# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
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#  fide research purposes only. It may contain copyright material
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data_e:\131030d\work\cu_131030d_0m

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C77 H56 Au2 F10 N2 O2'
_chemical_formula_weight         1625.17

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.9116(16)
_cell_length_b                   12.7221(17)
_cell_length_c                   21.939(3)
_cell_angle_alpha                92.367(9)
_cell_angle_beta                 90.803(9)
_cell_angle_gamma                102.203(8)
_cell_volume                     3245.8(8)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    9967
_cell_measurement_theta_min      3.56
_cell_measurement_theta_max      43.26

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.663
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1592
_exptl_absorpt_coefficient_mu    9.039
_exptl_absorpt_correction_type   none
_exptl_absorpt_correction_T_min  0.4101
_exptl_absorpt_correction_T_max  0.4651
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         0
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21688
_diffrn_reflns_av_R_equivalents  0.2465
_diffrn_reflns_av_sigmaI/netI    0.3666
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.02
_diffrn_reflns_theta_max         43.40
_reflns_number_total             4569
_reflns_number_gt                2733
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4569
_refine_ls_number_parameters     742
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.2354
_refine_ls_R_factor_gt           0.1066
_refine_ls_wR_factor_ref         0.3093
_refine_ls_wR_factor_gt          0.2691
_refine_ls_goodness_of_fit_ref   1.161
_refine_ls_restrained_S_all      1.161
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.02926(13) 1.27997(11) 0.06588(6) 0.0546(8) Uani 1 1 d . . .
Au2 Au 0.84313(14) 0.91205(13) -0.14466(8) 0.0732(8) Uani 1 1 d . . .
C1 C 0.037(2) 1.3674(18) -0.0054(11) 0.058(10) Uani 1 1 d G . .
C2 C -0.0197(17) 1.3568(16) -0.0618(14) 0.052(10) Uani 1 1 d G . .
C3 C 0.028(2) 1.418(2) -0.1096(10) 0.042(9) Uani 1 1 d G . .
C4 C 0.133(2) 1.4903(17) -0.1009(11) 0.040(9) Uani 1 1 d G . .
C5 C 0.1901(17) 1.5009(17) -0.0445(14) 0.063(11) Uani 1 1 d G . .
C6 C 0.142(2) 1.439(2) 0.0032(10) 0.054(10) Uani 1 1 d G . .
C7 C -0.098(3) 1.187(3) 0.1333(15) 0.049(10) Uani 1 1 d . . .
C8 C -0.205(2) 1.0552(17) 0.2062(12) 0.056(10) Uani 1 1 d G . .
C9 C -0.297(2) 0.973(2) 0.1864(8) 0.050(10) Uani 1 1 d G . .
H9 H -0.3222 0.9679 0.1449 0.060 Uiso 1 1 calc R . .
C10 C -0.3514(16) 0.8999(16) 0.2273(12) 0.042(9) Uani 1 1 d G . .
H10 H -0.4140 0.8440 0.2138 0.050 Uiso 1 1 calc R . .
C11 C -0.3143(19) 0.9081(17) 0.2880(10) 0.041(9) Uani 1 1 d G . .
C12 C -0.223(2) 0.990(2) 0.3078(8) 0.040(9) Uani 1 1 d G . .
H12 H -0.1972 0.9954 0.3493 0.048 Uiso 1 1 calc R . .
C13 C -0.1680(16) 1.0634(16) 0.2669(13) 0.056(10) Uani 1 1 d G . .
H13 H -0.1054 1.1193 0.2804 0.067 Uiso 1 1 calc R . .
C14 C -0.439(3) 0.754(3) 0.3093(15) 0.058(11) Uani 1 1 d . . .
H14A H -0.4160 0.7208 0.2712 0.070 Uiso 1 1 calc R . .
H14B H -0.5111 0.7785 0.3005 0.070 Uiso 1 1 calc R . .
C15 C -0.461(3) 0.667(3) 0.3610(16) 0.069(11) Uani 1 1 d . . .
H15A H -0.4986 0.6966 0.3957 0.082 Uiso 1 1 calc R . .
H15B H -0.5160 0.6019 0.3442 0.082 Uiso 1 1 calc R . .
C16 C -0.357(3) 0.633(2) 0.3845(14) 0.049(9) Uani 1 1 d . . .
H16A H -0.3768 0.5933 0.4221 0.058 Uiso 1 1 calc R . .
H16B H -0.2975 0.6980 0.3954 0.058 Uiso 1 1 calc R . .
C17 C -0.305(3) 0.557(2) 0.3358(13) 0.044(9) Uani 1 1 d . . .
H17A H -0.3648 0.4917 0.3251 0.053 Uiso 1 1 calc R . .
H17B H -0.2863 0.5965 0.2980 0.053 Uiso 1 1 calc R . .
C18 C -0.200(3) 0.525(2) 0.3597(14) 0.052(10) Uani 1 1 d . . .
H18A H -0.2194 0.4805 0.3958 0.062 Uiso 1 1 calc R . .
H18B H -0.1412 0.5893 0.3722 0.062 Uiso 1 1 calc R . .
C19 C -0.155(3) 0.459(2) 0.3088(12) 0.033(8) Uani 1 1 d . . .
H19A H -0.2132 0.3926 0.2990 0.040 Uiso 1 1 calc R . .
H19B H -0.1448 0.5017 0.2717 0.040 Uiso 1 1 calc R . .
C20 C -0.011(3) 0.365(2) 0.2687(12) 0.034(8) Uani 1 1 d . . .
H20A H 0.0051 0.4152 0.2349 0.040 Uiso 1 1 calc R . .
H20B H -0.0799 0.3095 0.2564 0.040 Uiso 1 1 calc R . .
C21 C 0.094(3) 0.308(2) 0.2758(14) 0.053(10) Uani 1 1 d . . .
H21A H 0.0814 0.2679 0.3136 0.063 Uiso 1 1 calc R . .
