# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2013


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data_sad_a
_database_code_depnum_ccdc_archive 'CCDC 912595'
#TrackingRef 'sad_a.cif'
_vrf_PLAT906_sad_a               
;
RESPONSE:
the data was checked for twinning but no twin law could be found.
;
_audit_creation_method           SHELXL-2012
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C24 H28 Cl F6 N3 Si'
_chemical_formula_sum            'C24 H28 Cl F6 N3 Si'
_chemical_formula_weight         536.03
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'
_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
_cell_length_a                   10.617(2)
_cell_length_b                   16.479(3)
_cell_length_c                   14.578(2)
_cell_angle_alpha                90
_cell_angle_beta                 93.59(2)
_cell_angle_gamma                90
_cell_volume                     2545.5(8)
_cell_formula_units_Z            4
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    3258
_cell_measurement_theta_min      2.285
_cell_measurement_theta_max      24.998
_exptl_crystal_description       plate
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.399
_exptl_crystal_F_000             1112
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.050
_exptl_absorpt_coefficient_mu    0.259
_shelx_estimated_absorpt_T_min   0.975
_shelx_estimated_absorpt_T_max   0.987
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9474
_exptl_absorpt_correction_T_max  0.999
_exptl_absorpt_process_details   'SADABS-2008/2, Sheldrick, Goettingen'
_exptl_special_details           
;
?
;
_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'rotating anode (TXS)'
_diffrn_radiation_monochromator  mirror
_diffrn_measurement_device_type  'Bruker Smart APEX II Ultra'
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            18144
_diffrn_reflns_sigmaI/netI       0.0448
_diffrn_reflns_av_R_equivalents  0.0441
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.867
_diffrn_reflns_theta_max         25.358
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             4661
_reflns_number_gt                3389
_reflns_threshold_expression     'I > 2\s(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .
_reflns_special_details          
;
The reflections were merged according to the crystal class
for structure refinement and the calculation of statistics.
_reflns_Friedel_fraction is defined as the number of unique
Friedel pairs measured divided by the number that would be
possible theoretically, ignoring centric projections and
systematic absences.
;
_computing_data_collection       'APEX2 v2011.2'
_computing_cell_refinement       'SAINT V7.68A'
_computing_data_reduction        'SAINT V7.68A'
_computing_structure_solution    'SHELXS in SHELXTL Version 2008/3'
_computing_structure_refinement  'SHELXS in SHELXTL Version 2008/3'
_computing_molecular_graphics    'XSHELL in SHELXTL-97'
_computing_publication_material  'XSHELL in SHELXTL-97'
_refine_special_details          
;
?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
w=1/[\s^2^(Fo^2^)+(0.0413P)^2^+0.4441P]
where P=(Fo^2^+2Fc^2^)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4661
_refine_ls_number_parameters     322
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0652
_refine_ls_R_factor_gt           0.0399
_refine_ls_wR_factor_ref         0.0904
_refine_ls_wR_factor_gt          0.0839
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_restrained_S_all      1.042
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.23500(5) 0.34735(4) 0.56873(4) 0.02832(15) Uani 1 1 d D . .
Si1 Si 0.20082(5) 0.33791(4) 0.42614(4) 0.01852(15) Uani 1 1 d D . .
F1 F 0.52375(13) 0.33105(10) 0.50699(10) 0.0467(4) Uani 1 1 d D . .
N1 N 0.04115(16) 0.32211(10) 0.38160(11) 0.0193(4) Uani 1 1 d D . .
C1 C 0.0383(2) 0.24219(12) 0.40723(13) 0.0185(5) Uani 1 1 d D . .
F2 F 0.60092(13) 0.44135(10) 0.45355(10) 0.0522(4) Uani 1 1 d D . .
N2 N 0.15423(17) 0.22392(10) 0.43642(11) 0.0187(4) Uani 1 1 d D . .
C2 C -0.0764(2) 0.19091(13) 0.40761(14) 0.0200(5) Uani 1 1 d D . .
F3 F 0.34306(16) 0.43584(10) 0.23194(11) 0.0595(5) Uani 1 1 d D . .
