# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2014

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#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
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#  except for the purpose of generating routine backup copies
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data_130314gm

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C48 H50 Ag2 Cu2 F6 N12 O5 Sb'
_chemical_formula_weight         1453.57

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   P2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   18.981(6)
_cell_length_b                   12.104(4)
_cell_length_c                   38.971(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 95.486(5)
_cell_angle_gamma                90.00
_cell_volume                     8912(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    3798
_cell_measurement_theta_min      2.305
_cell_measurement_theta_max      19.276

_exptl_crystal_description       block
_exptl_crystal_colour            brown
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.083
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2876
_exptl_absorpt_coefficient_mu    1.247
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7294
_exptl_absorpt_correction_T_max  0.8854
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            41820
_diffrn_reflns_av_R_equivalents  0.1027
_diffrn_reflns_av_sigmaI/netI    0.2082
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -45
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_theta_min         1.08
_diffrn_reflns_theta_max         24.50
_reflns_number_total             14745
_reflns_number_gt                4399
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0705P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         14745
_refine_ls_number_parameters     664
_refine_ls_number_restraints     28
_refine_ls_R_factor_all          0.1508
_refine_ls_R_factor_gt           0.0572
_refine_ls_wR_factor_ref         0.1463
_refine_ls_wR_factor_gt          0.1310
_refine_ls_goodness_of_fit_ref   0.657
_refine_ls_restrained_S_all      0.661
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.46354(3) 0.62240(7) 0.812109(15) 0.0864(3) Uani 1 1 d . . .
Ag2 Ag 0.62842(3) 0.63294(7) 0.773103(15) 0.0876(3) Uani 1 1 d . . .
C1 C 0.4332(5) 0.7919(8) 1.08496(19) 0.114(4) Uani 1 1 d . . .
H1A H 0.3944 0.8201 1.0964 0.171 Uiso 1 1 calc R . .
H1B H 0.4705 0.8457 1.0861 0.171 Uiso 1 1 calc R . .
H1C H 0.4504 0.7251 1.0961 0.171 Uiso 1 1 calc R . .
C2 C 0.4084(5) 0.7679(9) 1.0476(2) 0.071(3) Uani 1 1 d . . .
C3 C 0.4178(5) 0.8409(8) 1.0238(3) 0.099(3) Uani 1 1 d . . .
H3 H 0.4373 0.9076 1.0319 0.119 Uiso 1 1 calc R . .
C4 C 0.4027(5) 0.8336(9) 0.9871(2) 0.083(3) Uani 1 1 d . . .
C5 C 0.4159(7) 0.9408(8) 0.9682(2) 0.177(6) Uani 1 1 d . . .
H5A H 0.4545 0.9306 0.9543 0.265 Uiso 1 1 calc R . .
H5B H 0.4275 0.9985 0.9847 0.265 Uiso 1 1 calc R . .
H5C H 0.3741 0.9609 0.9537 0.265 Uiso 1 1 calc R . .
C6 C 0.3614(4) 0.7426(7) 0.9356(2) 0.064(2) Uani 1 1 d . . .
C7 C 0.4129(4) 0.7655(6) 0.91141(19) 0.062(2) Uani 1 1 d . . .
H7 H 0.4587 0.7856 0.9197 0.074 Uiso 1 1 calc R . .
C8 C 0.3961(4) 0.7584(6) 0.87765(16) 0.057(2) Uani 1 1 d . . .
H8 H 0.4308 0.7732 0.8629 0.068 Uiso 1 1 calc R . .
C9 C 0.3297(4) 0.7302(6) 0.86370(16) 0.054(2) Uani 1 1 d . . .
C10 C 0.2793(4) 0.7002(6) 0.88607(19) 0.064(2) Uani 1 1 d . . .
H10 H 0.2346 0.6760 0.8774 0.077 Uiso 1 1 calc R . .
C11 C 0.2976(4) 0.7076(7) 0.92175(19) 0.073(3) Uani 1 1 d . . .
H11 H 0.2641 0.6873 0.9365 0.088 Uiso 1 1 calc R . .
C12 C 0.3130(4) 0.7223(7) 0.82653(19) 0.062(2) Uani 1 1 d . . .
C13 C 0.1832(4) 0.4134(9) 1.0257(2) 0.139(4) Uani 1 1 d D . .
H13A H 0.1456 0.4612 1.0167 0.208 Uiso 1 1 calc R . .
H13B H 0.1900 0.4209 1.0504 0.208 Uiso 1 1 calc R . .
H13C H 0.1713 0.3382 1.0199 0.208 Uiso 1 1 calc R . .
C14 C 0.2535(4) 0.4460(12) 1.0098(2) 0.095(4) Uani 1 1 d D . .
C15 C 0.2910(5) 0.3652(9) 0.9948(2) 0.106(4) Uani 1 1 d . . .
H15 H 0.2783 0.2915 0.9969 0.127 Uiso 1 1 calc R . .
C16 C 0.3487(5) 0.3934(9) 0.9762(2) 0.068(2) Uani 1 1 d . . .
C17 C 0.3803(5) 0.2885(9) 0.9641(3) 0.125(4) Uani 1 1 d . . .
H17A H 0.4309 0.2955 0.9656 0.188 Uiso 1 1 calc R . .
H17B H 0.3624 0.2746 0.9406 0.188 Uiso 1 1 calc R . .
