# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2014

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4NaPF6
_database_code_depnum_ccdc_archive 'CCDC 1033776'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C60 H76 F6 N8 Na O8 P Rh4, C4 H10 O, C H4 O'
_chemical_formula_sum            'C65 H90 F6 N8 Na O10 P Rh4'
_chemical_formula_weight         1723.05

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.7562(6)
_cell_length_b                   16.3493(8)
_cell_length_c                   27.6506(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.707(1)
_cell_angle_gamma                90.00
_cell_volume                     7571.6(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    185(2)
_cell_measurement_reflns_used    46477
_cell_measurement_theta_min      3.07
_cell_measurement_theta_max      27.52

_exptl_crystal_description       prismatic
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.512
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3504
_exptl_absorpt_coefficient_mu    0.955
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.7626
_exptl_absorpt_correction_T_max  0.9105
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      185(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            72097
_diffrn_reflns_av_R_equivalents  0.0484
_diffrn_reflns_av_sigmaI/netI    0.0403
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         3.07
_diffrn_reflns_theta_max         27.49
_reflns_number_total             17312
_reflns_number_gt                11845
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    SIR2004
_computing_structure_refinement  SHELXL-97
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1275P)²+29.9532P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         17312
_refine_ls_number_parameters     856
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1115
_refine_ls_R_factor_gt           0.0811
_refine_ls_wR_factor_ref         0.2495
_refine_ls_wR_factor_gt          0.2270
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_restrained_S_all      1.030
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.27517(4) 0.05919(4) 0.27895(2) 0.0633(2) Uani 1 1 d . . .
Rh2 Rh 0.47131(3) 0.23118(4) 0.39859(2) 0.04985(17) Uani 1 1 d . . .
Rh3 Rh 0.21504(4) 0.35601(4) 0.487945(19) 0.05471(18) Uani 1 1 d . . .
Rh4 Rh 0.01967(3) 0.18201(4) 0.36812(2) 0.05674(19) Uani 1 1 d . . .
P1 P 0.25653(17) -0.01405(19) 0.49935(11) 0.0850(8) Uani 1 1 d . . .
Na1 Na 0.24577(14) 0.1487(2) 0.41174(10) 0.0561(8) Uani 1 1 d . . .
F1 F 0.2609(11) 0.0574(8) 0.4588(6) 0.262(8) Uani 1 1 d . . .
F2 F 0.3011(6) 0.0478(8) 0.5325(5) 0.197(6) Uani 1 1 d . . .
F3 F 0.1770(5) 0.0228(7) 0.5156(6) 0.226(7) Uani 1 1 d . . .
F4 F 0.2084(6) -0.0658(7) 0.4627(4) 0.178(5) Uani 1 1 d . . .
F5 F 0.3351(5) -0.0449(8) 0.4801(3) 0.180(5) Uani 1 1 d . . .
F6 F 0.2514(9) -0.0756(7) 0.5385(4) 0.220(6) Uani 1 1 d . . .
O1 O 0.3728(3) 0.1588(3) 0.36714(18) 0.0536(12) Uani 1 1 d . . .
O2 O 0.5314(4) 0.3251(4) 0.2837(2) 0.0834(19) Uani 1 1 d . . .
O3 O 0.3016(3) 0.2740(3) 0.45067(17) 0.0551(12) Uani 1 1 d . . .
O4 O 0.2952(6) 0.5458(4) 0.4449(3) 0.107(3) Uani 1 1 d . . .
O5 O 0.1204(3) 0.2231(3) 0.41600(18) 0.0561(12) Uani 1 1 d . . .
O6 O -0.0443(5) 0.3835(6) 0.3292(4) 0.128(3) Uani 1 1 d . . .
O7 O 0.1912(3) 0.1027(3) 0.33126(19) 0.0579(12) Uani 1 1 d . . .
O8 O 0.1904(5) 0.1660(6) 0.1732(2) 0.119(3) Uani 1 1 d . . .
O9 O 0.2191(9) 0.4507(11) 0.2358(5) 0.185(6) Uani 1 1 d . . .
O10 O 0.3246(5) 0.7632(7) 0.2405(4) 0.127(3) Uani 1 1 d . . .
N1 N 0.3431(3) 0.1665(4) 0.2855(2) 0.0543(15) Uani 1 1 d . . .
N2 N 0.4489(4) 0.2387(4) 0.3238(2) 0.0547(15) Uani 1 1 d . . .
N3 N 0.3974(4) 0.3333(4) 0.4028(2) 0.0537(14) Uani 1 1 d . . .
N4 N 0.3019(4) 0.4076(4) 0.4461(2) 0.0593(16) Uani 1 1 d . . .
N5 N 0.1427(4) 0.3637(5) 0.4252(3) 0.0669(18) Uani 1 1 d . . .
N6 N 0.0412(4) 0.3059(4) 0.3773(3) 0.0628(17) Uani 1 1 d . . .
N7 N 0.0925(4) 0.1920(5) 0.3064(2) 0.0615(17) Uani 1 1 d . . .
N8 N 0.1842(4) 0.1337(5) 0.2543(2) 0.068(2) Uani 1 1 d . . .
C1 C 0.3266(9) -0.0550(7) 0.3042(5) 0.106(4) Uani 1 1 d . . .
C2 C 0.2538(7) -0.0690(7) 0.2759(5) 0.106(4) Uani 1 1 d . . .
C3 C 0.2684(7) -0.0417(7) 0.2294(4) 0.101(4) Uani 1 1 d . . .
C4 C 0.3453(7) -0.0081(8) 0.2280(5) 0.101(4) Uani 1 1 d . . .
C5 C 0.3823(7) -0.0169(7) 0.2748(6) 0.104(4) Uani 1 1 d . . .
C6 C 0.3447(13) -0.0758(9) 0.3542(7) 0.167(8) Uani 1 1 d . . .
H6A H 0.3559 -0.0257 0.3727 0.200 Uiso 1 1 calc R . .
H6B H 0.3915 -0.1117 0.3560 0.200 Uiso 1 1 calc R . .
H6C H 0.2989 -0.1040 0.3679 0.200 Uiso 1 1 calc R . .
C7 C 0.1790(9) -0.1103(8) 0.2916(7) 0.157(8) Uani 1 1 d . . .
H7A H 0.1713 -0.1612 0.2734 0.188 Uiso 1 1 calc R . .
H7B H 0.1333 -0.0740 0.2854 0.188 Uiso 1 1 calc R . .
H7C H 0.1836 -0.1226 0.3263 0.188 Uiso 1 1 calc R . .
C8 C 0.2117(8) -0.0399(11) 0.1846(5) 0.155(8) Uani 1 1 d . . .
H8A H 0.1658 -0.0050 0.1911 0.186 Uiso 1 1 calc R . .
H8B H 0.1932 -0.0956 0.1773 0.186 Uiso 1 1 calc R . .
H8C H 0.2401 -0.0182 0.1569 0.186 Uiso 1 1 calc R . .
C9 C 0.3832(9) 0.0294(10) 0.1845(6) 0.159(8) Uani 1 1 d . . .
H9A H 0.3514 0.0764 0.1733 0.190 Uiso 1 1 calc R . .
H9B H 0.3855 -0.0114 0.1586 0.190 Uiso 1 1 calc R . .
H9C H 0.4375 0.0476 0.1934 0.190 Uiso 1 1 calc R . .
C10 C 0.4646(8) 0.0109(9) 0.2864(7) 0.153(7) Uani 1 1 d . . .
H10A H 0.4685 0.0699 0.2806 0.184 Uiso 1 1 calc R . .
H10B H 0.5020 -0.0180 0.2658 0.184 Uiso 1 1 calc R . .
H10C H 0.4780 -0.0006 0.3204 0.184 Uiso 1 1 calc R . .
C11 C 0.3861(4) 0.1869(5) 0.3247(3) 0.0518(17) Uani 1 1 d . . .
C12 C 0.4730(5) 0.2763(5) 0.2829(3) 0.062(2) Uani 1 1 d . . .
C13 C 0.4265(5) 0.2575(6) 0.2402(3) 0.066(2) Uani 1 1 d . . .
C14 C 0.3652(5) 0.2050(6) 0.2426(3) 0.069(2) Uani 1 1 d . . .
H14 H 0.3352 0.1932 0.2138 0.082 Uiso 1 1 calc R . .
C15 C 0.4514(7) 0.2961(8) 0.1925(3) 0.096(4) Uani 1 1 d . . .
H15A H 0.4068 0.3279 0.1785 0.115 Uiso 1 1 calc R . .
H15B H 0.4660 0.2529 0.1698 0.115 Uiso 1 1 calc R . .
H15C H 0.4973 0.3322 0.1985 0.115 Uiso 1 1 calc R . .
C16 C 0.5115(6) 0.1909(7) 0.4701(3) 0.077(3) Uani 1 1 d . . .
C17 C 0.5382(5) 0.1346(6) 0.4341(4) 0.069(2) Uani 1 1 d . . .
C18 C 0.5879(5) 0.1779(7) 0.4025(4) 0.077(3) Uani 1 1 d . . .
C19 C 0.5913(5) 0.2613(6) 0.4174(4) 0.075(3) Uani 1 1 d . . .
C20 C 0.5446(6) 0.2677(7) 0.4594(4) 0.079(3) Uani 1 1 d . . .
C21 C 0.4606(8) 0.1699(9) 0.5104(4) 0.104(4) Uani 1 1 d . . .
H21A H 0.4114 0.2023 0.5082 0.125 Uiso 1 1 calc R . .
H21B H 0.4891 0.1819 0.5411 0.125 Uiso 1 1 calc R . .
H21C H 0.4474 0.1116 0.5090 0.125 Uiso 1 1 calc R . .
C22 C 0.5169(7) 0.0464(6) 0.4316(4) 0.092(3) Uani 1 1 d . . .
H22A H 0.5656 0.0133 0.4346 0.110 Uiso 1 1 calc R . .
H22B H 0.4897 0.0348 0.4005 0.110 Uiso 1 1 calc R . .
H22C H 0.4815 0.0329 0.4580 0.110 Uiso 1 1 calc R . .
C23 C 0.6319(7) 0.1413(8) 0.3617(5) 0.106(4) Uani 1 1 d . . .
H23A H 0.6895 0.1473 0.3679 0.127 Uiso 1 1 calc R . .
H23B H 0.6167 0.1693 0.3315 0.127 Uiso 1 1 calc R . .
H23C H 0.6186 0.0830 0.3589 0.127 Uiso 1 1 calc R . .
C24 C 0.6399(6) 0.3277(7) 0.3946(5) 0.098(4) Uani 1 1 d . . .
H24A H 0.6226 0.3344 0.3606 0.117 Uiso 1 1 calc R . .
H24B H 0.6965 0.3126 0.3963 0.117 Uiso 1 1 calc R . .
H24C H 0.6323 0.3792 0.4119 0.117 Uiso 1 1 calc R . .
C25 C 0.5315(9) 0.3471(8) 0.4887(5) 0.121(5) Uani 1 1 d . . .
H25A H 0.5501 0.3387 0.5223 0.145 Uiso 1 1 calc R . .
H25B H 0.4745 0.3608 0.4879 0.145 Uiso 1 1 calc R . .
H25C H 0.5616 0.3919 0.4744 0.145 Uiso 1 1 calc R . .
C26 C 0.3364(5) 0.3376(4) 0.4321(2) 0.0505(17) Uani 1 1 d . . .
C27 C 0.3274(6) 0.4807(5) 0.4295(3) 0.070(2) Uani 1 1 d . . .
C28 C 0.3892(6) 0.4810(5) 0.3962(3) 0.067(2) Uani 1 1 d . . .
C29 C 0.4231(5) 0.4074(5) 0.3844(3) 0.0606(19) Uani 1 1 d . . .
H29 H 0.4660 0.4072 0.3628 0.073 Uiso 1 1 calc R . .
C30 C 0.4164(8) 0.5599(6) 0.3754(4) 0.101(4) Uani 1 1 d . . .
H30A H 0.4090 0.5585 0.3401 0.121 Uiso 1 1 calc R . .
H30B H 0.4730 0.5683 0.3839 0.121 Uiso 1 1 calc R . .
H30C H 0.3849 0.6048 0.3885 0.121 Uiso 1 1 calc R . .
C31 C 0.1664(8) 0.2935(6) 0.5499(3) 0.083(3) Uani 1 1 d . . .
C32 C 0.2407(8) 0.3261(7) 0.5620(3) 0.082(3) Uani 1 1 d . . .
C33 C 0.2387(9) 0.4131(8) 0.5548(3) 0.099(4) Uani 1 1 d . . .
C34 C 0.1585(10) 0.4315(7) 0.5384(4) 0.106(5) Uani 1 1 d . . .
C35 C 0.1164(8) 0.3591(8) 0.5361(4) 0.098(4) Uani 1 1 d . . .
C36 C 0.1439(11) 0.2060(7) 0.5496(5) 0.128(6) Uani 1 1 d . . .
H36A H 0.1526 0.1831 0.5820 0.153 Uiso 1 1 calc R . .
H36B H 0.1767 0.1764 0.5266 0.153 Uiso 1 1 calc R . .
H36C H 0.0874 0.2006 0.5398 0.153 Uiso 1 1 calc R . .
C37 C 0.3084(9) 0.2772(12) 0.5822(4) 0.136(6) Uani 1 1 d . . .
H37A H 0.3220 0.2340 0.5592 0.163 Uiso 1 1 calc R . .
H37B H 0.2932 0.2523 0.6128 0.163 Uiso 1 1 calc R . .
H37C H 0.3548 0.3128 0.5879 0.163 Uiso 1 1 calc R . .
C38 C 0.3000(14) 0.4739(12) 0.5642(6) 0.186(10) Uani 1 1 d . . .
H38A H 0.2830 0.5110 0.5898 0.223 Uiso 1 1 calc R . .
H38B H 0.3089 0.5052 0.5347 0.223 Uiso 1 1 calc R . .
H38C H 0.3497 0.4467 0.5746 0.223 Uiso 1 1 calc R . .
C39 C 0.1268(14) 0.5160(9) 0.5276(6) 0.200(11) Uani 1 1 d . . .
H39A H 0.0833 0.5284 0.5493 0.240 Uiso 1 1 calc R . .
H39B H 0.1068 0.5183 0.4940 0.240 Uiso 1 1 calc R . .
H39C H 0.1697 0.5561 0.5325 0.240 Uiso 1 1 calc R . .
C40 C 0.0297(8) 0.3509(11) 0.5186(6) 0.137(6) Uani 1 1 d . . .
H40A H 0.0246 0.3679 0.4847 0.165 Uiso 1 1 calc R . .
H40B H -0.0041 0.3857 0.5384 0.165 Uiso 1 1 calc R . .
H40C H 0.0127 0.2938 0.5216 0.165 Uiso 1 1 calc R . .
C41 C 0.1039(5) 0.3005(5) 0.4079(3) 0.062(2) Uani 1 1 d . . .
C42 C 0.0145(6) 0.3803(7) 0.3597(4) 0.081(3) Uani 1 1 d . . .
C43 C 0.0526(6) 0.4498(6) 0.3770(4) 0.075(2) Uani 1 1 d . . .
C44 C 0.1170(6) 0.4392(6) 0.4093(4) 0.076(2) Uani 1 1 d . . .
H44 H 0.1445 0.4864 0.4209 0.091 Uiso 1 1 calc R . .
C45 C 0.0268(10) 0.5306(8) 0.3573(5) 0.127(5) Uani 1 1 d . . .
H45A H -0.0296 0.5396 0.3643 0.153 Uiso 1 1 calc R . .
H45B H 0.0336 0.5315 0.3223 0.153 Uiso 1 1 calc R . .
H45C H 0.0592 0.5739 0.3725 0.153 Uiso 1 1 calc R . .
C46 C -0.0162(5) 0.0587(6) 0.3834(3) 0.068(2) Uani 1 1 d . . .
C47 C -0.0477(5) 0.1124(6) 0.4178(4) 0.076(3) Uani 1 1 d . . .
C48 C -0.0986(5) 0.1687(8) 0.3929(5) 0.095(4) Uani 1 1 d . . .
C49 C -0.0965(5) 0.1509(8) 0.3429(5) 0.093(3) Uani 1 1 d . . .
C50 C -0.0455(7) 0.0811(8) 0.3380(4) 0.089(3) Uani 1 1 d . . .
C51 C 0.0367(7) -0.0112(6) 0.3960(4) 0.086(3) Uani 1 1 d . . .
H51A H 0.0869 -0.0057 0.3790 0.104 Uiso 1 1 calc R . .
H51B H 0.0103 -0.0624 0.3862 0.104 Uiso 1 1 calc R . .
H51C H 0.0477 -0.0118 0.4310 0.104 Uiso 1 1 calc R . .
C52 C -0.0312(7) 0.1106(8) 0.4715(4) 0.092(3) Uani 1 1 d . . .
H52A H -0.0813 0.1025 0.4882 0.111 Uiso 1 1 calc R . .
H52B H -0.0069 0.1625 0.4818 0.111 Uiso 1 1 calc R . .
H52C H 0.0056 0.0656 0.4795 0.111 Uiso 1 1 calc R . .
C53 C -0.1439(7) 0.2396(9) 0.4161(6) 0.126(5) Uani 1 1 d . . .
H53A H -0.1056 0.2768 0.4321 0.152 Uiso 1 1 calc R . .
H53B H -0.1804 0.2178 0.4400 0.152 Uiso 1 1 calc R . .
H53C H -0.1745 0.2693 0.3910 0.152 Uiso 1 1 calc R . .
C54 C -0.1411(7) 0.1940(11) 0.3029(6) 0.137(6) Uani 1 1 d . . .
H54A H -0.1778 0.1556 0.2866 0.165 Uiso 1 1 calc R . .
H54B H -0.1032 0.2151 0.2796 0.165 Uiso 1 1 calc R . .
H54C H -0.1714 0.2395 0.3163 0.165 Uiso 1 1 calc R . .
C55 C -0.0265(9) 0.0392(9) 0.2902(4) 0.123(5) Uani 1 1 d . . .
H55A H -0.0434 -0.0182 0.2914 0.148 Uiso 1 1 calc R . .
H55B H 0.0312 0.0418 0.2853 0.148 Uiso 1 1 calc R . .
H55C H -0.0549 0.0670 0.2635 0.148 Uiso 1 1 calc R . .
C56 C 0.1539(4) 0.1455(5) 0.2971(3) 0.0541(17) Uani 1 1 d . . .
C57 C 0.1552(7) 0.1772(7) 0.2146(3) 0.087(3) Uani 1 1 d . . .
C58 C 0.0872(6) 0.2293(7) 0.2222(3) 0.075(3) Uani 1 1 d . . .
C59 C 0.0590(6) 0.2344(6) 0.2660(3) 0.077(3) Uani 1 1 d . . .
H59 H 0.0138 0.2682 0.2707 0.092 Uiso 1 1 calc R . .
C60 C 0.0530(9) 0.2737(8) 0.1784(4) 0.112(5) Uani 1 1 d . . .
H60A H 0.0556 0.3328 0.1840 0.135 Uiso 1 1 calc R . .
H60B H -0.0028 0.2573 0.1728 0.135 Uiso 1 1 calc R . .
H60C H 0.0838 0.2598 0.1500 0.135 Uiso 1 1 calc R . .
C61 C 0.2339(9) 0.3701(10) 0.3058(5) 0.122(5) Uani 1 1 d . . .
H61A H 0.2722 0.3332 0.2909 0.146 Uiso 1 1 calc R . .
H61B H 0.1802 0.3468 0.3025 0.146 Uiso 1 1 calc R . .
H61C H 0.2482 0.3769 0.3402 0.146 Uiso 1 1 calc R . .
C62 C 0.2354(17) 0.4402(16) 0.2845(7) 0.213(12) Uani 1 1 d . . .
H62A H 0.2894 0.4631 0.2909 0.255 Uiso 1 1 calc R . .
H62B H 0.1978 0.4759 0.3016 0.255 Uiso 1 1 calc R . .
C63 C 0.2621(14) 0.4333(17) 0.2021(11) 0.204(11) Uani 1 1 d . . .
H63A H 0.2723 0.3737 0.2034 0.245 Uiso 1 1 calc R . .
H63B H 0.3140 0.4611 0.2077 0.245 Uiso 1 1 calc R . .
C64 C 0.2334(12) 0.4532(10) 0.1533(6) 0.144(6) Uani 1 1 d . . .
H64A H 0.2259 0.5125 0.1505 0.173 Uiso 1 1 calc R . .
H64B H 0.1824 0.4255 0.1466 0.173 Uiso 1 1 calc R . .
H64C H 0.2726 0.4352 0.1300 0.173 Uiso 1 1 calc R . .
C65 C 0.3376(11) 0.6960(14) 0.2735(6) 0.163(8) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N8 2.053(8) . ?
Rh1 N1 2.096(6) . ?
Rh1 C2 2.128(10) . ?
Rh1 C3 2.145(8) . ?
Rh1 C4 2.161(10) . ?
Rh1 C1 2.164(14) . ?
Rh1 O7 2.169(5) . ?
Rh1 C5 2.190(12) . ?
Rh1 C56 2.536(8) . ?
Rh2 N3 2.084(6) . ?
Rh2 N2 2.095(6) . ?
Rh2 C19 2.119(7) . ?
Rh2 C20 2.136(8) . ?
Rh2 C18 2.139(9) . ?
Rh2 C17 2.155(8) . ?
Rh2 C16 2.171(9) . ?
Rh2 O1 2.190(5) . ?
Rh2 C11 2.562(7) . ?
Rh3 N4 2.066(7) . ?
Rh3 N5 2.092(7) . ?
Rh3 C33 2.098(8) . ?
Rh3 C34 2.109(9) . ?
Rh3 C32 2.136(9) . ?
Rh3 C35 2.153(9) . ?
Rh3 C31 2.174(8) . ?
Rh3 O3 2.249(5) . ?
Rh3 C26 2.608(8) . ?
Rh4 N6 2.072(7) . ?
Rh4 C49 2.110(9) . ?
Rh4 C48 2.128(8) . ?
Rh4 N7 2.133(6) . ?
Rh4 C47 2.133(8) . ?
Rh4 C50 2.134(11) . ?
Rh4 C46 2.149(9) . ?
Rh4 O5 2.218(5) . ?
Rh4 C41 2.619(11) . ?
P1 F6 1.482(8) . ?
P1 F5 1.520(9) . ?
P1 F4 1.531(8) . ?
P1 F3 1.542(9) . ?
P1 F2 1.543(9) . ?
P1 F1 1.623(11) . ?
Na1 F1 1.990(11) . ?
Na1 O5 2.434(6) . ?
Na1 O3 2.484(6) . ?
Na1 O7 2.496(6) . ?
Na1 O1 2.497(6) . ?
O1 C11 1.285(9) . ?
O2 C12 1.263(10) . ?
O3 C26 1.305(8) . ?
O4 C27 1.273(10) . ?
O5 C41 1.313(9) . ?
O6 C42 1.279(12) . ?
O7 C56 1.317(9) . ?
O8 C57 1.318(13) . ?
O9 C63 1.23(3) . ?
O9 C62 1.38(2) . ?
O10 C65 1.441(18) . ?
N1 C11 1.326(9) . ?
N1 C14 1.402(10) . ?
N2 C11 1.353(10) . ?
N2 C12 1.358(10) . ?
N3 C26 1.323(10) . ?
N3 C29 1.388(10) . ?
N4 C26 1.346(10) . ?
N4 C27 1.353(11) . ?
N5 C41 1.304(12) . ?
N5 C44 1.375(11) . ?
N6 C41 1.332(11) . ?
N6 C42 1.379(11) . ?
N7 C56 1.312(10) . ?
N7 C59 1.418(11) . ?
N8 C56 1.316(10) . ?
N8 C57 1.382(13) . ?
C1 C5 1.402(17) . ?
C1 C2 1.45(2) . ?
C1 C6 1.45(2) . ?
C2 C3 1.391(18) . ?
C2 C7 1.499(15) . ?
C3 C4 1.403(14) . ?
C3 C8 1.538(19) . ?
C4 C5 1.426(19) . ?
C4 C9 1.51(2) . ?
C5 C10 1.478(17) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C12 C13 1.428(12) . ?
C13 C14 1.343(11) . ?
C13 C15 1.534(12) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C20 1.407(14) . ?
C16 C17 1.436(14) . ?
C16 C21 1.465(14) . ?
C17 C18 1.416(14) . ?
C17 C22 1.487(13) . ?
C18 C19 1.425(14) . ?
C18 C23 1.491(16) . ?
C19 C20 1.422(15) . ?
C19 C24 1.508(13) . ?
C20 C25 1.550(16) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C27 C28 1.408(13) . ?
C28 C29 1.373(12) . ?
C28 C30 1.489(12) . ?
C29 H29 0.9500 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.386(16) . ?
C31 C35 1.406(16) . ?
C31 C36 1.479(15) . ?
C32 C33 1.436(16) . ?
C32 C37 1.484(17) . ?
C33 C34 1.437(19) . ?
C33 C38 1.449(19) . ?
C34 C35 1.379(17) . ?
C34 C39 1.506(18) . ?
C35 C40 1.524(19) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C42 C43 1.382(15) . ?
C43 C44 1.390(14) . ?
C43 C45 1.487(13) . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C50 1.385(14) . ?
C46 C47 1.408(14) . ?
C46 C51 1.482(14) . ?
C47 C48 1.418(13) . ?
C47 C52 1.503(14) . ?
C48 C49 1.415(17) . ?
C48 C53 1.535(18) . ?
C49 C50 1.434(17) . ?
C49 C54 1.492(16) . ?
C50 C55 1.530(17) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C57 C58 1.443(16) . ?
C58 C59 1.316(13) . ?
C58 C60 1.509(13) . ?
C59 H59 0.9500 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 C62 1.29(2) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C62 H62A 0.9900 . ?
C62 H62B 0.9900 . ?
C63 C64 1.46(3) . ?
C63 H63A 0.9900 . ?
C63 H63B 0.9900 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Rh1 N1 85.9(3) . . ?
N8 Rh1 C2 116.7(4) . . ?
N1 Rh1 C2 156.7(4) . . ?
N8 Rh1 C3 102.7(4) . . ?
N1 Rh1 C3 135.8(3) . . ?
C2 Rh1 C3 38.0(5) . . ?
N8 Rh1 C4 119.9(5) . . ?
N1 Rh1 C4 100.3(3) . . ?
C2 Rh1 C4 64.4(5) . . ?
C3 Rh1 C4 38.0(4) . . ?
N8 Rh1 C1 154.8(4) . . ?
N1 Rh1 C1 119.0(4) . . ?
C2 Rh1 C1 39.4(5) . . ?
C3 Rh1 C1 63.6(5) . . ?
C4 Rh1 C1 63.4(5) . . ?
N8 Rh1 O7 62.4(2) . . ?
N1 Rh1 O7 91.6(2) . . ?
C2 Rh1 O7 103.8(3) . . ?
C3 Rh1 O7 131.0(3) . . ?
C4 Rh1 O7 168.0(3) . . ?
C1 Rh1 O7 109.2(4) . . ?
N8 Rh1 C5 157.2(5) . . ?
N1 Rh1 C5 92.1(3) . . ?
C2 Rh1 C5 64.9(4) . . ?
C3 Rh1 C5 63.8(5) . . ?
C4 Rh1 C5 38.2(5) . . ?
C1 Rh1 C5 37.6(5) . . ?
O7 Rh1 C5 140.4(5) . . ?
N8 Rh1 C56 31.1(2) . . ?
N1 Rh1 C56 87.3(2) . . ?
C2 Rh1 C56 114.9(4) . . ?
C3 Rh1 C56 121.8(4) . . ?
C4 Rh1 C56 150.0(4) . . ?
C1 Rh1 C56 136.9(4) . . ?
O7 Rh1 C56 31.3(2) . . ?
C5 Rh1 C56 171.6(5) . . ?
N3 Rh2 N2 85.4(2) . . ?
N3 Rh2 C19 111.2(3) . . ?
N2 Rh2 C19 111.7(3) . . ?
N3 Rh2 C20 93.5(4) . . ?
N2 Rh2 C20 147.4(3) . . ?
C19 Rh2 C20 39.0(4) . . ?
N3 Rh2 C18 150.1(3) . . ?
N2 Rh2 C18 102.1(3) . . ?
C19 Rh2 C18 39.1(4) . . ?
C20 Rh2 C18 64.6(4) . . ?
N3 Rh2 C17 149.6(3) . . ?
N2 Rh2 C17 124.6(3) . . ?
C19 Rh2 C17 65.3(3) . . ?
C20 Rh2 C17 64.4(4) . . ?
C18 Rh2 C17 38.5(4) . . ?
N3 Rh2 C16 111.1(4) . . ?
N2 Rh2 C16 163.4(4) . . ?
C19 Rh2 C16 65.2(4) . . ?
C20 Rh2 C16 38.1(4) . . ?
C18 Rh2 C16 64.7(4) . . ?
C17 Rh2 C16 38.8(4) . . ?
N3 Rh2 O1 90.7(2) . . ?
N2 Rh2 O1 61.9(2) . . ?
C19 Rh2 O1 157.1(3) . . ?
C20 Rh2 O1 150.7(3) . . ?
C18 Rh2 O1 118.5(3) . . ?
C17 Rh2 O1 99.2(3) . . ?
C16 Rh2 O1 114.0(3) . . ?
N3 Rh2 C11 87.3(2) . . ?
N2 Rh2 C11 31.8(2) . . ?
C19 Rh2 C11 139.8(3) . . ?
C20 Rh2 C11 178.8(3) . . ?
C18 Rh2 C11 114.3(3) . . ?
C17 Rh2 C11 115.2(3) . . ?
C16 Rh2 C11 142.2(3) . . ?
O1 Rh2 C11 30.1(2) . . ?
N4 Rh3 N5 84.9(3) . . ?
N4 Rh3 C33 101.2(4) . . ?
N5 Rh3 C33 142.6(5) . . ?
N4 Rh3 C34 118.0(4) . . ?
N5 Rh3 C34 104.7(5) . . ?
C33 Rh3 C34 39.9(5) . . ?
N4 Rh3 C32 120.4(4) . . ?
N5 Rh3 C32 154.8(4) . . ?
C33 Rh3 C32 39.6(4) . . ?
C34 Rh3 C32 65.3(5) . . ?
N4 Rh3 C35 154.6(4) . . ?
N5 Rh3 C35 94.3(4) . . ?
C33 Rh3 C35 64.7(5) . . ?
C34 Rh3 C35 37.7(5) . . ?
C32 Rh3 C35 63.2(5) . . ?
N4 Rh3 C31 156.9(4) . . ?
N5 Rh3 C31 117.5(4) . . ?
C33 Rh3 C31 65.1(5) . . ?
C34 Rh3 C31 64.4(4) . . ?
C32 Rh3 C31 37.5(4) . . ?
C35 Rh3 C31 37.9(4) . . ?
N4 Rh3 O3 60.8(2) . . ?
N5 Rh3 O3 91.2(2) . . ?
C33 Rh3 O3 124.2(5) . . ?
C34 Rh3 O3 164.0(5) . . ?
C32 Rh3 O3 100.9(3) . . ?
C35 Rh3 O3 144.6(4) . . ?
C31 Rh3 O3 110.1(3) . . ?
N4 Rh3 C26 30.8(2) . . ?
N5 Rh3 C26 87.6(2) . . ?
C33 Rh3 C26 116.3(4) . . ?
C34 Rh3 C26 146.4(4) . . ?
C32 Rh3 C26 113.8(4) . . ?
C35 Rh3 C26 174.5(4) . . ?
C31 Rh3 C26 136.9(3) . . ?
O3 Rh3 C26 30.0(2) . . ?
N6 Rh4 C49 115.5(4) . . ?
N6 Rh4 C48 102.7(4) . . ?
C49 Rh4 C48 39.0(5) . . ?
N6 Rh4 N7 85.5(3) . . ?
C49 Rh4 N7 107.3(4) . . ?
C48 Rh4 N7 145.7(4) . . ?
N6 Rh4 C47 122.4(4) . . ?
C49 Rh4 C47 65.4(4) . . ?
C48 Rh4 C47 38.9(4) . . ?
N7 Rh4 C47 152.0(4) . . ?
N6 Rh4 C50 152.7(4) . . ?
C49 Rh4 C50 39.5(5) . . ?
C48 Rh4 C50 64.9(5) . . ?
N7 Rh4 C50 92.6(3) . . ?
C47 Rh4 C50 64.2(4) . . ?
N6 Rh4 C46 160.3(3) . . ?
C49 Rh4 C46 65.1(4) . . ?
C48 Rh4 C46 64.6(4) . . ?
N7 Rh4 C46 113.6(3) . . ?
C47 Rh4 C46 38.4(4) . . ?
C50 Rh4 C46 37.7(4) . . ?
N6 Rh4 O5 60.3(2) . . ?
C49 Rh4 O5 161.5(4) . . ?
C48 Rh4 O5 122.6(4) . . ?
N7 Rh4 O5 90.6(2) . . ?
C47 Rh4 O5 100.7(3) . . ?
C50 Rh4 O5 147.0(4) . . ?
C46 Rh4 O5 112.3(3) . . ?
N6 Rh4 C41 30.2(2) . . ?
C49 Rh4 C41 142.9(4) . . ?
C48 Rh4 C41 115.8(4) . . ?
N7 Rh4 C41 88.0(2) . . ?
C47 Rh4 C41 114.4(3) . . ?
C50 Rh4 C41 177.1(4) . . ?
C46 Rh4 C41 139.6(3) . . ?
O5 Rh4 C41 30.1(2) . . ?
F6 P1 F5 95.7(8) . . ?
F6 P1 F4 93.9(8) . . ?
F5 P1 F4 91.7(6) . . ?
F6 P1 F3 89.1(8) . . ?
F5 P1 F3 175.2(8) . . ?
F4 P1 F3 88.0(6) . . ?
F6 P1 F2 92.8(8) . . ?
F5 P1 F2 90.9(6) . . ?
F4 P1 F2 172.5(8) . . ?
F3 P1 F2 88.7(6) . . ?
F6 P1 F1 176.6(9) . . ?
F5 P1 F1 86.6(9) . . ?
F4 P1 F1 88.5(7) . . ?
F3 P1 F1 88.7(9) . . ?
F2 P1 F1 84.7(8) . . ?
F1 Na1 O5 115.9(6) . . ?
F1 Na1 O3 107.2(5) . . ?
O5 Na1 O3 83.2(2) . . ?
F1 Na1 O7 113.1(5) . . ?
O5 Na1 O7 84.23(19) . . ?
O3 Na1 O7 139.3(2) . . ?
F1 Na1 O1 106.2(6) . . ?
O5 Na1 O1 137.8(2) . . ?
O3 Na1 O1 81.00(19) . . ?
O7 Na1 O1 82.82(18) . . ?
P1 F1 Na1 169.7(13) . . ?
C11 O1 Rh2 91.2(4) . . ?
C11 O1 Na1 130.3(4) . . ?
Rh2 O1 Na1 118.9(2) . . ?
C26 O3 Rh3 90.4(5) . . ?
C26 O3 Na1 130.8(4) . . ?
Rh3 O3 Na1 116.8(2) . . ?
C41 O5 Rh4 92.1(5) . . ?
C41 O5 Na1 130.6(5) . . ?
Rh4 O5 Na1 117.5(2) . . ?
C56 O7 Rh1 89.9(4) . . ?
C56 O7 Na1 129.3(5) . . ?
Rh1 O7 Na1 117.7(2) . . ?
C63 O9 C62 127(2) . . ?
C11 N1 C14 115.3(6) . . ?
C11 N1 Rh1 124.2(5) . . ?
C14 N1 Rh1 117.3(5) . . ?
C11 N2 C12 123.4(7) . . ?
C11 N2 Rh2 93.5(5) . . ?
C12 N2 Rh2 143.1(5) . . ?
C26 N3 C29 115.6(6) . . ?
C26 N3 Rh2 123.2(5) . . ?
C29 N3 Rh2 119.1(5) . . ?
C26 N4 C27 120.7(7) . . ?
C26 N4 Rh3 97.5(5) . . ?
C27 N4 Rh3 141.7(6) . . ?
C41 N5 C44 116.6(8) . . ?
C41 N5 Rh3 121.8(6) . . ?
C44 N5 Rh3 119.2(7) . . ?
C41 N6 C42 121.6(8) . . ?
C41 N6 Rh4 98.2(5) . . ?
C42 N6 Rh4 140.0(7) . . ?
C56 N7 C59 115.0(7) . . ?
C56 N7 Rh4 125.7(6) . . ?
C59 N7 Rh4 116.5(6) . . ?
C56 N8 C57 120.2(9) . . ?
C56 N8 Rh1 95.2(5) . . ?
C57 N8 Rh1 144.0(7) . . ?
C5 C1 C2 108.8(13) . . ?
C5 C1 C6 122.3(16) . . ?
C2 C1 C6 128.9(15) . . ?
C5 C1 Rh1 72.3(8) . . ?
C2 C1 Rh1 69.0(8) . . ?
C6 C1 Rh1 125.5(9) . . ?
C3 C2 C1 106.3(10) . . ?
C3 C2 C7 125.7(14) . . ?
C1 C2 C7 127.8(15) . . ?
C3 C2 Rh1 71.7(6) . . ?
C1 C2 Rh1 71.6(6) . . ?
C7 C2 Rh1 125.0(9) . . ?
C2 C3 C4 109.7(12) . . ?
C2 C3 C8 129.0(11) . . ?
C4 C3 C8 121.1(12) . . ?
C2 C3 Rh1 70.3(5) . . ?
C4 C3 Rh1 71.6(5) . . ?
C8 C3 Rh1 121.3(10) . . ?
C3 C4 C5 108.1(12) . . ?
C3 C4 C9 126.2(13) . . ?
C5 C4 C9 125.7(11) . . ?
C3 C4 Rh1 70.4(5) . . ?
C5 C4 Rh1 72.0(6) . . ?
C9 C4 Rh1 124.3(9) . . ?
C1 C5 C4 107.0(11) . . ?
C1 C5 C10 130.2(16) . . ?
C4 C5 C10 122.8(14) . . ?
C1 C5 Rh1 70.2(7) . . ?
C4 C5 Rh1 69.8(7) . . ?
C10 C5 Rh1 125.1(8) . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O1 C11 N1 123.5(7) . . ?
O1 C11 N2 113.4(6) . . ?
N1 C11 N2 123.1(7) . . ?
O1 C11 Rh2 58.7(4) . . ?
N1 C11 Rh2 177.7(6) . . ?
N2 C11 Rh2 54.7(4) . . ?
O2 C12 N2 121.4(8) . . ?
O2 C12 C13 123.7(8) . . ?
N2 C12 C13 114.9(7) . . ?
C14 C13 C12 119.8(8) . . ?
C14 C13 C15 122.3(8) . . ?
C12 C13 C15 117.8(7) . . ?
C13 C14 N1 123.4(8) . . ?
C13 C14 H14 118.3 . . ?
N1 C14 H14 118.3 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C20 C16 C17 107.1(9) . . ?
C20 C16 C21 127.6(11) . . ?
C17 C16 C21 125.3(10) . . ?
C20 C16 Rh2 69.6(5) . . ?
C17 C16 Rh2 70.0(5) . . ?
C21 C16 Rh2 126.3(7) . . ?
C18 C17 C16 107.9(8) . . ?
C18 C17 C22 127.0(10) . . ?
C16 C17 C22 125.1(9) . . ?
C18 C17 Rh2 70.1(5) . . ?
C16 C17 Rh2 71.2(5) . . ?
C22 C17 Rh2 124.7(6) . . ?
C17 C18 C19 108.5(9) . . ?
C17 C18 C23 125.4(10) . . ?
C19 C18 C23 126.0(10) . . ?
C17 C18 Rh2 71.4(5) . . ?
C19 C18 Rh2 69.7(5) . . ?
C23 C18 Rh2 126.7(7) . . ?
C20 C19 C18 106.8(9) . . ?
C20 C19 C24 127.4(10) . . ?
C18 C19 C24 125.7(11) . . ?
C20 C19 Rh2 71.1(5) . . ?
C18 C19 Rh2 71.2(5) . . ?
C24 C19 Rh2 125.8(6) . . ?
C16 C20 C19 109.6(9) . . ?
C16 C20 C25 125.1(11) . . ?
C19 C20 C25 125.3(10) . . ?
C16 C20 Rh2 72.3(5) . . ?
C19 C20 Rh2 69.8(5) . . ?
C25 C20 Rh2 124.0(8) . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C16 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C17 C22 H22A 109.5 . . ?
C17 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C17 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C18 C23 H23A 109.5 . . ?
C18 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C18 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C19 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C19 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O3 C26 N3 124.1(7) . . ?
O3 C26 N4 111.3(7) . . ?
N3 C26 N4 124.6(6) . . ?
O3 C26 Rh3 59.6(4) . . ?
N3 C26 Rh3 176.2(5) . . ?
N4 C26 Rh3 51.8(4) . . ?
O4 C27 N4 119.0(8) . . ?
O4 C27 C28 122.9(8) . . ?
N4 C27 C28 118.1(7) . . ?
C29 C28 C27 118.0(7) . . ?
C29 C28 C30 122.3(9) . . ?
C27 C28 C30 119.7(8) . . ?
C28 C29 N3 122.9(7) . . ?
C28 C29 H29 118.6 . . ?
N3 C29 H29 118.6 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 C35 107.2(10) . . ?
C32 C31 C36 126.9(12) . . ?
C35 C31 C36 125.8(14) . . ?
C32 C31 Rh3 69.8(5) . . ?
C35 C31 Rh3 70.2(5) . . ?
C36 C31 Rh3 123.4(7) . . ?
C31 C32 C33 109.3(11) . . ?
C31 C32 C37 123.7(12) . . ?
C33 C32 C37 126.9(14) . . ?
C31 C32 Rh3 72.7(6) . . ?
C33 C32 Rh3 68.8(5) . . ?
C37 C32 Rh3 127.9(8) . . ?
C32 C33 C34 105.6(11) . . ?
C32 C33 C38 129.9(17) . . ?
C34 C33 C38 124.4(16) . . ?
C32 C33 Rh3 71.6(5) . . ?
C34 C33 Rh3 70.4(6) . . ?
C38 C33 Rh3 125.3(9) . . ?
C35 C34 C33 107.9(12) . . ?
C35 C34 C39 127.0(17) . . ?
C33 C34 C39 125.2(16) . . ?
C35 C34 Rh3 72.9(6) . . ?
C33 C34 Rh3 69.7(6) . . ?
C39 C34 Rh3 124.6(8) . . ?
C34 C35 C31 110.0(13) . . ?
C34 C35 C40 124.9(14) . . ?
C31 C35 C40 125.0(13) . . ?
C34 C35 Rh3 69.4(6) . . ?
C31 C35 Rh3 71.8(5) . . ?
C40 C35 Rh3 123.0(9) . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N5 C41 O5 127.0(8) . . ?
N5 C41 N6 123.7(7) . . ?
O5 C41 N6 109.3(8) . . ?
N5 C41 Rh4 175.1(6) . . ?
O5 C41 Rh4 57.8(5) . . ?
N6 C41 Rh4 51.5(5) . . ?
O6 C42 N6 120.2(11) . . ?
O6 C42 C43 122.3(9) . . ?
N6 C42 C43 117.5(9) . . ?
C42 C43 C44 117.5(8) . . ?
C42 C43 C45 118.5(10) . . ?
C44 C43 C45 123.8(11) . . ?
N5 C44 C43 123.1(10) . . ?
N5 C44 H44 118.5 . . ?
C43 C44 H44 118.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C50 C46 C47 108.5(9) . . ?
C50 C46 C51 127.6(10) . . ?
C47 C46 C51 123.8(9) . . ?
C50 C46 Rh4 70.6(6) . . ?
C47 C46 Rh4 70.2(5) . . ?
C51 C46 Rh4 126.9(6) . . ?
C46 C47 C48 108.0(10) . . ?
C46 C47 C52 126.3(9) . . ?
C48 C47 C52 125.6(11) . . ?
C46 C47 Rh4 71.4(5) . . ?
C48 C47 Rh4 70.4(5) . . ?
C52 C47 Rh4 124.1(7) . . ?
C49 C48 C47 107.9(11) . . ?
C49 C48 C53 126.2(11) . . ?
C47 C48 C53 125.8(12) . . ?
C49 C48 Rh4 69.8(5) . . ?
C47 C48 Rh4 70.7(4) . . ?
C53 C48 Rh4 122.3(9) . . ?
C48 C49 C50 106.8(9) . . ?
C48 C49 C54 126.9(13) . . ?
C50 C49 C54 126.3(13) . . ?
C48 C49 Rh4 71.2(5) . . ?
C50 C49 Rh4 71.2(5) . . ?
C54 C49 Rh4 124.6(9) . . ?
C46 C50 C49 108.7(10) . . ?
C46 C50 C55 125.9(12) . . ?
C49 C50 C55 125.4(12) . . ?
C46 C50 Rh4 71.7(6) . . ?
C49 C50 Rh4 69.3(6) . . ?
C55 C50 Rh4 124.4(8) . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C50 C55 H55A 109.5 . . ?
C50 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C50 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
N7 C56 N8 126.0(7) . . ?
N7 C56 O7 121.6(7) . . ?
N8 C56 O7 112.4(7) . . ?
N7 C56 Rh1 178.3(6) . . ?
N8 C56 Rh1 53.7(5) . . ?
O7 C56 Rh1 58.8(4) . . ?
O8 C57 N8 117.6(12) . . ?
O8 C57 C58 125.7(10) . . ?
N8 C57 C58 116.7(9) . . ?
C59 C58 C57 118.5(9) . . ?
C59 C58 C60 124.7(11) . . ?
C57 C58 C60 116.8(10) . . ?
C58 C59 N7 123.4(10) . . ?
C58 C59 H59 118.3 . . ?
N7 C59 H59 118.3 . . ?
C58 C60 H60A 109.5 . . ?
C58 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C58 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C61 C62 O9 123(2) . . ?
C61 C62 H62A 106.5 . . ?
O9 C62 H62A 106.5 . . ?
C61 C62 H62B 106.5 . . ?
O9 C62 H62B 106.5 . . ?
H62A C62 H62B 106.5 . . ?
O9 C63 C64 117.7(19) . . ?
O9 C63 H63A 107.9 . . ?
C64 C63 H63A 107.9 . . ?
O9 C63 H63B 107.9 . . ?
C64 C63 H63B 107.9 . . ?
H63A C63 H63B 107.2 . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F6 P1 F1 Na1 -61(17) . . . . ?
F5 P1 F1 Na1 166(6) . . . . ?
F4 P1 F1 Na1 75(6) . . . . ?
F3 P1 F1 Na1 -13(6) . . . . ?
F2 P1 F1 Na1 -102(6) . . . . ?
O5 Na1 F1 P1 9(6) . . . . ?
O3 Na1 F1 P1 99(6) . . . . ?
O7 Na1 F1 P1 -86(6) . . . . ?
O1 Na1 F1 P1 -175(6) . . . . ?
N3 Rh2 O1 C11 83.4(4) . . . . ?
N2 Rh2 O1 C11 -1.0(4) . . . . ?
C19 Rh2 O1 C11 -80.2(9) . . . . ?
C20 Rh2 O1 C11 -178.2(7) . . . . ?
C18 Rh2 O1 C11 -89.9(5) . . . . ?
C17 Rh2 O1 C11 -125.4(5) . . . . ?
C16 Rh2 O1 C11 -163.0(5) . . . . ?
N3 Rh2 O1 Na1 -55.3(3) . . . . ?
N2 Rh2 O1 Na1 -139.7(3) . . . . ?
C19 Rh2 O1 Na1 141.1(7) . . . . ?
C20 Rh2 O1 Na1 43.1(8) . . . . ?
C18 Rh2 O1 Na1 131.4(4) . . . . ?
C17 Rh2 O1 Na1 95.9(4) . . . . ?
C16 Rh2 O1 Na1 58.3(4) . . . . ?
C11 Rh2 O1 Na1 -138.7(5) . . . . ?
F1 Na1 O1 C11 154.7(7) . . . . ?
O5 Na1 O1 C11 -30.6(7) . . . . ?
O3 Na1 O1 C11 -99.9(6) . . . . ?
O7 Na1 O1 C11 42.6(6) . . . . ?
F1 Na1 O1 Rh2 -85.3(5) . . . . ?
O5 Na1 O1 Rh2 89.4(3) . . . . ?
O3 Na1 O1 Rh2 20.1(3) . . . . ?
O7 Na1 O1 Rh2 162.6(3) . . . . ?
N4 Rh3 O3 C26 -0.4(4) . . . . ?
N5 Rh3 O3 C26 83.1(4) . . . . ?
C33 Rh3 O3 C26 -84.0(6) . . . . ?
C34 Rh3 O3 C26 -90.4(14) . . . . ?
C32 Rh3 O3 C26 -119.2(5) . . . . ?
C35 Rh3 O3 C26 -177.7(7) . . . . ?
C31 Rh3 O3 C26 -157.0(5) . . . . ?
N4 Rh3 O3 Na1 -137.7(3) . . . . ?
N5 Rh3 O3 Na1 -54.3(3) . . . . ?
C33 Rh3 O3 Na1 138.6(5) . . . . ?
C34 Rh3 O3 Na1 132.2(13) . . . . ?
C32 Rh3 O3 Na1 103.5(4) . . . . ?
C35 Rh3 O3 Na1 44.9(8) . . . . ?
C31 Rh3 O3 Na1 65.7(4) . . . . ?
C26 Rh3 O3 Na1 -137.3(5) . . . . ?
F1 Na1 O3 C26 147.8(9) . . . . ?
O5 Na1 O3 C26 -97.2(7) . . . . ?
O7 Na1 O3 C26 -24.3(8) . . . . ?
O1 Na1 O3 C26 43.5(7) . . . . ?
F1 Na1 O3 Rh3 -95.7(6) . . . . ?
O5 Na1 O3 Rh3 19.3(2) . . . . ?
O7 Na1 O3 Rh3 92.2(3) . . . . ?
O1 Na1 O3 Rh3 160.0(2) . . . . ?
N6 Rh4 O5 C41 0.4(4) . . . . ?
C49 Rh4 O5 C41 -81.4(12) . . . . ?
C48 Rh4 O5 C41 -86.0(5) . . . . ?
N7 Rh4 O5 C41 84.9(4) . . . . ?
C47 Rh4 O5 C41 -120.9(5) . . . . ?
C50 Rh4 O5 C41 -179.4(6) . . . . ?
C46 Rh4 O5 C41 -159.2(5) . . . . ?
N6 Rh4 O5 Na1 -138.5(3) . . . . ?
C49 Rh4 O5 Na1 139.6(11) . . . . ?
C48 Rh4 O5 Na1 135.1(4) . . . . ?
N7 Rh4 O5 Na1 -54.1(3) . . . . ?
C47 Rh4 O5 Na1 100.1(4) . . . . ?
C50 Rh4 O5 Na1 41.7(7) . . . . ?
C46 Rh4 O5 Na1 61.8(4) . . . . ?
C41 Rh4 O5 Na1 -138.9(5) . . . . ?
F1 Na1 O5 C41 146.9(8) . . . . ?
O3 Na1 O5 C41 41.0(7) . . . . ?
O7 Na1 O5 C41 -100.2(7) . . . . ?
O1 Na1 O5 C41 -27.5(8) . . . . ?
F1 Na1 O5 Rh4 -93.0(6) . . . . ?
O3 Na1 O5 Rh4 161.2(2) . . . . ?
O7 Na1 O5 Rh4 20.0(3) . . . . ?
O1 Na1 O5 Rh4 92.7(3) . . . . ?
N8 Rh1 O7 C56 -2.3(4) . . . . ?
N1 Rh1 O7 C56 82.1(4) . . . . ?
C2 Rh1 O7 C56 -115.6(6) . . . . ?
C3 Rh1 O7 C56 -85.1(7) . . . . ?
C4 Rh1 O7 C56 -106(2) . . . . ?
C1 Rh1 O7 C56 -156.3(5) . . . . ?
C5 Rh1 O7 C56 177.4(5) . . . . ?
N8 Rh1 O7 Na1 -137.9(4) . . . . ?
N1 Rh1 O7 Na1 -53.5(3) . . . . ?
C2 Rh1 O7 Na1 108.8(5) . . . . ?
C3 Rh1 O7 Na1 139.3(6) . . . . ?
C4 Rh1 O7 Na1 118(2) . . . . ?
C1 Rh1 O7 Na1 68.0(5) . . . . ?
C5 Rh1 O7 Na1 41.8(6) . . . . ?
C56 Rh1 O7 Na1 -135.6(5) . . . . ?
F1 Na1 O7 C56 159.2(8) . . . . ?
O5 Na1 O7 C56 43.5(6) . . . . ?
O3 Na1 O7 C56 -29.0(7) . . . . ?
O1 Na1 O7 C56 -96.2(6) . . . . ?
F1 Na1 O7 Rh1 -85.4(7) . . . . ?
O5 Na1 O7 Rh1 158.9(3) . . . . ?
O3 Na1 O7 Rh1 86.4(4) . . . . ?
O1 Na1 O7 Rh1 19.2(3) . . . . ?
N8 Rh1 N1 C11 131.2(6) . . . . ?
C2 Rh1 N1 C11 -62.8(13) . . . . ?
C3 Rh1 N1 C11 -124.9(8) . . . . ?
C4 Rh1 N1 C11 -109.2(7) . . . . ?
C1 Rh1 N1 C11 -44.0(7) . . . . ?
O7 Rh1 N1 C11 69.0(6) . . . . ?
C5 Rh1 N1 C11 -71.5(7) . . . . ?
C56 Rh1 N1 C11 100.0(6) . . . . ?
N8 Rh1 N1 C14 -70.1(6) . . . . ?
C2 Rh1 N1 C14 95.9(12) . . . . ?
C3 Rh1 N1 C14 33.9(9) . . . . ?
C4 Rh1 N1 C14 49.6(7) . . . . ?
C1 Rh1 N1 C14 114.8(7) . . . . ?
O7 Rh1 N1 C14 -132.2(6) . . . . ?
C5 Rh1 N1 C14 87.2(7) . . . . ?
C56 Rh1 N1 C14 -101.2(6) . . . . ?
N3 Rh2 N2 C11 -92.4(5) . . . . ?
C19 Rh2 N2 C11 156.7(5) . . . . ?
C20 Rh2 N2 C11 178.4(6) . . . . ?
C18 Rh2 N2 C11 116.9(5) . . . . ?
C17 Rh2 N2 C11 82.4(5) . . . . ?
C16 Rh2 N2 C11 80.9(11) . . . . ?
O1 Rh2 N2 C11 0.9(4) . . . . ?
N3 Rh2 N2 C12 84.3(9) . . . . ?
C19 Rh2 N2 C12 -26.6(10) . . . . ?
C20 Rh2 N2 C12 -4.8(13) . . . . ?
C18 Rh2 N2 C12 -66.4(10) . . . . ?
C17 Rh2 N2 C12 -100.8(10) . . . . ?
C16 Rh2 N2 C12 -102.4(13) . . . . ?
O1 Rh2 N2 C12 177.7(10) . . . . ?
C11 Rh2 N2 C12 176.7(12) . . . . ?
N2 Rh2 N3 C26 129.1(6) . . . . ?
C19 Rh2 N3 C26 -119.5(6) . . . . ?
C20 Rh2 N3 C26 -83.7(6) . . . . ?
C18 Rh2 N3 C26 -124.6(8) . . . . ?
C17 Rh2 N3 C26 -42.5(9) . . . . ?
C16 Rh2 N3 C26 -48.9(6) . . . . ?
O1 Rh2 N3 C26 67.3(6) . . . . ?
C11 Rh2 N3 C26 97.2(6) . . . . ?
N2 Rh2 N3 C29 -68.0(6) . . . . ?
C19 Rh2 N3 C29 43.5(7) . . . . ?
C20 Rh2 N3 C29 79.3(6) . . . . ?
C18 Rh2 N3 C29 38.3(10) . . . . ?
C17 Rh2 N3 C29 120.4(7) . . . . ?
C16 Rh2 N3 C29 114.0(6) . . . . ?
O1 Rh2 N3 C29 -129.8(6) . . . . ?
C11 Rh2 N3 C29 -99.8(6) . . . . ?
N5 Rh3 N4 C26 -94.0(5) . . . . ?
C33 Rh3 N4 C26 123.4(6) . . . . ?
C34 Rh3 N4 C26 162.2(6) . . . . ?
C32 Rh3 N4 C26 85.9(6) . . . . ?
C35 Rh3 N4 C26 176.8(10) . . . . ?
C31 Rh3 N4 C26 72.3(9) . . . . ?
O3 Rh3 N4 C26 0.4(4) . . . . ?
N5 Rh3 N4 C27 82.3(10) . . . . ?
C33 Rh3 N4 C27 -60.3(11) . . . . ?
C34 Rh3 N4 C27 -21.6(12) . . . . ?
C32 Rh3 N4 C27 -97.8(10) . . . . ?
C35 Rh3 N4 C27 -6.9(16) . . . . ?
C31 Rh3 N4 C27 -111.5(12) . . . . ?
O3 Rh3 N4 C27 176.6(11) . . . . ?
C26 Rh3 N4 C27 176.3(13) . . . . ?
N4 Rh3 N5 C41 127.6(7) . . . . ?
C33 Rh3 N5 C41 -130.6(8) . . . . ?
C34 Rh3 N5 C41 -114.8(7) . . . . ?
C32 Rh3 N5 C41 -52.1(12) . . . . ?
C35 Rh3 N5 C41 -77.9(7) . . . . ?
C31 Rh3 N5 C41 -46.4(8) . . . . ?
O3 Rh3 N5 C41 67.1(6) . . . . ?
C26 Rh3 N5 C41 96.9(6) . . . . ?
N4 Rh3 N5 C44 -71.0(7) . . . . ?
C33 Rh3 N5 C44 30.8(10) . . . . ?
C34 Rh3 N5 C44 46.6(8) . . . . ?
C32 Rh3 N5 C44 109.2(10) . . . . ?
C35 Rh3 N5 C44 83.5(7) . . . . ?
C31 Rh3 N5 C44 115.0(7) . . . . ?
O3 Rh3 N5 C44 -131.5(7) . . . . ?
C26 Rh3 N5 C44 -101.7(7) . . . . ?
C49 Rh4 N6 C41 159.2(5) . . . . ?
C48 Rh4 N6 C41 120.0(5) . . . . ?
N7 Rh4 N6 C41 -93.7(5) . . . . ?
C47 Rh4 N6 C41 83.3(5) . . . . ?
C50 Rh4 N6 C41 179.3(7) . . . . ?
C46 Rh4 N6 C41 72.1(10) . . . . ?
O5 Rh4 N6 C41 -0.4(4) . . . . ?
C49 Rh4 N6 C42 -26.3(10) . . . . ?
C48 Rh4 N6 C42 -65.6(10) . . . . ?
N7 Rh4 N6 C42 80.7(9) . . . . ?
C47 Rh4 N6 C42 -102.3(9) . . . . ?
C50 Rh4 N6 C42 -6.2(13) . . . . ?
C46 Rh4 N6 C42 -113.4(12) . . . . ?
O5 Rh4 N6 C42 174.0(10) . . . . ?
C41 Rh4 N6 C42 174.5(12) . . . . ?
N6 Rh4 N7 C56 128.4(6) . . . . ?
C49 Rh4 N7 C56 -116.2(7) . . . . ?
C48 Rh4 N7 C56 -125.5(8) . . . . ?
C47 Rh4 N7 C56 -46.1(10) . . . . ?
C50 Rh4 N7 C56 -78.8(7) . . . . ?
C46 Rh4 N7 C56 -46.4(7) . . . . ?
O5 Rh4 N7 C56 68.3(6) . . . . ?
C41 Rh4 N7 C56 98.3(6) . . . . ?
N6 Rh4 N7 C59 -71.5(7) . . . . ?
C49 Rh4 N7 C59 43.8(8) . . . . ?
C48 Rh4 N7 C59 34.5(11) . . . . ?
C47 Rh4 N7 C59 113.9(8) . . . . ?
C50 Rh4 N7 C59 81.2(7) . . . . ?
C46 Rh4 N7 C59 113.6(7) . . . . ?
O5 Rh4 N7 C59 -131.7(6) . . . . ?
C41 Rh4 N7 C59 -101.7(6) . . . . ?
N1 Rh1 N8 C56 -91.7(5) . . . . ?
C2 Rh1 N8 C56 94.5(6) . . . . ?
C3 Rh1 N8 C56 132.2(5) . . . . ?
C4 Rh1 N8 C56 168.8(5) . . . . ?
C1 Rh1 N8 C56 78.4(10) . . . . ?
O7 Rh1 N8 C56 2.3(4) . . . . ?
C5 Rh1 N8 C56 -177.2(8) . . . . ?
N1 Rh1 N8 C57 77.7(10) . . . . ?
C2 Rh1 N8 C57 -96.2(11) . . . . ?
C3 Rh1 N8 C57 -58.5(11) . . . . ?
C4 Rh1 N8 C57 -21.8(11) . . . . ?
C1 Rh1 N8 C57 -112.3(12) . . . . ?
O7 Rh1 N8 C57 171.7(11) . . . . ?
C5 Rh1 N8 C57 -7.9(16) . . . . ?
C56 Rh1 N8 C57 169.3(13) . . . . ?
N8 Rh1 C1 C5 142.0(9) . . . . ?
N1 Rh1 C1 C5 -49.3(9) . . . . ?
C2 Rh1 C1 C5 119.1(11) . . . . ?
C3 Rh1 C1 C5 80.5(8) . . . . ?
C4 Rh1 C1 C5 37.8(7) . . . . ?
O7 Rh1 C1 C5 -152.4(7) . . . . ?
C56 Rh1 C1 C5 -170.2(6) . . . . ?
N8 Rh1 C1 C2 22.9(13) . . . . ?
N1 Rh1 C1 C2 -168.4(6) . . . . ?
C3 Rh1 C1 C2 -38.6(6) . . . . ?
C4 Rh1 C1 C2 -81.2(7) . . . . ?
O7 Rh1 C1 C2 88.5(7) . . . . ?
C5 Rh1 C1 C2 -119.1(11) . . . . ?
C56 Rh1 C1 C2 70.7(9) . . . . ?
N8 Rh1 C1 C6 -100.6(17) . . . . ?
N1 Rh1 C1 C6 68.1(16) . . . . ?
C2 Rh1 C1 C6 -123.5(18) . . . . ?
C3 Rh1 C1 C6 -162.1(17) . . . . ?
C4 Rh1 C1 C6 155.2(17) . . . . ?
O7 Rh1 C1 C6 -35.0(16) . . . . ?
C5 Rh1 C1 C6 117.4(19) . . . . ?
C56 Rh1 C1 C6 -52.8(17) . . . . ?
C5 C1 C2 C3 2.2(12) . . . . ?
C6 C1 C2 C3 -177.0(13) . . . . ?
Rh1 C1 C2 C3 63.7(8) . . . . ?
C5 C1 C2 C7 178.0(11) . . . . ?
C6 C1 C2 C7 -1(2) . . . . ?
Rh1 C1 C2 C7 -120.5(12) . . . . ?
C5 C1 C2 Rh1 -61.6(8) . . . . ?
C6 C1 C2 Rh1 119.3(13) . . . . ?
N8 Rh1 C2 C3 75.8(8) . . . . ?
N1 Rh1 C2 C3 -88.5(14) . . . . ?
C4 Rh1 C2 C3 -36.4(8) . . . . ?
C1 Rh1 C2 C3 -114.9(10) . . . . ?
O7 Rh1 C2 C3 141.5(7) . . . . ?
C5 Rh1 C2 C3 -78.9(8) . . . . ?
C56 Rh1 C2 C3 110.4(7) . . . . ?
N8 Rh1 C2 C1 -169.3(6) . . . . ?
N1 Rh1 C2 C1 26.4(15) . . . . ?
C3 Rh1 C2 C1 114.9(10) . . . . ?
C4 Rh1 C2 C1 78.6(8) . . . . ?
O7 Rh1 C2 C1 -103.6(7) . . . . ?
C5 Rh1 C2 C1 36.0(7) . . . . ?
C56 Rh1 C2 C1 -134.7(6) . . . . ?
N8 Rh1 C2 C7 -45.4(16) . . . . ?
N1 Rh1 C2 C7 150.2(12) . . . . ?
C3 Rh1 C2 C7 -121.2(18) . . . . ?
C4 Rh1 C2 C7 -157.6(17) . . . . ?
C1 Rh1 C2 C7 123.8(18) . . . . ?
O7 Rh1 C2 C7 20.3(15) . . . . ?
C5 Rh1 C2 C7 159.9(17) . . . . ?
C56 Rh1 C2 C7 -10.8(16) . . . . ?
C1 C2 C3 C4 -2.6(13) . . . . ?
C7 C2 C3 C4 -178.6(11) . . . . ?
Rh1 C2 C3 C4 61.1(8) . . . . ?
C1 C2 C3 C8 -178.6(12) . . . . ?
C7 C2 C3 C8 5(2) . . . . ?
Rh1 C2 C3 C8 -114.9(13) . . . . ?
C1 C2 C3 Rh1 -63.7(7) . . . . ?
C7 C2 C3 Rh1 120.4(12) . . . . ?
N8 Rh1 C3 C2 -117.4(8) . . . . ?
N1 Rh1 C3 C2 145.4(7) . . . . ?
C4 Rh1 C3 C2 119.8(13) . . . . ?
C1 Rh1 C3 C2 40.0(8) . . . . ?
O7 Rh1 C3 C2 -53.2(10) . . . . ?
C5 Rh1 C3 C2 82.1(9) . . . . ?
C56 Rh1 C3 C2 -90.7(9) . . . . ?
N8 Rh1 C3 C4 122.8(9) . . . . ?
N1 Rh1 C3 C4 25.6(12) . . . . ?
C2 Rh1 C3 C4 -119.8(13) . . . . ?
C1 Rh1 C3 C4 -79.8(10) . . . . ?
O7 Rh1 C3 C4 -172.9(7) . . . . ?
C5 Rh1 C3 C4 -37.7(9) . . . . ?
C56 Rh1 C3 C4 149.6(8) . . . . ?
N8 Rh1 C3 C8 7.0(10) . . . . ?
N1 Rh1 C3 C8 -90.2(10) . . . . ?
C2 Rh1 C3 C8 124.4(13) . . . . ?
C4 Rh1 C3 C8 -115.8(14) . . . . ?
C1 Rh1 C3 C8 164.4(11) . . . . ?
O7 Rh1 C3 C8 71.3(11) . . . . ?
C5 Rh1 C3 C8 -153.5(11) . . . . ?
C56 Rh1 C3 C8 33.8(11) . . . . ?
C2 C3 C4 C5 2.2(13) . . . . ?
C8 C3 C4 C5 178.5(10) . . . . ?
Rh1 C3 C4 C5 62.5(8) . . . . ?
C2 C3 C4 C9 -179.0(11) . . . . ?
C8 C3 C4 C9 -2.6(18) . . . . ?
Rh1 C3 C4 C9 -118.7(13) . . . . ?
C2 C3 C4 Rh1 -60.3(8) . . . . ?
C8 C3 C4 Rh1 116.1(11) . . . . ?
N8 Rh1 C4 C3 -71.1(10) . . . . ?
N1 Rh1 C4 C3 -162.2(9) . . . . ?
C2 Rh1 C4 C3 36.4(9) . . . . ?
C1 Rh1 C4 C3 80.4(10) . . . . ?
O7 Rh1 C4 C3 27(3) . . . . ?
C5 Rh1 C4 C3 117.6(12) . . . . ?
C56 Rh1 C4 C3 -59.5(13) . . . . ?
N8 Rh1 C4 C5 171.3(6) . . . . ?
N1 Rh1 C4 C5 80.2(7) . . . . ?
C2 Rh1 C4 C5 -81.3(8) . . . . ?
C3 Rh1 C4 C5 -117.6(12) . . . . ?
C1 Rh1 C4 C5 -37.2(7) . . . . ?
O7 Rh1 C4 C5 -91(2) . . . . ?
C56 Rh1 C4 C5 -177.1(6) . . . . ?
N8 Rh1 C4 C9 49.9(12) . . . . ?
N1 Rh1 C4 C9 -41.2(12) . . . . ?
C2 Rh1 C4 C9 157.4(13) . . . . ?
C3 Rh1 C4 C9 121.0(16) . . . . ?
C1 Rh1 C4 C9 -158.5(13) . . . . ?
O7 Rh1 C4 C9 147.5(16) . . . . ?
C5 Rh1 C4 C9 -121.4(14) . . . . ?
C56 Rh1 C4 C9 61.5(13) . . . . ?
C2 C1 C5 C4 -0.9(12) . . . . ?
C6 C1 C5 C4 178.4(11) . . . . ?
Rh1 C1 C5 C4 -60.4(8) . . . . ?
C2 C1 C5 C10 179.2(11) . . . . ?
C6 C1 C5 C10 -2(2) . . . . ?
Rh1 C1 C5 C10 119.7(12) . . . . ?
C2 C1 C5 Rh1 59.5(8) . . . . ?
C6 C1 C5 Rh1 -121.3(12) . . . . ?
C3 C4 C5 C1 -0.8(13) . . . . ?
C9 C4 C5 C1 -179.6(11) . . . . ?
Rh1 C4 C5 C1 60.7(8) . . . . ?
C3 C4 C5 C10 179.2(10) . . . . ?
C9 C4 C5 C10 0.4(18) . . . . ?
Rh1 C4 C5 C10 -119.4(11) . . . . ?
C3 C4 C5 Rh1 -61.4(8) . . . . ?
C9 C4 C5 Rh1 119.7(12) . . . . ?
N8 Rh1 C5 C1 -137.3(10) . . . . ?
N1 Rh1 C5 C1 138.4(8) . . . . ?
C2 Rh1 C5 C1 -37.8(8) . . . . ?
C3 Rh1 C5 C1 -80.1(8) . . . . ?
C4 Rh1 C5 C1 -117.6(10) . . . . ?
O7 Rh1 C5 C1 43.3(10) . . . . ?
C56 Rh1 C5 C1 53(2) . . . . ?
N8 Rh1 C5 C4 -19.7(13) . . . . ?
N1 Rh1 C5 C4 -104.0(7) . . . . ?
C2 Rh1 C5 C4 79.8(8) . . . . ?
C3 Rh1 C5 C4 37.5(7) . . . . ?
C1 Rh1 C5 C4 117.6(10) . . . . ?
O7 Rh1 C5 C4 160.9(6) . . . . ?
C56 Rh1 C5 C4 170(2) . . . . ?
N8 Rh1 C5 C10 96.9(16) . . . . ?
N1 Rh1 C5 C10 12.6(15) . . . . ?
C2 Rh1 C5 C10 -163.6(17) . . . . ?
C3 Rh1 C5 C10 154.1(17) . . . . ?
C4 Rh1 C5 C10 116.6(18) . . . . ?
C1 Rh1 C5 C10 -125.8(19) . . . . ?
O7 Rh1 C5 C10 -82.5(16) . . . . ?
C56 Rh1 C5 C10 -73(3) . . . . ?
Rh2 O1 C11 N1 -179.2(7) . . . . ?
Na1 O1 C11 N1 -48.5(10) . . . . ?
Rh2 O1 C11 N2 1.5(6) . . . . ?
Na1 O1 C11 N2 132.2(5) . . . . ?
Na1 O1 C11 Rh2 130.7(5) . . . . ?
C14 N1 C11 O1 178.4(7) . . . . ?
Rh1 N1 C11 O1 -22.5(10) . . . . ?
C14 N1 C11 N2 -2.3(11) . . . . ?
Rh1 N1 C11 N2 156.8(6) . . . . ?
C14 N1 C11 Rh2 15(14) . . . . ?
Rh1 N1 C11 Rh2 174(13) . . . . ?
C12 N2 C11 O1 -179.2(7) . . . . ?
Rh2 N2 C11 O1 -1.5(6) . . . . ?
C12 N2 C11 N1 1.5(12) . . . . ?
Rh2 N2 C11 N1 179.1(6) . . . . ?
C12 N2 C11 Rh2 -177.7(9) . . . . ?
N3 Rh2 C11 O1 -96.1(4) . . . . ?
N2 Rh2 C11 O1 178.3(7) . . . . ?
C19 Rh2 C11 O1 143.6(5) . . . . ?
C20 Rh2 C11 O1 132(17) . . . . ?
C18 Rh2 C11 O1 105.3(5) . . . . ?
C17 Rh2 C11 O1 62.7(5) . . . . ?
C16 Rh2 C11 O1 25.8(7) . . . . ?
N3 Rh2 C11 N1 67(14) . . . . ?
N2 Rh2 C11 N1 -18(13) . . . . ?
C19 Rh2 C11 N1 -53(14) . . . . ?
C20 Rh2 C11 N1 -65(23) . . . . ?
C18 Rh2 C11 N1 -91(14) . . . . ?
C17 Rh2 C11 N1 -134(13) . . . . ?
C16 Rh2 C11 N1 -171(13) . . . . ?
O1 Rh2 C11 N1 163(14) . . . . ?
N3 Rh2 C11 N2 85.5(5) . . . . ?
C19 Rh2 C11 N2 -34.8(7) . . . . ?
C20 Rh2 C11 N2 -46(17) . . . . ?
C18 Rh2 C11 N2 -73.1(5) . . . . ?
C17 Rh2 C11 N2 -115.6(5) . . . . ?
C16 Rh2 C11 N2 -152.5(6) . . . . ?
O1 Rh2 C11 N2 -178.3(7) . . . . ?
C11 N2 C12 O2 179.1(8) . . . . ?
Rh2 N2 C12 O2 3.0(15) . . . . ?
C11 N2 C12 C13 0.3(12) . . . . ?
Rh2 N2 C12 C13 -175.8(7) . . . . ?
O2 C12 C13 C14 -179.9(9) . . . . ?
N2 C12 C13 C14 -1.1(13) . . . . ?
O2 C12 C13 C15 2.7(15) . . . . ?
N2 C12 C13 C15 -178.6(9) . . . . ?
C12 C13 C14 N1 0.2(15) . . . . ?
C15 C13 C14 N1 177.6(9) . . . . ?
C11 N1 C14 C13 1.5(13) . . . . ?
Rh1 N1 C14 C13 -159.1(8) . . . . ?
N3 Rh2 C16 C20 -67.2(7) . . . . ?
N2 Rh2 C16 C20 120.0(11) . . . . ?
C19 Rh2 C16 C20 37.2(6) . . . . ?
C18 Rh2 C16 C20 80.5(7) . . . . ?
C17 Rh2 C16 C20 118.0(8) . . . . ?
O1 Rh2 C16 C20 -168.0(6) . . . . ?
C11 Rh2 C16 C20 178.2(5) . . . . ?
N3 Rh2 C16 C17 174.8(5) . . . . ?
N2 Rh2 C16 C17 2.0(13) . . . . ?
C19 Rh2 C16 C17 -80.8(6) . . . . ?
C20 Rh2 C16 C17 -118.0(8) . . . . ?
C18 Rh2 C16 C17 -37.5(5) . . . . ?
O1 Rh2 C16 C17 74.0(5) . . . . ?
C11 Rh2 C16 C17 60.2(7) . . . . ?
N3 Rh2 C16 C21 55.1(11) . . . . ?
N2 Rh2 C16 C21 -117.7(13) . . . . ?
C19 Rh2 C16 C21 159.5(12) . . . . ?
C20 Rh2 C16 C21 122.3(14) . . . . ?
C18 Rh2 C16 C21 -157.2(12) . . . . ?
C17 Rh2 C16 C21 -119.7(12) . . . . ?
O1 Rh2 C16 C21 -45.7(12) . . . . ?
C11 Rh2 C16 C21 -59.5(13) . . . . ?
C20 C16 C17 C18 0.8(10) . . . . ?
C21 C16 C17 C18 -178.2(9) . . . . ?
Rh2 C16 C17 C18 60.8(6) . . . . ?
C20 C16 C17 C22 -179.7(8) . . . . ?
C21 C16 C17 C22 1.2(15) . . . . ?
Rh2 C16 C17 C22 -119.7(8) . . . . ?
C20 C16 C17 Rh2 -60.0(6) . . . . ?
C21 C16 C17 Rh2 121.0(10) . . . . ?
N3 Rh2 C17 C18 -127.5(7) . . . . ?
N2 Rh2 C17 C18 62.7(7) . . . . ?
C19 Rh2 C17 C18 -37.5(6) . . . . ?
C20 Rh2 C17 C18 -80.8(6) . . . . ?
C16 Rh2 C17 C18 -118.0(8) . . . . ?
O1 Rh2 C17 C18 124.8(6) . . . . ?
C11 Rh2 C17 C18 98.0(6) . . . . ?
N3 Rh2 C17 C16 -9.6(9) . . . . ?
N2 Rh2 C17 C16 -179.3(5) . . . . ?
C19 Rh2 C17 C16 80.5(6) . . . . ?
C20 Rh2 C17 C16 37.2(5) . . . . ?
C18 Rh2 C17 C16 118.0(8) . . . . ?
O1 Rh2 C17 C16 -117.2(5) . . . . ?
C11 Rh2 C17 C16 -144.0(5) . . . . ?
N3 Rh2 C17 C22 110.7(10) . . . . ?
N2 Rh2 C17 C22 -59.1(10) . . . . ?
C19 Rh2 C17 C22 -159.3(11) . . . . ?
C20 Rh2 C17 C22 157.4(11) . . . . ?
C18 Rh2 C17 C22 -121.8(12) . . . . ?
C16 Rh2 C17 C22 120.2(11) . . . . ?
O1 Rh2 C17 C22 3.0(10) . . . . ?
C11 Rh2 C17 C22 -23.8(10) . . . . ?
C16 C17 C18 C19 -1.5(10) . . . . ?
C22 C17 C18 C19 179.1(8) . . . . ?
Rh2 C17 C18 C19 60.1(6) . . . . ?
C16 C17 C18 C23 176.2(9) . . . . ?
C22 C17 C18 C23 -3.3(15) . . . . ?
Rh2 C17 C18 C23 -122.3(10) . . . . ?
C16 C17 C18 Rh2 -61.5(6) . . . . ?
C22 C17 C18 Rh2 119.0(9) . . . . ?
N3 Rh2 C18 C17 126.5(7) . . . . ?
N2 Rh2 C18 C17 -131.6(6) . . . . ?
C19 Rh2 C18 C17 118.8(9) . . . . ?
C20 Rh2 C18 C17 80.1(7) . . . . ?
C16 Rh2 C18 C17 37.7(6) . . . . ?
O1 Rh2 C18 C17 -67.1(6) . . . . ?
C11 Rh2 C18 C17 -100.5(6) . . . . ?
N3 Rh2 C18 C19 7.6(11) . . . . ?
N2 Rh2 C18 C19 109.6(6) . . . . ?
C20 Rh2 C18 C19 -38.8(6) . . . . ?
C17 Rh2 C18 C19 -118.8(9) . . . . ?
C16 Rh2 C18 C19 -81.1(7) . . . . ?
O1 Rh2 C18 C19 174.0(5) . . . . ?
C11 Rh2 C18 C19 140.6(6) . . . . ?
N3 Rh2 C18 C23 -112.8(10) . . . . ?
N2 Rh2 C18 C23 -10.8(10) . . . . ?
C19 Rh2 C18 C23 -120.4(13) . . . . ?
C20 Rh2 C18 C23 -159.2(11) . . . . ?
C17 Rh2 C18 C23 120.7(12) . . . . ?
C16 Rh2 C18 C23 158.5(11) . . . . ?
O1 Rh2 C18 C23 53.6(11) . . . . ?
C11 Rh2 C18 C23 20.2(11) . . . . ?
C17 C18 C19 C20 1.5(10) . . . . ?
C23 C18 C19 C20 -176.1(9) . . . . ?
Rh2 C18 C19 C20 62.6(6) . . . . ?
C17 C18 C19 C24 177.8(8) . . . . ?
C23 C18 C19 C24 0.2(15) . . . . ?
Rh2 C18 C19 C24 -121.1(9) . . . . ?
C17 C18 C19 Rh2 -61.1(6) . . . . ?
C23 C18 C19 Rh2 121.3(10) . . . . ?
N3 Rh2 C19 C20 68.0(6) . . . . ?
N2 Rh2 C19 C20 161.5(6) . . . . ?
C18 Rh2 C19 C20 -116.1(9) . . . . ?
C17 Rh2 C19 C20 -79.2(7) . . . . ?
C16 Rh2 C19 C20 -36.3(6) . . . . ?
O1 Rh2 C19 C20 -129.7(8) . . . . ?
C11 Rh2 C19 C20 -179.6(5) . . . . ?
N3 Rh2 C19 C18 -175.9(6) . . . . ?
N2 Rh2 C19 C18 -82.4(6) . . . . ?
C20 Rh2 C19 C18 116.1(9) . . . . ?
C17 Rh2 C19 C18 36.9(6) . . . . ?
C16 Rh2 C19 C18 79.8(7) . . . . ?
O1 Rh2 C19 C18 -13.6(12) . . . . ?
C11 Rh2 C19 C18 -63.6(8) . . . . ?
N3 Rh2 C19 C24 -55.0(11) . . . . ?
N2 Rh2 C19 C24 38.5(11) . . . . ?
C20 Rh2 C19 C24 -123.0(13) . . . . ?
C18 Rh2 C19 C24 121.0(13) . . . . ?
C17 Rh2 C19 C24 157.9(12) . . . . ?
C16 Rh2 C19 C24 -159.2(12) . . . . ?
O1 Rh2 C19 C24 107.4(11) . . . . ?
C11 Rh2 C19 C24 57.4(12) . . . . ?
C17 C16 C20 C19 0.1(10) . . . . ?
C21 C16 C20 C19 179.1(9) . . . . ?
Rh2 C16 C20 C19 -60.2(6) . . . . ?
C17 C16 C20 C25 179.8(9) . . . . ?
C21 C16 C20 C25 -1.2(16) . . . . ?
Rh2 C16 C20 C25 119.5(10) . . . . ?
C17 C16 C20 Rh2 60.3(6) . . . . ?
C21 C16 C20 Rh2 -120.7(10) . . . . ?
C18 C19 C20 C16 -1.0(10) . . . . ?
C24 C19 C20 C16 -177.2(8) . . . . ?
Rh2 C19 C20 C16 61.7(6) . . . . ?
C18 C19 C20 C25 179.3(9) . . . . ?
C24 C19 C20 C25 3.1(15) . . . . ?
Rh2 C19 C20 C25 -118.0(10) . . . . ?
C18 C19 C20 Rh2 -62.7(6) . . . . ?
C24 C19 C20 Rh2 121.1(9) . . . . ?
N3 Rh2 C20 C16 120.5(6) . . . . ?
N2 Rh2 C20 C16 -152.7(6) . . . . ?
C19 Rh2 C20 C16 -119.5(9) . . . . ?
C18 Rh2 C20 C16 -80.7(7) . . . . ?
C17 Rh2 C20 C16 -37.8(6) . . . . ?
O1 Rh2 C20 C16 22.8(11) . . . . ?
C11 Rh2 C20 C16 -108(17) . . . . ?
N3 Rh2 C20 C19 -120.0(6) . . . . ?
N2 Rh2 C20 C19 -33.2(10) . . . . ?
C18 Rh2 C20 C19 38.8(6) . . . . ?
C17 Rh2 C20 C19 81.7(6) . . . . ?
C16 Rh2 C20 C19 119.5(9) . . . . ?
O1 Rh2 C20 C19 142.3(6) . . . . ?
C11 Rh2 C20 C19 12(17) . . . . ?
N3 Rh2 C20 C25 -0.3(10) . . . . ?
N2 Rh2 C20 C25 86.5(12) . . . . ?
C19 Rh2 C20 C25 119.7(12) . . . . ?
C18 Rh2 C20 C25 158.5(11) . . . . ?
C17 Rh2 C20 C25 -158.7(11) . . . . ?
C16 Rh2 C20 C25 -120.8(13) . . . . ?
O1 Rh2 C20 C25 -98.0(11) . . . . ?
C11 Rh2 C20 C25 132(17) . . . . ?
Rh3 O3 C26 N3 -178.9(6) . . . . ?
Na1 O3 C26 N3 -51.9(10) . . . . ?
Rh3 O3 C26 N4 0.5(6) . . . . ?
Na1 O3 C26 N4 127.5(6) . . . . ?
Na1 O3 C26 Rh3 127.0(6) . . . . ?
C29 N3 C26 O3 176.2(7) . . . . ?
Rh2 N3 C26 O3 -20.3(9) . . . . ?
C29 N3 C26 N4 -3.1(11) . . . . ?
Rh2 N3 C26 N4 160.4(6) . . . . ?
C29 N3 C26 Rh3 11(8) . . . . ?
Rh2 N3 C26 Rh3 174(7) . . . . ?
C27 N4 C26 O3 -177.9(7) . . . . ?
Rh3 N4 C26 O3 -0.6(6) . . . . ?
C27 N4 C26 N3 1.5(12) . . . . ?
Rh3 N4 C26 N3 178.8(6) . . . . ?
C27 N4 C26 Rh3 -177.3(9) . . . . ?
N4 Rh3 C26 O3 179.4(7) . . . . ?
N5 Rh3 C26 O3 -96.6(4) . . . . ?
C33 Rh3 C26 O3 113.4(5) . . . . ?
C34 Rh3 C26 O3 150.1(8) . . . . ?
C32 Rh3 C26 O3 69.5(5) . . . . ?
C35 Rh3 C26 O3 14(4) . . . . ?
C31 Rh3 C26 O3 32.4(7) . . . . ?
N4 Rh3 C26 N3 -15(8) . . . . ?
N5 Rh3 C26 N3 69(8) . . . . ?
C33 Rh3 C26 N3 -81(8) . . . . ?
C34 Rh3 C26 N3 -44(8) . . . . ?
C32 Rh3 C26 N3 -125(8) . . . . ?
C35 Rh3 C26 N3 180(100) . . . . ?
C31 Rh3 C26 N3 -162(8) . . . . ?
O3 Rh3 C26 N3 166(8) . . . . ?
N5 Rh3 C26 N4 84.0(5) . . . . ?
C33 Rh3 C26 N4 -66.0(6) . . . . ?
C34 Rh3 C26 N4 -29.3(10) . . . . ?
C32 Rh3 C26 N4 -109.9(6) . . . . ?
C35 Rh3 C26 N4 -166(4) . . . . ?
C31 Rh3 C26 N4 -146.9(6) . . . . ?
O3 Rh3 C26 N4 -179.4(7) . . . . ?
C26 N4 C27 O4 -177.5(9) . . . . ?
Rh3 N4 C27 O4 6.8(16) . . . . ?
C26 N4 C27 C28 1.9(13) . . . . ?
Rh3 N4 C27 C28 -173.7(7) . . . . ?
O4 C27 C28 C29 175.9(10) . . . . ?
N4 C27 C28 C29 -3.5(14) . . . . ?
O4 C27 C28 C30 -3.4(16) . . . . ?
N4 C27 C28 C30 177.2(10) . . . . ?
C27 C28 C29 N3 1.9(13) . . . . ?
C30 C28 C29 N3 -178.7(9) . . . . ?
C26 N3 C29 C28 1.3(11) . . . . ?
Rh2 N3 C29 C28 -162.9(7) . . . . ?
N4 Rh3 C31 C32 19.5(11) . . . . ?
N5 Rh3 C31 C32 -176.0(6) . . . . ?
C33 Rh3 C31 C32 -37.8(7) . . . . ?
C34 Rh3 C31 C32 -82.1(8) . . . . ?
C35 Rh3 C31 C32 -117.9(10) . . . . ?
O3 Rh3 C31 C32 81.6(6) . . . . ?
C26 Rh3 C31 C32 65.0(8) . . . . ?
N4 Rh3 C31 C35 137.4(9) . . . . ?
N5 Rh3 C31 C35 -58.1(8) . . . . ?
C33 Rh3 C31 C35 80.1(8) . . . . ?
C34 Rh3 C31 C35 35.8(8) . . . . ?
C32 Rh3 C31 C35 117.9(10) . . . . ?
O3 Rh3 C31 C35 -160.5(7) . . . . ?
C26 Rh3 C31 C35 -177.1(7) . . . . ?
N4 Rh3 C31 C36 -102.0(14) . . . . ?
N5 Rh3 C31 C36 62.5(13) . . . . ?
C33 Rh3 C31 C36 -159.3(14) . . . . ?
C34 Rh3 C31 C36 156.3(15) . . . . ?
C32 Rh3 C31 C36 -121.6(15) . . . . ?
C35 Rh3 C31 C36 120.5(16) . . . . ?
O3 Rh3 C31 C36 -40.0(13) . . . . ?
C26 Rh3 C31 C36 -56.6(15) . . . . ?
C35 C31 C32 C33 -1.2(10) . . . . ?
C36 C31 C32 C33 176.5(9) . . . . ?
Rh3 C31 C32 C33 59.3(6) . . . . ?
C35 C31 C32 C37 175.0(9) . . . . ?
C36 C31 C32 C37 -7.2(15) . . . . ?
Rh3 C31 C32 C37 -124.5(10) . . . . ?
C35 C31 C32 Rh3 -60.5(6) . . . . ?
C36 C31 C32 Rh3 117.2(9) . . . . ?
N4 Rh3 C32 C31 -171.3(5) . . . . ?
N5 Rh3 C32 C31 8.4(12) . . . . ?
C33 Rh3 C32 C31 119.4(11) . . . . ?
C34 Rh3 C32 C31 79.5(7) . . . . ?
C35 Rh3 C32 C31 37.5(6) . . . . ?
O3 Rh3 C32 C31 -108.9(6) . . . . ?
C26 Rh3 C32 C31 -137.4(6) . . . . ?
N4 Rh3 C32 C33 69.3(9) . . . . ?
N5 Rh3 C32 C33 -111.0(11) . . . . ?
C34 Rh3 C32 C33 -39.9(8) . . . . ?
C35 Rh3 C32 C33 -81.9(8) . . . . ?
C31 Rh3 C32 C33 -119.4(11) . . . . ?
O3 Rh3 C32 C33 131.7(8) . . . . ?
C26 Rh3 C32 C33 103.2(8) . . . . ?
N4 Rh3 C32 C37 -51.7(14) . . . . ?
N5 Rh3 C32 C37 128.0(13) . . . . ?
C33 Rh3 C32 C37 -121.0(17) . . . . ?
C34 Rh3 C32 C37 -160.9(15) . . . . ?
C35 Rh3 C32 C37 157.1(15) . . . . ?
C31 Rh3 C32 C37 119.6(15) . . . . ?
O3 Rh3 C32 C37 10.7(14) . . . . ?
C26 Rh3 C32 C37 -17.8(14) . . . . ?
C31 C32 C33 C34 0.8(11) . . . . ?
C37 C32 C33 C34 -175.2(10) . . . . ?
Rh3 C32 C33 C34 62.6(6) . . . . ?
C31 C32 C33 C38 177.2(11) . . . . ?
C37 C32 C33 C38 1.1(18) . . . . ?
Rh3 C32 C33 C38 -121.0(13) . . . . ?
C31 C32 C33 Rh3 -61.8(7) . . . . ?
C37 C32 C33 Rh3 122.2(10) . . . . ?
N4 Rh3 C33 C32 -124.6(7) . . . . ?
N5 Rh3 C33 C32 139.1(7) . . . . ?
C34 Rh3 C33 C32 114.8(11) . . . . ?
C35 Rh3 C33 C32 77.8(8) . . . . ?
C31 Rh3 C33 C32 35.8(7) . . . . ?
O3 Rh3 C33 C32 -62.4(9) . . . . ?
C26 Rh3 C33 C32 -96.2(8) . . . . ?
N4 Rh3 C33 C34 120.6(7) . . . . ?
N5 Rh3 C33 C34 24.3(11) . . . . ?
C32 Rh3 C33 C34 -114.8(11) . . . . ?
C35 Rh3 C33 C34 -37.0(7) . . . . ?
C31 Rh3 C33 C34 -79.1(8) . . . . ?
O3 Rh3 C33 C34 -177.3(6) . . . . ?
C26 Rh3 C33 C34 149.0(6) . . . . ?
N4 Rh3 C33 C38 1.7(17) . . . . ?
N5 Rh3 C33 C38 -94.6(18) . . . . ?
C34 Rh3 C33 C38 -118.9(19) . . . . ?
C32 Rh3 C33 C38 126(2) . . . . ?
C35 Rh3 C33 C38 -155.9(18) . . . . ?
C31 Rh3 C33 C38 162.1(18) . . . . ?
O3 Rh3 C33 C38 63.9(18) . . . . ?
C26 Rh3 C33 C38 30.1(18) . . . . ?
C32 C33 C34 C35 -0.1(11) . . . . ?
C38 C33 C34 C35 -176.7(10) . . . . ?
Rh3 C33 C34 C35 63.3(7) . . . . ?
C32 C33 C34 C39 177.9(10) . . . . ?
C38 C33 C34 C39 1.3(17) . . . . ?
Rh3 C33 C34 C39 -118.7(11) . . . . ?
C32 C33 C34 Rh3 -63.4(6) . . . . ?
C38 C33 C34 Rh3 120.0(11) . . . . ?
N4 Rh3 C34 C35 169.8(7) . . . . ?
N5 Rh3 C34 C35 77.8(9) . . . . ?
C33 Rh3 C34 C35 -117.2(11) . . . . ?
C32 Rh3 C34 C35 -77.6(9) . . . . ?
C31 Rh3 C34 C35 -36.0(8) . . . . ?
O3 Rh3 C34 C35 -108.9(15) . . . . ?
C26 Rh3 C34 C35 -173.7(7) . . . . ?
N4 Rh3 C34 C33 -73.1(8) . . . . ?
N5 Rh3 C34 C33 -165.0(7) . . . . ?
C32 Rh3 C34 C33 39.6(7) . . . . ?
C35 Rh3 C34 C33 117.2(11) . . . . ?
C31 Rh3 C34 C33 81.2(8) . . . . ?
O3 Rh3 C34 C33 8.3(18) . . . . ?
C26 Rh3 C34 C33 -56.6(11) . . . . ?
N4 Rh3 C34 C39 46.3(19) . . . . ?
N5 Rh3 C34 C39 -45.7(18) . . . . ?
C33 Rh3 C34 C39 119(2) . . . . ?
C32 Rh3 C34 C39 159.0(19) . . . . ?
C35 Rh3 C34 C39 -123(2) . . . . ?
C31 Rh3 C34 C39 -159.4(19) . . . . ?
O3 Rh3 C34 C39 127.6(16) . . . . ?
C26 Rh3 C34 C39 63(2) . . . . ?
C33 C34 C35 C31 -0.6(11) . . . . ?
C39 C34 C35 C31 -178.6(10) . . . . ?
Rh3 C34 C35 C31 60.6(7) . . . . ?
C33 C34 C35 C40 -177.8(10) . . . . ?
C39 C34 C35 C40 4.3(18) . . . . ?
Rh3 C34 C35 C40 -116.5(11) . . . . ?
C33 C34 C35 Rh3 -61.2(7) . . . . ?
C39 C34 C35 Rh3 120.8(12) . . . . ?
C32 C31 C35 C34 1.2(11) . . . . ?
C36 C31 C35 C34 -176.6(9) . . . . ?
Rh3 C31 C35 C34 -59.1(7) . . . . ?
C32 C31 C35 C40 178.3(10) . . . . ?
C36 C31 C35 C40 0.5(16) . . . . ?
Rh3 C31 C35 C40 118.0(11) . . . . ?
C32 C31 C35 Rh3 60.3(6) . . . . ?
C36 C31 C35 Rh3 -117.5(9) . . . . ?
N4 Rh3 C35 C34 -21.4(16) . . . . ?
N5 Rh3 C35 C34 -108.5(9) . . . . ?
C33 Rh3 C35 C34 39.2(9) . . . . ?
C32 Rh3 C35 C34 83.5(9) . . . . ?
C31 Rh3 C35 C34 120.5(13) . . . . ?
O3 Rh3 C35 C34 153.2(8) . . . . ?
C26 Rh3 C35 C34 141(4) . . . . ?
N4 Rh3 C35 C31 -141.9(9) . . . . ?
N5 Rh3 C35 C31 131.0(8) . . . . ?
C33 Rh3 C35 C31 -81.4(8) . . . . ?
C34 Rh3 C35 C31 -120.5(13) . . . . ?
C32 Rh3 C35 C31 -37.1(7) . . . . ?
O3 Rh3 C35 C31 32.7(12) . . . . ?
C26 Rh3 C35 C31 21(5) . . . . ?
N4 Rh3 C35 C40 97.6(14) . . . . ?
N5 Rh3 C35 C40 10.5(12) . . . . ?
C33 Rh3 C35 C40 158.2(14) . . . . ?
C34 Rh3 C35 C40 119.0(16) . . . . ?
C32 Rh3 C35 C40 -157.5(13) . . . . ?
C31 Rh3 C35 C40 -120.5(15) . . . . ?
O3 Rh3 C35 C40 -87.8(13) . . . . ?
C26 Rh3 C35 C40 -100(4) . . . . ?
C44 N5 C41 O5 176.3(7) . . . . ?
Rh3 N5 C41 O5 -21.8(11) . . . . ?
C44 N5 C41 N6 -1.7(12) . . . . ?
Rh3 N5 C41 N6 160.2(6) . . . . ?
C44 N5 C41 Rh4 8(7) . . . . ?
Rh3 N5 C41 Rh4 170(6) . . . . ?
Rh4 O5 C41 N5 -178.8(7) . . . . ?
Na1 O5 C41 N5 -48.9(11) . . . . ?
Rh4 O5 C41 N6 -0.6(6) . . . . ?
Na1 O5 C41 N6 129.3(6) . . . . ?
Na1 O5 C41 Rh4 129.9(6) . . . . ?
C42 N6 C41 N5 3.1(12) . . . . ?
Rh4 N6 C41 N5 178.9(7) . . . . ?
C42 N6 C41 O5 -175.1(7) . . . . ?
Rh4 N6 C41 O5 0.7(6) . . . . ?
C42 N6 C41 Rh4 -175.8(9) . . . . ?
N6 Rh4 C41 N5 -10(7) . . . . ?
C49 Rh4 C41 N5 -42(7) . . . . ?
C48 Rh4 C41 N5 -80(7) . . . . ?
N7 Rh4 C41 N5 74(7) . . . . ?
C47 Rh4 C41 N5 -123(7) . . . . ?
C50 Rh4 C41 N5 176(8) . . . . ?
C46 Rh4 C41 N5 -161(7) . . . . ?
O5 Rh4 C41 N5 169(7) . . . . ?
N6 Rh4 C41 O5 -179.3(7) . . . . ?
C49 Rh4 C41 O5 148.7(6) . . . . ?
C48 Rh4 C41 O5 110.9(5) . . . . ?
N7 Rh4 C41 O5 -94.7(4) . . . . ?
C47 Rh4 C41 O5 67.8(5) . . . . ?
C50 Rh4 C41 O5 7(7) . . . . ?
C46 Rh4 C41 O5 30.4(6) . . . . ?
C49 Rh4 C41 N6 -32.0(8) . . . . ?
C48 Rh4 C41 N6 -69.9(6) . . . . ?
N7 Rh4 C41 N6 84.5(5) . . . . ?
C47 Rh4 C41 N6 -113.0(5) . . . . ?
C50 Rh4 C41 N6 -174(7) . . . . ?
C46 Rh4 C41 N6 -150.4(5) . . . . ?
O5 Rh4 C41 N6 179.3(7) . . . . ?
C41 N6 C42 O6 177.7(9) . . . . ?
Rh4 N6 C42 O6 4.2(16) . . . . ?
C41 N6 C42 C43 -3.5(13) . . . . ?
Rh4 N6 C42 C43 -177.1(7) . . . . ?
O6 C42 C43 C44 -178.7(10) . . . . ?
N6 C42 C43 C44 2.6(14) . . . . ?
O6 C42 C43 C45 -3.2(17) . . . . ?
N6 C42 C43 C45 178.0(10) . . . . ?
C41 N5 C44 C43 0.8(13) . . . . ?
Rh3 N5 C44 C43 -161.5(8) . . . . ?
C42 C43 C44 N5 -1.4(15) . . . . ?
C45 C43 C44 N5 -176.5(11) . . . . ?
N6 Rh4 C46 C50 134.3(9) . . . . ?
C49 Rh4 C46 C50 37.8(7) . . . . ?
C48 Rh4 C46 C50 81.1(7) . . . . ?
N7 Rh4 C46 C50 -61.2(7) . . . . ?
C47 Rh4 C46 C50 119.0(9) . . . . ?
O5 Rh4 C46 C50 -162.2(6) . . . . ?
C41 Rh4 C46 C50 -178.1(6) . . . . ?
N6 Rh4 C46 C47 15.2(11) . . . . ?
C49 Rh4 C46 C47 -81.2(6) . . . . ?
C48 Rh4 C46 C47 -37.9(6) . . . . ?
N7 Rh4 C46 C47 179.8(5) . . . . ?
C50 Rh4 C46 C47 -119.0(9) . . . . ?
O5 Rh4 C46 C47 78.8(5) . . . . ?
C41 Rh4 C46 C47 62.9(7) . . . . ?
N6 Rh4 C46 C51 -102.8(12) . . . . ?
C49 Rh4 C46 C51 160.8(10) . . . . ?
C48 Rh4 C46 C51 -155.9(10) . . . . ?
N7 Rh4 C46 C51 61.8(9) . . . . ?
C47 Rh4 C46 C51 -118.0(11) . . . . ?
C50 Rh4 C46 C51 123.0(12) . . . . ?
O5 Rh4 C46 C51 -39.2(9) . . . . ?
C41 Rh4 C46 C51 -55.1(11) . . . . ?
C50 C46 C47 C48 0.8(10) . . . . ?
C51 C46 C47 C48 -177.0(8) . . . . ?
Rh4 C46 C47 C48 61.2(6) . . . . ?
C50 C46 C47 C52 -179.6(9) . . . . ?
C51 C46 C47 C52 2.6(14) . . . . ?
Rh4 C46 C47 C52 -119.2(9) . . . . ?
C50 C46 C47 Rh4 -60.4(6) . . . . ?
C51 C46 C47 Rh4 121.8(8) . . . . ?
N6 Rh4 C47 C46 -174.0(5) . . . . ?
C49 Rh4 C47 C46 80.3(7) . . . . ?
C48 Rh4 C47 C46 117.8(10) . . . . ?
N7 Rh4 C47 C46 -0.4(10) . . . . ?
C50 Rh4 C47 C46 36.5(6) . . . . ?
O5 Rh4 C47 C46 -112.5(5) . . . . ?
C41 Rh4 C47 C46 -140.7(5) . . . . ?
N6 Rh4 C47 C48 68.2(8) . . . . ?
C49 Rh4 C47 C48 -37.5(8) . . . . ?
N7 Rh4 C47 C48 -118.2(9) . . . . ?
C50 Rh4 C47 C48 -81.3(8) . . . . ?
C46 Rh4 C47 C48 -117.8(10) . . . . ?
O5 Rh4 C47 C48 129.7(8) . . . . ?
C41 Rh4 C47 C48 101.5(8) . . . . ?
N6 Rh4 C47 C52 -52.1(10) . . . . ?
C49 Rh4 C47 C52 -157.9(11) . . . . ?
C48 Rh4 C47 C52 -120.4(13) . . . . ?
N7 Rh4 C47 C52 121.5(10) . . . . ?
C50 Rh4 C47 C52 158.3(11) . . . . ?
C46 Rh4 C47 C52 121.8(11) . . . . ?
O5 Rh4 C47 C52 9.3(9) . . . . ?
C41 Rh4 C47 C52 -18.9(10) . . . . ?
C46 C47 C48 C49 -1.7(11) . . . . ?
C52 C47 C48 C49 178.7(9) . . . . ?
Rh4 C47 C48 C49 60.1(7) . . . . ?
C46 C47 C48 C53 -178.3(9) . . . . ?
C52 C47 C48 C53 2.1(16) . . . . ?
Rh4 C47 C48 C53 -116.4(11) . . . . ?
C46 C47 C48 Rh4 -61.9(6) . . . . ?
C52 C47 C48 Rh4 118.5(9) . . . . ?
N6 Rh4 C48 C49 115.0(7) . . . . ?
N7 Rh4 C48 C49 14.2(12) . . . . ?
C47 Rh4 C48 C49 -118.5(11) . . . . ?
C50 Rh4 C48 C49 -39.1(7) . . . . ?
C46 Rh4 C48 C49 -81.0(8) . . . . ?
O5 Rh4 C48 C49 177.7(6) . . . . ?
C41 Rh4 C48 C49 144.0(7) . . . . ?
N6 Rh4 C48 C47 -126.5(7) . . . . ?
C49 Rh4 C48 C47 118.5(11) . . . . ?
N7 Rh4 C48 C47 132.6(7) . . . . ?
C50 Rh4 C48 C47 79.3(8) . . . . ?
C46 Rh4 C48 C47 37.4(7) . . . . ?
O5 Rh4 C48 C47 -63.8(9) . . . . ?
C41 Rh4 C48 C47 -97.5(8) . . . . ?
N6 Rh4 C48 C53 -5.7(11) . . . . ?
C49 Rh4 C48 C53 -120.8(13) . . . . ?
N7 Rh4 C48 C53 -106.6(12) . . . . ?
C47 Rh4 C48 C53 120.8(14) . . . . ?
C50 Rh4 C48 C53 -159.9(12) . . . . ?
C46 Rh4 C48 C53 158.2(11) . . . . ?
O5 Rh4 C48 C53 57.0(11) . . . . ?
C41 Rh4 C48 C53 23.2(11) . . . . ?
C47 C48 C49 C50 2.0(11) . . . . ?
C53 C48 C49 C50 178.5(10) . . . . ?
Rh4 C48 C49 C50 62.7(7) . . . . ?
C47 C48 C49 C54 179.6(11) . . . . ?
C53 C48 C49 C54 -3.9(18) . . . . ?
Rh4 C48 C49 C54 -119.7(12) . . . . ?
C47 C48 C49 Rh4 -60.7(7) . . . . ?
C53 C48 C49 Rh4 115.8(11) . . . . ?
N6 Rh4 C49 C48 -78.4(7) . . . . ?
N7 Rh4 C49 C48 -171.7(7) . . . . ?
C47 Rh4 C49 C48 37.4(7) . . . . ?
C50 Rh4 C49 C48 116.0(10) . . . . ?
C46 Rh4 C49 C48 79.8(7) . . . . ?
O5 Rh4 C49 C48 -6.0(16) . . . . ?
C41 Rh4 C49 C48 -61.2(9) . . . . ?
N6 Rh4 C49 C50 165.6(6) . . . . ?
C48 Rh4 C49 C50 -116.0(10) . . . . ?
N7 Rh4 C49 C50 72.3(7) . . . . ?
C47 Rh4 C49 C50 -78.6(7) . . . . ?
C46 Rh4 C49 C50 -36.1(6) . . . . ?
O5 Rh4 C49 C50 -122.0(11) . . . . ?
C41 Rh4 C49 C50 -177.1(5) . . . . ?
N6 Rh4 C49 C54 44.0(14) . . . . ?
C48 Rh4 C49 C54 122.4(17) . . . . ?
N7 Rh4 C49 C54 -49.3(14) . . . . ?
C47 Rh4 C49 C54 159.8(15) . . . . ?
C50 Rh4 C49 C54 -121.6(16) . . . . ?
C46 Rh4 C49 C54 -157.8(15) . . . . ?
O5 Rh4 C49 C54 116.3(14) . . . . ?
C41 Rh4 C49 C54 61.2(16) . . . . ?
C47 C46 C50 C49 0.5(11) . . . . ?
C51 C46 C50 C49 178.1(9) . . . . ?
Rh4 C46 C50 C49 -59.7(7) . . . . ?
C47 C46 C50 C55 179.9(10) . . . . ?
C51 C46 C50 C55 -2.4(16) . . . . ?
Rh4 C46 C50 C55 119.7(11) . . . . ?
C47 C46 C50 Rh4 60.2(6) . . . . ?
C51 C46 C50 Rh4 -122.2(9) . . . . ?
C48 C49 C50 C46 -1.5(11) . . . . ?
C54 C49 C50 C46 -179.1(10) . . . . ?
Rh4 C49 C50 C46 61.2(7) . . . . ?
C48 C49 C50 C55 179.0(10) . . . . ?
C54 C49 C50 C55 1.4(18) . . . . ?
Rh4 C49 C50 C55 -118.3(10) . . . . ?
C48 C49 C50 Rh4 -62.7(7) . . . . ?
C54 C49 C50 Rh4 119.7(12) . . . . ?
N6 Rh4 C50 C46 -148.3(6) . . . . ?
C49 Rh4 C50 C46 -119.1(9) . . . . ?
C48 Rh4 C50 C46 -80.4(6) . . . . ?
N7 Rh4 C50 C46 126.5(6) . . . . ?
C47 Rh4 C50 C46 -37.1(6) . . . . ?
O5 Rh4 C50 C46 31.3(10) . . . . ?
C41 Rh4 C50 C46 25(7) . . . . ?
N6 Rh4 C50 C49 -29.2(11) . . . . ?
C48 Rh4 C50 C49 38.7(6) . . . . ?
N7 Rh4 C50 C49 -114.4(7) . . . . ?
C47 Rh4 C50 C49 82.0(7) . . . . ?
C46 Rh4 C50 C49 119.1(9) . . . . ?
O5 Rh4 C50 C49 150.4(6) . . . . ?
C41 Rh4 C50 C49 144(7) . . . . ?
N6 Rh4 C50 C55 90.2(14) . . . . ?
C49 Rh4 C50 C55 119.4(14) . . . . ?
C48 Rh4 C50 C55 158.1(13) . . . . ?
N7 Rh4 C50 C55 5.0(12) . . . . ?
C47 Rh4 C50 C55 -158.6(13) . . . . ?
C46 Rh4 C50 C55 -121.5(15) . . . . ?
O5 Rh4 C50 C55 -90.2(12) . . . . ?
C41 Rh4 C50 C55 -97(7) . . . . ?
C59 N7 C56 N8 -2.0(11) . . . . ?
Rh4 N7 C56 N8 158.3(6) . . . . ?
C59 N7 C56 O7 179.8(7) . . . . ?
Rh4 N7 C56 O7 -19.9(10) . . . . ?
C59 N7 C56 Rh1 77(19) . . . . ?
Rh4 N7 C56 Rh1 -123(19) . . . . ?
C57 N8 C56 N7 5.1(12) . . . . ?
Rh1 N8 C56 N7 177.9(7) . . . . ?
C57 N8 C56 O7 -176.5(7) . . . . ?
Rh1 N8 C56 O7 -3.7(6) . . . . ?
C57 N8 C56 Rh1 -172.8(9) . . . . ?
Rh1 O7 C56 N7 -178.0(6) . . . . ?
Na1 O7 C56 N7 -51.2(9) . . . . ?
Rh1 O7 C56 N8 3.5(6) . . . . ?
Na1 O7 C56 N8 130.4(6) . . . . ?
Na1 O7 C56 Rh1 126.9(5) . . . . ?
N8 Rh1 C56 N7 -80(19) . . . . ?
N1 Rh1 C56 N7 6(19) . . . . ?
C2 Rh1 C56 N7 179(100) . . . . ?
C3 Rh1 C56 N7 -139(19) . . . . ?
C4 Rh1 C56 N7 -100(19) . . . . ?
C1 Rh1 C56 N7 137(19) . . . . ?
O7 Rh1 C56 N7 104(19) . . . . ?
C5 Rh1 C56 N7 92(19) . . . . ?
N1 Rh1 C56 N8 86.4(5) . . . . ?
C2 Rh1 C56 N8 -101.0(7) . . . . ?
C3 Rh1 C56 N8 -58.2(7) . . . . ?
C4 Rh1 C56 N8 -19.6(9) . . . . ?
C1 Rh1 C56 N8 -142.3(7) . . . . ?
O7 Rh1 C56 N8 -176.0(7) . . . . ?
C5 Rh1 C56 N8 173(2) . . . . ?
N8 Rh1 C56 O7 176.0(7) . . . . ?
N1 Rh1 C56 O7 -97.6(4) . . . . ?
C2 Rh1 C56 O7 75.0(6) . . . . ?
C3 Rh1 C56 O7 117.8(6) . . . . ?
C4 Rh1 C56 O7 156.4(7) . . . . ?
C1 Rh1 C56 O7 33.7(7) . . . . ?
C5 Rh1 C56 O7 -11(2) . . . . ?
C56 N8 C57 O8 176.7(8) . . . . ?
Rh1 N8 C57 O8 9.0(15) . . . . ?
C56 N8 C57 C58 -5.0(12) . . . . ?
Rh1 N8 C57 C58 -172.6(7) . . . . ?
O8 C57 C58 C59 -179.7(9) . . . . ?
N8 C57 C58 C59 2.1(14) . . . . ?
O8 C57 C58 C60 1.1(15) . . . . ?
N8 C57 C58 C60 -177.1(9) . . . . ?
C57 C58 C59 N7 0.9(15) . . . . ?
C60 C58 C59 N7 -179.9(10) . . . . ?
C56 N7 C59 C58 -1.1(13) . . . . ?
Rh4 N7 C59 C58 -163.3(8) . . . . ?
C63 O9 C62 C61 -75(4) . . . . ?
C62 O9 C63 C64 -177(2) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.479
_refine_diff_density_min         -1.996
_refine_diff_density_rms         0.141

