# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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# 
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#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
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data_1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C44 H30 Eu2 N2 O16'
_chemical_formula_weight         1146.62

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.046(2)
_cell_length_b                   11.633(2)
_cell_length_c                   16.246(3)
_cell_angle_alpha                78.69(3)
_cell_angle_beta                 73.81(3)
_cell_angle_gamma                88.58(3)
_cell_volume                     1964.9(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    6763
_cell_measurement_theta_min      3.08
_cell_measurement_theta_max      25.02

_exptl_crystal_description       Block
_exptl_crystal_colour            Brown
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.938
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1124
_exptl_absorpt_coefficient_mu    3.245
_exptl_absorpt_correction_type   None
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS SPIDER CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  20s
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            14839
_diffrn_reflns_av_R_equivalents  0.0812
_diffrn_reflns_av_sigmaI/netI    0.1366
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         3.08
_diffrn_reflns_theta_max         25.02
_reflns_number_total             6763
_reflns_number_gt                5104
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0000P)²+1.0119P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         6763
_refine_ls_number_parameters     579
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0592
_refine_ls_R_factor_gt           0.0454
_refine_ls_wR_factor_ref         0.1189
_refine_ls_wR_factor_gt          0.1113
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.06566(3) 0.93808(2) 0.194169(15) 0.01890(12) Uani 1 1 d . . .
Eu2 Eu 0.54926(3) 0.55298(2) 0.309580(16) 0.02024(12) Uani 1 1 d . . .
O3 O 0.1422(4) 0.8771(4) 0.2179(3) 0.0328(10) Uani 1 1 d . . .
O4 O -0.0965(4) 0.7393(4) 0.2652(3) 0.0324(10) Uani 1 1 d . . .
O5 O 0.7269(4) 0.8933(4) 0.1965(3) 0.0357(12) Uani 1 1 d . . .
O6 O 0.5791(4) 0.7537(4) 0.2378(3) 0.0372(11) Uani 1 1 d . . .
O7 O 0.0240(5) 0.8636(4) 0.0667(3) 0.0318(11) Uani 1 1 d . . .
O8 O -0.0777(5) 1.0962(4) 0.0774(2) 0.0314(11) Uani 1 1 d . . .
O9 O 0.3420(4) 0.6142(4) 0.2862(3) 0.0337(10) Uani 1 1 d . . .
O10 O -0.0968(5) 0.9562(4) 0.3461(2) 0.0313(10) Uani 1 1 d . . .
O11 O -0.1783(5) 1.0944(4) 0.2659(3) 0.0333(11) Uani 1 1 d . . .
O13 O 0.3400(5) 0.6049(4) -0.2350(3) 0.0344(11) Uani 1 1 d . . .
O14 O 0.1117(4) 1.0655(4) 0.1855(3) 0.0321(10) Uani 1 1 d . . .
O16 O -0.2420(4) 0.5970(4) 0.3033(3) 0.0375(11) Uani 1 1 d . . .
O17 O -0.4355(5) 1.3968(4) 0.4239(3) 0.0338(11) Uani 1 1 d . . .
O22 O 0.3706(4) 0.4255(4) 0.3177(3) 0.0364(11) Uani 1 1 d . . .
O24 O 0.4158(5) 0.4624(4) -0.1553(3) 0.0397(12) Uani 1 1 d . . .
O25 O -0.4648(6) 1.3677(5) 0.5658(3) 0.0426(13) Uani 1 1 d . . .
C12 C -0.1313(6) 0.6326(5) 0.2814(4) 0.0256(14) Uani 1 1 d . . .
C15 C 0.1779(6) 0.9807(6) 0.2057(4) 0.0275(14) Uani 1 1 d . . .
C18 C 0.3940(6) 0.9211(5) 0.2198(4) 0.0237(13) Uani 1 1 d . . .
H18A H 0.3705 0.8431 0.2257 0.028 Uiso 1 1 calc R . .
C19 C 0.3042(6) 0.5104(6) 0.2974(4) 0.0250(14) Uani 1 1 d . . .
C20 C 0.3063(6) 1.0080(5) 0.2136(4) 0.0228(13) Uani 1 1 d . . .
C21A C 0.2284(7) 0.7058(6) -0.0847(4) 0.0275(14) Uani 1 1 d . . .
H21A H 0.2070 0.7389 -0.1355 0.033 Uiso 1 1 calc R . .
C23 C -0.1531(6) 1.0522(6) 0.3361(4) 0.0267(14) Uani 1 1 d . . .
C26 C 0.3587(6) 0.5586(6) -0.1637(4) 0.0272(14) Uani 1 1 d . . .
C27A C 0.1790(6) 0.7494(5) -0.0091(3) 0.0246(13) Uani 1 1 d . . .
C28 C 0.6155(6) 0.8585(6) 0.2181(4) 0.0267(14) Uani 1 1 d . . .
C29A C 0.0879(6) 0.8475(5) -0.0067(4) 0.0218(13) Uani 1 1 d . . .
C30A C -0.0306(6) 0.5417(6) 0.2788(4) 0.0302(15) Uani 1 1 d . . .
C31 C 0.5158(6) 0.9502(6) 0.2172(4) 0.0276(14) Uani 1 1 d . . .
C32 C 0.4622(8) 1.1554(7) 0.2071(6) 0.056(2) Uani 1 1 d . . .
H32A H 0.4842 1.2333 0.2031 0.067 Uiso 1 1 calc R . .
C33A C 0.3101(6) 0.6126(6) -0.0849(4) 0.0258(14) Uani 1 1 d . . .
C34A C 0.3463(7) 0.5680(7) -0.0108(4) 0.0394(17) Uani 1 1 d . . .
H34A H 0.4023 0.5070 -0.0114 0.047 Uiso 1 1 calc R . .
C35A C 0.2142(7) 0.7014(7) 0.0656(4) 0.0423(18) Uani 1 1 d . . .
H35A H 0.1796 0.7290 0.1169 0.051 Uiso 1 1 calc R . .
C37A C -0.3092(7) 1.2596(6) 0.4852(4) 0.0326(15) Uani 1 1 d . . .
