# Electronic Supplementary Material (ESI) for CrystEngComm # This journal is © The Royal Society of Chemistry 2013 ####################################################################### # # Cambridge Crystallographic Data Centre # CCDC # ####################################################################### # # This CIF contains data from an original supplementary publication # deposited with the CCDC, and may include chemical, crystal, # experimental, refinement, atomic coordinates, # anisotropic displacement parameters and molecular geometry data, # as required by the journal to which it was submitted. # # This CIF is provided on the understanding that it is used for bona # fide research purposes only. It may contain copyright material # of the CCDC or of third parties, and may not be copied or further # disseminated in any form, whether machine-readable or not, # except for the purpose of generating routine backup copies # on your local computer system. # # For further information on the CCDC, data deposition and # data retrieval see: # www.ccdc.cam.ac.uk # # Bona fide researchers may freely download Mercury and enCIFer # from this site to visualise CIF-encoded structures and # to carry out CIF format checking respectively. # ####################################################################### data_1 _database_code_depnum_ccdc_archive 'CCDC 910770' #TrackingRef '1.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C19 H11 Ag3 F6 O5' _chemical_formula_weight 756.89 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'C 2/c' _symmetry_space_group_name_Hall '-C 2yc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' _cell_length_a 20.9095(16) _cell_length_b 19.3423(8) _cell_length_c 11.6313(8) _cell_angle_alpha 90.00 _cell_angle_beta 119.100(10) _cell_angle_gamma 90.00 _cell_volume 4110.3(5) _cell_formula_units_Z 8 _cell_measurement_temperature 296 _cell_measurement_reflns_used 2603 _cell_measurement_theta_min 3.0613 _cell_measurement_theta_max 29.1032 _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.20 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.18 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.446 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2880 _exptl_absorpt_coefficient_mu 2.915 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.5933 _exptl_absorpt_correction_T_max 0.6220 _exptl_absorpt_process_details SADABS(2009) _exptl_special_details ; ? ; _diffrn_ambient_temperature 296 _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 8145 _diffrn_reflns_av_R_equivalents 0.0287 _diffrn_reflns_av_sigmaI/netI 0.0409 _diffrn_reflns_limit_h_min -24 _diffrn_reflns_limit_h_max 15 _diffrn_reflns_limit_k_min -22 _diffrn_reflns_limit_k_max 22 _diffrn_reflns_limit_l_min -11 _diffrn_reflns_limit_l_max 13 _diffrn_reflns_theta_min 3.07 _diffrn_reflns_theta_max 25.00 _reflns_number_total 3611 _reflns_number_gt 2874 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0648P)^2^+12.2152P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 3611 _refine_ls_number_parameters 318 _refine_ls_number_restraints 58 _refine_ls_R_factor_all 0.0619 _refine_ls_R_factor_gt 0.0484 _refine_ls_wR_factor_ref 0.1298 _refine_ls_wR_factor_gt 0.1214 _refine_ls_goodness_of_fit_ref 1.086 _refine_ls_restrained_S_all 1.093 _refine_ls_shift/su_max 0.006 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag -0.02863(3) -0.02865(2) 0.85724(5) 0.04174(19) Uani 1 1 d . . . Ag2 Ag 0.11635(4) 0.03067(3) 0.92604(7) 0.0574(2) Uani 1 1 d . . . Ag3 Ag -0.11609(4) 0.09489(3) 0.83402(6) 0.0554(2) Uani 1 1 d . . . O1 O 0.0853(4) 0.2246(3) 0.8677(6) 0.0688(17) Uani 1 1 d . . . O2 O 0.2094(4) -0.0100(4) 0.9089(7) 0.081(2) Uani 1 1 d . . . O3 O 0.1885(4) -0.0070(4) 0.7019(7) 0.085(2) Uani 1 1 d . . . O4 O -0.0760(3) -0.1271(2) 0.7632(4) 0.0467(12) Uani 1 1 d . . . O5 O -0.0996(3) -0.1038(2) 0.5578(5) 0.0513(13) Uani 1 1 d . . . C1 C 0.0097(4) 0.0745(3) 0.9069(6) 0.0403(16) Uani 1 1 d D . . C2 C 0.0329(5) 0.1325(3) 0.9316(7) 0.0501(19) Uani 1 1 d D . . C3 C 0.0576(6) 0.2058(4) 0.9547(9) 0.077(3) Uani 1 1 d . . . H3A H 0.0169 0.2356 0.9395 0.092 Uiso 1 1 calc R . . H3B H 0.0956 0.2116 1.0454 0.092 Uiso 1 1 calc R . . C4 C 0.1494(6) 0.1974(4) 0.8861(8) 0.061(2) Uani 1 1 d . . . C5 C 0.1638(5) 0.2077(4) 0.7807(7) 0.059(2) Uani 1 1 d . . . H5 H 0.1300 0.2306 0.7049 0.071 Uiso 1 1 calc R . . C6 C 0.2279(5) 0.1838(4) 0.7916(8) 0.058(2) Uani 1 1 d . . . H6 H 0.2370 0.1913 0.7219 0.070 Uiso 1 1 calc R . . C7 C 0.2803(5) 0.1488(4) 0.9017(7) 0.058(2) Uani 1 1 d . . . C8 C 0.2643(6) 0.1394(5) 1.0019(8) 0.072(3) Uani 1 1 d . . . H8 H 0.2978 0.1159 1.0770 0.087 Uiso 1 1 calc R . . C9 C 0.2001(6) 0.1634(4) 0.9960(8) 0.064(2) Uani 1 1 d . . . H9 H 0.1916 0.1563 1.0666 0.076 Uiso 1 1 calc R . . C10 C 0.3493(6) 0.1235(4) 0.9117(10) 0.070(3) Uani 1 1 d . . . C11 C 0.3534(7) 0.1021(6) 0.8017(12) 0.089(3) Uani 1 1 d . . . H11 H 0.3115 0.1022 0.7196 0.107 Uiso 1 1 calc R . . C12 C 0.4200(9) 0.0805(7) 0.8134(16) 0.117(5) Uani 1 1 d . . . H12 H 0.4219 0.0660 0.7388 0.141 Uiso 1 1 calc R . . C13 C 0.4827(8) 0.0805(8) 0.9327(19) 0.123(5) Uani 1 1 d . . . H13 H 0.5268 0.0663 0.9392 0.148 Uiso 1 1 calc R . . C14 C 0.4797(8) 0.1011(6) 1.0397(15) 0.107(4) Uani 1 1 d . . . H14 H 0.5224 0.1017 1.1206 0.128 Uiso 1 1 calc R . . C15 C 0.4143(7) 0.1216(5) 1.0322(11) 0.091(3) Uani 1 1 d . . . H15 H 0.4136 0.1343 1.1086 0.110 Uiso 1 1 calc R . . C16 C 0.2199(5) -0.0256(4) 0.8163(10) 0.058(2) Uani 1 1 d . A . C17 C 0.2807(5) -0.0779(5) 0.8546(7) 0.080(3) Uani 1 1 d D . . C18 C -0.0957(4) -0.1416(3) 0.6473(7) 0.0406(16) Uani 1 1 d . B . C19 C -0.1165(4) -0.2164(5) 0.6115(6) 0.067(2) Uani 1 1 d D . . F1 F 0.3203(6) -0.0647(6) 0.7950(11) 0.122(4) Uani 0.821(17) 1 d PD A 1 F3 F 0.3273(5) -0.0823(7) 0.9815(9) 0.164(6) Uani 0.821(17) 1 d PD A 1 F2 F 0.2537(5) -0.1417(4) 0.8152(12) 0.103(3) Uani 0.821(17) 1 d PD A 1 F2' F 0.261(2) -0.1251(17) 0.894(5) 0.103(3) Uani 0.179(17) 1 d PD A 2 F3' F 0.329(2) -0.049(3) 0.945(4) 0.164(6) Uani 0.179(17) 1 d PD A 2 F1' F 0.302(3) -0.098(3) 0.784(6) 0.122(4) Uani 0.179(17) 1 d PD A 2 F4 F -0.0846(5) -0.2428(4) 0.5456(9) 0.080(2) Uani 0.645(7) 1 d PDU B 1 F5 F -0.1882(5) -0.2184(4) 0.5191(8) 0.080(2) Uani 0.645(7) 1 d PDU B 1 F6 F -0.0974(7) -0.2580(5) 0.7130(10) 0.107(3) Uani 0.645(7) 1 d PDU B 1 F4' F -0.1590(8) -0.2363(8) 0.4932(12) 0.080(2) Uani 0.355(7) 1 d PDU B 2 F5' F -0.1435(8) -0.2458(8) 0.6797(13) 0.080(2) Uani 0.355(7) 1 d PDU B 2 F6' F -0.0565(8) -0.2524(9) 0.6465(16) 0.107(3) Uani 0.355(7) 1 d PDU B 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0484(4) 0.0320(3) 0.0429(3) -0.0040(2) 0.0207(3) -0.0021(2) Ag2 0.0553(4) 0.0556(4) 0.0723(5) -0.0108(3) 0.0398(4) -0.0005(3) Ag3 0.0575(4) 0.0601(4) 0.0459(4) 0.0055(3) 0.0232(3) 0.0142(3) O1 0.109(6) 0.046(3) 0.076(4) -0.003(3) 0.064(4) -0.020(3) O2 0.063(4) 0.085(4) 0.106(5) -0.034(4) 0.051(4) -0.006(3) O3 0.068(5) 0.090(5) 0.077(5) 0.015(4) 0.019(4) -0.009(4) O4 0.062(4) 0.037(3) 0.040(3) -0.005(2) 0.025(3) -0.014(2) O5 0.070(4) 0.047(3) 0.036(3) 0.000(2) 0.025(3) -0.013(2) C1 0.045(4) 0.047(4) 0.031(3) 0.002(3) 0.020(3) 0.003(3) C2 0.079(6) 0.035(4) 0.048(4) -0.008(3) 0.040(4) -0.011(4) C3 0.135(9) 0.048(5) 0.084(6) -0.028(4) 0.081(7) -0.033(5) C4 0.097(8) 0.035(4) 0.060(5) -0.012(4) 0.046(5) -0.025(4) C5 0.080(7) 0.052(5) 0.040(4) 0.000(3) 0.025(4) -0.025(4) C6 0.072(6) 0.054(5) 0.053(5) -0.002(4) 0.034(5) -0.022(4) C7 0.072(6) 0.053(5) 0.042(4) -0.008(3) 0.022(4) -0.023(4) C8 0.089(8) 0.062(6) 0.042(5) -0.003(4) 0.013(5) -0.021(5) C9 0.092(7) 0.058(5) 0.038(4) -0.011(4) 0.029(5) -0.030(5) C10 0.077(7) 0.050(5) 0.073(6) 0.006(4) 0.028(6) -0.020(5) C11 0.097(9) 0.092(8) 0.085(8) 0.028(6) 0.050(7) -0.010(6) C12 0.119(12) 0.132(11) 0.141(13) 0.035(10) 0.094(11) 0.012(9) C13 0.077(10) 0.113(11) 0.165(15) 0.050(11) 0.047(11) 0.011(8) C14 0.087(10) 0.087(9) 0.114(11) 0.001(7) 0.023(9) 0.006(7) C15 0.098(9) 0.059(6) 0.089(8) -0.006(5) 0.023(7) -0.010(6) C16 0.046(5) 0.053(5) 0.076(6) -0.020(4) 0.031(5) -0.015(4) C17 0.062(7) 0.103(8) 0.059(6) -0.004(5) 0.017(5) 0.009(6) C18 0.041(4) 0.038(4) 0.040(4) 0.001(3) 0.018(3) -0.002(3) C19 0.080(7) 0.068(6) 0.045(5) 0.011(4) 0.024(5) -0.002(5) F1 0.096(8) 0.135(10) 0.179(8) -0.036(8) 0.102(7) -0.010(7) F3 0.124(7) 0.237(14) 0.069(6) -0.012(7) -0.001(5) 0.099(9) F2 0.108(6) 0.063(4) 0.125(8) -0.007(5) 0.047(6) 0.028(4) F2' 0.108(6) 0.063(4) 0.125(8) -0.007(5) 0.047(6) 0.028(4) F3' 0.124(7) 0.237(14) 0.069(6) -0.012(7) -0.001(5) 0.099(9) F1' 0.096(8) 0.135(10) 0.179(8) -0.036(8) 0.102(7) -0.010(7) F4 0.085(2) 0.078(2) 0.078(2) -0.0040(14) 0.0399(16) 0.0010(14) F5 0.080(2) 0.079(2) 0.081(2) -0.0023(14) 0.0380(16) -0.0058(14) F6 0.110(3) 0.103(3) 0.107(3) 0.0011(14) 0.0506(18) -0.0015(14) F4' 0.085(2) 0.078(2) 0.078(2) -0.0040(14) 0.0399(16) 0.0010(14) F5' 0.080(2) 0.079(2) 0.081(2) -0.0023(14) 0.0380(16) -0.0058(14) F6' 0.110(3) 0.103(3) 0.107(3) 0.0011(14) 0.0506(18) -0.0015(14) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 C1 2.122(6) . ? Ag1 O4 2.179(4) . ? Ag1 Ag3 2.9405(8) . ? Ag1 Ag2 2.9642(9) . ? Ag1 Ag2 3.1079(9) 2_556 ? Ag1 Ag1 3.1342(10) 5_557 ? Ag1 Ag1 3.2498(11) 2_556 ? Ag2 O2 2.195(6) . ? Ag2 C1 2.293(7) . ? Ag2 C2 2.654(8) . ? Ag2 Ag1 3.1079(9) 2_556 ? Ag2 Ag3 3.2675(9) 2_556 ? Ag3 C1 2.371(7) . ? Ag3 O3 2.396(8) 2_556 ? Ag3 O5 2.459(5) 6_556 ? Ag3 C5 2.499(7) 2_556 ? Ag3 C6 2.690(8) 2_556 ? Ag3 Ag2 3.2675(9) 2_556 ? O1 C4 1.356(11) . ? O1 C3 1.437(10) . ? O2 C16 1.237(10) . ? O3 C16 1.216(11) . ? O3 Ag3 2.396(8) 2_556 ? O4 C18 1.236(8) . ? O5 C18 1.241(8) . ? O5 Ag3 2.459(5) 6 ? C1 C2 1.202(7) . ? C2 C3 1.486(10) . ? C3 H3A 0.9700 . ? C3 H3B 0.9700 . ? C4 C9 1.369(12) . ? C4 C5 1.412(11) . ? C5 C6 1.365(12) . ? C5 Ag3 2.499(7) 2_556 ? C5 H5 0.9300 . ? C6 C7 1.391(12) . ? C6 Ag3 2.690(8) 2_556 ? C6 H6 0.9300 . ? C7 C8 1.373(12) . ? C7 C10 1.472(14) . ? C8 C9 1.390(14) . ? C8 H8 0.9300 . ? C9 H9 0.9300 . ? C10 C11 1.387(14) . ? C10 C15 1.400(14) . ? C11 C12 1.396(18) . ? C11 H11 0.9300 . ? C12 C13 1.37(2) . ? C12 H12 0.9300 . ? C13 C14 1.337(19) . ? C13 H13 0.9300 . ? C14 C15 1.385(18) . ? C14 H14 0.9300 . ? C15 H15 0.9300 . ? C16 C17 1.512(13) . ? C17 F1' 1.18(4) . ? C17 F2' 1.18(3) . ? C17 F3' 1.18(4) . ? C17 F3 1.318(10) . ? C17 F1 1.339(10) . ? C17 F2 1.342(10) . ? C18 C19 1.510(11) . ? C19 F4' 1.281(12) . ? C19 F5' 1.306(12) . ? C19 F6' 1.315(12) . ? C19 F6 1.321(9) . ? C19 F4 1.338(8) . ? C19 F5 1.355(8) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Ag1 O4 167.7(2) . . ? C1 Ag1 Ag3 52.9(2) . . ? O4 Ag1 Ag3 123.58(14) . . ? C1 Ag1 Ag2 50.3(2) . . ? O4 Ag1 Ag2 129.01(14) . . ? Ag3 Ag1 Ag2 102.65(2) . . ? C1 Ag1 Ag2 83.78(17) . 2_556 ? O4 Ag1 Ag2 84.30(12) . 2_556 ? Ag3 Ag1 Ag2 65.33(2) . 2_556 ? Ag2 Ag1 Ag2 98.17(3) . 2_556 ? C1 Ag1 Ag1 58.68(17) . 5_557 ? O4 Ag1 Ag1 133.38(12) . 5_557 ? Ag3 Ag1 Ag1 73.14(2) . 5_557 ? Ag2 Ag1 Ag1 76.33(3) . 5_557 ? Ag2 Ag1 Ag1 135.82(3) 2_556 5_557 ? C1 Ag1 Ag1 88.73(18) . 2_556 ? O4 Ag1 Ag1 82.08(13) . 2_556 ? Ag3 Ag1 Ag1 111.983(19) . 2_556 ? Ag2 Ag1 Ag1 59.81(2) . 2_556 ? Ag2 Ag1 Ag1 55.526(19) 2_556 2_556 ? Ag1 Ag1 Ag1 136.05(4) 5_557 2_556 ? O2 Ag2 C1 170.6(3) . . ? O2 Ag2 C2 152.9(2) . . ? C1 Ag2 C2 26.87(19) . . ? O2 Ag2 Ag1 132.23(17) . . ? C1 Ag2 Ag1 45.42(16) . . ? C2 Ag2 Ag1 72.28(16) . . ? O2 Ag2 Ag1 82.18(18) . 2_556 ? C1 Ag2 Ag1 89.36(16) . 2_556 ? C2 Ag2 Ag1 104.11(16) . 2_556 ? Ag1 Ag2 Ag1 64.67(2) . 2_556 ? O2 Ag2 Ag3 69.8(2) . 2_556 ? C1 Ag2 Ag3 101.89(16) . 2_556 ? C2 Ag2 Ag3 92.01(15) . 2_556 ? Ag1 Ag2 Ag3 110.87(3) . 2_556 ? Ag1 Ag2 Ag3 54.864(18) 2_556 2_556 ? C1 Ag3 O3 115.0(2) . 2_556 ? C1 Ag3 O5 94.2(2) . 6_556 ? O3 Ag3 O5 89.7(2) 2_556 6_556 ? C1 Ag3 C5 114.9(3) . 2_556 ? O3 Ag3 C5 124.8(3) 2_556 2_556 ? O5 Ag3 C5 108.5(2) 6_556 2_556 ? C1 Ag3 C6 145.1(3) . 2_556 ? O3 Ag3 C6 97.0(3) 2_556 2_556 ? O5 Ag3 C6 99.6(2) 6_556 2_556 ? C5 Ag3 C6 30.2(3) 2_556 2_556 ? C1 Ag3 Ag1 45.55(15) . . ? O3 Ag3 Ag1 70.09(16) 2_556 . ? O5 Ag3 Ag1 101.49(11) 6_556 . ? C5 Ag3 Ag1 145.85(19) 2_556 . ? C6 Ag3 Ag1 155.07(17) 2_556 . ? C1 Ag3 Ag2 76.69(15) . 2_556 ? O3 Ag3 Ag2 79.01(18) 2_556 2_556 ? O5 Ag3 Ag2 160.49(11) 6_556 2_556 ? C5 Ag3 Ag2 90.98(17) 2_556 2_556 ? C6 Ag3 Ag2 97.49(17) 2_556 2_556 ? Ag1 Ag3 Ag2 59.81(2) . 2_556 ? C4 O1 C3 119.7(7) . . ? C16 O2 Ag2 135.0(7) . . ? C16 O3 Ag3 113.1(6) . 2_556 ? C18 O4 Ag1 125.1(4) . . ? C18 O5 Ag3 147.9(4) . 6 ? C2 C1 Ag1 177.0(6) . . ? C2 C1 Ag2 93.5(6) . . ? Ag1 C1 Ag2 84.2(2) . . ? C2 C1 Ag3 100.3(6) . . ? Ag1 C1 Ag3 81.5(2) . . ? Ag2 C1 Ag3 162.5(3) . . ? C1 C2 C3 176.6(9) . . ? C1 C2 Ag2 59.6(5) . . ? C3 C2 Ag2 122.5(6) . . ? O1 C3 C2 109.8(6) . . ? O1 C3 H3A 109.7 . . ? C2 C3 H3A 109.7 . . ? O1 C3 H3B 109.7 . . ? C2 C3 H3B 109.7 . . ? H3A C3 H3B 108.2 . . ? O1 C4 C9 126.3(8) . . ? O1 C4 C5 114.8(8) . . ? C9 C4 C5 118.9(10) . . ? C6 C5 C4 119.1(8) . . ? C6 C5 Ag3 82.7(5) . 