# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
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#  from this site to visualise CIF-encoded structures and 
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data_cd201298
#TrackingRef 'cd201298.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H20 F2 N2 O2'
_chemical_formula_weight         406.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.8897(16)
_cell_length_b                   9.8944(17)
_cell_length_c                   11.4945(18)
_cell_angle_alpha                107.042(3)
_cell_angle_beta                 92.711(4)
_cell_angle_gamma                99.386(3)
_cell_volume                     1055.6(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    1191
_cell_measurement_theta_min      4.382
_cell_measurement_theta_max      41.414

_exptl_crystal_description       prismatic
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.307
_exptl_crystal_size_mid          0.141
_exptl_crystal_size_min          0.086
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.279
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             424
_exptl_absorpt_coefficient_mu    0.094
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.42585
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            5581
_diffrn_reflns_av_R_equivalents  0.0523
_diffrn_reflns_av_sigmaI/netI    0.0714
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_theta_min         1.86
_diffrn_reflns_theta_max         25.48
_reflns_number_total             3856
_reflns_number_gt                1887
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0797P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.0024(9)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_number_reflns         3856
_refine_ls_number_parameters     282
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1050
_refine_ls_R_factor_gt           0.0583
_refine_ls_wR_factor_ref         0.1527
_refine_ls_wR_factor_gt          0.1381
_refine_ls_goodness_of_fit_ref   0.833
_refine_ls_restrained_S_all      0.833
_refine_ls_shift/su_max          0.036
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 1.26241(14) 0.29067(17) 0.30527(14) 0.0950(5) Uani 1 1 d . . .
F2 F 0.35707(17) -0.09679(17) 0.30871(15) 0.1016(6) Uani 1 1 d . . .
N1 N 1.1044(2) 0.2861(3) 0.4466(2) 0.0726(6) Uani 1 1 d . . .
N2 N 0.4335(2) 0.1256(2) 0.4521(2) 0.0737(6) Uani 1 1 d . . .
O1 O 0.78174(19) -0.0578(2) 0.42086(18) 0.0919(6) Uani 1 1 d . . .
O2 O 0.75614(19) 0.4415(2) 0.42176(18) 0.0930(6) Uani 1 1 d . . .
C1 C 0.8443(3) -0.0358(3) 0.3357(3) 0.0692(7) Uani 1 1 d . . .
C2 C 0.9592(2) 0.0822(3) 0.3563(2) 0.0649(7) Uani 1 1 d . . .
C3 C 1.0647(2) 0.0989(3) 0.2775(2) 0.0690(7) Uani 1 1 d . . .
H3 H 1.0731 0.0362 0.2013 0.083 Uiso 1 1 calc R . .
C4 C 1.1475(3) 0.2220(3) 0.3357(3) 0.0729(7) Uani 1 1 d . . .
C5 C 0.9881(3) 0.1992(3) 0.4596(2) 0.0691(7) Uani 1 1 d . . .
C6 C 0.9168(3) 0.2412(3) 0.5730(2) 0.0883(9) Uani 1 1 d . . .
H6A H 0.9160 0.1697 0.6143 0.132 Uiso 1 1 calc R . .
H6B H 0.8238 0.2483 0.5515 0.132 Uiso 1 1 calc R . .
H6C H 0.9646 0.3325 0.6259 0.132 Uiso 1 1 calc R . .
C7 C 0.7988(2) -0.1328(3) 0.2102(2) 0.0641(7) Uani 1 1 d . . .
C8 C 0.7957(2) -0.0836(3) 0.1089(2) 0.0688(7) Uani 1 1 d . . .
H8 H 0.8312 0.0123 0.1178 0.083 Uiso 1 1 calc R . .
C9 C 0.7411(3) -0.1742(3) -0.0040(3) 0.0811(8) Uani 1 1 d . . .
H9 H 0.7378 -0.1394 -0.0707 0.097 Uiso 1 1 calc R . .
