# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2014

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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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#  data retrieval see:
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data_JU93

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'H10 Al6 Na2 O30 P6'
_chemical_formula_weight         883.76

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Orthorhombic
_symmetry_space_group_name_H-M   Pca2(1)

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y, z'
'-x+1/2, y, z+1/2'

_cell_length_a                   17.495(4)
_cell_length_b                   10.321(2)
_cell_length_c                   13.577(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     2451.4(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            white
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.12
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.395
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1760
_exptl_absorpt_coefficient_mu    0.824
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.7278
_exptl_absorpt_correction_T_max  0.9069
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            21860
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_sigmaI/netI    0.0344
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         3.00
_diffrn_reflns_theta_max         27.48
_reflns_number_total             5516
_reflns_number_gt                4881
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0552P)²+0.0232P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   none
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.21(11)
_refine_ls_number_reflns         5516
_refine_ls_number_parameters     397
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0343
_refine_ls_R_factor_gt           0.0295
_refine_ls_wR_factor_ref         0.0820
_refine_ls_wR_factor_gt          0.0798
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_restrained_S_all      1.037
_refine_ls_shift/su_max          0.027
_refine_ls_shift/su_mean         0.008

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P -0.33008(6) -0.12801(8) 1.17525(7) 0.0075(2) Uani 1 1 d . . .
Al1 Al -0.10649(6) -0.38076(8) 1.20448(9) 0.0067(2) Uani 1 1 d . . .
P2 P -0.42349(5) -0.62004(7) 1.21202(7) 0.0067(2) Uani 1 1 d . . .
P3 P -0.20584(6) -0.38090(8) 1.39566(8) 0.0076(2) Uani 1 1 d . . .
Al2 Al -0.30539(6) -0.61893(9) 1.38156(10) 0.0088(3) Uani 1 1 d . . .
Al3 Al -0.20032(6) 0.07382(9) 1.15815(8) 0.0066(2) Uani 1 1 d . . .
P4 P -0.29439(6) 0.12179(8) 0.88952(8) 0.0079(2) Uani 1 1 d . . .
P5 P -0.07725(5) -0.12266(7) 1.07395(7) 0.0065(2) Uani 1 1 d . . .
Al4 Al -0.29921(6) -0.42905(9) 1.12540(9) 0.0073(2) Uani 1 1 d . . .
O8 O -0.20652(14) -0.3545(2) 1.1530(2) 0.0120(6) Uani 1 1 d . . .
O20 O -0.29302(14) 0.1498(2) 1.1330(2) 0.0121(6) Uani 1 1 d . . .
O9 O -0.13379(15) -0.3724(2) 1.3322(2) 0.0139(6) Uani 1 1 d . . .
O10 O -0.10971(14) -0.5460(2) 1.1638(2) 0.0128(6) Uani 1 1 d . . .
O16 O -0.18456(16) -0.4370(2) 1.4940(2) 0.0136(6) Uani 1 1 d . . .
O14 O -0.38628(14) -0.4953(2) 1.1743(2) 0.0124(6) Uani 1 1 d . . .
O1 O -0.36560(15) 0.1276(2) 0.9537(2) 0.0113(6) Uani 1 1 d . . .
O23 O -0.38963(14) -0.0440(2) 1.1229(2) 0.0114(6) Uani 1 1 d . . .
O19 O -0.18312(16) 0.0729(2) 1.2871(2) 0.0158(6) Uani 1 1 d . . .
O13 O -0.25074(16) -0.59100(18) 1.1352(2) 0.0108(6) Uani 1 1 d . . .
O11 O -0.34547(16) -0.6026(3) 1.4973(2) 0.0178(6) Uani 1 1 d . . .
O3 O -0.11884(15) -0.1627(2) 0.9776(2) 0.0152(6) Uani 1 1 d . . .
O4 O -0.11194(13) 0.0032(2) 1.1112(2) 0.0109(6) Uani 1 1 d . . .
O2 O -0.23517(14) 0.0289(2) 0.9346(2) 0.0135(6) Uani 1 1 d . . .
O15 O -0.34284(14) -0.2675(2) 1.1444(2) 0.0157(6) Uani 1 1 d . . .
O21 O -0.15309(14) 0.2313(2) 1.1293(2) 0.0146(6) Uani 1 1 d . . .
