# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               Chem.Commun.
_journal_coden_cambridge         0182
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_name        'Jinkui Tang'
_publ_contact_author_email       tang@ciac.jl.cn
_publ_author_name                'Jinkui Tang'

data_1
#TrackingRef '- Dy3Mac.cif'

_database_code_depnum_ccdc_archive 'CCDC 871485'
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C51 H99 Dy3 N10 O28'
_chemical_formula_weight         1787.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.833(2)
_cell_length_b                   16.5643(12)
_cell_length_c                   16.5770(12)
_cell_angle_alpha                119.774(1)
_cell_angle_beta                 100.183(1)
_cell_angle_gamma                90.507(1)
_cell_volume                     3457.3(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    185(2)
_cell_measurement_reflns_used    9621
_cell_measurement_theta_min      2.46
_cell_measurement_theta_max      26.04

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.13
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.717
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1794
_exptl_absorpt_coefficient_mu    3.295
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5733
_exptl_absorpt_correction_T_max  0.6740
_exptl_absorpt_process_details   (sadabs;bruker,2000)

_exptl_special_details           
;
'comamands "isor 0.01 o25 c49 and isor 0.001 c1 c37" have been used to restrain the anisotropic displacement parameters of the corresponding atoms'
;

_diffrn_ambient_temperature      185(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18996
_diffrn_reflns_av_R_equivalents  0.0270
_diffrn_reflns_av_sigmaI/netI    0.0582
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_theta_min         1.40
_diffrn_reflns_theta_max         26.07
_reflns_number_total             13427
_reflns_number_gt                10282
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0587P)^2^+7.1739P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         13427
_refine_ls_number_parameters     843
_refine_ls_number_restraints     24
_refine_ls_R_factor_all          0.0639
_refine_ls_R_factor_gt           0.0425
_refine_ls_wR_factor_ref         0.1224
_refine_ls_wR_factor_gt          0.1033
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_restrained_S_all      1.066
_refine_ls_shift/su_max          0.028
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.25236(2) 0.65475(2) 0.29165(2) 0.02077(9) Uani 1 1 d . . .
Dy2 Dy 0.22235(2) 0.82876(2) 0.51531(2) 0.01867(9) Uani 1 1 d . . .
Dy3 Dy 0.24443(2) 0.59786(2) 0.47047(2) 0.01975(9) Uani 1 1 d . . .
N1 N 0.2827(4) 0.7049(4) 0.1770(4) 0.0211(12) Uani 1 1 d . . .
H1 H 0.2264 0.7156 0.1511 0.025 Uiso 1 1 calc R . .
N2 N 0.2612(4) 0.5210(4) 0.1342(4) 0.0240(13) Uani 1 1 d . . .
H2 H 0.3171 0.4985 0.1430 0.029 Uiso 1 1 calc R . .
N3 N 0.2751(4) 0.4359(4) 0.4347(4) 0.0217(12) Uani 1 1 d . . .
H3 H 0.2236 0.3962 0.3908 0.026 Uiso 1 1 calc R . .
N4 N 0.2235(4) 0.5646(4) 0.5987(4) 0.0188(12) Uani 1 1 d . . .
H4 H 0.2763 0.5927 0.6464 0.023 Uiso 1 1 calc R . .
N5 N 0.2170(4) 0.9500(3) 0.6818(4) 0.0192(12) Uani 1 1 d . . .
H5 H 0.1630 0.9333 0.6938 0.023 Uiso 1 1 calc R . .
N6 N 0.1793(4) 0.9805(4) 0.5297(4) 0.0196(12) Uani 1 1 d . . .
H6 H 0.2318 1.0119 0.5300 0.024 Uiso 1 1 calc R . .
N7 N 0.0246(4) 0.7851(5) 0.5577(5) 0.0337(15) Uani 1 1 d . . .
N8 N 0.4575(4) 0.5832(5) 0.3033(5) 0.0331(15) Uani 1 1 d . . .
N9 N 0.9599(5) 0.4789(5) 0.1772(6) 0.0420(17) Uani 1 1 d . . .
N10 N 0.5203(5) 0.8520(7) 0.6771(7) 0.055(2) Uani 1 1 d . . .
O1 O 0.2324(3) 0.8139(3) 0.3685(3) 0.0218(10) Uani 1 1 d . . .
O2 O 0.2636(3) 0.5214(3) 0.3089(3) 0.0252(11) Uani 1 1 d . . .
O3 O 0.2246(3) 0.7480(3) 0.5992(3) 0.0223(10) Uani 1 1 d . . .
O4 O 0.3661(3) 0.9203(3) 0.5618(4) 0.0274(11) Uani 1 1 d . . .
O5 O 0.1022(3) 0.6471(3) 0.2057(4) 0.0314(12) Uani 1 1 d . . .
O6 O 0.0940(3) 0.5081(3) 0.3986(4) 0.0272(11) Uani 1 1 d . . .
O7 O 0.3964(3) 0.6255(3) 0.5622(4) 0.0298(12) Uani 1 1 d . . .
O8 O 0.0615(3) 0.8271(3) 0.5228(3) 0.0257(11) Uani 1 1 d . . .
O9 O -0.0002(4) 0.7006(4) 0.5095(6) 0.062(2) Uani 1 1 d . . .
O10 O 0.0128(5) 0.8323(6) 0.6391(5) 0.072(2) Uani 1 1 d . . .
O11 O 0.4151(3) 0.6470(3) 0.2945(4) 0.0295(11) Uani 1 1 d . . .
O12 O 0.4662(4) 0.5114(4) 0.2321(4) 0.0511(16) Uani 1 1 d . . .
O13 O 0.4878(4) 0.5973(4) 0.3843(4) 0.0468(15) Uani 1 1 d . . .
O14 O 0.1577(3) 0.6739(3) 0.3996(3) 0.0221(10) Uani 1 1 d . . .
H14 H 0.0893 0.6580 0.3774 0.027 Uiso 1 1 calc R . .
O15 O 0.3216(3) 0.7125(3) 0.4527(3) 0.0206(10) Uani 1 1 d . . .
H15A H 0.3899 0.7285 0.4749 0.025 Uiso 1 1 calc R . .
O16 O 0.9423(6) 0.4003(5) 0.1623(6) 0.081(2) Uani 1 1 d . . .
O17 O 0.9904(4) 0.5446(4) 0.2595(4) 0.0494(16) Uani 1 1 d . . .
O18 O 0.9492(5) 0.4937(5) 0.1095(5) 0.065(2) Uani 1 1 d . . .
O19 O 0.5055(4) 0.7801(5) 0.5942(6) 0.062(2) Uani 1 1 d . . .
O20 O 0.5330(6) 0.8468(7) 0.7484(7) 0.102(3) Uani 1 1 d . . .
O21 O 0.5204(4) 0.9321(4) 0.6838(4) 0.0456(15) Uani 1 1 d . . .
O22 O 0.0813(5) 0.6851(5) 0.0643(4) 0.0543(17) Uani 1 1 d . . .
H22 H 0.0607 0.6389 0.0099 0.081 Uiso 1 1 calc R . .
O23 O 0.4312(4) 0.6114(4) 0.7182(4) 0.0372(13) Uani 1 1 d . . .
H23 H 0.4554 0.5709 0.7287 0.056 Uiso 1 1 calc R . .
O24 O 0.3694(4) 0.0837(4) 0.5671(4) 0.0391(14) Uani 1 1 d . . .
H24 H 0.3984 0.1212 0.6227 0.059 Uiso 1 1 calc R . .
O25 O 0.4361(8) 0.1935(9) 0.8570(10) 0.153(5) Uani 1 1 d U . .
H25 H 0.4319 0.1360 0.8382 0.230 Uiso 1 1 calc R . .
O26 O 0.5312(7) 0.0737(7) 0.8655(6) 0.103(3) Uani 1 1 d . . .
H26 H 0.5314 0.0269 0.8120 0.154 Uiso 1 1 calc R . .
O27 O 0.0728(4) 0.3232(4) 0.3354(4) 0.0355(13) Uani 1 1 d . . .
H27 H 0.0492 0.2944 0.3578 0.053 Uiso 1 1 calc R . .
O28 O 0.4207(6) 0.2511(8) 0.7383(8) 0.117(4) Uani 1 1 d . . .
C1 C 0.2265(4) 0.8768(4) 0.3374(4) 0.0088(11) Uani 1 1 d U . .
C2 C 0.1640(4) 0.9437(4) 0.3668(5) 0.0205(14) Uani 1 1 d . . .
C3 C 0.1581(5) 1.0067(5) 0.3334(5) 0.0291(17) Uani 1 1 d . . .
H3A H 0.1165 1.0527 0.3543 0.035 Uiso 1 1 calc R . .
C4 C 0.2102(6) 1.0046(5) 0.2713(5) 0.0320(18) Uani 1 1 d . . .
C5 C 0.2706(5) 0.9370(5) 0.2420(5) 0.0264(16) Uani 1 1 d . . .
H5A H 0.3074 0.9338 0.1992 0.032 Uiso 1 1 calc R . .
C6 C 0.2780(4) 0.8736(4) 0.2746(5) 0.0205(14) Uani 1 1 d . . .
C7 C 0.1113(5) 0.9537(5) 0.4388(5) 0.0238(15) Uani 1 1 d . . .
H7A H 0.0738 0.8939 0.4164 0.029 Uiso 1 1 calc R . .
H7B H 0.0694 1.0027 0.4497 0.029 Uiso 1 1 calc R . .
C8 C 0.3407(5) 0.7972(5) 0.2364(5) 0.0236(15) Uani 1 1 d . . .
H8A H 0.3774 0.8080 0.1975 0.028 Uiso 1 1 calc R . .
H8B H 0.3837 0.7978 0.2896 0.028 Uiso 1 1 calc R . .
C9 C 0.2051(7) 1.0750(6) 0.2389(7) 0.052(3) Uani 1 1 d . . .
H9A H 0.1709 1.0451 0.1729 0.077 Uiso 1 1 calc R . .
H9B H 0.2676 1.0986 0.2432 0.077 Uiso 1 1 calc R . .
H9C H 0.1735 1.1271 0.2795 0.077 Uiso 1 1 calc R . .
C10 C 0.3205(5) 0.6342(5) 0.0974(5) 0.0259(16) Uani 1 1 d . . .
H10A H 0.3851 0.6287 0.1225 0.031 Uiso 1 1 calc R . .
C11 C 0.3211(6) 0.6574(5) 0.0190(5) 0.0361(19) Uani 1 1 d . . .
H11A H 0.3612 0.7166 0.0453 0.043 Uiso 1 1 calc R . .
H11B H 0.2579 0.6666 -0.0038 0.043 Uiso 1 1 calc R . .
C12 C 0.3561(7) 0.5790(6) -0.0652(6) 0.045(2) Uani 1 1 d . . .
H12A H 0.3513 0.5942 -0.1164 0.054 Uiso 1 1 calc R . .
H12B H 0.4219 0.5751 -0.0443 0.054 Uiso 1 1 calc R . .
C13 C 0.3015(7) 0.4861(5) -0.1032(6) 0.044(2) Uani 1 1 d . . .
H13A H 0.3292 0.4365 -0.1531 0.052 Uiso 1 1 calc R . .
H13B H 0.2377 0.4873 -0.1326 0.052 Uiso 1 1 calc R . .
C14 C 0.2990(7) 0.4629(5) -0.0250(5) 0.039(2) Uani 1 1 d . . .
H14A H 0.2592 0.4033 -0.0519 0.047 Uiso 1 1 calc R . .
H14B H 0.3619 0.4545 -0.0005 0.047 Uiso 1 1 calc R . .
C15 C 0.2620(5) 0.5403(5) 0.0564(5) 0.0250(16) Uani 1 1 d . . .
H15 H 0.1975 0.5459 0.0312 0.030 Uiso 1 1 calc R . .
C16 C 0.1883(5) 0.4460(5) 0.1120(5) 0.0288(17) Uani 1 1 d . . .
H16A H 0.1351 0.4746 0.1400 0.035 Uiso 1 1 calc R . .