H21B H 0.0869 0.2541 0.2416 0.063 Uiso 1 1 calc R . .
C22 C 0.216(3) 0.369(2) 0.2783(14) 0.053(10) Uani 1 1 d . . .
H22A H 0.2266 0.4292 0.3093 0.064 Uiso 1 1 calc R . .
H22B H 0.2678 0.3206 0.2894 0.064 Uiso 1 1 calc R . .
C23 C 0.243(3) 0.410(3) 0.2168(14) 0.061(11) Uani 1 1 d . . .
H23A H 0.2358 0.3490 0.1866 0.073 Uiso 1 1 calc R . .
H23B H 0.1871 0.4538 0.2050 0.073 Uiso 1 1 calc R . .
C24 C 0.361(3) 0.477(3) 0.2154(16) 0.071(12) Uani 1 1 d . . .
H24A H 0.3674 0.5360 0.2472 0.085 Uiso 1 1 calc R . .
H24B H 0.4154 0.4323 0.2271 0.085 Uiso 1 1 calc R . .
C25 C 0.398(4) 0.525(3) 0.1595(19) 0.102(16) Uani 1 1 d . . .
H25A H 0.3458 0.5725 0.1480 0.122 Uiso 1 1 calc R . .
H25B H 0.3908 0.4671 0.1271 0.122 Uiso 1 1 calc R . .
C26 C 0.559(3) 0.624(2) 0.1073(13) 0.090(14) Uani 1 1 d G . .
C27 C 0.5001(18) 0.6108(19) 0.0513(19) 0.081(13) Uani 1 1 d G . .
H27 H 0.4231 0.5708 0.0482 0.097 Uiso 1 1 calc R . .
C28 C 0.554(3) 0.656(2) -0.0001(12) 0.062(10) Uani 1 1 d G . .
H28 H 0.5139 0.6468 -0.0383 0.074 Uiso 1 1 calc R . .
C29 C 0.667(3) 0.715(2) 0.0045(13) 0.071(12) Uani 1 1 d G . .
C30 C 0.7253(18) 0.728(2) 0.0604(19) 0.091(14) Uani 1 1 d G . .
H30 H 0.8022 0.7682 0.0635 0.109 Uiso 1 1 calc R . .
C31 C 0.671(3) 0.683(2) 0.1118(12) 0.069(11) Uani 1 1 d G . .
H31 H 0.7114 0.6921 0.1501 0.083 Uiso 1 1 calc R . .
C33 C -0.040(3) 0.428(2) 0.3247(14) 0.047(10) Uani 1 1 d . . .
C35 C 0.0311(17) 0.4150(13) 0.4277(11) 0.037(8) Uani 1 1 d G . .
C34 C -0.049(2) 0.3643(19) 0.3835(7) 0.043(9) Uani 1 1 d G . .
C38 C -0.1239(17) 0.2681(19) 0.3955(10) 0.048(9) Uani 1 1 d G . .
H38 H -0.1789 0.2335 0.3653 0.057 Uiso 1 1 calc R . .
C39 C -0.1183(18) 0.2225(14) 0.4516(12) 0.063(11) Uani 1 1 d G . .
C40 C -0.038(2) 0.2732(18) 0.4958(8) 0.046(9) Uani 1 1 d G . .
H40 H -0.0340 0.2420 0.5342 0.056 Uiso 1 1 calc R . .
C41 C 0.0368(17) 0.3694(17) 0.4838(9) 0.044(9) Uani 1 1 d G . .
H41 H 0.0917 0.4040 0.5140 0.053 Uiso 1 1 calc R . .
C42 C -0.194(3) 0.115(2) 0.4633(13) 0.037(8) Uani 1 1 d . . .
C43 C -0.151(3) 0.037(3) 0.4971(15) 0.062(11) Uani 1 1 d . . .
H43 H -0.0730 0.0524 0.5109 0.074 Uiso 1 1 calc R . .
C44 C -0.218(4) -0.056(3) 0.5092(15) 0.053(10) Uani 1 1 d . . .
C45 C -0.330(4) -0.084(3) 0.4910(15) 0.055(10) Uani 1 1 d . . .
C46 C -0.379(3) -0.011(3) 0.4585(16) 0.062(11) Uani 1 1 d . . .
H46 H -0.4570 -0.0280 0.4456 0.074 Uiso 1 1 calc R . .
C47 C -0.306(3) 0.088(3) 0.4455(13) 0.046(9) Uani 1 1 d . . .
H47 H -0.3367 0.1382 0.4232 0.056 Uiso 1 1 calc R . .
C48 C -0.386(2) -0.1865(14) 0.5167(10) 0.040(9) Uani 1 1 d G . .
C49 C -0.3002(16) -0.226(2) 0.5461(11) 0.068(11) Uani 1 1 d G . .
C51 C -0.326(2) -0.326(2) 0.5718(10) 0.057(10) Uani 1 1 d G . .
H51 H -0.2674 -0.3527 0.5918 0.068 Uiso 1 1 calc R . .
C52 C -0.438(3) -0.3867(14) 0.5680(10) 0.093(14) Uani 1 1 d G . .
H52 H -0.4554 -0.4551 0.5856 0.112 Uiso 1 1 calc R . .
C53 C -0.5235(18) -0.347(2) 0.5387(11) 0.062(11) Uani 1 1 d G . .
H53 H -0.5998 -0.3891 0.5361 0.074 Uiso 1 1 calc R . .
C54 C -0.498(2) -0.247(2) 0.5130(10) 0.059(10) Uani 1 1 d G . .
H54 H -0.5562 -0.2205 0.4930 0.071 Uiso 1 1 calc R . .
C50 C -0.183(3) -0.143(3) 0.5510(18) 0.085(13) Uani 1 1 d . . .
H50A H -0.1189 -0.1727 0.5338 0.103 Uiso 1 1 calc R . .
H50B H -0.1628 -0.1147 0.5934 0.103 Uiso 1 1 calc R . .