H17C H 0.3678 0.2282 0.9783 0.188 Uiso 1 1 calc R . .
C18 C 0.4223(4) 0.5005(6) 0.9455(2) 0.058(2) Uani 1 1 d . . .
C19 C 0.4882(4) 0.5506(6) 0.95587(16) 0.058(2) Uani 1 1 d . . .
H19 H 0.4981 0.5742 0.9785 0.069 Uiso 1 1 calc R . .
C20 C 0.5392(4) 0.5652(6) 0.93204(18) 0.059(2) Uani 1 1 d . . .
H20 H 0.5822 0.5997 0.9387 0.070 Uiso 1 1 calc R . .
C21 C 0.5239(4) 0.5271(6) 0.89875(18) 0.047(2) Uani 1 1 d . . .
C22 C 0.4571(4) 0.4819(6) 0.88780(18) 0.062(2) Uani 1 1 d . . .
H22 H 0.4464 0.4621 0.8648 0.074 Uiso 1 1 calc R . .
C23 C 0.4074(3) 0.4669(6) 0.91115(19) 0.059(2) Uani 1 1 d . . .
H23 H 0.3640 0.4345 0.9040 0.071 Uiso 1 1 calc R . .
C24 C 0.5767(3) 0.5404(6) 0.8732(2) 0.055(2) Uani 1 1 d . . .
C25 C 0.6764(4) 0.5464(7) 0.85040(19) 0.059(2) Uani 1 1 d . . .
C26 C 0.7539(4) 0.5433(7) 0.8448(2) 0.063(2) Uani 1 1 d . . .
C27 C 0.7747(4) 0.5133(7) 0.8140(2) 0.079(3) Uani 1 1 d . . .
H27 H 0.7407 0.4963 0.7960 0.095 Uiso 1 1 calc R . .
C28 C 0.8469(4) 0.5069(7) 0.8085(2) 0.073(3) Uani 1 1 d . . .
H28 H 0.8616 0.4834 0.7877 0.087 Uiso 1 1 calc R . .
C29 C 0.8955(4) 0.5383(7) 0.8364(3) 0.068(3) Uani 1 1 d . . .
C30 C 0.8748(4) 0.5776(8) 0.8665(2) 0.091(3) Uani 1 1 d . . .
H30 H 0.9080 0.6027 0.8838 0.109 Uiso 1 1 calc R . .
C31 C 0.8018(4) 0.5798(8) 0.8711(2) 0.085(3) Uani 1 1 d . . .
H31 H 0.7864 0.6055 0.8916 0.102 Uiso 1 1 calc R . .
C32 C 0.9576(5) 0.3310(8) 0.8211(4) 0.238(9) Uani 1 1 d D . .
H32A H 0.9874 0.2729 0.8310 0.357 Uiso 1 1 calc R . .
H32B H 0.9448 0.3153 0.7972 0.357 Uiso 1 1 calc R . .
H32C H 0.9157 0.3358 0.8329 0.357 Uiso 1 1 calc R . .
C33 C 0.9986(5) 0.4432(10) 0.8246(3) 0.128(4) Uani 1 1 d D . .
C34 C 1.0686(7) 0.4343(10) 0.8168(3) 0.137(4) Uani 1 1 d U . .
H34 H 1.0821 0.3650 0.8094 0.164 Uiso 1 1 calc R . .
C35 C 1.1223(5) 0.5168(9) 0.8186(3) 0.096(3) Uani 1 1 d . . .
C36 C 1.1940(4) 0.4759(8) 0.8081(3) 0.118(4) Uani 1 1 d . . .
H36A H 1.2051 0.5142 0.7877 0.176 Uiso 1 1 calc R . .
H36B H 1.1914 0.3980 0.8035 0.176 Uiso 1 1 calc R . .
H36C H 1.2303 0.4900 0.8264 0.176 Uiso 1 1 calc R . .
C37 C 1.1322(6) 0.8776(10) 0.9178(3) 0.188(6) Uani 1 1 d D . .
H37A H 1.1207 0.9459 0.9284 0.282 Uiso 1 1 calc R . .
H37B H 1.1768 0.8849 0.9083 0.282 Uiso 1 1 calc R . .
H37C H 1.1353 0.8197 0.9347 0.282 Uiso 1 1 calc R . .
C38 C 1.0740(6) 0.8490(13) 0.8887(3) 0.133(5) Uani 1 1 d D . .
C39 C 1.0149(6) 0.9051(10) 0.8825(3) 0.142(5) Uani 1 1 d . . .
H39 H 1.0072 0.9648 0.8967 0.171 Uiso 1 1 calc R . .
C40 C 0.9610(5) 0.8797(11) 0.8548(3) 0.116(4) Uani 1 1 d D . .
C41 C 0.9095(6) 0.9795(9) 0.8481(3) 0.178(6) Uani 1 1 d D . .
H41A H 0.9042 0.9963 0.8240 0.268 Uiso 1 1 calc R . .
H41B H 0.9285 1.0427 0.8607 0.268 Uiso 1 1 calc R . .
H41C H 0.8642 0.9611 0.8556 0.268 Uiso 1 1 calc R . .
C42 C 0.9011(4) 0.7788(6) 0.8096(2) 0.059(2) Uani 1 1 d . . .
