# Electronic Supplementary Material (ESI) for Chemical Communications # This journal is © The Royal Society of Chemistry 2013 ####################################################################### # # Cambridge Crystallographic Data Centre # CCDC # ####################################################################### # # This CIF contains data from an original supplementary publication # deposited with the CCDC, and may include chemical, crystal, # experimental, refinement, atomic coordinates, # anisotropic displacement parameters and molecular geometry data, # as required by the journal to which it was submitted. # # This CIF is provided on the understanding that it is used for bona # fide research purposes only. It may contain copyright material # of the CCDC or of third parties, and may not be copied or further # disseminated in any form, whether machine-readable or not, # except for the purpose of generating routine backup copies # on your local computer system. # # For further information on the CCDC, data deposition and # data retrieval see: # www.ccdc.cam.ac.uk # # Bona fide researchers may freely download Mercury and enCIFer # from this site to visualise CIF-encoded structures and # to carry out CIF format checking respectively. # ####################################################################### data_1 _database_code_depnum_ccdc_archive 'CCDC 805806' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C38 H14 Ag8 F16 N2 O18' _chemical_formula_sum 'C38 H14 Ag8 F16 N2 O18' _chemical_formula_weight 1953.47 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M P2(1)/c _symmetry_space_group_name_Hall '-P 2ybc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 17.9401(17) _cell_length_b 12.8038(11) _cell_length_c 23.0195(16) _cell_angle_alpha 90.00 _cell_angle_beta 120.181(5) _cell_angle_gamma 90.00 _cell_volume 4570.8(7) _cell_formula_units_Z 4 _cell_measurement_temperature 296(2) _cell_measurement_reflns_used 9750 _cell_measurement_theta_min 2.38 _cell_measurement_theta_max 28.50 _exptl_crystal_description block _exptl_crystal_colour colorless _exptl_crystal_size_max 0.26 _exptl_crystal_size_mid 0.24 _exptl_crystal_size_min 0.22 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.839 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 3680 _exptl_absorpt_coefficient_mu 3.498 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.417 _exptl_absorpt_correction_T_max 0.465 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 296(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 25557 _diffrn_reflns_av_R_equivalents 0.0332 _diffrn_reflns_av_sigmaI/netI 0.0373 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_h_max 21 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min -27 _diffrn_reflns_limit_l_max 26 _diffrn_reflns_theta_min 1.79 _diffrn_reflns_theta_max 25.52 _reflns_number_total 8358 _reflns_number_gt 6406 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker SMART' _computing_cell_refinement 'Bruker SMART' _computing_data_reduction 'Bruker SAINT' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0334P)^2^+23.5503P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 8358 _refine_ls_number_parameters 777 _refine_ls_number_restraints 38 _refine_ls_R_factor_all 0.0603 _refine_ls_R_factor_gt 0.0412 _refine_ls_wR_factor_ref 0.0997 _refine_ls_wR_factor_gt 0.0895 _refine_ls_goodness_of_fit_ref 1.003 _refine_ls_restrained_S_all 1.009 _refine_ls_shift/su_max 0.004 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.55296(4) 0.96341(4) 0.97169(3) 0.05233(15) Uani 1 1 d . . . Ag2 Ag 0.41997(4) 0.72223(6) 0.92217(3) 0.0683(2) Uani 1 1 d . . . Ag3 Ag 0.54075(4) 0.83780(5) 0.80599(3) 0.05823(17) Uani 1 1 d . . . Ag4 Ag 0.41640(4) 0.80540(5) 0.65605(3) 0.05975(17) Uani 1 1 d . . . Ag5 Ag 0.53122(4) 0.57499(4) 0.70520(3) 0.04870(15) Uani 1 1 d . . . Ag6 Ag 0.40439(4) 0.57866(5) 0.76427(3) 0.05956(17) Uani 1 1 d . . . Ag7 Ag 0.55956(4) 0.46442(5) 0.97368(3) 0.0686(2) Uani 1 1 d . . . Ag8 Ag 0.52978(3) 0.79038(4) 1.05960(2) 0.04338(14) Uani 1 1 d . . . F1 F 0.8493(3) 1.1926(4) 1.1259(2) 0.0795(15) Uani 1 1 d . . . F2 F 0.9794(3) 1.0884(5) 1.1319(3) 0.109(2) Uani 1 1 d . . . F3 F 0.9547(4) 0.9567(5) 1.0313(3) 0.110(2) Uani 1 1 d . . . F4 F 0.7967(3) 0.9372(4) 0.9212(3) 0.0766(14) Uani 1 1 d . . . F5 F 0.2099(5) 1.0595(5) 0.8559(3) 0.112(2) Uani 1 1 d . . . F6 F 0.0543(4) 1.0078(7) 0.7568(5) 0.168(4) Uani 1 1 d . . . F7 F 0.0362(4) 0.8833(7) 0.6583(4) 0.163(3) Uani 1 1 d . . . F8 F 0.1708(6) 0.8078(5) 0.6572(3) 0.138(3) Uani 1 1 d . . . F9 F 0.7905(3) 0.8035(4) 1.0569(2) 0.0766(14) Uani 1 1 d . . . F10 F 0.9209(3) 0.7335(5) 1.0441(3) 0.0947(17) Uani 1 1 d . . . F11 F 0.8932(3) 0.5928(4) 0.9470(3) 0.0863(16) Uani 1 1 d . . . F12 F 0.7329(3) 0.5267(3) 0.8613(2) 0.0626(12) Uani 1 1 d . . . F13 F 0.7448(3) 0.7120(4) 0.8065(2) 0.0837(16) Uani 1 1 d . . . F14 F 0.9020(3) 0.6897(4) 0.8202(3) 0.0939(18) Uani 1 1 d . . . F15 F 0.9377(3) 0.7831(5) 0.7305(3) 0.0893(17) Uani 1 1 d . . . F16 F 0.8194(3) 0.8966(4) 0.6315(2) 0.0723(13) Uani 1 1 d . . . O1 O 0.6015(3) 1.1607(4) 0.9626(2) 0.0587(14) Uani 1 1 d . . . O2 O 0.6853(3) 1.2401(4) 1.0605(2) 0.0567(13) Uani 1 1 d . . . O3 O 0.6081(4) 0.9654(5) 0.8970(3) 0.0773(18) Uani 1 1 d . . . O4 O 0.6376(4) 1.1046(4) 0.8532(2) 0.0648(15) Uani 1 1 d U . . O5A O 0.4025(5) 0.9425(6) 0.9186(4) 0.067(2) Uani 0.715(5) 1 d PD . 1 O6A O 0.3903(5) 1.0792(6) 0.8550(4) 0.062(2) Uani 0.715(5) 1 d PD . 1 O7A O 0.3296(5) 0.7988(6) 0.7037(3) 0.0607(19) Uani 0.715(5) 1 d PD . 1 O8A O 0.4145(5) 0.8934(7) 0.7962(5) 0.081(3) Uani 0.715(5) 1 d PD . 1 O9A O 0.6233(9) 0.7915(6) 1.0193(3) 0.053(2) Uani 0.715(5) 1 d PD . 1 O10A O 0.5416(5) 0.6910(9) 0.9312(5) 0.084(4) Uani 0.715(5) 1 d PD . 1 O5B O 0.3516(13) 0.9994(17) 0.9200(7) 0.067(2) Uani 0.285(5) 1 d PD . 2 O6B O 0.4328(9) 1.0249(17) 0.8786(10) 0.062(2) Uani 0.285(5) 1 d PD . 2 O7B O 0.3977(11) 0.9052(14) 0.7413(9) 0.0607(19) Uani 0.285(5) 1 d PD . 2 O8B O 0.4057(11) 0.8221(16) 0.8080(8) 0.081(3) Uani 0.285(5) 1 d PD . 2 O9B O 0.635(3) 0.756(2) 1.0319(7) 0.053(2) Uani 0.285(5) 1 d PD . 2 O10B O 0.5478(12) 0.759(2) 0.9185(8) 0.084(4) Uani 0.285(5) 1 d PD . 2 O11 O 0.5541(4) 0.5148(5) 0.8663(3) 0.0783(17) Uani 1 1 d U . . O12 O 0.5531(3) 0.6488(4) 0.8060(2) 0.0521(12) Uani 1 1 d U . . O13 O 0.6146(3) 0.8888(4) 0.7526(2) 0.0523(12) Uani 1 1 d . . . O14 O 0.5524(3) 0.7623(4) 0.6769(2) 0.0478(11) Uani 1 1 d . . . O15 O 0.5710(3) 0.9088(4) 0.5962(3) 0.0646(15) Uani 1 1 d U . . O16 O 0.6635(3) 0.9786(4) 0.5703(2) 0.0556(13) Uani 1 1 d . . . O17 O 0.3219(3) 0.6339(5) 0.8116(2) 0.0637(15) Uani 1 1 d . . . N1 N 0.1785(4) 0.6086(5) 0.7421(3) 0.0539(15) Uani 1 1 d . . . C1 C 0.6730(4) 1.1811(5) 1.0135(3) 0.0432(16) Uani 1 1 d . . . C2 C 0.7483(4) 1.1238(5) 1.0170(3) 0.0424(15) Uani 1 1 d . . . C3 C 0.8313(5) 1.1316(6) 1.0728(3) 0.0548(19) Uani 1 1 d . . . C4 C 0.8992(5) 1.0774(7) 1.0770(4) 0.070(2) Uani 1 1 d . . . C5 C 0.8885(5) 1.0123(7) 1.0274(5) 0.069(2) Uani 1 1 d . . . C6 C 0.8078(5) 1.0032(6) 0.9712(4) 0.0559(19) Uani 1 1 d . . . C7 C 0.7382(4) 1.0579(5) 0.9649(3) 0.0415(15) Uani 1 1 d . . . C8 C 0.6535(5) 1.0423(6) 0.9001(4) 0.0509(18) Uani 1 1 d . . . C9 C 0.3616(5) 0.9983(6) 0.8672(4) 0.059(2) Uani 1 1 d D . . C10 C 0.2789(4) 0.9611(5) 0.8104(3) 0.0398(15) Uani 1 1 d . . . C11 C 0.2037(6) 0.9967(6) 0.8069(4) 0.060(2) Uani 1 1 d . . . C12 C 0.1251(6) 0.9710(8) 0.7577(6) 0.081(3) Uani 1 1 d . . . C13 C 0.1165(6) 0.9095(9) 0.7093(5) 0.087(3) Uani 1 1 d . . . C14 C 0.1859(7) 0.8708(7) 0.7077(4) 0.070(3) Uani 1 1 d . . . C15 C 0.2707(5) 0.8958(5) 0.7592(3) 0.0459(17) Uani 1 1 d . . . C16 C 0.3447(6) 0.8577(6) 0.7538(5) 0.067(2) Uani 1 1 d D . . C17 C 0.6140(5) 0.7333(6) 0.9735(3) 0.0491(17) Uani 1 1 d D . . C18 C 0.6883(4) 0.7004(5) 0.9649(3) 0.0385(14) Uani 1 1 d . . . C19 C 0.7732(5) 0.7345(6) 1.0078(3) 0.0498(18) Uani 1 1 d . . . C20 C 0.8408(5) 0.6991(6) 1.0020(4) 0.057(2) Uani 1 1 d . . . C21 C 0.8260(5) 0.6286(6) 0.9524(4) 0.0545(19) Uani 1 1 d . . . C22 C 0.7441(5) 0.5948(5) 0.9094(3) 0.0447(16) Uani 1 1 d . . . C23 C 0.6750(4) 0.6305(5) 0.9137(3) 0.0377(14) Uani 1 1 d . . . C24 C 0.5861(5) 0.5956(6) 0.8592(3) 0.0477(17) Uani 1 1 d . . . C25 C 0.6128(4) 0.8243(5) 0.7113(3) 0.0414(15) Uani 1 1 d . . . C26 C 0.6971(4) 0.8147(5) 0.7099(3) 0.0355(14) Uani 1 1 d . . . C27 C 0.7609(5) 0.7583(6) 0.7612(3) 0.0503(18) Uani 1 1 d . . . C28 C 0.8406(5) 0.7467(6) 0.7689(4) 0.060(2) Uani 1 1 d . . . C29 C 0.8590(5) 0.7938(6) 0.7243(4) 0.058(2) Uani 1 1 d . . . C30 C 0.7969(4) 0.8523(6) 0.6731(3) 0.0461(16) Uani 1 1 d . . . C31 C 0.7143(4) 0.8638(5) 0.6635(3) 0.0347(14) Uani 1 1 d . . . C32 C 0.6450(4) 0.9235(5) 0.6049(3) 0.0376(14) Uani 1 1 d . . . C33 C 0.2465(5) 0.6388(6) 0.7984(3) 0.0514(18) Uani 1 1 d . . . H33A H 0.2367 0.6666 0.8313 0.062 Uiso 1 1 calc R . . C34 C 0.1863(6) 0.5596(7) 0.6887(4) 0.074(3) Uani 1 1 d . . . H34A H 0.2452 0.5397 0.7054 0.111 Uiso 1 1 calc R . . H34B H 0.1688 0.6080 0.6522 0.111 Uiso 1 1 calc R . . H34C H 0.1502 0.4988 0.6731 0.111 Uiso 1 1 calc R . . C35 C 0.0931(6) 0.6197(10) 0.7323(5) 0.102(4) Uani 1 1 d . . . H35A H 0.0964 0.6530 0.7709 0.152 Uiso 1 1 calc R . . H35B H 0.0672 0.5520 0.7263 0.152 Uiso 1 1 calc R . . H35C H 0.0587 0.6615 0.6931 0.152 Uiso 1 1 calc R . . N2 N 0.1578(5) 0.8699(6) 0.4861(3) 0.072(2) Uani 1 1 d D . . O18A O 0.2909(17) 0.847(3) 0.5569(18) 0.084(7) Uani 0.409(8) 1 d PD . 1 C36A C 0.2409(10) 0.8996(15) 0.4940(11) 0.066(3) Uani 0.409(8) 1 d PD . 1 H36A H 0.2561 0.9388 0.4675 0.079 Uiso 0.409(8) 1 calc PR . 1 C37A C 0.0915(14) 0.912(2) 0.4251(9) 0.092(5) Uani 0.409(8) 1 d PD . 1 H37A H 0.0393 0.8733 0.4106 0.139 Uiso 0.409(8) 1 calc PR . 1 H37B H 0.1080 0.9077 0.3914 0.139 Uiso 0.409(8) 1 calc PR . 1 H37C H 0.0823 0.9839 0.4318 0.139 Uiso 0.409(8) 1 calc PR . 1 C38A C 0.1568(19) 0.820(2) 0.5394(10) 0.094(5) Uani 0.409(8) 1 d PD . 1 H38A H 0.1001 0.7927 0.5247 0.141 Uiso 0.409(8) 1 calc PR . 1 H38B H 0.1722 0.8684 0.5754 0.141 Uiso 0.409(8) 1 calc PR . 1 H38C H 0.1975 0.7631 0.5550 0.141 Uiso 0.409(8) 1 calc PR . 1 O18B O 0.3131(9) 0.873(2) 0.5483(12) 0.084(7) Uani 0.591(8) 1 d PD . 2 C36B C 0.2364(9) 0.8362(11) 0.5464(7) 0.066(3) Uani 0.591(8) 1 d PD . 2 H36B H 0.2367 0.7953 0.5800 0.079 Uiso 0.591(8) 1 calc PR . 2 C37B C 0.1557(14) 0.9290(14) 0.4345(8) 0.092(5) Uani 0.591(8) 1 d PD . 2 H37D H 0.1082 0.9067 0.3921 0.139 Uiso 0.591(8) 1 calc PR . 2 H37E H 0.2086 0.9196 0.4343 0.139 Uiso 0.591(8) 1 calc PR . 2 H37F H 0.1487 1.0015 0.4414 0.139 Uiso 0.591(8) 1 calc PR . 2 C38B C 0.0855(10) 0.8304(15) 0.4883(9) 0.094(5) Uani 0.591(8) 1 d PD . 2 H38D H 0.0502 0.7902 0.4486 0.141 Uiso 0.591(8) 1 calc PR . 2 H38E H 0.0524 0.8874 0.4908 0.141 Uiso 0.591(8) 1 calc PR . 2 H38F H 0.1048 0.7867 0.5272 0.141 Uiso 0.591(8) 1 calc PR . 