# Electronic Supplementary Material (ESI) for Chemical Communications
# This journal is © The Royal Society of Chemistry 2013

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_p

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C25 H36 Eu N O12'
_chemical_formula_weight         694.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/n  '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   8.9760(7)
_cell_length_b                   25.7636(19)
_cell_length_c                   11.8280(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.3230(10)
_cell_angle_gamma                90.00
_cell_volume                     2735.2(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    7946
_cell_measurement_theta_min      2.40
_cell_measurement_theta_max      27.57

_exptl_crystal_description       block
_exptl_crystal_colour            yellowish
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.687
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1408
_exptl_absorpt_coefficient_mu    2.357
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6500
_exptl_absorpt_correction_T_max  0.6763
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            13412
_diffrn_reflns_av_R_equivalents  0.0530
_diffrn_reflns_av_sigmaI/netI    0.0407
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         1.89
_diffrn_reflns_theta_max         25.00
_reflns_number_total             4808
_reflns_number_gt                4334
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'APEX2 (Bruker,2005)'
_computing_cell_refinement       'APEX2 (Bruker,2005)'
_computing_data_reduction        'SAINT (Bruker, 2005)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2008)'
_computing_publication_material  'publCIF (Westrip, 2010)'


_refine_special_details          
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0582P)^2^+3.4436P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4808
_refine_ls_number_parameters     350
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0414
_refine_ls_R_factor_gt           0.0370
_refine_ls_wR_factor_ref         0.0996
_refine_ls_wR_factor_gt          0.0966
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_restrained_S_all      1.056
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.98861(2) 0.377843(7) 0.990286(16) 0.01852(8) Uani 1 1 d . . .
C5 C 1.5091(4) 0.32678(16) 0.5448(4) 0.0223(9) Uani 1 1 d . . .
O10 O 1.0656(3) 0.45872(10) 0.9077(3) 0.0271(7) Uani 1 1 d . . .
H10A H 1.1033 0.4790 0.9589 0.041 Uiso 1 1 d R . .
H10B H 0.9899 0.4743 0.8767 0.041 Uiso 1 1 d R . .
O3 O 1.5357(4) 0.20038(11) 0.6096(3) 0.0323(7) Uani 1 1 d . . .
O2 O 1.2381(3) 0.34491(12) 0.9137(3) 0.0317(7) Uani 1 1 d . . .
C6 C 1.4781(5) 0.37741(14) 0.5805(4) 0.0191(9) Uani 1 1 d . . .
C13 C 1.5266(4) 0.42761(14) 0.3946(3) 0.0194(8) Uani 1 1 d . . .
O5 O 1.7640(4) 0.36517(12) 0.1015(3) 0.0444(10) Uani 1 1 d . . .
O6 O 1.8133(3) 0.44628(11) 0.0721(3) 0.0311(7) Uani 1 1 d . . .
O1 O 1.0629(3) 0.35972(12) 0.7898(3) 0.0319(7) Uani 1 1 d . . .
C22 C 1.7390(5) 0.41261(16) 0.1214(3) 0.0225(9) Uani 1 1 d . . .
C4 C 1.4289(5) 0.28457(15) 0.5914(4) 0.0235(9) Uani 1 1 d . . .
O4 O 1.4023(4) 0.21484(11) 0.4584(3) 0.0319(7) Uani 1 1 d . . .
O8 O 1.1487(5) 0.49203(13) 0.1991(4) 0.0533(11) Uani 1 1 d . . .
C16 C 1.4733(5) 0.43208(15) 0.1590(3) 0.0225(9) Uani 1 1 d . . .
C23 C 1.2019(5) 0.44796(16) 0.1871(4) 0.0261(10) Uani 1 1 d . . .
C17 C 1.3561(5) 0.43806(15) 0.2354(4) 0.0223(9) Uani 1 1 d . . .
C14 C 1.6453(4) 0.42435(15) 0.3190(4) 0.0199(8) Uani 1 1 d . . .
C1 C 1.1965(5) 0.34988(15) 0.8132(4) 0.0232(9) Uani 1 1 d . . .