C37 C 0.0603(16) 0.5219(16) 0.3454(11) 0.046(10) Uani 1 1 d G . .
C36 C 0.1014(18) 0.5119(15) 0.4041(10) 0.037(8) Uani 1 1 d G . .
C55 C 0.1932(19) 0.589(2) 0.4288(8) 0.037(9) Uani 1 1 d G . .
H55 H 0.2212 0.5818 0.4689 0.044 Uiso 1 1 calc R . .
C56 C 0.2440(16) 0.6753(16) 0.3950(12) 0.057(10) Uani 1 1 d G . .
H56 H 0.3067 0.7277 0.4119 0.069 Uiso 1 1 calc R . .
C57 C 0.203(2) 0.6853(16) 0.3363(11) 0.062(11) Uani 1 1 d G . .
C58 C 0.111(2) 0.609(2) 0.3116(8) 0.048(9) Uani 1 1 d G . .
H58 H 0.0831 0.6154 0.2715 0.058 Uiso 1 1 calc R . .
C59 C 0.266(3) 0.782(3) 0.3016(18) 0.046(10) Uani 1 1 d . . .
C60 C 0.314(3) 0.882(3) 0.3335(14) 0.043(9) Uani 1 1 d . . .
H60 H 0.3037 0.8909 0.3762 0.051 Uiso 1 1 calc R . .
C61 C 0.372(3) 0.963(3) 0.3027(17) 0.042(9) Uani 1 1 d . . .
C62 C 0.370(3) 0.949(3) 0.2384(17) 0.038(9) Uani 1 1 d . . .
C63 C 0.325(3) 0.867(3) 0.2142(14) 0.026(8) Uani 1 1 d . . .
H63 H 0.3318 0.8634 0.1711 0.031 Uiso 1 1 calc R . .
C64 C 0.266(3) 0.778(3) 0.239(2) 0.064(11) Uani 1 1 d . . .
H64 H 0.2278 0.7175 0.2145 0.077 Uiso 1 1 calc R . .
C66 C 0.480(2) 1.130(3) 0.2690(10) 0.062(11) Uani 1 1 d G . .
C67 C 0.4405(19) 1.0620(16) 0.2186(16) 0.053(10) Uani 1 1 d G . .
C68 C 0.469(2) 1.095(2) 0.1601(12) 0.065(11) Uani 1 1 d G . .
H68 H 0.4417 1.0487 0.1257 0.078 Uiso 1 1 calc R . .
C69 C 0.536(2) 1.197(2) 0.1521(10) 0.059(11) Uani 1 1 d G . .
H69 H 0.5549 1.2199 0.1122 0.071 Uiso 1 1 calc R . .
C70 C 0.575(2) 1.2654(15) 0.2025(16) 0.073(12) Uani 1 1 d G . .
H70 H 0.6210 1.3350 0.1970 0.088 Uiso 1 1 calc R . .
C71 C 0.547(2) 1.232(2) 0.2610(12) 0.083(13) Uani 1 1 d G . .
H71 H 0.5739 1.2788 0.2954 0.099 Uiso 1 1 calc R . .
C65 C 0.433(3) 1.070(3) 0.3244(15) 0.070(12) Uani 1 1 d . . .
H65A H 0.4968 1.0652 0.3529 0.084 Uiso 1 1 calc R . .
H65B H 0.3802 1.1087 0.3461 0.084 Uiso 1 1 calc R . .
C72 C 0.919(2) 1.020(2) -0.2075(15) 0.054(10) Uani 1 1 d G . .
C73 C 0.894(2) 0.999(2) -0.2694(17) 0.091(14) Uani 1 1 d G . .
C74 C 0.946(3) 1.071(3) -0.3117(11) 0.065(12) Uani 1 1 d G . .
C75 C 1.025(3) 1.164(2) -0.2922(15) 0.067(12) Uani 1 1 d G . .
C76 C 1.050(2) 1.1851(17) -0.2303(17) 0.068(11) Uani 1 1 d G . .
C77 C 0.997(2) 1.113(3) -0.1880(11) 0.053(10) Uani 1 1 d G . .
F1 F -0.1208(18) 1.2938(14) -0.0693(8) 0.064(6) Uani 1 1 d . . .
F2 F -0.0285(17) 1.4080(14) -0.1633(9) 0.070(6) Uani 1 1 d . . .
F3 F 0.1734(16) 1.5492(15) -0.1500(9) 0.073(6) Uani 1 1 d . . .
F4 F 0.2944(17) 1.5739(14) -0.0418(8) 0.066(6) Uani 1 1 d . . .
F5 F 0.2071(17) 1.4609(14) 0.0537(8) 0.065(6) Uani 1 1 d . . .
F6 F 0.8253(17) 0.9112(16) -0.2919(9) 0.075(6) Uani 1 1 d . . .
F7 F 0.9362(19) 1.0551(17) -0.3687(11) 0.087(7) Uani 1 1 d . . .
F8 F 1.0835(19) 1.2309(16) -0.3281(10) 0.089(7) Uani 1 1 d . . .
F9 F 1.1244(18) 1.2777(16) -0.2106(9) 0.081(7) Uani 1 1 d . . .
F10 F 1.024(2) 1.1351(19) -0.1279(12) 0.110(8) Uani 1 1 d . . .
N1 N -0.150(2) 1.129(2) 0.1653(12) 0.040(7) Uani 1 1 d . . .
N2 N 0.723(3) 0.769(3) -0.0449(16) 0.075(10) Uani 1 1 d . . .
O1 O -0.3574(18) 0.8385(17) 0.3272(9) 0.044(6) Uani 1 1 d . . .
O2 O 0.516(2) 0.588(2) 0.1618(10) 0.082(9) Uani 1 1 d . . .
C32 C 0.784(4) 0.817(4) -0.087(2) 0.110(16) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C7 2.01(4) . ?
Au1 C1 2.029(16) . ?
Au2 C32 1.83(5) . ?
