# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2014

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#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
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#  fide research purposes only. It may contain copyright material
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data_AL133

_audit_update_record             
;
2014-02-26 # Formatted by publCIF

;
# publcif _publ_body_element loop end

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C26 H15 F N O4 P W'
_chemical_formula_sum            'C26 H15 F N O4 P W'
_chemical_formula_weight         639.21

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           33
_space_group_name_H-M_alt        'P n a 21'
_space_group_name_Hall           'P 2c -2n'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, -y+1/2, z'

_cell_length_a                   15.8144(16)
_cell_length_b                   19.0204(17)
_cell_length_c                   7.3213(9)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2202.2(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    210(2)
_cell_measurement_reflns_used    7163
_cell_measurement_theta_min      3.25
_cell_measurement_theta_max      29.45

_exptl_crystal_description       platelet
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.928
_exptl_crystal_F_000             1232
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.060
_exptl_absorpt_coefficient_mu    5.362
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   integration
_exptl_absorpt_correction_T_min  0.4815
_exptl_absorpt_correction_T_max  0.7422
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-11 5 -12 0.0720
15 -2 16 0.0970
1 22 2 0.0470
0 -21 -1 0.0580
3 9 -22 0.0360
-1 -3 7 0.0240
1 8 16 0.0440

_exptl_absorpt_process_details   'STOE X-RED & X-SHAPE'

_exptl_special_details           ?

_diffrn_ambient_temperature      210(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   
'sealed X-ray tube, 12 x 0.4 mm long-fine focus'
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method'
_diffrn_detector_area_resol_mean 6.67
_diffrn_reflns_number            9573
_diffrn_reflns_av_unetI/netI     0.1063
_diffrn_reflns_av_R_equivalents  0.0982
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         3.248
_diffrn_reflns_theta_max         29.284
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measured_fraction_theta_full 0.981
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_Laue_measured_fraction_full 0.981
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_point_group_measured_fraction_full 0.990
_reflns_number_total             5136
_reflns_number_gt                2997
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.872
_reflns_Friedel_fraction_max     0.992
_reflns_Friedel_fraction_full    0.999

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'STOE X-AREA'
_computing_cell_refinement       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Diamond 2.1e'
_computing_publication_material  'X-STEP32, Microsoft Word'