C10 C 0.6911(3) -0.3168(4) -0.0186(3) 0.0974(10) Uani 1 1 d . . .
H10 H 0.6545 -0.3786 -0.0953 0.117 Uiso 1 1 calc R . .
C11 C 0.6950(3) -0.3672(4) 0.0790(4) 0.1071(11) Uani 1 1 d . . .
H11 H 0.6626 -0.4642 0.0684 0.129 Uiso 1 1 calc R . .
C12 C 0.7462(3) -0.2770(3) 0.1929(3) 0.0866(9) Uani 1 1 d . . .
H12 H 0.7458 -0.3126 0.2593 0.104 Uiso 1 1 calc R . .
C13 C 0.6995(2) 0.3336(3) 0.3391(3) 0.0676(7) Uani 1 1 d . . .
C14 C 0.5915(2) 0.2291(3) 0.3598(2) 0.0625(6) Uani 1 1 d . . .
C15 C 0.5342(2) 0.0886(3) 0.2805(2) 0.0701(7) Uani 1 1 d . . .
H15 H 0.5579 0.0452 0.2028 0.084 Uiso 1 1 calc R . .
C16 C 0.4400(3) 0.0324(3) 0.3404(3) 0.0744(7) Uani 1 1 d . . .
C17 C 0.5274(3) 0.2472(3) 0.4671(2) 0.0661(7) Uani 1 1 d . . .
C18 C 0.5431(3) 0.3692(3) 0.5825(2) 0.0874(9) Uani 1 1 d . . .
H18A H 0.5415 0.3327 0.6512 0.131 Uiso 1 1 calc R . .
H18B H 0.4688 0.4206 0.5823 0.131 Uiso 1 1 calc R . .
H18C H 0.6292 0.4330 0.5884 0.131 Uiso 1 1 calc R . .
C19 C 0.7449(3) 0.3120(3) 0.2135(3) 0.0687(7) Uani 1 1 d . . .
C20 C 0.6544(3) 0.2557(3) 0.1082(3) 0.0861(8) Uani 1 1 d . . .
H20 H 0.5613 0.2272 0.1143 0.103 Uiso 1 1 calc R . .
C21 C 0.6995(5) 0.2414(4) -0.0045(3) 0.1178(12) Uani 1 1 d . . .
H21 H 0.6374 0.2043 -0.0744 0.141 Uiso 1 1 calc R . .
C22 C 0.8366(6) 0.2818(5) -0.0140(4) 0.1332(16) Uani 1 1 d . . .
H22 H 0.8676 0.2703 -0.0908 0.160 Uiso 1 1 calc R . .
C23 C 0.9285(4) 0.3389(4) 0.0885(5) 0.1206(13) Uani 1 1 d . . .
H23 H 1.0215 0.3665 0.0812 0.145 Uiso 1 1 calc R . .
C24 C 0.8830(3) 0.3556(3) 0.2030(3) 0.0900(9) Uani 1 1 d . . .
H24 H 0.9450 0.3961 0.2728 0.108 Uiso 1 1 calc R . .
H1 H 1.145(3) 0.382(3) 0.506(2) 0.098(9) Uiso 1 1 d . . .