O6 O -0.08270(14) -0.2287(2) 1.1506(2) 0.0123(6) Uani 1 1 d . . .
O25 O -0.41789(15) -0.7238(2) 1.1340(2) 0.0135(6) Uani 1 1 d . . .
O24 O -0.34335(17) -0.1123(3) 1.2858(2) 0.0205(7) Uani 1 1 d . . .
O17 O -0.26494(14) -0.4705(2) 1.3451(2) 0.0129(6) Uani 1 1 d . . .
O7 O -0.00557(14) -0.4055(2) 1.24087(19) 0.0090(5) Uani 1 1 d . . .
O18 O -0.23801(15) -0.2447(2) 1.4074(2) 0.0171(6) Uani 1 1 d . . .
O5 O 0.00554(14) -0.0940(2) 1.0461(2) 0.0097(5) Uani 1 1 d . . .
O12 O -0.23931(16) -0.74308(18) 1.3818(2) 0.0180(6) Uani 1 1 d . . .
O26 O -0.38084(14) -0.6639(2) 1.3047(2) 0.0126(5) Uani 1 1 d . . .
O22 O -0.24822(16) -0.08649(19) 1.1487(2) 0.0118(6) Uani 1 1 d . . .
Al5 Al -0.30450(6) -0.12159(9) 1.40287(10) 0.0083(3) Uani 1 1 d . . .
P6 P -0.16843(6) 0.37256(7) 1.10728(8) 0.0080(2) Uani 1 1 d . . .
Al6 Al -0.39178(6) 0.12144(8) 1.08171(9) 0.0067(2) Uani 1 1 d . . .
Na1 Na -0.50998(8) -0.14940(14) 1.09490(14) 0.0292(3) Uani 1 1 d . . .
Na2 Na 0.00720(9) -0.18574(17) 0.87538(13) 0.0364(4) Uani 1 1 d . . .
O3W O -0.00544(16) -0.2516(4) 1.4456(3) 0.0614(12) Uani 1 1 d . . .
O1W O -0.4710(2) -0.6006(3) 0.9335(3) 0.0638(11) Uani 1 1 d . . .
O2W O 0.0112(2) 0.0200(4) 0.8082(3) 0.0632(10) Uani 1 1 d . . .
O4W O -0.49367(12) -0.2907(2) 1.2262(2) 0.0213(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O15 1.516(2) . ?
P1 O24 1.528(3) . ?
P1 O23 1.530(3) . ?
P1 O22 1.538(3) . ?
P1 Na1 3.3384(18) . ?
Al1 O6 1.780(2) . ?
Al1 O10 1.793(2) . ?
Al1 O9 1.801(3) . ?
Al1 O7 1.851(3) . ?
Al1 O8 1.904(3) . ?
P2 O25 1.509(3) . ?
P2 O7 1.512(2) 3_445 ?
P2 O14 1.531(2) . ?
P2 O26 1.531(3) . ?
P3 O16 1.502(3) . ?
P3 O18 1.522(2) . ?
P3 O9 1.529(3) . ?
P3 O17 1.548(2) . ?
Al2 O12 1.726(2) . ?
Al2 O11 1.730(3) . ?
Al2 O26 1.746(3) . ?
Al2 O17 1.758(2) . ?
Al3 O19 1.777(3) . ?
Al3 O4 1.824(3) . ?
Al3 O20 1.834(3) . ?
Al3 O22 1.859(2) . ?
Al3 O21 1.865(2) . ?
Al3 Na1 3.5262(19) 3 ?
P4 O12 1.518(2) 4_464 ?
P4 O1 1.521(3) . ?
P4 O19 1.530(3) 4_454 ?
P4 O2 1.538(3) . ?
P5 O6 1.514(3) . ?
P5 O4 1.521(2) . ?
P5 O5 1.526(3) . ?
P5 O3 1.553(3) . ?
P5 Na1 3.0578(17) 3 ?
P5 Na2 3.142(2) . ?
Al4 O14 1.797(3) . ?
Al4 O16 1.808(3) 4_454 ?
Al4 O8 1.833(3) . ?
Al4 O15 1.851(3) . ?
Al4 O13 1.879(2) . ?
O20 Al6 1.886(3) . ?
O10 P6 1.533(3) 1_545 ?
O16 Al4 1.808(3) 4_455 ?
O1 Al6 1.799(3) . ?
O1 Na2 2.538(3) 3_455 ?
