# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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#  data retrieval see:
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#  from this site to visualise CIF-encoded structures and 
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data_liuxh0307
_audit_creation_date             2014-03-10
_audit_creation_method           
;
Olex2 1.2
(compiled 2014.02.28 svn.r2899 for OlexSys, GUI svn.r4781)
;
_shelxl_version_number           2013-2
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         'C32 H28 N2 O2'
_chemical_formula_sum            'C32 H28 N2 O2'
_chemical_formula_weight         472.56
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   6.5198(3)
_cell_length_b                   16.3244(7)
_cell_length_c                   24.2413(9)
_cell_angle_alpha                90
_cell_angle_beta                 94.884(4)
_cell_angle_gamma                90
_cell_volume                     2570.66(18)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    2666
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.6710
_cell_measurement_theta_min      3.8270
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.076
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.56560
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.221
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1000
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.25
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_av_unetI/netI     0.0576
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.885
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            10786
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.885
_diffrn_reflns_theta_full        25.500
_diffrn_reflns_theta_max         28.477
_diffrn_reflns_theta_min         3.012
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 16.0733
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.885
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0117501000
_diffrn_orient_matrix_UB_12      -0.0322053000
_diffrn_orient_matrix_UB_13      -0.0196603000
_diffrn_orient_matrix_UB_21      0.0433167000
_diffrn_orient_matrix_UB_22      0.0251394000
_diffrn_orient_matrix_UB_23      -0.0198500000
_diffrn_orient_matrix_UB_31      0.0995747000
_diffrn_orient_matrix_UB_32      -0.0147309000
_diffrn_orient_matrix_UB_33      0.0090632000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3293
_reflns_number_total             5764
_reflns_odcompleteness_completeness 99.82
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection       
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction        
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         0.155
_refine_diff_density_min         -0.172
_refine_diff_density_rms         0.035
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     326
_refine_ls_number_reflns         5764
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1122
_refine_ls_R_factor_gt           0.0667
_refine_ls_restrained_S_all      1.073
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
;
 w=1/[σ²(Fo²)+(0.0532P)²+0.6680P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1549
_refine_ls_wR_factor_ref         0.1843
_refine_special_details          
;
 ?
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C9(H9)
2.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B), C18(H18A,H18B)
2.c Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C11(H11), C12(H12), C14(H14), C15(H15),
 C20(H20), C21(H21), C22(H22), C23(H23), C24(H24), C28(H28), C29(H29), C30(H30),
  C31(H31), C32(H32)
2.d Idealised Me refined as rotating group:
 C16(H16A,H16B,H16C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.1282(2) 0.68600(10) 0.15336(6) 0.0490(4) Uani 1 1 d . . . . .
O2 O 0.6514(3) 0.73053(13) 0.17341(8) 0.0759(6) Uani 1 1 d . . . . .
N1 N 0.2060(3) 0.67336(13) 0.28703(8) 0.0569(5) Uani 1 1 d . . . . .
N2 N 0.4059(3) 0.68851(14) 0.10373(8) 0.0621(6) Uani 1 1 d . . . . .
C1 C -0.0063(4) 0.6461(2) 0.27662(12) 0.0782(9) Uani 1 1 d . . . . .
H1A H -0.0656 0.6702 0.2423 0.094 Uiso 1 1 calc R . . . .
H1B H -0.0850 0.6652 0.3063 0.094 Uiso 1 1 calc R . . . .
C2 C -0.0222(5) 0.5557(2) 0.27278(14) 0.0930(11) Uani 1 1 d . . . . .
H2A H -0.1605 0.5409 0.2583 0.112 Uiso 1 1 calc R . . . .
H2B H 0.0021 0.5323 0.3095 0.112 Uiso 1 1 calc R . . . .
C3 C 0.1301(5) 0.5202(2) 0.23592(12) 0.0801(9) Uani 1 1 d . . . . .