C43 C 0.9192(4) 0.7528(7) 0.77700(18) 0.069(2) Uani 1 1 d . . .
H43 H 0.9667 0.7438 0.7736 0.082 Uiso 1 1 calc R . .
C44 C 0.8686(3) 0.7400(7) 0.74943(18) 0.065(2) Uani 1 1 d . . .
H44 H 0.8819 0.7212 0.7278 0.078 Uiso 1 1 calc R . .
C45 C 0.7963(4) 0.7558(7) 0.75430(19) 0.060(2) Uani 1 1 d . . .
C46 C 0.7781(4) 0.7851(6) 0.78703(18) 0.060(2) Uani 1 1 d . . .
H46 H 0.7309 0.7973 0.7905 0.072 Uiso 1 1 calc R . .
C47 C 0.8296(4) 0.7958(6) 0.81407(18) 0.067(2) Uani 1 1 d . . .
H47 H 0.8168 0.8147 0.8357 0.080 Uiso 1 1 calc R . .
C48 C 0.7426(4) 0.7382(7) 0.72579(18) 0.053(2) Uani 1 1 d . . .
Cu1 Cu 1.02608(5) 0.67118(9) 0.84218(2) 0.0715(3) Uani 1 1 d . . .
Cu2 Cu 0.34797(5) 0.61559(9) 0.99662(2) 0.0689(3) Uani 1 1 d . . .
F1 F 0.6909(4) 0.8244(6) 0.86029(19) 0.256(4) Uiso 1 1 d D . .
F2 F 0.5765(4) 0.7941(9) 0.8855(3) 0.336(6) Uiso 1 1 d D . .
F3 F 0.6263(8) 0.9914(9) 0.8790(3) 0.430(8) Uiso 1 1 d D . .
F4 F 0.6241(5) 0.9037(8) 0.9401(2) 0.385(7) Uiso 1 1 d D . .
F5 F 0.7464(5) 0.9182(14) 0.9137(3) 0.482(10) Uiso 1 1 d D . .
F6 F 0.6875(4) 0.7321(5) 0.91800(16) 0.189(3) Uiso 1 1 d D . .
N1 N 0.3762(3) 0.7449(6) 0.97143(15) 0.0556(18) Uani 1 1 d . . .
N2 N 0.5609(3) 0.5701(5) 0.84077(15) 0.0558(17) Uani 1 1 d . . .
N3 N 0.6261(3) 0.5767(5) 0.82575(14) 0.0623(19) Uani 1 1 d . . .
N4 N 0.6478(3) 0.5248(5) 0.87950(15) 0.0550(17) Uani 1 1 d . . .
N5 N 0.6830(3) 0.4881(6) 0.90994(17) 0.089(2) Uani 1 1 d . . .
H5D H 0.7291 0.4843 0.9076 0.133 Uiso 1 1 d R . .
H5E H 0.6668 0.4211 0.9144 0.133 Uiso 1 1 d R . .
N6 N 0.9712(3) 0.5401(7) 0.83195(19) 0.085(2) Uani 1 1 d . . .
N7 N 0.9572(3) 0.7886(6) 0.83758(17) 0.074(2) Uani 1 1 d . . .
N8 N 0.6814(3) 0.6904(5) 0.72832(13) 0.0622(18) Uani 1 1 d . . .
N9 N 0.3554(3) 0.6831(6) 0.80434(15) 0.074(2) Uani 1 1 d . . .
N10 N 0.2525(3) 0.7575(5) 0.80831(15) 0.0572(17) Uani 1 1 d . . .
N11 N 0.1963(3) 0.8172(5) 0.82160(14) 0.078(2) Uani 1 1 d . . .
H11B H 0.1744 0.8574 0.8047 0.117 Uiso 1 1 d R . .
H11C H 0.2144 0.8616 0.8384 0.117 Uiso 1 1 d R . .
N12 N 0.3719(3) 0.4931(6) 0.96984(16) 0.0609(19) Uani 1 1 d . . .
O25 O 1.0889(3) 0.7482(7) 0.87429(16) 0.120(3) Uani 1 1 d . . .
O26 O 1.1107(3) 0.6120(6) 0.82704(15) 0.0791(18) Uani 1 1 d . . .
O27 O 0.2658(3) 0.5497(6) 1.01233(15) 0.096(2) Uani 1 1 d . . .
O28 O 0.3766(3) 0.6754(6) 1.04261(12) 0.0779(18) Uani 1 1 d . . .
O1A O 0.5000 0.7021(18) 0.7500 0.258(9) Uani 1 2 d S A 1
H1AB H 0.5094 0.7451 0.7338 0.310 Uiso 1 1 d R A 1
O1B O 0.5000 0.5476(12) 0.7500 0.153(5) Uani 1 2 d S B 2
H1BB H 0.4657 0.5047 0.7438 0.184 Uiso 1 1 d R B 2
Sb1 Sb 0.66061(6) 0.86784(8) 0.90099(4) 0.1971(6) Uani 1 1 d D . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.161(6) . ?
Ag1 N9 2.174(6) . ?
Ag2 N3 2.166(6) . ?
Ag2 N8 2.207(5) . ?
C1 C2 1.515(11) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 O28 1.278(9) . ?
C2 C3 1.305(11) . ?
C3 C4 1.436(11) . ?
C3 H3 0.9300 . ?