C38 C 0.5507(7) 1.0674(7) 0.2108(6) 0.048(2) Uani 1 1 d . . .
H38A H 0.6327 1.0868 0.2091 0.057 Uiso 1 1 calc R . .
C40A C 0.0880(6) 0.5703(6) 0.2850(4) 0.0253(13) Uani 1 1 d . . .
H40A H 0.1077 0.6465 0.2877 0.030 Uiso 1 1 calc R . .
C42 C 0.1764(6) 0.4837(6) 0.2869(4) 0.0295(15) Uani 1 1 d . . .
C43A C -0.2712(7) 1.2083(6) 0.4118(4) 0.0279(15) Uani 1 1 d . . .
H43A H -0.3032 1.2341 0.3644 0.033 Uiso 1 1 calc R . .
C44A C -0.4093(6) 1.3501(5) 0.4915(4) 0.0256(14) Uani 1 1 d . . .
C45B C -0.1853(7) 1.1183(6) 0.4093(4) 0.0327(16) Uani 1 1 d . . .
C46B C -0.1336(9) 1.0847(8) 0.4786(5) 0.057(2) Uani 1 1 d . . .
H46A H -0.0750 1.0257 0.4768 0.068 Uiso 1 1 calc R . .
C47A C 0.3006(8) 0.6125(7) 0.0648(4) 0.048(2) Uani 1 1 d . . .
H47A H 0.3274 0.5834 0.1142 0.057 Uiso 1 1 calc R . .
C48 C 0.1473(8) 0.3728(7) 0.2795(6) 0.050(2) Uani 1 1 d . . .
H48A H 0.2071 0.3152 0.2804 0.060 Uiso 1 1 calc R . .
C49B C -0.1682(10) 1.1379(10) 0.5503(5) 0.078(4) Uani 1 1 d . . .
H49A H -0.1330 1.1145 0.5964 0.093 Uiso 1 1 calc R . .
C52A C -0.2544(9) 1.2254(8) 0.5539(5) 0.056(3) Uani 1 1 d . . .
H52A H -0.2764 1.2618 0.6019 0.068 Uiso 1 1 calc R . .
C53A C -0.0583(7) 0.4303(7) 0.2720(6) 0.056(2) Uani 1 1 d . . .
H53A H -0.1377 0.4116 0.2682 0.068 Uiso 1 1 calc R . .
C59 C 0.0331(9) 0.3451(8) 0.2709(8) 0.072(3) Uani 1 1 d . . .
H59A H 0.0161 0.2700 0.2643 0.086 Uiso 1 1 calc R . .
C61 C 0.3397(7) 1.1231(7) 0.2094(5) 0.0469(19) Uani 1 1 d . . .
H61A H 0.2797 1.1804 0.2082 0.056 Uiso 1 1 calc R . .
N1 N 0.7244(8) 0.7897(8) 0.0114(5) 0.068(2) Uani 1 1 d . . .
C3 C 0.5468(8) 0.9544(8) 0.0030(5) 0.065(3) Uani 1 1 d . . .
C4 C 0.7579(9) 0.8966(9) 0.0026(5) 0.062(2) Uani 1 1 d . . .
H4A H 0.8404 0.9161 -0.0006 0.074 Uiso 1 1 calc R . .
C5A C 0.8166(10) 0.7046(10) 0.0182(9) 0.089(4) Uani 1 1 d . . .
H1 H 0.7893 0.6322 0.0080 0.133 Uiso 1 1 calc R . .
H2 H 0.8281 0.6922 0.0756 0.133 Uiso 1 1 calc R . .
H3 H 0.8950 0.7315 -0.0245 0.133 Uiso 1 1 calc R . .
C6 C 0.6703(9) 0.9841(9) -0.0023(6) 0.068(3) Uani 1 1 d . . .
H6A H 0.6944 1.0622 -0.0091 0.082 Uiso 1 1 calc R . .
C11A C 0.6077(11) 0.7587(10) 0.0240(8) 0.092(4) Uani 1 1 d . . .
H11A H 0.5859 0.6791 0.0373 0.110 Uiso 1 1 calc R . .
C12A C 0.5156(12) 0.8373(10) 0.0186(8) 0.102(4) Uani 1 1 d . . .
H12A H 0.4334 0.8123 0.0254 0.123 Uiso 1 1 calc R . .
N2 N 0.2892(10) 0.2230(8) 0.5047(5) 0.085(3) Uani 1 1 d . . .
C7A C 0.1972(16) 0.3174(13) 0.5115(7) 0.119(6) Uani 1 1 d . . .
H4 H 0.1487 0.3110 0.5714 0.178 Uiso 1 1 calc R . .
H5 H 0.1418 0.3105 0.4764 0.178 Uiso 1 1 calc R . .
H6 H 0.2412 0.3923 0.4912 0.178 Uiso 1 1 calc R . .
C8 C 0.3273(10) 0.1873(10) 0.5722(7) 0.076(3) Uani 1 1 d . . .
H8A H 0.2964 0.2200 0.6216 0.091 Uiso 1 1 calc R . .
C9A C 0.4530(11) 0.0507(8) 0.5001(5) 0.081(3) Uani 1 1 d . . .
C10 C 0.4166(10) 0.0981(10) 0.5721(7) 0.080(3) Uani 1 1 d . . .
H10A H 0.4487 0.0732 0.6196 0.095 Uiso 1 1 calc R . .
C13 C 0.3267(19) 0.1797(13) 0.4380(8) 0.155(8) Uani 1 1 d . . .
H13A H 0.2974 0.2099 0.3900 0.186 Uiso 1 1 calc R . .
C14A C 0.4109(19) 0.0876(12) 0.4319(7) 0.153(8) Uani 1 1 d . . .
H14A H 0.4355 0.0546 0.3823 0.183 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O5 2.351(5) 1_455 ?
Eu1 O7 2.353(4) . ?
Eu1 O4 2.360(4) . ?
Eu1 O8 2.400(4) . ?
Eu1 O14 2.442(4) . ?
Eu1 O10 2.446(4) . ?
Eu1 O11 2.475(4) . ?