_vrf_PLAT241_I                   
;
PROBLEM: High      Ueq as Compared to Neighbors for .....         F1 Check 
RESPONSE: The F1 atom was probably disordered over several positions, but 
we have treated as a single atom for simplicity of the structure. 
;

_vrf_PLAT360_I                   
;
PROBLEM: Short  C(sp3)-C(sp3) Bond  C61    -   C62    ...       1.29 Ang. 
RESPONSE: These carbon atoms are of the solvated diethyl ether molecule, 
and have large thermal ellipsoids.  Therefore, the apparent bond length 
between these atoms would become shorter than the normal. 
;

_vrf_PLAT430_I                   
;
PROBLEM: Short Inter D...A Contact  O2     ..  O10     ..       2.72 Ang. 
RESPONSE: There would be a hydrogen bond between these atoms, although a H 
atom bound to O10 (a methanol molecule of crystallization) was not introduced
in this calculation.  
;

_vrf_PLAT601_I                   
;
PROBLEM: Structure Contains Solvent Accessible VOIDS of .        160 Ang3 
RESPONSE: Though some relatively large voids were found, we could not assign 
any reasonable structure for a molecule (or molecules) of solvent 
in these voids.  
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4NaBF4
_database_code_depnum_ccdc_archive 'CCDC 1033777'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C60 H76 B F4 N8 Na O8 Rh4, C4 H10 O, C H4 O, H2 O'
_chemical_formula_sum            'C65 H92 B F4 N8 Na O11 Rh4'
_chemical_formula_weight         1682.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.6620(7)
_cell_length_b                   16.4372(7)
_cell_length_c                   27.4724(10)
_cell_angle_alpha                90
_cell_angle_beta                 94.940(1)
_cell_angle_gamma                90
_cell_volume                     7496.1(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    233(2)
_cell_measurement_reflns_used    51963
_cell_measurement_theta_min      3.02
_cell_measurement_theta_max      27.52

_exptl_crystal_description       platelet
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.491
_exptl_crystal_F_000             3432
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    0.940
_shelx_estimated_absorpt_T_min   0.799
_shelx_estimated_absorpt_T_max   0.834
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.717
_exptl_absorpt_correction_T_max  0.829
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      233(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_reflns_number            72448
_diffrn_reflns_av_unetI/netI     0.0361
_diffrn_reflns_av_R_equivalents  0.0443
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         3.024
_diffrn_reflns_theta_max         27.484
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 0.998
_reflns_number_total             17152
_reflns_number_gt                12783
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    SIR2004
_computing_structure_refinement  SHELXL-2013
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-2013

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0947P)²+13.0479P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17152
_refine_ls_number_parameters     865
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0789
_refine_ls_R_factor_gt           0.0605
_refine_ls_wR_factor_ref         0.1818
_refine_ls_wR_factor_gt          0.1696
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_restrained_S_all      1.029
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.29045(2) 0.04212(2) 0.28939(2) 0.05099(12) Uani 1 1 d . . . . .
Rh2 Rh 0.47289(2) 0.24322(3) 0.41049(2) 0.05520(13) Uani 1 1 d . . . . .
Rh3 Rh 0.20495(3) 0.34327(3) 0.49017(2) 0.05374(12) Uani 1 1 d . . . . .
Rh4 Rh 0.02310(2) 0.16175(3) 0.35844(2) 0.05447(13) Uani 1 1 d . . . . .
Na1 Na 0.24984(12) 0.14999(12) 0.41259(7) 0.0523(4) Uani 1 1 d . . . . .
F1A F 0.2026(8) 0.0344(9) 0.4649(6) 0.168(7) Uani 0.5 1 d . . P . .
F1B F 0.283(2) 0.0546(9) 0.4659(4) 0.289(18) Uani 0.5 1 d . . P . .
F2 F 0.2892(7) -0.0594(4) 0.4931(3) 0.209(4) Uani 1 1 d . . . . .
F3 F 0.3187(8) 0.0572(9) 0.5162(13) 0.51(2) Uani 1 1 d . . . . .
F4 F 0.2250(10) 0.0161(7) 0.5351(4) 0.280(7) Uani 1 1 d . . . . .
O1 O 0.3784(2) 0.1595(2) 0.37848(13) 0.0504(8) Uani 1 1 d . . . . .
O2 O 0.5314(3) 0.3209(3) 0.29330(16) 0.0752(12) Uani 1 1 d . . . . .
O3 O 0.2954(2) 0.2709(2) 0.45441(12) 0.0510(8) Uani 1 1 d . . . . .
O4 O 0.2747(3) 0.5420(3) 0.44880(18) 0.0835(13) Uani 1 1 d . . . . .
O5 O 0.1189(2) 0.2079(2) 0.41295(12) 0.0502(8) Uani 1 1 d . . . . .
O6 O -0.0489(3) 0.3603(3) 0.31501(19) 0.0902(15) Uani 1 1 d . . . . .
O7 O 0.2009(2) 0.0899(2) 0.33624(12) 0.0485(7) Uani 1 1 d . . . . .
O8 O 0.2050(3) 0.1339(3) 0.17538(15) 0.0731(11) Uani 1 1 d . . . . .
O9 O 0.2266(6) 0.4497(6) 0.2401(3) 0.161(3) Uani 1 1 d D . . . .
O12 O 0.3315(4) 0.7454(4) 0.2333(3) 0.128(2) Uani 1 1 d . . . . .
O20A O 0.2396(17) 0.7459(17) 0.4820(11) 0.262(14) Uani 0.5 1 d . . P . .
O20B O 0.1571(11) 0.6506(13) 0.4011(13) 0.278(17) Uani 0.5 1 d . . P . .
N1 N 0.3508(2) 0.1549(2) 0.29457(15) 0.0486(9) Uani 1 1 d . . . . .
N2 N 0.4513(3) 0.2387(3) 0.33428(16) 0.0527(10) Uani 1 1 d . . . . .
N3 N 0.3866(3) 0.3367(2) 0.40888(16) 0.0534(10) Uani 1 1 d . . . . .
N4 N 0.2898(3) 0.4046(3) 0.45135(15) 0.0536(10) Uani 1 1 d . . . . .
N5 N 0.1315(3) 0.3478(3) 0.42374(17) 0.0573(10) Uani 1 1 d . . . . .
N6 N 0.0346(2) 0.2868(3) 0.36796(16) 0.0555(10) Uani 1 1 d . . . . .
N7 N 0.0996(2) 0.1742(3) 0.30207(15) 0.0504(9) Uani 1 1 d . . . . .
N8 N 0.1961(2) 0.1100(3) 0.25642(15) 0.0496(9) Uani 1 1 d . . . . .
C1 C 0.3911(3) 0.1828(3) 0.33471(18) 0.0462(10) Uani 1 1 d . . . . .
C2 C 0.4750(3) 0.2714(3) 0.2927(2) 0.0581(13) Uani 1 1 d . . . . .
C3 C 0.4300(3) 0.2464(3) 0.2479(2) 0.0569(12) Uani 1 1 d . . . . .
C4 C 0.3704(3) 0.1896(3) 0.25089(19) 0.0524(11) Uani 1 1 d . . . . .
H4 H 0.3411 0.1732 0.2218 0.063 Uiso 1 1 calc R U . . .
C5 C 0.4496(5) 0.2819(5) 0.1999(2) 0.0812(19) Uani 1 1 d . . . . .
H5A H 0.4025 0.3094 0.1846 0.097 Uiso 1 1 calc R U . . .
H5B H 0.4655 0.2387 0.1787 0.097 Uiso 1 1 calc R U . . .
H5C H 0.4934 0.3206 0.2055 0.097 Uiso 1 1 calc R U . . .
C6 C 0.3260(3) 0.3366(3) 0.43702(18) 0.0503(11) Uani 1 1 d . . . . .
C7 C 0.3088(4) 0.4803(3) 0.4347(2) 0.0621(14) Uani 1 1 d . . . . .
C8 C 0.3699(4) 0.4821(3) 0.4007(2) 0.0664(15) Uani 1 1 d . . . . .
C9 C 0.4061(4) 0.4106(4) 0.3905(2) 0.0637(14) Uani 1 1 d . . . . .
H9 H 0.4474 0.4122 0.3692 0.076 Uiso 1 1 calc R U . . .
C10 C 0.3921(6) 0.5617(4) 0.3783(3) 0.099(3) Uani 1 1 d . . . . .
H10A H 0.3821 0.5584 0.3430 0.118 Uiso 1 1 calc R U . . .
H10B H 0.4487 0.5729 0.3869 0.118 Uiso 1 1 calc R U . . .
H10C H 0.3598 0.6050 0.3905 0.118 Uiso 1 1 calc R U . . .
C11 C 0.0969(3) 0.2822(3) 0.40247(17) 0.0494(11) Uani 1 1 d . . . . .
C12 C 0.0045(3) 0.3579(4) 0.3498(2) 0.0664(15) Uani 1 1 d . . . . .
C13 C 0.0380(4) 0.4306(4) 0.3724(2) 0.0694(16) Uani 1 1 d . . . . .
C14 C 0.1002(4) 0.4208(4) 0.4078(2) 0.0679(15) Uani 1 1 d . . . . .
H14 H 0.1231 0.4680 0.4224 0.081 Uiso 1 1 calc R U . . .
C15 C 0.0069(5) 0.5119(5) 0.3557(3) 0.093(2) Uani 1 1 d . . . . .
H15A H 0.0499 0.5429 0.3428 0.112 Uiso 1 1 calc R U . . .
H15B H -0.0129 0.5409 0.3830 0.112 Uiso 1 1 calc R U . . .
H15C H -0.0367 0.5048 0.3302 0.112 Uiso 1 1 calc R U . . .
C16 C 0.1633(3) 0.1266(3) 0.29895(17) 0.0464(10) Uani 1 1 d . . . . .
C17 C 0.1714(3) 0.1468(3) 0.21281(19) 0.0566(12) Uani 1 1 d . . . . .
C18 C 0.1028(4) 0.2013(4) 0.21573(19) 0.0602(13) Uani 1 1 d . . . . .
C19 C 0.0712(3) 0.2117(4) 0.2590(2) 0.0589(13) Uani 1 1 d . . . . .
H19 H 0.0269 0.2468 0.2598 0.071 Uiso 1 1 calc R U . . .
C20 C 0.0706(5) 0.2445(5) 0.1691(2) 0.086(2) Uani 1 1 d . . . . .
H20A H 0.0749 0.3029 0.1738 0.103 Uiso 1 1 calc R U . . .
H20B H 0.0145 0.2299 0.1613 0.103 Uiso 1 1 calc R U . . .
H20C H 0.1018 0.2283 0.1425 0.103 Uiso 1 1 calc R U . . .
C21 C 0.2914(4) -0.0617(3) 0.2423(2) 0.0629(14) Uani 1 1 d . . . . .
C22 C 0.3694(4) -0.0255(3) 0.2478(3) 0.0721(17) Uani 1 1 d . . . . .
C23 C 0.3976(4) -0.0307(4) 0.2991(3) 0.082(2) Uani 1 1 d . . . . .
C24 C 0.3347(5) -0.0682(4) 0.3241(3) 0.083(2) Uani 1 1 d . . . . .
C25 C 0.2705(4) -0.0869(3) 0.2885(3) 0.0718(17) Uani 1 1 d . . . . .
C26 C 0.2395(5) -0.0708(5) 0.1951(3) 0.092(2) Uani 1 1 d . . . . .
H26A H 0.1894 -0.0414 0.1972 0.111 Uiso 1 1 calc R U . . .
H26B H 0.2279 -0.1279 0.1891 0.111 Uiso 1 1 calc R U . . .
H26C H 0.2675 -0.0489 0.1685 0.111 Uiso 1 1 calc R U . . .
C27 C 0.4158(5) 0.0069(4) 0.2077(4) 0.109(3) Uani 1 1 d . . . . .
H27A H 0.3851 0.0499 0.1906 0.131 Uiso 1 1 calc R U . . .
H27B H 0.4255 -0.0365 0.1851 0.131 Uiso 1 1 calc R U . . .
H27C H 0.4669 0.0286 0.2216 0.131 Uiso 1 1 calc R U . . .
C28 C 0.4774(5) 0.0007(6) 0.3199(5) 0.145(5) Uani 1 1 d . . . . .
H28A H 0.4804 0.0588 0.3141 0.174 Uiso 1 1 calc R U . . .
H28B H 0.5200 -0.0267 0.3044 0.174 Uiso 1 1 calc R U . . .
H28C H 0.4836 -0.0097 0.3548 0.174 Uiso 1 1 calc R U . . .
C29 C 0.3350(8) -0.0855(6) 0.3772(3) 0.150(5) Uani 1 1 d . . . . .
H29A H 0.3283 -0.1435 0.3821 0.180 Uiso 1 1 calc R U . . .
H29B H 0.2910 -0.0565 0.3904 0.180 Uiso 1 1 calc R U . . .
H29C H 0.3857 -0.0679 0.3939 0.180 Uiso 1 1 calc R U . . .
C30 C 0.1940(5) -0.1321(4) 0.2976(4) 0.107(3) Uani 1 1 d . . . . .
H30A H 0.1652 -0.1022 0.3210 0.128 Uiso 1 1 calc R U . . .
H30B H 0.2075 -0.1859 0.3103 0.128 Uiso 1 1 calc R U . . .
H30C H 0.1602 -0.1371 0.2671 0.128 Uiso 1 1 calc R U . . .
C31 C 0.5896(3) 0.1903(4) 0.4239(3) 0.0743(17) Uani 1 1 d . . . . .
C32 C 0.5957(3) 0.2759(4) 0.4277(2) 0.0693(15) Uani 1 1 d . . . . .
C33 C 0.5519(4) 0.3020(6) 0.4664(3) 0.092(2) Uani 1 1 d . . . . .
C34 C 0.5140(5) 0.2364(8) 0.4875(3) 0.112(3) Uani 1 1 d . . . . .
C35 C 0.5389(4) 0.1658(5) 0.4616(4) 0.099(3) Uani 1 1 d . . . . .
C36 C 0.6326(5) 0.1386(6) 0.3886(4) 0.124(4) Uani 1 1 d . . . . .
H36A H 0.6903 0.1453 0.3951 0.148 Uiso 1 1 calc R U . . .
H36B H 0.6163 0.1554 0.3554 0.148 Uiso 1 1 calc R U . . .
H36C H 0.6186 0.0819 0.3927 0.148 Uiso 1 1 calc R U . . .
C37 C 0.6439(5) 0.3325(5) 0.4006(4) 0.107(3) Uani 1 1 d . . . . .
H37A H 0.6838 0.3587 0.4231 0.129 Uiso 1 1 calc R U . . .
H37B H 0.6088 0.3734 0.3847 0.129 Uiso 1 1 calc R U . . .
H37C H 0.6707 0.3026 0.3762 0.129 Uiso 1 1 calc R U . . .
C38 C 0.5437(6) 0.3870(8) 0.4838(5) 0.168(6) Uani 1 1 d . . . . .
H38A H 0.5195 0.4203 0.4573 0.202 Uiso 1 1 calc R U . . .
H38B H 0.5964 0.4084 0.4947 0.202 Uiso 1 1 calc R U . . .
H38C H 0.5096 0.3877 0.5107 0.202 Uiso 1 1 calc R U . . .
C39 C 0.4615(6) 0.2272(13) 0.5287(4) 0.229(10) Uani 1 1 d . . . . .
H39A H 0.4893 0.1949 0.5545 0.275 Uiso 1 1 calc R U . . .
H39B H 0.4118 0.2001 0.5170 0.275 Uiso 1 1 calc R U . . .
H39C H 0.4492 0.2804 0.5414 0.275 Uiso 1 1 calc R U . . .
C40 C 0.5180(6) 0.0727(7) 0.4649(6) 0.215(9) Uani 1 1 d . . . . .
H40A H 0.4606 0.0650 0.4573 0.257 Uiso 1 1 calc R U . . .
H40B H 0.5333 0.0533 0.4977 0.257 Uiso 1 1 calc R U . . .
H40C H 0.5473 0.0425 0.4418 0.257 Uiso 1 1 calc R U . . .
C41 C 0.2321(5) 0.3843(5) 0.5634(2) 0.082(2) Uani 1 1 d . . . . .
C42 C 0.1588(6) 0.4185(5) 0.5445(3) 0.095(2) Uani 1 1 d . . . . .
C43 C 0.1052(4) 0.3525(6) 0.5337(3) 0.087(2) Uani 1 1 d . . . . .
C44 C 0.1457(4) 0.2791(4) 0.5454(2) 0.0738(17) Uani 1 1 d . . . . .
C45 C 0.2250(4) 0.3002(4) 0.56507(19) 0.0679(15) Uani 1 1 d . . . . .
C46 C 0.3097(7) 0.4300(7) 0.5810(3) 0.154(5) Uani 1 1 d . . . . .
H46A H 0.2994 0.4649 0.6083 0.185 Uiso 1 1 calc R U . . .
H46B H 0.3271 0.4629 0.5546 0.185 Uiso 1 1 calc R U . . .
H46C H 0.3515 0.3911 0.5914 0.185 Uiso 1 1 calc R U . . .
C47 C 0.1434(9) 0.5067(6) 0.5389(5) 0.173(6) Uani 1 1 d . . . . .
H47A H 0.1789 0.5294 0.5163 0.207 Uiso 1 1 calc R U . . .
H47B H 0.1533 0.5332 0.5704 0.207 Uiso 1 1 calc R U . . .
H47C H 0.0878 0.5154 0.5264 0.207 Uiso 1 1 calc R U . . .
C48 C 0.0200(5) 0.3586(9) 0.5134(4) 0.158(5) Uani 1 1 d . . . . .
H48A H 0.0175 0.3856 0.4820 0.190 Uiso 1 1 calc R U . . .
H48B H -0.0103 0.3897 0.5356 0.190 Uiso 1 1 calc R U . . .
H48C H -0.0028 0.3045 0.5095 0.190 Uiso 1 1 calc R U . . .
C49 C 0.1142(6) 0.1940(6) 0.5410(3) 0.112(3) Uani 1 1 d . . . . .
H49A H 0.0967 0.1826 0.5070 0.134 Uiso 1 1 calc R U . . .
H49B H 0.0690 0.1880 0.5607 0.134 Uiso 1 1 calc R U . . .
H49C H 0.1564 0.1562 0.5523 0.134 Uiso 1 1 calc R U . . .
C50 C 0.2862(6) 0.2400(7) 0.5843(3) 0.115(3) Uani 1 1 d . . . . .
H50A H 0.3016 0.2513 0.6185 0.138 Uiso 1 1 calc R U . . .
H50B H 0.3332 0.2438 0.5659 0.138 Uiso 1 1 calc R U . . .
H50C H 0.2637 0.1857 0.5810 0.138 Uiso 1 1 calc R U . . .
C51 C -0.1009(4) 0.1476(5) 0.3680(4) 0.106(3) Uani 1 1 d . . . . .
C52 C -0.0839(4) 0.1179(5) 0.3206(3) 0.086(2) Uani 1 1 d . . . . .
C53 C -0.0310(4) 0.0513(5) 0.3284(3) 0.0788(19) Uani 1 1 d . . . . .
C54 C -0.0106(4) 0.0402(4) 0.3774(2) 0.0732(17) Uani 1 1 d . . . . .
C55 C -0.0539(4) 0.0976(6) 0.4041(3) 0.090(2) Uani 1 1 d . . . . .
C56 C -0.1549(5) 0.2151(7) 0.3808(6) 0.179(6) Uani 1 1 d . . . . .
H56A H -0.1234 0.2566 0.3988 0.215 Uiso 1 1 calc R U . . .
H56B H -0.1954 0.1941 0.4008 0.215 Uiso 1 1 calc R U . . .
H56C H -0.1810 0.2385 0.3511 0.215 Uiso 1 1 calc R U . . .
C57 C -0.1236(6) 0.1504(8) 0.2748(4) 0.169(6) Uani 1 1 d . . . . .
H57A H -0.1564 0.1082 0.2583 0.203 Uiso 1 1 calc R U . . .
H57B H -0.0830 0.1683 0.2538 0.203 Uiso 1 1 calc R U . . .
H57C H -0.1575 0.1961 0.2819 0.203 Uiso 1 1 calc R U . . .
C58 C 0.0007(6) 0.0016(7) 0.2874(3) 0.128(4) Uani 1 1 d . . . . .
H58A H -0.0138 -0.0551 0.2911 0.154 Uiso 1 1 calc R U . . .
H58B H 0.0588 0.0066 0.2889 0.154 Uiso 1 1 calc R U . . .
H58C H -0.0228 0.0217 0.2562 0.154 Uiso 1 1 calc R U . . .
C59 C 0.0445(6) -0.0251(5) 0.4003(4) 0.111(3) Uani 1 1 d . . . . .
H59A H 0.0977 -0.0191 0.3889 0.133 Uiso 1 1 calc R U . . .
H59B H 0.0230 -0.0782 0.3909 0.133 Uiso 1 1 calc R U . . .
H59C H 0.0480 -0.0198 0.4355 0.133 Uiso 1 1 calc R U . . .
C60 C -0.0537(7) 0.1037(8) 0.4586(3) 0.156(5) Uani 1 1 d . . . . .
H60A H -0.1076 0.0940 0.4680 0.187 Uiso 1 1 calc R U . . .
H60B H -0.0361 0.1576 0.4692 0.187 Uiso 1 1 calc R U . . .
H60C H -0.0172 0.0634 0.4739 0.187 Uiso 1 1 calc R U . . .
C61 C 0.2268(8) 0.3584(9) 0.3070(4) 0.159(5) Uani 1 1 d D . . . .
H61A H 0.2521 0.3113 0.2936 0.190 Uiso 1 1 calc R U . . .
H61B H 0.1696 0.3483 0.3079 0.190 Uiso 1 1 calc R U . . .
H61C H 0.2509 0.3687 0.3398 0.190 Uiso 1 1 calc R U . . .
C62 C 0.2364(16) 0.4163(14) 0.2819(7) 0.321(16) Uani 1 1 d D . . . .
H62A H 0.2948 0.4234 0.2886 0.386 Uiso 1 1 calc R U . . .
H62B H 0.2133 0.4586 0.3016 0.386 Uiso 1 1 calc R U . . .
C63 C 0.2520(13) 0.4244(10) 0.1998(6) 0.213(8) Uani 1 1 d D . . . .
H63A H 0.2245 0.3726 0.1922 0.256 Uiso 1 1 calc R U . . .
H63B H 0.3092 0.4115 0.2070 0.256 Uiso 1 1 calc R U . . .
C64 C 0.2467(10) 0.4658(8) 0.1597(5) 0.175(6) Uani 1 1 d D . . . .
H64A H 0.2763 0.5164 0.1647 0.210 Uiso 1 1 calc R U . . .
H64B H 0.1905 0.4777 0.1500 0.210 Uiso 1 1 calc R U . . .
H64C H 0.2692 0.4345 0.1342 0.210 Uiso 1 1 calc R U . . .
C65 C 0.3508(6) 0.6807(9) 0.2625(5) 0.161(6) Uani 1 1 d . . . . .
B1 B 0.2648(6) 0.0145(6) 0.4977(5) 0.097(3) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N8 2.072(4) . ?
Rh1 N1 2.107(4) . ?
Rh1 C22 2.129(6) . ?
Rh1 C21 2.143(5) . ?
Rh1 C23 2.146(6) . ?
Rh1 C25 2.147(5) . ?
Rh1 C24 2.149(6) . ?
Rh1 O7 2.198(3) . ?
Rh1 C16 2.565(5) . ?
Rh2 N2 2.095(5) . ?
Rh2 N3 2.102(4) . ?
Rh2 C32 2.128(6) . ?
Rh2 C35 2.128(6) . ?
Rh2 C31 2.133(6) . ?
Rh2 C33 2.163(7) . ?
Rh2 C34 2.169(8) . ?
Rh2 O1 2.215(3) . ?
Rh2 C1 2.586(5) . ?
Rh3 N4 2.101(4) . ?
Rh3 N5 2.110(5) . ?
Rh3 C41 2.132(6) . ?
Rh3 C42 2.132(7) . ?
Rh3 C43 2.135(6) . ?
Rh3 C44 2.156(6) . ?
Rh3 C45 2.174(6) . ?
Rh3 O3 2.215(3) . ?
Rh3 C6 2.592(5) . ?
Rh4 N6 2.079(5) . ?
Rh4 N7 2.098(4) . ?
Rh4 C52 2.111(6) . ?
Rh4 C51 2.117(6) . ?
Rh4 C55 2.146(6) . ?
Rh4 C54 2.151(6) . ?
Rh4 C53 2.159(7) . ?
Rh4 O5 2.225(3) . ?
Rh4 C11 2.576(5) . ?
Na1 F1B 2.184(15) . ?
Na1 O5 2.382(4) . ?
Na1 O3 2.387(4) . ?
Na1 O7 2.397(4) . ?
Na1 O1 2.416(4) . ?
Na1 F1A 2.548(15) . ?
F1A B1 1.352(15) . ?
F1B B1 1.156(17) . ?
F2 B1 1.289(12) . ?
F3 B1 1.217(19) . ?
F4 B1 1.269(14) . ?
O1 C1 1.297(6) . ?
O2 C2 1.242(6) . ?
O3 C6 1.302(6) . ?
O4 C7 1.240(7) . ?
O5 C11 1.299(6) . ?
O6 C12 1.248(7) . ?
O7 C16 1.302(6) . ?
O8 C17 1.231(7) . ?
O9 C62 1.270(14) . ?
O9 C63 1.289(14) . ?
O12 C65 1.355(12) . ?
N1 C1 1.323(6) . ?
N1 C4 1.393(6) . ?
N2 C2 1.353(7) . ?
N2 C1 1.361(6) . ?
N3 C6 1.323(7) . ?
N3 C9 1.366(7) . ?
N4 C6 1.346(7) . ?
N4 C7 1.372(7) . ?
N5 C11 1.333(7) . ?
N5 C14 1.365(7) . ?
N6 C11 1.346(6) . ?
N6 C12 1.351(8) . ?
N7 C16 1.329(6) . ?
N7 C19 1.381(7) . ?
N8 C16 1.359(6) . ?
N8 C17 1.373(7) . ?
C2 C3 1.444(8) . ?
C3 C4 1.371(7) . ?
C3 C5 1.502(8) . ?
C4 H4 0.9400 . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C5 H5C 0.9700 . ?
C7 C8 1.439(8) . ?
C8 C9 1.361(9) . ?
C8 C10 1.505(8) . ?
C9 H9 0.9400 . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C10 H10C 0.9700 . ?
C12 C13 1.437(10) . ?
C13 C14 1.369(9) . ?
C13 C15 1.491(9) . ?
C14 H14 0.9400 . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 H15C 0.9700 . ?
C17 C18 1.459(8) . ?
C18 C19 1.351(8) . ?
C18 C20 1.522(8) . ?
C19 H19 0.9400 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 H20C 0.9700 . ?
C21 C25 1.408(9) . ?
C21 C22 1.426(9) . ?
C21 C26 1.502(10) . ?
C22 C23 1.449(11) . ?
C22 C27 1.497(10) . ?
C23 C24 1.439(11) . ?
C23 C28 1.493(10) . ?
C24 C25 1.420(10) . ?
C24 C29 1.487(11) . ?
C25 C30 1.515(9) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C26 H26C 0.9700 . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C27 H27C 0.9700 . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C28 H28C 0.9700 . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C29 H29C 0.9700 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C30 H30C 0.9700 . ?
C31 C32 1.414(9) . ?
C31 C35 1.448(11) . ?
C31 C36 1.515(12) . ?
C32 C33 1.406(10) . ?
C32 C37 1.472(9) . ?
C33 C34 1.400(13) . ?
C33 C38 1.486(14) . ?
C34 C35 1.440(13) . ?
C34 C39 1.499(13) . ?
C35 C40 1.574(13) . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C36 H36C 0.9700 . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C37 H37C 0.9700 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C38 H38C 0.9700 . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C39 H39C 0.9700 . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C40 H40C 0.9700 . ?
C41 C45 1.388(10) . ?
C41 C42 1.403(12) . ?
C41 C46 1.537(11) . ?
C42 C43 1.420(12) . ?
C42 C47 1.478(12) . ?
C43 C44 1.406(10) . ?
C43 C48 1.483(11) . ?
C44 C45 1.427(9) . ?
C44 C49 1.496(10) . ?
C45 C50 1.484(11) . ?
C46 H46A 0.9700 . ?
C46 H46B 0.9700 . ?
C46 H46C 0.9700 . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C47 H47C 0.9700 . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
C48 H48C 0.9700 . ?
C49 H49A 0.9700 . ?
C49 H49B 0.9700 . ?
C49 H49C 0.9700 . ?
C50 H50A 0.9700 . ?
C50 H50B 0.9700 . ?
C50 H50C 0.9700 . ?
C51 C52 1.440(12) . ?
C51 C55 1.461(12) . ?
C51 C56 1.490(13) . ?
C52 C53 1.410(11) . ?
C52 C57 1.472(11) . ?
C53 C54 1.373(9) . ?
C53 C58 1.522(11) . ?
C54 C55 1.428(11) . ?
C54 C59 1.512(11) . ?
C55 C60 1.501(11) . ?
C56 H56A 0.9700 . ?
C56 H56B 0.9700 . ?
C56 H56C 0.9700 . ?
C57 H57A 0.9700 . ?
C57 H57B 0.9700 . ?
C57 H57C 0.9700 . ?
C58 H58A 0.9700 . ?
C58 H58B 0.9700 . ?
C58 H58C 0.9700 . ?
C59 H59A 0.9700 . ?
C59 H59B 0.9700 . ?
C59 H59C 0.9700 . ?
C60 H60A 0.9700 . ?
C60 H60B 0.9700 . ?
C60 H60C 0.9700 . ?
C61 C62 1.194(15) . ?
C61 H61A 0.9700 . ?
C61 H61B 0.9700 . ?
C61 H61C 0.9700 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C63 C64 1.292(14) . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C64 H64A 0.9700 . ?
C64 H64B 0.9700 . ?
C64 H64C 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Rh1 N1 84.00(16) . . ?
N8 Rh1 C22 121.9(2) . . ?
N1 Rh1 C22 100.5(2) . . ?
N8 Rh1 C21 102.1(2) . . ?
N1 Rh1 C21 135.47(19) . . ?
C22 Rh1 C21 39.0(2) . . ?
N8 Rh1 C23 161.2(3) . . ?
N1 Rh1 C23 95.5(2) . . ?
C22 Rh1 C23 39.6(3) . . ?
C21 Rh1 C23 65.3(3) . . ?
N8 Rh1 C25 114.6(2) . . ?
N1 Rh1 C25 160.4(2) . . ?
C22 Rh1 C25 65.2(2) . . ?
C21 Rh1 C25 38.3(2) . . ?
C23 Rh1 C25 65.0(3) . . ?
N8 Rh1 C24 150.1(3) . . ?
N1 Rh1 C24 124.7(3) . . ?
C22 Rh1 C24 66.0(3) . . ?
C21 Rh1 C24 64.9(3) . . ?
C23 Rh1 C24 39.2(3) . . ?
C25 Rh1 C24 38.6(3) . . ?
N8 Rh1 O7 62.32(14) . . ?
N1 Rh1 O7 89.44(14) . . ?
C22 Rh1 O7 169.44(19) . . ?
C21 Rh1 O7 132.75(18) . . ?
C23 Rh1 O7 136.5(3) . . ?
C25 Rh1 O7 104.33(19) . . ?
C24 Rh1 O7 105.4(2) . . ?
N8 Rh1 C16 31.88(15) . . ?
N1 Rh1 C16 84.84(15) . . ?
C22 Rh1 C16 153.1(2) . . ?
C21 Rh1 C16 122.8(2) . . ?
C23 Rh1 C16 167.0(3) . . ?
C25 Rh1 C16 114.1(2) . . ?
C24 Rh1 C16 131.8(3) . . ?
O7 Rh1 C16 30.50(13) . . ?
N2 Rh2 N3 86.92(17) . . ?
N2 Rh2 C32 108.1(2) . . ?
N3 Rh2 C32 117.6(2) . . ?
N2 Rh2 C35 132.3(3) . . ?
N3 Rh2 C35 139.8(3) . . ?
C32 Rh2 C35 64.7(2) . . ?
N2 Rh2 C31 103.5(2) . . ?
N3 Rh2 C31 156.0(2) . . ?
C32 Rh2 C31 38.7(3) . . ?
C35 Rh2 C31 39.7(3) . . ?
N2 Rh2 C33 140.1(3) . . ?
N3 Rh2 C33 93.5(3) . . ?
C32 Rh2 C33 38.3(3) . . ?
C35 Rh2 C33 63.3(3) . . ?
C31 Rh2 C33 64.5(3) . . ?
N2 Rh2 C34 170.1(3) . . ?
N3 Rh2 C34 102.5(3) . . ?
C32 Rh2 C34 65.1(3) . . ?
C35 Rh2 C34 39.2(4) . . ?
C31 Rh2 C34 66.7(3) . . ?
C33 Rh2 C34 37.7(4) . . ?
N2 Rh2 O1 61.72(14) . . ?
N3 Rh2 O1 89.08(15) . . ?
C32 Rh2 O1 151.8(2) . . ?
C35 Rh2 O1 101.5(2) . . ?
C31 Rh2 O1 114.9(2) . . ?
C33 Rh2 O1 158.1(3) . . ?
C34 Rh2 O1 120.6(3) . . ?
N2 Rh2 C1 31.64(15) . . ?
N3 Rh2 C1 87.22(16) . . ?
C32 Rh2 C1 134.9(2) . . ?
C35 Rh2 C1 120.5(3) . . ?
C31 Rh2 C1 113.1(2) . . ?
C33 Rh2 C1 171.7(3) . . ?
C34 Rh2 C1 149.9(4) . . ?
O1 Rh2 C1 30.09(13) . . ?
N4 Rh3 N5 84.82(17) . . ?
N4 Rh3 C41 103.3(2) . . ?
N5 Rh3 C41 149.9(3) . . ?
N4 Rh3 C42 112.1(3) . . ?
N5 Rh3 C42 111.6(3) . . ?
C41 Rh3 C42 38.4(3) . . ?
N4 Rh3 C43 147.2(3) . . ?
N5 Rh3 C43 93.5(2) . . ?
C41 Rh3 C43 64.0(3) . . ?
C42 Rh3 C43 38.9(3) . . ?
N4 Rh3 C44 164.0(2) . . ?
N5 Rh3 C44 111.1(2) . . ?
C41 Rh3 C44 64.1(3) . . ?
C42 Rh3 C44 64.9(3) . . ?
C43 Rh3 C44 38.2(3) . . ?
N4 Rh3 C45 125.5(2) . . ?
N5 Rh3 C45 149.4(2) . . ?
C41 Rh3 C45 37.6(3) . . ?
C42 Rh3 C45 64.0(3) . . ?
C43 Rh3 C45 63.7(3) . . ?
C44 Rh3 C45 38.5(2) . . ?
N4 Rh3 O3 61.28(15) . . ?
N5 Rh3 O3 90.09(15) . . ?
C41 Rh3 O3 119.4(3) . . ?
C42 Rh3 O3 157.2(3) . . ?
C43 Rh3 O3 151.5(3) . . ?
C44 Rh3 O3 114.8(2) . . ?
C45 Rh3 O3 100.95(19) . . ?
N4 Rh3 C6 31.14(16) . . ?
N5 Rh3 C6 86.33(17) . . ?
C41 Rh3 C6 115.6(2) . . ?
C42 Rh3 C6 139.8(3) . . ?
C43 Rh3 C6 178.3(3) . . ?
C44 Rh3 C6 143.3(2) . . ?
C45 Rh3 C6 117.1(2) . . ?
O3 Rh3 C6 30.15(14) . . ?
N6 Rh4 N7 86.60(17) . . ?
N6 Rh4 C52 117.7(3) . . ?
N7 Rh4 C52 102.2(2) . . ?
N6 Rh4 C51 100.0(3) . . ?
N7 Rh4 C51 139.7(3) . . ?
C52 Rh4 C51 39.8(3) . . ?
N6 Rh4 C55 117.7(3) . . ?
N7 Rh4 C55 155.6(3) . . ?
C52 Rh4 C55 66.3(3) . . ?
C51 Rh4 C55 40.1(3) . . ?
N6 Rh4 C54 155.6(2) . . ?
N7 Rh4 C54 117.2(2) . . ?
C52 Rh4 C54 64.9(3) . . ?
C51 Rh4 C54 65.8(3) . . ?
C55 Rh4 C54 38.8(3) . . ?
N6 Rh4 C53 155.6(2) . . ?
N7 Rh4 C53 93.5(2) . . ?
C52 Rh4 C53 38.5(3) . . ?
C51 Rh4 C53 64.9(3) . . ?
C55 Rh4 C53 63.8(3) . . ?
C54 Rh4 C53 37.1(3) . . ?
N6 Rh4 O5 61.63(15) . . ?
N7 Rh4 O5 91.01(14) . . ?
C52 Rh4 O5 166.8(2) . . ?
C51 Rh4 O5 127.2(3) . . ?
C55 Rh4 O5 101.8(2) . . ?
C54 Rh4 O5 109.9(2) . . ?
C53 Rh4 O5 142.7(2) . . ?
N6 Rh4 C11 31.35(16) . . ?
N7 Rh4 C11 88.61(16) . . ?
C52 Rh4 C11 147.3(3) . . ?
C51 Rh4 C11 117.2(3) . . ?
C55 Rh4 C11 112.8(2) . . ?
C54 Rh4 C11 136.3(2) . . ?
C53 Rh4 C11 172.9(2) . . ?
O5 Rh4 C11 30.29(14) . . ?
F1B Na1 O5 117.6(10) . . ?
F1B Na1 O3 102.9(5) . . ?
O5 Na1 O3 85.34(14) . . ?
F1B Na1 O7 109.8(5) . . ?
O5 Na1 O7 85.73(13) . . ?
O3 Na1 O7 146.57(14) . . ?
F1B Na1 O1 97.2(10) . . ?
O5 Na1 O1 144.97(14) . . ?
O3 Na1 O1 82.91(13) . . ?
O7 Na1 O1 86.20(13) . . ?
O5 Na1 F1A 88.2(3) . . ?
O3 Na1 F1A 116.8(4) . . ?
O7 Na1 F1A 95.1(4) . . ?
O1 Na1 F1A 126.5(4) . . ?
B1 F1A Na1 107.5(9) . . ?
B1 F1B F3 54.0(9) . . ?
B1 F1B Na1 148(3) . . ?
F3 F1B Na1 132.3(13) . . ?
B1 F3 F1B 50.2(13) . . ?
C1 O1 Rh2 91.0(3) . . ?
C1 O1 Na1 126.9(3) . . ?
Rh2 O1 Na1 120.67(16) . . ?
C6 O3 Rh3 91.2(3) . . ?
C6 O3 Na1 129.2(3) . . ?
Rh3 O3 Na1 117.40(15) . . ?
C11 O5 Rh4 90.0(3) . . ?
C11 O5 Na1 128.0(3) . . ?
Rh4 O5 Na1 117.70(16) . . ?
C16 O7 Rh1 90.5(3) . . ?
C16 O7 Na1 127.0(3) . . ?
Rh1 O7 Na1 117.55(15) . . ?
C62 O9 C63 127.7(16) . . ?
C1 N1 C4 115.8(4) . . ?
C1 N1 Rh1 124.5(3) . . ?
C4 N1 Rh1 116.7(3) . . ?
C2 N2 C1 123.0(5) . . ?
C2 N2 Rh2 142.5(4) . . ?
C1 N2 Rh2 94.5(3) . . ?
C6 N3 C9 115.8(5) . . ?
C6 N3 Rh2 122.8(3) . . ?
C9 N3 Rh2 118.3(4) . . ?
C6 N4 C7 122.2(5) . . ?
C6 N4 Rh3 95.0(3) . . ?
C7 N4 Rh3 142.2(4) . . ?
C11 N5 C14 115.6(5) . . ?
C11 N5 Rh3 123.2(3) . . ?
C14 N5 Rh3 119.0(4) . . ?
C11 N6 C12 123.3(5) . . ?
C11 N6 Rh4 95.2(3) . . ?
C12 N6 Rh4 141.4(4) . . ?
C16 N7 C19 115.0(4) . . ?
C16 N7 Rh4 122.0(3) . . ?
C19 N7 Rh4 119.5(3) . . ?
C16 N8 C17 123.3(5) . . ?
C16 N8 Rh1 94.5(3) . . ?
C17 N8 Rh1 141.1(4) . . ?
O1 C1 N1 123.9(4) . . ?
O1 C1 N2 112.7(4) . . ?
N1 C1 N2 123.3(5) . . ?
O1 C1 Rh2 58.9(2) . . ?
N1 C1 Rh2 177.1(4) . . ?
N2 C1 Rh2 53.9(3) . . ?
O2 C2 N2 121.6(6) . . ?
O2 C2 C3 122.3(5) . . ?
N2 C2 C3 116.1(5) . . ?
C4 C3 C2 117.9(5) . . ?
C4 C3 C5 122.1(5) . . ?
C2 C3 C5 120.1(5) . . ?
C3 C4 N1 123.9(5) . . ?
C3 C4 H4 118.1 . . ?
N1 C4 H4 118.1 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
O3 C6 N3 123.9(5) . . ?
O3 C6 N4 112.5(4) . . ?
N3 C6 N4 123.6(5) . . ?
O3 C6 Rh3 58.7(2) . . ?
N3 C6 Rh3 177.1(4) . . ?
N4 C6 Rh3 53.8(3) . . ?
O4 C7 N4 120.7(5) . . ?
O4 C7 C8 123.7(5) . . ?
N4 C7 C8 115.6(5) . . ?
C9 C8 C7 117.9(5) . . ?
C9 C8 C10 122.4(6) . . ?
C7 C8 C10 119.7(6) . . ?
C8 C9 N3 124.6(5) . . ?
C8 C9 H9 117.7 . . ?
N3 C9 H9 117.7 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O5 C11 N5 124.0(4) . . ?
O5 C11 N6 113.2(5) . . ?
N5 C11 N6 122.7(5) . . ?
O5 C11 Rh4 59.7(3) . . ?
N5 C11 Rh4 176.2(4) . . ?
N6 C11 Rh4 53.5(3) . . ?
O6 C12 N6 121.9(6) . . ?
O6 C12 C13 121.9(6) . . ?
N6 C12 C13 116.2(5) . . ?
C14 C13 C12 116.8(6) . . ?
C14 C13 C15 123.2(7) . . ?
C12 C13 C15 119.9(6) . . ?
N5 C14 C13 125.2(6) . . ?
N5 C14 H14 117.4 . . ?
C13 C14 H14 117.4 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O7 C16 N7 123.7(4) . . ?
O7 C16 N8 112.5(4) . . ?
N7 C16 N8 123.8(4) . . ?
O7 C16 Rh1 59.0(2) . . ?
N7 C16 Rh1 176.1(4) . . ?
N8 C16 Rh1 53.7(2) . . ?
O8 C17 N8 122.0(5) . . ?
O8 C17 C18 124.5(5) . . ?
N8 C17 C18 113.6(5) . . ?
C19 C18 C17 119.5(5) . . ?
C19 C18 C20 123.0(6) . . ?
C17 C18 C20 117.5(5) . . ?
C18 C19 N7 124.6(5) . . ?
C18 C19 H19 117.7 . . ?
N7 C19 H19 117.7 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C25 C21 C22 108.7(6) . . ?
C25 C21 C26 125.4(6) . . ?
C22 C21 C26 125.9(6) . . ?
C25 C21 Rh1 71.0(3) . . ?
C22 C21 Rh1 70.0(3) . . ?
C26 C21 Rh1 124.5(5) . . ?
C21 C22 C23 107.2(6) . . ?
C21 C22 C27 126.5(7) . . ?
C23 C22 C27 126.3(7) . . ?
C21 C22 Rh1 71.0(3) . . ?
C23 C22 Rh1 70.8(4) . . ?
C27 C22 Rh1 126.2(4) . . ?
C24 C23 C22 107.5(6) . . ?
C24 C23 C28 128.7(9) . . ?
C22 C23 C28 123.7(9) . . ?
C24 C23 Rh1 70.5(4) . . ?
C22 C23 Rh1 69.6(3) . . ?
C28 C23 Rh1 124.0(5) . . ?
C25 C24 C23 107.5(6) . . ?
C25 C24 C29 125.0(9) . . ?
C23 C24 C29 127.6(9) . . ?
C25 C24 Rh1 70.6(4) . . ?
C23 C24 Rh1 70.3(4) . . ?
C29 C24 Rh1 124.7(5) . . ?
C21 C25 C24 109.1(6) . . ?
C21 C25 C30 124.7(7) . . ?
C24 C25 C30 126.0(7) . . ?
C21 C25 Rh1 70.7(3) . . ?
C24 C25 Rh1 70.8(3) . . ?
C30 C25 Rh1 127.9(5) . . ?
C21 C26 H26A 109.5 . . ?
C21 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C21 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C22 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C22 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C25 C30 H30A 109.5 . . ?
C25 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C25 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 C35 105.4(7) . . ?
C32 C31 C36 124.8(7) . . ?
C35 C31 C36 129.7(8) . . ?
C32 C31 Rh2 70.4(3) . . ?
C35 C31 Rh2 69.9(4) . . ?
C36 C31 Rh2 126.3(5) . . ?
C33 C32 C31 108.8(7) . . ?
C33 C32 C37 122.0(7) . . ?
C31 C32 C37 129.0(7) . . ?
C33 C32 Rh2 72.2(4) . . ?
C31 C32 Rh2 70.8(3) . . ?
C37 C32 Rh2 127.1(5) . . ?
C34 C33 C32 111.0(8) . . ?
C34 C33 C38 122.2(10) . . ?
C32 C33 C38 126.8(10) . . ?
C34 C33 Rh2 71.4(5) . . ?
C32 C33 Rh2 69.5(4) . . ?
C38 C33 Rh2 125.5(6) . . ?
C33 C34 C35 104.9(7) . . ?
C33 C34 C39 134.8(13) . . ?
C35 C34 C39 120.2(13) . . ?
C33 C34 Rh2 70.9(5) . . ?
C35 C34 Rh2 68.9(4) . . ?
C39 C34 Rh2 125.9(6) . . ?
C34 C35 C31 109.9(7) . . ?
C34 C35 C40 132.8(11) . . ?
C31 C35 C40 117.2(11) . . ?
C34 C35 Rh2 72.0(4) . . ?
C31 C35 Rh2 70.3(4) . . ?
C40 C35 Rh2 121.0(6) . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C45 C41 C42 109.7(7) . . ?
C45 C41 C46 123.2(9) . . ?
C42 C41 C46 127.0(9) . . ?
C45 C41 Rh3 72.9(3) . . ?
C42 C41 Rh3 70.8(4) . . ?
C46 C41 Rh3 123.9(5) . . ?
C41 C42 C43 106.4(7) . . ?
C41 C42 C47 124.7(10) . . ?
C43 C42 C47 128.9(10) . . ?
C41 C42 Rh3 70.8(4) . . ?
C43 C42 Rh3 70.7(4) . . ?
C47 C42 Rh3 124.5(6) . . ?
C44 C43 C42 109.1(7) . . ?
C44 C43 C48 124.7(9) . . ?
C42 C43 C48 126.2(9) . . ?
C44 C43 Rh3 71.7(4) . . ?
C42 C43 Rh3 70.5(4) . . ?
C48 C43 Rh3 124.1(6) . . ?
C43 C44 C45 106.8(6) . . ?
C43 C44 C49 128.7(8) . . ?
C45 C44 C49 124.4(8) . . ?
C43 C44 Rh3 70.1(4) . . ?
C45 C44 Rh3 71.5(3) . . ?
C49 C44 Rh3 125.3(5) . . ?
C41 C45 C44 107.9(7) . . ?
C41 C45 C50 128.1(8) . . ?
C44 C45 C50 123.9(7) . . ?
C41 C45 Rh3 69.5(4) . . ?
C44 C45 Rh3 70.1(3) . . ?
C50 C45 Rh3 126.7(5) . . ?
C41 C46 H46A 109.5 . . ?
C41 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C41 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C42 C47 H47A 109.5 . . ?
C42 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C42 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C43 C48 H48A 109.5 . . ?
C43 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C43 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C44 C49 H49A 109.5 . . ?
C44 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C44 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C52 C51 C55 106.7(7) . . ?
C52 C51 C56 129.5(11) . . ?
C55 C51 C56 123.9(11) . . ?
C52 C51 Rh4 69.9(4) . . ?
C55 C51 Rh4 71.0(4) . . ?
C56 C51 Rh4 124.3(6) . . ?
C53 C52 C51 107.1(7) . . ?
C53 C52 C57 129.8(10) . . ?
C51 C52 C57 122.8(10) . . ?
C53 C52 Rh4 72.5(4) . . ?
C51 C52 Rh4 70.3(4) . . ?
C57 C52 Rh4 126.5(6) . . ?
C54 C53 C52 110.6(7) . . ?
C54 C53 C58 125.6(8) . . ?
C52 C53 C58 123.8(8) . . ?
C54 C53 Rh4 71.1(4) . . ?
C52 C53 Rh4 68.9(4) . . ?
C58 C53 Rh4 125.0(5) . . ?
C53 C54 C55 108.7(7) . . ?
C53 C54 C59 126.3(8) . . ?
C55 C54 C59 124.9(7) . . ?
C53 C54 Rh4 71.7(4) . . ?
C55 C54 Rh4 70.4(4) . . ?
C59 C54 Rh4 126.7(5) . . ?
C54 C55 C51 106.8(7) . . ?
C54 C55 C60 126.7(9) . . ?
C51 C55 C60 126.5(10) . . ?
C54 C55 Rh4 70.8(3) . . ?
C51 C55 Rh4 68.9(4) . . ?
C60 C55 Rh4 126.9(5) . . ?
C51 C56 H56A 109.5 . . ?
C51 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C51 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C52 C57 H57A 109.5 . . ?
C52 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C52 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C53 C58 H58A 109.5 . . ?
C53 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C53 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C54 C59 H59A 109.5 . . ?
C54 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C54 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
C62 C61 H61A 109.5 . . ?
C62 C61 H61B 109.5 . . ?
H61A C61 H61B 109.5 . . ?
C62 C61 H61C 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C61 C62 O9 148(2) . . ?
C61 C62 H62A 99.6 . . ?
O9 C62 H62A 99.6 . . ?
C61 C62 H62B 99.6 . . ?
O9 C62 H62B 99.6 . . ?
H62A C62 H62B 104.1 . . ?
O9 C63 C64 124.1(14) . . ?
O9 C63 H63A 106.3 . . ?
C64 C63 H63A 106.3 . . ?
O9 C63 H63B 106.3 . . ?
C64 C63 H63B 106.3 . . ?
H63A C63 H63B 106.4 . . ?
C63 C64 H64A 109.5 . . ?
C63 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C63 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
F1B B1 F3 75.7(18) . . ?
F1B B1 F4 142.1(17) . . ?
F3 B1 F4 93.9(17) . . ?
F1B B1 F2 110.9(17) . . ?
F3 B1 F2 110.9(12) . . ?
F4 B1 F2 106.8(10) . . ?
F1B B1 F1A 66.1(18) . . ?
F3 B1 F1A 129.3(15) . . ?
F4 B1 F1A 96.3(13) . . ?
F2 B1 F1A 113.1(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh2 O1 C1 N1 -179.3(4) . . . . ?
Na1 O1 C1 N1 -48.7(6) . . . . ?
Rh2 O1 C1 N2 1.4(4) . . . . ?
Na1 O1 C1 N2 132.0(4) . . . . ?
Na1 O1 C1 Rh2 130.6(3) . . . . ?
C4 N1 C1 O1 177.3(4) . . . . ?
Rh1 N1 C1 O1 -23.1(7) . . . . ?
C4 N1 C1 N2 -3.4(7) . . . . ?
Rh1 N1 C1 N2 156.1(4) . . . . ?
C2 N2 C1 O1 179.8(4) . . . . ?
Rh2 N2 C1 O1 -1.5(4) . . . . ?
C2 N2 C1 N1 0.5(8) . . . . ?
Rh2 N2 C1 N1 179.2(4) . . . . ?
C2 N2 C1 Rh2 -178.7(6) . . . . ?
C1 N2 C2 O2 -178.2(5) . . . . ?
Rh2 N2 C2 O2 3.9(10) . . . . ?
C1 N2 C2 C3 2.8(7) . . . . ?
Rh2 N2 C2 C3 -175.1(4) . . . . ?
O2 C2 C3 C4 178.1(5) . . . . ?
N2 C2 C3 C4 -2.9(8) . . . . ?
O2 C2 C3 C5 -1.5(9) . . . . ?
N2 C2 C3 C5 177.5(6) . . . . ?
C2 C3 C4 N1 0.1(8) . . . . ?
C5 C3 C4 N1 179.6(6) . . . . ?
C1 N1 C4 C3 3.1(7) . . . . ?
Rh1 N1 C4 C3 -158.1(4) . . . . ?
Rh3 O3 C6 N3 -178.5(5) . . . . ?
Na1 O3 C6 N3 -50.9(7) . . . . ?
Rh3 O3 C6 N4 2.2(4) . . . . ?
Na1 O3 C6 N4 129.9(4) . . . . ?
Na1 O3 C6 Rh3 127.6(4) . . . . ?
C9 N3 C6 O3 174.4(5) . . . . ?
Rh2 N3 C6 O3 -26.0(7) . . . . ?
C9 N3 C6 N4 -6.5(8) . . . . ?
Rh2 N3 C6 N4 153.2(4) . . . . ?
C7 N4 C6 O3 -175.6(5) . . . . ?
Rh3 N4 C6 O3 -2.4(4) . . . . ?
C7 N4 C6 N3 5.2(8) . . . . ?
Rh3 N4 C6 N3 178.4(4) . . . . ?
C7 N4 C6 Rh3 -173.2(6) . . . . ?
C6 N4 C7 O4 -179.6(6) . . . . ?
Rh3 N4 C7 O4 11.6(10) . . . . ?
C6 N4 C7 C8 0.2(8) . . . . ?
Rh3 N4 C7 C8 -168.6(4) . . . . ?
O4 C7 C8 C9 176.1(6) . . . . ?
N4 C7 C8 C9 -3.7(9) . . . . ?
O4 C7 C8 C10 -3.3(10) . . . . ?
N4 C7 C8 C10 176.9(6) . . . . ?
C7 C8 C9 N3 2.4(9) . . . . ?
C10 C8 C9 N3 -178.3(6) . . . . ?
C6 N3 C9 C8 2.6(8) . . . . ?
Rh2 N3 C9 C8 -158.0(5) . . . . ?
Rh4 O5 C11 N5 179.5(5) . . . . ?
Na1 O5 C11 N5 -54.4(6) . . . . ?
Rh4 O5 C11 N6 0.1(4) . . . . ?
Na1 O5 C11 N6 126.2(4) . . . . ?
Na1 O5 C11 Rh4 126.1(3) . . . . ?
C14 N5 C11 O5 179.9(5) . . . . ?
Rh3 N5 C11 O5 -17.2(7) . . . . ?
C14 N5 C11 N6 -0.7(7) . . . . ?
Rh3 N5 C11 N6 162.1(4) . . . . ?
C12 N6 C11 O5 -176.7(4) . . . . ?
Rh4 N6 C11 O5 -0.1(4) . . . . ?
C12 N6 C11 N5 3.8(8) . . . . ?
Rh4 N6 C11 N5 -179.5(4) . . . . ?
C12 N6 C11 Rh4 -176.6(6) . . . . ?
C11 N6 C12 O6 174.0(5) . . . . ?
Rh4 N6 C12 O6 -0.6(10) . . . . ?
C11 N6 C12 C13 -5.2(8) . . . . ?
Rh4 N6 C12 C13 -179.8(4) . . . . ?
O6 C12 C13 C14 -175.4(6) . . . . ?
N6 C12 C13 C14 3.8(8) . . . . ?
O6 C12 C13 C15 2.4(9) . . . . ?
N6 C12 C13 C15 -178.3(6) . . . . ?
C11 N5 C14 C13 -0.5(8) . . . . ?
Rh3 N5 C14 C13 -164.1(5) . . . . ?
C12 C13 C14 N5 -1.1(9) . . . . ?
C15 C13 C14 N5 -178.9(6) . . . . ?
Rh1 O7 C16 N7 -176.7(4) . . . . ?
Na1 O7 C16 N7 -50.8(6) . . . . ?
Rh1 O7 C16 N8 4.0(4) . . . . ?
Na1 O7 C16 N8 129.9(4) . . . . ?
Na1 O7 C16 Rh1 125.9(3) . . . . ?
C19 N7 C16 O7 176.2(4) . . . . ?
Rh4 N7 C16 O7 -25.0(6) . . . . ?
C19 N7 C16 N8 -4.6(7) . . . . ?
Rh4 N7 C16 N8 154.2(4) . . . . ?
C17 N8 C16 O7 -174.4(4) . . . . ?
Rh1 N8 C16 O7 -4.3(4) . . . . ?
C17 N8 C16 N7 6.4(7) . . . . ?
Rh1 N8 C16 N7 176.5(4) . . . . ?
C17 N8 C16 Rh1 -170.1(5) . . . . ?
C16 N8 C17 O8 176.0(5) . . . . ?
Rh1 N8 C17 O8 11.8(9) . . . . ?
C16 N8 C17 C18 -4.0(7) . . . . ?
Rh1 N8 C17 C18 -168.2(4) . . . . ?
O8 C17 C18 C19 -179.1(6) . . . . ?
N8 C17 C18 C19 0.9(8) . . . . ?
O8 C17 C18 C20 0.4(9) . . . . ?
N8 C17 C18 C20 -179.6(5) . . . . ?
C17 C18 C19 N7 0.4(9) . . . . ?
C20 C18 C19 N7 -179.2(6) . . . . ?
C16 N7 C19 C18 1.4(8) . . . . ?
Rh4 N7 C19 C18 -158.0(5) . . . . ?
C25 C21 C22 C23 1.2(6) . . . . ?
C26 C21 C22 C23 -179.3(6) . . . . ?
Rh1 C21 C22 C23 62.0(4) . . . . ?
C25 C21 C22 C27 177.8(6) . . . . ?
C26 C21 C22 C27 -2.7(10) . . . . ?
Rh1 C21 C22 C27 -121.5(6) . . . . ?
C25 C21 C22 Rh1 -60.7(4) . . . . ?
C26 C21 C22 Rh1 118.8(6) . . . . ?
C21 C22 C23 C24 -1.5(6) . . . . ?
C27 C22 C23 C24 -178.1(6) . . . . ?
Rh1 C22 C23 C24 60.6(4) . . . . ?
C21 C22 C23 C28 180.0(6) . . . . ?
C27 C22 C23 C28 3.4(10) . . . . ?
Rh1 C22 C23 C28 -117.9(6) . . . . ?
C21 C22 C23 Rh1 -62.1(4) . . . . ?
C27 C22 C23 Rh1 121.3(6) . . . . ?
C22 C23 C24 C25 1.2(7) . . . . ?
C28 C23 C24 C25 179.6(6) . . . . ?
Rh1 C23 C24 C25 61.2(4) . . . . ?
C22 C23 C24 C29 -179.2(7) . . . . ?
C28 C23 C24 C29 -0.8(11) . . . . ?
Rh1 C23 C24 C29 -119.2(7) . . . . ?
C22 C23 C24 Rh1 -60.0(4) . . . . ?
C28 C23 C24 Rh1 118.4(7) . . . . ?
C22 C21 C25 C24 -0.5(7) . . . . ?
C26 C21 C25 C24 -180.0(6) . . . . ?
Rh1 C21 C25 C24 -60.6(4) . . . . ?
C22 C21 C25 C30 -176.6(6) . . . . ?
C26 C21 C25 C30 3.9(10) . . . . ?
Rh1 C21 C25 C30 123.3(6) . . . . ?
C22 C21 C25 Rh1 60.1(4) . . . . ?
C26 C21 C25 Rh1 -119.4(6) . . . . ?
C23 C24 C25 C21 -0.5(7) . . . . ?
C29 C24 C25 C21 179.9(6) . . . . ?
Rh1 C24 C25 C21 60.5(4) . . . . ?
C23 C24 C25 C30 175.6(6) . . . . ?
C29 C24 C25 C30 -4.0(11) . . . . ?
Rh1 C24 C25 C30 -123.4(7) . . . . ?
C23 C24 C25 Rh1 -61.0(4) . . . . ?
C29 C24 C25 Rh1 119.4(7) . . . . ?
C35 C31 C32 C33 1.0(7) . . . . ?
C36 C31 C32 C33 -176.1(6) . . . . ?
Rh2 C31 C32 C33 62.6(5) . . . . ?
C35 C31 C32 C37 175.7(7) . . . . ?
C36 C31 C32 C37 -1.4(11) . . . . ?
Rh2 C31 C32 C37 -122.7(7) . . . . ?
C35 C31 C32 Rh2 -61.6(4) . . . . ?
C36 C31 C32 Rh2 121.3(7) . . . . ?
C31 C32 C33 C34 -2.3(8) . . . . ?
C37 C32 C33 C34 -177.4(7) . . . . ?
Rh2 C32 C33 C34 59.5(5) . . . . ?
C31 C32 C33 C38 178.6(7) . . . . ?
C37 C32 C33 C38 3.4(12) . . . . ?
Rh2 C32 C33 C38 -119.7(8) . . . . ?
C31 C32 C33 Rh2 -61.7(4) . . . . ?
C37 C32 C33 Rh2 123.1(7) . . . . ?
C32 C33 C34 C35 2.5(8) . . . . ?
C38 C33 C34 C35 -178.3(7) . . . . ?
Rh2 C33 C34 C35 60.9(5) . . . . ?
C32 C33 C34 C39 179.6(9) . . . . ?
C38 C33 C34 C39 -1.2(14) . . . . ?
Rh2 C33 C34 C39 -122.0(10) . . . . ?
C32 C33 C34 Rh2 -58.4(5) . . . . ?
C38 C33 C34 Rh2 120.8(8) . . . . ?
C33 C34 C35 C31 -1.9(8) . . . . ?
C39 C34 C35 C31 -179.5(7) . . . . ?
Rh2 C34 C35 C31 60.4(5) . . . . ?
C33 C34 C35 C40 -178.2(8) . . . . ?
C39 C34 C35 C40 4.2(13) . . . . ?
Rh2 C34 C35 C40 -115.9(8) . . . . ?
C33 C34 C35 Rh2 -62.3(5) . . . . ?
C39 C34 C35 Rh2 120.1(7) . . . . ?
C32 C31 C35 C34 0.6(7) . . . . ?
C36 C31 C35 C34 177.5(7) . . . . ?
Rh2 C31 C35 C34 -61.4(5) . . . . ?
C32 C31 C35 C40 177.5(6) . . . . ?
C36 C31 C35 C40 -5.5(10) . . . . ?
Rh2 C31 C35 C40 115.6(6) . . . . ?
C32 C31 C35 Rh2 61.9(4) . . . . ?
C36 C31 C35 Rh2 -121.1(7) . . . . ?
C45 C41 C42 C43 -0.8(8) . . . . ?
C46 C41 C42 C43 -179.5(6) . . . . ?
Rh3 C41 C42 C43 62.1(5) . . . . ?
C45 C41 C42 C47 177.9(7) . . . . ?
C46 C41 C42 C47 -0.7(12) . . . . ?
Rh3 C41 C42 C47 -119.2(8) . . . . ?
C45 C41 C42 Rh3 -62.9(4) . . . . ?
C46 C41 C42 Rh3 118.5(7) . . . . ?
C41 C42 C43 C44 -0.5(8) . . . . ?
C47 C42 C43 C44 -179.2(8) . . . . ?
Rh3 C42 C43 C44 61.6(5) . . . . ?
C41 C42 C43 C48 179.4(7) . . . . ?
C47 C42 C43 C48 0.7(13) . . . . ?
Rh3 C42 C43 C48 -118.5(8) . . . . ?
C41 C42 C43 Rh3 -62.1(5) . . . . ?
C47 C42 C43 Rh3 119.2(9) . . . . ?
C42 C43 C44 C45 1.6(7) . . . . ?
C48 C43 C44 C45 -178.3(7) . . . . ?
Rh3 C43 C44 C45 62.5(4) . . . . ?
C42 C43 C44 C49 179.3(6) . . . . ?
C48 C43 C44 C49 -0.6(11) . . . . ?
Rh3 C43 C44 C49 -119.9(7) . . . . ?
C42 C43 C44 Rh3 -60.8(5) . . . . ?
C48 C43 C44 Rh3 119.3(8) . . . . ?
C42 C41 C45 C44 1.8(7) . . . . ?
C46 C41 C45 C44 -179.5(6) . . . . ?
Rh3 C41 C45 C44 -59.8(4) . . . . ?
C42 C41 C45 C50 -177.2(6) . . . . ?
C46 C41 C45 C50 1.6(10) . . . . ?
Rh3 C41 C45 C50 121.2(7) . . . . ?
C42 C41 C45 Rh3 61.6(5) . . . . ?
C46 C41 C45 Rh3 -119.7(6) . . . . ?
C43 C44 C45 C41 -2.1(7) . . . . ?
C49 C44 C45 C41 -179.9(6) . . . . ?
Rh3 C44 C45 C41 59.4(4) . . . . ?
C43 C44 C45 C50 176.9(6) . . . . ?
C49 C44 C45 C50 -0.9(9) . . . . ?
Rh3 C44 C45 C50 -121.5(6) . . . . ?
C43 C44 C45 Rh3 -61.5(4) . . . . ?
C49 C44 C45 Rh3 120.7(6) . . . . ?
C55 C51 C52 C53 1.8(7) . . . . ?
C56 C51 C52 C53 -178.0(8) . . . . ?
Rh4 C51 C52 C53 63.6(5) . . . . ?
C55 C51 C52 C57 176.7(7) . . . . ?
C56 C51 C52 C57 -3.1(12) . . . . ?
Rh4 C51 C52 C57 -121.4(7) . . . . ?
C55 C51 C52 Rh4 -61.9(5) . . . . ?
C56 C51 C52 Rh4 118.4(9) . . . . ?
C51 C52 C53 C54 -3.1(8) . . . . ?
C57 C52 C53 C54 -177.6(7) . . . . ?
Rh4 C52 C53 C54 59.0(5) . . . . ?
C51 C52 C53 C58 179.0(6) . . . . ?
C57 C52 C53 C58 4.6(12) . . . . ?
Rh4 C52 C53 C58 -118.8(7) . . . . ?
C51 C52 C53 Rh4 -62.2(5) . . . . ?
C57 C52 C53 Rh4 123.4(8) . . . . ?
C52 C53 C54 C55 3.2(7) . . . . ?
C58 C53 C54 C55 -179.0(6) . . . . ?
Rh4 C53 C54 C55 61.0(4) . . . . ?
C52 C53 C54 C59 179.7(6) . . . . ?
C58 C53 C54 C59 -2.5(11) . . . . ?
Rh4 C53 C54 C59 -122.6(7) . . . . ?
C52 C53 C54 Rh4 -57.7(5) . . . . ?
C58 C53 C54 Rh4 120.1(7) . . . . ?
C53 C54 C55 C51 -2.0(7) . . . . ?
C59 C54 C55 C51 -178.5(6) . . . . ?
Rh4 C54 C55 C51 59.8(4) . . . . ?
C53 C54 C55 C60 176.0(7) . . . . ?
C59 C54 C55 C60 -0.5(11) . . . . ?
Rh4 C54 C55 C60 -122.2(7) . . . . ?
C53 C54 C55 Rh4 -61.8(4) . . . . ?
C59 C54 C55 Rh4 121.7(6) . . . . ?
C52 C51 C55 C54 0.1(7) . . . . ?
C56 C51 C55 C54 179.9(7) . . . . ?
Rh4 C51 C55 C54 -61.0(4) . . . . ?
C52 C51 C55 C60 -177.9(7) . . . . ?
C56 C51 C55 C60 1.9(12) . . . . ?
Rh4 C51 C55 C60 121.0(7) . . . . ?
C52 C51 C55 Rh4 61.1(5) . . . . ?
C56 C51 C55 Rh4 -119.1(8) . . . . ?
C63 O9 C62 C61 -59(6) . . . . ?
C62 O9 C63 C64 -173(2) . . . . ?
Na1 F1B B1 F3 -114(3) . . . . ?
Na1 F1B B1 F4 -36(5) . . . . ?
Na1 F1B B1 F2 139(2) . . . . ?
Na1 F1A B1 F3 30(3) . . . . ?
Na1 F1A B1 F4 130.5(10) . . . . ?
Na1 F1A B1 F2 -118.1(10) . . . . ?

