# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_complex2

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C30 H40 Ge2 P2 Pt'
_chemical_formula_moiety         'C30 H40 Ge2 P2 Pt'
_chemical_formula_weight         802.86
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_Int_Tables_number      15
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-Y,1/2+Z
5 1/2+X,1/2+Y,+Z
6 1/2-X,1/2+Y,1/2-Z
7 1/2-X,1/2-Y,-Z
8 1/2+X,1/2-Y,1/2+Z
#------------------------------------------------------------------------------
_cell_length_a                   22.985(6)
_cell_length_b                   8.962(2)
_cell_length_c                   15.656(4)
_cell_angle_alpha                90.0000
_cell_angle_beta                 107.227(3)
_cell_angle_gamma                90.0000
_cell_volume                     3080.2(14)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    5275
_cell_measurement_theta_min      3.54
_cell_measurement_theta_max      27.47
_cell_measurement_temperature    113
#------------------------------------------------------------------------------
_exptl_crystal_description       prism
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.560
_exptl_crystal_size_mid          0.410
_exptl_crystal_size_min          0.280
_exptl_crystal_density_diffrn    1.731
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1568.00
_exptl_absorpt_coefficient_mu    6.571
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_correction_T_min  0.090
_exptl_absorpt_correction_T_max  0.159

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      113
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 7.314
_diffrn_reflns_number            11909
_diffrn_reflns_av_R_equivalents  0.0295
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 0.994
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_reflns_number_total             3517
_reflns_number_gt                3183
_reflns_threshold_expression     F²>2.0σ(F²)
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_all          0.0507
_refine_ls_R_factor_gt           0.0475
_refine_ls_wR_factor_ref         0.1242
_refine_ls_wR_factor_gt          0.1223
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_reflns         3517
_refine_ls_number_parameters     167
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0604P)²+81.1870P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.000
_refine_diff_density_max         8.700
_refine_diff_density_min         -1.540
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
Ge Ge 0.1547 1.8001
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.0000 0.5000 0.0000 0.01055(12) Uani 1.0 4 d . . .
Ge1 Ge 0.07389(3) 0.70114(8) 0.05758(5) 0.01846(18) Uani 1.0 8 d . . .
P1 P -0.07330(8) 0.6546(2) 0.02366(12) 0.0184(4) Uani 1.0 8 d . . .
C1 C 0.1097(3) 0.7784(8) -0.0352(5) 0.0191(14) Uani 1.0 8 d . . .
C2 C 0.0697(4) 0.7947(10) -0.1206(5) 0.0273(17) Uani 1.0 8 d . . .
C3 C 0.0874(4) 0.8632(11) -0.1888(6) 0.0334(19) Uani 1.0 8 d . . .
C4 C 0.1470(4) 0.9129(10) -0.1726(6) 0.0328(19) Uani 1.0 8 d . . .
C5 C 0.1877(4) 0.8964(10) -0.0894(6) 0.0289(17) Uani 1.0 8 d . . .
C6 C 0.1696(4) 0.8275(9) -0.0208(5) 0.0228(15) Uani 1.0 8 d . . .
C7 C 0.1396(3) 0.6545(9) 0.1683(5) 0.0198(14) Uani 1.0 8 d . . .
C8 C 0.1857(4) 0.7569(9) 0.2074(5) 0.0225(15) Uani 1.0 8 d . . .
C9 C 0.2291(4) 0.7286(10) 0.2878(5) 0.0253(16) Uani 1.0 8 d . . .
C10 C 0.2282(4) 0.5969(10) 0.3330(5) 0.0271(17) Uani 1.0 8 d . . .
C11 C 0.1833(4) 0.4921(9) 0.2964(6) 0.0243(16) Uani 1.0 8 d . . .
C12 C 0.1393(4) 0.5207(8) 0.2149(5) 0.0215(15) Uani 1.0 8 d . . .
C13 C -0.0590(4) 0.7096(10) 0.1402(5) 0.0280(17) Uani 1.0 8 d . . .
C14 C -0.1519(3) 0.5905(9) -0.0022(6) 0.0224(15) Uani 1.0 8 d . . .
C15 C -0.0836(4) 0.8278(8) -0.0384(6) 0.0255(16) Uani 1.0 8 d . . .
H1 H 0.038(4) 0.850(9) 0.093(5) 0.015(19) Uiso 1.0 8 d . . .
H2 H 0.0292 0.7583 -0.1328 0.0328 Uiso 1.0 8 calc R . .
H3 H 0.0589 0.8759 -0.2463 0.0401 Uiso 1.0 8 calc R . .
H4 H 0.1594 0.9583 -0.2192 0.0394 Uiso 1.0 8 calc R . .
H5 H 0.2283 0.9315 -0.0780 0.0347 Uiso 1.0 8 calc R . .
H6 H 0.1985 0.8142 0.0364 0.0273 Uiso 1.0 8 calc R . .
H7 H 0.1873 0.8485 0.1776 0.0270 Uiso 1.0 8 calc R . .
H8 H 0.2599 0.8006 0.3123 0.0304 Uiso 1.0 8 calc R . .
H9 H 0.2581 0.5781 0.3886 0.0326 Uiso 1.0 8 calc R . .
H10 H 0.1825 0.4008 0.3267 0.0292 Uiso 1.0 8 calc R . .
H11 H 0.1086 0.4484 0.1906 0.0257 Uiso 1.0 8 calc R . .
H12 H -0.0537 0.6201 0.1778 0.0336 Uiso 1.0 8 calc R . .
H13 H -0.0937 0.7675 0.1465 0.0336 Uiso 1.0 8 calc R . .
H14 H -0.0220 0.7706 0.1589 0.0336 Uiso 1.0 8 calc R . .
H15 H -0.1539 0.5047 0.0356 0.0269 Uiso 1.0 8 calc R . .
H16 H -0.1667 0.5612 -0.0653 0.0269 Uiso 1.0 8 calc R . .
H17 H -0.1774 0.6713 0.0091 0.0269 Uiso 1.0 8 calc R . .
H18 H -0.1020 0.8071 -0.1022 0.0306 Uiso 1.0 8 calc R . .
H19 H -0.0440 0.8762 -0.0293 0.0306 Uiso 1.0 8 calc R . .
H20 H -0.1105 0.8939 -0.0173 0.0306 Uiso 1.0 8 calc R . .



#==============================================================================
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_cell_refinement       CrystalClear
_computing_data_reduction        CrystalClear
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_molecular_graphics    'CrystalStructure 4.0'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
;
    ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
Pt1 Ge1 2.4576(8) yes . .
Pt1 Ge1 2.4576(8) yes . 3_565
Pt1 P1 2.294(2) yes . .
Pt1 P1 2.294(2) yes . 3_565
Ge1 C1 1.993(8) yes . .
Ge1 C7 1.977(6) yes . .
P1 C13 1.823(8) yes . .
P1 C14 1.824(7) yes . .
P1 C15 1.809(8) yes . .
C1 C2 1.388(10) yes . .
C1 C6 1.399(11) yes . .
C2 C3 1.394(13) yes . .
C3 C4 1.390(13) yes . .
C4 C5 1.369(11) yes . .
C5 C6 1.404(13) yes . .
C7 C8 1.399(10) yes . .
C7 C12 1.405(11) yes . .
C8 C9 1.378(10) yes . .
C9 C10 1.380(12) yes . .
C10 C11 1.387(11) yes . .
C11 C12 1.397(10) yes . .
Ge1 H1 1.74(9) no . .
C2 H2 0.950 no . .
C3 H3 0.950 no . .
C4 H4 0.950 no . .
C5 H5 0.950 no . .
C6 H6 0.950 no . .
C8 H7 0.950 no . .
C9 H8 0.950 no . .
C10 H9 0.950 no . .
C11 H10 0.950 no . .
C12 H11 0.950 no . .
C13 H12 0.980 no . .
C13 H13 0.980 no . .
C13 H14 0.980 no . .
C14 H15 0.980 no . .
C14 H16 0.980 no . .
C14 H17 0.980 no . .
C15 H18 0.980 no . .
C15 H19 0.980 no . .
C15 H20 0.980 no . .

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
Ge1 Pt1 Ge1 180.00(4) yes . . 3_565
Ge1 Pt1 P1 87.63(5) yes . . .
Ge1 Pt1 P1 92.37(5) yes . . 3_565
Ge1 Pt1 P1 92.37(5) yes 3_565 . .
Ge1 Pt1 P1 87.63(5) yes 3_565 . 3_565
P1 Pt1 P1 180.00(9) yes . . 3_565
Pt1 Ge1 C1 112.1(2) yes . . .
Pt1 Ge1 C7 115.6(3) yes . . .
C1 Ge1 C7 109.9(3) yes . . .
Pt1 P1 C13 113.7(3) yes . . .
Pt1 P1 C14 120.1(3) yes . . .
Pt1 P1 C15 114.7(3) yes . . .
C13 P1 C14 100.4(4) yes . . .
C13 P1 C15 105.2(4) yes . . .
C14 P1 C15 100.8(4) yes . . .
Ge1 C1 C2 116.1(6) yes . . .
Ge1 C1 C6 126.2(5) yes . . .
C2 C1 C6 117.5(8) yes . . .
C1 C2 C3 121.6(8) yes . . .
C2 C3 C4 119.8(7) yes . . .
C3 C4 C5 119.9(9) yes . . .
C4 C5 C6 120.1(8) yes . . .
C1 C6 C5 121.0(7) yes . . .
Ge1 C7 C8 121.9(6) yes . . .
Ge1 C7 C12 121.1(5) yes . . .
C8 C7 C12 116.9(6) yes . . .
C7 C8 C9 121.9(8) yes . . .
C8 C9 C10 120.7(7) yes . . .
C9 C10 C11 119.2(7) yes . . .
C10 C11 C12 120.2(7) yes . . .
C7 C12 C11 121.2(7) yes . . .
Pt1 Ge1 H1 110(3) no . . .
C1 Ge1 H1 108(3) no . . .
C7 Ge1 H1 101(3) no . . .
C1 C2 H2 119.191 no . . .
C3 C2 H2 119.206 no . . .
C2 C3 H3 120.081 no . . .
C4 C3 H3 120.103 no . . .
C3 C4 H4 120.069 no . . .
C5 C4 H4 120.055 no . . .
C4 C5 H5 119.944 no . . .
C6 C5 H5 119.937 no . . .
C1 C6 H6 119.494 no . . .
C5 C6 H6 119.503 no . . .
C7 C8 H7 119.034 no . . .
C9 C8 H7 119.044 no . . .
C8 C9 H8 119.670 no . . .
C10 C9 H8 119.675 no . . .
C9 C10 H9 120.378 no . . .
C11 C10 H9 120.388 no . . .
C10 C11 H10 119.916 no . . .
C12 C11 H10 119.916 no . . .
C7 C12 H11 119.419 no . . .
C11 C12 H11 119.428 no . . .
P1 C13 H12 109.465 no . . .
P1 C13 H13 109.479 no . . .
P1 C13 H14 109.460 no . . .
H12 C13 H13 109.485 no . . .
H12 C13 H14 109.463 no . . .
H13 C13 H14 109.474 no . . .
P1 C14 H15 109.469 no . . .
P1 C14 H16 109.471 no . . .
P1 C14 H17 109.468 no . . .
H15 C14 H16 109.472 no . . .
H15 C14 H17 109.477 no . . .
H16 C14 H17 109.471 no . . .
P1 C15 H18 109.471 no . . .
P1 C15 H19 109.460 no . . .
P1 C15 H20 109.474 no . . .
H18 C15 H19 109.465 no . . .
H18 C15 H20 109.478 no . . .
H19 C15 H20 109.480 no . . .
_database_code_depnum_ccdc_archive 'CCDC 979331'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_complex3

#==============================================================================
# CHEMICAL DATA

_chemical_formula_sum            'C45 H57 Ge3 P3 Pt3'
_chemical_formula_moiety         'C45 H57 Ge3 P3 Pt3'
_chemical_formula_weight         1493.91
_chemical_melting_point          ?

#==============================================================================
# CRYSTAL DATA
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_Int_Tables_number      2
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,-Y,-Z
#------------------------------------------------------------------------------
_cell_length_a                   12.539(2)
_cell_length_b                   13.863(2)
_cell_length_c                   15.866(3)
_cell_angle_alpha                66.820(8)
_cell_angle_beta                 79.268(10)
_cell_angle_gamma                66.814(9)
_cell_volume                     2328.9(8)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7301
_cell_measurement_theta_min      3.20
_cell_measurement_theta_max      27.48
_cell_measurement_temperature    293
#------------------------------------------------------------------------------
_exptl_crystal_description       prism
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_crystal_density_diffrn    2.130
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1404.00
_exptl_absorpt_coefficient_mu    10.983
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_absorpt_correction_T_min  0.081
_exptl_absorpt_correction_T_max  0.111

#==============================================================================
# EXPERIMENTAL DATA

_diffrn_ambient_temperature      293
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71070
_diffrn_measurement_device_type  'Rigaku Saturn70'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 7.314
_diffrn_reflns_number            19101
_diffrn_reflns_av_R_equivalents  0.0351
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measured_fraction_theta_full 0.960
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_standards_number         0
_diffrn_standards_interval_count .
_diffrn_standards_decay_%        ?

#==============================================================================
# REFINEMENT DATA

_refine_special_details          
;
    Refinement was performed using all reflections. The weighted 
    R-factor (wR) and goodness of fit (S) are based on F².
    R-factor (gt) are based on F. The threshold expression of
    F² > 2.0 sigma(F²) is used only for calculating R-factor (gt).
;
_reflns_number_total             10239
_reflns_number_gt                7179
_reflns_threshold_expression     F²>2.0σ(F²)
_refine_ls_structure_factor_coef Fsqd
_refine_ls_R_factor_gt           0.0310
_refine_ls_wR_factor_ref         0.0925
_refine_ls_number_restraints     0
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_reflns         10239
_refine_ls_number_parameters     496
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w = 1/[σ²(Fo²)+(0.0385P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_refine_ls_shift/su_max          0.001
_refine_diff_density_max         2.700
_refine_diff_density_min         -1.310
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
Ge Ge 0.1547 1.8001
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;

#==============================================================================
# ATOMIC COORDINATES AND THERMAL PARAMETERS