Eu1 O3 2.496(5) . ?
Eu1 C23 2.812(6) . ?
Eu1 C15 2.811(7) . ?
Eu2 O25 2.336(5) 2_576 ?
Eu2 O16 2.345(5) 1_655 ?
Eu2 O6 2.383(4) . ?
Eu2 O17 2.370(4) 1_645 ?
Eu2 O22 2.457(5) . ?
Eu2 O24 2.469(4) 2_665 ?
Eu2 O9 2.488(5) . ?
Eu2 O13 2.505(5) 2_665 ?
Eu2 C19 2.831(6) . ?
Eu2 C26 2.852(6) 2_665 ?
O3 C15 1.239(8) . ?
O4 C12 1.264(8) . ?
O5 C28 1.236(8) . ?
O5 Eu1 2.351(5) 1_655 ?
O6 C28 1.245(8) . ?
O7 C29A 1.252(7) . ?
O8 C29A 1.239(7) 2_575 ?
O9 C19 1.249(8) . ?
O10 C23 1.269(8) . ?
O11 C23 1.253(7) . ?
O13 C26 1.248(7) . ?
O13 Eu2 2.505(5) 2_665 ?
O14 C15 1.259(8) . ?
O16 C12 1.232(8) . ?
O16 Eu2 2.345(5) 1_455 ?
O17 C44A 1.232(7) . ?
O17 Eu2 2.370(4) 1_465 ?
O22 C19 1.262(8) . ?
O24 C26 1.274(8) . ?
O24 Eu2 2.469(4) 2_665 ?
O25 C44A 1.246(8) . ?
O25 Eu2 2.336(5) 2_576 ?
C12 C30A 1.512(9) . ?
C15 C20 1.506(9) . ?
C18 C20 1.391(9) . ?
C18 C31 1.383(9) . ?
C18 H18A 0.9300 . ?
C19 C42 1.515(9) . ?
C20 C61 1.381(10) . ?
C21A C27A 1.386(8) . ?
C21A C33A 1.393(9) . ?
C21A H21A 0.9300 . ?
C23 C45B 1.497(9) . ?
C26 C33A 1.495(9) . ?
C26 Eu2 2.852(6) 2_665 ?
C27A C35A 1.386(9) . ?
C27A C29A 1.502(8) . ?
C28 C31 1.515(9) . ?
C29A O8 1.239(7) 2_575 ?
C30A C53A 1.371(10) . ?
C30A C40A 1.395(9) . ?
C31 C38 1.403(10) . ?
C32 C38 1.402(11) . ?
C32 C61 1.401(11) . ?
C32 H32A 0.9300 . ?
C33A C34A 1.376(9) . ?
C34A C47A 1.387(9) . ?
C34A H34A 0.9300 . ?
C35A C47A 1.389(10) . ?
C35A H35A 0.9300 . ?
C37A C52A 1.401(10) . ?
C37A C43A 1.393(9) . ?
C37A C44A 1.504(9) . ?
C38 H38A 0.9300 . ?
C40A C42 1.387(9) . ?
C40A H40A 0.9300 . ?
C42 C48 1.373(10) . ?
C43A C45B 1.393(9) . ?
C43A H43A 0.9300 . ?
C45B C46B 1.386(10) . ?
C46B C49B 1.382(10) . ?
C46B H46A 0.9300 . ?
C47A H47A 0.9300 . ?
C48 C59 1.360(12) . ?
C48 H48A 0.9300 . ?
C49B C52A 1.375(11) . ?
C49B H49A 0.9300 . ?
C52A H52A 0.9300 . ?
C53A C59 1.397(11) . ?
C53A H53A 0.9300 . ?
C59 H59A 0.9300 . ?
C61 H61A 0.9300 . ?
N1 C11A 1.297(13) . ?
N1 C4 1.276(12) . ?
N1 C5A 1.414(13) . ?
C3 C6 1.391(12) . ?
C3 C12A 1.370(14) . ?
C3 C3 1.471(19) 2_675 ?
C4 C6 1.393(13) . ?
C4 H4A 0.9300 . ?
C5A H1 0.9600 . ?
C5A H2 0.9600 . ?
C5A H3 0.9600 . ?
C6 H6A 0.9300 . ?
C11A C12A 1.361(15) . ?
C11A H11A 0.9300 . ?
C12A H12A 0.9300 . ?
N2 C8 1.275(14) . ?
N2 C13 1.246(15) . ?
N2 C7A 1.477(15) . ?
C7A H4 0.9600 . ?
C7A H5 0.9600 . ?
C7A H6 0.9600 . ?
C8 C10 1.414(15) . ?
C8 H8A 0.9300 . ?
C9A C10 1.347(13) . ?
C9A C14A 1.310(16) . ?
C9A C9A 1.55(2) 2_656 ?
C10 H10A 0.9300 . ?
C13 C14A 1.400(18) . ?
C13 H13A 0.9300 . ?
C14A H14A 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Eu1 O7 93.34(18) 1_455 . ?
O5 Eu1 O4 76.55(17) 1_455 . ?
O7 Eu1 O4 84.98(16) . . ?
O5 Eu1 O8 84.01(16) 1_455 . ?
O7 Eu1 O8 75.89(15) . . ?
O4 Eu1 O8 151.81(17) . . ?
O5 Eu1 O14 155.89(17) 1_455 . ?
O7 Eu1 O14 98.08(17) . . ?
O4 Eu1 O14 125.43(15) . . ?
O8 Eu1 O14 78.34(16) . . ?
O5 Eu1 O10 100.70(17) 1_455 . ?
O7 Eu1 O10 155.72(16) . . ?
O4 Eu1 O10 79.23(15) . . ?
O8 Eu1 O10 124.94(14) . . ?
O14 Eu1 O10 76.79(16) . . ?
O5 Eu1 O11 80.12(18) 1_455 . ?
O7 Eu1 O11 150.07(14) . . ?
O4 Eu1 O11 121.00(15) . . ?
O8 Eu1 O11 74.40(14) . . ?
O14 Eu1 O11 79.40(16) . . ?
O10 Eu1 O11 53.19(14) . . ?