Au2 C72 2.071(19) . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C2 F1 1.30(2) . ?
C2 C3 1.3900 . ?
C3 F2 1.34(3) . ?
C3 C4 1.3900 . ?
C4 F3 1.37(2) . ?
C4 C5 1.3900 . ?
C5 F4 1.38(2) . ?
C5 C6 1.3900 . ?
C6 F5 1.33(3) . ?
C7 N1 1.13(3) . ?
C8 C9 1.3900 . ?
C8 C13 1.3900 . ?
C8 N1 1.39(3) . ?
C9 C10 1.3900 . ?
C9 H9 0.9500 . ?
C10 C11 1.3900 . ?
C10 H10 0.9500 . ?
C11 O1 1.29(2) . ?
C11 C12 1.3900 . ?
C12 C13 1.3900 . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 O1 1.33(3) . ?
C14 C15 1.61(4) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.49(5) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.62(4) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 C18 1.49(4) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C19 1.54(4) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C33 1.54(4) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 C33 1.52(4) . ?
C20 C21 1.58(4) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.50(4) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 C23 1.49(4) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C24 1.48(4) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 C25 1.42(4) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C25 O2 1.47(4) . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C26 O2 1.37(3) . ?
C26 C27 1.3900 . ?
C26 C31 1.3900 . ?
C27 C28 1.3900 . ?
C27 H27 0.9500 . ?
C28 C29 1.3900 . ?
C28 H28 0.9500 . ?
C29 C30 1.3900 . ?
C29 N2 1.41(4) . ?
C30 C31 1.3900 . ?
C30 H30 0.9500 . ?
C31 H31 0.9500 . ?
C33 C34 1.54(3) . ?
C33 C37 1.55(3) . ?
C35 C34 1.3900 . ?
C35 C41 1.3900 . ?
C35 C36 1.46(2) . ?
C34 C38 1.3900 . ?
C38 C39 1.3900 . ?
C38 H38 0.9500 . ?
C39 C40 1.3900 . ?
C39 C42 1.51(3) . ?
C40 C41 1.3900 . ?
C40 H40 0.9500 . ?
C41 H41 0.9500 . ?
C42 C47 1.34(4) . ?
C42 C43 1.44(4) . ?
C43 C44 1.32(4) . ?
C43 H43 0.9500 . ?
C44 C45 1.35(5) . ?
C44 C50 1.59(5) . ?
C45 C46 1.40(5) . ?
C45 C48 1.47(4) . ?
C46 C47 1.42(4) . ?
C46 H46 0.9500 . ?
C47 H47 0.9500 . ?
C48 C49 1.3900 . ?
C48 C54 1.3900 . ?
C49 C51 1.3900 . ?
C49 C50 1.56(4) . ?
C51 C52 1.3900 . ?
C51 H51 0.9500 . ?
C52 C53 1.3900 . ?
C52 H52 0.9500 . ?
C53 C54 1.3900 . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C37 C36 1.3900 . ?
C37 C58 1.3900 . ?
C36 C55 1.3900 . ?
C55 C56 1.3900 . ?
C55 H55 0.9500 . ?
C56 C57 1.3900 . ?
C56 H56 0.9500 . ?
C57 C58 1.3900 . ?
C57 C59 1.53(3) . ?
C58 H58 0.9500 . ?
C59 C64 1.38(4) . ?
C59 C60 1.43(4) . ?
C60 C61 1.33(4) . ?
C60 H60 0.9500 . ?
C61 C62 1.41(4) . ?
C61 C65 1.46(4) . ?
C62 C63 1.17(4) . ?
C62 C67 1.58(4) . ?
C63 C64 1.34(4) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C66 C67 1.3900 . ?
C66 C71 1.3900 . ?
C66 C65 1.51(4) . ?
C67 C68 1.3900 . ?
C68 C69 1.3900 . ?
C68 H68 0.9500 . ?
C69 C70 1.3900 . ?
C69 H69 0.9500 . ?
C70 C71 1.3900 . ?
C70 H70 0.9500 . ?
C71 H71 0.9500 . ?
C65 H65A 0.9900 . ?
C65 H65B 0.9900 . ?
C72 C73 1.3900 . ?
C72 C77 1.3900 . ?
C73 F6 1.31(3) . ?
C73 C74 1.3900 . ?
C74 F7 1.26(3) . ?
C74 C75 1.3900 . ?
C75 F8 1.29(2) . ?
C75 C76 1.3900 . ?
C76 F9 1.37(3) . ?
C76 C77 1.3900 . ?
C77 F10 1.35(3) . ?
N2 C32 1.28(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Au1 C1 176.9(12) . . ?
C32 Au2 C72 176.8(18) . . ?
C2 C1 C6 120.0 . . ?
C2 C1 Au1 121.6(18) . . ?
C6 C1 Au1 118.4(19) . . ?
F1 C2 C3 120(2) . . ?
F1 C2 C1 120(2) . . ?
C3 C2 C1 120.0 . . ?
F2 C3 C2 119(2) . . ?
F2 C3 C4 121(2) . . ?
C2 C3 C4 120.0 . . ?
F3 C4 C5 124(2) . . ?
F3 C4 C3 116(2) . . ?
C5 C4 C3 120.0 . . ?
F4 C5 C4 115(2) . . ?
F4 C5 C6 125(2) . . ?
C4 C5 C6 120.0 . . ?
F5 C6 C5 112(2) . . ?
F5 C6 C1 128(2) . . ?
C5 C6 C1 120.0 . . ?
N1 C7 Au1 170(3) . . ?
C9 C8 C13 120.0 . . ?
C9 C8 N1 120(2) . . ?
C13 C8 N1 120(2) . . ?
C8 C9 C10 120.0 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C10 C11 120.0 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 H10 120.0 . . ?
O1 C11 C12 117(2) . . ?
O1 C11 C10 123(2) . . ?
C12 C11 C10 120.0 . . ?
C11 C12 C13 120.0 . . ?
C11 C12 H12 120.0 . . ?