C4 C 0.1074(8) 0.4409(3) 0.21567(17) 0.1226(16) Uani 1 1 d . . . . .
H4 H -0.0084 0.4109 0.2231 0.147 Uiso 1 1 calc R . . . .
C5 C 0.2504(10) 0.4054(3) 0.18506(19) 0.133(2) Uani 1 1 d . . . . .
H5 H 0.2308 0.3521 0.1721 0.160 Uiso 1 1 calc R . . . .
C6 C 0.4219(8) 0.4480(3) 0.17338(15) 0.1128(15) Uani 1 1 d . . . . .
H6 H 0.5203 0.4236 0.1531 0.135 Uiso 1 1 calc R . . . .
C7 C 0.4483(5) 0.5287(2) 0.19217(11) 0.0817(9) Uani 1 1 d . . . . .
H7 H 0.5640 0.5583 0.1841 0.098 Uiso 1 1 calc R . . . .
C8 C 0.3019(4) 0.56488(16) 0.22298(10) 0.0623(7) Uani 1 1 d . . . . .
C9 C 0.3304(3) 0.65283(15) 0.24179(9) 0.0508(6) Uani 1 1 d . . . . .
H9 H 0.4747 0.6586 0.2562 0.061 Uiso 1 1 calc R . . . .
C10 C 0.2995(4) 0.67505(16) 0.34168(9) 0.0542(6) Uani 1 1 d . . . . .
C11 C 0.1980(4) 0.64970(19) 0.38679(11) 0.0710(8) Uani 1 1 d . . . . .
H11 H 0.0637 0.6302 0.3814 0.085 Uiso 1 1 calc R . . . .
C12 C 0.2962(5) 0.6533(2) 0.43993(11) 0.0797(9) Uani 1 1 d . . . . .
H12 H 0.2244 0.6364 0.4695 0.096 Uiso 1 1 calc R . . . .
C13 C 0.4942(5) 0.68069(18) 0.45069(11) 0.0720(8) Uani 1 1 d . . . . .
C14 C 0.5916(4) 0.70748(18) 0.40594(11) 0.0709(8) Uani 1 1 d . . . . .
H14 H 0.7251 0.7276 0.4117 0.085 Uiso 1 1 calc R . . . .
C15 C 0.4970(4) 0.70536(17) 0.35251(10) 0.0622(7) Uani 1 1 d . . . . .
H15 H 0.5676 0.7247 0.3234 0.075 Uiso 1 1 calc R . . . .
C16 C 0.6022(6) 0.6806(2) 0.50861(12) 0.1073(13) Uani 1 1 d . . . . .
H16A H 0.7446 0.6946 0.5068 0.161 Uiso 1 1 calc GR . . . .
H16B H 0.5923 0.6271 0.5246 0.161 Uiso 1 1 calc GR . . . .
H16C H 0.5383 0.7200 0.5310 0.161 Uiso 1 1 calc GR . . . .
C17 C 0.2948(3) 0.71370(14) 0.19255(9) 0.0479(5) Uani 1 1 d . . . . .
C18 C 0.2472(4) 0.80047(15) 0.21108(10) 0.0615(7) Uani 1 1 d . . . . .
H18A H 0.1165 0.7997 0.2274 0.074 Uiso 1 1 calc R . . . .
H18B H 0.3521 0.8168 0.2398 0.074 Uiso 1 1 calc R . . . .
C19 C 0.2365(4) 0.86415(15) 0.16611(10) 0.0564(6) Uani 1 1 d . . . . .
C20 C 0.4013(4) 0.91550(18) 0.15959(12) 0.0729(8) Uani 1 1 d . . . . .
H20 H 0.5210 0.9099 0.1830 0.087 Uiso 1 1 calc R . . . .
C21 C 0.3917(6) 0.97484(19) 0.11909(15) 0.0877(10) Uani 1 1 d . . . . .