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.28644(2) 0.77334(2) 0.278900(18) 0.01235(7) Uani 1.0 2 d . . .
Pt2 Pt 0.48867(2) 0.68589(2) 0.191965(18) 0.01240(7) Uani 1.0 2 d . . .
Pt3 Pt 0.47316(2) 0.82566(2) 0.278441(18) 0.01211(7) Uani 1.0 2 d . . .
Ge1 Ge 0.64970(6) 0.73122(6) 0.20674(5) 0.01299(16) Uani 1.0 2 d . . .
Ge2 Ge 0.28910(6) 0.89383(7) 0.35462(5) 0.01505(16) Uani 1.0 2 d . . .
Ge3 Ge 0.31640(6) 0.64317(6) 0.20271(5) 0.01376(16) Uani 1.0 2 d . . .
P1 P 0.09622(16) 0.80580(16) 0.31070(13) 0.0158(4) Uani 1.0 2 d . . .
P2 P 0.59240(17) 0.58683(17) 0.10223(13) 0.0172(4) Uani 1.0 2 d . . .
P3 P 0.55448(17) 0.93012(16) 0.30255(13) 0.0161(4) Uani 1.0 2 d . . .
C1 C 0.7146(6) 0.8280(6) 0.1002(5) 0.0137(15) Uani 1.0 2 d . . .
C2 C 0.8186(7) 0.8429(7) 0.0986(6) 0.0200(17) Uani 1.0 2 d . . .
C3 C 0.8480(7) 0.9256(7) 0.0262(6) 0.0239(18) Uani 1.0 2 d . . .
C4 C 0.7734(8) 0.9960(7) -0.0457(6) 0.0249(19) Uani 1.0 2 d . . .
C5 C 0.6704(7) 0.9818(7) -0.0460(5) 0.0222(18) Uani 1.0 2 d . . .
C6 C 0.6419(7) 0.8987(7) 0.0264(6) 0.0199(17) Uani 1.0 2 d . . .
C7 C 0.7741(7) 0.6140(6) 0.2865(5) 0.0146(15) Uani 1.0 2 d . . .
C8 C 0.7465(8) 0.5688(7) 0.3798(6) 0.030(2) Uani 1.0 2 d . . .
C9 C 0.8307(8) 0.4867(8) 0.4415(7) 0.038(3) Uani 1.0 2 d . . .
C10 C 0.9454(8) 0.4478(8) 0.4120(7) 0.035(3) Uani 1.0 2 d . . .
C11 C 0.9746(7) 0.4888(7) 0.3198(6) 0.0222(18) Uani 1.0 2 d . . .
C12 C 0.8903(7) 0.5704(7) 0.2592(6) 0.0206(17) Uani 1.0 2 d . . .
C13 C 0.1907(7) 1.0548(6) 0.3092(6) 0.0197(17) Uani 1.0 2 d . . .
C14 C 0.2152(7) 1.1188(7) 0.2203(6) 0.0251(18) Uani 1.0 2 d . . .
C15 C 0.1453(8) 1.2296(8) 0.1791(6) 0.032(2) Uani 1.0 2 d . . .
C16 C 0.0481(8) 1.2783(8) 0.2264(7) 0.034(3) Uani 1.0 2 d . . .
C17 C 0.0207(7) 1.2169(7) 0.3143(7) 0.031(2) Uani 1.0 2 d . . .
C18 C 0.0921(7) 1.1052(7) 0.3558(7) 0.0275(19) Uani 1.0 2 d . . .
C19 C 0.2818(7) 0.8405(7) 0.4889(5) 0.0210(17) Uani 1.0 2 d . . .
C20 C 0.2508(7) 0.9090(8) 0.5409(6) 0.0254(19) Uani 1.0 2 d . . .
C21 C 0.2490(8) 0.8647(8) 0.6361(6) 0.028(2) Uani 1.0 2 d . . .
C22 C 0.2783(8) 0.7509(8) 0.6810(6) 0.032(2) Uani 1.0 2 d . . .
C23 C 0.3091(8) 0.6802(8) 0.6317(6) 0.034(3) Uani 1.0 2 d . . .
C24 C 0.3104(7) 0.7247(7) 0.5367(6) 0.028(2) Uani 1.0 2 d . . .
C25 C 0.2319(7) 0.6899(6) 0.0908(5) 0.0167(16) Uani 1.0 2 d . . .
C26 C 0.1447(6) 0.6522(6) 0.0881(6) 0.0185(16) Uani 1.0 2 d . . .
C27 C 0.0884(7) 0.6914(7) 0.0078(6) 0.0234(18) Uani 1.0 2 d . . .
C28 C 0.1173(7) 0.7663(7) -0.0719(6) 0.0269(19) Uani 1.0 2 d . . .
C29 C 0.2026(8) 0.8046(7) -0.0690(6) 0.028(2) Uani 1.0 2 d . . .
C30 C 0.2594(7) 0.7657(7) 0.0111(6) 0.0233(18) Uani 1.0 2 d . . .
C31 C 0.3260(7) 0.4890(7) 0.2805(6) 0.0179(16) Uani 1.0 2 d . . .
C32 C 0.3693(8) 0.4469(7) 0.3671(6) 0.0244(18) Uani 1.0 2 d . . .
C33 C 0.3827(8) 0.3380(7) 0.4265(6) 0.032(2) Uani 1.0 2 d . . .
C34 C 0.3500(8) 0.2704(7) 0.4005(6) 0.031(2) Uani 1.0 2 d . . .
C35 C 0.3103(8) 0.3084(7) 0.3122(6) 0.028(2) Uani 1.0 2 d . . .
C36 C 0.2989(7) 0.4165(7) 0.2535(6) 0.0207(17) Uani 1.0 2 d . . .
C37 C 0.0059(7) 0.9286(7) 0.2235(6) 0.031(2) Uani 1.0 2 d . . .
C38 C 0.0311(7) 0.8339(7) 0.4135(6) 0.0238(18) Uani 1.0 2 d . . .
C39 C 0.0417(7) 0.6991(7) 0.3179(6) 0.0236(18) Uani 1.0 2 d . . .
C40 C 0.5871(8) 0.6675(7) -0.0205(6) 0.0281(19) Uani 1.0 2 d . . .
C41 C 0.5560(7) 0.4698(7) 0.1087(6) 0.0252(18) Uani 1.0 2 d . . .
C42 C 0.7477(7) 0.5203(8) 0.1150(6) 0.030(2) Uani 1.0 2 d . . .
C43 C 0.5573(8) 1.0521(7) 0.2022(6) 0.0255(19) Uani 1.0 2 d . . .
C44 C 0.4868(7) 0.9927(7) 0.3905(6) 0.0261(19) Uani 1.0 2 d . . .
C45 C 0.7067(6) 0.8632(7) 0.3363(5) 0.0190(16) Uani 1.0 2 d . . .
H1 H 0.8688 0.7967 0.1467 0.0240 Uiso 1.0 2 calc R . .
H2 H 0.9181 0.9343 0.0256 0.0287 Uiso 1.0 2 calc R . .
H3 H 0.7929 1.0525 -0.0937 0.0299 Uiso 1.0 2 calc R . .
H4 H 0.6207 1.0278 -0.0944 0.0266 Uiso 1.0 2 calc R . .
H5 H 0.5724 0.8895 0.0261 0.0238 Uiso 1.0 2 calc R . .
H6 H 0.6700 0.5943 0.4011 0.0360 Uiso 1.0 2 calc R . .
H7 H 0.8098 0.4577 0.5032 0.0455 Uiso 1.0 2 calc R . .
H8 H 1.0020 0.3946 0.4537 0.0416 Uiso 1.0 2 calc R . .
H9 H 1.0508 0.4615 0.2986 0.0266 Uiso 1.0 2 calc R . .
H10 H 0.9117 0.5977 0.1974 0.0247 Uiso 1.0 2 calc R . .
H11 H 0.2799 1.0863 0.1879 0.0301 Uiso 1.0 2 calc R . .
H12 H 0.1636 1.2711 0.1199 0.0388 Uiso 1.0 2 calc R . .
H13 H 0.0011 1.3527 0.1989 0.0414 Uiso 1.0 2 calc R . .
H14 H -0.0450 1.2495 0.3458 0.0376 Uiso 1.0 2 calc R . .
H15 H 0.0737 1.0640 0.4151 0.0330 Uiso 1.0 2 calc R . .
H16 H 0.2308 0.9861 0.5112 0.0305 Uiso 1.0 2 calc R . .
H17 H 0.2279 0.9120 0.6695 0.0330 Uiso 1.0 2 calc R . .
H18 H 0.2776 0.7212 0.7448 0.0381 Uiso 1.0 2 calc R . .
H19 H 0.3288 0.6032 0.6622 0.0408 Uiso 1.0 2 calc R . .
H20 H 0.3307 0.6768 0.5040 0.0340 Uiso 1.0 2 calc R . .
H21 H 0.1246 0.6005 0.1406 0.0221 Uiso 1.0 2 calc R . .
H22 H 0.0295 0.6667 0.0075 0.0281 Uiso 1.0 2 calc R . .
H23 H 0.0804 0.7903 -0.1261 0.0323 Uiso 1.0 2 calc R . .
H24 H 0.2219 0.8570 -0.1214 0.0338 Uiso 1.0 2 calc R . .
H25 H 0.3177 0.7913 0.0113 0.0279 Uiso 1.0 2 calc R . .
H26 H 0.3900 0.4926 0.3860 0.0293 Uiso 1.0 2 calc R . .
H27 H 0.4139 0.3110 0.4837 0.0381 Uiso 1.0 2 calc R . .
H28 H 0.3542 0.1993 0.4416 0.0366 Uiso 1.0 2 calc R . .
H29 H 0.2918 0.2616 0.2932 0.0335 Uiso 1.0 2 calc R . .
H30 H 0.2727 0.4417 0.1948 0.0248 Uiso 1.0 2 calc R . .
H31 H 0.0206 0.9936 0.2185 0.0370 Uiso 1.0 2 calc R . .
H32 H -0.0744 0.9391 0.2403 0.0370 Uiso 1.0 2 calc R . .
H33 H 0.0239 0.9178 0.1655 0.0370 Uiso 1.0 2 calc R . .
H34 H -0.0493 0.8422 0.4186 0.0286 Uiso 1.0 2 calc R . .
H35 H 0.0374 0.9018 0.4110 0.0286 Uiso 1.0 2 calc R . .
H36 H 0.0705 0.7727 0.4659 0.0286 Uiso 1.0 2 calc R . .
H37 H -0.0402 0.7227 0.3327 0.0283 Uiso 1.0 2 calc R . .
H38 H 0.0810 0.6297 0.3649 0.0283 Uiso 1.0 2 calc R . .
H39 H 0.0554 0.6885 0.2601 0.0283 Uiso 1.0 2 calc R . .
H40 H 0.5082 0.7001 -0.0390 0.0337 Uiso 1.0 2 calc R . .
H41 H 0.6332 0.6189 -0.0535 0.0337 Uiso 1.0 2 calc R . .
H42 H 0.6171 0.7260 -0.0335 0.0337 Uiso 1.0 2 calc R . .
H43 H 0.5632 0.4171 0.1706 0.0302 Uiso 1.0 2 calc R . .
H44 H 0.6079 0.4335 0.0685 0.0302 Uiso 1.0 2 calc R . .
H45 H 0.4776 0.4967 0.0904 0.0302 Uiso 1.0 2 calc R . .
H46 H 0.7818 0.4880 0.0684 0.0355 Uiso 1.0 2 calc R . .
H47 H 0.7638 0.4624 0.1744 0.0355 Uiso 1.0 2 calc R . .
H48 H 0.7800 0.5752 0.1089 0.0355 Uiso 1.0 2 calc R . .
H49 H 0.4800 1.0962 0.1807 0.0306 Uiso 1.0 2 calc R . .
H50 H 0.6063 1.0279 0.1547 0.0306 Uiso 1.0 2 calc R . .
H51 H 0.5870 1.0965 0.2181 0.0306 Uiso 1.0 2 calc R . .
H52 H 0.4865 0.9344 0.4488 0.0314 Uiso 1.0 2 calc R . .
H53 H 0.4085 1.0418 0.3748 0.0314 Uiso 1.0 2 calc R . .
H54 H 0.5300 1.0347 0.3941 0.0314 Uiso 1.0 2 calc R . .
H55 H 0.7272 0.9128 0.3532 0.0228 Uiso 1.0 2 calc R . .
H56 H 0.7561 0.8476 0.2857 0.0228 Uiso 1.0 2 calc R . .
H57 H 0.7161 0.7944 0.3875 0.0228 Uiso 1.0 2 calc R . .



#==============================================================================
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_cell_refinement       CrystalClear
_computing_data_reduction        CrystalClear
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_molecular_graphics    'CrystalStructure 4.0'

#==============================================================================
# MOLECULAR GEOMETRY

_geom_special_details            
;
    ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
Pt1 Pt2 2.7194(6) yes . .
Pt1 Pt3 2.7081(6) yes . .
Pt1 Ge2 2.4234(12) yes . .
Pt1 Ge3 2.4234(11) yes . .
Pt1 P1 2.243(2) yes . .
Pt2 Pt3 2.7150(6) yes . .
Pt2 Ge1 2.4120(11) yes . .
Pt2 Ge3 2.4158(10) yes . .
Pt2 P2 2.247(3) yes . .
Pt3 Ge1 2.4209(9) yes . .
Pt3 Ge2 2.4131(9) yes . .
Pt3 P3 2.242(3) yes . .
Ge1 C1 1.971(7) yes . .
Ge1 C7 1.948(7) yes . .
Ge2 C13 1.980(7) yes . .
Ge2 C19 1.958(8) yes . .
Ge3 C25 1.987(9) yes . .
Ge3 C31 1.970(8) yes . .
P1 C37 1.819(7) yes . .
P1 C38 1.798(10) yes . .
P1 C39 1.817(11) yes . .
P2 C40 1.822(8) yes . .
P2 C41 1.813(11) yes . .
P2 C42 1.808(8) yes . .
P3 C43 1.817(8) yes . .
P3 C44 1.831(10) yes . .
P3 C45 1.840(8) yes . .
C1 C2 1.393(13) yes . .
C1 C6 1.397(10) yes . .
C2 C3 1.381(11) yes . .
C3 C4 1.390(11) yes . .
C4 C5 1.382(14) yes . .
C5 C6 1.379(11) yes . .
C7 C8 1.397(11) yes . .
C7 C12 1.398(10) yes . .
C8 C9 1.389(12) yes . .
C9 C10 1.384(13) yes . .
C10 C11 1.381(12) yes . .
C11 C12 1.379(10) yes . .
C13 C14 1.392(11) yes . .
C13 C18 1.395(12) yes . .
C14 C15 1.385(11) yes . .
C15 C16 1.384(13) yes . .
C16 C17 1.380(13) yes . .
C17 C18 1.399(10) yes . .
C19 C20 1.394(15) yes . .
C19 C24 1.404(12) yes . .
C20 C21 1.388(12) yes . .
C21 C22 1.373(13) yes . .
C22 C23 1.383(16) yes . .
C23 C24 1.385(12) yes . .
C25 C26 1.399(14) yes . .
C25 C30 1.378(10) yes . .
C26 C27 1.380(13) yes . .
C27 C28 1.378(11) yes . .
C28 C29 1.384(16) yes . .
C29 C30 1.382(13) yes . .
C31 C32 1.387(12) yes . .
C31 C36 1.403(16) yes . .
C32 C33 1.391(12) yes . .
C33 C34 1.374(18) yes . .
C34 C35 1.401(14) yes . .
C35 C36 1.384(11) yes . .
C2 H1 0.930 no . .
C3 H2 0.930 no . .
C4 H3 0.930 no . .
C5 H4 0.930 no . .
C6 H5 0.930 no . .
C8 H6 0.930 no . .
C9 H7 0.930 no . .
C10 H8 0.930 no . .
C11 H9 0.930 no . .
C12 H10 0.930 no . .
C14 H11 0.930 no . .
C15 H12 0.930 no . .
C16 H13 0.930 no . .
C17 H14 0.930 no . .
C18 H15 0.930 no . .
C20 H16 0.930 no . .
C21 H17 0.930 no . .
C22 H18 0.930 no . .
C23 H19 0.930 no . .
C24 H20 0.930 no . .
C26 H21 0.930 no . .
C27 H22 0.930 no . .
C28 H23 0.930 no . .
C29 H24 0.930 no . .
C30 H25 0.930 no . .
C32 H26 0.930 no . .
C33 H27 0.930 no . .
C34 H28 0.930 no . .
C35 H29 0.930 no . .
C36 H30 0.930 no . .
C37 H31 0.960 no . .
C37 H32 0.960 no . .
C37 H33 0.960 no . .
C38 H34 0.960 no . .
C38 H35 0.960 no . .
C38 H36 0.960 no . .
C39 H37 0.960 no . .
C39 H38 0.960 no . .
C39 H39 0.960 no . .
C40 H40 0.960 no . .
C40 H41 0.960 no . .
C40 H42 0.960 no . .
C41 H43 0.960 no . .
C41 H44 0.960 no . .
C41 H45 0.960 no . .
C42 H46 0.960 no . .
C42 H47 0.960 no . .
C42 H48 0.960 no . .
C43 H49 0.960 no . .
C43 H50 0.960 no . .
C43 H51 0.960 no . .
C44 H52 0.960 no . .
C44 H53 0.960 no . .
C44 H54 0.960 no . .
C45 H55 0.960 no . .
C45 H56 0.960 no . .
C45 H57 0.960 no . .