_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0530P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.12(3)
_chemical_absolute_configuration ?
_refine_ls_number_reflns         5136
_refine_ls_number_parameters     308
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.1122
_refine_ls_R_factor_gt           0.0545
_refine_ls_wR_factor_ref         0.1268
_refine_ls_wR_factor_gt          0.1086
_refine_ls_goodness_of_fit_ref   0.944
_refine_ls_restrained_S_all      0.944
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3236(11) 0.1027(8) 0.264(2) 0.040(4) Uani 1 1 d . . . . .
C2 C 0.3806(10) 0.0491(7) 0.274(4) 0.039(4) Uani 1 1 d . . . . .
H2 H 0.3611 0.0049 0.2402 0.046 Uiso 1 1 calc R U . . .
C3 C 0.4644(11) 0.0529(8) 0.330(2) 0.039(5) Uani 1 1 d . . . . .
C4 C 0.4996(12) 0.1161(8) 0.388(2) 0.039(4) Uani 1 1 d . . . . .
H4 H 0.5551 0.1151 0.4296 0.047 Uiso 1 1 calc R U . . .
C5 C 0.4578(10) 0.1809(9) 0.390(2) 0.038(3) Uani 1 1 d . . . . .
C6 C 0.5001(11) 0.2456(9) 0.458(2) 0.037(4) Uani 1 1 d . . . . .
C7 C 0.5770(13) 0.2446(10) 0.544(3) 0.050(4) Uani 1 1 d . . . . .
H7 H 0.6060 0.2024 0.5588 0.060 Uiso 1 1 calc R U . . .
C8 C 0.6110(13) 0.3066(9) 0.607(3) 0.051(5) Uani 1 1 d . . . . .
H8 H 0.6614 0.3062 0.6724 0.061 Uiso 1 1 calc R U . . .
C9 C 0.5715(15) 0.3673(11) 0.575(3) 0.052(6) Uani 1 1 d . . . . .
H9 H 0.5961 0.4096 0.6094 0.063 Uiso 1 1 calc R U . . .
C10 C 0.4924(12) 0.3666(9) 0.488(2) 0.044(4) Uani 1 1 d . . . . .
H10 H 0.4630 0.4085 0.4733 0.053 Uiso 1 1 calc R U . . .
C11 C 0.2335(11) 0.0907(8) 0.213(2) 0.042(4) Uani 1 1 d . . . . .
C12 C 0.1880(11) 0.1367(9) 0.111(2) 0.045(4) Uani 1 1 d . . . . .
H12 H 0.2118 0.1789 0.0731 0.054 Uiso 1 1 calc R U . . .
C13 C 0.1031(13) 0.1193(11) 0.063(3) 0.049(5) Uani 1 1 d . . . . .
H13 H 0.0718 0.1509 -0.0061 0.059 Uiso 1 1 calc R U . . .
C14 C 0.0670(13) 0.0586(11) 0.116(3) 0.054(5) Uani 1 1 d . . . . .
H14 H 0.0121 0.0472 0.0811 0.065 Uiso 1 1 calc R U . . .
C15 C 0.1150(13) 0.0130(9) 0.223(2) 0.047(5) Uani 1 1 d . . . . .
H15 H 0.0906 -0.0284 0.2654 0.057 Uiso 1 1 calc R U . . .
C16 C 0.1958(11) 0.0275(8) 0.268(4) 0.047(6) Uani 1 1 d . . . . .
H16 H 0.2268 -0.0048 0.3364 0.057 Uiso 1 1 calc R U . . .
C17 C 0.5189(12) -0.0115(8) 0.328(3) 0.044(5) Uani 1 1 d . . . . .
C18 C 0.4853(12) -0.0767(9) 0.373(2) 0.046(4) Uani 1 1 d . . . . .
H18 H 0.4289 -0.0807 0.4073 0.055 Uiso 1 1 calc R U . . .
C19 C 0.5369(13) -0.1364(9) 0.367(2) 0.044(4) Uani 1 1 d . . . . .
H19 H 0.5152 -0.1800 0.4003 0.052 Uiso 1 1 calc R U . . .
C20 C 0.6174(12) -0.1307(8) 0.314(4) 0.050(6) Uani 1 1 d . . . . .
C21 C 0.6537(9) -0.0677(8) 0.268(4) 0.041(5) Uani 1 1 d . . . . .