_refine_diff_density_max         1.298
_refine_diff_density_min         -1.218
_refine_diff_density_rms         0.102


# start Validation Reply Form
_vrf_PLAT215_I                   
;
PROBLEM: Disordered F1B       has ADP max/min Ratio .....        7.0       
RESPONSE: In order to dissolve the positional disorder for the F atom 
directly bound to a Na^+^ ion, it should be assumed with more probable 
positions for this atom. However, for the simplicity of calculation we 
set only two possible positions for the disordered F atom, F1A and F1B.  
;
_vrf_PLAT234_I                   
;
PROBLEM: Large Hirshfeld Difference F3     --  B1      ..       0.36 Ang.  
RESPONSE: This is due to the positional disorder of one of the F (F1) 
atom of BF~4~^-^ anion.
;
_vrf_PLAT241_I                   
;
PROBLEM: High      Ueq as Compared to Neighbors for .....         F3 Check 
RESPONSE: This is due to the positional disorder of one of the F (F1) 
atom of BF~4~^-^ anion.
;
_vrf_PLAT242_I                   
;
PROBLEM: Low       Ueq as Compared to Neighbors for .....         B1 Check 
PROBLEM: Low       Ueq as Compared to Neighbors for .....        Na1 Check  
RESPONSE: This is due to the positional disorder of F atoms of BF~4~^-^ anion 
bound directly to the Na1 atom.
;
_vrf_PLAT360_I                   
;
PROBLEM: Short  C(sp3)-C(sp3) Bond  C61    -   C62    ...       1.19 Ang.  
PROBLEM: Short  C(sp3)-C(sp3) Bond  C63    -   C64    ...       1.29 Ang.  
RESPONSE: These carbon atoms are of the solvated diethyl ether molecule, 
and have large thermal ellipsoids.  Therefore, the apparent bond length 
between these atoms would become shorter than the normal. 
;
_vrf_PLAT430_I                   
;
PROBLEM: Short Inter D...A Contact  O2     ..  O12     ..       2.75 Ang.  
RESPONSE: There would be a hydrogen bond between these atoms, although a H 
atom bound to O12 was not introduced in this calculation.  
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4NaNO3
_database_code_depnum_ccdc_archive 'CCDC 1033778'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C60 H76 N9 Na O11 Rh4, 3(C2 H3 N), H2 O'
_chemical_formula_sum            'C66 H87 N12 Na O12 Rh4'
_chemical_formula_weight         1675.10

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, z'
'x, -y+1/2, z+1/2'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, -z'
'-x, y-1/2, -z-1/2'
'x-1/2, y, -z-1/2'

_cell_length_a                   22.6289(7)
_cell_length_b                   21.7265(7)
_cell_length_c                   29.7275(15)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     14615.4(10)
_cell_formula_units_Z            8
_cell_measurement_temperature    186(2)
_cell_measurement_reflns_used    51210
_cell_measurement_theta_min      3.03
_cell_measurement_theta_max      27.50

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.523
_exptl_crystal_F_000             6832
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.400
_exptl_absorpt_coefficient_mu    0.959
_shelx_estimated_absorpt_T_min   0.700
_shelx_estimated_absorpt_T_max   0.700
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.437
_exptl_absorpt_correction_T_max  0.682
_exptl_absorpt_process_details   ABSCOR

_exptl_special_details           ?

_diffrn_ambient_temperature      186(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_source                   ?
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_reflns_number            78632
_diffrn_reflns_av_unetI/netI     0.0332
_diffrn_reflns_av_R_equivalents  0.0426
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_theta_min         3.029
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.964
_diffrn_measured_fraction_theta_full 0.961
_diffrn_reflns_Laue_measured_fraction_max 0.964
_diffrn_reflns_Laue_measured_fraction_full 0.961
_diffrn_reflns_point_group_measured_fraction_max 0.964
_diffrn_reflns_point_group_measured_fraction_full 0.961
_reflns_number_total             16164
_reflns_number_gt                13013
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    SHELXS97
_computing_structure_refinement  SHELXL-2013
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-2013

_refine_special_details          
;
 ?
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0925P)²+11.0826P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         16164
_refine_ls_number_parameters     871
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0578
_refine_ls_R_factor_gt           0.0434
_refine_ls_wR_factor_ref         0.1464
_refine_ls_wR_factor_gt          0.1332
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.34130(2) 0.13700(2) 0.01332(2) 0.02733(9) Uani 1 1 d . . . . .
Rh2 Rh 0.50494(2) 0.31028(2) 0.04855(2) 0.03489(10) Uani 1 1 d . . . . .
Rh3 Rh 0.51564(2) 0.23312(2) 0.22051(2) 0.03244(9) Uani 1 1 d . . . . .
Rh4 Rh 0.35353(2) 0.05828(2) 0.18489(2) 0.03072(9) Uani 1 1 d . . . . .
Na1 Na 0.46479(6) 0.15121(7) 0.10708(6) 0.0335(3) Uani 1 1 d . . . . .
O1 O 0.45269(11) 0.22422(11) 0.04592(10) 0.0319(6) Uani 1 1 d . . . . .
O2 O 0.38546(17) 0.41380(14) 0.01836(13) 0.0572(9) Uani 1 1 d . . . . .
O3 O 0.50867(11) 0.23766(12) 0.14656(10) 0.0331(6) Uani 1 1 d . . . . .
O4 O 0.45447(14) 0.38473(14) 0.24320(11) 0.0471(8) Uani 1 1 d . . . . .
O5 O 0.42755(11) 0.12376(11) 0.18090(10) 0.0313(6) Uani 1 1 d . . . . .
O6 O 0.26854(13) 0.14257(15) 0.26877(13) 0.0493(8) Uani 1 1 d . . . . .
O7 O 0.37180(10) 0.11077(11) 0.08107(9) 0.0295(5) Uani 1 1 d . . . . .
O8 O 0.18655(13) 0.15988(19) 0.04355(12) 0.0559(9) Uani 1 1 d . . . . .
O9A O 0.5046(4) 0.0515(4) 0.0859(5) 0.080(3) Uani 0.5 1 d . . P . .
O9B O 0.5305(8) 0.0622(10) 0.1253(7) 0.186(10) Uani 0.5 1 d . . P . .
O10A O 0.5682(3) 0.1144(4) 0.1097(4) 0.070(3) Uani 0.5 1 d . . P . .
O10B O 0.5503(5) 0.1085(6) 0.0699(6) 0.122(5) Uani 0.5 1 d . . P . .
O11 O 0.5988(5) 0.0302(5) 0.1055(3) 0.249(7) Uani 1 1 d . . . . .
O12 O 0.3631(3) 0.5210(2) 0.0667(2) 0.0972(16) Uani 1 1 d . . . . .
N1 N 0.35248(13) 0.22985(14) 0.03051(12) 0.0321(7) Uani 1 1 d . . . . .
N2 N 0.41693(15) 0.31544(14) 0.02984(13) 0.0378(8) Uani 1 1 d . . . . .
N3 N 0.47257(14) 0.32691(14) 0.11347(12) 0.0330(7) Uani 1 1 d . . . . .
N4 N 0.48531(13) 0.31417(14) 0.19172(12) 0.0318(7) Uani 1 1 d . . . . .
N5 N 0.42623(13) 0.21126(15) 0.22525(12) 0.0336(7) Uani 1 1 d . . . . .
N6 N 0.35179(13) 0.13471(15) 0.22627(12) 0.0317(7) Uani 1 1 d . . . . .
N7 N 0.30508(13) 0.11245(14) 0.13997(12) 0.0308(7) Uani 1 1 d . . . . .
N8 N 0.27996(13) 0.13475(14) 0.06518(12) 0.0304(7) Uani 1 1 d . . . . .
N9 N 0.5596(3) 0.0645(3) 0.10019(19) 0.0743(16) Uani 1 1 d . . . . .
N13B N 0.7725(16) 0.5655(15) 0.1366(15) 0.292(19) Uiso 0.5 1 d D . P . .
N11 N 0.2094(6) 0.3117(5) 0.1522(7) 0.278(10) Uani 1 1 d . . . . .
N12 N 0.2342(4) -0.0720(4) 0.3484(3) 0.111(3) Uani 1 1 d . . . . .
N13A N 0.6384(10) 0.6392(10) 0.1164(9) 0.174(9) Uiso 0.5 1 d D . P . .
C1 C 0.40579(17) 0.25530(16) 0.03557(14) 0.0310(8) Uani 1 1 d . . . . .
C2 C 0.3733(2) 0.35826(18) 0.02209(16) 0.0412(10) Uani 1 1 d . . . . .
C3 C 0.3139(2) 0.3327(2) 0.01898(16) 0.0428(10) Uani 1 1 d . . . . .
C4 C 0.30700(18) 0.27122(18) 0.02257(15) 0.0377(9) Uani 1 1 d . . . . .
H4 H 0.2682 0.2551 0.0194 0.045 Uiso 1 1 calc R U . . .
C5 C 0.2627(2) 0.3757(2) 0.0120(2) 0.0602(15) Uani 1 1 d . . . . .
H5A H 0.2353 0.3722 0.0374 0.072 Uiso 1 1 calc R U . . .
H5B H 0.2422 0.3649 -0.0160 0.072 Uiso 1 1 calc R U . . .
H5C H 0.2772 0.4181 0.0100 0.072 Uiso 1 1 calc R U . . .
C6 C 0.48857(15) 0.29366(17) 0.14916(14) 0.0303(8) Uani 1 1 d . . . . .
C7 C 0.46086(17) 0.36962(18) 0.20322(17) 0.0377(9) Uani 1 1 d . . . . .
C8 C 0.44325(17) 0.40695(18) 0.16515(16) 0.0379(9) Uani 1 1 d . . . . .
C9 C 0.44980(17) 0.38434(17) 0.12335(15) 0.0361(9) Uani 1 1 d . . . . .
H9 H 0.4379 0.4096 0.0989 0.043 Uiso 1 1 calc R U . . .
C10 C 0.4173(2) 0.4702(2) 0.1735(2) 0.0590(14) Uani 1 1 d . . . . .
H10A H 0.3771 0.4718 0.1613 0.071 Uiso 1 1 calc R U . . .
H10B H 0.4418 0.5013 0.1586 0.071 Uiso 1 1 calc R U . . .
H10C H 0.4163 0.4783 0.2059 0.071 Uiso 1 1 calc R U . . .
C11 C 0.40322(16) 0.15825(17) 0.21053(14) 0.0307(8) Uani 1 1 d . . . . .
C12 C 0.31605(17) 0.16511(19) 0.25644(15) 0.0370(9) Uani 1 1 d . . . . .
C13 C 0.33924(19) 0.2235(2) 0.27200(17) 0.0417(10) Uani 1 1 d . . . . .
C14 C 0.39218(18) 0.2436(2) 0.25558(16) 0.0392(9) Uani 1 1 d . . . . .
H14 H 0.4065 0.2823 0.2657 0.047 Uiso 1 1 calc R U . . .
C15 C 0.3033(2) 0.2617(3) 0.3041(2) 0.0679(17) Uani 1 1 d . . . . .
H15A H 0.2928 0.3009 0.2898 0.082 Uiso 1 1 calc R U . . .
H15B H 0.3264 0.2697 0.3314 0.082 Uiso 1 1 calc R U . . .
H15C H 0.2671 0.2394 0.3121 0.082 Uiso 1 1 calc R U . . .
C16 C 0.31901(15) 0.11898(15) 0.09698(13) 0.0272(7) Uani 1 1 d . . . . .
C17 C 0.22170(17) 0.1473(2) 0.07413(15) 0.0375(9) Uani 1 1 d . . . . .
C18 C 0.20578(16) 0.1439(2) 0.12096(16) 0.0380(9) Uani 1 1 d . . . . .
C19 C 0.24727(16) 0.12680(19) 0.15158(15) 0.0346(8) Uani 1 1 d . . . . .
H19 H 0.2362 0.1246 0.1824 0.042 Uiso 1 1 calc R U . . .
C20 C 0.14353(19) 0.1577(3) 0.13470(18) 0.0566(14) Uani 1 1 d . . . . .
H20A H 0.1359 0.2019 0.1312 0.068 Uiso 1 1 calc R U . . .
H20B H 0.1378 0.1460 0.1662 0.068 Uiso 1 1 calc R U . . .
H20C H 0.1161 0.1344 0.1157 0.068 Uiso 1 1 calc R U . . .
C21 C 0.29863(17) 0.08050(19) -0.03653(14) 0.0363(9) Uani 1 1 d . . . . .
C22 C 0.31152(18) 0.14156(19) -0.05387(14) 0.0352(8) Uani 1 1 d . . . . .
C23 C 0.37486(18) 0.14861(19) -0.05399(15) 0.0371(9) Uani 1 1 d . . . . .
C24 C 0.40000(17) 0.09574(19) -0.03497(15) 0.0378(9) Uani 1 1 d . . . . .
C25 C 0.35308(18) 0.05294(19) -0.02358(16) 0.0388(9) Uani 1 1 d . . . . .
C26 C 0.2386(2) 0.0534(2) -0.03172(18) 0.0504(12) Uani 1 1 d . . . . .
H26A H 0.2307 0.0451 0.0001 0.060 Uiso 1 1 calc R U . . .
H26B H 0.2365 0.0148 -0.0487 0.060 Uiso 1 1 calc R U . . .
H26C H 0.2091 0.0823 -0.0434 0.060 Uiso 1 1 calc R U . . .
C27 C 0.2669(2) 0.1855(2) -0.07157(17) 0.0498(11) Uani 1 1 d . . . . .
H27A H 0.2599 0.1771 -0.1035 0.060 Uiso 1 1 calc R U . . .
H27B H 0.2814 0.2277 -0.0680 0.060 Uiso 1 1 calc R U . . .
H27C H 0.2298 0.1806 -0.0549 0.060 Uiso 1 1 calc R U . . .
C28 C 0.4072(2) 0.2037(2) -0.07088(19) 0.0551(13) Uani 1 1 d . . . . .
H28A H 0.4344 0.1914 -0.0949 0.066 Uiso 1 1 calc R U . . .
H28B H 0.4296 0.2223 -0.0462 0.066 Uiso 1 1 calc R U . . .
H28C H 0.3788 0.2337 -0.0827 0.066 Uiso 1 1 calc R U . . .
C29 C 0.4649(2) 0.0839(3) -0.0270(2) 0.0589(14) Uani 1 1 d . . . . .
H29A H 0.4808 0.1157 -0.0070 0.071 Uiso 1 1 calc R U . . .
H29B H 0.4860 0.0850 -0.0558 0.071 Uiso 1 1 calc R U . . .
H29C H 0.4699 0.0434 -0.0131 0.071 Uiso 1 1 calc R U . . .
C30 C 0.3610(2) -0.0099(2) -0.00460(19) 0.0528(12) Uani 1 1 d . . . . .
H30A H 0.3957 -0.0105 0.0150 0.063 Uiso 1 1 calc R U . . .
H30B H 0.3665 -0.0394 -0.0292 0.063 Uiso 1 1 calc R U . . .
H30C H 0.3258 -0.0212 0.0128 0.063 Uiso 1 1 calc R U . . .
C31 C 0.5479(2) 0.3545(2) -0.00713(19) 0.0553(13) Uani 1 1 d . . . . .
C32 C 0.5587(2) 0.3869(2) 0.03437(19) 0.0517(12) Uani 1 1 d . . . . .
C33 C 0.59132(19) 0.3467(2) 0.06355(17) 0.0449(11) Uani 1 1 d . . . . .
C34 C 0.59766(19) 0.2889(2) 0.04106(19) 0.0478(12) Uani 1 1 d . . . . .
C35 C 0.5709(2) 0.2943(2) -0.00224(19) 0.0516(13) Uani 1 1 d . . . . .
C36 C 0.5148(3) 0.3807(3) -0.0462(2) 0.0753(18) Uani 1 1 d . . . . .
H36A H 0.4818 0.4057 -0.0352 0.090 Uiso 1 1 calc R U . . .
H36B H 0.4996 0.3471 -0.0649 0.090 Uiso 1 1 calc R U . . .
H36C H 0.5414 0.4065 -0.0642 0.090 Uiso 1 1 calc R U . . .
C37 C 0.5428(3) 0.4531(2) 0.0436(2) 0.0648(16) Uani 1 1 d . . . . .
H37A H 0.5466 0.4614 0.0759 0.078 Uiso 1 1 calc R U . . .
H37B H 0.5020 0.4608 0.0341 0.078 Uiso 1 1 calc R U . . .
H37C H 0.5696 0.4802 0.0269 0.078 Uiso 1 1 calc R U . . .
C38 C 0.6120(2) 0.3620(2) 0.1100(2) 0.0569(14) Uani 1 1 d . . . . .
H38A H 0.6549 0.3567 0.1117 0.068 Uiso 1 1 calc R U . . .
H38B H 0.5928 0.3345 0.1316 0.068 Uiso 1 1 calc R U . . .
H38C H 0.6018 0.4047 0.1170 0.068 Uiso 1 1 calc R U . . .
C39 C 0.6268(2) 0.2330(2) 0.0580(3) 0.0667(17) Uani 1 1 d . . . . .
H39A H 0.6598 0.2221 0.0382 0.080 Uiso 1 1 calc R U . . .
H39B H 0.5983 0.1990 0.0587 0.080 Uiso 1 1 calc R U . . .
H39C H 0.6417 0.2405 0.0885 0.080 Uiso 1 1 calc R U . . .
C40 C 0.5709(2) 0.2446(3) -0.0370(2) 0.0644(16) Uani 1 1 d . . . . .
H40A H 0.6097 0.2429 -0.0516 0.077 Uiso 1 1 calc R U . . .
H40B H 0.5405 0.2534 -0.0596 0.077 Uiso 1 1 calc R U . . .
H40C H 0.5624 0.2050 -0.0226 0.077 Uiso 1 1 calc R U . . .
C41 C 0.5946(2) 0.2644(2) 0.2535(2) 0.0516(13) Uani 1 1 d . . . . .
C42 C 0.5502(2) 0.2454(3) 0.28547(19) 0.0560(13) Uani 1 1 d . . . . .
C43 C 0.5395(2) 0.1803(2) 0.27927(18) 0.0498(12) Uani 1 1 d . . . . .
C44 C 0.57474(19) 0.1608(2) 0.24262(18) 0.0442(11) Uani 1 1 d . . . . .
C45 C 0.60865(17) 0.2132(2) 0.22685(19) 0.0455(11) Uani 1 1 d . . . . .
C46 C 0.6197(3) 0.3286(2) 0.2487(3) 0.079(2) Uani 1 1 d . . . . .
H46A H 0.6098 0.3449 0.2189 0.095 Uiso 1 1 calc R U . . .
H46B H 0.6627 0.3271 0.2522 0.095 Uiso 1 1 calc R U . . .
H46C H 0.6028 0.3554 0.2719 0.095 Uiso 1 1 calc R U . . .
C47 C 0.5240(3) 0.2847(4) 0.3227(2) 0.093(3) Uani 1 1 d . . . . .
H47A H 0.5361 0.2684 0.3520 0.111 Uiso 1 1 calc R U . . .
H47B H 0.4808 0.2840 0.3205 0.111 Uiso 1 1 calc R U . . .
H47C H 0.5381 0.3272 0.3196 0.111 Uiso 1 1 calc R U . . .
C48 C 0.4980(3) 0.1421(3) 0.3056(2) 0.0723(18) Uani 1 1 d . . . . .
H48A H 0.5195 0.1078 0.3195 0.087 Uiso 1 1 calc R U . . .
H48B H 0.4672 0.1258 0.2857 0.087 Uiso 1 1 calc R U . . .
H48C H 0.4796 0.1672 0.3291 0.087 Uiso 1 1 calc R U . . .
C49 C 0.5808(2) 0.0972(2) 0.2244(2) 0.0680(17) Uani 1 1 d . . . . .
H49A H 0.5421 0.0822 0.2146 0.082 Uiso 1 1 calc R U . . .
H49B H 0.5964 0.0700 0.2479 0.082 Uiso 1 1 calc R U . . .
H49C H 0.6081 0.0975 0.1988 0.082 Uiso 1 1 calc R U . . .
C50 C 0.6504(2) 0.2100(3) 0.1886(2) 0.0678(17) Uani 1 1 d . . . . .
H50A H 0.6872 0.1904 0.1984 0.081 Uiso 1 1 calc R U . . .
H50B H 0.6589 0.2517 0.1778 0.081 Uiso 1 1 calc R U . . .
H50C H 0.6328 0.1859 0.1642 0.081 Uiso 1 1 calc R U . . .
C51 C 0.3568(3) -0.0138(2) 0.2330(2) 0.0562(13) Uani 1 1 d . . . . .
C52 C 0.3013(2) -0.0142(2) 0.21119(18) 0.0506(12) Uani 1 1 d . . . . .
C53 C 0.3108(2) -0.02627(19) 0.1655(2) 0.0495(12) Uani 1 1 d . . . . .
C54 C 0.3727(2) -0.03131(19) 0.1571(2) 0.0515(12) Uani 1 1 d . . . . .
C55 C 0.4011(2) -0.0233(2) 0.2004(2) 0.0617(17) Uani 1 1 d . . . . .
C56 C 0.3626(4) -0.0027(3) 0.2832(3) 0.101(3) Uani 1 1 d . . . . .
H56A H 0.3407 -0.0346 0.2995 0.121 Uiso 1 1 calc R U . . .
H56B H 0.3464 0.0378 0.2907 0.121 Uiso 1 1 calc R U . . .
H56C H 0.4044 -0.0043 0.2917 0.121 Uiso 1 1 calc R U . . .
C57 C 0.2417(3) -0.0061(3) 0.2323(3) 0.086(2) Uani 1 1 d . . . . .
H57A H 0.2183 -0.0437 0.2281 0.103 Uiso 1 1 calc R U . . .
H57B H 0.2213 0.0286 0.2181 0.103 Uiso 1 1 calc R U . . .
H57C H 0.2463 0.0019 0.2645 0.103 Uiso 1 1 calc R U . . .
C58 C 0.2653(3) -0.0307(3) 0.1288(3) 0.083(2) Uani 1 1 d . . . . .
H58A H 0.2440 0.0085 0.1264 0.100 Uiso 1 1 calc R U . . .
H58B H 0.2373 -0.0637 0.1358 0.100 Uiso 1 1 calc R U . . .
H58C H 0.2849 -0.0397 0.1001 0.100 Uiso 1 1 calc R U . . .
C59 C 0.4016(4) -0.0459(3) 0.1141(3) 0.096(3) Uani 1 1 d . . . . .
H59A H 0.3914 -0.0144 0.0918 0.115 Uiso 1 1 calc R U . . .
H59B H 0.3881 -0.0862 0.1035 0.115 Uiso 1 1 calc R U . . .
H59C H 0.4445 -0.0467 0.1183 0.115 Uiso 1 1 calc R U . . .
C60 C 0.4660(3) -0.0224(3) 0.2087(3) 0.103(3) Uani 1 1 d . . . . .
H60A H 0.4763 -0.0543 0.2307 0.124 Uiso 1 1 calc R U . . .
H60B H 0.4776 0.0180 0.2204 0.124 Uiso 1 1 calc R U . . .
H60C H 0.4870 -0.0304 0.1804 0.124 Uiso 1 1 calc R U . . .
C95B C 0.7528(12) 0.6094(16) 0.1235(15) 0.206(19) Uiso 0.5 1 d D . P . .
C96B C 0.6891(9) 0.6245(9) 0.1156(8) 0.105(5) Uiso 0.5 1 d D . P . .
C91 C 0.2591(6) 0.2974(4) 0.1504(5) 0.170(7) Uani 1 1 d . . . . .
C92 C 0.3181(3) 0.2795(3) 0.1452(2) 0.0741(17) Uani 1 1 d . . . . .
H92A H 0.3382 0.3085 0.1250 0.089 Uiso 1 1 calc R U . . .
H92B H 0.3197 0.2381 0.1323 0.089 Uiso 1 1 calc R U . . .
H92C H 0.3378 0.2796 0.1745 0.089 Uiso 1 1 calc R U . . .
C93 C 0.1869(5) -0.0712(4) 0.3381(3) 0.096(3) Uani 1 1 d . . . . .
C94 C 0.1241(4) -0.0697(5) 0.3259(4) 0.128(4) Uani 1 1 d . . . . .
H94A H 0.1045 -0.0363 0.3422 0.153 Uiso 1 1 calc R U . . .
H94B H 0.1057 -0.1091 0.3339 0.153 Uiso 1 1 calc R U . . .
H94C H 0.1202 -0.0629 0.2935 0.153 Uiso 1 1 calc R U . . .
C95A C 0.6702(15) 0.601(2) 0.118(3) 0.44(6) Uiso 0.5 1 d D . P . .
C96A C 0.7350(9) 0.5908(10) 0.1278(7) 0.098(5) Uiso 0.5 1 d D . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N8 2.075(3) . ?
Rh1 N1 2.096(3) . ?
Rh1 C22 2.110(4) . ?
Rh1 C25 2.147(4) . ?
Rh1 C24 2.151(4) . ?
Rh1 C21 2.153(4) . ?
Rh1 C23 2.155(4) . ?
Rh1 O7 2.204(3) . ?
Rh1 C16 2.568(4) . ?
Rh2 N2 2.071(4) . ?
Rh2 N3 2.096(3) . ?
Rh2 C32 2.104(4) . ?
Rh2 C31 2.147(5) . ?
Rh2 C35 2.151(4) . ?
Rh2 C33 2.156(4) . ?
Rh2 C34 2.160(4) . ?
Rh2 O1 2.214(2) . ?
Rh2 C1 2.571(4) . ?
Rh3 N4 2.075(3) . ?
Rh3 N5 2.083(3) . ?
Rh3 C42 2.101(5) . ?
Rh3 C41 2.149(4) . ?
Rh3 C45 2.157(4) . ?
Rh3 C43 2.159(5) . ?
Rh3 C44 2.166(4) . ?
Rh3 O3 2.206(3) . ?
Rh3 C6 2.570(4) . ?
Rh4 N6 2.067(3) . ?
Rh4 N7 2.091(3) . ?
Rh4 C52 2.119(4) . ?
Rh4 C51 2.122(5) . ?
Rh4 C55 2.126(4) . ?
Rh4 C53 2.155(4) . ?
Rh4 C54 2.158(4) . ?
Rh4 O5 2.201(2) . ?
Rh4 C11 2.562(4) . ?
Na1 O7 2.408(3) . ?
Na1 O10B 2.415(10) . ?
Na1 O5 2.425(3) . ?
Na1 O3 2.427(3) . ?
Na1 O1 2.428(3) . ?
Na1 O9A 2.430(7) . ?
Na1 O10A 2.475(8) . ?
Na1 O9B 2.499(12) . ?
Na1 N9 2.861(5) . ?
O1 C1 1.295(4) . ?
O2 C2 1.243(5) . ?
O3 C6 1.301(4) . ?
O4 C7 1.242(6) . ?
O5 C11 1.281(5) . ?
O6 C12 1.237(5) . ?
O7 C16 1.297(4) . ?
O8 C17 1.239(5) . ?
O9A N9 1.344(11) . ?
O9B N9 0.996(14) . ?
O10A N9 1.137(9) . ?
O10B N9 1.330(13) . ?
O11 N9 1.170(7) . ?
N1 C1 1.336(5) . ?
N1 C4 1.387(5) . ?
N2 C1 1.342(5) . ?
N2 C2 1.376(5) . ?
N3 C6 1.334(5) . ?
N3 C9 1.382(5) . ?
N4 C6 1.343(5) . ?
N4 C7 1.369(5) . ?
N5 C11 1.338(5) . ?
N5 C14 1.378(6) . ?
N6 C11 1.354(5) . ?
N6 C12 1.377(5) . ?
N7 C16 1.324(5) . ?
N7 C19 1.388(5) . ?
N8 C16 1.339(5) . ?
N8 C17 1.372(5) . ?
N13B C96A 1.04(3) . ?
N11 C91 1.167(16) . ?
N12 C93 1.113(10) . ?
N13A C96B 1.19(3) . ?
C2 C3 1.456(7) . ?
C3 C4 1.349(6) . ?
C3 C5 1.504(6) . ?
C4 H4 0.9500 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C7 C8 1.448(7) . ?
C8 C9 1.344(6) . ?
C8 C10 1.514(6) . ?
C9 H9 0.9500 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C12 C13 1.449(6) . ?
C13 C14 1.365(6) . ?
C13 C15 1.504(7) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C17 C18 1.440(6) . ?
C18 C19 1.359(6) . ?
C18 C20 1.497(5) . ?
C19 H19 0.9500 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C25 1.423(6) . ?
C21 C22 1.453(6) . ?
C21 C26 1.487(6) . ?
C22 C23 1.442(6) . ?
C22 C27 1.486(6) . ?
C23 C24 1.401(6) . ?
C23 C28 1.491(6) . ?
C24 C25 1.451(6) . ?
C24 C29 1.509(6) . ?
C25 C30 1.488(6) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C35 1.415(7) . ?
C31 C32 1.441(8) . ?
C31 C36 1.495(9) . ?
C32 C33 1.436(8) . ?
C32 C37 1.507(7) . ?
C33 C34 1.430(7) . ?
C33 C38 1.494(8) . ?
C34 C35 1.427(8) . ?
C34 C39 1.472(7) . ?
C35 C40 1.495(7) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C45 1.403(7) . ?
C41 C42 1.443(8) . ?
C41 C46 1.512(7) . ?
C42 C43 1.447(7) . ?
C42 C47 1.518(9) . ?
C43 C44 1.414(7) . ?
C43 C48 1.479(8) . ?
C44 C45 1.452(6) . ?
C44 C49 1.491(7) . ?
C45 C50 1.482(8) . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9800 . ?
C50 H50B 0.9800 . ?
C50 H50C 0.9800 . ?
C51 C55 1.410(9) . ?
C51 C52 1.415(8) . ?
C51 C56 1.515(10) . ?
C52 C53 1.400(8) . ?
C52 C57 1.498(8) . ?
C53 C54 1.427(7) . ?
C53 C58 1.504(8) . ?
C54 C55 1.449(8) . ?
C54 C59 1.471(9) . ?
C55 C60 1.489(7) . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C57 H57A 0.9800 . ?
C57 H57B 0.9800 . ?
C57 H57C 0.9800 . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C95B C96A 0.58(4) . ?
C95B C96B 1.498(18) . ?
C95B C95A 1.88(4) . ?
C96B C95A 0.67(6) . ?
C96B C96A 1.32(2) . ?
C91 C92 1.401(13) . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C93 C94 1.467(13) . ?
C94 H94A 0.9800 . ?
C94 H94B 0.9800 . ?
C94 H94C 0.9800 . ?
C95A C96A 1.510(19) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Rh1 N1 85.54(13) . . ?
N8 Rh1 C22 119.38(14) . . ?
N1 Rh1 C22 102.95(15) . . ?
N8 Rh1 C25 116.27(15) . . ?
N1 Rh1 C25 158.15(15) . . ?
C22 Rh1 C25 66.17(17) . . ?
N8 Rh1 C24 154.01(15) . . ?
N1 Rh1 C24 119.29(14) . . ?
C22 Rh1 C24 65.49(16) . . ?
C25 Rh1 C24 39.47(16) . . ?
N8 Rh1 C21 101.41(14) . . ?
N1 Rh1 C21 140.41(15) . . ?
C22 Rh1 C21 39.83(16) . . ?
C25 Rh1 C21 38.65(16) . . ?
C24 Rh1 C21 65.17(15) . . ?
N8 Rh1 C23 158.17(15) . . ?
N1 Rh1 C23 94.09(14) . . ?
C22 Rh1 C23 39.49(16) . . ?
C25 Rh1 C23 65.26(16) . . ?
C24 Rh1 C23 37.97(17) . . ?
C21 Rh1 C23 65.53(15) . . ?
N8 Rh1 O7 61.61(11) . . ?
N1 Rh1 O7 89.32(12) . . ?
C22 Rh1 O7 167.70(13) . . ?
C25 Rh1 O7 102.01(14) . . ?
C24 Rh1 O7 107.98(14) . . ?
C21 Rh1 O7 128.46(14) . . ?
C23 Rh1 O7 140.21(13) . . ?
N8 Rh1 C16 31.28(12) . . ?
N1 Rh1 C16 86.23(12) . . ?
C22 Rh1 C16 149.44(13) . . ?
C25 Rh1 C16 112.92(15) . . ?
C24 Rh1 C16 134.75(14) . . ?
C21 Rh1 C16 119.44(14) . . ?
C23 Rh1 C16 170.55(14) . . ?
O7 Rh1 C16 30.34(10) . . ?
N2 Rh2 N3 84.37(14) . . ?
N2 Rh2 C32 117.31(18) . . ?
N3 Rh2 C32 104.47(17) . . ?
N2 Rh2 C31 101.8(2) . . ?
N3 Rh2 C31 142.28(16) . . ?
C32 Rh2 C31 39.6(2) . . ?
N2 Rh2 C35 119.19(19) . . ?
N3 Rh2 C35 156.43(18) . . ?
C32 Rh2 C35 65.53(18) . . ?
C31 Rh2 C35 38.4(2) . . ?
N2 Rh2 C33 155.19(16) . . ?
N3 Rh2 C33 93.62(16) . . ?
C32 Rh2 C33 39.4(2) . . ?
C31 Rh2 C33 65.4(2) . . ?
C35 Rh2 C33 64.85(19) . . ?
N2 Rh2 C34 156.63(19) . . ?
N3 Rh2 C34 118.13(18) . . ?
C32 Rh2 C34 65.67(19) . . ?
C31 Rh2 C34 65.0(2) . . ?
C35 Rh2 C34 38.7(2) . . ?
C33 Rh2 C34 38.69(18) . . ?
N2 Rh2 O1 61.48(11) . . ?
N3 Rh2 O1 89.51(11) . . ?
C32 Rh2 O1 165.90(17) . . ?
C31 Rh2 O1 126.36(16) . . ?
C35 Rh2 O1 102.13(14) . . ?
C33 Rh2 O1 143.32(15) . . ?
C34 Rh2 O1 109.51(14) . . ?
N2 Rh2 C1 31.30(12) . . ?
N3 Rh2 C1 85.03(13) . . ?
C32 Rh2 C1 147.32(18) . . ?
C31 Rh2 C1 119.17(18) . . ?
C35 Rh2 C1 115.19(16) . . ?
C33 Rh2 C1 173.26(16) . . ?
C34 Rh2 C1 137.09(15) . . ?
O1 Rh2 C1 30.24(10) . . ?
N4 Rh3 N5 84.27(12) . . ?
N4 Rh3 C42 113.23(17) . . ?
N5 Rh3 C42 109.16(19) . . ?
N4 Rh3 C41 101.22(16) . . ?
N5 Rh3 C41 148.1(2) . . ?
C42 Rh3 C41 39.7(2) . . ?
N4 Rh3 C45 121.92(15) . . ?
N5 Rh3 C45 153.67(16) . . ?
C42 Rh3 C45 65.3(2) . . ?
C41 Rh3 C45 38.03(19) . . ?
N4 Rh3 C43 150.21(17) . . ?
N5 Rh3 C43 93.86(16) . . ?
C42 Rh3 C43 39.7(2) . . ?
C41 Rh3 C43 65.8(2) . . ?
C45 Rh3 C43 65.06(19) . . ?
N4 Rh3 C44 160.97(15) . . ?
N5 Rh3 C44 114.45(15) . . ?
C42 Rh3 C44 65.37(19) . . ?
C41 Rh3 C44 65.03(17) . . ?
C45 Rh3 C44 39.24(17) . . ?
C43 Rh3 C44 38.18(19) . . ?
N4 Rh3 O3 61.80(12) . . ?
N5 Rh3 O3 90.47(12) . . ?
C42 Rh3 O3 159.56(18) . . ?
C41 Rh3 O3 120.03(18) . . ?
C45 Rh3 O3 99.54(16) . . ?
C43 Rh3 O3 147.98(16) . . ?
C44 Rh3 O3 112.28(16) . . ?
N4 Rh3 C6 31.38(13) . . ?
N5 Rh3 C6 86.62(12) . . ?
C42 Rh3 C6 141.49(17) . . ?
C41 Rh3 C6 114.40(17) . . ?
C45 Rh3 C6 114.04(16) . . ?
C43 Rh3 C6 178.38(17) . . ?
C44 Rh3 C6 140.28(16) . . ?
O3 Rh3 C6 30.42(11) . . ?
N6 Rh4 N7 85.29(13) . . ?
N6 Rh4 C52 111.53(17) . . ?
N7 Rh4 C52 111.20(17) . . ?
N6 Rh4 C51 101.05(19) . . ?
N7 Rh4 C51 149.82(18) . . ?
C52 Rh4 C51 39.0(2) . . ?
N6 Rh4 C55 123.4(2) . . ?
N7 Rh4 C55 151.0(2) . . ?
C52 Rh4 C55 65.3(2) . . ?
C51 Rh4 C55 38.8(2) . . ?
N6 Rh4 C53 146.68(17) . . ?
N7 Rh4 C53 94.23(16) . . ?
C52 Rh4 C53 38.2(2) . . ?
C51 Rh4 C53 64.4(2) . . ?
C55 Rh4 C53 64.81(19) . . ?
N6 Rh4 C54 162.92(18) . . ?
N7 Rh4 C54 111.67(18) . . ?
C52 Rh4 C54 65.3(2) . . ?
C51 Rh4 C54 65.5(2) . . ?
C55 Rh4 C54 39.5(2) . . ?
C53 Rh4 C54 38.65(19) . . ?
N6 Rh4 O5 61.78(11) . . ?
N7 Rh4 O5 90.05(11) . . ?
C52 Rh4 O5 157.67(17) . . ?
C51 Rh4 O5 119.10(17) . . ?
C55 Rh4 O5 99.52(15) . . ?
C53 Rh4 O5 151.45(16) . . ?
C54 Rh4 O5 114.17(15) . . ?
N6 Rh4 C11 31.80(12) . . ?
N7 Rh4 C11 86.73(12) . . ?
C52 Rh4 C11 139.93(18) . . ?
C51 Rh4 C11 114.15(17) . . ?
C55 Rh4 C11 114.84(16) . . ?
C53 Rh4 C11 178.16(18) . . ?
C54 Rh4 C11 142.20(16) . . ?
O5 Rh4 C11 29.99(11) . . ?
O7 Na1 O10B 114.4(5) . . ?
O7 Na1 O5 84.10(10) . . ?
O10B Na1 O5 126.8(3) . . ?
O7 Na1 O3 142.67(10) . . ?
O10B Na1 O3 101.0(4) . . ?
O5 Na1 O3 83.97(11) . . ?
O7 Na1 O1 84.22(10) . . ?
O10B Na1 O1 89.9(3) . . ?
O5 Na1 O1 143.03(11) . . ?
O3 Na1 O1 84.42(10) . . ?
O7 Na1 O9A 85.2(2) . . ?
O5 Na1 O9A 98.3(3) . . ?
O3 Na1 O9A 131.6(2) . . ?
O1 Na1 O9A 115.5(3) . . ?
O7 Na1 O10A 136.0(2) . . ?
O5 Na1 O10A 102.8(3) . . ?
O3 Na1 O10A 81.2(2) . . ?
O1 Na1 O10A 109.9(3) . . ?
O9A Na1 O10A 50.9(3) . . ?
O7 Na1 O9B 107.9(6) . . ?
O10B Na1 O9B 47.5(4) . . ?
O5 Na1 O9B 79.7(4) . . ?
O3 Na1 O9B 104.5(7) . . ?
O1 Na1 O9B 137.3(4) . . ?
O7 Na1 N9 113.07(17) . . ?
O10B Na1 N9 27.6(3) . . ?
O5 Na1 N9 99.41(15) . . ?
O3 Na1 N9 103.72(16) . . ?
O1 Na1 N9 117.44(16) . . ?
O9A Na1 N9 27.9(2) . . ?
O10A Na1 N9 23.2(2) . . ?
O9B Na1 N9 20.0(3) . . ?
C1 O1 Rh2 90.3(2) . . ?
C1 O1 Na1 127.7(2) . . ?
Rh2 O1 Na1 117.71(13) . . ?
C6 O3 Rh3 90.4(2) . . ?
C6 O3 Na1 127.5(2) . . ?
Rh3 O3 Na1 118.46(12) . . ?
C11 O5 Rh4 90.8(2) . . ?
C11 O5 Na1 128.9(2) . . ?
Rh4 O5 Na1 118.17(12) . . ?
C16 O7 Rh1 90.5(2) . . ?
C16 O7 Na1 129.6(2) . . ?
Rh1 O7 Na1 118.22(12) . . ?
N9 O9A Na1 94.2(4) . . ?
N9 O9B O11 37.3(6) . . ?
N9 O9B Na1 101.0(9) . . ?
O11 O9B Na1 137.9(8) . . ?
N9 O10A Na1 97.8(5) . . ?
N9 O11 O9B 31.1(6) . . ?
C1 N1 C4 114.9(3) . . ?
C1 N1 Rh1 122.3(2) . . ?
C4 N1 Rh1 119.5(3) . . ?
C1 N2 C2 123.0(4) . . ?
C1 N2 Rh2 95.4(2) . . ?
C2 N2 Rh2 140.5(3) . . ?
C6 N3 C9 114.9(3) . . ?
C6 N3 Rh2 123.0(3) . . ?
C9 N3 Rh2 118.8(3) . . ?
C6 N4 C7 123.3(4) . . ?
C6 N4 Rh3 95.1(2) . . ?
C7 N4 Rh3 141.0(3) . . ?
C11 N5 C14 115.8(3) . . ?
C11 N5 Rh3 123.5(3) . . ?
C14 N5 Rh3 118.1(3) . . ?
C11 N6 C12 123.3(3) . . ?
C11 N6 Rh4 94.7(2) . . ?
C12 N6 Rh4 141.7(3) . . ?
C16 N7 C19 116.1(3) . . ?
C16 N7 Rh4 123.5(2) . . ?
C19 N7 Rh4 117.5(3) . . ?
C16 N8 C17 123.2(4) . . ?
C16 N8 Rh1 95.1(2) . . ?
C17 N8 Rh1 141.5(3) . . ?
O9B N9 O11 111.6(11) . . ?
O10A N9 O11 116.3(10) . . ?
O9B N9 O10B 116.1(9) . . ?
O11 N9 O10B 131.9(9) . . ?
O10A N9 O9A 116.1(6) . . ?
O11 N9 O9A 127.5(10) . . ?
O9B N9 Na1 59.0(7) . . ?
O10A N9 Na1 59.0(4) . . ?
O11 N9 Na1 168.1(5) . . ?
O10B N9 Na1 57.2(5) . . ?
O9A N9 Na1 57.9(4) . . ?
O1 C1 N1 123.5(3) . . ?
O1 C1 N2 112.6(3) . . ?
N1 C1 N2 124.0(3) . . ?
O1 C1 Rh2 59.43(18) . . ?
N1 C1 Rh2 176.0(3) . . ?
N2 C1 Rh2 53.3(2) . . ?
O2 C2 N2 120.8(4) . . ?
O2 C2 C3 124.7(4) . . ?
N2 C2 C3 114.5(4) . . ?
C4 C3 C2 118.7(4) . . ?
C4 C3 C5 122.4(4) . . ?
C2 C3 C5 118.9(4) . . ?
C3 C4 N1 124.7(4) . . ?
C3 C4 H4 117.7 . . ?
N1 C4 H4 117.7 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
O3 C6 N3 123.7(4) . . ?
O3 C6 N4 112.7(3) . . ?
N3 C6 N4 123.7(3) . . ?
O3 C6 Rh3 59.1(2) . . ?
N3 C6 Rh3 176.9(3) . . ?
N4 C6 Rh3 53.5(2) . . ?
O4 C7 N4 121.3(4) . . ?
O4 C7 C8 124.6(4) . . ?
N4 C7 C8 114.1(4) . . ?
C9 C8 C7 119.2(4) . . ?
C9 C8 C10 121.7(4) . . ?
C7 C8 C10 119.1(4) . . ?
C8 C9 N3 124.6(4) . . ?
C8 C9 H9 117.7 . . ?
N3 C9 H9 117.7 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O5 C11 N5 124.2(3) . . ?
O5 C11 N6 112.7(3) . . ?
N5 C11 N6 123.1(4) . . ?
O5 C11 Rh4 59.20(18) . . ?
N5 C11 Rh4 176.6(3) . . ?
N6 C11 Rh4 53.5(2) . . ?
O6 C12 N6 120.9(4) . . ?
O6 C12 C13 124.5(4) . . ?
N6 C12 C13 114.5(3) . . ?
C14 C13 C12 118.9(4) . . ?
C14 C13 C15 121.7(4) . . ?
C12 C13 C15 119.3(4) . . ?
C13 C14 N5 124.2(4) . . ?
C13 C14 H14 117.9 . . ?
N5 C14 H14 117.9 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O7 C16 N7 123.8(3) . . ?
O7 C16 N8 112.7(3) . . ?
N7 C16 N8 123.5(3) . . ?
O7 C16 Rh1 59.1(2) . . ?
N7 C16 Rh1 176.5(3) . . ?
N8 C16 Rh1 53.61(19) . . ?
O8 C17 N8 121.2(4) . . ?
O8 C17 C18 124.1(4) . . ?
N8 C17 C18 114.7(4) . . ?
C19 C18 C17 119.3(4) . . ?
C19 C18 C20 121.5(4) . . ?
C17 C18 C20 119.3(4) . . ?
C18 C19 N7 123.1(4) . . ?
C18 C19 H19 118.5 . . ?
N7 C19 H19 118.5 . . ?
C18 C20 H20A 109.5 . . ?
C18 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C18 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C25 C21 C22 107.8(3) . . ?
C25 C21 C26 126.7(4) . . ?
C22 C21 C26 125.4(4) . . ?
C25 C21 Rh1 70.5(2) . . ?
C22 C21 Rh1 68.5(2) . . ?
C26 C21 Rh1 124.7(3) . . ?
C23 C22 C21 107.3(3) . . ?
C23 C22 C27 127.4(4) . . ?
C21 C22 C27 125.1(4) . . ?
C23 C22 Rh1 71.9(2) . . ?
C21 C22 Rh1 71.7(2) . . ?
C27 C22 Rh1 125.6(3) . . ?
C24 C23 C22 108.4(3) . . ?
C24 C23 C28 126.5(4) . . ?
C22 C23 C28 125.0(4) . . ?
C24 C23 Rh1 70.9(2) . . ?
C22 C23 Rh1 68.6(2) . . ?
C28 C23 Rh1 125.4(3) . . ?
C23 C24 C25 108.8(4) . . ?
C23 C24 C29 126.7(4) . . ?
C25 C24 C29 124.5(4) . . ?
C23 C24 Rh1 71.2(2) . . ?
C25 C24 Rh1 70.1(2) . . ?
C29 C24 Rh1 124.5(3) . . ?
C21 C25 C24 107.5(4) . . ?
C21 C25 C30 126.3(4) . . ?
C24 C25 C30 126.1(4) . . ?
C21 C25 Rh1 70.9(2) . . ?
C24 C25 Rh1 70.4(2) . . ?
C30 C25 Rh1 127.0(4) . . ?
C21 C26 H26A 109.5 . . ?
C21 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C21 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C22 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C22 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C25 C30 H30A 109.5 . . ?
C25 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C25 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C35 C31 C32 107.5(5) . . ?
C35 C31 C36 128.0(5) . . ?
C32 C31 C36 124.4(5) . . ?
C35 C31 Rh2 71.0(3) . . ?
C32 C31 Rh2 68.6(3) . . ?
C36 C31 Rh2 122.9(4) . . ?
C33 C32 C31 107.9(4) . . ?
C33 C32 C37 126.3(5) . . ?
C31 C32 C37 125.6(5) . . ?
C33 C32 Rh2 72.2(2) . . ?
C31 C32 Rh2 71.8(2) . . ?
C37 C32 Rh2 125.5(4) . . ?
C34 C33 C32 107.7(5) . . ?
C34 C33 C38 126.5(5) . . ?
C32 C33 C38 125.8(4) . . ?
C34 C33 Rh2 70.8(2) . . ?
C32 C33 Rh2 68.4(2) . . ?
C38 C33 Rh2 123.8(3) . . ?
C35 C34 C33 107.9(4) . . ?
C35 C34 C39 124.5(5) . . ?
C33 C34 C39 127.6(6) . . ?
C35 C34 Rh2 70.3(3) . . ?
C33 C34 Rh2 70.5(2) . . ?
C39 C34 Rh2 125.2(3) . . ?
C31 C35 C34 109.0(4) . . ?
C31 C35 C40 126.6(6) . . ?
C34 C35 C40 124.4(5) . . ?
C31 C35 Rh2 70.6(3) . . ?
C34 C35 Rh2 71.0(3) . . ?
C40 C35 Rh2 126.9(3) . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C45 C41 C42 107.6(4) . . ?
C45 C41 C46 126.3(6) . . ?
C42 C41 C46 126.0(5) . . ?
C45 C41 Rh3 71.3(2) . . ?
C42 C41 Rh3 68.4(3) . . ?
C46 C41 Rh3 124.1(4) . . ?
C41 C42 C43 108.2(5) . . ?
C41 C42 C47 126.2(6) . . ?
C43 C42 C47 125.3(6) . . ?
C41 C42 Rh3 72.0(3) . . ?
C43 C42 Rh3 72.3(3) . . ?
C47 C42 Rh3 126.6(4) . . ?
C44 C43 C42 107.3(5) . . ?
C44 C43 C48 126.7(5) . . ?
C42 C43 C48 126.0(6) . . ?
C44 C43 Rh3 71.2(3) . . ?
C42 C43 Rh3 68.0(3) . . ?
C48 C43 Rh3 124.6(3) . . ?
C43 C44 C45 108.2(4) . . ?
C43 C44 C49 127.6(5) . . ?
C45 C44 C49 124.2(5) . . ?
C43 C44 Rh3 70.7(3) . . ?
C45 C44 Rh3 70.0(2) . . ?
C49 C44 Rh3 128.3(3) . . ?
C41 C45 C44 108.7(5) . . ?
C41 C45 C50 128.1(5) . . ?
C44 C45 C50 123.3(5) . . ?
C41 C45 Rh3 70.7(2) . . ?
C44 C45 Rh3 70.7(2) . . ?
C50 C45 Rh3 124.4(4) . . ?
C41 C46 H46A 109.5 . . ?
C41 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C41 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C42 C47 H47A 109.5 . . ?
C42 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C42 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C43 C48 H48A 109.5 . . ?
C43 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C43 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C44 C49 H49A 109.5 . . ?
C44 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C44 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C45 C50 H50A 109.5 . . ?
C45 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C45 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C55 C51 C52 108.4(5) . . ?
C55 C51 C56 129.7(6) . . ?
C52 C51 C56 122.0(6) . . ?
C55 C51 Rh4 70.7(3) . . ?
C52 C51 Rh4 70.4(3) . . ?
C56 C51 Rh4 123.4(4) . . ?
C53 C52 C51 108.1(5) . . ?
C53 C52 C57 124.5(6) . . ?
C51 C52 C57 127.3(6) . . ?
C53 C52 Rh4 72.3(3) . . ?
C51 C52 Rh4 70.6(3) . . ?
C57 C52 Rh4 124.7(4) . . ?
C52 C53 C54 109.5(5) . . ?
C52 C53 C58 127.7(6) . . ?
C54 C53 C58 122.8(6) . . ?
C52 C53 Rh4 69.5(3) . . ?
C54 C53 Rh4 70.8(2) . . ?
C58 C53 Rh4 123.8(4) . . ?
C53 C54 C55 105.8(5) . . ?
C53 C54 C59 127.2(6) . . ?
C55 C54 C59 126.9(6) . . ?
C53 C54 Rh4 70.5(2) . . ?
C55 C54 Rh4 69.0(3) . . ?
C59 C54 Rh4 128.0(4) . . ?
C51 C55 C54 108.2(4) . . ?
C51 C55 C60 125.9(7) . . ?
C54 C55 C60 125.8(7) . . ?
C51 C55 Rh4 70.5(3) . . ?
C54 C55 Rh4 71.4(2) . . ?
C60 C55 Rh4 121.6(3) . . ?
C51 C56 H56A 109.5 . . ?
C51 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C51 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
C52 C57 H57A 109.5 . . ?
C52 C57 H57B 109.5 . . ?
H57A C57 H57B 109.5 . . ?
C52 C57 H57C 109.5 . . ?
H57A C57 H57C 109.5 . . ?
H57B C57 H57C 109.5 . . ?
C53 C58 H58A 109.5 . . ?
C53 C58 H58B 109.5 . . ?
H58A C58 H58B 109.5 . . ?
C53 C58 H58C 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C54 C59 H59A 109.5 . . ?
C54 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C54 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
C55 C60 H60A 109.5 . . ?
C55 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C55 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
N13A C96B C95B 170(3) . . ?
N11 C91 C92 176.0(18) . . ?
C91 C92 H92A 109.5 . . ?
C91 C92 H92B 109.5 . . ?
H92A C92 H92B 109.5 . . ?
C91 C92 H92C 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
N12 C93 C94 178.4(11) . . ?
C93 C94 H94A 109.5 . . ?
C93 C94 H94B 109.5 . . ?
H94A C94 H94B 109.5 . . ?
C93 C94 H94C 109.5 . . ?
H94A C94 H94C 109.5 . . ?
H94B C94 H94C 109.5 . . ?
N13B C96A C95A 156(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Na1 O9B N9 O11 171.9(9) . . . . ?
O9A O9B N9 O10B 62.9(17) . . . . ?
O11 O9B N9 O10B -174(2) . . . . ?
Na1 O9B N9 O10B -2(2) . . . . ?
O11 O9B N9 Na1 -171.9(9) . . . . ?
Na1 O10A N9 O11 -167.6(7) . . . . ?
Na1 O10A N9 O9A 9.8(11) . . . . ?
Na1 O10B N9 O9B 2(2) . . . . ?
Na1 O10B N9 O11 -170.4(11) . . . . ?
O9B O9A N9 O10A -76.5(14) . . . . ?
Na1 O9A N9 O10A -10.0(11) . . . . ?
Na1 O9A N9 O11 167.1(8) . . . . ?
Na1 O9A N9 O10B -58.6(7) . . . . ?
Rh2 O1 C1 N1 -176.7(4) . . . . ?
Na1 O1 C1 N1 -50.4(5) . . . . ?
Rh2 O1 C1 N2 4.3(3) . . . . ?
Na1 O1 C1 N2 130.6(3) . . . . ?
Na1 O1 C1 Rh2 126.3(3) . . . . ?
C4 N1 C1 O1 175.6(4) . . . . ?
Rh1 N1 C1 O1 -24.9(5) . . . . ?
C4 N1 C1 N2 -5.5(6) . . . . ?
Rh1 N1 C1 N2 154.0(3) . . . . ?
C2 N2 C1 O1 -174.9(4) . . . . ?
Rh2 N2 C1 O1 -4.6(4) . . . . ?
C2 N2 C1 N1 6.1(7) . . . . ?
Rh2 N2 C1 N1 176.4(4) . . . . ?
C2 N2 C1 Rh2 -170.3(5) . . . . ?
C1 N2 C2 O2 177.7(4) . . . . ?
Rh2 N2 C2 O2 13.1(8) . . . . ?
C1 N2 C2 C3 -2.1(6) . . . . ?
Rh2 N2 C2 C3 -166.8(4) . . . . ?
O2 C2 C3 C4 178.4(5) . . . . ?
N2 C2 C3 C4 -1.8(6) . . . . ?
O2 C2 C3 C5 -1.7(7) . . . . ?
N2 C2 C3 C5 178.1(4) . . . . ?
C2 C3 C4 N1 2.1(7) . . . . ?
C5 C3 C4 N1 -177.8(5) . . . . ?
C1 N1 C4 C3 1.4(6) . . . . ?
Rh1 N1 C4 C3 -158.8(4) . . . . ?
Rh3 O3 C6 N3 -178.5(3) . . . . ?
Na1 O3 C6 N3 -51.1(5) . . . . ?
Rh3 O3 C6 N4 1.1(3) . . . . ?
Na1 O3 C6 N4 128.4(3) . . . . ?
Na1 O3 C6 Rh3 127.4(3) . . . . ?
C9 N3 C6 O3 177.2(3) . . . . ?
Rh2 N3 C6 O3 -23.6(5) . . . . ?
C9 N3 C6 N4 -2.4(5) . . . . ?
Rh2 N3 C6 N4 156.8(3) . . . . ?
C7 N4 C6 O3 -174.3(3) . . . . ?
Rh3 N4 C6 O3 -1.2(3) . . . . ?
C7 N4 C6 N3 5.3(5) . . . . ?
Rh3 N4 C6 N3 178.4(3) . . . . ?
C7 N4 C6 Rh3 -173.1(4) . . . . ?
C6 N4 C7 O4 174.2(4) . . . . ?
Rh3 N4 C7 O4 5.2(6) . . . . ?
C6 N4 C7 C8 -5.1(5) . . . . ?
Rh3 N4 C7 C8 -174.1(3) . . . . ?
O4 C7 C8 C9 -176.8(4) . . . . ?
N4 C7 C8 C9 2.5(5) . . . . ?
O4 C7 C8 C10 2.6(6) . . . . ?
N4 C7 C8 C10 -178.2(4) . . . . ?
C7 C8 C9 N3 0.0(6) . . . . ?
C10 C8 C9 N3 -179.3(4) . . . . ?
C6 N3 C9 C8 -0.2(6) . . . . ?
Rh2 N3 C9 C8 -160.3(3) . . . . ?
Rh4 O5 C11 N5 -179.4(4) . . . . ?
Na1 O5 C11 N5 -51.2(5) . . . . ?
Rh4 O5 C11 N6 1.8(3) . . . . ?
Na1 O5 C11 N6 130.0(3) . . . . ?
Na1 O5 C11 Rh4 128.2(3) . . . . ?
C14 N5 C11 O5 176.9(4) . . . . ?
Rh3 N5 C11 O5 -21.8(6) . . . . ?
C14 N5 C11 N6 -4.5(6) . . . . ?
Rh3 N5 C11 N6 156.9(3) . . . . ?
C12 N6 C11 O5 -176.3(4) . . . . ?
Rh4 N6 C11 O5 -2.0(3) . . . . ?
C12 N6 C11 N5 4.9(6) . . . . ?
Rh4 N6 C11 N5 179.2(3) . . . . ?
C12 N6 C11 Rh4 -174.3(5) . . . . ?
C11 N6 C12 O6 177.7(4) . . . . ?
Rh4 N6 C12 O6 6.9(8) . . . . ?
C11 N6 C12 C13 -2.9(6) . . . . ?
Rh4 N6 C12 C13 -173.7(3) . . . . ?
O6 C12 C13 C14 -179.6(5) . . . . ?
N6 C12 C13 C14 1.1(6) . . . . ?
O6 C12 C13 C15 -2.3(8) . . . . ?
N6 C12 C13 C15 178.4(5) . . . . ?
C12 C13 C14 N5 -1.0(7) . . . . ?
C15 C13 C14 N5 -178.3(5) . . . . ?
C11 N5 C14 C13 2.6(7) . . . . ?
Rh3 N5 C14 C13 -159.8(4) . . . . ?
Rh1 O7 C16 N7 -177.7(3) . . . . ?
Na1 O7 C16 N7 -49.3(5) . . . . ?
Rh1 O7 C16 N8 2.4(3) . . . . ?
Na1 O7 C16 N8 130.8(3) . . . . ?
Na1 O7 C16 Rh1 128.4(3) . . . . ?
C19 N7 C16 O7 176.1(3) . . . . ?
Rh4 N7 C16 O7 -23.6(5) . . . . ?
C19 N7 C16 N8 -4.0(5) . . . . ?
Rh4 N7 C16 N8 156.3(3) . . . . ?
C17 N8 C16 O7 -178.4(3) . . . . ?
Rh1 N8 C16 O7 -2.5(3) . . . . ?
C17 N8 C16 N7 1.7(6) . . . . ?
Rh1 N8 C16 N7 177.5(3) . . . . ?
C17 N8 C16 Rh1 -175.9(4) . . . . ?
C16 N8 C17 O8 -177.8(4) . . . . ?
Rh1 N8 C17 O8 8.8(7) . . . . ?
C16 N8 C17 C18 1.7(6) . . . . ?
Rh1 N8 C17 C18 -171.7(3) . . . . ?
O8 C17 C18 C19 177.0(4) . . . . ?
N8 C17 C18 C19 -2.5(6) . . . . ?
O8 C17 C18 C20 -1.6(7) . . . . ?
N8 C17 C18 C20 178.9(4) . . . . ?
C17 C18 C19 N7 0.2(6) . . . . ?
C20 C18 C19 N7 178.7(4) . . . . ?
C16 N7 C19 C18 3.0(6) . . . . ?
Rh4 N7 C19 C18 -158.5(3) . . . . ?
C25 C21 C22 C23 3.8(5) . . . . ?
C26 C21 C22 C23 -178.4(4) . . . . ?
Rh1 C21 C22 C23 63.5(3) . . . . ?
C25 C21 C22 C27 179.2(4) . . . . ?
C26 C21 C22 C27 -3.0(7) . . . . ?
Rh1 C21 C22 C27 -121.1(4) . . . . ?
C25 C21 C22 Rh1 -59.7(3) . . . . ?
C26 C21 C22 Rh1 118.1(4) . . . . ?
C21 C22 C23 C24 -3.4(5) . . . . ?
C27 C22 C23 C24 -178.6(4) . . . . ?
Rh1 C22 C23 C24 59.9(3) . . . . ?
C21 C22 C23 C28 177.6(4) . . . . ?
C27 C22 C23 C28 2.4(7) . . . . ?
Rh1 C22 C23 C28 -119.1(4) . . . . ?
C21 C22 C23 Rh1 -63.4(3) . . . . ?
C27 C22 C23 Rh1 121.4(5) . . . . ?
C22 C23 C24 C25 1.8(5) . . . . ?
C28 C23 C24 C25 -179.3(4) . . . . ?
Rh1 C23 C24 C25 60.3(3) . . . . ?
C22 C23 C24 C29 -178.0(4) . . . . ?
C28 C23 C24 C29 1.0(8) . . . . ?
Rh1 C23 C24 C29 -119.5(5) . . . . ?
C22 C23 C24 Rh1 -58.5(3) . . . . ?
C28 C23 C24 Rh1 120.5(5) . . . . ?
C22 C21 C25 C24 -2.8(5) . . . . ?
C26 C21 C25 C24 179.5(4) . . . . ?
Rh1 C21 C25 C24 -61.3(3) . . . . ?
C22 C21 C25 C30 -179.1(4) . . . . ?
C26 C21 C25 C30 3.1(7) . . . . ?
Rh1 C21 C25 C30 122.4(5) . . . . ?
C22 C21 C25 Rh1 58.5(3) . . . . ?
C26 C21 C25 Rh1 -119.3(4) . . . . ?
C23 C24 C25 C21 0.6(5) . . . . ?
C29 C24 C25 C21 -179.6(4) . . . . ?
Rh1 C24 C25 C21 61.6(3) . . . . ?
C23 C24 C25 C30 177.0(5) . . . . ?
C29 C24 C25 C30 -3.2(7) . . . . ?
Rh1 C24 C25 C30 -122.1(5) . . . . ?
C23 C24 C25 Rh1 -60.9(3) . . . . ?
C29 C24 C25 Rh1 118.9(4) . . . . ?
C35 C31 C32 C33 3.1(5) . . . . ?
C36 C31 C32 C33 179.7(5) . . . . ?
Rh2 C31 C32 C33 63.6(3) . . . . ?
C35 C31 C32 C37 178.3(4) . . . . ?
C36 C31 C32 C37 -5.0(8) . . . . ?
Rh2 C31 C32 C37 -121.1(5) . . . . ?
C35 C31 C32 Rh2 -60.6(3) . . . . ?
C36 C31 C32 Rh2 116.0(5) . . . . ?
C31 C32 C33 C34 -3.1(5) . . . . ?
C37 C32 C33 C34 -178.3(4) . . . . ?
Rh2 C32 C33 C34 60.2(3) . . . . ?
C31 C32 C33 C38 179.8(4) . . . . ?
C37 C32 C33 C38 4.6(7) . . . . ?
Rh2 C32 C33 C38 -116.9(4) . . . . ?
C31 C32 C33 Rh2 -63.3(3) . . . . ?
C37 C32 C33 Rh2 121.4(5) . . . . ?
C32 C33 C34 C35 2.0(5) . . . . ?
C38 C33 C34 C35 179.1(4) . . . . ?
Rh2 C33 C34 C35 60.7(3) . . . . ?
C32 C33 C34 C39 -178.6(4) . . . . ?
C38 C33 C34 C39 -1.6(7) . . . . ?
Rh2 C33 C34 C39 -119.9(5) . . . . ?
C32 C33 C34 Rh2 -58.7(3) . . . . ?
C38 C33 C34 Rh2 118.4(4) . . . . ?
C32 C31 C35 C34 -1.8(5) . . . . ?
C36 C31 C35 C34 -178.3(5) . . . . ?
Rh2 C31 C35 C34 -60.9(3) . . . . ?
C32 C31 C35 C40 -178.8(4) . . . . ?
C36 C31 C35 C40 4.8(8) . . . . ?
Rh2 C31 C35 C40 122.1(5) . . . . ?
C32 C31 C35 Rh2 59.1(3) . . . . ?
C36 C31 C35 Rh2 -117.4(5) . . . . ?
C33 C34 C35 C31 -0.1(5) . . . . ?
C39 C34 C35 C31 -179.5(4) . . . . ?
Rh2 C34 C35 C31 60.7(3) . . . . ?
C33 C34 C35 C40 176.9(4) . . . . ?
C39 C34 C35 C40 -2.5(7) . . . . ?
Rh2 C34 C35 C40 -122.3(4) . . . . ?
C33 C34 C35 Rh2 -60.8(3) . . . . ?
C39 C34 C35 Rh2 119.8(4) . . . . ?
C45 C41 C42 C43 2.9(5) . . . . ?
C46 C41 C42 C43 -179.1(4) . . . . ?
Rh3 C41 C42 C43 63.7(3) . . . . ?
C45 C41 C42 C47 176.7(5) . . . . ?
C46 C41 C42 C47 -5.4(8) . . . . ?
Rh3 C41 C42 C47 -122.6(5) . . . . ?
C45 C41 C42 Rh3 -60.8(3) . . . . ?
C46 C41 C42 Rh3 117.2(5) . . . . ?
C41 C42 C43 C44 -2.9(5) . . . . ?
C47 C42 C43 C44 -176.7(5) . . . . ?
Rh3 C42 C43 C44 60.6(3) . . . . ?
C41 C42 C43 C48 179.0(5) . . . . ?
C47 C42 C43 C48 5.2(8) . . . . ?
Rh3 C42 C43 C48 -117.6(5) . . . . ?
C41 C42 C43 Rh3 -63.5(3) . . . . ?
C47 C42 C43 Rh3 122.7(5) . . . . ?
C42 C43 C44 C45 1.7(5) . . . . ?
C48 C43 C44 C45 179.9(5) . . . . ?
Rh3 C43 C44 C45 60.3(3) . . . . ?
C42 C43 C44 C49 177.5(4) . . . . ?
C48 C43 C44 C49 -4.4(8) . . . . ?
Rh3 C43 C44 C49 -124.0(5) . . . . ?
C42 C43 C44 Rh3 -58.6(3) . . . . ?
C48 C43 C44 Rh3 119.6(5) . . . . ?
C42 C41 C45 C44 -1.9(5) . . . . ?
C46 C41 C45 C44 -179.8(4) . . . . ?
Rh3 C41 C45 C44 -60.8(3) . . . . ?
C42 C41 C45 C50 178.0(5) . . . . ?
C46 C41 C45 C50 0.0(8) . . . . ?
Rh3 C41 C45 C50 119.1(5) . . . . ?
C42 C41 C45 Rh3 58.9(3) . . . . ?
C46 C41 C45 Rh3 -119.1(5) . . . . ?
C43 C44 C45 C41 0.1(5) . . . . ?
C49 C44 C45 C41 -175.8(4) . . . . ?
Rh3 C44 C45 C41 60.8(3) . . . . ?
C43 C44 C45 C50 -179.8(4) . . . . ?
C49 C44 C45 C50 4.3(7) . . . . ?
Rh3 C44 C45 C50 -119.1(5) . . . . ?
C43 C44 C45 Rh3 -60.7(3) . . . . ?
C49 C44 C45 Rh3 123.4(5) . . . . ?
C55 C51 C52 C53 2.1(5) . . . . ?
C56 C51 C52 C53 -179.3(5) . . . . ?
Rh4 C51 C52 C53 63.0(3) . . . . ?
C55 C51 C52 C57 179.7(5) . . . . ?
C56 C51 C52 C57 -1.7(8) . . . . ?
Rh4 C51 C52 C57 -119.4(5) . . . . ?
C55 C51 C52 Rh4 -60.8(3) . . . . ?
C56 C51 C52 Rh4 117.8(5) . . . . ?
C51 C52 C53 C54 -2.2(5) . . . . ?
C57 C52 C53 C54 -179.9(5) . . . . ?
Rh4 C52 C53 C54 59.7(3) . . . . ?
C51 C52 C53 C58 -179.4(5) . . . . ?
C57 C52 C53 C58 2.9(8) . . . . ?
Rh4 C52 C53 C58 -117.5(5) . . . . ?
C51 C52 C53 Rh4 -61.9(3) . . . . ?
C57 C52 C53 Rh4 120.4(5) . . . . ?
C52 C53 C54 C55 1.5(5) . . . . ?
C58 C53 C54 C55 178.8(4) . . . . ?
Rh4 C53 C54 C55 60.4(3) . . . . ?
C52 C53 C54 C59 177.6(5) . . . . ?
C58 C53 C54 C59 -5.1(7) . . . . ?
Rh4 C53 C54 C59 -123.5(5) . . . . ?
C52 C53 C54 Rh4 -58.9(3) . . . . ?
C58 C53 C54 Rh4 118.4(5) . . . . ?
C52 C51 C55 C54 -1.2(5) . . . . ?
C56 C51 C55 C54 -179.7(5) . . . . ?
Rh4 C51 C55 C54 -61.8(3) . . . . ?
C52 C51 C55 C60 176.1(4) . . . . ?
C56 C51 C55 C60 -2.3(8) . . . . ?
Rh4 C51 C55 C60 115.5(5) . . . . ?
C52 C51 C55 Rh4 60.6(3) . . . . ?
C56 C51 C55 Rh4 -117.8(6) . . . . ?
C53 C54 C55 C51 -0.2(5) . . . . ?
C59 C54 C55 C51 -176.3(5) . . . . ?
Rh4 C54 C55 C51 61.2(3) . . . . ?
C53 C54 C55 C60 -177.5(4) . . . . ?
C59 C54 C55 C60 6.4(8) . . . . ?
Rh4 C54 C55 C60 -116.1(5) . . . . ?
C53 C54 C55 Rh4 -61.4(3) . . . . ?
C59 C54 C55 Rh4 122.5(5) . . . . ?