C13 C12 H12 120.0 . . ?
C12 C13 C8 120.0 . . ?
C12 C13 H13 120.0 . . ?
C8 C13 H13 120.0 . . ?
O1 C14 C15 111(3) . . ?
O1 C14 H14A 109.5 . . ?
C15 C14 H14A 109.5 . . ?
O1 C14 H14B 109.5 . . ?
C15 C14 H14B 109.5 . . ?
H14A C14 H14B 108.0 . . ?
C16 C15 C14 115(3) . . ?
C16 C15 H15A 108.4 . . ?
C14 C15 H15A 108.4 . . ?
C16 C15 H15B 108.4 . . ?
C14 C15 H15B 108.4 . . ?
H15A C15 H15B 107.5 . . ?
C15 C16 C17 113(3) . . ?
C15 C16 H16A 108.9 . . ?
C17 C16 H16A 108.9 . . ?
C15 C16 H16B 108.9 . . ?
C17 C16 H16B 108.9 . . ?
H16A C16 H16B 107.7 . . ?
C18 C17 C16 113(3) . . ?
C18 C17 H17A 109.0 . . ?
C16 C17 H17A 109.0 . . ?
C18 C17 H17B 109.0 . . ?
C16 C17 H17B 109.0 . . ?
H17A C17 H17B 107.8 . . ?
C17 C18 C19 108(3) . . ?
C17 C18 H18A 110.0 . . ?
C19 C18 H18A 110.0 . . ?
C17 C18 H18B 110.0 . . ?
C19 C18 H18B 110.0 . . ?
H18A C18 H18B 108.4 . . ?
C33 C19 C18 114(3) . . ?
C33 C19 H19A 108.7 . . ?
C18 C19 H19A 108.7 . . ?
C33 C19 H19B 108.7 . . ?
C18 C19 H19B 108.7 . . ?
H19A C19 H19B 107.6 . . ?
C33 C20 C21 117(3) . . ?
C33 C20 H20A 108.1 . . ?
C21 C20 H20A 108.1 . . ?
C33 C20 H20B 108.1 . . ?
C21 C20 H20B 108.1 . . ?
H20A C20 H20B 107.3 . . ?
C22 C21 C20 123(3) . . ?
C22 C21 H21A 106.6 . . ?
C20 C21 H21A 106.6 . . ?
C22 C21 H21B 106.6 . . ?
C20 C21 H21B 106.6 . . ?
H21A C21 H21B 106.6 . . ?
C23 C22 C21 107(3) . . ?
C23 C22 H22A 110.3 . . ?
C21 C22 H22A 110.3 . . ?
C23 C22 H22B 110.3 . . ?
C21 C22 H22B 110.3 . . ?
H22A C22 H22B 108.6 . . ?
C24 C23 C22 111(3) . . ?
C24 C23 H23A 109.4 . . ?
C22 C23 H23A 109.4 . . ?
C24 C23 H23B 109.4 . . ?
C22 C23 H23B 109.4 . . ?
H23A C23 H23B 108.0 . . ?
C25 C24 C23 118(3) . . ?
C25 C24 H24A 107.9 . . ?
C23 C24 H24A 107.9 . . ?
C25 C24 H24B 107.9 . . ?
C23 C24 H24B 107.9 . . ?
H24A C24 H24B 107.2 . . ?
C24 C25 O2 114(3) . . ?
C24 C25 H25A 108.8 . . ?
O2 C25 H25A 108.8 . . ?
C24 C25 H25B 108.8 . . ?
O2 C25 H25B 108.8 . . ?
H25A C25 H25B 107.7 . . ?
O2 C26 C27 127(3) . . ?
O2 C26 C31 113(3) . . ?
C27 C26 C31 120.0 . . ?
C28 C27 C26 120.0 . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C27 C28 C29 120.0 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 H28 120.0 . . ?
C30 C29 C28 120.0 . . ?
C30 C29 N2 117(3) . . ?
C28 C29 N2 122(3) . . ?
C29 C30 C31 120.0 . . ?
C29 C30 H30 120.0 . . ?
C31 C30 H30 120.0 . . ?
C30 C31 C26 120.0 . . ?
C30 C31 H31 120.0 . . ?
C26 C31 H31 120.0 . . ?
C20 C33 C19 106(3) . . ?
C20 C33 C34 113(3) . . ?
C19 C33 C34 111(2) . . ?
C20 C33 C37 112(2) . . ?
C19 C33 C37 116(2) . . ?
C34 C33 C37 98(2) . . ?
C34 C35 C41 120.0 . . ?
C34 C35 C36 110(2) . . ?
C41 C35 C36 130(2) . . ?
C35 C34 C38 120.0 . . ?
C35 C34 C33 111(2) . . ?
C38 C34 C33 129(2) . . ?
C39 C38 C34 120.0 . . ?
C39 C38 H38 120.0 . . ?
C34 C38 H38 120.0 . . ?
C38 C39 C40 120.0 . . ?
C38 C39 C42 120(2) . . ?
C40 C39 C42 120(2) . . ?
C41 C40 C39 120.0 . . ?
C41 C40 H40 120.0 . . ?
C39 C40 H40 120.0 . . ?
C40 C41 C35 120.0 . . ?
C40 C41 H41 120.0 . . ?
C35 C41 H41 120.0 . . ?
C47 C42 C43 117(3) . . ?
C47 C42 C39 123(3) . . ?
C43 C42 C39 120(3) . . ?
C44 C43 C42 121(3) . . ?
C44 C43 H43 119.7 . . ?
C42 C43 H43 119.7 . . ?
C43 C44 C45 123(3) . . ?
C43 C44 C50 125(4) . . ?
C45 C44 C50 112(3) . . ?
C44 C45 C46 119(3) . . ?
C44 C45 C48 111(3) . . ?
C46 C45 C48 130(4) . . ?
C45 C46 C47 117(3) . . ?
C45 C46 H46 121.4 . . ?