O5 Eu1 O3 151.02(15) 1_455 . ?
O7 Eu1 O3 79.94(17) . . ?
O4 Eu1 O3 74.80(15) . . ?
O8 Eu1 O3 120.74(15) . . ?
O14 Eu1 O3 52.70(14) . . ?
O10 Eu1 O3 78.20(16) . . ?
O11 Eu1 O3 118.89(15) . . ?
O5 Eu1 C23 91.42(19) 1_455 . ?
O7 Eu1 C23 172.81(17) . . ?
O4 Eu1 C23 101.40(17) . . ?
O8 Eu1 C23 99.27(16) . . ?
O14 Eu1 C23 75.55(17) . . ?
O10 Eu1 C23 26.79(16) . . ?
O11 Eu1 C23 26.45(16) . . ?
O3 Eu1 C23 98.39(17) . . ?
O5 Eu1 C15 175.21(16) 1_455 . ?
O7 Eu1 C15 89.44(18) . . ?
O4 Eu1 C15 99.83(18) . . ?
O8 Eu1 C15 100.47(18) . . ?
O14 Eu1 C15 26.57(17) . . ?
O10 Eu1 C15 75.38(17) . . ?
O11 Eu1 C15 99.36(18) . . ?
O3 Eu1 C15 26.14(17) . . ?
C23 Eu1 C15 86.20(19) . . ?
O25 Eu2 O16 93.5(2) 2_576 1_655 ?
O25 Eu2 O6 83.36(18) 2_576 . ?
O16 Eu2 O6 76.66(16) 1_655 . ?
O25 Eu2 O17 77.46(16) 2_576 1_645 ?
O16 Eu2 O17 84.01(17) 1_655 1_645 ?
O6 Eu2 O17 151.79(18) . 1_645 ?
O25 Eu2 O22 99.89(19) 2_576 . ?
O16 Eu2 O22 155.70(17) 1_655 . ?
O6 Eu2 O22 124.80(16) . . ?
O17 Eu2 O22 79.25(16) 1_645 . ?
O25 Eu2 O24 155.34(17) 2_576 2_665 ?
O16 Eu2 O24 98.17(18) 1_655 2_665 ?
O6 Eu2 O24 78.33(17) . 2_665 ?
O17 Eu2 O24 125.23(15) 1_645 2_665 ?
O22 Eu2 O24 77.75(17) . 2_665 ?
O25 Eu2 O9 80.36(18) 2_576 . ?
O16 Eu2 O9 150.88(16) 1_655 . ?
O6 Eu2 O9 74.37(16) . . ?
O17 Eu2 O9 121.58(16) 1_645 . ?
O22 Eu2 O9 52.57(15) . . ?
O24 Eu2 O9 78.91(16) 2_665 . ?
O25 Eu2 O13 151.88(15) 2_576 2_665 ?
O16 Eu2 O13 80.04(18) 1_655 2_665 ?
O6 Eu2 O13 120.87(16) . 2_665 ?
O17 Eu2 O13 74.68(14) 1_645 2_665 ?
O22 Eu2 O13 78.63(17) . 2_665 ?
O24 Eu2 O13 52.39(15) 2_665 2_665 ?
O9 Eu2 O13 117.84(16) . 2_665 ?
O25 Eu2 C19 90.8(2) 2_576 . ?
O16 Eu2 C19 173.75(16) 1_655 . ?
O6 Eu2 C19 99.33(17) . . ?
O17 Eu2 C19 101.40(17) 1_645 . ?
O22 Eu2 C19 26.43(17) . . ?
O24 Eu2 C19 76.19(18) 2_665 . ?
O9 Eu2 C19 26.16(17) . . ?
O13 Eu2 C19 98.25(18) 2_665 . ?
O25 Eu2 C26 175.87(19) 2_576 2_665 ?
O16 Eu2 C26 89.2(2) 1_655 2_665 ?
O6 Eu2 C26 100.35(18) . 2_665 ?
O17 Eu2 C26 99.69(16) 1_645 2_665 ?
O22 Eu2 C26 76.54(18) . 2_665 ?
O24 Eu2 C26 26.47(16) 2_665 2_665 ?
O9 Eu2 C26 98.83(17) . 2_665 ?
O13 Eu2 C26 25.92(16) 2_665 2_665 ?
C19 Eu2 C26 86.82(19) . 2_665 ?
C15 O3 Eu1 91.3(4) . . ?
C12 O4 Eu1 159.3(4) . . ?
C28 O5 Eu1 164.9(4) . 1_655 ?
C28 O6 Eu2 160.7(4) . . ?
C29A O7 Eu1 165.6(4) . . ?
C29A O8 Eu1 162.5(4) 2_575 . ?
C19 O9 Eu2 92.4(4) . . ?
C23 O10 Eu1 92.9(3) . . ?
C23 O11 Eu1 92.0(4) . . ?
C26 O13 Eu2 92.8(4) . 2_665 ?
C15 O14 Eu1 93.3(4) . . ?
C12 O16 Eu2 165.7(4) . 1_455 ?
C44A O17 Eu2 156.2(4) . 1_465 ?
C19 O22 Eu2 93.5(4) . . ?
C26 O24 Eu2 93.8(4) . 2_665 ?
C44A O25 Eu2 166.1(5) . 2_576 ?
O4 C12 O16 124.5(6) . . ?
O4 C12 C30A 117.8(6) . . ?
O16 C12 C30A 117.6(5) . . ?
O3 C15 O14 122.7(6) . . ?
O3 C15 C20 119.4(6) . . ?
O14 C15 C20 118.0(6) . . ?
O3 C15 Eu1 62.6(4) . . ?
O14 C15 Eu1 60.1(3) . . ?
C20 C15 Eu1 177.6(5) . . ?
C20 C18 C31 120.4(6) . . ?
C20 C18 H18A 119.8 . . ?
C31 C18 H18A 119.8 . . ?
O9 C19 O22 121.4(6) . . ?
O9 C19 C42 120.3(6) . . ?
O22 C19 C42 118.3(6) . . ?
O9 C19 Eu2 61.4(3) . . ?