_refine_diff_density_max         0.909
_refine_diff_density_min         -0.974
_refine_diff_density_rms         0.149

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4CaNO3
_database_code_depnum_ccdc_archive 'CCDC 1033779'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C62 H79 Ca N10 O11 Rh4 1+, 0.5(N O3), 0.5(O H), 9(H2 O)'
_chemical_formula_sum            'C62 H97.5 Ca N10.5 O22 Rh4'
_chemical_formula_weight         1793.72

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ca Ca 0.2262 0.3064 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_symmetry_space_group_name_Hall  '-P 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.3211(7)
_cell_length_b                   18.6735(10)
_cell_length_c                   18.7302(8)
_cell_angle_alpha                89.602(2)
_cell_angle_beta                 75.171(2)
_cell_angle_gamma                87.676(3)
_cell_volume                     3824.6(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    192(2)
_cell_measurement_reflns_used    27953
_cell_measurement_theta_min      3.13
_cell_measurement_theta_max      27.50

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.558
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1838
_exptl_absorpt_coefficient_mu    0.991
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.7898
_exptl_absorpt_correction_T_max  0.8265
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      192(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            36759
_diffrn_reflns_av_R_equivalents  0.0699
_diffrn_reflns_av_sigmaI/netI    0.0977
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         3.13
_diffrn_reflns_theta_max         27.49
_reflns_number_total             17268
_reflns_number_gt                13848
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    SHELXS-97
_computing_structure_refinement  SHELXL-97
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0594P)²+5.5009P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         17268
_refine_ls_number_parameters     937
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0660
_refine_ls_R_factor_gt           0.0545
_refine_ls_wR_factor_ref         0.1585
_refine_ls_wR_factor_gt          0.1441
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_restrained_S_all      1.068
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.69231(3) 0.751558(17) 0.426999(15) 0.02411(9) Uani 1 1 d . . .
Rh2 Rh 0.70700(3) 0.539541(16) 0.224348(15) 0.02223(9) Uani 1 1 d . . .
Rh3 Rh 0.68992(3) 0.739919(16) 0.014256(15) 0.02451(9) Uani 1 1 d . . .
Rh4 Rh 0.68969(3) 0.951530(17) 0.215359(16) 0.02536(10) Uani 1 1 d . . .
Ca1 Ca 0.76986(8) 0.74571(4) 0.20955(4) 0.02602(18) Uani 1 1 d . . .
O1 O 0.7369(3) 0.64104(15) 0.28174(13) 0.0250(6) Uani 1 1 d . . .
O2 O 0.4228(3) 0.49725(17) 0.35089(16) 0.0401(8) Uani 1 1 d . . .
O3 O 0.7315(3) 0.67786(15) 0.11125(14) 0.0249(6) Uani 1 1 d . . .
O4 O 0.4066(3) 0.65723(19) 0.01944(18) 0.0453(9) Uani 1 1 d . . .
O5 O 0.7255(3) 0.84913(15) 0.14694(14) 0.0265(6) Uani 1 1 d . . .
O6 O 0.3931(3) 0.99540(18) 0.18317(18) 0.0436(8) Uani 1 1 d . . .
O7 O 0.7262(3) 0.81404(15) 0.32017(14) 0.0270(6) Uani 1 1 d . . .
O8 O 0.3898(3) 0.83050(17) 0.50657(15) 0.0387(7) Uani 1 1 d . . .
O9 O 0.9697(4) 0.7531(4) 0.2352(2) 0.109(2) Uani 1 1 d . . .
O10 O 0.9752(4) 0.7392(4) 0.1262(2) 0.096(2) Uani 1 1 d . . .
O11 O 1.1434(4) 0.7436(2) 0.1576(2) 0.0655(11) Uani 1 1 d . . .
O12 O 0.2229(18) 0.2960(8) 0.3146(9) 0.128(6) Uani 0.50 1 d P . .
O16A O -0.007(3) 0.176(3) 0.2299(15) 0.29(3) Uani 0.33 1 d P . .
O16B O -0.068(3) 0.2402(17) 0.2451(13) 0.165(15) Uani 0.33 1 d P . .
O16C O -0.0829(16) 0.1765(14) 0.2546(10) 0.098(7) Uani 0.33 1 d P . .
O19 O 0.0022(4) 0.4578(3) 0.4374(2) 0.0681(12) Uani 1 1 d . . .
O20 O 0.2152(4) 0.4490(3) 0.3201(2) 0.0661(11) Uani 1 1 d . . .
O21 O 0.1926(5) 0.0558(3) 0.2917(2) 0.0770(13) Uani 1 1 d . . .
O22 O 0.9729(5) 0.3087(3) 0.4258(3) 0.0994(18) Uani 1 1 d . . .
O23 O 0.8552(5) 0.1799(3) 0.4203(3) 0.0928(17) Uani 1 1 d . . .
O24 O 0.7593(5) 0.2406(3) 0.1615(3) 0.1030(18) Uani 1 1 d . . .
O25 O 0.8019(5) 0.2880(4) 0.0101(3) 0.104(2) Uani 1 1 d . . .
O26 O 0.9983(4) 0.0453(3) 0.4315(3) 0.0847(15) Uani 1 1 d . . .
O121 O 0.1142(14) 0.3042(8) 0.2683(6) 0.120(5) Uani 0.50 1 d P . .
O122 O 0.277(2) 0.263(2) 0.2748(9) 0.30(2) Uani 0.50 1 d P . .
O123 O 0.1455(14) 0.1965(5) 0.2467(4) 0.115(5) Uani 0.50 1 d P . .
N1 N 0.5886(3) 0.67838(17) 0.38643(16) 0.0246(7) Uani 1 1 d . . .
N2 N 0.5823(3) 0.57074(18) 0.32172(16) 0.0249(7) Uani 1 1 d . . .
N3 N 0.5912(3) 0.59686(18) 0.17119(17) 0.0265(7) Uani 1 1 d . . .
N4 N 0.5705(3) 0.66373(18) 0.06816(17) 0.0252(7) Uani 1 1 d . . .
N5 N 0.5798(3) 0.81484(18) 0.08795(17) 0.0263(7) Uani 1 1 d . . .
N6 N 0.5621(3) 0.92140(18) 0.15880(17) 0.0268(7) Uani 1 1 d . . .
N7 N 0.5802(3) 0.89917(18) 0.30578(17) 0.0268(7) Uani 1 1 d . . .
N8 N 0.5620(3) 0.82938(18) 0.41311(17) 0.0277(7) Uani 1 1 d . . .
N9 N 1.0328(4) 0.7452(2) 0.1725(2) 0.0391(9) Uani 1 1 d . . .
N10 N 0.5312(4) 0.7484(2) 0.24635(19) 0.0355(8) Uani 1 1 d . . .
N12 N 0.1902(14) 0.2594(8) 0.2738(7) 0.080(4) Uani 0.50 1 d P . .
C1 C 0.8482(5) 0.7792(3) 0.4669(2) 0.0388(11) Uani 1 1 d . . .
C2 C 0.7387(5) 0.7931(3) 0.5224(2) 0.0393(11) Uani 1 1 d . . .
C3 C 0.6764(5) 0.7261(3) 0.5390(2) 0.0393(11) Uani 1 1 d . . .
C4 C 0.7528(5) 0.6716(3) 0.4943(2) 0.0380(11) Uani 1 1 d . . .
C5 C 0.8571(4) 0.7041(2) 0.4480(2) 0.0341(10) Uani 1 1 d . . .
C6 C 0.9417(5) 0.8303(3) 0.4320(3) 0.0568(15) Uani 1 1 d . . .
H6A H 0.9641 0.8232 0.3783 0.068 Uiso 1 1 calc R . .
H6B H 1.0144 0.8222 0.4508 0.068 Uiso 1 1 calc R . .
H6C H 0.9089 0.8794 0.4436 0.068 Uiso 1 1 calc R . .
C7 C 0.6958(6) 0.8645(3) 0.5574(3) 0.0628(17) Uani 1 1 d . . .
H7A H 0.7165 0.8673 0.6050 0.075 Uiso 1 1 calc R . .
H7B H 0.6069 0.8704 0.5653 0.075 Uiso 1 1 calc R . .
H7C H 0.7358 0.9026 0.5249 0.075 Uiso 1 1 calc R . .
C8 C 0.5607(5) 0.7162(4) 0.5955(3) 0.0646(18) Uani 1 1 d . . .
H8A H 0.5759 0.6843 0.6343 0.077 Uiso 1 1 calc R . .
H8B H 0.5016 0.6949 0.5726 0.077 Uiso 1 1 calc R . .
H8C H 0.5278 0.7627 0.6172 0.077 Uiso 1 1 calc R . .
C9 C 0.7257(6) 0.5939(3) 0.4943(3) 0.0592(16) Uani 1 1 d . . .
H9A H 0.7922 0.5652 0.5064 0.071 Uiso 1 1 calc R . .
H9B H 0.7181 0.5801 0.4453 0.071 Uiso 1 1 calc R . .
H9C H 0.6488 0.5854 0.5312 0.071 Uiso 1 1 calc R . .
C10 C 0.9602(5) 0.6658(3) 0.3951(3) 0.0535(14) Uani 1 1 d . . .
H10A H 0.9326 0.6204 0.3806 0.064 Uiso 1 1 calc R . .
H10B H 1.0274 0.6564 0.4185 0.064 Uiso 1 1 calc R . .
H10C H 0.9887 0.6956 0.3512 0.064 Uiso 1 1 calc R . .
C11 C 0.6351(4) 0.6316(2) 0.33178(19) 0.0229(8) Uani 1 1 d . . .
C12 C 0.4681(4) 0.5538(2) 0.3632(2) 0.0281(9) Uani 1 1 d . . .
C13 C 0.4098(4) 0.6068(2) 0.4187(2) 0.0293(9) Uani 1 1 d . . .
C14 C 0.4728(4) 0.6643(2) 0.4279(2) 0.0283(9) Uani 1 1 d . . .
H14 H 0.4345 0.6975 0.4657 0.034 Uiso 1 1 calc R . .
C15 C 0.2822(5) 0.5961(3) 0.4634(3) 0.0464(12) Uani 1 1 d . . .
H15A H 0.2514 0.6391 0.4932 0.056 Uiso 1 1 calc R . .
H15B H 0.2816 0.5548 0.4961 0.056 Uiso 1 1 calc R . .
H15C H 0.2298 0.5874 0.4303 0.056 Uiso 1 1 calc R . .
C16 C 0.8697(4) 0.4770(2) 0.2258(2) 0.0338(10) Uani 1 1 d . . .
C17 C 0.7664(4) 0.4347(2) 0.2515(2) 0.0358(10) Uani 1 1 d . . .
C18 C 0.7028(5) 0.4315(2) 0.1940(3) 0.0381(10) Uani 1 1 d . . .
C19 C 0.7734(4) 0.4689(2) 0.1311(2) 0.0312(9) Uani 1 1 d . . .
C20 C 0.8730(4) 0.4988(2) 0.1512(2) 0.0312(9) Uani 1 1 d . . .
C21 C 0.9630(5) 0.4958(4) 0.2657(3) 0.0567(15) Uani 1 1 d . . .
H21A H 1.0359 0.4642 0.2491 0.068 Uiso 1 1 calc R . .
H21B H 0.9290 0.4899 0.3190 0.068 Uiso 1 1 calc R . .
H21C H 0.9851 0.5457 0.2553 0.068 Uiso 1 1 calc R . .
C22 C 0.7289(6) 0.4004(3) 0.3249(3) 0.0627(17) Uani 1 1 d . . .
H22A H 0.7133 0.4373 0.3636 0.075 Uiso 1 1 calc R . .
H22B H 0.7943 0.3670 0.3314 0.075 Uiso 1 1 calc R . .
H22C H 0.6543 0.3743 0.3285 0.075 Uiso 1 1 calc R . .
C23 C 0.5922(5) 0.3910(3) 0.1981(3) 0.0549(14) Uani 1 1 d . . .
H23A H 0.6146 0.3398 0.1913 0.066 Uiso 1 1 calc R . .
H23B H 0.5538 0.4075 0.1593 0.066 Uiso 1 1 calc R . .
H23C H 0.5345 0.3988 0.2465 0.066 Uiso 1 1 calc R . .
C24 C 0.7415(5) 0.4763(3) 0.0590(3) 0.0490(13) Uani 1 1 d . . .
H24A H 0.6524 0.4775 0.0673 0.059 Uiso 1 1 calc R . .
H24B H 0.7775 0.4354 0.0272 0.059 Uiso 1 1 calc R . .
H24C H 0.7735 0.5208 0.0350 0.059 Uiso 1 1 calc R . .
C25 C 0.9660(5) 0.5443(3) 0.1038(3) 0.0466(12) Uani 1 1 d . . .
H25A H 0.9256 0.5877 0.0898 0.056 Uiso 1 1 calc R . .
H25B H 1.0088 0.5176 0.0592 0.056 Uiso 1 1 calc R . .
H25C H 1.0250 0.5578 0.1310 0.056 Uiso 1 1 calc R . .
C26 C 0.6308(4) 0.6449(2) 0.1183(2) 0.0240(8) Uani 1 1 d . . .
C27 C 0.4570(4) 0.6395(2) 0.0686(2) 0.0316(9) Uani 1 1 d . . .
C28 C 0.4059(4) 0.5928(2) 0.1298(2) 0.0310(9) Uani 1 1 d . . .
C29 C 0.4766(4) 0.5736(2) 0.1761(2) 0.0278(8) Uani 1 1 d . . .
H29 H 0.4436 0.5414 0.2150 0.033 Uiso 1 1 calc R . .
C30 C 0.2786(4) 0.5683(3) 0.1398(3) 0.0402(11) Uani 1 1 d . . .
H30A H 0.2744 0.5399 0.0968 0.048 Uiso 1 1 calc R . .
H30B H 0.2219 0.6101 0.1448 0.048 Uiso 1 1 calc R . .
H30C H 0.2561 0.5389 0.1844 0.048 Uiso 1 1 calc R . .
C31 C 0.8466(5) 0.7098(2) -0.0742(2) 0.0359(10) Uani 1 1 d . . .
C32 C 0.7377(5) 0.6957(2) -0.0954(2) 0.0384(11) Uani 1 1 d . . .
C33 C 0.6695(5) 0.7642(3) -0.0917(2) 0.0401(11) Uani 1 1 d . . .
C34 C 0.7401(5) 0.8183(3) -0.0714(2) 0.0411(12) Uani 1 1 d . . .
C35 C 0.8477(4) 0.7858(2) -0.0580(2) 0.0348(10) Uani 1 1 d . . .
C36 C 0.9462(5) 0.6563(3) -0.0712(3) 0.0500(13) Uani 1 1 d . . .
H36A H 0.9806 0.6355 -0.1204 0.060 Uiso 1 1 calc R . .
H36B H 0.9132 0.6182 -0.0365 0.060 Uiso 1 1 calc R . .
H36C H 1.0105 0.6798 -0.0547 0.060 Uiso 1 1 calc R . .
C37 C 0.6992(6) 0.6261(3) -0.1163(3) 0.0586(16) Uani 1 1 d . . .
H37A H 0.6916 0.5926 -0.0750 0.070 Uiso 1 1 calc R . .
H37B H 0.7602 0.6068 -0.1595 0.070 Uiso 1 1 calc R . .
H37C H 0.6200 0.6326 -0.1282 0.070 Uiso 1 1 calc R . .
C38 C 0.5507(6) 0.7749(4) -0.1129(3) 0.0629(17) Uani 1 1 d . . .
H38A H 0.5627 0.8057 -0.1566 0.075 Uiso 1 1 calc R . .
H38B H 0.4893 0.7976 -0.0719 0.075 Uiso 1 1 calc R . .
H38C H 0.5225 0.7283 -0.1241 0.075 Uiso 1 1 calc R . .
C39 C 0.7047(6) 0.8960(3) -0.0639(3) 0.0572(15) Uani 1 1 d . . .
H39A H 0.7064 0.9160 -0.1127 0.069 Uiso 1 1 calc R . .
H39B H 0.7624 0.9209 -0.0426 0.069 Uiso 1 1 calc R . .
H39C H 0.6220 0.9024 -0.0315 0.069 Uiso 1 1 calc R . .
C40 C 0.9465(5) 0.8223(3) -0.0357(3) 0.0522(13) Uani 1 1 d . . .
H40A H 0.9127 0.8469 0.0116 0.063 Uiso 1 1 calc R . .
H40B H 0.9824 0.8574 -0.0734 0.063 Uiso 1 1 calc R . .
H40C H 1.0099 0.7868 -0.0305 0.063 Uiso 1 1 calc R . .
C41 C 0.6210(4) 0.8598(2) 0.1297(2) 0.0266(8) Uani 1 1 d . . .
C42 C 0.4458(4) 0.9390(2) 0.1540(2) 0.0326(9) Uani 1 1 d . . .
C43 C 0.3926(4) 0.8887(2) 0.1139(2) 0.0325(9) Uani 1 1 d . . .
C44 C 0.4626(4) 0.8303(2) 0.0825(2) 0.0320(9) Uani 1 1 d . . .
H44 H 0.4280 0.7982 0.0551 0.038 Uiso 1 1 calc R . .
C45 C 0.2645(5) 0.9022(3) 0.1087(3) 0.0436(11) Uani 1 1 d . . .
H45A H 0.2564 0.9499 0.0880 0.052 Uiso 1 1 calc R . .
H45B H 0.2086 0.8996 0.1581 0.052 Uiso 1 1 calc R . .
H45C H 0.2441 0.8659 0.0767 0.052 Uiso 1 1 calc R . .
C46 C 0.8539(5) 1.0045(2) 0.1644(2) 0.0376(11) Uani 1 1 d . . .
C47 C 0.7516(5) 1.0488(2) 0.1602(2) 0.0378(10) Uani 1 1 d . . .
C48 C 0.6810(5) 1.0639(2) 0.2351(3) 0.0400(11) Uani 1 1 d . . .
C49 C 0.7457(5) 1.0291(3) 0.2839(2) 0.0399(11) Uani 1 1 d . . .
C50 C 0.8499(5) 0.9911(3) 0.2408(2) 0.0383(11) Uani 1 1 d . . .
C51 C 0.9511(5) 0.9749(3) 0.1015(3) 0.0535(14) Uani 1 1 d . . .
H51A H 0.9679 0.9242 0.1106 0.064 Uiso 1 1 calc R . .
H51B H 1.0257 1.0014 0.0965 0.064 Uiso 1 1 calc R . .
H51C H 0.9239 0.9795 0.0560 0.064 Uiso 1 1 calc R . .
C52 C 0.7197(6) 1.0758(3) 0.0921(3) 0.0574(15) Uani 1 1 d . . .
H52A H 0.7085 1.0352 0.0620 0.069 Uiso 1 1 calc R . .
H52B H 0.7859 1.1047 0.0636 0.069 Uiso 1 1 calc R . .
H52C H 0.6438 1.1054 0.1058 0.069 Uiso 1 1 calc R . .
C53 C 0.5688(6) 1.1109(3) 0.2566(3) 0.0635(17) Uani 1 1 d . . .
H53A H 0.5846 1.1525 0.2840 0.076 Uiso 1 1 calc R . .
H53B H 0.5023 1.0841 0.2879 0.076 Uiso 1 1 calc R . .
H53C H 0.5452 1.1273 0.2122 0.076 Uiso 1 1 calc R . .
C54 C 0.7069(7) 1.0302(3) 0.3663(3) 0.0643(18) Uani 1 1 d . . .
H54A H 0.7721 1.0493 0.3855 0.077 Uiso 1 1 calc R . .
H54B H 0.6908 0.9813 0.3846 0.077 Uiso 1 1 calc R . .
H54C H 0.6324 1.0606 0.3828 0.077 Uiso 1 1 calc R . .
C55 C 0.9456(5) 0.9484(3) 0.2673(3) 0.0585(15) Uani 1 1 d . . .
H55A H 0.9072 0.9094 0.2990 0.070 Uiso 1 1 calc R . .
H55B H 0.9849 0.9796 0.2954 0.070 Uiso 1 1 calc R . .
H55C H 1.0071 0.9283 0.2247 0.070 Uiso 1 1 calc R . .
C56 C 0.6220(4) 0.8491(2) 0.3451(2) 0.0251(8) Uani 1 1 d . . .
C57 C 0.4446(4) 0.8530(2) 0.4451(2) 0.0297(9) Uani 1 1 d . . .
C58 C 0.3916(4) 0.9048(2) 0.4026(2) 0.0316(9) Uani 1 1 d . . .
C59 C 0.4633(4) 0.9251(2) 0.3364(2) 0.0301(9) Uani 1 1 d . . .
H59 H 0.4299 0.9601 0.3093 0.036 Uiso 1 1 calc R . .
C60 C 0.2641(5) 0.9329(3) 0.4313(3) 0.0447(12) Uani 1 1 d . . .
H60A H 0.2080 0.8936 0.4355 0.054 Uiso 1 1 calc R . .
H60B H 0.2452 0.9692 0.3974 0.054 Uiso 1 1 calc R . .
H60C H 0.2548 0.9545 0.4801 0.054 Uiso 1 1 calc R . .
C61 C 0.4281(5) 0.7491(3) 0.2652(3) 0.0414(11) Uani 1 1 d . . .
C62 C 0.2957(6) 0.7505(5) 0.2909(4) 0.089(3) Uani 1 1 d . . .
H62A H 0.2674 0.7921 0.3231 0.107 Uiso 1 1 calc R . .
H62B H 0.2702 0.7065 0.3185 0.107 Uiso 1 1 calc R . .
H62C H 0.2602 0.7536 0.2484 0.107 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 N8 2.091(3) . ?
Rh1 N1 2.104(3) . ?
Rh1 C3 2.111(4) . ?
Rh1 C2 2.145(4) . ?
Rh1 C4 2.150(4) . ?
Rh1 C5 2.159(4) . ?
Rh1 C1 2.167(4) . ?
Rh1 O7 2.263(3) . ?
Rh1 C56 2.603(4) . ?
Rh2 N2 2.071(3) . ?
Rh2 N3 2.097(3) . ?
Rh2 C18 2.105(4) . ?
Rh2 C20 2.137(4) . ?
Rh2 C17 2.144(4) . ?
Rh2 C16 2.146(4) . ?
Rh2 C19 2.153(4) . ?
Rh2 O1 2.265(3) . ?
Rh2 C11 2.600(4) . ?
Rh3 N4 2.076(3) . ?
Rh3 C33 2.101(4) . ?
Rh3 N5 2.103(3) . ?
Rh3 C34 2.146(4) . ?
Rh3 C32 2.148(4) . ?
Rh3 C35 2.152(4) . ?
Rh3 C31 2.153(4) . ?
Rh3 O3 2.287(3) . ?
Rh3 C26 2.603(4) . ?
Rh4 N7 2.088(3) . ?
Rh4 N6 2.094(3) . ?
Rh4 C48 2.127(5) . ?
Rh4 C47 2.137(4) . ?
Rh4 C46 2.138(5) . ?
Rh4 C50 2.149(5) . ?
Rh4 C49 2.160(4) . ?
Rh4 O5 2.273(3) . ?
Ca1 O5 2.355(3) . ?
Ca1 O1 2.356(3) . ?
Ca1 O7 2.372(3) . ?
Ca1 O3 2.382(3) . ?
Ca1 O9 2.440(5) . ?
Ca1 O10 2.445(4) . ?
Ca1 N10 2.611(4) . ?
Ca1 N9 2.878(4) . ?
O1 C11 1.304(5) . ?
O2 C12 1.241(5) . ?
O3 C26 1.293(5) . ?
O4 C27 1.238(5) . ?
O5 C41 1.311(5) . ?
O6 C42 1.246(5) . ?
O7 C56 1.304(5) . ?
O8 C57 1.239(5) . ?
O9 N9 1.214(6) . ?
O10 N9 1.221(5) . ?
O11 N9 1.210(5) . ?
O121 N12 1.200(17) . ?
O122 N12 0.99(3) . ?
O123 N12 1.44(2) . ?
N1 C11 1.337(5) . ?
N1 C14 1.376(5) . ?
N2 C11 1.341(5) . ?
N2 C12 1.376(5) . ?
N3 C26 1.334(5) . ?
N3 C29 1.365(5) . ?
N4 C26 1.334(5) . ?
N4 C27 1.378(5) . ?
N5 C41 1.327(5) . ?
N5 C44 1.376(5) . ?
N6 C41 1.351(5) . ?
N6 C42 1.369(6) . ?
N7 C56 1.331(5) . ?
N7 C59 1.371(5) . ?
N8 C56 1.338(5) . ?
N8 C57 1.367(5) . ?
N10 C61 1.129(6) . ?
C1 C2 1.415(7) . ?
C1 C5 1.442(7) . ?
C1 C6 1.476(7) . ?
C2 C3 1.454(7) . ?
C2 C7 1.497(7) . ?
C3 C4 1.434(7) . ?
C3 C8 1.475(7) . ?
C4 C5 1.429(7) . ?
C4 C9 1.495(7) . ?
C5 C10 1.486(7) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C12 C13 1.452(6) . ?
C13 C14 1.348(6) . ?
C13 C15 1.493(6) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.415(7) . ?
C16 C20 1.442(6) . ?
C16 C21 1.496(7) . ?
C17 C18 1.444(7) . ?
C17 C22 1.481(6) . ?
C18 C19 1.438(6) . ?
C18 C23 1.474(7) . ?
C19 C20 1.413(6) . ?
C19 C24 1.489(6) . ?
C20 C25 1.486(6) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C27 C28 1.448(6) . ?
C28 C29 1.360(6) . ?
C28 C30 1.495(6) . ?
C29 H29 0.9500 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C32 1.424(7) . ?
C31 C35 1.455(6) . ?
C31 C36 1.489(7) . ?
C32 C33 1.460(7) . ?
C32 C37 1.474(7) . ?
C33 C34 1.424(7) . ?
C33 C38 1.503(7) . ?
C34 C35 1.417(7) . ?
C34 C39 1.488(7) . ?
C35 C40 1.483(7) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C42 C43 1.448(6) . ?
C43 C44 1.364(6) . ?
C43 C45 1.489(6) . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C47 1.415(7) . ?
C46 C50 1.440(6) . ?
C46 C51 1.483(7) . ?
C47 C48 1.449(6) . ?
C47 C52 1.492(6) . ?
C48 C49 1.446(7) . ?
C48 C53 1.483(7) . ?
C49 C50 1.414(7) . ?
C49 C54 1.492(6) . ?
C50 C55 1.501(7) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C57 C58 1.455(6) . ?
C58 C59 1.357(6) . ?
C58 C60 1.481(6) . ?
C59 H59 0.9500 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C61 C62 1.451(8) . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Rh1 N1 85.88(13) . . ?
N8 Rh1 C3 112.79(16) . . ?
N1 Rh1 C3 107.19(16) . . ?
N8 Rh1 C2 100.53(16) . . ?
N1 Rh1 C2 146.44(16) . . ?
C3 Rh1 C2 39.94(19) . . ?
N8 Rh1 C4 149.79(16) . . ?
N1 Rh1 C4 92.60(15) . . ?
C3 Rh1 C4 39.31(19) . . ?
C2 Rh1 C4 65.48(18) . . ?
N8 Rh1 C5 160.20(16) . . ?
N1 Rh1 C5 113.64(15) . . ?
C3 Rh1 C5 66.04(18) . . ?
C2 Rh1 C5 65.32(18) . . ?
C4 Rh1 C5 38.73(18) . . ?
N8 Rh1 C1 121.51(17) . . ?
N1 Rh1 C1 152.58(17) . . ?
C3 Rh1 C1 65.66(18) . . ?
C2 Rh1 C1 38.30(19) . . ?
C4 Rh1 C1 64.76(18) . . ?
C5 Rh1 C1 38.94(18) . . ?
N8 Rh1 O7 60.77(11) . . ?
N1 Rh1 O7 90.74(11) . . ?
C3 Rh1 O7 160.87(16) . . ?
C2 Rh1 O7 121.28(15) . . ?
C4 Rh1 O7 149.42(16) . . ?
C5 Rh1 O7 113.32(14) . . ?
C1 Rh1 O7 101.27(14) . . ?
N8 Rh1 C56 30.72(12) . . ?
N1 Rh1 C56 88.03(12) . . ?
C3 Rh1 C56 140.86(17) . . ?
C2 Rh1 C56 114.17(16) . . ?
C4 Rh1 C56 179.22(16) . . ?
C5 Rh1 C56 140.52(15) . . ?
C1 Rh1 C56 114.51(15) . . ?
O7 Rh1 C56 30.05(11) . . ?
N2 Rh2 N3 85.73(13) . . ?
N2 Rh2 C18 115.49(16) . . ?
N3 Rh2 C18 105.93(16) . . ?
N2 Rh2 C20 159.62(15) . . ?
N3 Rh2 C20 113.94(14) . . ?
C18 Rh2 C20 65.88(18) . . ?
N2 Rh2 C17 102.05(15) . . ?
N3 Rh2 C17 144.84(16) . . ?
C18 Rh2 C17 39.72(18) . . ?
C20 Rh2 C17 65.32(16) . . ?
N2 Rh2 C16 120.95(14) . . ?
N3 Rh2 C16 153.27(14) . . ?
C18 Rh2 C16 65.98(19) . . ?
C20 Rh2 C16 39.36(16) . . ?
C17 Rh2 C16 38.53(18) . . ?
N2 Rh2 C19 152.77(15) . . ?
N3 Rh2 C19 92.09(14) . . ?
C18 Rh2 C19 39.44(17) . . ?
C20 Rh2 C19 38.45(17) . . ?
C17 Rh2 C19 65.44(16) . . ?
C16 Rh2 C19 65.18(16) . . ?
N2 Rh2 O1 60.84(11) . . ?
N3 Rh2 O1 90.29(11) . . ?
C18 Rh2 O1 163.31(15) . . ?
C20 Rh2 O1 111.46(14) . . ?
C17 Rh2 O1 123.63(15) . . ?
C16 Rh2 O1 101.09(14) . . ?
C19 Rh2 O1 146.38(14) . . ?
N2 Rh2 C11 30.78(12) . . ?
N3 Rh2 C11 86.72(12) . . ?
C18 Rh2 C11 144.38(15) . . ?
C20 Rh2 C11 139.28(15) . . ?
C17 Rh2 C11 117.30(14) . . ?
C16 Rh2 C11 115.00(14) . . ?
C19 Rh2 C11 176.17(15) . . ?
O1 Rh2 C11 30.09(11) . . ?
N4 Rh3 C33 112.93(17) . . ?
N4 Rh3 N5 86.31(13) . . ?
C33 Rh3 N5 107.33(16) . . ?
N4 Rh3 C34 149.90(17) . . ?
C33 Rh3 C34 39.16(19) . . ?
N5 Rh3 C34 92.62(15) . . ?
N4 Rh3 C32 99.70(16) . . ?
C33 Rh3 C32 40.19(18) . . ?
N5 Rh3 C32 146.68(16) . . ?
C34 Rh3 C32 66.00(17) . . ?
N4 Rh3 C35 160.23(15) . . ?
C33 Rh3 C35 65.89(19) . . ?
N5 Rh3 C35 113.17(15) . . ?
C34 Rh3 C35 38.49(19) . . ?
C32 Rh3 C35 66.17(18) . . ?
N4 Rh3 C31 120.98(15) . . ?
C33 Rh3 C31 65.70(19) . . ?
N5 Rh3 C31 152.66(16) . . ?
C34 Rh3 C31 64.95(17) . . ?
C32 Rh3 C31 38.67(19) . . ?
C35 Rh3 C31 39.50(17) . . ?
N4 Rh3 O3 60.32(11) . . ?
C33 Rh3 O3 161.16(15) . . ?
N5 Rh3 O3 90.26(11) . . ?
C34 Rh3 O3 149.76(16) . . ?
C32 Rh3 O3 121.30(14) . . ?
C35 Rh3 O3 113.89(14) . . ?
C31 Rh3 O3 101.57(14) . . ?
N4 Rh3 C26 30.55(12) . . ?
C33 Rh3 C26 141.19(17) . . ?
N5 Rh3 C26 87.51(13) . . ?
C34 Rh3 C26 179.53(18) . . ?
C32 Rh3 C26 114.08(15) . . ?
C35 Rh3 C26 141.06(16) . . ?
C31 Rh3 C26 114.80(15) . . ?
O3 Rh3 C26 29.78(11) . . ?
N7 Rh4 N6 85.51(13) . . ?
N7 Rh4 C48 110.32(16) . . ?
N6 Rh4 C48 112.12(17) . . ?
N7 Rh4 C47 149.73(16) . . ?
N6 Rh4 C47 101.34(16) . . ?
C48 Rh4 C47 39.74(18) . . ?
N7 Rh4 C46 150.41(16) . . ?
N6 Rh4 C46 123.75(15) . . ?
C48 Rh4 C46 65.57(19) . . ?
C47 Rh4 C46 38.66(19) . . ?
N7 Rh4 C50 111.31(15) . . ?
N6 Rh4 C50 162.91(15) . . ?
C48 Rh4 C50 65.9(2) . . ?
C47 Rh4 C50 65.81(18) . . ?
C46 Rh4 C50 39.25(17) . . ?
N7 Rh4 C49 93.17(15) . . ?
N6 Rh4 C49 148.42(18) . . ?
C48 Rh4 C49 39.41(19) . . ?
C47 Rh4 C49 65.61(17) . . ?
C46 Rh4 C49 64.66(17) . . ?
C50 Rh4 C49 38.31(19) . . ?
N7 Rh4 O5 91.87(11) . . ?
N6 Rh4 O5 60.65(12) . . ?
C48 Rh4 O5 156.57(14) . . ?
C47 Rh4 O5 117.32(14) . . ?
C46 Rh4 O5 98.84(14) . . ?
C50 Rh4 O5 113.84(16) . . ?
C49 Rh4 O5 150.83(17) . . ?
O5 Ca1 O1 159.25(11) . . ?
O5 Ca1 O7 88.80(10) . . ?
O1 Ca1 O7 88.70(9) . . ?
O5 Ca1 O3 87.19(9) . . ?
O1 Ca1 O3 87.53(9) . . ?
O7 Ca1 O3 158.22(11) . . ?
O5 Ca1 O9 110.29(18) . . ?
O1 Ca1 O9 89.16(17) . . ?
O7 Ca1 O9 76.90(15) . . ?
O3 Ca1 O9 124.45(16) . . ?
O5 Ca1 O10 89.04(16) . . ?
O1 Ca1 O10 109.78(17) . . ?
O7 Ca1 O10 121.18(14) . . ?
O3 Ca1 O10 80.16(14) . . ?
O9 Ca1 O10 49.49(14) . . ?
O5 Ca1 N10 79.07(11) . . ?
O1 Ca1 N10 80.23(11) . . ?
O7 Ca1 N10 79.06(11) . . ?
O3 Ca1 N10 79.16(11) . . ?
O9 Ca1 N10 153.89(14) . . ?
O10 Ca1 N10 156.57(13) . . ?
O5 Ca1 N9 100.87(11) . . ?
O1 Ca1 N9 99.86(11) . . ?
O7 Ca1 N9 99.32(11) . . ?
O3 Ca1 N9 102.46(11) . . ?
O9 Ca1 N9 24.66(12) . . ?
O10 Ca1 N9 24.84(12) . . ?
N10 Ca1 N9 178.38(12) . . ?
C11 O1 Rh2 89.3(2) . . ?
C11 O1 Ca1 122.2(2) . . ?
Rh2 O1 Ca1 116.91(10) . . ?
C26 O3 Rh3 88.8(2) . . ?
C26 O3 Ca1 121.9(2) . . ?
Rh3 O3 Ca1 117.44(12) . . ?
C41 O5 Rh4 90.1(2) . . ?
C41 O5 Ca1 122.3(2) . . ?
Rh4 O5 Ca1 115.22(11) . . ?
C56 O7 Rh1 89.5(2) . . ?
C56 O7 Ca1 122.1(2) . . ?
Rh1 O7 Ca1 116.49(12) . . ?
N9 O9 Ca1 98.3(3) . . ?
N9 O10 Ca1 97.9(3) . . ?
C11 N1 C14 114.7(3) . . ?
C11 N1 Rh1 124.3(3) . . ?
C14 N1 Rh1 119.1(3) . . ?
C11 N2 C12 122.5(3) . . ?
C11 N2 Rh2 97.0(2) . . ?
C12 N2 Rh2 139.3(3) . . ?
C26 N3 C29 115.2(3) . . ?
C26 N3 Rh2 123.2(3) . . ?
C29 N3 Rh2 119.6(3) . . ?
C26 N4 C27 123.6(3) . . ?
C26 N4 Rh3 97.1(2) . . ?
C27 N4 Rh3 138.8(3) . . ?
C41 N5 C44 115.0(3) . . ?
C41 N5 Rh3 124.7(3) . . ?
C44 N5 Rh3 118.8(3) . . ?
C41 N6 C42 121.6(4) . . ?
C41 N6 Rh4 97.0(3) . . ?
C42 N6 Rh4 140.5(3) . . ?
C56 N7 C59 115.2(3) . . ?
C56 N7 Rh4 124.1(3) . . ?
C59 N7 Rh4 119.6(3) . . ?
C56 N8 C57 122.2(3) . . ?
C56 N8 Rh1 96.3(3) . . ?
C57 N8 Rh1 140.6(3) . . ?
O11 N9 O9 122.6(5) . . ?
O11 N9 O10 123.1(4) . . ?
O9 N9 O10 114.3(4) . . ?
O11 N9 Ca1 178.6(4) . . ?
O9 N9 Ca1 57.0(3) . . ?
O10 N9 Ca1 57.3(3) . . ?
C61 N10 Ca1 177.1(4) . . ?
O122 N12 O121 131(3) . . ?
O122 N12 O123 123(3) . . ?
O121 N12 O123 101.6(16) . . ?
C2 C1 C5 108.8(4) . . ?
C2 C1 C6 128.0(5) . . ?
C5 C1 C6 123.2(5) . . ?
C2 C1 Rh1 70.0(3) . . ?
C5 C1 Rh1 70.2(2) . . ?
C6 C1 Rh1 125.8(3) . . ?
C1 C2 C3 107.9(4) . . ?
C1 C2 C7 125.6(5) . . ?
C3 C2 C7 126.5(5) . . ?
C1 C2 Rh1 71.7(2) . . ?
C3 C2 Rh1 68.8(2) . . ?
C7 C2 Rh1 125.2(4) . . ?
C4 C3 C2 107.1(4) . . ?
C4 C3 C8 127.0(5) . . ?
C2 C3 C8 125.7(5) . . ?
C4 C3 Rh1 71.8(2) . . ?
C2 C3 Rh1 71.3(2) . . ?
C8 C3 Rh1 125.6(3) . . ?
C5 C4 C3 108.8(4) . . ?
C5 C4 C9 125.6(5) . . ?
C3 C4 C9 125.6(5) . . ?
C5 C4 Rh1 71.0(2) . . ?
C3 C4 Rh1 68.9(2) . . ?
C9 C4 Rh1 124.5(3) . . ?
C4 C5 C1 107.3(4) . . ?
C4 C5 C10 125.8(5) . . ?
C1 C5 C10 126.7(5) . . ?
C4 C5 Rh1 70.3(3) . . ?
C1 C5 Rh1 70.8(3) . . ?
C10 C5 Rh1 128.0(3) . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O1 C11 N1 123.0(3) . . ?
O1 C11 N2 112.7(3) . . ?
N1 C11 N2 124.2(4) . . ?
O1 C11 Rh2 60.57(19) . . ?
N1 C11 Rh2 175.2(3) . . ?
N2 C11 Rh2 52.23(19) . . ?
O2 C12 N2 119.8(4) . . ?
O2 C12 C13 125.5(4) . . ?
N2 C12 C13 114.7(3) . . ?
C14 C13 C12 118.7(4) . . ?
C14 C13 C15 122.3(4) . . ?
C12 C13 C15 119.0(4) . . ?
C13 C14 N1 124.8(4) . . ?
C13 C14 H14 117.6 . . ?
N1 C14 H14 117.6 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 C16 C20 107.9(4) . . ?
C17 C16 C21 127.8(4) . . ?
C20 C16 C21 124.3(5) . . ?
C17 C16 Rh2 70.7(3) . . ?
C20 C16 Rh2 70.0(2) . . ?
C21 C16 Rh2 126.0(3) . . ?
C16 C17 C18 108.1(4) . . ?
C16 C17 C22 126.1(5) . . ?
C18 C17 C22 125.8(5) . . ?
C16 C17 Rh2 70.8(3) . . ?
C18 C17 Rh2 68.7(2) . . ?
C22 C17 Rh2 125.5(3) . . ?
C19 C18 C17 107.4(4) . . ?
C19 C18 C23 127.2(4) . . ?
C17 C18 C23 125.2(5) . . ?
C19 C18 Rh2 72.1(2) . . ?
C17 C18 Rh2 71.6(3) . . ?
C23 C18 Rh2 126.1(4) . . ?
C20 C19 C18 108.1(4) . . ?
C20 C19 C24 127.2(4) . . ?
C18 C19 C24 124.6(4) . . ?
C20 C19 Rh2 70.2(2) . . ?
C18 C19 Rh2 68.5(2) . . ?
C24 C19 Rh2 125.1(3) . . ?
C19 C20 C16 108.4(4) . . ?
C19 C20 C25 125.9(4) . . ?
C16 C20 C25 125.7(4) . . ?
C19 C20 Rh2 71.4(2) . . ?
C16 C20 Rh2 70.6(2) . . ?
C25 C20 Rh2 124.1(3) . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C16 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C17 C22 H22A 109.5 . . ?
C17 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C17 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C18 C23 H23A 109.5 . . ?
C18 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C18 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C19 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C19 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O3 C26 N4 113.7(3) . . ?
O3 C26 N3 123.0(3) . . ?
N4 C26 N3 123.3(4) . . ?
O3 C26 Rh3 61.43(18) . . ?
N4 C26 Rh3 52.32(19) . . ?
N3 C26 Rh3 175.3(3) . . ?
O4 C27 N4 120.8(4) . . ?
O4 C27 C28 124.9(4) . . ?
N4 C27 C28 114.3(3) . . ?
C29 C28 C27 118.0(4) . . ?
C29 C28 C30 122.9(4) . . ?
C27 C28 C30 119.1(4) . . ?
C28 C29 N3 125.2(4) . . ?
C28 C29 H29 117.4 . . ?
N3 C29 H29 117.4 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C32 C31 C35 109.2(4) . . ?
C32 C31 C36 125.8(4) . . ?
C35 C31 C36 124.9(5) . . ?
C32 C31 Rh3 70.5(3) . . ?
C35 C31 Rh3 70.2(2) . . ?
C36 C31 Rh3 127.0(3) . . ?
C31 C32 C33 106.3(4) . . ?
C31 C32 C37 127.5(5) . . ?
C33 C32 C37 126.2(5) . . ?
C31 C32 Rh3 70.8(2) . . ?
C33 C32 Rh3 68.2(2) . . ?
C37 C32 Rh3 125.1(4) . . ?
C34 C33 C32 108.3(4) . . ?
C34 C33 C38 127.0(5) . . ?
C32 C33 C38 124.4(5) . . ?
C34 C33 Rh3 72.1(2) . . ?
C32 C33 Rh3 71.7(2) . . ?
C38 C33 Rh3 126.2(4) . . ?
C35 C34 C33 109.0(4) . . ?
C35 C34 C39 125.7(5) . . ?
C33 C34 C39 125.2(5) . . ?
C35 C34 Rh3 71.0(2) . . ?
C33 C34 Rh3 68.7(2) . . ?
C39 C34 Rh3 125.4(3) . . ?
C34 C35 C31 107.0(4) . . ?
C34 C35 C40 127.0(4) . . ?
C31 C35 C40 125.9(5) . . ?
C34 C35 Rh3 70.5(3) . . ?
C31 C35 Rh3 70.3(2) . . ?
C40 C35 Rh3 126.6(3) . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
O5 C41 N5 123.1(4) . . ?
O5 C41 N6 112.2(4) . . ?
N5 C41 N6 124.7(4) . . ?
O6 C42 N6 119.8(4) . . ?
O6 C42 C43 124.5(4) . . ?
N6 C42 C43 115.7(4) . . ?
C44 C43 C42 118.1(4) . . ?
C44 C43 C45 122.7(4) . . ?
C42 C43 C45 119.2(4) . . ?
C43 C44 N5 124.4(4) . . ?
C43 C44 H44 117.8 . . ?
N5 C44 H44 117.8 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C47 C46 C50 109.3(4) . . ?
C47 C46 C51 126.7(4) . . ?
C50 C46 C51 124.0(5) . . ?
C47 C46 Rh4 70.6(3) . . ?
C50 C46 Rh4 70.8(3) . . ?
C51 C46 Rh4 124.4(3) . . ?
C46 C47 C48 107.5(4) . . ?
C46 C47 C52 127.3(4) . . ?
C48 C47 C52 125.2(5) . . ?
C46 C47 Rh4 70.7(2) . . ?
C48 C47 Rh4 69.7(2) . . ?
C52 C47 Rh4 124.7(4) . . ?
C49 C48 C47 107.1(4) . . ?
C49 C48 C53 127.0(5) . . ?
C47 C48 C53 125.7(5) . . ?
C49 C48 Rh4 71.5(3) . . ?
C47 C48 Rh4 70.5(3) . . ?
C53 C48 Rh4 126.7(4) . . ?
C50 C49 C48 108.8(4) . . ?
C50 C49 C54 125.1(5) . . ?
C48 C49 C54 126.0(5) . . ?
C50 C49 Rh4 70.4(2) . . ?
C48 C49 Rh4 69.1(2) . . ?
C54 C49 Rh4 124.5(4) . . ?
C49 C50 C46 107.3(4) . . ?
C49 C50 C55 127.8(4) . . ?
C46 C50 C55 124.7(5) . . ?
C49 C50 Rh4 71.2(3) . . ?
C46 C50 Rh4 70.0(3) . . ?
C55 C50 Rh4 127.1(4) . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C50 C55 H55A 109.5 . . ?
C50 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C50 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
O7 C56 N7 122.6(4) . . ?
O7 C56 N8 113.4(3) . . ?
N7 C56 N8 124.0(4) . . ?
O7 C56 Rh1 60.41(19) . . ?
N7 C56 Rh1 177.0(3) . . ?
N8 C56 Rh1 53.0(2) . . ?
O8 C57 N8 120.4(4) . . ?
O8 C57 C58 123.9(4) . . ?
N8 C57 C58 115.8(4) . . ?
C59 C58 C57 117.3(4) . . ?
C59 C58 C60 122.4(4) . . ?
C57 C58 C60 120.3(4) . . ?
C58 C59 N7 125.1(4) . . ?
C58 C59 H59 117.5 . . ?
N7 C59 H59 117.5 . . ?
C58 C60 H60A 109.5 . . ?
C58 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C58 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
N10 C61 C62 178.9(6) . . ?
C61 C62 H62A 109.5 . . ?
C61 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C61 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Rh2 O1 C11 -2.0(2) . . . . ?
N3 Rh2 O1 C11 83.0(2) . . . . ?
C18 Rh2 O1 C11 -83.6(6) . . . . ?
C20 Rh2 O1 C11 -161.1(2) . . . . ?
C17 Rh2 O1 C11 -87.2(3) . . . . ?
C16 Rh2 O1 C11 -121.4(2) . . . . ?
C19 Rh2 O1 C11 177.2(3) . . . . ?
N2 Rh2 O1 Ca1 -128.22(17) . . . . ?
N3 Rh2 O1 Ca1 -43.28(15) . . . . ?
C18 Rh2 O1 Ca1 150.1(5) . . . . ?
C20 Rh2 O1 Ca1 72.70(17) . . . . ?
C17 Rh2 O1 Ca1 146.59(17) . . . . ?
C16 Rh2 O1 Ca1 112.39(16) . . . . ?
C19 Rh2 O1 Ca1 50.9(3) . . . . ?
C11 Rh2 O1 Ca1 -126.2(3) . . . . ?
O5 Ca1 O1 C11 -27.3(4) . . . . ?
O7 Ca1 O1 C11 55.9(3) . . . . ?
O3 Ca1 O1 C11 -102.7(3) . . . . ?
O9 Ca1 O1 C11 132.8(3) . . . . ?
O10 Ca1 O1 C11 178.7(3) . . . . ?
N10 Ca1 O1 C11 -23.2(3) . . . . ?
N9 Ca1 O1 C11 155.1(3) . . . . ?
O5 Ca1 O1 Rh2 80.4(3) . . . . ?
O7 Ca1 O1 Rh2 163.56(13) . . . . ?
O3 Ca1 O1 Rh2 5.01(13) . . . . ?
O9 Ca1 O1 Rh2 -119.52(17) . . . . ?
O10 Ca1 O1 Rh2 -73.60(17) . . . . ?
N10 Ca1 O1 Rh2 84.44(14) . . . . ?
N9 Ca1 O1 Rh2 -97.21(14) . . . . ?
N4 Rh3 O3 C26 -1.1(2) . . . . ?
C33 Rh3 O3 C26 -74.7(6) . . . . ?
N5 Rh3 O3 C26 84.5(2) . . . . ?
C34 Rh3 O3 C26 -179.8(3) . . . . ?
C32 Rh3 O3 C26 -84.2(3) . . . . ?
C35 Rh3 O3 C26 -159.8(2) . . . . ?
C31 Rh3 O3 C26 -120.3(2) . . . . ?
N4 Rh3 O3 Ca1 -126.89(18) . . . . ?
C33 Rh3 O3 Ca1 159.4(5) . . . . ?
N5 Rh3 O3 Ca1 -41.29(15) . . . . ?
C34 Rh3 O3 Ca1 54.4(3) . . . . ?
C32 Rh3 O3 Ca1 149.98(18) . . . . ?
C35 Rh3 O3 Ca1 74.33(18) . . . . ?
C31 Rh3 O3 Ca1 113.90(17) . . . . ?
C26 Rh3 O3 Ca1 -125.8(3) . . . . ?
O5 Ca1 O3 C26 -103.3(3) . . . . ?
O1 Ca1 O3 C26 56.6(3) . . . . ?
O7 Ca1 O3 C26 -23.7(4) . . . . ?
O9 Ca1 O3 C26 143.9(3) . . . . ?
O10 Ca1 O3 C26 167.1(3) . . . . ?
N10 Ca1 O3 C26 -23.9(3) . . . . ?
N9 Ca1 O3 C26 156.1(3) . . . . ?
O5 Ca1 O3 Rh3 3.85(13) . . . . ?
O1 Ca1 O3 Rh3 163.78(13) . . . . ?
O7 Ca1 O3 Rh3 83.5(3) . . . . ?
O9 Ca1 O3 Rh3 -108.9(2) . . . . ?
O10 Ca1 O3 Rh3 -85.66(19) . . . . ?
N10 Ca1 O3 Rh3 83.26(14) . . . . ?
N9 Ca1 O3 Rh3 -96.67(14) . . . . ?
N7 Rh4 O5 C41 82.5(2) . . . . ?
N6 Rh4 O5 C41 -1.3(2) . . . . ?
C48 Rh4 O5 C41 -79.1(5) . . . . ?
C47 Rh4 O5 C41 -89.2(3) . . . . ?
C46 Rh4 O5 C41 -125.2(2) . . . . ?
C50 Rh4 O5 C41 -163.1(2) . . . . ?
C49 Rh4 O5 C41 -177.6(3) . . . . ?
N7 Rh4 O5 Ca1 -43.75(15) . . . . ?
N6 Rh4 O5 Ca1 -127.54(17) . . . . ?
C48 Rh4 O5 Ca1 154.6(4) . . . . ?
C47 Rh4 O5 Ca1 144.56(18) . . . . ?
C46 Rh4 O5 Ca1 108.57(17) . . . . ?
C50 Rh4 O5 Ca1 70.58(18) . . . . ?
C49 Rh4 O5 Ca1 56.2(3) . . . . ?
O1 Ca1 O5 C41 -18.2(4) . . . . ?
O7 Ca1 O5 C41 -101.3(3) . . . . ?
O3 Ca1 O5 C41 57.3(3) . . . . ?
O9 Ca1 O5 C41 -176.9(3) . . . . ?
O10 Ca1 O5 C41 137.4(3) . . . . ?
N10 Ca1 O5 C41 -22.2(3) . . . . ?
N9 Ca1 O5 C41 159.4(3) . . . . ?
O1 Ca1 O5 Rh4 89.3(3) . . . . ?
O7 Ca1 O5 Rh4 6.13(14) . . . . ?
O3 Ca1 O5 Rh4 164.72(13) . . . . ?
O9 Ca1 O5 Rh4 -69.42(18) . . . . ?
O10 Ca1 O5 Rh4 -115.09(17) . . . . ?
N10 Ca1 O5 Rh4 85.22(14) . . . . ?
N9 Ca1 O5 Rh4 -93.13(14) . . . . ?
N8 Rh1 O7 C56 -0.1(2) . . . . ?
N1 Rh1 O7 C56 84.8(2) . . . . ?
C3 Rh1 O7 C56 -75.1(5) . . . . ?
C2 Rh1 O7 C56 -84.6(3) . . . . ?
C4 Rh1 O7 C56 -178.8(3) . . . . ?
C5 Rh1 O7 C56 -159.0(2) . . . . ?
C1 Rh1 O7 C56 -120.0(2) . . . . ?
N8 Rh1 O7 Ca1 -126.21(18) . . . . ?
N1 Rh1 O7 Ca1 -41.35(15) . . . . ?
C3 Rh1 O7 Ca1 158.8(4) . . . . ?
C2 Rh1 O7 Ca1 149.23(18) . . . . ?
C4 Rh1 O7 Ca1 55.0(3) . . . . ?
C5 Rh1 O7 Ca1 74.90(18) . . . . ?
C1 Rh1 O7 Ca1 113.84(18) . . . . ?
C56 Rh1 O7 Ca1 -126.1(3) . . . . ?
O5 Ca1 O7 C56 55.7(3) . . . . ?
O1 Ca1 O7 C56 -103.7(3) . . . . ?
O3 Ca1 O7 C56 -23.6(4) . . . . ?
O9 Ca1 O7 C56 166.9(3) . . . . ?
O10 Ca1 O7 C56 143.9(3) . . . . ?
N10 Ca1 O7 C56 -23.4(3) . . . . ?
N9 Ca1 O7 C56 156.5(3) . . . . ?
O5 Ca1 O7 Rh1 163.29(14) . . . . ?
O1 Ca1 O7 Rh1 3.89(14) . . . . ?
O3 Ca1 O7 Rh1 83.9(3) . . . . ?
O9 Ca1 O7 Rh1 -85.6(2) . . . . ?
O10 Ca1 O7 Rh1 -108.6(2) . . . . ?
N10 Ca1 O7 Rh1 84.18(14) . . . . ?
N9 Ca1 O7 Rh1 -95.89(14) . . . . ?
O5 Ca1 O9 N9 -71.1(5) . . . . ?
O1 Ca1 O9 N9 116.3(4) . . . . ?
O7 Ca1 O9 N9 -154.9(5) . . . . ?
O3 Ca1 O9 N9 29.8(5) . . . . ?
O10 Ca1 O9 N9 -1.0(4) . . . . ?
N10 Ca1 O9 N9 -178.3(3) . . . . ?
O5 Ca1 O10 N9 119.0(4) . . . . ?
O1 Ca1 O10 N9 -69.9(4) . . . . ?
O7 Ca1 O10 N9 31.0(5) . . . . ?
O3 Ca1 O10 N9 -153.7(4) . . . . ?
O9 Ca1 O10 N9 1.0(4) . . . . ?
N10 Ca1 O10 N9 178.0(3) . . . . ?
N8 Rh1 N1 C11 129.6(3) . . . . ?
C3 Rh1 N1 C11 -117.8(3) . . . . ?
C2 Rh1 N1 C11 -127.5(3) . . . . ?
C4 Rh1 N1 C11 -80.6(3) . . . . ?
C5 Rh1 N1 C11 -47.0(3) . . . . ?
C1 Rh1 N1 C11 -47.7(5) . . . . ?
O7 Rh1 N1 C11 69.0(3) . . . . ?
C56 Rh1 N1 C11 98.9(3) . . . . ?
N8 Rh1 N1 C14 -66.8(3) . . . . ?
C3 Rh1 N1 C14 45.8(3) . . . . ?
C2 Rh1 N1 C14 36.1(5) . . . . ?
C4 Rh1 N1 C14 83.0(3) . . . . ?
C5 Rh1 N1 C14 116.6(3) . . . . ?
C1 Rh1 N1 C14 115.9(4) . . . . ?
O7 Rh1 N1 C14 -127.4(3) . . . . ?
C56 Rh1 N1 C14 -97.5(3) . . . . ?
N3 Rh2 N2 C11 -90.8(2) . . . . ?
C18 Rh2 N2 C11 163.6(2) . . . . ?
C20 Rh2 N2 C11 74.6(5) . . . . ?
C17 Rh2 N2 C11 123.9(3) . . . . ?
C16 Rh2 N2 C11 87.5(3) . . . . ?
C19 Rh2 N2 C11 -177.0(3) . . . . ?
O1 Rh2 N2 C11 2.0(2) . . . . ?
N3 Rh2 N2 C12 75.8(4) . . . . ?
C18 Rh2 N2 C12 -29.8(5) . . . . ?
C20 Rh2 N2 C12 -118.9(5) . . . . ?
C17 Rh2 N2 C12 -69.5(4) . . . . ?
C16 Rh2 N2 C12 -106.0(4) . . . . ?
C19 Rh2 N2 C12 -10.5(6) . . . . ?
O1 Rh2 N2 C12 168.5(5) . . . . ?
C11 Rh2 N2 C12 166.5(6) . . . . ?
N2 Rh2 N3 C26 130.5(3) . . . . ?
C18 Rh2 N3 C26 -114.2(3) . . . . ?
C20 Rh2 N3 C26 -44.0(4) . . . . ?
C17 Rh2 N3 C26 -124.6(3) . . . . ?
C16 Rh2 N3 C26 -46.2(5) . . . . ?
C19 Rh2 N3 C26 -76.7(3) . . . . ?
O1 Rh2 N3 C26 69.8(3) . . . . ?
C11 Rh2 N3 C26 99.7(3) . . . . ?
N2 Rh2 N3 C29 -66.1(3) . . . . ?
C18 Rh2 N3 C29 49.2(3) . . . . ?
C20 Rh2 N3 C29 119.4(3) . . . . ?
C17 Rh2 N3 C29 38.8(4) . . . . ?
C16 Rh2 N3 C29 117.2(4) . . . . ?
C19 Rh2 N3 C29 86.7(3) . . . . ?
O1 Rh2 N3 C29 -126.9(3) . . . . ?
C11 Rh2 N3 C29 -97.0(3) . . . . ?
C33 Rh3 N4 C26 161.4(3) . . . . ?
N5 Rh3 N4 C26 -91.4(2) . . . . ?
C34 Rh3 N4 C26 179.8(3) . . . . ?
C32 Rh3 N4 C26 121.7(3) . . . . ?
C35 Rh3 N4 C26 79.1(5) . . . . ?
C31 Rh3 N4 C26 86.9(3) . . . . ?
O3 Rh3 N4 C26 1.0(2) . . . . ?
C33 Rh3 N4 C27 -27.2(5) . . . . ?
N5 Rh3 N4 C27 80.1(4) . . . . ?
C34 Rh3 N4 C27 -8.8(6) . . . . ?
C32 Rh3 N4 C27 -66.9(4) . . . . ?
C35 Rh3 N4 C27 -109.4(6) . . . . ?
C31 Rh3 N4 C27 -101.7(4) . . . . ?
O3 Rh3 N4 C27 172.5(5) . . . . ?
C26 Rh3 N4 C27 171.5(6) . . . . ?
N4 Rh3 N5 C41 127.0(3) . . . . ?
C33 Rh3 N5 C41 -120.1(3) . . . . ?
C34 Rh3 N5 C41 -83.1(3) . . . . ?
C32 Rh3 N5 C41 -130.9(4) . . . . ?
C35 Rh3 N5 C41 -49.5(4) . . . . ?
C31 Rh3 N5 C41 -49.7(5) . . . . ?
O3 Rh3 N5 C41 66.8(3) . . . . ?
C26 Rh3 N5 C41 96.4(3) . . . . ?
N4 Rh3 N5 C44 -67.7(3) . . . . ?
C33 Rh3 N5 C44 45.2(3) . . . . ?
C34 Rh3 N5 C44 82.2(3) . . . . ?
C32 Rh3 N5 C44 34.4(5) . . . . ?
C35 Rh3 N5 C44 115.8(3) . . . . ?
C31 Rh3 N5 C44 115.6(4) . . . . ?
O3 Rh3 N5 C44 -127.9(3) . . . . ?
C26 Rh3 N5 C44 -98.3(3) . . . . ?
N7 Rh4 N6 C41 -93.4(2) . . . . ?
C48 Rh4 N6 C41 156.4(2) . . . . ?
C47 Rh4 N6 C41 116.3(3) . . . . ?
C46 Rh4 N6 C41 81.8(3) . . . . ?
C50 Rh4 N6 C41 76.7(6) . . . . ?
C49 Rh4 N6 C41 177.8(3) . . . . ?
O5 Rh4 N6 C41 1.2(2) . . . . ?
N7 Rh4 N6 C42 74.6(4) . . . . ?
C48 Rh4 N6 C42 -35.5(5) . . . . ?
C47 Rh4 N6 C42 -75.6(5) . . . . ?
C46 Rh4 N6 C42 -110.1(4) . . . . ?
C50 Rh4 N6 C42 -115.3(6) . . . . ?
C49 Rh4 N6 C42 -14.2(6) . . . . ?
O5 Rh4 N6 C42 169.3(5) . . . . ?
N6 Rh4 N7 C56 127.9(3) . . . . ?
C48 Rh4 N7 C56 -120.2(3) . . . . ?
C47 Rh4 N7 C56 -127.2(4) . . . . ?
C46 Rh4 N7 C56 -44.1(5) . . . . ?
C50 Rh4 N7 C56 -49.0(4) . . . . ?
C49 Rh4 N7 C56 -83.7(3) . . . . ?
O5 Rh4 N7 C56 67.5(3) . . . . ?
N6 Rh4 N7 C59 -64.7(3) . . . . ?
C48 Rh4 N7 C59 47.2(3) . . . . ?
C47 Rh4 N7 C59 40.2(5) . . . . ?
C46 Rh4 N7 C59 123.3(4) . . . . ?
C50 Rh4 N7 C59 118.4(3) . . . . ?
C49 Rh4 N7 C59 83.7(3) . . . . ?
O5 Rh4 N7 C59 -125.1(3) . . . . ?
N1 Rh1 N8 C56 -93.1(2) . . . . ?
C3 Rh1 N8 C56 160.0(3) . . . . ?
C2 Rh1 N8 C56 120.2(3) . . . . ?
C4 Rh1 N8 C56 178.8(3) . . . . ?
C5 Rh1 N8 C56 77.7(5) . . . . ?
C1 Rh1 N8 C56 85.5(3) . . . . ?
O7 Rh1 N8 C56 0.1(2) . . . . ?
N1 Rh1 N8 C57 75.2(4) . . . . ?
C3 Rh1 N8 C57 -31.7(5) . . . . ?
C2 Rh1 N8 C57 -71.6(5) . . . . ?
C4 Rh1 N8 C57 -12.9(6) . . . . ?
C5 Rh1 N8 C57 -114.1(6) . . . . ?
C1 Rh1 N8 C57 -106.3(5) . . . . ?
O7 Rh1 N8 C57 168.3(5) . . . . ?
C56 Rh1 N8 C57 168.3(6) . . . . ?
Ca1 O9 N9 O11 -178.4(4) . . . . ?
Ca1 O9 N9 O10 1.6(6) . . . . ?
Ca1 O10 N9 O11 178.4(4) . . . . ?
Ca1 O10 N9 O9 -1.6(6) . . . . ?
O5 Ca1 N9 O11 -171(100) . . . . ?
O1 Ca1 N9 O11 9(15) . . . . ?
O7 Ca1 N9 O11 99(15) . . . . ?
O3 Ca1 N9 O11 -81(15) . . . . ?
O9 Ca1 N9 O11 74(15) . . . . ?
O10 Ca1 N9 O11 -108(15) . . . . ?
N10 Ca1 N9 O11 101(15) . . . . ?
O5 Ca1 N9 O9 115.3(5) . . . . ?
O1 Ca1 N9 O9 -65.5(5) . . . . ?
O7 Ca1 N9 O9 24.8(5) . . . . ?
O3 Ca1 N9 O9 -155.2(5) . . . . ?
O10 Ca1 N9 O9 178.2(7) . . . . ?
N10 Ca1 N9 O9 27(4) . . . . ?
O5 Ca1 N9 O10 -62.9(4) . . . . ?
O1 Ca1 N9 O10 116.2(4) . . . . ?
O7 Ca1 N9 O10 -153.5(4) . . . . ?
O3 Ca1 N9 O10 26.6(4) . . . . ?
O9 Ca1 N9 O10 -178.2(7) . . . . ?
N10 Ca1 N9 O10 -151(4) . . . . ?
O5 Ca1 N10 C61 -133(8) . . . . ?
O1 Ca1 N10 C61 48(8) . . . . ?
O7 Ca1 N10 C61 -42(8) . . . . ?
O3 Ca1 N10 C61 138(8) . . . . ?
O9 Ca1 N10 C61 -19(8) . . . . ?
O10 Ca1 N10 C61 166(8) . . . . ?
N9 Ca1 N10 C61 -45(10) . . . . ?
O12 O122 N12 O121 54(3) . . . . ?
O12 O122 N12 O123 -154(2) . . . . ?
O121 O12 N12 O122 142(3) . . . . ?
O122 O12 N12 O121 -142(3) . . . . ?
O122 O12 N12 O123 93(6) . . . . ?
O121 O12 N12 O123 -125(5) . . . . ?
O12 O121 N12 O122 -42(2) . . . . ?
O12 O121 N12 O123 162.1(17) . . . . ?
N8 Rh1 C1 C2 64.5(3) . . . . ?
N1 Rh1 C1 C2 -118.6(4) . . . . ?
C3 Rh1 C1 C2 -38.3(3) . . . . ?
C4 Rh1 C1 C2 -81.8(3) . . . . ?
C5 Rh1 C1 C2 -119.7(4) . . . . ?
O7 Rh1 C1 C2 127.0(3) . . . . ?
C56 Rh1 C1 C2 98.5(3) . . . . ?
N8 Rh1 C1 C5 -175.8(2) . . . . ?
N1 Rh1 C1 C5 1.1(5) . . . . ?
C3 Rh1 C1 C5 81.4(3) . . . . ?
C2 Rh1 C1 C5 119.7(4) . . . . ?
C4 Rh1 C1 C5 37.9(3) . . . . ?
O7 Rh1 C1 C5 -113.3(2) . . . . ?
C56 Rh1 C1 C5 -141.8(2) . . . . ?
N8 Rh1 C1 C6 -58.6(5) . . . . ?
N1 Rh1 C1 C6 118.3(5) . . . . ?
C3 Rh1 C1 C6 -161.3(6) . . . . ?
C2 Rh1 C1 C6 -123.1(6) . . . . ?
C4 Rh1 C1 C6 155.2(6) . . . . ?
C5 Rh1 C1 C6 117.3(6) . . . . ?
O7 Rh1 C1 C6 3.9(5) . . . . ?
C56 Rh1 C1 C6 -24.5(5) . . . . ?
C5 C1 C2 C3 -0.2(5) . . . . ?
C6 C1 C2 C3 179.9(4) . . . . ?
Rh1 C1 C2 C3 59.5(3) . . . . ?
C5 C1 C2 C7 179.6(4) . . . . ?
C6 C1 C2 C7 -0.3(8) . . . . ?
Rh1 C1 C2 C7 -120.7(5) . . . . ?
C5 C1 C2 Rh1 -59.7(3) . . . . ?
C6 C1 C2 Rh1 120.4(5) . . . . ?
N8 Rh1 C2 C1 -128.5(3) . . . . ?
N1 Rh1 C2 C1 133.0(3) . . . . ?
C3 Rh1 C2 C1 118.5(4) . . . . ?
C4 Rh1 C2 C1 79.7(3) . . . . ?
C5 Rh1 C2 C1 36.9(3) . . . . ?
O7 Rh1 C2 C1 -66.4(3) . . . . ?
C56 Rh1 C2 C1 -99.5(3) . . . . ?
N8 Rh1 C2 C3 113.1(3) . . . . ?
N1 Rh1 C2 C3 14.6(5) . . . . ?
C4 Rh1 C2 C3 -38.7(3) . . . . ?
C5 Rh1 C2 C3 -81.5(3) . . . . ?
C1 Rh1 C2 C3 -118.5(4) . . . . ?
O7 Rh1 C2 C3 175.1(2) . . . . ?
C56 Rh1 C2 C3 142.0(3) . . . . ?
N8 Rh1 C2 C7 -7.4(5) . . . . ?
N1 Rh1 C2 C7 -105.9(5) . . . . ?
C3 Rh1 C2 C7 -120.5(6) . . . . ?
C4 Rh1 C2 C7 -159.2(5) . . . . ?
C5 Rh1 C2 C7 158.0(5) . . . . ?
C1 Rh1 C2 C7 121.1(6) . . . . ?
O7 Rh1 C2 C7 54.7(5) . . . . ?
C56 Rh1 C2 C7 21.6(5) . . . . ?
C1 C2 C3 C4 2.0(5) . . . . ?
C7 C2 C3 C4 -177.9(5) . . . . ?
Rh1 C2 C3 C4 63.3(3) . . . . ?
C1 C2 C3 C8 177.8(4) . . . . ?
C7 C2 C3 C8 -2.1(7) . . . . ?
Rh1 C2 C3 C8 -120.9(5) . . . . ?
C1 C2 C3 Rh1 -61.3(3) . . . . ?
C7 C2 C3 Rh1 118.8(5) . . . . ?
N8 Rh1 C3 C4 165.1(3) . . . . ?
N1 Rh1 C3 C4 72.4(3) . . . . ?
C2 Rh1 C3 C4 -116.0(4) . . . . ?
C5 Rh1 C3 C4 -36.4(3) . . . . ?
C1 Rh1 C3 C4 -79.3(3) . . . . ?
O7 Rh1 C3 C4 -128.7(4) . . . . ?
C56 Rh1 C3 C4 -178.8(2) . . . . ?
N8 Rh1 C3 C2 -78.9(3) . . . . ?
N1 Rh1 C3 C2 -171.6(3) . . . . ?
C4 Rh1 C3 C2 116.0(4) . . . . ?
C5 Rh1 C3 C2 79.6(3) . . . . ?
C1 Rh1 C3 C2 36.7(3) . . . . ?
O7 Rh1 C3 C2 -12.7(6) . . . . ?
C56 Rh1 C3 C2 -62.8(4) . . . . ?
N8 Rh1 C3 C8 42.1(5) . . . . ?
N1 Rh1 C3 C8 -50.6(5) . . . . ?
C2 Rh1 C3 C8 121.0(6) . . . . ?
C4 Rh1 C3 C8 -123.0(6) . . . . ?
C5 Rh1 C3 C8 -159.4(6) . . . . ?
C1 Rh1 C3 C8 157.8(6) . . . . ?
O7 Rh1 C3 C8 108.3(6) . . . . ?
C56 Rh1 C3 C8 58.2(6) . . . . ?
C2 C3 C4 C5 -3.0(5) . . . . ?
C8 C3 C4 C5 -178.7(4) . . . . ?
Rh1 C3 C4 C5 60.0(3) . . . . ?
C2 C3 C4 C9 179.0(4) . . . . ?
C8 C3 C4 C9 3.2(7) . . . . ?
Rh1 C3 C4 C9 -118.1(4) . . . . ?
C2 C3 C4 Rh1 -63.0(3) . . . . ?
C8 C3 C4 Rh1 121.3(5) . . . . ?
N8 Rh1 C4 C5 -147.9(3) . . . . ?
N1 Rh1 C4 C5 125.8(3) . . . . ?
C3 Rh1 C4 C5 -119.9(4) . . . . ?
C2 Rh1 C4 C5 -80.5(3) . . . . ?
C1 Rh1 C4 C5 -38.1(3) . . . . ?
O7 Rh1 C4 C5 29.9(4) . . . . ?
C56 Rh1 C4 C5 -17(12) . . . . ?
N8 Rh1 C4 C3 -28.0(5) . . . . ?
N1 Rh1 C4 C3 -114.3(3) . . . . ?
C2 Rh1 C4 C3 39.4(3) . . . . ?
C5 Rh1 C4 C3 119.9(4) . . . . ?
C1 Rh1 C4 C3 81.8(3) . . . . ?
O7 Rh1 C4 C3 149.8(3) . . . . ?
C56 Rh1 C4 C3 103(12) . . . . ?
N8 Rh1 C4 C9 91.4(5) . . . . ?
N1 Rh1 C4 C9 5.1(5) . . . . ?
C3 Rh1 C4 C9 119.4(6) . . . . ?
C2 Rh1 C4 C9 158.8(5) . . . . ?
C5 Rh1 C4 C9 -120.7(6) . . . . ?
C1 Rh1 C4 C9 -158.8(5) . . . . ?
O7 Rh1 C4 C9 -90.7(5) . . . . ?
C56 Rh1 C4 C9 -138(11) . . . . ?
C3 C4 C5 C1 2.9(5) . . . . ?
C9 C4 C5 C1 -179.1(4) . . . . ?
Rh1 C4 C5 C1 61.5(3) . . . . ?
C3 C4 C5 C10 178.1(4) . . . . ?
C9 C4 C5 C10 -3.8(7) . . . . ?
Rh1 C4 C5 C10 -123.2(4) . . . . ?
C3 C4 C5 Rh1 -58.7(3) . . . . ?
C9 C4 C5 Rh1 119.4(4) . . . . ?
C2 C1 C5 C4 -1.6(5) . . . . ?
C6 C1 C5 C4 178.3(4) . . . . ?
Rh1 C1 C5 C4 -61.2(3) . . . . ?
C2 C1 C5 C10 -176.8(4) . . . . ?
C6 C1 C5 C10 3.1(7) . . . . ?
Rh1 C1 C5 C10 123.6(4) . . . . ?
C2 C1 C5 Rh1 59.6(3) . . . . ?
C6 C1 C5 Rh1 -120.5(4) . . . . ?
N8 Rh1 C5 C4 127.9(4) . . . . ?
N1 Rh1 C5 C4 -62.2(3) . . . . ?
C3 Rh1 C5 C4 36.9(3) . . . . ?
C2 Rh1 C5 C4 81.0(3) . . . . ?
C1 Rh1 C5 C4 117.3(4) . . . . ?
O7 Rh1 C5 C4 -163.9(2) . . . . ?
C56 Rh1 C5 C4 179.6(2) . . . . ?
N8 Rh1 C5 C1 10.6(6) . . . . ?
N1 Rh1 C5 C1 -179.5(2) . . . . ?
C3 Rh1 C5 C1 -80.4(3) . . . . ?
C2 Rh1 C5 C1 -36.3(3) . . . . ?
C4 Rh1 C5 C1 -117.3(4) . . . . ?
O7 Rh1 C5 C1 78.8(3) . . . . ?
C56 Rh1 C5 C1 62.3(3) . . . . ?
N8 Rh1 C5 C10 -111.5(5) . . . . ?
N1 Rh1 C5 C10 58.4(5) . . . . ?
C3 Rh1 C5 C10 157.5(5) . . . . ?
C2 Rh1 C5 C10 -158.5(5) . . . . ?
C4 Rh1 C5 C10 120.6(6) . . . . ?
C1 Rh1 C5 C10 -122.1(6) . . . . ?
O7 Rh1 C5 C10 -43.4(5) . . . . ?
C56 Rh1 C5 C10 -59.8(5) . . . . ?
Rh2 O1 C11 N1 -176.3(3) . . . . ?
Ca1 O1 C11 N1 -54.5(4) . . . . ?
Rh2 O1 C11 N2 2.9(3) . . . . ?
Ca1 O1 C11 N2 124.7(3) . . . . ?
Ca1 O1 C11 Rh2 121.8(2) . . . . ?
C14 N1 C11 O1 171.6(3) . . . . ?
Rh1 N1 C11 O1 -24.1(5) . . . . ?
C14 N1 C11 N2 -7.5(5) . . . . ?
Rh1 N1 C11 N2 156.8(3) . . . . ?
C14 N1 C11 Rh2 34(3) . . . . ?
Rh1 N1 C11 Rh2 -162(3) . . . . ?
C12 N2 C11 O1 -172.9(3) . . . . ?
Rh2 N2 C11 O1 -3.2(3) . . . . ?
C12 N2 C11 N1 6.3(6) . . . . ?
Rh2 N2 C11 N1 176.0(3) . . . . ?
C12 N2 C11 Rh2 -169.7(4) . . . . ?
N2 Rh2 C11 O1 176.6(4) . . . . ?
N3 Rh2 C11 O1 -96.2(2) . . . . ?
C18 Rh2 C11 O1 150.7(3) . . . . ?
C20 Rh2 C11 O1 27.6(3) . . . . ?
C17 Rh2 C11 O1 110.6(2) . . . . ?
C16 Rh2 C11 O1 67.6(3) . . . . ?
C19 Rh2 C11 O1 -24(2) . . . . ?
N2 Rh2 C11 N1 -44(3) . . . . ?
N3 Rh2 C11 N1 43(3) . . . . ?
C18 Rh2 C11 N1 -70(3) . . . . ?
C20 Rh2 C11 N1 167(3) . . . . ?
C17 Rh2 C11 N1 -110(3) . . . . ?
C16 Rh2 C11 N1 -153(3) . . . . ?
C19 Rh2 C11 N1 115(4) . . . . ?
O1 Rh2 C11 N1 140(3) . . . . ?
N3 Rh2 C11 N2 87.2(2) . . . . ?
C18 Rh2 C11 N2 -25.9(4) . . . . ?
C20 Rh2 C11 N2 -149.0(3) . . . . ?
C17 Rh2 C11 N2 -66.0(3) . . . . ?
C16 Rh2 C11 N2 -109.0(3) . . . . ?
C19 Rh2 C11 N2 159(2) . . . . ?
O1 Rh2 C11 N2 -176.6(4) . . . . ?
C11 N2 C12 O2 179.0(4) . . . . ?
Rh2 N2 C12 O2 14.9(7) . . . . ?
C11 N2 C12 C13 -0.3(5) . . . . ?
Rh2 N2 C12 C13 -164.4(3) . . . . ?
O2 C12 C13 C14 177.0(4) . . . . ?
N2 C12 C13 C14 -3.7(6) . . . . ?
O2 C12 C13 C15 -3.3(7) . . . . ?
N2 C12 C13 C15 176.0(4) . . . . ?
C12 C13 C14 N1 2.3(6) . . . . ?
C15 C13 C14 N1 -177.3(4) . . . . ?
C11 N1 C14 C13 3.1(6) . . . . ?
Rh1 N1 C14 C13 -162.0(3) . . . . ?
N2 Rh2 C16 C17 68.8(3) . . . . ?
N3 Rh2 C16 C17 -115.1(4) . . . . ?
C18 Rh2 C16 C17 -37.6(3) . . . . ?
C20 Rh2 C16 C17 -118.3(4) . . . . ?
C19 Rh2 C16 C17 -81.1(3) . . . . ?
O1 Rh2 C16 C17 131.3(2) . . . . ?
C11 Rh2 C16 C17 103.1(3) . . . . ?
N2 Rh2 C16 C20 -172.9(2) . . . . ?
N3 Rh2 C16 C20 3.2(5) . . . . ?
C18 Rh2 C16 C20 80.7(3) . . . . ?
C17 Rh2 C16 C20 118.3(4) . . . . ?
C19 Rh2 C16 C20 37.2(3) . . . . ?
O1 Rh2 C16 C20 -110.4(3) . . . . ?
C11 Rh2 C16 C20 -138.6(2) . . . . ?
N2 Rh2 C16 C21 -54.5(5) . . . . ?
N3 Rh2 C16 C21 121.7(5) . . . . ?
C18 Rh2 C16 C21 -160.8(5) . . . . ?
C20 Rh2 C16 C21 118.5(6) . . . . ?
C17 Rh2 C16 C21 -123.2(5) . . . . ?
C19 Rh2 C16 C21 155.7(5) . . . . ?
O1 Rh2 C16 C21 8.1(5) . . . . ?
C11 Rh2 C16 C21 -20.1(5) . . . . ?
C20 C16 C17 C18 -1.6(5) . . . . ?
C21 C16 C17 C18 179.8(5) . . . . ?
Rh2 C16 C17 C18 58.8(3) . . . . ?
C20 C16 C17 C22 179.1(5) . . . . ?
C21 C16 C17 C22 0.5(8) . . . . ?
Rh2 C16 C17 C22 -120.5(5) . . . . ?
C20 C16 C17 Rh2 -60.4(3) . . . . ?
C21 C16 C17 Rh2 121.0(5) . . . . ?
N2 Rh2 C17 C16 -125.2(2) . . . . ?
N3 Rh2 C17 C16 135.0(3) . . . . ?
C18 Rh2 C17 C16 119.3(4) . . . . ?
C20 Rh2 C17 C16 37.9(2) . . . . ?
C19 Rh2 C17 C16 80.4(3) . . . . ?
O1 Rh2 C17 C16 -62.3(3) . . . . ?
C11 Rh2 C17 C16 -96.6(3) . . . . ?
N2 Rh2 C17 C18 115.6(3) . . . . ?
N3 Rh2 C17 C18 15.7(4) . . . . ?
C20 Rh2 C17 C18 -81.3(3) . . . . ?
C16 Rh2 C17 C18 -119.3(4) . . . . ?
C19 Rh2 C17 C18 -38.9(3) . . . . ?
O1 Rh2 C17 C18 178.4(2) . . . . ?
C11 Rh2 C17 C18 144.1(3) . . . . ?
N2 Rh2 C17 C22 -3.9(5) . . . . ?
N3 Rh2 C17 C22 -103.8(5) . . . . ?
C18 Rh2 C17 C22 -119.5(6) . . . . ?
C20 Rh2 C17 C22 159.2(5) . . . . ?
C16 Rh2 C17 C22 121.2(6) . . . . ?
C19 Rh2 C17 C22 -158.4(5) . . . . ?
O1 Rh2 C17 C22 58.9(5) . . . . ?
C11 Rh2 C17 C22 24.6(5) . . . . ?
C16 C17 C18 C19 3.5(5) . . . . ?
C22 C17 C18 C19 -177.2(5) . . . . ?
Rh2 C17 C18 C19 63.6(3) . . . . ?
C16 C17 C18 C23 178.2(5) . . . . ?
C22 C17 C18 C23 -2.5(8) . . . . ?
Rh2 C17 C18 C23 -121.7(5) . . . . ?
C16 C17 C18 Rh2 -60.1(3) . . . . ?
C22 C17 C18 Rh2 119.2(5) . . . . ?
N2 Rh2 C18 C19 166.2(2) . . . . ?
N3 Rh2 C18 C19 73.3(3) . . . . ?
C20 Rh2 C18 C19 -36.2(3) . . . . ?
C17 Rh2 C18 C19 -116.0(4) . . . . ?
C16 Rh2 C18 C19 -79.5(3) . . . . ?
O1 Rh2 C18 C19 -120.6(5) . . . . ?
C11 Rh2 C18 C19 -179.5(2) . . . . ?
N2 Rh2 C18 C17 -77.8(3) . . . . ?
N3 Rh2 C18 C17 -170.7(2) . . . . ?
C20 Rh2 C18 C17 79.8(3) . . . . ?
C16 Rh2 C18 C17 36.5(3) . . . . ?
C19 Rh2 C18 C17 116.0(4) . . . . ?
O1 Rh2 C18 C17 -4.6(7) . . . . ?
C11 Rh2 C18 C17 -63.4(4) . . . . ?
N2 Rh2 C18 C23 42.8(5) . . . . ?
N3 Rh2 C18 C23 -50.1(5) . . . . ?
C20 Rh2 C18 C23 -159.6(5) . . . . ?
C17 Rh2 C18 C23 120.6(6) . . . . ?
C16 Rh2 C18 C23 157.1(5) . . . . ?
C19 Rh2 C18 C23 -123.4(6) . . . . ?
O1 Rh2 C18 C23 116.0(6) . . . . ?
C11 Rh2 C18 C23 57.2(6) . . . . ?
C17 C18 C19 C20 -4.1(5) . . . . ?
C23 C18 C19 C20 -178.7(5) . . . . ?
Rh2 C18 C19 C20 59.2(3) . . . . ?
C17 C18 C19 C24 178.1(4) . . . . ?
C23 C18 C19 C24 3.5(8) . . . . ?
Rh2 C18 C19 C24 -118.6(4) . . . . ?
C17 C18 C19 Rh2 -63.3(3) . . . . ?
C23 C18 C19 Rh2 122.1(5) . . . . ?
N2 Rh2 C19 C20 -147.9(3) . . . . ?
N3 Rh2 C19 C20 127.4(3) . . . . ?
C18 Rh2 C19 C20 -119.8(4) . . . . ?
C17 Rh2 C19 C20 -80.6(3) . . . . ?
C16 Rh2 C19 C20 -38.0(3) . . . . ?
O1 Rh2 C19 C20 33.7(4) . . . . ?
C11 Rh2 C19 C20 56(2) . . . . ?
N2 Rh2 C19 C18 -28.1(5) . . . . ?
N3 Rh2 C19 C18 -112.8(3) . . . . ?
C20 Rh2 C19 C18 119.8(4) . . . . ?
C17 Rh2 C19 C18 39.1(3) . . . . ?
C16 Rh2 C19 C18 81.7(3) . . . . ?
O1 Rh2 C19 C18 153.5(3) . . . . ?
C11 Rh2 C19 C18 175(2) . . . . ?
N2 Rh2 C19 C24 89.9(5) . . . . ?
N3 Rh2 C19 C24 5.2(4) . . . . ?
C18 Rh2 C19 C24 118.0(5) . . . . ?
C20 Rh2 C19 C24 -122.2(5) . . . . ?
C17 Rh2 C19 C24 157.2(5) . . . . ?
C16 Rh2 C19 C24 -160.2(5) . . . . ?
O1 Rh2 C19 C24 -88.5(5) . . . . ?
C11 Rh2 C19 C24 -67(2) . . . . ?
C18 C19 C20 C16 3.1(5) . . . . ?
C24 C19 C20 C16 -179.2(4) . . . . ?
Rh2 C19 C20 C16 61.3(3) . . . . ?
C18 C19 C20 C25 -177.3(4) . . . . ?
C24 C19 C20 C25 0.4(7) . . . . ?
Rh2 C19 C20 C25 -119.1(5) . . . . ?
C18 C19 C20 Rh2 -58.2(3) . . . . ?
C24 C19 C20 Rh2 119.5(5) . . . . ?
C17 C16 C20 C19 -0.9(5) . . . . ?
C21 C16 C20 C19 177.7(4) . . . . ?
Rh2 C16 C20 C19 -61.7(3) . . . . ?
C17 C16 C20 C25 179.4(4) . . . . ?
C21 C16 C20 C25 -1.9(7) . . . . ?
Rh2 C16 C20 C25 118.6(4) . . . . ?
C17 C16 C20 Rh2 60.8(3) . . . . ?
C21 C16 C20 Rh2 -120.6(5) . . . . ?
N2 Rh2 C20 C19 135.7(4) . . . . ?
N3 Rh2 C20 C19 -60.3(3) . . . . ?
C18 Rh2 C20 C19 37.2(3) . . . . ?
C17 Rh2 C20 C19 81.0(3) . . . . ?
C16 Rh2 C20 C19 118.1(4) . . . . ?
O1 Rh2 C20 C19 -160.7(2) . . . . ?
C11 Rh2 C20 C19 -175.2(2) . . . . ?
N2 Rh2 C20 C16 17.6(6) . . . . ?
N3 Rh2 C20 C16 -178.4(2) . . . . ?
C18 Rh2 C20 C16 -80.9(3) . . . . ?
C17 Rh2 C20 C16 -37.1(3) . . . . ?
C19 Rh2 C20 C16 -118.1(4) . . . . ?
O1 Rh2 C20 C16 81.2(3) . . . . ?
C11 Rh2 C20 C16 66.7(3) . . . . ?
N2 Rh2 C20 C25 -103.0(5) . . . . ?
N3 Rh2 C20 C25 61.0(4) . . . . ?
C18 Rh2 C20 C25 158.5(4) . . . . ?
C17 Rh2 C20 C25 -157.7(4) . . . . ?
C16 Rh2 C20 C25 -120.6(5) . . . . ?
C19 Rh2 C20 C25 121.3(5) . . . . ?
O1 Rh2 C20 C25 -39.4(4) . . . . ?
C11 Rh2 C20 C25 -53.8(5) . . . . ?
Rh3 O3 C26 N4 1.6(3) . . . . ?
Ca1 O3 C26 N4 123.6(3) . . . . ?
Rh3 O3 C26 N3 -178.1(4) . . . . ?
Ca1 O3 C26 N3 -56.1(5) . . . . ?
Ca1 O3 C26 Rh3 122.0(2) . . . . ?
C27 N4 C26 O3 -175.0(4) . . . . ?
Rh3 N4 C26 O3 -1.7(4) . . . . ?
C27 N4 C26 N3 4.6(6) . . . . ?
Rh3 N4 C26 N3 177.9(3) . . . . ?
C27 N4 C26 Rh3 -173.3(5) . . . . ?
C29 N3 C26 O3 172.5(4) . . . . ?
Rh2 N3 C26 O3 -23.4(5) . . . . ?
C29 N3 C26 N4 -7.1(6) . . . . ?
Rh2 N3 C26 N4 157.0(3) . . . . ?
C29 N3 C26 Rh3 14(4) . . . . ?
Rh2 N3 C26 Rh3 178(100) . . . . ?
N4 Rh3 C26 O3 178.2(4) . . . . ?
C33 Rh3 C26 O3 150.2(3) . . . . ?
N5 Rh3 C26 O3 -94.9(2) . . . . ?
C34 Rh3 C26 O3 12(19) . . . . ?
C32 Rh3 C26 O3 111.4(2) . . . . ?
C35 Rh3 C26 O3 30.1(3) . . . . ?
C31 Rh3 C26 O3 68.8(3) . . . . ?
C33 Rh3 C26 N4 -28.0(4) . . . . ?
N5 Rh3 C26 N4 86.9(3) . . . . ?
C34 Rh3 C26 N4 -166(30) . . . . ?
C32 Rh3 C26 N4 -66.8(3) . . . . ?
C35 Rh3 C26 N4 -148.1(3) . . . . ?
C31 Rh3 C26 N4 -109.4(3) . . . . ?
O3 Rh3 C26 N4 -178.2(4) . . . . ?
N4 Rh3 C26 N3 -22(3) . . . . ?
C33 Rh3 C26 N3 -50(4) . . . . ?
N5 Rh3 C26 N3 65(3) . . . . ?
C34 Rh3 C26 N3 172(100) . . . . ?
C32 Rh3 C26 N3 -89(3) . . . . ?
C35 Rh3 C26 N3 -170(3) . . . . ?
C31 Rh3 C26 N3 -131(3) . . . . ?
O3 Rh3 C26 N3 160(4) . . . . ?
C26 N4 C27 O4 -178.0(4) . . . . ?
Rh3 N4 C27 O4 12.1(7) . . . . ?
C26 N4 C27 C28 1.7(6) . . . . ?
Rh3 N4 C27 C28 -168.1(3) . . . . ?
O4 C27 C28 C29 174.8(4) . . . . ?
N4 C27 C28 C29 -4.9(6) . . . . ?
O4 C27 C28 C30 -5.6(7) . . . . ?
N4 C27 C28 C30 174.7(4) . . . . ?
C27 C28 C29 N3 2.5(6) . . . . ?
C30 C28 C29 N3 -177.1(4) . . . . ?
C26 N3 C29 C28 3.5(6) . . . . ?
Rh2 N3 C29 C28 -161.2(3) . . . . ?
N4 Rh3 C31 C32 64.2(3) . . . . ?
C33 Rh3 C31 C32 -39.0(3) . . . . ?
N5 Rh3 C31 C32 -119.7(4) . . . . ?
C34 Rh3 C31 C32 -82.3(3) . . . . ?
C35 Rh3 C31 C32 -120.0(4) . . . . ?
O3 Rh3 C31 C32 126.4(2) . . . . ?
C26 Rh3 C31 C32 98.2(3) . . . . ?
N4 Rh3 C31 C35 -175.9(2) . . . . ?
C33 Rh3 C31 C35 81.0(3) . . . . ?
N5 Rh3 C31 C35 0.3(5) . . . . ?
C34 Rh3 C31 C35 37.7(3) . . . . ?
C32 Rh3 C31 C35 120.0(4) . . . . ?
O3 Rh3 C31 C35 -113.7(3) . . . . ?
C26 Rh3 C31 C35 -141.9(2) . . . . ?
N4 Rh3 C31 C36 -56.5(5) . . . . ?
C33 Rh3 C31 C36 -159.7(5) . . . . ?
N5 Rh3 C31 C36 119.6(4) . . . . ?
C34 Rh3 C31 C36 157.0(5) . . . . ?
C32 Rh3 C31 C36 -120.7(6) . . . . ?
C35 Rh3 C31 C36 119.4(6) . . . . ?
O3 Rh3 C31 C36 5.7(5) . . . . ?
C26 Rh3 C31 C36 -22.5(5) . . . . ?
C35 C31 C32 C33 -0.5(5) . . . . ?
C36 C31 C32 C33 -178.6(4) . . . . ?
Rh3 C31 C32 C33 59.2(3) . . . . ?
C35 C31 C32 C37 -179.8(4) . . . . ?
C36 C31 C32 C37 2.0(7) . . . . ?
Rh3 C31 C32 C37 -120.1(5) . . . . ?
C35 C31 C32 Rh3 -59.7(3) . . . . ?
C36 C31 C32 Rh3 122.1(4) . . . . ?
N4 Rh3 C32 C31 -128.5(3) . . . . ?
C33 Rh3 C32 C31 117.3(4) . . . . ?
N5 Rh3 C32 C31 133.4(3) . . . . ?
C34 Rh3 C32 C31 79.3(3) . . . . ?
C35 Rh3 C32 C31 37.0(3) . . . . ?
O3 Rh3 C32 C31 -67.4(3) . . . . ?
C26 Rh3 C32 C31 -100.2(3) . . . . ?
N4 Rh3 C32 C33 114.2(3) . . . . ?
N5 Rh3 C32 C33 16.1(5) . . . . ?
C34 Rh3 C32 C33 -38.0(3) . . . . ?
C35 Rh3 C32 C33 -80.3(3) . . . . ?
C31 Rh3 C32 C33 -117.3(4) . . . . ?
O3 Rh3 C32 C33 175.3(3) . . . . ?
C26 Rh3 C32 C33 142.5(3) . . . . ?
N4 Rh3 C32 C37 -5.5(5) . . . . ?
C33 Rh3 C32 C37 -119.8(6) . . . . ?
N5 Rh3 C32 C37 -103.6(5) . . . . ?
C34 Rh3 C32 C37 -157.7(5) . . . . ?
C35 Rh3 C32 C37 160.0(5) . . . . ?
C31 Rh3 C32 C37 122.9(6) . . . . ?
O3 Rh3 C32 C37 55.5(5) . . . . ?
C26 Rh3 C32 C37 22.8(5) . . . . ?
C31 C32 C33 C34 2.2(5) . . . . ?
C37 C32 C33 C34 -178.4(4) . . . . ?
Rh3 C32 C33 C34 63.2(3) . . . . ?
C31 C32 C33 C38 177.2(4) . . . . ?
C37 C32 C33 C38 -3.5(7) . . . . ?
Rh3 C32 C33 C38 -121.8(5) . . . . ?
C31 C32 C33 Rh3 -61.0(3) . . . . ?
C37 C32 C33 Rh3 118.4(5) . . . . ?
N4 Rh3 C33 C34 165.5(3) . . . . ?
N5 Rh3 C33 C34 72.1(3) . . . . ?
C32 Rh3 C33 C34 -117.1(4) . . . . ?
C35 Rh3 C33 C34 -36.1(3) . . . . ?
C31 Rh3 C33 C34 -79.5(3) . . . . ?
O3 Rh3 C33 C34 -129.6(5) . . . . ?
C26 Rh3 C33 C34 -179.5(3) . . . . ?
N4 Rh3 C33 C32 -77.4(3) . . . . ?
N5 Rh3 C33 C32 -170.8(3) . . . . ?
C34 Rh3 C33 C32 117.1(4) . . . . ?
C35 Rh3 C33 C32 81.0(3) . . . . ?
C31 Rh3 C33 C32 37.5(3) . . . . ?
O3 Rh3 C33 C32 -12.6(7) . . . . ?
C26 Rh3 C33 C32 -62.4(4) . . . . ?
N4 Rh3 C33 C38 42.2(5) . . . . ?
N5 Rh3 C33 C38 -51.2(5) . . . . ?
C34 Rh3 C33 C38 -123.3(6) . . . . ?
C32 Rh3 C33 C38 119.7(6) . . . . ?
C35 Rh3 C33 C38 -159.3(5) . . . . ?
C31 Rh3 C33 C38 157.2(5) . . . . ?
O3 Rh3 C33 C38 107.1(6) . . . . ?
C26 Rh3 C33 C38 57.2(6) . . . . ?
C32 C33 C34 C35 -3.2(5) . . . . ?
C38 C33 C34 C35 -178.0(5) . . . . ?
Rh3 C33 C34 C35 59.7(3) . . . . ?
C32 C33 C34 C39 178.0(4) . . . . ?
C38 C33 C34 C39 3.2(8) . . . . ?
Rh3 C33 C34 C39 -119.1(5) . . . . ?
C32 C33 C34 Rh3 -62.9(3) . . . . ?
C38 C33 C34 Rh3 122.3(5) . . . . ?
N4 Rh3 C34 C35 -147.7(3) . . . . ?
C33 Rh3 C34 C35 -120.3(4) . . . . ?
N5 Rh3 C34 C35 125.1(3) . . . . ?
C32 Rh3 C34 C35 -81.3(3) . . . . ?
C31 Rh3 C34 C35 -38.7(3) . . . . ?
O3 Rh3 C34 C35 30.1(4) . . . . ?
C26 Rh3 C34 C35 18(19) . . . . ?
N4 Rh3 C34 C33 -27.4(5) . . . . ?
N5 Rh3 C34 C33 -114.6(3) . . . . ?
C32 Rh3 C34 C33 39.0(3) . . . . ?
C35 Rh3 C34 C33 120.3(4) . . . . ?
C31 Rh3 C34 C33 81.6(3) . . . . ?
O3 Rh3 C34 C33 150.4(3) . . . . ?
C26 Rh3 C34 C33 138(19) . . . . ?
N4 Rh3 C34 C39 91.5(6) . . . . ?
C33 Rh3 C34 C39 118.9(6) . . . . ?
N5 Rh3 C34 C39 4.3(5) . . . . ?
C32 Rh3 C34 C39 157.8(6) . . . . ?
C35 Rh3 C34 C39 -120.8(6) . . . . ?
C31 Rh3 C34 C39 -159.5(6) . . . . ?
O3 Rh3 C34 C39 -90.7(6) . . . . ?
C26 Rh3 C34 C39 -103(19) . . . . ?
C33 C34 C35 C31 2.9(5) . . . . ?
C39 C34 C35 C31 -178.3(4) . . . . ?
Rh3 C34 C35 C31 61.2(3) . . . . ?
C33 C34 C35 C40 180.0(4) . . . . ?
C39 C34 C35 C40 -1.3(7) . . . . ?
Rh3 C34 C35 C40 -121.7(5) . . . . ?
C33 C34 C35 Rh3 -58.3(3) . . . . ?
C39 C34 C35 Rh3 120.5(5) . . . . ?
C32 C31 C35 C34 -1.5(5) . . . . ?
C36 C31 C35 C34 176.7(4) . . . . ?
Rh3 C31 C35 C34 -61.3(3) . . . . ?
C32 C31 C35 C40 -178.6(4) . . . . ?
C36 C31 C35 C40 -0.4(7) . . . . ?
Rh3 C31 C35 C40 121.6(4) . . . . ?
C32 C31 C35 Rh3 59.9(3) . . . . ?
C36 C31 C35 Rh3 -122.0(4) . . . . ?
N4 Rh3 C35 C34 127.6(4) . . . . ?
C33 Rh3 C35 C34 36.7(3) . . . . ?
N5 Rh3 C35 C34 -62.7(3) . . . . ?
C32 Rh3 C35 C34 80.8(3) . . . . ?
C31 Rh3 C35 C34 117.1(4) . . . . ?
O3 Rh3 C35 C34 -164.0(2) . . . . ?
C26 Rh3 C35 C34 -179.8(2) . . . . ?
N4 Rh3 C35 C31 10.5(6) . . . . ?
C33 Rh3 C35 C31 -80.5(3) . . . . ?
N5 Rh3 C35 C31 -179.9(2) . . . . ?
C34 Rh3 C35 C31 -117.1(4) . . . . ?
C32 Rh3 C35 C31 -36.3(3) . . . . ?
O3 Rh3 C35 C31 78.9(3) . . . . ?
C26 Rh3 C35 C31 63.1(3) . . . . ?
N4 Rh3 C35 C40 -110.2(5) . . . . ?
C33 Rh3 C35 C40 158.8(5) . . . . ?
N5 Rh3 C35 C40 59.4(5) . . . . ?
C34 Rh3 C35 C40 122.2(5) . . . . ?
C32 Rh3 C35 C40 -157.0(5) . . . . ?
C31 Rh3 C35 C40 -120.7(5) . . . . ?
O3 Rh3 C35 C40 -41.8(5) . . . . ?
C26 Rh3 C35 C40 -57.6(5) . . . . ?
Rh4 O5 C41 N5 -178.6(4) . . . . ?
Ca1 O5 C41 N5 -58.3(5) . . . . ?
Rh4 O5 C41 N6 1.8(3) . . . . ?
Ca1 O5 C41 N6 122.2(3) . . . . ?
C44 N5 C41 O5 172.9(4) . . . . ?
Rh3 N5 C41 O5 -21.3(5) . . . . ?
C44 N5 C41 N6 -7.6(6) . . . . ?
Rh3 N5 C41 N6 158.2(3) . . . . ?
C42 N6 C41 O5 -173.1(3) . . . . ?
Rh4 N6 C41 O5 -2.0(3) . . . . ?
C42 N6 C41 N5 7.4(6) . . . . ?
Rh4 N6 C41 N5 178.4(3) . . . . ?
C41 N6 C42 O6 178.1(4) . . . . ?
Rh4 N6 C42 O6 12.1(7) . . . . ?
C41 N6 C42 C43 -1.9(6) . . . . ?
Rh4 N6 C42 C43 -167.9(3) . . . . ?
O6 C42 C43 C44 177.7(4) . . . . ?
N6 C42 C43 C44 -2.3(6) . . . . ?
O6 C42 C43 C45 -2.6(7) . . . . ?
N6 C42 C43 C45 177.4(4) . . . . ?
C42 C43 C44 N5 1.8(6) . . . . ?
C45 C43 C44 N5 -177.9(4) . . . . ?
C41 N5 C44 C43 3.0(6) . . . . ?
Rh3 N5 C44 C43 -163.7(3) . . . . ?
N7 Rh4 C46 C47 -126.8(3) . . . . ?
N6 Rh4 C46 C47 62.8(3) . . . . ?
C48 Rh4 C46 C47 -38.4(3) . . . . ?
C50 Rh4 C46 C47 -119.6(4) . . . . ?
C49 Rh4 C46 C47 -82.0(3) . . . . ?
O5 Rh4 C46 C47 123.3(2) . . . . ?
N7 Rh4 C46 C50 -7.2(5) . . . . ?
N6 Rh4 C46 C50 -177.6(3) . . . . ?
C48 Rh4 C46 C50 81.2(3) . . . . ?
C47 Rh4 C46 C50 119.6(4) . . . . ?
C49 Rh4 C46 C50 37.6(3) . . . . ?
O5 Rh4 C46 C50 -117.1(3) . . . . ?
N7 Rh4 C46 C51 111.4(5) . . . . ?
N6 Rh4 C46 C51 -59.0(5) . . . . ?
C48 Rh4 C46 C51 -160.2(5) . . . . ?
C47 Rh4 C46 C51 -121.8(5) . . . . ?
C50 Rh4 C46 C51 118.6(6) . . . . ?
C49 Rh4 C46 C51 156.2(5) . . . . ?
O5 Rh4 C46 C51 1.5(5) . . . . ?
C50 C46 C47 C48 -0.1(5) . . . . ?
C51 C46 C47 C48 179.4(5) . . . . ?
Rh4 C46 C47 C48 60.4(3) . . . . ?
C50 C46 C47 C52 -180.0(5) . . . . ?
C51 C46 C47 C52 -0.5(8) . . . . ?
Rh4 C46 C47 C52 -119.5(5) . . . . ?
C50 C46 C47 Rh4 -60.5(3) . . . . ?
C51 C46 C47 Rh4 119.0(5) . . . . ?
N7 Rh4 C47 C46 128.3(3) . . . . ?
N6 Rh4 C47 C46 -131.0(2) . . . . ?
C48 Rh4 C47 C46 117.9(4) . . . . ?
C50 Rh4 C47 C46 37.1(3) . . . . ?
C49 Rh4 C47 C46 79.3(3) . . . . ?
O5 Rh4 C47 C46 -68.4(3) . . . . ?
N7 Rh4 C47 C48 10.4(5) . . . . ?
N6 Rh4 C47 C48 111.1(3) . . . . ?
C46 Rh4 C47 C48 -117.9(4) . . . . ?
C50 Rh4 C47 C48 -80.8(3) . . . . ?
C49 Rh4 C47 C48 -38.6(3) . . . . ?
O5 Rh4 C47 C48 173.7(3) . . . . ?
N7 Rh4 C47 C52 -109.1(5) . . . . ?
N6 Rh4 C47 C52 -8.4(5) . . . . ?
C48 Rh4 C47 C52 -119.5(6) . . . . ?
C46 Rh4 C47 C52 122.6(5) . . . . ?
C50 Rh4 C47 C52 159.7(5) . . . . ?
C49 Rh4 C47 C52 -158.1(5) . . . . ?
O5 Rh4 C47 C52 54.3(5) . . . . ?
C46 C47 C48 C49 1.6(5) . . . . ?
C52 C47 C48 C49 -178.5(5) . . . . ?
Rh4 C47 C48 C49 62.6(3) . . . . ?
C46 C47 C48 C53 177.3(5) . . . . ?
C52 C47 C48 C53 -2.8(8) . . . . ?
Rh4 C47 C48 C53 -121.7(5) . . . . ?
C46 C47 C48 Rh4 -61.0(3) . . . . ?
C52 C47 C48 Rh4 118.9(5) . . . . ?
N7 Rh4 C48 C49 69.0(3) . . . . ?
N6 Rh4 C48 C49 162.5(3) . . . . ?
C47 Rh4 C48 C49 -116.5(4) . . . . ?
C46 Rh4 C48 C49 -79.2(3) . . . . ?
C50 Rh4 C48 C49 -36.0(3) . . . . ?
O5 Rh4 C48 C49 -130.6(4) . . . . ?
N7 Rh4 C48 C47 -174.4(3) . . . . ?
N6 Rh4 C48 C47 -81.0(3) . . . . ?
C46 Rh4 C48 C47 37.3(3) . . . . ?
C50 Rh4 C48 C47 80.6(3) . . . . ?
C49 Rh4 C48 C47 116.5(4) . . . . ?
O5 Rh4 C48 C47 -14.1(6) . . . . ?
N7 Rh4 C48 C53 -53.8(5) . . . . ?
N6 Rh4 C48 C53 39.6(5) . . . . ?
C47 Rh4 C48 C53 120.6(6) . . . . ?
C46 Rh4 C48 C53 157.9(5) . . . . ?
C50 Rh4 C48 C53 -158.8(5) . . . . ?
C49 Rh4 C48 C53 -122.9(6) . . . . ?
O5 Rh4 C48 C53 106.5(5) . . . . ?
C47 C48 C49 C50 -2.5(5) . . . . ?
C53 C48 C49 C50 -178.2(5) . . . . ?
Rh4 C48 C49 C50 59.4(3) . . . . ?
C47 C48 C49 C54 179.9(5) . . . . ?
C53 C48 C49 C54 4.2(8) . . . . ?
Rh4 C48 C49 C54 -118.2(5) . . . . ?
C47 C48 C49 Rh4 -61.9(3) . . . . ?
C53 C48 C49 Rh4 122.4(5) . . . . ?
N7 Rh4 C49 C50 121.1(3) . . . . ?
N6 Rh4 C49 C50 -152.3(3) . . . . ?
C48 Rh4 C49 C50 -120.2(4) . . . . ?
C47 Rh4 C49 C50 -81.3(3) . . . . ?
C46 Rh4 C49 C50 -38.5(3) . . . . ?
O5 Rh4 C49 C50 21.6(4) . . . . ?
N7 Rh4 C49 C48 -118.7(3) . . . . ?
N6 Rh4 C49 C48 -32.1(4) . . . . ?
C47 Rh4 C49 C48 38.9(3) . . . . ?
C46 Rh4 C49 C48 81.7(3) . . . . ?
C50 Rh4 C49 C48 120.2(4) . . . . ?
O5 Rh4 C49 C48 141.7(3) . . . . ?
N7 Rh4 C49 C54 1.3(5) . . . . ?
N6 Rh4 C49 C54 87.9(6) . . . . ?
C48 Rh4 C49 C54 120.0(6) . . . . ?
C47 Rh4 C49 C54 158.9(6) . . . . ?
C46 Rh4 C49 C54 -158.3(6) . . . . ?
C50 Rh4 C49 C54 -119.8(6) . . . . ?
O5 Rh4 C49 C54 -98.2(5) . . . . ?
C48 C49 C50 C46 2.4(5) . . . . ?
C54 C49 C50 C46 -179.9(5) . . . . ?
Rh4 C49 C50 C46 61.0(3) . . . . ?
C48 C49 C50 C55 178.5(5) . . . . ?
C54 C49 C50 C55 -3.9(8) . . . . ?
Rh4 C49 C50 C55 -122.9(5) . . . . ?
C48 C49 C50 Rh4 -58.6(3) . . . . ?
C54 C49 C50 Rh4 119.1(5) . . . . ?
C47 C46 C50 C49 -1.4(5) . . . . ?
C51 C46 C50 C49 179.1(4) . . . . ?
Rh4 C46 C50 C49 -61.8(3) . . . . ?
C47 C46 C50 C55 -177.7(5) . . . . ?
C51 C46 C50 C55 2.8(7) . . . . ?
Rh4 C46 C50 C55 121.9(5) . . . . ?
C47 C46 C50 Rh4 60.4(3) . . . . ?
C51 C46 C50 Rh4 -119.1(5) . . . . ?
N7 Rh4 C50 C49 -66.6(3) . . . . ?
N6 Rh4 C50 C49 124.0(5) . . . . ?
C48 Rh4 C50 C49 37.0(3) . . . . ?
C47 Rh4 C50 C49 80.7(3) . . . . ?
C46 Rh4 C50 C49 117.3(4) . . . . ?
O5 Rh4 C50 C49 -168.7(2) . . . . ?
N7 Rh4 C50 C46 176.2(3) . . . . ?
N6 Rh4 C50 C46 6.7(7) . . . . ?
C48 Rh4 C50 C46 -80.3(3) . . . . ?
C47 Rh4 C50 C46 -36.6(3) . . . . ?
C49 Rh4 C50 C46 -117.3(4) . . . . ?
O5 Rh4 C50 C46 74.0(3) . . . . ?
N7 Rh4 C50 C55 57.2(5) . . . . ?
N6 Rh4 C50 C55 -112.2(6) . . . . ?
C48 Rh4 C50 C55 160.7(5) . . . . ?
C47 Rh4 C50 C55 -155.5(5) . . . . ?
C46 Rh4 C50 C55 -119.0(6) . . . . ?
C49 Rh4 C50 C55 123.8(6) . . . . ?
O5 Rh4 C50 C55 -45.0(5) . . . . ?
Rh1 O7 C56 N7 -179.3(4) . . . . ?
Ca1 O7 C56 N7 -57.9(5) . . . . ?
Rh1 O7 C56 N8 0.1(3) . . . . ?
Ca1 O7 C56 N8 121.5(3) . . . . ?
Ca1 O7 C56 Rh1 121.4(2) . . . . ?
C59 N7 C56 O7 172.8(4) . . . . ?
Rh4 N7 C56 O7 -19.3(5) . . . . ?
C59 N7 C56 N8 -6.6(6) . . . . ?
Rh4 N7 C56 N8 161.3(3) . . . . ?
C59 N7 C56 Rh1 4(6) . . . . ?
Rh4 N7 C56 Rh1 172(5) . . . . ?
C57 N8 C56 O7 -171.3(4) . . . . ?
Rh1 N8 C56 O7 -0.1(3) . . . . ?
C57 N8 C56 N7 8.1(6) . . . . ?
Rh1 N8 C56 N7 179.3(3) . . . . ?
C57 N8 C56 Rh1 -171.2(4) . . . . ?
N8 Rh1 C56 O7 179.9(4) . . . . ?
N1 Rh1 C56 O7 -94.9(2) . . . . ?
C3 Rh1 C56 O7 149.9(3) . . . . ?
C2 Rh1 C56 O7 111.1(2) . . . . ?
C4 Rh1 C56 O7 48(12) . . . . ?
C5 Rh1 C56 O7 31.2(3) . . . . ?
C1 Rh1 C56 O7 68.9(3) . . . . ?
N8 Rh1 C56 N7 -11(5) . . . . ?
N1 Rh1 C56 N7 74(5) . . . . ?
C3 Rh1 C56 N7 -41(6) . . . . ?
C2 Rh1 C56 N7 -80(6) . . . . ?
C4 Rh1 C56 N7 -142(11) . . . . ?
C5 Rh1 C56 N7 -160(5) . . . . ?
C1 Rh1 C56 N7 -122(5) . . . . ?
O7 Rh1 C56 N7 169(6) . . . . ?
N1 Rh1 C56 N8 85.2(2) . . . . ?
C3 Rh1 C56 N8 -30.0(4) . . . . ?
C2 Rh1 C56 N8 -68.7(3) . . . . ?
C4 Rh1 C56 N8 -132(12) . . . . ?
C5 Rh1 C56 N8 -148.6(3) . . . . ?
C1 Rh1 C56 N8 -110.9(3) . . . . ?
O7 Rh1 C56 N8 -179.9(4) . . . . ?
C56 N8 C57 O8 176.1(4) . . . . ?
Rh1 N8 C57 O8 9.9(7) . . . . ?
C56 N8 C57 C58 -3.9(6) . . . . ?
Rh1 N8 C57 C58 -170.1(3) . . . . ?
O8 C57 C58 C59 179.2(4) . . . . ?
N8 C57 C58 C59 -0.8(6) . . . . ?
O8 C57 C58 C60 -1.1(7) . . . . ?
N8 C57 C58 C60 178.8(4) . . . . ?
C57 C58 C59 N7 2.0(6) . . . . ?
C60 C58 C59 N7 -177.6(4) . . . . ?
C56 N7 C59 C58 1.4(6) . . . . ?
Rh4 N7 C59 C58 -167.0(3) . . . . ?
Ca1 N10 C61 C62 27(42) . . . . ?