C47 C46 H46 121.4 . . ?
C42 C47 C46 123(3) . . ?
C42 C47 H47 118.6 . . ?
C46 C47 H47 118.6 . . ?
C49 C48 C54 120.0 . . ?
C49 C48 C45 107(3) . . ?
C54 C48 C45 133(3) . . ?
C51 C49 C48 120.0 . . ?
C51 C49 C50 127(2) . . ?
C48 C49 C50 113(2) . . ?
C52 C51 C49 120.0 . . ?
C52 C51 H51 120.0 . . ?
C49 C51 H51 120.0 . . ?
C53 C52 C51 120.0 . . ?
C53 C52 H52 120.0 . . ?
C51 C52 H52 120.0 . . ?
C52 C53 C54 120.0 . . ?
C52 C53 H53 120.0 . . ?
C54 C53 H53 120.0 . . ?
C53 C54 C48 120.0 . . ?
C53 C54 H54 120.0 . . ?
C48 C54 H54 120.0 . . ?
C49 C50 C44 97(3) . . ?
C49 C50 H50A 112.4 . . ?
C44 C50 H50A 112.4 . . ?
C49 C50 H50B 112.4 . . ?
C44 C50 H50B 112.4 . . ?
H50A C50 H50B 110.0 . . ?
C36 C37 C58 120.0 . . ?
C36 C37 C33 113(2) . . ?
C58 C37 C33 127(2) . . ?
C37 C36 C55 120.0 . . ?
C37 C36 C35 107(2) . . ?
C55 C36 C35 133(2) . . ?
C56 C55 C36 120.0 . . ?
C56 C55 H55 120.0 . . ?
C36 C55 H55 120.0 . . ?
C55 C56 C57 120.0 . . ?
C55 C56 H56 120.0 . . ?
C57 C56 H56 120.0 . . ?
C58 C57 C56 120.0 . . ?
C58 C57 C59 123(3) . . ?
C56 C57 C59 117(3) . . ?
C57 C58 C37 120.0 . . ?
C57 C58 H58 120.0 . . ?
C37 C58 H58 120.0 . . ?
C64 C59 C60 118(2) . . ?
C64 C59 C57 121(4) . . ?
C60 C59 C57 120(3) . . ?
C61 C60 C59 119(3) . . ?
C61 C60 H60 120.4 . . ?
C59 C60 H60 120.4 . . ?
C60 C61 C62 117(3) . . ?
C60 C61 C65 130(4) . . ?
C62 C61 C65 113(3) . . ?
C63 C62 C61 121(3) . . ?
C63 C62 C67 137(4) . . ?
C61 C62 C67 102(3) . . ?
C62 C63 C64 129(3) . . ?
C62 C63 H63 115.4 . . ?
C64 C63 H63 115.4 . . ?
C63 C64 C59 115(3) . . ?
C63 C64 H64 122.5 . . ?
C59 C64 H64 122.5 . . ?
C67 C66 C71 120.0 . . ?
C67 C66 C65 106(3) . . ?
C71 C66 C65 134(3) . . ?
C68 C67 C66 120.0 . . ?
C68 C67 C62 129(3) . . ?
C66 C67 C62 111(3) . . ?
C67 C68 C69 120.0 . . ?
C67 C68 H68 120.0 . . ?
C69 C68 H68 120.0 . . ?
C70 C69 C68 120.0 . . ?
C70 C69 H69 120.0 . . ?
C68 C69 H69 120.0 . . ?
C69 C70 C71 120.0 . . ?
C69 C70 H70 120.0 . . ?
C71 C70 H70 120.0 . . ?
C70 C71 C66 120.0 . . ?
C70 C71 H71 120.0 . . ?
C66 C71 H71 120.0 . . ?
C61 C65 C66 107(3) . . ?
C61 C65 H65A 110.3 . . ?
C66 C65 H65A 110.3 . . ?
C61 C65 H65B 110.3 . . ?
C66 C65 H65B 110.3 . . ?
H65A C65 H65B 108.6 . . ?
C73 C72 C77 120.0 . . ?
C73 C72 Au2 120(2) . . ?
C77 C72 Au2 120(2) . . ?
F6 C73 C74 116(3) . . ?
F6 C73 C72 124(3) . . ?
C74 C73 C72 120.0 . . ?
F7 C74 C73 125(3) . . ?
F7 C74 C75 115(3) . . ?
C73 C74 C75 120.0 . . ?
F8 C75 C74 124(3) . . ?
F8 C75 C76 116(3) . . ?
C74 C75 C76 120.0 . . ?
F9 C76 C75 120(3) . . ?
F9 C76 C77 120(3) . . ?
C75 C76 C77 120.0 . . ?
F10 C77 C76 119(3) . . ?
F10 C77 C72 121(3) . . ?
C76 C77 C72 120.0 . . ?
C7 N1 C8 176(3) . . ?
C32 N2 C29 174(4) . . ?
C11 O1 C14 119(2) . . ?
C26 O2 C25 115(3) . . ?
N2 C32 Au2 163(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 Au1 C1 C2 37(24) . . . . ?
C7 Au1 C1 C6 -144(23) . . . . ?
C6 C1 C2 F1 -176(2) . . . . ?
Au1 C1 C2 F1 4(2) . . . . ?
C6 C1 C2 C3 0.0 . . . . ?
Au1 C1 C2 C3 179.8(16) . . . . ?
F1 C2 C3 F2 -3(2) . . . . ?
C1 C2 C3 F2 -179(2) . . . . ?
F1 C2 C3 C4 176(2) . . . . ?
C1 C2 C3 C4 0.0 . . . . ?
F2 C3 C4 F3 0(2) . . . . ?
C2 C3 C4 F3 -179(2) . . . . ?
F2 C3 C4 C5 179(2) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
F3 C4 C5 F4 -2(2) . . . . ?
C3 C4 C5 F4 179(2) . . . . ?
F3 C4 C5 C6 179(2) . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
F4 C5 C6 F5 2(2) . . . . ?