O22 C19 Eu2 60.0(3) . . ?
C42 C19 Eu2 176.8(5) . . ?
C61 C20 C18 119.5(6) . . ?
C61 C20 C15 118.9(6) . . ?
C18 C20 C15 121.5(6) . . ?
C27A C21A C33A 120.2(6) . . ?
C27A C21A H21A 119.9 . . ?
C33A C21A H21A 119.9 . . ?
O11 C23 O10 121.7(6) . . ?
O11 C23 C45B 119.6(6) . . ?
O10 C23 C45B 118.7(5) . . ?
O11 C23 Eu1 61.6(3) . . ?
O10 C23 Eu1 60.3(3) . . ?
C45B C23 Eu1 173.8(5) . . ?
O13 C26 O24 121.0(6) . . ?
O13 C26 C33A 120.7(6) . . ?
O24 C26 C33A 118.3(5) . . ?
O13 C26 Eu2 61.3(3) . 2_665 ?
O24 C26 Eu2 59.8(3) . 2_665 ?
C33A C26 Eu2 177.8(4) . 2_665 ?
C21A C27A C35A 119.4(6) . . ?
C21A C27A C29A 121.1(5) . . ?
C35A C27A C29A 119.5(5) . . ?
O5 C28 O6 125.0(6) . . ?
O5 C28 C31 117.7(6) . . ?
O6 C28 C31 117.3(6) . . ?
O8 C29A O7 124.6(6) 2_575 . ?
O8 C29A C27A 117.7(5) 2_575 . ?
O7 C29A C27A 117.6(5) . . ?
C53A C30A C40A 120.4(7) . . ?
C53A C30A C12 119.1(6) . . ?
C40A C30A C12 120.4(6) . . ?
C38 C31 C18 120.0(6) . . ?
C38 C31 C28 118.3(6) . . ?
C18 C31 C28 121.6(6) . . ?
C38 C32 C61 118.4(7) . . ?
C38 C32 H32A 120.8 . . ?
C61 C32 H32A 120.8 . . ?
C34A C33A C21A 119.5(6) . . ?
C34A C33A C26 118.9(6) . . ?
C21A C33A C26 121.6(5) . . ?
C33A C34A C47A 121.1(6) . . ?
C33A C34A H34A 119.4 . . ?
C47A C34A H34A 119.4 . . ?
C47A C35A C27A 120.8(6) . . ?
C47A C35A H35A 119.6 . . ?
C27A C35A H35A 119.6 . . ?
C52A C37A C43A 119.5(6) . . ?
C52A C37A C44A 119.9(6) . . ?
C43A C37A C44A 120.6(6) . . ?
C31 C38 C32 120.1(7) . . ?
C31 C38 H38A 119.9 . . ?
C32 C38 H38A 119.9 . . ?
C42 C40A C30A 119.2(6) . . ?
C42 C40A H40A 120.4 . . ?
C30A C40A H40A 120.4 . . ?
C48 C42 C40A 119.6(7) . . ?
C48 C42 C19 119.9(6) . . ?
C40A C42 C19 120.6(6) . . ?
C45B C43A C37A 120.2(6) . . ?
C45B C43A H43A 119.9 . . ?
C37A C43A H43A 119.9 . . ?
O17 C44A O25 124.5(6) . . ?
O17 C44A C37A 118.1(5) . . ?
O25 C44A C37A 117.3(5) . . ?
C46B C45B C43A 119.3(6) . . ?
C46B C45B C23 118.9(6) . . ?
C43A C45B C23 121.7(6) . . ?
C49B C46B C45B 120.6(7) . . ?
C49B C46B H46A 119.7 . . ?
C45B C46B H46A 119.7 . . ?
C34A C47A C35A 118.8(6) . . ?
C34A C47A H47A 120.6 . . ?
C35A C47A H47A 120.6 . . ?
C42 C48 C59 121.6(7) . . ?
C42 C48 H48A 119.2 . . ?
C59 C48 H48A 119.2 . . ?
C46B C49B C52A 120.5(7) . . ?
C46B C49B H49A 119.8 . . ?
C52A C49B H49A 119.8 . . ?
C49B C52A C37A 119.9(6) . . ?
C49B C52A H52A 120.1 . . ?
C37A C52A H52A 120.1 . . ?
C59 C53A C30A 119.7(8) . . ?
C59 C53A H53A 120.1 . . ?
C30A C53A H53A 120.1 . . ?
C53A C59 C48 119.4(8) . . ?
C53A C59 H59A 120.3 . . ?
C48 C59 H59A 120.3 . . ?
C20 C61 C32 121.4(7) . . ?
C20 C61 H61A 119.3 . . ?
C32 C61 H61A 119.3 . . ?
C11A N1 C4 121.5(11) . . ?
C11A N1 C5A 120.8(9) . . ?
C4 N1 C5A 117.2(9) . . ?
C6 C3 C12A 117.1(10) . . ?
C6 C3 C3 120.7(11) . 2_675 ?
C12A C3 C3 122.1(11) . 2_675 ?
N1 C4 C6 119.8(10) . . ?
N1 C4 H4A 120.1 . . ?
C6 C4 H4A 120.1 . . ?
N1 C5A H1 109.5 . . ?
N1 C5A H2 109.5 . . ?
H1 C5A H2 109.5 . . ?
N1 C5A H3 109.5 . . ?
H1 C5A H3 109.5 . . ?
H2 C5A H3 109.5 . . ?
C3 C6 C4 119.9(9) . . ?
C3 C6 H6A 120.1 . . ?
C4 C6 H6A 120.1 . . ?
N1 C11A C12A 122.9(11) . . ?
N1 C11A H11A 118.5 . . ?
C12A C11A H11A 118.5 . . ?
C11A C12A C3 118.4(11) . . ?
C11A C12A H12A 120.8 . . ?
C3 C12A H12A 120.8 . . ?
C8 N2 C13 121.7(13) . . ?
C8 N2 C7A 115.5(9) . . ?
C13 N2 C7A 122.8(11) . . ?
N2 C7A H4 109.5 . . ?
N2 C7A H5 109.5 . . ?