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0618(4) 0.0559(3) 0.0486(3) -0.0022(2) 0.0347(3) 0.0022(3) Ag2 0.0443(3) 0.1002(5) 0.0482(3) -0.0248(3) 0.0143(3) 0.0014(3) Ag3 0.0616(4) 0.0623(4) 0.0661(4) -0.0217(3) 0.0435(3) -0.0112(3) Ag4 0.0495(4) 0.0788(4) 0.0533(3) -0.0064(3) 0.0276(3) -0.0010(3) Ag5 0.0604(4) 0.0510(3) 0.0426(3) -0.0031(2) 0.0317(3) 0.0043(3) Ag6 0.0529(4) 0.0745(4) 0.0523(3) -0.0111(3) 0.0271(3) -0.0059(3) Ag7 0.0690(4) 0.0780(4) 0.0451(3) -0.0157(3) 0.0186(3) -0.0318(3) Ag8 0.0419(3) 0.0493(3) 0.0383(3) -0.0031(2) 0.0196(2) 0.0025(2) F1 0.067(3) 0.094(4) 0.045(2) -0.011(2) 0.004(2) -0.010(3) F2 0.049(3) 0.130(5) 0.089(4) 0.017(4) -0.008(3) 0.012(3) F3 0.069(4) 0.126(5) 0.129(5) 0.030(4) 0.045(4) 0.047(4) F4 0.088(4) 0.071(3) 0.089(3) -0.002(3) 0.058(3) 0.014(3) F5 0.166(6) 0.095(4) 0.149(5) -0.044(4) 0.133(5) -0.018(4) F6 0.073(5) 0.163(7) 0.283(11) 0.016(7) 0.101(6) 0.028(5) F7 0.075(4) 0.187(8) 0.124(6) -0.003(5) -0.025(4) -0.032(5) F8 0.234(9) 0.105(5) 0.078(4) -0.039(4) 0.082(5) -0.042(5) F9 0.077(3) 0.084(3) 0.057(3) -0.028(2) 0.025(2) -0.017(3) F10 0.048(3) 0.130(5) 0.077(3) -0.007(3) 0.010(3) -0.018(3) F11 0.064(3) 0.112(4) 0.105(4) 0.019(3) 0.058(3) 0.025(3) F12 0.091(3) 0.054(2) 0.070(3) -0.004(2) 0.060(3) 0.009(2) F13 0.077(3) 0.110(4) 0.064(3) 0.052(3) 0.035(3) 0.015(3) F14 0.065(3) 0.111(4) 0.075(3) 0.043(3) 0.013(3) 0.038(3) F15 0.044(3) 0.128(5) 0.095(4) 0.024(3) 0.034(3) 0.028(3) F16 0.059(3) 0.103(4) 0.074(3) 0.025(3) 0.048(3) 0.013(3) O1 0.045(3) 0.088(4) 0.040(3) -0.020(3) 0.019(2) 0.001(3) O2 0.057(3) 0.065(3) 0.049(3) -0.025(2) 0.028(2) -0.017(3) O3 0.079(4) 0.102(5) 0.067(4) -0.045(3) 0.049(3) -0.051(4) O4 0.073(4) 0.078(4) 0.040(3) -0.004(3) 0.026(2) 0.015(3) O5A 0.060(5) 0.071(5) 0.054(4) 0.008(4) 0.016(4) -0.014(4) O6A 0.067(6) 0.065(6) 0.057(5) -0.017(4) 0.033(4) -0.025(4) O7A 0.072(5) 0.075(5) 0.047(4) -0.027(3) 0.039(4) -0.011(4) O8A 0.049(4) 0.082(6) 0.115(7) -0.056(6) 0.043(4) -0.016(5) O9A 0.064(6) 0.048(7) 0.054(4) -0.011(4) 0.035(4) 0.008(6) O10A 0.048(4) 0.134(10) 0.076(5) -0.051(7) 0.034(4) -0.004(6) O5B 0.060(5) 0.071(5) 0.054(4) 0.008(4) 0.016(4) -0.014(4) O6B 0.067(6) 0.065(6) 0.057(5) -0.017(4) 0.033(4) -0.025(4) O7B 0.072(5) 0.075(5) 0.047(4) -0.027(3) 0.039(4) -0.011(4) O8B 0.049(4) 0.082(6) 0.115(7) -0.056(6) 0.043(4) -0.016(5) O9B 0.064(6) 0.048(7) 0.054(4) -0.011(4) 0.035(4) 0.008(6) O10B 0.048(4) 0.134(10) 0.076(5) -0.051(7) 0.034(4) -0.004(6) O11 0.075(4) 0.084(4) 0.075(4) 0.000(3) 0.037(3) -0.032(3) O12 0.065(3) 0.050(3) 0.035(2) -0.008(2) 0.020(2) 0.004(2) O13 0.068(3) 0.057(3) 0.042(3) -0.004(2) 0.036(2) -0.006(3) O14 0.046(3) 0.055(3) 0.045(3) -0.002(2) 0.026(2) -0.011(2) O15 0.049(3) 0.086(4) 0.065(3) 0.041(3) 0.033(3) 0.024(3) O16 0.049(3) 0.071(3) 0.047(3) 0.028(2) 0.024(2) 0.005(2) O17 0.046(3) 0.096(4) 0.045(3) -0.015(3) 0.020(2) 0.000(3) N1 0.045(4) 0.070(4) 0.047(3) -0.014(3) 0.023(3) -0.010(3) C1 0.043(4) 0.052(4) 0.034(3) 0.000(3) 0.019(3) -0.006(3) C2 0.043(4) 0.046(4) 0.036(3) 0.005(3) 0.018(3) -0.006(3) C3 0.050(5) 0.058(5) 0.043(4) 0.003(3) 0.013(3) -0.006(4) C4 0.048(5) 0.080(6) 0.059(5) 0.012(5) 0.009(4) 0.003(4) C5 0.044(5) 0.078(6) 0.077(6) 0.028(5) 0.025(4) 0.019(4) C6 0.062(5) 0.050(4) 0.071(5) 0.010(4) 0.045(4) 0.007(4) C7 0.037(4) 0.049(4) 0.038(3) 0.007(3) 0.019(3) -0.005(3) C8 0.055(5) 0.063(5) 0.043(4) -0.012(3) 0.031(4) -0.004(4) C9 0.070(6) 0.045(4) 0.050(4) 0.001(3) 0.022(4) -0.017(4) C10 0.048(4) 0.039(3) 0.039(3) 0.004(3) 0.027(3) -0.006(3) C11 0.070(6) 0.064(5) 0.065(5) -0.007(4) 0.049(5) -0.008(4) C12 0.049(6) 0.084(7) 0.105(8) 0.008(6) 0.035(6) 0.002(5) C13 0.059(6) 0.097(8) 0.072(6) 0.006(6) 0.009(5) -0.008(5) C14 0.107(8) 0.059(5) 0.041(4) -0.013(4) 0.034(5) -0.016(5) C15 0.065(5) 0.035(3) 0.054(4) 0.006(3) 0.042(4) 0.001(3) C16 0.078(6) 0.050(5) 0.099(7) 0.018(5) 0.064(6) 0.011(4) C17 0.054(5) 0.053(4) 0.042(4) -0.001(3) 0.026(3) 0.007(3) C18 0.046(4) 0.039(3) 0.036(3) 0.001(3) 0.025(3) 0.001(3) C19 0.059(5) 0.050(4) 0.038(4) -0.001(3) 0.023(3) -0.008(3) C20 0.039(4) 0.074(5) 0.054(4) 0.012(4) 0.021(4) -0.003(4) C21 0.051(5) 0.063(5) 0.064(5) 0.015(4) 0.040(4) 0.012(4) C22 0.060(5) 0.042(4) 0.046(4) 0.007(3) 0.038(4) 0.006(3) C23 0.046(4) 0.037(3) 0.036(3) 0.005(3) 0.026(3) -0.001(3) C24 0.052(4) 0.051(4) 0.045(4) -0.010(3) 0.028(3) -0.007(3) C25 0.046(4) 0.048(4) 0.032(3) 0.012(3) 0.021(3) 0.002(3) C26 0.040(4) 0.038(3) 0.028(3) -0.004(2) 0.017(3) -0.001(3) C27 0.051(5) 0.056(4) 0.041(4) 0.013(3) 0.021(3) 0.003(3) C28 0.049(5) 0.067(5) 0.048(4) 0.017(4) 0.013(4) 0.018(4) C29 0.042(4) 0.074(5) 0.055(4) 0.005(4) 0.021(4) 0.016(4) C30 0.044(4) 0.056(4) 0.042(4) 0.008(3) 0.025(3) 0.005(3) C31 0.039(4) 0.034(3) 0.031(3) 0.003(2) 0.018(3) 0.002(3) C32 0.032(4) 0.048(4) 0.033(3) 0.000(3) 0.016(3) 0.005(3) C33 0.056(5) 0.058(5) 0.045(4) -0.011(3) 0.029(4) -0.008(4) C34 0.068(6) 0.094(7) 0.045(4) -0.022(4) 0.018(4) -0.002(5) C35 0.071(7) 0.141(10) 0.095(7) -0.044(7) 0.044(6) -0.026(7) N2 0.072(5) 0.085(5) 0.058(4) -0.019(4) 0.031(4) -0.004(4) O18A 0.053(9) 0.098(15) 0.076(8) -0.035(7) 0.015(7) -0.002(9) C36A 0.060(8) 0.061(7) 0.087(9) -0.039(6) 0.045(7) -0.016(6) C37A 0.104(14) 0.107(11) 0.074(9) -0.008(8) 0.050(11) -0.010(11) C38A 0.093(12) 0.110(11) 0.088(11) -0.011(10) 0.052(8) 0.003(10) O18B 0.053(9) 0.098(15) 0.076(8) -0.035(7) 0.015(7) -0.002(9) C36B 0.060(8) 0.061(7) 0.087(9) -0.039(6) 0.045(7) -0.016(6) C37B 0.104(14) 0.107(11) 0.074(9) -0.008(8) 0.050(11) -0.010(11) C38B 0.093(12) 0.110(11) 0.088(11) -0.011(10) 0.052(8) 0.003(10) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 O5B 2.255(17) 3_677 ? Ag1 O6B 2.28(2) . ? Ag1 O5A 2.352(8) . ? Ag1 O3 2.375(5) . ? Ag1 O9A 2.500(7) . ? Ag1 O5A 2.537(8) 3_677 ? Ag1 Ag1 2.9458(11) 3_677 ? Ag1 Ag8 3.1659(8) . ? Ag2 O10A 2.123(9) . ? Ag2 O2 2.173(5) 3_677 ? Ag2 O10B 2.38(3) . ? Ag2 O17 2.519(5) . ? Ag2 Ag8 2.8956(8) . ? Ag2 Ag7 3.2724(10) 3_667 ? Ag3 O8A 2.276(8) . ? Ag3 O13 2.309(5) . ? Ag3 O7B 2.39(2) . ? Ag3 O12 2.430(5) . ? Ag3 O3 2.444(5) . ? Ag3 O8B 2.46(2) . ? Ag3 Ag4 3.0529(9) . ? Ag3 Ag5 3.2592(9) 2_656 ? Ag4 O14 2.305(5) . ? Ag4 O7A 2.315(7) . ? Ag4 O18A 2.32(3) . ? Ag4 O18B 2.39(2) . ? Ag4 O7B 2.502(16) . ? Ag5 O12 2.349(4) . ? Ag5 O6B 2.408(18) 2_646 ? Ag5 O6A 2.422(8) 2_646 ? Ag5 O7B 2.508(16) 2_646 ? Ag5 O8A 2.528(10) 2_646 ? Ag5 O14 2.564(5) . ? Ag5 Ag6 3.1842(8) . ? Ag5 Ag3 3.2592(9) 2_646 ? Ag6 O17 2.345(5) . ? Ag6 O4 2.436(5) 2_646 ? Ag6 O13 2.458(5) 2_646 ? Ag6 O12 2.503(5) . ? Ag7 O16 2.188(5) 4_576 ? Ag7 O15 2.189(5) 2_646 ? Ag7 O11 2.509(6) . ? Ag7 Ag7 3.0771(15) 3_667 ? Ag7 Ag2 3.2724(11) 3_667 ? Ag8 O1 2.234(5) 3_677 ? Ag8 O9A 2.289(13) . ? Ag8 O9B 2.32(4) . ? Ag8 O6A 2.423(7) 3_677 ? F1 C3 1.345(9) . ? F2 C4 1.363(9) . ? F3 C5 1.348(9) . ? F4 C6 1.360(9) . ? F5 C11 1.343(9) . ? F6 C12 1.346(11) . ? F7 C13 1.367(11) . ? F8 C14 1.327(9) . ? F9 C19 1.344(8) . ? F10 C20 1.341(9) . ? F11 C21 1.352(8) . ? F12 C22 1.343(7) . ? F13 C27 1.350(8) . ? F14 C28 1.354(8) . ? F15 C29 1.352(9) . ? F16 C30 1.335(8) . ? O1 C1 1.255(8) . ? O1 Ag8 2.234(5) 3_677 ? O2 C1 1.244(8) . ? O2 Ag2 2.173(5) 3_677 ? O3 C8 1.257(9) . ? O4 C8 1.255(9) . ? O4 Ag6 2.436(5) 2_656 ? O5A C9 1.256(9) . ? O5A Ag1 2.537(8) 3_677 ? O6A C9 1.250(9) . ? O6A Ag5 2.422(8) 2_656 ? O6A Ag8 2.423(7) 3_677 ? O7A C16 1.288(10) . ? O8A C16 1.224(11) . ? O8A Ag5 2.528(10) 2_656 ? O9A C17 1.232(8) . ? O10A C17 1.287(10) . ? O5B C9 1.314(12) . ? O5B Ag1 2.255(16) 3_677 ? O6B C9 1.217(12) . ? O6B Ag5 2.408(18) 2_656 ? O7B C16 1.278(12) . ? O7B O8B 1.81(3) . ? O7B Ag5 2.508(16) 2_656 ? O8B C16 1.261(13) . ? O9B C17 1.233(11) . ? O10B C17 1.269(12) . ? O11 C24 1.235(9) . ? O12 C24 1.258(8) . ? O13 C25 1.248(8) . ? O13 Ag6 2.458(5) 2_656 ? O14 C25 1.252(8) . ? O15 C32 1.253(8) . ? O15 Ag7 2.189(5) 2_656 ? O16 C32 1.229(8) . ? O16 Ag7 2.188(4) 4_575 ? O17 C33 1.229(9) . ? N1 C33 1.315(9) . ? N1 C35 1.439(11) . ? N1 C34 1.448(9) . ? C1 C2 1.504(10) . ? C2 C3 1.397(9) . ? C2 C7 1.403(9) . ? C3 C4 1.362(12) . ? C4 C5 1.349(12) . ? C5 C6 1.379(11) . ? C6 C7 1.373(10) . ? C7 C8 1.515(10) . ? C9 C10 1.478(10) . ? C10 C11 1.388(10) . ? C10 C15 1.393(9) . ? C11 C12 1.332(12) . ? C12 C13 1.307(14) . ? C13 C14 1.357(14) . ? C14 C15 1.417(12) . ? C15 C16 1.476(11) . ? C17 C18 1.504(10) . ? C18 C23 1.400(8) . ? C18 C19 1.404(10) . ? C19 C20 1.362(11) . ? C20 C21 1.373(11) . ? C21 C22 1.364(10) . ? C22 C23 1.372(9) . ? C23 C24 1.518(9) . ? C25 C26 1.532(9) . ? C26 C27 1.366(9) . ? C26 C31 1.401(8) . ? C27 C28 1.359(11) . ? C28 C29 1.367(11) . ? C29 C30 1.368(10) . ? C30 C31 1.393(9) . ? C31 C32 1.504(8) . ? C33 H33A 0.9300 . ? C34 H34A 0.9600 . ? C34 H34B 0.9600 . ? C34 H34C 0.9600 . ? C35 H35A 0.9600 . ? C35 H35B 0.9600 . ? C35 H35C 0.9600 . ? N2 C37B 1.393(11) . ? N2 C38A 1.395(12) . ? N2 C37A 1.414(12) . ? N2 C38B 1.418(11) . ? N2 C36A 1.459(14) . ? N2 C36B 1.462(14) . ? O18A C36A 1.43(2) . ? C36A H36A 0.9300 . ? C37A H37A 0.9600 . ? C37A H37B 0.9600 . ? C37A H37C 0.9600 . ? C38A H38A 0.9600 . ? C38A H38B 0.9600 . ? C38A H38C 0.9600 . ? O18B C36B 1.44(2) . ? C36B H36B 0.9300 . ? C37B H37D 0.9600 . ? C37B H37E 0.9600 . ? C37B H37F 0.9600 . ? C38B H38D 0.9600 . ? C38B H38E 0.9600 . ? C38B H38F 0.9600 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag O5B Ag1 O6B 143.0(8) 3_677 . ? O5B Ag1 O5A 129.3(4) 3_677 . ? O6B Ag1 O5A 42.0(4) . . ? O5B Ag1 O3 115.9(4) 3_677 . ? O6B Ag1 O3 81.8(4) . . ? O5A Ag1 O3 114.3(2) . . ? O5B Ag1 O9A 76.5(6) 3_677 . ? O6B Ag1 O9A 138.2(6) . . ? O5A Ag1 O9A 108.8(4) . . ? O3 Ag1 O9A 91.4(3) . . ? O5B Ag1 O5A 27.7(5) 3_677 3_677 ? O6B Ag1 O5A 116.5(5) . 3_677 ? O5A Ag1 O5A 106.0(2) . 3_677 ? O3 Ag1 O5A 132.7(2) . 3_677 ? O9A Ag1 O5A 98.3(2) . 3_677 ? O5B Ag1 Ag1 75.1(5) 3_677 3_677 ? O6B Ag1 Ag1 77.9(4) . 3_677 ? O5A Ag1 Ag1 55.9(2) . 3_677 ? O3 Ag1 Ag1 155.87(18) . 3_677 ? O9A Ag1 Ag1 112.4(3) . 3_677 ? O5A Ag1 Ag1 50.12(19) 3_677 3_677 ? O5B Ag1 Ag8 73.2(5) 3_677 . ? O6B Ag1 Ag8 118.4(4) . . ? O5A Ag1 Ag8 76.54(17) . . ? O3 Ag1 Ag8 134.93(17) . . ? O9A Ag1 Ag8 45.8(3) . . ? O5A Ag1 Ag8 76.87(16) 3_677 . ? Ag1 Ag1 Ag8 67.57(2) 3_677 . ? O10A Ag2 O2 165.8(3) . 3_677 ? O10A Ag2 O10B 23.2(6) . . ? O2 Ag2 O10B 154.7(7) 3_677 . ? O10A Ag2 O17 100.1(2) . . ? O2 Ag2 O17 93.17(17) 3_677 . ? O10B Ag2 O17 104.4(5) . . ? O10A Ag2 Ag8 81.3(2) . . ? O2 Ag2 Ag8 84.78(12) 3_677 . ? O10B Ag2 Ag8 80.9(5) . . ? O17 Ag2 Ag8 170.01(14) . . ? O10A Ag2 Ag7 93.4(3) . 3_667 ? O2 Ag2 Ag7 79.32(15) 3_677 3_667 ? O10B Ag2 Ag7 114.5(5) . 3_667 ? O17 Ag2 Ag7 100.17(14) . 3_667 ? Ag8 Ag2 Ag7 69.85(2) . 3_667 ? O8A Ag3 O13 131.9(3) . . ? O8A Ag3 O7B 28.5(4) . . ? O13 Ag3 O7B 106.9(4) . . ? O8A Ag3 O12 113.4(3) . . ? O13 Ag3 O12 101.85(17) . . ? O7B Ag3 O12 115.4(4) . . ? O8A Ag3 O3 85.1(2) . . ? O13 Ag3 O3 95.69(18) . . ? O7B Ag3 O3 101.9(4) . . ? O12 Ag3 O3 131.3(2) . . ? O8A Ag3 O8B 23.7(4) . . ? O13 Ag3 O8B 150.4(4) . . ? O7B Ag3 O8B 44.0(5) . . ? O12 Ag3 O8B 90.5(5) . . ? O3 Ag3 O8B 96.0(5) . . ? O8A Ag3 Ag4 78.8(2) . . ? O13 Ag3 Ag4 74.05(12) . . ? O7B Ag3 Ag4 53.0(4) . . ? O12 Ag3 Ag4 83.09(11) . . ? O3 Ag3 Ag4 145.64(17) . . ? O8B Ag3 Ag4 81.0(4) . . ? O8A Ag3 Ag5 50.6(3) . 2_656 ? O13 Ag3 Ag5 90.28(13) . 2_656 ? O7B Ag3 Ag5 49.9(4) . 2_656 ? O12 Ag3 Ag5 163.81(13) . 2_656 ? O3 Ag3 Ag5 56.66(17) . 2_656 ? O8B Ag3 Ag5 73.9(5) . 2_656 ? Ag4 Ag3 Ag5 90.11(2) . 2_656 ? O14 Ag4 O7A 141.9(2) . . ? O14 Ag4 O18A 131.4(11) . . ? O7A Ag4 O18A 85.6(10) . . ? O14 Ag4 O18B 119.4(5) . . ? O7A Ag4 O18B 98.6(6) . . ? O18A Ag4 O18B 15.1(11) . . ? O14 Ag4 O7B 120.3(4) . . ? O7A Ag4 O7B 42.2(4) . . ? O18A Ag4 O7B 102.0(13) . . ? O18B Ag4 O7B 106.8(9) . . ? O14 Ag4 Ag3 72.64(11) . . ? O7A Ag4 Ag3 75.67(17) . . ? O18A Ag4 Ag3 151.1(12) . . ? O18B Ag4 Ag3 150.2(7) . . ? O7B Ag4 Ag3 49.7(5) . . ? O12 Ag5 O6B 156.9(5) . 2_646 ? O12 Ag5 O6A 134.4(2) . 2_646 ? O6B Ag5 O6A 23.2(5) 2_646 2_646 ? O12 Ag5 O7B 94.2(4) . 