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
Pt2 Pt1 Pt3 60.031(16) yes . . .
Pt2 Pt1 Ge2 115.79(3) yes . . .
Pt2 Pt1 Ge3 55.68(3) yes . . .
Pt2 Pt1 P1 151.02(7) yes . . .
Pt3 Pt1 Ge2 55.77(2) yes . . .
Pt3 Pt1 Ge3 115.68(3) yes . . .
Pt3 Pt1 P1 148.18(7) yes . . .
Ge2 Pt1 Ge3 171.09(3) yes . . .
Ge2 Pt1 P1 92.85(7) yes . . .
Ge3 Pt1 P1 95.88(7) yes . . .
Pt1 Pt2 Pt3 59.779(15) yes . . .
Pt1 Pt2 Ge1 115.63(3) yes . . .
Pt1 Pt2 Ge3 55.94(3) yes . . .
Pt1 Pt2 P2 151.19(7) yes . . .
Pt3 Pt2 Ge1 55.98(3) yes . . .
Pt3 Pt2 Ge3 115.70(3) yes . . .
Pt3 Pt2 P2 148.73(7) yes . . .
Ge1 Pt2 Ge3 170.16(3) yes . . .
Ge1 Pt2 P2 93.15(7) yes . . .
Ge3 Pt2 P2 95.50(8) yes . . .
Pt1 Pt3 Pt2 60.190(14) yes . . .
Pt1 Pt3 Ge1 115.73(3) yes . . .
Pt1 Pt3 Ge2 56.13(3) yes . . .
Pt1 Pt3 P3 151.40(5) yes . . .
Pt2 Pt3 Ge1 55.67(3) yes . . .
Pt2 Pt3 Ge2 116.31(3) yes . . .
Pt2 Pt3 P3 147.25(5) yes . . .
Ge1 Pt3 Ge2 170.79(4) yes . . .
Ge1 Pt3 P3 92.55(6) yes . . .
Ge2 Pt3 P3 95.97(6) yes . . .
Pt2 Ge1 Pt3 68.36(3) yes . . .
Pt2 Ge1 C1 121.2(3) yes . . .
Pt2 Ge1 C7 118.3(3) yes . . .
Pt3 Ge1 C1 116.4(2) yes . . .
Pt3 Ge1 C7 117.6(3) yes . . .
C1 Ge1 C7 109.8(3) yes . . .
Pt1 Ge2 Pt3 68.10(3) yes . . .
Pt1 Ge2 C13 119.2(3) yes . . .
Pt1 Ge2 C19 118.9(4) yes . . .
Pt3 Ge2 C13 120.5(3) yes . . .
Pt3 Ge2 C19 118.2(2) yes . . .
C13 Ge2 C19 107.9(4) yes . . .
Pt1 Ge3 Pt2 68.38(3) yes . . .
Pt1 Ge3 C25 121.2(3) yes . . .
Pt1 Ge3 C31 117.6(3) yes . . .
Pt2 Ge3 C25 120.5(3) yes . . .
Pt2 Ge3 C31 116.0(3) yes . . .
C25 Ge3 C31 108.7(4) yes . . .
Pt1 P1 C37 112.6(3) yes . . .
Pt1 P1 C38 119.7(4) yes . . .
Pt1 P1 C39 117.8(3) yes . . .
C37 P1 C38 101.4(4) yes . . .
C37 P1 C39 101.6(5) yes . . .
C38 P1 C39 100.9(5) yes . . .
Pt2 P2 C40 115.0(3) yes . . .
Pt2 P2 C41 117.9(3) yes . . .
Pt2 P2 C42 118.3(4) yes . . .
C40 P2 C41 102.0(5) yes . . .
C40 P2 C42 100.2(4) yes . . .
C41 P2 C42 100.5(5) yes . . .
Pt3 P3 C43 113.4(4) yes . . .
Pt3 P3 C44 117.9(4) yes . . .
Pt3 P3 C45 117.8(4) yes . . .
C43 P3 C44 102.0(4) yes . . .
C43 P3 C45 102.5(4) yes . . .
C44 P3 C45 100.8(5) yes . . .
Ge1 C1 C2 124.9(6) yes . . .
Ge1 C1 C6 116.4(6) yes . . .
C2 C1 C6 118.0(7) yes . . .
C1 C2 C3 120.6(7) yes . . .
C2 C3 C4 120.3(9) yes . . .
C3 C4 C5 120.0(8) yes . . .
C4 C5 C6 119.3(7) yes . . .
C1 C6 C5 121.8(9) yes . . .
Ge1 C7 C8 118.0(6) yes . . .
Ge1 C7 C12 125.8(6) yes . . .
C8 C7 C12 116.2(7) yes . . .
C7 C8 C9 121.5(8) yes . . .
C8 C9 C10 120.5(8) yes . . .
C9 C10 C11 119.2(8) yes . . .
C10 C11 C12 119.7(7) yes . . .
C7 C12 C11 122.8(7) yes . . .
Ge2 C13 C14 116.9(6) yes . . .
Ge2 C13 C18 124.7(6) yes . . .
C14 C13 C18 118.0(7) yes . . .
C13 C14 C15 121.5(8) yes . . .
C14 C15 C16 119.7(8) yes . . .
C15 C16 C17 120.3(7) yes . . .
C16 C17 C18 119.7(8) yes . . .
C13 C18 C17 120.8(8) yes . . .
Ge2 C19 C20 124.9(6) yes . . .
Ge2 C19 C24 117.9(8) yes . . .
C20 C19 C24 117.2(8) yes . . .
C19 C20 C21 121.5(8) yes . . .
C20 C21 C22 120.0(10) yes . . .
C21 C22 C23 120.2(8) yes . . .
C22 C23 C24 119.7(9) yes . . .
C19 C24 C23 121.4(10) yes . . .
Ge3 C25 C26 124.1(5) yes . . .
Ge3 C25 C30 118.1(8) yes . . .
C26 C25 C30 117.8(8) yes . . .
C25 C26 C27 120.2(7) yes . . .
C26 C27 C28 121.7(10) yes . . .
C27 C28 C29 118.1(9) yes . . .
C28 C29 C30 120.5(8) yes . . .
C25 C30 C29 121.7(10) yes . . .
Ge3 C31 C32 116.9(8) yes . . .
Ge3 C31 C36 125.4(6) yes . . .
C32 C31 C36 117.5(8) yes . . .
C31 C32 C33 121.6(11) yes . . .
C32 C33 C34 119.9(9) yes . . .
C33 C34 C35 120.0(8) yes . . .
C34 C35 C36 119.2(11) yes . . .
C31 C36 C35 121.6(9) yes . . .
C1 C2 H1 119.701 no . . .
C3 C2 H1 119.702 no . . .
C2 C3 H2 119.850 no . . .
C4 C3 H2 119.852 no . . .
C3 C4 H3 120.012 no . . .
C5 C4 H3 120.005 no . . .
C4 C5 H4 120.331 no . . .
C6 C5 H4 120.333 no . . .
C1 C6 H5 119.124 no . . .
C5 C6 H5 119.119 no . . .
C7 C8 H6 119.245 no . . .
C9 C8 H6 119.248 no . . .
C8 C9 H7 119.730 no . . .
C10 C9 H7 119.733 no . . .
C9 C10 H8 120.412 no . . .
C11 C10 H8 120.416 no . . .
C10 C11 H9 120.129 no . . .
C12 C11 H9 120.131 no . . .
C7 C12 H10 118.576 no . . .
C11 C12 H10 118.575 no . . .
C13 C14 H11 119.269 no . . .
C15 C14 H11 119.272 no . . .
C14 C15 H12 120.147 no . . .
C16 C15 H12 120.141 no . . .
C15 C16 H13 119.872 no . . .
C17 C16 H13 119.865 no . . .
C16 C17 H14 120.138 no . . .
C18 C17 H14 120.137 no . . .
C13 C18 H15 119.594 no . . .
C17 C18 H15 119.596 no . . .
C19 C20 H16 119.273 no . . .
C21 C20 H16 119.254 no . . .
C20 C21 H17 120.006 no . . .
C22 C21 H17 119.999 no . . .
C21 C22 H18 119.893 no . . .
C23 C22 H18 119.887 no . . .
C22 C23 H19 120.146 no . . .
C24 C23 H19 120.160 no . . .
C19 C24 H20 119.294 no . . .
C23 C24 H20 119.294 no . . .
C25 C26 H21 119.876 no . . .
C27 C26 H21 119.889 no . . .
C26 C27 H22 119.164 no . . .
C28 C27 H22 119.169 no . . .
C27 C28 H23 120.937 no . . .
C29 C28 H23 120.941 no . . .
C28 C29 H24 119.728 no . . .
C30 C29 H24 119.746 no . . .
C25 C30 H25 119.177 no . . .
C29 C30 H25 119.171 no . . .
C31 C32 H26 119.209 no . . .
C33 C32 H26 119.208 no . . .
C32 C33 H27 120.043 no . . .
C34 C33 H27 120.040 no . . .
C33 C34 H28 119.986 no . . .
C35 C34 H28 119.992 no . . .
C34 C35 H29 120.395 no . . .
C36 C35 H29 120.397 no . . .
C31 C36 H30 119.203 no . . .
C35 C36 H30 119.210 no . . .
P1 C37 H31 109.474 no . . .
P1 C37 H32 109.477 no . . .
P1 C37 H33 109.467 no . . .
H31 C37 H32 109.479 no . . .
H31 C37 H33 109.462 no . . .
H32 C37 H33 109.468 no . . .
P1 C38 H34 109.477 no . . .
P1 C38 H35 109.477 no . . .
P1 C38 H36 109.469 no . . .
H34 C38 H35 109.472 no . . .
H34 C38 H36 109.464 no . . .
H35 C38 H36 109.468 no . . .
P1 C39 H37 109.471 no . . .
P1 C39 H38 109.467 no . . .
P1 C39 H39 109.471 no . . .
H37 C39 H38 109.469 no . . .
H37 C39 H39 109.477 no . . .
H38 C39 H39 109.472 no . . .
P2 C40 H40 109.471 no . . .
P2 C40 H41 109.469 no . . .
P2 C40 H42 109.474 no . . .
H40 C40 H41 109.466 no . . .
H40 C40 H42 109.470 no . . .
H41 C40 H42 109.477 no . . .
P2 C41 H43 109.475 no . . .
P2 C41 H44 109.474 no . . .
P2 C41 H45 109.474 no . . .
H43 C41 H44 109.465 no . . .
H43 C41 H45 109.472 no . . .
H44 C41 H45 109.468 no . . .
P2 C42 H46 109.467 no . . .
P2 C42 H47 109.474 no . . .
P2 C42 H48 109.470 no . . .
H46 C42 H47 109.478 no . . .
H46 C42 H48 109.464 no . . .
H47 C42 H48 109.475 no . . .
P3 C43 H49 109.470 no . . .
P3 C43 H50 109.474 no . . .
P3 C43 H51 109.461 no . . .
H49 C43 H50 109.479 no . . .
H49 C43 H51 109.467 no . . .
H50 C43 H51 109.476 no . . .
P3 C44 H52 109.471 no . . .
P3 C44 H53 109.468 no . . .
P3 C44 H54 109.464 no . . .
H52 C44 H53 109.472 no . . .
H52 C44 H54 109.480 no . . .
H53 C44 H54 109.471 no . . .
P3 C45 H55 109.471 no . . .
P3 C45 H56 109.465 no . . .
P3 C45 H57 109.472 no . . .
H55 C45 H56 109.475 no . . .
H55 C45 H57 109.477 no . . .
H56 C45 H57 109.467 no . . .
_database_code_depnum_ccdc_archive 'CCDC 979332'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_complex4

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C108 H140 Ge6 O8 P6 Pt6'
_chemical_formula_weight         3358.09

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   12.053(3)
_cell_length_b                   23.593(6)
_cell_length_c                   20.308(5)
_cell_angle_alpha                90
_cell_angle_beta                 91.905(4)
_cell_angle_gamma                90
_cell_volume                     5772(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    90(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.932
_exptl_crystal_F_000             3204
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    8.910
_shelx_estimated_absorpt_T_min   0.269
_shelx_estimated_absorpt_T_max   0.469
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.269
_exptl_absorpt_correction_T_max  0.469
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      90(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            23758
_diffrn_reflns_av_unetI/netI     0.1365
_diffrn_reflns_av_R_equivalents  0.0768
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.323
_diffrn_reflns_theta_max         23.177
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 0.783
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 0.783
_diffrn_reflns_point_group_measured_fraction_max 0.948
_diffrn_reflns_point_group_measured_fraction_full 0.746
_reflns_number_total             15612
_reflns_number_gt                11806
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.858
_reflns_Friedel_fraction_max     0.902
_reflns_Friedel_fraction_full    0.708