H4 C7A H5 109.5 . . ?
N2 C7A H6 109.5 . . ?
H4 C7A H6 109.5 . . ?
H5 C7A H6 109.5 . . ?
N2 C8 C10 120.0(10) . . ?
N2 C8 H8A 120.0 . . ?
C10 C8 H8A 120.0 . . ?
C10 C9A C14A 121.8(12) . . ?
C10 C9A C9A 117.8(11) . 2_656 ?
C14A C9A C9A 120.4(11) . 2_656 ?
C9A C10 C8 117.0(10) . . ?
C9A C10 H10A 121.5 . . ?
C8 C10 H10A 121.5 . . ?
N2 C13 C14A 123.2(13) . . ?
N2 C13 H13A 118.4 . . ?
C14A C13 H13A 118.4 . . ?
C9A C14A C13 116.2(12) . . ?
C9A C14A H14A 121.9 . . ?
C13 C14A H14A 121.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Eu1 O3 C15 -171.6(3) 1_455 . . . ?
O7 Eu1 O3 C15 109.8(4) . . . . ?
O4 Eu1 O3 C15 -162.7(4) . . . . ?
O8 Eu1 O3 C15 43.0(4) . . . . ?
O14 Eu1 O3 C15 1.5(3) . . . . ?
O10 Eu1 O3 C15 -80.8(4) . . . . ?
O11 Eu1 O3 C15 -45.4(4) . . . . ?
C23 Eu1 O3 C15 -63.1(4) . . . . ?
O5 Eu1 O4 C12 42.2(12) 1_455 . . . ?
O7 Eu1 O4 C12 -52.4(12) . . . . ?
O8 Eu1 O4 C12 -5.5(14) . . . . ?
O14 Eu1 O4 C12 -148.8(12) . . . . ?
O10 Eu1 O4 C12 146.1(13) . . . . ?
O11 Eu1 O4 C12 111.8(12) . . . . ?
O3 Eu1 O4 C12 -133.4(13) . . . . ?
C23 Eu1 O4 C12 130.9(12) . . . . ?
C15 Eu1 O4 C12 -141.0(12) . . . . ?
O25 Eu2 O6 C28 58.2(15) 2_576 . . . ?
O16 Eu2 O6 C28 -37.0(14) 1_655 . . . ?
O17 Eu2 O6 C28 11.0(16) 1_645 . . . ?
O22 Eu2 O6 C28 155.7(14) . . . . ?
O24 Eu2 O6 C28 -138.4(15) 2_665 . . . ?
O9 Eu2 O6 C28 140.0(15) . . . . ?
O13 Eu2 O6 C28 -106.5(14) 2_665 . . . ?
C19 Eu2 O6 C28 147.9(14) . . . . ?
C26 Eu2 O6 C28 -123.6(15) 2_665 . . . ?
O5 Eu1 O7 C29A 133.9(17) 1_455 . . . ?
O4 Eu1 O7 C29A -149.9(17) . . . . ?
O8 Eu1 O7 C29A 51.0(17) . . . . ?
O14 Eu1 O7 C29A -24.8(17) . . . . ?
O10 Eu1 O7 C29A -100.5(17) . . . . ?
O11 Eu1 O7 C29A 58.0(19) . . . . ?
O3 Eu1 O7 C29A -74.5(17) . . . . ?
C15 Eu1 O7 C29A -50.0(17) . . . . ?
O5 Eu1 O8 C29A -62.6(14) 1_455 . . 2_575 ?
O7 Eu1 O8 C29A 32.4(14) . . . 2_575 ?
O4 Eu1 O8 C29A -16.3(16) . . . 2_575 ?
O14 Eu1 O8 C29A 133.9(14) . . . 2_575 ?
O10 Eu1 O8 C29A -161.5(14) . . . 2_575 ?
O11 Eu1 O8 C29A -144.0(15) . . . 2_575 ?
O3 Eu1 O8 C29A 101.3(14) . . . 2_575 ?
C23 Eu1 O8 C29A -153.1(14) . . . 2_575 ?
C15 Eu1 O8 C29A 119.1(14) . . . 2_575 ?
O25 Eu2 O9 C19 -112.2(4) 2_576 . . . ?
O16 Eu2 O9 C19 168.1(4) 1_655 . . . ?
O6 Eu2 O9 C19 162.0(4) . . . . ?
O17 Eu2 O9 C19 -43.5(4) 1_645 . . . ?
O22 Eu2 O9 C19 -1.8(3) . . . . ?
O24 Eu2 O9 C19 81.2(4) 2_665 . . . ?
O13 Eu2 O9 C19 45.0(4) 2_665 . . . ?
C26 Eu2 O9 C19 63.7(4) 2_665 . . . ?
O5 Eu1 O10 C23 -71.4(4) 1_455 . . . ?
O7 Eu1 O10 C23 164.3(4) . . . . ?
O4 Eu1 O10 C23 -145.4(4) . . . . ?
O8 Eu1 O10 C23 18.7(4) . . . . ?
O14 Eu1 O10 C23 84.0(4) . . . . ?
O11 Eu1 O10 C23 -2.5(4) . . . . ?
O3 Eu1 O10 C23 138.1(4) . . . . ?
C15 Eu1 O10 C23 111.4(4) . . . . ?
O5 Eu1 O11 C23 114.0(4) 1_455 . . . ?
O7 Eu1 O11 C23 -166.6(4) . . . . ?
O4 Eu1 O11 C23 46.3(4) . . . . ?
O8 Eu1 O11 C23 -159.5(4) . . . . ?
O14 Eu1 O11 C23 -78.8(4) . . . . ?
O10 Eu1 O11 C23 2.5(4) . . . . ?
O3 Eu1 O11 C23 -42.7(4) . . . . ?
C15 Eu1 O11 C23 -61.2(4) . . . . ?
O5 Eu1 O14 C15 170.4(4) 1_455 . . . ?
O7 Eu1 O14 C15 -72.2(4) . . . . ?
O4 Eu1 O14 C15 17.4(4) . . . . ?
O8 Eu1 O14 C15 -145.9(4) . . . . ?