2_646 ? O6B Ag5 O7B 83.6(6) 2_646 2_646 ? O6A Ag5 O7B 90.1(4) 2_646 2_646 ? O12 Ag5 O8A 120.6(2) . 2_646 ? O6B Ag5 O8A 59.0(5) 2_646 2_646 ? O6A Ag5 O8A 71.0(3) 2_646 2_646 ? O7B Ag5 O8A 26.5(4) 2_646 2_646 ? O12 Ag5 O14 84.39(16) . . ? O6B Ag5 O14 84.9(5) 2_646 . ? O6A Ag5 O14 68.3(2) 2_646 . ? O7B Ag5 O14 146.3(4) 2_646 . ? O8A Ag5 O14 138.6(2) 2_646 . ? O12 Ag5 Ag6 51.12(13) . . ? O6B Ag5 Ag6 152.0(5) 2_646 . ? O6A Ag5 Ag6 171.73(18) 2_646 . ? O7B Ag5 Ag6 95.7(3) 2_646 . ? O8A Ag5 Ag6 112.46(19) 2_646 . ? O14 Ag5 Ag6 108.90(11) . . ? O12 Ag5 Ag3 108.40(12) . 2_646 ? O6B Ag5 Ag3 86.8(5) 2_646 2_646 ? O6A Ag5 Ag3 107.25(19) 2_646 2_646 ? O7B Ag5 Ag3 46.7(5) 2_646 2_646 ? O8A Ag5 Ag3 44.10(19) 2_646 2_646 ? O14 Ag5 Ag3 162.80(10) . 2_646 ? Ag6 Ag5 Ag3 73.01(2) . 2_646 ? O17 Ag6 O4 123.99(19) . 2_646 ? O17 Ag6 O13 107.57(19) . 2_646 ? O4 Ag6 O13 91.07(17) 2_646 2_646 ? O17 Ag6 O12 120.83(17) . . ? O4 Ag6 O12 93.02(17) 2_646 . ? O13 Ag6 O12 116.86(16) 2_646 . ? O17 Ag6 Ag5 162.97(15) . . ? O4 Ag6 Ag5 54.35(14) 2_646 . ? O13 Ag6 Ag5 89.44(11) 2_646 . ? O12 Ag6 Ag5 46.93(10) . . ? O16 Ag7 O15 154.93(19) 4_576 2_646 ? O16 Ag7 O11 120.48(19) 4_576 . ? O15 Ag7 O11 82.08(19) 2_646 . ? O16 Ag7 Ag7 84.67(13) 4_576 3_667 ? O15 Ag7 Ag7 71.78(13) 2_646 3_667 ? O11 Ag7 Ag7 128.39(16) . 3_667 ? O16 Ag7 Ag2 76.96(15) 4_576 3_667 ? O15 Ag7 Ag2 89.14(16) 2_646 3_667 ? O11 Ag7 Ag2 147.57(16) . 3_667 ? Ag7 Ag7 Ag2 76.83(3) 3_667 3_667 ? O1 Ag8 O9A 144.0(2) 3_677 . ? O1 Ag8 O9B 154.3(5) 3_677 . ? O9A Ag8 O9B 13.0(7) . . ? O1 Ag8 O6A 96.8(2) 3_677 3_677 ? O9A Ag8 O6A 94.0(3) . 3_677 ? O9B Ag8 O6A 97.0(8) . 3_677 ? O1 Ag8 Ag2 76.98(11) 3_677 . ? O9A Ag8 Ag2 78.1(2) . . ? O9B Ag8 Ag2 81.0(6) . . ? O6A Ag8 Ag2 153.36(19) 3_677 . ? O1 Ag8 Ag1 96.88(15) 3_677 . ? O9A Ag8 Ag1 51.55(19) . . ? O9B Ag8 Ag1 64.5(7) . . ? O6A Ag8 Ag1 79.75(17) 3_677 . ? Ag2 Ag8 Ag1 75.42(2) . . ? C1 O1 Ag8 128.3(4) . 3_677 ? C1 O2 Ag2 120.2(4) . 3_677 ? C8 O3 Ag1 117.5(4) . . ? C8 O3 Ag3 126.7(5) . . ? Ag1 O3 Ag3 114.1(2) . . ? C8 O4 Ag6 132.7(5) . 2_656 ? C9 O5A Ag1 113.5(6) . . ? C9 O5A Ag1 114.2(6) . 3_677 ? Ag1 O5A Ag1 74.0(2) . 3_677 ? C9 O6A Ag5 122.2(6) . 2_656 ? C9 O6A Ag8 122.1(6) . 3_677 ? Ag5 O6A Ag8 101.7(3) 2_656 3_677 ? C16 O7A Ag4 120.9(6) . . ? C16 O8A Ag3 122.0(7) . . ? C16 O8A Ag5 125.4(8) . 2_656 ? Ag3 O8A Ag5 85.3(3) . 2_656 ? C17 O9A Ag8 122.2(10) . . ? C17 O9A Ag1 109.6(6) . . ? Ag8 O9A Ag1 82.7(3) . . ? C17 O10A Ag2 126.3(7) . . ? C9 O5B Ag1 130.1(12) . 3_677 ? C9 O6B Ag1 120.0(14) . . ? C9 O6B Ag5 125.2(13) . 2_656 ? Ag1 O6B Ag5 109.7(5) . 2_656 ? C16 O7B O8B 44.0(9) . . ? C16 O7B Ag3 112.1(13) . . ? O8B O7B Ag3 70.0(9) . . ? C16 O7B Ag4 110.0(10) . . ? O8B O7B Ag4 112.3(11) . . ? Ag3 O7B Ag4 77.2(5) . . ? C16 O7B Ag5 123.6(11) . 2_656 ? O8B O7B Ag5 106.8(10) . 2_656 ? Ag3 O7B Ag5 83.4(5) . 2_656 ? Ag4 O7B Ag5 126.3(5) . 2_656 ? C16 O8B O7B 44.8(9) . . ? C16 O8B Ag3 109.0(14) . . ? O7B O8B Ag3 66.1(9) . . ? C17 O9B Ag8 120(3) . . ? C17 O10B Ag2 110.4(16) . . ? C24 O11 Ag7 123.8(5) . . ? C24 O12 Ag5 120.4(4) . . ? C24 O12 Ag3 122.5(4) . . ? Ag5 O12 Ag3 115.50(19) . . ? C24 O12 Ag6 94.0(4) . . ? Ag5 O12 Ag6 81.95(14) . . ? Ag3 O12 Ag6 106.14(18) . . ? C25 O13 Ag3 114.6(4) . . ? C25 O13 Ag6 125.9(4) . 2_656 ? Ag3 O13 Ag6 107.01(19) . 2_656 ? C25 O14 Ag4 118.0(4) . . ? C25 O14 Ag5 128.6(4) . . ? Ag4 O14 Ag5 90.00(15) . . ? C32 O15 Ag7 136.5(4) . 2_656 ? C32 O16 Ag7 118.7(4) . 4_575 ? C33 O17 Ag6 140.5(5) . . ? C33 O17 Ag2 110.5(4) . . ? Ag6 O17 Ag2 108.8(2) . . ? C33 N1 C35 120.9(7) . . ? C33 N1 C34 121.7(7) . . ? C35 N1 C34 117.4(7) . . ? O2 C1 O1 126.1(7) . . ? O2 C1 C2 119.1(6) . . ? O1 C1 C2 114.7(6) . . ? C3 C2 C7 116.7(7) . . ? C3 C2 C1 121.9(6) . . ? C7 C2 C1 121.4(6) . . ? F1 C3 C4 115.6(7) . . ? F1 C3 C2 122.3(7) . . ? C4 C3 C2 122.0(7) . . ? C5 C4 C3 120.9(7) . . ? C5 C4 F2 118.8(9) . . ? C3 C4 F2 120.3(9) . . ? F3 C5 C4 121.7(8) . . ? F3 C5 C6 119.5(9) . . ? C4 C5 C6 118.8(8) . . ? F4 C6 C7 119.3(7) . . ? F4 C6 C5 118.9(7) . . ? C7 C6 C5 121.8(8) . . ? C6 C7 C2 119.8(6) . . ? C6 C7 C8 116.5(6) . . ? C2 C7 C8 123.8(6) . . ? O4 C8 O3 126.2(7) . . ? O4 C8 C7 116.4(7) . . ? O3 C8 C7 117.4(7) . . ? O6B C9 O6A 46.3(10) . . ? O6B C9 O5A 84.4(12) . . ? O6A C9 O5A 124.8(8) . . ? O6B C9 O5B 114.5(14) . . ? O6A C9 O5B 117.5(11) . . ? O5A C9 O5B 54.6(10) . . ? O6B C9 C10 139.4(12) . . ? O6A C9 C10 114.4(7) . . ? O5A C9 C10 120.1(7) . . ? O5B C9 C10 106.1(11) . . ? C11 C10 C15 117.6(7) . . ? C11 C10 C9 117.4(7) . . ? C15 C10 C9 125.0(7) . . ? C12 C11 F5 117.9(9) . . ? C12 C11 C10 123.4(8) . . ? F5 C11 C10 118.7(8) . . ? C13 C12 C11 119.7(9) . . ? C13 C12 F6 119.4(10) . . ? C11 C12 F6 120.9(11) . . ? C12 C13 C14 121.7(9) . . ? C12 C13 F7 120.1(11) . . ? C14 C13 F7 118.1(11) . . ? F8 C14 C13 117.4(10) . . ? F8 C14 C15 122.0(9) . . ? C13 C14 C15 120.6(7) . . ? C10 C15 C14 117.1(7) . . ? C10 C15 C16 123.6(7) . . ? C14 C15 C16 119.3(7) . . ? O8A C16 O8B 46.8(11) . . ? O8A C16 O7B 54.8(9) . . ? O8B C16 O7B 91.2(16) . . ? O8A C16 O7A 127.1(9) . . ? O8B C16 O7A 111.2(12) . . ? O7B C16 O7A 85.6(10) . . ? O8A C16 C15 114.3(8) . . ? O8B C16 C15 114.0(13) . . ? O7B C16 C15 131.6(11) . . ? O7A C16 C15 118.3(8) . . ? O9A C17 O9B 24.5(13) . . ? O9A C17 O10B 110.7(14) . . ? O9B C17 O10B 130(2) . . ? O9A C17 O10A 123.5(10) . . ? O9B C17 O10A 124(2) . . ? O10B C17 O10A 43.2(13) . . ? O9A C17 C18 122.3(9) . . ? O9B C17 C18 114(2) . . ? O10B C17 C18 112.9(13) . . ? O10A C17 C18 114.1(7) . . ? C23 C18 C19 117.2(6) . . ? C23 C18 C17 120.1(6) . . ? C19 C18 C17 122.7(6) . . ? F9 C19 C20 117.4(7) . . ? F9 C19 C18 120.4(7) . . ? C20 C19 C18 122.1(7) . . ? F10 C20 C19 120.3(8) . . ? F10 C20 C21 120.3(7) . . ? C19 C20 C21 119.4(7) . . ? F11 C21 C22 120.7(7) . . ? F11 C21 C20 119.4(7) . . ? C22 C21 C20 119.9(7) . . ? F12 C22 C21 117.6(6) . . ? F12 C22 C23 120.6(6) . . ? C21 C22 C23 121.7(6) . . ? C22 C23 C18 119.6(6) . . ? C22 C23 C24 117.0(6) . . ? C18 C23 C24 123.3(6) . . ? O11 C24 O12 124.0(7) . . ? O11 C24 C23 120.1(7) . . ? O12 C24 C23 115.6(6) . . ? O13 C25 O14 125.7(6) . . ? O13 C25 C26 114.8(6) . . ? O14 C25 C26 119.1(6) . . ? C27 C26 C31 119.1(6) . . ? C27 C26 C25 115.5(6) . . ? C31 C26 C25 125.2(5) . . ? F13 C27 C28 118.1(6) . . ? F13 C27 C26 119.2(7) . . ? C28 C27 C26 122.6(7) . . ? F14 C28 C27 120.9(7) . . ? F14 C28 C29 119.7(7) . . ? C27 C28 C29 119.4(7) . . ? F15 C29 C28 120.7(7) . . ? F15 C29 C30 120.0(7) . . ? C28 C29 C30 119.3(7) . . ? F16 C30 C29 116.2(6) . . ? F16 C30 C31 121.5(6) . . ? C29 C30 C31 122.3(6) . . ? C30 C31 C26 117.3(5) . . ? C30 C31 C32 121.9(5) . . ? C26 C31 C32 120.8(6) . . ? O16 C32 O15 126.3(6) . . ? O16 C32 C31 120.2(6) . . ? O15 C32 C31 113.5(6) . . ? O17 C33 N1 126.2(7) . . ? O17 C33 H33A 116.9 . . ? N1 C33 H33A 116.9 . . ? N1 C34 H34A 109.5 . . ? N1 C34 H34B 109.5 . . ? H34A C34 H34B 109.5 . . ? N1 C34 H34C 109.5 . . ? H34A C34 H34C 109.5 . . ? H34B C34 H34C 109.5 . . ? N1 C35 H35A 109.5 . . ? N1 C35 H35B 109.5 . . ? H35A C35 H35B 109.5 . . ? N1 C35 H35C 109.5 . . ? H35A C35 H35C 109.5 . . ? H35B C35 H35C 109.5 . . ? C37B N2 C38A 174.2(15) . . ? C37B N2 C37A 45.3(12) . . ? C38A N2 C37A 132.4(18) . . ? C37B N2 C38B 126.3(13) . . ? C38A N2 C38B 52.1(13) . . ? C37A N2 C38B 81.1(14) . . ? C37B N2 C36A 63.4(12) . . ? C38A N2 C36A 118.4(16) . . ? C37A N2 C36A 108.7(16) . . ? C38B N2 C36A 170.1(14) . . ? C37B N2 C36B 124.8(12) . . ? C38A N2 C36B 57.3(13) . . ? C37A N2 C36B 170.0(15) . . ? C38B N2 C36B 108.9(11) . . ? C36A N2 C36B 61.4(12) . . ? C36A O18A Ag4 155(2) . . ? O18A C36A N2 94.9(18) . . ? O18A C36A H36A 132.6 . . ? N2 C36A H36A 132.6 . . ? N2 C37A H37A 109.5 . . ? N2 C37A H37B 109.5 . . ? N2 C37A H37C 109.5 . . ? N2 C38A H38A 109.5 . . ? N2 C38A H38B 109.5 . . ? N2 C38A H38C 109.5 . . ? C36B O18B Ag4 98.2(13) . . ? O18B C36B N2 112.6(15) . . ? O18B C36B H36B 123.7 . . ? N2 C36B H36B 123.7 . . ? N2 C37B H37D 109.5 . . ? N2 C37B H37E 109.5 . . ? H37D C37B H37E 109.5 . . ? N2 C37B H37F 109.5 . . ? H37D C37B H37F 109.5 . . ? H37E C37B H37F 109.5 . . ? N2 C38B H38D 109.5 . . ? N2 C38B H38E 109.5 . . ? H38D C38B H38E 109.5 . . ? N2 C38B H38F 109.5 . . ? H38D C38B H38F 109.5 . . ? H38E C38B H38F 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag O8A Ag3 Ag4 O14 176.8(3) . . . . ? O13 Ag3 Ag4 O14 36.85(18) . . . . ? O7B Ag3 Ag4 O14 163.2(5) . . . . ? O12 Ag3 Ag4 O14 -67.62(17) . . . . ? O3 Ag3 Ag4 O14 113.2(3) . . . . ? O8B Ag3 Ag4 O14 -159.2(5) . . . . ? Ag5 Ag3 Ag4 O14 127.11(12) 2_656 . . . ? O8A Ag3 Ag4 O7A -24.6(3) . . . . ? O13 Ag3 Ag4 O7A -164.6(2) . . . . ? O7B Ag3 Ag4 O7A -38.2(5) . . . . ? O12 Ag3 Ag4 O7A 91.0(2) . . . . ? O3 Ag3 Ag4 O7A -88.2(3) . . . . ? O8B Ag3 Ag4 O7A -0.7(5) . . . . ? Ag5 Ag3 Ag4 O7A -74.3(2) 2_656 . . . ? O8A Ag3 Ag4 O18A 26.4(18) . . . . ? O13 Ag3 Ag4 O18A -113.5(17) . . . . ? O7B Ag3 Ag4 O18A 12.8(18) . . . . ? O12 Ag3 Ag4 O18A 142.0(17) . . . . ? O3 Ag3 Ag4 O18A -37.1(18) . . . . ? O8B Ag3 Ag4 O18A 50.4(18) . . . . ? Ag5 Ag3 Ag4 O18A -23.2(17) 2_656 . . . ? O8A Ag3 Ag4 O18B 57.6(9) . . . . ? O13 Ag3 Ag4 O18B -82.4(9) . . . . ? O7B Ag3 Ag4 O18B 44.0(10) . . . . ? O12 Ag3 Ag4 O18B 173.2(9) . . . . ? O3 Ag3 Ag4 O18B -6.0(9) . . . . ? O8B Ag3 Ag4 O18B 81.6(10) . . . . ? Ag5 Ag3 Ag4 O18B 7.9(9) 2_656 . . . ? O8A Ag3 Ag4 O7B 13.6(5) . . . . ? O13 Ag3 Ag4 O7B -126.3(5) . . . . ? O12 Ag3 Ag4 O7B 129.2(5) . . . . ? O3 Ag3 Ag4 O7B -49.9(5) . . . . ? O8B Ag3 Ag4 O7B 37.6(6) . . . . ? Ag5 Ag3 Ag4 O7B -36.1(5) 2_656 . . . ? O12 Ag5 Ag6 O17 49.0(5) . . . . ? O6B Ag5 Ag6 O17 -133.3(10) 2_646 . . . ? O6A Ag5 Ag6 O17 -85.9(14) 2_646 . . . ? O7B Ag5 Ag6 O17 139.7(6) 2_646 . . . ? O8A Ag5 Ag6 O17 161.0(5) 2_646 . . . ? O14 Ag5 Ag6 O17 -16.9(4) . . . . ? Ag3 Ag5 Ag6 O17 -178.9(4) 2_646 . . . ? O12 Ag5 Ag6 O4 139.4(2) . . . 2_646 ? O6B Ag5 Ag6 O4 -42.9(10) 2_646 . . 2_646 ? O6A Ag5 Ag6 O4 4.6(13) 2_646 . . 2_646 ? O7B Ag5 Ag6 O4 -129.8(5) 2_646 . . 2_646 ? O8A Ag5 Ag6 O4 -108.6(3) 2_646 . . 2_646 ? O14 Ag5 Ag6 O4 73.5(2) . . . 2_646 ? Ag3 Ag5 Ag6 O4 -88.50(17) 2_646 . . 2_646 ? O12 Ag5 Ag6 O13 -128.88(19) . . . 2_646 ? O6B Ag5 Ag6 O13 48.9(10) 2_646 . . 2_646 ? O6A Ag5 Ag6 O13 96.3(13) 2_646 . . 2_646 ? O7B Ag5 Ag6 O13 -38.1(5) 2_646 . . 2_646 ? O8A Ag5 Ag6 O13 -16.9(3) 2_646 . . 2_646 ? O14 Ag5 Ag6 O13 165.24(16) . . . 2_646 ? Ag3 Ag5 Ag6 O13 3.22(11) 2_646 . . 2_646 ? O6B Ag5 Ag6 O12 177.7(10) 2_646 . . . ? O6A Ag5 Ag6 O12 -134.8(13) 2_646 . . . ? O7B Ag5 Ag6 O12 90.8(5) 2_646 . . . ? O8A Ag5 Ag6 O12 112.0(3) 2_646 . . . ? O14 Ag5 Ag6 O12 -65.87(18) . . . . ? Ag3 Ag5 Ag6 O12 132.10(15) 2_646 . . . ? O10A Ag2 Ag8 O1 172.3(4) . . . 3_677 ? O2 Ag2 Ag8 O1 -10.2(2) 3_677 . . 3_677 ? O10B Ag2 Ag8 O1 148.9(6) . . . 3_677 ? O17 Ag2 Ag8 O1 -88.8(7) . . . 3_677 ? Ag7 Ag2 Ag8 O1 -90.74(16) 3_667 . . 3_677 ? O10A Ag2 Ag8 O9A 18.6(4) . . . . ? O2 Ag2 Ag8 O9A -164.0(2) 3_677 . . . ? O10B Ag2 Ag8 O9A -4.9(6) . . . . ? O17 Ag2 Ag8 O9A 117.5(8) . . . . ? Ag7 Ag2 Ag8 O9A 115.47(19) 3_667 . . . ? O10A Ag2 Ag8 O9B 5.7(8) . . . . ? O2 Ag2 Ag8 O9B -176.9(7) 3_677 . . . ? O10B Ag2 Ag8 O9B -17.8(9) . . . . ? O17 Ag2 Ag8 O9B 104.6(10) . . . . ? Ag7 Ag2 Ag8 O9B 102.6(7) 3_667 . . . ? O10A Ag2 Ag8 O6A 93.4(5) . . . 3_677 ? O2 Ag2 Ag8 O6A -89.2(5) 3_677 . . 3_677 ? O10B Ag2 Ag8 O6A 69.9(7) . . . 3_677 ? O17 Ag2 Ag8 O6A -167.7(9) . . . 3_677 ? Ag7 Ag2 Ag8 O6A -169.7(5) 3_667 . . 