H2 H 0.373(3) 0.113(3) 0.508(2) 0.092(9) Uiso 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
F1 0.0705(10) 0.1018(12) 0.1009(12) 0.0279(9) 0.0133(9) -0.0130(9)
F2 0.1109(12) 0.0811(12) 0.1007(12) 0.0253(9) 0.0184(9) -0.0145(10)
N1 0.0671(14) 0.0764(17) 0.0710(16) 0.0233(13) -0.0006(12) 0.0046(13)
N2 0.0731(15) 0.0791(17) 0.0711(17) 0.0269(13) 0.0165(13) 0.0103(13)
O1 0.0821(13) 0.1120(16) 0.0866(14) 0.0458(12) 0.0184(11) 0.0003(11)
O2 0.0841(13) 0.0774(14) 0.0975(15) 0.0094(11) 0.0125(11) -0.0104(11)
C1 0.0594(15) 0.0745(19) 0.084(2) 0.0362(16) 0.0116(15) 0.0164(14)
C2 0.0560(15) 0.0611(17) 0.0774(18) 0.0244(14) 0.0031(13) 0.0050(13)
C3 0.0604(15) 0.0672(18) 0.0756(17) 0.0181(14) 0.0121(14) 0.0063(14)
C4 0.0566(16) 0.080(2) 0.082(2) 0.0311(16) 0.0099(14) -0.0003(15)
C5 0.0564(15) 0.080(2) 0.0734(19) 0.0315(16) 0.0015(13) 0.0066(14)
C6 0.0852(19) 0.102(2) 0.078(2) 0.0263(16) 0.0130(16) 0.0178(17)
C7 0.0492(14) 0.0626(18) 0.0816(19) 0.0239(15) 0.0103(13) 0.0091(12)
C8 0.0555(15) 0.0639(17) 0.083(2) 0.0169(15) 0.0140(14) 0.0090(13)
C9 0.0679(17) 0.088(2) 0.077(2) 0.0114(17) 0.0119(15) 0.0078(16)
C10 0.078(2) 0.084(3) 0.102(3) -0.0073(19) 0.0033(18) 0.0028(18)
C11 0.094(2) 0.059(2) 0.155(4) 0.020(2) 0.005(2) 0.0030(17)
C12 0.0737(18) 0.067(2) 0.120(3) 0.0340(19) 0.0056(18) 0.0071(16)
C13 0.0560(15) 0.0612(17) 0.0835(19) 0.0181(15) 0.0056(14) 0.0127(14)
C14 0.0530(14) 0.0636(17) 0.0715(17) 0.0222(13) 0.0100(13) 0.0086(13)
C15 0.0624(16) 0.0718(19) 0.0762(17) 0.0229(15) 0.0170(14) 0.0088(14)
C16 0.0720(18) 0.0652(19) 0.083(2) 0.0253(16) 0.0051(15) -0.0012(15)
C17 0.0624(15) 0.0613(17) 0.0737(18) 0.0208(13) 0.0046(14) 0.0092(14)
C18 0.093(2) 0.087(2) 0.0786(19) 0.0198(16) 0.0195(16) 0.0141(17)
C19 0.0671(17) 0.0593(17) 0.087(2) 0.0273(14) 0.0224(16) 0.0179(13)
C20 0.101(2) 0.075(2) 0.082(2) 0.0272(16) 0.0079(19) 0.0081(17)
C21 0.182(4) 0.091(3) 0.080(3) 0.0301(18) 0.028(3) 0.012(3)
C22 0.200(5) 0.110(3) 0.117(3) 0.050(3) 0.087(4) 0.057(3)
C23 0.114(3) 0.115(3) 0.164(4) 0.068(3) 0.080(3) 0.045(2)
C24 0.0744(19) 0.094(2) 0.120(3) 0.0503(19) 0.0337(19) 0.0285(16)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C4 1.342(3) . ?
F2 C16 1.340(3) . ?
N1 C5 1.362(3) . ?
N1 C4 1.369(3) . ?
N1 H1 1.00(3) . ?
N2 C16 1.356(3) . ?
N2 C17 1.356(3) . ?
N2 H2 0.92(3) . ?
O1 C1 1.236(3) . ?
O2 C13 1.231(3) . ?
C1 C2 1.446(3) . ?
C1 C7 1.481(3) . ?
C2 C5 1.373(3) . ?
C2 C3 1.434(3) . ?
C3 C4 1.321(3) . ?
C3 H3 0.9300 . ?
C5 C6 1.495(3) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 C12 1.389(3) . ?
C7 C8 1.389(3) . ?
C8 C9 1.368(3) . ?
C8 H8 0.9300 . ?
C9 C10 1.374(4) . ?