N3 N 0.33335(16) 0.32232(10) 0.36311(11) 0.0198(4) Uani 1 1 d D . .
C3 C -0.1555(2) 0.19896(14) 0.47955(15) 0.0266(5) Uani 1 1 d D . .
H3 H -0.1341 0.2356 0.5284 0.032 Uiso 1 1 calc RD . .
C4 C -0.2651(2) 0.15377(15) 0.48015(17) 0.0336(6) Uani 1 1 d D . .
H4 H -0.3192 0.1593 0.5292 0.040 Uiso 1 1 calc RD . .
F4 F 0.42699(17) 0.52100(9) 0.32802(11) 0.0595(5) Uani 1 1 d D . .
C5 C -0.2957(2) 0.10033(14) 0.40891(18) 0.0347(6) Uani 1 1 d D . .
H5 H -0.3711 0.0693 0.4092 0.042 Uiso 1 1 calc RD . .
F5 F 0.54341(15) 0.44344(9) 0.25424(11) 0.0568(5) Uani 1 1 d D . .
C6 C -0.2174(2) 0.09189(14) 0.33761(16) 0.0306(6) Uani 1 1 d D . .
H6 H -0.2391 0.0551 0.2890 0.037 Uiso 1 1 calc RD . .
F6 F 0.20135(11) 0.43734(7) 0.41423(8) 0.0248(3) Uani 1 1 d D . .
C7 C -0.1071(2) 0.13688(13) 0.33668(15) 0.0247(5) Uani 1 1 d D . .
H7 H -0.0529 0.1308 0.2877 0.030 Uiso 1 1 calc RD . .
C8 C -0.0568(2) 0.37583(13) 0.33435(14) 0.0215(5) Uani 1 1 d D . .
C9 C -0.1719(2) 0.32948(15) 0.29427(17) 0.0346(6) Uani 1 1 d D . .
H9A H -0.2164 0.3049 0.3443 0.052 Uiso 1 1 calc RD . .
H9B H -0.1447 0.2868 0.2531 0.052 Uiso 1 1 calc RD . .
H9C H -0.2287 0.3669 0.2597 0.052 Uiso 1 1 calc RD . .
C10 C -0.0983(2) 0.43823(14) 0.40299(15) 0.0307(6) Uani 1 1 d D . .
H10A H -0.1366 0.4105 0.4538 0.046 Uiso 1 1 calc RD . .
H10B H -0.1602 0.4750 0.3725 0.046 Uiso 1 1 calc RD . .
H10C H -0.0249 0.4695 0.4270 0.046 Uiso 1 1 calc RD . .
C11 C 0.0043(2) 0.41786(14) 0.25431(15) 0.0292(6) Uani 1 1 d D . .
H11A H 0.0795 0.4476 0.2778 0.044 Uiso 1 1 calc RD . .
H11B H -0.0560 0.4558 0.2241 0.044 Uiso 1 1 calc RD . .
H11C H 0.0285 0.3770 0.2098 0.044 Uiso 1 1 calc RD . .
C12 C 0.2017(2) 0.14702(13) 0.48088(14) 0.0230(5) Uani 1 1 d D . .
C13 C 0.1320(2) 0.12872(14) 0.56700(15) 0.0308(6) Uani 1 1 d D . .
H13A H 0.1729 0.0831 0.6001 0.046 Uiso 1 1 calc RD . .
H13B H 0.0441 0.1146 0.5493 0.046 Uiso 1 1 calc RD . .
H13C H 0.1341 0.1767 0.6068 0.046 Uiso 1 1 calc RD . .
C14 C 0.1877(2) 0.07651(14) 0.41273(15) 0.0325(6) Uani 1 1 d D . .
H14A H 0.2271 0.0278 0.4403 0.049 Uiso 1 1 calc RD . .
H14B H 0.2290 0.0905 0.3566 0.049 Uiso 1 1 calc RD . .
H14C H 0.0979 0.0661 0.3976 0.049 Uiso 1 1 calc RD . .
C15 C 0.3415(2) 0.15854(14) 0.50761(15) 0.0295(6) Uani 1 1 d D . .