3_677 ? O10A Ag2 Ag8 Ag1 71.5(3) . . . . ? O2 Ag2 Ag8 Ag1 -111.01(14) 3_677 . . . ? O10B Ag2 Ag8 Ag1 48.1(6) . . . . ? O17 Ag2 Ag8 Ag1 170.5(7) . . . . ? Ag7 Ag2 Ag8 Ag1 168.47(2) 3_667 . . . ? O5B Ag1 Ag8 O1 111.9(5) 3_677 . . 3_677 ? O6B Ag1 Ag8 O1 -29.8(6) . . . 3_677 ? O5A Ag1 Ag8 O1 -26.8(2) . . . 3_677 ? O3 Ag1 Ag8 O1 -137.9(2) . . . 3_677 ? O9A Ag1 Ag8 O1 -160.8(3) . . . 3_677 ? O5A Ag1 Ag8 O1 83.4(2) 3_677 . . 3_677 ? Ag1 Ag1 Ag8 O1 31.47(12) 3_677 . . 3_677 ? O5B Ag1 Ag8 O9A -87.2(6) 3_677 . . . ? O6B Ag1 Ag8 O9A 131.0(7) . . . . ? O5A Ag1 Ag8 O9A 134.0(4) . . . . ? O3 Ag1 Ag8 O9A 22.9(4) . . . . ? O5A Ag1 Ag8 O9A -115.7(4) 3_677 . . . ? Ag1 Ag1 Ag8 O9A -167.7(3) 3_677 . . . ? O5B Ag1 Ag8 O9B -86.6(9) 3_677 . . . ? O6B Ag1 Ag8 O9B 131.6(9) . . . . ? O5A Ag1 Ag8 O9B 134.6(8) . . . . ? O3 Ag1 Ag8 O9B 23.5(8) . . . . ? O9A Ag1 Ag8 O9B 0.6(10) . . . . ? O5A Ag1 Ag8 O9B -115.1(8) 3_677 . . . ? Ag1 Ag1 Ag8 O9B -167.1(7) 3_677 . . . ? O5B Ag1 Ag8 O6A 16.3(6) 3_677 . . 3_677 ? O6B Ag1 Ag8 O6A -125.5(6) . . . 3_677 ? O5A Ag1 Ag8 O6A -122.5(3) . . . 3_677 ? O3 Ag1 Ag8 O6A 126.4(3) . . . 3_677 ? O9A Ag1 Ag8 O6A 103.5(4) . . . 3_677 ? O5A Ag1 Ag8 O6A -12.2(3) 3_677 . . 3_677 ? Ag1 Ag1 Ag8 O6A -64.2(2) 3_677 . . 3_677 ? O5B Ag1 Ag8 Ag2 -173.5(5) 3_677 . . . ? O6B Ag1 Ag8 Ag2 44.8(6) . . . . ? O5A Ag1 Ag8 Ag2 47.7(2) . . . . ? O3 Ag1 Ag8 Ag2 -63.32(19) . . . . ? O9A Ag1 Ag8 Ag2 -86.2(3) . . . . ? O5A Ag1 Ag8 Ag2 158.03(19) 3_677 . . . ? Ag1 Ag1 Ag8 Ag2 106.05(3) 3_677 . . . ? O5B Ag1 O3 C8 -47.4(9) 3_677 . . . ? O6B Ag1 O3 C8 98.4(8) . . . . ? O5A Ag1 O3 C8 125.6(6) . . . . ? O9A Ag1 O3 C8 -123.1(7) . . . . ? O5A Ag1 O3 C8 -20.4(8) 3_677 . . . ? Ag1 Ag1 O3 C8 65.4(7) 3_677 . . . ? Ag8 Ag1 O3 C8 -139.3(5) . . . . ? O5B Ag1 O3 Ag3 146.5(6) 3_677 . . . ? O6B Ag1 O3 Ag3 -67.7(6) . . . . ? O5A Ag1 O3 Ag3 -40.5(4) . . . . ? O9A Ag1 O3 Ag3 70.8(4) . . . . ? O5A Ag1 O3 Ag3 173.5(3) 3_677 . . . ? Ag1 Ag1 O3 Ag3 -100.7(4) 3_677 . . . ? Ag8 Ag1 O3 Ag3 54.6(4) . . . . ? O8A Ag3 O3 C8 -119.8(8) . . . . ? O13 Ag3 O3 C8 11.9(7) . . . . ? O7B Ag3 O3 C8 -96.7(8) . . . . ? O12 Ag3 O3 C8 123.1(7) . . . . ? O8B Ag3 O3 C8 -140.9(8) . . . . ? Ag4 Ag3 O3 C8 -58.0(8) . . . . ? Ag5 Ag3 O3 C8 -74.7(7) 2_656 . . . ? O8A Ag3 O3 Ag1 44.7(4) . . . . ? O13 Ag3 O3 Ag1 176.5(3) . . . . ? O7B Ag3 O3 Ag1 67.9(5) . . . . ? O12 Ag3 O3 Ag1 -72.3(4) . . . . ? O8B Ag3 O3 Ag1 23.7(5) . . . . ? Ag4 Ag3 O3 Ag1 106.6(3) . . . . ? Ag5 Ag3 O3 Ag1 89.9(3) 2_656 . . . ? O5B Ag1 O5A C9 127.2(10) 3_677 . . . ? O6B Ag1 O5A C9 -2.1(9) . . . . ? O3 Ag1 O5A C9 -44.7(7) . . . . ? O9A Ag1 O5A C9 -145.2(6) . . . . ? O5A Ag1 O5A C9 109.9(7) 3_677 . . . ? Ag1 Ag1 O5A C9 109.9(7) 3_677 . . . ? Ag8 Ag1 O5A C9 -178.2(7) . . . . ? O5B Ag1 O5A Ag1 17.2(7) 3_677 . . 3_677 ? O6B Ag1 O5A Ag1 -112.1(8) . . . 3_677 ? O3 Ag1 O5A Ag1 -154.63(19) . . . 3_677 ? O9A Ag1 O5A Ag1 104.9(2) . . . 3_677 ? O5A Ag1 O5A Ag1 0.0 3_677 . . 3_677 ? Ag8 Ag1 O5A Ag1 71.84(11) . . . 3_677 ? O14 Ag4 O7A C16 70.7(8) . . . . ? O18A Ag4 O7A C16 -121.6(13) . . . . ? O18B Ag4 O7A C16 -113.9(10) . . . . ? O7B Ag4 O7A C16 -8.4(9) . . . . ? Ag3 Ag4 O7A C16 36.3(7) . . . . ? O13 Ag3 O8A C16 86.1(10) . . . . ? O7B Ag3 O8A C16 52.9(10) . . . . ? O12 Ag3 O8A C16 -47.5(11) . . . . ? O3 Ag3 O8A C16 179.3(10) . . . . ? O8B Ag3 O8A C16 -63.3(10) . . . . ? Ag4 Ag3 O8A C16 29.8(9) . . . . ? Ag5 Ag3 O8A C16 129.3(11) 2_656 . . . ? O13 Ag3 O8A Ag5 -43.2(4) . . . 2_656 ? O7B Ag3 O8A Ag5 -76.3(10) . . . 2_656 ? O12 Ag3 O8A Ag5 -176.83(15) . . . 2_656 ? O3 Ag3 O8A Ag5 50.0(2) . . . 2_656 ? O8B Ag3 O8A Ag5 167.4(13) . . . 2_656 ? Ag4 Ag3 O8A Ag5 -99.5(2) . . . 2_656 ? O1 Ag8 O9A C17 -74.9(8) 3_677 . . . ? O9B Ag8 O9A C17 74(4) . . . . ? O6A Ag8 O9A C17 177.8(7) 3_677 . . . ? Ag2 Ag8 O9A C17 -27.9(7) . . . . ? Ag1 Ag8 O9A C17 -108.6(8) . . . . ? O1 Ag8 O9A Ag1 33.7(5) 3_677 . . . ? O9B Ag8 O9A Ag1 -178(4) . . . . ? O6A Ag8 O9A Ag1 -73.6(3) 3_677 . . . ? Ag2 Ag8 O9A Ag1 80.74(19) . . . . ? O5B Ag1 O9A C17 -158.8(11) 3_677 . . . ? O6B Ag1 O9A C17 36.8(14) . . . . ? O5A Ag1 O9A C17 73.9(10) . . . . ? O3 Ag1 O9A C17 -42.4(10) . . . . ? O5A Ag1 O9A C17 -176.0(9) 3_677 . . . ? Ag1 Ag1 O9A C17 133.9(9) 3_677 . . . ? Ag8 Ag1 O9A C17 121.6(11) . . . . ? O5B Ag1 O9A Ag8 79.6(4) 3_677 . . . ? O6B Ag1 O9A Ag8 -84.7(6) . . . . ? O5A Ag1 O9A Ag8 -47.7(3) . . . . ? O3 Ag1 O9A Ag8 -164.0(2) . . . . ? O5A Ag1 O9A Ag8 62.4(3) 3_677 . . . ? Ag1 Ag1 O9A Ag8 12.3(3) 3_677 . . . ? O2 Ag2 O10A C17 -33(2) 3_677 . . . ? O10B Ag2 O10A C17 64.8(13) . . . . ? O17 Ag2 O10A C17 167.7(10) . . . . ? Ag8 Ag2 O10A C17 -22.3(10) . . . . ? Ag7 Ag2 O10A C17 -91.3(10) 3_667 . . . ? O5B Ag1 O6B C9 -93.3(17) 3_677 . . . ? O5A Ag1 O6B C9 2.3(10) . . . . ? O3 Ag1 O6B C9 143.8(16) . . . . ? O9A Ag1 O6B C9 60.9(18) . . . . ? O5A Ag1 O6B C9 -82.3(16) 3_677 . . . ? Ag1 Ag1 O6B C9 -49.3(14) 3_677 . . . ? Ag8 Ag1 O6B C9 6.7(18) . . . . ? O5B Ag1 O6B Ag5 110.7(10) 3_677 . . 2_656 ? O5A Ag1 O6B Ag5 -153.6(13) . . . 2_656 ? O3 Ag1 O6B Ag5 -12.2(6) . . . 2_656 ? O9A Ag1 O6B Ag5 -95.0(8) . . . 2_656 ? O5A Ag1 O6B Ag5 121.8(6) 3_677 . . 2_656 ? Ag1 Ag1 O6B Ag5 154.7(8) 3_677 . . 2_656 ? Ag8 Ag1 O6B Ag5 -149.3(5) . . . 2_656 ? O8A Ag3 O7B C16 -44.4(9) . . . . ? O13 Ag3 O7B C16 160.7(10) . . . . ? O12 Ag3 O7B C16 48.3(12) . . . . ? O3 Ag3 O7B C16 -99.5(11) . . . . ? O8B Ag3 O7B C16 -13.1(10) . . . . ? Ag4 Ag3 O7B C16 106.7(11) . . . . ? Ag5 Ag3 O7B C16 -123.7(13) 2_656 . . . ? O8A Ag3 O7B O8B -31.3(8) . . . . ? O13 Ag3 O7B O8B 173.9(8) . . . . ? O12 Ag3 O7B O8B 61.4(9) . . . . ? O3 Ag3 O7B O8B -86.4(8) . . . . ? Ag4 Ag3 O7B O8B 119.8(9) . . . . ? Ag5 Ag3 O7B O8B -110.6(9) 2_656 . . . ? O8A Ag3 O7B Ag4 -151.1(11) . . . . ? O13 Ag3 O7B Ag4 54.0(4) . . . . ? O12 Ag3 O7B Ag4 -58.4(4) . . . . ? O3 Ag3 O7B Ag4 153.8(3) . . . . ? O8B Ag3 O7B Ag4 -119.8(9) . . . . ? Ag5 Ag3 O7B Ag4 129.6(5) 2_656 . . . ? O8A Ag3 O7B Ag5 79.3(9) . . . 2_656 ? O13 Ag3 O7B Ag5 -75.6(4) . . . 2_656 ? O12 Ag3 O7B Ag5 171.99(18) . . . 2_656 ? O3 Ag3 O7B Ag5 24.2(4) . . . 2_656 ? O8B Ag3 O7B Ag5 110.6(9) . . . 2_656 ? Ag4 Ag3 O7B Ag5 -129.6(5) . . . 2_656 ? O14 Ag4 O7B C16 -127.8(11) . . . . ? O7A Ag4 O7B C16 7.7(8) . . . . ? O18A Ag4 O7B C16 77.2(16) . . . . ? O18B Ag4 O7B C16 92.0(13) . . . . ? Ag3 Ag4 O7B C16 -109.1(14) . . . . ? O14 Ag4 O7B O8B -80.4(10) . . . . ? O7A Ag4 O7B O8B 55.0(9) . . . . ? O18A Ag4 O7B O8B 124.5(13) . . . . ? O18B Ag4 O7B O8B 139.3(11) . . . . ? Ag3 Ag4 O7B O8B -61.8(10) . . . . ? O14 Ag4 O7B Ag3 -18.6(5) . . . . ? O7A Ag4 O7B Ag3 116.8(8) . . . . ? O18A Ag4 O7B Ag3 -173.7(9) . . . . ? O18B Ag4 O7B Ag3 -158.9(5) . . . . ? O14 Ag4 O7B Ag5 53.1(11) . . . 2_656 ? O7A Ag4 O7B Ag5 -171.4(15) . . . 2_656 ? O18A Ag4 O7B Ag5 -101.9(13) . . . 2_656 ? O18B Ag4 O7B Ag5 -87.1(10) . . . 2_656 ? Ag3 Ag4 O7B Ag5 71.8(8) . . . 2_656 ? Ag3 O7B O8B C16 -162.4(13) . . . . ? Ag4 O7B O8B C16 -96.2(12) . . . . ? Ag5 O7B O8B C16 121.4(14) 2_656 . . . ? C16 O7B O8B Ag3 162.4(13) . . . . ? Ag4 O7B O8B Ag3 66.2(7) . . . . ? Ag5 O7B O8B Ag3 -76.3(7) 2_656 . . . ? O8A Ag3 O8B C16 51.1(9) . . . . ? O13 Ag3 O8B C16 1(2) . . . . ? O7B Ag3 O8B C16 13.0(10) . . . . ? O12 Ag3 O8B C16 -114.5(13) . . . . ? O3 Ag3 O8B C16 113.9(13) . . . . ? Ag4 Ag3 O8B C16 -31.5(12) . . . . ? Ag5 Ag3 O8B C16 61.2(12) 2_656 . . . ? O8A Ag3 O8B O7B 38.1(9) . . . . ? O13 Ag3 O8B O7B -12.0(15) . . . . ? O12 Ag3 O8B O7B -127.5(8) . . . . ? O3 Ag3 O8B O7B 100.9(8) . . . . ? Ag4 Ag3 O8B O7B -44.6(7) . . . . ? Ag5 Ag3 O8B O7B 48.2(7) 2_656 . . . ? O1 Ag8 O9B C17 -25(4) 3_677 . . . ? O9A Ag8 O9B C17 -69(3) . . . . ? O6A Ag8 O9B C17 -147(2) 3_677 . . . ? Ag2 Ag8 O9B C17 7(2) . . . . ? Ag1 Ag8 O9B C17 -71.4(19) . . . . ? O10A Ag2 O10B C17 -52.1(10) . . . . ? O2 Ag2 O10B C17 93.3(18) 3_677 . . . ? O17 Ag2 O10B C17 -134.2(15) . . . . ? Ag8 Ag2 O10B C17 37.1(15) . . . . ? Ag7 Ag2 O10B C17 -25.8(19) 3_667 . . . ? O16 Ag7 O11 C24 -26.2(7) 4_576 . . . ? O15 Ag7 O11 C24 142.1(7) 2_646 . . . ? Ag7 Ag7 O11 C24 83.0(7) 3_667 . . . ? Ag2 Ag7 O11 C24 -142.2(5) 3_667 . . . ? O6B Ag5 O12 C24 -87.4(13) 2_646 . . . ? O6A Ag5 O12 C24 -98.3(6) 2_646 . . . ? O7B Ag5 O12 C24 -4.0(7) 2_646 . . . ? O8A Ag5 O12 C24 -5.4(6) 2_646 . . . ? O14 Ag5 O12 C24 -150.3(5) . . . . ? Ag6 Ag5 O12 C24 89.9(5) . . . . ? Ag3 Ag5 O12 C24 41.5(5) 2_646 . . . ? O6B Ag5 O12 Ag3 78.6(12) 2_646 . . . ? O6A Ag5 O12 Ag3 67.7(3) 2_646 . . . ? O7B Ag5 O12 Ag3 161.9(5) 2_646 . . . ? O8A Ag5 O12 Ag3 160.5(3) 2_646 . . . ? O14 Ag5 O12 Ag3 15.7(2) . . . . ? Ag6 Ag5 O12 Ag3 -104.1(2) . . . . ? Ag3 Ag5 O12 Ag3 -152.50(16) 2_646 . . . ? O6B Ag5 O12 Ag6 -177.3(12) 2_646 . . . ? O6A Ag5 O12 Ag6 171.8(2) 2_646 . . . ? O7B Ag5 O12 Ag6 -94.0(4) 2_646 . . . ? O8A Ag5 O12 Ag6 -95.4(2) 2_646 . . . ? O14 Ag5 O12 Ag6 119.82(15) . . . . ? Ag3 Ag5 O12 Ag6 -48.40(12) 2_646 . . . ? O8A Ag3 O12 C24 -90.8(6) . . . . ? O13 Ag3 O12 C24 122.6(5) . . . . ? O7B Ag3 O12 C24 -122.1(6) . . . . ? O3 Ag3 O12 C24 14.0(6) . . . . ? O8B Ag3 O12 C24 -84.5(6) . . . . ? Ag4 Ag3 O12 C24 -165.4(5) . . . . ? Ag5 Ag3 O12 C24 -99.6(6) 2_656 . . . ? O8A Ag3 O12 Ag5 103.5(3) . . . . ? O13 Ag3 O12 Ag5 -43.1(2) . . . . ? O7B Ag3 O12 Ag5 72.3(5) . . . . ? O3 Ag3 O12 Ag5 -151.7(2) . . . . ? O8B Ag3 O12 Ag5 109.8(4) . . . . ? Ag4 Ag3 O12 Ag5 28.97(19) . . . . ? Ag5 Ag3 O12 Ag5 94.7(4) 2_656 . . . ? O8A Ag3 O12 Ag6 14.9(3) . . . . ? O13 Ag3 O12 Ag6 -131.73(18) . . . . ? O7B Ag3 O12 Ag6 -16.4(4) . . . . ? O3 Ag3 O12 Ag6 119.7(2) . . . . ? O8B Ag3 O12 Ag6 21.2(4) . . . . ? Ag4 Ag3 O12 Ag6 -59.69(13) . . . . ? Ag5 Ag3 O12 Ag6 6.1(5) 2_656 . . . ? O17 Ag6 O12 C24 74.8(4) . . . . ? O4 Ag6 O12 C24 -152.1(4) 2_646 . . . ? O13 Ag6 O12 C24 -59.4(4) 2_646 . . . ? Ag5 Ag6 O12 C24 -120.2(4) . . . . ? O17 Ag6 O12 Ag5 -165.09(17) . . . . ? O4 Ag6 O12 Ag5 -31.98(18) 2_646 . . . ? O13 Ag6 O12 Ag5 60.76(18) 2_646 . . . ? O17 Ag6 O12 Ag3 -50.8(2) . . . . ? O4 Ag6 O12 Ag3 82.3(2) 2_646 . . . ? O13 Ag6 O12 Ag3 175.07(14) 2_646 . . . ? Ag5 Ag6 O12 Ag3 114.3(2) . . . . ? O8A Ag3 O13 C25 -108.1(5) . . . . ? O7B Ag3 O13 C25 -92.3(6) . . . . ? O12 Ag3 O13 C25 29.1(5) . . . . ? O3 Ag3 O13 C25 163.4(5) . . . . ? O8B Ag3 O13 C25 -83.7(11) . . . . ? Ag4 Ag3 O13 C25 -50.1(4) . . . . ? Ag5 Ag3 O13 C25 -140.1(4) 2_656 . . . ? O8A Ag3 O13 Ag6 36.4(4) . . . 2_656 ? O7B Ag3 O13 Ag6 52.2(4) . . . 2_656 ? O12 Ag3 O13 Ag6 173.65(17) . . . 2_656 ? O3 Ag3 O13 Ag6 -52.1(2) . . . 2_656 ? O8B Ag3 O13 Ag6 60.9(11) . . . 2_656 ? Ag4 Ag3 O13 Ag6 94.48(16) . . . 2_656 ? Ag5 Ag3 O13 Ag6 4.45(16) 2_656 . . 