O23 Al6 1.797(2) . ?
O23 Na1 2.400(3) . ?
O19 P4 1.530(3) 4_455 ?
O13 P6 1.536(3) 1_545 ?
O11 P6 1.534(3) 4_445 ?
O3 Al5 1.734(3) 4_454 ?
O3 Na2 2.616(3) . ?
O4 Na1 2.347(3) 3 ?
O2 Al5 1.755(2) 4_454 ?
O21 P6 1.513(2) . ?
O21 Na1 2.683(3) 3 ?
O25 Al6 1.807(3) 1_545 ?
O24 Al5 1.731(3) . ?
O7 P2 1.512(2) 3_545 ?
O18 Al5 1.724(2) . ?
O5 Al6 1.882(3) 3 ?
O5 Na2 2.504(3) . ?
O5 Na1 2.612(3) 3 ?
O12 P4 1.518(2) 4_445 ?
Al5 O3 1.734(3) 4_455 ?
Al5 O2 1.755(2) 4_455 ?
P6 O10 1.533(3) 1_565 ?
P6 O11 1.534(3) 4_464 ?
P6 O13 1.536(3) 1_565 ?
Al6 O25 1.807(3) 1_565 ?
Al6 O5 1.882(3) 3_455 ?
Al6 Na2 3.378(2) 3_455 ?
Al6 Na1 3.4816(19) . ?
Na1 O3W 2.301(4) 4_454 ?
Na1 O4W 2.320(3) . ?
Na1 O4 2.347(3) 3_455 ?
Na1 O5 2.612(3) 3_455 ?
Na1 O21 2.683(3) 3_455 ?
Na1 P5 3.0578(17) 3_455 ?
Na1 Al3 3.5262(19) 3_455 ?
Na1 Na2 3.827(3) 4_455 ?
Na2 O4W 2.309(3) 4_454 ?
Na2 O2W 2.312(4) . ?
Na2 O1W 2.373(4) 3_545 ?
Na2 O1 2.538(3) 3 ?
Na2 Al6 3.378(2) 3 ?
Na2 Na1 3.827(3) 4_454 ?
O3W Na1 2.301(4) 4_455 ?
O1W Na2 2.373(4) 3_445 ?
O4W Na2 2.309(3) 4_455 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O15 P1 O24 110.46(17) . . ?
O15 P1 O23 108.03(15) . . ?
O24 P1 O23 107.02(17) . . ?
O15 P1 O22 109.71(13) . . ?
O24 P1 O22 110.01(17) . . ?
O23 P1 O22 111.56(15) . . ?
O15 P1 Na1 73.03(10) . . ?
O24 P1 Na1 100.65(13) . . ?
O23 P1 Na1 40.87(9) . . ?
O22 P1 Na1 145.08(12) . . ?
O6 Al1 O10 135.96(15) . . ?
O6 Al1 O9 114.52(13) . . ?
O10 Al1 O9 109.51(13) . . ?
O6 Al1 O7 90.47(11) . . ?
O10 Al1 O7 88.92(11) . . ?
O9 Al1 O7 90.14(13) . . ?
O6 Al1 O8 86.49(12) . . ?
O10 Al1 O8 89.61(12) . . ?
O9 Al1 O8 95.91(14) . . ?
O7 Al1 O8 173.91(14) . . ?
O25 P2 O7 111.54(14) . 3_445 ?
O25 P2 O14 109.52(16) . . ?
O7 P2 O14 110.13(13) 3_445 . ?
O25 P2 O26 109.57(15) . . ?
O7 P2 O26 107.55(16) 3_445 . ?
O14 P2 O26 108.46(15) . . ?
O16 P3 O18 110.74(17) . . ?
O16 P3 O9 108.56(16) . . ?
O18 P3 O9 108.10(15) . . ?
O16 P3 O17 109.22(15) . . ?
O18 P3 O17 110.57(16) . . ?
O9 P3 O17 109.61(16) . . ?
O12 Al2 O11 110.00(16) . . ?
O12 Al2 O26 108.07(14) . . ?
O11 Al2 O26 105.24(15) . . ?
O12 Al2 O17 112.19(13) . . ?
O11 Al2 O17 109.51(15) . . ?
O26 Al2 O17 111.59(14) . . ?
O19 Al3 O4 101.46(14) . . ?
O19 Al3 O20 109.61(14) . . ?