2_556 ? C4 C5 Ag3 98.1(5) . 2_556 ? C6 C5 H5 120.5 . . ? C4 C5 H5 120.5 . . ? Ag3 C5 H5 89.2 2_556 . ? C5 C6 C7 123.3(8) . . ? C5 C6 Ag3 67.1(5) . 2_556 ? C7 C6 Ag3 106.0(5) . 2_556 ? C5 C6 H6 118.3 . . ? C7 C6 H6 118.3 . . ? Ag3 C6 H6 96.8 2_556 . ? C8 C7 C6 115.9(9) . . ? C8 C7 C10 121.6(9) . . ? C6 C7 C10 122.5(8) . . ? C7 C8 C9 122.9(9) . . ? C7 C8 H8 118.6 . . ? C9 C8 H8 118.6 . . ? C4 C9 C8 119.9(8) . . ? C4 C9 H9 120.1 . . ? C8 C9 H9 120.1 . . ? C11 C10 C15 116.7(11) . . ? C11 C10 C7 121.6(9) . . ? C15 C10 C7 121.7(10) . . ? C10 C11 C12 120.4(13) . . ? C10 C11 H11 119.8 . . ? C12 C11 H11 119.8 . . ? C13 C12 C11 121.1(14) . . ? C13 C12 H12 119.5 . . ? C11 C12 H12 119.5 . . ? C14 C13 C12 119.3(15) . . ? C14 C13 H13 120.4 . . ? C12 C13 H13 120.4 . . ? C13 C14 C15 121.2(14) . . ? C13 C14 H14 119.4 . . ? C15 C14 H14 119.4 . . ? C14 C15 C10 121.3(13) . . ? C14 C15 H15 119.3 . . ? C10 C15 H15 119.3 . . ? O3 C16 O2 130.6(9) . . ? O3 C16 C17 116.7(8) . . ? O2 C16 C17 112.7(8) . . ? F1' C17 F2' 109.4(19) . . ? F1' C17 F3' 109.2(19) . . ? F2' C17 F3' 109.0(18) . . ? F1' C17 F3 115(4) . . ? F2' C17 F3 74(2) . . ? F2' C17 F1 140(2) . . ? F3' C17 F1 84(2) . . ? F3 C17 F1 106.5(7) . . ? F1' C17 F2 72(2) . . ? F3' C17 F2 140(3) . . ? F3 C17 F2 106.4(7) . . ? F1 C17 F2 105.1(6) . . ? F1' C17 C16 125(4) . . ? F2' C17 C16 103(2) . . ? F3' C17 C16 100(3) . . ? F3 C17 C16 115.6(9) . . ? F1 C17 C16 111.3(9) . . ? F2 C17 C16 111.2(7) . . ? O5 C18 O4 129.3(6) . . ? O5 C18 C19 116.1(6) . . ? O4 C18 C19 114.6(6) . . ? F4' C19 F5' 104.0(8) . . ? F4' C19 F6' 103.5(8) . . ? F5' C19 F6' 102.1(7) . . ? F4' C19 F6 121.8(11) . . ? F6' C19 F6 64.6(7) . . ? F4' C19 F4 63.3(7) . . ? F5' C19 F4 131.6(11) . . ? F6' C19 F4 46.2(7) . . ? F6 C19 F4 105.1(8) . . ? F5' C19 F5 80.3(8) . . ? F6' C19 F5 138.7(10) . . ? F6 C19 F5 115.4(9) . . ? F4 C19 F5 101.7(7) . . ? F4' C19 C18 122.7(9) . . ? F5' C19 C18 113.7(9) . . ? F6' C19 C18 108.6(10) . . ? F6 C19 C18 114.6(7) . . ? F4 C19 C18 111.5(7) . . ? F5 C19 C18 107.8(7) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C1 Ag1 Ag2 O2 -167.4(4) . . . . ? O4 Ag1 Ag2 O2 -3.3(3) . . . . ? Ag3 Ag1 Ag2 O2 -159.0(3) . . . . ? Ag2 Ag1 Ag2 O2 -92.6(3) 2_556 . . . ? Ag1 Ag1 Ag2 O2 132.1(3) 5_557 . . . ? Ag1 Ag1 Ag2 O2 -50.7(3) 2_556 . . . ? O4 Ag1 Ag2 C1 164.1(3) . . . . ? Ag3 Ag1 Ag2 C1 8.4(2) . . . . ? Ag2 Ag1 Ag2 C1 74.9(2) 2_556 . . . ? Ag1 Ag1 Ag2 C1 -60.4(2) 5_557 . . . ? Ag1 Ag1 Ag2 C1 116.7(2) 2_556 . . . ? C1 Ag1 Ag2 C2 -0.9(3) . . . . ? O4 Ag1 Ag2 C2 163.2(2) . . . . ? Ag3 Ag1 Ag2 C2 7.49(16) . . . . ? Ag2 Ag1 Ag2 C2 73.92(16) 2_556 . . . ? Ag1 Ag1 Ag2 C2 -61.38(16) 5_557 . . . ? Ag1 Ag1 Ag2 C2 115.75(16) 2_556 . . . ? C1 Ag1 Ag2 Ag1 -116.7(2) . . . 2_556 ? O4 Ag1 Ag2 Ag1 47.43(16) . . . 2_556 ? Ag3 Ag1 Ag2 Ag1 -108.26(2) . . . 2_556 ? Ag2 Ag1 Ag2 Ag1 -41.83(3) 2_556 . . 2_556 ? Ag1 Ag1 Ag2 Ag1 -177.13(2) 5_557 . . 2_556 ? C1 Ag1 Ag2 Ag3 -86.2(2) . . . 2_556 ? O4 Ag1 Ag2 Ag3 77.90(16) . . . 2_556 ? Ag3 Ag1 Ag2 Ag3 -77.79(3) . . . 2_556 ? Ag2 Ag1 Ag2 Ag3 -11.36(3) 2_556 . . 2_556 ? Ag1 Ag1 Ag2 Ag3 -146.66(3) 5_557 . . 2_556 ? Ag1 Ag1 Ag2 Ag3 30.468(18) 2_556 . . 2_556 ? O4 Ag1 Ag3 C1 -165.5(3) . . . . ? Ag2 Ag1 Ag3 C1 -8.1(2) . . . . ? Ag2 Ag1 Ag3 C1 -101.4(2) 2_556 . . . ? Ag1 Ag1 Ag3 C1 63.1(2) 5_557 . . . ? Ag1 Ag1 Ag3 C1 -70.4(2) 2_556 . . . ? C1 Ag1 Ag3 O3 -170.0(3) . . . 2_556 ? O4 Ag1 Ag3 O3 24.5(2) . . . 2_556 ? Ag2 Ag1 Ag3 O3 -178.09(19) . . . 2_556 ? Ag2 Ag1 Ag3 O3 88.63(19) 2_556 . . 2_556 ? Ag1 Ag1 Ag3 O3 -106.82(19) 5_557 . . 2_556 ? Ag1 Ag1 Ag3 O3 119.63(19) 2_556 . . 2_556 ? C1 Ag1 Ag3 O5 -84.6(2) . . . 6_556 ? O4 Ag1 Ag3 O5 109.9(2) . . . 6_556 ? Ag2 Ag1 Ag3 O5 -92.69(14) . . . 6_556 ? Ag2 Ag1 Ag3 O5 174.03(14) 2_556 . . 6_556 ? Ag1 Ag1 Ag3 O5 -21.42(14) 5_557 . . 6_556 ? Ag1 Ag1 Ag3 O5 -154.97(14) 2_556 . . 6_556 ? C1 Ag1 Ag3 C5 66.8(4) . . . 2_556 ? O4 Ag1 Ag3 C5 -98.8(4) . . . 2_556 ? Ag2 Ag1 Ag3 C5 58.6(4) . . . 2_556 ? Ag2 Ag1 Ag3 C5 -34.6(4) 2_556 . . 2_556 ? Ag1 Ag1 Ag3 C5 129.9(4) 5_557 . . 2_556 ? Ag1 Ag1 Ag3 C5 -3.6(4) 2_556 . . 2_556 ? C1 Ag1 Ag3 C6 128.1(5) . . . 2_556 ? O4 Ag1 Ag3 C6 -37.5(5) . . . 2_556 ? Ag2 Ag1 Ag3 C6 119.9(5) . . . 2_556 ? Ag2 Ag1 Ag3 C6 26.7(5) 2_556 . . 2_556 ? Ag1 Ag1 Ag3 C6 -168.8(5) 5_557 . . 2_556 ? Ag1 Ag1 Ag3 C6 57.7(5) 2_556 . . 2_556 ? C1 Ag1 Ag3 Ag2 101.4(2) . . . 2_556 ? O4 Ag1 Ag3 Ag2 -64.14(15) . . . 2_556 ? Ag2 Ag1 Ag3 Ag2 93.28(3) . . . 2_556 ? Ag1 Ag1 Ag3 Ag2 164.55(3) 5_557 . . 2_556 ? Ag1 Ag1 Ag3 Ag2 31.00(2) 2_556 . . 2_556 ? C2 Ag2 O2 C16 -84.8(9) . . . . ? Ag1 Ag2 O2 C16 65.9(9) . . . . ? Ag1 Ag2 O2 C16 21.0(8) 2_556 . . . ? Ag3 Ag2 O2 C16 -34.4(8) 2_556 . . . ? C1 Ag1 O4 C18 12.7(14) . . . . ? Ag3 Ag1 O4 C18 82.0(6) . . . . ? Ag2 Ag1 O4 C18 -69.2(6) . . . . ? Ag2 Ag1 O4 C18 26.7(6) 2_556 . . . ? Ag1 Ag1 O4 C18 -179.5(5) 5_557 . . . ? Ag1 Ag1 O4 C18 -29.2(6) 2_556 . . . ? O4 Ag1 C1 Ag2 -92.0(11) . . . . ? Ag3 Ag1 C1 Ag2 -169.7(3) . . . . ? Ag2 Ag1 C1 Ag2 -106.03(15) 2_556 . . . ? Ag1 Ag1 C1 Ag2 98.3(2) 5_557 . . . ? Ag1 Ag1 C1 Ag2 -50.58(14) 2_556 . . . ? O4 Ag1 C1 Ag3 77.7(11) . . . . ? Ag2 Ag1 C1 Ag3 169.7(3) . . . . ? Ag2 Ag1 C1 Ag3 63.64(12) 2_556 . . . ? Ag1 Ag1 C1 Ag3 -91.98(18) 5_557 . . . ? Ag1 Ag1 C1 Ag3 119.09(13) 2_556 . . . ? Ag1 Ag2 C1 C2 -178.0(6) . . . . ? Ag1 Ag2 C1 C2 -124.2(5) 2_556 . . . ? Ag3 Ag2 C1 C2 -70.4(5) 2_556 . . . ? C2 Ag2 C1 Ag1 178.0(6) . . . . ? Ag1 Ag2 C1 Ag1 53.86(15) 2_556 . . . ? Ag3 Ag2 C1 Ag1 107.67(15) 2_556 . . . ? C2 Ag2 C1 Ag3 142.0(13) . . . . ? Ag1 Ag2 C1 Ag3 -36.0(9) . . . . ? Ag1 Ag2 C1 Ag3 17.8(10) 2_556 . . . ? Ag3 Ag2 C1 Ag3 71.6(10) 2_556 . . . ? O3 Ag3 C1 C2 -172.0(5) 2_556 . . . ? O5 Ag3 C1 C2 -80.4(5) 6_556 . . . ? C5 Ag3 C1 C2 32.3(5) 2_556 . . . ? C6 Ag3 C1 C2 33.1(7) 2_556 . . . ? Ag1 Ag3 C1 C2 177.6(6) . . . . ? Ag2 Ag3 C1 C2 117.1(5) 2_556 . . . ? O3 Ag3 C1 Ag1 10.4(3) 2_556 . . . ? O5 Ag3 C1 Ag1 101.99(19) 6_556 . . . ? C5 Ag3 C1 Ag1 -145.3(2) 2_556 . . . ? C6 Ag3 C1 Ag1 -144.5(3) 2_556 . . . ? Ag2 Ag3 C1 Ag1 -60.53(13) 2_556 . . . ? O3 Ag3 C1 Ag2 46.7(11) 2_556 . . . ? O5 Ag3 C1 Ag2 138.3(10) 6_556 . . . ? C5 Ag3 C1 Ag2 -109.1(10) 2_556 . . . ? C6 Ag3 C1 Ag2 -108.2(10) 2_556 . . . ? Ag1 Ag3 C1 Ag2 36.3(9) . . . . ? Ag2 Ag3 C1 Ag2 -24.2(10) 2_556 . . . ? Ag3 C1 C2 Ag2 -169.1(4) . . . . ? O2 Ag2 C2 C1 159.1(6) . . . . ? Ag1 Ag2 C2 C1 1.5(4) . . . . ? Ag1 Ag2 C2 C1 58.6(5) 2_556 . . . ? Ag3 Ag2 C2 C1 112.8(5) 2_556 . . . ? O2 Ag2 C2 C3 -17.7(9) . . . . ? C1 Ag2 C2 C3 -176.8(9) . . . . ? Ag1 Ag2 C2 C3 -175.3(6) . . . . ? Ag1 Ag2 C2 C3 -118.2(6) 2_556 . . . ? Ag3 Ag2 C2 C3 -64.0(6) 2_556 . . . ? C4 O1 C3 C2 -70.0(10) . . . . ? Ag2 C2 C3 O1 50.5(10) . . . . ? C3 O1 C4 C9 -14.2(12) . . . . ? C3 O1 C4 C5 167.4(6) . . . . ? O1 C4 C5 C6 178.2(7) . . . . ? C9 C4 C5 C6 -0.3(11) . . . . ? O1 C4 C5 Ag3 -95.7(6) . . . 2_556 ? C9 C4 C5 Ag3 85.8(7) . . . 2_556 ? C4 C5 C6 C7 0.6(12) . . . . ? Ag3 C5 C6 C7 -94.7(7) 2_556 . . . ? C4 C5 C6 Ag3 95.3(7) . . . 2_556 ? C5 C6 C7 C8 -0.3(12) . . . . ? Ag3 C6 C7 C8 -73.1(8) 2_556 . . . ? C5 C6 C7 C10 -179.8(7) . . . . ? Ag3 C6 C7 C10 107.3(7) 2_556 . . . ? C6 C7 C8 C9 -0.4(12) . . . . ? C10 C7 C8 C9 179.2(8) . . . . ? O1 C4 C9 C8 -178.7(7) . . . . ? C5 C4 C9 C8 -0.4(12) . . . . ? C7 C8 C9 C4 0.7(13) . . . . ? C8 C7 C10 C11 148.7(9) . . . . ? C6 C7 C10 C11 -31.7(12) . . . . ? C8 C7 C10 C15 -33.0(12) . . . . ? C6 C7 C10 C15 146.5(9) . . . . ? C15 C10 C11 C12 -0.5(14) . . . . ? C7 C10 C11 C12 177.9(10) . . . . ? C10 C11 C12 C13 -0.6(18) . . . . ? C11 C12 C13 C14 0(2) . . . . ? C12 C13 C14 C15 1(2) . . . . ? C13 C14 C15 C10 -2(2) . . . . ? C11 C10 C15 C14 1.7(15) . . . . ? C7 C10 C15 C14 -176.6(10) . . . . ? Ag3 O3 C16 O2 16.6(12) 2_556 . . . ? Ag3 O3 C16 C17 -165.3(5) 2_556 . . . ? Ag2 O2 C16 O3 22.5(15) . . . . ? Ag2 O2 C16 C17 -155.7(6) . . . . ? O3 C16 C17 F1' 5(3) . . . . ? O2 C16 C17 F1' -177(3) . . . . ? O3 C16 C17 F2' -121(3) . . . . ? O2 C16 C17 F2' 58(3) . . . . ? O3 C16 C17 F3' 127(3) . . . . ? O2 C16 C17 F3' -55(3) . . . . ? O3 C16 C17 F3 160.9(8) . . . . ? O2 C16 C17 F3 -20.7(10) . . . . ? O3 C16 C17 F1 39.2(10) . . . . ? O2 C16 C17 F1 -142.4(8) . . . . ? O3 C16 C17 F2 -77.7(10) . . . . ? O2 C16 C17 F2 100.7(9) . . . . ? Ag3 O5 C18 O4 168.8(6) 6 . . . ? Ag3 O5 C18 C19 -10.2(13) 6 . . . ? Ag1 O4 C18 O5 -7.4(11) . . . . ? Ag1 O4 C18 C19 171.6(4) . . . . ? O5 C18 C19 F4' -24.0(12) . . . . ? O4 C18 C19 F4' 156.9(9) . . . . ? O5 C18 C19 F5' -150.7(9) . . . . ? O4 C18 C19 F5' 30.3(10) . . . . ? O5 C18 C19 F6' 96.5(10) . . . . ? O4 C18 C19 F6' -82.6(10) . . . . ? O5 C18 C19 F6 166.4(9) . . . . ? O4 C18 C19 F6 -12.7(11) . . . . ? O5 C18 C19 F4 47.2(9) . . . . ? O4 C18 C19 F4 -131.9(7) . . . . ? O5 C18 C19 F5 -63.6(9) . . . . ? O4 C18 C19 F5 117.3(7) . . . . ? _diffrn_measured_fraction_theta_max 0.998 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.998 _refine_diff_density_max 1.355 _refine_diff_density_min -1.000 _refine_diff_density_rms 0.174 data_2 _database_code_depnum_ccdc_archive 'CCDC 910771' #TrackingRef '2.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C27 H16 Ag6 F15 N O12' _chemical_formula_weight 1478.63 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1 ' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 11.746(2) _cell_length_b 12.454(3) _cell_length_c 14.005(3) _cell_angle_alpha 76.38(3) _cell_angle_beta 74.67(3) _cell_angle_gamma 87.77(3) _cell_volume 1919.6(7) _cell_formula_units_Z 2 _cell_measurement_temperature 296 _cell_measurement_reflns_used 5547 _cell_measurement_theta_min 1.7982 _cell_measurement_theta_max 29.1423 _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.20 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.18 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.558 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1396 _exptl_absorpt_coefficient_mu 3.132 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.5731 _exptl_absorpt_correction_T_max 0.6025 _exptl_absorpt_process_details SADABS(2009) _exptl_special_details ; ? ; _diffrn_ambient_temperature 296 _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 19407 _diffrn_reflns_av_R_equivalents 0.0280 _diffrn_reflns_av_sigmaI/netI 0.0306 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_h_max 13 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 16 _diffrn_reflns_theta_min 2.43 _diffrn_reflns_theta_max 25.00 _reflns_number_total 6751 _reflns_number_gt 5938 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0452P)^2^+17.4041P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6751 _refine_ls_number_parameters 595 _refine_ls_number_restraints 219 _refine_ls_R_factor_all 0.0594 _refine_ls_R_factor_gt 0.0524 _refine_ls_wR_factor_ref 0.1226 _refine_ls_wR_factor_gt 0.1180 _refine_ls_goodness_of_fit_ref 1.030 _refine_ls_restrained_S_all 1.027 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.65882(5) 0.76629(5) 0.45878(5) 0.04250(17) Uani 1 1 d . . . Ag2 Ag 0.55077(6) 0.61241(5) 0.39314(6) 0.05239(19) Uani 1 1 d . . . Ag3 Ag 0.74778(7) 0.77161(6) 0.22395(6) 0.0582(2) Uani 1 1 d . . . Ag4 Ag 0.57490(6) 0.98233(5) 0.37761(5) 0.04490(17) Uani 1 1 d . . . Ag5 Ag 0.39563(6) 0.76813(6) 0.51085(6) 0.0595(2) Uani 1 1 d . . . Ag6 Ag 0.91435(6) 0.86799(6) 0.02730(5) 0.0553(2) Uani 1 1 d . . . C1 C 0.5442(6) 0.7961(6) 0.3571(5) 0.0336(15) Uani 1 1 d . . . C2 C 0.5120(7) 0.8431(7) 0.2833(6) 0.0422(18) Uani 1 1 d . . . O1 O 0.5489(6) 0.8729(6) 0.1021(5) 0.0629(17) Uani 1 1 d . . . O2 O 0.7747(5) 0.9485(5) 0.2370(4) 0.0489(14) Uani 1 1 d . . . O3 O 0.9253(5) 1.0098(4) 0.0993(4) 0.0416(12) Uani 1 1 d . . . O4 O 0.7637(5) 0.8736(5) 0.5155(5) 0.0530(15) Uani 1 1 d . . . O5 O 0.6588(5) 1.0281(4) 0.4949(4) 0.0443(13) Uani 1 1 d . . . O6 O 0.4869(6) 0.7307(5) 0.6525(5) 0.0603(16) Uani 1 1 d . . . O7 O 0.5124(6) 0.8783(5) 0.7115(5) 0.0579(16) Uani 1 1 d . . . O8 O 0.6222(5) 0.5004(5) 0.5314(5) 0.0573(16) Uani 1 1 d . . . O9 O 0.7527(5) 0.6216(5) 0.5377(5) 0.0546(15) Uani 1 1 d . . . O10 O 0.7352(6) 0.6449(5) 0.1354(5) 0.0660(18) Uani 1 1 d . . . O11 O 0.8728(6) 0.7127(5) -0.0080(5) 0.0643(18) Uani 1 1 d . . . O1W O 0.6170(9) 0.4868(6) 0.2992(6) 0.108(3) Uani 1 1 d . . . H1WA H 0.6131 0.4197 0.3322 0.129 Uiso 1 1 d R . . H1WB H 0.6815 0.5040 0.2534 0.129 Uiso 1 1 d R . . C3 C 0.6260(8) 0.9561(8) 0.0424(6) 0.049(2) Uani 1 1 d . . . C4 C 0.7046(8) 0.9297(8) -0.0422(7) 0.055(2) Uani 1 1 d . . . H4 H 0.7003 0.8598 -0.0541 0.066 Uiso 1 1 calc R . . C5 C 0.7883(8) 1.0052(8) -0.1082(7) 0.054(2) Uani 1 1 d . . . H5 H 0.8403 0.9849 -0.1633 0.065 Uiso 1 1 calc R . . C6 C 0.7970(7) 1.1113(8) -0.0945(6) 0.050(2) Uani 1 1 d . . . C7 C 0.7147(8) 1.1370(8) -0.0099(7) 0.055(2) Uani 1 1 d . . . H7 H 