H16B H 0.1666 0.4066 0.0423 0.035 Uiso 1 1 calc R . .
C17 C 0.2268(5) 0.3872(5) 0.1519(5) 0.0254(16) Uani 1 1 d . . .
C18 C 0.2300(5) 0.2918(5) 0.0905(5) 0.0308(17) Uani 1 1 d . . .
H18A H 0.2028 0.2647 0.0250 0.037 Uiso 1 1 calc R . .
C19 C 0.2715(6) 0.2361(5) 0.1226(6) 0.0349(19) Uani 1 1 d . . .
C20 C 0.3139(5) 0.2784(5) 0.2177(6) 0.0303(17) Uani 1 1 d . . .
H20 H 0.3443 0.2415 0.2409 0.036 Uiso 1 1 calc R . .
C21 C 0.3131(5) 0.3725(5) 0.2798(5) 0.0244(15) Uani 1 1 d . . .
C22 C 0.2687(4) 0.4284(4) 0.2483(4) 0.0098(11) Uani 1 1 d . . .
C23 C 0.2741(8) 0.1331(5) 0.0560(7) 0.057(3) Uani 1 1 d . . .
H23A H 0.2130 0.0994 0.0395 0.086 Uiso 1 1 calc R . .
H23B H 0.3192 0.1090 0.0871 0.086 Uiso 1 1 calc R . .
H23C H 0.2919 0.1241 -0.0019 0.086 Uiso 1 1 calc R . .
C24 C 0.3527(5) 0.4123(5) 0.3836(5) 0.0269(16) Uani 1 1 d . . .
H24A H 0.3871 0.3660 0.3936 0.032 Uiso 1 1 calc R . .
H24B H 0.3958 0.4693 0.4079 0.032 Uiso 1 1 calc R . .
C25 C 0.2868(5) 0.4185(4) 0.5153(5) 0.0217(15) Uani 1 1 d . . .
H25A H 0.3490 0.4485 0.5571 0.026 Uiso 1 1 calc R . .
C26 C 0.2792(6) 0.3139(5) 0.4827(5) 0.0297(17) Uani 1 1 d . . .
H26A H 0.3285 0.2848 0.4477 0.036 Uiso 1 1 calc R . .
H26B H 0.2190 0.2829 0.4389 0.036 Uiso 1 1 calc R . .
C27 C 0.2880(5) 0.2992(5) 0.5683(6) 0.0331(18) Uani 1 1 d . . .
H27A H 0.2793 0.2313 0.5454 0.040 Uiso 1 1 calc R . .
H27B H 0.3506 0.3243 0.6086 0.040 Uiso 1 1 calc R . .
C28 C 0.2166(5) 0.3480(5) 0.6275(5) 0.0277(16) Uani 1 1 d . . .
H28A H 0.1540 0.3177 0.5897 0.033 Uiso 1 1 calc R . .
H28B H 0.2267 0.3415 0.6846 0.033 Uiso 1 1 calc R . .
C29 C 0.2237(5) 0.4516(5) 0.6579(5) 0.0275(16) Uani 1 1 d . . .
H29A H 0.2840 0.4831 0.7011 0.033 Uiso 1 1 calc R . .
H29B H 0.1747 0.4811 0.6931 0.033 Uiso 1 1 calc R . .
C30 C 0.2139(5) 0.4647(4) 0.5717(5) 0.0227(15) Uani 1 1 d . . .
H30 H 0.1518 0.4349 0.5299 0.027 Uiso 1 1 calc R . .
C31 C 0.1457(4) 0.6171(4) 0.6396(5) 0.0229(15) Uani 1 1 d . . .
H31A H 0.0993 0.6179 0.5892 0.027 Uiso 1 1 calc R . .
H31B H 0.1152 0.5865 0.6675 0.027 Uiso 1 1 calc R . .
C32 C 0.1853(5) 0.7151(5) 0.7148(5) 0.0232(15) Uani 1 1 d . . .
C33 C 0.1889(5) 0.7425(5) 0.8095(5) 0.0263(16) Uani 1 1 d . . .
H33 H 0.1639 0.6993 0.8238 0.032 Uiso 1 1 calc R . .
C34 C 0.2277(5) 0.8306(5) 0.8838(5) 0.0265(16) Uani 1 1 d . . .
C35 C 0.2630(5) 0.8909(5) 0.8588(5) 0.0255(16) Uani 1 1 d . . .
H35 H 0.2886 0.9522 0.9079 0.031 Uiso 1 1 calc R . .
C36 C 0.2625(4) 0.8657(5) 0.7652(5) 0.0209(14) Uani 1 1 d . . .
C37 C 0.2226(4) 0.7748(4) 0.6917(4) 0.0064(11) Uani 1 1 d U . .
C38 C 0.2292(6) 0.8613(5) 0.9863(5) 0.041(2) Uani 1 1 d . . .
H38A H 0.2904 0.8931 1.0249 0.061 Uiso 1 1 calc R . .
H38B H 0.2157 0.8064 0.9917 0.061 Uiso 1 1 calc R . .
H38C H 0.1827 0.9044 1.0088 0.061 Uiso 1 1 calc R . .
C39 C 0.2941(5) 0.9386(5) 0.7448(6) 0.0263(16) Uani 1 1 d . . .
H39A H 0.3140 0.9988 0.8049 0.032 Uiso 1 1 calc R . .
H39B H 0.3473 0.9193 0.7134 0.032 Uiso 1 1 calc R . .
C40 C 0.2123(5) 1.0462(4) 0.7006(5) 0.0217(15) Uani 1 1 d . . .
H40 H 0.2751 1.0717 0.7040 0.026 Uiso 1 1 calc R . .
C41 C 0.1827(6) 1.1120(5) 0.7938(6) 0.0370(19) Uani 1 1 d . . .
H41A H 0.1221 1.0860 0.7932 0.044 Uiso 1 1 calc R . .
H41B H 0.2279 1.1157 0.8475 0.044 Uiso 1 1 calc R . .
C42 C 0.1757(6) 1.2095(5) 0.8088(5) 0.0328(18) Uani 1 1 d . . .
H42A H 0.2373 1.2379 0.8146 0.039 Uiso 1 1 calc R . .
H42B H 0.1545 1.2491 0.8686 0.039 Uiso 1 1 calc R . .
C43 C 0.1079(5) 1.2061(5) 0.7253(5) 0.0296(17) Uani 1 1 d . . .
H43A H 0.0451 1.1830 0.7228 0.036 Uiso 1 1 calc R . .
H43B H 0.1065 1.2698 0.7345 0.036 Uiso 1 1 calc R . .
C44 C 0.1375(5) 1.1416(4) 0.6328(5) 0.0240(15) Uani 1 1 d . . .
H44A H 0.1972 1.1689 0.6330 0.029 Uiso 1 1 calc R . .
H44B H 0.0914 1.1372 0.5792 0.029 Uiso 1 1 calc R . .
C45 C 0.1471(4) 1.0430(4) 0.6173(5) 0.0199(14) Uani 1 1 d . . .
H45 H 0.0850 1.0148 0.6123 0.024 Uiso 1 1 calc R . .
C46 C 0.0435(7) 0.7657(7) 0.0712(8) 0.059(3) Uani 1 1 d . . .
H46A H 0.0626 0.8182 0.1365 0.088 Uiso 1 1 calc R . .
H46B H -0.0239 0.7535 0.0541 0.088 Uiso 1 1 calc R . .
H46C H 0.0657 0.7813 0.0278 0.088 Uiso 1 1 calc R . .
C47 C 0.4478(6) 0.6997(6) 0.8041(6) 0.046(2) Uani 1 1 d . . .
H47A H 0.5142 0.7199 0.8254 0.069 Uiso 1 1 calc R . .
H47B H 0.4246 0.6941 0.8531 0.069 Uiso 1 1 calc R . .
H47C H 0.4161 0.7460 0.7928 0.069 Uiso 1 1 calc R . .
C48 C 0.4138(6) 0.0912(6) 0.4999(7) 0.051(2) Uani 1 1 d . . .
H48A H 0.3861 0.1371 0.4853 0.077 Uiso 1 1 calc R . .
H48B H 0.4059 0.0301 0.4414 0.077 Uiso 1 1 calc R . .
H48C H 0.4797 0.1115 0.5274 0.077 Uiso 1 1 calc R . .
C49 C 0.4183(11) 0.2477(12) 0.9578(12) 0.126(6) Uani 1 1 d U . .
H49A H 0.4715 0.2939 1.0001 0.188 Uiso 1 1 calc R . .
H49B H 0.4089 0.2041 0.9801 0.188 Uiso 1 1 calc R . .
H49C H 0.3632 0.2799 0.9576 0.188 Uiso 1 1 calc R . .
C50 C 0.5174(10) 0.0424(12) 0.9319(10) 0.117(6) Uani 1 1 d . . .
H50A H 0.5741 0.0202 0.9501 0.176 Uiso 1 1 calc R . .
H50B H 0.4669 -0.0086 0.9010 0.176 Uiso 1 1 calc R . .
H50C H 0.5020 0.0948 0.9887 0.176 Uiso 1 1 calc R . .
C51 C 0.0610(6) 0.2642(6) 0.2350(6) 0.044(2) Uani 1 1 d . . .
H51A H 0.0502 0.3020 0.2045 0.066 Uiso 1 1 calc R . .
H51B H 0.0081 0.2169 0.2114 0.066 Uiso 1 1 calc R . .