O10 Eu1 O14 C15 83.7(4) . . . . ?
O11 Eu1 O14 C15 138.1(4) . . . . ?
O3 Eu1 O14 C15 -1.4(3) . . . . ?
C23 Eu1 O14 C15 111.3(4) . . . . ?
O25 Eu2 O22 C19 71.4(4) 2_576 . . . ?
O16 Eu2 O22 C19 -166.2(4) 1_655 . . . ?
O6 Eu2 O22 C19 -17.3(4) . . . . ?
O17 Eu2 O22 C19 146.5(4) 1_645 . . . ?
O24 Eu2 O22 C19 -83.6(4) 2_665 . . . ?
O9 Eu2 O22 C19 1.8(3) . . . . ?
O13 Eu2 O22 C19 -137.2(4) 2_665 . . . ?
C26 Eu2 O22 C19 -110.7(4) 2_665 . . . ?
Eu1 O4 C12 O16 -64.5(15) . . . . ?
Eu1 O4 C12 C30A 119.2(11) . . . . ?
Eu2 O16 C12 O4 67(2) 1_455 . . . ?
Eu2 O16 C12 C30A -116.8(17) 1_455 . . . ?
Eu1 O3 C15 O14 -2.7(6) . . . . ?
Eu1 O3 C15 C20 178.3(5) . . . . ?
Eu1 O14 C15 O3 2.7(6) . . . . ?
Eu1 O14 C15 C20 -178.3(5) . . . . ?
O7 Eu1 C15 O3 -67.9(4) . . . . ?
O4 Eu1 C15 O3 16.9(4) . . . . ?
O8 Eu1 C15 O3 -143.4(4) . . . . ?
O14 Eu1 C15 O3 -177.4(6) . . . . ?
O10 Eu1 C15 O3 93.0(4) . . . . ?
O11 Eu1 C15 O3 140.9(4) . . . . ?
C23 Eu1 C15 O3 117.8(4) . . . . ?
O7 Eu1 C15 O14 109.5(4) . . . . ?
O4 Eu1 C15 O14 -165.7(3) . . . . ?
O8 Eu1 C15 O14 34.0(4) . . . . ?
O10 Eu1 C15 O14 -89.6(4) . . . . ?
O11 Eu1 C15 O14 -41.7(4) . . . . ?
O3 Eu1 C15 O14 177.4(6) . . . . ?
C23 Eu1 C15 O14 -64.8(4) . . . . ?
Eu2 O9 C19 O22 3.2(6) . . . . ?
Eu2 O9 C19 C42 -176.9(5) . . . . ?
Eu2 O22 C19 O9 -3.3(6) . . . . ?
Eu2 O22 C19 C42 176.8(5) . . . . ?
O6 Eu2 C19 O9 -17.5(4) . . . . ?
O17 Eu2 C19 O9 143.3(3) 1_645 . . . ?
O22 Eu2 C19 O9 176.8(6) . . . . ?
O24 Eu2 C19 O9 -92.9(4) 2_665 . . . ?
O13 Eu2 C19 O9 -140.8(4) 2_665 . . . ?
C26 Eu2 C19 O9 -117.5(4) 2_665 . . . ?
O25 Eu2 C19 O22 -111.0(4) 2_576 . . . ?
O6 Eu2 C19 O22 165.6(4) . . . . ?
O17 Eu2 C19 O22 -33.6(4) 1_645 . . . ?
O24 Eu2 C19 O22 90.2(4) 2_665 . . . ?
O9 Eu2 C19 O22 -176.8(6) . . . . ?
O13 Eu2 C19 O22 42.3(4) 2_665 . . . ?
C26 Eu2 C19 O22 65.7(4) 2_665 . . . ?
C31 C18 C20 C61 -3.3(9) . . . . ?
C31 C18 C20 C15 172.8(5) . . . . ?
O3 C15 C20 C61 -173.0(6) . . . . ?
O14 C15 C20 C61 8.0(9) . . . . ?
O3 C15 C20 C18 10.9(9) . . . . ?
O14 C15 C20 C18 -168.1(5) . . . . ?
Eu1 O11 C23 O10 -4.6(6) . . . . ?
Eu1 O11 C23 C45B 173.0(6) . . . . ?
Eu1 O10 C23 O11 4.7(6) . . . . ?
Eu1 O10 C23 C45B -173.0(5) . . . . ?
O5 Eu1 C23 O11 -64.2(4) 1_455 . . . ?
O4 Eu1 C23 O11 -140.8(4) . . . . ?
O8 Eu1 C23 O11 19.9(4) . . . . ?
O14 Eu1 C23 O11 95.3(4) . . . . ?
O10 Eu1 C23 O11 -175.5(6) . . . . ?
O3 Eu1 C23 O11 143.1(4) . . . . ?
C15 Eu1 C23 O11 120.0(4) . . . . ?
O5 Eu1 C23 O10 111.3(4) 1_455 . . . ?
O4 Eu1 C23 O10 34.7(4) . . . . ?
O8 Eu1 C23 O10 -164.6(4) . . . . ?
O14 Eu1 C23 O10 -89.3(4) . . . . ?
O11 Eu1 C23 O10 175.5(6) . . . . ?
O3 Eu1 C23 O10 -41.4(4) . . . . ?
C15 Eu1 C23 O10 -64.6(4) . . . . ?
Eu2 O13 C26 O24 -1.2(7) 2_665 . . . ?
Eu2 O13 C26 C33A -178.9(6) 2_665 . . . ?
Eu2 O24 C26 O13 1.2(7) 2_665 . . . ?
Eu2 O24 C26 C33A 178.9(5) 2_665 . . . ?
C33A C21A C27A C35A 1.7(10) . . . . ?
C33A C21A C27A C29A -178.2(6) . . . . ?
Eu1 O5 C28 O6 -69(2) 1_655 . . . ?
Eu1 O5 C28 C31 113.9(17) 1_655 . . . ?
Eu2 O6 C28 O5 55.9(18) . . . . ?
Eu2 O6 C28 C31 -126.7(13) . . . . ?
Eu1 O7 C29A O8 -70(2) . . . 2_575 ?