C4 N1 1.311(9) . ?
C4 C5 1.525(11) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C11 1.346(9) . ?
C6 N1 1.396(8) . ?
C6 C7 1.450(9) . ?
C7 C8 1.326(8) . ?
C7 H7 0.9300 . ?
C8 C9 1.367(8) . ?
C8 H8 0.9300 . ?
C9 C10 1.403(8) . ?
C9 C12 1.456(9) . ?
C10 C11 1.404(9) . ?
C10 H10 0.9300 . ?
C11 H11 0.9300 . ?
C12 N9 1.325(8) . ?
C12 N10 1.359(8) . ?
C13 C14 1.575(7) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 O27 1.279(12) . ?
C14 C15 1.372(13) . ?
C15 C16 1.412(11) . ?
C15 H15 0.9300 . ?
C16 N12 1.316(9) . ?
C16 C17 1.501(11) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 C23 1.403(9) . ?
C18 N12 1.412(8) . ?
C18 C19 1.414(9) . ?
C19 C20 1.416(8) . ?
C19 H19 0.9300 . ?
C20 C21 1.381(9) . ?
C20 H20 0.9300 . ?
C21 C22 1.409(9) . ?
C21 C24 1.487(8) . ?
C22 C23 1.385(8) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 N2 1.322(8) . ?
C24 N4 1.361(8) . ?
C25 N4 1.329(8) . ?
C25 N3 1.338(8) . ?
C25 C26 1.509(9) . ?
C26 C27 1.347(9) . ?
C26 C31 1.377(10) . ?
C27 C28 1.408(9) . ?
C27 H27 0.9300 . ?
C28 C29 1.410(10) . ?
C28 H28 0.9300 . ?
C29 C30 1.357(10) . ?
C29 N6 1.465(9) . ?
C30 C31 1.413(10) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C32 C33 1.564(8) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 N6 1.325(11) . ?
C33 C34 1.396(13) . ?
C34 C35 1.423(13) . ?
C34 H34 0.9300 . ?
C35 O26 1.224(9) . ?
C35 C36 1.540(11) . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C37 C38 1.543(8) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 C39 1.315(13) . ?
C38 O25 1.384(13) . ?
C39 C40 1.446(12) . ?
C39 H39 0.9300 . ?
C40 N7 1.289(11) . ?
C40 C41 1.560(8) . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 C43 1.382(9) . ?
C42 C47 1.401(9) . ?
C42 N7 1.454(9) . ?
C43 C44 1.379(9) . ?
C43 H43 0.9300 . ?
C44 C45 1.417(8) . ?
C44 H44 0.9300 . ?
C45 C46 1.398(9) . ?
C45 C48 1.450(9) . ?
C46 C47 1.373(9) . ?
C46 H46 0.9300 . ?
C47 H47 0.9300 . ?
C48 N8 1.311(8) . ?
C48 N10 1.361(8) 2_656 ?
Cu1 O25 1.890(7) . ?
Cu1 O26 1.903(5) . ?
Cu1 N6 1.918(8) . ?
Cu1 N7 1.928(7) . ?
Cu2 N12 1.894(6) . ?
Cu2 O27 1.905(6) . ?
Cu2 N1 1.949(7) . ?
Cu2 O28 1.961(6) . ?
F1 Sb1 1.816(7) . ?
F2 Sb1 1.877(7) . ?
F3 Sb1 1.812(8) . ?
F4 Sb1 1.788(8) . ?
F5 Sb1 1.765(8) . ?
F6 Sb1 1.826(6) . ?
N2 N3 1.421(6) . ?
N4 N5 1.378(7) . ?
N5 H5D 0.8900 . ?
N5 H5E 0.8901 . ?
N8 N9 1.394(7) 2_656 ?
N9 N8 1.394(7) 2_656 ?
N10 C48 1.361(8) 2_656 ?
N10 N11 1.426(7) . ?
N11 H11B 0.8902 . ?
N11 H11C 0.8900 . ?
O1A H1AB 0.8500 . ?
O1B H1BB 0.8499 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N9 157.0(2) . . ?
N3 Ag2 N8 154.1(2) . . ?
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
O28 C2 C3 125.4(10) . . ?
O28 C2 C1 114.4(9) . . ?
C3 C2 C1 120.1(10) . . ?
C2 C3 C4 129.7(9) . . ?
C2 C3 H3 115.1 . . ?
C4 C3 H3 115.1 . . ?
N1 C4 C3 123.0(8) . . ?
N1 C4 C5 123.2(8) . . ?
C3 C4 C5 113.7(9) . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C11 C6 N1 119.7(7) . . ?
C11 C6 C7 115.8(7) . . ?
N1 C6 C7 124.2(7) . . ?
C8 C7 C6 121.4(7) . . ?
C8 C7 H7 119.3 . . ?
C6 C7 H7 119.3 . . ?
C7 C8 C9 122.3(7) . . ?
C7 C8 H8 118.8 . . ?
C9 C8 H8 118.8 . . ?
C8 C9 C10 118.4(6) . . ?
C8 C9 C12 121.1(6) . . ?
C10 C9 C12 120.3(7) . . ?
C9 C10 C11 118.7(7) . . ?
C9 C10 H10 120.7 . . ?
C11 C10 H10 120.7 . . ?
C6 C11 C10 123.2(7) . . ?