H51C H 0.1167 0.2332 0.2201 0.066 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.02944(18) 0.01669(16) 0.01914(18) 0.01042(13) 0.00751(14) 0.00626(12)
Dy2 0.02316(17) 0.01607(15) 0.01922(18) 0.00997(13) 0.00672(13) 0.00526(12)
Dy3 0.02541(17) 0.01655(15) 0.02055(18) 0.01121(14) 0.00649(13) 0.00518(12)
N1 0.025(3) 0.017(3) 0.018(3) 0.006(2) 0.005(2) 0.004(2)
N2 0.040(3) 0.018(3) 0.018(3) 0.010(2) 0.013(3) 0.010(2)
N3 0.027(3) 0.020(3) 0.022(3) 0.012(3) 0.010(2) 0.007(2)
N4 0.025(3) 0.017(3) 0.017(3) 0.010(2) 0.006(2) 0.003(2)
N5 0.024(3) 0.013(3) 0.018(3) 0.007(2) 0.001(2) 0.001(2)
N6 0.022(3) 0.022(3) 0.023(3) 0.016(3) 0.008(2) 0.005(2)
N7 0.024(3) 0.048(4) 0.044(4) 0.033(4) 0.010(3) 0.012(3)
N8 0.027(3) 0.037(4) 0.044(4) 0.026(4) 0.011(3) 0.009(3)
N9 0.034(4) 0.043(4) 0.053(5) 0.028(4) 0.007(4) -0.003(3)
N10 0.026(4) 0.082(7) 0.087(7) 0.067(6) 0.004(4) 0.007(4)
O1 0.028(3) 0.016(2) 0.021(3) 0.009(2) 0.007(2) 0.0064(19)
O2 0.035(3) 0.018(2) 0.025(3) 0.011(2) 0.011(2) 0.009(2)
O3 0.028(3) 0.019(2) 0.025(3) 0.014(2) 0.009(2) 0.0055(19)
O4 0.025(3) 0.028(3) 0.032(3) 0.016(2) 0.007(2) 0.002(2)
O5 0.032(3) 0.028(3) 0.036(3) 0.017(2) 0.008(2) 0.004(2)
O6 0.023(2) 0.027(3) 0.034(3) 0.018(2) 0.002(2) 0.001(2)
O7 0.030(3) 0.029(3) 0.037(3) 0.022(2) 0.007(2) 0.005(2)
O8 0.025(3) 0.026(3) 0.032(3) 0.019(2) 0.007(2) 0.005(2)
O9 0.041(4) 0.045(4) 0.108(6) 0.051(4) -0.009(4) -0.014(3)
O10 0.073(5) 0.119(7) 0.066(5) 0.068(5) 0.049(4) 0.052(5)
O11 0.033(3) 0.029(3) 0.031(3) 0.018(2) 0.009(2) 0.010(2)
O12 0.062(4) 0.039(3) 0.053(4) 0.020(3) 0.022(3) 0.029(3)
O13 0.041(3) 0.060(4) 0.050(4) 0.039(3) 0.000(3) 0.005(3)
O14 0.023(2) 0.023(2) 0.025(3) 0.014(2) 0.008(2) 0.0059(19)
O15 0.025(2) 0.017(2) 0.020(3) 0.008(2) 0.008(2) 0.0066(18)
O16 0.098(6) 0.045(4) 0.106(7) 0.041(5) 0.029(5) -0.011(4)
O17 0.048(4) 0.051(4) 0.038(4) 0.020(3) -0.008(3) -0.011(3)
O18 0.065(5) 0.089(6) 0.054(4) 0.051(4) -0.007(4) -0.014(4)
O19 0.042(4) 0.052(4) 0.101(6) 0.050(5) 0.001(4) -0.004(3)
O20 0.119(7) 0.136(8) 0.108(7) 0.106(7) 0.018(6) 0.037(6)
O21 0.045(3) 0.045(4) 0.056(4) 0.034(3) 0.005(3) -0.002(3)
O22 0.069(4) 0.061(4) 0.035(4) 0.028(3) 0.004(3) 0.013(4)
O23 0.046(3) 0.030(3) 0.035(3) 0.019(3) -0.002(3) 0.006(2)
O24 0.039(3) 0.035(3) 0.052(4) 0.026(3) 0.015(3) 0.004(2)
O25 0.140(8) 0.148(8) 0.163(8) 0.068(7) 0.044(7) 0.018(6)
O26 0.081(6) 0.126(8) 0.059(6) 0.015(5) 0.018(5) -0.028(6)
O27 0.043(3) 0.030(3) 0.040(3) 0.021(3) 0.012(3) 0.001(2)
O28 0.055(5) 0.138(9) 0.128(9) 0.050(7) 0.005(5) -0.008(5)
C1 0.0090(14) 0.0096(14) 0.0076(14) 0.0046(10) 0.0011(9) 0.0015(9)
C2 0.023(3) 0.021(3) 0.017(4) 0.010(3) 0.001(3) 0.001(3)
C3 0.043(4) 0.015(3) 0.027(4) 0.010(3) 0.003(3) 0.011(3)
C4 0.063(5) 0.015(3) 0.020(4) 0.010(3) 0.012(4) 0.009(3)
C5 0.040(4) 0.022(4) 0.022(4) 0.014(3) 0.011(3) 0.003(3)
C6 0.025(4) 0.019(3) 0.016(3) 0.008(3) 0.004(3) -0.001(3)
C7 0.027(4) 0.020(3) 0.023(4) 0.010(3) 0.004(3) 0.003(3)
C8 0.027(4) 0.026(4) 0.016(4) 0.011(3) 0.002(3) -0.002(3)
C9 0.098(8) 0.033(5) 0.045(6) 0.030(4) 0.033(5) 0.021(5)
C10 0.041(4) 0.019(3) 0.017(4) 0.008(3) 0.009(3) 0.005(3)
C11 0.064(6) 0.024(4) 0.022(4) 0.011(3) 0.016(4) 0.004(4)
C12 0.073(6) 0.038(5) 0.029(5) 0.016(4) 0.023(4) 0.006(4)
C13 0.072(6) 0.031(4) 0.022(4) 0.006(4) 0.018(4) 0.005(4)
C14 0.070(6) 0.023(4) 0.024(4) 0.007(3) 0.019(4) 0.008(4)
C15 0.038(4) 0.019(3) 0.020(4) 0.012(3) 0.005(3) 0.008(3)
C16 0.039(4) 0.018(3) 0.027(4) 0.010(3) 0.008(3) 0.003(3)
C17 0.034(4) 0.021(3) 0.033(4) 0.020(3) 0.015(3) 0.008(3)
C18 0.050(5) 0.019(3) 0.025(4) 0.011(3) 0.012(4) 0.001(3)
C19 0.064(6) 0.017(4) 0.030(4) 0.012(3) 0.026(4) 0.009(3)
C20 0.047(5) 0.024(4) 0.039(5) 0.024(4) 0.027(4) 0.019(3)
C21 0.034(4) 0.024(3) 0.031(4) 0.020(3) 0.022(3) 0.013(3)
C22 0.016(3) 0.010(3) 0.007(3) 0.006(2) 0.007(2) 0.001(2)
C23 0.121(9) 0.019(4) 0.046(6) 0.018(4) 0.045(6) 0.024(5)
C24 0.028(4) 0.025(4) 0.034(4) 0.018(3) 0.014(3) 0.011(3)
C25 0.028(4) 0.017(3) 0.023(4) 0.012(3) 0.007(3) 0.003(3)
C26 0.043(4) 0.024(4) 0.029(4) 0.016(3) 0.014(3) 0.009(3)
C27 0.043(5) 0.023(4) 0.042(5) 0.022(4) 0.014(4) 0.011(3)
C28 0.037(4) 0.026(4) 0.030(4) 0.023(3) 0.004(3) 0.004(3)
C29 0.039(4) 0.025(4) 0.023(4) 0.016(3) 0.008(3) 0.001(3)
C30 0.033(4) 0.017(3) 0.022(4) 0.013(3) 0.007(3) 0.003(3)
C31 0.023(3) 0.022(3) 0.031(4) 0.019(3) 0.007(3) 0.007(3)
C32 0.028(4) 0.021(3) 0.021(4) 0.010(3) 0.007(3) 0.009(3)
C33 0.032(4) 0.023(4) 0.029(4) 0.015(3) 0.014(3) 0.010(3)
C34 0.041(4) 0.023(4) 0.016(4) 0.009(3) 0.007(3) 0.007(3)
C35 0.035(4) 0.022(3) 0.022(4) 0.012(3) 0.010(3) 0.011(3)
C36 0.023(3) 0.024(3) 0.022(4) 0.016(3) 0.004(3) 0.005(3)
C37 0.0065(14) 0.0067(13) 0.0059(14) 0.0034(10) 0.0004(9) 0.0019(9)
C38 0.069(6) 0.029(4) 0.024(4) 0.013(4) 0.011(4) 0.006(4)
C39 0.022(4) 0.033(4) 0.042(5) 0.029(4) 0.017(3) 0.016(3)
C40 0.026(4) 0.017(3) 0.019(4) 0.007(3) 0.004(3) 0.002(3)
C41 0.049(5) 0.034(4) 0.029(4) 0.015(4) 0.013(4) 0.016(4)
C42 0.047(5) 0.019(4) 0.025(4) 0.007(3) 0.005(4) 0.012(3)
C43 0.040(4) 0.016(3) 0.032(4) 0.010(3) 0.011(3) 0.012(3)
C44 0.029(4) 0.020(3) 0.025(4) 0.012(3) 0.006(3) 0.005(3)
C45 0.021(3) 0.016(3) 0.020(4) 0.007(3) 0.004(3) 0.006(3)
C46 0.053(6) 0.062(6) 0.073(7) 0.043(6) 0.012(5) 0.009(5)
C47 0.048(5) 0.044(5) 0.047(6) 0.022(4) 0.013(4) 0.005(4)
C48 0.054(6) 0.050(5) 0.077(7) 0.043(5) 0.043(5) 0.023(4)
C49 0.118(9) 0.126(9) 0.124(9) 0.055(7) 0.029(7) 0.008(7)
C50 0.089(11) 0.180(18) 0.061(9) 0.046(11) 0.011(8) 0.008(11)
C51 0.041(5) 0.037(5) 0.046(6) 0.014(4) 0.010(4) 0.008(4)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.340(4) . ?
Dy1 O15 2.360(4) . ?
Dy1 O2 2.367(4) . ?
Dy1 O14 2.368(5) . ?
Dy1 O5 2.388(5) . ?
Dy1 O11 2.412(5) . ?
Dy1 N2 2.475(5) . ?
Dy1 N1 2.523(6) . ?
Dy1 Dy2 3.4992(5) . ?
Dy1 Dy3 3.5473(5) . ?
Dy2 O1 2.354(5) . ?
Dy2 O15 2.357(4) . ?
Dy2 O3 2.358(4) . ?
Dy2 O14 2.367(5) . ?
Dy2 O4 2.376(5) . ?
Dy2 O8 2.412(5) . ?
Dy2 N5 2.497(5) . ?
Dy2 N6 2.504(5) . ?
Dy2 Dy3 3.5457(5) . ?
Dy3 O14 2.363(4) . ?
Dy3 O15 2.375(4) . ?
Dy3 O7 2.384(5) . ?
Dy3 O2 2.401(5) . ?
Dy3 O3 2.406(4) . ?
Dy3 O6 2.419(5) . ?
Dy3 N3 2.509(5) . ?
Dy3 N4 2.512(5) . ?
N1 C10 1.472(8) . ?
N1 C8 1.493(8) . ?
N2 C15 1.476(9) . ?
N2 C16 1.494(9) . ?
N3 C25 1.482(8) . ?
N3 C24 1.491(9) . ?
N4 C30 1.482(8) . ?
N4 C31 1.502(8) . ?
N5 C40 1.469(8) . ?
N5 C39 1.487(8) . ?
N6 C45 1.472(8) . ?
N6 C7 1.508(8) . ?
N7 O10 1.225(9) . ?
N7 O9 1.228(9) . ?
N7 O8 1.274(8) . ?
N8 O12 1.219(8) . ?
N8 O13 1.238(8) . ?
N8 O11 1.291(7) . ?
N9 O16 1.214(9) . ?
N9 O17 1.244(9) . ?
N9 O18 1.248(9) . ?
N10 O20 1.209(10) . ?
N10 O19 1.272(11) . ?
N10 O21 1.276(9) . ?
O1 C1 1.369(7) . ?
O2 C22 1.371(7) . ?
O3 C37 1.374(7) . ?
O22 C46 1.413(10) . ?
O23 C47 1.424(10) . ?
O24 C48 1.445(10) . ?
O25 C49 1.529(18) . ?
O26 C50 1.473(16) . ?
O27 C51 1.426(10) . ?
C1 C6 1.377(9) . ?
C1 C2 1.403(8) . ?
C2 C3 1.400(9) . ?
C2 C7 1.483(9) . ?
C3 C4 1.380(11) . ?
C4 C5 1.387(10) . ?
C4 C9 1.504(10) . ?
C5 C6 1.399(9) . ?
C6 C8 1.516(9) . ?
C10 C11 1.529(10) . ?
C10 C15 1.533(9) . ?
C11 C12 1.540(11) . ?
C12 C13 1.501(11) . ?
C13 C14 1.531(11) . ?
C14 C15 1.523(10) . ?
C16 C17 1.494(9) . ?
C17 C18 1.399(9) . ?
C17 C22 1.400(9) . ?
C18 C19 1.376(10) . ?
C19 C20 1.385(11) . ?
C19 C23 1.508(10) . ?
C20 C21 1.379(9) . ?
C21 C22 1.390(8) . ?
C21 C24 1.499(10) . ?
C25 C30 1.513(9) . ?
C25 C26 1.534(9) . ?
C26 C27 1.540(10) . ?
C27 C28 1.527(10) . ?
C28 C29 1.526(9) . ?
C29 C30 1.532(9) . ?
C31 C32 1.499(9) . ?
C32 C37 1.368(9) . ?
C32 C33 1.391(10) . ?
C33 C34 1.389(10) . ?
C34 C35 1.386(10) . ?
C34 C38 1.507(10) . ?
C35 C36 1.391(9) . ?
C36 C37 1.418(8) . ?
C36 C39 1.498(9) . ?
C40 C45 1.517(9) . ?
C40 C41 1.531(10) . ?
C41 C42 1.514(10) . ?
C42 C43 1.536(10) . ?
C43 C44 1.518(10) . ?
C44 C45 1.535(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O15 75.26(15) . . ?
O1 Dy1 O2 144.68(16) . . ?
O15 Dy1 O2 74.44(15) . . ?
