# Electronic Supplementary Material (ESI) for Chemical Communications.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C33 H46 Ga N'
_chemical_formula_sum            'C33 H46 Ga N'
_chemical_formula_weight         526.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 21/c'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   8.0037(11)
_cell_length_b                   42.296(5)
_cell_length_c                   9.1578(11)
_cell_angle_alpha                90.00
_cell_angle_beta                 98.422(7)
_cell_angle_gamma                90.00
_cell_volume                     3066.7(7)
_cell_formula_units_Z            4
_cell_measurement_temperature    93(2)
_cell_measurement_reflns_used    12260
_cell_measurement_theta_min      6.42
_cell_measurement_theta_max      54.87

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.140
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1128
_exptl_absorpt_coefficient_mu    0.917
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.9957
_exptl_absorpt_correction_T_max  0.9957
_exptl_absorpt_process_details   
;
 ?
;

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      93(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'rigaku raxis rapid'
_diffrn_measurement_method       'oscillation method'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            29745
_diffrn_reflns_av_R_equivalents  0.0894
_diffrn_reflns_av_sigmaI/netI    0.0902
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -54
_diffrn_reflns_limit_k_max       54
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         3.20
_diffrn_reflns_theta_max         27.49
_reflns_number_total             7025
_reflns_number_gt                4190
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       PROCESS-AUTO
_computing_cell_refinement       PROCESS-AUTO
_computing_data_reduction        'Yadokari-XG (Wakita, 2000)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Yadokari-XG 2009 (Wakita Nemoto et al., 2009)'
_computing_publication_material  
;Yadokari-XG 2009 (Wakita,Nemoto et al., 2009)
;

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0712P)²+1.1773P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7025
_refine_ls_number_parameters     328
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1106
_refine_ls_R_factor_gt           0.0601
_refine_ls_wR_factor_ref         0.1693
_refine_ls_wR_factor_gt          0.1407
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_restrained_S_all      1.027
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga1 Ga 0.81895(5) 0.145010(9) 0.04880(4) 0.05820(16) Uani 1 1 d . . .
N1 N 1.0394(4) 0.14889(7) -0.0536(3) 0.0655(8) Uani 1 1 d . . .
C7 C 0.8952(5) 0.08510(8) 0.2510(4) 0.0599(9) Uani 1 1 d . . .
C8 C 0.9229(4) 0.10485(8) 0.1335(4) 0.0561(8) Uani 1 1 d . . .
C9 C 1.0426(4) 0.09505(8) 0.0469(4) 0.0586(8) Uani 1 1 d . . .
C10 C 0.9072(5) 0.19697(9) 0.2700(4) 0.0698(10) Uani 1 1 d . . .
H1 H 1.0134 0.1876 0.2884 0.084 Uiso 1 1 calc R . .
C1 C 0.4509(5) 0.09758(10) -0.2588(4) 0.0682(10) Uani 1 1 d . . .
C11 C 0.6344(5) 0.19968(8) 0.1348(4) 0.0652(9) Uani 1 1 d . . .
H2 H 0.5531 0.1922 0.0597 0.078 Uiso 1 1 calc R . .
C12 C 0.7883(5) 0.18457(8) 0.1587(4) 0.0615(9) Uani 1 1 d . . .
C2 C 0.5730(5) 0.10585(9) -0.1412(4) 0.0636(9) Uani 1 1 d . . .
H3 H 0.6114 0.0904 -0.0719 0.076 Uiso 1 1 calc R . .
C13 C 1.1338(5) 0.06744(9) 0.0733(4) 0.0666(10) Uani 1 1 d . . .
H4 H 1.2140 0.0621 0.0135 0.080 Uiso 1 1 calc R . .
C3 C 0.6407(5) 0.13616(9) -0.1222(4) 0.0648(9) Uani 1 1 d . . .
C14 C 1.1074(5) 0.04765(9) 0.1873(4) 0.0657(9) Uani 1 1 d . . .
C15 C 0.7712(5) 0.09428(10) 0.3581(4) 0.0704(10) Uani 1 1 d . . .
C16 C 0.8731(5) 0.22292(9) 0.3548(4) 0.0738(11) Uani 1 1 d . . .
C17 C 0.7163(6) 0.23658(9) 0.3253(5) 0.0773(11) Uani 1 1 d . . .