C6 C11 H11 118.4 . . ?
C10 C11 H11 118.4 . . ?
N9 C12 N10 107.9(6) . . ?
N9 C12 C9 125.8(7) . . ?
N10 C12 C9 126.3(7) . . ?
C14 C13 H13A 109.5 . . ?
C14 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C14 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
O27 C14 C15 129.4(8) . . ?
O27 C14 C13 111.7(11) . . ?
C15 C14 C13 118.8(11) . . ?
C14 C15 C16 120.3(10) . . ?
C14 C15 H15 119.8 . . ?
C16 C15 H15 119.8 . . ?
N12 C16 C15 127.5(9) . . ?
N12 C16 C17 124.4(8) . . ?
C15 C16 C17 108.0(9) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C23 C18 N12 122.3(7) . . ?
C23 C18 C19 119.3(6) . . ?
N12 C18 C19 118.3(7) . . ?
C18 C19 C20 120.6(6) . . ?
C18 C19 H19 119.7 . . ?
C20 C19 H19 119.7 . . ?
C21 C20 C19 118.6(7) . . ?
C21 C20 H20 120.7 . . ?
C19 C20 H20 120.7 . . ?
C20 C21 C22 121.1(6) . . ?
C20 C21 C24 119.8(7) . . ?
C22 C21 C24 118.9(6) . . ?
C23 C22 C21 120.2(7) . . ?
C23 C22 H22 119.9 . . ?
C21 C22 H22 119.9 . . ?
C22 C23 C18 120.1(7) . . ?
C22 C23 H23 120.0 . . ?
C18 C23 H23 120.0 . . ?
N2 C24 N4 109.9(6) . . ?
N2 C24 C21 124.3(6) . . ?
N4 C24 C21 125.8(7) . . ?
N4 C25 N3 110.2(6) . . ?
N4 C25 C26 127.0(7) . . ?
N3 C25 C26 122.8(6) . . ?
C27 C26 C31 121.4(7) . . ?
C27 C26 C25 120.6(7) . . ?
C31 C26 C25 117.9(7) . . ?
C26 C27 C28 121.5(8) . . ?
C26 C27 H27 119.2 . . ?
C28 C27 H27 119.2 . . ?
C27 C28 C29 116.2(7) . . ?
C27 C28 H28 121.9 . . ?
C29 C28 H28 121.9 . . ?
C30 C29 C28 122.5(7) . . ?
C30 C29 N6 117.8(8) . . ?
C28 C29 N6 119.3(8) . . ?
C29 C30 C31 119.0(8) . . ?
C29 C30 H30 120.5 . . ?
C31 C30 H30 120.5 . . ?
C26 C31 C30 119.0(8) . . ?
C26 C31 H31 120.5 . . ?
C30 C31 H31 120.5 . . ?
C33 C32 H32A 109.5 . . ?
C33 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C33 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N6 C33 C34 121.1(9) . . ?
N6 C33 C32 125.9(8) . . ?
C34 C33 C32 112.9(10) . . ?
C33 C34 C35 128.8(11) . . ?
C33 C34 H34 115.6 . . ?
C35 C34 H34 115.6 . . ?
O26 C35 C34 121.8(9) . . ?
O26 C35 C36 124.1(9) . . ?
C34 C35 C36 114.0(10) . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C38 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C39 C38 O25 125.7(9) . . ?
C39 C38 C37 124.0(12) . . ?
O25 C38 C37 109.6(11) . . ?
C38 C39 C40 124.0(10) . . ?
C38 C39 H39 118.0 . . ?
C40 C39 H39 118.0 . . ?
N7 C40 C39 124.8(10) . . ?
N7 C40 C41 125.0(8) . . ?
C39 C40 C41 110.3(10) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C43 C42 C47 118.5(7) . . ?
C43 C42 N7 118.7(7) . . ?
C47 C42 N7 122.8(7) . . ?
C44 C43 C42 121.7(7) . . ?
C44 C43 H43 119.1 . . ?
C42 C43 H43 119.1 . . ?
C43 C44 C45 119.5(7) . . ?
C43 C44 H44 120.3 . . ?
C45 C44 H44 120.3 . . ?
C46 C45 C44 118.9(7) . . ?
C46 C45 C48 121.3(6) . . ?
C44 C45 C48 119.8(7) . . ?
C47 C46 C45 120.3(7) . . ?
C47 C46 H46 119.9 . . ?
C45 C46 H46 119.9 . . ?
C46 C47 C42 121.1(7) . . ?
C46 C47 H47 119.4 . . ?
C42 C47 H47 119.4 . . ?
N8 C48 N10 107.1(6) . 2_656 ?
N8 C48 C45 124.8(6) . . ?
N10 C48 C45 127.9(6) 2_656 . ?
O25 Cu1 O26 83.8(3) . . ?
O25 Cu1 N6 147.2(3) . . ?
O26 Cu1 N6 94.7(3) . . ?
O25 Cu1 N7 94.5(3) . . ?
O26 Cu1 N7 146.5(3) . . ?
N6 Cu1 N7 103.9(3) . . ?
N12 Cu2 O27 95.5(3) . . ?
N12 Cu2 N1 105.0(3) . . ?
O27 Cu2 N1 140.5(3) . . ?
N12 Cu2 O28 137.1(3) . . ?