O1 Dy1 O14 75.05(15) . . ?
O15 Dy1 O14 60.95(15) . . ?
O2 Dy1 O14 74.63(15) . . ?
O1 Dy1 O5 80.34(16) . . ?
O15 Dy1 O5 135.74(17) . . ?
O2 Dy1 O5 109.98(17) . . ?
O14 Dy1 O5 77.43(17) . . ?
O1 Dy1 O11 106.18(16) . . ?
O15 Dy1 O11 75.13(16) . . ?
O2 Dy1 O11 83.05(16) . . ?
O14 Dy1 O11 134.47(16) . . ?
O5 Dy1 O11 148.08(17) . . ?
O1 Dy1 N2 141.97(17) . . ?
O15 Dy1 N2 138.07(17) . . ?
O2 Dy1 N2 73.17(17) . . ?
O14 Dy1 N2 131.68(17) . . ?
O5 Dy1 N2 80.89(18) . . ?
O11 Dy1 N2 75.18(18) . . ?
O1 Dy1 N1 76.36(16) . . ?
O15 Dy1 N1 130.80(17) . . ?
O2 Dy1 N1 138.37(16) . . ?
O14 Dy1 N1 143.66(16) . . ?
O5 Dy1 N1 76.07(18) . . ?
O11 Dy1 N1 75.34(17) . . ?
N2 Dy1 N1 67.14(17) . . ?
O1 Dy1 Dy2 41.96(11) . . ?
O15 Dy1 Dy2 42.09(10) . . ?
O2 Dy1 Dy2 102.72(11) . . ?
O14 Dy1 Dy2 42.33(11) . . ?
O5 Dy1 Dy2 96.73(12) . . ?
O11 Dy1 Dy2 108.96(12) . . ?
N2 Dy1 Dy2 174.00(13) . . ?
N1 Dy1 Dy2 117.76(12) . . ?
O1 Dy1 Dy3 102.38(11) . . ?
O15 Dy1 Dy3 41.65(11) . . ?
O2 Dy1 Dy3 42.30(11) . . ?
O14 Dy1 Dy3 41.37(10) . . ?
O5 Dy1 Dy3 112.22(12) . . ?
O11 Dy1 Dy3 97.11(11) . . ?
N2 Dy1 Dy3 115.30(12) . . ?
N1 Dy1 Dy3 171.44(13) . . ?
Dy2 Dy1 Dy3 60.417(10) . . ?
O1 Dy2 O15 75.06(15) . . ?
O1 Dy2 O3 144.53(15) . . ?
O15 Dy2 O3 74.52(15) . . ?
O1 Dy2 O14 74.81(15) . . ?
O15 Dy2 O14 61.03(15) . . ?
O3 Dy2 O14 74.75(15) . . ?
O1 Dy2 O4 80.78(16) . . ?
O15 Dy2 O4 78.19(16) . . ?
O3 Dy2 O4 110.10(16) . . ?
O14 Dy2 O4 136.43(16) . . ?
O1 Dy2 O8 107.45(16) . . ?
O15 Dy2 O8 134.65(16) . . ?
O3 Dy2 O8 82.04(15) . . ?
O14 Dy2 O8 75.69(16) . . ?
O4 Dy2 O8 147.04(16) . . ?
O1 Dy2 N5 141.02(16) . . ?
O15 Dy2 N5 131.96(16) . . ?
O3 Dy2 N5 74.24(16) . . ?
O14 Dy2 N5 139.37(17) . . ?
O4 Dy2 N5 79.43(18) . . ?
O8 Dy2 N5 74.59(17) . . ?
O1 Dy2 N6 75.37(16) . . ?
O15 Dy2 N6 143.20(17) . . ?
O3 Dy2 N6 139.41(17) . . ?
O14 Dy2 N6 129.45(16) . . ?
O4 Dy2 N6 75.90(17) . . ?
O8 Dy2 N6 75.60(16) . . ?
N5 Dy2 N6 67.41(17) . . ?
O1 Dy2 Dy1 41.65(10) . . ?
O15 Dy2 Dy1 42.16(11) . . ?
O3 Dy2 Dy1 102.88(11) . . ?
O14 Dy2 Dy1 42.37(11) . . ?
O4 Dy2 Dy1 96.89(12) . . ?
O8 Dy2 Dy1 110.47(12) . . ?
N5 Dy2 Dy1 174.00(12) . . ?
N6 Dy2 Dy1 116.49(13) . . ?
O1 Dy2 Dy3 102.11(10) . . ?
O15 Dy2 Dy3 41.67(11) . . ?
O3 Dy2 Dy3 42.42(11) . . ?
O14 Dy2 Dy3 41.39(10) . . ?
O4 Dy2 Dy3 113.41(11) . . ?
O8 Dy2 Dy3 96.35(11) . . ?
N5 Dy2 Dy3 116.52(12) . . ?
N6 Dy2 Dy3 170.08(13) . . ?
Dy1 Dy2 Dy3 60.463(9) . . ?
O14 Dy3 O15 60.82(15) . . ?
O14 Dy3 O7 135.26(16) . . ?
O15 Dy3 O7 75.67(16) . . ?
O14 Dy3 O2 74.11(15) . . ?
O15 Dy3 O2 73.55(15) . . ?
O7 Dy3 O2 104.49(17) . . ?
O14 Dy3 O3 73.93(15) . . ?
O15 Dy3 O3 73.31(15) . . ?
O7 Dy3 O3 84.60(16) . . ?
O2 Dy3 O3 142.06(15) . . ?
O14 Dy3 O6 74.25(15) . . ?
O15 Dy3 O6 133.33(15) . . ?
O7 Dy3 O6 150.45(16) . . ?
O2 Dy3 O6 83.13(17) . . ?
O3 Dy3 O6 107.10(16) . . ?
O14 Dy3 N3 139.94(17) . . ?
O15 Dy3 N3 133.10(16) . . ?
O7 Dy3 N3 78.21(17) . . ?
O2 Dy3 N3 76.27(17) . . ?
O3 Dy3 N3 141.34(17) . . ?
O6 Dy3 N3 75.99(17) . . ?
O14 Dy3 N4 132.69(16) . . ?
O15 Dy3 N4 139.68(16) . . ?
O7 Dy3 N4 75.86(17) . . ?
O2 Dy3 N4 141.72(16) . . ?
O3 Dy3 N4 76.12(16) . . ?
O6 Dy3 N4 80.72(17) . . ?
N3 Dy3 N4 66.24(17) . . ?
O14 Dy3 Dy2 41.47(11) . . ?
O15 Dy3 Dy2 41.28(10) . . ?
O7 Dy3 Dy2 98.14(11) . . ?
O2 Dy3 Dy2 100.69(10) . . ?
O3 Dy3 Dy2 41.38(10) . . ?
O6 Dy3 Dy2 108.58(11) . . ?
N3 Dy3 Dy2 174.34(13) . . ?
N4 Dy3 Dy2 117.31(12) . . ?
O14 Dy3 Dy1 41.49(11) . . ?
O15 Dy3 Dy1 41.33(11) . . ?
O7 Dy3 Dy1 108.76(12) . . ?
O2 Dy3 Dy1 41.57(10) . . ?
O3 Dy3 Dy1 100.50(11) . . ?
O6 Dy3 Dy1 95.93(11) . . ?
N3 Dy3 Dy1 117.73(13) . . ?
N4 Dy3 Dy1 174.17(12) . . ?
Dy2 Dy3 Dy1 59.120(9) . . ?
C10 N1 C8 115.0(5) . . ?
C10 N1 Dy1 114.1(4) . . ?
C8 N1 Dy1 105.8(4) . . ?
C15 N2 C16 114.5(5) . . ?
C15 N2 Dy1 117.6(4) . . ?
C16 N2 Dy1 106.4(4) . . ?
C25 N3 C24 114.8(5) . . ?
C25 N3 Dy3 116.7(4) . . ?
C24 N3 Dy3 106.2(4) . . ?
C30 N4 C31 114.3(5) . . ?
C30 N4 Dy3 116.3(4) . . ?
C31 N4 Dy3 106.2(4) . . ?
C40 N5 C39 114.9(5) . . ?
C40 N5 Dy2 116.0(4) . . ?
C39 N5 Dy2 106.7(4) . . ?
C45 N6 C7 114.8(5) . . ?
C45 N6 Dy2 114.3(4) . . ?
C7 N6 Dy2 105.3(4) . . ?
O10 N7 O9 122.0(8) . . ?
O10 N7 O8 117.7(7) . . ?
O9 N7 O8 120.3(7) . . ?
O12 N8 O13 122.4(7) . . ?
O12 N8 O11 119.2(7) . . ?
O13 N8 O11 118.5(7) . . ?
O16 N9 O17 120.5(8) . . ?
O16 N9 O18 119.9(8) . . ?
O17 N9 O18 119.6(7) . . ?
O20 N10 O19 122.6(9) . . ?
O20 N10 O21 119.7(10) . . ?
O19 N10 O21 117.7(8) . . ?
C1 O1 Dy1 131.6(4) . . ?
C1 O1 Dy2 132.0(4) . . ?
Dy1 O1 Dy2 96.39(16) . . ?
C22 O2 Dy1 134.5(4) . . ?
C22 O2 Dy3 129.1(4) . . ?
Dy1 O2 Dy3 96.12(16) . . ?
C37 O3 Dy2 133.9(3) . . ?
C37 O3 Dy3 129.8(3) . . ?
Dy2 O3 Dy3 96.19(17) . . ?
N7 O8 Dy2 123.3(4) . . ?
N8 O11 Dy1 121.9(4) . . ?
Dy3 O14 Dy2 97.13(16) . . ?
Dy3 O14 Dy1 97.14(16) . . ?
Dy2 O14 Dy1 95.30(16) . . ?
Dy2 O15 Dy1 95.76(15) . . ?
Dy2 O15 Dy3 97.05(16) . . ?
Dy1 O15 Dy3 97.02(16) . . ?
O1 C1 C6 121.5(5) . . ?
O1 C1 C2 119.6(5) . . ?
C6 C1 C2 118.9(5) . . ?
C3 C2 C1 118.8(6) . . ?
C3 C2 C7 120.1(6) . . ?
C1 C2 C7 120.8(6) . . ?
C4 C3 C2 122.6(6) . . ?
C3 C4 C5 117.7(6) . . ?
C3 C4 C9 121.7(7) . . ?
C5 C4 C9 120.5(7) . . ?
C4 C5 C6 120.7(7) . . ?
C1 C6 C5 121.3(6) . . ?
C1 C6 C8 119.6(6) . . ?
C5 C6 C8 119.1(6) . . ?
C2 C7 N6 108.1(5) . . ?
N1 C8 C6 108.8(5) . . ?
N1 C10 C11 113.4(6) . . ?
N1 C10 C15 107.6(6) . . ?
C11 C10 C15 109.7(6) . . ?
C10 C11 C12 111.7(6) . . ?
C13 C12 C11 111.3(7) . . ?
C12 C13 C14 111.9(7) . . ?
C15 C14 C13 111.2(6) . . ?
N2 C15 C14 112.4(5) . . ?
N2 C15 C10 108.3(5) . . ?
C14 C15 C10 110.5(6) . . ?
C17 C16 N2 109.4(6) . . ?
C18 C17 C22 119.7(6) . . ?
C18 C17 C16 119.4(7) . . ?
C22 C17 C16 120.5(6) . . ?
C19 C18 C17 121.7(7) . . ?
C18 C19 C20 117.7(7) . . ?
C18 C19 C23 121.4(8) . . ?
C20 C19 C23 120.9(7) . . ?
C21 C20 C19 121.9(7) . . ?
C20 C21 C22 120.5(7) . . ?
C20 C21 C24 119.3(6) . . ?
C22 C21 C24 120.0(6) . . ?
O2 C22 C21 121.9(5) . . ?
O2 C22 C17 119.6(5) . . ?
C21 C22 C17 118.4(6) . . ?
N3 C24 C21 108.2(6) . . ?
N3 C25 C30 107.9(5) . . ?
N3 C25 C26 112.6(5) . . ?