0.7164 1.2077 0.0010 0.067 Uiso 1 1 calc R . . C8 C 0.6319(8) 1.0608(8) 0.0570(7) 0.056(2) Uani 1 1 d . . . H8 H 0.5796 1.0804 0.1124 0.067 Uiso 1 1 calc R . . C9 C 0.8906(8) 1.1927(8) -0.1627(7) 0.053(2) Uani 1 1 d . . . C10 C 0.9502(8) 1.1782(9) -0.2600(7) 0.059(2) Uani 1 1 d . . . H10 H 0.9305 1.1180 -0.2816 0.071 Uiso 1 1 calc R . . C11 C 1.0375(9) 1.2524(10) -0.3236(8) 0.068(3) Uani 1 1 d . . . H11 H 1.0747 1.2421 -0.3881 0.081 Uiso 1 1 calc R . . C12 C 1.0704(9) 1.3410(9) -0.2935(8) 0.067(3) Uani 1 1 d . . . H12 H 1.1302 1.3900 -0.3365 0.080 Uiso 1 1 calc R . . C13 C 1.0123(10) 1.3559(9) -0.1975(9) 0.070(3) Uani 1 1 d . . . H13 H 1.0327 1.4162 -0.1763 0.084 Uiso 1 1 calc R . . C14 C 0.9248(9) 1.2823(8) -0.1333(8) 0.061(2) Uani 1 1 d . . . H14 H 0.8880 1.2931 -0.0689 0.074 Uiso 1 1 calc R . . C15 C 0.8526(7) 1.0170(7) 0.1806(6) 0.0403(17) Uani 1 1 d . C . C16 C 0.8600(6) 1.1214(7) 0.2157(5) 0.051(2) Uani 1 1 d D . . C17 C 0.7349(7) 0.9670(7) 0.5272(6) 0.0411(18) Uani 1 1 d . B . C18 C 0.8025(8) 1.0147(7) 0.5876(7) 0.052(2) Uani 1 1 d . . . C19 C 0.5166(8) 0.7799(7) 0.7099(6) 0.0463(19) Uani 1 1 d . A . C20 C 0.5682(8) 0.7083(7) 0.7912(7) 0.066(3) Uani 1 1 d D . . C21 C 0.7048(7) 0.5299(7) 0.5595(7) 0.0441(19) Uani 1 1 d . D . C23 C 0.7983(9) 0.6445(8) 0.0499(8) 0.057(2) Uani 1 1 d . E . C24 C 0.7827(8) 0.5415(11) 0.0107(7) 0.088(4) Uani 1 1 d D . . C25 C 0.4663(8) 0.8879(9) 0.1926(7) 0.058(2) Uani 1 1 d . . . H25A H 0.3922 0.8505 0.2009 0.069 Uiso 1 1 calc R . . H25B H 0.4515 0.9660 0.1869 0.069 Uiso 1 1 calc R . . C26 C 0.1131(10) 0.6919(8) 0.6088(9) 0.068(3) Uani 1 1 d . . . C27 C -0.0156(11) 0.6767(12) 0.6455(12) 0.104(5) Uani 1 1 d . . . H27A H -0.0511 0.7469 0.6494 0.156 Uiso 1 1 calc R . . H27B H -0.0358 0.6275 0.7118 0.156 Uiso 1 1 calc R . . H27C H -0.0443 0.6459 0.5993 0.156 Uiso 1 1 calc R . . F1 F 0.6813(9) 0.7334(9) 0.7757(9) 0.110(3) Uani 0.716(7) 1 d PDU A 1 F2 F 0.5121(10) 0.7187(10) 0.8839(8) 0.113(3) Uani 0.716(7) 1 d PDU A 1 F3 F 0.5623(8) 0.6007(7) 0.7980(7) 0.085(2) Uani 0.716(7) 1 d PDU A 1 F2' F 0.4848(19) 0.6405(15) 0.8557(17) 0.113(3) Uani 0.284(7) 1 d PDU A 2 F1' F 0.6103(13) 0.760(2) 0.8463(15) 0.110(3) Uani 0.284(7) 1 d PDU A 2 F3' F 0.6568(14) 0.6486(13) 0.7558(17) 0.085(2) Uani 0.284(7) 1 d PDU A 2 F4 F 0.8541(15) 0.9412(9) 0.6439(10) 0.067(2) Uani 0.63(2) 1 d PU B 1 F4' F 0.803(2) 0.9346(14) 0.6754(17) 0.067(2) Uani 0.37(2) 1 d P B 2 F5 F 0.7425(5) 1.0860(6) 0.6354(5) 0.086(2) Uani 1 1 d . B . F6 F 0.8988(5) 1.0683(6) 0.5267(6) 0.096(2) Uani 1 1 d . B . F7 F 0.9061(9) 1.2070(8) 0.1417(8) 0.104(3) Uani 0.726(7) 1 d PDU C 1 F8 F 0.9242(9) 1.1055(9) 0.2814(8) 0.103(3) Uani 0.726(7) 1 d PDU C 1 F9 F 0.7579(7) 1.1562(7) 0.2614(6) 0.069(2) Uani 0.726(7) 1 d PDU C 1 F7' F 0.8004(13) 1.2002(19) 0.1728(12) 0.104(3) Uani 0.274(7) 1 d PDU C 2 F9' F 0.8191(11) 1.1110(16) 0.3138(12) 0.069(2) Uani 0.274(7) 1 d PDU C 2 F8' F 0.9664(16) 1.1614(19) 0.1968(13) 0.103(3) Uani 0.274(7) 1 d PDU C 2 F10 F 0.7763(7) 0.4723(6) 0.7064(5) 0.085(2) Uani 0.907(7) 1 d PD D 1 F11 F 0.7145(8) 0.3443(7) 0.6505(7) 0.106(3) Uani 0.907(7) 1 d PDU D 1 F12 F 0.8691(8) 0.4207(8) 0.5780(8) 0.127(4) Uani 0.907(7) 1 d PD D 1 F10' F 0.658(5) 0.408(3) 0.731(4) 0.085(2) Uani 0.093(7) 1 d PD D 2 F11' F 0.776(2) 0.378(4) 0.536(4) 0.106(3) Uani 0.093(7) 1 d PD D 2 F12' F 0.868(4) 0.530(4) 0.610(2) 0.127(4) Uani 0.093(7) 1 d PD D 2 F13 F 0.8302(12) 0.4574(12) 0.0614(11) 0.138(5) Uani 0.642(8) 1 d PDU E 1 F14 F 0.8338(11) 0.5506(10) -0.0874(8) 0.105(3) Uani 0.642(8) 1 d PDU E 1 F15 F 0.6701(10) 0.5186(11) 0.0249(10) 0.115(4) Uani 0.642(8) 1 d PDU E 1 F13' F 0.8853(17) 0.5026(19) -0.0248(12) 0.138(5) Uani 0.358(8) 1 d PDU E 2 F14' F 0.7283(13) 0.5612(17) -0.0606(12) 0.105(3) Uani 0.358(8) 1 d PDU E 2 F15' F 0.7245(14) 0.4576(16) 0.0777(16) 0.115(4) Uani 0.358(8) 1 d PDU E 2 N1 N 0.2120(8) 0.7049(7) 0.5812(7) 0.070(2) Uani 1 1 d . . . C22 C 0.7620(8) 0.4425(7) 0.6272(7) 0.075(3) Uani 1 1 d D . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0481(4) 0.0368(3) 0.0495(4) -0.0114(3) -0.0235(3) 0.0015(3) Ag2 0.0673(4) 0.0318(3) 0.0636(4) -0.0107(3) -0.0258(4) -0.0069(3) Ag3 0.0612(4) 0.0453(4) 0.0612(4) -0.0202(3) 0.0034(3) -0.0034(3) Ag4 0.0500(4) 0.0355(3) 0.0525(4) -0.0125(3) -0.0176(3) 0.0040(3) Ag5 0.0488(4) 0.0615(5) 0.0630(5) -0.0177(4) -0.0037(3) 0.0034(3) Ag6 0.0611(4) 0.0483(4) 0.0519(4) -0.0183(3) 0.0010(3) -0.0132(3) C1 0.038(4) 0.028(4) 0.037(4) -0.007(3) -0.014(3) 0.000(3) C2 0.037(4) 0.041(4) 0.045(5) -0.006(4) -0.009(4) 0.001(3) O1 0.075(5) 0.069(4) 0.047(4) -0.013(3) -0.022(3) 0.007(4) O2 0.044(3) 0.051(3) 0.048(3) -0.014(3) -0.001(3) -0.010(3) O3 0.041(3) 0.045(3) 0.039(3) -0.016(2) -0.004(2) -0.001(2) O4 0.051(3) 0.046(3) 0.077(4) -0.030(3) -0.031(3) 0.009(3) O5 0.044(3) 0.044(3) 0.051(3) -0.017(3) -0.019(3) 0.004(3) O6 0.072(4) 0.060(4) 0.053(4) -0.018(3) -0.019(3) 0.004(3) O7 0.071(4) 0.039(3) 0.062(4) -0.011(3) -0.017(3) 0.012(3) O8 0.059(4) 0.048(3) 0.069(4) 0.005(3) -0.038(3) -0.014(3) O9 0.053(4) 0.037(3) 0.075(4) -0.002(3) -0.030(3) -0.002(3) O10 0.066(4) 0.056(4) 0.072(5) -0.027(3) 0.003(4) -0.014(3) O11 0.075(5) 0.049(4) 0.063(4) -0.018(3) -0.002(3) -0.009(3) O1W 0.178(10) 0.058(5) 0.069(5) -0.027(4) 0.014(6) -0.023(5) C3 0.050(5) 0.062(6) 0.038(4) -0.006(4) -0.024(4) 0.012(4) C4 0.065(6) 0.063(6) 0.049(5) -0.025(5) -0.030(5) 0.022(5) C5 0.054(5) 0.071(6) 0.047(5) -0.024(5) -0.022(4) 0.020(5) C6 0.045(5) 0.069(6) 0.044(5) -0.024(4) -0.021(4) 0.022(4) C7 0.051(5) 0.061(6) 0.062(6) -0.029(5) -0.017(4) 0.016(4) C8 0.049(5) 0.076(7) 0.051(5) -0.028(5) -0.018(4) 0.020(5) C9 0.046(5) 0.071(6) 0.047(5) -0.018(4) -0.021(4) 0.025(4) C10 0.055(6) 0.077(7) 0.050(5) -0.020(5) -0.021(4) 0.016(5) C11 0.058(6) 0.094(8) 0.050(6) -0.014(6) -0.018(5) 0.019(6) C12 0.051(6) 0.076(7) 0.065(6) -0.006(6) -0.014(5) 0.015(5) C13 0.069(7) 0.063(7) 0.082(8) -0.017(6) -0.026(6) 0.006(5) C14 0.065(6) 0.066(6) 0.057(6) -0.019(5) -0.023(5) 0.015(5) C15 0.035(4) 0.046(5) 0.040(4) -0.013(4) -0.008(3) 0.000(3) C16 0.044(5) 0.062(6) 0.042(5) -0.018(4) 0.008(4) -0.017(4) C17 0.039(4) 0.042(5) 0.043(4) -0.015(4) -0.006(3) -0.007(4) C18 0.057(5) 0.049(5) 0.060(5) -0.028(4) -0.021(5) 0.011(4) C19 0.050(5) 0.046(5) 0.040(4) -0.011(4) -0.007(4) 0.007(4) C20 0.098(8) 0.040(5) 0.064(6) -0.022(5) -0.019(6) 0.005(5) C21 0.041(4) 0.039(4) 0.055(5) -0.011(4) -0.019(4) 0.007(4) C23 0.059(6) 0.045(5) 0.067(6) -0.018(5) -0.011(5) 0.006(4) C24 0.078(8) 0.108(10) 0.073(8) -0.034(7) 0.000(6) -0.008(7) C25 0.052(5) 0.075(7) 0.048(5) -0.006(5) -0.022(4) 0.010(5) C26 0.065(7) 0.053(6) 0.084(7) -0.027(5) -0.008(6) -0.007(5) C27 0.069(8) 0.098(10) 0.136(12) -0.035(9) 0.000(8) -0.028(7) F1 0.109(4) 0.111(4) 0.111(4) -0.0225(16) -0.0330(17) 0.0023(14) F2 0.115(4) 0.112(4) 0.110(4) -0.0252(16) -0.0297(16) 0.0054(14) F3 0.087(3) 0.083(3) 0.085(3) -0.0189(15) -0.0238(15) 0.0059(14) F2' 0.115(4) 0.112(4) 0.110(4) -0.0252(16) -0.0297(16) 0.0054(14) F1' 0.109(4) 0.111(4) 0.111(4) -0.0225(16) -0.0330(17) 0.0023(14) F3' 0.087(3) 0.083(3) 0.085(3) -0.0189(15) -0.0238(15) 0.0059(14) F4 0.068(2) 0.068(2) 0.067(2) -0.0161(11) -0.0191(12) 0.0014(10) F4' 0.068(2) 0.068(2) 0.067(2) -0.0161(11) -0.0191(12) 0.0014(10) F5 0.072(4) 0.109(5) 0.116(5) -0.087(4) -0.042(4) 0.028(4) F6 0.054(4) 0.117(6) 0.127(6) -0.057(5) -0.014(4) -0.023(4) F7 0.106(3) 0.102(3) 0.105(3) -0.0270(16) -0.0235(16) 0.0009(14) F8 0.104(3) 0.104(3) 0.105(3) -0.0290(16) -0.0302(16) 0.0016(14) F9 0.069(2) 0.066(2) 0.070(2) -0.0203(14) -0.0123(14) 0.0014(14) F7' 0.106(3) 0.102(3) 0.105(3) -0.0270(16) -0.0235(16) 0.0009(14) F9' 0.069(2) 0.066(2) 0.070(2) -0.0203(14) -0.0123(14) 0.0014(14) F8' 0.104(3) 0.104(3) 0.105(3) -0.0290(16) -0.0302(16) 0.0016(14) F10 0.129(6) 0.065(4) 0.078(5) -0.006(4) -0.065(5) 0.010(4) F11 0.107(3) 0.105(3) 0.107(3) -0.0230(12) -0.0305(12) 0.0017(10) F12 0.123(7) 0.131(8) 0.155(9) -0.052(7) -0.080(7) 0.085(6) F10' 0.129(6) 0.065(4) 0.078(5) -0.006(4) -0.065(5) 0.010(4) F11' 0.107(3) 0.105(3) 0.107(3) -0.0230(12) -0.0305(12) 0.0017(10) F12' 0.123(7) 0.131(8) 0.155(9) -0.052(7) -0.080(7) 0.085(6) F13 0.138(5) 0.137(5) 0.138(5) -0.0325(12) -0.0361(14) 0.0037(7) F14 0.108(4) 0.105(4) 0.105(4) -0.0271(16) -0.0276(16) 0.0012(14) F15 0.115(4) 0.114(4) 0.115(4) -0.0294(17) -0.0291(17) -0.0006(14) F13' 0.138(5) 0.137(5) 0.138(5) -0.0325(12) -0.0361(14) 0.0037(7) F14' 0.108(4) 0.105(4) 0.105(4) -0.0271(16) -0.0276(16) 0.0012(14) F15' 0.115(4) 0.114(4) 0.115(4) -0.0294(17) -0.0291(17) -0.0006(14) N1 0.060(5) 0.069(6) 0.081(6) -0.035(5) -0.005(5) -0.005(4) C22 0.091(8) 0.036(5) 0.115(10) -0.004(5) -0.069(8) -0.008(5) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 C1 2.169(7) . ? Ag1 O4 2.254(6) . ? Ag1 O9 2.288(6) . ? Ag1 Ag2 2.7865(11) . ? Ag1 Ag4 2.9067(12) . ? Ag1 Ag5 2.9831(12) . ? Ag1 Ag3 3.1619(13) . ? Ag2 C1 2.227(7) . ? Ag2 O1W 2.262(8) . ? Ag2 O8 2.368(6) 2_666 ? Ag2 O8 2.428(6) . ? Ag2 Ag5 3.0725(14) . ? Ag2 Ag3 3.1853(17) . ? Ag3 O10 2.256(6) . ? Ag3 O2 2.294(6) . ? Ag3 C1 2.672(7) . ? Ag3 Ag6 2.9376(16) . ? Ag4 O7 2.267(6) 2_676 ? Ag4 O5 2.309(5) . ? Ag4 C1 2.455(7) . ? Ag4 C2 2.644(8) . ? Ag4 Ag5 3.3239(17) . ? Ag5 N1 2.210(9) . ? Ag5 C1 2.348(7) . ? Ag5 O6 2.440(6) . ? Ag5 O5 2.581(5) 2_676 ? Ag6 O11 2.208(6) . ? Ag6 O3 2.253(5) . ? Ag6 O3 2.489(5) 2_775 ? C1 C2 1.207(11) . ? C2 C25 1.489(11) . ? O1 C3 1.363(11) . ? O1 C25 1.425(11) . ? O2 C15 1.245(9) . ? O3 C15 1.249(9) . ? O3 Ag6 2.489(5) 2_775 ? O4 C17 1.234(10) . ? O5 C17 1.259(10) . ? O5 Ag5 2.581(5) 2_676 ? O6 C19 1.241(10) . ? O7 C19 1.230(10) . ? O7 Ag4 2.267(6) 2_676 ? O8 C21 1.237(10) . ? O8 Ag2 2.368(6) 2_666 ? O9 C21 1.228(10) . ? O10 C23 1.231(11) . ? O11 C23 1.226(11) . ? O1W H1WA 0.8500 . ? O1W H1WB 0.8500 . ? C3 C8 1.374(13) . ? C3 C4 1.394(12) . ? C4 C5 1.373(14) . ? C4 H4 0.9300 . ? C5 C6 1.391(13) . ? C5 H5 0.9300 . ? C6 C7 1.410(12) . ? C6 C9 1.491(13) . ? C7 C8 1.377(14) . ? C7 H7 0.9300 . ? C8 H8 0.9300 . ? C9 C14 1.383(14) . ? C9 C10 1.407(12) . ? C10 C11 1.378(15) . ? C10 H10 0.9300 . ? C11 C12 1.373(15) . ? C11 H11 0.9300 . ? C12 C13 1.389(15) . ? C12 H12 0.9300 . ? C13 C14 1.379(15) . ? C13 H13 0.9300 . ? C14 H14 0.9300 . ? C15 C16 1.507(12) . ? C16 F9' 1.307(16) . ? C16 F8' 1.301(17) . ? C16 F7' 1.306(17) . ? C16 F8 1.313(9) . ? C16 F7 1.316(9) . ? C16 F9 1.312(8) . ? C17 C18 1.526(12) . ? C18 F5 1.310(10) . ? C18 F6 1.316(11) . ? C18 F4 1.303(13) . ? C18 F4' 1.39(2) . ? C19 C20 1.518(13) . ? C20 F1' 1.311(18) . ? C20 F2' 1.313(18) . ? C20 F3' 1.313(18) . ? C20 F2 1.325(10) . ? C20 F3 1.324(9) . ? C20 F1 1.326(10) . ? C21 C22 1.526(12) . ? C23 C24 1.543(16) . ? C24 F14' 1.294(16) . ? C24 F15' 1.302(17) . ? C24 F13' 1.298(17) . ? C24 F13 1.314(11) . ? C24 F15 1.316(11) . ? C24 F14 1.326(11) . ? C25 H25A 0.9700 . ? C25 H25B 0.9700 . ? C26 N1 1.129(12) . ? C26 C27 1.466(16) . ? C27 H27A 0.9600 . ? C27 H27B 0.9600 . ? C27 H27C 0.9600 . ? F10 C22 1.301(8) . ? F11 C22 1.297(8) . ? F12 C22 1.316(8) . ? F10' C22 1.62(5) . ? F11' C22 1.63(5) . ? F12' C22 1.63(5) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Ag1 O4 135.2(2) . . ? C1 Ag1 O9 138.6(2) . . ? O4 Ag1 O9 85.5(2) . . ? C1 Ag1 Ag2 51.59(18) . . ? O4 Ag1 Ag2 172.49(15) . . ? O9 Ag1 Ag2 87.34(15) . . ? C1 Ag1 Ag4 55.58(18) . . ? O4 Ag1 Ag4 80.10(15) . . ? O9 Ag1 Ag4 165.65(15) . . ? Ag2 Ag1 Ag4 107.00(3) . . ? C1 Ag1 Ag5 51.3(2) . . ? O4 Ag1 Ag5 121.72(16) . . ? O9 Ag1 Ag5 120.07(16) . . ? Ag2 Ag1 Ag5 64.25(3) . . ? Ag4 Ag1 Ag5 68.70(4) . . ? C1 Ag1 Ag3 56.5(2) . . ? O4 Ag1 Ag3 115.37(17) . . ? O9 Ag1 Ag3 105.34(18) . . ? Ag2 Ag1 Ag3 64.39(4) . . ? Ag4 Ag1 Ag3 81.01(4) . . ? Ag5 Ag1 Ag3 106.95(4) . . ? C1 Ag2 O1W 134.0(3) . . ? C1 Ag2 O8 121.9(2) . 2_666 ? O1W Ag2 O8 87.0(3) . 2_666 ? C1 Ag2 O8 124.9(2) . . ? O1W Ag2 O8 89.8(3) . . ? O8 Ag2 O8 84.3(2) 2_666 . ? C1 Ag2 Ag1 49.74(18) . . ? O1W Ag2 Ag1 134.6(3) . . ? O8 Ag2 Ag1 132.86(17) 2_666 . ? O8 Ag2 Ag1 76.39(14) . . ? C1 Ag2 Ag5 49.50(19) . . ? O1W Ag2 Ag5 164.1(3) . . ? O8 Ag2 Ag5 80.45(17) 2_666 . ? O8 Ag2 Ag5 98.51(17) . . ? Ag1 Ag2 Ag5 60.98(3) . . ? C1 Ag2 Ag3 55.84(19) . . ? O1W Ag2 Ag3 84.4(2) . . ? O8 Ag2 Ag3 159.80(15) 2_666 . ? O8 Ag2 Ag3 113.88(15) . . ? Ag1 Ag2 Ag3 63.53(3) . . ? Ag5 Ag2 Ag3 104.23(4) . . ? O10 Ag3 O2 152.9(2) . . ? O10 Ag3 C1 113.1(2) . . ? O2 Ag3 C1 79.9(2) . . ? O10 Ag3 Ag6 79.17(17) . . ? O2 Ag3 Ag6 77.74(14) . . ? C1 Ag3 Ag6 145.91(15) . . ? O10 Ag3 Ag1 131.70(18) . . ? O2 Ag3 Ag1 74.32(14) . . ? C1 Ag3 Ag1 42.62(15) . . ? Ag6 Ag3 Ag1 147.12(3) . . ? O10 Ag3 Ag2 81.60(17) . . ? O2 Ag3 Ag2 120.07(14) . . ? C1 Ag3 Ag2 43.60(15) . . ? Ag6 Ag3 Ag2 160.60(3) . . ? Ag1 Ag3 Ag2 52.08(3) . . ? O7 Ag4 O5 116.0(2) 2_676 . ? O7 Ag4 C1 116.3(2) 2_676 . ? O5 Ag4 C1 127.0(2) . . ? O7 Ag4 C2 90.1(2) 2_676 . ? O5 Ag4 C2 153.9(2) . . ? C1 Ag4 C2 27.1(2) . . ? O7 Ag4 Ag1 163.05(17) 2_676 . ? O5 Ag4 Ag1 80.93(14) . . ? C1 Ag4 Ag1 46.79(17) . . ? C2 Ag4 Ag1 72.95(17) . . ? O7 Ag4 Ag5 114.29(17) 2_676 . ? O5 Ag4 Ag5 104.25(14) . . ? C1 Ag4 Ag5 44.88(17) . . ? C2 Ag4 Ag5 60.15(17) . . ? Ag1 Ag4 Ag5 56.74(3) . . ? N1 Ag5 C1 141.8(3) . . ? N1 Ag5 O6 104.1(3) . . ? C1 Ag5 O6 109.1(2) . . ? N1 Ag5 O5 94.1(3) . 