O4 Al3 O20 148.81(15) . . ?
O19 Al3 O22 98.01(14) . . ?
O4 Al3 O22 90.15(12) . . ?
O20 Al3 O22 88.23(12) . . ?
O19 Al3 O21 97.85(14) . . ?
O4 Al3 O21 84.21(11) . . ?
O20 Al3 O21 88.86(11) . . ?
O22 Al3 O21 163.94(14) . . ?
O19 Al3 Na1 94.67(11) . 3 ?
O4 Al3 Na1 37.14(8) . 3 ?
O20 Al3 Na1 134.05(10) . 3 ?
O22 Al3 Na1 127.29(9) . 3 ?
O21 Al3 Na1 48.52(8) . 3 ?
O12 P4 O1 108.76(14) 4_464 . ?
O12 P4 O19 109.90(17) 4_464 4_454 ?
O1 P4 O19 108.80(16) . 4_454 ?
O12 P4 O2 109.77(16) 4_464 . ?
O1 P4 O2 110.39(16) . . ?
O19 P4 O2 109.20(15) 4_454 . ?
O6 P5 O4 111.35(16) . . ?
O6 P5 O5 111.74(14) . . ?
O4 P5 O5 107.20(13) . . ?
O6 P5 O3 110.94(15) . . ?
O4 P5 O3 108.71(15) . . ?
O5 P5 O3 106.70(16) . . ?
O6 P5 Na1 128.63(12) . 3 ?
O4 P5 Na1 48.55(9) . 3 ?
O5 P5 Na1 58.65(9) . 3 ?
O3 P5 Na1 120.21(11) . 3 ?
O6 P5 Na2 118.02(12) . . ?
O4 P5 Na2 130.54(12) . . ?
O5 P5 Na2 51.77(11) . . ?
O3 P5 Na2 56.11(11) . . ?
Na1 P5 Na2 95.11(5) 3 . ?
O14 Al4 O16 102.36(14) . 4_454 ?
O14 Al4 O8 146.52(15) . . ?
O16 Al4 O8 111.06(14) 4_454 . ?
O14 Al4 O15 86.65(11) . . ?
O16 Al4 O15 96.53(13) 4_454 . ?
O8 Al4 O15 87.62(11) . . ?
O14 Al4 O13 91.03(12) . . ?
O16 Al4 O13 95.77(13) 4_454 . ?
O8 Al4 O13 87.68(12) . . ?
O15 Al4 O13 167.69(14) . . ?
Al4 O8 Al1 145.93(15) . . ?
Al3 O20 Al6 144.36(15) . . ?
P3 O9 Al1 139.30(19) . . ?
P6 O10 Al1 134.17(16) 1_545 . ?
P3 O16 Al4 145.14(18) . 4_455 ?
P2 O14 Al4 143.53(16) . . ?
P4 O1 Al6 139.50(19) . . ?
P4 O1 Na2 119.18(16) . 3_455 ?
Al6 O1 Na2 100.94(12) . 3_455 ?
P1 O23 Al6 134.18(16) . . ?
P1 O23 Na1 114.47(13) . . ?
Al6 O23 Na1 111.28(12) . . ?
P4 O19 Al3 148.20(19) 4_455 . ?
P6 O13 Al4 128.57(15) 1_545 . ?
P6 O11 Al2 143.51(19) 4_445 . ?
P5 O3 Al5 142.18(18) . 4_454 ?
P5 O3 Na2 94.37(12) . . ?
Al5 O3 Na2 111.32(15) 4_454 . ?
P5 O4 Al3 142.72(15) . . ?
P5 O4 Na1 102.39(13) . 3 ?
Al3 O4 Na1 114.87(11) . 3 ?
P4 O2 Al5 136.08(19) . 4_454 ?
P1 O15 Al4 146.40(17) . . ?
P6 O21 Al3 143.42(16) . . ?
P6 O21 Na1 115.76(13) . 3 ?
Al3 O21 Na1 100.11(10) . 3 ?
P5 O6 Al1 159.1(2) . . ?
P2 O25 Al6 156.9(2) . 1_545 ?
P1 O24 Al5 146.8(2) . . ?
P3 O17 Al2 131.68(18) . . ?
P2 O7 Al1 144.38(17) 3_545 . ?
P3 O18 Al5 157.9(2) . . ?
P5 O5 Al6 144.41(18) . 3 ?