_diffrn_measured_fraction_theta_max 0.984
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.984
_refine_diff_density_max         1.692
_refine_diff_density_min         -1.011
_refine_diff_density_rms         0.147

# start Validation Reply Form
_vrf_PLAT214_I                   
;
PROBLEM: Atom O16A    (Anion/Solvent) ADP max/min Ratio          6.3 prolat
RESPONSE: This atom was one of the positionally disordered O atoms for a 
solvated water molecule. The occupation parameter of this atom might be 
smaller than 0.333, but we assume this value for the simplicity of 
calculation. 
;
_vrf_PLAT430_I                   
;
PROBLEM: Short Inter D...A Contact  O123   ..  O16A    ..       1.89 Ang. 
PROBLEM: Short Inter D...A Contact  O123   ..  O16B    ..       2.53 Ang. 
PROBLEM: Short Inter D...A Contact  O24    ..  O25     ..       2.89 Ang. 
RESPONSE: There would be a hydrogen bond between these atoms, although a 
H atoms of solvated water molecules did not included in the calculation.
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4LaNO3
_database_code_depnum_ccdc_archive 'CCDC 1033780'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        ?

_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C62 H79 La N11 O14 Rh4 1+, N O3 1-, 2(H2 O)'
_chemical_formula_sum            'C62 H83 La N12 O19 Rh4'
_chemical_formula_weight         1850.95

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z'
'-x, -y, z'

_cell_length_a                   18.7826(10)
_cell_length_b                   19.9113(12)
_cell_length_c                   10.6111(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3968.4(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    186(2)
_cell_measurement_reflns_used    20647
_cell_measurement_theta_min      3.01
_cell_measurement_theta_max      27.55

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.549
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1856
_exptl_absorpt_coefficient_mu    1.410
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.6936
_exptl_absorpt_correction_T_max  0.7657
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      186(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            39209
_diffrn_reflns_av_R_equivalents  0.0661
_diffrn_reflns_av_sigmaI/netI    0.0536
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         27.48
_reflns_number_total             9089
_reflns_number_gt                7827
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    'Il Milione'
_computing_structure_refinement  SHELXL-97
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0971P)²+11.3665P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.50(3)
_refine_ls_number_reflns         9089
_refine_ls_number_parameters     571
_refine_ls_number_restraints     1402
_refine_ls_R_factor_all          0.0723
_refine_ls_R_factor_gt           0.0624
_refine_ls_wR_factor_ref         0.1827
_refine_ls_wR_factor_gt          0.1740
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_restrained_S_all      1.041
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
La1 La 0.5000 0.0000 0.42744(4) 0.03150(14) Uani 1 2 d SU . .
N511 N 0.5000 0.0000 0.1672(7) 0.0361(15) Uani 1 2 d SU . .
C511 C 0.5000 0.0000 0.0618(8) 0.0390(18) Uani 1 2 d SU . .
C512 C 0.5000 0.0000 -0.0763(12) 0.090(4) Uani 1 2 d SU . .
N521 N 0.5745(6) 0.0597(6) 0.6613(9) 0.083(2) Uani 1 1 d DU . .
O521 O 0.6040(6) 0.0924(5) 0.7531(8) 0.105(3) Uani 1 1 d DU . .
O522 O 0.5984(5) 0.0053(6) 0.6154(8) 0.096(2) Uani 1 1 d DU . .
O523 O 0.5154(6) 0.0822(5) 0.6198(9) 0.105(3) Uani 1 1 d DU . .
N531 N -0.0451(16) 0.0502(14) 1.045(5) 0.393(18) Uani 0.50 1 d PDU . .
O531 O 0.0000 0.0000 1.052(5) 0.401(18) Uani 1 2 d SDU . .
O532 O -0.029(3) 0.1077(14) 1.001(7) 0.37(2) Uani 0.50 1 d PDU . .
O533 O -0.1109(12) 0.034(3) 1.042(7) 0.38(2) Uani 0.50 1 d PDU . .
O541 O 0.9689(16) 0.0961(16) 0.409(3) 0.263(13) Uani 0.80 1 d PU A 3
O542 O 0.975(3) 0.017(3) 0.681(5) 0.14(2) Uani 0.20 1 d PU . 4
Rh3 Rh 0.31043(7) 0.13337(8) 0.25089(14) 0.0446(3) Uani 0.683(3) 1 d PU . 1
Rh4 Rh 0.64261(8) 0.18232(7) 0.24098(11) 0.0388(3) Uani 0.683(3) 1 d PU . 1
O101 O 0.4671(4) 0.1147(3) 0.3518(6) 0.0350(14) Uani 0.683(3) 1 d PDU . 1
O102 O 0.6044(4) 0.2064(3) 0.0539(7) 0.0413(16) Uani 0.683(3) 1 d PDU . 1
N101 N 0.5350(5) 0.1633(3) 0.1987(8) 0.0354(16) Uani 0.683(3) 1 d PDU . 1
C101 C 0.4710(5) 0.1394(3) 0.2434(8) 0.0340(16) Uani 0.683(3) 1 d PDU . 1
N102 N 0.4106(5) 0.1446(4) 0.1694(9) 0.0429(18) Uani 0.683(3) 1 d PDU . 1
C102 C 0.4183(6) 0.1691(5) 0.0515(10) 0.0445(19) Uani 0.683(3) 1 d PDU . 1
H102 H 0.3768 0.1707 0.0005 0.053 Uiso 0.683(3) 1 calc PR . 1
C103 C 0.4790(6) 0.1913(5) -0.0005(10) 0.0415(18) Uani 0.683(3) 1 d PDU . 1
C104 C 0.5391(5) 0.1879(4) 0.0794(9) 0.0370(17) Uani 0.683(3) 1 d PDU . 1
C105 C 0.4781(13) 0.2209(7) -0.1322(14) 0.044(4) Uani 0.40 1 d PDU . 1
H10A H 0.4905 0.2686 -0.1281 0.066 Uiso 0.683(3) 1 calc PR . 1
H10B H 0.4304 0.2159 -0.1686 0.066 Uiso 0.683(3) 1 calc PR . 1
H10C H 0.5128 0.1972 -0.1851 0.066 Uiso 0.683(3) 1 calc PR . 1
O201 O 0.6194(4) 0.0339(4) 0.3501(6) 0.0342(15) Uani 0.683(3) 1 d PDU . 1
O202 O 0.7249(4) -0.1002(4) 0.0656(8) 0.0465(17) Uani 0.683(3) 1 d PDU . 1
N201 N 0.6754(4) -0.0310(5) 0.2022(8) 0.0393(17) Uani 0.683(3) 1 d PDU . 1
C201 C 0.6509(4) 0.0298(5) 0.2431(8) 0.0366(17) Uani 0.683(3) 1 d PDU . 1
N202 N 0.6613(4) 0.0866(5) 0.1716(8) 0.0421(17) Uani 0.683(3) 1 d PDU . 1
C202 C 0.6936(5) 0.0782(6) 0.0573(10) 0.0449(19) Uani 0.683(3) 1 d PDU . 1
H202 H 0.6998 0.1173 0.0071 0.054 Uiso 0.683(3) 1 calc PR . 1
C203 C 0.7172(5) 0.0202(6) 0.0093(10) 0.050(2) Uani 0.683(3) 1 d PDU . 1
C204 C 0.7069(4) -0.0370(5) 0.0882(9) 0.0417(18) Uani 0.683(3) 1 d PDU . 1
C205 C 0.7538(6) 0.0196(10) -0.1174(12) 0.074(4) Uani 0.683(3) 1 d PDU . 1
H20A H 0.7190 0.0093 -0.1833 0.111 Uiso 0.683(3) 1 calc PR . 1
H20B H 0.7913 -0.0146 -0.1175 0.111 Uiso 0.683(3) 1 calc PR . 1
H20C H 0.7749 0.0638 -0.1336 0.111 Uiso 0.683(3) 1 calc PR . 1
C301 C 0.3058(4) 0.1640(4) 0.4484(7) 0.064(3) Uani 0.683(3) 1 d PGU . 1
C302 C 0.3156(4) 0.2212(4) 0.3724(7) 0.064(2) Uani 0.683(3) 1 d PGU . 1
C303 C 0.2579(4) 0.2246(4) 0.2856(8) 0.068(2) Uani 0.683(3) 1 d PGU . 1
C304 C 0.2125(4) 0.1693(4) 0.3080(8) 0.074(2) Uani 0.683(3) 1 d PGU . 1
C305 C 0.2420(4) 0.1319(4) 0.4086(8) 0.071(3) Uani 0.683(3) 1 d PGU . 1
C306 C 0.3545(6) 0.1412(6) 0.5530(10) 0.084(4) Uani 0.683(3) 1 d PGU . 1
H30A H 0.3329 0.1520 0.6346 0.126 Uiso 0.683(3) 1 calc PR . 1
H30B H 0.4004 0.1643 0.5455 0.126 Uiso 0.683(3) 1 calc PR . 1
H30C H 0.3619 0.0926 0.5469 0.126 Uiso 0.683(3) 1 calc PR . 1
C307 C 0.3766(6) 0.2700(6) 0.3821(11) 0.087(4) Uani 0.683(3) 1 d PGU . 1
H30D H 0.3900 0.2853 0.2975 0.131 Uiso 0.683(3) 1 calc PR . 1
H30E H 0.4174 0.2478 0.4219 0.131 Uiso 0.683(3) 1 calc PR . 1
H30F H 0.3621 0.3087 0.4330 0.131 Uiso 0.683(3) 1 calc PR . 1
C308 C 0.2469(6) 0.2775(6) 0.1870(12) 0.090(5) Uani 0.683(3) 1 d PGU . 1
H30G H 0.2009 0.2703 0.1453 0.136 Uiso 0.683(3) 1 calc PR . 1
H30H H 0.2852 0.2748 0.1244 0.136 Uiso 0.683(3) 1 calc PR . 1
H30I H 0.2473 0.3219 0.2267 0.136 Uiso 0.683(3) 1 calc PR . 1
C309 C 0.1446(6) 0.1533(6) 0.2374(13) 0.107(5) Uani 0.683(3) 1 d PGU . 1
H30J H 0.1233 0.1123 0.2721 0.161 Uiso 0.683(3) 1 calc PR . 1
H30K H 0.1555 0.1464 0.1480 0.161 Uiso 0.683(3) 1 calc PR . 1
H30L H 0.1111 0.1907 0.2462 0.161 Uiso 0.683(3) 1 calc PR . 1
C310 C 0.2112(6) 0.0690(6) 0.4636(12) 0.099(5) Uani 0.683(3) 1 d PGU . 1
H31A H 0.2496 0.0374 0.4829 0.148 Uiso 0.683(3) 1 calc PR . 1
H31B H 0.1784 0.0486 0.4027 0.148 Uiso 0.683(3) 1 calc PR . 1
H31C H 0.1852 0.0800 0.5411 0.148 Uiso 0.683(3) 1 calc PR . 1
C401 C 0.7046(4) 0.1838(4) 0.4166(7) 0.058(2) Uani 0.683(3) 1 d PGU . 1
C402 C 0.7485(4) 0.2049(4) 0.3145(7) 0.068(2) Uani 0.683(3) 1 d PGU . 1
C403 C 0.7163(4) 0.2626(4) 0.2603(7) 0.071(2) Uani 0.683(3) 1 d PGU . 1
C404 C 0.6526(4) 0.2772(3) 0.3290(7) 0.066(3) Uani 0.683(3) 1 d PGU . 1
C405 C 0.6454(4) 0.2285(4) 0.4256(7) 0.060(2) Uani 0.683(3) 1 d PGU . 1
C406 C 0.7186(6) 0.1244(5) 0.5008(10) 0.081(4) Uani 0.683(3) 1 d PGU . 1
H40A H 0.7567 0.0969 0.4645 0.121 Uiso 0.683(3) 1 calc PR . 1
H40B H 0.6751 0.0974 0.5082 0.121 Uiso 0.683(3) 1 calc PR . 1
H40C H 0.7330 0.1402 0.5844 0.121 Uiso 0.683(3) 1 calc PR . 1
C407 C 0.8172(6) 0.1719(6) 0.2711(11) 0.092(5) Uani 0.683(3) 1 d PGU . 1
H40D H 0.8573 0.1904 0.3187 0.138 Uiso 0.683(3) 1 calc PR . 1
H40E H 0.8242 0.1805 0.1810 0.138 Uiso 0.683(3) 1 calc PR . 1
H40F H 0.8143 0.1233 0.2855 0.138 Uiso 0.683(3) 1 calc PR . 1
C408 C 0.7448(6) 0.3016(5) 0.1493(11) 0.085(5) Uani 0.683(3) 1 d PGU . 1
H40G H 0.7052 0.3219 0.1031 0.127 Uiso 0.683(3) 1 calc PR . 1
H40H H 0.7710 0.2712 0.0934 0.127 Uiso 0.683(3) 1 calc PR . 1
H40I H 0.7769 0.3370 0.1794 0.127 Uiso 0.683(3) 1 calc PR . 1
C409 C 0.6015(6) 0.3343(5) 0.3038(11) 0.101(5) Uani 0.683(3) 1 d PGU . 1
H40J H 0.5711 0.3412 0.3777 0.151 Uiso 0.683(3) 1 calc PR . 1
H40K H 0.5718 0.3234 0.2307 0.151 Uiso 0.683(3) 1 calc PR . 1
H40L H 0.6285 0.3754 0.2866 0.151 Uiso 0.683(3) 1 calc PR . 1
C410 C 0.5853(6) 0.2248(6) 0.5210(10) 0.092(5) Uani 0.683(3) 1 d PGU . 1
H41A H 0.5707 0.2704 0.5446 0.139 Uiso 0.683(3) 1 calc PR . 1
H41B H 0.6016 0.2007 0.5961 0.139 Uiso 0.683(3) 1 calc PR . 1
H41C H 0.5447 0.2010 0.4839 0.139 Uiso 0.683(3) 1 calc PR . 1
Rh8 Rh 0.33448(18) 0.16371(18) 0.2423(3) 0.0464(8) Uani 0.317(3) 1 d PU . 2
Rh9 Rh 0.66988(18) 0.15475(19) 0.2512(3) 0.0485(8) Uani 0.317(3) 1 d PU . 2
O601 O 0.5111(9) 0.1183(7) 0.3537(12) 0.036(3) Uiso 0.317(3) 1 d PDU . 2
O602 O 0.3672(8) 0.1896(8) 0.0506(16) 0.050(3) Uiso 0.317(3) 1 d PDU . 2
N601 N 0.4392(9) 0.1559(6) 0.1947(15) 0.039(3) Uiso 0.317(3) 1 d PDU . 2
C601 C 0.5059(9) 0.1424(6) 0.2421(13) 0.034(3) Uiso 0.317(3) 1 d PDU . 2
N602 N 0.5678(10) 0.1546(7) 0.1747(15) 0.040(3) Uiso 0.317(3) 1 d PDU . 2
C602 C 0.5596(10) 0.1795(9) 0.0565(17) 0.039(3) Uiso 0.317(3) 1 d PDU . 2
H602 H 0.6017 0.1876 0.0093 0.047 Uiso 0.317(3) 1 calc PR . 2
C603 C 0.4978(10) 0.1936(8) 0.0004(15) 0.041(3) Uiso 0.317(3) 1 d PDU . 2
C604 C 0.4362(9) 0.1813(6) 0.0749(16) 0.042(3) Uiso 0.317(3) 1 d PDU . 2
C605 C 0.5031(17) 0.2222(11) -0.1317(18) 0.047(5) Uiso 0.30 1 d PDU . 2
C606 C 0.4880(17) 0.2009(14) -0.148(3) 0.036(4) Uiso 0.30 1 d PU B 3
O701 O 0.6241(8) -0.0171(8) 0.3511(13) 0.041(3) Uiso 0.317(3) 1 d PDU . 2
O702 O 0.7076(9) 0.1283(7) 0.0630(18) 0.051(3) Uiso 0.317(3) 1 d PDU . 2
N701 N 0.6683(7) 0.0559(9) 0.1999(15) 0.041(3) Uiso 0.317(3) 1 d PDU . 2
C701 C 0.6523(6) -0.0077(9) 0.2422(14) 0.039(3) Uiso 0.317(3) 1 d PDU . 2
N702 N 0.6662(8) -0.0650(9) 0.1707(15) 0.046(3) Uiso 0.317(3) 1 d PDU . 2
C702 C 0.6952(10) -0.0531(10) 0.0555(17) 0.046(3) Uiso 0.317(3) 1 d PDU . 2
H702 H 0.7046 -0.0915 0.0050 0.055 Uiso 0.317(3) 1 calc PR . 2
C703 C 0.7121(9) 0.0063(10) 0.0050(16) 0.046(3) Uiso 0.317(3) 1 d PDU . 2
C704 C 0.6978(7) 0.0632(9) 0.0819(17) 0.045(3) Uiso 0.317(3) 1 d PDU . 2
C705 C 0.7447(12) 0.0025(18) -0.1254(18) 0.049(5) Uiso 0.317(3) 1 d PDU . 2
H70A H 0.7937 0.0192 -0.1224 0.074 Uiso 0.317(3) 1 calc PR . 2
H70B H 0.7168 0.0301 -0.1838 0.074 Uiso 0.317(3) 1 calc PR . 2
H70C H 0.7446 -0.0442 -0.1544 0.074 Uiso 0.317(3) 1 calc PR . 2
C801 C 0.3268(8) 0.2024(8) 0.4264(16) 0.065(4) Uiso 0.317(3) 1 d PGU . 2
C802 C 0.3141(9) 0.2506(8) 0.3290(17) 0.071(3) Uiso 0.317(3) 1 d PGU . 2
C803 C 0.2505(10) 0.2309(9) 0.2620(18) 0.072(3) Uiso 0.317(3) 1 d PGU . 2
C804 C 0.2239(10) 0.1705(9) 0.3180(18) 0.074(3) Uiso 0.317(3) 1 d PGU . 2
C805 C 0.2711(9) 0.1529(8) 0.4196(17) 0.068(3) Uiso 0.317(3) 1 d PGU . 2
C806 C 0.3887(13) 0.2036(12) 0.521(2) 0.078(7) Uiso 0.317(3) 1 d PGU . 2
H80A H 0.4105 0.2483 0.5212 0.117 Uiso 0.317(3) 1 calc PR . 2
H80B H 0.4244 0.1702 0.4959 0.117 Uiso 0.317(3) 1 calc PR . 2
H80C H 0.3709 0.1930 0.6051 0.117 Uiso 0.317(3) 1 calc PR . 2
C807 C 0.3602(13) 0.3121(13) 0.302(3) 0.098(8) Uiso 0.317(3) 1 d PGU . 2
H80D H 0.3379 0.3520 0.3383 0.147 Uiso 0.317(3) 1 calc PR . 2
H80E H 0.3647 0.3179 0.2102 0.147 Uiso 0.317(3) 1 calc PR . 2
H80F H 0.4075 0.3057 0.3384 0.147 Uiso 0.317(3) 1 calc PR . 2
C808 C 0.2171(14) 0.2677(13) 0.151(3) 0.081(8) Uiso 0.317(3) 1 d PGU . 2
C809 C 0.1572(14) 0.1318(13) 0.277(3) 0.093(7) Uiso 0.317(3) 1 d PGU . 2
H80J H 0.1524 0.0910 0.3277 0.140 Uiso 0.317(3) 1 calc PR . 2
H80K H 0.1615 0.1195 0.1876 0.140 Uiso 0.317(3) 1 calc PR . 2
H80L H 0.1151 0.1601 0.2884 0.140 Uiso 0.317(3) 1 calc PR . 2
C810 C 0.2633(14) 0.0922(13) 0.505(3) 0.092(7) Uiso 0.317(3) 1 d PGU . 2
H81A H 0.3002 0.0935 0.5706 0.138 Uiso 0.317(3) 1 calc PR . 2
H81B H 0.2684 0.0510 0.4556 0.138 Uiso 0.317(3) 1 calc PR . 2
H81C H 0.2162 0.0929 0.5452 0.138 Uiso 0.317(3) 1 calc PR . 2
C901 C 0.7301(9) 0.1637(8) 0.4039(16) 0.064(3) Uiso 0.317(3) 1 d PGU . 2
C902 C 0.7562(9) 0.2042(9) 0.3028(17) 0.070(3) Uiso 0.317(3) 1 d PGU . 2
C903 C 0.7069(9) 0.2578(9) 0.2851(17) 0.071(3) Uiso 0.317(3) 1 d PGU . 2
C904 C 0.6504(8) 0.2504(8) 0.3752(16) 0.066(4) Uiso 0.317(3) 1 d PGU . 2
C905 C 0.6647(8) 0.1922(8) 0.4486(15) 0.061(4) Uiso 0.317(3) 1 d PGU . 2
C906 C 0.7657(13) 0.1012(12) 0.455(2) 0.095(8) Uiso 0.317(3) 1 d PGU . 2
H90A H 0.7390 0.0846 0.5279 0.142 Uiso 0.317(3) 1 calc PR . 2
H90B H 0.8145 0.1119 0.4804 0.142 Uiso 0.317(3) 1 calc PR . 2
H90C H 0.7666 0.0665 0.3893 0.142 Uiso 0.317(3) 1 calc PR . 2
C907 C 0.8244(14) 0.1924(13) 0.227(3) 0.091(8) Uiso 0.317(3) 1 d PGU . 2
H90D H 0.8304 0.1441 0.2126 0.137 Uiso 0.317(3) 1 calc PR . 2
H90E H 0.8652 0.2095 0.2750 0.137 Uiso 0.317(3) 1 calc PR . 2
H90F H 0.8211 0.2159 0.1465 0.137 Uiso 0.317(3) 1 calc PR . 2
C908 C 0.7134(14) 0.3130(13) 0.188(3) 0.080(7) Uiso 0.317(3) 1 d PGU . 2
H90G H 0.6887 0.2995 0.1104 0.121 Uiso 0.317(3) 1 calc PR . 2
H90H H 0.7638 0.3209 0.1689 0.121 Uiso 0.317(3) 1 calc PR . 2
H90I H 0.6920 0.3543 0.2204 0.121 Uiso 0.317(3) 1 calc PR . 2
C909 C 0.5862(13) 0.2964(13) 0.390(2) 0.094(7) Uiso 0.317(3) 1 d PGU . 2
C910 C 0.6185(12) 0.1655(12) 0.555(2) 0.068(7) Uiso 0.317(3) 1 d PGU . 2
H91A H 0.6282 0.1175 0.5676 0.102 Uiso 0.317(3) 1 calc PR . 2
H91B H 0.5682 0.1717 0.5342 0.102 Uiso 0.317(3) 1 calc PR . 2
H91C H 0.6295 0.1899 0.6332 0.102 Uiso 0.317(3) 1 calc PR . 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
La1 O201 2.481(7) . ?
La1 O201 2.481(7) 4_655 ?
La1 O601 2.490(13) . ?
La1 O601 2.490(13) 4_655 ?
La1 O701 2.491(14) . ?
La1 O701 2.491(14) 4_655 ?
La1 O101 2.498(7) . ?
La1 O101 2.498(7) 4_655 ?
La1 O523 2.632(8) 4_655 ?
La1 O523 2.632(8) . ?
La1 O522 2.722(7) 4_655 ?
La1 O522 2.722(7) . ?
N511 C511 1.119(11) . ?
C511 C512 1.465(15) . ?
N521 O522 1.270(15) . ?
N521 O523 1.274(15) . ?
N521 O521 1.296(12) . ?
N531 O532 1.273(18) . ?
N531 O533 1.279(18) . ?
N531 O531 1.312(16) . ?
O531 N531 1.312(16) 4 ?
O542 O542 1.17(11) 4_755 ?
Rh3 C304 2.065(8) . ?
Rh3 N102 2.082(10) . ?
Rh3 C303 2.099(8) . ?
Rh3 C305 2.110(8) . ?
Rh3 N201 2.119(9) 4_655 ?
Rh3 C302 2.175(7) . ?
Rh3 O202 2.178(9) 4_655 ?
Rh3 C301 2.184(7) . ?
Rh3 C204 2.602(10) 4_655 ?
Rh4 N202 2.072(9) . ?
Rh4 N101 2.104(9) . ?
Rh4 C404 2.115(7) . ?
Rh4 C403 2.125(7) . ?
Rh4 C405 2.164(7) . ?
Rh4 O102 2.165(8) . ?
Rh4 C402 2.183(8) . ?
Rh4 C401 2.198(7) . ?
Rh4 C104 2.595(10) . ?
O101 C101 1.254(10) . ?
O102 C104 1.310(11) . ?
N101 C104 1.360(12) . ?
N101 C101 1.378(11) . ?
C101 N102 1.383(11) . ?
N102 C102 1.350(12) . ?
C102 C103 1.341(14) . ?
C103 C104 1.413(13) . ?
C103 C105 1.517(14) . ?
O201 C201 1.284(10) . ?
O202 C204 1.326(11) . ?
O202 Rh3 2.178(9) 4_655 ?
N201 C204 1.351(12) . ?
N201 C201 1.366(11) . ?
N201 Rh3 2.119(9) 4_655 ?
C201 N202 1.377(11) . ?
N202 C202 1.367(13) . ?
C202 C203 1.338(15) . ?
C203 C204 1.427(14) . ?
C203 C205 1.510(13) . ?
C204 Rh3 2.602(10) 4_655 ?
C301 C302 1.409(4) . ?
C301 C305 1.421(4) . ?
C301 C306 1.509(5) . ?
C302 C303 1.423(4) . ?
C302 C307 1.506(5) . ?
C303 C304 1.412(4) . ?
C303 C308 1.500(5) . ?
C304 C305 1.415(4) . ?
C304 C309 1.513(5) . ?
C305 C310 1.498(5) . ?
C401 C402 1.424(4) . ?
C401 C405 1.427(4) . ?
C401 C406 1.506(4) . ?
C402 C403 1.419(4) . ?
C402 C407 1.520(4) . ?
C403 C404 1.431(4) . ?
C403 C408 1.509(4) . ?
C404 C405 1.417(4) . ?
C404 C409 1.513(4) . ?
C405 C410 1.518(4) . ?
Rh8 C802 1.997(18) . ?
Rh8 N601 2.037(18) . ?
Rh8 C803 2.08(2) . ?
Rh8 C801 2.105(17) . ?
Rh8 N702 2.108(18) 4_655 ?
Rh8 O602 2.187(18) . ?
Rh8 C804 2.23(2) . ?
Rh8 C805 2.237(19) . ?
Rh9 C902 1.97(2) . ?
Rh9 C901 1.984(19) . ?
Rh9 N701 2.042(18) . ?
Rh9 N602 2.082(18) . ?
Rh9 O702 2.184(19) . ?
Rh9 C903 2.197(19) . ?
Rh9 C905 2.226(16) . ?
Rh9 C904 2.344(17) . ?
Rh9 C704 2.612(18) . ?
O601 C601 1.281(14) . ?
O602 C604 1.332(16) . ?
N601 C604 1.369(16) . ?
N601 C601 1.377(15) . ?
C601 N602 1.386(15) . ?
N602 C602 1.357(16) . ?
C602 C603 1.334(18) . ?
C603 C604 1.421(17) . ?
C603 C605 1.516(16) . ?
O701 C701 1.286(14) . ?
O702 C704 1.324(16) . ?
N701 C701 1.376(15) . ?
N701 C704 1.377(16) . ?
C701 N702 1.395(15) . ?
N702 C702 1.358(16) . ?
N702 Rh8 2.108(18) 4_655 ?
C702 C703 1.337(19) . ?
C703 C704 1.422(17) . ?
C703 C705 1.515(15) . ?
C801 C802 1.431(9) . ?
C801 C805 1.441(10) . ?
C801 C806 1.534(10) . ?
C802 C803 1.445(10) . ?
C802 C807 1.526(10) . ?
C803 C804 1.432(9) . ?
C803 C808 1.525(10) . ?
C804 C805 1.439(10) . ?
C804 C809 1.535(10) . ?
C805 C810 1.520(10) . ?
C901 C902 1.429(9) . ?
C901 C905 1.435(9) . ?
C901 C906 1.512(10) . ?
C902 C903 1.426(9) . ?
C902 C907 1.528(10) . ?
C903 C904 1.436(9) . ?
C903 C908 1.514(10) . ?
C904 C905 1.422(9) . ?
C904 C909 1.521(10) . ?
C905 C910 1.524(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O201 La1 O201 141.4(3) . 4_655 ?
O201 La1 O601 64.1(4) . . ?
O201 La1 O601 103.2(4) 4_655 . ?
O201 La1 O601 103.2(4) . 4_655 ?
O201 La1 O601 64.1(4) 4_655 4_655 ?
O601 La1 O601 143.4(6) . 4_655 ?
O201 La1 O701 23.6(4) . . ?
O201 La1 O701 134.5(3) 4_655 . ?
O601 La1 O701 87.0(5) . . ?
O601 La1 O701 81.2(5) 4_655 . ?
O201 La1 O701 134.5(3) . 4_655 ?
O201 La1 O701 23.6(4) 4_655 4_655 ?
O601 La1 O701 81.2(5) . 4_655 ?
O601 La1 O701 87.0(5) 4_655 4_655 ?
O701 La1 O701 142.1(6) . 4_655 ?
O201 La1 O101 82.5(2) . . ?
O201 La1 O101 85.3(2) 4_655 . ?
O601 La1 O101 19.2(4) . . ?
O601 La1 O101 137.9(3) 4_655 . ?
O701 La1 O101 104.6(4) . . ?
O701 La1 O101 62.6(4) 4_655 . ?
O201 La1 O101 85.3(2) . 4_655 ?
O201 La1 O101 82.5(2) 4_655 4_655 ?
O601 La1 O101 137.9(3) . 4_655 ?
O601 La1 O101 19.2(4) 4_655 4_655 ?
O701 La1 O101 62.6(4) . 4_655 ?
O701 La1 O101 104.6(4) 4_655 4_655 ?
O101 La1 O101 142.5(3) . 4_655 ?
O201 La1 O523 121.7(3) . 4_655 ?
O201 La1 O523 89.3(3) 4_655 4_655 ?
O601 La1 O523 147.2(4) . 4_655 ?
O601 La1 O523 69.3(4) 4_655 4_655 ?
O701 La1 O523 105.7(4) . 4_655 ?
O701 La1 O523 103.5(4) 4_655 4_655 ?
O101 La1 O523 142.2(3) . 4_655 ?
O101 La1 O523 73.0(3) 4_655 4_655 ?
O201 La1 O523 89.3(3) . . ?
O201 La1 O523 121.7(3) 4_655 . ?
O601 La1 O523 69.3(4) . . ?
O601 La1 O523 147.2(4) 4_655 . ?
O701 La1 O523 103.5(4) . . ?
O701 La1 O523 105.7(4) 4_655 . ?
O101 La1 O523 73.0(3) . . ?
O101 La1 O523 142.2(3) 4_655 . ?
O523 La1 O523 78.3(5) 4_655 . ?
O201 La1 O522 150.1(3) . 4_655 ?
O201 La1 O522 67.5(3) 4_655 4_655 ?
O601 La1 O522 108.9(4) . 4_655 ?
O601 La1 O522 97.8(4) 4_655 4_655 ?
O701 La1 O522 150.3(4) . 4_655 ?
O701 La1 O522 66.9(4) 4_655 4_655 ?
O101 La1 O522 95.9(3) . 4_655 ?
O101 La1 O522 111.6(3) 4_655 4_655 ?
O523 La1 O522 48.1(3) 4_655 4_655 ?
O523 La1 O522 62.0(3) . 4_655 ?
O201 La1 O522 67.5(3) . . ?
O201 La1 O522 150.1(3) 4_655 . ?
O601 La1 O522 97.8(4) . . ?
O601 La1 O522 108.9(4) 4_655 . ?
O701 La1 O522 66.9(4) . . ?
O701 La1 O522 150.3(4) 4_655 . ?
O101 La1 O522 111.6(3) . . ?
O101 La1 O522 95.9(3) 4_655 . ?
O523 La1 O522 62.0(3) 4_655 . ?
O523 La1 O522 48.1(3) . . ?
O522 La1 O522 85.8(4) 4_655 . ?
C511 N511 La1 180.0 . . ?
N511 C511 C512 180.0 . . ?
O522 N521 O523 118.3(9) . . ?
O522 N521 O521 124.4(12) . . ?
O523 N521 O521 117.2(11) . . ?
N521 O522 La1 94.2(7) . . ?
N521 O523 La1 98.4(7) . . ?
O532 N531 O533 117.0(16) . . ?
O532 N531 O531 123.3(19) . . ?
O533 N531 O531 115.6(17) . . ?
N531 O531 N531 174(7) . 4 ?
C304 Rh3 N102 152.8(3) . . ?
C304 Rh3 C303 39.63(17) . . ?
N102 Rh3 C303 113.8(3) . . ?
C304 Rh3 C305 39.61(17) . . ?
N102 Rh3 C305 151.7(3) . . ?
C303 Rh3 C305 65.6(3) . . ?
C304 Rh3 N201 121.1(3) . 4_655 ?
N102 Rh3 N201 83.6(3) . 4_655 ?
C303 Rh3 N201 159.0(3) . 4_655 ?
C305 Rh3 N201 104.9(3) . 4_655 ?
C304 Rh3 C302 65.6(3) . . ?
N102 Rh3 C302 96.8(3) . . ?
C303 Rh3 C302 38.84(16) . . ?
C305 Rh3 C302 64.4(2) . . ?
N201 Rh3 C302 155.8(3) 4_655 . ?
C304 Rh3 O202 95.7(3) . 4_655 ?
N102 Rh3 O202 86.2(3) . 4_655 ?
C303 Rh3 O202 106.1(3) . 4_655 ?
C305 Rh3 O202 121.8(3) . 4_655 ?
N201 Rh3 O202 61.7(3) 4_655 4_655 ?
C302 Rh3 O202 142.4(3) . 4_655 ?
C304 Rh3 C301 65.5(3) . . ?
N102 Rh3 C301 113.9(3) . . ?
C303 Rh3 C301 64.6(2) . . ?
C305 Rh3 C301 38.60(15) . . ?
N201 Rh3 C301 120.5(3) 4_655 . ?
C302 Rh3 C301 37.71(14) . . ?
O202 Rh3 C301 159.8(3) 4_655 . ?
C304 Rh3 C204 109.8(3) . 4_655 ?
N102 Rh3 C204 85.2(3) . 4_655 ?
C303 Rh3 C204 134.1(3) . 4_655 ?
C305 Rh3 C204 116.1(3) . 4_655 ?
N201 Rh3 C204 31.2(3) 4_655 4_655 ?
C302 Rh3 C204 172.8(3) . 4_655 ?
O202 Rh3 C204 30.6(3) 4_655 4_655 ?
C301 Rh3 C204 146.9(3) . 4_655 ?
N202 Rh4 N101 85.5(3) . . ?
N202 Rh4 C404 164.3(3) . . ?
N101 Rh4 C404 109.9(3) . . ?
N202 Rh4 C403 128.0(3) . . ?
N101 Rh4 C403 141.4(3) . . ?
C404 Rh4 C403 39.44(16) . . ?
N202 Rh4 C405 135.0(3) . . ?
N101 Rh4 C405 107.0(3) . . ?
C404 Rh4 C405 38.65(15) . . ?
C403 Rh4 C405 65.0(2) . . ?
N202 Rh4 O102 86.2(3) . . ?
N101 Rh4 O102 61.7(3) . . ?
C404 Rh4 O102 103.7(3) . . ?
C403 Rh4 O102 97.9(3) . . ?
C405 Rh4 O102 138.0(3) . . ?
N202 Rh4 C402 99.4(3) . . ?
N101 Rh4 C402 171.1(3) . . ?
C404 Rh4 C402 65.0(2) . . ?
C403 Rh4 C402 38.44(15) . . ?
C405 Rh4 C402 64.4(2) . . ?
O102 Rh4 C402 125.7(3) . . ?
N202 Rh4 C401 102.9(3) . . ?
N101 Rh4 C401 133.8(3) . . ?
C404 Rh4 C401 64.3(2) . . ?
C403 Rh4 C401 64.0(2) . . ?
C405 Rh4 C401 38.20(14) . . ?
O102 Rh4 C401 161.8(3) . . ?
C402 Rh4 C401 37.94(14) . . ?
N202 Rh4 C104 86.1(3) . . ?
N101 Rh4 C104 31.5(3) . . ?
C404 Rh4 C104 108.7(3) . . ?
C403 Rh4 C104 121.3(3) . . ?
C405 Rh4 C104 126.7(3) . . ?
O102 Rh4 C104 30.3(3) . . ?
C402 Rh4 C104 155.5(3) . . ?
C401 Rh4 C104 163.1(3) . . ?
C101 O101 La1 129.7(4) . . ?
C104 O102 Rh4 93.3(6) . . ?
C104 N101 C101 119.5(8) . . ?
C104 N101 Rh4 94.6(6) . . ?
C101 N101 Rh4 145.8(6) . . ?
O101 C101 N101 120.1(8) . . ?
O101 C101 N102 120.2(8) . . ?
N101 C101 N102 119.7(8) . . ?
C102 N102 C101 117.7(9) . . ?
C102 N102 Rh3 121.4(7) . . ?
C101 N102 Rh3 119.8(6) . . ?
C103 C102 N102 126.3(10) . . ?
C102 C103 C104 114.5(9) . . ?
C102 C103 C105 119.9(13) . . ?
C104 C103 C105 125.5(12) . . ?
O102 C104 N101 110.3(8) . . ?
O102 C104 C103 127.6(9) . . ?
N101 C104 C103 122.1(9) . . ?
O102 C104 Rh4 56.4(5) . . ?
N101 C104 Rh4 53.9(5) . . ?
C103 C104 Rh4 175.5(6) . . ?
C201 O201 La1 133.8(4) . . ?
C204 O202 Rh3 92.6(6) . 4_655 ?
C204 N201 C201 120.7(8) . . ?
C204 N201 Rh3 94.5(6) . 4_655 ?
C201 N201 Rh3 144.8(7) . 4_655 ?
O201 C201 N201 119.6(8) . . ?
O201 C201 N202 120.0(8) . . ?
N201 C201 N202 120.4(8) . . ?
C202 N202 C201 116.9(9) . . ?
C202 N202 Rh4 120.2(7) . . ?
C201 N202 Rh4 122.4(6) . . ?
C203 C202 N202 126.2(10) . . ?
C202 C203 C204 114.9(9) . . ?
C202 C203 C205 119.8(12) . . ?
C204 C203 C205 125.3(12) . . ?
O202 C204 N201 110.9(9) . . ?
O202 C204 C203 128.1(9) . . ?
N201 C204 C203 121.0(9) . . ?
O202 C204 Rh3 56.7(5) . 4_655 ?
N201 C204 Rh3 54.3(5) . 4_655 ?
C203 C204 Rh3 174.3(7) . 4_655 ?
C302 C301 C305 107.7 . . ?
C302 C301 C306 125.8 . . ?
C305 C301 C306 126.5 . . ?
C302 C301 Rh3 70.8(3) . . ?
C305 C301 Rh3 67.9(3) . . ?
C306 C301 Rh3 126.7(3) . . ?
C301 C302 C303 108.0 . . ?
C301 C302 C307 125.6 . . ?
C303 C302 C307 126.4 . . ?
C301 C302 Rh3 71.5(2) . . ?
C303 C302 Rh3 67.7(3) . . ?
C307 C302 Rh3 126.4(3) . . ?
C304 C303 C302 108.4 . . ?
C304 C303 C308 125.5 . . ?
C302 C303 C308 126.1 . . ?
C304 C303 Rh3 68.9(3) . . ?
C302 C303 Rh3 73.5(3) . . ?
C308 C303 Rh3 123.4(2) . . ?
C303 C304 C305 107.4 . . ?
C303 C304 C309 126.2 . . ?
C305 C304 C309 126.4 . . ?
C303 C304 Rh3 71.5(3) . . ?
C305 C304 Rh3 71.9(3) . . ?
C309 C304 Rh3 122.1(2) . . ?
C304 C305 C301 108.5 . . ?
C304 C305 C310 125.6 . . ?
C301 C305 C310 125.9 . . ?
C304 C305 Rh3 68.5(3) . . ?
C301 C305 Rh3 73.5(3) . . ?
C310 C305 Rh3 123.8(3) . . ?
C402 C401 C405 108.5 . . ?
C402 C401 C406 125.6 . . ?
C405 C401 C406 125.8 . . ?
C402 C401 Rh4 70.5(2) . . ?
C405 C401 Rh4 69.6(2) . . ?
C406 C401 Rh4 125.8(2) . . ?
C403 C402 C401 107.5 . . ?
C403 C402 C407 126.1 . . ?
C401 C402 C407 126.4 . . ?
C403 C402 Rh4 68.6(2) . . ?
C401 C402 Rh4 71.6(2) . . ?
C407 C402 Rh4 125.2(2) . . ?
C402 C403 C404 108.3 . . ?
C402 C403 C408 125.5 . . ?
C404 C403 C408 126.2 . . ?
C402 C403 Rh4 73.0(2) . . ?
C404 C403 Rh4 69.9(3) . . ?
C408 C403 Rh4 122.9(2) . . ?
C405 C404 C403 108.1 . . ?
C405 C404 C409 125.6 . . ?
C403 C404 C409 126.4 . . ?
C405 C404 Rh4 72.5(2) . . ?
C403 C404 Rh4 70.6(3) . . ?
C409 C404 Rh4 122.5(2) . . ?
C404 C405 C401 107.6 . . ?
C404 C405 C410 125.9 . . ?
C401 C405 C410 126.5 . . ?
C404 C405 Rh4 68.8(2) . . ?
C401 C405 Rh4 72.2(2) . . ?
C410 C405 Rh4 124.4(2) . . ?
C802 Rh8 N601 111.4(6) . . ?
C802 Rh8 C803 41.5(4) . . ?
N601 Rh8 C803 143.8(6) . . ?
C802 Rh8 C801 40.7(4) . . ?
N601 Rh8 C801 108.9(6) . . ?
C803 Rh8 C801 67.6(6) . . ?
C802 Rh8 N702 166.7(7) . 4_655 ?
N601 Rh8 N702 81.1(5) . 4_655 ?
C803 Rh8 N702 129.2(7) . 4_655 ?
C801 Rh8 N702 132.5(6) . 4_655 ?
C802 Rh8 O602 106.2(6) . . ?
N601 Rh8 O602 61.0(5) . . ?
C803 Rh8 O602 98.9(6) . . ?
C801 Rh8 O602 142.8(6) . . ?
N702 Rh8 O602 83.4(6) 4_655 . ?
C802 Rh8 C804 66.7(6) . . ?
N601 Rh8 C804 173.2(6) . . ?
C803 Rh8 C804 38.6(4) . . ?
C801 Rh8 C804 65.2(6) . . ?
N702 Rh8 C804 100.4(7) 4_655 . ?
O602 Rh8 C804 125.6(6) . . ?
C802 Rh8 C805 66.1(6) . . ?
N601 Rh8 C805 135.7(6) . . ?
C803 Rh8 C805 64.8(6) . . ?
C801 Rh8 C805 38.6(3) . . ?
N702 Rh8 C805 102.1(6) 4_655 . ?
O602 Rh8 C805 162.7(6) . . ?
C804 Rh8 C805 37.6(3) . . ?
C902 Rh9 C901 42.3(4) . . ?
C902 Rh9 N701 124.5(6) . . ?
C901 Rh9 N701 108.2(6) . . ?
C902 Rh9 N602 149.9(7) . . ?
C901 Rh9 N602 147.5(7) . . ?
N701 Rh9 N602 83.2(5) . . ?
C902 Rh9 O702 96.2(7) . . ?
C901 Rh9 O702 125.7(6) . . ?
N701 Rh9 O702 61.9(6) . . ?
N602 Rh9 O702 86.7(6) . . ?
C902 Rh9 C903 39.5(4) . . ?
C901 Rh9 C903 66.6(6) . . ?
N701 Rh9 C903 161.6(6) . . ?
N602 Rh9 C903 110.9(6) . . ?
O702 Rh9 C903 105.8(6) . . ?
C902 Rh9 C905 66.9(6) . . ?
C901 Rh9 C905 39.3(4) . . ?
N701 Rh9 C905 125.0(6) . . ?
N602 Rh9 C905 109.1(6) . . ?
O702 Rh9 C905 162.9(6) . . ?
C903 Rh9 C905 63.0(5) . . ?
C902 Rh9 C904 64.4(5) . . ?
C901 Rh9 C904 63.8(5) . . ?
N701 Rh9 C904 158.5(6) . . ?
N602 Rh9 C904 94.3(6) . . ?
O702 Rh9 C904 139.5(6) . . ?
C903 Rh9 C904 36.7(3) . . ?
C905 Rh9 C904 36.1(3) . . ?
C902 Rh9 C704 112.0(6) . . ?
C901 Rh9 C704 120.6(6) . . ?
N701 Rh9 C704 31.5(5) . . ?
N602 Rh9 C704 85.2(5) . . ?
O702 Rh9 C704 30.4(4) . . ?
C903 Rh9 C704 134.5(6) . . ?
C905 Rh9 C704 152.9(5) . . ?
C904 Rh9 C704 169.9(6) . . ?
C601 O601 La1 129.7(6) . . ?
C604 O602 Rh8 93.7(11) . . ?
C604 N601 C601 116.7(14) . . ?
C604 N601 Rh8 99.3(11) . . ?
C601 N601 Rh8 143.5(12) . . ?
O601 C601 N601 118.7(15) . . ?
O601 C601 N602 118.6(14) . . ?
N601 C601 N602 122.7(13) . . ?
C602 N602 C601 116.5(15) . . ?
C602 N602 Rh9 117.7(13) . . ?
C601 N602 Rh9 124.8(11) . . ?
C603 C602 N602 126.0(17) . . ?
C602 C603 C604 115.0(14) . . ?
C602 C603 C605 115.7(17) . . ?
C604 C603 C605 129.2(18) . . ?
O602 C604 N601 105.4(14) . . ?
O602 C604 C603 131.5(15) . . ?
N601 C604 C603 123.1(14) . . ?
C701 O701 La1 131.2(7) . . ?
C704 O702 Rh9 93.0(12) . . ?
C701 N701 C704 118.8(14) . . ?
C701 N701 Rh9 143.4(12) . . ?
C704 N701 Rh9 97.7(11) . . ?
O701 C701 N701 121.1(15) . . ?
O701 C701 N702 116.5(14) . . ?
N701 C701 N702 122.3(13) . . ?
C702 N702 C701 114.9(15) . . ?
C702 N702 Rh8 119.3(13) . 4_655 ?
C701 N702 Rh8 124.4(11) . 4_655 ?
C703 C702 N702 127.6(17) . . ?
C702 C703 C704 115.5(14) . . ?
C702 C703 C705 114.7(18) . . ?
C704 C703 C705 129.8(19) . . ?
O702 C704 N701 107.3(15) . . ?
O702 C704 C703 131.8(16) . . ?
N701 C704 C703 120.9(14) . . ?
O702 C704 Rh9 56.6(10) . . ?
N701 C704 Rh9 50.8(9) . . ?
C703 C704 Rh9 171.3(12) . . ?
C802 C801 C805 107.6 . . ?
C802 C801 C806 125.9 . . ?
C805 C801 C806 126.5 . . ?
C802 C801 Rh8 65.6(6) . . ?
C805 C801 Rh8 75.7(6) . . ?
C806 C801 Rh8 124.0(6) . . ?
C801 C802 C803 108.1 . . ?
C801 C802 C807 125.6 . . ?
C803 C802 C807 126.3 . . ?
C801 C802 Rh8 73.7(6) . . ?
C803 C802 Rh8 72.3(6) . . ?
C807 C802 Rh8 119.9(6) . . ?
C804 C803 C802 108.2 . . ?
C804 C803 C808 125.5 . . ?
C802 C803 C808 126.2 . . ?
C804 C803 Rh8 76.5(6) . . ?
C802 C803 Rh8 66.2(6) . . ?
C808 C803 Rh8 123.0(6) . . ?
C803 C804 C805 107.5 . . ?
C803 C804 C809 126.1 . . ?
C805 C804 C809 126.4 . . ?
C803 C804 Rh8 64.9(6) . . ?
C805 C804 Rh8 71.5(5) . . ?
C809 C804 Rh8 128.8(5) . . ?
C804 C805 C801 108.6 . . ?
C804 C805 C810 125.7 . . ?
C801 C805 C810 125.8 . . ?
C804 C805 Rh8 71.0(6) . . ?
C801 C805 Rh8 65.7(6) . . ?
C810 C805 Rh8 129.2(6) . . ?
C902 C901 C905 108.5 . . ?
C902 C901 C906 125.6 . . ?
C905 C901 C906 125.9 . . ?
C902 C901 Rh9 68.5(6) . . ?
C905 C901 Rh9 79.5(6) . . ?
C906 C901 Rh9 118.0(6) . . ?
C903 C902 C901 107.4 . . ?
C903 C902 C907 126.2 . . ?
C901 C902 C907 126.4 . . ?
C903 C902 Rh9 78.7(6) . . ?
C901 C902 Rh9 69.2(6) . . ?
C907 C902 Rh9 117.8(6) . . ?
C902 C903 C904 108.4 . . ?
C902 C903 C908 125.5 . . ?
C904 C903 C908 126.1 . . ?
C902 C903 Rh9 61.8(6) . . ?
C904 C903 Rh9 77.2(6) . . ?
C908 C903 Rh9 126.3(5) . . ?
C905 C904 C903 107.9 . . ?
C905 C904 C909 125.6 . . ?
C903 C904 C909 126.4 . . ?
C905 C904 Rh9 67.4(5) . . ?
C903 C904 Rh9 66.1(5) . . ?
C909 C904 Rh9 132.2(6) . . ?
C904 C905 C901 107.7 . . ?
C904 C905 C910 125.8 . . ?
C901 C905 C910 126.5 . . ?
C904 C905 Rh9 76.5(6) . . ?
C901 C905 Rh9 61.2(6) . . ?
C910 C905 Rh9 127.4(6) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.476
_refine_diff_density_min         -1.039
_refine_diff_density_rms         0.141
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4EuNO3
_database_code_depnum_ccdc_archive 'CCDC 1033781'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C62 H79 Eu N11 O14 Rh4 1+, N O3 1-, 2(H2 O)'
_chemical_formula_sum            'C62 H83 Eu N12 O19 Rh4'
_chemical_formula_weight         1864.00

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P 21 21 2'
_symmetry_space_group_name_Hall  'P 2 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z'
'-x, -y, z'

_cell_length_a                   18.4641(7)
_cell_length_b                   19.8783(8)
_cell_length_c                   10.5405(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3868.7(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    186(2)
_cell_measurement_reflns_used    22317
_cell_measurement_theta_min      3.01
_cell_measurement_theta_max      27.52