2_676 ? C1 Ag5 O5 98.2(2) . 2_676 ? O6 Ag5 O5 99.8(2) . 2_676 ? N1 Ag5 Ag1 157.9(3) . . ? C1 Ag5 Ag1 46.13(18) . . ? O6 Ag5 Ag1 62.99(16) . . ? O5 Ag5 Ag1 105.41(13) 2_676 . ? N1 Ag5 Ag2 112.9(2) . . ? C1 Ag5 Ag2 46.15(17) . . ? O6 Ag5 Ag2 95.85(16) . . ? O5 Ag5 Ag2 144.24(13) 2_676 . ? Ag1 Ag5 Ag2 54.77(3) . . ? N1 Ag5 Ag4 147.4(2) . . ? C1 Ag5 Ag4 47.54(17) . . ? O6 Ag5 Ag4 94.16(16) . . ? O5 Ag5 Ag4 55.80(13) 2_676 . ? Ag1 Ag5 Ag4 54.56(3) . . ? Ag2 Ag5 Ag4 91.30(3) . . ? O11 Ag6 O3 166.2(2) . . ? O11 Ag6 O3 117.6(2) . 2_775 ? O3 Ag6 O3 76.11(19) . 2_775 ? O11 Ag6 Ag3 82.29(17) . . ? O3 Ag6 Ag3 83.96(14) . . ? O3 Ag6 Ag3 158.91(12) 2_775 . ? C2 C1 Ag1 155.6(6) . . ? C2 C1 Ag2 118.9(6) . . ? Ag1 C1 Ag2 78.7(2) . . ? C2 C1 Ag5 114.2(6) . . ? Ag1 C1 Ag5 82.6(2) . . ? Ag2 C1 Ag5 84.3(2) . . ? C2 C1 Ag4 85.2(5) . . ? Ag1 C1 Ag4 77.6(2) . . ? Ag2 C1 Ag4 155.8(3) . . ? Ag5 C1 Ag4 87.6(2) . . ? C2 C1 Ag3 85.5(5) . . ? Ag1 C1 Ag3 80.8(2) . . ? Ag2 C1 Ag3 80.6(2) . . ? Ag5 C1 Ag3 159.4(3) . . ? Ag4 C1 Ag3 100.6(2) . . ? C1 C2 C25 173.1(9) . . ? C1 C2 Ag4 67.7(5) . . ? C25 C2 Ag4 119.0(6) . . ? C3 O1 C25 120.5(8) . . ? C15 O2 Ag3 127.0(5) . . ? C15 O3 Ag6 120.9(5) . . ? C15 O3 Ag6 134.9(5) . 2_775 ? Ag6 O3 Ag6 103.89(19) . 2_775 ? C17 O4 Ag1 124.1(5) . . ? C17 O5 Ag4 120.0(5) . . ? C17 O5 Ag5 133.7(5) . 2_676 ? Ag4 O5 Ag5 104.0(2) . 2_676 ? C19 O6 Ag5 139.7(6) . . ? C19 O7 Ag4 129.0(6) . 2_676 ? C21 O8 Ag2 136.7(6) . 2_666 ? C21 O8 Ag2 123.3(5) . . ? Ag2 O8 Ag2 95.7(2) 2_666 . ? C21 O9 Ag1 116.7(5) . . ? C23 O10 Ag3 124.9(6) . . ? C23 O11 Ag6 123.4(6) . . ? Ag2 O1W H1WA 115.9 . . ? Ag2 O1W H1WB 115.7 . . ? H1WA O1W H1WB 113.2 . . ? O1 C3 C8 126.7(8) . . ? O1 C3 C4 114.9(9) . . ? C8 C3 C4 118.4(9) . . ? C5 C4 C3 121.1(9) . . ? C5 C4 H4 119.4 . . ? C3 C4 H4 119.4 . . ? C6 C5 C4 121.6(9) . . ? C6 C5 H5 119.2 . . ? C4 C5 H5 119.2 . . ? C5 C6 C7 116.3(9) . . ? C5 C6 C9 122.3(8) . . ? C7 C6 C9 121.4(8) . . ? C8 C7 C6 122.1(9) . . ? C8 C7 H7 119.0 . . ? C6 C7 H7 119.0 . . ? C7 C8 C3 120.4(9) . . ? C7 C8 H8 119.8 . . ? C3 C8 H8 119.8 . . ? C14 C9 C10 117.5(10) . . ? C14 C9 C6 122.5(8) . . ? C10 C9 C6 120.0(9) . . ? C11 C10 C9 120.7(10) . . ? C11 C10 H10 119.7 . . ? C9 C10 H10 119.7 . . ? C10 C11 C12 121.3(10) . . ? C10 C11 H11 119.4 . . ? C12 C11 H11 119.4 . . ? C13 C12 C11 118.5(10) . . ? C13 C12 H12 120.7 . . ? C11 C12 H12 120.7 . . ? C14 C13 C12 120.7(11) . . ? C14 C13 H13 119.6 . . ? C12 C13 H13 119.6 . . ? C9 C14 C13 121.4(10) . . ? C9 C14 H14 119.3 . . ? C13 C14 H14 119.3 . . ? O3 C15 O2 128.3(8) . . ? O3 C15 C16 116.3(7) . . ? O2 C15 C16 115.5(6) . . ? F9' C16 F8' 103.1(11) . . ? F9' C16 F7' 106.1(10) . . ? F8' C16 F7' 106.2(11) . . ? F9' C16 F8 54.6(4) . . ? F8' C16 F8 55.1(4) . . ? F7' C16 F8 138.8(15) . . ? F9' C16 F7 131.5(13) . . ? F8' C16 F7 55.2(4) . . ? F7' C16 F7 54.6(4) . . ? F8 C16 F7 107.7(7) . . ? F9' C16 F9 54.3(4) . . ? F8' C16 F9 130.6(15) . . ? F7' C16 F9 55.0(4) . . ? F8 C16 F9 106.2(7) . . ? F7 C16 F9 103.9(7) . . ? F9' C16 C15 114.5(11) . . ? F8' C16 C15 114.9(14) . . ? F7' C16 C15 111.2(14) . . ? F8 C16 C15 110.0(8) . . ? F7 C16 C15 114.0(8) . . ? F9 C16 C15 114.5(7) . . ? O4 C17 O5 128.6(7) . . ? O4 C17 C18 115.3(7) . . ? O5 C17 C18 116.1(7) . . ? F5 C18 F6 105.8(8) . . ? F5 C18 F4 113.7(10) . . ? F6 C18 F4 97.2(10) . . ? F5 C18 F4' 95.3(12) . . ? F6 C18 F4' 123.0(13) . . ? F5 C18 C17 113.6(7) . . ? F6 C18 C17 110.6(7) . . ? F4 C18 C17 114.3(8) . . ? F4' C18 C17 107.8(10) . . ? O7 C19 O6 130.7(8) . . ? O7 C19 C20 113.8(8) . . ? O6 C19 C20 115.5(7) . . ? F1' C20 F2' 105.9(12) . . ? F1' C20 F3' 103.5(12) . . ? F2' C20 F3' 107.8(10) . . ? F1' C20 F2 54.8(4) . . ? F2' C20 F2 54.9(4) . . ? F3' C20 F2 133.6(15) . . ? F1' C20 F3 128.7(16) . . ? F2' C20 F3 55.1(4) . . ? F3' C20 F3 54.9(4) . . ? F2 C20 F3 103.7(8) . . ? F1' C20 F1 55.0(4) . . ? F2' C20 F1 139.9(16) . . ? F3' C20 F1 54.9(4) . . ? F2 C20 F1 107.7(8) . . ? F3 C20 F1 106.1(8) . . ? F1' C20 C19 116.3(14) . . ? F2' C20 C19 108.6(15) . . ? F3' C20 C19 114.1(13) . . ? F2 C20 C19 112.3(9) . . ? F3 C20 C19 114.9(8) . . ? F1 C20 C19 111.4(9) . . ? O9 C21 O8 129.0(8) . . ? O9 C21 C22 112.9(7) . . ? O8 C21 C22 118.1(7) . . ? O11 C23 O10 129.7(9) . . ? O11 C23 C24 115.3(8) . . ? O10 C23 C24 115.0(8) . . ? F14' C24 F15' 104.3(12) . . ? F14' C24 F13' 108.0(11) . . ? F15' C24 F13' 104.3(13) . . ? F14' C24 F13 138.4(17) . . ? F15' C24 F13 54.7(5) . . ? F13' C24 F13 55.7(5) . . ? F14' C24 F15 55.5(5) . . ? F15' C24 F15 55.4(5) . . ? F13' C24 F15 139.3(18) . . ? F13 C24 F15 109.1(8) . . ? F14' C24 F14 54.9(5) . . ? F15' C24 F14 129.0(16) . . ? F13' C24 F14 55.6(5) . . ? F13 C24 F14 107.2(9) . . ? F15 C24 F14 106.7(8) . . ? F14' C24 C23 113.4(14) . . ? F15' C24 C23 116.5(14) . . ? F13' C24 C23 109.7(15) . . ? F13 C24 C23 108.3(11) . . ? F15 C24 C23 111.0(10) . . ? F14 C24 C23 114.5(10) . . ? O1 C25 C2 110.8(7) . . ? O1 C25 H25A 109.5 . . ? C2 C25 H25A 109.5 . . ? O1 C25 H25B 109.5 . . ? C2 C25 H25B 109.5 . . ? H25A C25 H25B 108.1 . . ? N1 C26 C27 179.0(12) . . ? C26 C27 H27A 109.5 . . ? C26 C27 H27B 109.5 . . ? H27A C27 H27B 109.5 . . ? C26 C27 H27C 109.5 . . ? H27A C27 H27C 109.5 . . ? H27B C27 H27C 109.5 . . ? C26 N1 Ag5 167.1(9) . . ? F10 C22 F11 112.4(8) . . ? F10 C22 F12 104.5(8) . . ? F11 C22 F12 98.8(9) . . ? F10 C22 F10' 62.9(7) . . ? F11 C22 F10' 62.4(7) . . ? F12 C22 F10' 146(2) . . ? F10 C22 F12' 62.0(7) . . ? F11 C22 F12' 154.4(18) . . ? F12 C22 F12' 61.7(7) . . ? F10' C22 F12' 123.7(8) . . ? F10 C22 F11' 162.1(18) . . ? F11 C22 F11' 62.1(8) . . ? F12 C22 F11' 61.8(8) . . ? F10' C22 F11' 121.0(6) . . ? F12' C22 F11' 114.9(8) . . ? F10 C22 C21 113.7(7) . . ? F11 C22 C21 114.5(8) . . ? F12 C22 C21 111.5(7) . . ? F10' C22 C21 103(2) . . ? F12' C22 C21 89.3(19) . . ? F11' C22 C21 83.2(19) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag O9 Ag1 Ag2 C1 -174.8(3) . . . . ? Ag4 Ag1 Ag2 C1 4.5(2) . . . . ? Ag5 Ag1 Ag2 C1 59.8(2) . . . . ? Ag3 Ag1 Ag2 C1 -66.4(2) . . . . ? C1 Ag1 Ag2 O1W 116.4(4) . . . . ? O9 Ag1 Ag2 O1W -58.4(4) . . . . ? Ag4 Ag1 Ag2 O1W 120.8(3) . . . . ? Ag5 Ag1 Ag2 O1W 176.1(3) . . . . ? Ag3 Ag1 Ag2 O1W 50.0(3) . . . . ? C1 Ag1 Ag2 O8 -99.1(3) . . . 2_666 ? O9 Ag1 Ag2 O8 86.1(3) . . . 2_666 ? Ag4 Ag1 Ag2 O8 -94.6(2) . . . 2_666 ? Ag5 Ag1 Ag2 O8 -39.3(2) . . . 2_666 ? Ag3 Ag1 Ag2 O8 -165.5(2) . . . 2_666 ? C1 Ag1 Ag2 O8 -167.7(3) . . . . ? O9 Ag1 Ag2 O8 17.4(2) . . . . ? Ag4 Ag1 Ag2 O8 -163.27(17) . . . . ? Ag5 Ag1 Ag2 O8 -107.97(17) . . . . ? Ag3 Ag1 Ag2 O8 125.86(17) . . . . ? C1 Ag1 Ag2 Ag5 -59.8(2) . . . . ? O9 Ag1 Ag2 Ag5 125.41(17) . . . . ? Ag4 Ag1 Ag2 Ag5 -55.30(4) . . . . ? Ag3 Ag1 Ag2 Ag5 -126.17(4) . . . . ? C1 Ag1 Ag2 Ag3 66.4(2) . . . . ? O9 Ag1 Ag2 Ag3 -108.42(17) . . . . ? Ag4 Ag1 Ag2 Ag3 70.87(4) . . . . ? Ag5 Ag1 Ag2 Ag3 126.17(4) . . . . ? C1 Ag1 Ag3 O10 -79.0(3) . . . . ? O4 Ag1 Ag3 O10 152.1(3) . . . . ? O9 Ag1 Ag3 O10 59.8(3) . . . . ? Ag2 Ag1 Ag3 O10 -19.6(3) . . . . ? Ag4 Ag1 Ag3 O10 -133.4(3) . . . . ? Ag5 Ag1 Ag3 O10 -69.1(3) . . . . ? C1 Ag1 Ag3 O2 92.1(3) . . . . ? O4 Ag1 Ag3 O2 -36.9(2) . . . . ? O9 Ag1 Ag3 O2 -129.2(2) . . . . ? Ag2 Ag1 Ag3 O2 151.45(16) . . . . ? Ag4 Ag1 Ag3 O2 37.62(15) . . . . ? Ag5 Ag1 Ag3 O2 101.98(16) . . . . ? O4 Ag1 Ag3 C1 -128.9(3) . . . . ? O9 Ag1 Ag3 C1 138.7(3) . . . . ? Ag2 Ag1 Ag3 C1 59.4(2) . . . . ? Ag4 Ag1 Ag3 C1 -54.4(2) . . . . ? Ag5 Ag1 Ag3 C1 9.9(2) . . . . ? C1 Ag1 Ag3 Ag6 124.9(2) . . . . ? O4 Ag1 Ag3 Ag6 -4.05(18) . . . . ? O9 Ag1 Ag3 Ag6 -96.40(16) . . . . ? Ag2 Ag1 Ag3 Ag6 -175.74(7) . . . . ? Ag4 Ag1 Ag3 Ag6 70.43(6) . . . . ? Ag5 Ag1 Ag3 Ag6 134.79(6) . . . . ? C1 Ag1 Ag3 Ag2 -59.4(2) . . . . ? O4 Ag1 Ag3 Ag2 171.69(16) . . . . ? O9 Ag1 Ag3 Ag2 79.34(15) . . . . ? Ag4 Ag1 Ag3 Ag2 -113.84(3) . . . . ? Ag5 Ag1 Ag3 Ag2 -49.47(3) . . . . ? C1 Ag2 Ag3 O10 -137.0(3) . . . . ? O1W Ag2 Ag3 O10 18.6(3) . . . . ? O8 Ag2 Ag3 O10 -46.8(5) 2_666 . . . ? O8 Ag2 Ag3 O10 105.9(3) . . . . ? Ag1 Ag2 Ag3 O10 165.3(2) . . . . ? Ag5 Ag2 Ag3 O10 -147.9(2) . . . . ? C1 Ag2 Ag3 O2 25.6(3) . . . . ? O1W Ag2 Ag3 O2 -178.9(3) . . . . ? O8 Ag2 Ag3 O2 115.8(5) 2_666 . . . ? O8 Ag2 Ag3 O2 -91.6(3) . . . . ? Ag1 Ag2 Ag3 O2 -32.12(18) . . . . ? Ag5 Ag2 Ag3 O2 14.62(18) . . . . ? O1W Ag2 Ag3 C1 155.5(4) . . . . ? O8 Ag2 Ag3 C1 90.2(5) 2_666 . . . ? O8 Ag2 Ag3 C1 -117.2(3) . . . . ? Ag1 Ag2 Ag3 C1 -57.7(2) . . . . ? Ag5 Ag2 Ag3 C1 -11.0(2) . . . . ? C1 Ag2 Ag3 Ag6 -129.3(2) . . . . ? O1W Ag2 Ag3 Ag6 26.3(3) . . . . ? O8 Ag2 Ag3 Ag6 -39.1(5) 2_666 . . . ? O8 Ag2 Ag3 Ag6 113.6(2) . . . . ? Ag1 Ag2 Ag3 Ag6 173.03(11) . . . . ? Ag5 Ag2 Ag3 Ag6 -140.23(10) . . . . ? C1 Ag2 Ag3 Ag1 57.7(2) . . . . ? O1W Ag2 Ag3 Ag1 -146.8(3) . . . . ? O8 Ag2 Ag3 Ag1 147.9(5) 2_666 . . . ? O8 Ag2 Ag3 Ag1 -59.47(18) . . . . ? Ag5 Ag2 Ag3 Ag1 46.74(3) . . . . ? C1 Ag1 Ag4 O7 -5.4(6) . . . 2_676 ? O4 Ag1 Ag4 O7 167.8(6) . . . 2_676 ? O9 Ag1 Ag4 O7 167.4(9) . . . 2_676 ? Ag2 Ag1 Ag4 O7 -9.7(6) . . . 2_676 ? Ag5 Ag1 Ag4 O7 -62.3(6) . . . 2_676 ? Ag3 Ag1 Ag4 O7 49.9(6) . . . 2_676 ? C1 Ag1 Ag4 O5 170.6(3) . . . . ? O4 Ag1 Ag4 O5 -16.1(2) . . . . ? O9 Ag1 Ag4 O5 -16.5(7) . . . . ? Ag2 Ag1 Ag4 O5 166.40(14) . . . . ? Ag5 Ag1 Ag4 O5 113.76(15) . . . . ? Ag3 Ag1 Ag4 O5 -134.00(14) . . . . ? O4 Ag1 Ag4 C1 173.3(3) . . . . ? O9 Ag1 Ag4 C1 172.9(7) . . . . ? Ag2 Ag1 Ag4 C1 -4.2(2) . . . . ? Ag5 Ag1 Ag4 C1 -56.9(2) . . . . ? Ag3 Ag1 Ag4 C1 55.4(2) . . . . ? C1 Ag1 Ag4 C2 -8.2(3) . . . . ? O4 Ag1 Ag4 C2 165.1(2) . . . . ? O9 Ag1 Ag4 C2 164.7(7) . . . . ? Ag2 Ag1 Ag4 C2 -12.44(18) . . . . ? Ag5 Ag1 Ag4 C2 -65.08(18) . . . . ? Ag3 Ag1 Ag4 C2 47.17(18) . . . . ? C1 Ag1 Ag4 Ag5 56.9(2) . . . . ? O4 Ag1 Ag4 Ag5 -129.86(17) . . . . ? O9 Ag1 Ag4 Ag5 -130.2(7) . . . . ? Ag2 Ag1 Ag4 Ag5 52.64(3) . . . . ? Ag3 Ag1 Ag4 Ag5 112.24(4) . . . . ? C1 Ag1 Ag5 N1 122.1(6) . . . . ? O4 Ag1 Ag5 N1 -112.9(6) . . . . ? O9 Ag1 Ag5 N1 -8.3(6) . . . . ? Ag2 Ag1 Ag5 N1 61.9(6) . . . . ? Ag4 Ag1 Ag5 N1 -175.6(6) . . . . ? Ag3 Ag1 Ag5 N1 111.5(6) . . . . ? O4 Ag1 Ag5 C1 125.0(3) . . . . ? O9 Ag1 Ag5 C1 -130.4(3) . . . . ? Ag2 Ag1 Ag5 C1 -60.2(2) . . . . ? Ag4 Ag1 Ag5 C1 62.3(2) . . . . ? Ag3 Ag1 Ag5 C1 -10.6(2) . . . . ? C1 Ag1 Ag5 O6 -179.8(3) . . . . ? O4 Ag1 Ag5 O6 -54.8(3) . . . . ? O9 Ag1 Ag5 O6 49.8(3) . . . . ? Ag2 Ag1 Ag5 O6 120.00(18) . . . . ? Ag4 Ag1 Ag5 O6 -117.56(18) . . . . ? Ag3 Ag1 Ag5 O6 169.55(17) . . . . ? C1 Ag1 Ag5 O5 -86.5(3) . . . 2_676 ? O4 Ag1 Ag5 O5 38.5(2) . . . 2_676 ? O9 Ag1 Ag5 O5 143.1(2) . . . 2_676 ? Ag2 Ag1 Ag5 O5 -146.70(13) . . . 2_676 ? Ag4 Ag1 Ag5 O5 -24.25(13) . . . 2_676 ? Ag3 Ag1 Ag5 O5 -97.14(13) . . . 2_676 ? C1 Ag1 Ag5 Ag2 60.2(2) . . . . ? O4 Ag1 Ag5 Ag2 -174.8(2) . . . . ? O9 Ag1 Ag5 Ag2 -70.19(19) . . . . ? Ag4 Ag1 Ag5 Ag2 122.45(3) . . . . ? Ag3 Ag1 Ag5 Ag2 49.56(3) . . . . ? C1 Ag1 Ag5 Ag4 -62.3(2) . . . . ? O4 Ag1 Ag5 Ag4 62.75(19) . . . . ? O9 Ag1 Ag5 Ag4 167.37(19) . . . . ? Ag2 Ag1 Ag5 Ag4 -122.45(3) . . . . ? Ag3 Ag1 Ag5 Ag4 -72.89(4) . . . . ? C1 Ag2 Ag5 N1 141.0(4) . . . . ? O1W Ag2 Ag5 N1 31.2(8) . . . . ? O8 Ag2 Ag5 N1 -7.0(3) 2_666 . . . ? O8 Ag2 Ag5 N1 -89.7(3) . . . . ? Ag1 Ag2 Ag5 N1 -158.9(3) . . . . ? Ag3 Ag2 Ag5 N1 152.9(3) . . . . ? O1W Ag2 Ag5 C1 -109.8(8) . . . . ? O8 Ag2 Ag5 C1 -148.0(3) 2_666 . . . ? O8 Ag2 Ag5 C1 129.3(3) . . . . ? Ag1 Ag2 Ag5 C1 60.1(2) . . . . ? Ag3 Ag2 Ag5 C1 11.9(2) . . . . ? C1 Ag2 Ag5 O6 -111.0(3) . . . . ? O1W Ag2 Ag5 O6 139.2(8) . . . . ? O8 Ag2 Ag5 O6 101.0(2) 2_666 . . . ? O8 Ag2 Ag5 O6 18.3(2) . . . . ? Ag1 Ag2 Ag5 O6 -50.86(16) . . . . ? Ag3 Ag2 Ag5 O6 -99.06(16) . . . . ? C1 Ag2 Ag5 O5 4.8(3) . . . 2_676 ? O1W Ag2 Ag5 O5 -105.0(8) . . . 2_676 ? O8 Ag2 Ag5 O5 -143.2(3) 2_666 . . 2_676 ? O8 Ag2 Ag5 O5 134.1(2) . . . 2_676 ? Ag1 Ag2 Ag5 O5 64.9(2) . . . 2_676 ? Ag3 Ag2 Ag5 O5 16.7(2) . . . 2_676 ? C1 Ag2 Ag5 Ag1 -60.1(2) . . . . ? O1W Ag2 Ag5 Ag1 -169.9(8) . . . . ? O8 Ag2 Ag5 Ag1 151.89(14) 2_666 . . . ? O8 Ag2 Ag5 Ag1 69.20(14) . . . . ? Ag3 Ag2 Ag5 Ag1 -48.20(3) . . . . ? C1 Ag2 Ag5 Ag4 -16.7(2) . . . . ? O1W Ag2 Ag5 Ag4 -126.5(8) . . . . ? O8 Ag2 Ag5 Ag4 -164.65(14) 2_666 . . . ? O8 Ag2 Ag5 Ag4 112.65(14) . . . . ? Ag1 Ag2 Ag5 Ag4 43.45(3) . . . . ? Ag3 Ag2 Ag5 Ag4 -4.75(3) . . . . ? O7 Ag4 Ag5 N1 -19.5(5) 2_676 . . . ? O5 Ag4 Ag5 N1 108.1(5) . . . . ? C1 Ag4 Ag5 N1 -123.2(5) . . . . ? C2 Ag4 Ag5 N1 -94.6(5) . . . . ? Ag1 Ag4 Ag5 N1 177.0(4) . . . . ? O7 Ag4 Ag5 C1 103.7(3) 2_676 . . . ? O5 Ag4 Ag5 C1 -128.7(3) . . . . ? C2 Ag4 Ag5 C1 28.5(3) . . . . ? Ag1 Ag4 Ag5 C1 -59.9(2) . . . . ? O7 Ag4 Ag5 O6 -144.1(2) 2_676 . . . ? O5 Ag4 Ag5 O6 -16.5(2) . . . . ? C1 Ag4 Ag5 O6 112.3(3) . . . . ? C2 Ag4 Ag5 O6 140.8(3) . . . . ? Ag1 Ag4 Ag5 O6 52.37(16) . . . . ? O7 Ag4 Ag5 O5 -45.1(2) 2_676 . . 