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Flack x determined using 3721 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.573(17)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         15612
_refine_ls_number_parameters     1231
_refine_ls_number_restraints     1561
_refine_ls_R_factor_all          0.0977
_refine_ls_R_factor_gt           0.0655
_refine_ls_wR_factor_ref         0.1404
_refine_ls_wR_factor_gt          0.1313
_refine_ls_goodness_of_fit_ref   1.336
_refine_ls_restrained_S_all      1.281
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.96838(11) 0.38151(5) 0.52316(7) 0.0129(4) Uani 1 1 d . U . . .
Pt2 Pt 0.98492(11) 0.40137(6) 0.65434(7) 0.0136(4) Uani 1 1 d . U . . .
Pt3 Pt 1.01504(11) 0.29530(6) 0.60838(7) 0.0127(3) Uani 1 1 d . U . . .
Pt6 Pt 0.46664(11) 1.05949(6) 0.88359(7) 0.0158(4) Uani 1 1 d . U . . .
Ge4 Ge 0.3362(3) 0.95441(19) 0.9583(2) 0.0182(10) Uani 1 1 d . U . . .
Ge1 Ge 1.1564(3) 0.40425(17) 0.5447(2) 0.0145(9) Uani 1 1 d . U . . .
Ge5 Ge 0.6920(3) 0.95945(18) 0.8865(2) 0.0162(9) Uani 1 1 d . U . . .
Ge2 Ge 0.7977(3) 0.39492(18) 0.6120(2) 0.0147(9) Uani 1 1 d . U . . .
Ge3 Ge 0.8467(3) 0.27752(17) 0.5436(2) 0.0162(9) Uani 1 1 d . U . . .
Ge6 Ge 0.6387(3) 1.08266(17) 0.9402(2) 0.0171(9) Uani 1 1 d . U . . .
P5 P 0.5302(9) 0.8831(5) 0.7694(6) 0.031(3) Uani 1 1 d . U . . .
P1 P 0.9455(9) 0.4190(5) 0.4233(5) 0.023(2) Uani 1 1 d . U . . .
P3 P 1.0810(8) 0.2053(4) 0.6183(5) 0.021(2) Uani 1 1 d . U . . .
P4 P 0.5538(9) 0.9465(5) 1.0769(6) 0.031(3) Uani 1 1 d . U . . .
P2 P 0.9625(8) 0.4631(5) 0.7370(5) 0.025(2) Uani 1 1 d . U . . .
P6 P 0.3881(8) 1.1436(4) 0.8686(6) 0.023(2) Uani 1 1 d . U . . .
C1 C 1.131(3) 0.3388(15) 0.6657(17) 0.015(5) Uani 1 1 d . U . . .
C2 C 1.180(3) 0.3895(16) 0.6410(17) 0.013(4) Uani 1 1 d . U . . .
C3 C 1.169(3) 0.3174(16) 0.7292(18) 0.019(5) Uani 1 1 d . U . . .
C4 C 1.128(3) 0.3049(19) 0.8417(19) 0.030(9) Uani 1 1 d . U . . .
H1 H 1.1571 0.2670 0.8410 0.046 Uiso 1 1 calc R U . . .
H2 H 1.0655 0.3062 0.8698 0.046 Uiso 1 1 calc R U . . .
H3 H 1.1843 0.3304 0.8581 0.046 Uiso 1 1 calc R U . . .
C5 C 1.260(3) 0.4190(14) 0.6830(17) 0.015(5) Uani 1 1 d . U . . .
C53 C 0.310(3) 0.9597(16) 0.8624(19) 0.018(5) Uani 1 1 d . U . . .
C54 C 0.322(3) 1.0263(17) 0.764(2) 0.028(6) Uani 1 1 d . U . . .
C76 C 0.749(3) 0.8921(18) 0.9268(19) 0.023(5) Uani 1 1 d . U . . .
C52 C 0.356(3) 1.0054(15) 0.8334(19) 0.019(6) Uani 1 1 d . U . . .
C25 C 0.692(3) 0.3611(16) 0.6694(18) 0.018(5) Uani 1 1 d . U . . .
C58 C 0.231(3) 1.0008(18) 1.0018(19) 0.021(5) Uani 1 1 d . U . . .
C19 C 0.733(3) 0.4674(16) 0.5746(19) 0.022(6) Uani 1 1 d . U . . .
C81 C 0.859(3) 0.8919(18) 0.9602(18) 0.028(6) Uani 1 1 d . U . . .
H89 H 0.8976 0.9261 0.9616 0.034 Uiso 1 1 calc R U . . .
O1 O 1.261(2) 0.4242(11) 0.7428(12) 0.033(6) Uani 1 1 d . U . . .
C77 C 0.702(3) 0.8399(18) 0.928(2) 0.028(6) Uani 1 1 d . U . . .
H85 H 0.6309 0.8364 0.9091 0.033 Uiso 1 1 calc R U . . .
C83 C 0.552(4) 1.1200(19) 1.066(2) 0.034(6) Uani 1 1 d . U . . .
H90 H 0.4835 1.1116 1.0458 0.041 Uiso 1 1 calc R U . . .
C14 C 1.378(3) 0.3650(17) 0.5012(18) 0.023(6) Uani 1 1 d . U . . .
H12 H 1.4056 0.3947 0.5271 0.028 Uiso 1 1 calc R U . . .
C70 C 0.792(3) 0.9928(18) 0.8203(19) 0.025(5) Uani 1 1 d . U . . .
C56 C 0.229(3) 0.9182(15) 0.8215(19) 0.022(5) Uani 1 1 d . U . . .
C13 C 1.263(3) 0.3559(17) 0.4978(19) 0.020(5) Uani 1 1 d . U . . .
C45 C 0.962(3) 0.4947(17) 0.419(2) 0.029(9) Uani 1 1 d . U . . .
H43 H 0.9246 0.5088 0.3801 0.044 Uiso 1 1 calc R U . . .
H44 H 1.0397 0.5037 0.4179 0.044 Uiso 1 1 calc R U . . .
H45 H 0.9310 0.5118 0.4573 0.044 Uiso 1 1 calc R U . . .
C24 C 0.630(3) 0.4742(15) 0.5511(18) 0.023(6) Uani 1 1 d . U . . .
H21 H 0.5830 0.4433 0.5531 0.028 Uiso 1 1 calc R U . . .
C15 C 1.450(3) 0.3330(16) 0.4688(18) 0.026(6) Uani 1 1 d . U . . .
H13 H 1.5260 0.3409 0.4717 0.032 Uiso 1 1 calc R U . . .
C60 C 0.035(3) 1.0323(16) 1.0213(19) 0.029(6) Uani 1 1 d . U . . .
H71 H -0.0403 1.0272 1.0134 0.035 Uiso 1 1 calc R U . . .
C47 C 0.830(3) 0.491(2) 0.743(2) 0.036(9) Uani 1 1 d . U . . .
H49 H 0.8258 0.5127 0.7833 0.054 Uiso 1 1 calc R U . . .
H51 H 0.7765 0.4610 0.7437 0.054 Uiso 1 1 calc R U . . .
H50 H 0.8135 0.5156 0.7062 0.054 Uiso 1 1 calc R U . . .
C59 C 0.111(3) 0.9953(18) 0.9899(19) 0.026(6) Uani 1 1 d . U . . .
H70 H 0.0842 0.9672 0.9615 0.032 Uiso 1 1 calc R U . . .
C99 C 0.676(3) 0.861(2) 0.749(2) 0.029(9) Uani 1 1 d . U . . .
H117 H 0.6732 0.8344 0.7133 0.044 Uiso 1 1 calc R U . . .
H116 H 0.7116 0.8438 0.7870 0.044 Uiso 1 1 calc R U . . .
H115 H 0.7176 0.8939 0.7364 0.044 Uiso 1 1 calc R U . . .
C20 C 0.809(3) 0.5123(18) 0.573(2) 0.028(6) Uani 1 1 d . U . . .
H17 H 0.8821 0.5086 0.5883 0.034 Uiso 1 1 calc R U . . .
C82 C 0.648(3) 1.1121(15) 1.0286(18) 0.026(5) Uani 1 1 d . U . . .
C78 C 0.749(3) 0.791(2) 0.954(2) 0.036(6) Uani 1 1 d . U . . .
H86 H 0.7132 0.7564 0.9530 0.043 Uiso 1 1 calc R U . . .
C64 C 0.303(3) 0.8768(16) 0.9846(18) 0.024(5) Uani 1 1 d . U . . .
C94 C 0.565(4) 0.8676(18) 1.084(2) 0.039(10) Uani 1 1 d . U . . .
H102 H 0.5555 0.8563 1.1285 0.059 Uiso 1 1 calc R U . . .
H101 H 0.6372 0.8557 1.0701 0.059 Uiso 1 1 calc R U . . .
H100 H 0.5090 0.8502 1.0559 0.059 Uiso 1 1 calc R U . . .
C16 C 1.410(3) 0.2863(17) 0.4294(18) 0.025(6) Uani 1 1 d . U . . .
H14 H 1.4598 0.2625 0.4092 0.029 Uiso 1 1 calc R U . . .
C17 C 1.301(3) 0.2765(18) 0.4214(19) 0.027(6) Uani 1 1 d . U . . .
H15 H 1.2732 0.2483 0.3935 0.032 Uiso 1 1 calc R U . . .
C48 C 0.996(3) 0.4327(16) 0.8179(18) 0.030(8) Uani 1 1 d . U . . .
H52 H 0.9567 0.4527 0.8509 0.046 Uiso 1 1 calc R U . . .
H53 H 1.0747 0.4360 0.8272 0.046 Uiso 1 1 calc R U . . .
H54 H 0.9754 0.3934 0.8182 0.046 Uiso 1 1 calc R U . . .
C28 C 0.528(3) 0.3146(16) 0.7520(18) 0.027(6) Uani 1 1 d . U . . .
H24 H 0.4727 0.3025 0.7797 0.033 Uiso 1 1 calc R U . . .
C51 C 1.090(3) 0.1780(16) 0.7004(18) 0.023(8) Uani 1 1 d . U . . .
H61 H 1.1223 0.1408 0.6999 0.035 Uiso 1 1 calc R U . . .
H62 H 1.0175 0.1761 0.7180 0.035 Uiso 1 1 calc R U . . .
H63 H 1.1364 0.2025 0.7274 0.035 Uiso 1 1 calc R U . . .
C18 C 1.228(3) 0.3130(17) 0.459(2) 0.027(6) Uani 1 1 d . U . . .
H16 H 1.1522 0.3058 0.4564 0.033 Uiso 1 1 calc R U . . .
C29 C 0.632(3) 0.3258(15) 0.7757(18) 0.028(6) Uani 1 1 d . U . . .
H25 H 0.6514 0.3158 0.8188 0.034 Uiso 1 1 calc R U . . .
C26 C 0.586(3) 0.3438(14) 0.6426(18) 0.024(6) Uani 1 1 d . U . . .
H22 H 0.5702 0.3473 0.5977 0.029 Uiso 1 1 calc R U . . .
C30 C 0.709(3) 0.3521(14) 0.7369(17) 0.023(6) Uani 1 1 d . U . . .
H26 H 0.7752 0.3643 0.7568 0.028 Uiso 1 1 calc R U . . .
C46 C 1.049(3) 0.5272(16) 0.736(2) 0.036(9) Uani 1 1 d . U . . .
H47 H 1.0411 0.5451 0.6933 0.054 Uiso 1 1 calc R U . . .
H48 H 1.1256 0.5170 0.7438 0.054 Uiso 1 1 calc R U . . .
H46 H 1.0264 0.5529 0.7692 0.054 Uiso 1 1 calc R U . . .
C50 C 1.004(3) 0.1474(15) 0.5736(18) 0.026(8) Uani 1 1 d . U . . .
H58 H 1.0390 0.1117 0.5837 0.039 Uiso 1 1 calc R U . . .
H60 H 1.0059 0.1542 0.5270 0.039 Uiso 1 1 calc R U . . .
H59 H 0.9288 0.1467 0.5870 0.039 Uiso 1 1 calc R U . . .
C27 C 0.505(3) 0.3218(14) 0.6831(17) 0.024(6) Uani 1 1 d . U . . .
H23 H 0.4362 0.3117 0.6650 0.029 Uiso 1 1 calc R U . . .
C44 C 0.807(3) 0.4119(16) 0.3910(19) 0.035(9) Uani 1 1 d . U . . .
H42 H 0.7596 0.3997 0.4254 0.052 Uiso 1 1 calc R U . . .
H40 H 0.8050 0.3845 0.3561 0.052 Uiso 1 1 calc R U . . .
H41 H 0.7813 0.4478 0.3742 0.052 Uiso 1 1 calc R U . . .
O2 O 1.3414(18) 0.4419(10) 0.6480(12) 0.020(5) Uani 1 1 d . U . . .
O4 O 1.093(2) 0.3213(11) 0.7760(12) 0.021(5) Uani 1 1 d . U . . .
O3 O 1.259(2) 0.2915(11) 0.7402(13) 0.033(6) Uani 1 1 d . U . . .
C61 C 0.069(3) 1.0727(17) 1.0603(19) 0.029(6) Uani 1 1 d . U . . .
H72 H 0.0186 1.0957 1.0818 0.035 Uiso 1 1 calc R U . . .
C62 C 0.189(3) 1.0805(19) 1.069(2) 0.031(6) Uani 1 1 d . U . . .
H73 H 0.2143 1.1102 1.0953 0.037 Uiso 1 1 calc R U . . .
C65 C 0.232(3) 0.8643(17) 1.0373(18) 0.027(6) Uani 1 1 d . U . . .
H75 H 0.2021 0.8942 1.0607 0.033 Uiso 1 1 calc R U . . .
C63 C 0.265(3) 1.0477(18) 1.041(2) 0.029(6) Uani 1 1 d . U . . .
H74 H 0.3402 1.0557 1.0470 0.035 Uiso 1 1 calc R U . . .
C101 C 0.388(3) 1.1689(18) 0.785(2) 0.035(9) Uani 1 1 d . U . . .
H122 H 0.3516 1.2051 0.7827 0.052 Uiso 1 1 calc R U . . .
H123 H 0.3486 1.1425 0.7570 0.052 Uiso 1 1 calc R U . . .
H121 H 0.4628 1.1726 0.7714 0.052 Uiso 1 1 calc R U . . .
C96 C 0.447(3) 0.9607(19) 1.1392(19) 0.031(9) Uani 1 1 d . U . . .
H107 H 0.3749 0.9598 1.1183 0.046 Uiso 1 1 calc R U . . .
H106 H 0.4604 0.9974 1.1585 0.046 Uiso 1 1 calc R U . . .
H108 H 0.4523 0.9323 1.1730 0.046 Uiso 1 1 calc R U . . .
C79 C 0.859(3) 0.798(2) 0.985(2) 0.042(7) Uani 1 1 d . U . . .
H87 H 0.8946 0.7660 1.0017 0.050 Uiso 1 1 calc R U . . .
C98 C 0.464(3) 0.8124(17) 0.781(2) 0.044(10) Uani 1 1 d . U . . .
H114 H 0.3864 0.8173 0.7880 0.067 Uiso 1 1 calc R U . . .
H112 H 0.4983 0.7941 0.8189 0.067 Uiso 1 1 calc R U . . .
H113 H 0.4741 0.7895 0.7428 0.067 Uiso 1 1 calc R U . . .
C80 C 0.911(3) 0.8456(17) 0.990(2) 0.038(7) Uani 1 1 d . U . . .
H88 H 0.9798 0.8486 1.0122 0.045 Uiso 1 1 calc R U . . .
C100 C 0.240(3) 1.1389(16) 0.8837(19) 0.031(8) Uani 1 1 d . U . . .
H118 H 0.2047 1.1739 0.8711 0.046 Uiso 1 1 calc R U . . .
H119 H 0.2298 1.1319 0.9296 0.046 Uiso 1 1 calc R U . . .
H120 H 0.2082 1.1084 0.8581 0.046 Uiso 1 1 calc R U . . .
C75 C 0.905(3) 0.9912(16) 0.8281(19) 0.034(6) Uani 1 1 d . U . . .
H84 H 0.9366 0.9712 0.8634 0.041 Uiso 1 1 calc R U . . .
O8 O 0.1520(19) 0.8991(10) 0.8622(12) 0.023(5) Uani 1 1 d . U . . .
C33 C 0.964(4) 0.2161(19) 0.360(2) 0.037(7) Uani 1 1 d . U . . .
H33 H 1.0299 0.1999 0.3464 0.045 Uiso 1 1 calc R U . . .