C4 C5 C6 F5 -179(2) . . . . ?
F4 C5 C6 C1 -179(2) . . . . ?
C4 C5 C6 C1 0.0 . . . . ?
C2 C1 C6 F5 179(3) . . . . ?
Au1 C1 C6 F5 -1(2) . . . . ?
C2 C1 C6 C5 0.0 . . . . ?
Au1 C1 C6 C5 -179.8(15) . . . . ?
C1 Au1 C7 N1 -38(36) . . . . ?
C13 C8 C9 C10 0.0 . . . . ?
N1 C8 C9 C10 180(2) . . . . ?
C8 C9 C10 C11 0.0 . . . . ?
C9 C10 C11 O1 -176(2) . . . . ?
C9 C10 C11 C12 0.0 . . . . ?
O1 C11 C12 C13 176(2) . . . . ?
C10 C11 C12 C13 0.0 . . . . ?
C11 C12 C13 C8 0.0 . . . . ?
C9 C8 C13 C12 0.0 . . . . ?
N1 C8 C13 C12 -180(2) . . . . ?
O1 C14 C15 C16 -52(4) . . . . ?
C14 C15 C16 C17 -72(4) . . . . ?
C15 C16 C17 C18 179(3) . . . . ?
C16 C17 C18 C19 -177(2) . . . . ?
C17 C18 C19 C33 175(2) . . . . ?
C33 C20 C21 C22 -74(3) . . . . ?
C20 C21 C22 C23 -69(4) . . . . ?
C21 C22 C23 C24 177(3) . . . . ?
C22 C23 C24 C25 -179(3) . . . . ?
C23 C24 C25 O2 -179(3) . . . . ?
O2 C26 C27 C28 178(3) . . . . ?
C31 C26 C27 C28 0.0 . . . . ?
C26 C27 C28 C29 0.0 . . . . ?
C27 C28 C29 C30 0.0 . . . . ?
C27 C28 C29 N2 -175(3) . . . . ?
C28 C29 C30 C31 0.0 . . . . ?
N2 C29 C30 C31 175(2) . . . . ?
C29 C30 C31 C26 0.0 . . . . ?
O2 C26 C31 C30 -178(2) . . . . ?
C27 C26 C31 C30 0.0 . . . . ?
C21 C20 C33 C19 -171(2) . . . . ?
C21 C20 C33 C34 -49(3) . . . . ?
C21 C20 C33 C37 61(3) . . . . ?
C18 C19 C33 C20 -180(2) . . . . ?
C18 C19 C33 C34 57(3) . . . . ?
C18 C19 C33 C37 -55(3) . . . . ?
C41 C35 C34 C38 0.0 . . . . ?
C36 C35 C34 C38 178.3(17) . . . . ?
C41 C35 C34 C33 -180(2) . . . . ?
C36 C35 C34 C33 -1(2) . . . . ?
C20 C33 C34 C35 119(2) . . . . ?
C19 C33 C34 C35 -122(2) . . . . ?
C37 C33 C34 C35 0(2) . . . . ?
C20 C33 C34 C38 -61(3) . . . . ?
C19 C33 C34 C38 58(3) . . . . ?
C37 C33 C34 C38 -179.3(15) . . . . ?
C35 C34 C38 C39 0.0 . . . . ?
C33 C34 C38 C39 180(2) . . . . ?
C34 C38 C39 C40 0.0 . . . . ?
C34 C38 C39 C42 -176(2) . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C42 C39 C40 C41 176(2) . . . . ?
C39 C40 C41 C35 0.0 . . . . ?
C34 C35 C41 C40 0.0 . . . . ?
C36 C35 C41 C40 -178(2) . . . . ?
C38 C39 C42 C47 -42(4) . . . . ?
C40 C39 C42 C47 141(3) . . . . ?
C38 C39 C42 C43 141(2) . . . . ?
C40 C39 C42 C43 -36(3) . . . . ?
C47 C42 C43 C44 0(5) . . . . ?
C39 C42 C43 C44 178(3) . . . . ?
C42 C43 C44 C45 0(5) . . . . ?
C42 C43 C44 C50 -174(3) . . . . ?
C43 C44 C45 C46 -1(6) . . . . ?
C50 C44 C45 C46 174(3) . . . . ?
C43 C44 C45 C48 -174(3) . . . . ?
C50 C44 C45 C48 1(4) . . . . ?
C44 C45 C46 C47 1(5) . . . . ?
C48 C45 C46 C47 173(3) . . . . ?
C43 C42 C47 C46 0(5) . . . . ?
C39 C42 C47 C46 -177(3) . . . . ?
C45 C46 C47 C42 0(5) . . . . ?
C44 C45 C48 C49 -6(3) . . . . ?
C46 C45 C48 C49 -178(3) . . . . ?
C44 C45 C48 C54 178(2) . . . . ?
C46 C45 C48 C54 6(5) . . . . ?
C54 C48 C49 C51 0.0 . . . . ?
C45 C48 C49 C51 -176(2) . . . . ?
C54 C48 C49 C50 -175(2) . . . . ?
C45 C48 C49 C50 9(3) . . . . ?
C48 C49 C51 C52 0.0 . . . . ?
C50 C49 C51 C52 174(3) . . . . ?
C49 C51 C52 C53 0.0 . . . . ?
C51 C52 C53 C54 0.0 . . . . ?
C52 C53 C54 C48 0.0 . . . . ?
C49 C48 C54 C53 0.0 . . . . ?
C45 C48 C54 C53 175(3) . . . . ?
C51 C49 C50 C44 177.6(18) . . . . ?
C48 C49 C50 C44 -8(3) . . . . ?
C43 C44 C50 C49 179(3) . . . . ?
C45 C44 C50 C49 4(4) . . . . ?
C20 C33 C37 C36 -119(2) . . . . ?
C19 C33 C37 C36 120(2) . . . . ?
C34 C33 C37 C36 1(2) . . . . ?