C15 C 1.6152(4) 0.42454(15) 0.2019(3) 0.0205(9) Uani 1 1 d . . .
C18 C 1.3814(4) 0.43588(15) 0.3521(4) 0.0210(9) Uani 1 1 d . . .
C11 C 1.4572(5) 0.23033(15) 0.5499(4) 0.0235(9) Uani 1 1 d . . .
C2 C 1.3057(4) 0.34252(15) 0.7178(4) 0.0229(9) Uani 1 1 d . . .
C21 C 1.4452(5) 0.4347(2) 0.0338(4) 0.0334(11) Uani 1 1 d . . .
H21A H 1.3924 0.4042 0.0099 0.050 Uiso 1 1 calc R . .
H21B H 1.5386 0.4367 -0.0051 0.050 Uiso 1 1 calc R . .
H21C H 1.3868 0.4649 0.0167 0.050 Uiso 1 1 calc R . .
C20 C 1.8073(5) 0.42173(19) 0.3550(4) 0.0324(11) Uani 1 1 d . . .
H20A H 1.8201 0.4396 0.4256 0.049 Uiso 1 1 calc R . .
H20B H 1.8680 0.4379 0.2985 0.049 Uiso 1 1 calc R . .
H20C H 1.8364 0.3861 0.3636 0.049 Uiso 1 1 calc R . .
C7 C 1.3824(5) 0.38509(15) 0.6722(4) 0.0210(9) Uani 1 1 d . . .
C19 C 1.2510(5) 0.44411(18) 0.4312(4) 0.0309(10) Uani 1 1 d . . .
H19A H 1.2527 0.4180 0.4892 0.046 Uiso 1 1 calc R . .
H19B H 1.1594 0.4417 0.3893 0.046 Uiso 1 1 calc R . .
H19C H 1.2584 0.4778 0.4653 0.046 Uiso 1 1 calc R . .
O9 O 0.7774(4) 0.39229(17) 0.8560(3) 0.0531(10) Uani 1 1 d . . .
C3 C 1.3243(5) 0.29216(15) 0.6756(4) 0.0249(9) Uani 1 1 d . . .
C10 C 1.6317(5) 0.31512(17) 0.4628(4) 0.0369(12) Uani 1 1 d . . .
H10C H 1.6011 0.3253 0.3881 0.055 Uiso 1 1 calc R . .
H10D H 1.6526 0.2786 0.4637 0.055 Uiso 1 1 calc R . .
H10E H 1.7196 0.3340 0.4842 0.055 Uiso 1 1 calc R . .
C8 C 1.3581(6) 0.43793(15) 0.7248(4) 0.0321(11) Uani 1 1 d . . .
H8A H 1.4526 0.4531 0.7441 0.048 Uiso 1 1 calc R . .
H8B H 1.2991 0.4343 0.7918 0.048 Uiso 1 1 calc R . .
H8C H 1.3070 0.4600 0.6719 0.048 Uiso 1 1 calc R . .
C9 C 1.2384(6) 0.24759(17) 0.7236(5) 0.0500(15) Uani 1 1 d . . .
H9C H 1.1717 0.2601 0.7806 0.075 Uiso 1 1 calc R . .
H9D H 1.3063 0.2230 0.7566 0.075 Uiso 1 1 calc R . .
H9E H 1.1822 0.2311 0.6645 0.075 Uiso 1 1 calc R . .
C12 C 1.5530(5) 0.42316(16) 0.5225(3) 0.0212(9) Uani 1 1 d . . .
H12A H 1.6595 0.4208 0.5360 0.025 Uiso 1 1 calc R . .
H12B H 1.5183 0.4549 0.5578 0.025 Uiso 1 1 calc R . .
O7 O 1.1378(3) 0.41085(12) 0.1368(3) 0.0300(7) Uani 1 1 d . . .
O1W O 1.5452(6) 0.3083(2) 0.9384(6) 0.1013(19) Uani 1 1 d . . .
N1 N 1.6933(9) 0.2306(3) 0.7994(6) 0.103(2) Uani 1 1 d . . .