H21 H 0.7103 -0.0654 0.2345 0.049 Uiso 1 1 calc R U . . .
C22 C 0.6036(10) -0.0068(7) 0.273(4) 0.042(4) Uani 1 1 d . . . . .
H22 H 0.6264 0.0365 0.2400 0.051 Uiso 1 1 calc R U . . .
C25 C 0.2711(14) 0.3337(9) 0.536(3) 0.052(5) Uani 1 1 d . . . . .
C24 C 0.3320(12) 0.4190(9) 0.266(6) 0.055(7) Uani 1 1 d . . . . .
C23 C 0.3827(11) 0.3162(10) 0.044(3) 0.043(4) Uani 1 1 d . . . . .
C26 C 0.2151(15) 0.3153(11) 0.175(3) 0.058(5) Uani 1 1 d . . . . .
N2 N 0.4583(10) 0.3066(7) 0.426(2) 0.044(3) Uani 1 1 d . . . . .
O3 O 0.2403(12) 0.3478(10) 0.676(2) 0.078(5) Uani 1 1 d . . . . .
O2 O 0.3362(10) 0.4784(6) 0.236(2) 0.068(5) Uani 1 1 d . . . . .
O1 O 0.4094(10) 0.3226(8) -0.103(2) 0.065(4) Uani 1 1 d . . . . .
O4 O 0.1498(10) 0.3146(8) 0.109(3) 0.072(4) Uani 1 1 d . . . . .
F1 F 0.6681(6) -0.1883(4) 0.302(5) 0.063(3) Uani 1 1 d . . . . .
P1 P 0.3540(3) 0.1892(2) 0.3221(7) 0.0356(13) Uani 1 1 d . . . . .
W1 W 0.32656(4) 0.31612(3) 0.29109(10) 0.04099(17) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.36(2) . ?
C1 C11 1.49(3) . ?
C1 P1 1.766(17) . ?
C2 C3 1.39(2) . ?
C3 C4 1.39(2) . ?
C3 C17 1.50(2) . ?
C4 C5 1.40(2) . ?
C5 C6 1.49(2) . ?
C5 P1 1.722(17) . ?
C6 N2 1.36(2) . ?
C6 C7 1.37(3) . ?
C7 C8 1.38(3) . ?
C8 C9 1.33(3) . ?
C9 C10 1.40(3) . ?
C10 N2 1.34(2) . ?
C11 C12 1.35(2) . ?
C11 C16 1.40(2) . ?
C12 C13 1.43(3) . ?
C13 C14 1.34(3) . ?
C14 C15 1.40(3) . ?
C15 C16 1.35(3) . ?
C17 C18 1.39(2) . ?
C17 C22 1.40(3) . ?
C18 C19 1.40(2) . ?
C19 C20 1.34(3) . ?
C20 F1 1.360(18) . ?
C20 C21 1.37(2) . ?
C21 C22 1.40(2) . ?
C25 O3 1.17(3) . ?
C25 W1 2.02(2) . ?
C24 O2 1.15(2) . ?
C24 W1 1.967(17) . ?
C23 O1 1.16(2) . ?
C23 W1 2.014(19) . ?
C26 O4 1.14(2) . ?
C26 W1 1.96(2) . ?
N2 W1 2.312(15) . ?
P1 W1 2.464(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C11 122.1(15) . . ?
C2 C1 P1 120.2(14) . . ?
C11 C1 P1 117.6(12) . . ?
C1 C2 C3 127.5(15) . . ?
C2 C3 C4 121.1(15) . . ?
C2 C3 C17 120.3(14) . . ?
C4 C3 C17 118.6(15) . . ?
C3 C4 C5 125.1(17) . . ?
C4 C5 C6 121.3(15) . . ?
C4 C5 P1 121.9(13) . . ?
C6 C5 P1 116.7(12) . . ?
N2 C6 C7 121.7(16) . . ?
N2 C6 C5 115.4(15) . . ?
C7 C6 C5 122.8(16) . . ?
C6 C7 C8 119.3(18) . . ?
C9 C8 C7 119.9(19) . . ?
C8 C9 C10 119.3(17) . . ?
N2 C10 C9 121.4(17) . . ?
C12 C11 C16 119.2(18) . . ?
C12 C11 C1 123.2(15) . . ?
C16 C11 C1 117.6(17) . . ?
C11 C12 C13 119.0(17) . . ?
C14 C13 C12 121.9(19) . . ?
C13 C14 C15 117.6(19) . . ?
C16 C15 C14 121.8(18) . . ?
C15 C16 C11 120(2) . . ?
C18 C17 C22 119.4(15) . . ?
C18 C17 C3 120.6(17) . . ?
C22 C17 C3 119.9(14) . . ?
C17 C18 C19 119.7(18) . . ?
C20 C19 C18 119.9(16) . . ?
C19 C20 F1 121.0(16) . . ?
C19 C20 C21 122.8(15) . . ?
F1 C20 C21 116.2(18) . . ?