C20 C33 C37 C58 60(3) . . . . ?
C19 C33 C37 C58 -62(3) . . . . ?
C34 C33 C37 C58 179.5(15) . . . . ?
C58 C37 C36 C55 0.0 . . . . ?
C33 C37 C36 C55 179(2) . . . . ?
C58 C37 C36 C35 179.5(17) . . . . ?
C33 C37 C36 C35 -2(2) . . . . ?
C34 C35 C36 C37 1.9(16) . . . . ?
C41 C35 C36 C37 180.0(13) . . . . ?
C34 C35 C36 C55 -178.6(15) . . . . ?
C41 C35 C36 C55 -1(3) . . . . ?
C37 C36 C55 C56 0.0 . . . . ?
C35 C36 C55 C56 -179(2) . . . . ?
C36 C55 C56 C57 0.0 . . . . ?
C55 C56 C57 C58 0.0 . . . . ?
C55 C56 C57 C59 -178(2) . . . . ?
C56 C57 C58 C37 0.0 . . . . ?
C59 C57 C58 C37 178(2) . . . . ?
C36 C37 C58 C57 0.0 . . . . ?
C33 C37 C58 C57 -179(2) . . . . ?
C58 C57 C59 C64 -25(4) . . . . ?
C56 C57 C59 C64 154(3) . . . . ?
C58 C57 C59 C60 148(3) . . . . ?
C56 C57 C59 C60 -34(4) . . . . ?
C64 C59 C60 C61 -10(5) . . . . ?
C57 C59 C60 C61 177(3) . . . . ?
C59 C60 C61 C62 9(5) . . . . ?
C59 C60 C61 C65 -177(3) . . . . ?
C60 C61 C62 C63 -5(5) . . . . ?
C65 C61 C62 C63 179(3) . . . . ?
C60 C61 C62 C67 177(3) . . . . ?
C65 C61 C62 C67 1(3) . . . . ?
C61 C62 C63 C64 4(6) . . . . ?
C67 C62 C63 C64 -179(3) . . . . ?
C62 C63 C64 C59 -5(6) . . . . ?
C60 C59 C64 C63 8(5) . . . . ?
C57 C59 C64 C63 -179(3) . . . . ?
C71 C66 C67 C68 0.0 . . . . ?
C65 C66 C67 C68 179(2) . . . . ?
C71 C66 C67 C62 178(2) . . . . ?
C65 C66 C67 C62 -3(2) . . . . ?
C63 C62 C67 C68 1(5) . . . . ?
C61 C62 C67 C68 178.8(19) . . . . ?
C63 C62 C67 C66 -176(4) . . . . ?
C61 C62 C67 C66 1(3) . . . . ?
C66 C67 C68 C69 0.0 . . . . ?
C62 C67 C68 C69 -177(3) . . . . ?
C67 C68 C69 C70 0.0 . . . . ?
C68 C69 C70 C71 0.0 . . . . ?
C69 C70 C71 C66 0.0 . . . . ?
C67 C66 C71 C70 0.0 . . . . ?
C65 C66 C71 C70 -179(3) . . . . ?
C60 C61 C65 C66 -178(3) . . . . ?
C62 C61 C65 C66 -3(4) . . . . ?
C67 C66 C65 C61 3(3) . . . . ?
C71 C66 C65 C61 -177(2) . . . . ?
C32 Au2 C72 C73 131(32) . . . . ?
C32 Au2 C72 C77 -47(32) . . . . ?
C77 C72 C73 F6 177(3) . . . . ?
Au2 C72 C73 F6 -2(3) . . . . ?
C77 C72 C73 C74 0.0 . . . . ?
Au2 C72 C73 C74 -178.7(18) . . . . ?
F6 C73 C74 F7 -3(3) . . . . ?
C72 C73 C74 F7 174(3) . . . . ?
F6 C73 C74 C75 -177(3) . . . . ?
C72 C73 C74 C75 0.0 . . . . ?
F7 C74 C75 F8 0(3) . . . . ?
C73 C74 C75 F8 175(3) . . . . ?
F7 C74 C75 C76 -175(3) . . . . ?
C73 C74 C75 C76 0.0 . . . . ?
F8 C75 C76 F9 6(3) . . . . ?
C74 C75 C76 F9 -178(2) . . . . ?
F8 C75 C76 C77 -175(2) . . . . ?
C74 C75 C76 C77 0.0 . . . . ?
F9 C76 C77 F10 -2(3) . . . . ?
C75 C76 C77 F10 179(3) . . . . ?
F9 C76 C77 C72 178(2) . . . . ?
C75 C76 C77 C72 0.0 . . . . ?
C73 C72 C77 F10 -179(3) . . . . ?
Au2 C72 C77 F10 -1(2) . . . . ?
C73 C72 C77 C76 0.0 . . . . ?
Au2 C72 C77 C76 178.7(18) . . . . ?
Au1 C7 N1 C8 136(33) . . . . ?
C9 C8 N1 C7 -124(40) . . . . ?
C13 C8 N1 C7 56(41) . . . . ?
C30 C29 N2 C32 31(35) . . . . ?
C28 C29 N2 C32 -153(33) . . . . ?
C12 C11 O1 C14 -175(2) . . . . ?
C10 C11 O1 C14 1(3) . . . . ?
C15 C14 O1 C11 168(3) . . . . ?
C27 C26 O2 C25 2(4) . . . . ?
C31 C26 O2 C25 -180(3) . . . . ?
C24 C25 O2 C26 173(3) . . . . ?
C29 N2 C32 Au2 -136(28) . . . . ?
C72 Au2 C32 N2 129(28) . . . . ?

_diffrn_measured_fraction_theta_max 0.949
_diffrn_reflns_theta_full        43.40
_diffrn_measured_fraction_theta_full 0.949
_refine_diff_density_max         2.444
_refine_diff_density_min         -1.083
_refine_diff_density_rms         0.263
_database_code_depnum_ccdc_archive 'CCDC 1002798'