C84 C 0.555(4) 1.140(2) 1.130(2) 0.044(7) Uani 1 1 d . U . . .
H91 H 0.4894 1.1452 1.1525 0.052 Uiso 1 1 calc R U . . .
C57 C 0.082(3) 0.8589(15) 0.8324(19) 0.030(8) Uani 1 1 d . U . . .
H68 H 0.1183 0.8419 0.7960 0.045 Uiso 1 1 calc R U . . .
H69 H 0.0147 0.8770 0.8167 0.045 Uiso 1 1 calc R U . . .
H67 H 0.0644 0.8302 0.8639 0.045 Uiso 1 1 calc R U . . .
C6 C 1.426(3) 0.4727(16) 0.6873(18) 0.033(9) Uani 1 1 d . U . . .
H5 H 1.4664 0.4971 0.6591 0.050 Uiso 1 1 calc R U . . .
H4 H 1.4753 0.4462 0.7086 0.050 Uiso 1 1 calc R U . . .
H6 H 1.3900 0.4951 0.7200 0.050 Uiso 1 1 calc R U . . .
C41 C 0.646(3) 0.1715(18) 0.666(2) 0.039(6) Uani 1 1 d . U . . .
H30 H 0.6557 0.1519 0.7055 0.047 Uiso 1 1 calc R U . . .
C66 C 0.206(3) 0.8111(14) 1.0547(18) 0.027(6) Uani 1 1 d . U . . .
H76 H 0.1596 0.8053 1.0896 0.032 Uiso 1 1 calc R U . . .
O7 O 0.239(3) 0.9067(13) 0.7668(14) 0.049(8) Uani 1 1 d . U . . .
C40 C 0.546(3) 0.1685(17) 0.629(2) 0.038(6) Uani 1 1 d . U . . .
H29 H 0.4885 0.1464 0.6442 0.045 Uiso 1 1 calc R U . . .
C38 C 0.619(3) 0.2279(15) 0.544(2) 0.036(6) Uani 1 1 d . U . . .
H27 H 0.6104 0.2448 0.5025 0.043 Uiso 1 1 calc R U . . .
C49 C 1.227(3) 0.2016(15) 0.5912(17) 0.027(8) Uani 1 1 d . U . . .
H57 H 1.2754 0.2189 0.6239 0.041 Uiso 1 1 calc R U . . .
H56 H 1.2331 0.2212 0.5501 0.041 Uiso 1 1 calc R U . . .
H55 H 1.2480 0.1626 0.5857 0.041 Uiso 1 1 calc R U . . .
C87 C 0.750(3) 1.1223(15) 1.0657(19) 0.034(6) Uani 1 1 d . U . . .
H94 H 0.8165 1.1169 1.0441 0.041 Uiso 1 1 calc R U . . .
C39 C 0.532(3) 0.1987(15) 0.5691(19) 0.037(6) Uani 1 1 d . U . . .
H28 H 0.4637 0.1987 0.5469 0.045 Uiso 1 1 calc R U . . .
C21 C 0.767(3) 0.5638(19) 0.546(2) 0.032(6) Uani 1 1 d . U . . .
H18 H 0.8140 0.5951 0.5455 0.039 Uiso 1 1 calc R U . . .
C32 C 0.949(4) 0.2328(18) 0.427(2) 0.032(6) Uani 1 1 d . U . . .
H32 H 1.0075 0.2273 0.4571 0.038 Uiso 1 1 calc R U . . .
C34 C 0.875(3) 0.2259(16) 0.319(2) 0.040(6) Uani 1 1 d . U . . .
H34 H 0.8829 0.2191 0.2746 0.047 Uiso 1 1 calc R U . . .
C85 C 0.653(3) 1.1513(17) 1.160(2) 0.045(7) Uani 1 1 d . U . . .
H92 H 0.6546 1.1675 1.2020 0.054 Uiso 1 1 calc R U . . .
C42 C 0.737(3) 0.2083(16) 0.639(2) 0.034(6) Uani 1 1 d . U . . .
H31 H 0.8027 0.2136 0.6634 0.041 Uiso 1 1 calc R U . . .
C37 C 0.725(3) 0.2331(16) 0.5800(19) 0.030(5) Uani 1 1 d . U . . .
C31 C 0.854(3) 0.2565(14) 0.4489(17) 0.024(5) Uani 1 1 d . U . . .
C22 C 0.664(3) 0.5697(17) 0.521(2) 0.032(6) Uani 1 1 d . U . . .
H19 H 0.6400 0.6037 0.5023 0.038 Uiso 1 1 calc R U . . .
C102 C 0.437(3) 1.2040(15) 0.9146(19) 0.032(8) Uani 1 1 d . U . . .
H124 H 0.5100 1.2142 0.9004 0.048 Uiso 1 1 calc R U . . .
H125 H 0.4412 1.1948 0.9607 0.048 Uiso 1 1 calc R U . . .
H126 H 0.3875 1.2352 0.9072 0.048 Uiso 1 1 calc R U . . .
O5 O 0.228(2) 1.0434(12) 0.7479(13) 0.035(7) Uani 1 1 d . U . . .
O6 O 0.405(2) 1.0228(12) 0.7214(13) 0.029(6) Uani 1 1 d . U . . .
Pt4 Pt 0.52358(12) 0.98135(6) 0.97567(8) 0.0153(4) Uani 1 1 d . U . . .
Pt5 Pt 0.50314(11) 0.95109(6) 0.84783(8) 0.0164(4) Uani 1 1 d . U . . .
C69 C 0.343(3) 0.8297(17) 0.9531(19) 0.032(6) Uani 1 1 d . U . . .
H79 H 0.3903 0.8362 0.9185 0.039 Uiso 1 1 calc R U . . .
C68 C 0.320(3) 0.7732(17) 0.9679(19) 0.035(6) Uani 1 1 d . U . . .
H78 H 0.3495 0.7433 0.9444 0.042 Uiso 1 1 calc R U . . .
C97 C 0.480(3) 0.9016(17) 0.687(2) 0.037(9) Uani 1 1 d . U . . .
H111 H 0.4868 0.8694 0.6588 0.056 Uiso 1 1 calc R U . . .
H110 H 0.5229 0.9325 0.6711 0.056 Uiso 1 1 calc R U . . .
H109 H 0.4034 0.9126 0.6887 0.056 Uiso 1 1 calc R U . . .
C67 C 0.248(3) 0.7642(17) 1.0218(18) 0.033(6) Uani 1 1 d . U . . .
H77 H 0.2299 0.7276 1.0346 0.039 Uiso 1 1 calc R U . . .
C71 C 0.740(3) 1.0187(16) 0.7660(19) 0.036(6) Uani 1 1 d . U . . .
H80 H 0.6637 1.0176 0.7585 0.043 Uiso 1 1 calc R U . . .
C72 C 0.814(3) 1.0479(18) 0.721(2) 0.046(7) Uani 1 1 d . U . . .
H81 H 0.7852 1.0678 0.6849 0.055 Uiso 1 1 calc R U . . .
C74 C 0.975(4) 1.0186(16) 0.785(2) 0.041(7) Uani 1 1 d . U . . .
H83 H 1.0514 1.0183 0.7913 0.050 Uiso 1 1 calc R U . . .
C55 C 0.370(3) 1.043(2) 0.657(2) 0.035(9) Uani 1 1 d . U . . .
H64 H 0.3155 1.0175 0.6384 0.052 Uiso 1 1 calc R U . . .
H66 H 0.4333 1.0440 0.6294 0.052 Uiso 1 1 calc R U . . .
H65 H 0.3394 1.0801 0.6608 0.052 Uiso 1 1 calc R U . . .
C73 C 0.926(4) 1.0455(19) 0.733(2) 0.046(7) Uani 1 1 d . U . . .
H82 H 0.9719 1.0638 0.7042 0.055 Uiso 1 1 calc R U . . .
C95 C 0.687(4) 0.9738(18) 1.113(2) 0.053(10) Uani 1 1 d . U . . .
H105 H 0.6841 1.0144 1.1143 0.080 Uiso 1 1 calc R U . . .
H103 H 0.7464 0.9620 1.0857 0.080 Uiso 1 1 calc R U . . .
H104 H 0.6981 0.9590 1.1563 0.080 Uiso 1 1 calc R U . . .
C93 C 0.717(3) 1.1663(15) 0.8450(18) 0.031(6) Uani 1 1 d . U . . .
H99 H 0.6425 1.1694 0.8329 0.037 Uiso 1 1 calc R U . . .
C88 C 0.755(3) 1.1246(16) 0.8944(18) 0.027(5) Uani 1 1 d . U . . .
C89 C 0.867(3) 1.1183(16) 0.9083(19) 0.034(6) Uani 1 1 d . U . . .
H95 H 0.8950 1.0907 0.9369 0.041 Uiso 1 1 calc R U . . .
C23 C 0.590(3) 0.5214(15) 0.5249(18) 0.029(6) Uani 1 1 d . U . . .
H20 H 0.5163 0.5236 0.5094 0.034 Uiso 1 1 calc R U . . .
C8 C 1.153(3) 0.5229(16) 0.5707(19) 0.030(6) Uani 1 1 d . U . . .
H7 H 1.1107 0.5116 0.6059 0.037 Uiso 1 1 calc R U . . .
C7 C 1.196(3) 0.4814(17) 0.5291(18) 0.024(5) Uani 1 1 d . U . . .
C12 C 1.261(3) 0.4999(16) 0.4791(18) 0.027(6) Uani 1 1 d . U . . .
H11 H 1.2917 0.4745 0.4499 0.033 Uiso 1 1 calc R U . . .
C36 C 0.767(3) 0.2636(16) 0.3993(18) 0.035(6) Uani 1 1 d . U . . .
H36 H 0.7021 0.2820 0.4097 0.042 Uiso 1 1 calc R U . . .
C35 C 0.780(3) 0.2443(16) 0.339(2) 0.041(6) Uani 1 1 d . U . . .
H35 H 0.7188 0.2439 0.3094 0.049 Uiso 1 1 calc R U . . .
C86 C 0.758(3) 1.1394(16) 1.130(2) 0.043(6) Uani 1 1 d . U . . .
H93 H 0.8258 1.1432 1.1527 0.052 Uiso 1 1 calc R U . . .
C92 C 0.791(3) 1.1991(16) 0.8182(19) 0.034(6) Uani 1 1 d . U . . .
H98 H 0.7669 1.2255 0.7867 0.040 Uiso 1 1 calc R U . . .
C91 C 0.900(3) 1.1957(17) 0.835(2) 0.035(6) Uani 1 1 d . U . . .
H97 H 0.9478 1.2217 0.8169 0.042 Uiso 1 1 calc R U . . .
C90 C 0.939(3) 1.1591(16) 0.874(2) 0.035(6) Uani 1 1 d . U . . .
H96 H 1.0157 1.1574 0.8816 0.042 Uiso 1 1 calc R U . . .
C11 C 1.280(3) 0.5606(16) 0.4736(19) 0.031(6) Uani 1 1 d . U . . .
H10 H 1.3235 0.5741 0.4401 0.037 Uiso 1 1 calc R U . . .
C10 C 1.236(3) 0.5972(17) 0.515(2) 0.038(6) Uani 1 1 d . U . . .
H9 H 1.2509 0.6357 0.5114 0.046 Uiso 1 1 calc R U . . .
C9 C 1.171(3) 0.5783(17) 0.561(2) 0.039(6) Uani 1 1 d . U . . .
H8 H 1.1369 0.6043 0.5883 0.047 Uiso 1 1 calc R U . . .
C43 C 1.024(3) 0.392(2) 0.355(2) 0.041(9) Uani 1 1 d . U . . .
H37 H 0.9911 0.4053 0.3143 0.061 Uiso 1 1 calc R U . . .
H39 H 1.0240 0.3516 0.3560 0.061 Uiso 1 1 calc R U . . .
H38 H 1.0993 0.4057 0.3593 0.061 Uiso 1 1 calc R U . . .
C105 C 0.604(5) 0.665(3) 0.706(3) 0.090(10) Uani 1 1 d . U . . .
H133 H 0.5533 0.6833 0.7355 0.108 Uiso 1 1 calc R U . . .
H132 H 0.6102 0.6887 0.6668 0.108 Uiso 1 1 calc R U . . .
C103 C 0.453(5) 0.625(2) 0.650(3) 0.096(14) Uani 1 1 d . U . . .
H128 H 0.3932 0.6261 0.6800 0.145 Uiso 1 1 calc R U . . .
H129 H 0.4392 0.5958 0.6179 0.145 Uiso 1 1 calc R U . . .
H127 H 0.4566 0.6611 0.6275 0.145 Uiso 1 1 calc R U . . .
C106 C 0.733(5) 0.654(2) 0.744(3) 0.086(10) Uani 1 1 d . U . . .
H135 H 0.7249 0.6252 0.7782 0.103 Uiso 1 1 calc R U . . .
H134 H 0.7826 0.6385 0.7120 0.103 Uiso 1 1 calc R U . . .
C107 C 0.790(5) 0.711(3) 0.778(3) 0.086(10) Uani 1 1 d . U . . .
H137 H 0.7402 0.7267 0.8098 0.103 Uiso 1 1 calc R U . . .
H136 H 0.7991 0.7396 0.7438 0.103 Uiso 1 1 calc R U . . .
C104 C 0.569(5) 0.613(2) 0.690(3) 0.088(10) Uani 1 1 d . U . . .
H131 H 0.5574 0.5905 0.7286 0.106 Uiso 1 1 calc R U . . .
H130 H 0.6213 0.5942 0.6620 0.106 Uiso 1 1 calc R U . . .
C108 C 0.916(5) 0.700(3) 0.816(3) 0.103(15) Uani 1 1 d . U . . .
H139 H 0.9055 0.6815 0.8579 0.154 Uiso 1 1 calc R U . . .
H140 H 0.9536 0.7351 0.8231 0.154 Uiso 1 1 calc R U . . .
H138 H 0.9598 0.6755 0.7892 0.154 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.222(11) . ?
Pt1 Ge1 2.356(4) . ?
Pt1 Pt2 2.706(2) . ?
Pt1 Pt3 2.717(2) . ?
Pt1 Ge2 2.799(4) . ?
Pt1 Ge3 2.895(4) . ?
Pt2 P2 2.245(11) . ?
Pt2 C1 2.30(3) . ?
Pt2 Ge2 2.393(4) . ?
Pt2 C2 2.39(3) . ?
Pt2 Pt3 2.700(2) . ?
Pt2 Ge1 3.088(4) . ?
Pt3 C1 2.06(4) . ?
Pt3 P3 2.275(10) . ?
Pt3 Ge3 2.419(4) . ?
Pt6 C52 2.09(4) . ?
Pt6 P6 2.215(10) . ?
Pt6 Ge6 2.401(4) . ?
Pt6 Pt4 2.698(2) . ?
Pt6 Pt5 2.699(2) . ?
Ge4 C58 1.92(4) . ?
Ge4 C64 1.95(4) . ?
Ge4 C53 1.97(4) . ?
Ge4 Pt4 2.361(4) . ?
Ge4 Pt5 3.063(4) . ?
Ge1 C7 1.91(4) . ?
Ge1 C13 1.99(4) . ?
Ge1 C2 2.00(3) . ?
Ge5 C76 1.91(4) . ?
Ge5 C70 1.99(4) . ?
Ge5 Pt5 2.391(4) . ?
Ge5 Pt4 2.813(4) . ?
Ge2 C25 1.93(4) . ?
Ge2 C19 2.02(4) . ?
Ge3 C37 1.96(4) . ?
Ge3 C31 1.99(4) . ?
Ge6 C82 1.92(4) . ?
Ge6 C88 1.97(4) . ?
Ge6 Pt4 2.868(4) . ?
P5 C97 1.81(4) . ?
P5 C98 1.87(4) . ?
P5 C99 1.89(4) . ?
P5 Pt5 2.292(12) . ?
P1 C44 1.78(4) . ?
P1 C45 1.80(4) . ?
P1 C43 1.82(4) . ?
P3 C51 1.79(4) . ?
P3 C49 1.86(3) . ?
P3 C50 1.87(3) . ?
P4 C95 1.85(4) . ?
P4 C96 1.86(4) . ?
P4 C94 1.87(4) . ?
P4 Pt4 2.233(12) . ?
P2 C47 1.74(4) . ?
P2 C48 1.83(4) . ?
P2 C46 1.84(4) . ?
P6 C102 1.79(4) . ?
P6 C101 1.80(4) . ?
P6 C100 1.82(4) . ?
C1 C2 1.43(5) . ?
C1 C3 1.44(5) . ?
C2 C5 1.44(5) . ?
C3 O3 1.26(4) . ?
C3 O4 1.34(4) . ?
C4 O4 1.44(4) . ?
C5 O1 1.22(4) . ?
C5 O2 1.34(4) . ?
C53 C52 1.36(5) . ?
C53 C56 1.59(5) . ?
C53 Pt5 2.37(3) . ?
C54 O5 1.24(4) . ?
C54 O6 1.35(4) . ?
C54 C52 1.54(5) . ?
C76 C77 1.36(6) . ?
C76 C81 1.47(5) . ?
C52 Pt5 2.20(4) . ?
C25 C30 1.40(5) . ?
C25 C26 1.43(5) . ?
C58 C63 1.41(6) . ?
C58 C59 1.46(5) . ?
C19 C24 1.32(5) . ?
C19 C20 1.40(5) . ?
C81 C80 1.39(5) . ?
C77 C78 1.38(6) . ?