2_656 ? O7A Ag4 O14 C25 -82.5(5) . . . . ? O18A Ag4 O14 C25 113.9(15) . . . . ? O18B Ag4 O14 C25 102.6(9) . . . . ? O7B Ag4 O14 C25 -32.7(6) . . . . ? Ag3 Ag4 O14 C25 -47.5(4) . . . . ? O7A Ag4 O14 Ag5 52.4(4) . . . . ? O18A Ag4 O14 Ag5 -111.1(14) . . . . ? O18B Ag4 O14 Ag5 -122.4(8) . . . . ? O7B Ag4 O14 Ag5 102.2(5) . . . . ? Ag3 Ag4 O14 Ag5 87.43(10) . . . . ? O12 Ag5 O14 C25 51.9(6) . . . . ? O6B Ag5 O14 C25 -107.5(7) 2_646 . . . ? O6A Ag5 O14 C25 -90.8(6) 2_646 . . . ? O7B Ag5 O14 C25 -37.1(9) 2_646 . . . ? O8A Ag5 O14 C25 -79.5(7) 2_646 . . . ? Ag6 Ag5 O14 C25 97.5(5) . . . . ? Ag3 Ag5 O14 C25 -169.0(4) 2_646 . . . ? O12 Ag5 O14 Ag4 -75.02(17) . . . . ? O6B Ag5 O14 Ag4 125.5(4) 2_646 . . . ? O6A Ag5 O14 Ag4 142.2(3) 2_646 . . . ? O7B Ag5 O14 Ag4 -164.1(7) 2_646 . . . ? O8A Ag5 O14 Ag4 153.5(3) 2_646 . . . ? Ag6 Ag5 O14 Ag4 -29.47(14) . . . . ? Ag3 Ag5 O14 Ag4 64.0(4) 2_646 . . . ? O4 Ag6 O17 C33 40.2(9) 2_646 . . . ? O13 Ag6 O17 C33 -63.5(9) 2_646 . . . ? O12 Ag6 O17 C33 158.7(8) . . . . ? Ag5 Ag6 O17 C33 118.7(8) . . . . ? O4 Ag6 O17 Ag2 -134.4(2) 2_646 . . . ? O13 Ag6 O17 Ag2 121.9(2) 2_646 . . . ? O12 Ag6 O17 Ag2 -15.9(3) . . . . ? Ag5 Ag6 O17 Ag2 -55.8(5) . . . . ? O10A Ag2 O17 C33 176.7(6) . . . . ? O2 Ag2 O17 C33 1.7(5) 3_677 . . . ? O10B Ag2 O17 C33 -159.9(7) . . . . ? Ag8 Ag2 O17 C33 79.5(9) . . . . ? Ag7 Ag2 O17 C33 81.4(5) 3_667 . . . ? O10A Ag2 O17 Ag6 -6.9(4) . . . . ? O2 Ag2 O17 Ag6 178.0(2) 3_677 . . . ? O10B Ag2 O17 Ag6 16.4(6) . . . . ? Ag8 Ag2 O17 Ag6 -104.2(7) . . . . ? Ag7 Ag2 O17 Ag6 -102.3(2) 3_667 . . . ? Ag2 O2 C1 O1 20.6(10) 3_677 . . . ? Ag2 O2 C1 C2 -156.9(5) 3_677 . . . ? Ag8 O1 C1 O2 -5.7(11) 3_677 . . . ? Ag8 O1 C1 C2 172.0(4) 3_677 . . . ? O2 C1 C2 C3 2.8(10) . . . . ? O1 C1 C2 C3 -175.1(6) . . . . ? O2 C1 C2 C7 -178.7(6) . . . . ? O1 C1 C2 C7 3.5(9) . . . . ? C7 C2 C3 F1 179.6(6) . . . . ? C1 C2 C3 F1 -1.8(11) . . . . ? C7 C2 C3 C4 -0.6(11) . . . . ? C1 C2 C3 C4 178.0(7) . . . . ? F1 C3 C4 C5 178.8(8) . . . . ? C2 C3 C4 C5 -1.0(13) . . . . ? F1 C3 C4 F2 -1.2(12) . . . . ? C2 C3 C4 F2 179.0(7) . . . . ? C3 C4 C5 F3 -178.7(8) . . . . ? F2 C4 C5 F3 1.3(14) . . . . ? C3 C4 C5 C6 1.5(14) . . . . ? F2 C4 C5 C6 -178.5(8) . . . . ? F3 C5 C6 F4 0.5(12) . . . . ? C4 C5 C6 F4 -179.7(7) . . . . ? F3 C5 C6 C7 179.8(7) . . . . ? C4 C5 C6 C7 -0.4(13) . . . . ? F4 C6 C7 C2 178.1(6) . . . . ? C5 C6 C7 C2 -1.2(11) . . . . ? F4 C6 C7 C8 -1.8(10) . . . . ? C5 C6 C7 C8 178.9(7) . . . . ? C3 C2 C7 C6 1.6(9) . . . . ? C1 C2 C7 C6 -177.0(6) . . . . ? C3 C2 C7 C8 -178.5(6) . . . . ? C1 C2 C7 C8 2.9(10) . . . . ? Ag6 O4 C8 O3 -47.8(11) 2_656 . . . ? Ag6 O4 C8 C7 128.1(6) 2_656 . . . ? Ag1 O3 C8 O4 -120.2(7) . . . . ? Ag3 O3 C8 O4 43.9(11) . . . . ? Ag1 O3 C8 C7 63.9(8) . . . . ? Ag3 O3 C8 C7 -132.0(6) . . . . ? C6 C7 C8 O4 -91.4(8) . . . . ? C2 C7 C8 O4 88.7(8) . . . . ? C6 C7 C8 O3 84.9(8) . . . . ? C2 C7 C8 O3 -95.0(8) . . . . ? Ag1 O6B C9 O6A 149(2) . . . . ? Ag5 O6B C9 O6A -58.5(14) 2_656 . . . ? Ag1 O6B C9 O5A -2.9(13) . . . . ? Ag5 O6B C9 O5A 149.1(15) 2_656 . . . ? Ag1 O6B C9 O5B 44(2) . . . . ? Ag5 O6B C9 O5B -164.0(14) 2_656 . . . ? Ag1 O6B C9 C10 -134.2(12) . . . . ? Ag5 O6B C9 C10 18(3) 2_656 . . . ? Ag5 O6A C9 O6B 55.0(14) 2_656 . . . ? Ag8 O6A C9 O6B -77.8(15) 3_677 . . . ? Ag5 O6A C9 O5A 89.1(10) 2_656 . . . ? Ag8 O6A C9 O5A -43.6(13) 3_677 . . . ? Ag5 O6A C9 O5B 153.5(12) 2_656 . . . ? Ag8 O6A C9 O5B 20.8(15) 3_677 . . . ? Ag5 O6A C9 C10 -81.1(9) 2_656 . . . ? Ag8 O6A C9 C10 146.2(6) 3_677 . . . ? Ag1 O5A C9 O6B 2.7(12) . . . . ? Ag1 O5A C9 O6B 85.0(11) 3_677 . . . ? Ag1 O5A C9 O6A -21.4(12) . . . . ? Ag1 O5A C9 O6A 60.9(12) 3_677 . . . ? Ag1 O5A C9 O5B -122.7(13) . . . . ? Ag1 O5A C9 O5B -40.4(11) 3_677 . . . ? Ag1 O5A C9 C10 148.3(6) . . . . ? Ag1 O5A C9 C10 -129.4(6) 3_677 . . . ? Ag1 O5B C9 O6B -3(2) 3_677 . . . ? Ag1 O5B C9 O6A -55(2) 3_677 . . . ? Ag1 O5B C9 O5A 60.3(14) 3_677 . . . ? Ag1 O5B C9 C10 176.1(13) 3_677 . . . ? O6B C9 C10 C11 -142.2(19) . . . . ? O6A C9 C10 C11 -91.7(10) . . . . ? O5A C9 C10 C11 97.6(10) . . . . ? O5B C9 C10 C11 39.5(13) . . . . ? O6B C9 C10 C15 36(2) . . . . ? O6A C9 C10 C15 86.2(10) . . . . ? O5A C9 C10 C15 -84.5(10) . . . . ? O5B C9 C10 C15 -142.6(12) . . . . ? C15 C10 C11 C12 0.6(12) . . . . ? C9 C10 C11 C12 178.6(8) . . . . ? C15 C10 C11 F5 179.8(6) . . . . ? C9 C10 C11 F5 -2.2(10) . . . . ? F5 C11 C12 C13 -179.6(9) . . . . ? C10 C11 C12 C13 -0.4(15) . . . . ? F5 C11 C12 F6 0.7(14) . . . . ? C10 C11 C12 F6 180.0(8) . . . . ? C11 C12 C13 C14 0.0(17) . . . . ? F6 C12 C13 C14 179.7(9) . . . . ? C11 C12 C13 F7 -179.5(9) . . . . ? F6 C12 C13 F7 0.2(16) . . . . ? C12 C13 C14 F8 179.1(9) . . . . ? F7 C13 C14 F8 -1.5(14) . . . . ? C12 C13 C14 C15 0.2(15) . . . . ? F7 C13 C14 C15 179.7(8) . . . . ? C11 C10 C15 C14 -0.3(9) . . . . ? C9 C10 C15 C14 -178.2(7) . . . . ? C11 C10 C15 C16 175.8(7) . . . . ? C9 C10 C15 C16 -2.0(10) . . . . ? F8 C14 C15 C10 -178.8(7) . . . . ? C13 C14 C15 C10 0.0(12) . . . . ? F8 C14 C15 C16 4.9(11) . . . . ? C13 C14 C15 C16 -176.3(8) . . . . ? Ag3 O8A C16 O8B 73.7(16) . . . . ? Ag5 O8A C16 O8B -177.4(19) 2_656 . . . ? Ag3 O8A C16 O7B -60.5(12) . . . . ? Ag5 O8A C16 O7B 48.4(13) 2_656 . . . ? Ag3 O8A C16 O7A -11.2(16) . . . . ? Ag5 O8A C16 O7A 97.7(10) 2_656 . . . ? Ag3 O8A C16 C15 174.5(6) . . . . ? Ag5 O8A C16 C15 -76.6(10) 2_656 . . . ? O7B O8B C16 O8A -35.9(15) . . . . ? Ag3 O8B C16 O8A -52.9(12) . . . . ? Ag3 O8B C16 O7B -17.0(13) . . . . ? O7B O8B C16 O7A 85.7(12) . . . . ? Ag3 O8B C16 O7A 68.7(13) . . . . ? O7B O8B C16 C15 -137.4(13) . . . . ? Ag3 O8B C16 C15 -154.5(7) . . . . ? O8B O7B C16 O8A 31.5(13) . . . . ? Ag3 O7B C16 O8A 49.4(9) . . . . ? Ag4 O7B C16 O8A 133.3(15) . . . . ? Ag5 O7B C16 O8A -47.6(11) 2_656 . . . ? Ag3 O7B C16 O8B 17.9(14) . . . . ? Ag4 O7B C16 O8B 101.8(13) . . . . ? Ag5 O7B C16 O8B -79.1(16) 2_656 . . . ? O8B O7B C16 O7A -111.2(12) . . . . ? Ag3 O7B C16 O7A -93.3(9) . . . . ? Ag4 O7B C16 O7A -9.3(10) . . . . ? Ag5 O7B C16 O7A 169.8(13) 2_656 . . . ? O8B O7B C16 C15 124.3(18) . . . . ? Ag3 O7B C16 C15 142.2(10) . . . . ? Ag4 O7B C16 C15 -133.9(10) . . . . ? Ag5 O7B C16 C15 45(2) 2_656 . . . ? Ag4 O7A C16 O8A -27.4(14) . . . . ? Ag4 O7A C16 O8B -78.5(15) . . . . ? Ag4 O7A C16 O7B 11.1(12) . . . . ? Ag4 O7A C16 C15 146.7(5) . . . . ? C10 C15 C16 O8A -4.2(12) . . . . ? C14 C15 C16 O8A 171.8(9) . . . . ? C10 C15 C16 O8B 47.4(15) . . . . ? C14 C15 C16 O8B -136.6(14) . . . . ? C10 C15 C16 O7B -67.9(17) . . . . ? C14 C15 C16 O7B 108.2(15) . . . . ? C10 C15 C16 O7A -179.1(7) . . . . ? C14 C15 C16 O7A -3.0(11) . . . . ? Ag8 O9A C17 O9B -79(6) . . . . ? Ag1 O9A C17 O9B -173(7) . . . . ? Ag8 O9A C17 O10B 68.4(17) . . . . ? Ag1 O9A C17 O10B -25.2(18) . . . . ? Ag8 O9A C17 O10A 21.6(12) . . . . ? Ag1 O9A C17 O10A -72.0(12) . . . . ? Ag8 O9A C17 C18 -154.6(6) . . . . ? Ag1 O9A C17 C18 111.7(8) . . . . ? Ag8 O9B C17 O9A 70(5) . . . . ? Ag8 O9B C17 O10B 29(4) . . . . ? Ag8 O9B C17 O10A -26(3) . . . . ? Ag8 O9B C17 C18 -172.9(11) . . . . ? Ag2 O10B C17 O9A -68.9(17) . . . . ? Ag2 O10B C17 O9B -52(3) . . . . ? Ag2 O10B C17 O10A 48.5(14) . . . . ? Ag2 O10B C17 C18 149.9(9) . . . . ? Ag2 O10A C17 O9A 7.1(15) . . . . ? Ag2 O10A C17 O9B 37(2) . . . . ? Ag2 O10A C17 O10B -78(2) . . . . ? Ag2 O10A C17 C18 -176.3(6) . . . . ? O9A C17 C18 C23 177.2(7) . . . . ? O9B C17 C18 C23 151.2(17) . . . . ? O10B C17 C18 C23 -46.7(17) . . . . ? O10A C17 C18 C23 0.6(11) . . . . ? O9A C17 C18 C19 -0.8(11) . . . . ? O9B C17 C18 C19 -26.8(19) . . . . ? O10B C17 C18 C19 135.3(16) . . . . ? O10A C17 C18 C19 -177.3(8) . . . . ? C23 C18 C19 F9 178.4(6) . . . . ? C17 C18 C19 F9 -3.6(10) . . . . ? C23 C18 C19 C20 -2.1(10) . . . . ? C17 C18 C19 C20 175.9(7) . . . . ? F9 C19 C20 F10 -0.4(11) . . . . ? C18 C19 C20 F10 -179.9(7) . . . . ? F9 C19 C20 C21 -179.9(6) . . . . ? C18 C19 C20 C21 0.6(11) . . . . ? F10 C20 C21 F11 1.0(11) . . . . ? C19 C20 C21 F11 -179.4(7) . . . . ? F10 C20 C21 C22 -179.4(7) . . . . ? C19 C20 C21 C22 0.1(11) . . . . ? F11 C21 C22 F12 -1.1(10) . . . . ? C20 C21 C22 F12 179.3(6) . . . . ? F11 C21 C22 C23 -179.7(6) . . . . ? C20 C21 C22 C23 0.8(11) . . . . ? F12 C22 C23 C18 179.1(5) . . . . ? C21 C22 C23 C18 -2.4(10) . . . . ? F12 C22 C23 C24 -4.3(9) . . . . ? C21 C22 C23 C24 174.2(6) . . . . ? C19 C18 C23 C22 3.0(9) . . . . ? C17 C18 C23 C22 -175.1(6) . . . . ? C19 C18 C23 C24 -173.4(6) . . . . ? C17 C18 C23 C24 8.6(9) . . . . ? Ag7 O11 C24 O12 -143.3(6) . . . . ? Ag7 O11 C24 C23 43.2(9) . . . . ? Ag5 O12 C24 O11 -60.9(9) . . . . ? Ag3 O12 C24 O11 134.1(7) . . . . ? Ag6 O12 C24 O11 22.1(8) . . . . ? Ag5 O12 C24 C23 112.8(5) . . . . ? Ag3 O12 C24 C23 -52.1(8) . . . . ? Ag6 O12 C24 C23 -164.2(5) . . . . ? C22 C23 C24 O11 90.1(8) . . . . ? C18 C23 C24 O11 -93.5(9) . . . . ? C22 C23 C24 O12 -84.0(8) . . . . ? C18 C23 C24 O12 92.5(8) . . . . ? Ag3 O13 C25 O14 31.1(8) . . . . ? Ag6 O13 C25 O14 -105.6(7) 2_656 . . . ? Ag3 O13 C25 C26 -141.9(4) . . . . ? Ag6 O13 C25 C26 81.3(6) 2_656 . . . ? Ag4 O14 C25 O13 24.0(8) . . . . ? Ag5 O14 C25 O13 -91.1(8) . . . . ? Ag4 O14 C25 C26 -163.2(4) . . . . ? Ag5 O14 C25 C26 81.6(6) . . . . ? O13 C25 C26 C27 77.4(8) . . . . ? O14 C25 C26 C27 -96.1(7) . . . . ? O13 C25 C26 C31 -98.6(7) . . . . ? O14 C25 C26 C31 87.9(8) . . . . ? C31 C26 C27 F13 179.2(6) . . . . ? C25 C26 C27 F13 3.0(10) . . . . ? C31 C26 C27 C28 -0.7(11) . . . . ? C25 C26 C27 C28 -176.9(7) . . . . ? F13 C27 C28 F14 0.5(12) . . . . ? C26 C27 C28 F14 -179.6(7) . . . . ? F13 C27 C28 C29 -179.3(7) . . . . ? C26 C27 C28 C29 0.7(13) . . . . ? F14 C28 C29 F15 0.6(13) . . . . ? C27 C28 C29 F15 -179.6(7) . . . . ? F14 C28 C29 C30 -179.2(7) . . . . ? C27 C28 C29 C30 0.5(13) . . . . ? F15 C29 C30 F16 -0.2(11) . . . . ? C28 C29 C30 F16 179.6(7) . . . . ? F15 C29 C30 C31 178.5(7) . . . . ? C28 C29 C30 C31 -1.7(12) . . . . ? F16 C30 C31 C26 -179.8(6) . . . . ? C29 C30 C31 C26 1.6(10) . . . . ? F16 C30 C31 C32 2.0(10) . . . . ? C29 C30 C31 C32 -176.6(7) . . . . ? C27 C26 C31 C30 -0.4(9) . . . . ? C25 C26 C31 C30 175.4(6) . . . . ? C27 C26 C31 C32 177.8(6) . . . . ? C25 C26 C31 C32 -6.4(9) . . . . ? Ag7 O16 C32 O15 -12.2(10) 4_575 . . . ? Ag7 O16 C32 C31 166.5(4) 4_575 . . . ? Ag7 O15 C32 O16 -2.1(12) 2_656 . . . ? Ag7 O15 C32 C31 179.1(5) 2_656 . . . ? C30 C31 C32 O16 -12.5(10) . . . . ? C26 C31 C32 O16 169.3(6) . . . . ? C30 C31 C32 O15 166.4(6) . . . . ? C26 C31 C32 O15 -11.8(9) . . . . ? Ag6 O17 C33 N1 -0.7(14) . . . . ? Ag2 O17 C33 N1 173.8(6) . . . . ? C35 N1 C33 O17 -179.2(9) . . . . ? C34 N1 C33 O17 3.0(13) . . . . ? O14 Ag4 O18A C36A -46(8) . . . . ? O7A Ag4 O18A C36A 144(8) . . . . ? O18B Ag4 O18A C36A -6(2) . . . . ? O7B Ag4 O18A C36A 105(8) . . . . ? Ag3 Ag4 O18A C36A 95(8) . . . . ? Ag4 O18A C36A N2 -168(7) . . . . ? C37B N2 C36A O18A -179(2) . . . . ? C38A N2 C36A O18A 7(3) . . . . ? C37A N2 C36A O18A -180(2) . . . . ? C38B N2 C36A O18A -7(8) . . . . ? C36B N2 C36A O18A 1(2) . . . . ? O14 Ag4 O18B C36B 151.2(12) . . . . ? O7A Ag4 O18B C36B -25.6(16) . . . . ? O18A Ag4 O18B C36B 5(6) . . . . ? O7B Ag4 O18B C36B -68.1(16) . . . . ? Ag3 Ag4 O18B C36B -101.7(14) . . . . ? Ag4 O18B C36B N2 177.1(8) . . . . ? C37B N2 C36B O18B 2(2) . . . . ? C38A N2 C36B O18B -172(2) . . . . ? C37A N2 C36B O18B -3(8) . . . . ? C38B N2 C36B O18B -179.9(17) . . . . ? C36A N2 C36B O18B 1.5(17) . . . . ? _diffrn_measured_fraction_theta_max 0.981 _diffrn_reflns_theta_full 25.52 _diffrn_measured_fraction_theta_full 0.981 _refine_diff_density_max 1.280 _refine_diff_density_min -1.355 _refine_diff_density_rms 0.118 data_2 _database_code_depnum_ccdc_archive 'CCDC 805807' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C19 H7 Ag4 F8 N O9 ' _chemical_formula_sum 'C19 H7 Ag4 F8 N O9' _chemical_formula_weight 976.74 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Triclinic _symmetry_space_group_name_H-M P-1 _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 7.659(7) _cell_length_b 11.510(10) _cell_length_c 13.686(12) _cell_angle_alpha 74.096(9) _cell_angle_beta 82.415(9) _cell_angle_gamma 76.996(9) _cell_volume 1127.4(16) _cell_formula_units_Z 2 _cell_measurement_temperature 296(2) _cell_measurement_reflns_used 7533 _cell_measurement_theta_min 0.00 _cell_measurement_theta_max 0.00 _exptl_crystal_description block _exptl_crystal_colour pink _exptl_crystal_size_max 0.26 _exptl_crystal_size_mid 0.24 _exptl_crystal_size_min 0.24 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.877 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 920 _exptl_absorpt_coefficient_mu 3.546 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.4591 _exptl_absorpt_correction_T_max 0.4833 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 296(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean ? _diffrn_reflns_number 7708 _diffrn_reflns_av_R_equivalents 0.0413 _diffrn_reflns_av_sigmaI/netI 0.0549 _diffrn_reflns_limit_h_min -8 _diffrn_reflns_limit_h_max 9 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 13 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_theta_min 1.88 _diffrn_reflns_theta_max 25.00 _reflns_number_total 3886 _reflns_number_gt 3634 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker SMART' _computing_cell_refinement 'Bruker SMART' _computing_data_reduction 'Bruker SAINT' _computing_structure_solution 'SHELXS-97 (Sheldrick, 2008)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 2008)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0982P)^2^+3.2053P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 3886 _refine_ls_number_parameters 372 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0467 _refine_ls_R_factor_gt 0.0441 _refine_ls_wR_factor_ref 0.1447 _refine_ls_wR_factor_gt 0.1393 _refine_ls_goodness_of_fit_ref 1.076 _refine_ls_restrained_S_all 1.076 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.80211(7) 0.77404(5) 0.89759(4) 0.02556(19) Uani 1 1 d . . . Ag2 Ag 0.45760(7) 0.69284(5) 0.97421(4) 0.02352(19) Uani 1 1 d . . . Ag3 Ag 0.80432(7) 0.50351(5) 1.10251(4) 0.02545(19) Uani 1 1 d . . . Ag4 Ag 0.74678(7) 1.02198(5) 0.99129(4) 0.02566(19) Uani 1 1 d . . . C1 C 0.5256(9) 0.9775(6) 0.8091(5) 0.0239(15) Uani 1 1 d . . . C2 C 0.4287(9) 1.0932(6) 0.7372(5) 0.0210(14) Uani 1 1 d . . . C3 C 0.3791(8) 1.2096(6) 0.7603(5) 0.0176(13) Uani 1 1 d . . . C4 C 0.2874(9) 1.3065(6) 0.6890(5) 0.0206(13) Uani 1 1 d . . . C5 C 0.2415(9) 1.2932(6) 0.5981(5) 0.0231(14) Uani 1 1 d . . . C6 C 0.2973(10) 1.1793(7) 0.5752(5) 0.0267(15) Uani 1 1 d . . . C7 C 0.3901(9) 1.0815(6) 0.6454(5) 0.0234(14) Uani 1 1 d . . . C8 C 0.7862(9) 0.5188(6) 0.8640(5) 0.0191(14) Uani 1 1 d . . . C9 C 0.8000(8) 0.4264(6) 0.7994(5) 0.0186(13) Uani 1 1 d . . . C10 C 0.8825(9) 0.3018(6) 0.8320(5) 0.0201(14) Uani 1 1 d . . . C11 C 0.8904(9) 0.2240(6) 0.7699(5) 0.0200(13) Uani 1 1 d . . . C12 C 0.8069(10) 0.2676(7) 0.6784(5) 0.0247(15) Uani 1 1 d . . . C13 C 0.7249(10) 0.3886(7) 0.6487(5) 0.0240(15) Uani 1 1 d . . . C14 C 0.7212(9) 0.4686(7) 0.7082(6) 0.0253(15) Uani 1 1 d . . . C15 C 0.8117(9) 0.2169(7) 1.2101(6) 0.0253(15) Uani 1 1 d . . . H15 H 0.8468 0.1485 1.1832 0.030 Uiso 1 1 calc R . . C16 C 0.8026(14) 0.3050(9) 1.3512(7) 0.047(2) Uani 1 1 d . . . H16A H 0.7193 0.3697 1.3107 0.070 Uiso 1 1 calc R . . H16B H 0.9056 0.3360 1.3578 0.070 Uiso 1 1 calc R . . H16C H 0.7455 0.2760 1.4175 0.070 Uiso 1 1 calc R . . C17 C 0.9680(12) 0.0917(7) 1.3574(7) 0.0380(19) Uani 1 1 d . . . H17A H 1.0033 0.0353 1.3147 0.057 Uiso 1 1 calc R . . H17B H 0.8999 0.0552 1.4175 0.057 Uiso 1 1 calc R . . H17C H 1.0732 0.1099 1.3764 0.057 Uiso 1 1 calc R . . C32 C 0.9708(8) 0.2510(6) 0.9323(5) 0.0187(13) Uani 1 1 d . . . C37 C 0.4246(8) 1.2262(6) 0.8588(5) 0.0198(14) Uani 1 1 d . . . F1 F 0.2270(6) 1.4205(4) 0.7050(4) 0.0357(10) Uani 1 1 d . . . F2 F 0.1424(6) 1.3886(4) 0.5326(3) 0.0355(10) Uani 1 1 d . . . F3 F 0.2552(7) 1.1642(5) 0.4879(4) 0.0466(13) Uani 1 1 d . . . F4 F 0.4407(7) 0.9707(4) 0.6223(3) 0.0403(11) Uani 1 1 d . . . F5 F 0.9830(6) 0.1066(4) 0.7920(3) 0.0299(9) Uani 1 1 d . . . F6 F 0.8197(7) 0.1906(4) 0.6159(3) 0.0375(11) Uani 1 1 d . . . F7 F 0.6384(7) 0.4300(5) 0.5604(3) 0.0406(11) Uani 1 1 d . . . F8 F 0.6362(6) 0.5873(4) 0.6771(3) 0.0368(10) Uani 1 1 d . . . N1 N 0.8588(8) 0.2043(6) 1.3023(5) 0.0251(13) Uani 1 1 d . . . O1 O 0.6903(6) 0.9687(5) 0.8135(4) 0.0326(12) Uani 1 1 d . . . O2 O 0.4316(7) 0.9004(5) 0.8530(4) 0.0304(12) Uani 1 1 d . . . O3 O 0.4416(7) 1.1299(5) 0.9321(4) 0.0252(11) Uani 1 1 d . . . O4 O 0.4463(7) 1.3298(5) 0.8613(4) 0.0262(11) Uani 1 1 d . . . O5 O 0.8798(7) 0.5987(5) 0.8331(4) 0.0301(12) Uani 1 1 d . . . O6 O 0.6777(7) 0.5053(5) 0.9423(4) 0.0264(11) Uani 1 1 d . . . O7 O 1.0494(7) 0.3235(4) 0.9576(4) 0.0240(10) Uani 1 1 d . . . O8 O 0.9654(6) 0.1435(4) 0.9828(4) 0.0238(10) Uani 1 1 d . . . O9 O 0.7242(7) 0.3124(5) 1.1554(4) 0.0322(12) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0261(3) 0.0213(3) 0.0297(3) -0.0052(2) -0.0104(2) -0.0023(2) Ag2 0.0248(3) 0.0248(3) 0.0245(3) -0.0098(2) -0.0072(2) -0.0049(2) Ag3 0.0299(3) 0.0201(3) 0.0303(3) -0.0071(2) -0.0058(2) -0.0100(2) Ag4 0.0190(3) 0.0278(3) 0.0316(3) -0.0048(2) -0.0056(2) -0.0088(2) C1 0.025(4) 0.022(3) 0.026(4) -0.011(3) -0.007(3) 0.001(3) C2 0.019(3) 0.018(3) 0.027(4) -0.002(3) -0.006(3) -0.008(3) C3 0.011(3) 0.020(3) 0.020(3) -0.003(3) 0.006(2) -0.007(2) C4 0.017(3) 0.020(3) 0.025(3) -0.005(3) 0.003(3) -0.005(3) C5 0.018(3) 0.025(4) 0.021(3) 0.002(3) -0.007(3) -0.001(3) C6 0.031(4) 0.038(4) 0.017(3) -0.009(3) -0.009(3) -0.013(3) C7 0.028(4) 0.019(3) 0.025(4) -0.007(3) -0.004(3) -0.005(3) C8 0.018(3) 0.021(3) 0.019(3) -0.012(3) -0.008(3) 0.005(3) C9 0.017(3) 0.019(3) 0.022(3) -0.006(3) -0.002(3) -0.006(3) C10 0.017(3) 0.020(3) 0.024(3) -0.010(3) 0.003(3) -0.002(3) C11 0.018(3) 0.023(3) 0.022(3) -0.008(3) -0.008(3) -0.004(3) C12 0.032(4) 0.030(4) 0.019(3) -0.015(3) 0.002(3) -0.012(3) C13 0.030(4) 0.032(4) 0.012(3) -0.002(3) -0.007(3) -0.011(3) C14 0.023(4) 0.029(4) 0.024(4) -0.011(3) -0.003(3) -0.002(3) C15 0.025(4) 0.026(4) 0.031(4) -0.009(3) -0.001(3) -0.016(3) C16 0.062(6) 0.042(5) 0.040(5) -0.021(4) -0.014(4) 0.004(4) C17 0.047(5) 0.030(4) 0.041(5) -0.012(4) -0.021(4) -0.001(4) C32 0.017(3) 0.021(3) 0.018(3) -0.007(3) -0.002(2) -0.003(3) C37 0.013(3) 0.023(4) 0.024(4) -0.008(3) -0.002(3) -0.002(3) F1 0.045(3) 0.021(2) 0.041(3) -0.0097(19) -0.009(2) -0.0010(19) F2 0.034(2) 0.034(2) 0.032(2) 0.0046(19) -0.0107(19) -0.0044(19) F3 0.061(3) 0.060(3) 0.026(2) -0.016(2) -0.026(2) -0.006(3) F4 0.063(3) 0.034(3) 0.029(2) -0.018(2) -0.013(2) -0.004(2) F5 0.036(2) 0.019(2) 0.037(2) -0.0141(18) -0.0066(19) 0.0014(17) F6 0.055(3) 0.037(3) 0.030(2) -0.021(2) -0.007(2) -0.011(2) F7 0.050(3) 0.047(3) 0.026(2) -0.007(2) -0.020(2) -0.006(2) F8 0.046(3) 0.029(2) 0.032(2) -0.0067(19) -0.014(2) 0.004(2) N1 0.025(3) 0.030(3) 0.025(3) -0.009(3) -0.004(2) -0.011(3) O1 0.015(3) 0.036(3) 0.041(3) -0.002(2) -0.004(2) 0.000(2) O2 0.041(3) 0.020(3) 0.033(3) 0.002(2) -0.013(2) -0.017(2) O3 0.033(3) 0.029(3) 0.017(2) -0.003(2) -0.008(2) -0.013(2) O4 0.027(3) 0.027(3) 0.030(3) -0.015(2) -0.001(2) -0.007(2) O5 0.031(3) 0.027(3) 0.038(3) -0.016(2) 0.007(2) -0.015(2) O6 0.028(3) 0.028(3) 0.027(3) -0.011(2) -0.006(2) -0.004(2) O7 0.031(3) 0.018(2) 0.026(2) -0.0022(19) -0.013(2) -0.010(2) O8 0.025(3) 0.028(3) 0.022(2) -0.002(2) -0.007(2) -0.015(2) O9 0.043(3) 0.029(3) 0.030(3) -0.001(2) -0.015(2) -0.021(2) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 O1 2.250(6) . ? Ag1 O7 2.298(5) 2_767 ? Ag1 O5 2.346(5) . ? Ag1 Ag2 2.963(2) . ? Ag1 Ag4 3.360(2) . ? Ag2 O4 2.388(5) 2_677 ? Ag2 O9 2.416(5) 2_667 ? Ag2 O2 2.490(5) . ? Ag2 O6 2.525(5) . ? Ag2 Ag3 3.378(2) . ? Ag3 O9 2.315(5) . ? Ag3 O7 2.400(5) 2_767 ? Ag3 O4 2.494(5) 2_677 ? Ag3 O6 2.506(5) . ? Ag3 O5 2.593(6) 2_767 ? Ag4 O8 2.385(5) 1_565 ? Ag4 O3 2.443(5) 2_677 ? Ag4 O3 2.510(5) . ? Ag4 O8 2.561(5) 2_767 ? C1 O2 1.244(9) . ? C1 O1 1.251(9) . ? C1 C2 1.524(10) . ? C2 C7 1.375(10) . ? C2 C3 1.418(9) . ? C3 C4 1.386(10) . ? C3 C37 1.507(9) . ? C4 F1 1.357(8) . ? C4 C5 1.393(10) . ? C5 F2 1.360(8) . ? C5 C6 1.391(10) . ? C6 F3 1.343(8) . ? C6 C7 1.387(10) . ? C7 F4 1.357(8) . ? C8 O5 1.241(9) . ? C8 O6 1.263(9) . ? C8 C9 1.537(8) . ? C9 C14 1.376(10) . ? C9 C10 1.404(10) . ? C10 C11 1.380(9) . ? C10 C32 1.521(10) . ? C11 F5 1.349(8) . ? C11 C12 1.397(10) . ? C12 C13 1.364(11) . ? C12 F6 1.372(8) . ? C13 F7 1.370(8) . ? C13 C14 1.380(10) . ? C14 F8 1.351(9) . ? C15 O9 1.252(9) . ? C15 N1 1.319(10) . ? C15 H15 0.9300 . ? C16 N1 1.450(10) . ? C16 H16A 0.9600 . ? C16 H16B 0.9600 . ? C16 H16C 0.9600 . ? C17 N1 1.446(10) . ? C17 H17A 0.9600 . ? C17 H17B 0.9600 . ? C17 H17C 0.9600 . ? C32 O8 1.248(8) . ? C32 O7 1.271(8) . ? C37 O4 1.251(8) . ? C37 O3 1.270(9) . ? O3 Ag4 2.443(5) 2_677 ? O4 Ag2 2.388(5) 2_677 ? O4 Ag3 2.494(5) 2_677 ? O5 Ag3 2.593(6) 2_767 ? O7 Ag1 2.298(5) 2_767 ? O7 Ag3 2.400(5) 2_767 ? O8 Ag4 2.385(5) 1_545 ? O8 Ag4 2.561(5) 2_767 ? O9 Ag2 2.416(5) 2_667 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag O1 Ag1 O7 137.40(19) . 2_767 ? O1 Ag1 O5 127.6(2) . . ? O7 Ag1 O5 92.93(19) 2_767 . ? O1 Ag1 Ag2 98.37(13) . . ? O7 Ag1 Ag2 96.82(13) 2_767 . ? O5 Ag1 Ag2 85.88(13) . . ? O1 Ag1 Ag4 55.10(16) . . ? O7 Ag1 Ag4 83.08(13) 2_767 . ? O5 Ag1 Ag4 172.76(13) . . ? Ag2 Ag1 Ag4 100.56(4) . . ? O4 Ag2 O9 160.10(18) 2_677 2_667 ? O4 Ag2 O2 117.26(17) 2_677 . ? O9 Ag2 O2 75.09(17) 2_667 . ? O4 Ag2 O6 94.55(16) 2_677 . ? O9 Ag2 O6 90.43(18) 2_667 . ? O2 Ag2 O6 123.04(18) . . ? O4 Ag2 Ag1 84.56(13) 2_677 . ? O9 Ag2 Ag1 115.31(14) 2_667 . ? O2 Ag2 Ag1 64.62(13) . . ? O6 Ag2 Ag1 73.84(13) . . ? O4 Ag2 Ag3 47.53(12) 2_677 . ? O9 Ag2 Ag3 136.78(14) 2_667 . ? O2 Ag2 Ag3 131.83(12) . . ? O6 Ag2 Ag3 47.57(12) . . ? O9 Ag3 O7 167.75(19) . 2_767 ? O9 Ag3 O4 111.75(19) . 2_677 ? O7 Ag3 O4 80.33(18) 2_767 2_677 ? O9 Ag3 O6 81.56(17) . . ? O7 Ag3 O6 100.46(17) 2_767 . ? O4 Ag3 O6 92.47(17) 2_677 . ? O9 Ag3 O5 89.04(18) . 2_767 ? O7 Ag3 O5 80.34(17) 2_767 2_767 ? O4 Ag3 O5 136.25(16) 2_677 2_767 ? O6 Ag3 O5 129.54(16) . 2_767 ? O9 Ag3 Ag2 105.14(14) . . ? O7 Ag3 Ag2 84.70(13) 2_767 . ? O4 Ag3 Ag2 44.94(12) 2_677 . ? O6 Ag3 Ag2 48.07(12) . . ? O5 Ag3 Ag2 164.01(12) 2_767 . ? O8 Ag4 O3 157.54(16) 1_565 2_677 ? O8 Ag4 O3 118.36(17) 1_565 . ? O3 Ag4 O3 76.37(19) 2_677 . ? O8 Ag4 O8 78.64(19) 1_565 2_767 ? O3 Ag4 O8 91.91(17) 2_677 2_767 ? O3 Ag4 O8 158.65(15) . 2_767 ? O8 Ag4 Ag1 126.50(13) 1_565 . ? O3 Ag4 Ag1 61.71(12) 2_677 . ? O3 Ag4 Ag1 99.07(11) . . ? O8 Ag4 Ag1 59.58(11) 2_767 . ? O2 C1 O1 127.8(7) . . ? O2 C1 C2 115.4(6) . . ? O1 C1 C2 116.6(6) . . ? C7 C2 C3 119.7(6) . . ? C7 C2 C1 116.9(6) . . ? C3 C2 C1 123.4(6) . . ? C4 C3 C2 117.3(6) . . ? C4 C3 C37 121.7(6) . . ? C2 C3 C37 120.9(6) . . ? F1 C4 C3 122.4(6) . . ? F1 C4 C5 114.7(6) . . ? C3 C4 C5 122.9(6) . . ? F2 C5 C6 120.0(6) . . ? F2 C5 C4 121.2(6) . . ? C6 C5 C4 118.8(6) . . ? F3 C6 C7 120.9(7) . . ? F3 C6 C5 119.9(6) . . ? C7 C6 C5 119.1(6) . . ? F4 C7 C2 119.7(6) . . ? F4 C7 C6 118.1(6) . . ? C2 C7 C6 122.2(6) . . ? O5 C8 O6 127.4(6) . . ? O5 C8 C9 117.1(6) . . ? O6 C8 C9 115.5(6) . . ? C14 C9 C10 119.8(6) . . ? C14 C9 C8 117.5(6) . . ? C10 C9 C8 122.6(6) . . ? C11 C10 C9 119.5(6) . . ? C11 C10 C32 118.9(6) . . ? C9 C10 C32 121.6(6) . . ? F5 C11 C10 122.4(6) . . ? F5 C11 C12 117.6(6) . . ? C10 C11 C12 120.0(6) . . ? C13 C12 F6 120.6(6) . . ? C13 C12 C11 119.7(6) . . ? F6 C12 C11 119.5(7) . . ? C12 C13 F7 119.4(6) . . ? C12 C13 C14 121.0(7) . . ? F7 C13 C14 119.5(7) . . ? F8 C14 C9 120.7(6) . . ? F8 C14 C13 119.4(7) . . ? C9 C14 C13 119.9(7) . . ? O9 C15 N1 126.0(7) . . ? O9 C15 H15 117.0 . . ? N1 C15 H15 117.0 . . ? N1 C16 H16A 109.5 . . ? N1 C16 H16B 109.5 . . ? H16A C16 H16B 109.5 . . ? N1 C16 H16C 109.5 . . ? H16A C16 H16C 109.5 . . ? H16B C16 H16C 109.5 . . ? N1 C17 H17A 109.5 . . ? N1 C17 H17B 109.5 . . ? H17A C17 H17B 109.5 . . ? N1 C17 H17C 109.5 . . ? H17A C17 H17C 109.5 . . ? H17B C17 H17C 109.5 . . ? O8 C32 O7 124.6(6) . . ? O8 C32 C10 119.6(6) . . ? O7 C32 C10 115.8(6) . . ? O4 C37 O3 126.0(6) . . ? O4 C37 C3 118.8(6) . . ? O3 C37 C3 115.2(6) . . ? C15 N1 C17 121.8(6) . . ? C15 N1 C16 120.3(7) . . ? C17 N1 C16 117.9(6) . . ? C1 O1 Ag1 107.6(5) . . ? C1 O2 Ag2 140.3(5) . . ? C37 O3 Ag4 133.6(4) . 