O27 Cu2 O28 91.4(3) . . ?
N1 Cu2 O28 95.7(3) . . ?
C4 N1 C6 120.8(7) . . ?
C4 N1 Cu2 122.4(5) . . ?
C6 N1 Cu2 116.6(6) . . ?
C24 N2 N3 106.4(6) . . ?
C24 N2 Ag1 132.8(4) . . ?
N3 N2 Ag1 120.4(4) . . ?
C25 N3 N2 106.2(5) . . ?
C25 N3 Ag2 133.5(5) . . ?
N2 N3 Ag2 120.3(4) . . ?
C25 N4 C24 107.3(6) . . ?
C25 N4 N5 126.5(6) . . ?
C24 N4 N5 126.1(6) . . ?
N4 N5 H5D 109.1 . . ?
N4 N5 H5E 108.4 . . ?
H5D N5 H5E 109.5 . . ?
C33 N6 C29 114.9(8) . . ?
C33 N6 Cu1 124.2(6) . . ?
C29 N6 Cu1 120.4(6) . . ?
C40 N7 C42 117.5(7) . . ?
C40 N7 Cu1 125.3(6) . . ?
C42 N7 Cu1 116.8(5) . . ?
C48 N8 N9 109.2(5) . 2_656 ?
C48 N8 Ag2 132.3(5) . . ?
N9 N8 Ag2 118.4(4) 2_656 . ?
C12 N9 N8 106.9(6) . 2_656 ?
C12 N9 Ag1 130.9(5) . . ?
N8 N9 Ag1 122.1(4) 2_656 . ?
C12 N10 C48 108.8(6) . 2_656 ?
C12 N10 N11 126.3(6) . . ?
C48 N10 N11 124.4(6) 2_656 . ?
N10 N11 H11B 108.7 . . ?
N10 N11 H11C 108.8 . . ?
H11B N11 H11C 109.5 . . ?
C16 N12 C18 116.5(7) . . ?
C16 N12 Cu2 120.7(5) . . ?
C18 N12 Cu2 122.2(5) . . ?
C38 O25 Cu1 124.3(6) . . ?
C35 O26 Cu1 128.0(6) . . ?
C14 O27 Cu2 122.3(6) . . ?
C2 O28 Cu2 123.2(6) . . ?
F5 Sb1 F4 95.7(4) . . ?
F5 Sb1 F3 97.3(8) . . ?
F4 Sb1 F3 92.9(3) . . ?
F5 Sb1 F1 89.2(3) . . ?
F4 Sb1 F1 175.0(4) . . ?
F3 Sb1 F1 87.5(3) . . ?
F5 Sb1 F6 89.5(7) . . ?
F4 Sb1 F6 91.5(3) . . ?
F3 Sb1 F6 171.5(5) . . ?
F1 Sb1 F6 87.5(3) . . ?
F5 Sb1 F2 171.1(6) . . ?
F4 Sb1 F2 90.1(3) . . ?
F3 Sb1 F2 89.1(7) . . ?
F1 Sb1 F2 84.9(3) . . ?
F6 Sb1 F2 83.6(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O28 C2 C3 C4 -6.9(17) . . . . ?
C1 C2 C3 C4 175.9(9) . . . . ?
C2 C3 C4 N1 -1.1(17) . . . . ?
C2 C3 C4 C5 175.3(11) . . . . ?
C11 C6 C7 C8 3.9(12) . . . . ?
N1 C6 C7 C8 177.7(8) . . . . ?
C6 C7 C8 C9 0.5(13) . . . . ?
C7 C8 C9 C10 -4.6(12) . . . . ?
C7 C8 C9 C12 -179.6(8) . . . . ?
C8 C9 C10 C11 4.2(11) . . . . ?
C12 C9 C10 C11 179.2(7) . . . . ?
N1 C6 C11 C10 -178.3(7) . . . . ?
C7 C6 C11 C10 -4.2(13) . . . . ?
C9 C10 C11 C6 0.3(13) . . . . ?
C8 C9 C12 N9 38.0(13) . . . . ?
C10 C9 C12 N9 -136.9(8) . . . . ?
C8 C9 C12 N10 -139.4(8) . . . . ?
C10 C9 C12 N10 45.7(12) . . . . ?
O27 C14 C15 C16 -6.4(17) . . . . ?
C13 C14 C15 C16 171.4(8) . . . . ?
C14 C15 C16 N12 -2.5(15) . . . . ?
C14 C15 C16 C17 178.1(9) . . . . ?
C23 C18 C19 C20 -1.1(11) . . . . ?
N12 C18 C19 C20 -176.8(7) . . . . ?
C18 C19 C20 C21 -1.5(11) . . . . ?
C19 C20 C21 C22 4.6(11) . . . . ?
C19 C20 C21 C24 -179.5(6) . . . . ?
C20 C21 C22 C23 -5.2(11) . . . . ?
C24 C21 C22 C23 178.9(7) . . . . ?
C21 C22 C23 C18 2.4(12) . . . . ?
N12 C18 C23 C22 176.2(7) . . . . ?
C19 C18 C23 C22 0.6(12) . . . . ?
C20 C21 C24 N2 -138.3(8) . . . . ?
C22 C21 C24 N2 37.6(11) . . . . ?
C20 C21 C24 N4 41.2(11) . . . . ?