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.600
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1868
_exptl_absorpt_coefficient_mu    1.705
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.6752
_exptl_absorpt_correction_T_max  0.8480
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      186(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            38771
_diffrn_reflns_av_R_equivalents  0.0472
_diffrn_reflns_av_sigmaI/netI    0.0377
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         3.01
_diffrn_reflns_theta_max         27.48
_reflns_number_total             8861
_reflns_number_gt                7917
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    'Il Milione'
_computing_structure_refinement  SHELXL-97
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0603P)²+15.5959P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.503(16)
_refine_ls_number_reflns         8861
_refine_ls_number_parameters     573
_refine_ls_number_restraints     1418
_refine_ls_R_factor_all          0.0578
_refine_ls_R_factor_gt           0.0493
_refine_ls_wR_factor_ref         0.1349
_refine_ls_wR_factor_gt          0.1256
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.5000 0.0000 0.41541(4) 0.02689(11) Uani 1 2 d SU . .
N511 N 0.5000 0.0000 0.1628(6) 0.0309(14) Uani 1 2 d SU . .
C511 C 0.5000 0.0000 0.0598(8) 0.0383(18) Uani 1 2 d SU . .
C512 C 0.5000 0.0000 -0.0791(12) 0.086(4) Uani 1 2 d SU . .
N521 N 0.5779(5) 0.0532(5) 0.6497(9) 0.072(2) Uani 1 1 d DU . .
O521 O 0.6053(4) 0.0859(4) 0.7406(7) 0.089(2) Uani 1 1 d DU . .
O522 O 0.5966(4) -0.0010(5) 0.6090(7) 0.090(2) Uani 1 1 d DU . .
O523 O 0.5247(4) 0.0791(4) 0.5948(8) 0.082(2) Uani 1 1 d DU . .
N531 N -0.027(2) 0.0540(11) 1.034(3) 0.253(10) Uani 0.50 1 d PDU . .
O531 O 0.0000 0.0000 0.988(3) 0.256(10) Uani 1 2 d SDU . .
O532 O -0.046(2) 0.1040(10) 0.977(3) 0.226(12) Uani 0.50 1 d PDU . .
O533 O -0.059(2) 0.0469(19) 1.139(3) 0.277(13) Uani 0.50 1 d PDU . .
O541 O 0.9551(13) 0.0866(13) 0.457(2) 0.216(10) Uani 0.80 1 d PU A 3
O542 O 0.969(2) 0.010(3) 0.708(4) 0.106(15) Uani 0.20 1 d PU . 4
Rh3 Rh 0.30360(5) 0.12822(5) 0.25355(8) 0.0337(2) Uani 0.779(2) 1 d PU . 1
Rh4 Rh 0.63828(5) 0.18580(5) 0.24122(7) 0.0307(2) Uani 0.779(2) 1 d PU . 1
O101 O 0.4634(3) 0.1093(3) 0.3502(5) 0.0294(12) Uani 0.779(2) 1 d PDU . 1
O102 O 0.5990(3) 0.2086(3) 0.0533(5) 0.0333(13) Uani 0.779(2) 1 d PDU . 1
N101 N 0.5296(4) 0.1630(3) 0.1975(6) 0.0281(13) Uani 0.779(2) 1 d PDU . 1
C101 C 0.4668(4) 0.1365(3) 0.2420(7) 0.0292(13) Uani 0.779(2) 1 d PDU . 1
N102 N 0.4055(4) 0.1415(3) 0.1679(6) 0.0325(14) Uani 0.779(2) 1 d PDU . 1
C102 C 0.4122(5) 0.1665(4) 0.0497(8) 0.0354(16) Uani 0.779(2) 1 d PDU . 1
H102 H 0.3699 0.1673 -0.0016 0.042 Uiso 0.779(2) 1 calc PR . 1
C103 C 0.4744(5) 0.1908(4) -0.0028(7) 0.0365(16) Uani 0.779(2) 1 d PDU . 1
C104 C 0.5351(4) 0.1881(3) 0.0774(7) 0.0291(13) Uani 0.779(2) 1 d PDU . 1
C105 C 0.4781(15) 0.2237(6) -0.1327(13) 0.046(4) Uani 0.40 1 d PDU . 1
H10A H 0.5003 0.2683 -0.1249 0.069 Uiso 0.779(2) 1 calc PR . 1
H10B H 0.4291 0.2282 -0.1673 0.069 Uiso 0.779(2) 1 calc PR . 1
H10C H 0.5074 0.1958 -0.1897 0.069 Uiso 0.779(2) 1 calc PR . 1
O201 O 0.6151(3) 0.0356(3) 0.3467(5) 0.0285(12) Uani 0.779(2) 1 d PDU . 1
O202 O 0.7343(3) -0.0929(3) 0.0703(6) 0.0395(13) Uani 0.779(2) 1 d PDU . 1
N201 N 0.6790(3) -0.0268(3) 0.2057(6) 0.0288(13) Uani 0.779(2) 1 d PDU . 1
C201 C 0.6500(3) 0.0330(4) 0.2435(7) 0.0274(13) Uani 0.779(2) 1 d PDU . 1
N202 N 0.6604(3) 0.0892(4) 0.1702(6) 0.0315(13) Uani 0.779(2) 1 d PDU . 1
C202 C 0.6954(4) 0.0823(5) 0.0573(8) 0.0366(16) Uani 0.779(2) 1 d PDU . 1
H202 H 0.7009 0.1213 0.0062 0.044 Uiso 0.779(2) 1 calc PR . 1
C203 C 0.7231(4) 0.0232(5) 0.0120(8) 0.0404(17) Uani 0.779(2) 1 d PDU . 1
C204 C 0.7131(4) -0.0333(4) 0.0910(8) 0.0356(15) Uani 0.779(2) 1 d PDU . 1
C205 C 0.7636(5) 0.0205(10) -0.1112(10) 0.069(4) Uani 0.779(2) 1 d PDU . 1
H20A H 0.7335 -0.0016 -0.1756 0.103 Uiso 0.779(2) 1 calc PR . 1
H20B H 0.8085 -0.0050 -0.0998 0.103 Uiso 0.779(2) 1 calc PR . 1
H20C H 0.7751 0.0663 -0.1389 0.103 Uiso 0.779(2) 1 calc PR . 1
C301 C 0.3030(3) 0.1648(3) 0.4489(5) 0.0461(19) Uani 0.779(2) 1 d PGU . 1
C302 C 0.3033(3) 0.2200(3) 0.3644(5) 0.0453(18) Uani 0.779(2) 1 d PGU . 1
C303 C 0.2409(3) 0.2154(3) 0.2869(5) 0.0427(19) Uani 0.779(2) 1 d PGU . 1
C304 C 0.2021(3) 0.1572(3) 0.3236(5) 0.051(2) Uani 0.779(2) 1 d PGU . 1
C305 C 0.2404(3) 0.1259(3) 0.4237(5) 0.0529(19) Uani 0.779(2) 1 d PGU . 1
C306 C 0.3593(4) 0.1499(4) 0.5482(7) 0.069(3) Uani 0.779(2) 1 d PGU . 1
H30A H 0.3516 0.1792 0.6218 0.104 Uiso 0.779(2) 1 calc PR . 1
H30B H 0.4076 0.1581 0.5130 0.104 Uiso 0.779(2) 1 calc PR . 1
H30C H 0.3553 0.1028 0.5745 0.104 Uiso 0.779(2) 1 calc PR . 1
C307 C 0.3600(4) 0.2743(4) 0.3580(8) 0.070(3) Uani 0.779(2) 1 d PGU . 1
H30D H 0.3539 0.3001 0.2795 0.105 Uiso 0.779(2) 1 calc PR . 1
H30E H 0.4082 0.2538 0.3592 0.105 Uiso 0.779(2) 1 calc PR . 1
H30F H 0.3548 0.3044 0.4311 0.105 Uiso 0.779(2) 1 calc PR . 1
C308 C 0.2197(4) 0.2637(4) 0.1837(8) 0.069(3) Uani 0.779(2) 1 d PGU . 1
H30G H 0.2072 0.2386 0.1068 0.103 Uiso 0.779(2) 1 calc PR . 1
H30H H 0.2603 0.2940 0.1657 0.103 Uiso 0.779(2) 1 calc PR . 1
H30I H 0.1777 0.2901 0.2113 0.103 Uiso 0.779(2) 1 calc PR . 1
C309 C 0.1322(4) 0.1328(4) 0.2662(8) 0.089(4) Uani 0.779(2) 1 d PGU . 1
H30J H 0.1344 0.0840 0.2547 0.134 Uiso 0.779(2) 1 calc PR . 1
H30K H 0.1249 0.1546 0.1837 0.134 Uiso 0.779(2) 1 calc PR . 1
H30L H 0.0919 0.1441 0.3227 0.134 Uiso 0.779(2) 1 calc PR . 1
C310 C 0.2185(4) 0.0625(4) 0.4915(8) 0.082(4) Uani 0.779(2) 1 d PGU . 1
H31A H 0.2560 0.0281 0.4795 0.123 Uiso 0.779(2) 1 calc PR . 1
H31B H 0.1725 0.0462 0.4568 0.123 Uiso 0.779(2) 1 calc PR . 1
H31C H 0.2128 0.0718 0.5822 0.123 Uiso 0.779(2) 1 calc PR . 1
C401 C 0.6997(2) 0.1886(2) 0.4157(4) 0.0398(16) Uani 0.779(2) 1 d PGU . 1
C402 C 0.7422(3) 0.2123(2) 0.3130(5) 0.0417(18) Uani 0.779(2) 1 d PGU . 1
C403 C 0.7072(3) 0.2695(2) 0.2610(5) 0.0442(18) Uani 0.779(2) 1 d PGU . 1
C404 C 0.6431(3) 0.2811(2) 0.3316(5) 0.046(2) Uani 0.779(2) 1 d PGU . 1
C405 C 0.6384(2) 0.2311(2) 0.4272(4) 0.0433(17) Uani 0.779(2) 1 d PGU . 1
C406 C 0.7167(4) 0.1287(4) 0.4982(6) 0.058(3) Uani 0.779(2) 1 d PGU . 1
H40A H 0.7505 0.0989 0.4537 0.087 Uiso 0.779(2) 1 calc PR . 1
H40B H 0.6719 0.1041 0.5168 0.087 Uiso 0.779(2) 1 calc PR . 1
H40C H 0.7386 0.1440 0.5777 0.087 Uiso 0.779(2) 1 calc PR . 1
C407 C 0.8124(4) 0.1820(4) 0.2672(7) 0.067(3) Uani 0.779(2) 1 d PGU . 1
H40D H 0.8513 0.1933 0.3267 0.100 Uiso 0.779(2) 1 calc PR . 1
H40E H 0.8241 0.2001 0.1831 0.100 Uiso 0.779(2) 1 calc PR . 1
H40F H 0.8073 0.1330 0.2618 0.100 Uiso 0.779(2) 1 calc PR . 1
C408 C 0.7336(4) 0.3107(4) 0.1502(7) 0.067(3) Uani 0.779(2) 1 d PGU . 1
H40G H 0.6921 0.3249 0.0987 0.100 Uiso 0.779(2) 1 calc PR . 1
H40H H 0.7665 0.2835 0.0983 0.100 Uiso 0.779(2) 1 calc PR . 1
H40I H 0.7593 0.3505 0.1816 0.100 Uiso 0.779(2) 1 calc PR . 1
C409 C 0.5892(4) 0.3369(4) 0.3089(7) 0.072(3) Uani 0.779(2) 1 d PGU . 1
H40J H 0.5823 0.3624 0.3875 0.108 Uiso 0.779(2) 1 calc PR . 1
H40K H 0.5428 0.3175 0.2822 0.108 Uiso 0.779(2) 1 calc PR . 1
H40L H 0.6075 0.3668 0.2424 0.108 Uiso 0.779(2) 1 calc PR . 1
C410 C 0.5788(4) 0.2244(4) 0.5240(7) 0.057(3) Uani 0.779(2) 1 d PGU . 1
H41A H 0.5554 0.2681 0.5365 0.085 Uiso 0.779(2) 1 calc PR . 1
H41B H 0.5992 0.2088 0.6046 0.085 Uiso 0.779(2) 1 calc PR . 1
H41C H 0.5429 0.1917 0.4939 0.085 Uiso 0.779(2) 1 calc PR . 1
Rh8 Rh 0.32900(18) 0.16005(19) 0.2392(3) 0.0334(8) Uani 0.221(2) 1 d PU . 2
Rh9 Rh 0.66870(18) 0.15773(18) 0.2523(3) 0.0335(8) Uani 0.221(2) 1 d PU . 2
O601 O 0.5131(11) 0.1184(8) 0.3514(15) 0.035(3) Uiso 0.221(2) 1 d PDU . 2
O602 O 0.3635(9) 0.1849(10) 0.0448(18) 0.038(4) Uiso 0.221(2) 1 d PDU . 2
N601 N 0.4366(11) 0.1530(7) 0.1936(16) 0.030(3) Uiso 0.221(2) 1 d PDU . 2
C601 C 0.5041(11) 0.1398(7) 0.2399(16) 0.028(3) Uiso 0.221(2) 1 d PDU . 2
N602 N 0.5655(11) 0.1503(9) 0.1674(16) 0.033(3) Uiso 0.221(2) 1 d PDU . 2
C602 C 0.5563(12) 0.1726(10) 0.0474(18) 0.033(3) Uiso 0.221(2) 1 d PDU . 2
H602 H 0.5985 0.1794 -0.0025 0.040 Uiso 0.221(2) 1 calc PR . 2
C603 C 0.4912(12) 0.1862(8) -0.0075(15) 0.032(3) Uiso 0.221(2) 1 d PDU . 2
C604 C 0.4301(10) 0.1761(7) 0.0710(17) 0.032(3) Uiso 0.221(2) 1 d PDU . 2
C605 C 0.4878(19) 0.2120(11) -0.1425(14) 0.026(5) Uiso 0.30 1 d PDU . 2
C606 C 0.4806(14) 0.1947(13) -0.1494(15) 0.029(4) Uiso 0.30 1 d PDU B 3
O701 O 0.6249(9) -0.0166(10) 0.3500(16) 0.036(3) Uiso 0.221(2) 1 d PDU . 2
O702 O 0.7098(10) 0.1298(9) 0.0634(19) 0.037(3) Uiso 0.221(2) 1 d PDU . 2
N701 N 0.6690(8) 0.0577(10) 0.2027(17) 0.031(3) Uiso 0.221(2) 1 d PDU . 2
C701 C 0.6539(8) -0.0064(10) 0.2429(16) 0.030(3) Uiso 0.221(2) 1 d PDU . 2
N702 N 0.6709(10) -0.0615(11) 0.1679(17) 0.036(3) Uiso 0.221(2) 1 d PDU . 2
C702 C 0.7012(12) -0.0493(12) 0.0539(19) 0.040(3) Uiso 0.221(2) 1 d PDU . 2
H702 H 0.7124 -0.0871 0.0023 0.048 Uiso 0.221(2) 1 calc PR . 2
C703 C 0.7172(10) 0.0128(12) 0.0062(19) 0.038(3) Uiso 0.221(2) 1 d PDU . 2
C704 C 0.7002(8) 0.0676(10) 0.0857(18) 0.035(3) Uiso 0.221(2) 1 d PDU . 2
C705 C 0.7517(14) 0.014(2) -0.124(2) 0.024(5) Uiso 0.221(2) 1 d PDU . 2
H70A H 0.8044 0.0172 -0.1149 0.036 Uiso 0.221(2) 1 calc PR . 2
H70B H 0.7337 0.0527 -0.1715 0.036 Uiso 0.221(2) 1 calc PR . 2
H70C H 0.7395 -0.0276 -0.1692 0.036 Uiso 0.221(2) 1 calc PR . 2
C801 C 0.3277(10) 0.2043(10) 0.4247(19) 0.048(3) Uiso 0.221(2) 1 d PGU . 2
C802 C 0.3181(10) 0.2565(10) 0.3335(19) 0.050(4) Uiso 0.221(2) 1 d PGU . 2
C803 C 0.2534(10) 0.2427(10) 0.264(2) 0.044(3) Uiso 0.221(2) 1 d PGU . 2
C804 C 0.2230(11) 0.1820(10) 0.313(2) 0.048(3) Uiso 0.221(2) 1 d PGU . 2
C805 C 0.2689(10) 0.1583(10) 0.4121(19) 0.049(3) Uiso 0.221(2) 1 d PGU . 2
C806 C 0.3895(15) 0.1988(15) 0.519(3) 0.074(8) Uiso 0.221(2) 1 d PGU . 2
H80A H 0.3749 0.2188 0.5998 0.111 Uiso 0.221(2) 1 calc PR . 2
H80B H 0.4319 0.2228 0.4857 0.111 Uiso 0.221(2) 1 calc PR . 2
H80C H 0.4017 0.1513 0.5315 0.111 Uiso 0.221(2) 1 calc PR . 2
C807 C 0.3679(15) 0.3161(15) 0.313(3) 0.075(8) Uiso 0.221(2) 1 d PGU . 2
H80D H 0.3941 0.3107 0.2332 0.113 Uiso 0.221(2) 1 calc PR . 2
H80E H 0.4026 0.3188 0.3836 0.113 Uiso 0.221(2) 1 calc PR . 2
H80F H 0.3392 0.3576 0.3105 0.113 Uiso 0.221(2) 1 calc PR . 2
C808 C 0.2224(16) 0.2851(15) 0.158(3) 0.070(8) Uiso 0.221(2) 1 d PGU . 2
H80G H 0.2147 0.3312 0.1883 0.104 Uiso 0.221(2) 1 calc PR . 2
H80H H 0.1761 0.2659 0.1303 0.104 Uiso 0.221(2) 1 calc PR . 2
H80I H 0.2564 0.2857 0.0865 0.104 Uiso 0.221(2) 1 calc PR . 2
C809 C 0.1541(16) 0.1486(15) 0.267(3) 0.076(7) Uiso 0.221(2) 1 d PGU . 2
C810 C 0.2573(16) 0.0953(14) 0.490(3) 0.064(6) Uiso 0.221(2) 1 d PGU . 2
H81A H 0.2096 0.0971 0.5307 0.095 Uiso 0.221(2) 1 calc PR . 2
H81B H 0.2949 0.0922 0.5556 0.095 Uiso 0.221(2) 1 calc PR . 2
H81C H 0.2599 0.0557 0.4349 0.095 Uiso 0.221(2) 1 calc PR . 2
C901 C 0.7270(9) 0.1614(9) 0.4290(16) 0.040(3) Uiso 0.221(2) 1 d PGU . 2
C902 C 0.7660(10) 0.1918(9) 0.3291(18) 0.043(3) Uiso 0.221(2) 1 d PGU . 2
C903 C 0.7254(10) 0.2473(10) 0.2851(18) 0.044(4) Uiso 0.221(2) 1 d PGU . 2
C904 C 0.6613(9) 0.2511(10) 0.3578(17) 0.045(3) Uiso 0.221(2) 1 d PGU . 2
C905 C 0.6623(9) 0.1980(9) 0.4467(16) 0.042(3) Uiso 0.221(2) 1 d PGU . 2
C906 C 0.7503(13) 0.1007(13) 0.503(2) 0.050(7) Uiso 0.221(2) 1 d PGU . 2
H90A H 0.7470 0.0606 0.4494 0.074 Uiso 0.221(2) 1 calc PR . 2
H90B H 0.7186 0.0952 0.5771 0.074 Uiso 0.221(2) 1 calc PR . 2
H90C H 0.8004 0.1066 0.5317 0.074 Uiso 0.221(2) 1 calc PR . 2
C907 C 0.8380(14) 0.1692(14) 0.279(3) 0.071(8) Uiso 0.221(2) 1 d PGU . 2
H90D H 0.8734 0.2056 0.2879 0.107 Uiso 0.221(2) 1 calc PR . 2
H90E H 0.8331 0.1575 0.1886 0.107 Uiso 0.221(2) 1 calc PR . 2
H90F H 0.8545 0.1297 0.3261 0.107 Uiso 0.221(2) 1 calc PR . 2
C908 C 0.7466(14) 0.2940(15) 0.180(3) 0.056(6) Uiso 0.221(2) 1 d PGU . 2
H90G H 0.7041 0.3194 0.1515 0.083 Uiso 0.221(2) 1 calc PR . 2
H90H H 0.7659 0.2678 0.1084 0.083 Uiso 0.221(2) 1 calc PR . 2
H90I H 0.7838 0.3253 0.2100 0.083 Uiso 0.221(2) 1 calc PR . 2
C909 C 0.6025(14) 0.3026(14) 0.343(3) 0.064(7) Uiso 0.221(2) 1 d PGU . 2
H90J H 0.5565 0.2799 0.3250 0.096 Uiso 0.221(2) 1 calc PR . 2
H90K H 0.6145 0.3330 0.2730 0.096 Uiso 0.221(2) 1 calc PR . 2
H90L H 0.5979 0.3285 0.4218 0.096 Uiso 0.221(2) 1 calc PR . 2
C910 C 0.6047(13) 0.1831(13) 0.543(2) 0.051(6) Uiso 0.221(2) 1 d PGU . 2
H91A H 0.5945 0.2238 0.5926 0.077 Uiso 0.221(2) 1 calc PR . 2
H91B H 0.6215 0.1473 0.6000 0.077 Uiso 0.221(2) 1 calc PR . 2
H91C H 0.5605 0.1685 0.4998 0.077 Uiso 0.221(2) 1 calc PR . 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O201 2.354(5) 4_655 ?
Eu1 O201 2.354(5) . ?
Eu1 O101 2.378(5) 4_655 ?
Eu1 O101 2.378(5) . ?
Eu1 O701 2.430(17) . ?
Eu1 O701 2.430(17) 4_655 ?
Eu1 O601 2.460(17) 4_655 ?
Eu1 O601 2.460(17) . ?
Eu1 O523 2.501(7) 4_655 ?
Eu1 O523 2.501(7) . ?
Eu1 N511 2.663(7) . ?
Eu1 O522 2.710(8) . ?
N511 C511 1.086(11) . ?
C511 C512 1.464(15) . ?
N521 O522 1.211(12) . ?
N521 O523 1.251(12) . ?
N521 O521 1.263(11) . ?
N531 O532 1.213(15) . ?
N531 O533 1.258(15) . ?
N531 O531 1.278(14) . ?
O531 N531 1.278(14) 4 ?
O542 O542 1.23(9) 4_755 ?
Rh3 C304 2.095(5) . ?
Rh3 N201 2.102(7) 4_655 ?
Rh3 N102 2.103(7) . ?
Rh3 C303 2.113(5) . ?
Rh3 C305 2.140(5) . ?
Rh3 C302 2.167(5) . ?
Rh3 O202 2.171(7) 4_655 ?
Rh3 C301 2.184(5) . ?
Rh3 C204 2.567(9) 4_655 ?
Rh4 N202 2.102(7) . ?
Rh4 C403 2.105(5) . ?
Rh4 N101 2.108(7) . ?
Rh4 C404 2.122(5) . ?
Rh4 C402 2.129(5) . ?
Rh4 C405 2.157(4) . ?
Rh4 O102 2.158(6) . ?
Rh4 C401 2.162(5) . ?
Rh4 C104 2.571(8) . ?
O101 C101 1.264(9) . ?
O102 C104 1.273(9) . ?
N101 C101 1.358(9) . ?
N101 C104 1.365(9) . ?
C101 N102 1.379(9) . ?
N102 C102 1.347(10) . ?
C102 C103 1.363(12) . ?
C103 C104 1.405(11) . ?
C103 C105 1.520(13) . ?
O201 C201 1.265(9) . ?
O202 C204 1.267(9) . ?
O202 Rh3 2.171(7) 4_655 ?
N201 C201 1.363(9) . ?
N201 C204 1.369(10) . ?
N201 Rh3 2.102(7) 4_655 ?
C201 N202 1.372(9) . ?
N202 C202 1.361(10) . ?
C202 C203 1.368(12) . ?
C203 C204 1.410(11) . ?
C203 C205 1.499(11) . ?
C204 Rh3 2.567(9) 4_655 ?
C301 C302 1.415(3) . ?
C301 C305 1.415(3) . ?
C301 C306 1.504(3) . ?
C302 C303 1.415(3) . ?
C302 C307 1.504(3) . ?
C303 C304 1.415(3) . ?
C303 C308 1.504(3) . ?
C304 C305 1.415(3) . ?
C304 C309 1.504(3) . ?
C305 C310 1.504(3) . ?
C401 C402 1.418(3) . ?
C401 C405 1.418(3) . ?
C401 C406 1.507(3) . ?
C402 C403 1.418(3) . ?
C402 C407 1.507(3) . ?
C403 C404 1.418(3) . ?
C403 C408 1.507(3) . ?
C404 C405 1.418(3) . ?
C404 C409 1.508(3) . ?
C405 C410 1.507(3) . ?
Rh8 N601 2.05(2) . ?
Rh8 N702 2.10(2) 4_655 ?
Rh8 C805 2.13(2) . ?
Rh8 C801 2.15(2) . ?
Rh8 C804 2.15(2) . ?
Rh8 C802 2.17(2) . ?
Rh8 C803 2.17(2) . ?
Rh8 O602 2.20(2) . ?
Rh8 C604 2.594(19) . ?
Rh9 N701 2.06(2) . ?
Rh9 C902 2.08(2) . ?
Rh9 C903 2.09(2) . ?
Rh9 N602 2.11(2) . ?
Rh9 C901 2.152(18) . ?
Rh9 C904 2.168(19) . ?
Rh9 O702 2.20(2) . ?
Rh9 C905 2.203(17) . ?
Rh9 C704 2.58(2) . ?
O601 C601 1.262(15) . ?
O602 C604 1.272(16) . ?
N601 C601 1.364(15) . ?
N601 C604 1.376(16) . ?
C601 N602 1.382(15) . ?
N602 C602 1.351(16) . ?
C602 C603 1.360(18) . ?
C603 C604 1.413(17) . ?
C603 C605 1.515(15) . ?
O701 C701 1.266(15) . ?
O702 C704 1.272(16) . ?
N701 C701 1.372(15) . ?
N701 C704 1.375(16) . ?
C701 N702 1.386(15) . ?
N702 C702 1.348(16) . ?
N702 Rh8 2.10(2) 4_655 ?
C702 C703 1.365(18) . ?
C703 C704 1.409(17) . ?
C703 C705 1.512(15) . ?
C801 C802 1.425(11) . ?
C801 C805 1.425(11) . ?
C801 C806 1.515(12) . ?
C802 C803 1.425(11) . ?
C802 C807 1.515(12) . ?
C803 C804 1.425(11) . ?
C803 C808 1.515(12) . ?
C804 C805 1.425(11) . ?
C804 C809 1.515(12) . ?
C805 C810 1.515(12) . ?
C901 C902 1.412(10) . ?
C901 C905 1.412(10) . ?
C901 C906 1.501(10) . ?
C902 C903 1.412(10) . ?
C902 C907 1.501(11) . ?
C903 C904 1.412(10) . ?
C903 C908 1.501(11) . ?
C904 C905 1.412(10) . ?
C904 C909 1.501(10) . ?
C905 C910 1.501(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O201 Eu1 O201 144.2(3) 4_655 . ?
O201 Eu1 O101 83.9(2) 4_655 4_655 ?
O201 Eu1 O101 85.9(2) . 4_655 ?
O201 Eu1 O101 85.9(2) 4_655 . ?
O201 Eu1 O101 83.9(2) . . ?
O101 Eu1 O101 146.4(3) 4_655 . ?
O201 Eu1 O701 136.8(4) 4_655 . ?
O201 Eu1 O701 25.4(5) . . ?
O101 Eu1 O701 61.6(5) 4_655 . ?
O101 Eu1 O701 108.2(5) . . ?
O201 Eu1 O701 25.4(5) 4_655 4_655 ?
O201 Eu1 O701 136.8(4) . 4_655 ?
O101 Eu1 O701 108.2(5) 4_655 4_655 ?
O101 Eu1 O701 61.6(5) . 4_655 ?
O701 Eu1 O701 147.0(8) . 4_655 ?
O201 Eu1 O601 62.6(5) 4_655 4_655 ?
O201 Eu1 O601 107.0(5) . 4_655 ?
O101 Eu1 O601 22.2(5) 4_655 4_655 ?
O101 Eu1 O601 140.1(4) . 4_655 ?
O701 Eu1 O601 83.4(7) . 4_655 ?
O701 Eu1 O601 87.6(7) 4_655 4_655 ?
O201 Eu1 O601 107.0(5) 4_655 . ?
O201 Eu1 O601 62.6(5) . . ?
O101 Eu1 O601 140.1(4) 4_655 . ?
O101 Eu1 O601 22.2(5) . . ?
O701 Eu1 O601 87.6(7) . . ?
O701 Eu1 O601 83.4(7) 4_655 . ?
O601 Eu1 O601 148.2(7) 4_655 . ?
O201 Eu1 O523 83.1(2) 4_655 4_655 ?
O201 Eu1 O523 125.9(2) . 4_655 ?
O101 Eu1 O523 72.3(2) 4_655 4_655 ?
O101 Eu1 O523 137.8(2) . 4_655 ?
O701 Eu1 O523 107.6(5) . 4_655 ?
O701 Eu1 O523 97.3(5) 4_655 4_655 ?
O601 Eu1 O523 65.7(4) 4_655 4_655 ?
O601 Eu1 O523 145.7(4) . 4_655 ?
O201 Eu1 O523 125.9(2) 4_655 . ?
O201 Eu1 O523 83.1(2) . . ?
O101 Eu1 O523 137.8(2) 4_655 . ?
O101 Eu1 O523 72.3(2) . . ?
O701 Eu1 O523 97.3(5) . . ?
O701 Eu1 O523 107.6(5) 4_655 . ?
O601 Eu1 O523 145.7(4) 4_655 . ?
O601 Eu1 O523 65.7(4) . . ?
O523 Eu1 O523 81.7(4) 4_655 . ?
O201 Eu1 N511 72.08(13) 4_655 . ?
O201 Eu1 N511 72.08(13) . . ?
O101 Eu1 N511 73.20(13) 4_655 . ?
O101 Eu1 N511 73.21(13) . . ?
O701 Eu1 N511 73.5(4) . . ?
O701 Eu1 N511 73.5(4) 4_655 . ?
O601 Eu1 N511 74.1(4) 4_655 . ?
O601 Eu1 N511 74.1(4) . . ?
O523 Eu1 N511 139.1(2) 4_655 . ?
O523 Eu1 N511 139.1(2) . . ?
O201 Eu1 O522 145.4(2) 4_655 . ?
O201 Eu1 O522 68.9(2) . . ?
O101 Eu1 O522 91.3(2) 4_655 . ?
O101 Eu1 O522 114.3(3) . . ?
O701 Eu1 O522 65.7(4) . . ?
O701 Eu1 O522 147.1(4) 4_655 . ?
O601 Eu1 O522 105.3(5) 4_655 . ?
O601 Eu1 O522 98.6(5) . . ?
O523 Eu1 O522 63.0(3) 4_655 . ?
O523 Eu1 O522 46.8(3) . . ?
N511 Eu1 O522 138.85(17) . . ?
C511 N511 Eu1 180.0 . . ?
N511 C511 C512 180.0 . . ?
O522 N521 O523 115.1(9) . . ?
O522 N521 O521 127.8(10) . . ?
O523 N521 O521 117.0(10) . . ?
O522 N521 Eu1 62.4(6) . . ?
O523 N521 Eu1 52.9(5) . . ?
O521 N521 Eu1 169.2(8) . . ?
N521 O522 Eu1 94.2(6) . . ?
N521 O523 Eu1 103.6(6) . . ?
O532 N531 O533 113.1(15) . . ?
O532 N531 O531 127.9(18) . . ?
O533 N531 O531 114.8(15) . . ?
N531 O531 N531 136(3) . 4 ?
C304 Rh3 N201 119.0(2) . 4_655 ?
C304 Rh3 N102 156.5(2) . . ?
N201 Rh3 N102 83.2(2) 4_655 . ?
C304 Rh3 C303 39.30(11) . . ?
N201 Rh3 C303 155.5(2) 4_655 . ?
N102 Rh3 C303 117.3(2) . . ?
C304 Rh3 C305 39.01(11) . . ?
N201 Rh3 C305 105.3(2) 4_655 . ?
N102 Rh3 C305 148.2(2) . . ?
C303 Rh3 C305 65.14(16) . . ?
C304 Rh3 C302 64.95(16) . . ?
N201 Rh3 C302 159.6(2) 4_655 . ?
N102 Rh3 C302 97.3(2) . . ?
C303 Rh3 C302 38.59(10) . . ?
C305 Rh3 C302 64.21(16) . . ?
C304 Rh3 O202 96.5(2) . 4_655 ?
N201 Rh3 O202 61.7(2) 4_655 4_655 ?
N102 Rh3 O202 87.0(2) . 4_655 ?
C303 Rh3 O202 103.7(2) . 4_655 ?
C305 Rh3 O202 124.2(2) . 4_655 ?
C302 Rh3 O202 138.7(2) . 4_655 ?
C304 Rh3 C301 64.65(16) . . ?
N201 Rh3 C301 123.1(2) 4_655 . ?
N102 Rh3 C301 111.6(2) . . ?
C303 Rh3 C301 64.38(16) . . ?
C305 Rh3 C301 38.19(10) . . ?
C302 Rh3 C301 37.95(10) . . ?
O202 Rh3 C301 160.9(2) 4_655 . ?
C304 Rh3 C204 109.2(2) . 4_655 ?
N201 Rh3 C204 32.2(2) 4_655 4_655 ?
N102 Rh3 C204 85.0(2) . 4_655 ?
C303 Rh3 C204 130.4(2) . 4_655 ?
C305 Rh3 C204 118.6(2) . 4_655 ?
C302 Rh3 C204 168.1(2) . 4_655 ?
O202 Rh3 C204 29.5(2) 4_655 4_655 ?
C301 Rh3 C204 150.8(2) . 4_655 ?
N202 Rh4 C403 129.8(2) . . ?
N202 Rh4 N101 84.8(2) . . ?
C403 Rh4 N101 140.1(2) . . ?
N202 Rh4 C404 165.4(2) . . ?
C403 Rh4 C404 39.19(10) . . ?
N101 Rh4 C404 109.3(2) . . ?
N202 Rh4 C402 100.2(2) . . ?
C403 Rh4 C402 39.13(10) . . ?
N101 Rh4 C402 171.4(2) . . ?
C404 Rh4 C402 65.31(15) . . ?
N202 Rh4 C405 134.8(2) . . ?
C403 Rh4 C405 65.13(15) . . ?
N101 Rh4 C405 106.8(2) . . ?
C404 Rh4 C405 38.69(9) . . ?
C402 Rh4 C405 64.72(14) . . ?
N202 Rh4 O102 86.0(2) . . ?
C403 Rh4 O102 97.4(2) . . ?
N101 Rh4 O102 61.6(2) . . ?
C404 Rh4 O102 103.8(2) . . ?
C402 Rh4 O102 125.3(2) . . ?
C405 Rh4 O102 138.3(2) . . ?
N202 Rh4 C401 103.0(2) . . ?
C403 Rh4 C401 65.05(15) . . ?
N101 Rh4 C401 133.7(2) . . ?
C404 Rh4 C401 64.76(14) . . ?
C402 Rh4 C401 38.58(9) . . ?
C405 Rh4 C401 38.34(9) . . ?
O102 Rh4 C401 162.23(19) . . ?
N202 Rh4 C104 85.4(2) . . ?
C403 Rh4 C104 120.0(2) . . ?
N101 Rh4 C104 32.0(2) . . ?
C404 Rh4 C104 108.46(19) . . ?
C402 Rh4 C104 154.4(2) . . ?
C405 Rh4 C104 127.1(2) . . ?
O102 Rh4 C104 29.6(2) . . ?
C401 Rh4 C104 163.7(2) . . ?
C101 O101 Eu1 129.6(4) . . ?
C104 O102 Rh4 93.5(4) . . ?
C101 N101 C104 121.8(6) . . ?
C101 N101 Rh4 145.2(5) . . ?
C104 N101 Rh4 93.0(5) . . ?
O101 C101 N101 121.4(7) . . ?
O101 C101 N102 120.1(7) . . ?
N101 C101 N102 118.5(7) . . ?
C102 N102 C101 118.4(7) . . ?
C102 N102 Rh3 121.7(6) . . ?
C101 N102 Rh3 118.8(5) . . ?
N102 C102 C103 125.7(8) . . ?
C102 C103 C104 114.5(7) . . ?
C102 C103 C105 123.8(12) . . ?
C104 C103 C105 121.5(12) . . ?
O102 C104 N101 111.8(7) . . ?
O102 C104 C103 127.4(7) . . ?
N101 C104 C103 120.8(7) . . ?
O102 C104 Rh4 56.9(4) . . ?
N101 C104 Rh4 55.0(4) . . ?
C103 C104 Rh4 174.7(5) . . ?
C201 O201 Eu1 135.4(4) . . ?
C204 O202 Rh3 92.8(5) . 4_655 ?
C201 N201 C204 121.4(7) . . ?
C201 N201 Rh3 145.7(5) . 4_655 ?
C204 N201 Rh3 92.9(5) . 4_655 ?
O201 C201 N201 119.2(7) . . ?
O201 C201 N202 121.4(6) . . ?
N201 C201 N202 119.4(6) . . ?
C202 N202 C201 118.5(7) . . ?
C202 N202 Rh4 119.7(6) . . ?
C201 N202 Rh4 121.1(5) . . ?
N202 C202 C203 124.7(8) . . ?
C202 C203 C204 115.4(7) . . ?
C202 C203 C205 121.3(11) . . ?
C204 C203 C205 123.3(11) . . ?
O202 C204 N201 112.5(7) . . ?
O202 C204 C203 127.0(8) . . ?
N201 C204 C203 120.5(7) . . ?
O202 C204 Rh3 57.6(4) . 4_655 ?
N201 C204 Rh3 54.9(4) . 4_655 ?
C203 C204 Rh3 174.3(6) . 4_655 ?
C302 C301 C305 108.0 . . ?
C302 C301 C306 126.0 . . ?
C305 C301 C306 126.0 . . ?
C302 C301 Rh3 70.39(17) . . ?
C305 C301 Rh3 69.23(18) . . ?
C306 C301 Rh3 125.96(16) . . ?
C301 C302 C303 108.0 . . ?
C301 C302 C307 126.0 . . ?
C303 C302 C307 126.0 . . ?
C301 C302 Rh3 71.66(17) . . ?
C303 C302 Rh3 68.62(17) . . ?
C307 C302 Rh3 125.30(18) . . ?
C304 C303 C302 108.0 . . ?
C304 C303 C308 126.0 . . ?
C302 C303 C308 126.0 . . ?
C304 C303 Rh3 69.70(19) . . ?
C302 C303 Rh3 72.79(17) . . ?
C308 C303 Rh3 123.15(16) . . ?
C305 C304 C303 108.0 . . ?
C305 C304 C309 126.0 . . ?
C303 C304 C309 126.0 . . ?
C305 C304 Rh3 72.20(17) . . ?
C303 C304 Rh3 71.01(18) . . ?
C309 C304 Rh3 122.47(17) . . ?
C301 C305 C304 108.0 . . ?
C301 C305 C310 126.0 . . ?
C304 C305 C310 126.0 . . ?
C301 C305 Rh3 72.58(18) . . ?
C304 C305 Rh3 68.79(17) . . ?
C310 C305 Rh3 124.22(17) . . ?
C402 C401 C405 108.0 . . ?
C402 C401 C406 126.0 . . ?
C405 C401 C406 126.0 . . ?
C402 C401 Rh4 69.48(16) . . ?
C405 C401 Rh4 70.67(16) . . ?
C406 C401 Rh4 125.43(16) . . ?
C401 C402 C403 108.0 . . ?
C401 C402 C407 126.0 . . ?
C403 C402 C407 126.0 . . ?
C401 C402 Rh4 71.93(15) . . ?
C403 C402 Rh4 69.51(16) . . ?
C407 C402 Rh4 124.17(16) . . ?
C404 C403 C402 108.0 . . ?
C404 C403 C408 126.0 . . ?
C402 C403 C408 126.0 . . ?
C404 C403 Rh4 71.06(16) . . ?
C402 C403 Rh4 71.37(17) . . ?
C408 C403 Rh4 123.22(15) . . ?
C403 C404 C405 108.0 . . ?
C403 C404 C409 126.0 . . ?
C405 C404 C409 126.0 . . ?
C403 C404 Rh4 69.74(16) . . ?
C405 C404 Rh4 71.99(15) . . ?
C409 C404 Rh4 123.90(16) . . ?
C404 C405 C401 108.0 . . ?
C404 C405 C410 126.0 . . ?
C401 C405 C410 126.0 . . ?
C404 C405 Rh4 69.32(16) . . ?
C401 C405 Rh4 70.99(17) . . ?
C410 C405 Rh4 125.27(15) . . ?
N601 Rh8 N702 81.4(6) . 4_655 ?
N601 Rh8 C805 134.7(7) . . ?
N702 Rh8 C805 106.9(7) 4_655 . ?
N601 Rh8 C801 104.6(7) . . ?
N702 Rh8 C801 135.2(7) 4_655 . ?
C805 Rh8 C801 38.9(4) . . ?
N601 Rh8 C804 168.8(7) . . ?
N702 Rh8 C804 108.7(8) 4_655 . ?
C805 Rh8 C804 38.9(4) . . ?
C801 Rh8 C804 64.9(6) . . ?
N601 Rh8 C802 104.9(6) . . ?
N702 Rh8 C802 171.7(7) 4_655 . ?
C805 Rh8 C802 64.8(6) . . ?
C801 Rh8 C802 38.6(4) . . ?
C804 Rh8 C802 64.5(6) . . ?
N601 Rh8 C803 134.7(7) . . ?
N702 Rh8 C803 138.7(7) 4_655 . ?
C805 Rh8 C803 64.8(6) . . ?
C801 Rh8 C803 64.6(6) . . ?
C804 Rh8 C803 38.5(4) . . ?
C802 Rh8 C803 38.3(4) . . ?
N601 Rh8 O602 61.1(6) . . ?
N702 Rh8 O602 82.9(7) 4_655 . ?
C805 Rh8 O602 161.6(7) . . ?
C801 Rh8 O602 139.4(7) . . ?
C804 Rh8 O602 123.7(7) . . ?
C802 Rh8 O602 104.8(7) . . ?
C803 Rh8 O602 97.5(7) . . ?
N601 Rh8 C604 31.8(5) . . ?
N702 Rh8 C604 82.5(6) 4_655 . ?
C805 Rh8 C604 163.7(6) . . ?
C801 Rh8 C604 125.5(6) . . ?
C804 Rh8 C604 151.3(7) . . ?
C802 Rh8 C604 105.7(6) . . ?
C803 Rh8 C604 116.9(7) . . ?
O602 Rh8 C604 29.3(4) . . ?
N701 Rh9 C902 114.2(6) . . ?
N701 Rh9 C903 149.6(7) . . ?
C902 Rh9 C903 39.5(4) . . ?
N701 Rh9 N602 80.1(6) . . ?
C902 Rh9 N602 165.0(7) . . ?
C903 Rh9 N602 125.5(7) . . ?
N701 Rh9 C901 104.5(6) . . ?
C902 Rh9 C901 38.9(4) . . ?
C903 Rh9 C901 65.1(6) . . ?
N602 Rh9 C901 145.2(7) . . ?
N701 Rh9 C904 163.5(7) . . ?
C902 Rh9 C904 65.0(6) . . ?
C903 Rh9 C904 38.6(4) . . ?
N602 Rh9 C904 102.7(7) . . ?
C901 Rh9 C904 63.8(5) . . ?
N701 Rh9 O702 61.7(6) . . ?
C902 Rh9 O702 97.8(7) . . ?
C903 Rh9 O702 101.0(7) . . ?
N602 Rh9 O702 84.9(7) . . ?
C901 Rh9 O702 128.2(7) . . ?
C904 Rh9 O702 134.5(6) . . ?
N701 Rh9 C905 126.0(7) . . ?
C902 Rh9 C905 64.3(6) . . ?
C903 Rh9 C905 64.2(5) . . ?
N602 Rh9 C905 111.8(7) . . ?
C901 Rh9 C905 37.8(3) . . ?
C904 Rh9 C905 37.7(3) . . ?
O702 Rh9 C905 162.0(6) . . ?
N701 Rh9 C704 32.1(5) . . ?
C902 Rh9 C704 107.3(6) . . ?
C903 Rh9 C704 126.3(6) . . ?
N602 Rh9 C704 82.3(6) . . ?
C901 Rh9 C704 120.0(6) . . ?
C904 Rh9 C704 163.7(6) . . ?
O702 Rh9 C704 29.6(4) . . ?
C905 Rh9 C704 154.0(6) . . ?
C601 O601 Eu1 124.4(7) . . ?
C604 O602 Rh8 92.7(12) . . ?
C601 N601 C604 118.7(16) . . ?
C601 N601 Rh8 144.6(13) . . ?
C604 N601 Rh8 96.5(12) . . ?
O601 C601 N601 121.2(17) . . ?
O601 C601 N602 117.3(16) . . ?
N601 C601 N602 121.5(14) . . ?
C602 N602 C601 117.6(16) . . ?
C602 N602 Rh9 119.2(14) . . ?
C601 N602 Rh9 121.1(12) . . ?
N602 C602 C603 125.0(18) . . ?
C602 C603 C604 115.3(14) . . ?
C602 C603 C605 120.2(19) . . ?
C604 C603 C605 124.4(19) . . ?
O602 C604 N601 109.5(16) . . ?
O602 C604 C603 128.7(17) . . ?
N601 C604 C603 121.8(15) . . ?
O602 C604 Rh8 57.9(11) . . ?
N601 C604 Rh8 51.7(10) . . ?
C603 C604 Rh8 172.7(12) . . ?
C701 O701 Eu1 129.3(8) . . ?
C704 O702 Rh9 91.7(13) . . ?
C701 N701 C704 119.6(16) . . ?
C701 N701 Rh9 145.0(13) . . ?
C704 N701 Rh9 95.2(12) . . ?
O701 C701 N701 120.6(17) . . ?
O701 C701 N702 118.5(16) . . ?
N701 C701 N702 120.8(15) . . ?
C702 N702 C701 117.3(17) . . ?
C702 N702 Rh8 119.1(14) . 4_655 ?
C701 N702 Rh8 122.3(12) . 4_655 ?
N702 C702 C703 125.5(18) . . ?
C702 C703 C704 115.6(15) . . ?
C702 C703 C705 116.0(19) . . ?
C704 C703 C705 128(2) . . ?
O702 C704 N701 111.3(17) . . ?
O702 C704 C703 127.6(17) . . ?
N701 C704 C703 121.1(15) . . ?
O702 C704 Rh9 58.7(11) . . ?
N701 C704 Rh9 52.6(10) . . ?
C703 C704 Rh9 173.3(13) . . ?
C802 C801 C805 108.0 . . ?
C802 C801 C806 126.0 . . ?
C805 C801 C806 126.0 . . ?
C802 C801 Rh8 71.6(7) . . ?
C805 C801 Rh8 70.1(7) . . ?
C806 C801 Rh8 123.9(7) . . ?
C801 C802 C803 108.0 . . ?
C801 C802 C807 126.0 . . ?
C803 C802 C807 126.0 . . ?
C801 C802 Rh8 69.8(7) . . ?
C803 C802 Rh8 70.9(7) . . ?
C807 C802 Rh8 124.8(7) . . ?
C804 C803 C802 108.0 . . ?
C804 C803 C808 126.0 . . ?
C802 C803 C808 126.0 . . ?
C804 C803 Rh8 69.9(7) . . ?
C802 C803 Rh8 70.7(7) . . ?
C808 C803 Rh8 125.0(6) . . ?
C805 C804 C803 108.0 . . ?
C805 C804 C809 126.0 . . ?
C803 C804 C809 126.0 . . ?
C805 C804 Rh8 69.9(7) . . ?
C803 C804 Rh8 71.6(7) . . ?
C809 C804 Rh8 124.1(7) . . ?
C804 C805 C801 108.0 . . ?
C804 C805 C810 126.0 . . ?
C801 C805 C810 126.0 . . ?
C804 C805 Rh8 71.2(7) . . ?
C801 C805 Rh8 71.0(7) . . ?
C810 C805 Rh8 123.5(7) . . ?
C902 C901 C905 108.0 . . ?
C902 C901 C906 126.0 . . ?
C905 C901 C906 126.0 . . ?
C902 C901 Rh9 67.9(6) . . ?
C905 C901 Rh9 73.1(6) . . ?
C906 C901 Rh9 124.6(6) . . ?
C901 C902 C903 108.0 . . ?
C901 C902 C907 126.0 . . ?
C903 C902 C907 126.0 . . ?
C901 C902 Rh9 73.2(6) . . ?
C903 C902 Rh9 70.6(7) . . ?
C907 C902 Rh9 121.9(6) . . ?
C904 C903 C902 108.0 . . ?
C904 C903 C908 126.0 . . ?
C902 C903 C908 126.0 . . ?
C904 C903 Rh9 73.5(6) . . ?
C902 C903 Rh9 69.9(7) . . ?
C908 C903 Rh9 122.3(6) . . ?
C905 C904 C903 108.0 . . ?
C905 C904 C909 126.0 . . ?
C903 C904 C909 126.0 . . ?
C905 C904 Rh9 72.5(6) . . ?
C903 C904 Rh9 67.8(6) . . ?
C909 C904 Rh9 125.2(6) . . ?
C904 C905 C901 108.0 . . ?
C904 C905 C910 126.0 . . ?
C901 C905 C910 126.0 . . ?
C904 C905 Rh9 69.8(6) . . ?
C901 C905 Rh9 69.1(6) . . ?
C910 C905 Rh9 126.6(6) . . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         0.979
_refine_diff_density_min         -1.554
_refine_diff_density_rms         0.130
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4DyNO3
_database_code_depnum_ccdc_archive 'CCDC 1033782'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C60 H76 Dy N10 O14 Rh4 1+, N O3 1-, C5 H6 N2 O2, C H4 O'
_chemical_formula_sum            'C66 H86 Dy N13 O20 Rh4'
_chemical_formula_weight         1955.62

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.9749(6)
_cell_length_b                   18.7743(6)
_cell_length_c                   28.0431(10)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.975(1)
_cell_angle_gamma                90.00
_cell_volume                     7339.9(5)
_cell_formula_units_Z            4
_cell_measurement_temperature    191(2)
_cell_measurement_reflns_used    53964
_cell_measurement_theta_min      3.04
_cell_measurement_theta_max      27.48