C9 H9 0.9300 . ?
C10 C11 1.357(4) . ?
C10 H10 0.9300 . ?
C11 C12 1.367(4) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.440(3) . ?
C13 C19 1.499(3) . ?
C14 C17 1.392(3) . ?
C14 C15 1.427(3) . ?
C15 C16 1.330(3) . ?
C15 H15 0.9300 . ?
C17 C18 1.490(3) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.384(4) . ?
C19 C24 1.385(4) . ?
C20 C21 1.365(4) . ?
C20 H20 0.9300 . ?
C21 C22 1.369(5) . ?
C21 H21 0.9300 . ?
C22 C23 1.369(5) . ?
C22 H22 0.9300 . ?
C23 C24 1.384(5) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C5 N1 C4 107.5(2) . . ?
C5 N1 H1 124.6(15) . . ?
C4 N1 H1 127.7(15) . . ?
C16 N2 C17 108.7(2) . . ?
C16 N2 H2 127.0(17) . . ?
C17 N2 H2 124.3(17) . . ?
O1 C1 C2 121.4(3) . . ?
O1 C1 C7 118.6(2) . . ?
C2 C1 C7 119.9(2) . . ?
C5 C2 C3 107.3(2) . . ?
C5 C2 C1 124.9(2) . . ?
C3 C2 C1 127.8(3) . . ?
C4 C3 C2 105.7(2) . . ?
C4 C3 H3 127.1 . . ?
C2 C3 H3 127.1 . . ?
C3 C4 F1 131.6(3) . . ?
C3 C4 N1 111.4(2) . . ?
F1 C4 N1 117.0(2) . . ?
N1 C5 C2 108.0(2) . . ?
N1 C5 C6 119.9(2) . . ?
C2 C5 C6 132.1(2) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C12 C7 C8 117.9(2) . . ?
C12 C7 C1 119.3(3) . . ?
C8 C7 C1 122.7(2) . . ?
C9 C8 C7 120.9(3) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C8 C9 C10 119.9(3) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
C11 C10 C9 120.0(3) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C12 120.7(3) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C7 120.6(3) . . ?
C11 C12 H12 119.7 . . ?
C7 C12 H12 119.7 . . ?
O2 C13 C14 122.1(2) . . ?
O2 C13 C19 118.4(2) . . ?
C14 C13 C19 119.5(2) . . ?
C17 C14 C15 107.2(2) . . ?
C17 C14 C13 124.6(2) . . ?
C15 C14 C13 128.1(2) . . ?
C16 C15 C14 105.9(2) . . ?
C16 C15 H15 127.0 . . ?
C14 C15 H15 127.0 . . ?
C15 C16 F2 130.8(3) . . ?
C15 C16 N2 111.1(2) . . ?
F2 C16 N2 118.1(2) . . ?
N2 C17 C14 107.1(2) . . ?
N2 C17 C18 120.4(2) . . ?
C14 C17 C18 132.4(2) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 C24 118.8(3) . . ?
C20 C19 C13 122.9(2) . . ?
C24 C19 C13 118.3(3) . . ?
C21 C20 C19 121.1(3) . . ?
C21 C20 H20 119.5 . . ?
C19 C20 H20 119.5 . . ?
C20 C21 C22 119.7(4) . . ?
C20 C21 H21 120.2 . . ?
C22 C21 H21 120.2 . . ?
C21 C22 C23 120.6(4) . . ?
C21 C22 H22 119.7 . . ?
C23 C22 H22 119.7 . . ?
C22 C23 C24 119.9(4) . . ?
C22 C23 H23 120.1 . . ?
C24 C23 H23 120.1 . . ?
C23 C24 C19 119.9(3) . . ?
C23 C24 H24 120.0 . . ?
C19 C24 H24 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 C2 C5 -17.5(4) . . . . ?
C7 C1 C2 C5 162.0(2) . . . . ?
O1 C1 C2 C3 160.8(2) . . . . ?