H21 H 0.5034 1.0093 0.1156 0.105 Uiso 1 1 calc R . . . .
C22 C 0.2173(6) 0.9829(2) 0.08411(13) 0.0920(10) Uani 1 1 d . . . . .
H22 H 0.2108 1.0223 0.0563 0.110 Uiso 1 1 calc R . . . .
C23 C 0.0526(6) 0.93297(19) 0.08991(13) 0.0854(10) Uani 1 1 d . . . . .
H23 H -0.0662 0.9390 0.0662 0.102 Uiso 1 1 calc R . . . .
C24 C 0.0603(4) 0.87356(17) 0.13061(12) 0.0696(8) Uani 1 1 d . . . . .
H24 H -0.0529 0.8399 0.1342 0.084 Uiso 1 1 calc R . . . .
C25 C 0.4755(4) 0.71308(16) 0.15704(10) 0.0573(6) Uani 1 1 d . . . . .
C26 C 0.2115(4) 0.67397(15) 0.10536(9) 0.0517(6) Uani 1 1 d . . . . .
C27 C 0.0727(4) 0.64465(16) 0.05917(10) 0.0601(7) Uani 1 1 d . . . . .
C28 C 0.1397(5) 0.6421(2) 0.00634(12) 0.0846(9) Uani 1 1 d . . . . .
H28 H 0.2713 0.6600 0.0003 0.101 Uiso 1 1 calc R . . . .
C29 C 0.0104(7) 0.6128(3) -0.03709(13) 0.1072(13) Uani 1 1 d . . . . .
H29 H 0.0545 0.6114 -0.0726 0.129 Uiso 1 1 calc R . . . .
C30 C -0.1828(7) 0.5856(3) -0.02830(16) 0.1111(14) Uani 1 1 d . . . . .
H30 H -0.2685 0.5650 -0.0577 0.133 Uiso 1 1 calc R . . . .
C31 C -0.2504(5) 0.5885(2) 0.02377(15) 0.1023(12) Uani 1 1 d . . . . .
H31 H -0.3817 0.5701 0.0297 0.123 Uiso 1 1 calc R . . . .
C32 C -0.1225(4) 0.61911(19) 0.06748(12) 0.0784(9) Uani 1 1 d . . . . .
H32 H -0.1692 0.6223 0.1026 0.094 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C17 1.453(2) . ?
O1 C26 1.340(3) . ?
O2 C25 1.215(3) . ?
N1 C1 1.455(3) . ?
N1 C9 1.457(3) . ?
N1 C10 1.411(3) . ?
N2 C25 1.392(3) . ?
N2 C26 1.293(3) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C1 C2 1.481(4) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C2 C3 1.507(5) . ?
C3 C4 1.388(5) . ?
C3 C8 1.395(4) . ?
C4 H4 0.9300 . ?
C4 C5 1.368(6) . ?
C5 H5 0.9300 . ?
C5 C6 1.366(6) . ?
C6 H6 0.9300 . ?
C6 C7 1.400(5) . ?
C7 H7 0.9300 . ?
C7 C8 1.393(4) . ?
C8 C9 1.513(3) . ?
C9 H9 0.9800 . ?
C9 C17 1.555(3) . ?
C10 C11 1.389(3) . ?
C10 C15 1.383(3) . ?
C11 H11 0.9300 . ?
C11 C12 1.390(4) . ?
C12 H12 0.9300 . ?
C12 C13 1.370(4) . ?
C13 C14 1.374(4) . ?
C13 C16 1.516(4) . ?
C14 H14 0.9300 . ?
C14 C15 1.387(3) . ?
C15 H15 0.9300 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C18 1.526(3) . ?
C17 C25 1.517(3) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 C19 1.504(3) . ?
C19 C20 1.383(4) . ?
C19 C24 1.384(3) . ?
C20 H20 0.9300 . ?
C20 C21 1.377(4) . ?
C21 H21 0.9300 . ?