H1A H 1.7148 0.2591 0.8405 0.124 Uiso 1 1 calc R . .
H1B H 1.6208 0.2386 0.7495 0.124 Uiso 1 1 calc R . .
C25 C 1.6448(12) 0.1870(4) 0.8748(9) 0.114(3) Uiso 1 1 d . . .
H25A H 1.6281 0.1564 0.8302 0.172 Uiso 1 1 calc R . .
H25B H 1.5542 0.1965 0.9123 0.172 Uiso 1 1 calc R . .
H25C H 1.7210 0.1802 0.9302 0.172 Uiso 1 1 calc R . .
C24 C 1.8300(18) 0.2114(6) 0.7389(15) 0.207(7) Uiso 1 1 d . . .
H24A H 1.8005 0.1901 0.6761 0.310 Uiso 1 1 calc R . .
H24B H 1.8902 0.1914 0.7902 0.310 Uiso 1 1 calc R . .
H24C H 1.8864 0.2405 0.7120 0.310 Uiso 1 1 calc R . .
O2W O 0.8963(9) 0.4218(3) 0.6431(5) 0.137(3) Uani 1 1 d . . .
H2WA H 0.9468 0.4004 0.6824 0.164 Uiso 1 1 d R . .
H2WB H 0.8778 0.4482 0.6839 0.164 Uiso 1 1 d R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Eu1 0.02157(13) 0.01332(13) 0.02076(13) 0.00048(7) 0.00839(9) 0.00065(7)
C5 0.026(2) 0.021(2) 0.020(2) 0.0026(17) 0.0095(17) -0.0030(16)
O10 0.0318(16) 0.0142(14) 0.0354(17) 0.0035(13) 0.0046(14) 0.0010(12)
O3 0.0394(18) 0.0199(15) 0.0377(18) -0.0055(13) 0.0007(15) 0.0070(13)
O2 0.0359(17) 0.0351(18) 0.0241(17) -0.0015(13) 0.0110(14) 0.0048(14)
C6 0.022(2) 0.016(2) 0.020(2) 0.0011(15) 0.0069(17) 0.0017(15)
C13 0.026(2) 0.0102(18) 0.022(2) -0.0001(15) 0.0056(17) -0.0004(15)
O5 0.056(2) 0.0172(16) 0.060(2) 0.0057(16) 0.0389(19) 0.0074(15)
O6 0.0317(16) 0.0194(15) 0.0423(19) -0.0028(13) 0.0204(15) -0.0064(13)
O1 0.0303(17) 0.0349(17) 0.0307(17) -0.0020(14) 0.0096(14) 0.0034(14)
C22 0.024(2) 0.021(2) 0.022(2) 0.0010(17) 0.0067(17) 0.0009(17)
C4 0.030(2) 0.0135(19) 0.027(2) -0.0010(17) 0.0078(19) 0.0002(17)
O4 0.0475(19) 0.0207(15) 0.0275(17) -0.0045(13) 0.0036(15) 0.0049(14)
O8 0.052(2) 0.033(2) 0.075(3) -0.0116(18) -0.026(2) 0.0180(16)
C16 0.029(2) 0.016(2) 0.023(2) 0.0016(16) 0.0048(18) -0.0011(16)
C23 0.028(2) 0.024(2) 0.027(2) 0.0028(18) 0.0063(18) 0.0052(18)
C17 0.024(2) 0.015(2) 0.028(2) -0.0013(17) 0.0038(18) 0.0004(16)
C14 0.0192(19) 0.0131(19) 0.028(2) 0.0017(16) 0.0065(17) -0.0006(15)
C1 0.032(2) 0.0105(19) 0.028(2) -0.0039(16) 0.0120(19) -0.0022(16)
C15 0.024(2) 0.0131(19) 0.025(2) -0.0005(16) 0.0086(17) -0.0011(16)
C18 0.022(2) 0.0151(19) 0.026(2) -0.0024(16) 0.0077(17) -0.0005(15)