C22 C21 C24 N4 -142.9(8) . . . . ?
N4 C25 C26 C27 147.2(9) . . . . ?
N3 C25 C26 C27 -35.4(12) . . . . ?
N4 C25 C26 C31 -37.5(13) . . . . ?
N3 C25 C26 C31 139.9(9) . . . . ?
C31 C26 C27 C28 6.6(14) . . . . ?
C25 C26 C27 C28 -178.2(8) . . . . ?
C26 C27 C28 C29 -2.7(13) . . . . ?
C27 C28 C29 C30 -3.1(13) . . . . ?
C27 C28 C29 N6 -176.4(7) . . . . ?
C28 C29 C30 C31 4.7(14) . . . . ?
N6 C29 C30 C31 178.2(8) . . . . ?
C27 C26 C31 C30 -4.8(14) . . . . ?
C25 C26 C31 C30 179.9(7) . . . . ?
C29 C30 C31 C26 -0.8(13) . . . . ?
N6 C33 C34 C35 7(2) . . . . ?
C32 C33 C34 C35 -176.9(12) . . . . ?
C33 C34 C35 O26 -2(2) . . . . ?
C33 C34 C35 C36 179.6(12) . . . . ?
O25 C38 C39 C40 -11(2) . . . . ?
C37 C38 C39 C40 178.7(12) . . . . ?
C38 C39 C40 N7 14(2) . . . . ?
C38 C39 C40 C41 -163.9(13) . . . . ?
C47 C42 C43 C44 -2.1(13) . . . . ?
N7 C42 C43 C44 178.6(8) . . . . ?
C42 C43 C44 C45 1.2(13) . . . . ?
C43 C44 C45 C46 0.6(12) . . . . ?
C43 C44 C45 C48 -177.5(8) . . . . ?
C44 C45 C46 C47 -1.4(12) . . . . ?
C48 C45 C46 C47 176.6(8) . . . . ?
C45 C46 C47 C42 0.5(12) . . . . ?
C43 C42 C47 C46 1.2(12) . . . . ?
N7 C42 C47 C46 -179.6(8) . . . . ?
C46 C45 C48 N8 -38.2(12) . . . . ?
C44 C45 C48 N8 139.9(8) . . . . ?
C46 C45 C48 N10 148.3(8) . . . 2_656 ?
C44 C45 C48 N10 -33.6(13) . . . 2_656 ?
C3 C4 N1 C6 179.0(8) . . . . ?
C5 C4 N1 C6 2.9(13) . . . . ?
C3 C4 N1 Cu2 4.5(12) . . . . ?
C5 C4 N1 Cu2 -171.6(8) . . . . ?
C11 C6 N1 C4 -130.1(9) . . . . ?
C7 C6 N1 C4 56.3(11) . . . . ?
C11 C6 N1 Cu2 44.7(9) . . . . ?
C7 C6 N1 Cu2 -128.9(7) . . . . ?
N12 Cu2 N1 C4 -143.7(7) . . . . ?
O27 Cu2 N1 C4 97.5(7) . . . . ?
O28 Cu2 N1 C4 -1.6(7) . . . . ?
N12 Cu2 N1 C6 41.6(5) . . . . ?
O27 Cu2 N1 C6 -77.2(6) . . . . ?
O28 Cu2 N1 C6 -176.3(5) . . . . ?
N4 C24 N2 N3 -1.6(8) . . . . ?
C21 C24 N2 N3 178.0(7) . . . . ?
N4 C24 N2 Ag1 -174.1(5) . . . . ?
C21 C24 N2 Ag1 5.5(12) . . . . ?
N9 Ag1 N2 C24 16.6(11) . . . . ?
N9 Ag1 N2 N3 -155.1(6) . . . . ?
N4 C25 N3 N2 -1.7(9) . . . . ?
C26 C25 N3 N2 -179.5(7) . . . . ?
N4 C25 N3 Ag2 176.1(5) . . . . ?
C26 C25 N3 Ag2 -1.7(12) . . . . ?
C24 N2 N3 C25 2.0(8) . . . . ?
Ag1 N2 N3 C25 175.6(5) . . . . ?
C24 N2 N3 Ag2 -176.2(5) . . . . ?
Ag1 N2 N3 Ag2 -2.5(7) . . . . ?
N8 Ag2 N3 C25 -9.2(11) . . . . ?
N8 Ag2 N3 N2 168.4(5) . . . . ?
N3 C25 N4 C24 0.8(9) . . . . ?
C26 C25 N4 C24 178.4(8) . . . . ?
N3 C25 N4 N5 177.8(7) . . . . ?
C26 C25 N4 N5 -4.6(13) . . . . ?
N2 C24 N4 C25 0.5(9) . . . . ?
C21 C24 N4 C25 -179.0(7) . . . . ?
N2 C24 N4 N5 -176.4(7) . . . . ?
C21 C24 N4 N5 4.0(12) . . . . ?
C34 C33 N6 C29 174.6(10) . . . . ?
C32 C33 N6 C29 -1.1(17) . . . . ?
C34 C33 N6 Cu1 -13.4(17) . . . . ?
C32 C33 N6 Cu1 171.0(10) . . . . ?
C30 C29 N6 C33 124.3(10) . . . . ?
C28 C29 N6 C33 -62.0(12) . . . . ?