C30 C25 C26 110.2(6) . . ?
C25 C26 C27 110.8(6) . . ?
C28 C27 C26 111.1(6) . . ?
C29 C28 C27 110.7(6) . . ?
C28 C29 C30 111.2(6) . . ?
N4 C30 C25 107.4(5) . . ?
N4 C30 C29 112.7(5) . . ?
C25 C30 C29 110.6(6) . . ?
C32 C31 N4 107.8(5) . . ?
C37 C32 C33 120.3(6) . . ?
C37 C32 C31 120.9(6) . . ?
C33 C32 C31 118.6(6) . . ?
C34 C33 C32 122.5(7) . . ?
C35 C34 C33 116.3(6) . . ?
C35 C34 C38 121.2(7) . . ?
C33 C34 C38 122.5(7) . . ?
C34 C35 C36 123.1(7) . . ?
C35 C36 C37 118.6(6) . . ?
C35 C36 C39 119.0(6) . . ?
C37 C36 C39 122.0(6) . . ?
C32 C37 O3 121.6(5) . . ?
C32 C37 C36 119.2(6) . . ?
O3 C37 C36 119.1(5) . . ?
N5 C39 C36 109.2(6) . . ?
N5 C40 C45 108.4(5) . . ?
N5 C40 C41 113.8(6) . . ?
C45 C40 C41 110.5(6) . . ?
C42 C41 C40 112.1(6) . . ?
C41 C42 C43 110.6(6) . . ?
C44 C43 C42 109.9(6) . . ?
C43 C44 C45 112.4(6) . . ?
N6 C45 C40 108.6(5) . . ?
N6 C45 C44 113.2(5) . . ?
C40 C45 C44 111.3(5) . . ?

_diffrn_measured_fraction_theta_max 0.980
_diffrn_reflns_theta_full        26.07
_diffrn_measured_fraction_theta_full 0.980
_refine_diff_density_max         2.361
_refine_diff_density_min         -1.362
_refine_diff_density_rms         0.246

#===END

data_2
#TrackingRef '- Dy3Mac.cif'

_database_code_depnum_ccdc_archive 'CCDC 871486'
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C52 H85 Dy3 N10 O12 S4'
_chemical_formula_weight         1658.04

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   16.9137(12)
_cell_length_b                   16.8688(12)
_cell_length_c                   29.163(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.316(1)
_cell_angle_gamma                90.00
_cell_volume                     8320.6(10)
_cell_formula_units_Z            4
_cell_measurement_temperature    185(2)
_cell_measurement_reflns_used    9890
_cell_measurement_theta_min      2.41
_cell_measurement_theta_max      25.99

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.21
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.324
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3300
_exptl_absorpt_coefficient_mu    2.815
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5396
_exptl_absorpt_correction_T_max  0.5894
_exptl_absorpt_process_details   '(Sadabs; bruker,2000)'

_exptl_special_details           
;
'comamands " isor 0.001 c1 c20 c21 and isor 0.01 s4 s4' s3 c36 c41 c42 c43 c52 c53 c51 c22" have been used to restrain the anisotropic displacement parameters of the corresponding atoms, and "dfix 1.43 0.01 c52 o9 c53 o10" have been used to restrain the lengths of methanol C-O'
;

_diffrn_ambient_temperature      185(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            44473
_diffrn_reflns_av_R_equivalents  0.0779
_diffrn_reflns_av_sigmaI/netI    0.1011
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         1.39
_diffrn_reflns_theta_max         26.02
_reflns_number_total             16330
_reflns_number_gt                9278
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1137P)^2^+110.7617P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16330
_refine_ls_number_parameters     755
_refine_ls_number_restraints     86
_refine_ls_R_factor_all          0.1408
_refine_ls_R_factor_gt           0.0805
_refine_ls_wR_factor_ref         0.2584
_refine_ls_wR_factor_gt          0.2235
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.013
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.37570(3) 0.24650(4) 0.13998(2) 0.02926(19) Uani 1 1 d . A .
Dy2 Dy 0.58032(3) 0.24114(4) 0.16435(2) 0.02893(19) Uani 1 1 d . A .
Dy3 Dy 0.44205(3) 0.23783(4) 0.25453(2) 0.03010(19) Uani 1 1 d . A .
N1 N 0.6739(6) 0.2599(8) 0.0977(4) 0.043(3) Uani 1 1 d . . .
H1 H 0.6719 0.2133 0.0806 0.051 Uiso 1 1 calc R . .
N2 N 0.7222(7) 0.2223(8) 0.1867(4) 0.045(3) Uani 1 1 d . . .
H2 H 0.7376 0.2686 0.2016 0.053 Uiso 1 1 calc R . .
N3 N 0.4952(6) 0.2518(7) 0.3361(4) 0.035(3) Uani 1 1 d . . .
H3 H 0.5172 0.2033 0.3444 0.043 Uiso 1 1 calc R . .
N4 N 0.3368(6) 0.2215(8) 0.3136(4) 0.042(3) Uani 1 1 d . . .
H4 H 0.3073 0.2680 0.3128 0.050 Uiso 1 1 calc R . .
N5 N 0.2288(6) 0.2661(8) 0.1256(4) 0.041(3) Uani 1 1 d . . .
H5 H 0.2040 0.2184 0.1325 0.049 Uiso 1 1 calc R . .
N6 N 0.3387(6) 0.2352(8) 0.0575(4) 0.041(3) Uani 1 1 d . . .
H6 H 0.3535 0.2830 0.0442 0.049 Uiso 1 1 calc R . .
N7 N 0.6057(7) 0.1058(8) 0.1373(4) 0.043(3) Uani 1 1 d . . .
N8 N 0.4656(7) 0.1030(9) 0.2820(5) 0.050(3) Uani 1 1 d . . .
N9 N 0.3656(7) 0.3838(8) 0.1155(4) 0.044(3) Uani 1 1 d . . .
N10 N 0.4075(8) 0.3710(9) 0.2756(5) 0.050(4) Uani 1 1 d . . .
O1 O 0.4982(5) 0.2463(5) 0.0988(3) 0.029(2) Uani 1 1 d . . .
O2 O 0.5811(5) 0.2382(6) 0.2470(3) 0.035(2) Uani 1 1 d . . .
O3 O 0.3180(5) 0.2409(5) 0.2143(3) 0.032(2) Uani 1 1 d . . .
O4 O 0.4667(5) 0.3123(5) 0.1871(3) 0.028(2) Uani 1 1 d . . .
H4B H 0.4676 0.3715 0.1883 0.033 Uiso 1 1 calc R A .
O5 O 0.4660(5) 0.1702(5) 0.1850(3) 0.029(2) Uani 1 1 d . . .
H5B H 0.4651 0.1110 0.1837 0.034 Uiso 1 1 calc R A .
O6 O 0.6265(6) 0.3740(7) 0.1748(4) 0.052(3) Uani 1 1 d . . .
O7 O 0.3267(5) 0.1142(6) 0.1339(3) 0.041(2) Uani 1 1 d . . .
O8 O 0.7688(8) 0.3951(10) 0.2130(5) 0.086(5) Uani 1 1 d . . .
H8 H 0.7800 0.4323 0.1951 0.129 Uiso 1 1 calc R . .
O9 O 0.4215(8) 1.0035(7) 0.1717(5) 0.067(4) Uani 1 1 d D . .
H9 H 0.4391 0.9808 0.1483 0.101 Uiso 1 1 calc R . .
O10 O 0.6583(10) -0.0258(14) 0.3555(7) 0.130(7) Uani 1 1 d D . .
H10 H 0.6092 -0.0233 0.3510 0.194 Uiso 1 1 calc R . .
O11 O 0.5178(11) 0.4892(10) 0.1838(7) 0.122(6) Uani 1 1 d . . .
O12 O 0.1679(8) 0.0859(10) 0.1327(7) 0.110(6) Uani 1 1 d . . .
S1 S 0.5645(5) -0.0418(5) 0.1029(3) 0.127(3) Uani 1 1 d . . .
S2 S 0.4693(3) -0.0204(4) 0.3453(2) 0.092(2) Uani 1 1 d . . .
C1 C 0.5134(5) 0.2473(6) 0.0514(3) 0.0064(18) Uani 1 1 d U . .
C2 C 0.4646(7) 0.2118(8) 0.0210(5) 0.032(3) Uani 1 1 d . . .
C3 C 0.4816(7) 0.2128(10) -0.0253(5) 0.038(4) Uani 1 1 d . . .
H3A H 0.4471 0.1859 -0.0459 0.046 Uiso 1 1 calc R . .
C4 C 0.5461(8) 0.2512(9) -0.0425(5) 0.038(3) Uani 1 1 d . . .
C5 C 0.5967(8) 0.2883(9) -0.0109(5) 0.039(4) Uani 1 1 d . . .
H5A H 0.6423 0.3154 -0.0214 0.047 Uiso 1 1 calc R . .
C6 C 0.5809(8) 0.2855(9) 0.0352(5) 0.035(3) Uani 1 1 d . . .
C7 C 0.5627(9) 0.2525(11) -0.0952(6) 0.054(5) Uani 1 1 d . . .
H7A H 0.5490 0.2010 -0.1086 0.080 Uiso 1 1 calc R . .
H7B H 0.6189 0.2634 -0.1004 0.080 Uiso 1 1 calc R . .
H7C H 0.5307 0.2940 -0.1098 0.080 Uiso 1 1 calc R . .
C8 C 0.6395(9) 0.3222(10) 0.0687(5) 0.045(4) Uani 1 1 d . . .
H8A H 0.6820 0.3495 0.0516 0.054 Uiso 1 1 calc R . .
H8B H 0.6124 0.3618 0.0881 0.054 Uiso 1 1 calc R . .
C9 C 0.7579(8) 0.2709(13) 0.1116(5) 0.060(5) Uani 1 1 d . . .
H9A H 0.7636 0.3251 0.1251 0.072 Uiso 1 1 calc R . .
C10 C 0.8169(10) 0.2630(14) 0.0722(6) 0.080(7) Uani 1 1 d . . .
H10A H 0.8112 0.2099 0.0581 0.096 Uiso 1 1 calc R . .
H10B H 0.8043 0.3030 0.0484 0.096 Uiso 1 1 calc R . .
C11 C 0.9028(10) 0.2742(17) 0.0879(8) 0.098(9) Uani 1 1 d . . .
H11A H 0.9390 0.2678 0.0616 0.117 Uiso 1 1 calc R . .
H11B H 0.9101 0.3280 0.1008 0.117 Uiso 1 1 calc R . .
C12 C 0.9204(9) 0.2137(17) 0.1234(6) 0.088(8) Uani 1 1 d . . .
H12A H 0.9755 0.2206 0.1342 0.106 Uiso 1 1 calc R . .
H12B H 0.9161 0.1603 0.1095 0.106 Uiso 1 1 calc R . .
C13 C 0.8654(9) 0.2182(15) 0.1643(6) 0.074(6) Uani 1 1 d . . .
H13A H 0.8731 0.2694 0.1803 0.089 Uiso 1 1 calc R . .
H13B H 0.8780 0.1749 0.1861 0.089 Uiso 1 1 calc R . .
C14 C 0.7787(8) 0.2108(12) 0.1482(5) 0.053(5) Uani 1 1 d . . .
H14 H 0.7706 0.1565 0.1352 0.064 Uiso 1 1 calc R . .
C15 C 0.7242(8) 0.1590(10) 0.2217(5) 0.043(4) Uani 1 1 d . . .
H15A H 0.7759 0.1317 0.2209 0.052 Uiso 1 1 calc R . .
H15B H 0.6823 0.1195 0.2151 0.052 Uiso 1 1 calc R . .
C16 C 0.7115(8) 0.1945(10) 0.2679(5) 0.040(4) Uani 1 1 d . . .
C17 C 0.7738(9) 0.1914(12) 0.2990(5) 0.056(5) Uani 1 1 d . . .
H17 H 0.8195 0.1610 0.2921 0.068 Uiso 1 1 calc R . .