C11 0.026(2) 0.018(2) 0.027(2) -0.0006(17) 0.0172(19) -0.0005(17)
C2 0.025(2) 0.018(2) 0.026(2) 0.0023(17) 0.0106(18) 0.0005(16)
C21 0.034(2) 0.043(3) 0.023(2) 0.000(2) 0.003(2) -0.001(2)
C20 0.025(2) 0.043(3) 0.029(2) 0.005(2) 0.0059(19) 0.000(2)
C7 0.030(2) 0.0127(19) 0.020(2) -0.0025(15) 0.0050(18) 0.0005(16)
C19 0.025(2) 0.035(3) 0.033(3) 0.000(2) 0.009(2) 0.0063(19)
O9 0.041(2) 0.078(3) 0.040(2) -0.005(2) -0.0006(17) 0.015(2)
C3 0.034(2) 0.015(2) 0.027(2) -0.0004(17) 0.0152(19) -0.0031(17)
C10 0.045(3) 0.019(2) 0.048(3) 0.000(2) 0.030(2) 0.003(2)
C8 0.053(3) 0.013(2) 0.031(2) -0.0043(18) 0.019(2) -0.0043(19)
C9 0.062(3) 0.020(2) 0.069(4) -0.006(2) 0.046(3) -0.009(2)
C12 0.024(2) 0.020(2) 0.020(2) -0.0006(16) 0.0079(17) -0.0014(17)
O7 0.0274(16) 0.0305(17) 0.0320(17) -0.0022(14) 0.0014(14) -0.0044(13)
O1W 0.068(3) 0.111(4) 0.125(5) -0.040(4) -0.022(3) 0.026(3)
N1 0.125(6) 0.092(5) 0.092(5) -0.038(4) -0.012(4) -0.016(5)
O2W 0.191(7) 0.121(5) 0.097(5) -0.004(4) -0.069(5) 0.029(5)

_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O7 2.343(3) 1_556 ?
Eu1 O10 2.405(3) . ?
Eu1 O5 2.436(3) 1_456 ?
Eu1 O9 2.494(4) . ?
Eu1 O3 2.495(3) 4_566 ?
Eu1 O1 2.511(3) . ?
Eu1 O4 2.538(3) 4_566 ?
Eu1 O6 2.557(3) 1_456 ?
Eu1 O2 2.565(3) . ?
Eu1 C22 2.875(4) 1_456 ?
Eu1 C11 2.889(4) 4_566 ?
Eu1 C1 2.904(4) . ?
C5 C6 1.399(5) . ?
C5 C4 1.417(6) . ?
C5 C10 1.501(6) . ?
O3 C11 1.259(5) . ?
O3 Eu1 2.495(3) 4_665 ?
O2 C1 1.250(5) . ?
C6 C7 1.402(6) . ?
C6 C12 1.522(5) . ?
C13 C14 1.397(6) . ?
C13 C18 1.411(6) . ?
C13 C12 1.534(5) . ?
O5 C22 1.265(5) . ?
O5 Eu1 2.436(3) 1_654 ?
O6 C22 1.241(5) . ?
O6 Eu1 2.557(3) 1_654 ?
O1 C1 1.256(5) . ?
C22 C15 1.499(5) . ?
C22 Eu1 2.875(4) 1_654 ?
C4 C3 1.387(6) . ?
C4 C11 1.503(5) . ?
O4 C11 1.252(5) . ?
O4 Eu1 2.538(3) 4_665 ?
O8 C23 1.240(5) . ?
C16 C15 1.383(6) . ?
C16 C17 1.399(6) . ?
C16 C21 1.501(6) . ?
C23 O7 1.263(5) . ?
C23 C17 1.515(6) . ?
C17 C18 1.399(6) . ?
C14 C15 1.410(6) . ?
C14 C20 1.514(6) . ?
C1 C2 1.510(6) . ?
C18 C19 1.517(6) . ?
C11 Eu1 2.889(4) 4_665 ?
C2 C3 1.401(6) . ?
C2 C7 1.404(6) . ?
C7 C8 1.513(5) . ?
C3 C9 1.497(6) . ?
O7 Eu1 2.343(3) 1_554 ?