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.770
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3916
_exptl_absorpt_coefficient_mu    1.966
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.4716
_exptl_absorpt_correction_T_max  0.6945
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      191(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            70811
_diffrn_reflns_av_R_equivalents  0.0521
_diffrn_reflns_av_sigmaI/netI    0.0418
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         3.04
_diffrn_reflns_theta_max         27.48
_reflns_number_total             16784
_reflns_number_gt                14397
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    SIR2004
_computing_structure_refinement  SHELXL-97
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0630P)²+52.9780P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16784
_refine_ls_number_parameters     937
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0602
_refine_ls_R_factor_gt           0.0507
_refine_ls_wR_factor_ref         0.1323
_refine_ls_wR_factor_gt          0.1262
_refine_ls_goodness_of_fit_ref   0.965
_refine_ls_restrained_S_all      0.965
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.765324(17) 0.243323(12) 0.246803(8) 0.02080(7) Uani 1 1 d . . .
Rh1 Rh 0.90097(3) 0.41837(2) 0.348541(15) 0.02742(10) Uani 1 1 d . . .
Rh2 Rh 0.56010(3) 0.20164(2) 0.367889(15) 0.02769(10) Uani 1 1 d . . .
Rh3 Rh 0.49655(3) 0.19553(2) 0.145117(16) 0.02998(11) Uani 1 1 d . . .
Rh4 Rh 0.87452(3) 0.37761(2) 0.125174(15) 0.02581(10) Uani 1 1 d . . .
O1 O 0.7831(3) 0.2795(2) 0.32310(14) 0.0363(9) Uani 1 1 d . . .
O2 O 0.5159(3) 0.3022(2) 0.39891(17) 0.0412(10) Uani 1 1 d . . .
O3 O 0.6292(3) 0.1882(2) 0.26451(15) 0.0341(9) Uani 1 1 d . . .
O4 O 0.3856(3) 0.2693(3) 0.16880(16) 0.0428(10) Uani 1 1 d . . .
O5 O 0.7181(3) 0.2337(2) 0.16722(14) 0.0345(9) Uani 1 1 d . . .
O6 O 0.7545(3) 0.4388(2) 0.09064(14) 0.0343(9) Uani 1 1 d . . .
O7 O 0.8769(3) 0.3248(2) 0.23060(15) 0.0322(9) Uani 1 1 d . . .
O8 O 0.8494(3) 0.5210(2) 0.31792(15) 0.0369(9) Uani 1 1 d . . .
O9 O 0.8260(8) 0.1273(5) 0.2318(5) 0.227(9) Uani 1 1 d . . .
O10 O 0.8921(8) 0.1723(4) 0.2830(4) 0.176(6) Uani 1 1 d . . .
O11 O 0.9388(5) 0.0708(3) 0.2721(3) 0.096(3) Uani 1 1 d . . .
O12 O 0.6717(3) 0.3414(2) 0.23672(18) 0.0444(11) Uani 1 1 d . . .
O13 O 0.5650(5) 0.3887(3) 0.2772(3) 0.081(2) Uani 1 1 d . . .
O14 O 0.5911(7) 0.4287(4) 0.2085(3) 0.116(3) Uani 1 1 d . . .
O15 O 0.8975(7) 0.8176(6) -0.0270(3) 0.121(3) Uani 1 1 d . . .
O16 O 0.8276(7) 0.8130(5) 0.0373(3) 0.111(3) Uani 1 1 d . . .
O17 O 0.8344(8) 0.9151(5) 0.0006(4) 0.124(3) Uani 1 1 d . . .
O18 O 0.8369(6) 0.6283(4) 0.0921(3) 0.088(2) Uani 1 1 d . . .
O19 O 0.7137(6) 0.4905(4) -0.0304(3) 0.089(2) Uani 1 1 d . . .
O20 O 0.6907(9) 0.8851(9) 0.1011(5) 0.191(6) Uani 1 1 d . . .
N1 N 0.7603(4) 0.3854(3) 0.35946(17) 0.0339(11) Uani 1 1 d . . .
N2 N 0.6503(4) 0.2928(2) 0.36563(16) 0.0290(10) Uani 1 1 d . . .
N3 N 0.5013(4) 0.2315(3) 0.30049(18) 0.0325(10) Uani 1 1 d . . .
N4 N 0.5000(3) 0.2280(3) 0.21746(18) 0.0325(10) Uani 1 1 d . . .
N5 N 0.5848(4) 0.2811(3) 0.12918(17) 0.0324(10) Uani 1 1 d . . .
N6 N 0.7322(3) 0.3369(3) 0.12510(15) 0.0273(9) Uani 1 1 d . . .
N7 N 0.8527(3) 0.4289(2) 0.18999(17) 0.0295(10) Uani 1 1 d . . .
N8 N 0.8661(3) 0.4281(2) 0.27319(16) 0.0280(10) Uani 1 1 d . . .
N9 N 0.8874(4) 0.1213(3) 0.2630(2) 0.0421(13) Uani 1 1 d . . .
N10 N 0.6073(4) 0.3878(3) 0.24074(18) 0.0337(11) Uani 1 1 d . . .
N11 N 0.8572(6) 0.8484(6) 0.0015(4) 0.083(3) Uani 1 1 d . . .
N12 N 0.8257(7) 0.6723(5) 0.0207(3) 0.095(3) Uani 1 1 d . . .
H12 H 0.8520 0.7122 0.0315 0.113 Uiso 1 1 calc R . .
N13 N 0.7756(6) 0.5565(4) 0.0294(3) 0.071(2) Uani 1 1 d . . .
H13 H 0.7686 0.5203 0.0487 0.085 Uiso 1 1 calc R . .
C1 C 1.0259(4) 0.3521(3) 0.3575(2) 0.0365(13) Uani 1 1 d . . .
C2 C 1.0539(4) 0.4253(3) 0.3536(2) 0.0355(13) Uani 1 1 d . . .
C3 C 1.0161(4) 0.4631(3) 0.3925(2) 0.0351(13) Uani 1 1 d . . .
C4 C 0.9644(4) 0.4135(4) 0.4196(2) 0.0360(13) Uani 1 1 d . . .
C5 C 0.9717(4) 0.3453(3) 0.3985(2) 0.0370(13) Uani 1 1 d . . .
C6 C 1.0522(5) 0.2934(4) 0.3255(3) 0.0520(18) Uani 1 1 d . . .
H6A H 0.9938 0.2708 0.3113 0.062 Uiso 1 1 calc R . .
H6B H 1.0905 0.2580 0.3441 0.062 Uiso 1 1 calc R . .
H6C H 1.0896 0.3125 0.3002 0.062 Uiso 1 1 calc R . .
C7 C 1.1150(5) 0.4569(5) 0.3178(3) 0.0529(18) Uani 1 1 d . . .
H7A H 1.1738 0.4759 0.3341 0.063 Uiso 1 1 calc R . .
H7B H 1.0799 0.4954 0.3007 0.063 Uiso 1 1 calc R . .
H7C H 1.1316 0.4201 0.2950 0.063 Uiso 1 1 calc R . .
C8 C 1.0262(6) 0.5413(4) 0.4014(3) 0.057(2) Uani 1 1 d . . .
H8A H 0.9965 0.5676 0.3740 0.068 Uiso 1 1 calc R . .
H8B H 1.0943 0.5537 0.4057 0.068 Uiso 1 1 calc R . .
H8C H 0.9943 0.5540 0.4303 0.068 Uiso 1 1 calc R . .
C9 C 0.9147(6) 0.4292(5) 0.4642(2) 0.056(2) Uani 1 1 d . . .
H9A H 0.9447 0.4016 0.4909 0.067 Uiso 1 1 calc R . .
H9B H 0.8468 0.4161 0.4593 0.067 Uiso 1 1 calc R . .
H9C H 0.9201 0.4802 0.4715 0.067 Uiso 1 1 calc R . .
C10 C 0.9325(6) 0.2774(4) 0.4163(3) 0.055(2) Uani 1 1 d . . .
H10A H 0.8628 0.2814 0.4174 0.066 Uiso 1 1 calc R . .
H10B H 0.9615 0.2675 0.4485 0.066 Uiso 1 1 calc R . .
H10C H 0.9475 0.2384 0.3948 0.066 Uiso 1 1 calc R . .
C11 C 0.7311(4) 0.3182(3) 0.34868(18) 0.0306(12) Uani 1 1 d . . .
C12 C 0.5928(4) 0.3356(3) 0.3901(2) 0.0308(12) Uani 1 1 d . . .
C13 C 0.6211(5) 0.4053(3) 0.4028(2) 0.0338(13) Uani 1 1 d . . .
C14 C 0.7062(5) 0.4259(3) 0.3859(2) 0.0342(13) Uani 1 1 d . . .
H14 H 0.7285 0.4725 0.3936 0.041 Uiso 1 1 calc R . .
C15 C 0.5597(6) 0.4501(4) 0.4328(3) 0.0527(19) Uani 1 1 d . . .
H15A H 0.5406 0.4936 0.4154 0.063 Uiso 1 1 calc R . .
H15B H 0.5961 0.4627 0.4628 0.063 Uiso 1 1 calc R . .
H15C H 0.5023 0.4232 0.4399 0.063 Uiso 1 1 calc R . .
C16 C 0.6529(4) 0.1166(3) 0.3933(2) 0.0322(12) Uani 1 1 d . . .
C17 C 0.6058(5) 0.1477(3) 0.4318(2) 0.0347(13) Uani 1 1 d . . .
C18 C 0.5045(4) 0.1376(3) 0.4214(2) 0.0329(12) Uani 1 1 d . . .
C19 C 0.4885(4) 0.1022(3) 0.3764(2) 0.0320(12) Uani 1 1 d . . .
C20 C 0.5817(5) 0.0878(3) 0.3590(2) 0.0332(12) Uani 1 1 d . . .
C21 C 0.7588(5) 0.1154(4) 0.3887(3) 0.0477(17) Uani 1 1 d . . .
H21A H 0.7903 0.0900 0.4161 0.057 Uiso 1 1 calc R . .
H21B H 0.7832 0.1643 0.3881 0.057 Uiso 1 1 calc R . .
H21C H 0.7725 0.0910 0.3591 0.057 Uiso 1 1 calc R . .
C22 C 0.6535(6) 0.1831(4) 0.4747(2) 0.0478(16) Uani 1 1 d . . .
H22A H 0.6910 0.2238 0.4646 0.057 Uiso 1 1 calc R . .
H22B H 0.6961 0.1491 0.4920 0.057 Uiso 1 1 calc R . .
H22C H 0.6047 0.1997 0.4955 0.057 Uiso 1 1 calc R . .
C23 C 0.4276(5) 0.1646(4) 0.4505(3) 0.0485(17) Uani 1 1 d . . .
H23A H 0.3863 0.1250 0.4589 0.058 Uiso 1 1 calc R . .
H23B H 0.3892 0.2001 0.4321 0.058 Uiso 1 1 calc R . .
H23C H 0.4563 0.1865 0.4798 0.058 Uiso 1 1 calc R . .
C24 C 0.3946(5) 0.0817(4) 0.3515(3) 0.0471(17) Uani 1 1 d . . .
H24A H 0.3555 0.1245 0.3453 0.057 Uiso 1 1 calc R . .
H24B H 0.3608 0.0489 0.3717 0.057 Uiso 1 1 calc R . .
H24C H 0.4058 0.0583 0.3212 0.057 Uiso 1 1 calc R . .
C25 C 0.6001(6) 0.0452(4) 0.3163(2) 0.0482(17) Uani 1 1 d . . .
H25A H 0.6347 0.0016 0.3261 0.058 Uiso 1 1 calc R . .
H25B H 0.6389 0.0730 0.2952 0.058 Uiso 1 1 calc R . .
H25C H 0.5390 0.0325 0.2991 0.058 Uiso 1 1 calc R . .
C26 C 0.5444(4) 0.2150(3) 0.2610(2) 0.0323(13) Uani 1 1 d . . .
C27 C 0.4164(4) 0.2644(3) 0.2128(2) 0.0338(13) Uani 1 1 d . . .
C28 C 0.3723(4) 0.2875(4) 0.2533(2) 0.0389(14) Uani 1 1 d . . .
C29 C 0.4176(5) 0.2672(3) 0.2961(2) 0.0381(14) Uani 1 1 d . . .
H29 H 0.3879 0.2791 0.3246 0.046 Uiso 1 1 calc R . .
C30 C 0.2818(6) 0.3294(6) 0.2489(3) 0.074(3) Uani 1 1 d . . .
H30A H 0.2919 0.3753 0.2651 0.089 Uiso 1 1 calc R . .
H30B H 0.2311 0.3030 0.2637 0.089 Uiso 1 1 calc R . .
H30C H 0.2628 0.3376 0.2151 0.089 Uiso 1 1 calc R . .
C31 C 0.5479(5) 0.0887(3) 0.1426(2) 0.0392(14) Uani 1 1 d . . .
C32 C 0.4481(5) 0.0887(3) 0.1545(2) 0.0368(14) Uani 1 1 d . . .
C33 C 0.3931(5) 0.1210(3) 0.1152(2) 0.0363(13) Uani 1 1 d . . .
C34 C 0.4584(5) 0.1414(3) 0.0796(2) 0.0369(13) Uani 1 1 d . . .
C35 C 0.5529(5) 0.1197(3) 0.0973(2) 0.0395(14) Uani 1 1 d . . .
C36 C 0.6276(6) 0.0571(4) 0.1742(3) 0.056(2) Uani 1 1 d . . .
H36A H 0.6765 0.0935 0.1819 0.067 Uiso 1 1 calc R . .
H36B H 0.6564 0.0174 0.1576 0.067 Uiso 1 1 calc R . .
H36C H 0.6022 0.0398 0.2038 0.067 Uiso 1 1 calc R . .
C37 C 0.4099(6) 0.0587(4) 0.1982(3) 0.0541(19) Uani 1 1 d . . .
H37A H 0.3647 0.0202 0.1893 0.065 Uiso 1 1 calc R . .
H37B H 0.3768 0.0961 0.2150 0.065 Uiso 1 1 calc R . .
H37C H 0.4630 0.0398 0.2191 0.065 Uiso 1 1 calc R . .
C38 C 0.2887(5) 0.1340(4) 0.1120(3) 0.0495(17) Uani 1 1 d . . .
H38A H 0.2725 0.1655 0.1381 0.059 Uiso 1 1 calc R . .
H38B H 0.2548 0.0886 0.1144 0.059 Uiso 1 1 calc R . .
H38C H 0.2696 0.1565 0.0812 0.059 Uiso 1 1 calc R . .
C39 C 0.4283(6) 0.1735(4) 0.0323(2) 0.0548(19) Uani 1 1 d . . .
H39A H 0.4433 0.1405 0.0067 0.066 Uiso 1 1 calc R . .
H39B H 0.4628 0.2184 0.0285 0.066 Uiso 1 1 calc R . .
H39C H 0.3591 0.1827 0.0305 0.066 Uiso 1 1 calc R . .
C40 C 0.6422(6) 0.1286(4) 0.0714(3) 0.059(2) Uani 1 1 d . . .
H40A H 0.6708 0.0818 0.0663 0.071 Uiso 1 1 calc R . .
H40B H 0.6880 0.1583 0.0905 0.071 Uiso 1 1 calc R . .
H40C H 0.6263 0.1515 0.0404 0.071 Uiso 1 1 calc R . .
C41 C 0.6798(4) 0.2831(3) 0.14123(19) 0.0303(12) Uani 1 1 d . . .
C42 C 0.6916(4) 0.3918(3) 0.09997(17) 0.0249(10) Uani 1 1 d . . .
C43 C 0.5922(4) 0.3924(3) 0.08683(18) 0.0255(10) Uani 1 1 d . . .
C44 C 0.5442(4) 0.3347(3) 0.10291(19) 0.0292(11) Uani 1 1 d . . .
H44 H 0.4771 0.3322 0.0950 0.035 Uiso 1 1 calc R . .
C45 C 0.5466(5) 0.4500(3) 0.0555(2) 0.0384(14) Uani 1 1 d . . .
H45A H 0.4954 0.4729 0.0721 0.046 Uiso 1 1 calc R . .
H45B H 0.5197 0.4290 0.0255 0.046 Uiso 1 1 calc R . .
H45C H 0.5951 0.4855 0.0486 0.046 Uiso 1 1 calc R . .
C46 C 0.9885(5) 0.3018(3) 0.1311(2) 0.0371(14) Uani 1 1 d . . .
C47 C 0.9431(5) 0.2982(3) 0.0843(2) 0.0371(13) Uani 1 1 d . . .
C48 C 0.9524(4) 0.3651(4) 0.0622(2) 0.0341(13) Uani 1 1 d . . .
C49 C 1.0020(4) 0.4124(3) 0.0960(2) 0.0332(12) Uani 1 1 d . . .
C50 C 1.0266(4) 0.3725(3) 0.1381(2) 0.0349(13) Uani 1 1 d . . .
C51 C 1.0042(6) 0.2396(4) 0.1647(3) 0.058(2) Uani 1 1 d . . .
H51A H 1.0435 0.2036 0.1500 0.070 Uiso 1 1 calc R . .
H51B H 0.9421 0.2188 0.1713 0.070 Uiso 1 1 calc R . .
H51C H 1.0371 0.2560 0.1947 0.070 Uiso 1 1 calc R . .
C52 C 0.8934(6) 0.2331(4) 0.0629(3) 0.063(2) Uani 1 1 d . . .
H52A H 0.9245 0.2187 0.0341 0.075 Uiso 1 1 calc R . .
H52B H 0.8258 0.2442 0.0544 0.075 Uiso 1 1 calc R . .
H52C H 0.8977 0.1942 0.0862 0.075 Uiso 1 1 calc R . .
C53 C 0.9167(6) 0.3847(5) 0.0127(2) 0.057(2) Uani 1 1 d . . .
H53A H 0.8469 0.3784 0.0091 0.069 Uiso 1 1 calc R . .
H53B H 0.9469 0.3539 -0.0102 0.069 Uiso 1 1 calc R . .
H53C H 0.9326 0.4345 0.0066 0.069 Uiso 1 1 calc R . .
C54 C 1.0257(5) 0.4884(4) 0.0873(3) 0.058(2) Uani 1 1 d . . .
H54A H 1.0955 0.4947 0.0900 0.070 Uiso 1 1 calc R . .
H54B H 0.9968 0.5184 0.1111 0.070 Uiso 1 1 calc R . .
H54C H 1.0004 0.5023 0.0552 0.070 Uiso 1 1 calc R . .
C55 C 1.0796(6) 0.3993(5) 0.1826(3) 0.064(2) Uani 1 1 d . . .
H55A H 1.0434 0.4384 0.1959 0.077 Uiso 1 1 calc R . .
H55B H 1.1429 0.4165 0.1750 0.077 Uiso 1 1 calc R . .
H55C H 1.0871 0.3606 0.2060 0.077 Uiso 1 1 calc R . .
C56 C 0.8654(4) 0.3930(3) 0.2317(2) 0.0274(11) Uani 1 1 d . . .
C57 C 0.8478(4) 0.4990(3) 0.27494(18) 0.0262(11) Uani 1 1 d . . .
C58 C 0.8323(4) 0.5382(3) 0.2321(2) 0.0284(11) Uani 1 1 d . . .
C59 C 0.8371(4) 0.4995(3) 0.19162(19) 0.0291(11) Uani 1 1 d . . .
H59 H 0.8288 0.5241 0.1620 0.035 Uiso 1 1 calc R . .
C60 C 0.8203(5) 0.6176(3) 0.2330(3) 0.0434(15) Uani 1 1 d . . .
H60A H 0.7603 0.6307 0.2150 0.052 Uiso 1 1 calc R . .
H60B H 0.8744 0.6403 0.2185 0.052 Uiso 1 1 calc R . .
H60C H 0.8183 0.6337 0.2662 0.052 Uiso 1 1 calc R . .
C61 C 0.8170(8) 0.6207(5) 0.0499(4) 0.069(2) Uani 1 1 d . . .
C62 C 0.7463(6) 0.5474(4) -0.0176(3) 0.0573(19) Uani 1 1 d . . .
C63 C 0.7534(8) 0.6075(5) -0.0502(4) 0.073(3) Uani 1 1 d . . .
C64 C 0.7938(8) 0.6675(6) -0.0300(4) 0.082(3) Uani 1 1 d . . .
H64 H 0.8015 0.7079 -0.0497 0.098 Uiso 1 1 calc R . .
C65 C 0.7240(8) 0.6047(7) -0.1008(4) 0.086(3) Uani 1 1 d . . .
H65A H 0.7796 0.6139 -0.1194 0.104 Uiso 1 1 calc R . .
H65B H 0.6748 0.6410 -0.1084 0.104 Uiso 1 1 calc R . .
H65C H 0.6978 0.5575 -0.1089 0.104 Uiso 1 1 calc R . .
C66 C 0.7244(9) 0.9469(5) 0.0766(5) 0.090(3) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.242(4) . ?
Dy1 O3 2.251(4) . ?
Dy1 O7 2.252(4) . ?
Dy1 O12 2.266(4) . ?
Dy1 O5 2.290(4) . ?
Dy1 O9 2.385(7) . ?
Dy1 O10 2.387(6) . ?
Dy1 N9 2.873(5) . ?
Rh1 N1 2.104(5) . ?
Rh1 C3 2.130(6) . ?
Rh1 C4 2.125(6) . ?
Rh1 C2 2.136(6) . ?
Rh1 N8 2.143(5) . ?
Rh1 C1 2.144(6) . ?
Rh1 C5 2.151(6) . ?
Rh1 O8 2.209(4) . ?
Rh2 N3 2.085(5) . ?
Rh2 C18 2.114(5) . ?
Rh2 C17 2.118(6) . ?
Rh2 N2 2.129(5) . ?
Rh2 C19 2.140(6) . ?
Rh2 C16 2.147(5) . ?
Rh2 C20 2.174(6) . ?
Rh2 O2 2.186(5) . ?
Rh3 N5 2.092(5) . ?
Rh3 N4 2.116(5) . ?
Rh3 C31 2.133(6) . ?
Rh3 C34 2.135(6) . ?
Rh3 C32 2.138(6) . ?
Rh3 C33 2.140(6) . ?
Rh3 C35 2.143(6) . ?
Rh3 O4 2.215(5) . ?
Rh3 C27 2.612(7) . ?
Rh4 N7 2.098(5) . ?
Rh4 C49 2.115(6) . ?
Rh4 N6 2.131(5) . ?
Rh4 C46 2.134(6) . ?
Rh4 C50 2.133(6) . ?
Rh4 C47 2.147(6) . ?
Rh4 C48 2.150(5) . ?
Rh4 O6 2.201(4) . ?
Rh4 C42 2.618(5) . ?
O1 C11 1.281(7) . ?
O2 C12 1.283(7) . ?
O3 C26 1.285(7) . ?
O4 C27 1.281(7) . ?
O5 C41 1.275(7) . ?
O6 C42 1.285(7) . ?
O7 C56 1.291(6) . ?
O8 C57 1.273(7) . ?
O9 N9 1.188(9) . ?
O10 N9 1.108(8) . ?
O11 N9 1.207(7) . ?
O12 N10 1.262(6) . ?
O13 N10 1.216(7) . ?
O14 N10 1.196(8) . ?
O15 N11 1.164(12) . ?
O16 N11 1.295(11) . ?
O17 N11 1.291(13) . ?
O18 C61 1.205(11) . ?
O19 C62 1.206(10) . ?
O20 C66 1.444(18) . ?
N1 C14 1.333(8) . ?
N1 C11 1.353(8) . ?
N2 C11 1.343(8) . ?
N2 C12 1.355(7) . ?
N3 C26 1.333(8) . ?
N3 C29 1.347(8) . ?
N4 C27 1.352(8) . ?
N4 C26 1.353(8) . ?
N5 C41 1.348(8) . ?
N5 C44 1.349(7) . ?
N6 C41 1.343(8) . ?
N6 C42 1.352(7) . ?
N7 C59 1.345(7) . ?
N7 C56 1.351(7) . ?
N8 C56 1.337(7) . ?
N8 C57 1.357(7) . ?
N12 C61 1.279(12) . ?
N12 C64 1.462(14) . ?
N12 H12 0.8800 . ?
N13 C62 1.363(11) . ?
N13 C61 1.438(12) . ?
N13 H13 0.8800 . ?
C1 C5 1.426(9) . ?
C1 C2 1.436(9) . ?
C1 C6 1.482(9) . ?
C2 C3 1.432(9) . ?
C2 C7 1.486(9) . ?
C3 C4 1.429(9) . ?
C3 C8 1.496(9) . ?
C4 C5 1.418(9) . ?
C4 C9 1.502(9) . ?
C5 C10 1.488(9) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C12 C13 1.406(8) . ?
C13 C14 1.365(9) . ?
C13 C15 1.502(9) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.425(8) . ?
C16 C20 1.442(9) . ?
C16 C21 1.495(9) . ?
C17 C18 1.439(9) . ?
C17 C22 1.490(9) . ?
C18 C19 1.431(8) . ?
C18 C23 1.482(9) . ?
C19 C20 1.448(9) . ?
C19 C24 1.493(9) . ?
C20 C25 1.479(9) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C27 C28 1.399(9) . ?
C28 C29 1.373(9) . ?
C28 C30 1.487(9) . ?
C29 H29 0.9500 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C35 1.404(9) . ?
C31 C32 1.456(10) . ?
C31 C36 1.498(9) . ?
C32 C33 1.433(8) . ?
C32 C37 1.482(9) . ?
C33 C34 1.449(9) . ?
C33 C38 1.476(10) . ?
C34 C35 1.436(9) . ?
C34 C39 1.492(9) . ?
C35 C40 1.496(10) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C42 C43 1.413(8) . ?
C43 C44 1.367(8) . ?
C43 C45 1.506(7) . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C47 1.420(9) . ?
C46 C50 1.439(9) . ?
C46 C51 1.507(9) . ?
C47 C48 1.409(9) . ?
C47 C52 1.509(10) . ?
C48 C49 1.440(9) . ?
C48 C53 1.489(9) . ?
C49 C50 1.421(8) . ?
C49 C54 1.490(9) . ?
C50 C55 1.493(9) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C57 C58 1.413(7) . ?
C58 C59 1.353(8) . ?
C58 C60 1.501(8) . ?
C59 H59 0.9500 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C62 C63 1.459(13) . ?
C63 C64 1.366(15) . ?
C63 C65 1.451(14) . ?
C64 H64 0.9500 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O3 88.19(16) . . ?
O1 Dy1 O7 87.37(16) . . ?
O3 Dy1 O7 164.55(14) . . ?
O1 Dy1 O12 84.12(17) . . ?
O3 Dy1 O12 84.92(16) . . ?
O7 Dy1 O12 79.91(16) . . ?
O1 Dy1 O5 163.60(15) . . ?
O3 Dy1 O5 89.31(16) . . ?
O7 Dy1 O5 90.78(16) . . ?
O12 Dy1 O5 79.51(16) . . ?
O1 Dy1 O9 115.3(3) . . ?
O3 Dy1 O9 86.3(4) . . ?
O7 Dy1 O9 109.0(4) . . ?
O12 Dy1 O9 158.4(2) . . ?
O5 Dy1 O9 80.7(3) . . ?
O1 Dy1 O10 74.6(3) . . ?
O3 Dy1 O10 105.3(4) . . ?
O7 Dy1 O10 87.8(3) . . ?
O12 Dy1 O10 155.8(2) . . ?
O5 Dy1 O10 121.7(3) . . ?
O9 Dy1 O10 45.8(3) . . ?
O1 Dy1 N9 93.74(16) . . ?
O3 Dy1 N9 95.77(16) . . ?
O7 Dy1 N9 99.29(15) . . ?
O12 Dy1 N9 177.73(17) . . ?
O5 Dy1 N9 102.64(16) . . ?
O9 Dy1 N9 23.9(2) . . ?
O10 Dy1 N9 21.9(2) . . ?
N1 Rh1 C3 135.1(2) . . ?
N1 Rh1 C4 100.6(2) . . ?
C3 Rh1 C4 39.2(2) . . ?
N1 Rh1 C2 161.7(2) . . ?
C3 Rh1 C2 39.2(2) . . ?
C4 Rh1 C2 65.8(2) . . ?
N1 Rh1 N8 91.02(18) . . ?
C3 Rh1 N8 130.4(2) . . ?
C4 Rh1 N8 168.3(2) . . ?
C2 Rh1 N8 102.6(2) . . ?
N1 Rh1 C1 125.0(2) . . ?
C3 Rh1 C1 65.5(2) . . ?
C4 Rh1 C1 65.3(2) . . ?
C2 Rh1 C1 39.2(2) . . ?
N8 Rh1 C1 107.0(2) . . ?
N1 Rh1 C5 96.3(2) . . ?
C3 Rh1 C5 65.2(2) . . ?
C4 Rh1 C5 38.7(2) . . ?
C2 Rh1 C5 65.4(2) . . ?
N8 Rh1 C5 139.3(2) . . ?
C1 Rh1 C5 38.8(2) . . ?
N1 Rh1 O8 91.73(19) . . ?
C3 Rh1 O8 95.4(2) . . ?
C4 Rh1 O8 120.4(2) . . ?
C2 Rh1 O8 105.7(2) . . ?
N8 Rh1 O8 59.81(16) . . ?
C1 Rh1 O8 142.4(2) . . ?
C5 Rh1 O8 158.7(2) . . ?
N3 Rh2 C18 131.0(2) . . ?
N3 Rh2 C17 166.5(2) . . ?
C18 Rh2 C17 39.7(2) . . ?
N3 Rh2 N2 87.32(18) . . ?
C18 Rh2 N2 136.6(2) . . ?
C17 Rh2 N2 105.4(2) . . ?
N3 Rh2 C19 100.3(2) . . ?
C18 Rh2 C19 39.3(2) . . ?
C17 Rh2 C19 66.7(2) . . ?
N2 Rh2 C19 170.9(2) . . ?
N3 Rh2 C16 133.8(2) . . ?
C18 Rh2 C16 65.4(2) . . ?
C17 Rh2 C16 39.0(2) . . ?
N2 Rh2 C16 105.2(2) . . ?
C19 Rh2 C16 65.8(2) . . ?
N3 Rh2 C20 102.1(2) . . ?
C18 Rh2 C20 65.4(2) . . ?
C17 Rh2 C20 65.9(2) . . ?
N2 Rh2 C20 134.4(2) . . ?
C19 Rh2 C20 39.2(2) . . ?
C16 Rh2 C20 39.0(2) . . ?
N3 Rh2 O2 91.37(19) . . ?
C18 Rh2 O2 94.6(2) . . ?
C17 Rh2 O2 98.8(2) . . ?
N2 Rh2 O2 60.08(17) . . ?
C19 Rh2 O2 124.2(2) . . ?
C16 Rh2 O2 133.7(2) . . ?
C20 Rh2 O2 160.0(2) . . ?
N5 Rh3 N4 90.52(19) . . ?
N5 Rh3 C31 120.7(2) . . ?
N4 Rh3 C31 108.5(2) . . ?
N5 Rh3 C34 107.3(2) . . ?
N4 Rh3 C34 161.8(2) . . ?
C31 Rh3 C34 65.6(2) . . ?
N5 Rh3 C32 160.5(2) . . ?
N4 Rh3 C32 98.0(2) . . ?
C31 Rh3 C32 39.9(3) . . ?
C34 Rh3 C32 66.2(2) . . ?
N5 Rh3 C33 144.1(2) . . ?
N4 Rh3 C33 122.3(2) . . ?
C31 Rh3 C33 65.9(2) . . ?
C34 Rh3 C33 39.6(2) . . ?
C32 Rh3 C33 39.1(2) . . ?
N5 Rh3 C35 97.4(2) . . ?
N4 Rh3 C35 143.8(2) . . ?
C31 Rh3 C35 38.3(3) . . ?
C34 Rh3 C35 39.2(3) . . ?
C32 Rh3 C35 65.6(3) . . ?
C33 Rh3 C35 65.7(3) . . ?
N5 Rh3 O4 91.11(19) . . ?
N4 Rh3 O4 60.14(18) . . ?
C31 Rh3 O4 147.4(2) . . ?
C34 Rh3 O4 114.7(2) . . ?
C32 Rh3 O4 108.4(2) . . ?
C33 Rh3 O4 93.3(2) . . ?
C35 Rh3 O4 153.9(2) . . ?
N5 Rh3 C27 93.64(19) . . ?
N4 Rh3 C27 31.03(18) . . ?
C31 Rh3 C27 130.7(2) . . ?
C34 Rh3 C27 140.1(2) . . ?
C32 Rh3 C27 102.7(2) . . ?
C33 Rh3 C27 107.3(2) . . ?
C35 Rh3 C27 168.1(2) . . ?
O4 Rh3 C27 29.33(17) . . ?
N7 Rh4 C49 111.8(2) . . ?
N7 Rh4 N6 88.49(17) . . ?
C49 Rh4 N6 157.2(2) . . ?
N7 Rh4 C46 113.0(2) . . ?
C49 Rh4 C46 65.9(2) . . ?
N6 Rh4 C46 116.9(2) . . ?
N7 Rh4 C50 94.4(2) . . ?
C49 Rh4 C50 39.1(2) . . ?
N6 Rh4 C50 154.5(2) . . ?
C46 Rh4 C50 39.4(2) . . ?
N7 Rh4 C47 151.5(2) . . ?
C49 Rh4 C47 65.7(2) . . ?
N6 Rh4 C47 101.6(2) . . ?
C46 Rh4 C47 38.7(2) . . ?
C50 Rh4 C47 65.4(2) . . ?
N7 Rh4 C48 150.9(2) . . ?
C49 Rh4 C48 39.5(2) . . ?
N6 Rh4 C48 119.1(2) . . ?
C46 Rh4 C48 64.7(2) . . ?
C50 Rh4 C48 65.1(2) . . ?
C47 Rh4 C48 38.3(2) . . ?
N7 Rh4 O6 89.40(17) . . ?
C49 Rh4 O6 107.76(19) . . ?
N6 Rh4 O6 60.30(16) . . ?
C46 Rh4 O6 157.5(2) . . ?
C50 Rh4 O6 144.9(2) . . ?
C47 Rh4 O6 118.8(2) . . ?
C48 Rh4 O6 96.28(19) . . ?
N7 Rh4 C42 89.38(17) . . ?
C49 Rh4 C42 134.2(2) . . ?
N6 Rh4 C42 30.97(17) . . ?
C46 Rh4 C42 143.0(2) . . ?
C50 Rh4 C42 173.2(2) . . ?
C47 Rh4 C42 113.0(2) . . ?
C48 Rh4 C42 109.26(19) . . ?
O6 Rh4 C42 29.34(15) . . ?
C11 O1 Dy1 132.6(4) . . ?
C12 O2 Rh2 94.7(4) . . ?
C26 O3 Dy1 126.3(4) . . ?
C27 O4 Rh3 92.8(4) . . ?
C41 O5 Dy1 125.5(4) . . ?
C42 O6 Rh4 93.6(3) . . ?
C56 O7 Dy1 125.4(3) . . ?
C57 O8 Rh1 93.9(3) . . ?
N9 O9 Dy1 101.8(5) . . ?
N9 O10 Dy1 104.5(5) . . ?
N10 O12 Dy1 163.4(4) . . ?
C14 N1 C11 118.8(5) . . ?
C14 N1 Rh1 119.0(4) . . ?
C11 N1 Rh1 120.8(4) . . ?
C11 N2 C12 120.8(5) . . ?
C11 N2 Rh2 144.0(4) . . ?
C12 N2 Rh2 95.1(4) . . ?
C26 N3 C29 118.7(5) . . ?
C26 N3 Rh2 121.2(4) . . ?
C29 N3 Rh2 120.1(4) . . ?
C27 N4 C26 121.2(5) . . ?
C27 N4 Rh3 95.2(4) . . ?
C26 N4 Rh3 142.4(4) . . ?
C41 N5 C44 119.0(5) . . ?
C41 N5 Rh3 123.6(4) . . ?
C44 N5 Rh3 117.3(4) . . ?
C41 N6 C42 122.0(5) . . ?
C41 N6 Rh4 143.1(4) . . ?
C42 N6 Rh4 94.8(3) . . ?
C59 N7 C56 118.3(5) . . ?
C59 N7 Rh4 121.0(4) . . ?
C56 N7 Rh4 120.2(4) . . ?
C56 N8 C57 121.6(5) . . ?
C56 N8 Rh1 143.5(4) . . ?
C57 N8 Rh1 94.5(3) . . ?
O10 N9 O9 107.8(6) . . ?
O10 N9 O11 124.0(7) . . ?
O9 N9 O11 128.3(7) . . ?
O10 N9 Dy1 53.5(4) . . ?
O9 N9 Dy1 54.3(4) . . ?
O11 N9 Dy1 176.9(6) . . ?
O14 N10 O13 123.3(7) . . ?
O14 N10 O12 118.3(6) . . ?
O13 N10 O12 118.4(6) . . ?
O15 N11 O17 126.8(12) . . ?
O15 N11 O16 118.2(12) . . ?
O17 N11 O16 114.9(11) . . ?
C61 N12 C64 122.7(9) . . ?
C61 N12 H12 118.7 . . ?
C64 N12 H12 118.7 . . ?
C62 N13 C61 125.2(8) . . ?
C62 N13 H13 117.4 . . ?
C61 N13 H13 117.4 . . ?
C5 C1 C2 108.0(6) . . ?
C5 C1 C6 126.0(6) . . ?
C2 C1 C6 125.9(6) . . ?
C5 C1 Rh1 70.9(4) . . ?
C2 C1 Rh1 70.1(3) . . ?
C6 C1 Rh1 126.5(4) . . ?
C3 C2 C1 107.4(6) . . ?
C3 C2 C7 125.3(6) . . ?
C1 C2 C7 127.2(6) . . ?
C3 C2 Rh1 70.2(3) . . ?
C1 C2 Rh1 70.7(3) . . ?
C7 C2 Rh1 126.8(5) . . ?
C2 C3 C4 108.1(5) . . ?
C2 C3 C8 125.3(6) . . ?
C4 C3 C8 126.6(6) . . ?
C2 C3 Rh1 70.6(3) . . ?
C4 C3 Rh1 70.2(3) . . ?
C8 C3 Rh1 122.8(5) . . ?
C5 C4 C3 108.2(5) . . ?
C5 C4 C9 125.2(6) . . ?
C3 C4 C9 126.5(6) . . ?
C5 C4 Rh1 71.6(3) . . ?
C3 C4 Rh1 70.6(3) . . ?
C9 C4 Rh1 125.8(5) . . ?
C4 C5 C1 108.3(5) . . ?
C4 C5 C10 126.5(6) . . ?
C1 C5 C10 125.2(7) . . ?
C4 C5 Rh1 69.7(3) . . ?
C1 C5 Rh1 70.4(3) . . ?
C10 C5 Rh1 127.1(4) . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O1 C11 N2 121.4(6) . . ?
O1 C11 N1 118.6(5) . . ?
N2 C11 N1 119.9(5) . . ?
O2 C12 N2 110.0(5) . . ?
O2 C12 C13 129.2(5) . . ?
N2 C12 C13 120.9(5) . . ?
C14 C13 C12 114.3(5) . . ?
C14 C13 C15 125.6(6) . . ?
C12 C13 C15 120.1(6) . . ?
N1 C14 C13 124.9(6) . . ?
N1 C14 H14 117.5 . . ?
C13 C14 H14 117.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 C16 C20 109.0(5) . . ?
C17 C16 C21 125.7(6) . . ?
C20 C16 C21 125.3(6) . . ?
C17 C16 Rh2 69.4(3) . . ?
C20 C16 Rh2 71.5(3) . . ?
C21 C16 Rh2 124.2(4) . . ?
C16 C17 C18 107.1(5) . . ?
C16 C17 C22 126.0(6) . . ?
C18 C17 C22 126.9(6) . . ?
C16 C17 Rh2 71.6(3) . . ?
C18 C17 Rh2 70.0(3) . . ?
C22 C17 Rh2 124.1(4) . . ?
C19 C18 C17 109.3(5) . . ?
C19 C18 C23 124.7(6) . . ?
C17 C18 C23 125.8(6) . . ?
C19 C18 Rh2 71.3(3) . . ?
C17 C18 Rh2 70.3(3) . . ?
C23 C18 Rh2 120.8(4) . . ?
C18 C19 C20 107.2(5) . . ?
C18 C19 C24 127.7(6) . . ?
C20 C19 C24 125.2(6) . . ?
C18 C19 Rh2 69.4(3) . . ?
C20 C19 Rh2 71.7(3) . . ?
C24 C19 Rh2 125.1(4) . . ?
C16 C20 C19 107.5(5) . . ?
C16 C20 C25 126.4(6) . . ?
C19 C20 C25 125.9(6) . . ?
C16 C20 Rh2 69.5(3) . . ?
C19 C20 Rh2 69.1(3) . . ?
C25 C20 Rh2 131.2(4) . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C16 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C17 C22 H22A 109.5 . . ?
C17 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C17 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C18 C23 H23A 109.5 . . ?
C18 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C18 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C19 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C19 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O3 C26 N3 119.7(5) . . ?
O3 C26 N4 120.2(6) . . ?
N3 C26 N4 120.2(5) . . ?
O4 C27 N4 111.1(6) . . ?
O4 C27 C28 128.4(6) . . ?
N4 C27 C28 120.3(5) . . ?
O4 C27 Rh3 57.9(3) . . ?
N4 C27 Rh3 53.8(3) . . ?
C28 C27 Rh3 168.2(5) . . ?
C29 C28 C27 115.0(6) . . ?
C29 C28 C30 123.8(6) . . ?
C27 C28 C30 121.2(6) . . ?
N3 C29 C28 124.2(6) . . ?
N3 C29 H29 117.9 . . ?
C28 C29 H29 117.9 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C35 C31 C32 108.4(5) . . ?
C35 C31 C36 128.2(7) . . ?
C32 C31 C36 123.4(6) . . ?
C35 C31 Rh3 71.2(4) . . ?
C32 C31 Rh3 70.2(3) . . ?
C36 C31 Rh3 126.2(4) . . ?
C33 C32 C31 107.2(6) . . ?
C33 C32 C37 126.3(7) . . ?
C31 C32 C37 126.5(6) . . ?
C33 C32 Rh3 70.5(3) . . ?
C31 C32 Rh3 69.9(3) . . ?
C37 C32 Rh3 126.4(5) . . ?
C32 C33 C34 108.1(6) . . ?
C32 C33 C38 126.3(6) . . ?
C34 C33 C38 125.5(6) . . ?
C32 C33 Rh3 70.3(3) . . ?
C34 C33 Rh3 70.0(3) . . ?
C38 C33 Rh3 123.6(5) . . ?
C35 C34 C33 107.2(5) . . ?
C35 C34 C39 128.1(7) . . ?
C33 C34 C39 124.6(6) . . ?
C35 C34 Rh3 70.7(3) . . ?
C33 C34 Rh3 70.4(3) . . ?
C39 C34 Rh3 127.7(5) . . ?
C31 C35 C34 109.1(6) . . ?
C31 C35 C40 125.5(7) . . ?
C34 C35 C40 125.4(7) . . ?
C31 C35 Rh3 70.5(4) . . ?
C34 C35 Rh3 70.1(4) . . ?
C40 C35 Rh3 125.8(5) . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
O5 C41 N6 121.5(6) . . ?
O5 C41 N5 119.3(5) . . ?
N6 C41 N5 119.2(5) . . ?
O6 C42 N6 111.2(5) . . ?
O6 C42 C43 128.0(5) . . ?
N6 C42 C43 120.7(5) . . ?
O6 C42 Rh4 57.1(3) . . ?
N6 C42 Rh4 54.2(3) . . ?
C43 C42 Rh4 174.5(4) . . ?
C44 C43 C42 113.9(5) . . ?
C44 C43 C45 124.3(5) . . ?
C42 C43 C45 121.8(5) . . ?
N5 C44 C43 125.0(5) . . ?
N5 C44 H44 117.5 . . ?
C43 C44 H44 117.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C47 C46 C50 107.9(5) . . ?
C47 C46 C51 125.4(7) . . ?
C50 C46 C51 126.3(7) . . ?
C47 C46 Rh4 71.1(3) . . ?
C50 C46 Rh4 70.2(3) . . ?
C51 C46 Rh4 129.8(5) . . ?
C48 C47 C46 108.3(6) . . ?
C48 C47 C52 127.0(7) . . ?
C46 C47 C52 124.7(7) . . ?
C48 C47 Rh4 71.0(3) . . ?
C46 C47 Rh4 70.2(3) . . ?
C52 C47 Rh4 124.4(5) . . ?
C47 C48 C49 108.4(5) . . ?
C47 C48 C53 126.4(7) . . ?
C49 C48 C53 125.2(6) . . ?
C47 C48 Rh4 70.7(3) . . ?
C49 C48 Rh4 69.0(3) . . ?
C53 C48 Rh4 125.6(5) . . ?
C50 C49 C48 107.4(5) . . ?
C50 C49 C54 126.7(6) . . ?
C48 C49 C54 125.9(6) . . ?
C50 C49 Rh4 71.2(3) . . ?
C48 C49 Rh4 71.6(3) . . ?
C54 C49 Rh4 124.2(4) . . ?
C49 C50 C46 107.9(5) . . ?
C49 C50 C55 126.5(7) . . ?
C46 C50 C55 125.6(6) . . ?
C49 C50 Rh4 69.8(3) . . ?
C46 C50 Rh4 70.3(3) . . ?
C55 C50 Rh4 123.9(5) . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C50 C55 H55A 109.5 . . ?
C50 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C50 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
O7 C56 N8 121.0(5) . . ?
O7 C56 N7 118.9(5) . . ?
N8 C56 N7 120.0(5) . . ?
O8 C57 N8 111.2(5) . . ?
O8 C57 C58 128.8(5) . . ?
N8 C57 C58 119.9(5) . . ?
C59 C58 C57 114.8(5) . . ?
C59 C58 C60 124.1(5) . . ?
C57 C58 C60 120.9(5) . . ?
N7 C59 C58 125.1(5) . . ?
N7 C59 H59 117.4 . . ?
C58 C59 H59 117.4 . . ?
C58 C60 H60A 109.5 . . ?
C58 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C58 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
O18 C61 N12 120.9(9) . . ?
O18 C61 N13 123.4(9) . . ?
N12 C61 N13 115.6(9) . . ?
O19 C62 N13 118.8(9) . . ?
O19 C62 C63 122.6(9) . . ?
N13 C62 C63 118.6(8) . . ?
C64 C63 C62 115.0(9) . . ?
C64 C63 C65 121.0(10) . . ?
C62 C63 C65 123.9(10) . . ?
C63 C64 N12 122.9(9) . . ?
C63 C64 H64 118.6 . . ?
N12 C64 H64 118.6 . . ?
C63 C65 H65A 109.5 . . ?
C63 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C63 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Dy1 O1 C11 -60.5(6) . . . . ?
O7 Dy1 O1 C11 104.7(6) . . . . ?
O12 Dy1 O1 C11 24.6(6) . . . . ?
O5 Dy1 O1 C11 20.8(9) . . . . ?
O9 Dy1 O1 C11 -145.6(7) . . . . ?
O10 Dy1 O1 C11 -166.9(7) . . . . ?
N9 Dy1 O1 C11 -156.2(6) . . . . ?
N3 Rh2 O2 C12 -88.5(4) . . . . ?
C18 Rh2 O2 C12 140.2(4) . . . . ?
C17 Rh2 O2 C12 100.4(4) . . . . ?
N2 Rh2 O2 C12 -2.4(3) . . . . ?
C19 Rh2 O2 C12 168.1(3) . . . . ?
C16 Rh2 O2 C12 80.1(4) . . . . ?
C20 Rh2 O2 C12 138.8(6) . . . . ?
O1 Dy1 O3 C26 91.0(5) . . . . ?
O7 Dy1 O3 C26 17.6(9) . . . . ?
O12 Dy1 O3 C26 6.7(5) . . . . ?
O5 Dy1 O3 C26 -72.8(5) . . . . ?
O9 Dy1 O3 C26 -153.5(6) . . . . ?
O10 Dy1 O3 C26 164.4(5) . . . . ?
N9 Dy1 O3 C26 -175.5(5) . . . . ?
N5 Rh3 O4 C27 -95.5(4) . . . . ?
N4 Rh3 O4 C27 -5.5(3) . . . . ?
C31 Rh3 O4 C27 72.0(5) . . . . ?
C34 Rh3 O4 C27 154.9(4) . . . . ?
C32 Rh3 O4 C27 83.3(4) . . . . ?
C33 Rh3 O4 C27 120.2(4) . . . . ?
C35 Rh3 O4 C27 155.2(5) . . . . ?
O1 Dy1 O5 C41 18.7(9) . . . . ?
O3 Dy1 O5 C41 99.9(5) . . . . ?
O7 Dy1 O5 C41 -64.6(5) . . . . ?
O12 Dy1 O5 C41 14.9(5) . . . . ?
O9 Dy1 O5 C41 -173.7(6) . . . . ?
O10 Dy1 O5 C41 -152.5(6) . . . . ?
N9 Dy1 O5 C41 -164.3(5) . . . . ?
N7 Rh4 O6 C42 -89.8(3) . . . . ?
C49 Rh4 O6 C42 157.5(3) . . . . ?
N6 Rh4 O6 C42 -1.2(3) . . . . ?
C46 Rh4 O6 C42 87.8(6) . . . . ?
C50 Rh4 O6 C42 173.4(4) . . . . ?
C47 Rh4 O6 C42 86.0(4) . . . . ?
C48 Rh4 O6 C42 118.8(3) . . . . ?
O1 Dy1 O7 C56 -69.1(5) . . . . ?
O3 Dy1 O7 C56 4.4(9) . . . . ?
O12 Dy1 O7 C56 15.4(5) . . . . ?
O5 Dy1 O7 C56 94.6(5) . . . . ?
O9 Dy1 O7 C56 175.0(5) . . . . ?
O10 Dy1 O7 C56 -143.7(5) . . . . ?
N9 Dy1 O7 C56 -162.4(4) . . . . ?
N1 Rh1 O8 C57 -94.9(3) . . . . ?
C3 Rh1 O8 C57 129.5(4) . . . . ?
C4 Rh1 O8 C57 161.7(3) . . . . ?
C2 Rh1 O8 C57 90.9(4) . . . . ?
N8 Rh1 O8 C57 -4.7(3) . . . . ?
C1 Rh1 O8 C57 73.6(5) . . . . ?
C5 Rh1 O8 C57 152.9(6) . . . . ?
O1 Dy1 O9 N9 -27.0(12) . . . . ?
O3 Dy1 O9 N9 -113.3(11) . . . . ?
O7 Dy1 O9 N9 69.2(12) . . . . ?
O12 Dy1 O9 N9 -179.4(5) . . . . ?
O5 Dy1 O9 N9 156.8(11) . . . . ?
O10 Dy1 O9 N9 2.3(9) . . . . ?
O1 Dy1 O10 N9 150.2(11) . . . . ?
O3 Dy1 O10 N9 66.5(11) . . . . ?
O7 Dy1 O10 N9 -121.9(10) . . . . ?
O12 Dy1 O10 N9 179.1(5) . . . . ?
O5 Dy1 O10 N9 -32.4(12) . . . . ?
O9 Dy1 O10 N9 -2.5(9) . . . . ?
O1 Dy1 O12 N10 -54.8(14) . . . . ?
O3 Dy1 O12 N10 33.9(14) . . . . ?
O7 Dy1 O12 N10 -143.1(15) . . . . ?
O5 Dy1 O12 N10 124.2(15) . . . . ?
O9 Dy1 O12 N10 100.3(19) . . . . ?
O10 Dy1 O12 N10 -82.7(17) . . . . ?
N9 Dy1 O12 N10 -74(5) . . . . ?
C3 Rh1 N1 C14 42.6(6) . . . . ?
C4 Rh1 N1 C14 64.5(5) . . . . ?
C2 Rh1 N1 C14 105.1(8) . . . . ?
N8 Rh1 N1 C14 -116.7(4) . . . . ?
C1 Rh1 N1 C14 131.7(4) . . . . ?
C5 Rh1 N1 C14 103.4(5) . . . . ?
O8 Rh1 N1 C14 -56.9(4) . . . . ?
C3 Rh1 N1 C11 -123.8(4) . . . . ?
C4 Rh1 N1 C11 -101.9(4) . . . . ?
C2 Rh1 N1 C11 -61.3(9) . . . . ?
N8 Rh1 N1 C11 76.9(4) . . . . ?
C1 Rh1 N1 C11 -34.7(5) . . . . ?
C5 Rh1 N1 C11 -63.0(4) . . . . ?
O8 Rh1 N1 C11 136.7(4) . . . . ?
N3 Rh2 N2 C11 -81.2(6) . . . . ?
C18 Rh2 N2 C11 123.9(6) . . . . ?
C17 Rh2 N2 C11 94.2(6) . . . . ?
C19 Rh2 N2 C11 65.3(15) . . . . ?
C16 Rh2 N2 C11 53.7(7) . . . . ?
C20 Rh2 N2 C11 23.1(7) . . . . ?
O2 Rh2 N2 C11 -174.3(7) . . . . ?
N3 Rh2 N2 C12 95.4(3) . . . . ?
C18 Rh2 N2 C12 -59.6(5) . . . . ?
C17 Rh2 N2 C12 -89.2(4) . . . . ?
C19 Rh2 N2 C12 -118.1(13) . . . . ?
C16 Rh2 N2 C12 -129.8(3) . . . . ?
C20 Rh2 N2 C12 -160.3(3) . . . . ?
O2 Rh2 N2 C12 2.2(3) . . . . ?
C18 Rh2 N3 C26 -120.5(5) . . . . ?
C17 Rh2 N3 C26 -78.5(11) . . . . ?
N2 Rh2 N3 C26 82.2(4) . . . . ?
C19 Rh2 N3 C26 -92.7(5) . . . . ?
C16 Rh2 N3 C26 -26.4(6) . . . . ?
C20 Rh2 N3 C26 -52.7(5) . . . . ?
O2 Rh2 N3 C26 142.2(4) . . . . ?
C18 Rh2 N3 C29 58.5(6) . . . . ?
C17 Rh2 N3 C29 100.4(10) . . . . ?
N2 Rh2 N3 C29 -98.8(5) . . . . ?
C19 Rh2 N3 C29 86.3(5) . . . . ?
C16 Rh2 N3 C29 152.5(5) . . . . ?
C20 Rh2 N3 C29 126.2(5) . . . . ?
O2 Rh2 N3 C29 -38.9(5) . . . . ?
N5 Rh3 N4 C27 96.2(4) . . . . ?
C31 Rh3 N4 C27 -141.0(4) . . . . ?
C34 Rh3 N4 C27 -72.9(8) . . . . ?
C32 Rh3 N4 C27 -101.4(4) . . . . ?
C33 Rh3 N4 C27 -68.3(4) . . . . ?
C35 Rh3 N4 C27 -160.5(4) . . . . ?
O4 Rh3 N4 C27 5.2(3) . . . . ?
N5 Rh3 N4 C26 -97.9(7) . . . . ?
C31 Rh3 N4 C26 24.9(7) . . . . ?
C34 Rh3 N4 C26 93.0(9) . . . . ?
C32 Rh3 N4 C26 64.5(7) . . . . ?
C33 Rh3 N4 C26 97.6(7) . . . . ?
C35 Rh3 N4 C26 5.4(8) . . . . ?
O4 Rh3 N4 C26 171.1(7) . . . . ?
C27 Rh3 N4 C26 165.9(9) . . . . ?
N4 Rh3 N5 C41 75.4(5) . . . . ?
C31 Rh3 N5 C41 -36.6(5) . . . . ?
C34 Rh3 N5 C41 -108.1(5) . . . . ?
C32 Rh3 N5 C41 -40.8(9) . . . . ?
C33 Rh3 N5 C41 -127.2(5) . . . . ?
C35 Rh3 N5 C41 -69.2(5) . . . . ?
O4 Rh3 N5 C41 135.5(4) . . . . ?
C27 Rh3 N5 C41 106.3(4) . . . . ?
N4 Rh3 N5 C44 -108.7(4) . . . . ?
C31 Rh3 N5 C44 139.3(4) . . . . ?
C34 Rh3 N5 C44 67.8(5) . . . . ?
C32 Rh3 N5 C44 135.1(6) . . . . ?
C33 Rh3 N5 C44 48.7(6) . . . . ?
C35 Rh3 N5 C44 106.7(4) . . . . ?
O4 Rh3 N5 C44 -48.5(4) . . . . ?
C27 Rh3 N5 C44 -77.8(4) . . . . ?
N7 Rh4 N6 C41 -86.0(6) . . . . ?
C49 Rh4 N6 C41 120.6(7) . . . . ?
C46 Rh4 N6 C41 29.2(7) . . . . ?
C50 Rh4 N6 C41 11.0(9) . . . . ?
C47 Rh4 N6 C41 67.1(6) . . . . ?
C48 Rh4 N6 C41 103.8(6) . . . . ?
O6 Rh4 N6 C41 -176.2(7) . . . . ?
C42 Rh4 N6 C41 -177.3(8) . . . . ?
N7 Rh4 N6 C42 91.3(3) . . . . ?
C49 Rh4 N6 C42 -62.1(6) . . . . ?
C46 Rh4 N6 C42 -153.5(3) . . . . ?
C50 Rh4 N6 C42 -171.6(4) . . . . ?
C47 Rh4 N6 C42 -115.6(3) . . . . ?
C48 Rh4 N6 C42 -78.9(4) . . . . ?
O6 Rh4 N6 C42 1.1(3) . . . . ?
C49 Rh4 N7 C59 64.7(5) . . . . ?
N6 Rh4 N7 C59 -104.5(4) . . . . ?
C46 Rh4 N7 C59 136.8(4) . . . . ?
C50 Rh4 N7 C59 100.9(5) . . . . ?
C47 Rh4 N7 C59 143.6(5) . . . . ?
C48 Rh4 N7 C59 57.7(7) . . . . ?
O6 Rh4 N7 C59 -44.2(4) . . . . ?
C42 Rh4 N7 C59 -73.5(4) . . . . ?
C49 Rh4 N7 C56 -107.3(4) . . . . ?
N6 Rh4 N7 C56 83.4(4) . . . . ?
C46 Rh4 N7 C56 -35.3(5) . . . . ?
C50 Rh4 N7 C56 -71.2(4) . . . . ?
C47 Rh4 N7 C56 -28.5(7) . . . . ?
C48 Rh4 N7 C56 -114.4(5) . . . . ?
O6 Rh4 N7 C56 143.8(4) . . . . ?
C42 Rh4 N7 C56 114.4(4) . . . . ?
N1 Rh1 N8 C56 -91.5(6) . . . . ?
C3 Rh1 N8 C56 107.6(6) . . . . ?
C4 Rh1 N8 C56 82.8(13) . . . . ?
C2 Rh1 N8 C56 76.1(7) . . . . ?
C1 Rh1 N8 C56 35.7(7) . . . . ?
C5 Rh1 N8 C56 9.3(8) . . . . ?
O8 Rh1 N8 C56 177.1(7) . . . . ?
N1 Rh1 N8 C57 95.9(3) . . . . ?
C3 Rh1 N8 C57 -65.0(4) . . . . ?
C4 Rh1 N8 C57 -89.9(11) . . . . ?
C2 Rh1 N8 C57 -96.6(4) . . . . ?
C1 Rh1 N8 C57 -136.9(3) . . . . ?
C5 Rh1 N8 C57 -163.3(3) . . . . ?
O8 Rh1 N8 C57 4.4(3) . . . . ?
Dy1 O10 N9 O9 3.7(14) . . . . ?
Dy1 O10 N9 O11 -177.7(7) . . . . ?
Dy1 O9 N9 O10 -3.7(14) . . . . ?
Dy1 O9 N9 O11 177.9(8) . . . . ?
O1 Dy1 N9 O10 -28.7(11) . . . . ?
O3 Dy1 N9 O10 -117.2(11) . . . . ?
O7 Dy1 N9 O10 59.3(11) . . . . ?
O12 Dy1 N9 O10 -10(5) . . . . ?
O5 Dy1 N9 O10 152.2(11) . . . . ?
O9 Dy1 N9 O10 175.6(17) . . . . ?
O1 Dy1 N9 O9 155.7(12) . . . . ?
O3 Dy1 N9 O9 67.1(12) . . . . ?
O7 Dy1 N9 O9 -116.4(12) . . . . ?
O12 Dy1 N9 O9 175(5) . . . . ?
O5 Dy1 N9 O9 -23.5(12) . . . . ?
O10 Dy1 N9 O9 -175.6(17) . . . . ?
O1 Dy1 N9 O11 8(10) . . . . ?
O3 Dy1 N9 O11 -80(10) . . . . ?
O7 Dy1 N9 O11 96(10) . . . . ?
O12 Dy1 N9 O11 27(13) . . . . ?
O5 Dy1 N9 O11 -171(10) . . . . ?
O9 Dy1 N9 O11 -147(10) . . . . ?
O10 Dy1 N9 O11 37(10) . . . . ?
Dy1 O12 N10 O14 -162.3(13) . . . . ?
Dy1 O12 N10 O13 17.7(18) . . . . ?
N1 Rh1 C1 C5 -48.8(4) . . . . ?
C3 Rh1 C1 C5 80.3(4) . . . . ?
C4 Rh1 C1 C5 36.9(4) . . . . ?
C2 Rh1 C1 C5 118.3(5) . . . . ?
N8 Rh1 C1 C5 -152.5(3) . . . . ?
O8 Rh1 C1 C5 145.3(3) . . . . ?
N1 Rh1 C1 C2 -167.1(3) . . . . ?
C3 Rh1 C1 C2 -38.0(4) . . . . ?
C4 Rh1 C1 C2 -81.4(4) . . . . ?
N8 Rh1 C1 C2 89.2(4) . . . . ?
C5 Rh1 C1 C2 -118.3(5) . . . . ?
O8 Rh1 C1 C2 27.0(5) . . . . ?
N1 Rh1 C1 C6 72.4(7) . . . . ?
C3 Rh1 C1 C6 -158.5(7) . . . . ?
C4 Rh1 C1 C6 158.2(7) . . . . ?
C2 Rh1 C1 C6 -120.5(8) . . . . ?
N8 Rh1 C1 C6 -31.2(7) . . . . ?
C5 Rh1 C1 C6 121.2(8) . . . . ?
O8 Rh1 C1 C6 -93.5(7) . . . . ?
C5 C1 C2 C3 -0.1(7) . . . . ?
C6 C1 C2 C3 -177.8(6) . . . . ?
Rh1 C1 C2 C3 60.9(4) . . . . ?
C5 C1 C2 C7 176.9(6) . . . . ?
C6 C1 C2 C7 -0.8(10) . . . . ?
Rh1 C1 C2 C7 -122.1(6) . . . . ?
C5 C1 C2 Rh1 -61.0(4) . . . . ?
C6 C1 C2 Rh1 121.3(6) . . . . ?
N1 Rh1 C2 C3 -82.1(8) . . . . ?
C4 Rh1 C2 C3 -37.6(4) . . . . ?
N8 Rh1 C2 C3 140.9(3) . . . . ?
C1 Rh1 C2 C3 -117.6(5) . . . . ?
C5 Rh1 C2 C3 -80.3(4) . . . . ?
O8 Rh1 C2 C3 79.1(4) . . . . ?
N1 Rh1 C2 C1 35.5(9) . . . . ?
C3 Rh1 C2 C1 117.6(5) . . . . ?
C4 Rh1 C2 C1 80.0(4) . . . . ?
N8 Rh1 C2 C1 -101.5(4) . . . . ?
C5 Rh1 C2 C1 37.3(4) . . . . ?
O8 Rh1 C2 C1 -163.3(3) . . . . ?
N1 Rh1 C2 C7 158.1(6) . . . . ?
C3 Rh1 C2 C7 -119.8(8) . . . . ?
C4 Rh1 C2 C7 -157.4(7) . . . . ?
N8 Rh1 C2 C7 21.1(6) . . . . ?
C1 Rh1 C2 C7 122.6(8) . . . . ?
C5 Rh1 C2 C7 159.9(7) . . . . ?
O8 Rh1 C2 C7 -40.7(6) . . . . ?
C1 C2 C3 C4 -0.8(7) . . . . ?
C7 C2 C3 C4 -177.8(6) . . . . ?
Rh1 C2 C3 C4 60.5(4) . . . . ?
C1 C2 C3 C8 -178.3(6) . . . . ?
C7 C2 C3 C8 4.6(10) . . . . ?
Rh1 C2 C3 C8 -117.0(6) . . . . ?
C1 C2 C3 Rh1 -61.3(4) . . . . ?
C7 C2 C3 Rh1 121.7(6) . . . . ?
N1 Rh1 C3 C2 153.8(4) . . . . ?
C4 Rh1 C3 C2 118.4(5) . . . . ?
N8 Rh1 C3 C2 -53.8(4) . . . . ?
C1 Rh1 C3 C2 38.0(4) . . . . ?
C5 Rh1 C3 C2 80.9(4) . . . . ?
O8 Rh1 C3 C2 -108.2(4) . . . . ?
N1 Rh1 C3 C4 35.4(5) . . . . ?
C2 Rh1 C3 C4 -118.4(5) . . . . ?
N8 Rh1 C3 C4 -172.3(3) . . . . ?
C1 Rh1 C3 C4 -80.4(4) . . . . ?
C5 Rh1 C3 C4 -37.6(4) . . . . ?
O8 Rh1 C3 C4 133.3(4) . . . . ?
N1 Rh1 C3 C8 -86.1(7) . . . . ?
C4 Rh1 C3 C8 -121.4(8) . . . . ?
C2 Rh1 C3 C8 120.1(7) . . . . ?
N8 Rh1 C3 C8 66.3(7) . . . . ?
C1 Rh1 C3 C8 158.2(7) . . . . ?
C5 Rh1 C3 C8 -159.0(7) . . . . ?
O8 Rh1 C3 C8 11.9(6) . . . . ?
C2 C3 C4 C5 1.4(7) . . . . ?
C8 C3 C4 C5 178.8(6) . . . . ?
Rh1 C3 C4 C5 62.1(4) . . . . ?
C2 C3 C4 C9 178.5(6) . . . . ?
C8 C3 C4 C9 -4.0(10) . . . . ?
Rh1 C3 C4 C9 -120.7(7) . . . . ?
C2 C3 C4 Rh1 -60.7(4) . . . . ?
C8 C3 C4 Rh1 116.7(7) . . . . ?
N1 Rh1 C4 C5 86.8(4) . . . . ?
C3 Rh1 C4 C5 -117.8(5) . . . . ?
C2 Rh1 C4 C5 -80.2(4) . . . . ?
N8 Rh1 C4 C5 -87.4(11) . . . . ?
C1 Rh1 C4 C5 -37.0(4) . . . . ?
O8 Rh1 C4 C5 -174.9(3) . . . . ?
N1 Rh1 C4 C3 -155.4(4) . . . . ?
C2 Rh1 C4 C3 37.6(4) . . . . ?
N8 Rh1 C4 C3 30.4(13) . . . . ?
C1 Rh1 C4 C3 80.8(4) . . . . ?
C5 Rh1 C4 C3 117.8(5) . . . . ?
O8 Rh1 C4 C3 -57.1(4) . . . . ?
N1 Rh1 C4 C9 -33.8(7) . . . . ?
C3 Rh1 C4 C9 121.6(8) . . . . ?
C2 Rh1 C4 C9 159.1(7) . . . . ?
N8 Rh1 C4 C9 152.0(9) . . . . ?
C1 Rh1 C4 C9 -157.6(7) . . . . ?
C5 Rh1 C4 C9 -120.6(8) . . . . ?
O8 Rh1 C4 C9 64.5(7) . . . . ?
C3 C4 C5 C1 -1.4(7) . . . . ?
C9 C4 C5 C1 -178.6(6) . . . . ?
Rh1 C4 C5 C1 60.0(4) . . . . ?
C3 C4 C5 C10 176.9(6) . . . . ?
C9 C4 C5 C10 -0.3(10) . . . . ?
Rh1 C4 C5 C10 -121.7(6) . . . . ?
C3 C4 C5 Rh1 -61.4(4) . . . . ?
C9 C4 C5 Rh1 121.4(6) . . . . ?
C2 C1 C5 C4 0.9(7) . . . . ?
C6 C1 C5 C4 178.6(6) . . . . ?
Rh1 C1 C5 C4 -59.6(4) . . . . ?
C2 C1 C5 C10 -177.4(6) . . . . ?
C6 C1 C5 C10 0.3(10) . . . . ?
Rh1 C1 C5 C10 122.1(6) . . . . ?
C2 C1 C5 Rh1 60.5(4) . . . . ?
C6 C1 C5 Rh1 -121.8(6) . . . . ?
N1 Rh1 C5 C4 -99.2(4) . . . . ?
C3 Rh1 C5 C4 38.1(4) . . . . ?
C2 Rh1 C5 C4 81.4(4) . . . . ?
N8 Rh1 C5 C4 161.9(3) . . . . ?
C1 Rh1 C5 C4 119.2(5) . . . . ?
O8 Rh1 C5 C4 12.3(8) . . . . ?
N1 Rh1 C5 C1 141.7(4) . . . . ?
C3 Rh1 C5 C1 -81.1(4) . . . . ?
C4 Rh1 C5 C1 -119.2(5) . . . . ?
C2 Rh1 C5 C1 -37.7(4) . . . . ?
N8 Rh1 C5 C1 42.7(5) . . . . ?
O8 Rh1 C5 C1 -106.9(6) . . . . ?
N1 Rh1 C5 C10 21.8(7) . . . . ?
C3 Rh1 C5 C10 159.1(7) . . . . ?
C4 Rh1 C5 C10 121.0(8) . . . . ?
C2 Rh1 C5 C10 -157.6(7) . . . . ?
N8 Rh1 C5 C10 -77.1(7) . . . . ?
C1 Rh1 C5 C10 -119.8(8) . . . . ?
O8 Rh1 C5 C10 133.3(6) . . . . ?
Dy1 O1 C11 N2 75.0(7) . . . . ?
Dy1 O1 C11 N1 -106.5(6) . . . . ?
C12 N2 C11 O1 -175.8(5) . . . . ?
Rh2 N2 C11 O1 0.2(9) . . . . ?
C12 N2 C11 N1 5.7(8) . . . . ?
Rh2 N2 C11 N1 -178.3(4) . . . . ?
C14 N1 C11 O1 179.7(5) . . . . ?
Rh1 N1 C11 O1 -13.8(7) . . . . ?
C14 N1 C11 N2 -1.7(8) . . . . ?
Rh1 N1 C11 N2 164.7(4) . . . . ?
Rh2 O2 C12 N2 3.4(5) . . . . ?
Rh2 O2 C12 C13 -175.5(6) . . . . ?
C11 N2 C12 O2 174.1(5) . . . . ?
Rh2 N2 C12 O2 -3.5(5) . . . . ?
C11 N2 C12 C13 -6.8(8) . . . . ?
Rh2 N2 C12 C13 175.5(5) . . . . ?
O2 C12 C13 C14 -177.3(6) . . . . ?
N2 C12 C13 C14 3.8(8) . . . . ?
O2 C12 C13 C15 3.2(10) . . . . ?
N2 C12 C13 C15 -175.6(6) . . . . ?
C11 N1 C14 C13 -1.2(9) . . . . ?
Rh1 N1 C14 C13 -167.9(5) . . . . ?
C12 C13 C14 N1 0.1(9) . . . . ?
C15 C13 C14 N1 179.6(6) . . . . ?
N3 Rh2 C16 C17 -163.0(3) . . . . ?
C18 Rh2 C16 C17 -38.9(4) . . . . ?
N2 Rh2 C16 C17 95.8(4) . . . . ?
C19 Rh2 C16 C17 -82.2(4) . . . . ?
C20 Rh2 C16 C17 -119.5(5) . . . . ?
O2 Rh2 C16 C17 32.9(5) . . . . ?
N3 Rh2 C16 C20 -43.5(5) . . . . ?
C18 Rh2 C16 C20 80.6(4) . . . . ?
C17 Rh2 C16 C20 119.5(5) . . . . ?
N2 Rh2 C16 C20 -144.7(3) . . . . ?
C19 Rh2 C16 C20 37.3(3) . . . . ?
O2 Rh2 C16 C20 152.3(3) . . . . ?
N3 Rh2 C16 C21 77.1(6) . . . . ?
C18 Rh2 C16 C21 -158.7(6) . . . . ?
C17 Rh2 C16 C21 -119.9(7) . . . . ?
N2 Rh2 C16 C21 -24.1(6) . . . . ?
C19 Rh2 C16 C21 157.9(6) . . . . ?
C20 Rh2 C16 C21 120.7(7) . . . . ?
O2 Rh2 C16 C21 -87.0(6) . . . . ?
C20 C16 C17 C18 0.5(6) . . . . ?
C21 C16 C17 C18 179.3(5) . . . . ?
Rh2 C16 C17 C18 61.4(4) . . . . ?
C20 C16 C17 C22 179.9(6) . . . . ?
C21 C16 C17 C22 -1.3(10) . . . . ?
Rh2 C16 C17 C22 -119.3(6) . . . . ?
C20 C16 C17 Rh2 -60.8(4) . . . . ?
C21 C16 C17 Rh2 118.0(6) . . . . ?
N3 Rh2 C17 C16 64.6(11) . . . . ?
C18 Rh2 C17 C16 116.8(5) . . . . ?
N2 Rh2 C17 C16 -95.3(4) . . . . ?
C19 Rh2 C17 C16 79.9(4) . . . . ?
C20 Rh2 C17 C16 36.9(4) . . . . ?
O2 Rh2 C17 C16 -156.6(3) . . . . ?
N3 Rh2 C17 C18 -52.1(11) . . . . ?
N2 Rh2 C17 C18 147.9(3) . . . . ?
C19 Rh2 C17 C18 -36.9(3) . . . . ?
C16 Rh2 C17 C18 -116.8(5) . . . . ?
C20 Rh2 C17 C18 -79.9(4) . . . . ?
O2 Rh2 C17 C18 86.6(4) . . . . ?
N3 Rh2 C17 C22 -173.8(8) . . . . ?
C18 Rh2 C17 C22 -121.7(7) . . . . ?
N2 Rh2 C17 C22 26.2(6) . . . . ?
C19 Rh2 C17 C22 -158.6(6) . . . . ?
C16 Rh2 C17 C22 121.6(7) . . . . ?
C20 Rh2 C17 C22 158.4(6) . . . . ?
O2 Rh2 C17 C22 -35.0(6) . . . . ?
C16 C17 C18 C19 -1.5(6) . . . . ?
C22 C17 C18 C19 179.2(6) . . . . ?
Rh2 C17 C18 C19 60.9(4) . . . . ?
C16 C17 C18 C23 -176.7(6) . . . . ?
C22 C17 C18 C23 3.9(10) . . . . ?
Rh2 C17 C18 C23 -114.3(6) . . . . ?
C16 C17 C18 Rh2 -62.4(4) . . . . ?
C22 C17 C18 Rh2 118.3(6) . . . . ?
N3 Rh2 C18 C19 46.4(5) . . . . ?
C17 Rh2 C18 C19 -119.5(5) . . . . ?
N2 Rh2 C18 C19 -167.7(3) . . . . ?
C16 Rh2 C18 C19 -81.3(4) . . . . ?
C20 Rh2 C18 C19 -38.2(3) . . . . ?
O2 Rh2 C18 C19 142.3(3) . . . . ?
N3 Rh2 C18 C17 165.9(3) . . . . ?
N2 Rh2 C18 C17 -48.2(5) . . . . ?
C19 Rh2 C18 C17 119.5(5) . . . . ?
C16 Rh2 C18 C17 38.2(4) . . . . ?
C20 Rh2 C18 C17 81.2(4) . . . . ?
O2 Rh2 C18 C17 -98.2(4) . . . . ?
N3 Rh2 C18 C23 -73.4(6) . . . . ?
C17 Rh2 C18 C23 120.7(7) . . . . ?
N2 Rh2 C18 C23 72.5(6) . . . . ?
C19 Rh2 C18 C23 -119.9(7) . . . . ?
C16 Rh2 C18 C23 158.9(6) . . . . ?
C20 Rh2 C18 C23 -158.1(6) . . . . ?
O2 Rh2 C18 C23 22.4(5) . . . . ?
C17 C18 C19 C20 1.8(6) . . . . ?
C23 C18 C19 C20 177.1(6) . . . . ?
Rh2 C18 C19 C20 62.1(4) . . . . ?
C17 C18 C19 C24 -179.3(6) . . . . ?
C23 C18 C19 C24 -4.0(10) . . . . ?
Rh2 C18 C19 C24 -119.0(6) . . . . ?
C17 C18 C19 Rh2 -60.3(4) . . . . ?
C23 C18 C19 Rh2 115.1(6) . . . . ?
N3 Rh2 C19 C18 -146.2(4) . . . . ?
C17 Rh2 C19 C18 37.3(4) . . . . ?
N2 Rh2 C19 C18 67.9(14) . . . . ?
C16 Rh2 C19 C18 80.1(4) . . . . ?
C20 Rh2 C19 C18 117.2(5) . . . . ?
O2 Rh2 C19 C18 -47.5(4) . . . . ?
N3 Rh2 C19 C20 96.6(3) . . . . ?
C18 Rh2 C19 C20 -117.2(5) . . . . ?
C17 Rh2 C19 C20 -79.9(4) . . . . ?
N2 Rh2 C19 C20 -49.3(14) . . . . ?
C16 Rh2 C19 C20 -37.1(3) . . . . ?
O2 Rh2 C19 C20 -164.7(3) . . . . ?
N3 Rh2 C19 C24 -24.0(6) . . . . ?
C18 Rh2 C19 C24 122.2(7) . . . . ?
C17 Rh2 C19 C24 159.6(6) . . . . ?
N2 Rh2 C19 C24 -169.9(11) . . . . ?
C16 Rh2 C19 C24 -157.6(6) . . . . ?
C20 Rh2 C19 C24 -120.6(7) . . . . ?
O2 Rh2 C19 C24 74.8(6) . . . . ?
C17 C16 C20 C19 0.6(6) . . . . ?
C21 C16 C20 C19 -178.2(5) . . . . ?
Rh2 C16 C20 C19 -58.9(4) . . . . ?
C17 C16 C20 C25 -173.8(6) . . . . ?
C21 C16 C20 C25 7.4(9) . . . . ?
Rh2 C16 C20 C25 126.8(6) . . . . ?
C17 C16 C20 Rh2 59.5(4) . . . . ?
C21 C16 C20 Rh2 -119.3(6) . . . . ?
C18 C19 C20 C16 -1.5(6) . . . . ?
C24 C19 C20 C16 179.6(5) . . . . ?
Rh2 C19 C20 C16 59.1(4) . . . . ?
C18 C19 C20 C25 172.9(6) . . . . ?
C24 C19 C20 C25 -6.0(9) . . . . ?
Rh2 C19 C20 C25 -126.5(6) . . . . ?
C18 C19 C20 Rh2 -60.6(4) . . . . ?
C24 C19 C20 Rh2 120.5(6) . . . . ?
N3 Rh2 C20 C16 149.5(3) . . . . ?
C18 Rh2 C20 C16 -80.8(4) . . . . ?
C17 Rh2 C20 C16 -36.9(3) . . . . ?
N2 Rh2 C20 C16 51.3(4) . . . . ?
C19 Rh2 C20 C16 -119.0(5) . . . . ?
O2 Rh2 C20 C16 -79.3(7) . . . . ?
N3 Rh2 C20 C19 -91.5(3) . . . . ?
C18 Rh2 C20 C19 38.3(3) . . . . ?
C17 Rh2 C20 C19 82.1(4) . . . . ?
N2 Rh2 C20 C19 170.3(3) . . . . ?
C16 Rh2 C20 C19 119.0(5) . . . . ?
O2 Rh2 C20 C19 39.8(8) . . . . ?
N3 Rh2 C20 C25 28.5(7) . . . . ?
C18 Rh2 C20 C25 158.2(7) . . . . ?
C17 Rh2 C20 C25 -157.9(7) . . . . ?
N2 Rh2 C20 C25 -69.7(7) . . . . ?
C19 Rh2 C20 C25 120.0(8) . . . . ?
C16 Rh2 C20 C25 -121.0(8) . . . . ?
O2 Rh2 C20 C25 159.7(6) . . . . ?
Dy1 O3 C26 N3 -108.4(5) . . . . ?
Dy1 O3 C26 N4 70.1(7) . . . . ?
C29 N3 C26 O3 172.3(5) . . . . ?
Rh2 N3 C26 O3 -8.8(7) . . . . ?
C29 N3 C26 N4 -6.2(8) . . . . ?
Rh2 N3 C26 N4 172.7(4) . . . . ?
C27 N4 C26 O3 -171.4(5) . . . . ?
Rh3 N4 C26 O3 25.1(9) . . . . ?
C27 N4 C26 N3 7.1(8) . . . . ?
Rh3 N4 C26 N3 -156.5(5) . . . . ?
Rh3 O4 C27 N4 8.0(5) . . . . ?
Rh3 O4 C27 C28 -167.8(6) . . . . ?
C26 N4 C27 O4 -178.4(5) . . . . ?
Rh3 N4 C27 O4 -8.4(5) . . . . ?
C26 N4 C27 C28 -2.2(9) . . . . ?
Rh3 N4 C27 C28 167.8(5) . . . . ?
C26 N4 C27 Rh3 -170.0(6) . . . . ?
N5 Rh3 C27 O4 85.8(4) . . . . ?
N4 Rh3 C27 O4 170.7(6) . . . . ?
C31 Rh3 C27 O4 -137.4(4) . . . . ?
C34 Rh3 C27 O4 -37.0(5) . . . . ?
C32 Rh3 C27 O4 -105.0(4) . . . . ?
C33 Rh3 C27 O4 -64.6(4) . . . . ?
C35 Rh3 C27 O4 -116.5(10) . . . . ?
N5 Rh3 C27 N4 -84.9(4) . . . . ?
C31 Rh3 C27 N4 51.9(5) . . . . ?
C34 Rh3 C27 N4 152.3(4) . . . . ?
C32 Rh3 C27 N4 84.4(4) . . . . ?
C33 Rh3 C27 N4 124.7(4) . . . . ?
C35 Rh3 C27 N4 72.8(11) . . . . ?
O4 Rh3 C27 N4 -170.7(6) . . . . ?
N5 Rh3 C27 C28 -148(2) . . . . ?
N4 Rh3 C27 C28 -63(2) . . . . ?
C31 Rh3 C27 C28 -11(2) . . . . ?
C34 Rh3 C27 C28 89(2) . . . . ?
C32 Rh3 C27 C28 21(2) . . . . ?
C33 Rh3 C27 C28 61(2) . . . . ?
C35 Rh3 C27 C28 10(3) . . . . ?
O4 Rh3 C27 C28 126(2) . . . . ?
O4 C27 C28 C29 172.4(6) . . . . ?
N4 C27 C28 C29 -3.1(9) . . . . ?
Rh3 C27 C28 C29 53(2) . . . . ?
O4 C27 C28 C30 -6.2(12) . . . . ?
N4 C27 C28 C30 178.2(7) . . . . ?
Rh3 C27 C28 C30 -125(2) . . . . ?
C26 N3 C29 C28 0.7(10) . . . . ?
Rh2 N3 C29 C28 -178.3(5) . . . . ?
C27 C28 C29 N3 3.9(10) . . . . ?
C30 C28 C29 N3 -177.4(8) . . . . ?
N5 Rh3 C31 C35 -59.4(4) . . . . ?
N4 Rh3 C31 C35 -161.5(4) . . . . ?
C34 Rh3 C31 C35 37.0(4) . . . . ?
C32 Rh3 C31 C35 118.4(5) . . . . ?
C33 Rh3 C31 C35 80.6(4) . . . . ?
O4 Rh3 C31 C35 135.3(4) . . . . ?
C27 Rh3 C31 C35 173.2(3) . . . . ?
N5 Rh3 C31 C32 -177.8(3) . . . . ?
N4 Rh3 C31 C32 80.1(4) . . . . ?
C34 Rh3 C31 C32 -81.4(4) . . . . ?
C33 Rh3 C31 C32 -37.8(3) . . . . ?
C35 Rh3 C31 C32 -118.4(5) . . . . ?
O4 Rh3 C31 C32 16.8(6) . . . . ?
C27 Rh3 C31 C32 54.7(4) . . . . ?
N5 Rh3 C31 C36 64.7(7) . . . . ?
N4 Rh3 C31 C36 -37.4(7) . . . . ?
C34 Rh3 C31 C36 161.1(8) . . . . ?
C32 Rh3 C31 C36 -117.5(8) . . . . ?
C33 Rh3 C31 C36 -155.3(8) . . . . ?
C35 Rh3 C31 C36 124.1(8) . . . . ?
O4 Rh3 C31 C36 -100.6(7) . . . . ?
C27 Rh3 C31 C36 -62.7(8) . . . . ?
C35 C31 C32 C33 -0.3(7) . . . . ?
C36 C31 C32 C33 -178.0(6) . . . . ?
Rh3 C31 C32 C33 61.0(4) . . . . ?
C35 C31 C32 C37 177.6(6) . . . . ?
C36 C31 C32 C37 -0.1(10) . . . . ?
Rh3 C31 C32 C37 -121.1(7) . . . . ?
C35 C31 C32 Rh3 -61.3(4) . . . . ?
C36 C31 C32 Rh3 121.0(6) . . . . ?
N5 Rh3 C32 C33 -111.9(6) . . . . ?
N4 Rh3 C32 C33 133.0(4) . . . . ?
C31 Rh3 C32 C33 -117.6(5) . . . . ?
C34 Rh3 C32 C33 -37.7(4) . . . . ?
C35 Rh3 C32 C33 -80.8(4) . . . . ?
O4 Rh3 C32 C33 71.9(4) . . . . ?
C27 Rh3 C32 C33 101.8(4) . . . . ?
N5 Rh3 C32 C31 5.6(8) . . . . ?
N4 Rh3 C32 C31 -109.4(4) . . . . ?
C34 Rh3 C32 C31 79.9(4) . . . . ?
C33 Rh3 C32 C31 117.6(5) . . . . ?
C35 Rh3 C32 C31 36.8(4) . . . . ?
O4 Rh3 C32 C31 -170.5(3) . . . . ?
C27 Rh3 C32 C31 -140.6(3) . . . . ?
N5 Rh3 C32 C37 126.8(7) . . . . ?
N4 Rh3 C32 C37 11.7(6) . . . . ?
C31 Rh3 C32 C37 121.1(7) . . . . ?
C34 Rh3 C32 C37 -159.0(7) . . . . ?
C33 Rh3 C32 C37 -121.3(8) . . . . ?
C35 Rh3 C32 C37 157.9(7) . . . . ?
O4 Rh3 C32 C37 -49.4(6) . . . . ?
C27 Rh3 C32 C37 -19.5(6) . . . . ?
C31 C32 C33 C34 -0.5(7) . . . . ?
C37 C32 C33 C34 -178.5(6) . . . . ?
Rh3 C32 C33 C34 60.0(4) . . . . ?
C31 C32 C33 C38 -178.5(6) . . . . ?
C37 C32 C33 C38 3.6(11) . . . . ?
Rh3 C32 C33 C38 -117.9(7) . . . . ?
C31 C32 C33 Rh3 -60.6(4) . . . . ?
C37 C32 C33 Rh3 121.5(7) . . . . ?
N5 Rh3 C33 C32 148.1(4) . . . . ?
N4 Rh3 C33 C32 -59.0(5) . . . . ?
C31 Rh3 C33 C32 38.5(4) . . . . ?
C34 Rh3 C33 C32 118.8(6) . . . . ?
C35 Rh3 C33 C32 80.7(4) . . . . ?
O4 Rh3 C33 C32 -115.4(4) . . . . ?
C27 Rh3 C33 C32 -89.1(4) . . . . ?
N5 Rh3 C33 C34 29.3(6) . . . . ?
N4 Rh3 C33 C34 -177.7(3) . . . . ?
C31 Rh3 C33 C34 -80.3(4) . . . . ?
C32 Rh3 C33 C34 -118.8(6) . . . . ?
C35 Rh3 C33 C34 -38.1(4) . . . . ?
O4 Rh3 C33 C34 125.8(4) . . . . ?
C27 Rh3 C33 C34 152.2(3) . . . . ?
N5 Rh3 C33 C38 -90.7(6) . . . . ?
N4 Rh3 C33 C38 62.2(6) . . . . ?
C31 Rh3 C33 C38 159.6(6) . . . . ?
C34 Rh3 C33 C38 -120.0(7) . . . . ?
C32 Rh3 C33 C38 121.2(7) . . . . ?
C35 Rh3 C33 C38 -158.2(6) . . . . ?
O4 Rh3 C33 C38 5.8(5) . . . . ?
C27 Rh3 C33 C38 32.1(6) . . . . ?
C32 C33 C34 C35 1.2(7) . . . . ?
C38 C33 C34 C35 179.1(6) . . . . ?
Rh3 C33 C34 C35 61.4(4) . . . . ?
C32 C33 C34 C39 176.9(6) . . . . ?
C38 C33 C34 C39 -5.2(10) . . . . ?
Rh3 C33 C34 C39 -122.9(6) . . . . ?
C32 C33 C34 Rh3 -60.3(4) . . . . ?
C38 C33 C34 Rh3 117.7(7) . . . . ?
N5 Rh3 C34 C35 80.3(4) . . . . ?
N4 Rh3 C34 C35 -111.1(8) . . . . ?
C31 Rh3 C34 C35 -36.2(4) . . . . ?
C32 Rh3 C34 C35 -80.0(4) . . . . ?
C33 Rh3 C34 C35 -117.2(5) . . . . ?
O4 Rh3 C34 C35 179.8(3) . . . . ?
C27 Rh3 C34 C35 -161.3(4) . . . . ?
N5 Rh3 C34 C33 -162.5(3) . . . . ?
N4 Rh3 C34 C33 6.1(9) . . . . ?
C31 Rh3 C34 C33 81.0(4) . . . . ?
C32 Rh3 C34 C33 37.2(4) . . . . ?
C35 Rh3 C34 C33 117.2(5) . . . . ?
O4 Rh3 C34 C33 -63.0(4) . . . . ?
C27 Rh3 C34 C33 -44.0(5) . . . . ?
N5 Rh3 C34 C39 -43.4(7) . . . . ?
N4 Rh3 C34 C39 125.2(8) . . . . ?
C31 Rh3 C34 C39 -159.9(7) . . . . ?
C32 Rh3 C34 C39 156.3(7) . . . . ?
C33 Rh3 C34 C39 119.1(8) . . . . ?
C35 Rh3 C34 C39 -123.7(8) . . . . ?
O4 Rh3 C34 C39 56.1(7) . . . . ?
C27 Rh3 C34 C39 75.0(7) . . . . ?
C32 C31 C35 C34 1.1(7) . . . . ?
C36 C31 C35 C34 178.6(6) . . . . ?
Rh3 C31 C35 C34 -59.7(4) . . . . ?
C32 C31 C35 C40 -178.6(6) . . . . ?
C36 C31 C35 C40 -1.1(10) . . . . ?
Rh3 C31 C35 C40 120.6(6) . . . . ?
C32 C31 C35 Rh3 60.7(4) . . . . ?
C36 C31 C35 Rh3 -121.7(7) . . . . ?
C33 C34 C35 C31 -1.4(7) . . . . ?
C39 C34 C35 C31 -176.9(6) . . . . ?
Rh3 C34 C35 C31 59.9(4) . . . . ?
C33 C34 C35 C40 178.3(6) . . . . ?
C39 C34 C35 C40 2.8(10) . . . . ?
Rh3 C34 C35 C40 -120.4(6) . . . . ?
C33 C34 C35 Rh3 -61.3(4) . . . . ?
C39 C34 C35 Rh3 123.2(7) . . . . ?
N5 Rh3 C35 C31 131.7(4) . . . . ?
N4 Rh3 C35 C31 30.7(6) . . . . ?
C34 Rh3 C35 C31 -119.8(5) . . . . ?
C32 Rh3 C35 C31 -38.2(4) . . . . ?
C33 Rh3 C35 C31 -81.4(4) . . . . ?
O4 Rh3 C35 C31 -120.3(5) . . . . ?
C27 Rh3 C35 C31 -25.9(12) . . . . ?
N5 Rh3 C35 C34 -108.4(4) . . . . ?
N4 Rh3 C35 C34 150.5(4) . . . . ?
C31 Rh3 C35 C34 119.8(5) . . . . ?
C32 Rh3 C35 C34 81.6(4) . . . . ?
C33 Rh3 C35 C34 38.5(3) . . . . ?
O4 Rh3 C35 C34 -0.4(7) . . . . ?
C27 Rh3 C35 C34 94.0(11) . . . . ?
N5 Rh3 C35 C40 11.5(7) . . . . ?
N4 Rh3 C35 C40 -89.6(7) . . . . ?
C31 Rh3 C35 C40 -120.2(8) . . . . ?
C34 Rh3 C35 C40 119.9(8) . . . . ?
C32 Rh3 C35 C40 -158.5(7) . . . . ?
C33 Rh3 C35 C40 158.4(7) . . . . ?
O4 Rh3 C35 C40 119.5(7) . . . . ?
C27 Rh3 C35 C40 -146.1(9) . . . . ?
Dy1 O5 C41 N6 76.6(6) . . . . ?
Dy1 O5 C41 N5 -104.2(5) . . . . ?
C42 N6 C41 O5 -175.9(5) . . . . ?
Rh4 N6 C41 O5 0.9(9) . . . . ?
C42 N6 C41 N5 4.9(8) . . . . ?
Rh4 N6 C41 N5 -178.3(4) . . . . ?
C44 N5 C41 O5 178.0(5) . . . . ?
Rh3 N5 C41 O5 -6.2(7) . . . . ?
C44 N5 C41 N6 -2.8(8) . . . . ?
Rh3 N5 C41 N6 173.0(4) . . . . ?
Rh4 O6 C42 N6 1.7(4) . . . . ?
Rh4 O6 C42 C43 -177.5(5) . . . . ?
C41 N6 C42 O6 176.3(5) . . . . ?
Rh4 N6 C42 O6 -1.8(4) . . . . ?
C41 N6 C42 C43 -4.4(8) . . . . ?
Rh4 N6 C42 C43 177.5(4) . . . . ?
C41 N6 C42 Rh4 178.1(6) . . . . ?
N7 Rh4 C42 O6 89.9(3) . . . . ?
C49 Rh4 C42 O6 -30.6(4) . . . . ?
N6 Rh4 C42 O6 178.0(5) . . . . ?
C46 Rh4 C42 O6 -140.6(4) . . . . ?
C50 Rh4 C42 O6 -34.1(19) . . . . ?
C47 Rh4 C42 O6 -108.3(3) . . . . ?
C48 Rh4 C42 O6 -67.3(4) . . . . ?
N7 Rh4 C42 N6 -88.1(3) . . . . ?
C49 Rh4 C42 N6 151.4(3) . . . . ?
C46 Rh4 C42 N6 41.4(5) . . . . ?
C50 Rh4 C42 N6 147.9(17) . . . . ?
C47 Rh4 C42 N6 73.7(4) . . . . ?
C48 Rh4 C42 N6 114.7(3) . . . . ?
O6 Rh4 C42 N6 -178.0(5) . . . . ?
N7 Rh4 C42 C43 -111(4) . . . . ?
C49 Rh4 C42 C43 129(4) . . . . ?
N6 Rh4 C42 C43 -23(4) . . . . ?
C46 Rh4 C42 C43 19(4) . . . . ?
C50 Rh4 C42 C43 125(4) . . . . ?
C47 Rh4 C42 C43 51(4) . . . . ?
C48 Rh4 C42 C43 92(4) . . . . ?
O6 Rh4 C42 C43 159(4) . . . . ?
O6 C42 C43 C44 -179.1(5) . . . . ?
N6 C42 C43 C44 1.7(7) . . . . ?
Rh4 C42 C43 C44 23(4) . . . . ?
O6 C42 C43 C45 4.2(9) . . . . ?
N6 C42 C43 C45 -175.0(5) . . . . ?
Rh4 C42 C43 C45 -154(4) . . . . ?
C41 N5 C44 C43 0.3(8) . . . . ?
Rh3 N5 C44 C43 -175.8(4) . . . . ?
C42 C43 C44 N5 0.2(8) . . . . ?
C45 C43 C44 N5 176.9(5) . . . . ?
N7 Rh4 C46 C47 174.8(3) . . . . ?
C49 Rh4 C46 C47 -80.6(4) . . . . ?
N6 Rh4 C46 C47 74.3(4) . . . . ?
C50 Rh4 C46 C47 -117.9(5) . . . . ?
C48 Rh4 C46 C47 -37.0(4) . . . . ?
O6 Rh4 C46 C47 -2.6(8) . . . . ?
C42 Rh4 C46 C47 51.9(5) . . . . ?
N7 Rh4 C46 C50 -67.3(4) . . . . ?
C49 Rh4 C46 C50 37.3(3) . . . . ?
N6 Rh4 C46 C50 -167.8(3) . . . . ?
C47 Rh4 C46 C50 117.9(5) . . . . ?
C48 Rh4 C46 C50 80.9(4) . . . . ?
O6 Rh4 C46 C50 115.4(6) . . . . ?
C42 Rh4 C46 C50 169.8(3) . . . . ?
N7 Rh4 C46 C51 54.1(8) . . . . ?
C49 Rh4 C46 C51 158.7(8) . . . . ?
N6 Rh4 C46 C51 -46.5(8) . . . . ?
C50 Rh4 C46 C51 121.4(8) . . . . ?
C47 Rh4 C46 C51 -120.7(9) . . . . ?
C48 Rh4 C46 C51 -157.8(8) . . . . ?
O6 Rh4 C46 C51 -123.3(7) . . . . ?
C42 Rh4 C46 C51 -68.9(8) . . . . ?
C50 C46 C47 C48 0.1(7) . . . . ?
C51 C46 C47 C48 -173.0(6) . . . . ?
Rh4 C46 C47 C48 61.0(4) . . . . ?
C50 C46 C47 C52 -179.6(6) . . . . ?
C51 C46 C47 C52 7.2(10) . . . . ?
Rh4 C46 C47 C52 -118.7(6) . . . . ?
C50 C46 C47 Rh4 -60.9(4) . . . . ?
C51 C46 C47 Rh4 126.0(6) . . . . ?
N7 Rh4 C47 C48 -128.5(4) . . . . ?
C49 Rh4 C47 C48 -37.3(4) . . . . ?
N6 Rh4 C47 C48 122.7(4) . . . . ?
C46 Rh4 C47 C48 -118.6(5) . . . . ?
C50 Rh4 C47 C48 -80.4(4) . . . . ?
O6 Rh4 C47 C48 60.3(4) . . . . ?
C42 Rh4 C47 C48 92.4(4) . . . . ?
N7 Rh4 C47 C46 -10.0(7) . . . . ?
C49 Rh4 C47 C46 81.2(4) . . . . ?
N6 Rh4 C47 C46 -118.8(4) . . . . ?
C50 Rh4 C47 C46 38.1(4) . . . . ?
C48 Rh4 C47 C46 118.6(5) . . . . ?
O6 Rh4 C47 C46 178.9(3) . . . . ?
C42 Rh4 C47 C46 -149.1(3) . . . . ?
N7 Rh4 C47 C52 109.1(7) . . . . ?
C49 Rh4 C47 C52 -159.7(7) . . . . ?
N6 Rh4 C47 C52 0.3(7) . . . . ?
C46 Rh4 C47 C52 119.1(8) . . . . ?
C50 Rh4 C47 C52 157.2(7) . . . . ?
C48 Rh4 C47 C52 -122.4(8) . . . . ?
O6 Rh4 C47 C52 -62.0(7) . . . . ?
C42 Rh4 C47 C52 -30.0(7) . . . . ?
C46 C47 C48 C49 -1.7(7) . . . . ?
C52 C47 C48 C49 178.1(6) . . . . ?
Rh4 C47 C48 C49 58.8(4) . . . . ?
C46 C47 C48 C53 178.9(6) . . . . ?
C52 C47 C48 C53 -1.4(10) . . . . ?
Rh4 C47 C48 C53 -120.6(6) . . . . ?
C46 C47 C48 Rh4 -60.5(4) . . . . ?
C52 C47 C48 Rh4 119.2(7) . . . . ?
N7 Rh4 C48 C47 129.9(5) . . . . ?
C49 Rh4 C48 C47 119.6(5) . . . . ?
N6 Rh4 C48 C47 -70.6(4) . . . . ?
C46 Rh4 C48 C47 37.4(4) . . . . ?
C50 Rh4 C48 C47 81.1(4) . . . . ?
O6 Rh4 C48 C47 -130.0(4) . . . . ?
C42 Rh4 C48 C47 -102.9(4) . . . . ?
N7 Rh4 C48 C49 10.3(6) . . . . ?
N6 Rh4 C48 C49 169.8(3) . . . . ?
C46 Rh4 C48 C49 -82.1(4) . . . . ?
C50 Rh4 C48 C49 -38.4(4) . . . . ?
C47 Rh4 C48 C49 -119.6(5) . . . . ?
O6 Rh4 C48 C49 110.4(3) . . . . ?
C42 Rh4 C48 C49 137.5(3) . . . . ?
N7 Rh4 C48 C53 -108.7(7) . . . . ?
C49 Rh4 C48 C53 -119.0(8) . . . . ?
N6 Rh4 C48 C53 50.9(7) . . . . ?
C46 Rh4 C48 C53 158.9(7) . . . . ?
C50 Rh4 C48 C53 -157.4(7) . . . . ?
C47 Rh4 C48 C53 121.5(8) . . . . ?
O6 Rh4 C48 C53 -8.5(7) . . . . ?
C42 Rh4 C48 C53 18.5(7) . . . . ?
C47 C48 C49 C50 2.6(7) . . . . ?
C53 C48 C49 C50 -177.9(6) . . . . ?
Rh4 C48 C49 C50 62.5(4) . . . . ?
C47 C48 C49 C54 -179.3(6) . . . . ?
C53 C48 C49 C54 0.2(10) . . . . ?
Rh4 C48 C49 C54 -119.3(6) . . . . ?
C47 C48 C49 Rh4 -59.9(4) . . . . ?
C53 C48 C49 Rh4 119.5(6) . . . . ?
N7 Rh4 C49 C50 68.8(4) . . . . ?
N6 Rh4 C49 C50 -140.0(5) . . . . ?
C46 Rh4 C49 C50 -37.6(4) . . . . ?
C47 Rh4 C49 C50 -80.3(4) . . . . ?
C48 Rh4 C49 C50 -116.5(5) . . . . ?
O6 Rh4 C49 C50 165.5(3) . . . . ?
C42 Rh4 C49 C50 -179.3(3) . . . . ?
N7 Rh4 C49 C48 -174.6(3) . . . . ?
N6 Rh4 C49 C48 -23.4(7) . . . . ?
C46 Rh4 C49 C48 78.9(4) . . . . ?
C50 Rh4 C49 C48 116.5(5) . . . . ?
C47 Rh4 C49 C48 36.3(4) . . . . ?
O6 Rh4 C49 C48 -78.0(4) . . . . ?
C42 Rh4 C49 C48 -62.8(4) . . . . ?
N7 Rh4 C49 C54 -53.3(7) . . . . ?
N6 Rh4 C49 C54 97.9(8) . . . . ?
C46 Rh4 C49 C54 -159.7(7) . . . . ?
C50 Rh4 C49 C54 -122.1(8) . . . . ?
C47 Rh4 C49 C54 157.6(7) . . . . ?
C48 Rh4 C49 C54 121.4(7) . . . . ?
O6 Rh4 C49 C54 43.4(6) . . . . ?
C42 Rh4 C49 C54 58.6(7) . . . . ?
C48 C49 C50 C46 -2.5(6) . . . . ?
C54 C49 C50 C46 179.4(6) . . . . ?
Rh4 C49 C50 C46 60.3(4) . . . . ?
C48 C49 C50 C55 179.4(6) . . . . ?
C54 C49 C50 C55 1.3(10) . . . . ?
Rh4 C49 C50 C55 -117.8(7) . . . . ?
C48 C49 C50 Rh4 -62.8(4) . . . . ?
C54 C49 C50 Rh4 119.1(6) . . . . ?
C47 C46 C50 C49 1.5(7) . . . . ?
C51 C46 C50 C49 174.6(6) . . . . ?
Rh4 C46 C50 C49 -59.9(4) . . . . ?
C47 C46 C50 C55 179.6(6) . . . . ?
C51 C46 C50 C55 -7.3(10) . . . . ?
Rh4 C46 C50 C55 118.2(7) . . . . ?
C47 C46 C50 Rh4 61.5(4) . . . . ?
C51 C46 C50 Rh4 -125.5(6) . . . . ?
N7 Rh4 C50 C49 -119.7(4) . . . . ?
N6 Rh4 C50 C49 144.6(4) . . . . ?
C46 Rh4 C50 C49 118.6(5) . . . . ?
C47 Rh4 C50 C49 81.1(4) . . . . ?
C48 Rh4 C50 C49 38.8(4) . . . . ?
O6 Rh4 C50 C49 -24.5(5) . . . . ?
C42 Rh4 C50 C49 4(2) . . . . ?
N7 Rh4 C50 C46 121.7(3) . . . . ?
C49 Rh4 C50 C46 -118.6(5) . . . . ?
N6 Rh4 C50 C46 25.9(6) . . . . ?
C47 Rh4 C50 C46 -37.5(3) . . . . ?
C48 Rh4 C50 C46 -79.8(4) . . . . ?
O6 Rh4 C50 C46 -143.1(4) . . . . ?
C42 Rh4 C50 C46 -114.6(17) . . . . ?
N7 Rh4 C50 C55 1.3(7) . . . . ?
C49 Rh4 C50 C55 121.0(8) . . . . ?
N6 Rh4 C50 C55 -94.4(8) . . . . ?
C46 Rh4 C50 C55 -120.3(8) . . . . ?
C47 Rh4 C50 C55 -157.8(7) . . . . ?
C48 Rh4 C50 C55 159.8(7) . . . . ?
O6 Rh4 C50 C55 96.5(7) . . . . ?
C42 Rh4 C50 C55 125.0(16) . . . . ?
Dy1 O7 C56 N8 75.4(6) . . . . ?
Dy1 O7 C56 N7 -104.8(5) . . . . ?
C57 N8 C56 O7 -175.5(5) . . . . ?
Rh1 N8 C56 O7 13.1(9) . . . . ?
C57 N8 C56 N7 4.6(8) . . . . ?
Rh1 N8 C56 N7 -166.7(4) . . . . ?
C59 N7 C56 O7 177.5(5) . . . . ?
Rh4 N7 C56 O7 -10.2(7) . . . . ?
C59 N7 C56 N8 -2.7(8) . . . . ?
Rh4 N7 C56 N8 169.6(4) . . . . ?
Rh1 O8 C57 N8 6.9(5) . . . . ?
Rh1 O8 C57 C58 -171.6(5) . . . . ?
C56 N8 C57 O8 178.0(5) . . . . ?
Rh1 N8 C57 O8 -7.2(5) . . . . ?
C56 N8 C57 C58 -3.4(8) . . . . ?
Rh1 N8 C57 C58 171.5(5) . . . . ?
O8 C57 C58 C59 178.6(6) . . . . ?
N8 C57 C58 C59 0.2(8) . . . . ?
O8 C57 C58 C60 3.7(9) . . . . ?
N8 C57 C58 C60 -174.7(5) . . . . ?
C56 N7 C59 C58 -0.5(9) . . . . ?
Rh4 N7 C59 C58 -172.7(4) . . . . ?
C57 C58 C59 N7 1.7(8) . . . . ?
C60 C58 C59 N7 176.5(6) . . . . ?
C64 N12 C61 O18 -174.0(10) . . . . ?
C64 N12 C61 N13 1.5(16) . . . . ?
C62 N13 C61 O18 175.5(10) . . . . ?
C62 N13 C61 N12 0.2(15) . . . . ?
C61 N13 C62 O19 179.1(9) . . . . ?
C61 N13 C62 C63 -2.5(14) . . . . ?
O19 C62 C63 C64 -178.7(10) . . . . ?
N13 C62 C63 C64 2.9(13) . . . . ?
O19 C62 C63 C65 -1.2(16) . . . . ?
N13 C62 C63 C65 -179.5(9) . . . . ?
C62 C63 C64 N12 -1.4(15) . . . . ?
C65 C63 C64 N12 -179.1(10) . . . . ?
C61 N12 C64 C63 -0.9(18) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        27.48
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.895
_refine_diff_density_min         -1.848
_refine_diff_density_rms         0.147

# start Validation Reply Form
_vrf_PLAT241_I                   
;
PROBLEM: High      Ueq as Compared to Neighbors for .....         O9 Check 
PROBLEM: High      Ueq as Compared to Neighbors for .....        O10 Check 
RESPONSE: The O9 and O10 atoms of the coordinated NO~3~^-^ ion might be 
disordered with a different conformation; however, for a simplicity of 
calculation we ignore the disorder, and, therefore, the thermal ellipsoids 
of O9 and O10 atoms became rather large compared to the neighbors.
;
_vrf_PLAT242_I                   
;
PROBLEM: Low       Ueq as Compared to Neighbors for .....        Dy1 Check 
PROBLEM: Low       Ueq as Compared to Neighbors for .....         N9 Check 
RESPONSE: The O9 and O10 atoms of the coordinated NO~3~^-^ ion might be 
disordered with a different conformation; however, for a simplicity of 
calculation we ignore the disorder, and, therefore, the thermal ellipsoids 
of O9 and O10 atoms became rather large compared to the neighbors.
;
_vrf_PLAT213_I                   
;
PROBLEM: Atom O9              has ADP max/min Ratio .....        5.0 prolat
PROBLEM: Atom O10             has ADP max/min Ratio .....        4.3 prolat 
RESPONSE: The O9 and O10 atoms of the coordinated NO~3~^-^ ion might be 
disordered with a different conformation; however, for a simplicity of 
calculation we ignore the disorder, and, therefore, the thermal ellipsoids 
of O9 and O10 atoms became rather large compared to the neighbors.
;
_vrf_PLAT220_I                   
;
PROBLEM: Large Non-Solvent  O     Ueq(max)/Ueq(min) Range        7.1 Ratio 
RESPONSE: The O9 and O10 atoms of the coordinated NO~3~^-^ ion might be 
disordered with a different conformation; however, for a simplicity of 
calculation we ignore the disorder, and, therefore, the thermal ellipsoids 
of O9 and O10 atoms became rather large compared to the neighbors.
;
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/. 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Rh4ErNO3
_database_code_depnum_ccdc_archive 'CCDC 1033783'
_audit_update_record             
;
2014-11-12 deposited with the CCDC.
2014-12-11 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         
'C60 H76 Er N10 O14 Rh4 1+, N O3 1-, C5 H6 N2 O2, C H4 O'
_chemical_formula_sum            'C66 H86 Er N13 O20 Rh4'
_chemical_formula_weight         1960.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Er Er -0.2586 4.9576 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   13.8619(4)
_cell_length_b                   18.8672(8)
_cell_length_c                   28.1155(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 93.687(1)
_cell_angle_gamma                90.00
_cell_volume                     7338.0(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    40916
_cell_measurement_theta_min      3.04
_cell_measurement_theta_max      27.57

_exptl_crystal_description       prismatic
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.774
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3924
_exptl_absorpt_coefficient_mu    2.092
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.767
_exptl_absorpt_correction_T_max  0.812
_exptl_absorpt_process_details   NUMABS

_exptl_special_details           ?

_diffrn_ambient_temperature      191(2)
_diffrn_radiation_wavelength     0.71075
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_detector_area_resol_mean 10.00
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            71554
_diffrn_reflns_av_R_equivalents  0.0917
_diffrn_reflns_av_sigmaI/netI    0.0698
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         3.04
_diffrn_reflns_theta_max         27.49
_reflns_number_total             16780
_reflns_number_gt                12502
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'RAPID AUTO'
_computing_cell_refinement       'RAPID AUTO'
_computing_data_reduction        'RAPID AUTO'
_computing_structure_solution    SIR2004
_computing_structure_refinement  SHELXL-97
_computing_molecular_graphics    ?
_computing_publication_material  SHELXL-97