C83 C84 1.39(6) . ?
C83 C82 1.42(6) . ?
C14 C15 1.34(5) . ?
C14 C13 1.40(5) . ?
C70 C75 1.37(5) . ?
C70 C71 1.39(5) . ?
C56 O7 1.15(4) . ?
C56 O8 1.34(4) . ?
C13 C18 1.34(5) . ?
C24 C23 1.32(5) . ?
C15 C16 1.44(5) . ?
C60 C61 1.29(5) . ?
C60 C59 1.43(5) . ?
C20 C21 1.42(6) . ?
C82 C87 1.44(5) . ?
C78 C79 1.45(6) . ?
C64 C69 1.38(5) . ?
C64 C65 1.42(5) . ?
C16 C17 1.33(5) . ?
C17 C18 1.47(6) . ?
C28 C29 1.35(5) . ?
C28 C27 1.43(5) . ?
C29 C30 1.39(5) . ?
C26 C27 1.39(5) . ?
O2 C6 1.46(4) . ?
C61 C62 1.47(5) . ?
C62 C63 1.34(5) . ?
C65 C66 1.34(5) . ?
C79 C80 1.28(5) . ?
C75 C74 1.40(5) . ?
O8 C57 1.40(4) . ?
C33 C34 1.36(6) . ?
C33 C32 1.42(6) . ?
C84 C85 1.34(6) . ?
C41 C40 1.39(6) . ?
C41 C42 1.52(5) . ?
C66 C67 1.40(5) . ?
C40 C39 1.42(5) . ?
C38 C39 1.37(5) . ?
C38 C37 1.46(5) . ?
C87 C86 1.36(5) . ?
C21 C22 1.33(5) . ?
C32 C31 1.37(5) . ?
C34 C35 1.30(5) . ?
C85 C86 1.45(5) . ?
C42 C37 1.33(5) . ?
C31 C36 1.43(5) . ?
C22 C23 1.45(5) . ?
O6 C55 1.44(5) . ?
Pt4 Pt5 2.696(2) . ?
C69 C68 1.40(5) . ?
C68 C67 1.43(5) . ?
C71 C72 1.47(5) . ?
C72 C73 1.37(6) . ?
C74 C73 1.34(6) . ?
C93 C92 1.31(5) . ?
C93 C88 1.46(5) . ?
C88 C89 1.38(5) . ?
C89 C90 1.49(5) . ?
C8 C9 1.34(5) . ?
C8 C7 1.40(5) . ?
C7 C12 1.37(5) . ?
C12 C11 1.46(5) . ?
C36 C35 1.32(5) . ?
C92 C91 1.35(5) . ?
C91 C90 1.25(5) . ?
C11 C10 1.33(5) . ?
C10 C9 1.32(5) . ?
C105 C104 1.33(7) . ?
C105 C106 1.74(8) . ?
C103 C104 1.62(7) . ?
C106 C107 1.66(6) . ?
C107 C108 1.70(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 Ge1 99.7(3) . . ?
P1 Pt1 Pt2 146.4(3) . . ?
Ge1 Pt1 Pt2 74.84(11) . . ?
P1 Pt1 Pt3 153.7(3) . . ?
Ge1 Pt1 Pt3 82.79(11) . . ?
Pt2 Pt1 Pt3 59.71(6) . . ?
P1 Pt1 Ge2 118.2(3) . . ?
Ge1 Pt1 Ge2 125.27(14) . . ?
Pt2 Pt1 Ge2 51.49(9) . . ?
Pt3 Pt1 Ge2 79.33(10) . . ?
P1 Pt1 Ge3 114.8(3) . . ?
Ge1 Pt1 Ge3 130.93(14) . . ?
Pt2 Pt1 Ge3 91.54(10) . . ?
Pt3 Pt1 Ge3 50.93(9) . . ?
Ge2 Pt1 Ge3 67.47(13) . . ?
P2 Pt2 C1 116.9(9) . . ?
P2 Pt2 Ge2 100.0(3) . . ?
C1 Pt2 Ge2 134.7(9) . . ?
P2 Pt2 C2 107.6(9) . . ?
C1 Pt2 C2 35.5(12) . . ?
Ge2 Pt2 C2 150.6(8) . . ?
P2 Pt2 Pt3 151.7(3) . . ?
C1 Pt2 Pt3 47.9(9) . . ?
Ge2 Pt2 Pt3 87.30(12) . . ?
C2 Pt2 Pt3 73.1(9) . . ?
P2 Pt2 Pt1 147.3(3) . . ?
C1 Pt2 Pt1 91.0(9) . . ?
Ge2 Pt2 Pt1 66.28(11) . . ?
C2 Pt2 Pt1 84.8(8) . . ?
Pt3 Pt2 Pt1 60.36(5) . . ?
P2 Pt2 Ge1 128.6(3) . . ?
C1 Pt2 Ge1 63.8(9) . . ?
Ge2 Pt2 Ge1 112.86(13) . . ?
C2 Pt2 Ge1 40.3(8) . . ?
Pt3 Pt2 Ge1 70.75(9) . . ?
Pt1 Pt2 Ge1 47.42(8) . . ?
C1 Pt3 P3 100.7(10) . . ?
C1 Pt3 Ge3 159.1(10) . . ?
P3 Pt3 Ge3 99.8(3) . . ?
C1 Pt3 Pt2 56.0(10) . . ?
P3 Pt3 Pt2 152.3(3) . . ?
Ge3 Pt3 Pt2 103.24(11) . . ?
C1 Pt3 Pt1 96.3(9) . . ?
P3 Pt3 Pt1 145.1(3) . . ?
Ge3 Pt3 Pt1 68.35(11) . . ?
Pt2 Pt3 Pt1 59.93(6) . . ?
C52 Pt6 P6 102.5(10) . . ?
C52 Pt6 Ge6 154.3(10) . . ?
P6 Pt6 Ge6 102.7(3) . . ?
C52 Pt6 Pt4 93.7(10) . . ?
P6 Pt6 Pt4 143.6(3) . . ?
Ge6 Pt6 Pt4 68.15(11) . . ?
C52 Pt6 Pt5 52.9(10) . . ?
P6 Pt6 Pt5 152.2(3) . . ?
Ge6 Pt6 Pt5 101.47(11) . . ?
Pt4 Pt6 Pt5 59.93(6) . . ?
C58 Ge4 C64 105.4(16) . . ?
C58 Ge4 C53 109.4(16) . . ?
C64 Ge4 C53 107.6(16) . . ?
C58 Ge4 Pt4 115.0(12) . . ?
C64 Ge4 Pt4 114.5(11) . . ?
C53 Ge4 Pt4 104.7(10) . . ?
C58 Ge4 Pt5 144.5(12) . . ?
C64 Ge4 Pt5 108.8(11) . . ?
C53 Ge4 Pt5 50.6(10) . . ?
Pt4 Ge4 Pt5 57.88(10) . . ?
C7 Ge1 C13 107.4(16) . . ?
C7 Ge1 C2 107.5(15) . . ?
C13 Ge1 C2 107.2(15) . . ?
C7 Ge1 Pt1 115.3(11) . . ?
C13 Ge1 Pt1 114.5(11) . . ?
C2 Ge1 Pt1 104.4(9) . . ?
C7 Ge1 Pt2 108.4(11) . . ?
C13 Ge1 Pt2 142.5(11) . . ?
C2 Ge1 Pt2 50.8(9) . . ?
Pt1 Ge1 Pt2 57.74(10) . . ?
C76 Ge5 C70 113.8(16) . . ?
C76 Ge5 Pt5 113.4(12) . . ?
C70 Ge5 Pt5 113.6(11) . . ?
C76 Ge5 Pt4 97.6(11) . . ?
C70 Ge5 Pt4 145.6(12) . . ?
Pt5 Ge5 Pt4 61.78(10) . . ?
C25 Ge2 C19 108.9(15) . . ?
C25 Ge2 Pt2 116.4(10) . . ?
C19 Ge2 Pt2 115.4(11) . . ?
C25 Ge2 Pt1 149.1(11) . . ?
C19 Ge2 Pt1 97.8(11) . . ?
Pt2 Ge2 Pt1 62.24(10) . . ?
C37 Ge3 C31 106.7(15) . . ?
C37 Ge3 Pt3 120.6(12) . . ?
C31 Ge3 Pt3 120.5(11) . . ?
C37 Ge3 Pt1 153.3(11) . . ?
C31 Ge3 Pt1 92.0(10) . . ?
Pt3 Ge3 Pt1 60.72(10) . . ?
C82 Ge6 C88 103.8(16) . . ?
C82 Ge6 Pt6 123.6(11) . . ?
C88 Ge6 Pt6 120.2(11) . . ?
C82 Ge6 Pt4 94.6(11) . . ?
C88 Ge6 Pt4 153.3(11) . . ?
Pt6 Ge6 Pt4 60.86(10) . . ?
C97 P5 C98 101.7(19) . . ?
C97 P5 C99 98.7(19) . . ?
C98 P5 C99 101(2) . . ?
C97 P5 Pt5 114.9(14) . . ?
C98 P5 Pt5 117.7(14) . . ?
C99 P5 Pt5 119.9(14) . . ?
C44 P1 C45 100.4(18) . . ?
C44 P1 C43 101.3(19) . . ?
C45 P1 C43 104(2) . . ?
C44 P1 Pt1 112.6(14) . . ?
C45 P1 Pt1 115.3(14) . . ?
C43 P1 Pt1 120.2(16) . . ?
C51 P3 C49 103.1(17) . . ?
C51 P3 C50 101.9(17) . . ?
C49 P3 C50 106.2(17) . . ?
C51 P3 Pt3 115.5(13) . . ?
C49 P3 Pt3 110.4(12) . . ?
C50 P3 Pt3 118.3(12) . . ?
C95 P4 C96 106(2) . . ?
C95 P4 C94 105(2) . . ?
C96 P4 C94 100(2) . . ?
C95 P4 Pt4 110.2(15) . . ?
C96 P4 Pt4 117.7(14) . . ?
C94 P4 Pt4 116.3(15) . . ?
C47 P2 C48 105(2) . . ?
C47 P2 C46 102(2) . . ?
C48 P2 C46 103.1(18) . . ?
C47 P2 Pt2 115.8(15) . . ?
C48 P2 Pt2 112.9(13) . . ?
C46 P2 Pt2 116.1(14) . . ?
C102 P6 C101 102.5(19) . . ?
C102 P6 C100 105.7(18) . . ?
C101 P6 C100 101.9(19) . . ?
C102 P6 Pt6 120.5(14) . . ?
C101 P6 Pt6 114.5(15) . . ?
C100 P6 Pt6 109.8(13) . . ?
C2 C1 C3 119(3) . . ?
C2 C1 Pt3 120(3) . . ?
C3 C1 Pt3 121(2) . . ?
C2 C1 Pt2 75.7(19) . . ?
C3 C1 Pt2 122(2) . . ?
Pt3 C1 Pt2 76.2(11) . . ?
C1 C2 C5 118(3) . . ?
C1 C2 Ge1 116(3) . . ?
C5 C2 Ge1 124(2) . . ?
C1 C2 Pt2 68.9(18) . . ?
C5 C2 Pt2 121(2) . . ?
Ge1 C2 Pt2 88.9(12) . . ?
O3 C3 O4 121(3) . . ?
O3 C3 C1 125(3) . . ?
O4 C3 C1 114(3) . . ?
O1 C5 O2 121(3) . . ?
O1 C5 C2 128(3) . . ?
O2 C5 C2 111(3) . . ?
C52 C53 C56 121(3) . . ?
C52 C53 Ge4 115(3) . . ?
C56 C53 Ge4 124(2) . . ?
C52 C53 Pt5 66(2) . . ?
C56 C53 Pt5 118(2) . . ?
Ge4 C53 Pt5 89.5(13) . . ?
O5 C54 O6 123(4) . . ?
O5 C54 C52 124(3) . . ?
O6 C54 C52 113(3) . . ?
C77 C76 C81 111(4) . . ?
C77 C76 Ge5 128(3) . . ?
C81 C76 Ge5 120(3) . . ?
C53 C52 C54 123(3) . . ?
C53 C52 Pt6 123(3) . . ?
C54 C52 Pt6 114(2) . . ?
C53 C52 Pt5 80(2) . . ?
C54 C52 Pt5 120(3) . . ?
Pt6 C52 Pt5 78.0(12) . . ?
C30 C25 C26 115(3) . . ?
C30 C25 Ge2 125(3) . . ?
C26 C25 Ge2 119(3) . . ?
C63 C58 C59 116(4) . . ?
C63 C58 Ge4 121(3) . . ?
C59 C58 Ge4 123(3) . . ?
C24 C19 C20 120(4) . . ?
C24 C19 Ge2 126(3) . . ?
C20 C19 Ge2 114(3) . . ?
C80 C81 C76 126(4) . . ?
C76 C77 C78 126(4) . . ?
C84 C83 C82 123(4) . . ?
C15 C14 C13 123(4) . . ?
C75 C70 C71 121(4) . . ?
C75 C70 Ge5 122(3) . . ?
C71 C70 Ge5 116(3) . . ?
O7 C56 O8 128(4) . . ?
O7 C56 C53 124(3) . . ?
O8 C56 C53 108(3) . . ?
C18 C13 C14 116(4) . . ?
C18 C13 Ge1 121(3) . . ?
C14 C13 Ge1 123(3) . . ?
C23 C24 C19 125(4) . . ?
C14 C15 C16 119(3) . . ?
C61 C60 C59 122(4) . . ?
C60 C59 C58 121(4) . . ?
C19 C20 C21 116(4) . . ?
C83 C82 C87 114(3) . . ?
C83 C82 Ge6 121(3) . . ?
C87 C82 Ge6 125(3) . . ?
C77 C78 C79 116(4) . . ?
C69 C64 C65 114(3) . . ?
C69 C64 Ge4 123(3) . . ?
C65 C64 Ge4 122(3) . . ?
C17 C16 C15 121(4) . . ?
C16 C17 C18 116(4) . . ?
C29 C28 C27 118(3) . . ?
C13 C18 C17 125(4) . . ?
C28 C29 C30 121(4) . . ?
C27 C26 C25 121(3) . . ?
C29 C30 C25 123(3) . . ?
C26 C27 C28 121(3) . . ?
C5 O2 C6 115(3) . . ?
C3 O4 C4 117(3) . . ?
C60 C61 C62 117(4) . . ?
C63 C62 C61 125(4) . . ?
C66 C65 C64 123(4) . . ?
C62 C63 C58 120(4) . . ?
C80 C79 C78 125(4) . . ?
C79 C80 C81 116(4) . . ?
C70 C75 C74 122(4) . . ?
C56 O8 C57 112(3) . . ?
C34 C33 C32 114(4) . . ?
C85 C84 C83 119(4) . . ?
C40 C41 C42 117(4) . . ?
C65 C66 C67 122(3) . . ?
C41 C40 C39 121(4) . . ?
C39 C38 C37 121(4) . . ?
C86 C87 C82 125(4) . . ?
C38 C39 C40 120(4) . . ?
C22 C21 C20 123(4) . . ?
C31 C32 C33 124(4) . . ?
C35 C34 C33 124(4) . . ?
C84 C85 C86 123(4) . . ?
C37 C42 C41 121(4) . . ?
C42 C37 C38 119(4) . . ?
C42 C37 Ge3 121(3) . . ?
C38 C37 Ge3 120(3) . . ?
C32 C31 C36 114(3) . . ?
C32 C31 Ge3 119(3) . . ?
C36 C31 Ge3 127(3) . . ?
C21 C22 C23 118(4) . . ?
C54 O6 C55 111(3) . . ?
P4 Pt4 Ge4 99.5(3) . . ?
P4 Pt4 Pt5 142.8(3) . . ?
Ge4 Pt4 Pt5 74.23(12) . . ?
P4 Pt4 Pt6 156.8(3) . . ?
Ge4 Pt4 Pt6 81.96(12) . . ?
Pt5 Pt4 Pt6 60.04(6) . . ?
P4 Pt4 Ge5 115.3(3) . . ?
Ge4 Pt4 Ge5 124.13(15) . . ?
Pt5 Pt4 Ge5 51.39(9) . . ?
Pt6 Pt4 Ge5 81.46(10) . . ?
P4 Pt4 Ge6 118.2(3) . . ?
Ge4 Pt4 Ge6 130.92(15) . . ?
Pt5 Pt4 Ge6 90.48(10) . . ?
Pt6 Pt4 Ge6 50.99(9) . . ?
Ge5 Pt4 Ge6 68.04(13) . . ?
C52 Pt5 P5 116.6(10) . . ?
C52 Pt5 C53 34.3(13) . . ?
P5 Pt5 C53 108.1(10) . . ?
C52 Pt5 Ge5 138.6(10) . . ?
P5 Pt5 Ge5 97.5(3) . . ?
C53 Pt5 Ge5 151.9(9) . . ?
C52 Pt5 Pt4 91.2(10) . . ?
P5 Pt5 Pt4 147.6(3) . . ?
C53 Pt5 Pt4 85.2(9) . . ?
Ge5 Pt5 Pt4 66.83(11) . . ?
C52 Pt5 Pt6 49.1(10) . . ?
P5 Pt5 Pt6 151.5(3) . . ?
C53 Pt5 Pt6 73.5(9) . . ?
Ge5 Pt5 Pt6 89.74(12) . . ?
Pt4 Pt5 Pt6 60.03(6) . . ?
C52 Pt5 Ge4 62.4(10) . . ?
P5 Pt5 Ge4 129.7(3) . . ?
C53 Pt5 Ge4 39.9(9) . . ?
Ge5 Pt5 Ge4 113.51(14) . . ?
Pt4 Pt5 Ge4 47.89(9) . . ?
Pt6 Pt5 Ge4 70.23(10) . . ?
C64 C69 C68 126(4) . . ?
C69 C68 C67 116(4) . . ?
C66 C67 C68 119(4) . . ?
C70 C71 C72 116(4) . . ?
C73 C72 C71 119(4) . . ?
C73 C74 C75 117(4) . . ?
C74 C73 C72 125(4) . . ?
C92 C93 C88 119(4) . . ?
C89 C88 C93 119(3) . . ?
C89 C88 Ge6 124(3) . . ?
C93 C88 Ge6 117(3) . . ?
C88 C89 C90 115(4) . . ?
C24 C23 C22 117(4) . . ?
C9 C8 C7 122(4) . . ?
C12 C7 C8 117(4) . . ?
C12 C7 Ge1 125(3) . . ?
C8 C7 Ge1 118(3) . . ?
C7 C12 C11 118(4) . . ?
C35 C36 C31 121(4) . . ?
C34 C35 C36 121(4) . . ?
C87 C86 C85 116(4) . . ?
C93 C92 C91 122(4) . . ?
C90 C91 C92 123(4) . . ?
C91 C90 C89 122(4) . . ?
C10 C11 C12 122(4) . . ?
C9 C10 C11 119(4) . . ?
C10 C9 C8 122(4) . . ?
C104 C105 C106 104(5) . . ?
C107 C106 C105 114(4) . . ?
C106 C107 C108 114(4) . . ?
C105 C104 C103 103(5) . . ?