2_676 ? O5 Ag4 Ag5 O5 82.6(2) . . . 2_676 ? C1 Ag4 Ag5 O5 -148.7(3) . . . 2_676 ? C2 Ag4 Ag5 O5 -120.2(2) . . . 2_676 ? Ag1 Ag4 Ag5 O5 151.40(15) . . . 2_676 ? O7 Ag4 Ag5 Ag1 163.54(18) 2_676 . . . ? O5 Ag4 Ag5 Ag1 -68.83(14) . . . . ? C1 Ag4 Ag5 Ag1 59.9(2) . . . . ? C2 Ag4 Ag5 Ag1 88.4(2) . . . . ? O7 Ag4 Ag5 Ag2 119.95(18) 2_676 . . . ? O5 Ag4 Ag5 Ag2 -112.42(14) . . . . ? C1 Ag4 Ag5 Ag2 16.3(2) . . . . ? C2 Ag4 Ag5 Ag2 44.8(2) . . . . ? Ag1 Ag4 Ag5 Ag2 -43.59(3) . . . . ? O10 Ag3 Ag6 O11 -4.5(3) . . . . ? O2 Ag3 Ag6 O11 -170.1(2) . . . . ? C1 Ag3 Ag6 O11 -120.0(3) . . . . ? Ag1 Ag3 Ag6 O11 157.6(2) . . . . ? Ag2 Ag3 Ag6 O11 -12.2(2) . . . . ? O10 Ag3 Ag6 O3 175.1(2) . . . . ? O2 Ag3 Ag6 O3 9.5(2) . . . . ? C1 Ag3 Ag6 O3 59.6(3) . . . . ? Ag1 Ag3 Ag6 O3 -22.78(16) . . . . ? Ag2 Ag3 Ag6 O3 167.39(17) . . . . ? O10 Ag3 Ag6 O3 -165.8(4) . . . 2_775 ? O2 Ag3 Ag6 O3 28.5(4) . . . 2_775 ? C1 Ag3 Ag6 O3 78.7(5) . . . 2_775 ? Ag1 Ag3 Ag6 O3 -3.7(4) . . . 2_775 ? Ag2 Ag3 Ag6 O3 -173.6(4) . . . 2_775 ? O4 Ag1 C1 C2 36.9(17) . . . . ? O9 Ag1 C1 C2 -131.0(15) . . . . ? Ag2 Ag1 C1 C2 -138.8(17) . . . . ? Ag4 Ag1 C1 C2 46.4(15) . . . . ? Ag5 Ag1 C1 C2 135.5(17) . . . . ? Ag3 Ag1 C1 C2 -56.7(15) . . . . ? O4 Ag1 C1 Ag2 175.7(2) . . . . ? O9 Ag1 C1 Ag2 7.8(4) . . . . ? Ag4 Ag1 C1 Ag2 -174.8(3) . . . . ? Ag5 Ag1 C1 Ag2 -85.7(2) . . . . ? Ag3 Ag1 C1 Ag2 82.12(19) . . . . ? O4 Ag1 C1 Ag5 -98.6(3) . . . . ? O9 Ag1 C1 Ag5 93.5(4) . . . . ? Ag2 Ag1 C1 Ag5 85.7(2) . . . . ? Ag4 Ag1 C1 Ag5 -89.1(2) . . . . ? Ag3 Ag1 C1 Ag5 167.8(3) . . . . ? O4 Ag1 C1 Ag4 -9.4(4) . . . . ? O9 Ag1 C1 Ag4 -177.3(3) . . . . ? Ag2 Ag1 C1 Ag4 174.8(3) . . . . ? Ag5 Ag1 C1 Ag4 89.1(2) . . . . ? Ag3 Ag1 C1 Ag4 -103.1(2) . . . . ? O4 Ag1 C1 Ag3 93.6(3) . . . . ? O9 Ag1 C1 Ag3 -74.3(4) . . . . ? Ag2 Ag1 C1 Ag3 -82.12(19) . . . . ? Ag4 Ag1 C1 Ag3 103.1(2) . . . . ? Ag5 Ag1 C1 Ag3 -167.8(3) . . . . ? O1W Ag2 C1 C2 44.5(9) . . . . ? O8 Ag2 C1 C2 -76.5(7) 2_666 . . . ? O8 Ag2 C1 C2 176.5(6) . . . . ? Ag1 Ag2 C1 C2 161.9(8) . . . . ? Ag5 Ag2 C1 C2 -114.5(7) . . . . ? Ag3 Ag2 C1 C2 79.5(7) . . . . ? O1W Ag2 C1 Ag1 -117.4(4) . . . . ? O8 Ag2 C1 Ag1 121.5(2) 2_666 . . . ? O8 Ag2 C1 Ag1 14.6(4) . . . . ? Ag5 Ag2 C1 Ag1 83.5(2) . . . . ? Ag3 Ag2 C1 Ag1 -82.46(19) . . . . ? O1W Ag2 C1 Ag5 159.0(4) . . . . ? O8 Ag2 C1 Ag5 38.0(3) 2_666 . . . ? O8 Ag2 C1 Ag5 -68.9(3) . . . . ? Ag1 Ag2 C1 Ag5 -83.5(2) . . . . ? Ag3 Ag2 C1 Ag5 -166.0(3) . . . . ? O1W Ag2 C1 Ag4 -129.8(8) . . . . ? O8 Ag2 C1 Ag4 109.1(8) 2_666 . . . ? O8 Ag2 C1 Ag4 2.2(10) . . . . ? Ag1 Ag2 C1 Ag4 -12.4(7) . . . . ? Ag5 Ag2 C1 Ag4 71.1(8) . . . . ? Ag3 Ag2 C1 Ag4 -94.9(9) . . . . ? O1W Ag2 C1 Ag3 -35.0(5) . . . . ? O8 Ag2 C1 Ag3 -156.01(19) 2_666 . . . ? O8 Ag2 C1 Ag3 97.0(3) . . . . ? Ag1 Ag2 C1 Ag3 82.46(19) . . . . ? Ag5 Ag2 C1 Ag3 166.0(3) . . . . ? N1 Ag5 C1 C2 49.5(8) . . . . ? O6 Ag5 C1 C2 -161.4(6) . . . . ? O5 Ag5 C1 C2 -58.0(6) 2_676 . . . ? Ag1 Ag5 C1 C2 -161.5(7) . . . . ? Ag2 Ag5 C1 C2 119.2(7) . . . . ? Ag4 Ag5 C1 C2 -83.7(6) . . . . ? N1 Ag5 C1 Ag1 -149.0(4) . . . . ? O6 Ag5 C1 Ag1 0.2(3) . . . . ? O5 Ag5 C1 Ag1 103.6(2) 2_676 . . . ? Ag2 Ag5 C1 Ag1 -79.3(2) . . . . ? Ag4 Ag5 C1 Ag1 77.8(2) . . . . ? N1 Ag5 C1 Ag2 -69.7(5) . . . . ? O6 Ag5 C1 Ag2 79.4(3) . . . . ? O5 Ag5 C1 Ag2 -177.18(18) 2_676 . . . ? Ag1 Ag5 C1 Ag2 79.3(2) . . . . ? Ag4 Ag5 C1 Ag2 157.1(3) . . . . ? N1 Ag5 C1 Ag4 133.2(4) . . . . ? O6 Ag5 C1 Ag4 -77.7(2) . . . . ? O5 Ag5 C1 Ag4 25.7(2) 2_676 . . . ? Ag1 Ag5 C1 Ag4 -77.8(2) . . . . ? Ag2 Ag5 C1 Ag4 -157.1(3) . . . . ? N1 Ag5 C1 Ag3 -112.5(9) . . . . ? O6 Ag5 C1 Ag3 36.6(9) . . . . ? O5 Ag5 C1 Ag3 140.0(9) 2_676 . . . ? Ag1 Ag5 C1 Ag3 36.4(8) . . . . ? Ag2 Ag5 C1 Ag3 -42.9(8) . . . . ? Ag4 Ag5 C1 Ag3 114.3(10) . . . . ? O7 Ag4 C1 C2 15.7(6) 2_676 . . . ? O5 Ag4 C1 C2 -174.2(5) . . . . ? Ag1 Ag4 C1 C2 -162.6(6) . . . . ? Ag5 Ag4 C1 C2 114.5(6) . . . . ? O7 Ag4 C1 Ag1 178.2(2) 2_676 . . . ? O5 Ag4 C1 Ag1 -11.6(3) . . . . ? C2 Ag4 C1 Ag1 162.6(6) . . . . ? Ag5 Ag4 C1 Ag1 -82.9(2) . . . . ? O7 Ag4 C1 Ag2 -169.3(8) 2_676 . . . ? O5 Ag4 C1 Ag2 0.8(10) . . . . ? C2 Ag4 C1 Ag2 175.0(12) . . . . ? Ag1 Ag4 C1 Ag2 12.4(7) . . . . ? Ag5 Ag4 C1 Ag2 -70.5(8) . . . . ? O7 Ag4 C1 Ag5 -98.8(3) 2_676 . . . ? O5 Ag4 C1 Ag5 71.3(3) . . . . ? C2 Ag4 C1 Ag5 -114.5(6) . . . . ? Ag1 Ag4 C1 Ag5 82.9(2) . . . . ? O7 Ag4 C1 Ag3 100.2(3) 2_676 . . . ? O5 Ag4 C1 Ag3 -89.7(3) . . . . ? C2 Ag4 C1 Ag3 84.5(5) . . . . ? Ag1 Ag4 C1 Ag3 -78.1(2) . . . . ? Ag5 Ag4 C1 Ag3 -161.0(4) . . . . ? O10 Ag3 C1 C2 -73.1(6) . . . . ? O2 Ag3 C1 C2 82.0(5) . . . . ? Ag6 Ag3 C1 C2 32.4(7) . . . . ? Ag1 Ag3 C1 C2 159.8(6) . . . . ? Ag2 Ag3 C1 C2 -120.3(6) . . . . ? O10 Ag3 C1 Ag1 127.2(3) . . . . ? O2 Ag3 C1 Ag1 -77.8(2) . . . . ? Ag6 Ag3 C1 Ag1 -127.38(19) . . . . ? Ag2 Ag3 C1 Ag1 79.9(2) . . . . ? O10 Ag3 C1 Ag2 47.2(3) . . . . ? O2 Ag3 C1 Ag2 -157.7(2) . . . . ? Ag6 Ag3 C1 Ag2 152.70(13) . . . . ? Ag1 Ag3 C1 Ag2 -79.9(2) . . . . ? O10 Ag3 C1 Ag5 90.6(9) . . . . ? O2 Ag3 C1 Ag5 -114.4(9) . . . . ? Ag6 Ag3 C1 Ag5 -164.0(7) . . . . ? Ag1 Ag3 C1 Ag5 -36.6(8) . . . . ? Ag2 Ag3 C1 Ag5 43.3(8) . . . . ? O10 Ag3 C1 Ag4 -157.4(3) . . . . ? O2 Ag3 C1 Ag4 -2.3(2) . . . . ? Ag6 Ag3 C1 Ag4 -51.9(4) . . . . ? Ag1 Ag3 C1 Ag4 75.5(2) . . . . ? Ag2 Ag3 C1 Ag4 155.4(4) . . . . ? Ag1 C1 C2 Ag4 -45.2(14) . . . . ? Ag2 C1 C2 Ag4 -177.7(6) . . . . ? Ag5 C1 C2 Ag4 85.2(4) . . . . ? Ag3 C1 C2 Ag4 -101.0(2) . . . . ? O7 Ag4 C2 C1 -166.0(5) 2_676 . . . ? O5 Ag4 C2 C1 10.6(8) . . . . ? Ag1 Ag4 C2 C1 13.2(5) . . . . ? Ag5 Ag4 C2 C1 -47.8(5) . . . . ? O7 Ag4 C2 C25 12.0(6) 2_676 . . . ? O5 Ag4 C2 C25 -171.4(5) . . . . ? C1 Ag4 C2 C25 178.0(10) . . . . ? Ag1 Ag4 C2 C25 -168.8(6) . . . . ? Ag5 Ag4 C2 C25 130.3(7) . . . . ? O10 Ag3 O2 C15 -45.5(9) . . . . ? C1 Ag3 O2 C15 -167.3(7) . . . . ? Ag6 Ag3 O2 C15 -13.2(6) . . . . ? Ag1 Ag3 O2 C15 149.2(7) . . . . ? Ag2 Ag3 O2 C15 175.1(6) . . . . ? O11 Ag6 O3 C15 -10.9(13) . . . . ? O3 Ag6 O3 C15 174.5(7) 2_775 . . . ? Ag3 Ag6 O3 C15 -12.5(6) . . . . ? O11 Ag6 O3 Ag6 174.6(9) . . . 2_775 ? O3 Ag6 O3 Ag6 0.0 2_775 . . 2_775 ? Ag3 Ag6 O3 Ag6 173.05(18) . . . 2_775 ? C1 Ag1 O4 C17 30.6(8) . . . . ? O9 Ag1 O4 C17 -157.4(7) . . . . ? Ag4 Ag1 O4 C17 22.7(6) . . . . ? Ag5 Ag1 O4 C17 -34.6(7) . . . . ? Ag3 Ag1 O4 C17 97.7(7) . . . . ? O7 Ag4 O5 C17 -160.8(5) 2_676 . . . ? C1 Ag4 O5 C17 29.0(7) . . . . ? C2 Ag4 O5 C17 23.0(9) . . . . ? Ag1 Ag4 O5 C17 20.5(5) . . . . ? Ag5 Ag4 O5 C17 72.6(6) . . . . ? O7 Ag4 O5 Ag5 4.3(3) 2_676 . . 2_676 ? C1 Ag4 O5 Ag5 -165.9(2) . . . 2_676 ? C2 Ag4 O5 Ag5 -171.9(4) . . . 2_676 ? Ag1 Ag4 O5 Ag5 -174.45(19) . . . 2_676 ? Ag5 Ag4 O5 Ag5 -122.30(15) . . . 2_676 ? N1 Ag5 O6 C19 -102.5(9) . . . . ? C1 Ag5 O6 C19 96.6(9) . . . . ? O5 Ag5 O6 C19 -5.6(9) 2_676 . . . ? Ag1 Ag5 O6 C19 96.7(9) . . . . ? Ag2 Ag5 O6 C19 142.1(9) . . . . ? Ag4 Ag5 O6 C19 50.3(9) . . . . ? C1 Ag2 O8 C21 -34.9(8) . . . . ? O1W Ag2 O8 C21 112.8(7) . . . . ? O8 Ag2 O8 C21 -160.2(8) 2_666 . . . ? Ag1 Ag2 O8 C21 -23.5(7) . . . . ? Ag5 Ag2 O8 C21 -80.8(7) . . . . ? Ag3 Ag2 O8 C21 29.0(8) . . . . ? C1 Ag2 O8 Ag2 125.3(3) . . . 2_666 ? O1W Ag2 O8 Ag2 -87.0(3) . . . 2_666 ? O8 Ag2 O8 Ag2 0.0 2_666 . . 2_666 ? Ag1 Ag2 O8 Ag2 136.7(2) . . . 2_666 ? Ag5 Ag2 O8 Ag2 79.42(19) . . . 2_666 ? Ag3 Ag2 O8 Ag2 -170.82(12) . . . 2_666 ? C1 Ag1 O9 C21 -30.1(8) . . . . ? O4 Ag1 O9 C21 158.5(7) . . . . ? Ag2 Ag1 O9 C21 -23.9(6) . . . . ? Ag4 Ag1 O9 C21 158.8(5) . . . . ? Ag5 Ag1 O9 C21 34.1(7) . . . . ? Ag3 Ag1 O9 C21 -86.4(6) . . . . ? O2 Ag3 O10 C23 39.1(11) . . . . ? C1 Ag3 O10 C23 153.6(8) . . . . ? Ag6 Ag3 O10 C23 7.0(8) . . . . ? Ag1 Ag3 O10 C23 -160.1(7) . . . . ? Ag2 Ag3 O10 C23 -175.6(8) . . . . ? O3 Ag6 O11 C23 3.5(16) . . . . ? O3 Ag6 O11 C23 177.6(7) 2_775 . . . ? Ag3 Ag6 O11 C23 5.1(8) . . . . ? C25 O1 C3 C8 -2.9(12) . . . . ? C25 O1 C3 C4 178.1(7) . . . . ? O1 C3 C4 C5 -179.1(7) . . . . ? C8 C3 C4 C5 1.7(12) . . . . ? C3 C4 C5 C6 -1.0(13) . . . . ? C4 C5 C6 C7 -0.6(12) . . . . ? C4 C5 C6 C9 177.3(8) . . . . ? C5 C6 C7 C8 1.5(13) . . . . ? C9 C6 C7 C8 -176.4(8) . . . . ? C6 C7 C8 C3 -0.8(14) . . . . ? O1 C3 C8 C7 -179.9(8) . . . . ? C4 C3 C8 C7 -0.8(13) . . . . ? C5 C6 C9 C14 -158.6(9) . . . . ? C7 C6 C9 C14 19.1(13) . . . . ? C5 C6 C9 C10 19.5(12) . . . . ? C7 C6 C9 C10 -162.7(8) . . . . ? C14 C9 C10 C11 -1.3(13) . . . . ? C6 C9 C10 C11 -179.5(8) . . . . ? C9 C10 C11 C12 1.2(15) . . . . ? C10 C11 C12 C13 -1.0(15) . . . . ? C11 C12 C13 C14 1.0(15) . . . . ? C10 C9 C14 C13 1.3(14) . . . . ? C6 C9 C14 C13 179.4(9) . . . . ? C12 C13 C14 C9 -1.1(15) . . . . ? Ag6 O3 C15 O2 6.8(12) . . . . ? Ag6 O3 C15 O2 179.2(6) 2_775 . . . ? Ag6 O3 C15 C16 -173.5(5) . . . . ? Ag6 O3 C15 C16 -1.1(11) 2_775 . . . ? Ag3 O2 C15 O3 8.1(13) . . . . ? Ag3 O2 C15 C16 -171.6(5) . . . . ? O3 C15 C16 F9' -154.8(7) . . . . ? O2 C15 C16 F9' 24.9(10) . . . . ? O3 C15 C16 F8' -35.7(10) . . . . ? O2 C15 C16 F8' 144.0(8) . . . . ? O3 C15 C16 F7' 84.9(8) . . . . ? O2 C15 C16 F7' -95.3(8) . . . . ? O3 C15 C16 F8 -95.6(8) . . . . ? O2 C15 C16 F8 84.2(8) . . . . ? O3 C15 C16 F7 25.5(10) . . . . ? O2 C15 C16 F7 -154.8(8) . . . . ? O3 C15 C16 F9 145.0(7) . . . . ? O2 C15 C16 F9 -35.3(10) . . . . ? Ag1 O4 C17 O5 -13.9(12) . . . . ? Ag1 O4 C17 C18 167.1(6) . . . . ? Ag4 O5 C17 O4 -10.5(11) . . . . ? Ag5 O5 C17 O4 -170.3(6) 2_676 . . . ? Ag4 O5 C17 C18 168.4(5) . . . . ? Ag5 O5 C17 C18 8.6(11) 2_676 . . . ? O4 C17 C18 F5 -152.5(8) . . . . ? O5 C17 C18 F5 28.4(12) . . . . ? O4 C17 C18 F6 88.7(10) . . . . ? O5 C17 C18 F6 -90.4(9) . . . . ? O4 C17 C18 F4 -19.8(14) . . . . ? O5 C17 C18 F4 161.1(11) . . . . ? O4 C17 C18 F4' -48.3(15) . . . . ? O5 C17 C18 F4' 132.6(14) . . . . ? Ag4 O7 C19 O6 9.0(15) 2_676 . . . ? Ag4 O7 C19 C20 -171.8(5) 2_676 . . . ? Ag5 O6 C19 O7 -3.2(17) . . . . ? Ag5 O6 C19 C20 177.6(6) . . . . ? O7 C19 C20 F1' -5.6(11) . . . . ? O6 C19 C20 F1' 173.8(8) . . . . ? O7 C19 C20 F2' 113.8(8) . . . . ? O6 C19 C20 F2' -66.9(9) . . . . ? O7 C19 C20 F3' -126.0(8) . . . . ? O6 C19 C20 F3' 53.4(10) . . . . ? O7 C19 C20 F2 55.0(10) . . . . ? O6 C19 C20 F2 -125.7(8) . . . . ? O7 C19 C20 F3 173.2(8) . . . . ? O6 C19 C20 F3 -7.4(11) . . . . ? O7 C19 C20 F1 -66.0(9) . . . . ? O6 C19 C20 F1 113.3(9) . . . . ? Ag1 O9 C21 O8 12.5(13) . . . . ? Ag1 O9 C21 C22 -170.3(5) . . . . ? Ag2 O8 C21 O9 -138.1(8) 2_666 . . . ? Ag2 O8 C21 O9 12.4(14) . . . . ? Ag2 O8 C21 C22 44.9(12) 2_666 . . . ? Ag2 O8 C21 C22 -164.6(6) . . . . ? Ag6 O11 C23 O10 -1.3(16) . . . . ? Ag6 O11 C23 C24 179.9(6) . . . . ? Ag3 O10 C23 O11 -5.8(16) . . . . ? Ag3 O10 C23 C24 173.0(6) . . . . ? O11 C23 C24 F14' -73.5(11) . . . . ? O10 C23 C24 F14' 107.5(10) . . . . ? O11 C23 C24 F15' 165.4(9) . . . . ? O10 C23 C24 F15' -13.5(13) . . . . ? O11 C23 C24 F13' 47.3(12) . . . . ? O10 C23 C24 F13' -131.7(10) . . . . ? O11 C23 C24 F13 106.5(10) . . . . ? O10 C23 C24 F13 -72.5(11) . . . . ? O11 C23 C24 F15 -133.8(9) . . . . ? O10 C23 C24 F15 47.2(11) . . . . ? O11 C23 C24 F14 -13.0(12) . . . . ? O10 C23 C24 F14 168.1(9) . . . . ? C3 O1 C25 C2 -96.3(9) . . . . ? Ag4 C2 C25 O1 110.1(8) . . . . ? C1 Ag5 N1 C26 -84(4) . . . . ? O6 Ag5 N1 C26 126(4) . . . . ? O5 Ag5 N1 C26 25(4) 2_676 . . . ? Ag1 Ag5 N1 C26 177(4) . . . . ? Ag2 Ag5 N1 C26 -131(4) . . . . ? Ag4 Ag5 N1 C26 4(4) . . . . ? O9 C21 C22 F10 49.9(11) . . . . ? O8 C21 C22 F10 -132.6(9) . . . . ? O9 C21 C22 F11 -179.1(8) . . . . ? O8 C21 C22 F11 -1.6(12) . . . . ? O9 C21 C22 F12 -68.0(10) . . . . ? O8 C21 C22 F12 109.5(9) . . . . ? O9 C21 C22 F10' 115.6(8) . . . . ? O8 C21 C22 F10' -66.9(9) . . . . ? O9 C21 C22 F12' -8.9(9) . . . . ? O8 C21 C22 F12' 168.6(9) . . . . ? O9 C21 C22 F11' -124.0(8) . . . . ? O8 C21 C22 F11' 53.5(9) . . . . ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_site_symmetry_A O1W H1WA O6 0.85 2.19 2.871(10) 137.2 2_666 O1W H1WB O10 0.85 2.09 2.733(10) 131.8 . _diffrn_measured_fraction_theta_max 0.999 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.999 _refine_diff_density_max 1.907 _refine_diff_density_min -1.019 _refine_diff_density_rms 0.144 data_3 _database_code_depnum_ccdc_archive 'CCDC 910772' #TrackingRef '3.