C21 C22 1.365(4) . ?
C22 H22 0.9300 . ?
C22 C23 1.364(4) . ?
C23 H23 0.9300 . ?
C23 C24 1.381(4) . ?
C24 H24 0.9300 . ?
C26 C27 1.459(3) . ?
C27 C28 1.389(4) . ?
C27 C32 1.370(4) . ?
C28 H28 0.9300 . ?
C28 C29 1.377(4) . ?
C29 H29 0.9300 . ?
C29 C30 1.369(5) . ?
C30 H30 0.9300 . ?
C30 C31 1.373(5) . ?
C31 H31 0.9300 . ?
C31 C32 1.384(4) . ?
C32 H32 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C26 O1 C17 106.12(17) . . ?
C1 N1 C9 112.4(2) . . ?
C10 N1 C1 119.8(2) . . ?
C10 N1 C9 119.18(18) . . ?
C26 N2 C25 105.5(2) . . ?
N1 C1 H1A 109.2 . . ?
N1 C1 H1B 109.2 . . ?
N1 C1 C2 112.1(2) . . ?
H1A C1 H1B 107.9 . . ?
C2 C1 H1A 109.2 . . ?
C2 C1 H1B 109.2 . . ?
C1 C2 H2A 109.2 . . ?
C1 C2 H2B 109.2 . . ?
C1 C2 C3 112.0(3) . . ?
H2A C2 H2B 107.9 . . ?
C3 C2 H2A 109.2 . . ?
C3 C2 H2B 109.2 . . ?
C4 C3 C2 120.9(4) . . ?
C4 C3 C8 118.1(4) . . ?
C8 C3 C2 121.0(3) . . ?
C3 C4 H4 119.0 . . ?
C5 C4 C3 121.9(5) . . ?
C5 C4 H4 119.0 . . ?
C4 C5 H5 119.8 . . ?
C6 C5 C4 120.3(4) . . ?
C6 C5 H5 119.8 . . ?
C5 C6 H6 120.3 . . ?
C5 C6 C7 119.4(4) . . ?
C7 C6 H6 120.3 . . ?
C6 C7 H7 119.9 . . ?
C8 C7 C6 120.2(4) . . ?
C8 C7 H7 119.9 . . ?
C3 C8 C9 120.6(3) . . ?
C7 C8 C3 120.0(3) . . ?
C7 C8 C9 119.5(3) . . ?
N1 C9 C8 112.5(2) . . ?
N1 C9 H9 106.8 . . ?
N1 C9 C17 111.98(19) . . ?
C8 C9 H9 106.8 . . ?
C8 C9 C17 111.62(18) . . ?
C17 C9 H9 106.8 . . ?
C11 C10 N1 122.5(2) . . ?
C15 C10 N1 120.4(2) . . ?
C15 C10 C11 117.1(2) . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.3(3) . . ?
C12 C11 H11 119.9 . . ?
C11 C12 H12 118.6 . . ?
C13 C12 C11 122.8(3) . . ?
C13 C12 H12 118.6 . . ?
C12 C13 C14 116.4(2) . . ?
C12 C13 C16 122.1(3) . . ?
C14 C13 C16 121.4(3) . . ?
C13 C14 H14 119.0 . . ?
C13 C14 C15 122.0(3) . . ?
C15 C14 H14 119.0 . . ?
C10 C15 C14 121.3(3) . . ?
C10 C15 H15 119.4 . . ?
C14 C15 H15 119.4 . . ?
C13 C16 H16A 109.5 . . ?
C13 C16 H16B 109.5 . . ?
C13 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
O1 C17 C9 110.94(18) . . ?
O1 C17 C18 108.78(18) . . ?
O1 C17 C25 101.57(17) . . ?
C18 C17 C9 112.83(19) . . ?
C25 C17 C9 111.02(19) . . ?
C25 C17 C18 111.1(2) . . ?