_refine_diff_density_max         9.119
_refine_diff_density_min         -1.466
_refine_diff_density_rms         0.278

_shelxl_version_number           2013-2
_database_code_depnum_ccdc_archive 'CCDC 979333'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_complex5

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C53 H65 Ge3 O4 P3 Pt3'
_chemical_formula_weight         1662.00

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   21.046(6)
_cell_length_b                   12.804(4)
_cell_length_c                   20.027(5)
_cell_angle_alpha                90
_cell_angle_beta                 93.534(3)
_cell_angle_gamma                90
_cell_volume                     5387(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    90(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.049
_exptl_crystal_F_000             3160
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_exptl_absorpt_coefficient_mu    9.546
_shelx_estimated_absorpt_T_min   0.269
_shelx_estimated_absorpt_T_max   0.469
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.269
_exptl_absorpt_correction_T_max  0.469
_exptl_absorpt_process_details   ?

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      90(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            25119
_diffrn_reflns_av_unetI/netI     0.3067
_diffrn_reflns_av_R_equivalents  0.4150
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         1.863
_diffrn_reflns_theta_max         25.027
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measured_fraction_theta_full 0.975
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_Laue_measured_fraction_full 0.975
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_point_group_measured_fraction_full 0.975
_reflns_number_total             9504
_reflns_number_gt                7065
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0883P)²]
 where P=(Fo²+2Fc²)/3
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9504
_refine_ls_number_parameters     608
_refine_ls_number_restraints     982
_refine_ls_R_factor_all          0.1060
_refine_ls_R_factor_gt           0.0921
_refine_ls_wR_factor_ref         0.2617
_refine_ls_wR_factor_gt          0.2482
_refine_ls_goodness_of_fit_ref   0.981
_refine_ls_restrained_S_all      0.993
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.18805(3) 0.49200(5) 0.18637(3) 0.0128(2) Uani 1 1 d . U . . .
Pt3 Pt 0.30222(3) 0.42198(5) 0.13520(3) 0.0137(2) Uani 1 1 d . U . . .
Pt2 Pt 0.28513(3) 0.62656(5) 0.16001(3) 0.0142(2) Uani 1 1 d . U . . .
Ge2 Ge 0.28336(8) 0.60944(15) 0.27770(9) 0.0159(4) Uani 1 1 d . U . . .
Ge1 Ge 0.17775(8) 0.54892(14) 0.07109(8) 0.0141(4) Uani 1 1 d . U . . .
Ge3 Ge 0.26919(8) 0.30940(14) 0.22168(8) 0.0153(4) Uani 1 1 d . U . . .
P1 P 0.0822(2) 0.4728(4) 0.1978(2) 0.0169(8) Uani 1 1 d . U . . .
P2 P 0.3183(2) 0.7926(4) 0.1584(2) 0.0216(9) Uani 1 1 d . U . . .
P3 P 0.3669(2) 0.3005(4) 0.0967(2) 0.0218(9) Uani 1 1 d . U . . .
O4 O 0.2229(5) 0.5347(10) 0.4184(6) 0.0183(9) Uani 1 1 d . U . . .
O2 O 0.3745(5) 0.6009(10) -0.0189(6) 0.0182(10) Uani 1 1 d . U . . .
O3 O 0.1282(6) 0.5236(10) 0.3626(6) 0.0194(12) Uani 1 1 d . U . . .
O1 O 0.4282(6) 0.5694(10) 0.0778(6) 0.0202(13) Uani 1 1 d . U . . .
C1 C 0.3149(8) 0.5461(14) 0.0703(8) 0.0165(8) Uani 1 1 d . U . . .
C15 C 0.1205(8) 0.6688(14) 0.0584(8) 0.0154(6) Uani 1 1 d . U . . .
C33 C 0.3325(8) 0.2349(14) 0.2782(8) 0.0170(6) Uani 1 1 d . U . . .
C9 C 0.1555(8) 0.4416(14) 0.0007(8) 0.0159(6) Uani 1 1 d . U . . .
C3 C 0.3788(8) 0.5742(14) 0.0464(8) 0.0177(9) Uani 1 1 d . U . . .
C40 C 0.1733(7) 0.2225(14) 0.1250(8) 0.0171(8) Uani 1 1 d . U . . .
H34 H 0.1899 0.2721 0.0971 0.021 Uiso 1 1 calc R U . . .
C5 C 0.2268(8) 0.4950(14) 0.3038(8) 0.0169(6) Uani 1 1 d . U . . .
C44 C 0.1759(8) 0.1364(14) 0.2336(8) 0.0171(8) Uani 1 1 d . U . . .
H38 H 0.1931 0.1287 0.2772 0.021 Uiso 1 1 calc R U . . .
C7 C 0.1857(8) 0.5198(14) 0.3628(8) 0.0177(8) Uani 1 1 d . U . . .
C22 C 0.2743(8) 0.8031(14) 0.3566(8) 0.0171(8) Uani 1 1 d . U . . .
H19 H 0.3163 0.7907 0.3717 0.021 Uiso 1 1 calc R U . . .
C39 C 0.2018(8) 0.2083(14) 0.1901(8) 0.0166(6) Uani 1 1 d . U . . .
C20 C 0.1123(8) 0.7372(13) 0.1063(8) 0.0159(8) Uani 1 1 d . U . . .
H18 H 0.1337 0.7261 0.1477 0.019 Uiso 1 1 calc R U . . .
C27 C 0.3677(8) 0.5862(14) 0.3222(8) 0.0174(6) Uani 1 1 d . U . . .
C26 C 0.1798(8) 0.7507(14) 0.2983(8) 0.0172(8) Uani 1 1 d . U . . .
H23 H 0.1572 0.7012 0.2725 0.021 Uiso 1 1 calc R U . . .
C2 C 0.2594(8) 0.6056(14) 0.0470(8) 0.0154(6) Uani 1 1 d . U . . .
H1 H 0.2621 0.6634 0.0152 0.018 Uiso 1 1 calc R U . . .
C6 C 0.2192(8) 0.3951(14) 0.2844(8) 0.0170(8) Uani 1 1 d . U . . .
H5 H 0.1858 0.3601 0.3029 0.020 Uiso 1 1 calc R U . . .
C11 C 0.1938(8) 0.2991(14) -0.0662(8) 0.0172(9) Uani 1 1 d . U . . .
H10 H 0.2280 0.2620 -0.0814 0.021 Uiso 1 1 calc R U . . .
C21 C 0.2436(8) 0.7310(14) 0.3170(8) 0.0168(6) Uani 1 1 d . U . . .
C38 C 0.3354(8) 0.1258(14) 0.2866(8) 0.0176(8) Uani 1 1 d . U . . .
H33 H 0.3028 0.0852 0.2669 0.021 Uiso 1 1 calc R U . . .
C41 C 0.1220(8) 0.1652(14) 0.1024(8) 0.0175(9) Uani 1 1 d . U . . .
H35 H 0.1055 0.1723 0.0584 0.021 Uiso 1 1 calc R U . . .
C51 C 0.3422(9) 0.1636(15) 0.0959(9) 0.0221(14) Uani 1 1 d . U . . .
H58 H 0.3687 0.1243 0.0677 0.033 Uiso 1 1 calc R U . . .
H57 H 0.2986 0.1586 0.0790 0.033 Uiso 1 1 calc R U . . .
H59 H 0.3463 0.1362 0.1405 0.033 Uiso 1 1 calc R U . . .
C16 C 0.0879(8) 0.6867(14) -0.0050(8) 0.0160(8) Uani 1 1 d . U . . .
H14 H 0.0931 0.6403 -0.0400 0.019 Uiso 1 1 calc R U . . .
C25 C 0.1489(8) 0.8401(14) 0.3162(8) 0.0175(9) Uani 1 1 d . U . . .
H22 H 0.1061 0.8486 0.3029 0.021 Uiso 1 1 calc R U . . .
C36 C 0.4320(8) 0.1322(14) 0.3510(8) 0.0184(9) Uani 1 1 d . U . . .
H31 H 0.4655 0.0976 0.3739 0.022 Uiso 1 1 calc R U . . .
C13 C 0.0813(8) 0.3430(14) -0.0722(8) 0.0172(9) Uani 1 1 d . U . . .
H12 H 0.0405 0.3352 -0.0922 0.021 Uiso 1 1 calc R U . . .
C10 C 0.2046(8) 0.3774(13) -0.0199(8) 0.0166(8) Uani 1 1 d . U . . .
H9 H 0.2458 0.3881 -0.0017 0.020 Uiso 1 1 calc R U . . .
C14 C 0.0957(8) 0.4210(14) -0.0230(8) 0.0167(8) Uani 1 1 d . U . . .
H13 H 0.0624 0.4592 -0.0067 0.020 Uiso 1 1 calc R U . . .
C12 C 0.1340(8) 0.2754(14) -0.0899(8) 0.0174(9) Uani 1 1 d . U . . .
H11 H 0.1263 0.2172 -0.1170 0.021 Uiso 1 1 calc R U . . .
C47 C 0.0426(8) 0.5860(14) 0.2333(8) 0.0177(13) Uani 1 1 d . U . . .
H45 H 0.0206 0.6247 0.1979 0.027 Uiso 1 1 calc R U . . .
H47 H 0.0738 0.6299 0.2561 0.027 Uiso 1 1 calc R U . . .
H46 H 0.0127 0.5623 0.2643 0.027 Uiso 1 1 calc R U . . .
C23 C 0.2447(8) 0.8961(14) 0.3758(8) 0.0176(9) Uani 1 1 d . U . . .
H20 H 0.2680 0.9430 0.4031 0.021 Uiso 1 1 calc R U . . .
C4 C 0.4357(8) 0.6299(14) -0.0444(8) 0.0188(14) Uani 1 1 d . U . . .
H4 H 0.4546 0.6849 -0.0174 0.028 Uiso 1 1 calc R U . . .
H3 H 0.4292 0.6534 -0.0898 0.028 Uiso 1 1 calc R U . . .
H2 H 0.4635 0.5703 -0.0427 0.028 Uiso 1 1 calc R U . . .
C34 C 0.3824(8) 0.2893(14) 0.3122(8) 0.0179(8) Uani 1 1 d . U . . .
H29 H 0.3814 0.3619 0.3110 0.021 Uiso 1 1 calc R U . . .
C17 C 0.0481(8) 0.7738(13) -0.0152(8) 0.0164(9) Uani 1 1 d . U . . .
H15 H 0.0270 0.7858 -0.0566 0.020 Uiso 1 1 calc R U . . .
C42 C 0.0946(8) 0.0964(15) 0.1451(8) 0.0175(9) Uani 1 1 d . U . . .
H36 H 0.0568 0.0631 0.1311 0.021 Uiso 1 1 calc R U . . .
C48 C 0.2636(9) 0.8922(15) 0.1707(9) 0.0225(14) Uani 1 1 d . U . . .
H50 H 0.2453 0.8825 0.2130 0.034 Uiso 1 1 calc R U . . .
H49 H 0.2305 0.8904 0.1355 0.034 Uiso 1 1 calc R U . . .
H48 H 0.2849 0.9585 0.1704 0.034 Uiso 1 1 calc R U . . .
C18 C 0.0406(8) 0.8424(14) 0.0383(8) 0.0164(9) Uani 1 1 d . U . . .
H16 H 0.0133 0.8992 0.0326 0.020 Uiso 1 1 calc R U . . .
C24 C 0.1814(8) 0.9210(14) 0.3552(8) 0.0177(9) Uani 1 1 d . U . . .
H21 H 0.1622 0.9838 0.3658 0.021 Uiso 1 1 calc R U . . .
C49 C 0.3513(8) 0.8355(15) 0.0793(8) 0.0223(14) Uani 1 1 d . U . . .
H53 H 0.3532 0.9104 0.0783 0.034 Uiso 1 1 calc R U . . .
H51 H 0.3245 0.8109 0.0421 0.034 Uiso 1 1 calc R U . . .
H52 H 0.3934 0.8075 0.0766 0.034 Uiso 1 1 calc R U . . .
C35 C 0.4327(8) 0.2419(14) 0.3473(8) 0.0183(9) Uani 1 1 d . U . . .
H30 H 0.4658 0.2807 0.3677 0.022 Uiso 1 1 calc R U . . .
C29 C 0.4370(8) 0.5490(14) 0.4195(8) 0.0186(9) Uani 1 1 d . U . . .