C18 C 0.7695(8) 0.2333(12) 0.3409(5) 0.059(5) Uani 1 1 d . . .
C19 C 0.6985(9) 0.2691(11) 0.3518(6) 0.055(5) Uani 1 1 d . . .
H19 H 0.6923 0.2930 0.3811 0.067 Uiso 1 1 calc R . .
C20 C 0.6418(5) 0.2352(6) 0.2782(3) 0.0085(19) Uani 1 1 d U . .
C21 C 0.8395(10) 0.2352(10) 0.3718(6) 0.055(4) Uani 1 1 d U . .
H21A H 0.8259 0.2629 0.4002 0.082 Uiso 1 1 calc R . .
H21B H 0.8829 0.2630 0.3566 0.082 Uiso 1 1 calc R . .
H21C H 0.8559 0.1808 0.3789 0.082 Uiso 1 1 calc R . .
C22 C 0.6366(9) 0.2707(10) 0.3210(6) 0.051(4) Uani 1 1 d U . .
C23 C 0.5612(8) 0.3118(10) 0.3351(5) 0.049(4) Uani 1 1 d . . .
H23A H 0.5680 0.3360 0.3658 0.059 Uiso 1 1 calc R . .
H23B H 0.5483 0.3545 0.3130 0.059 Uiso 1 1 calc R . .
C24 C 0.4339(8) 0.2706(12) 0.3697(5) 0.050(5) Uani 1 1 d . . .
H24 H 0.4150 0.3260 0.3644 0.061 Uiso 1 1 calc R . .
C25 C 0.4593(9) 0.2618(14) 0.4194(6) 0.078(7) Uani 1 1 d . . .
H25A H 0.5053 0.2967 0.4252 0.094 Uiso 1 1 calc R . .
H25B H 0.4764 0.2065 0.4248 0.094 Uiso 1 1 calc R . .
C26 C 0.3942(10) 0.2824(16) 0.4535(7) 0.090(8) Uani 1 1 d . . .
H26A H 0.3770 0.3380 0.4493 0.108 Uiso 1 1 calc R . .
H26B H 0.4138 0.2759 0.4854 0.108 Uiso 1 1 calc R . .
C27 C 0.3252(10) 0.2259(15) 0.4443(6) 0.077(7) Uani 1 1 d . . .
H27A H 0.2810 0.2389 0.4651 0.093 Uiso 1 1 calc R . .
H27B H 0.3421 0.1708 0.4509 0.093 Uiso 1 1 calc R . .
C28 C 0.2964(10) 0.2317(13) 0.3938(6) 0.071(6) Uani 1 1 d . . .
H28A H 0.2525 0.1938 0.3886 0.085 Uiso 1 1 calc R . .
H28B H 0.2765 0.2858 0.3876 0.085 Uiso 1 1 calc R . .
C29 C 0.3647(7) 0.2126(12) 0.3615(5) 0.048(4) Uani 1 1 d . . .
H29 H 0.3830 0.1570 0.3668 0.058 Uiso 1 1 calc R . .
C30 C 0.2821(8) 0.1571(10) 0.2976(5) 0.046(4) Uani 1 1 d . . .
H30A H 0.2571 0.1303 0.3241 0.056 Uiso 1 1 calc R . .
H30B H 0.3110 0.1171 0.2793 0.056 Uiso 1 1 calc R . .
C31 C 0.2194(7) 0.1997(9) 0.2679(4) 0.036(3) Uani 1 1 d . . .
C32 C 0.1413(8) 0.1993(9) 0.2817(5) 0.041(4) Uani 1 1 d . . .
H32 H 0.1273 0.1708 0.3085 0.049 Uiso 1 1 calc R . .
C33 C 0.0847(8) 0.2380(9) 0.2581(5) 0.039(4) Uani 1 1 d . . .
C34 C 0.1042(8) 0.2793(10) 0.2199(6) 0.048(4) Uani 1 1 d . . .
H34 H 0.0645 0.3070 0.2032 0.058 Uiso 1 1 calc R . .
C35 C 0.1839(8) 0.2810(9) 0.2049(5) 0.038(4) Uani 1 1 d . . .
C36 C 0.2409(6) 0.2404(6) 0.2287(3) 0.014(2) Uani 1 1 d U . .
C37 C -0.0036(9) 0.2414(12) 0.2739(6) 0.061(5) Uani 1 1 d . . .
H37A H -0.0167 0.1925 0.2904 0.091 Uiso 1 1 calc R . .
H37B H -0.0382 0.2466 0.2470 0.091 Uiso 1 1 calc R . .
H37C H -0.0111 0.2870 0.2942 0.091 Uiso 1 1 calc R . .
C38 C 0.2044(8) 0.3246(9) 0.1616(5) 0.044(4) Uani 1 1 d . . .
H38A H 0.1581 0.3553 0.1507 0.053 Uiso 1 1 calc R . .
H38B H 0.2482 0.3622 0.1677 0.053 Uiso 1 1 calc R . .
C39 C 0.2081(8) 0.2856(12) 0.0778(5) 0.056(5) Uani 1 1 d . . .
H39 H 0.2263 0.3406 0.0708 0.068 Uiso 1 1 calc R . .
C40 C 0.1201(9) 0.2797(16) 0.0685(6) 0.087(8) Uani 1 1 d . . .
H40A H 0.1020 0.2250 0.0748 0.104 Uiso 1 1 calc R . .
H40B H 0.0916 0.3160 0.0893 0.104 Uiso 1 1 calc R . .
C41 C 0.1013(13) 0.3009(16) 0.0198(8) 0.097(7) Uani 1 1 d U . .
H41A H 0.0439 0.2946 0.0141 0.116 Uiso 1 1 calc R . .
H41B H 0.1156 0.3569 0.0141 0.116 Uiso 1 1 calc R . .
C42 C 0.1460(14) 0.2490(15) -0.0114(9) 0.096(7) Uani 1 1 d U . .
H42A H 0.1357 0.2658 -0.0434 0.115 Uiso 1 1 calc R . .
H42B H 0.1265 0.1939 -0.0081 0.115 Uiso 1 1 calc R . .
C43 C 0.2338(12) 0.2501(13) -0.0027(7) 0.075(6) Uani 1 1 d U . .
H43A H 0.2546 0.3038 -0.0090 0.090 Uiso 1 1 calc R . .
H43B H 0.2600 0.2125 -0.0238 0.090 Uiso 1 1 calc R . .
C44 C 0.2539(8) 0.2269(13) 0.0478(5) 0.058(5) Uani 1 1 d . . .
H44 H 0.2362 0.1714 0.0542 0.069 Uiso 1 1 calc R . .
C45 C 0.3901(8) 0.1748(9) 0.0367(5) 0.037(3) Uani 1 1 d . . .
H45A H 0.3626 0.1499 0.0103 0.045 Uiso 1 1 calc R . .
H45B H 0.4021 0.1329 0.0595 0.045 Uiso 1 1 calc R . .
C46 C 0.5910(10) 0.0448(11) 0.1239(6) 0.055(5) Uani 1 1 d . . .
C47 C 0.4683(9) 0.0499(12) 0.3070(6) 0.053(4) Uani 1 1 d . . .
C48 C 0.3574(12) 0.4466(12) 0.1064(6) 0.065(5) Uani 1 1 d . . .
C51 C 0.7828(15) 0.4210(15) 0.2613(8) 0.107(8) Uani 1 1 d U . .
H51A H 0.8369 0.4411 0.2645 0.160 Uiso 1 1 calc R . .
H51B H 0.7754 0.3759 0.2820 0.160 Uiso 1 1 calc R . .
H51C H 0.7453 0.4631 0.2692 0.160 Uiso 1 1 calc R . .
C52 C 0.3876(12) 0.9458(11) 0.2019(7) 0.082(6) Uani 1 1 d DU . .
H52A H 0.4271 0.9051 0.2091 0.123 Uiso 1 1 calc R . .
H52B H 0.3418 0.9211 0.1869 0.123 Uiso 1 1 calc R . .
H52C H 0.3708 0.9718 0.2303 0.123 Uiso 1 1 calc R . .
C53 C 0.683(2) 0.0402(19) 0.3836(13) 0.197(17) Uani 1 1 d DU . .
H53A H 0.7115 0.0205 0.4106 0.296 Uiso 1 1 calc R . .
H53B H 0.6366 0.0704 0.3933 0.296 Uiso 1 1 calc R . .
H53C H 0.7180 0.0747 0.3658 0.296 Uiso 1 1 calc R . .
S3 S 0.3368(7) 0.5387(5) 0.0903(3) 0.154(3) Uani 1 1 d U . .