H5 H 0.6921 0.2540 0.3807 0.093 Uiso 1 1 calc R . .
C18 C 0.5943(5) 0.22544(9) 0.2171(5) 0.0718(10) Uani 1 1 d . . .
C4 C 0.5805(5) 0.15843(10) -0.2304(4) 0.0727(10) Uani 1 1 d . . .
H6 H 0.6198 0.1791 -0.2199 0.087 Uiso 1 1 calc R . .
C19 C 1.0674(5) 0.11515(9) -0.0863(4) 0.0705(10) Uani 1 1 d . . .
H7 H 1.1810 0.1123 -0.1091 0.085 Uiso 1 1 calc R . .
H8 H 0.9883 0.1086 -0.1715 0.085 Uiso 1 1 calc R . .
C5 C 0.4640(6) 0.15060(11) -0.3529(5) 0.0792(12) Uani 1 1 d . . .
C20 C 0.9872(5) 0.05693(9) 0.2733(4) 0.0660(9) Uani 1 1 d . . .
H9 H 0.9665 0.0437 0.3499 0.079 Uiso 1 1 calc R . .
C21 C 1.2043(6) 0.01655(10) 0.2226(4) 0.0839(13) Uani 1 1 d . . .
C6 C 0.4003(5) 0.12032(12) -0.3632(4) 0.0790(12) Uani 1 1 d . . .
H10 H 0.3201 0.1151 -0.4436 0.095 Uiso 1 1 calc R . .
C22 C 0.3803(6) 0.06490(11) -0.2748(5) 0.0927(14) Uani 1 1 d . . .
H11 H 0.2594 0.0659 -0.2958 0.139 Uiso 1 1 calc R . .
H12 H 0.4128 0.0534 -0.1847 0.139 Uiso 1 1 calc R . .
H13 H 0.4234 0.0543 -0.3542 0.139 Uiso 1 1 calc R . .
C23 C 1.0233(6) 0.16764(10) -0.1916(5) 0.0880(13) Uani 1 1 d . . .
H14 H 1.1245 0.1655 -0.2356 0.132 Uiso 1 1 calc R . .
H15 H 1.0064 0.1895 -0.1696 0.132 Uiso 1 1 calc R . .
H16 H 0.9286 0.1601 -0.2592 0.132 Uiso 1 1 calc R . .
C24 C 0.6043(6) 0.10535(12) 0.2764(5) 0.0932(14) Uani 1 1 d . . .
H17 H 0.5595 0.0895 0.2062 0.140 Uiso 1 1 calc R . .
H18 H 0.6205 0.1247 0.2257 0.140 Uiso 1 1 calc R . .
H19 H 0.5267 0.1088 0.3454 0.140 Uiso 1 1 calc R . .
C25 C 0.8488(6) 0.12142(13) 0.4564(5) 0.1035(16) Uani 1 1 d . . .
H20 H 0.8708 0.1390 0.3958 0.155 Uiso 1 1 calc R . .
H21 H 0.9526 0.1145 0.5133 0.155 Uiso 1 1 calc R . .
H22 H 0.7715 0.1278 0.5218 0.155 Uiso 1 1 calc R . .
C26 C 0.7401(7) 0.06696(14) 0.4589(6) 0.126(2) Uani 1 1 d . . .
H23 H 0.6618 0.0735 0.5230 0.189 Uiso 1 1 calc R . .
H24 H 0.8449 0.0609 0.5169 0.189 Uiso 1 1 calc R . .
H25 H 0.6941 0.0493 0.4002 0.189 Uiso 1 1 calc R . .
C27 C 1.0808(8) -0.01112(11) 0.2141(6) 0.117(2) Uani 1 1 d . . .
H26 H 1.0208 -0.0127 0.1157 0.176 Uiso 1 1 calc R . .
H27 H 1.0020 -0.0077 0.2821 0.176 Uiso 1 1 calc R . .
H28 H 1.1421 -0.0303 0.2393 0.176 Uiso 1 1 calc R . .
C28 C 1.3007(7) 0.01840(13) 0.3784(5) 0.1054(16) Uani 1 1 d . . .
H29 H 1.2221 0.0200 0.4478 0.158 Uiso 1 1 calc R . .