H25 H 0.4430 0.5474 0.4659 0.022 Uiso 1 1 calc R U . . .
C32 C 0.4212(8) 0.5688(14) 0.2811(8) 0.0180(8) Uani 1 1 d . U . . .
H28 H 0.4166 0.5753 0.2348 0.022 Uiso 1 1 calc R U . . .
C52 C 0.3890(8) 0.3146(15) 0.0099(8) 0.0225(14) Uani 1 1 d . U . . .
H62 H 0.4126 0.3780 0.0054 0.034 Uiso 1 1 calc R U . . .
H60 H 0.3511 0.3168 -0.0194 0.034 Uiso 1 1 calc R U . . .
H61 H 0.4147 0.2562 -0.0018 0.034 Uiso 1 1 calc R U . . .
C45 C 0.0332(8) 0.4433(14) 0.1226(8) 0.0174(13) Uani 1 1 d . U . . .
H39 H -0.0086 0.4236 0.1345 0.026 Uiso 1 1 calc R U . . .
H40 H 0.0519 0.3868 0.0992 0.026 Uiso 1 1 calc R U . . .
H41 H 0.0304 0.5039 0.0943 0.026 Uiso 1 1 calc R U . . .
C28 C 0.3770(8) 0.5714(14) 0.3914(8) 0.0182(8) Uani 1 1 d . U . . .
H24 H 0.3428 0.5767 0.4184 0.022 Uiso 1 1 calc R U . . .
C30 C 0.4889(8) 0.5286(14) 0.3816(8) 0.0187(9) Uani 1 1 d . U . . .
H26 H 0.5280 0.5072 0.4012 0.022 Uiso 1 1 calc R U . . .
C37 C 0.3840(8) 0.0771(14) 0.3223(8) 0.0181(9) Uani 1 1 d . U . . .
H32 H 0.3838 0.0048 0.3267 0.022 Uiso 1 1 calc R U . . .
C31 C 0.4793(8) 0.5420(14) 0.3129(8) 0.0186(9) Uani 1 1 d . U . . .
H27 H 0.5138 0.5325 0.2867 0.022 Uiso 1 1 calc R U . . .
C19 C 0.0727(8) 0.8270(14) 0.0985(8) 0.0162(9) Uani 1 1 d . U . . .
H17 H 0.0689 0.8737 0.1336 0.019 Uiso 1 1 calc R U . . .
C50 C 0.3821(8) 0.8313(15) 0.2181(9) 0.0224(14) Uani 1 1 d . U . . .
H54 H 0.3986 0.8978 0.2054 0.034 Uiso 1 1 calc R U . . .
H55 H 0.4155 0.7801 0.2187 0.034 Uiso 1 1 calc R U . . .
H56 H 0.3661 0.8364 0.2618 0.034 Uiso 1 1 calc R U . . .
C46 C 0.0594(8) 0.3642(14) 0.2516(8) 0.0175(13) Uani 1 1 d . U . . .
H44 H 0.0786 0.3737 0.2959 0.026 Uiso 1 1 calc R U . . .
H43 H 0.0736 0.2994 0.2336 0.026 Uiso 1 1 calc R U . . .
H42 H 0.0139 0.3628 0.2534 0.026 Uiso 1 1 calc R U . . .
C53 C 0.4428(8) 0.2998(15) 0.1460(9) 0.0219(14) Uani 1 1 d . U . . .
H65 H 0.4355 0.2869 0.1922 0.033 Uiso 1 1 calc R U . . .
H64 H 0.4634 0.3662 0.1420 0.033 Uiso 1 1 calc R U . . .
H63 H 0.4696 0.2457 0.1299 0.033 Uiso 1 1 calc R U . . .
C8 C 0.1895(8) 0.5555(15) 0.4764(8) 0.0197(14) Uani 1 1 d . U . . .
H7 H 0.1650 0.6182 0.4698 0.030 Uiso 1 1 calc R U . . .
H6 H 0.2194 0.5642 0.5142 0.030 Uiso 1 1 calc R U . . .
H8 H 0.1616 0.4982 0.4845 0.030 Uiso 1 1 calc R U . . .
C43 C 0.1228(8) 0.0755(14) 0.2096(8) 0.0175(9) Uani 1 1 d . U . . .
H37 H 0.1069 0.0228 0.2359 0.021 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.266(4) . ?
Pt1 C6 2.381(17) . ?
Pt1 Ge1 2.4179(19) . ?
Pt1 C5 2.442(17) . ?
Pt1 Pt2 2.7486(10) . ?
Pt1 Pt3 2.8162(10) . ?
Pt3 C1 2.081(17) . ?
Pt3 P3 2.235(5) . ?
Pt3 Ge3 2.3893(19) . ?
Pt3 Pt2 2.6945(12) . ?
Pt2 C1 2.196(16) . ?
Pt2 P2 2.239(5) . ?
Pt2 C2 2.311(16) . ?
Pt2 Ge2 2.3697(19) . ?
Ge2 C27 1.958(17) . ?
Ge2 C21 1.956(17) . ?
Ge2 C5 1.979(17) . ?
Ge1 C2 1.953(17) . ?
Ge1 C15 1.958(17) . ?
Ge1 C9 2.003(17) . ?
Ge3 C33 1.944(17) . ?
Ge3 C39 1.995(17) . ?
Ge3 C6 2.013(17) . ?
P1 C45 1.812(17) . ?
P1 C47 1.836(18) . ?
P1 C46 1.842(17) . ?
P2 C48 1.746(19) . ?
P2 C50 1.812(18) . ?
P2 C49 1.852(17) . ?
P3 C51 1.83(2) . ?
P3 C53 1.826(18) . ?
P3 C52 1.836(17) . ?
O4 C7 1.33(2) . ?
O4 C8 1.421(19) . ?
O2 C3 1.35(2) . ?
O2 C4 1.462(19) . ?
O3 C7 1.21(2) . ?
O1 C3 1.18(2) . ?
C1 C2 1.45(2) . ?
C1 C3 1.50(2) . ?
C15 C20 1.32(2) . ?
C15 C16 1.42(2) . ?
C33 C34 1.40(2) . ?
C33 C38 1.41(2) . ?
C9 C14 1.34(2) . ?
C9 C10 1.40(2) . ?
C40 C41 1.36(2) . ?
C40 C39 1.41(2) . ?
C5 C6 1.34(2) . ?
C5 C7 1.54(2) . ?
C44 C39 1.40(2) . ?
C44 C43 1.42(2) . ?
C22 C21 1.36(2) . ?
C22 C23 1.41(2) . ?
C20 C19 1.42(2) . ?
C27 C28 1.40(2) . ?
C27 C32 1.45(2) . ?
C26 C25 1.37(2) . ?
C26 C21 1.39(2) . ?
C11 C12 1.35(2) . ?
C11 C10 1.37(2) . ?
C38 C37 1.36(2) . ?
C41 C42 1.38(2) . ?
C16 C17 1.40(2) . ?
C25 C24 1.44(2) . ?
C36 C37 1.33(2) . ?
C36 C35 1.41(2) . ?
C13 C14 1.42(2) . ?
C13 C12 1.47(2) . ?
C23 C24 1.41(2) . ?
C34 C35 1.37(2) . ?
C17 C18 1.40(2) . ?
C42 C43 1.42(2) . ?
C18 C19 1.36(2) . ?
C29 C28 1.38(2) . ?
C29 C30 1.39(2) . ?
C32 C31 1.39(2) . ?
C30 C31 1.39(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 C6 94.8(4) . . ?
P1 Pt1 Ge1 95.64(12) . . ?
C6 Pt1 Ge1 161.6(4) . . ?
P1 Pt1 C5 100.1(4) . . ?
C6 Pt1 C5 32.3(6) . . ?
Ge1 Pt1 C5 156.9(4) . . ?
P1 Pt1 Pt2 146.52(12) . . ?
C6 Pt1 Pt2 108.3(4) . . ?
Ge1 Pt1 Pt2 69.61(5) . . ?
C5 Pt1 Pt2 88.1(4) . . ?
P1 Pt1 Pt3 150.25(12) . . ?
C6 Pt1 Pt3 86.3(4) . . ?
Ge1 Pt1 Pt3 77.11(5) . . ?
C5 Pt1 Pt3 96.5(4) . . ?
Pt2 Pt1 Pt3 57.91(3) . . ?
C1 Pt3 P3 102.2(5) . . ?
C1 Pt3 Ge3 165.4(5) . . ?
P3 Pt3 Ge3 92.33(13) . . ?
C1 Pt3 Pt2 52.9(5) . . ?
P3 Pt3 Pt2 146.21(13) . . ?
Ge3 Pt3 Pt2 113.88(5) . . ?
C1 Pt3 Pt1 97.4(5) . . ?
P3 Pt3 Pt1 153.96(13) . . ?
Ge3 Pt3 Pt1 68.62(5) . . ?
Pt2 Pt3 Pt1 59.79(2) . . ?
C1 Pt2 P2 109.2(5) . . ?
C1 Pt2 C2 37.4(6) . . ?
P2 Pt2 C2 98.7(5) . . ?
C1 Pt2 Ge2 142.5(5) . . ?
P2 Pt2 Ge2 97.26(13) . . ?
C2 Pt2 Ge2 161.2(4) . . ?
C1 Pt2 Pt3 49.1(5) . . ?
P2 Pt2 Pt3 151.09(12) . . ?
C2 Pt2 Pt3 74.5(4) . . ?
Ge2 Pt2 Pt3 95.97(5) . . ?
C1 Pt2 Pt1 96.7(5) . . ?
P2 Pt2 Pt1 146.54(12) . . ?
C2 Pt2 Pt1 89.0(4) . . ?
Ge2 Pt2 Pt1 72.15(5) . . ?
Pt3 Pt2 Pt1 62.31(3) . . ?
C27 Ge2 C21 109.6(7) . . ?
C27 Ge2 C5 108.1(7) . . ?
C21 Ge2 C5 101.7(7) . . ?
C27 Ge2 Pt2 113.4(5) . . ?
C21 Ge2 Pt2 111.1(5) . . ?
C5 Ge2 Pt2 112.2(5) . . ?
C2 Ge1 C15 102.7(7) . . ?
C2 Ge1 C9 104.5(7) . . ?
C15 Ge1 C9 109.3(7) . . ?
C2 Ge1 Pt1 108.7(5) . . ?
C15 Ge1 Pt1 112.3(5) . . ?
C9 Ge1 Pt1 118.0(5) . . ?
C33 Ge3 C39 108.4(7) . . ?
C33 Ge3 C6 105.7(7) . . ?
C39 Ge3 C6 99.4(7) . . ?
C33 Ge3 Pt3 119.9(5) . . ?
C39 Ge3 Pt3 113.2(5) . . ?
C6 Ge3 Pt3 108.1(5) . . ?
C45 P1 C47 103.7(8) . . ?
C45 P1 C46 99.9(8) . . ?
C47 P1 C46 103.2(8) . . ?
C45 P1 Pt1 116.8(6) . . ?
C47 P1 Pt1 115.2(6) . . ?
C46 P1 Pt1 115.8(6) . . ?
C48 P2 C50 100.1(9) . . ?
C48 P2 C49 100.9(9) . . ?
C50 P2 C49 100.4(8) . . ?
C48 P2 Pt2 118.9(7) . . ?
C50 P2 Pt2 118.0(7) . . ?
C49 P2 Pt2 115.4(6) . . ?
C51 P3 C53 103.8(9) . . ?
C51 P3 C52 100.0(9) . . ?
C53 P3 C52 104.4(8) . . ?
C51 P3 Pt3 119.4(6) . . ?
C53 P3 Pt3 110.4(6) . . ?
C52 P3 Pt3 117.0(7) . . ?
C7 O4 C8 114.5(13) . . ?
C3 O2 C4 113.3(13) . . ?
C2 C1 C3 119.5(15) . . ?
C2 C1 Pt3 118.1(12) . . ?
C3 C1 Pt3 122.3(12) . . ?
C2 C1 Pt2 75.6(9) . . ?
C3 C1 Pt2 117.1(11) . . ?
Pt3 C1 Pt2 78.1(5) . . ?
C20 C15 C16 117.7(16) . . ?
C20 C15 Ge1 122.2(13) . . ?
C16 C15 Ge1 120.1(12) . . ?
C34 C33 C38 114.2(16) . . ?
C34 C33 Ge3 120.4(13) . . ?
C38 C33 Ge3 125.4(13) . . ?
C14 C9 C10 118.2(16) . . ?
C14 C9 Ge1 123.8(13) . . ?
C10 C9 Ge1 117.7(12) . . ?
O1 C3 O2 122.2(15) . . ?
O1 C3 C1 126.4(16) . . ?
O2 C3 C1 111.3(14) . . ?
C41 C40 C39 121.5(16) . . ?
C6 C5 C7 110.9(15) . . ?
C6 C5 Ge2 133.7(14) . . ?
C7 C5 Ge2 115.2(12) . . ?
C6 C5 Pt1 71.4(10) . . ?
C7 C5 Pt1 125.0(11) . . ?
Ge2 C5 Pt1 85.8(6) . . ?
C39 C44 C43 118.6(15) . . ?
O3 C7 O4 122.2(15) . . ?
O3 C7 C5 127.8(14) . . ?
O4 C7 C5 110.0(14) . . ?
C21 C22 C23 122.2(16) . . ?
C44 C39 C40 120.0(16) . . ?
C44 C39 Ge3 121.7(12) . . ?
C40 C39 Ge3 117.6(12) . . ?
C15 C20 C19 124.0(16) . . ?
C28 C27 C32 118.3(16) . . ?
C28 C27 Ge2 122.6(12) . . ?
C32 C27 Ge2 118.5(12) . . ?
C25 C26 C21 122.9(16) . . ?
C1 C2 Ge1 115.4(12) . . ?
C1 C2 Pt2 67.0(9) . . ?
Ge1 C2 Pt2 87.6(6) . . ?
C5 C6 Ge3 130.0(14) . . ?
C5 C6 Pt1 76.3(10) . . ?
Ge3 C6 Pt1 84.1(6) . . ?
C12 C11 C10 120.9(16) . . ?
C22 C21 C26 116.8(16) . . ?
C22 C21 Ge2 125.3(13) . . ?
C26 C21 Ge2 117.7(12) . . ?
C37 C38 C33 122.8(17) . . ?
C40 C41 C42 119.4(16) . . ?
C17 C16 C15 120.5(16) . . ?
C26 C25 C24 121.5(16) . . ?
C37 C36 C35 121.1(17) . . ?
C14 C13 C12 116.8(15) . . ?
C11 C10 C9 122.1(16) . . ?
C9 C14 C13 122.5(16) . . ?
C11 C12 C13 118.9(16) . . ?
C24 C23 C22 122.6(16) . . ?
C35 C34 C33 124.0(17) . . ?
C18 C17 C16 118.8(15) . . ?
C41 C42 C43 121.3(17) . . ?
C19 C18 C17 120.9(17) . . ?
C23 C24 C25 113.8(16) . . ?
C34 C35 C36 117.2(17) . . ?
C28 C29 C30 123.0(16) . . ?
C31 C32 C27 118.1(15) . . ?
C29 C28 C27 120.1(15) . . ?
C31 C30 C29 116.4(17) . . ?
C36 C37 C38 120.5(17) . . ?
C30 C31 C32 123.8(16) . . ?
C18 C19 C20 118.0(16) . . ?
C42 C43 C44 118.8(16) . . ?

_refine_diff_density_max         4.343
_refine_diff_density_min         -5.820
_refine_diff_density_rms         0.436

_shelxl_version_number           2013-2;
_database_code_depnum_ccdc_archive 'CCDC 979334'