P5 O5 Na2 99.63(13) . . ?
Al6 O5 Na2 99.79(12) 3 . ?
P5 O5 Na1 91.42(11) . 3 ?
Al6 O5 Na1 100.30(10) 3 3 ?
Na2 O5 Na1 126.85(12) . 3 ?
P4 O12 Al2 160.5(2) 4_445 . ?
P2 O26 Al2 141.35(17) . . ?
P1 O22 Al3 130.67(14) . . ?
O18 Al5 O24 109.80(16) . . ?
O18 Al5 O3 108.69(14) . 4_455 ?
O24 Al5 O3 104.31(16) . 4_455 ?
O18 Al5 O2 112.14(13) . 4_455 ?
O24 Al5 O2 109.34(15) . 4_455 ?
O3 Al5 O2 112.27(14) 4_455 4_455 ?
O21 P6 O10 108.10(15) . 1_565 ?
O21 P6 O11 108.99(17) . 4_464 ?
O10 P6 O11 106.80(17) 1_565 4_464 ?
O21 P6 O13 110.71(13) . 1_565 ?
O10 P6 O13 111.74(14) 1_565 1_565 ?
O11 P6 O13 110.36(17) 4_464 1_565 ?
O23 Al6 O1 109.19(13) . . ?
O23 Al6 O25 136.30(15) . 1_565 ?
O1 Al6 O25 114.41(13) . 1_565 ?
O23 Al6 O5 87.54(11) . 3_455 ?
O1 Al6 O5 89.99(13) . 3_455 ?
O25 Al6 O5 89.59(12) 1_565 3_455 ?
O23 Al6 O20 90.77(12) . . ?
O1 Al6 O20 96.79(14) . . ?
O25 Al6 O20 87.09(13) 1_565 . ?
O5 Al6 O20 173.19(15) 3_455 . ?
O23 Al6 Na2 117.11(10) . 3_455 ?
O1 Al6 Na2 47.54(9) . 3_455 ?
O25 Al6 Na2 91.15(11) 1_565 3_455 ?
O5 Al6 Na2 46.92(9) 3_455 3_455 ?
O20 Al6 Na2 139.04(10) . 3_455 ?
O23 Al6 Na1 39.97(8) . . ?
O1 Al6 Na1 103.24(9) . . ?
O25 Al6 Na1 122.64(10) 1_565 . ?
O5 Al6 Na1 47.58(7) 3_455 . ?
O20 Al6 Na1 130.53(9) . . ?
Na2 Al6 Na1 83.67(5) 3_455 . ?
O3W Na1 O4W 111.98(14) 4_454 . ?
O3W Na1 O4 117.83(13) 4_454 3_455 ?
O4W Na1 O4 115.16(12) . 3_455 ?
O3W Na1 O23 104.14(12) 4_454 . ?
O4W Na1 O23 93.17(10) . . ?
O4 Na1 O23 111.14(10) 3_455 . ?
O3W Na1 O5 101.82(14) 4_454 3_455 ?
O4W Na1 O5 141.86(12) . 3_455 ?
O4 Na1 O5 58.99(9) 3_455 3_455 ?
O23 Na1 O5 60.87(8) . 3_455 ?
O3W Na1 O21 96.81(11) 4_454 3_455 ?
O4W Na1 O21 77.47(9) . 3_455 ?
O4 Na1 O21 58.45(8) 3_455 3_455 ?
O23 Na1 O21 159.00(12) . 3_455 ?
O5 Na1 O21 116.36(9) 3_455 3_455 ?
O3W Na1 P5 112.58(12) 4_454 3_455 ?
O4W Na1 P5 134.10(10) . 3_455 ?
O4 Na1 P5 29.06(6) 3_455 3_455 ?
O23 Na1 P5 86.35(7) . 3_455 ?
O5 Na1 P5 29.93(6) 3_455 3_455 ?
O21 Na1 P5 86.92(6) 3_455 3_455 ?
O3W Na1 P1 101.98(9) 4_454 . ?
O4W Na1 P1 71.01(6) . . ?
O4 Na1 P1 130.04(9) 3_455 . ?
O23 Na1 P1 24.66(6) . . ?
O5 Na1 P1 85.49(7) 3_455 . ?
O21 Na1 P1 147.51(9) 3_455 . ?
P5 Na1 P1 109.42(5) 3_455 . ?