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C60 H44 Ag6 N2 O10' _chemical_formula_weight 1600.19 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 7.6485(2) _cell_length_b 11.1943(3) _cell_length_c 30.1822(7) _cell_angle_alpha 94.781(2) _cell_angle_beta 92.459(2) _cell_angle_gamma 90.367(2) _cell_volume 2572.70(11) _cell_formula_units_Z 2 _cell_measurement_temperature 296(2) _cell_measurement_reflns_used 5000 _cell_measurement_theta_min 3.0370 _cell_measurement_theta_max 29.2541 _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.21 _exptl_crystal_size_mid 0.20 _exptl_crystal_size_min 0.19 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.066 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1560 _exptl_absorpt_coefficient_mu 2.304 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.6433 _exptl_absorpt_correction_T_max 0.6686 _exptl_absorpt_process_details SADABS(2009) _exptl_special_details ; ? ; _diffrn_ambient_temperature 296(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 17096 _diffrn_reflns_av_R_equivalents 0.0309 _diffrn_reflns_av_sigmaI/netI 0.0539 _diffrn_reflns_limit_h_min -9 _diffrn_reflns_limit_h_max 9 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 13 _diffrn_reflns_limit_l_min -35 _diffrn_reflns_limit_l_max 35 _diffrn_reflns_theta_min 3.04 _diffrn_reflns_theta_max 25.00 _reflns_number_total 9016 _reflns_number_gt 7145 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0511P)^2^+10.0785P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 9016 _refine_ls_number_parameters 716 _refine_ls_number_restraints 57 _refine_ls_R_factor_all 0.0709 _refine_ls_R_factor_gt 0.0542 _refine_ls_wR_factor_ref 0.1351 _refine_ls_wR_factor_gt 0.1253 _refine_ls_goodness_of_fit_ref 1.024 _refine_ls_restrained_S_all 1.073 _refine_ls_shift/su_max 0.010 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.31524(7) 0.75190(5) 0.028808(17) 0.03382(15) Uani 1 1 d . . . Ag2 Ag 0.26800(11) 0.48801(6) -0.02775(3) 0.0729(3) Uani 1 1 d . . . Ag3 Ag -0.04400(8) 0.78284(8) 0.06231(3) 0.0752(3) Uani 1 1 d . . . Ag4 Ag 0.29062(12) 1.01068(7) 0.06948(4) 0.0891(3) Uani 1 1 d . . . Ag5 Ag 0.30934(7) 1.24891(5) 0.016381(17) 0.03589(16) Uani 1 1 d . . . Ag6 Ag -0.05588(8) 1.25111(8) 0.04806(3) 0.0675(2) Uani 1 1 d U . . O1 O 0.2753(6) 0.5859(5) -0.14860(15) 0.0408(12) Uani 1 1 d . A . O2 O 0.3102(8) 1.1679(5) -0.15568(17) 0.0491(14) Uani 1 1 d . A . O3 O 0.2182(7) 1.1613(5) 0.18660(16) 0.0459(13) Uani 1 1 d . A . O4 O 0.2075(7) 0.7372(5) 0.19517(16) 0.0460(13) Uani 1 1 d . . . O5 O 0.1175(13) 0.5067(9) 0.1102(4) 0.120(3) Uani 1 1 d U . . O6 O 0.0758(11) 0.5023(8) 0.0427(3) 0.100(3) Uani 1 1 d U . . O7 O 0.3302(8) 0.5221(6) 0.0675(3) 0.076(2) Uani 1 1 d U . . N1 N 0.1826(11) 0.5122(6) 0.0773(4) 0.070(2) Uani 1 1 d U . . C1 C 0.3327(8) 0.6853(6) -0.0376(2) 0.0288(15) Uani 1 1 d . . . C2 C 0.3610(8) 0.6648(6) -0.0766(2) 0.0293(15) Uani 1 1 d . . . C3 C 0.4121(9) 0.6496(7) -0.1233(2) 0.0384(17) Uani 1 1 d . . . H3A H 0.4301 0.7272 -0.1345 0.046 Uiso 1 1 calc R A . H3B H 0.5203 0.6052 -0.1254 0.046 Uiso 1 1 calc R . . C4 C 0.2918(9) 0.5738(6) -0.1937(2) 0.0314(15) Uani 1 1 d . . . C5 C 0.1614(8) 0.5059(6) -0.2177(2) 0.0313(15) Uani 1 1 d . A . H5 H 0.0726 0.4710 -0.2030 0.038 Uiso 1 1 calc R . . C6 C 0.4219(9) 0.6247(7) -0.2166(2) 0.0391(18) Uani 1 1 d . A . H6 H 0.5102 0.6703 -0.2010 0.047 Uiso 1 1 calc R . . C7 C 0.4214(9) 0.6081(7) -0.2624(2) 0.0378(17) Uani 1 1 d . . . H7 H 0.5113 0.6421 -0.2771 0.045 Uiso 1 1 calc R A . C8 C 0.2919(8) 0.5426(6) -0.2872(2) 0.0284(14) Uani 1 1 d . A . C9 C 0.1640(9) 0.4905(6) -0.2635(2) 0.0329(16) Uani 1 1 d . . . H9 H 0.0771 0.4437 -0.2791 0.040 Uiso 1 1 calc R A . C10 C 0.2865(8) 0.5317(6) -0.3366(2) 0.0299(15) Uani 1 1 d . . . C11 C 0.2044(9) 0.4355(7) -0.3616(2) 0.0397(18) Uani 1 1 d . A . H11 H 0.1530 0.3748 -0.3471 0.048 Uiso 1 1 calc R . . C12 C 0.1985(10) 0.4291(7) -0.4074(2) 0.0443(19) Uani 1 1 d . . . H12 H 0.1436 0.3638 -0.4234 0.053 Uiso 1 1 calc R A . C13 C 0.2714(10) 0.5167(7) -0.4296(3) 0.0438(19) Uani 1 1 d . A . H13 H 0.2654 0.5116 -0.4606 0.053 Uiso 1 1 calc R . . C14 C 0.3536(10) 0.6123(7) -0.4059(3) 0.0437(19) Uani 1 1 d . . . H14 H 0.4048 0.6723 -0.4207 0.052 Uiso 1 1 calc R A . C15 C 0.3598(10) 0.6192(7) -0.3602(3) 0.0406(18) Uani 1 1 d . A . H15 H 0.4152 0.6848 -0.3445 0.049 Uiso 1 1 calc R . . C16 C 0.3204(9) 1.2930(6) -0.04990(19) 0.0328(16) Uani 1 1 d D . . C17 C 0.3318(9) 1.2915(6) -0.0900(2) 0.0337(16) Uani 1 1 d D . . C18 C 0.3625(10) 1.2862(7) -0.1378(2) 0.0391(17) Uani 1 1 d . . . H18A H 0.2937 1.3462 -0.1518 0.047 Uiso 1 1 calc R A . H18B H 0.4852 1.3004 -0.1426 0.047 Uiso 1 1 calc R . . C19 C 0.3117(9) 1.1453(6) -0.2013(2) 0.0365(17) Uani 1 1 d . . . C20 C 0.2589(10) 1.0301(7) -0.2177(3) 0.0438(19) Uani 1 1 d . A . H20 H 0.2290 0.9739 -0.1982 0.053 Uiso 1 1 calc R . . C21 C 0.2512(10) 0.9998(7) -0.2631(2) 0.0403(18) Uani 1 1 d . . . H21 H 0.2155 0.9227 -0.2737 0.048 Uiso 1 1 calc R A . C22 C 0.2950(8) 1.0808(6) -0.2932(2) 0.0288(15) Uani 1 1 d . A . C23 C 0.3501(9) 1.1949(6) -0.2752(2) 0.0373(17) Uani 1 1 d . . . H23 H 0.3820 1.2512 -0.2944 0.045 Uiso 1 1 calc R A . C24 C 0.3586(10) 1.2265(7) -0.2302(2) 0.0396(18) Uani 1 1 d . A . H24 H 0.3962 1.3030 -0.2195 0.048 Uiso 1 1 calc R . . C25 C 0.2868(8) 1.0499(6) -0.3419(2) 0.0312(15) Uani 1 1 d . . . C26 C 0.1881(9) 0.9520(6) -0.3624(3) 0.0415(18) Uani 1 1 d . A . H26 H 0.1268 0.9037 -0.3447 0.050 Uiso 1 1 calc R . . C27 C 0.1799(10) 0.9259(7) -0.4076(3) 0.0433(19) Uani 1 1 d . . . H27 H 0.1135 0.8606 -0.4199 0.052 Uiso 1 1 calc R A . C28 C 0.2680(10) 0.9948(7) -0.4348(3) 0.046(2) Uani 1 1 d . A . H28 H 0.2620 0.9763 -0.4654 0.055 Uiso 1 1 calc R . . C29 C 0.3656(10) 1.0915(7) -0.4164(3) 0.0433(19) Uani 1 1 d . . . H29 H 0.4255 1.1390 -0.4347 0.052 Uiso 1 1 calc R A . C30 C 0.3749(9) 1.1185(7) -0.3709(3) 0.0401(18) Uani 1 1 d . A . H30 H 0.4417 1.1842 -0.3591 0.048 Uiso 1 1 calc R . . C31 C 0.2112(8) 1.2081(6) 0.0773(2) 0.0350(16) Uani 1 1 d . A . C32 C 0.1545(9) 1.2110(6) 0.1138(2) 0.0336(16) Uani 1 1 d . A . C33 C 0.0988(10) 1.2254(8) 0.1598(2) 0.051(2) Uani 1 1 d . . . H33A H 0.0993 1.3096 0.1704 0.061 Uiso 1 1 calc R A . H33B H -0.0190 1.1938 0.1614 0.061 Uiso 1 1 calc R . . C34 C 0.3301(9) 1.1209(7) 0.2565(2) 0.0374(17) Uani 1 1 d . A . H34 H 0.4117 1.0725 0.2419 0.045 Uiso 1 1 calc R . . C35 C 0.2059(9) 1.1791(6) 0.2320(2) 0.0328(16) Uani 1 1 d . . . C36 C 0.0842(9) 1.2491(7) 0.2538(2) 0.0425(18) Uani 1 1 d . A . H36 H -0.0023 1.2874 0.2378 0.051 Uiso 1 1 calc R . . C37 C 0.0918(10) 1.2619(7) 0.3001(2) 0.0432(19) Uani 1 1 d . . . H37 H 0.0095 1.3098 0.3146 0.052 Uiso 1 1 calc R A . C38 C 0.2162(8) 1.2066(6) 0.3253(2) 0.0309(15) Uani 1 1 d . A . C39 C 0.3348(9) 1.1338(6) 0.3024(2) 0.0370(17) Uani 1 1 d . . . H39 H 0.4188 1.0931 0.3183 0.044 Uiso 1 1 calc R A . C40 C 0.2228(9) 1.2219(6) 0.3752(2) 0.0338(16) Uani 1 1 d . . . C41 C 0.1567(10) 1.3238(7) 0.3977(3) 0.0426(18) Uani 1 1 d . A . H41 H 0.1076 1.3837 0.3817 0.051 Uiso 1 1 calc R . . C42 C 0.1634(11) 1.3369(8) 0.4440(3) 0.051(2) Uani 1 1 d . . . H42 H 0.1165 1.4048 0.4587 0.062 Uiso 1 1 calc R A . C43 C 0.2378(11) 1.2514(8) 0.4680(3) 0.051(2) Uani 1 1 d . A . H43 H 0.2441 1.2615 0.4990 0.061 Uiso 1 1 calc R . . C44 C 0.3031(11) 1.1503(8) 0.4462(3) 0.055(2) Uani 1 1 d . . . H44 H 0.3533 1.0914 0.4625 0.066 Uiso 1 1 calc R A . C45 C 0.2953(10) 1.1350(7) 0.4002(2) 0.0433(19) Uani 1 1 d . A . H45 H 0.3393 1.0654 0.3860 0.052 Uiso 1 1 calc R . . C46 C 0.2249(8) 0.8248(6) 0.0896(2) 0.0321(16) Uani 1 1 d . A . C47 C 0.1966(9) 0.8337(6) 0.1287(2) 0.0341(16) Uani 1 1 d . . . C48 C 0.1746(11) 0.8478(8) 0.1770(3) 0.049(2) Uani 1 1 d . A . H48A H 0.2551 0.9086 0.1907 0.058 Uiso 1 1 calc R . . H48B H 0.0563 0.8733 0.1830 0.058 Uiso 1 1 calc R . . C49 C 0.2044(9) 0.7389(7) 0.2410(2) 0.0370(17) Uani 1 1 d . . . C50 C 0.1508(10) 0.8357(7) 0.2681(3) 0.0434(19) Uani 1 1 d . . . H50 H 0.1102 0.9045 0.2559 0.052 Uiso 1 1 calc R . . C51 C 0.1583(9) 0.8291(7) 0.3137(2) 0.0395(18) Uani 1 1 d . . . H51 H 0.1251 0.8958 0.3317 0.047 Uiso 1 1 calc R . . C52 C 0.2123(8) 0.7289(6) 0.3337(2) 0.0299(15) Uani 1 1 d . . . C53 C 0.2620(9) 0.6309(6) 0.3054(2) 0.0387(17) Uani 1 1 d . . . H53 H 0.2983 0.5608 0.3174 0.046 Uiso 1 1 calc R . . C54 C 0.2579(10) 0.6369(7) 0.2595(3) 0.0415(19) Uani 1 1 d . . . H54 H 0.2918 0.5710 0.2411 0.050 Uiso 1 1 calc R . . C55 C 0.2182(8) 0.7265(6) 0.3830(2) 0.0304(15) Uani 1 1 d . . . C56 C 0.1219(9) 0.8083(7) 0.4091(2) 0.0391(17) Uani 1 1 d . . . H56 H 0.0506 0.8628 0.3955 0.047 Uiso 1 1 calc R . . C57 C 0.1311(10) 0.8092(7) 0.4549(3) 0.0456(19) Uani 1 1 d . . . H57 H 0.0657 0.8643 0.4718 0.055 Uiso 1 1 calc R . . C58 C 0.2349(11) 0.7304(7) 0.4756(3) 0.049(2) Uani 1 1 d . . . H58 H 0.2409 0.7321 0.5065 0.058 Uiso 1 1 calc R . . C59 C 0.3296(11) 0.6491(8) 0.4508(3) 0.050(2) Uani 1 1 d . . . H59 H 0.3991 0.5944 0.4649 0.060 Uiso 1 1 calc R . . C60 C 0.3232(10) 0.6474(7) 0.4051(3) 0.0424(18) Uani 1 1 d . . . H60 H 0.3903 0.5923 0.3886 0.051 Uiso 1 1 calc R . . N2 N 0.6874(18) 1.0148(15) 0.0535(5) 0.082(4) Uani 0.614(8) 1 d PDU A 1 O8 O 0.5598(16) 0.9986(16) 0.0234(4) 0.119(5) Uani 0.614(8) 1 d PDU . 1 O9 O 0.8383(15) 1.0102(12) 0.0414(4) 0.098(3) Uani 0.614(8) 1 d PDU A 1 O10 O 0.6473(18) 1.046(3) 0.0923(5) 0.114(5) Uani 0.614(8) 1 d PDU A 1 N2' N 0.685(3) 1.038(4) 0.0903(8) 0.082(4) Uani 0.386(8) 1 d PD A 2 O8' O 0.613(3) 0.991(3) 0.0552(7) 0.119(5) Uani 0.386(8) 1 d PD A 2 O9' O 0.843(2) 1.0280(19) 0.0959(7) 0.098(3) Uani 0.386(8) 1 d PD A 2 O10' O 0.594(3) 1.068(2) 0.1215(7) 0.114(5) Uani 0.386(8) 1 d PD A 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0367(3) 0.0406(3) 0.0236(3) -0.0026(2) 0.0045(2) 0.0009(2) Ag2 0.0917(6) 0.0336(4) 0.0927(6) 0.0036(4) -0.0025(5) 0.0001(4) Ag3 0.0299(3) 0.1165(7) 0.0749(5) -0.0144(5) -0.0011(3) -0.0167(4) Ag4 0.0928(6) 0.0353(4) 0.1389(9) 0.0181(5) -0.0192(6) 0.0004(4) Ag5 0.0352(3) 0.0464(3) 0.0271(3) 0.0074(2) 0.0052(2) 0.0020(2) Ag6 0.0301(3) 0.1005(6) 0.0736(5) 0.0222(4) -0.0081(3) 0.0147(3) O1 0.037(3) 0.061(3) 0.023(3) -0.004(2) 0.000(2) -0.012(2) O2 0.074(4) 0.042(3) 0.032(3) 0.006(2) 0.009(3) -0.001(3) O3 0.047(3) 0.065(4) 0.027(3) 0.010(3) 0.002(2) 0.019(3) O4 0.065(4) 0.049(3) 0.024(3) 0.000(2) 0.004(2) 0.003(3) O5 0.125(4) 0.119(4) 0.118(4) 0.010(2) 0.018(2) 0.000(2) O6 0.076(4) 0.105(4) 0.118(5) 0.017(4) -0.016(4) -0.005(3) O7 0.046(3) 0.068(4) 0.117(6) 0.027(4) -0.003(3) 0.006(3) N1 0.057(3) 0.026(3) 0.127(6) 0.002(4) 0.014(5) -0.001(3) C1 0.026(3) 0.031(4) 0.030(4) -0.001(3) 0.005(3) -0.003(3) C2 0.026(3) 0.034(4) 0.027(4) 0.003(3) -0.002(3) 0.001(3) C3 0.034(4) 0.051(5) 0.029(4) -0.002(3) -0.004(3) -0.004(3) C4 0.035(4) 0.035(4) 0.023(4) -0.005(3) 0.001(3) 0.002(3) C5 0.028(3) 0.036(4) 0.030(4) 0.003(3) 0.002(3) -0.001(3) C6 0.038(4) 0.054(5) 0.024(4) -0.002(3) -0.001(3) -0.015(3) C7 0.033(4) 0.049(4) 0.031(4) 0.000(3) 0.005(3) -0.009(3) C8 0.029(3) 0.028(3) 0.027(4) 0.000(3) 0.001(3) 0.006(3) C9 0.031(4) 0.035(4) 0.032(4) -0.001(3) -0.003(3) -0.006(3) C10 0.026(3) 0.038(4) 0.025(4) -0.001(3) 0.003(3) 0.006(3) C11 0.044(4) 0.042(4) 0.033(4) 0.000(3) 0.007(3) -0.008(3) C12 0.056(5) 0.045(5) 0.030(4) -0.009(4) -0.003(4) -0.004(4) C13 0.050(5) 0.056(5) 0.026(4) 0.005(4) 0.004(3) 0.003(4) C14 0.045(4) 0.050(5) 0.038(4) 0.011(4) 0.006(3) -0.004(4) C15 0.043(4) 0.040(4) 0.037(4) -0.002(3) 0.001(3) -0.009(3) C16 0.037(4) 0.044(4) 0.016(3) -0.006(3) 0.000(3) -0.001(3) C17 0.031(4) 0.026(4) 0.045(5) 0.005(3) 0.001(3) 0.001(3) C18 0.045(4) 0.044(4) 0.029(4) 0.008(3) 0.005(3) 0.001(3) C19 0.036(4) 0.041(4) 0.033(4) 0.001(3) 0.007(3) 0.006(3) C20 0.051(5) 0.040(4) 0.042(5) 0.012(4) 0.010(4) 0.000(4) C21 0.046(4) 0.036(4) 0.038(4) -0.005(3) 0.004(3) -0.002(3) C22 0.021(3) 0.034(4) 0.030(4) 0.002(3) 0.000(3) 0.002(3) C23 0.045(4) 0.036(4) 0.031(4) 0.004(3) 0.003(3) -0.004(3) C24 0.048(4) 0.037(4) 0.033(4) -0.005(3) 0.004(3) -0.009(3) C25 0.024(3) 0.032(4) 0.038(4) -0.001(3) 0.004(3) 0.008(3) C26 0.041(4) 0.035(4) 0.048(5) 0.000(4) 0.005(3) -0.003(3) C27 0.046(4) 0.041(4) 0.041(5) -0.010(4) -0.002(4) -0.005(4) C28 0.050(5) 0.057(5) 0.029(4) -0.008(4) -0.003(3) -0.002(4) C29 0.051(5) 0.042(4) 0.037(4) 0.006(4) 0.007(4) -0.003(4) C30 0.041(4) 0.039(4) 0.040(4) 0.001(3) 0.005(3) -0.004(3) C31 0.025(3) 0.043(4) 0.037(4) 0.006(3) 0.001(3) 0.001(3) C32 0.030(4) 0.039(4) 0.033(4) 0.011(3) 0.003(3) 0.004(3) C33 0.047(5) 0.078(6) 0.031(4) 0.014(4) 0.009(3) 0.020(4) C34 0.033(4) 0.043(4) 0.036(4) -0.001(3) 0.005(3) 0.007(3) C35 0.035(4) 0.040(4) 0.025(4) 0.008(3) 0.005(3) 0.006(3) C36 0.035(4) 0.057(5) 0.037(4) 0.014(4) 0.002(3) 0.018(4) C37 0.040(4) 0.058(5) 0.033(4) 0.005(4) 0.010(3) 0.015(4) C38 0.031(4) 0.033(4) 0.029(4) 0.006(3) 0.004(3) 0.000(3) C39 0.037(4) 0.039(4) 0.035(4) 0.004(3) -0.002(3) 0.006(3) C40 0.030(4) 0.037(4) 0.034(4) 0.005(3) 0.004(3) -0.004(3) C41 0.045(4) 0.042(4) 0.041(5) 0.002(4) 0.001(3) 0.004(4) C42 0.054(5) 0.054(5) 0.044(5) -0.013(4) 0.011(4) 0.002(4) C43 0.052(5) 0.071(6) 0.029(4) -0.002(4) 0.003(4) -0.005(4) C44 0.060(5) 0.068(6) 0.041(5) 0.017(4) 0.009(4) 0.008(5) C45 0.049(5) 0.050(5) 0.031(4) 0.002(4) 0.006(3) 0.006(4) C46 0.028(3) 