C20 C21 C22 118.6(16) . . ?
C17 C22 C21 119.5(15) . . ?
O3 C25 W1 176.1(16) . . ?
O2 C24 W1 174(3) . . ?
O1 C23 W1 172.4(16) . . ?
O4 C26 W1 179(2) . . ?
C10 N2 C6 118.2(16) . . ?
C10 N2 W1 116.1(12) . . ?
C6 N2 W1 125.5(11) . . ?
C5 P1 C1 104.1(8) . . ?
C5 P1 W1 106.5(6) . . ?
C1 P1 W1 147.5(6) . . ?
C26 W1 C24 90.4(9) . . ?
C26 W1 C23 90.4(8) . . ?
C24 W1 C23 84.0(13) . . ?
C26 W1 C25 89.8(9) . . ?
C24 W1 C25 86.4(12) . . ?
C23 W1 C25 170.5(7) . . ?
C26 W1 N2 175.0(7) . . ?
C24 W1 N2 94.5(8) . . ?
C23 W1 N2 89.2(6) . . ?
C25 W1 N2 91.5(7) . . ?
C26 W1 P1 101.0(6) . . ?
C24 W1 P1 167.3(6) . . ?
C23 W1 P1 90.3(5) . . ?
C25 W1 P1 99.0(5) . . ?
N2 W1 P1 74.0(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 C1 C2 C3 -176(2) . . . . ?
P1 C1 C2 C3 1(4) . . . . ?
C1 C2 C3 C4 2(4) . . . . ?
C1 C2 C3 C17 -179(2) . . . . ?
C2 C3 C4 C5 -3(3) . . . . ?
C17 C3 C4 C5 177.1(16) . . . . ?
C3 C4 C5 C6 178.9(15) . . . . ?
C3 C4 C5 P1 2(2) . . . . ?
C4 C5 C6 N2 169.9(14) . . . . ?
P1 C5 C6 N2 -13(2) . . . . ?
C4 C5 C6 C7 -8(3) . . . . ?
P1 C5 C6 C7 168.9(15) . . . . ?
N2 C6 C7 C8 3(3) . . . . ?
C5 C6 C7 C8 -178.4(17) . . . . ?
C6 C7 C8 C9 -4(3) . . . . ?
C7 C8 C9 C10 5(3) . . . . ?
C8 C9 C10 N2 -5(3) . . . . ?
C2 C1 C11 C12 -144(2) . . . . ?
P1 C1 C11 C12 39(2) . . . . ?
C2 C1 C11 C16 34(3) . . . . ?
P1 C1 C11 C16 -143.5(17) . . . . ?
C16 C11 C12 C13 0(3) . . . . ?
C1 C11 C12 C13 177.7(16) . . . . ?
C11 C12 C13 C14 0(3) . . . . ?
C12 C13 C14 C15 2(3) . . . . ?
C13 C14 C15 C16 -3(3) . . . . ?
C14 C15 C16 C11 2(3) . . . . ?
C12 C11 C16 C15 -1(3) . . . . ?
C1 C11 C16 C15 -178.9(19) . . . . ?
C2 C3 C17 C18 -36(3) . . . . ?
C4 C3 C17 C18 143.4(17) . . . . ?
C2 C3 C17 C22 141(2) . . . . ?
C4 C3 C17 C22 -39(3) . . . . ?
C22 C17 C18 C19 1(3) . . . . ?
C3 C17 C18 C19 178.7(17) . . . . ?
C17 C18 C19 C20 -2(3) . . . . ?
C18 C19 C20 F1 -178(2) . . . . ?
C18 C19 C20 C21 2(4) . . . . ?
C19 C20 C21 C22 -2(4) . . . . ?
F1 C20 C21 C22 178(3) . . . . ?
C18 C17 C22 C21 -1(4) . . . . ?
C3 C17 C22 C21 -179(2) . . . . ?
C20 C21 C22 C17 1(4) . . . . ?
C9 C10 N2 C6 4(3) . . . . ?
C9 C10 N2 W1 179.0(15) . . . . ?
C7 C6 N2 C10 -3(2) . . . . ?
C5 C6 N2 C10 178.5(15) . . . . ?
C7 C6 N2 W1 -178.0(13) . . . . ?
C5 C6 N2 W1 4(2) . . . . ?
C4 C5 P1 C1 0.8(16) . . . . ?
C6 C5 P1 C1 -176.5(12) . . . . ?
C4 C5 P1 W1 -168.0(12) . . . . ?
C6 C5 P1 W1 14.7(14) . . . . ?
C2 C1 P1 C5 -2(2) . . . . ?
C11 C1 P1 C5 175.4(13) . . . . ?
C2 C1 P1 W1 157.7(15) . . . . ?
C11 C1 P1 W1 -25(2) . . . . ?

_refine_diff_density_max         0.962
_refine_diff_density_min         -1.293
_refine_diff_density_rms         0.155
_database_code_depnum_ccdc_archive 'CCDC 988905'