2_677 ? C37 O3 Ag4 120.3(4) . . ? Ag4 O3 Ag4 103.63(19) 2_677 . ? C37 O4 Ag2 106.8(4) . 2_677 ? C37 O4 Ag3 123.5(4) . 2_677 ? Ag2 O4 Ag3 87.53(16) 2_677 2_677 ? C8 O5 Ag1 117.9(4) . . ? C8 O5 Ag3 106.2(4) . 2_767 ? Ag1 O5 Ag3 102.96(19) . 2_767 ? C8 O6 Ag3 114.5(4) . . ? C8 O6 Ag2 118.4(4) . . ? Ag3 O6 Ag2 84.36(15) . . ? C32 O7 Ag1 111.1(4) . 2_767 ? C32 O7 Ag3 145.6(4) . 2_767 ? Ag1 O7 Ag3 98.98(17) 2_767 2_767 ? C32 O8 Ag4 129.7(4) . 1_545 ? C32 O8 Ag4 120.7(4) . 2_767 ? Ag4 O8 Ag4 101.37(19) 1_545 2_767 ? C15 O9 Ag3 126.0(4) . . ? C15 O9 Ag2 122.7(4) . 2_667 ? Ag3 O9 Ag2 105.2(2) . 2_667 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag O1 Ag1 Ag2 O4 -116.5(2) . . . 2_677 ? O7 Ag1 Ag2 O4 23.59(17) 2_767 . . 2_677 ? O5 Ag1 Ag2 O4 116.05(19) . . . 2_677 ? Ag4 Ag1 Ag2 O4 -60.60(12) . . . 2_677 ? O1 Ag1 Ag2 O9 64.5(2) . . . 2_667 ? O7 Ag1 Ag2 O9 -155.38(19) 2_767 . . 2_667 ? O5 Ag1 Ag2 O9 -62.9(2) . . . 2_667 ? Ag4 Ag1 Ag2 O9 120.43(15) . . . 2_667 ? O1 Ag1 Ag2 O2 7.2(2) . . . . ? O7 Ag1 Ag2 O2 147.26(18) 2_767 . . . ? O5 Ag1 Ag2 O2 -120.3(2) . . . . ? Ag4 Ag1 Ag2 O2 63.07(15) . . . . ? O1 Ag1 Ag2 O6 147.2(2) . . . . ? O7 Ag1 Ag2 O6 -72.76(17) 2_767 . . . ? O5 Ag1 Ag2 O6 19.70(19) . . . . ? Ag4 Ag1 Ag2 O6 -156.95(12) . . . . ? O1 Ag1 Ag2 Ag3 -162.68(15) . . . . ? O7 Ag1 Ag2 Ag3 -22.60(12) 2_767 . . . ? O5 Ag1 Ag2 Ag3 69.86(15) . . . . ? O4 Ag2 Ag3 O9 105.8(2) 2_677 . . . ? O9 Ag2 Ag3 O9 -46.8(3) 2_667 . . . ? O2 Ag2 Ag3 O9 -163.4(2) . . . . ? O6 Ag2 Ag3 O9 -63.4(2) . . . . ? Ag1 Ag2 Ag3 O9 -151.06(15) . . . . ? O4 Ag2 Ag3 O7 -81.6(2) 2_677 . . 2_767 ? O9 Ag2 Ag3 O7 125.8(2) 2_667 . . 2_767 ? O2 Ag2 Ag3 O7 9.2(2) . . . 2_767 ? O6 Ag2 Ag3 O7 109.2(2) . . . 2_767 ? Ag1 Ag2 Ag3 O7 21.53(12) . . . 2_767 ? O9 Ag2 Ag3 O4 -152.5(3) 2_667 . . 2_677 ? O2 Ag2 Ag3 O4 90.8(2) . . . 2_677 ? O6 Ag2 Ag3 O4 -169.2(2) . . . 2_677 ? Ag1 Ag2 Ag3 O4 103.14(17) . . . 2_677 ? O4 Ag2 Ag3 O6 169.2(2) 2_677 . . . ? O9 Ag2 Ag3 O6 16.7(2) 2_667 . . . ? O2 Ag2 Ag3 O6 -100.0(2) . . . . ? Ag1 Ag2 Ag3 O6 -87.65(17) . . . . ? O4 Ag2 Ag3 O5 -102.4(4) 2_677 . . 2_767 ? O9 Ag2 Ag3 O5 105.0(4) 2_667 . . 2_767 ? O2 Ag2 Ag3 O5 -11.6(4) . . . 2_767 ? O6 Ag2 Ag3 O5 88.4(4) . . . 2_767 ? Ag1 Ag2 Ag3 O5 0.7(4) . . . 2_767 ? O1 Ag1 Ag4 O8 -92.8(2) . . . 1_565 ? O7 Ag1 Ag4 O8 78.6(2) 2_767 . . 1_565 ? Ag2 Ag1 Ag4 O8 174.31(15) . . . 1_565 ? O1 Ag1 Ag4 O3 112.1(2) . . . 2_677 ? O7 Ag1 Ag4 O3 -76.51(19) 2_767 . . 2_677 ? Ag2 Ag1 Ag4 O3 19.17(13) . . . 2_677 ? O1 Ag1 Ag4 O3 42.98(19) . . . . ? O7 Ag1 Ag4 O3 -145.60(17) 2_767 . . . ? Ag2 Ag1 Ag4 O3 -49.92(12) . . . . ? O1 Ag1 Ag4 O8 -136.8(2) . . . 2_767 ? O7 Ag1 Ag4 O8 34.59(17) 2_767 . . 2_767 ? Ag2 Ag1 Ag4 O8 130.27(13) . . . 2_767 ? O2 C1 C2 C7 -74.5(8) . . . . ? O1 C1 C2 C7 102.5(8) . . . . ? O2 C1 C2 C3 105.9(7) . . . . ? O1 C1 C2 C3 -77.1(9) . . . . ? C7 C2 C3 C4 2.0(9) . . . . ? C1 C2 C3 C4 -178.4(6) . . . . ? C7 C2 C3 C37 -178.1(6) . . . . ? C1 C2 C3 C37 1.5(10) . . . . ? C2 C3 C4 F1 177.2(6) . . . . ? C37 C3 C4 F1 -2.7(9) . . . . ? C2 C3 C4 C5 0.8(9) . . . . ? C37 C3 C4 C5 -179.1(6) . . . . ? F1 C4 C5 F2 -0.6(9) . . . . ? C3 C4 C5 F2 176.1(6) . . . . ? F1 C4 C5 C6 -179.8(6) . . . . ? C3 C4 C5 C6 -3.2(10) . . . . ? F2 C5 C6 F3 0.9(10) . . . . ? C4 C5 C6 F3 -179.8(6) . . . . ? F2 C5 C6 C7 -176.6(6) . . . . ? C4 C5 C6 C7 2.6(10) . . . . ? C3 C2 C7 F4 178.7(6) . . . . ? C1 C2 C7 F4 -0.9(10) . . . . ? C3 C2 C7 C6 -2.5(11) . . . . ? C1 C2 C7 C6 177.9(6) . . . . ? F3 C6 C7 F4 1.4(10) . . . . ? C5 C6 C7 F4 179.0(6) . . . . ? F3 C6 C7 C2 -177.4(7) . . . . ? C5 C6 C7 C2 0.1(11) . . . . ? O5 C8 C9 C14 -72.8(8) . . . . ? O6 C8 C9 C14 106.2(7) . . . . ? O5 C8 C9 C10 109.7(7) . . . . ? O6 C8 C9 C10 -71.2(8) . . . . ? C14 C9 C10 C11 2.8(10) . . . . ? C8 C9 C10 C11 -179.9(6) . . . . ? C14 C9 C10 C32 -179.8(6) . . . . ? C8 C9 C10 C32 -2.5(9) . . . . ? C9 C10 C11 F5 173.3(6) . . . . ? C32 C10 C11 F5 -4.2(10) . . . . ? C9 C10 C11 C12 -3.9(10) . . . . ? C32 C10 C11 C12 178.6(6) . . . . ? F5 C11 C12 C13 -174.4(6) . . . . ? C10 C11 C12 C13 2.9(10) . . . . ? F5 C11 C12 F6 0.9(9) . . . . ? C10 C11 C12 F6 178.2(6) . . . . ? F6 C12 C13 F7 6.8(10) . . . . ? C11 C12 C13 F7 -178.0(6) . . . . ? F6 C12 C13 C14 -175.9(6) . . . . ? C11 C12 C13 C14 -0.7(11) . . . . ? C10 C9 C14 F8 177.9(6) . . . . ? C8 C9 C14 F8 0.4(10) . . . . ? C10 C9 C14 C13 -0.6(10) . . . . ? C8 C9 C14 C13 -178.1(6) . . . . ? C12 C13 C14 F8 -178.9(6) . . . . ? F7 C13 C14 F8 -1.7(10) . . . . ? C12 C13 C14 C9 -0.4(11) . . . . ? F7 C13 C14 C9 176.8(6) . . . . ? C11 C10 C32 O8 -36.8(9) . . . . ? C9 C10 C32 O8 145.8(6) . . . . ? C11 C10 C32 O7 141.9(6) . . . . ? C9 C10 C32 O7 -35.5(9) . . . . ? C4 C3 C37 O4 -28.2(9) . . . . ? C2 C3 C37 O4 151.9(6) . . . . ? C4 C3 C37 O3 153.4(6) . . . . ? C2 C3 C37 O3 -26.5(9) . . . . ? O9 C15 N1 C17 -176.8(7) . . . . ? O9 C15 N1 C16 2.7(11) . . . . ? O2 C1 O1 Ag1 8.6(9) . . . . ? C2 C1 O1 Ag1 -168.0(5) . . . . ? O7 Ag1 O1 C1 -120.8(5) 2_767 . . . ? O5 Ag1 O1 C1 80.2(5) . . . . ? Ag2 Ag1 O1 C1 -11.1(5) . . . . ? Ag4 Ag1 O1 C1 -108.2(5) . . . . ? O1 C1 O2 Ag2 1.6(12) . . . . ? C2 C1 O2 Ag2 178.2(5) . . . . ? O4 Ag2 O2 C1 60.2(8) 2_677 . . . ? O9 Ag2 O2 C1 -136.6(7) 2_667 . . . ? O6 Ag2 O2 C1 -56.0(8) . . . . ? Ag1 Ag2 O2 C1 -8.6(7) . . . . ? Ag3 Ag2 O2 C1 4.1(8) . . . . ? O4 C37 O3 Ag4 130.4(6) . . . 2_677 ? C3 C37 O3 Ag4 -51.4(8) . . . 2_677 ? O4 C37 O3 Ag4 -70.6(8) . . . . ? C3 C37 O3 Ag4 107.6(5) . . . . ? O8 Ag4 O3 C37 33.7(5) 1_565 . . . ? O3 Ag4 O3 C37 -164.5(6) 2_677 . . . ? O8 Ag4 O3 C37 -106.2(6) 2_767 . . . ? Ag1 Ag4 O3 C37 -106.7(5) . . . . ? O8 Ag4 O3 Ag4 -161.76(16) 1_565 . . 2_677 ? O3 Ag4 O3 Ag4 0.0 2_677 . . 2_677 ? O8 Ag4 O3 Ag4 58.3(5) 2_767 . . 2_677 ? Ag1 Ag4 O3 Ag4 57.82(16) . . . 2_677 ? O3 C37 O4 Ag2 3.4(8) . . . 2_677 ? C3 C37 O4 Ag2 -174.8(4) . . . 2_677 ? O3 C37 O4 Ag3 -95.0(7) . . . 2_677 ? C3 C37 O4 Ag3 86.9(6) . . . 2_677 ? O6 C8 O5 Ag1 -17.1(9) . . . . ? C9 C8 O5 Ag1 161.8(4) . . . . ? O6 C8 O5 Ag3 97.6(7) . . . 2_767 ? C9 C8 O5 Ag3 -83.5(6) . . . 2_767 ? O1 Ag1 O5 C8 -111.2(5) . . . . ? O7 Ag1 O5 C8 82.8(5) 2_767 . . . ? Ag2 Ag1 O5 C8 -13.8(5) . . . . ? O1 Ag1 O5 Ag3 132.3(2) . . . 2_767 ? O7 Ag1 O5 Ag3 -33.7(2) 2_767 . . 2_767 ? Ag2 Ag1 O5 Ag3 -130.29(16) . . . 2_767 ? O5 C8 O6 Ag3 -50.1(8) . . . . ? C9 C8 O6 Ag3 131.0(5) . . . . ? O5 C8 O6 Ag2 47.0(9) . . . . ? C9 C8 O6 Ag2 -131.9(5) . . . . ? O9 Ag3 O6 C8 -122.1(5) . . . . ? O7 Ag3 O6 C8 45.7(5) 2_767 . . . ? O4 Ag3 O6 C8 126.3(5) 2_677 . . . ? O5 Ag3 O6 C8 -40.4(5) 2_767 . . . ? Ag2 Ag3 O6 C8 118.7(5) . . . . ? O9 Ag3 O6 Ag2 119.23(19) . . . . ? O7 Ag3 O6 Ag2 -73.02(18) 2_767 . . . ? O4 Ag3 O6 Ag2 7.61(16) 2_677 . . . ? O5 Ag3 O6 Ag2 -159.08(15) 2_767 . . . ? O4 Ag2 O6 C8 -122.8(5) 2_677 . . . ? O9 Ag2 O6 C8 76.4(5) 2_667 . . . ? O2 Ag2 O6 C8 4.0(5) . . . . ? Ag1 Ag2 O6 C8 -39.8(4) . . . . ? Ag3 Ag2 O6 C8 -114.9(5) . . . . ? O4 Ag2 O6 Ag3 -7.96(16) 2_677 . . . ? O9 Ag2 O6 Ag3 -168.68(16) 2_667 . . . ? O2 Ag2 O6 Ag3 118.91(17) . . . . ? Ag1 Ag2 O6 Ag3 75.03(11) . . . . ? O8 C32 O7 Ag1 4.1(8) . . . 2_767 ? C10 C32 O7 Ag1 -174.5(4) . . . 2_767 ? O8 C32 O7 Ag3 153.3(6) . . . 2_767 ? C10 C32 O7 Ag3 -25.3(10) . . . 2_767 ? O7 C32 O8 Ag4 153.1(5) . . . 1_545 ? C10 C32 O8 Ag4 -28.4(8) . . . 1_545 ? O7 C32 O8 Ag4 -64.6(8) . . . 2_767 ? C10 C32 O8 Ag4 114.0(5) . . . 2_767 ? N1 C15 O9 Ag3 57.9(9) . . . . ? N1 C15 O9 Ag2 -153.8(5) . . . 2_667 ? O7 Ag3 O9 C15 41.1(11) 2_767 . . . ? O4 Ag3 O9 C15 -129.2(6) 2_677 . . . ? O6 Ag3 O9 C15 141.5(6) . . . . ? O5 Ag3 O9 C15 11.3(6) 2_767 . . . ? Ag2 Ag3 O9 C15 -176.2(6) . . . . ? O7 Ag3 O9 Ag2 -111.6(8) 2_767 . . 2_667 ? O4 Ag3 O9 Ag2 78.2(2) 2_677 . . 2_667 ? O6 Ag3 O9 Ag2 -11.1(2) . . . 2_667 ? O5 Ag3 O9 Ag2 -141.4(2) 2_767 . . 2_667 ? Ag2 Ag3 O9 Ag2 31.1(2) . . . 2_667 ? _diffrn_measured_fraction_theta_max 0.981 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.981 _refine_diff_density_max 1.331 _refine_diff_density_min -1.536 _refine_diff_density_rms 0.286 data_3 _database_code_depnum_ccdc_archive 'CCDC 805808' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C19 H7 Ag4 F8 N O9 ' _chemical_formula_sum 'C19 H7 Ag4 F8 N O9' _chemical_formula_weight 976.74 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M P2(1)/c _symmetry_space_group_name_Hall '-P 2ybc ' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 15.6663(14) _cell_length_b 11.4910(11) _cell_length_c 13.2146(12) _cell_angle_alpha 90.00 _cell_angle_beta 108.8200(10) _cell_angle_gamma 90.00 _cell_volume 2251.7(4) _cell_formula_units_Z 4 _cell_measurement_temperature 296(2) _cell_measurement_reflns_used 9983 _cell_measurement_theta_min 2.24 _cell_measurement_theta_max 27.60 _exptl_crystal_description block _exptl_crystal_colour colorless _exptl_crystal_size_max 0.28 _exptl_crystal_size_mid 0.26 _exptl_crystal_size_min 0.26 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.881 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1840 _exptl_absorpt_coefficient_mu 3.551 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.389 _exptl_absorpt_correction_T_max 0.395 _exptl_absorpt_process_details SADABS _exptl_special_details ; ? ; _diffrn_ambient_temperature 296(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean ? _diffrn_reflns_number 19131 _diffrn_reflns_av_R_equivalents 0.0406 _diffrn_reflns_av_sigmaI/netI 0.0328 _diffrn_reflns_limit_h_min -20 _diffrn_reflns_limit_h_max 20 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 17 _diffrn_reflns_theta_min 2.24 _diffrn_reflns_theta_max 27.63 _reflns_number_total 5200 _reflns_number_gt 4730 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker SMART' _computing_cell_refinement 'Bruker SMART' _computing_data_reduction 'Bruker SAINT' _computing_structure_solution 'SHELXS-97 (Sheldrick, 2008)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 2008)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0377P)^2^+4.8336P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 5200 _refine_ls_number_parameters 379 _refine_ls_number_restraints 40 _refine_ls_R_factor_all 0.0333 _refine_ls_R_factor_gt 0.0295 _refine_ls_wR_factor_ref 0.0806 _refine_ls_wR_factor_gt 0.0781 _refine_ls_goodness_of_fit_ref 1.087 _refine_ls_restrained_S_all 1.141 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.485218(19) 0.65379(3) 0.31658(2) 0.02521(9) Uani 1 1 d . . . Ag2 Ag 0.587947(19) 0.87196(3) 0.37057(2) 0.02689(9) Uani 1 1 d . . . Ag3 Ag 0.48844(2) 0.39030(3) 0.42058(3) 0.02801(9) Uani 1 1 d . . . Ag4 Ag 0.42861(2) 0.83434(3) 0.49214(2) 0.03283(10) Uani 1 1 d . . . C1 C 0.6896(2) 0.6751(3) 0.4995(3) 0.0188(7) Uani 1 1 d . . . C2 C 0.7701(2) 0.6077(3) 0.5714(3) 0.0186(7) Uani 1 1 d . . . C3 C 0.7594(2) 0.4930(3) 0.6015(3) 0.0186(7) Uani 1 1 d . . . C4 C 0.8334(3) 0.4310(3) 0.6632(3) 0.0230(7) Uani 1 1 d . . . C5 C 0.9187(3) 0.4809(4) 0.7003(3) 0.0268(8) Uani 1 1 d . . . C6 C 0.9295(2) 0.5943(4) 0.6737(3) 0.0271(8) Uani 1 1 d . . . C7 