C17 C18 H18A 108.5 . . ?
C17 C18 H18B 108.5 . . ?
H18A C18 H18B 107.5 . . ?
C19 C18 C17 115.2(2) . . ?
C19 C18 H18A 108.5 . . ?
C19 C18 H18B 108.5 . . ?
C20 C19 C18 120.9(2) . . ?
C20 C19 C24 118.3(3) . . ?
C24 C19 C18 120.8(2) . . ?
C19 C20 H20 119.4 . . ?
C21 C20 C19 121.3(3) . . ?
C21 C20 H20 119.4 . . ?
C20 C21 H21 120.2 . . ?
C22 C21 C20 119.7(3) . . ?
C22 C21 H21 120.2 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 120.0(3) . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 119.6 . . ?
C22 C23 C24 120.8(3) . . ?
C24 C23 H23 119.6 . . ?
C19 C24 H24 120.0 . . ?
C23 C24 C19 120.0(3) . . ?
C23 C24 H24 120.0 . . ?
O2 C25 N2 126.5(2) . . ?
O2 C25 C17 124.8(2) . . ?
N2 C25 C17 108.7(2) . . ?
O1 C26 C27 116.3(2) . . ?
N2 C26 O1 118.1(2) . . ?
N2 C26 C27 125.6(2) . . ?
C28 C27 C26 119.6(3) . . ?
C32 C27 C26 120.7(2) . . ?
C32 C27 C28 119.7(3) . . ?
C27 C28 H28 120.2 . . ?
C29 C28 C27 119.7(3) . . ?
C29 C28 H28 120.2 . . ?
C28 C29 H29 119.8 . . ?
C30 C29 C28 120.3(3) . . ?
C30 C29 H29 119.8 . . ?
C29 C30 H30 119.9 . . ?
C29 C30 C31 120.2(3) . . ?
C31 C30 H30 119.9 . . ?
C30 C31 H31 120.1 . . ?
C30 C31 C32 119.8(4) . . ?
C32 C31 H31 120.1 . . ?
C27 C32 C31 120.2(3) . . ?
C27 C32 H32 119.9 . . ?
C31 C32 H32 119.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C17 C18 C19 -63.5(3) . . . . ?
O1 C17 C25 O2 -178.3(2) . . . . ?
O1 C17 C25 N2 1.0(2) . . . . ?
O1 C26 C27 C28 170.7(2) . . . . ?
O1 C26 C27 C32 -9.8(4) . . . . ?
N1 C1 C2 C3 -47.1(3) . . . . ?
N1 C9 C17 O1 -89.8(2) . . . . ?
N1 C9 C17 C18 32.5(3) . . . . ?
N1 C9 C17 C25 158.05(19) . . . . ?
N1 C10 C11 C12 -179.4(3) . . . . ?
N1 C10 C15 C14 -179.9(2) . . . . ?
N2 C26 C27 C28 -9.8(4) . . . . ?
N2 C26 C27 C32 169.7(3) . . . . ?
C1 N1 C9 C8 -47.3(3) . . . . ?
C1 N1 C9 C17 79.4(3) . . . . ?
C1 N1 C10 C11 1.5(4) . . . . ?
C1 N1 C10 C15 -176.2(3) . . . . ?
C1 C2 C3 C4 -163.7(3) . . . . ?
C1 C2 C3 C8 18.9(4) . . . . ?
C2 C3 C4 C5 -175.8(3) . . . . ?
C2 C3 C8 C7 175.3(2) . . . . ?
C2 C3 C8 C9 -5.1(4) . . . . ?
C3 C4 C5 C6 -0.1(6) . . . . ?
C3 C8 C9 N1 18.8(3) . . . . ?
C3 C8 C9 C17 -108.1(2) . . . . ?
C4 C3 C8 C7 -2.2(4) . . . . ?
C4 C3 C8 C9 177.4(3) . . . . ?