0.039(4) 0.029(4) -0.001(3) 0.002(3) 0.002(3) C47 0.032(4) 0.039(4) 0.031(4) -0.003(3) 0.001(3) 0.004(3) C48 0.052(5) 0.060(5) 0.034(4) 0.004(4) 0.008(4) 0.016(4) C49 0.035(4) 0.047(5) 0.028(4) -0.002(3) 0.002(3) -0.003(3) C50 0.046(4) 0.047(5) 0.039(4) 0.009(4) 0.007(3) 0.017(4) C51 0.046(4) 0.044(4) 0.029(4) 0.000(3) 0.007(3) 0.007(3) C52 0.023(3) 0.035(4) 0.032(4) 0.003(3) 0.003(3) -0.005(3) C53 0.044(4) 0.033(4) 0.039(4) 0.003(3) 0.006(3) 0.001(3) C54 0.046(4) 0.039(4) 0.037(4) -0.009(4) 0.009(3) -0.005(3) C55 0.029(3) 0.035(4) 0.027(4) 0.003(3) 0.002(3) -0.004(3) C56 0.042(4) 0.041(4) 0.035(4) 0.008(3) 0.001(3) 0.001(3) C57 0.053(5) 0.048(5) 0.035(4) -0.003(4) 0.007(4) -0.003(4) C58 0.062(5) 0.055(5) 0.028(4) 0.007(4) -0.002(4) -0.002(4) C59 0.058(5) 0.055(5) 0.039(5) 0.016(4) 0.003(4) 0.011(4) C60 0.046(4) 0.041(4) 0.041(5) 0.005(4) 0.014(4) 0.010(4) N2 0.083(5) 0.078(5) 0.084(5) 0.009(2) 0.002(2) 0.001(2) O8 0.120(5) 0.119(5) 0.119(5) 0.009(2) 0.004(2) 0.002(2) O9 0.097(4) 0.094(4) 0.104(4) 0.011(2) 0.004(2) -0.001(2) O10 0.117(5) 0.111(5) 0.114(5) 0.013(2) 0.005(2) 0.002(2) N2' 0.083(5) 0.078(5) 0.084(5) 0.009(2) 0.002(2) 0.001(2) O8' 0.120(5) 0.119(5) 0.119(5) 0.009(2) 0.004(2) 0.002(2) O9' 0.097(4) 0.094(4) 0.104(4) 0.011(2) 0.004(2) -0.001(2) O10' 0.117(5) 0.111(5) 0.114(5) 0.013(2) 0.005(2) 0.002(2) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 C1 2.089(6) . ? Ag1 C46 2.093(6) . ? Ag1 Ag3 2.9807(8) . ? Ag1 Ag6 2.9851(9) 2_575 ? Ag1 Ag4 3.0607(9) . ? Ag1 Ag5 3.2310(7) 2_675 ? Ag1 Ag2 3.2960(8) . ? Ag2 C16 2.273(7) 1_545 ? Ag2 C1 2.306(7) . ? Ag2 C2 2.676(7) . ? Ag2 Ag5 3.0996(10) 1_545 ? Ag3 C46 2.216(7) . ? Ag3 C16 2.277(7) 2_575 ? Ag3 C17 2.547(6) 2_575 ? Ag3 C47 2.685(7) . ? Ag3 Ag5 3.0532(9) 2_575 ? Ag4 C46 2.275(7) . ? Ag4 C31 2.291(7) . ? Ag4 O8' 2.53(2) . ? Ag4 O8 2.531(13) . ? Ag4 Ag5 3.2292(10) . ? Ag5 C31 2.100(7) . ? Ag5 C16 2.105(6) . ? Ag5 Ag6 2.9907(8) . ? Ag5 Ag3 3.0532(9) 2_575 ? Ag5 Ag2 3.0996(10) 1_565 ? Ag5 Ag1 3.2310(7) 2_675 ? Ag6 C1 2.256(7) 2_575 ? Ag6 C31 2.262(7) . ? Ag6 C32 2.571(7) . ? Ag6 C2 2.673(6) 2_575 ? Ag6 Ag1 2.9851(9) 2_575 ? O1 C4 1.367(8) . ? O1 C3 1.421(8) . ? O2 C19 1.379(8) . ? O2 C18 1.436(8) . ? O3 C35 1.377(8) . ? O3 C33 1.430(9) . ? O4 C49 1.383(8) . ? O4 C48 1.415(10) . ? O5 N1 1.136(12) . ? O6 N1 1.294(12) . ? O7 N1 1.186(9) . ? C1 C2 1.211(9) . ? C1 Ag6 2.256(6) 2_575 ? C2 C3 1.473(9) . ? C2 Ag6 2.673(6) 2_575 ? C3 H3A 0.9700 . ? C3 H3B 0.9700 . ? C4 C6 1.382(9) . ? C4 C5 1.392(9) . ? C5 C9 1.380(9) . ? C5 H5 0.9300 . ? C6 C7 1.380(10) . ? C6 H6 0.9300 . ? C7 C8 1.384(9) . ? C7 H7 0.9300 . ? C8 C9 1.390(9) . ? C8 C10 1.484(9) . ? C9 H9 0.9300 . ? C10 C15 1.386(10) . ? C10 C11 1.392(9) . ? C11 C12 1.377(10) . ? C11 H11 0.9300 . ? C12 C13 1.363(11) . ? C12 H12 0.9300 . ? C13 C14 1.370(11) . ? C13 H13 0.9300 . ? C14 C15 1.375(10) . ? C14 H14 0.9300 . ? C15 H15 0.9300 . ? C16 C17 1.216(7) . ? C16 Ag2 2.273(7) 1_565 ? C16 Ag3 2.277(7) 2_575 ? C17 C18 1.467(9) . ? C17 Ag3 2.547(6) 2_575 ? C18 H18A 0.9700 . ? C18 H18B 0.9700 . ? C19 C24 1.369(10) . ? C19 C20 1.393(10) . ? C20 C21 1.381(10) . ? C20 H20 0.9300 . ? C21 C22 1.386(10) . ? C21 H21 0.9300 . ? C22 C23 1.401(9) . ? C22 C25 1.480(9) . ? C23 C24 1.371(10) . ? C23 H23 0.9300 . ? C24 H24 0.9300 . ? C25 C30 1.401(10) . ? C25 C26 1.411(9) . ? C26 C27 1.369(11) . ? C26 H26 0.9300 . ? C27 C28 1.367(11) . ? C27 H27 0.9300 . ? C28 C29 1.375(10) . ? C28 H28 0.9300 . ? C29 C30 1.381(10) . ? C29 H29 0.9300 . ? C30 H30 0.9300 . ? C31 C32 1.198(9) . ? C32 C33 1.466(10) . ? C33 H33A 0.9700 . ? C33 H33B 0.9700 . ? C34 C35 1.378(10) . ? C34 C39 1.379(10) . ? C34 H34 0.9300 . ? C35 C36 1.375(9) . ? C36 C37 1.390(10) . ? C36 H36 0.9300 . ? C37 C38 1.375(10) . ? C37 H37 0.9300 . ? C38 C39 1.391(9) . ? C38 C40 1.501(9) . ? C39 H39 0.9300 . ? C40 C45 1.385(11) . ? C40 C41 1.387(10) . ? C41 C42 1.393(11) . ? C41 H41 0.9300 . ? C42 C43 1.362(12) . ? C42 H42 0.9300 . ? C43 C44 1.369(11) . ? C43 H43 0.9300 . ? C44 C45 1.382(11) . ? C44 H44 0.9300 . ? C45 H45 0.9300 . ? C46 C47 1.204(9) . ? C47 C48 1.470(10) . ? C48 H48A 0.9700 . ? C48 H48B 0.9700 . ? C49 C54 1.369(11) . ? C49 C50 1.378(10) . ? C50 C51 1.383(10) . ? C50 H50 0.9300 . ? C51 C52 1.375(10) . ? C51 H51 0.9300 . ? C52 C53 1.398(9) . ? C52 C55 1.490(9) . ? C53 C54 1.393(10) . ? C53 H53 0.9300 . ? C54 H54 0.9300 . ? C55 C56 1.392(9) . ? C55 C60 1.390(10) . ? C56 C57 1.381(10) . ? C56 H56 0.9300 . ? C57 C58 1.363(11) . ? C57 H57 0.9300 . ? C58 C59 1.362(11) . ? C58 H58 0.9300 . ? C59 C60 1.378(11) . ? C59 H59 0.9300 . ? C60 H60 0.9300 . ? N2 O10 1.245(15) . ? N2 O9 1.225(14) . ? N2 O8 1.305(15) . ? O8 O8 1.65(2) 2_675 ? N2' O9' 1.218(18) . ? N2' O10' 1.222(19) . ? N2' O8' 1.246(19) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Ag1 C46 164.0(3) . . ? C1 Ag1 Ag3 116.59(17) . . ? C46 Ag1 Ag3 47.96(18) . . ? C1 Ag1 Ag6 48.98(18) . 2_575 ? C46 Ag1 Ag6 115.16(19) . 2_575 ? Ag3 Ag1 Ag6 70.44(2) . 2_575 ? C1 Ag1 Ag4 130.01(19) . . ? C46 Ag1 Ag4 48.01(19) . . ? Ag3 Ag1 Ag4 72.87(3) . . ? Ag6 Ag1 Ag4 101.91(3) 2_575 . ? C1 Ag1 Ag5 60.67(17) . 2_675 ? C46 Ag1 Ag5 133.83(18) . 2_675 ? Ag3 Ag1 Ag5 171.45(3) . 2_675 ? Ag6 Ag1 Ag5 104.20(2) 2_575 2_675 ? Ag4 Ag1 Ag5 102.42(3) . 2_675 ? C1 Ag1 Ag2 43.99(18) . . ? C46 Ag1 Ag2 133.63(19) . . ? Ag3 Ag1 Ag2 99.93(3) . . ? Ag6 Ag1 Ag2 66.13(3) 2_575 . ? Ag4 Ag1 Ag2 167.84(3) . . ? Ag5 Ag1 Ag2 83.40(2) 2_675 . ? C16 Ag2 C1 145.8(2) 1_545 . ? C16 Ag2 C2 121.3(2) 1_545 . ? C1 Ag2 C2 26.8(2) . . ? C16 Ag2 Ag5 42.77(16) 1_545 1_545 ? C1 Ag2 Ag5 155.07(17) . 1_545 ? C2 Ag2 Ag5 156.38(14) . 1_545 ? C16 Ag2 Ag1 158.98(17) 1_545 . ? C1 Ag2 Ag1 38.99(16) . . ? C2 Ag2 Ag1 65.78(14) . . ? Ag5 Ag2 Ag1 122.64(3) 1_545 . ? C46 Ag3 C16 164.3(3) . 2_575 ? C46 Ag3 C17 137.8(2) . 2_575 ? C16 Ag3 C17 28.50(18) 2_575 2_575 ? C46 Ag3 C47 26.3(2) . . ? C16 Ag3 C47 140.8(2) 2_575 . ? C17 Ag3 C47 112.4(2) 2_575 . ? C46 Ag3 Ag1 44.55(17) . . ? C16 Ag3 Ag1 140.74(15) 2_575 . ? C17 Ag3 Ag1 154.22(15) 2_575 . ? C47 Ag3 Ag1 69.70(14) . . ? C46 Ag3 Ag5 150.55(18) . 2_575 ? C16 Ag3 Ag5 43.56(16) 2_575 2_575 ? C17 Ag3 Ag5 71.48(15) 2_575 2_575 ? C47 Ag3 Ag5 173.97(16) . 2_575 ? Ag1 Ag3 Ag5 108.96(3) . 2_575 ? C46 Ag4 C31 143.7(2) . . ? C46 Ag4 O8' 101.6(7) . . ? C31 Ag4 O8' 110.9(7) . . ? C46 Ag4 O8 109.2(4) . . ? C31 Ag4 O8 107.1(4) . . ? O8' Ag4 O8 23.6(6) . . ? C46 Ag4 Ag1 43.13(16) . . ? C31 Ag4 Ag1 159.55(19) . . ? O8' Ag4 Ag1 77.5(6) . . ? O8 Ag4 Ag1 72.8(4) . . ? C46 Ag4 Ag5 163.30(18) . . ? C31 Ag4 Ag5 40.41(18) . . ? O8' Ag4 Ag5 85.3(7) . . ? O8 Ag4 Ag5 71.7(4) . . ? Ag1 Ag4 Ag5 126.11(4) . . ? C31 Ag5 C16 161.4(3) . . ? C31 Ag5 Ag6 49.01(19) . . ? C16 Ag5 Ag6 112.47(19) . . ? C31 Ag5 Ag3 114.35(19) . 2_575 ? C16 Ag5 Ag3 48.19(18) . 2_575 ? Ag6 Ag5 Ag3 69.39(2) . 2_575 ? C31 Ag5 Ag2 126.85(19) . 1_565 ? C16 Ag5 Ag2 47.16(19) . 1_565 ? Ag6 Ag5 Ag2 93.92(3) . 1_565 ? Ag3 Ag5 Ag2 70.04(3) 2_575 1_565 ? C31 Ag5 Ag4 45.01(19) . . ? C16 Ag5 Ag4 138.10(19) . . ? Ag6 Ag5 Ag4 76.67(3) . . ? Ag3 Ag5 Ag4 107.46(3) 2_575 . ? Ag2 Ag5 Ag4 170.44(3) 1_565 . ? C31 Ag5 Ag1 137.12(19) . 2_675 ? C16 Ag5 Ag1 61.33(18) . 2_675 ? Ag6 Ag5 Ag1 173.65(3) . 2_675 ? Ag3 Ag5 Ag1 104.36(2) 2_575 2_675 ? Ag2 Ag5 Ag1 82.63(2) 1_565 2_675 ? Ag4 Ag5 Ag1 106.89(3) . 2_675 ? C1 Ag6 C31 164.7(2) 2_575 . ? C1 Ag6 C32 137.8(2) 2_575 . ? C31 Ag6 C32 27.8(2) . . ? C1 Ag6 C2 26.8(2) 2_575 2_575 ? C31 Ag6 C2 138.1(2) . 2_575 ? C32 Ag6 C2 111.0(2) . 2_575 ? C1 Ag6 Ag1 44.33(16) 2_575 2_575 ? C31 Ag6 Ag1 150.99(18) . 2_575 ? C32 Ag6 Ag1 169.15(16) . 2_575 ? C2 Ag6 Ag1 70.73(14) 2_575 2_575 ? C1 Ag6 Ag5 146.66(17) 2_575 . ? C31 Ag6 Ag5 44.50(18) . . ? C32 Ag6 Ag5 71.70(15) . . ? C2 Ag6 Ag5 159.91(15) 2_575 . ? Ag1 Ag6 Ag5 110.54(3) 2_575 . ? C4 O1 C3 116.2(5) . . ? C19 O2 C18 116.7(6) . . ? C35 O3 C33 117.1(5) . . ? C49 O4 C48 115.9(5) . . ? O5 N1 O7 133.4(12) . . ? O5 N1 O6 114.4(10) . . ? O7 N1 O6 112.2(10) . . ? C2 C1 Ag1 168.3(6) . . ? C2 C1 Ag6 96.2(5) . 2_575 ? Ag1 C1 Ag6 86.7(2) . 2_575 ? C2 C1 Ag2 93.8(5) . . ? Ag1 C1 Ag2 97.0(3) . . ? Ag6 C1 Ag2 97.7(2) 2_575 . ? C1 C2 C3 173.5(7) . . ? C1 C2 Ag2 59.3(4) . . ? C3 C2 Ag2 125.6(5) . . ? C1 C2 Ag6 57.1(4) . 2_575 ? C3 C2 Ag6 126.2(5) . 2_575 ? Ag2 C2 Ag6 79.97(18) . 2_575 ? O1 C3 C2 107.9(5) . . ? O1 C3 H3A 110.1 . . ? C2 C3 H3A 110.1 . . ? O1 C3 H3B 110.1 . . ? C2 C3 H3B 110.1 . . ? H3A C3 H3B 108.4 . . ? O1 C4 C6 125.9(6) . . ? O1 C4 C5 115.4(6) . . ? C6 C4 C5 118.7(6) . . ? C9 C5 C4 119.9(6) . . ? C9 C5 H5 120.0 . . ? C4 C5 H5 120.0 . . ? C7 C6 C4 120.3(6) . . ? C7 C6 H6 119.9 . . ? C4 C6 H6 119.9 . . ? C6 C7 C8 122.3(6) . . ? C6 C7 H7 118.9 . . ? C8 C7 H7 118.9 . . ? C7 C8 C9 116.5(6) . . ? C7 C8 C10 121.8(6) . . ? C9 C8 C10 121.7(6) . . ? C5 C9 C8 122.3(6) . . ? C5 C9 H9 118.8 . . ? C8 C9 H9 118.8 . . ? C15 C10 C11 116.7(6) . . ? C15 C10 C8 121.3(6) . . ? C11 C10 C8 122.0(6) . . ? C12 C11 C10 120.6(7) . . ? C12 C11 H11 119.7 . . ? C10 C11 H11 119.7 . . ? C13 C12 C11 121.3(7) . . ? C13 C12 H12 119.3 . . ? C11 C12 H12 119.3 . . ? C12 C13 C14 119.3(7) . . ? C12 C13 H13 120.3 . . ? C14 C13 H13 120.3 . . ? C13 C14 C15 119.6(7) . . ? C13 C14 H14 120.2 . . ? C15 C14 H14 120.2 . . ? C14 C15 C10 122.4(7) . . ? C14 C15 H15 118.8 . . ? C10 C15 H15 118.8 . . ? C17 C16 Ag5 165.6(6) . . ? C17 C16 Ag2 104.3(5) . 1_565 ? Ag5 C16 Ag2 90.1(2) . 1_565 ? C17 C16 Ag3 88.2(5) . 2_575 ? Ag5 C16 Ag3 88.3(2) . 2_575 ? Ag2 C16 Ag3 101.8(3) 1_565 2_575 ? C16 C17 C18 174.7(7) . . ? C16 C17 Ag3 63.3(4) . 2_575 ? C18 C17 Ag3 120.8(5) . 2_575 ? O2 C18 C17 106.1(6) . . ? O2 C18 H18A 110.5 . . ? C17 C18 H18A 110.5 . . ? O2 C18 H18B 110.5 . . ? C17 C18 H18B 110.5 . . ? H18A C18 H18B 108.7 . . ? C24 C19 O2 125.1(6) . . ? C24 C19 C20 119.6(7) . . ? O2 C19 C20 115.4(7) . . ? C21 C20 C19 119.7(7) . . ? C21 C20 H20 120.1 . . ? C19 C20 H20 120.1 . . ? C20 C21 C22 122.0(7) . . ? C20 C21 H21 119.0 . . ? C22 C21 H21 119.0 . . ? C21 C22 C23 116.4(6) . . ? C21 C22 C25 122.7(6) . . ? C23 C22 C25 120.9(6) . . ? C24 C23 C22 122.4(7) . . ? C24 C23 H23 118.8 . . ? C22 C23 H23 118.8 . . ? C23 C24 C19 120.0(7) . . ? C23 C24 H24 120.0 . . ? C19 C24 H24 120.0 . . ? C30 C25 C26 115.5(7) . . ? C30 C25 C22 121.7(6) . . ? C26 C25 C22 122.8(6) . . ? C27 C26 C25 122.0(7) . . ? C27 C26 H26 119.0 . . ? C25 C26 H26 119.0 . . ? C28 C27 C26 120.8(7) . . ? C28 C27 H27 119.6 . . ? C26 C27 H27 119.6 . . ? C27 C28 C29 119.4(7) . . ? C27 C28 H28 120.3 . . ? C29 C28 H28 120.3 . . ? C28 C29 C30 120.2(7) . . ? C28 C29 H29 119.9 . . ? C30 C29 H29 119.9 . . ? C29 C30 C25 122.1(7) . . ? C29 C30 H30 118.9 . . ? C25 C30 H30 118.9 . . ? C32 C31 Ag5 165.9(6) . . ? C32 C31 Ag6 90.6(5) . . ? Ag5 C31 Ag6 86.5(3) . . ? C32 C31 Ag4 99.1(5) . . ? Ag5 C31 Ag4 94.6(3) . . ? Ag6 C31 Ag4 116.1(3) . . ? C31 C32 C33 173.7(8) . . ? C31 C32 Ag6 61.6(5) . . ? C33 C32 Ag6 121.3(5) . . ? O3 C33 C32 108.0(6) . . ? O3 C33 H33A 110.1 . . ? C32 C33 H33A 110.1 . . ? O3 C33 H33B 110.1 . . ? C32 C33 H33B 110.1 . . ? H33A C33 H33B 108.4 . . ? C35 C34 C39 120.7(6) . . ? C35 C34 H34 119.7 . . ? C39 C34 H34 119.7 . . ? C36 C35 O3 125.7(6) . . ? C36 C35 C34 119.3(6) . . ? O3 C35 C34 115.0(6) . . ? C35 C36 C37 119.2(7) . . ? C35 C36 H36 120.4 . . ? C37 C36 H36 120.4 . . ? C38 C37 C36 122.7(6) . . ? C38 C37 H37 118.6 . . ? C36 C37 H37 118.6 . . ? C37 C38 C39 116.9(6) . . ? C37 C38 C40 121.9(6) . . ? C39 C38 C40 121.2(6) . . ? C34 C39 C38 121.2(7) . . ? C34 C39 H39 119.4 . . ? C38 C39 H39 119.4 . . ? C45 C40 C41 118.1(7) . . ? C45 C40 C38 121.0(6) . . ? C41 C40 C38 120.9(7) . . ? C42 C41 C40 120.3(8) . . ? C42 C41 H41 119.8 . . ? C40 C41 H41 119.8 . . ? C43 C42 C41 120.8(7) . . ? C43 C42 H42 119.6 . . ? C41 C42 H42 119.6 . . ? C42 C43 C44 119.3(8) . . ? C42 C43 H43 120.4 . . ? C44 C43 H43 120.4 . . ? C43 C44 C45 120.7(9) . . ? C43 C44 H44 119.6 . . ? C45 C44 H44 119.6 . . ? C40 C45 C44 120.8(7) . . ? C40 C45 H45 119.6 . . ? C44 C45 H45 119.6 . . ? C47 C46 Ag1 159.1(6) . . ? C47 C46 Ag3 99.2(5) . . ? Ag1 C46 Ag3 87.5(2) . . ? C47 C46 Ag4 108.0(5) . . ? Ag1 C46 Ag4 88.9(3) . . ? Ag3 C46 Ag4 106.1(3) . . ? C46 C47 C48 176.0(8) . . ? C46 C47 Ag3 54.6(4) . . ? C48 C47 Ag3 129.4(5) . . ? O4 C48 C47 109.4(6) . . ? O4 C48 H48A 109.8 . . ? C47 C48 H48A 109.8 . . ? O4 C48 H48B 109.8 . . ? C47 C48 H48B 109.8 . . ? H48A C48 H48B 108.2 . . ? C54 C49 C50 119.6(7) . . ? C54 C49 O4 116.6(6) . . ? C50 C49 O4 123.8(7) . . ? C49 C50 C51 119.0(7) . . ? C49 C50 H50 120.5 . . ? C51 C50 H50 120.5 . . ? C52 C51 C50 123.4(7) . . ? C52 C51 H51 118.3 . . ? C50 C51 H51 118.3 . . ? C51 C52 C53 116.5(6) . . ? C51 C52 C55 121.2(6) . . ? C53 C52 C55 122.3(7) . . ? C52 C53 C54 120.8(7) . . ? C52 C53 H53 119.6 . . ? C54 C53 H53 119.6 . . ? C49 C54 C53 120.7(6) . . ? C49 C54 H54 119.7 . . ? C53 C54 H54 119.7 . . ? C56 C55 C60 117.3(7) . . ? C56 C55 C52 120.3(7) . . ? C60 C55 C52 122.4(6) . . ? C57 C56 C55 120.6(7) . . ? C57 C56 H56 119.7 . . ? C55 C56 H56 119.7 . . ? C58 C57 C56 120.8(7) . . ? C58 C57 H57 119.6 . . ? C56 C57 H57 119.6 . . ? C59 C58 C57 119.6(8) . . ? C59 C58 H58 120.2 . . ? C57 C58 H58 120.2 . . ? C58 C59 C60 120.4(8) . . ? C58 C59 H59 119.8 . . ? C60 C59 H59 119.8 . . ? C59 C60 C55 121.2(7) . . ? C59 C60 H60 119.4 . . ? C55 C60 H60 119.4 . . ? O10 N2 O9 123.7(11) . . ? O10 N2 O8 117.2(10) . . ? O9 N2 O8 118.7(10) . . ? N2 O8 O8 162.2(18) . 