H15A H 0.3523 0.2037 0.5511 0.044 Uiso 1 1 calc RD . .
H15B H 0.3866 0.1705 0.4525 0.044 Uiso 1 1 calc RD . .
H15C H 0.3756 0.1088 0.5364 0.044 Uiso 1 1 calc RD . .
C16 C 0.3499(2) 0.25983(13) 0.29626(13) 0.0204(5) Uani 1 1 d D . .
C17 C 0.2476(2) 0.23419(13) 0.23972(14) 0.0234(5) Uani 1 1 d D . .
H17 H 0.1677 0.2595 0.2439 0.028 Uiso 1 1 calc RD . .
C18 C 0.2615(2) 0.17171(14) 0.17703(14) 0.0298(6) Uani 1 1 d D . .
H18 H 0.1907 0.1536 0.1394 0.036 Uiso 1 1 calc RD . .
C19 C 0.3777(3) 0.13602(14) 0.16936(15) 0.0337(6) Uani 1 1 d D . .
H19 H 0.3871 0.0930 0.1270 0.040 Uiso 1 1 calc RD . .
C20 C 0.4797(3) 0.16289(15) 0.22313(16) 0.0357(6) Uani 1 1 d D . .
H20 H 0.5602 0.1392 0.2167 0.043 Uiso 1 1 calc RD . .
C21 C 0.4667(2) 0.22452(14) 0.28700(14) 0.0267(5) Uani 1 1 d D . .
H21 H 0.5379 0.2424 0.3243 0.032 Uiso 1 1 calc RD . .
C22 C 0.4297(2) 0.38238(14) 0.36983(15) 0.0246(5) Uani 1 1 d D . .
C23 C 0.4350(2) 0.44526(15) 0.29654(17) 0.0346(6) Uani 1 1 d D . .
C24 C 0.5137(2) 0.38448(16) 0.43967(17) 0.0332(6) Uani 1 1 d D . .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Cl1 0.0324(3) 0.0330(3) 0.0195(3) -0.0057(2) 0.0014(2) 0.0014(3)
Si1 0.0186(3) 0.0194(3) 0.0176(3) -0.0007(2) 0.0012(2) 0.0016(3)
F1 0.0347(9) 0.0623(11) 0.0412(9) 0.0017(8) -0.0122(7) 0.0003(8)
N1 0.0199(10) 0.0171(10) 0.0207(9) 0.0008(7) 0.0004(7) 0.0023(8)
C1 0.0221(12) 0.0203(12) 0.0134(10) -0.0035(9) 0.0029(9) 0.0003(10)
F2 0.0281(9) 0.0605(11) 0.0680(11) -0.0221(8) 0.0042(7) -0.0157(8)
N2 0.0218(10) 0.0179(10) 0.0163(9) 0.0018(7) 0.0010(7) 0.0005(8)
C2 0.0226(12) 0.0160(11) 0.0216(11) 0.0014(9) 0.0010(9) 0.0018(9)
F3 0.0654(12) 0.0582(11) 0.0531(10) 0.0336(8) -0.0107(9) -0.0169(9)
N3 0.0200(10) 0.0184(10) 0.0210(9) -0.0019(7) 0.0024(7) 0.0005(8)
C3 0.0302(14) 0.0246(13) 0.0253(12) -0.0010(10) 0.0047(10) -0.0003(11)
C4 0.0280(14) 0.0337(15) 0.0401(15) 0.0074(12) 0.0101(11) -0.0008(12)
F4 0.0850(13) 0.0226(9) 0.0748(11) 0.0003(8) 0.0363(10) 0.0014(8)
C5 0.0256(14) 0.0229(14) 0.0554(17) 0.0055(12) 0.0017(12) -0.0046(11)
F5 0.0559(11) 0.0515(10) 0.0677(11) 0.0101(8) 0.0417(9) 0.0031(8)
C6 0.0306(14) 0.0208(13) 0.0392(14) -0.0035(11) -0.0075(11) 0.0008(11)
F6 0.0214(7) 0.0237(7) 0.0295(7) 0.0010(5) 0.0035(5) 0.0016(5)
C7 0.0238(13) 0.0218(13) 0.0285(12) 0.0002(10) 0.0012(10) 0.0040(10)
C8 0.0206(12) 0.0194(12) 0.0243(12) 0.0018(9) -0.0010(9) 0.0044(9)