S4 S 0.4496(9) 0.5379(8) 0.2908(5) 0.102(4) Uani 0.50 1 d PU A 1
S4' S 0.3269(9) 0.5063(9) 0.2502(6) 0.118(5) Uani 0.50 1 d PU B 2
C49 C 0.424(3) 0.443(3) 0.2811(13) 0.060(11) Uani 0.50 1 d P A 1
C49' C 0.372(2) 0.423(3) 0.2666(15) 0.059(11) Uani 0.50 1 d P B 2

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Dy1 0.0208(3) 0.0395(4) 0.0274(3) 0.0035(3) -0.0007(2) -0.0022(3)
Dy2 0.0196(3) 0.0415(4) 0.0257(3) -0.0028(3) 0.0011(2) -0.0040(3)
Dy3 0.0196(3) 0.0447(4) 0.0260(3) -0.0006(3) 0.0010(2) -0.0001(3)
N1 0.027(6) 0.080(10) 0.021(6) -0.001(6) -0.004(5) -0.003(6)
N2 0.037(6) 0.073(10) 0.024(6) -0.008(6) 0.007(5) -0.006(6)
N3 0.020(5) 0.055(8) 0.031(6) -0.007(6) 0.000(4) -0.005(5)
N4 0.023(5) 0.076(10) 0.026(6) 0.005(6) 0.002(5) -0.007(6)
N5 0.009(5) 0.071(9) 0.043(7) 0.012(7) -0.002(5) 0.002(5)
N6 0.030(6) 0.059(9) 0.034(7) 0.004(6) -0.004(5) -0.001(6)
N7 0.030(6) 0.054(9) 0.044(8) -0.010(7) -0.006(6) -0.004(6)
N8 0.045(8) 0.059(10) 0.046(9) 0.006(7) 0.003(6) 0.014(7)
N9 0.043(7) 0.036(8) 0.052(9) 0.008(6) -0.005(6) 0.005(6)
N10 0.051(8) 0.052(10) 0.047(9) -0.004(7) 0.014(7) 0.022(8)
O1 0.024(4) 0.039(6) 0.024(5) 0.000(4) 0.001(4) 0.000(4)
O2 0.016(4) 0.057(7) 0.032(5) -0.001(5) 0.007(4) 0.005(4)
O3 0.020(4) 0.048(6) 0.027(5) 0.004(4) -0.009(4) -0.003(4)
O4 0.024(4) 0.024(5) 0.036(5) -0.001(4) 0.005(4) -0.004(4)
O5 0.026(4) 0.027(5) 0.033(5) 0.000(4) 0.001(4) -0.001(4)
O6 0.039(6) 0.066(8) 0.050(7) -0.010(6) 0.004(5) -0.023(5)
O7 0.031(5) 0.056(7) 0.034(6) 0.005(5) -0.001(4) -0.009(5)
O8 0.064(8) 0.126(14) 0.068(10) -0.006(9) -0.009(7) -0.038(9)
O9 0.063(8) 0.062(8) 0.077(10) 0.021(7) 0.012(7) 0.001(7)
O10 0.087(12) 0.19(2) 0.111(15) -0.025(14) -0.001(11) 0.052(13)
O11 0.128(15) 0.090(13) 0.148(17) 0.015(11) 0.015(12) -0.012(11)
O12 0.049(8) 0.099(12) 0.181(18) 0.003(12) 0.003(9) -0.009(8)
S1 0.124(6) 0.097(5) 0.160(8) -0.067(5) 0.036(5) -0.034(5)
S2 0.074(3) 0.089(4) 0.113(5) 0.050(4) -0.007(3) -0.015(3)
C1 0.007(2) 0.006(2) 0.006(2) 0.0004(10) 0.0000(10) 0.0001(10)
C2 0.025(6) 0.032(8) 0.039(8) 0.001(6) 0.000(6) 0.004(6)
C3 0.024(6) 0.061(10) 0.031(8) 0.001(7) 0.004(6) -0.003(7)
C4 0.034(7) 0.052(10) 0.030(7) 0.012(7) 0.002(6) 0.008(7)
C5 0.022(6) 0.063(10) 0.033(8) 0.001(7) 0.009(6) 0.001(7)
C6 0.030(7) 0.047(9) 0.029(8) -0.003(6) 0.003(6) -0.001(6)
C7 0.033(8) 0.084(14) 0.044(9) 0.010(9) 0.011(7) 0.006(8)
C8 0.041(8) 0.060(11) 0.032(8) 0.004(7) -0.003(7) -0.015(8)
C9 0.030(7) 0.123(17) 0.027(8) -0.004(9) 0.010(6) -0.018(9)
C10 0.039(9) 0.16(2) 0.041(10) -0.011(12) 0.020(8) -0.014(11)
C11 0.032(9) 0.20(3) 0.063(14) -0.020(16) 0.012(9) -0.022(13)
C12 0.027(8) 0.20(3) 0.040(11) -0.017(14) 0.000(8) 0.005(12)
C13 0.036(9) 0.14(2) 0.045(11) -0.009(12) -0.005(8) 0.002(11)
C14 0.025(7) 0.104(15) 0.031(9) 0.002(9) -0.002(6) 0.001(8)
C15 0.028(7) 0.064(11) 0.037(9) -0.003(8) -0.002(6) 0.004(7)
C16 0.026(7) 0.071(11) 0.022(7) 0.002(7) 0.004(6) -0.013(7)
C17 0.033(8) 0.103(15) 0.034(9) -0.006(9) -0.007(7) 0.010(9)
C18 0.020(7) 0.126(17) 0.031(8) -0.010(9) 0.007(6) -0.008(8)
C19 0.027(7) 0.085(14) 0.054(10) -0.018(9) 0.003(7) -0.006(8)
C20 0.008(2) 0.009(2) 0.008(2) 0.0000(10) 0.0003(10) -0.0004(10)
C21 0.055(4) 0.055(4) 0.055(4) -0.0003(10) -0.0004(10) 0.0003(10)
C22 0.037(6) 0.065(8) 0.050(7) -0.012(6) 0.006(6) -0.008(6)
C23 0.039(8) 0.071(12) 0.036(9) -0.011(8) -0.005(7) 0.005(8)
C24 0.024(7) 0.100(14) 0.027(8) -0.014(8) 0.008(6) -0.013(8)
C25 0.022(7) 0.18(2) 0.033(9) 0.001(12) -0.009(6) -0.011(10)
C26 0.043(10) 0.18(2) 0.053(12) 0.010(14) 0.008(9) -0.027(13)
C27 0.041(9) 0.16(2) 0.031(9) 0.002(11) 0.000(8) -0.010(11)
C28 0.044(9) 0.112(17) 0.057(12) -0.010(11) 0.022(9) -0.015(10)
C29 0.018(6) 0.099(14) 0.028(8) 0.001(8) -0.003(6) -0.001(7)
C30 0.024(7) 0.070(12) 0.045(10) 0.001(8) 0.007(7) -0.003(7)
C31 0.024(6) 0.064(10) 0.020(7) -0.008(7) 0.000(5) -0.013(7)
C32 0.030(7) 0.052(10) 0.041(9) -0.011(7) 0.008(6) -0.011(7)
C33 0.022(6) 0.062(11) 0.033(8) -0.003(7) 0.004(6) -0.008(7)
C34 0.019(6) 0.061(11) 0.065(11) -0.016(9) 0.009(7) 0.012(7)
C35 0.025(7) 0.058(10) 0.030(8) -0.009(7) 0.000(6) 0.000(7)
C36 0.018(4) 0.017(5) 0.006(4) -0.007(4) 0.000(4) -0.007(4)
C37 0.033(8) 0.103(16) 0.046(10) -0.016(10) 0.004(7) 0.007(9)
C38 0.032(7) 0.049(10) 0.052(10) 0.011(8) -0.002(7) 0.014(7)
C39 0.029(7) 0.101(15) 0.039(9) 0.026(9) -0.002(7) 0.002(9)
C40 0.019(7) 0.19(2) 0.049(11) 0.024(13) -0.006(7) 0.020(11)
C41 0.078(10) 0.119(11) 0.093(11) 0.009(9) -0.004(8) 0.009(8)
C42 0.083(10) 0.121(11) 0.084(10) -0.003(8) -0.007(8) -0.002(8)
C43 0.065(8) 0.106(10) 0.054(8) 0.006(8) 0.002(7) 0.002(8)
C44 0.014(6) 0.123(16) 0.036(9) 0.005(9) -0.003(6) -0.001(8)
C45 0.034(7) 0.052(10) 0.026(8) -0.006(7) -0.004(6) -0.009(7)
C46 0.050(10) 0.054(12) 0.062(12) -0.018(9) 0.002(9) -0.005(9)
C47 0.044(9) 0.073(13) 0.043(10) 0.003(9) -0.015(8) -0.004(9)
C48 0.085(14) 0.050(12) 0.059(12) 0.003(9) 0.024(10) -0.017(11)
C51 0.117(11) 0.103(11) 0.100(11) -0.016(9) 0.001(9) -0.017(9)
C52 0.085(9) 0.084(10) 0.077(9) 0.025(8) -0.005(8) 0.000(8)
C53 0.191(19) 0.194(19) 0.207(19) -0.004(10) 0.002(10) -0.013(10)
S3 0.217(7) 0.088(5) 0.157(7) 0.040(5) 0.068(6) 0.026(5)
S4 0.117(8) 0.086(7) 0.103(8) -0.010(6) 0.023(6) 0.004(6)
S4' 0.118(8) 0.105(8) 0.133(9) 0.034(7) 0.027(7) 0.029(7)
C49 0.07(3) 0.07(3) 0.05(2) 0.009(19) 0.02(2) 0.04(2)
C49' 0.05(2) 0.06(3) 0.07(3) 0.00(2) 0.04(2) 0.01(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O4 2.338(8) . ?
Dy1 O3 2.384(9) . ?
Dy1 O5 2.384(8) . ?
Dy1 O7 2.387(10) . ?
Dy1 O1 2.402(8) . ?
Dy1 N9 2.430(13) . ?
Dy1 N6 2.491(11) . ?
Dy1 N5 2.540(10) . ?
Dy1 Dy3 3.5210(9) . ?
Dy1 Dy2 3.5304(8) . ?
Dy2 O5 2.355(8) . ?
Dy2 O1 2.359(8) . ?
Dy2 O4 2.365(8) . ?
Dy2 O6 2.393(11) . ?
Dy2 O2 2.411(9) . ?
Dy2 N7 2.454(14) . ?
Dy2 N2 2.503(12) . ?
Dy2 N1 2.534(11) . ?
Dy2 Dy3 3.5295(8) . ?
Dy3 O2 2.363(8) . ?
Dy3 O5 2.364(9) . ?
Dy3 O4 2.372(9) . ?
Dy3 O3 2.398(8) . ?
Dy3 N10 2.402(14) . ?
Dy3 N8 2.443(14) . ?
Dy3 N4 2.499(11) . ?
Dy3 N3 2.550(11) . ?
N1 C8 1.467(19) . ?
N1 C9 1.487(18) . ?
N2 C15 1.476(19) . ?
N2 C14 1.492(18) . ?
N3 C24 1.465(17) . ?
N3 C23 1.508(19) . ?
N4 C29 1.481(18) . ?
N4 C30 1.499(19) . ?
N5 C39 1.473(19) . ?
N5 C38 1.501(19) . ?
N6 C44 1.466(16) . ?
N6 C45 1.472(18) . ?
N7 C46 1.128(19) . ?
N8 C47 1.16(2) . ?
N9 C48 1.10(2) . ?
N10 C49' 1.10(4) . ?
N10 C49 1.26(5) . ?
O1 C1 1.405(12) . ?
O2 C20 1.368(13) . ?
O3 C36 1.372(13) . ?
O8 C51 1.49(3) . ?
O9 C52 1.434(9) . ?
O10 C53 1.443(10) . ?
S1 C46 1.645(19) . ?
S2 C47 1.630(19) . ?
C1 C2 1.349(16) . ?
C1 C6 1.397(16) . ?
C2 C3 1.383(19) . ?
C2 C45 1.480(18) . ?
C3 C4 1.367(19) . ?
C4 C5 1.40(2) . ?
C4 C7 1.56(2) . ?
C5 C6 1.372(19) . ?
C6 C8 1.520(19) . ?
C9 C14 1.51(2) . ?
C9 C10 1.53(2) . ?
C10 C11 1.53(2) . ?
C11 C12 1.48(3) . ?
C12 C13 1.52(2) . ?
C13 C14 1.54(2) . ?
C15 C16 1.492(19) . ?
C16 C17 1.388(19) . ?
C16 C20 1.398(17) . ?
C17 C18 1.41(2) . ?
C18 C19 1.38(2) . ?
C18 C21 1.48(2) . ?
C19 C22 1.38(2) . ?
C20 C22 1.388(19) . ?
C22 C23 1.51(2) . ?
C24 C25 1.52(2) . ?
C24 C29 1.54(2) . ?
C25 C26 1.53(2) . ?
C26 C27 1.53(3) . ?
C27 C28 1.55(3) . ?
C28 C29 1.53(2) . ?
C30 C31 1.54(2) . ?
C31 C32 1.382(18) . ?
C31 C36 1.385(17) . ?
C32 C33 1.34(2) . ?
C33 C34 1.36(2) . ?
C33 C37 1.568(19) . ?
C34 C35 1.419(18) . ?
C35 C36 1.369(18) . ?
C35 C38 1.50(2) . ?
C39 C40 1.51(2) . ?
C39 C44 1.53(2) . ?
C40 C41 1.50(3) . ?
C41 C42 1.47(3) . ?
C42 C43 1.51(3) . ?
C43 C44 1.56(2) . ?
C48 S3 1.66(2) . ?
S4 C49 1.68(5) . ?
S4' C49' 1.66(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Dy1 O3 75.8(3) . . ?
O4 Dy1 O5 61.0(3) . . ?
O3 Dy1 O5 75.1(3) . . ?
O4 Dy1 O7 135.6(3) . . ?
O3 Dy1 O7 83.5(3) . . ?
O5 Dy1 O7 75.9(3) . . ?
O4 Dy1 O1 74.2(3) . . ?
O3 Dy1 O1 144.5(3) . . ?
O5 Dy1 O1 73.9(3) . . ?
O7 Dy1 O1 105.2(3) . . ?
O4 Dy1 N9 76.4(4) . . ?
O3 Dy1 N9 106.1(4) . . ?
O5 Dy1 N9 136.1(4) . . ?
O7 Dy1 N9 147.8(4) . . ?
O1 Dy1 N9 85.0(4) . . ?
O4 Dy1 N6 140.0(3) . . ?
O3 Dy1 N6 140.7(3) . . ?
O5 Dy1 N6 130.3(3) . . ?
O7 Dy1 N6 76.8(4) . . ?
O1 Dy1 N6 74.3(3) . . ?
N9 Dy1 N6 76.8(4) . . ?
O4 Dy1 N5 132.5(4) . . ?
O3 Dy1 N5 75.5(3) . . ?
O5 Dy1 N5 141.7(3) . . ?
O7 Dy1 N5 76.8(4) . . ?
O1 Dy1 N5 139.8(3) . . ?
N9 Dy1 N5 76.1(4) . . ?
N6 Dy1 N5 67.0(4) . . ?
O4 Dy1 Dy3 42.0(2) . . ?
O3 Dy1 Dy3 42.75(19) . . ?
O5 Dy1 Dy3 41.9(2) . . ?
O7 Dy1 Dy3 98.1(2) . . ?