N1 C25 1.501(11) . ?
N1 C24 1.507(16) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Eu1 O10 79.73(11) 1_556 . ?
O7 Eu1 O5 96.94(12) 1_556 1_456 ?
O10 Eu1 O5 125.19(10) . 1_456 ?
O7 Eu1 O9 147.75(12) 1_556 . ?
O10 Eu1 O9 80.27(13) . . ?
O5 Eu1 O9 74.65(14) 1_456 . ?
O7 Eu1 O3 77.33(10) 1_556 4_566 ?
O10 Eu1 O3 151.84(10) . 4_566 ?
O5 Eu1 O3 74.01(11) 1_456 4_566 ?
O9 Eu1 O3 127.34(13) . 4_566 ?
O7 Eu1 O1 127.74(10) 1_556 . ?
O10 Eu1 O1 72.48(10) . . ?
O5 Eu1 O1 135.25(13) 1_456 . ?
O9 Eu1 O1 68.36(11) . . ?
O3 Eu1 O1 109.81(10) 4_566 . ?
O7 Eu1 O4 128.61(10) 1_556 4_566 ?
O10 Eu1 O4 147.47(10) . 4_566 ?
O5 Eu1 O4 72.61(11) 1_456 4_566 ?
O9 Eu1 O4 79.36(13) . 4_566 ?
O3 Eu1 O4 51.30(10) 4_566 4_566 ?
O1 Eu1 O4 76.53(10) . 4_566 ?
O7 Eu1 O6 79.64(11) 1_556 1_456 ?
O10 Eu1 O6 74.64(9) . 1_456 ?
O5 Eu1 O6 51.31(10) 1_456 1_456 ?
O9 Eu1 O6 70.80(12) . 1_456 ?
O3 Eu1 O6 116.46(10) 4_566 1_456 ?
O1 Eu1 O6 130.77(10) . 1_456 ?
O4 Eu1 O6 121.13(10) 4_566 1_456 ?
O7 Eu1 O2 83.37(10) 1_556 . ?
O10 Eu1 O2 83.67(10) . . ?
O5 Eu1 O2 150.87(10) 1_456 . ?
O9 Eu1 O2 119.12(11) . . ?
O3 Eu1 O2 77.70(10) 4_566 . ?
O1 Eu1 O2 50.80(10) . . ?
O4 Eu1 O2 84.43(10) 4_566 . ?
O6 Eu1 O2 154.44(10) 1_456 . ?
O7 Eu1 C22 86.09(11) 1_556 1_456 ?
O10 Eu1 C22 100.12(11) . 1_456 ?
O5 Eu1 C22 25.90(11) 1_456 1_456 ?
O9 Eu1 C22 72.86(12) . 1_456 ?
O3 Eu1 C22 94.39(11) 4_566 1_456 ?
O1 Eu1 C22 141.20(11) . 1_456 ?
O4 Eu1 C22 97.76(11) 4_566 1_456 ?
O6 Eu1 C22 25.57(10) 1_456 1_456 ?
O2 Eu1 C22 167.99(11) . 1_456 ?
O7 Eu1 C11 103.05(12) 1_556 4_566 ?
O10 Eu1 C11 164.54(10) . 4_566 ?
O5 Eu1 C11 69.93(11) 1_456 4_566 ?
O9 Eu1 C11 102.98(14) . 4_566 ?
O3 Eu1 C11 25.74(11) 4_566 4_566 ?
O1 Eu1 C11 94.46(11) . 4_566 ?
O4 Eu1 C11 25.65(11) 4_566 4_566 ?
O6 Eu1 C11 120.78(10) 1_456 4_566 ?
O2 Eu1 C11 81.58(10) . 4_566 ?
C22 Eu1 C11 95.26(11) 1_456 4_566 ?
O7 Eu1 C1 104.85(11) 1_556 . ?
O10 Eu1 C1 74.61(10) . . ?
O5 Eu1 C1 153.33(12) 1_456 . ?
O9 Eu1 C1 93.85(12) . . ?
O3 Eu1 C1 95.74(11) 4_566 . ?