H30 H 1.3728 0.0366 0.3869 0.158 Uiso 1 1 calc R . .
H31 H 1.3680 -0.0003 0.3988 0.158 Uiso 1 1 calc R . .
C29 C 1.1844(6) 0.16076(12) 0.0499(5) 0.0915(13) Uani 1 1 d . . .
H32 H 1.1975 0.1483 0.1384 0.137 Uiso 1 1 calc R . .
H33 H 1.1649 0.1824 0.0740 0.137 Uiso 1 1 calc R . .
H34 H 1.2851 0.1593 0.0049 0.137 Uiso 1 1 calc R . .
C30 C 1.0037(7) 0.23539(12) 0.4752(6) 0.1144(18) Uani 1 1 d . . .
H35 H 1.0887 0.2466 0.4323 0.172 Uiso 1 1 calc R . .
H36 H 1.0548 0.2181 0.5332 0.172 Uiso 1 1 calc R . .
H37 H 0.9511 0.2494 0.5371 0.172 Uiso 1 1 calc R . .
C31 C 0.4129(8) 0.17481(14) -0.4730(6) 0.124(2) Uani 1 1 d . . .
H38 H 0.4023 0.1952 -0.4291 0.186 Uiso 1 1 calc R . .
H39 H 0.3066 0.1688 -0.5288 0.186 Uiso 1 1 calc R . .
H40 H 0.4974 0.1757 -0.5373 0.186 Uiso 1 1 calc R . .
C32 C 0.4188(6) 0.24012(11) 0.1918(7) 0.1113(17) Uani 1 1 d . . .
H41 H 0.4194 0.2594 0.2473 0.167 Uiso 1 1 calc R . .
H42 H 0.3390 0.2256 0.2235 0.167 Uiso 1 1 calc R . .
H43 H 0.3874 0.2446 0.0887 0.167 Uiso 1 1 calc R . .
C33 C 1.3297(8) 0.01040(14) 0.1152(6) 0.138(2) Uani 1 1 d . . .
H44 H 1.3919 -0.0086 0.1434 0.207 Uiso 1 1 calc R . .
H45 H 1.4065 0.0279 0.1176 0.207 Uiso 1 1 calc R . .
H46 H 1.2695 0.0080 0.0172 0.207 Uiso 1 1 calc R . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga1 C12 1.986(4) . ?
Ga1 C3 1.993(4) . ?
Ga1 C8 1.998(3) . ?
Ga1 N1 2.123(3) . ?
N1 C29 1.475(5) . ?
N1 C23 1.482(5) . ?
N1 C19 1.482(4) . ?
C7 C20 1.400(5) . ?
C7 C8 1.405(5) . ?
C7 C15 1.544(5) . ?
C8 C9 1.393(4) . ?
C9 C13 1.380(5) . ?
C9 C19 1.523(5) . ?
C10 C12 1.391(5) . ?
C10 C16 1.395(5) . ?
C1 C6 1.375(6) . ?
C1 C2 1.389(5) . ?
C1 C22 1.492(6) . ?
C11 C12 1.376(5) . ?
C11 C18 1.389(5) . ?
C2 C3 1.393(5) . ?
C13 C14 1.379(5) . ?
C3 C4 1.400(5) . ?
C14 C20 1.386(5) . ?
C14 C21 1.537(5) . ?
C15 C24 1.507(6) . ?
C15 C26 1.522(6) . ?
C15 C25 1.533(6) . ?
C16 C17 1.371(5) . ?
C16 C30 1.499(6) . ?
C17 C18 1.370(5) . ?
C18 C32 1.522(6) . ?
C4 C5 1.390(6) . ?
C5 C6 1.377(6) . ?
C5 C31 1.515(6) . ?
C21 C28 1.522(6) . ?
C21 C27 1.526(7) . ?
C21 C33 1.527(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C12 Ga1 C3 115.39(15) . . ?
C12 Ga1 C8 126.51(14) . . ?
C3 Ga1 C8 110.79(15) . . ?
C12 Ga1 N1 109.34(13) . . ?
C3 Ga1 N1 102.31(14) . . ?
C8 Ga1 N1 84.91(12) . . ?
C29 N1 C23 109.2(3) . . ?
C29 N1 C19 109.3(3) . . ?
C23 N1 C19 109.9(3) . . ?