C9 0.0289(14) 0.0334(15) 0.0394(14) 0.0074(12) -0.0133(11) 0.0018(11)
C10 0.0281(14) 0.0336(14) 0.0301(13) -0.0021(11) -0.0013(10) 0.0094(11)
C11 0.0331(14) 0.0294(14) 0.0247(12) 0.0062(10) -0.0017(10) 0.0076(11)
C12 0.0302(14) 0.0206(12) 0.0180(11) 0.0039(9) -0.0005(9) 0.0042(10)
C13 0.0365(15) 0.0301(14) 0.0259(12) 0.0107(10) 0.0023(10) 0.0030(11)
C14 0.0455(16) 0.0221(13) 0.0294(13) 0.0017(10) -0.0026(11) 0.0104(12)
C15 0.0343(14) 0.0287(14) 0.0251(12) 0.0086(10) -0.0011(10) 0.0081(11)
C16 0.0245(13) 0.0211(12) 0.0161(11) 0.0025(9) 0.0043(9) 0.0026(10)
C17 0.0277(13) 0.0239(13) 0.0188(11) 0.0039(9) 0.0035(9) 0.0009(10)
C18 0.0448(16) 0.0278(14) 0.0169(11) 0.0011(10) 0.0022(10) -0.0040(12)
C19 0.0587(18) 0.0257(14) 0.0172(12) -0.0012(10) 0.0076(12) 0.0088(13)
C20 0.0424(16) 0.0374(15) 0.0282(13) 0.0031(11) 0.0102(11) 0.0155(13)
C21 0.0285(14) 0.0306(14) 0.0214(12) 0.0017(10) 0.0040(10) 0.0050(11)
C22 0.0201(12) 0.0246(13) 0.0296(13) -0.0047(10) 0.0060(10) 0.0006(10)
C23 0.0342(15) 0.0276(15) 0.0438(16) 0.0006(12) 0.0157(12) -0.0018(12)
C24 0.0211(13) 0.0387(15) 0.0401(15) -0.0089(12) 0.0035(11) -0.0063(12)
_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 Si1 2.0935(8) . ?
Si1 F6 1.6476(13) . ?
Si1 N3 1.7470(18) . ?
Si1 N1 1.7959(18) . ?
Si1 N2 1.9507(18) . ?
Si1 C1 2.342(2) . ?
F1 C24 1.318(3) . ?
N1 C1 1.370(3) . ?
N1 C8 1.500(3) . ?
C1 N2 1.312(3) . ?
C1 C2 1.482(3) . ?
F2 C24 1.324(3) . ?
N2 C12 1.496(3) . ?
C2 C7 1.388(3) . ?
C2 C3 1.390(3) . ?
F3 C23 1.322(3) . ?
N3 C22 1.423(3) . ?
N3 C16 1.436(3) . ?
C3 C4 1.382(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.385(3) . ?
C4 H4 0.9500 . ?
F4 C23 1.334(3) . ?
C5 C6 1.378(3) . ?
C5 H5 0.9500 . ?
F5 C23 1.340(3) . ?
C6 C7 1.387(3) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 C10 1.519(3) . ?
C8 C9 1.526(3) . ?
C8 C11 1.535(3) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C15 1.522(3) . ?
C12 C13 1.527(3) . ?
C12 C14 1.530(3) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C21 1.384(3) . ?
C16 C17 1.388(3) . ?
C17 C18 1.391(3) . ?
C17 H17 0.9500 . ?
C18 C19 1.378(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.370(4) . ?
C19 H19 0.9500 . ?
C20 C21 1.391(3) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C24 1.311(3) . ?
C22 C23 1.492(3) . ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F6 Si1 N3 94.74(7) . . ?
F6 Si1 N1 96.63(7) . . ?
N3 Si1 N1 124.17(8) . . ?
F6 Si1 N2 165.53(8) . . ?