O1 Dy1 Dy3 101.7(2) . . ?
N9 Dy1 Dy3 109.9(3) . . ?
N6 Dy1 Dy3 172.1(3) . . ?
N5 Dy1 Dy3 118.0(3) . . ?
O4 Dy1 Dy2 41.6(2) . . ?
O3 Dy1 Dy2 102.81(19) . . ?
O5 Dy1 Dy2 41.5(2) . . ?
O7 Dy1 Dy2 109.3(2) . . ?
O1 Dy1 Dy2 41.7(2) . . ?
N9 Dy1 Dy2 98.7(3) . . ?
N6 Dy1 Dy2 115.7(3) . . ?
N5 Dy1 Dy2 173.6(3) . . ?
Dy3 Dy1 Dy2 60.071(16) . . ?
O5 Dy2 O1 75.2(3) . . ?
O5 Dy2 O4 61.1(3) . . ?
O1 Dy2 O4 74.5(3) . . ?
O5 Dy2 O6 135.3(3) . . ?
O1 Dy2 O6 105.0(3) . . ?
O4 Dy2 O6 75.7(3) . . ?
O5 Dy2 O2 74.6(3) . . ?
O1 Dy2 O2 144.2(3) . . ?
O4 Dy2 O2 74.3(3) . . ?
O6 Dy2 O2 83.8(3) . . ?
O5 Dy2 N7 75.8(3) . . ?
O1 Dy2 N7 82.9(4) . . ?
O4 Dy2 N7 135.0(3) . . ?
O6 Dy2 N7 148.7(4) . . ?
O2 Dy2 N7 107.6(4) . . ?
O5 Dy2 N2 131.0(4) . . ?
O1 Dy2 N2 140.8(3) . . ?
O4 Dy2 N2 140.4(4) . . ?
O6 Dy2 N2 76.9(4) . . ?
O2 Dy2 N2 74.8(3) . . ?
N7 Dy2 N2 78.2(4) . . ?
O5 Dy2 N1 141.0(3) . . ?
O1 Dy2 N1 75.0(3) . . ?
O4 Dy2 N1 131.6(4) . . ?
O6 Dy2 N1 77.1(4) . . ?
O2 Dy2 N1 140.4(3) . . ?
N7 Dy2 N1 76.0(4) . . ?
N2 Dy2 N1 67.3(4) . . ?
O5 Dy2 Dy3 41.7(2) . . ?
O1 Dy2 Dy3 102.4(2) . . ?
O4 Dy2 Dy3 41.9(2) . . ?
O6 Dy2 Dy3 97.9(2) . . ?
O2 Dy2 Dy3 41.80(19) . . ?
N7 Dy2 Dy3 110.1(3) . . ?
N2 Dy2 Dy3 116.2(3) . . ?
N1 Dy2 Dy3 173.3(3) . . ?
O5 Dy2 Dy1 42.2(2) . . ?
O1 Dy2 Dy1 42.6(2) . . ?
O4 Dy2 Dy1 41.1(2) . . ?
O6 Dy2 Dy1 108.7(3) . . ?
O2 Dy2 Dy1 101.63(19) . . ?
N7 Dy2 Dy1 97.6(3) . . ?
N2 Dy2 Dy1 173.1(3) . . ?
N1 Dy2 Dy1 117.3(2) . . ?
Dy3 Dy2 Dy1 59.833(17) . . ?
O2 Dy3 O5 75.3(3) . . ?
O2 Dy3 O4 75.1(3) . . ?
O5 Dy3 O4 60.8(3) . . ?
O2 Dy3 O3 145.4(3) . . ?
O5 Dy3 O3 75.2(3) . . ?
O4 Dy3 O3 75.0(3) . . ?
O2 Dy3 N10 105.4(4) . . ?
O5 Dy3 N10 135.5(4) . . ?
O4 Dy3 N10 76.2(4) . . ?
O3 Dy3 N10 83.7(4) . . ?
O2 Dy3 N8 82.7(4) . . ?
O5 Dy3 N8 78.7(4) . . ?
O4 Dy3 N8 137.3(4) . . ?
O3 Dy3 N8 108.7(4) . . ?
N10 Dy3 N8 145.7(5) . . ?
O2 Dy3 N4 141.0(3) . . ?
O5 Dy3 N4 131.6(4) . . ?
O4 Dy3 N4 139.3(4) . . ?
O3 Dy3 N4 73.4(3) . . ?
N10 Dy3 N4 75.6(5) . . ?
N8 Dy3 N4 77.7(4) . . ?
O2 Dy3 N3 75.0(3) . . ?
O5 Dy3 N3 141.6(3) . . ?
O4 Dy3 N3 131.5(3) . . ?
O3 Dy3 N3 139.2(3) . . ?
N10 Dy3 N3 76.1(4) . . ?
N8 Dy3 N3 74.0(4) . . ?
N4 Dy3 N3 67.4(4) . . ?
O2 Dy3 Dy1 102.9(2) . . ?
O5 Dy3 Dy1 42.4(2) . . ?
O4 Dy3 Dy1 41.3(2) . . ?
O3 Dy3 Dy1 42.4(2) . . ?
N10 Dy3 Dy1 97.3(3) . . ?
N8 Dy3 Dy1 113.6(3) . . ?
N4 Dy3 Dy1 115.7(3) . . ?
N3 Dy3 Dy1 172.0(3) . . ?
O2 Dy3 Dy2 42.9(2) . . ?
O5 Dy3 Dy2 41.5(2) . . ?
O4 Dy3 Dy2 41.75(19) . . ?
O3 Dy3 Dy2 102.5(2) . . ?
N10 Dy3 Dy2 109.8(3) . . ?
N8 Dy3 Dy2 98.7(3) . . ?
N4 Dy3 Dy2 173.1(3) . . ?
N3 Dy3 Dy2 117.5(2) . . ?
Dy1 Dy3 Dy2 60.096(17) . . ?
C8 N1 C9 116.2(13) . . ?
C8 N1 Dy2 106.5(8) . . ?
C9 N1 Dy2 114.0(8) . . ?
C15 N2 C14 114.5(13) . . ?
C15 N2 Dy2 106.9(8) . . ?
C14 N2 Dy2 115.9(9) . . ?
C24 N3 C23 113.2(11) . . ?
C24 N3 Dy3 113.3(8) . . ?
C23 N3 Dy3 107.5(8) . . ?
C29 N4 C30 114.4(12) . . ?
C29 N4 Dy3 115.9(8) . . ?
C30 N4 Dy3 107.9(8) . . ?
C39 N5 C38 116.9(13) . . ?
C39 N5 Dy1 114.3(8) . . ?
C38 N5 Dy1 104.0(8) . . ?
C44 N6 C45 115.8(12) . . ?
C44 N6 Dy1 115.7(9) . . ?
C45 N6 Dy1 107.7(8) . . ?
C46 N7 Dy2 157.1(12) . . ?
C47 N8 Dy3 159.0(14) . . ?
C48 N9 Dy1 175.6(14) . . ?
C49' N10 C49 52(3) . . ?
C49' N10 Dy3 145(3) . . ?
C49 N10 Dy3 152(2) . . ?
C1 O1 Dy2 133.4(6) . . ?
C1 O1 Dy1 130.9(6) . . ?
Dy2 O1 Dy1 95.7(3) . . ?
C20 O2 Dy3 133.0(7) . . ?
C20 O2 Dy2 131.7(6) . . ?
Dy3 O2 Dy2 95.3(3) . . ?
C36 O3 Dy1 132.2(7) . . ?
C36 O3 Dy3 132.9(7) . . ?
Dy1 O3 Dy3 94.8(3) . . ?
Dy1 O4 Dy2 97.3(3) . . ?
Dy1 O4 Dy3 96.8(3) . . ?
Dy2 O4 Dy3 96.4(3) . . ?
Dy2 O5 Dy3 96.8(3) . . ?
Dy2 O5 Dy1 96.3(3) . . ?
Dy3 O5 Dy1 95.7(3) . . ?
C2 C1 C6 118.7(10) . . ?
C2 C1 O1 121.8(9) . . ?
C6 C1 O1 119.5(9) . . ?
C1 C2 C3 120.5(12) . . ?
C1 C2 C45 120.2(12) . . ?
C3 C2 C45 119.2(12) . . ?
C4 C3 C2 122.3(14) . . ?
C3 C4 C5 117.1(13) . . ?
C3 C4 C7 121.1(13) . . ?
C5 C4 C7 121.9(13) . . ?
C6 C5 C4 120.5(13) . . ?
C5 C6 C1 120.8(12) . . ?
C5 C6 C8 119.1(12) . . ?
C1 C6 C8 120.1(12) . . ?
N1 C8 C6 109.5(13) . . ?
N1 C9 C14 109.1(13) . . ?
N1 C9 C10 114.3(13) . . ?
C14 C9 C10 108.7(16) . . ?
C11 C10 C9 112.7(15) . . ?
C12 C11 C10 108.1(18) . . ?
C11 C12 C13 113.1(18) . . ?
C12 C13 C14 110.0(14) . . ?
N2 C14 C9 107.3(13) . . ?
N2 C14 C13 111.8(13) . . ?
C9 C14 C13 112.2(15) . . ?
N2 C15 C16 109.4(13) . . ?
C17 C16 C20 121.2(13) . . ?
C17 C16 C15 117.5(13) . . ?
C20 C16 C15 121.0(12) . . ?
C16 C17 C18 120.1(15) . . ?
C19 C18 C17 117.9(14) . . ?
C19 C18 C21 122.8(15) . . ?
C17 C18 C21 119.3(14) . . ?
C22 C19 C18 121.0(16) . . ?
O2 C20 C22 122.1(10) . . ?
O2 C20 C16 120.4(10) . . ?
C22 C20 C16 117.5(11) . . ?
C19 C22 C20 121.9(14) . . ?
C19 C22 C23 118.1(14) . . ?
C20 C22 C23 120.0(13) . . ?
N3 C23 C22 108.8(13) . . ?
N3 C24 C25 114.9(13) . . ?
N3 C24 C29 107.4(12) . . ?
C25 C24 C29 107.2(13) . . ?
C24 C25 C26 113.5(14) . . ?
C25 C26 C27 107.2(18) . . ?
C26 C27 C28 111.3(16) . . ?
C29 C28 C27 109.7(15) . . ?
N4 C29 C28 108.8(12) . . ?
N4 C29 C24 108.6(13) . . ?
C28 C29 C24 110.3(14) . . ?
N4 C30 C31 104.9(12) . . ?
C32 C31 C36 119.8(14) . . ?
C32 C31 C30 119.3(13) . . ?
C36 C31 C30 120.8(11) . . ?
C33 C32 C31 121.9(14) . . ?
C32 C33 C34 119.6(13) . . ?
C32 C33 C37 122.9(14) . . ?
C34 C33 C37 117.4(14) . . ?
C33 C34 C35 119.9(15) . . ?
C36 C35 C34 120.1(14) . . ?
C36 C35 C38 120.3(11) . . ?
C34 C35 C38 119.6(13) . . ?
C35 C36 O3 120.7(10) . . ?
C35 C36 C31 118.7(11) . . ?
O3 C36 C31 120.6(10) . . ?
N5 C38 C35 109.4(12) . . ?
N5 C39 C40 112.5(12) . . ?
N5 C39 C44 106.2(13) . . ?
C40 C39 C44 110.8(16) . . ?
C41 C40 C39 110.9(16) . . ?
C42 C41 C40 110(2) . . ?
C41 C42 C43 113(2) . . ?
C42 C43 C44 111.5(17) . . ?
N6 C44 C39 109.0(14) . . ?
N6 C44 C43 111.4(13) . . ?
C39 C44 C43 105.5(15) . . ?
N6 C45 C2 110.0(12) . . ?
N7 C46 S1 176.4(18) . . ?
N8 C47 S2 175.5(18) . . ?
N9 C48 S3 174(2) . . ?
N10 C49 S4 177(4) . . ?
N10 C49' S4' 173(3) . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        26.02
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         2.090
_refine_diff_density_min         -2.515
_refine_diff_density_rms         0.251