Eu1 O7 C29A C27A 113.2(16) . . . . ?
C21A C27A C29A O8 -14.3(9) . . . 2_575 ?
C35A C27A C29A O8 165.8(6) . . . 2_575 ?
C21A C27A C29A O7 163.0(6) . . . . ?
C35A C27A C29A O7 -16.8(9) . . . . ?
O4 C12 C30A C53A -162.3(7) . . . . ?
O16 C12 C30A C53A 21.2(9) . . . . ?
O4 C12 C30A C40A 19.0(9) . . . . ?
O16 C12 C30A C40A -157.6(6) . . . . ?
C20 C18 C31 C38 1.8(9) . . . . ?
C20 C18 C31 C28 -176.2(5) . . . . ?
O5 C28 C31 C38 -13.7(9) . . . . ?
O6 C28 C31 C38 168.7(6) . . . . ?
O5 C28 C31 C18 164.4(6) . . . . ?
O6 C28 C31 C18 -13.2(9) . . . . ?
C27A C21A C33A C34A -3.2(11) . . . . ?
C27A C21A C33A C26 176.1(6) . . . . ?
O13 C26 C33A C34A -171.6(7) . . . . ?
O24 C26 C33A C34A 10.6(10) . . . . ?
O13 C26 C33A C21A 9.1(10) . . . . ?
O24 C26 C33A C21A -168.7(6) . . . . ?
C21A C33A C34A C47A 1.4(12) . . . . ?
C26 C33A C34A C47A -177.9(7) . . . . ?
C21A C27A C35A C47A 1.7(12) . . . . ?
C29A C27A C35A C47A -178.5(7) . . . . ?
C18 C31 C38 C32 0.0(11) . . . . ?
C28 C31 C38 C32 178.1(7) . . . . ?
C61 C32 C38 C31 -0.3(13) . . . . ?
C53A C30A C40A C42 -2.0(10) . . . . ?
C12 C30A C40A C42 176.7(5) . . . . ?
C30A C40A C42 C48 2.4(10) . . . . ?
C30A C40A C42 C19 -177.4(6) . . . . ?
O9 C19 C42 C48 165.2(7) . . . . ?
O22 C19 C42 C48 -14.9(9) . . . . ?
O9 C19 C42 C40A -15.0(9) . . . . ?
O22 C19 C42 C40A 164.9(6) . . . . ?
C52A C37A C43A C45B 4.1(11) . . . . ?
C44A C37A C43A C45B -175.2(7) . . . . ?
Eu2 O17 C44A O25 68.9(14) 1_465 . . . ?
Eu2 O17 C44A C37A -115.2(10) 1_465 . . . ?
Eu2 O25 C44A O17 -64(2) 2_576 . . . ?
Eu2 O25 C44A C37A 120.4(19) 2_576 . . . ?
C52A C37A C44A O17 164.4(7) . . . . ?
C43A C37A C44A O17 -16.4(10) . . . . ?
C52A C37A C44A O25 -19.5(11) . . . . ?
C43A C37A C44A O25 159.8(6) . . . . ?
C37A C43A C45B C46B -3.2(12) . . . . ?
C37A C43A C45B C23 173.2(6) . . . . ?
O11 C23 C45B C46B -166.2(7) . . . . ?
O10 C23 C45B C46B 11.5(11) . . . . ?
O11 C23 C45B C43A 17.4(10) . . . . ?
O10 C23 C45B C43A -164.9(6) . . . . ?
C43A C45B C46B C49B 1.2(14) . . . . ?
C23 C45B C46B C49B -175.3(9) . . . . ?
C33A C34A C47A C35A 1.8(13) . . . . ?
C27A C35A C47A C34A -3.4(13) . . . . ?
C40A C42 C48 C59 -0.5(12) . . . . ?
C19 C42 C48 C59 179.3(8) . . . . ?
C45B C46B C49B C52A -0.1(17) . . . . ?
C46B C49B C52A C37A 1.0(17) . . . . ?
C43A C37A C52A C49B -3.0(14) . . . . ?
C44A C37A C52A C49B 176.3(9) . . . . ?
C40A C30A C53A C59 -0.3(13) . . . . ?
C12 C30A C53A C59 -179.0(8) . . . . ?
C30A C53A C59 C48 2.2(15) . . . . ?
C42 C48 C59 C53A -1.8(15) . . . . ?
C18 C20 C61 C32 3.1(11) . . . . ?
C15 C20 C61 C32 -173.1(7) . . . . ?
C38 C32 C61 C20 -1.3(13) . . . . ?
C11A N1 C4 C6 -6.4(14) . . . . ?
C5A N1 C4 C6 -178.5(9) . . . . ?
C12A C3 C6 C4 4.1(14) . . . . ?
C3 C3 C6 C4 -179.3(9) 2_675 . . . ?
N1 C4 C6 C3 0.4(13) . . . . ?
C4 N1 C11A C12A 7.9(18) . . . . ?
C5A N1 C11A C12A 179.7(12) . . . . ?
N1 C11A C12A C3 -3(2) . . . . ?
C6 C3 C12A C11A -2.9(17) . . . . ?
C3 C3 C12A C11A -179.4(11) 2_675 . . . ?
C13 N2 C8 C10 1.4(18) . . . . ?
C7A N2 C8 C10 -179.3(11) . . . . ?
C14A C9A C10 C8 2.0(18) . . . . ?
C9A C9A C10 C8 -177.7(10) 2_656 . . . ?
N2 C8 C10 C9A -3.1(15) . . . . ?
C8 N2 C13 C14A 1(3) . . . . ?
C7A N2 C13 C14A -177.9(16) . . . . ?
C10 C9A C14A C13 0(2) . . . . ?
C9A C9A C14A C13 -179.8(15) 2_656 . . . ?
N2 C13 C14A C9A -2(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.974
_diffrn_reflns_theta_full        25.02
_diffrn_measured_fraction_theta_full 0.974
_refine_diff_density_max         1.225
_refine_diff_density_min         -2.531
_refine_diff_density_rms         0.170
_database_code_depnum_ccdc_archive 'CCDC 1016434'