C 0.8565(3) 0.6568(3) 0.6090(3) 0.0234(8) Uani 1 1 d . . . C8 C 0.6672(2) 0.4349(3) 0.5766(3) 0.0187(7) Uani 1 1 d . . . C9 C 0.3916(2) 0.9051(3) 0.2601(3) 0.0195(7) Uani 1 1 d . . . C10 C 0.3089(2) 0.9807(3) 0.2202(3) 0.0214(7) Uani 1 1 d . A . C11 C 0.3148(3) 1.0967(4) 0.2521(3) 0.0250(8) Uani 1 1 d . . . C12 C 0.2385(4) 1.1658(4) 0.2127(4) 0.0417(12) Uani 1 1 d D A . C13 C 0.1566(3) 1.1216(6) 0.1477(4) 0.0583(19) Uani 1 1 d D . . C14 C 0.1532(3) 1.0051(6) 0.1187(4) 0.0510(16) Uani 1 1 d D A . C15 C 0.2285(3) 0.9364(5) 0.1544(3) 0.0348(10) Uani 1 1 d . . . C16 C 0.3989(3) 1.1434(3) 0.3327(3) 0.0269(8) Uani 1 1 d . . . C17 C 0.7175(3) 1.0917(4) 0.3864(3) 0.0353(10) Uani 1 1 d . . . H17 H 0.7284 1.1107 0.3232 0.042 Uiso 1 1 calc R . . C18 C 0.7772(3) 1.0474(4) 0.5745(3) 0.0342(9) Uani 1 1 d . . . H18A H 0.7651 1.1175 0.6070 0.051 Uiso 1 1 calc R . . H18B H 0.8313 1.0120 0.6205 0.051 Uiso 1 1 calc R . . H18C H 0.7276 0.9944 0.5634 0.051 Uiso 1 1 calc R . . C19 C 0.8803(4) 1.0923(6) 0.4708(5) 0.0615(15) Uani 1 1 d U . . H19A H 0.8783 1.1191 0.4013 0.092 Uiso 1 1 calc R . . H19B H 0.9127 1.0200 0.4863 0.092 Uiso 1 1 calc R . . H19C H 0.9103 1.1492 0.5235 0.092 Uiso 1 1 calc R . . F1 F 0.82427(16) 0.3201(2) 0.6930(2) 0.0334(5) Uani 1 1 d . . . F2 F 0.98981(16) 0.4204(2) 0.7638(2) 0.0392(6) Uani 1 1 d . . . F3 F 1.01179(16) 0.6449(2) 0.7116(2) 0.0393(6) Uani 1 1 d . . . F4 F 0.87382(16) 0.7658(2) 0.5867(2) 0.0351(6) Uani 1 1 d . . . F5 F 0.2415(3) 1.2801(3) 0.2388(3) 0.0704(12) Uani 1 1 d D . . F6A F 0.0757(3) 1.1735(5) 0.1049(4) 0.0411(9) Uani 0.614(6) 1 d PDU A 1 F7A F 0.0786(3) 0.9446(5) 0.0497(4) 0.0368(9) Uani 0.614(6) 1 d PDU A 1 F6B F 0.0977(5) 1.2194(7) 0.1249(6) 0.0411(9) Uani 0.386(6) 1 d PDU A 2 F7B F 0.0689(4) 0.9962(8) 0.0598(6) 0.0368(9) Uani 0.386(6) 1 d PDU A 2 F8 F 0.2200(2) 0.8256(3) 0.1207(2) 0.0499(8) Uani 1 1 d . A . N1 N 0.7886(2) 1.0750(4) 0.4730(3) 0.0337(8) Uani 1 1 d . . . O1 O 0.61605(18) 0.6206(2) 0.4664(2) 0.0251(6) Uani 1 1 d . . . O2 O 0.70350(18) 0.7775(2) 0.4778(2) 0.0300(6) Uani 1 1 d . . . O3 O 0.64460(19) 0.3623(2) 0.5016(2) 0.0264(6) Uani 1 1 d . . . O4 O 0.62385(17) 0.4628(2) 0.6381(2) 0.0234(5) Uani 1 1 d . . . O5 O 0.38194(19) 0.8101(2) 0.3026(2) 0.0259(6) Uani 1 1 d . . . O6 O 0.46380(16) 0.9447(2) 0.2504(2) 0.0203(5) Uani 1 1 d . . . O7 O 0.42899(19) 1.0882(3) 0.4190(2) 0.0270(6) Uani 1 1 d . . . O8 O 0.4338(3) 1.2329(3) 0.3082(3) 0.0474(9) Uani 1 1 d . . . O9 O 0.63753(19) 1.0839(2) 0.3831(2) 0.0273(6) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.02055(15) 0.02504(16) 0.02929(17) 0.00356(11) 0.00700(12) -0.00161(10) Ag2 0.02101(15) 0.02137(15) 0.03145(17) 0.00510(11) -0.00104(12) -0.00001(10) Ag3 0.02127(15) 0.03024(17) 0.03075(17) -0.00744(12) 0.00594(12) 0.00037(11) Ag4 0.03709(18) 0.03636(19) 0.02012(16) -0.00175(12) 0.00238(13) 0.00332(13) C1 0.0216(17) 0.0198(17) 0.0143(16) -0.0015(12) 0.0050(13) 0.0025(13) C2 0.0167(16) 0.0207(17) 0.0185(16) -0.0022(13) 0.0060(13) 0.0013(13) C3 0.0154(15) 0.0237(18) 0.0169(16) -0.0020(13) 0.0054(12) 0.0006(13) C4 0.0242(18) 0.0207(18) 0.0237(18) 0.0024(14) 0.0074(14) 0.0038(14) C5 0.0194(17) 0.031(2) 0.0267(19) 0.0009(15) 0.0025(14) 0.0079(15) C6 0.0134(16) 0.034(2) 0.032(2) -0.0051(16) 0.0044(15) -0.0033(14) C7 0.0227(18) 0.0224(18) 0.0256(19) -0.0019(14) 0.0084(15) -0.0017(14) C8 0.0168(16) 0.0168(16) 0.0209(17) 0.0032(13) 0.0039(13) 0.0013(12) C9 0.0177(16) 0.0230(17) 0.0141(15) -0.0020(13) 0.0001(12) -0.0006(13) C10 0.0172(16) 0.033(2) 0.0147(16) 0.0052(14) 0.0054(13) -0.0020(14) C11 0.0278(19) 0.030(2) 0.0204(18) 0.0056(14) 0.0121(15) 0.0092(15) C12 0.053(3) 0.052(3) 0.032(2) 0.015(2) 0.029(2) 0.031(2) C13 0.034(3) 0.115(6) 0.032(3) 0.037(3) 0.020(2) 0.044(3) C14 0.0152(19) 0.108(5) 0.028(2) 0.026(3) 0.0040(16) 0.008(2) C15 0.025(2) 0.058(3) 0.0204(19) 0.0117(18) 0.0062(16) -0.0070(19) C16 0.040(2) 0.0248(19) 0.0209(19) -0.0054(14) 0.0163(17) -0.0022(16) C17 0.034(2) 0.050(3) 0.023(2) 0.0005(18) 0.0106(17) -0.005(2) C18 0.040(2) 0.038(2) 0.025(2) 0.0047(17) 0.0103(17) 0.0009(19) C19 0.0598(18) 0.0648(18) 0.0606(18) 0.0017(10) 0.0205(11) 0.0002(10) F1 0.0284(12) 0.0257(12) 0.0418(14) 0.0106(10) 0.0054(11) 0.0043(10) F2 0.0211(12) 0.0389(15) 0.0496(16) 0.0066(12) 0.0002(11) 0.0094(10) F3 0.0165(11) 0.0402(15) 0.0536(17) -0.0046(12) 0.0008(11) -0.0048(10) F4 0.0255(12) 0.0248(12) 0.0499(15) 0.0034(11) 0.0052(11) -0.0083(9) F5 0.118(3) 0.061(2) 0.0470(18) 0.0157(16) 0.046(2) 0.061(2) F6A 0.0391(11) 0.0426(12) 0.0413(11) 0.0007(7) 0.0123(7) 0.0027(7) F7A 0.0335(10) 0.0380(12) 0.0371(10) 0.0005(7) 0.0088(7) 0.0006(7) F6B 0.0391(11) 0.0426(12) 0.0413(11) 0.0007(7) 0.0123(7) 0.0027(7) F7B 0.0335(10) 0.0380(12) 0.0371(10) 0.0005(7) 0.0088(7) 0.0006(7) F8 0.0490(17) 0.062(2) 0.0310(14) -0.0033(13) 0.0019(12) -0.0345(15) N1 0.0305(18) 0.046(2) 0.0254(18) 0.0048(15) 0.0103(14) 0.0001(16) O1 0.0190(13) 0.0283(14) 0.0244(13) 0.0067(11) 0.0022(10) -0.0020(10) O2 0.0240(13) 0.0211(14) 0.0390(16) 0.0054(12) 0.0022(12) 0.0009(11) O3 0.0231(13) 0.0261(14) 0.0278(14) -0.0041(11) 0.0052(11) -0.0029(11) O4 0.0216(12) 0.0263(14) 0.0249(13) 0.0032(10) 0.0109(10) -0.0001(10) O5 0.0319(15) 0.0217(13) 0.0250(14) 0.0019(10) 0.0104(11) -0.0025(11) O6 0.0182(12) 0.0222(13) 0.0194(12) 0.0018(10) 0.0046(9) 0.0009(10) O7 0.0304(15) 0.0302(15) 0.0211(13) -0.0010(11) 0.0092(11) -0.0019(11) O8 0.086(3) 0.0291(17) 0.0323(17) -0.0077(13) 0.0269(18) -0.0213(17) O9 0.0288(14) 0.0279(14) 0.0272(14) -0.0038(11) 0.0118(11) -0.0075(11) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 O1 2.376(3) . ? Ag1 O5 2.384(3) . ? Ag1 O4 2.395(3) 3_666 ? Ag1 O8 2.550(4) 2_645 ? Ag1 Ag2 2.9399(5) . ? Ag1 Ag3 3.3187(5) . ? Ag2 O2 2.193(3) . ? Ag2 O6 2.238(2) . ? Ag2 O9 2.545(3) . ? Ag3 O8 2.321(3) 1_545 ? Ag3 O3 2.355(3) . ? Ag3 O4 2.380(3) 3_666 ? Ag3 O1 2.550(3) 3_666 ? Ag3 Ag4 2.9521(5) 3_666 ? Ag3 Ag3 3.2252(6) 3_666 ? Ag4 O7 2.336(3) 3_676 ? Ag4 O5 2.388(3) . ? Ag4 O9 2.403(3) 3_676 ? Ag4 O3 2.548(3) 3_666 ? Ag4 Ag3 2.9522(5) 3_666 ? C1 O2 1.246(5) . ? C1 O1 1.259(4) . ? C1 C2 1.523(5) . ? C2 C7 1.401(5) . ? C2 C3 1.402(5) . ? C3 C4 1.382(5) . ? C3 C8 1.527(5) . ? C4 F1 1.355(4) . ? C4 C5 1.391(5) . ? C5 F2 1.351(4) . ? C5 C6 1.375(6) . ? C6 F3 1.354(4) . ? C6 C7 1.388(5) . ? C7 F4 1.335(4) . ? C8 O3 1.256(5) . ? C8 O4 1.257(4) . ? C9 O5 1.259(5) . ? C9 O6 1.264(4) . ? C9 C10 1.507(5) . ? C10 C15 1.376(5) . ? C10 C11 1.393(6) . ? C11 C12 1.389(6) . ? C11 C16 1.501(6) . ? C12 F5 1.355(5) . ? C12 C13 1.390(9) . ? C13 F6A 1.349(5) . ? C13 C14 1.388(9) . ? C13 F6B 1.423(7) . ? C14 F7B 1.303(6) . ? C14 C15 1.370(7) . ? C14 F7A 1.411(6) . ? C15 F8 1.342(6) . ? C16 O8 1.256(5) . ? C16 O7 1.256(5) . ? C17 O9 1.243(5) . ? C17 N1 1.328(6) . ? C17 H17 0.9300 . ? C18 N1 1.444(5) . ? C18 H18A 0.9600 . ? C18 H18B 0.9600 . ? C18 H18C 0.9600 . ? C19 N1 1.460(7) . ? C19 H19A 0.9600 . ? C19 H19B 0.9600 . ? C19 H19C 0.9600 . ? O1 Ag3 2.550(3) 3_666 ? O3 Ag4 2.548(3) 3_666 ? O4 Ag3 2.380(3) 3_666 ? O4 Ag1 2.394(3) 3_666 ? O7 Ag4 2.336(3) 3_676 ? O8 Ag3 2.321(3) 1_565 ? O8 Ag1 2.550(4) 2_655 ? O9 Ag4 2.403(3) 3_676 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag O1 Ag1 O5 124.52(10) . . ? O1 Ag1 O4 101.26(9) . 3_666 ? O5 Ag1 O4 85.40(9) . 3_666 ? O1 Ag1 O8 96.92(11) . 2_645 ? O5 Ag1 O8 98.52(10) . 2_645 ? O4 Ag1 O8 154.83(11) 3_666 2_645 ? O1 Ag1 Ag2 71.16(7) . . ? O5 Ag1 Ag2 71.41(7) . . ? O4 Ag1 Ag2 142.70(7) 3_666 . ? O8 Ag1 Ag2 60.35(8) 2_645 . ? O1 Ag1 Ag3 67.35(7) . . ? O5 Ag1 Ag3 129.68(7) . . ? O4 Ag1 Ag3 45.78(6) 3_666 . ? O8 Ag1 Ag3 130.45(7) 2_645 . ? Ag2 Ag1 Ag3 138.028(13) . . ? O2 Ag2 O6 172.10(10) . . ? O2 Ag2 O9 105.11(10) . . ? O6 Ag2 O9 82.31(9) . . ? O2 Ag2 Ag1 90.45(7) . . ? O6 Ag2 Ag1 82.17(7) . . ? O9 Ag2 Ag1 164.44(7) . . ? O8 Ag3 O3 107.40(13) 1_545 . ? O8 Ag3 O4 105.22(12) 1_545 3_666 ? O3 Ag3 O4 142.69(10) . 3_666 ? O8 Ag3 O1 99.35(11) 1_545 3_666 ? O3 Ag3 O1 119.75(9) . 3_666 ? O4 Ag3 O1 71.29(9) 3_666 3_666 ? O8 Ag3 Ag4 66.04(10) 1_545 3_666 ? O3 Ag3 Ag4 56.02(7) . 3_666 ? O4 Ag3 Ag4 158.96(6) 3_666 3_666 ? O1 Ag3 Ag4 90.75(6) 3_666 3_666 ? O8 Ag3 Ag3 165.05(10) 1_545 3_666 ? O3 Ag3 Ag3 85.92(7) . 3_666 ? O4 Ag3 Ag3 64.78(7) 3_666 3_666 ? O1 Ag3 Ag3 67.41(6) 3_666 3_666 ? Ag4 Ag3 Ag3 119.103(17) 3_666 3_666 ? O8 Ag3 Ag1 119.50(8) 1_545 . ? O3 Ag3 Ag1 100.81(7) . . ? O4 Ag3 Ag1 46.15(6) 3_666 . ? O1 Ag3 Ag1 111.13(6) 3_666 . ? Ag4 Ag3 Ag1 154.887(14) 3_666 . ? Ag3 Ag3 Ag1 62.604(13) 3_666 . ? O7 Ag4 O5 119.42(10) 3_676 . ? O7 Ag4 O9 93.41(9) 3_676 3_676 ? O5 Ag4 O9 135.32(10) . 3_676 ? O7 Ag4 O3 133.52(10) 3_676 3_666 ? O5 Ag4 O3 86.67(9) . 3_666 ? O9 Ag4 O3 91.50(9) 3_676 3_666 ? O7 Ag4 Ag3 84.73(7) 3_676 3_666 ? O5 Ag4 Ag3 104.76(7) . 3_666 ? O9 Ag4 Ag3 107.87(7) 3_676 3_666 ? O3 Ag4 Ag3 50.04(6) 3_666 3_666 ? O2 C1 O1 126.7(3) . . ? O2 C1 C2 116.9(3) . . ? O1 C1 C2 116.4(3) . . ? C7 C2 C3 117.9(3) . . ? C7 C2 C1 121.8(3) . . ? C3 C2 C1 120.3(3) . . ? C4 C3 C2 119.9(3) . . ? C4 C3 C8 117.2(3) . . ? C2 C3 C8 122.8(3) . . ? F1 C4 C3 120.7(3) . . ? F1 C4 C5 117.7(3) . . ? C3 C4 C5 121.6(3) . . ? F2 C5 C6 120.1(4) . . ? F2 C5 C4 120.9(4) . . ? C6 C5 C4 119.0(3) . . ? F3 C6 C5 119.6(4) . . ? F3 C6 C7 120.2(4) . . ? C5 C6 C7 120.2(3) . . ? F4 C7 C6 115.8(3) . . ? F4 C7 C2 122.8(3) . . ? C6 C7 C2 121.4(3) . . ? O3 C8 O4 127.3(3) . . ? O3 C8 C3 117.8(3) . . ? O4 C8 C3 114.8(3) . . ? O5 C9 O6 126.7(3) . . ? O5 C9 C10 116.3(3) . . ? O6 C9 C10 117.0(3) . . ? C15 C10 C11 120.2(4) . . ? C15 C10 C9 121.1(4) . . ? C11 C10 C9 118.7(3) . . ? C12 C11 C10 117.9(4) . . ? C12 C11 C16 121.0(4) . . ? C10 C11 C16 121.0(3) . . ? F5 C12 C11 120.2(5) . . ? F5 C12 C13 117.5(4) . . ? C11 C12 C13 122.3(4) . . ? F6A C13 C14 111.3(6) . . ? F6A C13 C12 130.7(6) . . ? C14 C13 C12 118.0(4) . . ? C14 C13 F6B 137.6(6) . . ? C12 C13 F6B 104.4(6) . . ? F7B C14 C15 138.9(7) . . ? F7B C14 C13 100.5(6) . . ? C15 C14 C13 120.6(4) . . ? C15 C14 F7A 112.3(6) . . ? C13 C14 F7A 127.1(5) . . ? F8 C15 C14 116.8(4) . . ? F8 C15 C10 122.2(4) . . ? C14 C15 C10 121.0(5) . . ? O8 C16 O7 125.5(4) . . ? O8 C16 C11 117.7(4) . . ? O7 C16 C11 116.8(4) . . ? O9 C17 N1 125.1(4) . . ? O9 C17 H17 117.5 . . ? N1 C17 H17 117.5 . . ? N1 C18 H18A 109.5 . . ? N1 C18 H18B 109.5 . . ? H18A C18 H18B 109.5 . . ? N1 C18 H18C 109.5 . . ? H18A C18 H18C 109.5 . . ? H18B C18 H18C 109.5 . . ? N1 C19 H19A 109.5 . . ? N1 C19 H19B 109.5 . . ? H19A C19 H19B 109.5 . . ? N1 C19 H19C 109.5 . . ? H19A C19 H19C 109.5 . . ? H19B C19 H19C 109.5 . . ? C17 N1 C18 120.8(4) . . ? C17 N1 C19 121.4(4) . . ? C18 N1 C19 117.7(4) . . ? C1 O1 Ag1 131.0(2) . . ? C1 O1 Ag3 120.6(2) . 3_666 ? Ag1 O1 Ag3 87.23(9) . 3_666 ? C1 O2 Ag2 116.5(2) . . ? C8 O3 Ag3 104.8(2) . . ? C8 O3 Ag4 125.3(2) . 3_666 ? Ag3 O3 Ag4 73.94(8) . 3_666 ? C8 O4 Ag3 117.8(2) . 3_666 ? C8 O4 Ag1 126.6(2) . 3_666 ? Ag3 O4 Ag1 88.07(9) 3_666 3_666 ? C9 O5 Ag1 120.8(2) . . ? C9 O5 Ag4 109.1(2) . . ? Ag1 O5 Ag4 92.08(10) . . ? C9 O6 Ag2 113.3(2) . . ? C16 O7 Ag4 106.4(3) . 3_676 ? C16 O8 Ag3 125.1(3) . 1_565 ? C16 O8 Ag1 102.9(3) . 2_655 ? Ag3 O8 Ag1 122.25(15) 1_565 2_655 ? C17 O9 Ag4 127.0(3) . 3_676 ? C17 O9 Ag2 110.7(3) . . ? Ag4 O9 Ag2 103.23(10) 3_676 . ? _diffrn_measured_fraction_theta_max 0.993 _diffrn_reflns_theta_full 27.63 _diffrn_measured_fraction_theta_full 0.993 _refine_diff_density_max 1.297 _refine_diff_density_min -1.275 _refine_diff_density_rms 0.142