C7 C1 C2 C3 -19.7(4) . . . . ?
C5 C2 C3 C4 -0.6(3) . . . . ?
C1 C2 C3 C4 -179.2(2) . . . . ?
C2 C3 C4 F1 179.9(3) . . . . ?
C2 C3 C4 N1 0.4(3) . . . . ?
C5 N1 C4 C3 0.0(3) . . . . ?
C5 N1 C4 F1 -179.5(2) . . . . ?
C4 N1 C5 C2 -0.4(3) . . . . ?
C4 N1 C5 C6 179.9(2) . . . . ?
C3 C2 C5 N1 0.7(3) . . . . ?
C1 C2 C5 N1 179.2(2) . . . . ?
C3 C2 C5 C6 -179.7(3) . . . . ?
C1 C2 C5 C6 -1.2(4) . . . . ?
O1 C1 C7 C12 -33.9(3) . . . . ?
C2 C1 C7 C12 146.6(2) . . . . ?
O1 C1 C7 C8 140.7(2) . . . . ?
C2 C1 C7 C8 -38.8(3) . . . . ?
C12 C7 C8 C9 0.7(3) . . . . ?
C1 C7 C8 C9 -173.9(2) . . . . ?
C7 C8 C9 C10 -1.4(4) . . . . ?
C8 C9 C10 C11 0.5(4) . . . . ?
C9 C10 C11 C12 1.2(5) . . . . ?
C10 C11 C12 C7 -1.9(5) . . . . ?
C8 C7 C12 C11 0.9(4) . . . . ?
C1 C7 C12 C11 175.7(3) . . . . ?
O2 C13 C14 C17 9.4(4) . . . . ?
C19 C13 C14 C17 -170.4(2) . . . . ?
O2 C13 C14 C15 -167.7(2) . . . . ?
C19 C13 C14 C15 12.6(4) . . . . ?
C17 C14 C15 C16 1.3(3) . . . . ?
C13 C14 C15 C16 178.7(2) . . . . ?
C14 C15 C16 F2 -179.2(3) . . . . ?
C14 C15 C16 N2 -0.5(3) . . . . ?
C17 N2 C16 C15 -0.5(3) . . . . ?
C17 N2 C16 F2 178.4(2) . . . . ?
C16 N2 C17 C14 1.3(3) . . . . ?
C16 N2 C17 C18 -180.0(2) . . . . ?
C15 C14 C17 N2 -1.6(3) . . . . ?
C13 C14 C17 N2 -179.2(2) . . . . ?
C15 C14 C17 C18 179.9(3) . . . . ?
C13 C14 C17 C18 2.4(4) . . . . ?
O2 C13 C19 C20 -142.1(3) . . . . ?
C14 C13 C19 C20 37.7(3) . . . . ?
O2 C13 C19 C24 35.4(3) . . . . ?
C14 C13 C19 C24 -144.8(2) . . . . ?
C24 C19 C20 C21 0.8(4) . . . . ?
C13 C19 C20 C21 178.2(3) . . . . ?
C19 C20 C21 C22 0.7(5) . . . . ?
C20 C21 C22 C23 -1.2(6) . . . . ?
C21 C22 C23 C24 0.3(6) . . . . ?
C22 C23 C24 C19 1.2(5) . . . . ?
C20 C19 C24 C23 -1.7(4) . . . . ?
C13 C19 C24 C23 -179.3(3) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2 O1 0.92(3) 1.85(3) 2.741(3) 163(2) 2_656
N1 H1 O2 1.00(3) 1.79(3) 2.767(3) 164(2) 2_766

_diffrn_measured_fraction_theta_max 0.985
_diffrn_reflns_theta_full        25.48
_diffrn_measured_fraction_theta_full 0.985
_refine_diff_density_max         0.211
_refine_diff_density_min         -0.182
_refine_diff_density_rms         0.048



_database_code_depnum_ccdc_archive 'CCDC 837294'