25 H25B 112.3 . . ?
H25A C25 H25B 109.9 . . ?
C25 C26 N17 97.4(13) . . ?
C25 C26 H26A 112.3 . . ?
N17 C26 H26A 112.3 . . ?
C25 C26 H26B 112.3 . . ?
N17 C26 H26B 112.3 . . ?
H26A C26 H26B 109.9 . . ?
C28 C27 N17 96.4(12) . . ?
C28 C27 H27A 112.5 . . ?
N17 C27 H27A 112.5 . . ?
C28 C27 H27B 112.5 . . ?
N17 C27 H27B 112.5 . . ?
H27A C27 H27B 110.0 . . ?
C27 C28 N18 96.8(12) . . ?
C27 C28 N18 102(5) . 3_756 ?
N18 C28 N18 61.7(12) . 3_756 ?
C27 C28 H28A 112.4 . . ?
N18 C28 H28A 112.4 . . ?
N18 C28 H28A 145.4 3_756 . ?
C27 C28 H28B 112.4 . . ?
N18 C28 H28B 112.4 . . ?
N18 C28 H28B 53.4 3_756 . ?
H28A C28 H28B 110.0 . . ?

_diffrn_measured_fraction_theta_max 0.970
_diffrn_reflns_theta_full        25.60
_diffrn_measured_fraction_theta_full 0.970
_refine_diff_density_max         2.123
_refine_diff_density_min         -1.657
_refine_diff_density_rms         0.312