C30 C29 N6 Cu1 -48.1(10) . . . . ?
C28 C29 N6 Cu1 125.6(8) . . . . ?
O25 Cu1 N6 C33 -73.5(11) . . . . ?
O26 Cu1 N6 C33 12.4(9) . . . . ?
N7 Cu1 N6 C33 164.3(9) . . . . ?
O25 Cu1 N6 C29 98.2(8) . . . . ?
O26 Cu1 N6 C29 -175.9(6) . . . . ?
N7 Cu1 N6 C29 -24.0(7) . . . . ?
C39 C40 N7 C42 -177.3(10) . . . . ?
C41 C40 N7 C42 0.7(15) . . . . ?
C39 C40 N7 Cu1 -5.2(16) . . . . ?
C41 C40 N7 Cu1 172.9(8) . . . . ?
C43 C42 N7 C40 124.8(10) . . . . ?
C47 C42 N7 C40 -54.4(12) . . . . ?
C43 C42 N7 Cu1 -48.0(9) . . . . ?
C47 C42 N7 Cu1 132.8(7) . . . . ?
O25 Cu1 N7 C40 -3.7(9) . . . . ?
O26 Cu1 N7 C40 -89.3(9) . . . . ?
N6 Cu1 N7 C40 149.0(8) . . . . ?
O25 Cu1 N7 C42 168.5(6) . . . . ?
O26 Cu1 N7 C42 82.9(8) . . . . ?
N6 Cu1 N7 C42 -38.8(6) . . . . ?
N10 C48 N8 N9 -2.8(9) 2_656 . . 2_656 ?
C45 C48 N8 N9 -177.4(7) . . . 2_656 ?
N10 C48 N8 Ag2 -178.7(5) 2_656 . . . ?
C45 C48 N8 Ag2 6.6(12) . . . . ?
N3 Ag2 N8 C48 -23.4(11) . . . . ?
N3 Ag2 N8 N9 160.9(5) . . . 2_656 ?
N10 C12 N9 N8 -2.4(9) . . . 2_656 ?
C9 C12 N9 N8 179.8(7) . . . 2_656 ?
N10 C12 N9 Ag1 175.2(5) . . . . ?
C9 C12 N9 Ag1 -2.5(13) . . . . ?
N2 Ag1 N9 C12 8.2(12) . . . . ?
N2 Ag1 N9 N8 -174.4(5) . . . 2_656 ?
N9 C12 N10 C48 0.8(9) . . . 2_656 ?
C9 C12 N10 C48 178.5(7) . . . 2_656 ?
N9 C12 N10 N11 -172.1(6) . . . . ?
C9 C12 N10 N11 5.7(13) . . . . ?
C15 C16 N12 C18 -168.9(8) . . . . ?
C17 C16 N12 C18 10.3(12) . . . . ?
C15 C16 N12 Cu2 19.3(13) . . . . ?
C17 C16 N12 Cu2 -161.5(7) . . . . ?
C23 C18 N12 C16 61.3(11) . . . . ?
C19 C18 N12 C16 -123.2(8) . . . . ?
C23 C18 N12 Cu2 -127.1(7) . . . . ?
C19 C18 N12 Cu2 48.5(9) . . . . ?
O27 Cu2 N12 C16 -22.0(7) . . . . ?
N1 Cu2 N12 C16 -167.9(6) . . . . ?
O28 Cu2 N12 C16 76.1(8) . . . . ?
O27 Cu2 N12 C18 166.7(6) . . . . ?
N1 Cu2 N12 C18 20.8(7) . . . . ?
O28 Cu2 N12 C18 -95.2(7) . . . . ?
C39 C38 O25 Cu1 0.1(18) . . . . ?
C37 C38 O25 Cu1 171.2(7) . . . . ?
O26 Cu1 O25 C38 152.6(9) . . . . ?
N6 Cu1 O25 C38 -118.3(9) . . . . ?
N7 Cu1 O25 C38 6.3(9) . . . . ?
C34 C35 O26 Cu1 4.3(16) . . . . ?
C36 C35 O26 Cu1 -177.3(7) . . . . ?
O25 Cu1 O26 C35 139.0(9) . . . . ?
N6 Cu1 O26 C35 -8.1(9) . . . . ?
N7 Cu1 O26 C35 -132.2(9) . . . . ?
C15 C14 O27 Cu2 -3.7(15) . . . . ?
C13 C14 O27 Cu2 178.3(5) . . . . ?
N12 Cu2 O27 C14 15.3(8) . . . . ?
N1 Cu2 O27 C14 137.0(7) . . . . ?
O28 Cu2 O27 C14 -122.3(7) . . . . ?
C3 C2 O28 Cu2 9.5(13) . . . . ?
C1 C2 O28 Cu2 -173.2(5) . . . . ?
N12 Cu2 O28 C2 114.3(7) . . . . ?
O27 Cu2 O28 C2 -146.1(7) . . . . ?
N1 Cu2 O28 C2 -5.0(7) . . . . ?

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.004 -0.004 0.004 4585 1865 ' '
2 1.000 0.463 0.250 18 6 ' '
3 0.000 0.537 0.750 19 6 ' '

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        24.50
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         0.551
_refine_diff_density_min         -0.730
_refine_diff_density_rms         0.081
_database_code_depnum_ccdc_archive 'CCDC 978498'