O3W Na1 Al6 104.65(11) 4_454 . ?
O4W Na1 Al6 118.10(8) . . ?
O4 Na1 Al6 86.57(7) 3_455 . ?
O23 Na1 Al6 28.76(6) . . ?
O5 Na1 Al6 32.12(6) 3_455 . ?
O21 Na1 Al6 144.68(7) 3_455 . ?
P5 Na1 Al6 59.11(4) 3_455 . ?
P1 Na1 Al6 53.40(3) . . ?
O3W Na1 Al3 115.26(9) 4_454 3_455 ?
O4W Na1 Al3 93.91(7) . 3_455 ?
O4 Na1 Al3 27.99(6) 3_455 3_455 ?
O23 Na1 Al3 133.60(9) . 3_455 ?
O5 Na1 Al3 86.98(7) 3_455 3_455 ?
O21 Na1 Al3 31.37(5) 3_455 3_455 ?
P5 Na1 Al3 57.05(3) 3_455 3_455 ?
P1 Na1 Al3 142.76(6) . 3_455 ?
Al6 Na1 Al3 113.31(5) . 3_455 ?
O3W Na1 Na2 146.13(12) 4_454 4_455 ?
O4W Na1 Na2 34.16(8) . 4_455 ?
O4 Na1 Na2 88.79(9) 3_455 4_455 ?
O23 Na1 Na2 82.85(9) . 4_455 ?
O5 Na1 Na2 110.21(9) 3_455 4_455 ?
O21 Na1 Na2 78.91(8) 3_455 4_455 ?
P5 Na1 Na2 100.81(6) 3_455 4_455 ?
P1 Na1 Na2 70.69(4) . 4_455 ?
Al6 Na1 Na2 97.03(5) . 4_455 ?
Al3 Na1 Na2 77.96(5) 3_455 4_455 ?
O4W Na2 O2W 95.05(14) 4_454 . ?
O4W Na2 O1W 82.65(13) 4_454 3_545 ?
O2W Na2 O1W 168.45(16) . 3_545 ?
O4W Na2 O5 171.19(11) 4_454 . ?
O2W Na2 O5 91.04(14) . . ?
O1W Na2 O5 92.62(13) 3_545 . ?
O4W Na2 O1 124.62(10) 4_454 3 ?
O2W Na2 O1 85.49(13) . 3 ?
O1W Na2 O1 86.53(13) 3_545 3 ?
O5 Na2 O1 62.16(9) . 3 ?
O4W Na2 O3 114.94(10) 4_454 . ?
O2W Na2 O3 98.70(13) . . ?
O1W Na2 O3 92.51(14) 3_545 . ?
O5 Na2 O3 57.64(9) . . ?
O1 Na2 O3 119.69(11) 3 . ?
O4W Na2 P5 143.28(9) 4_454 . ?
O2W Na2 P5 99.34(13) . . ?
O1W Na2 P5 89.03(12) 3_545 . ?
O5 Na2 P5 28.61(6) . . ?
O1 Na2 P5 90.22(8) 3 . ?
O3 Na2 P5 29.52(6) . . ?
O4W Na2 Al6 150.83(9) 4_454 3 ?
O2W Na2 Al6 97.52(12) . 3 ?
O1W Na2 Al6 79.79(11) 3_545 3 ?
O5 Na2 Al6 33.29(6) . 3 ?
O1 Na2 Al6 31.52(7) 3 3 ?
O3 Na2 Al6 89.03(8) . 3 ?
P5 Na2 Al6 59.59(4) . 3 ?
O4W Na2 Na1 34.35(7) 4_454 4_454 ?
O2W Na2 Na1 61.13(12) . 4_454 ?
O1W Na2 Na1 114.82(12) 3_545 4_454 ?
O5 Na2 Na1 152.16(9) . 4_454 ?
O1 Na2 Na1 112.48(9) 3 4_454 ?
O3 Na2 Na1 121.99(8) . 4_454 ?
P5 Na2 Na1 147.08(6) . 4_454 ?
Al6 Na2 Na1 143.06(6) 3 4_454 ?
Na2 O4W Na1 111.49(12) 4_455 . ?

_diffrn_measured_fraction_theta_max 0.988
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.988
_refine_diff_density_max         0.668
_refine_diff_density_min         -0.441
_refine_diff_density_rms         0.098
_database_code_depnum_ccdc_archive 'CCDC 979303'