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0880P)²+44.3674P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         16780
_refine_ls_number_parameters     862
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0917
_refine_ls_R_factor_gt           0.0668
_refine_ls_wR_factor_ref         0.1810
_refine_ls_wR_factor_gt          0.1652
_refine_ls_goodness_of_fit_ref   0.986
_refine_ls_restrained_S_all      0.986
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Er1 Er 0.23446(2) 0.755898(17) 0.253436(11) 0.03105(10) Uani 1 1 d . . .
Rh1 Rh 0.12229(4) 0.62132(3) 0.37372(2) 0.03609(15) Uani 1 1 d . . .
Rh2 Rh 0.10136(5) 0.58285(3) 0.15032(2) 0.03963(16) Uani 1 1 d . . .
Rh3 Rh 0.44146(5) 0.80083(3) 0.13342(2) 0.03922(16) Uani 1 1 d . . .
Rh4 Rh 0.50093(5) 0.80500(3) 0.35672(2) 0.04038(16) Uani 1 1 d . . .
O1 O 0.1233(4) 0.6748(3) 0.2683(2) 0.0437(13) Uani 1 1 d . . .
O2 O 0.1532(5) 0.4802(3) 0.1810(2) 0.0527(15) Uani 1 1 d . . .
O3 O 0.2200(4) 0.7212(3) 0.1773(2) 0.0487(14) Uani 1 1 d . . .
O4 O 0.4901(5) 0.7000(3) 0.1023(2) 0.0554(16) Uani 1 1 d . . .
O5 O 0.3693(4) 0.8132(3) 0.2375(2) 0.0485(14) Uani 1 1 d . . .
O6 O 0.6144(5) 0.7338(4) 0.3329(2) 0.0565(16) Uani 1 1 d . . .
O7 O 0.2794(4) 0.7642(3) 0.33256(19) 0.0444(13) Uani 1 1 d . . .
O8 O 0.2444(4) 0.5607(3) 0.4090(2) 0.0500(14) Uani 1 1 d . . .
O9 O 0.1556(7) 0.8601(5) 0.2818(3) 0.090(3) Uani 1 1 d . . .
O10 O 0.1237(7) 0.8349(5) 0.2111(3) 0.093(3) Uani 1 1 d . . .
O11 O 0.0578(6) 0.9264(4) 0.2364(3) 0.088(3) Uani 1 1 d . . .
O12 O 0.3302(4) 0.6597(3) 0.2630(3) 0.0574(17) Uani 1 1 d . . .
O13 O 0.4096(10) 0.5728(6) 0.2900(4) 0.143(5) Uani 1 1 d . . .
O14 O 0.4375(7) 0.6139(4) 0.2230(3) 0.087(3) Uani 1 1 d . . .
O15 O 0.1066(13) 0.1898(10) 0.5205(6) 0.181(6) Uiso 1 1 d . . .
O16 O 0.1696(11) 0.0833(9) 0.4938(5) 0.160(5) Uiso 1 1 d . . .
O17 O 0.1816(9) 0.1868(7) 0.4585(5) 0.132(4) Uiso 1 1 d . . .
O18 O 0.1630(7) 0.3715(5) 0.4063(4) 0.100(3) Uiso 1 1 d . . .
O19 O 0.2837(9) 0.5078(7) 0.5295(4) 0.127(4) Uiso 1 1 d . . .
O20 O 0.3122(12) 0.1331(9) 0.3924(6) 0.170(6) Uiso 1 1 d . . .
N1 N 0.1467(5) 0.5718(4) 0.3089(2) 0.0409(15) Uani 1 1 d . . .
N2 N 0.1351(4) 0.5729(4) 0.2253(2) 0.0395(15) Uani 1 1 d . . .
N3 N 0.2438(5) 0.6153(4) 0.1404(2) 0.0444(16) Uani 1 1 d . . .
N4 N 0.3535(5) 0.7088(3) 0.1349(2) 0.0394(15) Uani 1 1 d . . .
N5 N 0.5000(5) 0.7715(4) 0.2011(2) 0.0450(16) Uani 1 1 d . . .
N6 N 0.5006(5) 0.7737(4) 0.2845(2) 0.0401(15) Uani 1 1 d . . .
N7 N 0.4142(5) 0.7183(3) 0.3714(2) 0.0414(15) Uani 1 1 d . . .
N8 N 0.2658(4) 0.6619(4) 0.3748(2) 0.0399(15) Uani 1 1 d . . .
N9 N 0.1104(5) 0.8764(4) 0.2422(3) 0.0500(18) Uani 1 1 d . . .
N10 N 0.3943(5) 0.6135(4) 0.2595(3) 0.0449(16) Uani 1 1 d . . .
N11 N 0.1445(11) 0.1496(9) 0.4980(6) 0.119(4) Uiso 1 1 d . . .
N12 N 0.1736(10) 0.3261(8) 0.4783(5) 0.116(4) Uiso 1 1 d . . .
H12 H 0.1494 0.2855 0.4677 0.139 Uiso 1 1 calc R . .
N13 N 0.2223(9) 0.4441(7) 0.4712(4) 0.097(3) Uiso 1 1 d . . .
H13 H 0.2287 0.4806 0.4522 0.116 Uiso 1 1 calc R . .
C1 C 0.0034(7) 0.6937(5) 0.3665(3) 0.051(2) Uani 1 1 d . . .
C2 C -0.0317(6) 0.6219(5) 0.3620(3) 0.047(2) Uani 1 1 d . . .
C3 C -0.0036(6) 0.5862(5) 0.4052(3) 0.0451(19) Uani 1 1 d . . .
C4 C 0.0450(6) 0.6361(5) 0.4361(3) 0.0437(19) Uani 1 1 d . . .
C5 C 0.0509(6) 0.7014(4) 0.4121(3) 0.0445(19) Uani 1 1 d . . .
C6 C -0.0174(9) 0.7521(6) 0.3308(4) 0.080(4) Uani 1 1 d . . .
H6A H 0.0436 0.7735 0.3223 0.096 Uiso 1 1 calc R . .
H6B H -0.0576 0.7884 0.3448 0.096 Uiso 1 1 calc R . .
H6C H -0.0517 0.7326 0.3022 0.096 Uiso 1 1 calc R . .
C7 C -0.0828(8) 0.5887(7) 0.3187(4) 0.081(4) Uani 1 1 d . . .
H7A H -0.1449 0.5693 0.3272 0.097 Uiso 1 1 calc R . .
H7B H -0.0428 0.5505 0.3069 0.097 Uiso 1 1 calc R . .
H7C H -0.0938 0.6247 0.2938 0.097 Uiso 1 1 calc R . .
C8 C -0.0236(7) 0.5102(5) 0.4166(4) 0.067(3) Uani 1 1 d . . .
H8A H 0.0063 0.4795 0.3936 0.080 Uiso 1 1 calc R . .
H8B H -0.0936 0.5022 0.4147 0.080 Uiso 1 1 calc R . .
H8C H 0.0033 0.4994 0.4489 0.080 Uiso 1 1 calc R . .
C9 C 0.0838(8) 0.6207(7) 0.4868(3) 0.068(3) Uani 1 1 d . . .
H9A H 0.0523 0.6521 0.5089 0.082 Uiso 1 1 calc R . .
H9B H 0.1537 0.6288 0.4896 0.082 Uiso 1 1 calc R . .
H9C H 0.0702 0.5712 0.4947 0.082 Uiso 1 1 calc R . .
C10 C 0.0960(9) 0.7683(6) 0.4312(5) 0.076(3) Uani 1 1 d . . .
H10A H 0.1647 0.7601 0.4398 0.091 Uiso 1 1 calc R . .
H10B H 0.0637 0.7832 0.4595 0.091 Uiso 1 1 calc R . .
H10C H 0.0891 0.8054 0.4069 0.091 Uiso 1 1 calc R . .
C11 C 0.1352(5) 0.6074(4) 0.2668(3) 0.0404(18) Uani 1 1 d . . .
C12 C 0.1544(6) 0.5026(4) 0.2239(3) 0.0362(16) Uani 1 1 d . . .
C13 C 0.1685(5) 0.4631(4) 0.2663(3) 0.0357(16) Uani 1 1 d . . .
C14 C 0.1624(5) 0.5017(4) 0.3071(3) 0.0391(17) Uani 1 1 d . . .
H14 H 0.1699 0.4770 0.3366 0.047 Uiso 1 1 calc R . .
C15 C 0.1826(7) 0.3843(4) 0.2662(3) 0.052(2) Uani 1 1 d . . .
H15A H 0.1288 0.3614 0.2812 0.062 Uiso 1 1 calc R . .
H15B H 0.2434 0.3725 0.2842 0.062 Uiso 1 1 calc R . .
H15C H 0.1849 0.3675 0.2334 0.062 Uiso 1 1 calc R . .
C16 C -0.0240(6) 0.6496(5) 0.1406(3) 0.048(2) Uani 1 1 d . . .
C17 C 0.0309(6) 0.6554(5) 0.0996(3) 0.049(2) Uani 1 1 d . . .
C18 C 0.0384(7) 0.5864(5) 0.0791(3) 0.050(2) Uani 1 1 d . . .
C19 C -0.0148(7) 0.5386(5) 0.1071(3) 0.053(2) Uani 1 1 d . . .
C20 C -0.0530(6) 0.5779(5) 0.1448(3) 0.0453(19) Uani 1 1 d . . .
C21 C -0.0498(7) 0.7088(6) 0.1717(4) 0.065(3) Uani 1 1 d . . .
H21A H -0.0258 0.6989 0.2046 0.078 Uiso 1 1 calc R . .
H21B H -0.1202 0.7142 0.1703 0.078 Uiso 1 1 calc R . .
H21C H -0.0204 0.7527 0.1608 0.078 Uiso 1 1 calc R . .
C22 C 0.0711(8) 0.7212(6) 0.0810(4) 0.068(3) Uani 1 1 d . . .
H22A H 0.0429 0.7298 0.0487 0.081 Uiso 1 1 calc R . .
H22B H 0.1414 0.7166 0.0802 0.081 Uiso 1 1 calc R . .
H22C H 0.0559 0.7609 0.1016 0.081 Uiso 1 1 calc R . .
C23 C 0.0903(9) 0.5687(7) 0.0346(3) 0.076(3) Uani 1 1 d . . .
H23A H 0.1587 0.5816 0.0395 0.091 Uiso 1 1 calc R . .
H23B H 0.0608 0.5954 0.0075 0.091 Uiso 1 1 calc R . .
H23C H 0.0847 0.5178 0.0280 0.091 Uiso 1 1 calc R . .
C24 C -0.0279(9) 0.4607(5) 0.0985(4) 0.075(3) Uani 1 1 d . . .
H24A H -0.0969 0.4500 0.0932 0.091 Uiso 1 1 calc R . .
H24B H -0.0010 0.4343 0.1263 0.091 Uiso 1 1 calc R . .
H24C H 0.0057 0.4469 0.0703 0.091 Uiso 1 1 calc R . .
C25 C -0.1178(8) 0.5491(6) 0.1814(4) 0.067(3) Uani 1 1 d . . .
H25A H -0.1809 0.5726 0.1777 0.080 Uiso 1 1 calc R . .
H25B H -0.0884 0.5582 0.2134 0.080 Uiso 1 1 calc R . .
H25C H -0.1261 0.4980 0.1767 0.080 Uiso 1 1 calc R . .
C26 C 0.2718(6) 0.6828(5) 0.1511(3) 0.0418(19) Uani 1 1 d . . .
C27 C 0.4120(6) 0.6657(4) 0.1109(3) 0.0396(17) Uani 1 1 d . . .
C28 C 0.3851(6) 0.5970(4) 0.0976(3) 0.0432(19) Uani 1 1 d . . .
C29 C 0.2984(7) 0.5760(4) 0.1140(3) 0.047(2) Uani 1 1 d . . .
H29 H 0.2761 0.5297 0.1058 0.057 Uiso 1 1 calc R . .
C30 C 0.4489(8) 0.5522(5) 0.0680(4) 0.064(3) Uani 1 1 d . . .
H30A H 0.4132 0.5390 0.0381 0.077 Uiso 1 1 calc R . .
H30B H 0.4683 0.5092 0.0858 0.077 Uiso 1 1 calc R . .
H30C H 0.5066 0.5793 0.0610 0.077 Uiso 1 1 calc R . .
C31 C 0.3451(6) 0.8845(4) 0.1070(3) 0.0417(18) Uani 1 1 d . . .
C32 C 0.4165(6) 0.9138(4) 0.1416(3) 0.0412(18) Uani 1 1 d . . .
C33 C 0.5115(6) 0.8995(4) 0.1252(3) 0.0436(19) Uani 1 1 d . . .
C34 C 0.4971(6) 0.8642(5) 0.0801(3) 0.0435(19) Uani 1 1 d . . .
C35 C 0.3957(6) 0.8535(4) 0.0693(3) 0.0429(18) Uani 1 1 d . . .
C36 C 0.2396(7) 0.8859(6) 0.1110(4) 0.065(3) Uani 1 1 d . . .
H36A H 0.2150 0.8372 0.1118 0.078 Uiso 1 1 calc R . .
H36B H 0.2088 0.9109 0.0835 0.078 Uiso 1 1 calc R . .
H36C H 0.2249 0.9105 0.1404 0.078 Uiso 1 1 calc R . .
C37 C 0.3962(8) 0.9567(5) 0.1845(3) 0.060(3) Uani 1 1 d . . .
H37A H 0.4205 1.0050 0.1808 0.072 Uiso 1 1 calc R . .
H37B H 0.4284 0.9350 0.2129 0.072 Uiso 1 1 calc R . .
H37C H 0.3263 0.9581 0.1879 0.072 Uiso 1 1 calc R . .
C38 C 0.6051(7) 0.9223(5) 0.1497(4) 0.057(2) Uani 1 1 d . . .
H38A H 0.6374 0.9558 0.1294 0.069 Uiso 1 1 calc R . .
H38B H 0.6465 0.8808 0.1558 0.069 Uiso 1 1 calc R . .
H38C H 0.5927 0.9452 0.1800 0.069 Uiso 1 1 calc R . .
C39 C 0.5759(8) 0.8383(5) 0.0509(4) 0.061(3) Uani 1 1 d . . .
H39A H 0.5679 0.8589 0.0188 0.074 Uiso 1 1 calc R . .
H39B H 0.5730 0.7865 0.0486 0.074 Uiso 1 1 calc R . .
H39C H 0.6386 0.8526 0.0659 0.074 Uiso 1 1 calc R . .
C40 C 0.3498(8) 0.8186(5) 0.0263(3) 0.060(2) Uani 1 1 d . . .
H40A H 0.3730 0.7696 0.0246 0.072 Uiso 1 1 calc R . .
H40B H 0.3665 0.8445 -0.0022 0.072 Uiso 1 1 calc R . .
H40C H 0.2794 0.8186 0.0282 0.072 Uiso 1 1 calc R . .
C41 C 0.4558(5) 0.7868(4) 0.2405(3) 0.043(2) Uani 1 1 d . . .
C42 C 0.5849(6) 0.7382(4) 0.2882(3) 0.0417(18) Uani 1 1 d . . .
C43 C 0.6293(6) 0.7158(5) 0.2479(3) 0.047(2) Uani 1 1 d . . .
C44 C 0.5834(7) 0.7375(5) 0.2050(3) 0.052(2) Uani 1 1 d . . .
H44 H 0.6142 0.7272 0.1765 0.062 Uiso 1 1 calc R . .
C45 C 0.7193(8) 0.6741(8) 0.2514(5) 0.088(4) Uani 1 1 d . . .
H45A H 0.7086 0.6298 0.2686 0.105 Uiso 1 1 calc R . .
H45B H 0.7704 0.7015 0.2687 0.105 Uiso 1 1 calc R . .
H45C H 0.7389 0.6632 0.2194 0.105 Uiso 1 1 calc R . .
C46 C 0.4464(6) 0.9095(5) 0.3605(3) 0.050(2) Uani 1 1 d . . .
C47 C 0.4416(7) 0.8778(4) 0.4064(3) 0.049(2) Uani 1 1 d . . .
C48 C 0.5381(7) 0.8583(5) 0.4220(3) 0.048(2) Uani 1 1 d . . .
C49 C 0.6028(7) 0.8795(5) 0.3870(3) 0.047(2) Uani 1 1 d . . .
C50 C 0.5462(7) 0.9122(4) 0.3480(3) 0.050(2) Uani 1 1 d . . .
C51 C 0.3644(8) 0.9421(6) 0.3300(4) 0.075(3) Uani 1 1 d . . .
H51A H 0.3366 0.9814 0.3473 0.090 Uiso 1 1 calc R . .
H51B H 0.3146 0.9062 0.3227 0.090 Uiso 1 1 calc R . .
H51C H 0.3889 0.9598 0.3003 0.090 Uiso 1 1 calc R . .
C52 C 0.3531(8) 0.8664(6) 0.4322(4) 0.072(3) Uani 1 1 d . . .
H52A H 0.3594 0.8910 0.4630 0.086 Uiso 1 1 calc R . .
H52B H 0.3442 0.8155 0.4375 0.086 Uiso 1 1 calc R . .
H52C H 0.2970 0.8851 0.4132 0.086 Uiso 1 1 calc R . .
C53 C 0.5722(8) 0.8238(6) 0.4690(3) 0.062(3) Uani 1 1 d . . .
H53A H 0.5398 0.7780 0.4720 0.075 Uiso 1 1 calc R . .
H53B H 0.5566 0.8546 0.4954 0.075 Uiso 1 1 calc R . .
H53C H 0.6423 0.8164 0.4698 0.075 Uiso 1 1 calc R . .
C54 C 0.7090(7) 0.8684(5) 0.3892(4) 0.060(3) Uani 1 1 d . . .
H54A H 0.7416 0.9143 0.3872 0.072 Uiso 1 1 calc R . .
H54B H 0.7257 0.8385 0.3625 0.072 Uiso 1 1 calc R . .
H54C H 0.7297 0.8452 0.4193 0.072 Uiso 1 1 calc R . .
C55 C 0.5825(9) 0.9446(6) 0.3046(3) 0.067(3) Uani 1 1 d . . .
H55A H 0.6166 0.9087 0.2869 0.080 Uiso 1 1 calc R . .
H55B H 0.6270 0.9834 0.3137 0.080 Uiso 1 1 calc R . .
H55C H 0.5280 0.9632 0.2844 0.080 Uiso 1 1 calc R . .
C56 C 0.3186(7) 0.7155(4) 0.3590(3) 0.0417(18) Uani 1 1 d . . .
C57 C 0.3074(5) 0.6068(4) 0.4002(2) 0.0335(16) Uani 1 1 d . . .
C58 C 0.4064(5) 0.6075(4) 0.4135(3) 0.0347(16) Uani 1 1 d . . .
C59 C 0.4550(6) 0.6647(4) 0.3976(3) 0.0370(16) Uani 1 1 d . . .
H59 H 0.5226 0.6671 0.4054 0.044 Uiso 1 1 calc R . .
C60 C 0.4541(7) 0.5510(5) 0.4443(3) 0.053(2) Uani 1 1 d . . .
H60A H 0.4816 0.5722 0.4740 0.064 Uiso 1 1 calc R . .
H60B H 0.5058 0.5288 0.4273 0.064 Uiso 1 1 calc R . .
H60C H 0.4062 0.5151 0.4517 0.064 Uiso 1 1 calc R . .
C61 C 0.1786(11) 0.3784(8) 0.4495(6) 0.098(4) Uiso 1 1 d . . .
C62 C 0.2520(10) 0.4523(8) 0.5160(5) 0.084(3) Uiso 1 1 d . . .
C63 C 0.2462(12) 0.3911(9) 0.5503(6) 0.109(5) Uiso 1 1 d . . .
C64 C 0.2074(11) 0.3328(9) 0.5283(6) 0.107(5) Uiso 1 1 d . . .
H64 H 0.2017 0.2918 0.5476 0.128 Uiso 1 1 calc R . .
C65 C 0.2759(12) 0.3904(9) 0.5991(6) 0.109(5) Uiso 1 1 d . . .
H65A H 0.3279 0.3557 0.6049 0.131 Uiso 1 1 calc R . .
H65B H 0.2210 0.3775 0.6177 0.131 Uiso 1 1 calc R . .
H65C H 0.2994 0.4376 0.6088 0.131 Uiso 1 1 calc R . .
C66 C 0.280(2) 0.0500(15) 0.4336(10) 0.194(11) Uiso 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Er1 O5 2.229(6) . ?
Er1 O1 2.230(5) . ?
Er1 O3 2.235(6) . ?
Er1 O12 2.253(6) . ?
Er1 O7 2.277(5) . ?
Er1 O10 2.402(7) . ?
Er1 O9 2.410(8) . ?
Er1 N9 2.856(6) . ?
Rh1 N1 2.094(7) . ?
Rh1 C3 2.114(8) . ?
Rh1 C4 2.131(8) . ?
Rh1 N8 2.130(7) . ?
Rh1 C5 2.136(8) . ?
Rh1 C2 2.138(8) . ?
Rh1 C1 2.140(8) . ?
Rh1 O8 2.222(6) . ?
Rh2 N3 2.103(7) . ?
Rh2 C19 2.125(8) . ?
Rh2 C20 2.138(8) . ?
Rh2 C18 2.133(8) . ?
Rh2 N2 2.138(6) . ?
Rh2 C16 2.149(9) . ?
Rh2 C17 2.163(8) . ?
Rh2 O2 2.221(6) . ?
Rh3 N5 2.093(7) . ?
Rh3 C34 2.103(8) . ?
Rh3 C33 2.120(8) . ?
Rh3 C35 2.120(8) . ?
Rh3 N4 2.123(7) . ?
Rh3 C31 2.168(8) . ?
Rh3 C32 2.174(8) . ?
Rh3 O4 2.217(6) . ?
Rh4 N7 2.087(7) . ?
Rh4 N6 2.114(7) . ?
Rh4 C46 2.117(9) . ?
Rh4 C48 2.126(8) . ?
Rh4 C49 2.131(8) . ?
Rh4 C50 2.137(8) . ?
Rh4 C47 2.159(9) . ?
Rh4 O6 2.205(7) . ?
O1 C11 1.282(9) . ?
O2 C12 1.279(9) . ?
O3 C26 1.286(10) . ?
O4 C27 1.299(10) . ?
O5 C41 1.296(9) . ?
O6 C42 1.298(10) . ?
O7 C56 1.281(9) . ?
O8 C57 1.267(9) . ?
O9 N9 1.279(10) . ?
O10 N9 1.198(10) . ?
O11 N9 1.196(9) . ?
O12 N10 1.253(8) . ?
O13 N10 1.162(10) . ?
O14 N10 1.221(10) . ?
O15 N11 1.138(19) . ?
O16 N11 1.306(19) . ?
O17 N11 1.435(17) . ?
O18 C61 1.227(16) . ?
O19 C62 1.189(16) . ?
N1 C14 1.342(10) . ?
N1 C11 1.361(11) . ?
N2 C11 1.337(10) . ?
N2 C12 1.353(10) . ?
N3 C29 1.322(11) . ?
N3 C26 1.359(11) . ?
N4 C26 1.339(11) . ?
N4 C27 1.358(10) . ?
N5 C41 1.332(11) . ?
N5 C44 1.322(12) . ?
N6 C42 1.345(11) . ?
N6 C41 1.372(11) . ?
N7 C56 1.350(11) . ?
N7 C59 1.352(10) . ?
N8 C56 1.341(11) . ?
N8 C57 1.368(10) . ?
N12 C61 1.281(19) . ?
N12 C64 1.460(19) . ?
N12 H12 0.8800 . ?
N13 C62 1.310(17) . ?
N13 C61 1.493(18) . ?
N13 H13 0.8800 . ?
C1 C5 1.411(13) . ?
C1 C2 1.443(13) . ?
C1 C6 1.504(13) . ?
C2 C3 1.420(12) . ?
C2 C7 1.505(13) . ?
C3 C4 1.420(12) . ?
C3 C8 1.499(13) . ?
C4 C5 1.410(12) . ?
C4 C9 1.520(12) . ?
C5 C10 1.494(13) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C12 C13 1.408(11) . ?
C13 C14 1.369(11) . ?
C13 C15 1.499(11) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C20 1.418(13) . ?
C16 C17 1.425(13) . ?
C16 C21 1.477(13) . ?
C17 C18 1.431(13) . ?
C17 C22 1.470(13) . ?
C18 C19 1.433(13) . ?
C18 C23 1.521(13) . ?
C19 C20 1.425(13) . ?
C19 C24 1.498(13) . ?
C20 C25 1.507(13) . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C27 C28 1.393(12) . ?
C28 C29 1.373(13) . ?
C28 C30 1.510(12) . ?
C29 H29 0.9500 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C35 1.433(12) . ?
C31 C32 1.452(12) . ?
C31 C36 1.474(12) . ?
C32 C33 1.448(12) . ?
C32 C37 1.494(12) . ?
C33 C34 1.434(12) . ?
C33 C38 1.492(12) . ?
C34 C35 1.433(12) . ?
C34 C39 1.491(12) . ?
C35 C40 1.483(12) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C42 C43 1.389(12) . ?
C43 C44 1.389(13) . ?
C43 C45 1.474(12) . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 C47 1.427(13) . ?
C46 C50 1.450(14) . ?
C46 C51 1.508(12) . ?
C47 C48 1.429(13) . ?
C47 C52 1.482(13) . ?
C48 C49 1.430(13) . ?
C48 C53 1.521(12) . ?
C49 C50 1.444(11) . ?
C49 C54 1.484(13) . ?
C50 C55 1.483(13) . ?
C51 H51A 0.9800 . ?
C51 H51B 0.9800 . ?
C51 H51C 0.9800 . ?
C52 H52A 0.9800 . ?
C52 H52B 0.9800 . ?
C52 H52C 0.9800 . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 H55A 0.9800 . ?
C55 H55B 0.9800 . ?
C55 H55C 0.9800 . ?
C57 C58 1.399(10) . ?
C58 C59 1.364(11) . ?
C58 C60 1.500(11) . ?
C59 H59 0.9500 . ?
C60 H60A 0.9800 . ?
C60 H60B 0.9800 . ?
C60 H60C 0.9800 . ?
C62 C63 1.51(2) . ?
C63 C64 1.36(2) . ?
C63 C65 1.41(2) . ?
C64 H64 0.9500 . ?
C65 H65A 0.9800 . ?
C65 H65B 0.9800 . ?
C65 H65C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Er1 O1 165.58(19) . . ?
O5 Er1 O3 88.5(2) . . ?
O1 Er1 O3 87.6(2) . . ?
O5 Er1 O12 85.4(2) . . ?
O1 Er1 O12 80.4(2) . . ?
O3 Er1 O12 83.9(2) . . ?
O5 Er1 O7 89.0(2) . . ?
O1 Er1 O7 90.7(2) . . ?
O3 Er1 O7 163.4(2) . . ?
O12 Er1 O7 79.5(2) . . ?
O5 Er1 O10 96.7(3) . . ?
O1 Er1 O10 95.3(3) . . ?
O3 Er1 O10 72.0(3) . . ?
O12 Er1 O10 155.8(3) . . ?
O7 Er1 O10 124.6(2) . . ?
O5 Er1 O9 94.3(3) . . ?
O1 Er1 O9 99.5(3) . . ?
O3 Er1 O9 122.8(2) . . ?
O12 Er1 O9 153.3(3) . . ?
O7 Er1 O9 73.8(2) . . ?
O10 Er1 O9 50.8(3) . . ?
O5 Er1 N9 95.7(2) . . ?
O1 Er1 N9 98.6(2) . . ?
O3 Er1 N9 96.4(2) . . ?
O12 Er1 N9 178.9(2) . . ?
O7 Er1 N9 100.2(2) . . ?
O10 Er1 N9 24.4(2) . . ?
O9 Er1 N9 26.4(2) . . ?
N1 Rh1 C3 114.1(3) . . ?
N1 Rh1 C4 153.1(3) . . ?
C3 Rh1 C4 39.1(3) . . ?
N1 Rh1 N8 88.3(2) . . ?
C3 Rh1 N8 154.4(3) . . ?
C4 Rh1 N8 117.4(3) . . ?
N1 Rh1 C5 149.4(3) . . ?
C3 Rh1 C5 65.7(3) . . ?
C4 Rh1 C5 38.6(3) . . ?
N8 Rh1 C5 101.6(3) . . ?
N1 Rh1 C2 94.8(3) . . ?
C3 Rh1 C2 39.0(3) . . ?
C4 Rh1 C2 64.9(3) . . ?
N8 Rh1 C2 157.3(3) . . ?
C5 Rh1 C2 65.4(3) . . ?
N1 Rh1 C1 111.6(3) . . ?
C3 Rh1 C1 65.7(3) . . ?
C4 Rh1 C1 64.5(3) . . ?
N8 Rh1 C1 119.0(3) . . ?
C5 Rh1 C1 38.5(3) . . ?
C2 Rh1 C1 39.4(4) . . ?
N1 Rh1 O8 89.9(2) . . ?
C3 Rh1 O8 106.1(3) . . ?
C4 Rh1 O8 96.3(3) . . ?
N8 Rh1 O8 59.7(2) . . ?
C5 Rh1 O8 120.2(3) . . ?
C2 Rh1 O8 142.7(3) . . ?
C1 Rh1 O8 158.5(3) . . ?
N3 Rh2 C19 136.2(3) . . ?
N3 Rh2 C20 161.3(3) . . ?
C19 Rh2 C20 39.0(4) . . ?
N3 Rh2 C18 101.4(3) . . ?
C19 Rh2 C18 39.3(3) . . ?
C20 Rh2 C18 65.6(3) . . ?
N3 Rh2 N2 90.5(2) . . ?
C19 Rh2 N2 129.7(3) . . ?
C20 Rh2 N2 102.8(3) . . ?
C18 Rh2 N2 168.1(3) . . ?
N3 Rh2 C16 124.8(3) . . ?
C19 Rh2 C16 65.2(4) . . ?
C20 Rh2 C16 38.6(3) . . ?
C18 Rh2 C16 65.4(3) . . ?
N2 Rh2 C16 107.5(3) . . ?
N3 Rh2 C17 96.7(3) . . ?
C19 Rh2 C17 65.1(3) . . ?
C20 Rh2 C17 64.7(3) . . ?
C18 Rh2 C17 38.9(4) . . ?
N2 Rh2 C17 140.0(3) . . ?
C16 Rh2 C17 38.6(3) . . ?
N3 Rh2 O2 91.3(3) . . ?
C19 Rh2 O2 95.3(3) . . ?
C20 Rh2 O2 106.7(3) . . ?
C18 Rh2 O2 119.6(3) . . ?
N2 Rh2 O2 59.7(2) . . ?
C16 Rh2 O2 143.0(3) . . ?
C17 Rh2 O2 158.2(3) . . ?
N5 Rh3 C34 131.3(3) . . ?
N5 Rh3 C33 100.3(3) . . ?
C34 Rh3 C33 39.7(3) . . ?
N5 Rh3 C35 166.9(3) . . ?
C34 Rh3 C35 39.7(3) . . ?
C33 Rh3 C35 67.0(3) . . ?
N5 Rh3 N4 87.4(3) . . ?
C34 Rh3 N4 135.8(3) . . ?
C33 Rh3 N4 171.2(3) . . ?
C35 Rh3 N4 105.0(3) . . ?
N5 Rh3 C31 134.3(3) . . ?
C34 Rh3 C31 65.6(3) . . ?
C33 Rh3 C31 66.4(3) . . ?
C35 Rh3 C31 39.0(3) . . ?
N4 Rh3 C31 105.1(3) . . ?
N5 Rh3 C32 102.6(3) . . ?
C34 Rh3 C32 65.5(3) . . ?
C33 Rh3 C32 39.4(3) . . ?
C35 Rh3 C32 65.7(3) . . ?
N4 Rh3 C32 134.8(3) . . ?
C31 Rh3 C32 39.1(3) . . ?
N5 Rh3 O4 91.3(3) . . ?
C34 Rh3 O4 94.1(3) . . ?
C33 Rh3 O4 123.8(3) . . ?
C35 Rh3 O4 98.5(3) . . ?
N4 Rh3 O4 59.8(2) . . ?
C31 Rh3 O4 133.3(3) . . ?
C32 Rh3 O4 159.6(3) . . ?
N7 Rh4 N6 90.3(3) . . ?
N7 Rh4 C46 120.5(3) . . ?
N6 Rh4 C46 109.2(3) . . ?
N7 Rh4 C48 108.1(3) . . ?
N6 Rh4 C48 161.1(3) . . ?
C46 Rh4 C48 65.4(3) . . ?
N7 Rh4 C49 144.5(3) . . ?
N6 Rh4 C49 121.9(3) . . ?
C46 Rh4 C49 66.1(3) . . ?
C48 Rh4 C49 39.3(3) . . ?
N7 Rh4 C50 160.4(3) . . ?
N6 Rh4 C50 97.9(3) . . ?
C46 Rh4 C50 39.9(4) . . ?
C48 Rh4 C50 66.1(3) . . ?
C49 Rh4 C50 39.6(3) . . ?
N7 Rh4 C47 97.1(3) . . ?
N6 Rh4 C47 145.2(3) . . ?
C46 Rh4 C47 39.0(4) . . ?
C48 Rh4 C47 38.9(3) . . ?
C49 Rh4 C47 65.9(3) . . ?
C50 Rh4 C47 66.3(4) . . ?
N7 Rh4 O6 90.8(3) . . ?
N6 Rh4 O6 59.7(2) . . ?
C46 Rh4 O6 147.8(3) . . ?
C48 Rh4 O6 114.4(3) . . ?
C49 Rh4 O6 93.2(3) . . ?
C50 Rh4 O6 108.7(3) . . ?
C47 Rh4 O6 153.2(3) . . ?
C11 O1 Er1 125.6(5) . . ?
C12 O2 Rh2 93.5(5) . . ?
C26 O3 Er1 134.0(5) . . ?
C27 O4 Rh3 94.3(5) . . ?
C41 O5 Er1 125.8(5) . . ?
C42 O6 Rh4 94.0(5) . . ?
C56 O7 Er1 126.6(5) . . ?
C57 O8 Rh1 94.3(5) . . ?
N9 O9 Er1 96.6(5) . . ?
N9 O10 Er1 99.6(5) . . ?
N10 O12 Er1 164.9(6) . . ?
C14 N1 C11 117.7(7) . . ?
C14 N1 Rh1 120.5(5) . . ?
C11 N1 Rh1 121.3(5) . . ?
C11 N2 C12 120.9(7) . . ?
C11 N2 Rh2 143.7(6) . . ?
C12 N2 Rh2 95.2(5) . . ?
C29 N3 C26 118.9(7) . . ?
C29 N3 Rh2 119.2(6) . . ?
C26 N3 Rh2 120.1(6) . . ?
C26 N4 C27 119.5(7) . . ?
C26 N4 Rh3 143.6(6) . . ?
C27 N4 Rh3 96.8(5) . . ?
C41 N5 C44 118.9(7) . . ?
C41 N5 Rh3 121.8(6) . . ?
C44 N5 Rh3 119.3(6) . . ?
C42 N6 C41 120.0(7) . . ?
C42 N6 Rh4 96.7(5) . . ?
C41 N6 Rh4 142.2(6) . . ?
C56 N7 C59 118.8(7) . . ?
C56 N7 Rh4 123.2(5) . . ?
C59 N7 Rh4 117.8(5) . . ?
C56 N8 C57 121.8(6) . . ?
C56 N8 Rh1 142.7(5) . . ?
C57 N8 Rh1 95.5(5) . . ?
O11 N9 O10 122.4(9) . . ?
O11 N9 O9 124.7(9) . . ?
O10 N9 O9 112.9(7) . . ?
O11 N9 Er1 178.4(7) . . ?
O10 N9 Er1 56.0(4) . . ?
O9 N9 Er1 56.9(4) . . ?
O13 N10 O14 123.3(9) . . ?
O13 N10 O12 119.9(9) . . ?
O14 N10 O12 116.9(8) . . ?
O15 N11 O16 145(2) . . ?
O15 N11 O17 107.9(17) . . ?
O16 N11 O17 106.8(15) . . ?
C61 N12 C64 121.0(15) . . ?
C61 N12 H12 119.5 . . ?
C64 N12 H12 119.5 . . ?
C62 N13 C61 125.8(13) . . ?
C62 N13 H13 117.1 . . ?
C61 N13 H13 117.1 . . ?
C5 C1 C2 108.0(7) . . ?
C5 C1 C6 126.0(10) . . ?
C2 C1 C6 125.6(10) . . ?
C5 C1 Rh1 70.6(5) . . ?
C2 C1 Rh1 70.2(5) . . ?
C6 C1 Rh1 130.1(6) . . ?
C3 C2 C1 107.4(8) . . ?
C3 C2 C7 125.7(10) . . ?
C1 C2 C7 126.8(9) . . ?
C3 C2 Rh1 69.5(5) . . ?
C1 C2 Rh1 70.4(5) . . ?
C7 C2 Rh1 122.4(7) . . ?
C2 C3 C4 107.6(8) . . ?
C2 C3 C8 126.2(9) . . ?
C4 C3 C8 126.2(9) . . ?
C2 C3 Rh1 71.4(5) . . ?
C4 C3 Rh1 71.1(5) . . ?
C8 C3 Rh1 123.9(6) . . ?
C5 C4 C3 109.0(8) . . ?
C5 C4 C9 126.1(9) . . ?
C3 C4 C9 124.9(9) . . ?
C5 C4 Rh1 70.9(5) . . ?
C3 C4 Rh1 69.8(5) . . ?
C9 C4 Rh1 125.5(6) . . ?
C4 C5 C1 107.9(8) . . ?
C4 C5 C10 127.0(9) . . ?
C1 C5 C10 125.0(9) . . ?
C4 C5 Rh1 70.5(5) . . ?
C1 C5 Rh1 70.9(5) . . ?
C10 C5 Rh1 125.6(6) . . ?
C1 C6 H6A 109.5 . . ?
C1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 C8 H8A 109.5 . . ?
C3 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C3 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C4 C9 H9A 109.5 . . ?
C4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C5 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C5 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O1 C11 N2 121.3(8) . . ?
O1 C11 N1 117.9(7) . . ?
N2 C11 N1 120.8(7) . . ?
O2 C12 N2 111.1(7) . . ?
O2 C12 C13 127.9(7) . . ?
N2 C12 C13 120.9(7) . . ?
C14 C13 C12 114.5(7) . . ?
C14 C13 C15 122.9(7) . . ?
C12 C13 C15 122.5(7) . . ?
N1 C14 C13 125.1(7) . . ?
N1 C14 H14 117.4 . . ?
C13 C14 H14 117.4 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C20 C16 C17 108.1(8) . . ?
C20 C16 C21 126.3(9) . . ?
C17 C16 C21 125.6(9) . . ?
C20 C16 Rh2 70.3(5) . . ?
C17 C16 Rh2 71.2(5) . . ?
C21 C16 Rh2 126.3(6) . . ?
C18 C17 C16 108.2(8) . . ?
C18 C17 C22 125.8(9) . . ?
C16 C17 C22 126.0(9) . . ?
C18 C17 Rh2 69.4(5) . . ?
C16 C17 Rh2 70.2(5) . . ?
C22 C17 Rh2 127.1(6) . . ?
C17 C18 C19 107.4(8) . . ?
C17 C18 C23 125.6(9) . . ?
C19 C18 C23 127.0(9) . . ?
C17 C18 Rh2 71.7(5) . . ?
C19 C18 Rh2 70.1(5) . . ?
C23 C18 Rh2 125.4(7) . . ?
C20 C19 C18 108.1(8) . . ?
C20 C19 C24 125.8(10) . . ?
C18 C19 C24 126.1(10) . . ?
C20 C19 Rh2 71.0(5) . . ?
C18 C19 Rh2 70.6(5) . . ?
C24 C19 Rh2 123.9(7) . . ?
C16 C20 C19 108.3(8) . . ?
C16 C20 C25 125.8(9) . . ?
C19 C20 C25 125.9(9) . . ?
C16 C20 Rh2 71.1(5) . . ?
C19 C20 Rh2 70.0(5) . . ?
C25 C20 Rh2 127.1(6) . . ?
C16 C21 H21A 109.5 . . ?
C16 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C16 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C17 C22 H22A 109.5 . . ?
C17 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C17 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C18 C23 H23A 109.5 . . ?
C18 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C18 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C19 C24 H24A 109.5 . . ?
C19 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C19 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
O3 C26 N4 120.3(8) . . ?
O3 C26 N3 119.4(8) . . ?
N4 C26 N3 120.3(7) . . ?
O4 C27 N4 109.0(7) . . ?
O4 C27 C28 128.7(8) . . ?
N4 C27 C28 122.3(8) . . ?
C29 C28 C27 113.7(8) . . ?
C29 C28 C30 125.4(8) . . ?
C27 C28 C30 120.9(8) . . ?
N3 C29 C28 124.9(8) . . ?
N3 C29 H29 117.5 . . ?
C28 C29 H29 117.5 . . ?
C28 C30 H30A 109.5 . . ?
C28 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C28 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C35 C31 C32 107.8(7) . . ?
C35 C31 C36 126.8(8) . . ?
C32 C31 C36 125.4(8) . . ?
C35 C31 Rh3 68.7(4) . . ?
C32 C31 Rh3 70.7(4) . . ?
C36 C31 Rh3 125.4(6) . . ?
C33 C32 C31 108.1(7) . . ?
C33 C32 C37 125.5(8) . . ?
C31 C32 C37 126.2(8) . . ?
C33 C32 Rh3 68.3(4) . . ?
C31 C32 Rh3 70.2(4) . . ?
C37 C32 Rh3 131.0(6) . . ?
C34 C33 C32 106.9(7) . . ?
C34 C33 C38 127.6(8) . . ?
C32 C33 C38 125.4(8) . . ?
C34 C33 Rh3 69.5(5) . . ?
C32 C33 Rh3 72.3(5) . . ?
C38 C33 Rh3 126.4(6) . . ?
C35 C34 C33 109.4(7) . . ?
C35 C34 C39 125.5(8) . . ?
C33 C34 C39 125.0(8) . . ?
C35 C34 Rh3 70.8(5) . . ?
C33 C34 Rh3 70.8(4) . . ?
C39 C34 Rh3 121.5(6) . . ?
C34 C35 C31 107.8(7) . . ?
C34 C35 C40 126.8(8) . . ?
C31 C35 C40 125.4(8) . . ?
C34 C35 Rh3 69.5(4) . . ?
C31 C35 Rh3 72.3(4) . . ?
C40 C35 Rh3 125.0(6) . . ?
C31 C36 H36A 109.5 . . ?
C31 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C31 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
C32 C37 H37A 109.5 . . ?
C32 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C32 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C33 C38 H38A 109.5 . . ?
C33 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C33 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C35 C40 H40A 109.5 . . ?
C35 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C35 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
O5 C41 N5 120.2(8) . . ?
O5 C41 N6 119.4(8) . . ?
N5 C41 N6 120.4(7) . . ?
O6 C42 N6 108.9(8) . . ?
O6 C42 C43 129.9(8) . . ?
N6 C42 C43 121.1(7) . . ?
C42 C43 C44 114.7(8) . . ?
C42 C43 C45 121.6(9) . . ?
C44 C43 C45 123.7(9) . . ?
N5 C44 C43 124.4(9) . . ?
N5 C44 H44 117.8 . . ?
C43 C44 H44 117.8 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C47 C46 C50 109.5(7) . . ?
C47 C46 C51 127.4(10) . . ?
C50 C46 C51 122.9(10) . . ?
C47 C46 Rh4 72.1(5) . . ?
C50 C46 Rh4 70.8(5) . . ?
C51 C46 Rh4 127.6(6) . . ?
C48 C47 C46 106.8(8) . . ?
C48 C47 C52 126.9(9) . . ?
C46 C47 C52 126.3(9) . . ?
C48 C47 Rh4 69.3(5) . . ?
C46 C47 Rh4 68.9(5) . . ?
C52 C47 Rh4 125.9(6) . . ?
C47 C48 C49 109.4(8) . . ?
C47 C48 C53 127.6(9) . . ?
C49 C48 C53 122.9(9) . . ?
C47 C48 Rh4 71.8(5) . . ?
C49 C48 Rh4 70.5(5) . . ?
C53 C48 Rh4 126.3(7) . . ?
C50 C49 C48 107.9(8) . . ?
C50 C49 C54 125.5(9) . . ?
C48 C49 C54 126.6(8) . . ?
C50 C49 Rh4 70.4(5) . . ?
C48 C49 Rh4 70.2(5) . . ?
C54 C49 Rh4 123.6(7) . . ?
C49 C50 C46 106.4(8) . . ?
C49 C50 C55 127.2(9) . . ?
C46 C50 C55 126.4(8) . . ?
C49 C50 Rh4 70.0(5) . . ?
C46 C50 Rh4 69.3(5) . . ?
C55 C50 Rh4 127.0(7) . . ?
C46 C51 H51A 109.5 . . ?
C46 C51 H51B 109.5 . . ?
H51A C51 H51B 109.5 . . ?
C46 C51 H51C 109.5 . . ?
H51A C51 H51C 109.5 . . ?
H51B C51 H51C 109.5 . . ?
C47 C52 H52A 109.5 . . ?
C47 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C47 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C48 C53 H53A 109.5 . . ?
C48 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C48 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C49 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C49 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C50 C55 H55A 109.5 . . ?
C50 C55 H55B 109.5 . . ?
H55A C55 H55B 109.5 . . ?
C50 C55 H55C 109.5 . . ?
H55A C55 H55C 109.5 . . ?
H55B C55 H55C 109.5 . . ?
O7 C56 N8 120.9(8) . . ?
O7 C56 N7 119.7(8) . . ?
N8 C56 N7 119.4(7) . . ?
O8 C57 N8 110.5(7) . . ?
O8 C57 C58 129.1(7) . . ?
N8 C57 C58 120.3(7) . . ?
C59 C58 C57 114.6(7) . . ?
C59 C58 C60 122.9(7) . . ?
C57 C58 C60 122.4(7) . . ?
C58 C59 N7 124.9(7) . . ?
C58 C59 H59 117.5 . . ?
N7 C59 H59 117.5 . . ?
C58 C60 H60A 109.5 . . ?
C58 C60 H60B 109.5 . . ?
H60A C60 H60B 109.5 . . ?
C58 C60 H60C 109.5 . . ?
H60A C60 H60C 109.5 . . ?
H60B C60 H60C 109.5 . . ?
O18 C61 N12 122.1(16) . . ?
O18 C61 N13 122.2(14) . . ?
N12 C61 N13 114.7(14) . . ?
O19 C62 N13 119.8(14) . . ?
O19 C62 C63 120.2(14) . . ?
N13 C62 C63 119.9(14) . . ?
C64 C63 C65 121.2(17) . . ?
C64 C63 C62 111.4(15) . . ?
C65 C63 C62 127.4(16) . . ?
C63 C64 N12 127.1(16) . . ?
C63 C64 H64 116.5 . . ?
N12 C64 H64 116.5 . . ?
C63 C65 H65A 109.5 . . ?
C63 C65 H65B 109.5 . . ?
H65A C65 H65B 109.5 . . ?
C63 C65 H65C 109.5 . . ?
H65A C65 H65C 109.5 . . ?
H65B C65 H65C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Er1 O1 C11 -5.8(13) . . . . ?
O3 Er1 O1 C11 68.8(7) . . . . ?
O12 Er1 O1 C11 -15.4(7) . . . . ?
O7 Er1 O1 C11 -94.6(7) . . . . ?
O10 Er1 O1 C11 140.5(7) . . . . ?
O9 Er1 O1 C11 -168.4(7) . . . . ?
N9 Er1 O1 C11 164.9(7) . . . . ?
N3 Rh2 O2 C12 94.1(5) . . . . ?
C19 Rh2 O2 C12 -129.2(5) . . . . ?
C20 Rh2 O2 C12 -91.0(5) . . . . ?
C18 Rh2 O2 C12 -162.0(5) . . . . ?
N2 Rh2 O2 C12 4.3(4) . . . . ?
C16 Rh2 O2 C12 -74.3(6) . . . . ?
C17 Rh2 O2 C12 -154.1(8) . . . . ?
O5 Er1 O3 C26 62.5(8) . . . . ?
O1 Er1 O3 C26 -103.6(8) . . . . ?
O12 Er1 O3 C26 -23.0(8) . . . . ?
O7 Er1 O3 C26 -19.1(14) . . . . ?
O10 Er1 O3 C26 160.1(9) . . . . ?
O9 Er1 O3 C26 156.7(8) . . . . ?
N9 Er1 O3 C26 158.0(8) . . . . ?
N5 Rh3 O4 C27 88.6(5) . . . . ?
C34 Rh3 O4 C27 -139.9(5) . . . . ?
C33 Rh3 O4 C27 -168.2(5) . . . . ?
C35 Rh3 O4 C27 -100.2(5) . . . . ?
N4 Rh3 O4 C27 2.3(4) . . . . ?
C31 Rh3 O4 C27 -79.9(6) . . . . ?
C32 Rh3 O4 C27 -138.1(8) . . . . ?
O1 Er1 O5 C41 -14.8(14) . . . . ?
O3 Er1 O5 C41 -89.3(7) . . . . ?
O12 Er1 O5 C41 -5.3(7) . . . . ?
O7 Er1 O5 C41 74.3(7) . . . . ?
O10 Er1 O5 C41 -161.0(7) . . . . ?
O9 Er1 O5 C41 148.0(7) . . . . ?
N9 Er1 O5 C41 174.4(7) . . . . ?
N7 Rh4 O6 C42 95.2(5) . . . . ?
N6 Rh4 O6 C42 5.3(5) . . . . ?
C46 Rh4 O6 C42 -72.4(7) . . . . ?
C48 Rh4 O6 C42 -154.5(5) . . . . ?
C49 Rh4 O6 C42 -120.1(5) . . . . ?
C50 Rh4 O6 C42 -82.9(5) . . . . ?
C47 Rh4 O6 C42 -157.3(7) . . . . ?
O5 Er1 O7 C56 -100.4(7) . . . . ?
O1 Er1 O7 C56 65.2(7) . . . . ?
O3 Er1 O7 C56 -18.8(13) . . . . ?
O12 Er1 O7 C56 -14.9(7) . . . . ?
O10 Er1 O7 C56 162.1(7) . . . . ?
O9 Er1 O7 C56 164.9(8) . . . . ?
N9 Er1 O7 C56 164.1(7) . . . . ?
N1 Rh1 O8 C57 89.1(5) . . . . ?
C3 Rh1 O8 C57 -155.7(5) . . . . ?
C4 Rh1 O8 C57 -117.1(5) . . . . ?
N8 Rh1 O8 C57 1.0(4) . . . . ?
C5 Rh1 O8 C57 -84.9(5) . . . . ?
C2 Rh1 O8 C57 -173.1(5) . . . . ?
C1 Rh1 O8 C57 -91.6(9) . . . . ?
O5 Er1 O9 N9 94.0(6) . . . . ?
O1 Er1 O9 N9 -90.3(7) . . . . ?
O3 Er1 O9 N9 3.0(8) . . . . ?
O12 Er1 O9 N9 -177.7(5) . . . . ?
O7 Er1 O9 N9 -178.3(7) . . . . ?
O10 Er1 O9 N9 -1.1(6) . . . . ?
O5 Er1 O10 N9 -88.9(7) . . . . ?
O1 Er1 O10 N9 99.1(7) . . . . ?
O3 Er1 O10 N9 -175.1(8) . . . . ?
O12 Er1 O10 N9 177.5(6) . . . . ?
O7 Er1 O10 N9 4.6(9) . . . . ?
O9 Er1 O10 N9 1.2(6) . . . . ?
O5 Er1 O12 N10 -36(2) . . . . ?
O1 Er1 O12 N10 141(2) . . . . ?
O3 Er1 O12 N10 53(2) . . . . ?
O7 Er1 O12 N10 -126(2) . . . . ?
O10 Er1 O12 N10 60(2) . . . . ?
O9 Er1 O12 N10 -127(2) . . . . ?
N9 Er1 O12 N10 160(12) . . . . ?
C3 Rh1 N1 C14 -62.8(7) . . . . ?
C4 Rh1 N1 C14 -58.8(9) . . . . ?
N8 Rh1 N1 C14 104.5(6) . . . . ?
C5 Rh1 N1 C14 -145.3(6) . . . . ?
C2 Rh1 N1 C14 -98.0(6) . . . . ?
C1 Rh1 N1 C14 -134.8(6) . . . . ?
O8 Rh1 N1 C14 44.9(6) . . . . ?
C3 Rh1 N1 C11 108.9(6) . . . . ?
C4 Rh1 N1 C11 112.9(8) . . . . ?
N8 Rh1 N1 C11 -83.8(6) . . . . ?
C5 Rh1 N1 C11 26.4(9) . . . . ?
C2 Rh1 N1 C11 73.7(6) . . . . ?
C1 Rh1 N1 C11 36.9(7) . . . . ?
O8 Rh1 N1 C11 -143.4(6) . . . . ?
N3 Rh2 N2 C11 91.8(9) . . . . ?
C19 Rh2 N2 C11 -107.1(9) . . . . ?
C20 Rh2 N2 C11 -75.0(9) . . . . ?
C18 Rh2 N2 C11 -86.8(18) . . . . ?
C16 Rh2 N2 C11 -35.2(9) . . . . ?
C17 Rh2 N2 C11 -9.2(11) . . . . ?
O2 Rh2 N2 C11 -177.0(10) . . . . ?
N3 Rh2 N2 C12 -95.3(5) . . . . ?
C19 Rh2 N2 C12 65.7(6) . . . . ?
C20 Rh2 N2 C12 97.9(5) . . . . ?
C18 Rh2 N2 C12 86.0(17) . . . . ?
C16 Rh2 N2 C12 137.7(5) . . . . ?
C17 Rh2 N2 C12 163.7(5) . . . . ?
O2 Rh2 N2 C12 -4.1(4) . . . . ?
C19 Rh2 N3 C29 -41.4(8) . . . . ?
C20 Rh2 N3 C29 -106.7(11) . . . . ?
C18 Rh2 N3 C29 -62.8(7) . . . . ?
N2 Rh2 N3 C29 117.4(6) . . . . ?
C16 Rh2 N3 C29 -130.7(6) . . . . ?
C17 Rh2 N3 C29 -102.0(7) . . . . ?
O2 Rh2 N3 C29 57.7(6) . . . . ?
C19 Rh2 N3 C26 123.3(6) . . . . ?
C20 Rh2 N3 C26 57.9(12) . . . . ?
C18 Rh2 N3 C26 101.8(6) . . . . ?
N2 Rh2 N3 C26 -77.9(6) . . . . ?
C16 Rh2 N3 C26 33.9(7) . . . . ?
C17 Rh2 N3 C26 62.6(6) . . . . ?
O2 Rh2 N3 C26 -137.6(6) . . . . ?
N5 Rh3 N4 C26 82.1(9) . . . . ?
C34 Rh3 N4 C26 -123.7(9) . . . . ?
C33 Rh3 N4 C26 -68(2) . . . . ?
C35 Rh3 N4 C26 -93.8(9) . . . . ?
C31 Rh3 N4 C26 -53.3(9) . . . . ?
C32 Rh3 N4 C26 -23.2(10) . . . . ?
O4 Rh3 N4 C26 175.0(9) . . . . ?
N5 Rh3 N4 C27 -95.2(5) . . . . ?
C34 Rh3 N4 C27 59.1(6) . . . . ?
C33 Rh3 N4 C27 114.3(19) . . . . ?
C35 Rh3 N4 C27 89.0(5) . . . . ?
C31 Rh3 N4 C27 129.5(5) . . . . ?
C32 Rh3 N4 C27 159.6(5) . . . . ?
O4 Rh3 N4 C27 -2.2(4) . . . . ?
C34 Rh3 N5 C41 121.3(7) . . . . ?
C33 Rh3 N5 C41 93.1(7) . . . . ?
C35 Rh3 N5 C41 79.5(15) . . . . ?
N4 Rh3 N5 C41 -82.5(6) . . . . ?
C31 Rh3 N5 C41 26.2(8) . . . . ?
C32 Rh3 N5 C41 52.9(7) . . . . ?
O4 Rh3 N5 C41 -142.1(6) . . . . ?
C34 Rh3 N5 C44 -58.0(8) . . . . ?
C33 Rh3 N5 C44 -86.2(7) . . . . ?
C35 Rh3 N5 C44 -99.9(15) . . . . ?
N4 Rh3 N5 C44 98.2(7) . . . . ?
C31 Rh3 N5 C44 -153.1(6) . . . . ?
C32 Rh3 N5 C44 -126.4(7) . . . . ?
O4 Rh3 N5 C44 38.5(7) . . . . ?
N7 Rh4 N6 C42 -95.9(5) . . . . ?
C46 Rh4 N6 C42 141.4(5) . . . . ?
C48 Rh4 N6 C42 71.4(11) . . . . ?
C49 Rh4 N6 C42 68.1(6) . . . . ?
C50 Rh4 N6 C42 102.0(5) . . . . ?
C47 Rh4 N6 C42 161.2(6) . . . . ?
O6 Rh4 N6 C42 -5.2(5) . . . . ?
N7 Rh4 N6 C41 97.7(9) . . . . ?
C46 Rh4 N6 C41 -25.0(9) . . . . ?
C48 Rh4 N6 C41 -95.0(12) . . . . ?
C49 Rh4 N6 C41 -98.2(9) . . . . ?
C50 Rh4 N6 C41 -64.4(9) . . . . ?
C47 Rh4 N6 C41 -5.2(11) . . . . ?
O6 Rh4 N6 C41 -171.5(10) . . . . ?
N6 Rh4 N7 C56 -75.9(6) . . . . ?
C46 Rh4 N7 C56 36.7(7) . . . . ?
C48 Rh4 N7 C56 108.4(6) . . . . ?
C49 Rh4 N7 C56 127.7(7) . . . . ?
C50 Rh4 N7 C56 39.1(12) . . . . ?
C47 Rh4 N7 C56 70.0(7) . . . . ?
O6 Rh4 N7 C56 -135.6(6) . . . . ?
N6 Rh4 N7 C59 108.9(6) . . . . ?
C46 Rh4 N7 C59 -138.4(6) . . . . ?
C48 Rh4 N7 C59 -66.8(6) . . . . ?
C49 Rh4 N7 C59 -47.4(9) . . . . ?
C50 Rh4 N7 C59 -136.1(8) . . . . ?
C47 Rh4 N7 C59 -105.1(6) . . . . ?
O6 Rh4 N7 C59 49.2(6) . . . . ?
N1 Rh1 N8 C56 85.1(9) . . . . ?
C3 Rh1 N8 C56 -122.6(9) . . . . ?
C4 Rh1 N8 C56 -103.3(9) . . . . ?
C5 Rh1 N8 C56 -65.7(9) . . . . ?
C2 Rh1 N8 C56 -13.3(13) . . . . ?
C1 Rh1 N8 C56 -28.7(10) . . . . ?
O8 Rh1 N8 C56 176.0(10) . . . . ?
N1 Rh1 N8 C57 -91.8(5) . . . . ?
C3 Rh1 N8 C57 60.5(8) . . . . ?
C4 Rh1 N8 C57 79.8(5) . . . . ?
C5 Rh1 N8 C57 117.4(5) . . . . ?
C2 Rh1 N8 C57 169.8(7) . . . . ?
C1 Rh1 N8 C57 154.4(5) . . . . ?
O8 Rh1 N8 C57 -0.9(4) . . . . ?
Er1 O10 N9 O11 -179.8(8) . . . . ?
Er1 O10 N9 O9 -2.0(10) . . . . ?
Er1 O9 N9 O11 179.7(9) . . . . ?
Er1 O9 N9 O10 1.9(10) . . . . ?
O5 Er1 N9 O11 99(28) . . . . ?
O1 Er1 N9 O11 -79(28) . . . . ?
O3 Er1 N9 O11 10(28) . . . . ?
O12 Er1 N9 O11 -97(32) . . . . ?
O7 Er1 N9 O11 -171(28) . . . . ?
O10 Er1 N9 O11 5(28) . . . . ?
O9 Er1 N9 O11 -173(28) . . . . ?
O5 Er1 N9 O10 93.8(8) . . . . ?
O1 Er1 N9 O10 -83.8(8) . . . . ?
O3 Er1 N9 O10 4.7(8) . . . . ?
O12 Er1 N9 O10 -102(13) . . . . ?
O7 Er1 N9 O10 -176.2(7) . . . . ?
O9 Er1 N9 O10 -177.9(11) . . . . ?
O5 Er1 N9 O9 -88.3(7) . . . . ?
O1 Er1 N9 O9 94.0(7) . . . . ?
O3 Er1 N9 O9 -177.5(7) . . . . ?
O12 Er1 N9 O9 76(13) . . . . ?
O7 Er1 N9 O9 1.7(7) . . . . ?
O10 Er1 N9 O9 177.9(11) . . . . ?
Er1 O12 N10 O13 165(2) . . . . ?
Er1 O12 N10 O14 -16(3) . . . . ?
N1 Rh1 C1 C5 -171.5(5) . . . . ?
C3 Rh1 C1 C5 80.9(5) . . . . ?
C4 Rh1 C1 C5 37.6(5) . . . . ?
N8 Rh1 C1 C5 -70.9(5) . . . . ?
C2 Rh1 C1 C5 118.4(7) . . . . ?
O8 Rh1 C1 C5 9.3(11) . . . . ?
N1 Rh1 C1 C2 70.1(5) . . . . ?
C3 Rh1 C1 C2 -37.5(5) . . . . ?
C4 Rh1 C1 C2 -80.8(5) . . . . ?
N8 Rh1 C1 C2 170.7(4) . . . . ?
C5 Rh1 C1 C2 -118.4(7) . . . . ?
O8 Rh1 C1 C2 -109.1(9) . . . . ?
N1 Rh1 C1 C6 -50.2(12) . . . . ?
C3 Rh1 C1 C6 -157.9(12) . . . . ?
C4 Rh1 C1 C6 158.9(12) . . . . ?
N8 Rh1 C1 C6 50.3(12) . . . . ?
C5 Rh1 C1 C6 121.2(13) . . . . ?
C2 Rh1 C1 C6 -120.4(13) . . . . ?
O8 Rh1 C1 C6 130.6(10) . . . . ?
C5 C1 C2 C3 -0.8(9) . . . . ?
C6 C1 C2 C3 -174.2(8) . . . . ?
Rh1 C1 C2 C3 60.0(6) . . . . ?
C5 C1 C2 C7 -177.0(9) . . . . ?
C6 C1 C2 C7 9.5(14) . . . . ?
Rh1 C1 C2 C7 -116.3(9) . . . . ?
C5 C1 C2 Rh1 -60.7(6) . . . . ?
C6 C1 C2 Rh1 125.8(9) . . . . ?
N1 Rh1 C2 C3 123.2(5) . . . . ?
C4 Rh1 C2 C3 -38.4(5) . . . . ?
N8 Rh1 C2 C3 -139.7(7) . . . . ?
C5 Rh1 C2 C3 -81.1(5) . . . . ?
C1 Rh1 C2 C3 -118.1(7) . . . . ?
O8 Rh1 C2 C3 27.1(7) . . . . ?
N1 Rh1 C2 C1 -118.6(5) . . . . ?
C3 Rh1 C2 C1 118.1(7) . . . . ?
C4 Rh1 C2 C1 79.8(5) . . . . ?
N8 Rh1 C2 C1 -21.6(10) . . . . ?
C5 Rh1 C2 C1 37.1(5) . . . . ?
O8 Rh1 C2 C1 145.2(5) . . . . ?
N1 Rh1 C2 C7 3.2(9) . . . . ?
C3 Rh1 C2 C7 -120.0(11) . . . . ?
C4 Rh1 C2 C7 -158.4(10) . . . . ?
N8 Rh1 C2 C7 100.3(11) . . . . ?
C5 Rh1 C2 C7 158.9(10) . . . . ?
C1 Rh1 C2 C7 121.8(11) . . . . ?
O8 Rh1 C2 C7 -92.9(10) . . . . ?
C1 C2 C3 C4 1.8(9) . . . . ?
C7 C2 C3 C4 178.2(9) . . . . ?
Rh1 C2 C3 C4 62.3(6) . . . . ?
C1 C2 C3 C8 -179.4(8) . . . . ?
C7 C2 C3 C8 -3.1(14) . . . . ?
Rh1 C2 C3 C8 -118.9(9) . . . . ?
C1 C2 C3 Rh1 -60.5(6) . . . . ?
C7 C2 C3 Rh1 115.8(9) . . . . ?
N1 Rh1 C3 C2 -66.0(6) . . . . ?
C4 Rh1 C3 C2 116.8(7) . . . . ?
N8 Rh1 C3 C2 144.6(7) . . . . ?
C5 Rh1 C3 C2 80.4(6) . . . . ?
C1 Rh1 C3 C2 37.9(5) . . . . ?
O8 Rh1 C3 C2 -163.3(5) . . . . ?
N1 Rh1 C3 C4 177.2(5) . . . . ?
N8 Rh1 C3 C4 27.8(9) . . . . ?
C5 Rh1 C3 C4 -36.5(5) . . . . ?
C2 Rh1 C3 C4 -116.8(7) . . . . ?
C1 Rh1 C3 C4 -78.9(5) . . . . ?
O8 Rh1 C3 C4 79.9(5) . . . . ?
N1 Rh1 C3 C8 55.7(9) . . . . ?
C4 Rh1 C3 C8 -121.4(11) . . . . ?
N8 Rh1 C3 C8 -93.7(10) . . . . ?
C5 Rh1 C3 C8 -157.9(10) . . . . ?
C2 Rh1 C3 C8 121.7(11) . . . . ?
C1 Rh1 C3 C8 159.6(10) . . . . ?
O8 Rh1 C3 C8 -41.6(9) . . . . ?
C2 C3 C4 C5 -2.3(9) . . . . ?
C8 C3 C4 C5 179.0(8) . . . . ?
Rh1 C3 C4 C5 60.3(6) . . . . ?
C2 C3 C4 C9 177.6(8) . . . . ?
C8 C3 C4 C9 -1.1(14) . . . . ?
Rh1 C3 C4 C9 -119.9(8) . . . . ?
C2 C3 C4 Rh1 -62.5(6) . . . . ?
C8 C3 C4 Rh1 118.7(9) . . . . ?
N1 Rh1 C4 C5 -125.4(7) . . . . ?
C3 Rh1 C4 C5 -119.7(7) . . . . ?
N8 Rh1 C4 C5 73.4(6) . . . . ?
C2 Rh1 C4 C5 -81.4(6) . . . . ?
C1 Rh1 C4 C5 -37.6(5) . . . . ?
O8 Rh1 C4 C5 132.4(5) . . . . ?
N1 Rh1 C4 C3 -5.7(9) . . . . ?
N8 Rh1 C4 C3 -166.9(5) . . . . ?
C5 Rh1 C4 C3 119.7(7) . . . . ?
C2 Rh1 C4 C3 38.3(5) . . . . ?
C1 Rh1 C4 C3 82.1(6) . . . . ?
O8 Rh1 C4 C3 -107.9(5) . . . . ?
N1 Rh1 C4 C9 113.4(9) . . . . ?
C3 Rh1 C4 C9 119.1(11) . . . . ?
N8 Rh1 C4 C9 -47.8(9) . . . . ?
C5 Rh1 C4 C9 -121.2(11) . . . . ?
C2 Rh1 C4 C9 157.4(10) . . . . ?
C1 Rh1 C4 C9 -158.8(10) . . . . ?
O8 Rh1 C4 C9 11.2(9) . . . . ?
C3 C4 C5 C1 1.8(9) . . . . ?
C9 C4 C5 C1 -178.1(8) . . . . ?
Rh1 C4 C5 C1 61.4(6) . . . . ?
C3 C4 C5 C10 179.9(8) . . . . ?
C9 C4 C5 C10 0.0(14) . . . . ?
Rh1 C4 C5 C10 -120.5(9) . . . . ?
C3 C4 C5 Rh1 -59.6(6) . . . . ?
C9 C4 C5 Rh1 120.5(8) . . . . ?
C2 C1 C5 C4 -0.6(9) . . . . ?
C6 C1 C5 C4 172.8(9) . . . . ?
Rh1 C1 C5 C4 -61.1(6) . . . . ?
C2 C1 C5 C10 -178.8(8) . . . . ?
C6 C1 C5 C10 -5.4(14) . . . . ?
Rh1 C1 C5 C10 120.7(9) . . . . ?
C2 C1 C5 Rh1 60.5(6) . . . . ?
C6 C1 C5 Rh1 -126.1(9) . . . . ?
N1 Rh1 C5 C4 133.6(6) . . . . ?
C3 Rh1 C5 C4 36.9(5) . . . . ?
N8 Rh1 C5 C4 -119.7(5) . . . . ?
C2 Rh1 C5 C4 80.0(5) . . . . ?
C1 Rh1 C5 C4 117.9(7) . . . . ?
O8 Rh1 C5 C4 -58.2(6) . . . . ?
N1 Rh1 C5 C1 15.7(8) . . . . ?
C3 Rh1 C5 C1 -80.9(6) . . . . ?
C4 Rh1 C5 C1 -117.9(7) . . . . ?
N8 Rh1 C5 C1 122.4(5) . . . . ?
C2 Rh1 C5 C1 -37.9(5) . . . . ?
O8 Rh1 C5 C1 -176.1(5) . . . . ?
N1 Rh1 C5 C10 -104.2(10) . . . . ?
C3 Rh1 C5 C10 159.1(10) . . . . ?
C4 Rh1 C5 C10 122.2(11) . . . . ?
N8 Rh1 C5 C10 2.5(10) . . . . ?
C2 Rh1 C5 C10 -157.8(10) . . . . ?
C1 Rh1 C5 C10 -120.0(11) . . . . ?
O8 Rh1 C5 C10 64.0(10) . . . . ?
Er1 O1 C11 N2 -75.9(9) . . . . ?
Er1 O1 C11 N1 105.0(7) . . . . ?
C12 N2 C11 O1 175.3(7) . . . . ?
Rh2 N2 C11 O1 -12.9(13) . . . . ?
C12 N2 C11 N1 -5.5(11) . . . . ?
Rh2 N2 C11 N1 166.2(6) . . . . ?
C14 N1 C11 O1 -177.7(7) . . . . ?
Rh1 N1 C11 O1 10.4(9) . . . . ?
C14 N1 C11 N2 3.1(11) . . . . ?
Rh1 N1 C11 N2 -168.8(5) . . . . ?
Rh2 O2 C12 N2 -6.3(6) . . . . ?
Rh2 O2 C12 C13 170.7(8) . . . . ?
C11 N2 C12 O2 -178.3(7) . . . . ?
Rh2 N2 C12 O2 6.6(7) . . . . ?
C11 N2 C12 C13 4.4(11) . . . . ?
Rh2 N2 C12 C13 -170.7(6) . . . . ?
O2 C12 C13 C14 -177.7(8) . . . . ?
N2 C12 C13 C14 -0.9(11) . . . . ?
O2 C12 C13 C15 -1.5(13) . . . . ?
N2 C12 C13 C15 175.3(7) . . . . ?
C11 N1 C14 C13 0.5(12) . . . . ?
Rh1 N1 C14 C13 172.5(6) . . . . ?
C12 C13 C14 N1 -1.5(11) . . . . ?
C15 C13 C14 N1 -177.7(8) . . . . ?
N3 Rh2 C16 C20 167.9(4) . . . . ?
C19 Rh2 C16 C20 37.6(5) . . . . ?
C18 Rh2 C16 C20 81.0(5) . . . . ?
N2 Rh2 C16 C20 -88.7(5) . . . . ?
C17 Rh2 C16 C20 118.1(7) . . . . ?
O2 Rh2 C16 C20 -26.1(7) . . . . ?
N3 Rh2 C16 C17 49.9(6) . . . . ?
C19 Rh2 C16 C17 -80.5(6) . . . . ?
C20 Rh2 C16 C17 -118.1(7) . . . . ?
C18 Rh2 C16 C17 -37.0(5) . . . . ?
N2 Rh2 C16 C17 153.2(5) . . . . ?
O2 Rh2 C16 C17 -144.2(5) . . . . ?
N3 Rh2 C16 C21 -71.0(9) . . . . ?
C19 Rh2 C16 C21 158.7(10) . . . . ?
C20 Rh2 C16 C21 121.1(11) . . . . ?
C18 Rh2 C16 C21 -157.9(10) . . . . ?
N2 Rh2 C16 C21 32.4(9) . . . . ?
C17 Rh2 C16 C21 -120.8(11) . . . . ?
O2 Rh2 C16 C21 95.0(9) . . . . ?
C20 C16 C17 C18 -1.7(9) . . . . ?
C21 C16 C17 C18 -179.0(8) . . . . ?
Rh2 C16 C17 C18 59.2(6) . . . . ?
C20 C16 C17 C22 177.0(8) . . . . ?
C21 C16 C17 C22 -0.3(14) . . . . ?
Rh2 C16 C17 C22 -122.0(9) . . . . ?
C20 C16 C17 Rh2 -60.9(6) . . . . ?
C21 C16 C17 Rh2 121.8(8) . . . . ?
N3 Rh2 C17 C18 99.9(5) . . . . ?
C19 Rh2 C17 C18 -38.5(5) . . . . ?
C20 Rh2 C17 C18 -81.8(6) . . . . ?
N2 Rh2 C17 C18 -161.3(5) . . . . ?
C16 Rh2 C17 C18 -119.3(7) . . . . ?
O2 Rh2 C17 C18 -10.9(11) . . . . ?
N3 Rh2 C17 C16 -140.8(5) . . . . ?
C19 Rh2 C17 C16 80.8(6) . . . . ?
C20 Rh2 C17 C16 37.5(5) . . . . ?
C18 Rh2 C17 C16 119.3(7) . . . . ?
N2 Rh2 C17 C16 -42.0(7) . . . . ?
O2 Rh2 C17 C16 108.4(9) . . . . ?
N3 Rh2 C17 C22 -20.1(10) . . . . ?
C19 Rh2 C17 C22 -158.4(11) . . . . ?
C20 Rh2 C17 C22 158.3(10) . . . . ?
C18 Rh2 C17 C22 -119.9(11) . . . . ?
N2 Rh2 C17 C22 78.7(10) . . . . ?
C16 Rh2 C17 C22 120.7(11) . . . . ?
O2 Rh2 C17 C22 -130.8(9) . . . . ?
C16 C17 C18 C19 1.7(10) . . . . ?
C22 C17 C18 C19 -177.1(9) . . . . ?
Rh2 C17 C18 C19 61.3(6) . . . . ?
C16 C17 C18 C23 179.4(9) . . . . ?
C22 C17 C18 C23 0.6(15) . . . . ?
Rh2 C17 C18 C23 -120.9(9) . . . . ?
C16 C17 C18 Rh2 -59.7(6) . . . . ?
C22 C17 C18 Rh2 121.6(9) . . . . ?
N3 Rh2 C18 C17 -86.5(5) . . . . ?
C19 Rh2 C18 C17 117.0(8) . . . . ?
C20 Rh2 C18 C17 79.4(6) . . . . ?
N2 Rh2 C18 C17 92.1(16) . . . . ?
C16 Rh2 C18 C17 36.7(5) . . . . ?
O2 Rh2 C18 C17 175.4(5) . . . . ?
N3 Rh2 C18 C19 156.5(6) . . . . ?
C20 Rh2 C18 C19 -37.7(6) . . . . ?
N2 Rh2 C18 C19 -24.9(19) . . . . ?
C16 Rh2 C18 C19 -80.3(6) . . . . ?
C17 Rh2 C18 C19 -117.0(8) . . . . ?
O2 Rh2 C18 C19 58.3(6) . . . . ?
N3 Rh2 C18 C23 34.6(10) . . . . ?
C19 Rh2 C18 C23 -121.9(12) . . . . ?
C20 Rh2 C18 C23 -159.5(10) . . . . ?
N2 Rh2 C18 C23 -146.8(14) . . . . ?
C16 Rh2 C18 C23 157.9(10) . . . . ?
C17 Rh2 C18 C23 121.1(11) . . . . ?
O2 Rh2 C18 C23 -63.5(10) . . . . ?
C17 C18 C19 C20 -1.0(10) . . . . ?
C23 C18 C19 C20 -178.7(9) . . . . ?
Rh2 C18 C19 C20 61.4(6) . . . . ?
C17 C18 C19 C24 179.3(9) . . . . ?
C23 C18 C19 C24 1.5(15) . . . . ?
Rh2 C18 C19 C24 -118.4(10) . . . . ?
C17 C18 C19 Rh2 -62.4(6) . . . . ?
C23 C18 C19 Rh2 119.9(10) . . . . ?
N3 Rh2 C19 C20 -152.5(5) . . . . ?
C18 Rh2 C19 C20 -118.0(8) . . . . ?
N2 Rh2 C19 C20 55.5(7) . . . . ?
C16 Rh2 C19 C20 -37.2(5) . . . . ?
C17 Rh2 C19 C20 -79.9(6) . . . . ?
O2 Rh2 C19 C20 110.0(5) . . . . ?
N3 Rh2 C19 C18 -34.5(8) . . . . ?
C20 Rh2 C19 C18 118.0(8) . . . . ?
N2 Rh2 C19 C18 173.5(5) . . . . ?
C16 Rh2 C19 C18 80.8(6) . . . . ?
C17 Rh2 C19 C18 38.1(6) . . . . ?
O2 Rh2 C19 C18 -132.0(6) . . . . ?
N3 Rh2 C19 C24 86.7(10) . . . . ?
C20 Rh2 C19 C24 -120.9(11) . . . . ?
C18 Rh2 C19 C24 121.1(12) . . . . ?
N2 Rh2 C19 C24 -65.4(11) . . . . ?
C16 Rh2 C19 C24 -158.1(11) . . . . ?
C17 Rh2 C19 C24 159.2(11) . . . . ?
O2 Rh2 C19 C24 -10.9(10) . . . . ?
C17 C16 C20 C19 1.1(9) . . . . ?
C21 C16 C20 C19 178.4(8) . . . . ?
Rh2 C16 C20 C19 -60.4(6) . . . . ?
C17 C16 C20 C25 -175.8(8) . . . . ?
C21 C16 C20 C25 1.5(14) . . . . ?
Rh2 C16 C20 C25 122.7(9) . . . . ?
C17 C16 C20 Rh2 61.5(6) . . . . ?
C21 C16 C20 Rh2 -121.2(8) . . . . ?
C18 C19 C20 C16 -0.1(10) . . . . ?
C24 C19 C20 C16 179.7(9) . . . . ?
Rh2 C19 C20 C16 61.1(6) . . . . ?
C18 C19 C20 C25 176.8(8) . . . . ?
C24 C19 C20 C25 -3.4(15) . . . . ?
Rh2 C19 C20 C25 -122.0(9) . . . . ?
C18 C19 C20 Rh2 -61.2(6) . . . . ?
C24 C19 C20 Rh2 118.6(9) . . . . ?
N3 Rh2 C20 C16 -32.3(12) . . . . ?
C19 Rh2 C20 C16 -118.5(7) . . . . ?
C18 Rh2 C20 C16 -80.6(5) . . . . ?
N2 Rh2 C20 C16 102.1(5) . . . . ?
C17 Rh2 C20 C16 -37.5(5) . . . . ?
O2 Rh2 C20 C16 163.9(5) . . . . ?
N3 Rh2 C20 C19 86.2(11) . . . . ?
C18 Rh2 C20 C19 37.9(5) . . . . ?
N2 Rh2 C20 C19 -139.4(5) . . . . ?
C16 Rh2 C20 C19 118.5(7) . . . . ?
C17 Rh2 C20 C19 81.0(6) . . . . ?
O2 Rh2 C20 C19 -77.6(5) . . . . ?
N3 Rh2 C20 C25 -153.4(9) . . . . ?
C19 Rh2 C20 C25 120.4(11) . . . . ?
C18 Rh2 C20 C25 158.3(10) . . . . ?
N2 Rh2 C20 C25 -19.0(9) . . . . ?
C16 Rh2 C20 C25 -121.1(11) . . . . ?
C17 Rh2 C20 C25 -158.6(10) . . . . ?
O2 Rh2 C20 C25 42.9(9) . . . . ?
Er1 O3 C26 N4 -75.2(10) . . . . ?
Er1 O3 C26 N3 104.0(9) . . . . ?
C27 N4 C26 O3 174.1(7) . . . . ?
Rh3 N4 C26 O3 -2.8(13) . . . . ?
C27 N4 C26 N3 -5.1(10) . . . . ?
Rh3 N4 C26 N3 178.1(6) . . . . ?
C29 N3 C26 O3 -179.0(7) . . . . ?
Rh2 N3 C26 O3 16.3(9) . . . . ?
C29 N3 C26 N4 0.2(11) . . . . ?
Rh2 N3 C26 N4 -164.5(5) . . . . ?
Rh3 O4 C27 N4 -3.3(6) . . . . ?
Rh3 O4 C27 C28 174.4(8) . . . . ?
C26 N4 C27 O4 -174.7(7) . . . . ?
Rh3 N4 C27 O4 3.4(7) . . . . ?
C26 N4 C27 C28 7.4(11) . . . . ?
Rh3 N4 C27 C28 -174.4(7) . . . . ?
O4 C27 C28 C29 178.0(8) . . . . ?
N4 C27 C28 C29 -4.6(11) . . . . ?
O4 C27 C28 C30 -1.6(13) . . . . ?
N4 C27 C28 C30 175.8(8) . . . . ?
C26 N3 C29 C28 2.7(12) . . . . ?
Rh2 N3 C29 C28 167.5(7) . . . . ?
C27 C28 C29 N3 -0.5(12) . . . . ?
C30 C28 C29 N3 179.1(8) . . . . ?
N5 Rh3 C31 C35 163.2(5) . . . . ?
C34 Rh3 C31 C35 38.4(5) . . . . ?
C33 Rh3 C31 C35 82.1(5) . . . . ?
N4 Rh3 C31 C35 -95.4(5) . . . . ?
C32 Rh3 C31 C35 119.0(7) . . . . ?
O4 Rh3 C31 C35 -33.0(6) . . . . ?
N5 Rh3 C31 C32 44.2(6) . . . . ?
C34 Rh3 C31 C32 -80.6(5) . . . . ?
C33 Rh3 C31 C32 -36.9(5) . . . . ?
C35 Rh3 C31 C32 -119.0(7) . . . . ?
N4 Rh3 C31 C32 145.6(4) . . . . ?
O4 Rh3 C31 C32 -152.0(4) . . . . ?
N5 Rh3 C31 C36 -76.1(9) . . . . ?
C34 Rh3 C31 C36 159.2(9) . . . . ?
C33 Rh3 C31 C36 -157.2(9) . . . . ?
C35 Rh3 C31 C36 120.8(10) . . . . ?
N4 Rh3 C31 C36 25.3(9) . . . . ?
C32 Rh3 C31 C36 -120.3(10) . . . . ?
O4 Rh3 C31 C36 87.8(9) . . . . ?
C35 C31 C32 C33 -1.0(8) . . . . ?
C36 C31 C32 C33 178.2(8) . . . . ?
Rh3 C31 C32 C33 57.9(5) . . . . ?
C35 C31 C32 C37 174.2(8) . . . . ?
C36 C31 C32 C37 -6.6(13) . . . . ?
Rh3 C31 C32 C37 -126.9(8) . . . . ?
C35 C31 C32 Rh3 -58.9(5) . . . . ?
C36 C31 C32 Rh3 120.3(8) . . . . ?
N5 Rh3 C32 C33 90.9(5) . . . . ?
C34 Rh3 C32 C33 -39.0(5) . . . . ?
C35 Rh3 C32 C33 -82.7(5) . . . . ?
N4 Rh3 C32 C33 -170.1(4) . . . . ?
C31 Rh3 C32 C33 -119.9(7) . . . . ?
O4 Rh3 C32 C33 -40.9(10) . . . . ?
N5 Rh3 C32 C31 -149.2(5) . . . . ?
C34 Rh3 C32 C31 80.9(5) . . . . ?
C33 Rh3 C32 C31 119.9(7) . . . . ?
C35 Rh3 C32 C31 37.2(5) . . . . ?
N4 Rh3 C32 C31 -50.2(6) . . . . ?
O4 Rh3 C32 C31 79.0(10) . . . . ?
N5 Rh3 C32 C37 -27.9(9) . . . . ?
C34 Rh3 C32 C37 -157.8(10) . . . . ?
C33 Rh3 C32 C37 -118.8(11) . . . . ?
C35 Rh3 C32 C37 158.5(10) . . . . ?
N4 Rh3 C32 C37 71.1(10) . . . . ?
C31 Rh3 C32 C37 121.3(11) . . . . ?
O4 Rh3 C32 C37 -159.7(8) . . . . ?
C31 C32 C33 C34 2.2(9) . . . . ?
C37 C32 C33 C34 -173.1(8) . . . . ?
Rh3 C32 C33 C34 61.3(5) . . . . ?
C31 C32 C33 C38 178.4(8) . . . . ?
C37 C32 C33 C38 3.1(13) . . . . ?
Rh3 C32 C33 C38 -122.5(8) . . . . ?
C31 C32 C33 Rh3 -59.1(5) . . . . ?
C37 C32 C33 Rh3 125.6(8) . . . . ?
N5 Rh3 C33 C34 146.2(5) . . . . ?
C35 Rh3 C33 C34 -37.1(5) . . . . ?
N4 Rh3 C33 C34 -64(2) . . . . ?
C31 Rh3 C33 C34 -79.7(5) . . . . ?
C32 Rh3 C33 C34 -116.4(7) . . . . ?
O4 Rh3 C33 C34 47.7(6) . . . . ?
N5 Rh3 C33 C32 -97.4(5) . . . . ?
C34 Rh3 C33 C32 116.4(7) . . . . ?
C35 Rh3 C33 C32 79.3(5) . . . . ?
N4 Rh3 C33 C32 53(2) . . . . ?
C31 Rh3 C33 C32 36.6(5) . . . . ?
O4 Rh3 C33 C32 164.0(4) . . . . ?
N5 Rh3 C33 C38 24.0(9) . . . . ?
C34 Rh3 C33 C38 -122.2(10) . . . . ?
C35 Rh3 C33 C38 -159.3(9) . . . . ?
N4 Rh3 C33 C38 174.0(16) . . . . ?
C31 Rh3 C33 C38 158.0(9) . . . . ?
C32 Rh3 C33 C38 121.4(10) . . . . ?
O4 Rh3 C33 C38 -74.6(9) . . . . ?
C32 C33 C34 C35 -2.6(9) . . . . ?
C38 C33 C34 C35 -178.7(8) . . . . ?
Rh3 C33 C34 C35 60.5(6) . . . . ?
C32 C33 C34 C39 -178.6(8) . . . . ?
C38 C33 C34 C39 5.3(14) . . . . ?
Rh3 C33 C34 C39 -115.5(9) . . . . ?
C32 C33 C34 Rh3 -63.1(5) . . . . ?
C38 C33 C34 Rh3 120.8(9) . . . . ?
N5 Rh3 C34 C35 -166.3(5) . . . . ?
C33 Rh3 C34 C35 -119.6(7) . . . . ?
N4 Rh3 C34 C35 49.0(7) . . . . ?
C31 Rh3 C34 C35 -37.8(5) . . . . ?
C32 Rh3 C34 C35 -80.9(5) . . . . ?
O4 Rh3 C34 C35 98.4(5) . . . . ?
N5 Rh3 C34 C33 -46.7(7) . . . . ?
C35 Rh3 C34 C33 119.6(7) . . . . ?
N4 Rh3 C34 C33 168.6(5) . . . . ?
C31 Rh3 C34 C33 81.8(5) . . . . ?
C32 Rh3 C34 C33 38.7(5) . . . . ?
O4 Rh3 C34 C33 -142.0(5) . . . . ?
N5 Rh3 C34 C39 73.2(9) . . . . ?
C33 Rh3 C34 C39 119.9(10) . . . . ?
C35 Rh3 C34 C39 -120.5(10) . . . . ?
N4 Rh3 C34 C39 -71.5(9) . . . . ?
C31 Rh3 C34 C39 -158.3(8) . . . . ?
C32 Rh3 C34 C39 158.6(8) . . . . ?
O4 Rh3 C34 C39 -22.1(8) . . . . ?
C33 C34 C35 C31 2.0(9) . . . . ?
C39 C34 C35 C31 178.0(8) . . . . ?
Rh3 C34 C35 C31 62.5(5) . . . . ?
C33 C34 C35 C40 -179.5(8) . . . . ?
C39 C34 C35 C40 -3.5(14) . . . . ?
Rh3 C34 C35 C40 -119.0(9) . . . . ?
C33 C34 C35 Rh3 -60.5(6) . . . . ?
C39 C34 C35 Rh3 115.5(9) . . . . ?
C32 C31 C35 C34 -0.6(9) . . . . ?
C36 C31 C35 C34 -179.8(8) . . . . ?
Rh3 C31 C35 C34 -60.8(5) . . . . ?
C32 C31 C35 C40 -179.1(8) . . . . ?
C36 C31 C35 C40 1.7(14) . . . . ?
Rh3 C31 C35 C40 120.8(9) . . . . ?
C32 C31 C35 Rh3 60.1(5) . . . . ?
C36 C31 C35 Rh3 -119.0(8) . . . . ?
N5 Rh3 C35 C34 51.7(15) . . . . ?
C33 Rh3 C35 C34 37.1(5) . . . . ?
N4 Rh3 C35 C34 -147.0(5) . . . . ?
C31 Rh3 C35 C34 117.5(7) . . . . ?
C32 Rh3 C35 C34 80.3(5) . . . . ?
O4 Rh3 C35 C34 -86.1(5) . . . . ?
N5 Rh3 C35 C31 -65.8(15) . . . . ?
C34 Rh3 C35 C31 -117.5(7) . . . . ?
C33 Rh3 C35 C31 -80.4(5) . . . . ?
N4 Rh3 C35 C31 95.5(5) . . . . ?
C32 Rh3 C35 C31 -37.2(5) . . . . ?
O4 Rh3 C35 C31 156.4(5) . . . . ?
N5 Rh3 C35 C40 173.0(11) . . . . ?
C34 Rh3 C35 C40 121.3(10) . . . . ?
C33 Rh3 C35 C40 158.4(9) . . . . ?
N4 Rh3 C35 C40 -25.7(8) . . . . ?
C31 Rh3 C35 C40 -121.2(10) . . . . ?
C32 Rh3 C35 C40 -158.4(9) . . . . ?
O4 Rh3 C35 C40 35.2(8) . . . . ?
Er1 O5 C41 N5 106.9(8) . . . . ?
Er1 O5 C41 N6 -71.9(9) . . . . ?
C44 N5 C41 O5 -172.5(8) . . . . ?
Rh3 N5 C41 O5 8.1(10) . . . . ?
C44 N5 C41 N6 6.3(12) . . . . ?
Rh3 N5 C41 N6 -173.0(5) . . . . ?
C42 N6 C41 O5 171.5(7) . . . . ?
Rh4 N6 C41 O5 -24.1(13) . . . . ?
C42 N6 C41 N5 -7.3(11) . . . . ?
Rh4 N6 C41 N5 157.0(7) . . . . ?
Rh4 O6 C42 N6 -7.7(7) . . . . ?
Rh4 O6 C42 C43 168.8(9) . . . . ?
C41 N6 C42 O6 178.4(7) . . . . ?
Rh4 N6 C42 O6 8.0(7) . . . . ?
C41 N6 C42 C43 1.6(12) . . . . ?
Rh4 N6 C42 C43 -168.8(7) . . . . ?
O6 C42 C43 C44 -171.6(9) . . . . ?
N6 C42 C43 C44 4.5(13) . . . . ?
O6 C42 C43 C45 6.7(16) . . . . ?
N6 C42 C43 C45 -177.2(10) . . . . ?
C41 N5 C44 C43 0.3(14) . . . . ?
Rh3 N5 C44 C43 179.7(7) . . . . ?
C42 C43 C44 N5 -5.7(14) . . . . ?
C45 C43 C44 N5 176.1(11) . . . . ?
N7 Rh4 C46 C47 59.9(6) . . . . ?
N6 Rh4 C46 C47 162.1(5) . . . . ?
C48 Rh4 C46 C47 -37.4(5) . . . . ?
C49 Rh4 C46 C47 -80.6(5) . . . . ?
C50 Rh4 C46 C47 -118.9(7) . . . . ?
O6 Rh4 C46 C47 -134.5(6) . . . . ?
N7 Rh4 C46 C50 178.8(4) . . . . ?
N6 Rh4 C46 C50 -79.0(5) . . . . ?
C48 Rh4 C46 C50 81.5(5) . . . . ?
C49 Rh4 C46 C50 38.3(5) . . . . ?
C47 Rh4 C46 C50 118.9(7) . . . . ?
O6 Rh4 C46 C50 -15.7(8) . . . . ?
N7 Rh4 C46 C51 -63.9(11) . . . . ?
N6 Rh4 C46 C51 38.3(11) . . . . ?
C48 Rh4 C46 C51 -161.2(11) . . . . ?
C49 Rh4 C46 C51 155.6(11) . . . . ?
C50 Rh4 C46 C51 117.3(12) . . . . ?
C47 Rh4 C46 C51 -123.8(12) . . . . ?
O6 Rh4 C46 C51 101.7(10) . . . . ?
C50 C46 C47 C48 -2.1(9) . . . . ?
C51 C46 C47 C48 -176.8(8) . . . . ?
Rh4 C46 C47 C48 59.2(6) . . . . ?
C50 C46 C47 C52 178.9(8) . . . . ?
C51 C46 C47 C52 4.3(15) . . . . ?
Rh4 C46 C47 C52 -119.8(9) . . . . ?
C50 C46 C47 Rh4 -61.3(6) . . . . ?
C51 C46 C47 Rh4 124.0(9) . . . . ?
N7 Rh4 C47 C48 110.2(5) . . . . ?
N6 Rh4 C47 C48 -149.0(5) . . . . ?
C46 Rh4 C47 C48 -118.5(7) . . . . ?
C49 Rh4 C47 C48 -37.3(5) . . . . ?
C50 Rh4 C47 C48 -80.7(5) . . . . ?
O6 Rh4 C47 C48 4.1(10) . . . . ?
N7 Rh4 C47 C46 -131.3(5) . . . . ?
N6 Rh4 C47 C46 -30.5(8) . . . . ?
C48 Rh4 C47 C46 118.5(7) . . . . ?
C49 Rh4 C47 C46 81.2(5) . . . . ?
C50 Rh4 C47 C46 37.8(5) . . . . ?
O6 Rh4 C47 C46 122.6(7) . . . . ?
N7 Rh4 C47 C52 -11.1(10) . . . . ?
N6 Rh4 C47 C52 89.7(10) . . . . ?
C46 Rh4 C47 C52 120.2(11) . . . . ?
C48 Rh4 C47 C52 -121.3(11) . . . . ?
C49 Rh4 C47 C52 -158.5(10) . . . . ?
C50 Rh4 C47 C52 158.0(10) . . . . ?
O6 Rh4 C47 C52 -117.2(9) . . . . ?
C46 C47 C48 C49 1.9(10) . . . . ?
C52 C47 C48 C49 -179.2(9) . . . . ?
Rh4 C47 C48 C49 60.8(6) . . . . ?
C46 C47 C48 C53 178.9(9) . . . . ?
C52 C47 C48 C53 -2.2(15) . . . . ?
Rh4 C47 C48 C53 -122.2(9) . . . . ?
C46 C47 C48 Rh4 -58.9(6) . . . . ?
C52 C47 C48 Rh4 120.0(9) . . . . ?
N7 Rh4 C48 C47 -78.5(6) . . . . ?
N6 Rh4 C48 C47 114.8(10) . . . . ?
C46 Rh4 C48 C47 37.4(5) . . . . ?
C49 Rh4 C48 C47 119.2(8) . . . . ?
C50 Rh4 C48 C47 81.3(6) . . . . ?
O6 Rh4 C48 C47 -178.0(5) . . . . ?
N7 Rh4 C48 C49 162.3(5) . . . . ?
N6 Rh4 C48 C49 -4.3(13) . . . . ?
C46 Rh4 C48 C49 -81.7(6) . . . . ?
C50 Rh4 C48 C49 -37.8(5) . . . . ?
C47 Rh4 C48 C49 -119.2(8) . . . . ?
O6 Rh4 C48 C49 62.8(6) . . . . ?
N7 Rh4 C48 C53 45.2(9) . . . . ?
N6 Rh4 C48 C53 -121.4(10) . . . . ?
C46 Rh4 C48 C53 161.2(10) . . . . ?
C49 Rh4 C48 C53 -117.1(11) . . . . ?
C50 Rh4 C48 C53 -154.9(10) . . . . ?
C47 Rh4 C48 C53 123.7(11) . . . . ?
O6 Rh4 C48 C53 -54.3(9) . . . . ?
C47 C48 C49 C50 -0.9(10) . . . . ?
C53 C48 C49 C50 -178.1(8) . . . . ?
Rh4 C48 C49 C50 60.7(6) . . . . ?
C47 C48 C49 C54 -179.3(8) . . . . ?
C53 C48 C49 C54 3.5(14) . . . . ?
Rh4 C48 C49 C54 -117.7(9) . . . . ?
C47 C48 C49 Rh4 -61.6(6) . . . . ?
C53 C48 C49 Rh4 121.3(9) . . . . ?
N7 Rh4 C49 C50 -148.2(6) . . . . ?
N6 Rh4 C49 C50 60.0(6) . . . . ?
C46 Rh4 C49 C50 -38.5(6) . . . . ?
C48 Rh4 C49 C50 -118.3(8) . . . . ?
C47 Rh4 C49 C50 -81.4(6) . . . . ?
O6 Rh4 C49 C50 115.9(6) . . . . ?
N7 Rh4 C49 C48 -29.8(8) . . . . ?
N6 Rh4 C49 C48 178.3(5) . . . . ?
C46 Rh4 C49 C48 79.8(6) . . . . ?
C50 Rh4 C49 C48 118.3(8) . . . . ?
C47 Rh4 C49 C48 36.9(5) . . . . ?
O6 Rh4 C49 C48 -125.7(5) . . . . ?
N7 Rh4 C49 C54 91.6(9) . . . . ?
N6 Rh4 C49 C54 -60.2(8) . . . . ?
C46 Rh4 C49 C54 -158.8(9) . . . . ?
C48 Rh4 C49 C54 121.4(10) . . . . ?
C50 Rh4 C49 C54 -120.2(10) . . . . ?
C47 Rh4 C49 C54 158.4(8) . . . . ?
O6 Rh4 C49 C54 -4.3(8) . . . . ?
C48 C49 C50 C46 -0.4(9) . . . . ?
C54 C49 C50 C46 178.0(8) . . . . ?
Rh4 C49 C50 C46 60.1(6) . . . . ?
C48 C49 C50 C55 177.6(9) . . . . ?
C54 C49 C50 C55 -3.9(15) . . . . ?
Rh4 C49 C50 C55 -121.9(9) . . . . ?
C48 C49 C50 Rh4 -60.5(6) . . . . ?
C54 C49 C50 Rh4 117.9(9) . . . . ?
C47 C46 C50 C49 1.6(9) . . . . ?
C51 C46 C50 C49 176.5(8) . . . . ?
Rh4 C46 C50 C49 -60.5(6) . . . . ?
C47 C46 C50 C55 -176.5(9) . . . . ?
C51 C46 C50 C55 -1.5(14) . . . . ?
Rh4 C46 C50 C55 121.4(9) . . . . ?
C47 C46 C50 Rh4 62.1(6) . . . . ?
C51 C46 C50 Rh4 -122.9(8) . . . . ?
N7 Rh4 C50 C49 114.1(9) . . . . ?
N6 Rh4 C50 C49 -132.1(5) . . . . ?
C46 Rh4 C50 C49 117.3(8) . . . . ?
C48 Rh4 C50 C49 37.6(6) . . . . ?
C47 Rh4 C50 C49 80.3(6) . . . . ?
O6 Rh4 C50 C49 -71.5(6) . . . . ?
N7 Rh4 C50 C46 -3.1(11) . . . . ?
N6 Rh4 C50 C46 110.7(5) . . . . ?
C48 Rh4 C50 C46 -79.7(6) . . . . ?
C49 Rh4 C50 C46 -117.3(8) . . . . ?
C47 Rh4 C50 C46 -37.0(5) . . . . ?
O6 Rh4 C50 C46 171.3(5) . . . . ?
N7 Rh4 C50 C55 -123.8(11) . . . . ?
N6 Rh4 C50 C55 -10.0(9) . . . . ?
C46 Rh4 C50 C55 -120.7(10) . . . . ?
C48 Rh4 C50 C55 159.6(10) . . . . ?
C49 Rh4 C50 C55 122.1(11) . . . . ?
C47 Rh4 C50 C55 -157.6(10) . . . . ?
O6 Rh4 C50 C55 50.6(9) . . . . ?
Er1 O7 C56 N8 -77.1(9) . . . . ?
Er1 O7 C56 N7 103.5(8) . . . . ?
C57 N8 C56 O7 175.3(7) . . . . ?
Rh1 N8 C56 O7 -1.1(13) . . . . ?
C57 N8 C56 N7 -5.3(11) . . . . ?
Rh1 N8 C56 N7 178.3(6) . . . . ?
C59 N7 C56 O7 -177.2(7) . . . . ?
Rh4 N7 C56 O7 7.7(10) . . . . ?
C59 N7 C56 N8 3.4(11) . . . . ?
Rh4 N7 C56 N8 -171.7(5) . . . . ?
Rh1 O8 C57 N8 -1.5(6) . . . . ?
Rh1 O8 C57 C58 177.2(7) . . . . ?
C56 N8 C57 O8 -176.3(7) . . . . ?
Rh1 N8 C57 O8 1.5(6) . . . . ?
C56 N8 C57 C58 5.0(11) . . . . ?
Rh1 N8 C57 C58 -177.2(6) . . . . ?
O8 C57 C58 C59 178.9(8) . . . . ?
N8 C57 C58 C59 -2.6(10) . . . . ?
O8 C57 C58 C60 -3.0(13) . . . . ?
N8 C57 C58 C60 175.5(7) . . . . ?
C57 C58 C59 N7 0.9(11) . . . . ?
C60 C58 C59 N7 -177.3(7) . . . . ?
C56 N7 C59 C58 -1.2(12) . . . . ?
Rh4 N7 C59 C58 174.1(6) . . . . ?
C64 N12 C61 O18 170.0(14) . . . . ?
C64 N12 C61 N13 1(2) . . . . ?
C62 N13 C61 O18 -171.1(14) . . . . ?
C62 N13 C61 N12 -2(2) . . . . ?
C61 N13 C62 O19 -178.2(14) . . . . ?
C61 N13 C62 C63 2(2) . . . . ?
O19 C62 C63 C64 179.5(15) . . . . ?
N13 C62 C63 C64 -1(2) . . . . ?
O19 C62 C63 C65 -1(3) . . . . ?
N13 C62 C63 C65 179.0(16) . . . . ?
C65 C63 C64 N12 179.9(15) . . . . ?
C62 C63 C64 N12 0(2) . . . . ?
C61 N12 C64 C63 0(3) . . . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         2.166
_refine_diff_density_min         -1.267
_refine_diff_density_rms         0.164

#==END