C29 N1 Ga1 111.7(2) . . ?
C23 N1 Ga1 116.4(3) . . ?
C19 N1 Ga1 100.1(2) . . ?
C20 C7 C8 118.7(3) . . ?
C20 C7 C15 119.6(3) . . ?
C8 C7 C15 121.7(3) . . ?
C9 C8 C7 117.3(3) . . ?
C9 C8 Ga1 108.3(2) . . ?
C7 C8 Ga1 134.4(3) . . ?
C13 C9 C8 122.8(3) . . ?
C13 C9 C19 119.0(3) . . ?
C8 C9 C19 118.1(3) . . ?
C12 C10 C16 122.4(4) . . ?
C6 C1 C2 117.8(4) . . ?
C6 C1 C22 120.7(4) . . ?
C2 C1 C22 121.5(4) . . ?
C12 C11 C18 123.4(4) . . ?
C11 C12 C10 116.2(3) . . ?
C11 C12 Ga1 119.0(3) . . ?
C10 C12 Ga1 124.5(3) . . ?
C1 C2 C3 123.0(4) . . ?
C14 C13 C9 120.7(3) . . ?
C2 C3 C4 116.3(4) . . ?
C2 C3 Ga1 119.4(3) . . ?
C4 C3 Ga1 124.2(3) . . ?
C13 C14 C20 117.0(3) . . ?
C13 C14 C21 123.3(3) . . ?
C20 C14 C21 119.6(3) . . ?
C24 C15 C26 109.0(4) . . ?
C24 C15 C25 108.2(4) . . ?
C26 C15 C25 107.5(4) . . ?
C24 C15 C7 111.6(3) . . ?
C26 C15 C7 111.8(3) . . ?
C25 C15 C7 108.6(3) . . ?
C17 C16 C10 118.0(4) . . ?
C17 C16 C30 121.0(4) . . ?
C10 C16 C30 120.9(4) . . ?
C18 C17 C16 122.2(4) . . ?
C17 C18 C11 117.7(4) . . ?
C17 C18 C32 121.0(4) . . ?
C11 C18 C32 121.3(4) . . ?
C5 C4 C3 122.1(4) . . ?
N1 C19 C9 109.5(3) . . ?
C6 C5 C4 118.4(4) . . ?
C6 C5 C31 121.4(4) . . ?
C4 C5 C31 120.2(5) . . ?
C14 C20 C7 123.5(3) . . ?
C28 C21 C27 108.8(4) . . ?
C28 C21 C33 108.8(4) . . ?
C27 C21 C33 108.6(4) . . ?
C28 C21 C14 108.9(4) . . ?
C27 C21 C14 110.0(4) . . ?
C33 C21 C14 111.7(4) . . ?
C1 C6 C5 122.3(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C12 Ga1 N1 C29 47.6(3) . . . . ?
C3 Ga1 N1 C29 170.4(3) . . . . ?
C8 Ga1 N1 C29 -79.4(3) . . . . ?
C12 Ga1 N1 C23 -78.6(3) . . . . ?
C3 Ga1 N1 C23 44.2(3) . . . . ?
C8 Ga1 N1 C23 154.4(3) . . . . ?
C12 Ga1 N1 C19 163.2(2) . . . . ?
C3 Ga1 N1 C19 -74.0(3) . . . . ?
C8 Ga1 N1 C19 36.2(2) . . . . ?
C20 C7 C8 C9 -0.5(5) . . . . ?
C15 C7 C8 C9 177.3(3) . . . . ?
C20 C7 C8 Ga1 175.8(3) . . . . ?
C15 C7 C8 Ga1 -6.4(6) . . . . ?
C12 Ga1 C8 C9 -130.8(2) . . . . ?
C3 Ga1 C8 C9 80.8(3) . . . . ?
N1 Ga1 C8 C9 -20.4(2) . . . . ?
C12 Ga1 C8 C7 52.7(4) . . . . ?
C3 Ga1 C8 C7 -95.7(4) . . . . ?
N1 Ga1 C8 C7 163.0(4) . . . . ?
C7 C8 C9 C13 -0.7(5) . . . . ?
Ga1 C8 C9 C13 -178.0(3) . . . . ?
C7 C8 C9 C19 176.5(3) . . . . ?