O1 Eu1 C1 25.52(11) . . ?
O4 Eu1 C1 81.74(10) 4_566 . ?
O6 Eu1 C1 147.51(10) 1_456 . ?
O2 Eu1 C1 25.48(11) . . ?
C22 Eu1 C1 166.49(12) 1_456 . ?
C11 Eu1 C1 90.03(11) 4_566 . ?
C6 C5 C4 119.8(4) . . ?
C6 C5 C10 121.9(4) . . ?
C4 C5 C10 118.2(4) . . ?
C11 O3 Eu1 94.9(3) . 4_665 ?
C1 O2 Eu1 92.6(3) . . ?
C5 C6 C7 119.2(3) . . ?
C5 C6 C12 119.8(4) . . ?
C7 C6 C12 120.9(3) . . ?
C14 C13 C18 119.2(4) . . ?
C14 C13 C12 120.8(4) . . ?
C18 C13 C12 120.0(3) . . ?
C22 O5 Eu1 96.8(3) . 1_654 ?
C22 O6 Eu1 91.7(2) . 1_654 ?
C1 O1 Eu1 95.0(3) . . ?
O6 C22 O5 119.4(4) . . ?
O6 C22 C15 123.9(4) . . ?
O5 C22 C15 116.7(3) . . ?
O6 C22 Eu1 62.7(2) . 1_654 ?
O5 C22 Eu1 57.3(2) . 1_654 ?
C15 C22 Eu1 171.5(3) . 1_654 ?
C3 C4 C5 121.2(4) . . ?
C3 C4 C11 118.8(4) . . ?
C5 C4 C11 120.0(4) . . ?
C11 O4 Eu1 93.0(2) . 4_665 ?
C15 C16 C17 118.2(4) . . ?
C15 C16 C21 121.2(4) . . ?
C17 C16 C21 120.6(4) . . ?
O8 C23 O7 124.9(4) . . ?
O8 C23 C17 117.5(4) . . ?
O7 C23 C17 117.6(4) . . ?
C16 C17 C18 121.0(4) . . ?
C16 C17 C23 117.6(4) . . ?
C18 C17 C23 121.4(4) . . ?
C13 C14 C15 119.1(4) . . ?
C13 C14 C20 123.9(4) . . ?
C15 C14 C20 117.0(4) . . ?
O2 C1 O1 120.7(4) . . ?
O2 C1 C2 120.4(4) . . ?
O1 C1 C2 118.9(4) . . ?
O2 C1 Eu1 61.9(2) . . ?
O1 C1 Eu1 59.5(2) . . ?
C2 C1 Eu1 172.8(3) . . ?
C16 C15 C14 122.2(4) . . ?
C16 C15 C22 118.7(4) . . ?
C14 C15 C22 119.0(4) . . ?
C17 C18 C13 120.1(4) . . ?
C17 C18 C19 118.8(4) . . ?
C13 C18 C19 121.1(4) . . ?
O4 C11 O3 120.4(4) . . ?
O4 C11 C4 120.8(4) . . ?
O3 C11 C4 118.8(4) . . ?
O4 C11 Eu1 61.3(2) . 4_665 ?
O3 C11 Eu1 59.4(2) . 4_665 ?
C4 C11 Eu1 173.4(3) . 4_665 ?
C3 C2 C7 121.8(4) . . ?
C3 C2 C1 117.5(3) . . ?
C7 C2 C1 120.7(4) . . ?
C6 C7 C2 119.4(3) . . ?
C6 C7 C8 122.4(4) . . ?
C2 C7 C8 118.2(4) . . ?
C4 C3 C2 118.0(4) . . ?
C4 C3 C9 121.1(4) . . ?
C2 C3 C9 120.9(4) . . ?
C6 C12 C13 115.9(3) . . ?
C23 O7 Eu1 151.7(3) . 1_554 ?
C25 N1 C24 106.0(9) . . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         1.773
_refine_diff_density_min         -0.984
_refine_diff_density_rms         0.136
_database_code_depnum_ccdc_archive 'CCDC 942215'