N3 Si1 N2 96.62(8) . . ?
N1 Si1 N2 69.51(8) . . ?
F6 Si1 Cl1 91.67(5) . . ?
N3 Si1 Cl1 115.97(7) . . ?
N1 Si1 Cl1 118.08(6) . . ?
N2 Si1 Cl1 91.39(5) . . ?
F6 Si1 C1 131.67(7) . . ?
N3 Si1 C1 116.81(8) . . ?
N1 Si1 C1 35.68(7) . . ?
N2 Si1 C1 34.08(7) . . ?
Cl1 Si1 C1 104.33(6) . . ?
C1 N1 C8 131.76(18) . . ?
C1 N1 Si1 94.44(13) . . ?
C8 N1 Si1 133.79(14) . . ?
N2 C1 N1 105.82(18) . . ?
N2 C1 C2 128.46(19) . . ?
N1 C1 C2 125.57(19) . . ?
N2 C1 Si1 56.41(11) . . ?
N1 C1 Si1 49.88(10) . . ?
C2 C1 Si1 169.45(15) . . ?
C1 N2 C12 128.22(18) . . ?
C1 N2 Si1 89.50(13) . . ?
C12 N2 Si1 140.23(14) . . ?
C7 C2 C3 119.9(2) . . ?
C7 C2 C1 121.20(19) . . ?
C3 C2 C1 118.90(19) . . ?
C22 N3 C16 115.31(17) . . ?
C22 N3 Si1 117.45(13) . . ?
C16 N3 Si1 126.81(14) . . ?
C4 C3 C2 120.1(2) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C3 C4 C5 119.7(2) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C6 C5 C4 120.4(2) . . ?
C6 C5 H5 119.8 . . ?
C4 C5 H5 119.8 . . ?
C5 C6 C7 120.2(2) . . ?
C5 C6 H6 119.9 . . ?
C7 C6 H6 119.9 . . ?
C6 C7 C2 119.7(2) . . ?
C6 C7 H7 120.2 . . ?
C2 C7 H7 120.2 . . ?
N1 C8 C10 108.56(17) . . ?
N1 C8 C9 113.33(18) . . ?
C10 C8 C9 109.42(19) . . ?
N1 C8 C11 107.53(17) . . ?
C10 C8 C11 110.43(18) . . ?
C9 C8 C11 107.54(18) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C8 C11 H11A 109.5 . . ?
C8 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C8 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N2 C12 C15 107.57(17) . . ?
N2 C12 C13 110.84(17) . . ?
C15 C12 C13 109.23(18) . . ?
N2 C12 C14 110.20(16) . . ?
C15 C12 C14 108.34(18) . . ?
C13 C12 C14 110.56(19) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C21 C16 C17 119.1(2) . . ?
C21 C16 N3 121.1(2) . . ?
C17 C16 N3 119.79(19) . . ?
C16 C17 C18 120.3(2) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C19 C18 C17 120.1(2) . . ?
C19 C18 H18 120.0 . . ?
C17 C18 H18 120.0 . . ?
C20 C19 C18 119.7(2) . . ?
C20 C19 H19 120.2 . . ?
C18 C19 H19 120.2 . . ?
C19 C20 C21 120.7(2) . . ?
C19 C20 H20 119.6 . . ?
C21 C20 H20 119.6 . . ?
C16 C21 C20 120.0(2) . . ?
C16 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C24 C22 N3 121.5(2) . . ?
C24 C22 C23 118.9(2) . . ?
N3 C22 C23 119.5(2) . . ?
F3 C23 F4 107.1(2) . . ?
F3 C23 F5 106.7(2) . . ?
F4 C23 F5 104.7(2) . . ?
F3 C23 C22 111.7(2) . . ?
F4 C23 C22 113.4(2) . . ?
F5 C23 C22 112.7(2) . . ?
C22 C24 F1 125.4(2) . . ?
C22 C24 F2 124.9(2) . . ?
F1 C24 F2 109.6(2) . . ?
_refine_diff_density_max         0.251
_refine_diff_density_min         -0.311
_refine_diff_density_rms         0.049