Ga1 C8 C9 C19 -0.7(4) . . . . ?
C18 C11 C12 C10 -1.4(6) . . . . ?
C18 C11 C12 Ga1 172.8(3) . . . . ?
C16 C10 C12 C11 1.0(6) . . . . ?
C16 C10 C12 Ga1 -172.9(3) . . . . ?
C3 Ga1 C12 C11 14.1(3) . . . . ?
C8 Ga1 C12 C11 -133.1(3) . . . . ?
N1 Ga1 C12 C11 128.7(3) . . . . ?
C3 Ga1 C12 C10 -172.2(3) . . . . ?
C8 Ga1 C12 C10 40.7(4) . . . . ?
N1 Ga1 C12 C10 -57.5(3) . . . . ?
C6 C1 C2 C3 2.5(5) . . . . ?
C22 C1 C2 C3 -179.5(4) . . . . ?
C8 C9 C13 C14 1.3(6) . . . . ?
C19 C9 C13 C14 -176.0(3) . . . . ?
C1 C2 C3 C4 -0.8(5) . . . . ?
C1 C2 C3 Ga1 -178.8(3) . . . . ?
C12 Ga1 C3 C2 -134.7(3) . . . . ?
C8 Ga1 C3 C2 17.5(3) . . . . ?
N1 Ga1 C3 C2 106.7(3) . . . . ?
C12 Ga1 C3 C4 47.5(4) . . . . ?
C8 Ga1 C3 C4 -160.2(3) . . . . ?
N1 Ga1 C3 C4 -71.1(3) . . . . ?
C9 C13 C14 C20 -0.5(6) . . . . ?
C9 C13 C14 C21 179.9(4) . . . . ?
C20 C7 C15 C24 -134.3(4) . . . . ?
C8 C7 C15 C24 47.9(5) . . . . ?
C20 C7 C15 C26 -11.9(6) . . . . ?
C8 C7 C15 C26 170.3(4) . . . . ?
C20 C7 C15 C25 106.6(4) . . . . ?
C8 C7 C15 C25 -71.3(5) . . . . ?
C12 C10 C16 C17 -0.5(6) . . . . ?
C12 C10 C16 C30 179.2(4) . . . . ?
C10 C16 C17 C18 0.4(6) . . . . ?
C30 C16 C17 C18 -179.3(4) . . . . ?
C16 C17 C18 C11 -0.8(6) . . . . ?
C16 C17 C18 C32 177.1(4) . . . . ?
C12 C11 C18 C17 1.3(6) . . . . ?
C12 C11 C18 C32 -176.5(4) . . . . ?
C2 C3 C4 C5 -2.2(6) . . . . ?
Ga1 C3 C4 C5 175.7(3) . . . . ?
C29 N1 C19 C9 73.5(4) . . . . ?
C23 N1 C19 C9 -166.8(3) . . . . ?
Ga1 N1 C19 C9 -43.8(3) . . . . ?
C13 C9 C19 N1 -149.4(3) . . . . ?
C8 C9 C19 N1 33.2(5) . . . . ?
C3 C4 C5 C6 3.3(6) . . . . ?
C3 C4 C5 C31 -175.2(4) . . . . ?
C13 C14 C20 C7 -0.9(6) . . . . ?
C21 C14 C20 C7 178.8(4) . . . . ?
C8 C7 C20 C14 1.4(6) . . . . ?
C15 C7 C20 C14 -176.5(3) . . . . ?
C13 C14 C21 C28 119.4(4) . . . . ?
C20 C14 C21 C28 -60.2(5) . . . . ?
C13 C14 C21 C27 -121.4(4) . . . . ?
C20 C14 C21 C27 59.0(5) . . . . ?
C13 C14 C21 C33 -0.8(6) . . . . ?
C20 C14 C21 C33 179.6(4) . . . . ?
C2 C1 C6 C5 -1.2(6) . . . . ?
C22 C1 C6 C5 -179.3(4) . . . . ?
C4 C5 C6 C1 -1.6(6) . . . . ?
C31 C5 C6 C1 176.9(4) . . . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.364
_refine_diff_density_min         -0.740
_refine_diff_density_rms         0.057
_chemical_absolute_configuration ?
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: chloroform and methanol'
_database_code_depnum_ccdc_archive 'CCDC 1023564'