C4 C5 C6 C7 -1.1(6) . . . . ?
C5 C6 C7 C8 0.7(5) . . . . ?
C6 C7 C8 C3 1.0(4) . . . . ?
C6 C7 C8 C9 -178.6(2) . . . . ?
C7 C8 C9 N1 -161.7(2) . . . . ?
C7 C8 C9 C17 71.4(3) . . . . ?
C8 C3 C4 C5 1.8(5) . . . . ?
C8 C9 C17 O1 37.4(3) . . . . ?
C8 C9 C17 C18 159.7(2) . . . . ?
C8 C9 C17 C25 -74.8(3) . . . . ?
C9 N1 C1 C2 63.7(3) . . . . ?
C9 N1 C10 C11 -143.9(3) . . . . ?
C9 N1 C10 C15 38.4(3) . . . . ?
C9 C17 C18 C19 173.0(2) . . . . ?
C9 C17 C25 O2 -60.3(3) . . . . ?
C9 C17 C25 N2 119.0(2) . . . . ?
C10 N1 C1 C2 -83.9(3) . . . . ?
C10 N1 C9 C8 100.5(3) . . . . ?
C10 N1 C9 C17 -132.8(2) . . . . ?
C10 C11 C12 C13 -0.5(5) . . . . ?
C11 C10 C15 C14 2.3(4) . . . . ?
C11 C12 C13 C14 2.0(5) . . . . ?
C11 C12 C13 C16 -177.2(3) . . . . ?
C12 C13 C14 C15 -1.4(4) . . . . ?
C13 C14 C15 C10 -0.8(4) . . . . ?
C15 C10 C11 C12 -1.6(4) . . . . ?
C16 C13 C14 C15 177.8(3) . . . . ?
C17 O1 C26 N2 -0.3(3) . . . . ?
C17 O1 C26 C27 179.3(2) . . . . ?
C17 C18 C19 C20 -99.7(3) . . . . ?
C17 C18 C19 C24 81.1(3) . . . . ?
C18 C17 C25 O2 66.2(3) . . . . ?
C18 C17 C25 N2 -114.5(2) . . . . ?
C18 C19 C20 C21 -179.0(3) . . . . ?
C18 C19 C24 C23 179.3(3) . . . . ?
C19 C20 C21 C22 -0.8(5) . . . . ?
C20 C19 C24 C23 0.1(4) . . . . ?
C20 C21 C22 C23 0.9(5) . . . . ?
C21 C22 C23 C24 -0.6(5) . . . . ?
C22 C23 C24 C19 0.0(5) . . . . ?
C24 C19 C20 C21 0.2(4) . . . . ?
C25 N2 C26 O1 0.9(3) . . . . ?
C25 N2 C26 C27 -178.6(2) . . . . ?
C25 C17 C18 C19 47.5(3) . . . . ?
C26 O1 C17 C9 -118.5(2) . . . . ?
C26 O1 C17 C18 116.8(2) . . . . ?
C26 O1 C17 C25 -0.5(2) . . . . ?
C26 N2 C25 O2 178.1(3) . . . . ?
C26 N2 C25 C17 -1.2(3) . . . . ?
C26 C27 C28 C29 178.6(3) . . . . ?
C26 C27 C32 C31 -177.6(3) . . . . ?
C27 C28 C29 C30 -0.6(6) . . . . ?
C28 C27 C32 C31 1.9(5) . . . . ?
C28 C29 C30 C31 1.1(6) . . . . ?
C29 C30 C31 C32 0.0(6) . . . . ?
C30 C31 C32 C27 -1.4(5) . . . . ?
C32 C27 C28 C29 -0.9(5) . . . . ?

_olex2_computing_structure_refinement_long 'ShelXL (Sheldrick, 2008)'
_olex2_computing_structure_solution_long 'ShelXS (Sheldrick, 2008)'
_database_code_depnum_ccdc_archive 'CCDC 992779'