2_675 ? N2 O8 Ag4 102.8(8) . . ? O8 O8 Ag4 91.9(9) 2_675 . ? O9' N2' O10' 120.8(14) . . ? O9' N2' O8' 118.7(14) . . ? O10' N2' O8' 118.4(14) . . ? N2' O8' Ag4 103.4(12) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C1 Ag1 Ag2 C16 116.7(5) . . . 1_545 ? C46 Ag1 Ag2 C16 -85.6(5) . . . 1_545 ? Ag3 Ag1 Ag2 C16 -125.0(5) . . . 1_545 ? Ag6 Ag1 Ag2 C16 171.7(5) 2_575 . . 1_545 ? Ag4 Ag1 Ag2 C16 -177.7(5) . . . 1_545 ? Ag5 Ag1 Ag2 C16 62.9(5) 2_675 . . 1_545 ? C46 Ag1 Ag2 C1 157.6(4) . . . . ? Ag3 Ag1 Ag2 C1 118.2(3) . . . . ? Ag6 Ag1 Ag2 C1 54.9(3) 2_575 . . . ? Ag4 Ag1 Ag2 C1 65.6(3) . . . . ? Ag5 Ag1 Ag2 C1 -53.8(3) 2_675 . . . ? C1 Ag1 Ag2 C2 2.2(3) . . . . ? C46 Ag1 Ag2 C2 159.8(3) . . . . ? Ag3 Ag1 Ag2 C2 120.37(15) . . . . ? Ag6 Ag1 Ag2 C2 57.07(15) 2_575 . . . ? Ag4 Ag1 Ag2 C2 67.7(2) . . . . ? Ag5 Ag1 Ag2 C2 -51.67(15) 2_675 . . . ? C1 Ag1 Ag2 Ag5 157.0(3) . . . 1_545 ? C46 Ag1 Ag2 Ag5 -45.4(3) . . . 1_545 ? Ag3 Ag1 Ag2 Ag5 -84.81(4) . . . 1_545 ? Ag6 Ag1 Ag2 Ag5 -148.12(4) 2_575 . . 1_545 ? Ag4 Ag1 Ag2 Ag5 -137.45(13) . . . 1_545 ? Ag5 Ag1 Ag2 Ag5 103.14(3) 2_675 . . 1_545 ? C1 Ag1 Ag3 C46 -175.1(3) . . . . ? Ag6 Ag1 Ag3 C46 -158.1(3) 2_575 . . . ? Ag4 Ag1 Ag3 C46 -48.3(3) . . . . ? Ag2 Ag1 Ag3 C46 141.8(3) . . . . ? C1 Ag1 Ag3 C16 27.2(4) . . . 2_575 ? C46 Ag1 Ag3 C16 -157.8(4) . . . 2_575 ? Ag6 Ag1 Ag3 C16 44.1(3) 2_575 . . 2_575 ? Ag4 Ag1 Ag3 C16 153.9(3) . . . 2_575 ? Ag2 Ag1 Ag3 C16 -16.0(3) . . . 2_575 ? C1 Ag1 Ag3 C17 75.9(4) . . . 2_575 ? C46 Ag1 Ag3 C17 -109.0(4) . . . 2_575 ? Ag6 Ag1 Ag3 C17 92.8(4) 2_575 . . 2_575 ? Ag4 Ag1 Ag3 C17 -157.4(4) . . . 2_575 ? Ag2 Ag1 Ag3 C17 32.7(4) . . . 2_575 ? C1 Ag1 Ag3 C47 175.7(3) . . . . ? C46 Ag1 Ag3 C47 -9.3(3) . . . . ? Ag6 Ag1 Ag3 C47 -167.41(17) 2_575 . . . ? Ag4 Ag1 Ag3 C47 -57.61(17) . . . . ? Ag2 Ag1 Ag3 C47 132.48(17) . . . . ? C1 Ag1 Ag3 Ag5 -10.6(2) . . . 2_575 ? C46 Ag1 Ag3 Ag5 164.5(3) . . . 2_575 ? Ag6 Ag1 Ag3 Ag5 6.35(3) 2_575 . . 2_575 ? Ag4 Ag1 Ag3 Ag5 116.15(4) . . . 2_575 ? Ag2 Ag1 Ag3 Ag5 -53.77(4) . . . 2_575 ? C1 Ag1 Ag4 C46 158.9(3) . . . . ? Ag3 Ag1 Ag4 C46 48.3(2) . . . . ? Ag6 Ag1 Ag4 C46 113.3(2) 2_575 . . . ? Ag5 Ag1 Ag4 C46 -139.1(2) 2_675 . . . ? Ag2 Ag1 Ag4 C46 103.3(3) . . . . ? C1 Ag1 Ag4 C31 38.3(5) . . . . ? C46 Ag1 Ag4 C31 -120.7(6) . . . . ? Ag3 Ag1 Ag4 C31 -72.4(5) . . . . ? Ag6 Ag1 Ag4 C31 -7.4(5) 2_575 . . . ? Ag5 Ag1 Ag4 C31 100.2(5) 2_675 . . . ? Ag2 Ag1 Ag4 C31 -17.4(5) . . . . ? C1 Ag1 Ag4 O8' -78.6(6) . . . . ? C46 Ag1 Ag4 O8' 122.5(6) . . . . ? Ag3 Ag1 Ag4 O8' 170.8(6) . . . . ? Ag6 Ag1 Ag4 O8' -124.2(6) 2_575 . . . ? Ag5 Ag1 Ag4 O8' -16.6(6) 2_675 . . . ? Ag2 Ag1 Ag4 O8' -134.2(6) . . . . ? C1 Ag1 Ag4 O8 -54.6(4) . . . . ? C46 Ag1 Ag4 O8 146.5(4) . . . . ? Ag3 Ag1 Ag4 O8 -165.3(3) . . . . ? Ag6 Ag1 Ag4 O8 -100.3(3) 2_575 . . . ? Ag5 Ag1 Ag4 O8 7.4(3) 2_675 . . . ? Ag2 Ag1 Ag4 O8 -110.2(3) . . . . ? C1 Ag1 Ag4 Ag5 -3.9(2) . . . . ? C46 Ag1 Ag4 Ag5 -162.8(3) . . . . ? Ag3 Ag1 Ag4 Ag5 -114.56(4) . . . . ? Ag6 Ag1 Ag4 Ag5 -49.58(4) 2_575 . . . ? Ag5 Ag1 Ag4 Ag5 58.07(4) 2_675 . . . ? Ag2 Ag1 Ag4 Ag5 -59.54(16) . . . . ? C46 Ag4 Ag5 C31 114.2(6) . . . . ? O8' Ag4 Ag5 C31 -130.3(5) . . . . ? O8 Ag4 Ag5 C31 -150.1(4) . . . . ? Ag1 Ag4 Ag5 C31 158.8(3) . . . . ? C46 Ag4 Ag5 C16 -39.0(6) . . . . ? C31 Ag4 Ag5 C16 -153.2(4) . . . . ? O8' Ag4 Ag5 C16 76.5(5) . . . . ? O8 Ag4 Ag5 C16 56.8(4) . . . . ? Ag1 Ag4 Ag5 C16 5.6(3) . . . . ? C46 Ag4 Ag5 Ag6 69.9(6) . . . . ? C31 Ag4 Ag5 Ag6 -44.3(3) . . . . ? O8' Ag4 Ag5 Ag6 -174.6(4) . . . . ? O8 Ag4 Ag5 Ag6 165.7(3) . . . . ? Ag1 Ag4 Ag5 Ag6 114.54(4) . . . . ? C46 Ag4 Ag5 Ag3 6.9(6) . . . 2_575 ? C31 Ag4 Ag5 Ag3 -107.3(3) . . . 2_575 ? O8' Ag4 Ag5 Ag3 122.4(4) . . . 2_575 ? O8 Ag4 Ag5 Ag3 102.7(3) . . . 2_575 ? Ag1 Ag4 Ag5 Ag3 51.53(5) . . . 2_575 ? C46 Ag4 Ag5 Ag1 -104.6(6) . . . 2_675 ? C31 Ag4 Ag5 Ag1 141.2(3) . . . 2_675 ? O8' Ag4 Ag5 Ag1 10.8(4) . . . 2_675 ? O8 Ag4 Ag5 Ag1 -8.9(3) . . . 2_675 ? Ag1 Ag4 Ag5 Ag1 -60.02(4) . . . 2_675 ? C31 Ag5 Ag6 C1 163.1(4) . . . 2_575 ? C16 Ag5 Ag6 C1 -19.2(4) . . . 2_575 ? Ag3 Ag5 Ag6 C1 -41.3(3) 2_575 . . 2_575 ? Ag2 Ag5 Ag6 C1 25.6(3) 1_565 . . 2_575 ? Ag4 Ag5 Ag6 C1 -156.1(3) . . . 2_575 ? C16 Ag5 Ag6 C31 177.7(3) . . . . ? Ag3 Ag5 Ag6 C31 155.6(3) 2_575 . . . ? Ag2 Ag5 Ag6 C31 -137.5(3) 1_565 . . . ? Ag4 Ag5 Ag6 C31 40.8(3) . . . . ? C31 Ag5 Ag6 C32 6.7(3) . . . . ? C16 Ag5 Ag6 C32 -175.6(3) . . . . ? Ag3 Ag5 Ag6 C32 162.30(17) 2_575 . . . ? Ag2 Ag5 Ag6 C32 -130.73(17) 1_565 . . . ? Ag4 Ag5 Ag6 C32 47.56(17) . . . . ? C31 Ag5 Ag6 C2 108.1(5) . . . 2_575 ? C16 Ag5 Ag6 C2 -74.2(5) . . . 2_575 ? Ag3 Ag5 Ag6 C2 -96.3(4) 2_575 . . 2_575 ? Ag2 Ag5 Ag6 C2 -29.4(4) 1_565 . . 2_575 ? Ag4 Ag5 Ag6 C2 148.9(4) . . . 2_575 ? C31 Ag5 Ag6 Ag1 -162.0(3) . . . 2_575 ? C16 Ag5 Ag6 Ag1 15.7(2) . . . 2_575 ? Ag3 Ag5 Ag6 Ag1 -6.43(3) 2_575 . . 2_575 ? Ag2 Ag5 Ag6 Ag1 60.53(3) 1_565 . . 2_575 ? Ag4 Ag5 Ag6 Ag1 -121.18(3) . . . 2_575 ? C46 Ag1 C1 C2 112(3) . . . . ? Ag3 Ag1 C1 C2 126(3) . . . . ? Ag6 Ag1 C1 C2 105(3) 2_575 . . . ? Ag4 Ag1 C1 C2 36(3) . . . . ? Ag5 Ag1 C1 C2 -45(3) 2_675 . . . ? Ag2 Ag1 C1 C2 -158(3) . . . . ? C46 Ag1 C1 Ag6 7.9(10) . . . 2_575 ? Ag3 Ag1 C1 Ag6 21.3(2) . . . 2_575 ? Ag4 Ag1 C1 Ag6 -68.1(2) . . . 2_575 ? Ag5 Ag1 C1 Ag6 -149.5(3) 2_675 . . 2_575 ? Ag2 Ag1 C1 Ag6 97.4(2) . . . 2_575 ? C46 Ag1 C1 Ag2 -89.5(10) . . . . ? Ag3 Ag1 C1 Ag2 -76.1(2) . . . . ? Ag6 Ag1 C1 Ag2 -97.4(2) 2_575 . . . ? Ag4 Ag1 C1 Ag2 -165.50(7) . . . . ? Ag5 Ag1 C1 Ag2 113.1(3) 2_675 . . . ? C16 Ag2 C1 C2 30.4(7) 1_545 . . . ? Ag5 Ag2 C1 C2 124.2(5) 1_545 . . . ? Ag1 Ag2 C1 C2 175.6(6) . . . . ? C16 Ag2 C1 Ag1 -145.3(3) 1_545 . . . ? C2 Ag2 C1 Ag1 -175.6(6) . . . . ? Ag5 Ag2 C1 Ag1 -51.4(5) 1_545 . . . ? C16 Ag2 C1 Ag6 127.1(4) 1_545 . . 2_575 ? C2 Ag2 C1 Ag6 96.8(5) . . . 2_575 ? Ag5 Ag2 C1 Ag6 -139.0(2) 1_545 . . 2_575 ? Ag1 Ag2 C1 Ag6 -87.6(2) . . . 2_575 ? Ag1 C1 C2 Ag2 158(3) . . . . ? Ag6 C1 C2 Ag2 -98.2(3) 2_575 . . . ? Ag1 C1 C2 Ag6 -104(3) . . . 2_575 ? Ag2 C1 C2 Ag6 98.2(3) . . . 2_575 ? C16 Ag2 C2 C1 -160.6(5) 1_545 . . . ? Ag5 Ag2 C2 C1 -119.6(5) 1_545 . . . ? Ag1 Ag2 C2 C1 -3.0(4) . . . . ? C16 Ag2 C2 C3 14.3(6) 1_545 . . . ? C1 Ag2 C2 C3 174.9(8) . . . . ? Ag5 Ag2 C2 C3 55.3(7) 1_545 . . . ? Ag1 Ag2 C2 C3 171.9(6) . . . . ? C16 Ag2 C2 Ag6 141.9(2) 1_545 . . 2_575 ? C1 Ag2 C2 Ag6 -57.5(4) . . . 2_575 ? Ag5 Ag2 C2 Ag6 -177.1(2) 1_545 . . 2_575 ? Ag1 Ag2 C2 Ag6 -60.51(10) . . . 2_575 ? C4 O1 C3 C2 173.7(6) . . . . ? Ag2 C2 C3 O1 54.8(7) . . . . ? Ag6 C2 C3 O1 -50.1(8) 2_575 . . . ? C3 O1 C4 C6 -4.8(10) . . . . ? C3 O1 C4 C5 176.8(6) . . . . ? O1 C4 C5 C9 178.6(6) . . . . ? C6 C4 C5 C9 0.1(10) . . . . ? O1 C4 C6 C7 -178.3(7) . . . . ? C5 C4 C6 C7 0.0(11) . . . . ? C4 C6 C7 C8 1.0(12) . . . . ? C6 C7 C8 C9 -2.0(11) . . . . ? C6 C7 C8 C10 176.1(7) . . . . ? C4 C5 C9 C8 -1.2(11) . . . . ? C7 C8 C9 C5 2.1(10) . . . . ? C10 C8 C9 C5 -176.0(6) . . . . ? C7 C8 C10 C15 -26.2(10) . . . . ? C9 C8 C10 C15 151.8(7) . . . . ? C7 C8 C10 C11 155.4(7) . . . . ? C9 C8 C10 C11 -26.6(10) . . . . ? C15 C10 C11 C12 0.2(11) . . . . ? C8 C10 C11 C12 178.6(7) . . . . ? C10 C11 C12 C13 -0.4(12) . . . . ? C11 C12 C13 C14 0.6(12) . . . . ? C12 C13 C14 C15 -0.6(12) . . . . ? C13 C14 C15 C10 0.5(12) . . . . ? C11 C10 C15 C14 -0.3(11) . . . . ? C8 C10 C15 C14 -178.7(7) . . . . ? C31 Ag5 C16 C17 -99(2) . . . . ? Ag6 Ag5 C16 C17 -104(2) . . . . ? Ag3 Ag5 C16 C17 -76(2) 2_575 . . . ? Ag2 Ag5 C16 C17 -178(3) 1_565 . . . ? Ag4 Ag5 C16 C17 -9(3) . . . . ? Ag1 Ag5 C16 C17 74(2) 2_675 . . . ? C31 Ag5 C16 Ag2 79.0(8) . . . 1_565 ? Ag6 Ag5 C16 Ag2 73.6(2) . . . 1_565 ? Ag3 Ag5 C16 Ag2 101.8(3) 2_575 . . 1_565 ? Ag4 Ag5 C16 Ag2 168.60(7) . . . 1_565 ? Ag1 Ag5 C16 Ag2 -107.9(2) 2_675 . . 1_565 ? C31 Ag5 C16 Ag3 -22.8(9) . . . 2_575 ? Ag6 Ag5 C16 Ag3 -28.2(2) . . . 2_575 ? Ag2 Ag5 C16 Ag3 -101.8(3) 1_565 . . 2_575 ? Ag4 Ag5 C16 Ag3 66.8(3) . . . 2_575 ? Ag1 Ag5 C16 Ag3 150.3(3) 2_675 . . 2_575 ? Ag5 C16 C17 Ag3 76(2) . . . 2_575 ? Ag2 C16 C17 Ag3 -101.7(3) 1_565 . . 2_575 ? C19 O2 C18 C17 174.0(6) . . . . ? Ag3 C17 C18 O2 -47.3(7) 2_575 . . . ? C18 O2 C19 C24 -0.1(10) . . . . ? C18 O2 C19 C20 -179.5(6) . . . . ? C24 C19 C20 C21 -1.2(11) . . . . ? O2 C19 C20 C21 178.2(7) . . . . ? C19 C20 C21 C22 0.1(12) . . . . ? C20 C21 C22 C23 0.9(11) . . . . ? C20 C21 C22 C25 -179.7(6) . . . . ? C21 C22 C23 C24 -0.8(10) . . . . ? C25 C22 C23 C24 179.8(7) . . . . ? C22 C23 C24 C19 -0.2(11) . . . . ? O2 C19 C24 C23 -178.1(7) . . . . ? C20 C19 C24 C23 1.3(11) . . . . ? C21 C22 C25 C30 -162.1(7) . . . . ? C23 C22 C25 C30 17.3(10) . . . . ? C21 C22 C25 C26 19.2(10) . . . . ? C23 C22 C25 C26 -161.4(7) . . . . ? C30 C25 C26 C27 0.2(10) . . . . ? C22 C25 C26 C27 179.0(7) . . . . ? C25 C26 C27 C28 -0.1(12) . . . . ? C26 C27 C28 C29 -0.2(12) . . . . ? C27 C28 C29 C30 0.3(12) . . . . ? C28 C29 C30 C25 -0.1(12) . . . . ? C26 C25 C30 C29 -0.1(10) . . . . ? C22 C25 C30 C29 -178.9(7) . . . . ? C16 Ag5 C31 C32 -85(3) . . . . ? Ag6 Ag5 C31 C32 -79(2) . . . . ? Ag3 Ag5 C31 C32 -104(2) 2_575 . . . ? Ag2 Ag5 C31 C32 -21(3) 1_565 . . . ? Ag4 Ag5 C31 C32 166(3) . . . . ? Ag1 Ag5 C31 C32 104(2) 2_675 . . . ? C16 Ag5 C31 Ag6 -6.7(9) . . . . ? Ag3 Ag5 C31 Ag6 -25.1(3) 2_575 . . . ? Ag2 Ag5 C31 Ag6 57.4(3) 1_565 . . . ? Ag4 Ag5 C31 Ag6 -115.9(3) . . . . ? Ag1 Ag5 C31 Ag6 -177.69(6) 2_675 . . . ? C16 Ag5 C31 Ag4 109.2(8) . . . . ? Ag6 Ag5 C31 Ag4 115.9(3) . . . . ? Ag3 Ag5 C31 Ag4 90.8(2) 2_575 . . . ? Ag2 Ag5 C31 Ag4 173.35(6) 1_565 . . . ? Ag1 Ag5 C31 Ag4 -61.8(3) 2_675 . . . ? C1 Ag6 C31 C32 23.4(12) 2_575 . . . ? C2 Ag6 C31 C32 15.5(7) 2_575 . . . ? Ag1 Ag6 C31 C32 -157.2(4) 2_575 . . . ? Ag5 Ag6 C31 C32 166.2(6) . . . . ? C1 Ag6 C31 Ag5 -142.8(8) 2_575 . . . ? C32 Ag6 C31 Ag5 -166.2(6) . . . . ? C2 Ag6 C31 Ag5 -150.7(2) 2_575 . . . ? Ag1 Ag6 C31 Ag5 36.6(5) 2_575 . . . ? C1 Ag6 C31 Ag4 123.8(8) 2_575 . . . ? C32 Ag6 C31 Ag4 100.4(6) . . . . ? C2 Ag6 C31 Ag4 115.9(3) 2_575 . . . ? Ag1 Ag6 C31 Ag4 -56.8(5) 2_575 . . . ? Ag5 Ag6 C31 Ag4 -93.4(3) . . . . ? C46 Ag4 C31 C32 29.8(7) . . . . ? O8' Ag4 C31 C32 -122.1(7) . . . . ? O8 Ag4 C31 C32 -146.8(5) . . . . ? Ag1 Ag4 C31 C32 126.7(5) . . . . ? Ag5 Ag4 C31 C32 -176.5(7) . . . . ? C46 Ag4 C31 Ag5 -153.7(3) . . . . ? O8' Ag4 C31 Ag5 54.4(6) . . . . ? O8 Ag4 C31 Ag5 29.7(4) . . . . ? Ag1 Ag4 C31 Ag5 -56.8(6) . . . . ? C46 Ag4 C31 Ag6 -65.4(6) . . . . ? O8' Ag4 C31 Ag6 142.7(6) . . . . ? O8 Ag4 C31 Ag6 118.0(4) . . . . ? Ag1 Ag4 C31 Ag6 31.5(7) . . . . ? Ag5 Ag4 C31 Ag6 88.3(4) . . . . ? Ag5 C31 C32 Ag6 78(2) . . . . ? Ag4 C31 C32 Ag6 -116.5(3) . . . . ? C1 Ag6 C32 C31 -171.0(5) 2_575 . . . ? C2 Ag6 C32 C31 -169.0(5) 2_575 . . . ? Ag1 Ag6 C32 C31 93.6(9) 2_575 . . . ? Ag5 Ag6 C32 C31 -10.2(5) . . . . ? C1 Ag6 C32 C33 2.6(8) 2_575 . . . ? C31 Ag6 C32 C33 173.6(9) . . . . ? C2 Ag6 C32 C33 4.6(7) 2_575 . . . ? Ag1 Ag6 C32 C33 -92.8(10) 2_575 . . . ? Ag5 Ag6 C32 C33 163.4(6) . . . . ? C35 O3 C33 C32 169.8(6) . . . . ? Ag6 C32 C33 O3 161.4(5) . . . . ? C33 O3 C35 C36 2.9(11) . . . . ? C33 O3 C35 C34 -176.4(7) . . . . ? C39 C34 C35 C36 -1.0(11) . . . . ? C39 C34 C35 O3 178.4(6) . . . . ? O3 C35 C36 C37 -177.8(7) . . . . ? C34 C35 C36 C37 1.5(11) . . . . ? C35 C36 C37 C38 -0.4(12) . . . . ? C36 C37 C38 C39 -1.2(11) . . . . ? C36 C37 C38 C40 179.7(7) . . . . ? C35 C34 C39 C38 -0.7(11) . . . . ? C37 C38 C39 C34 1.8(10) . . . . ? C40 C38 C39 C34 -179.1(6) . . . . ? C37 C38 C40 C45 154.0(7) . . . . ? C39 C38 C40 C45 -25.0(10) . . . . ? C37 C38 C40 C41 -26.0(10) . . . . ? C39 C38 C40 C41 154.9(7) . . . . ? C45 C40 C41 C42 -0.2(11) . . . . ? C38 C40 C41 C42 179.9(7) . . . . ? C40 C41 C42 C43 1.3(12) . . . . ? C41 C42 C43 C44 -1.4(13) . . . . ? C42 C43 C44 C45 0.5(13) . . . . ? C41 C40 C45 C44 -0.8(11) . . . . ? C38 C40 C45 C44 179.2(7) . . . . ? C43 C44 C45 C40 0.6(13) . . . . ? C1 Ag1 C46 C47 125.6(16) . . . . ? Ag3 Ag1 C46 C47 109.3(17) . . . . ? Ag6 Ag1 C46 C47 132.2(16) 2_575 . . . ? Ag4 Ag1 C46 C47 -144.5(18) . . . . ? Ag5 Ag1 C46 C47 -82.1(17) 2_675 . . . ? Ag2 Ag1 C46 C47 51.9(17) . . . . ? C1 Ag1 C46 Ag3 16.2(11) . . . . ? Ag6 Ag1 C46 Ag3 22.8(3) 2_575 . . . ? Ag4 Ag1 C46 Ag3 106.2(3) . . . . ? Ag5 Ag1 C46 Ag3 168.57(5) 2_675 . . . ? Ag2 Ag1 C46 Ag3 -57.4(3) . . . . ? C1 Ag1 C46 Ag4 -89.9(9) . . . . ? Ag3 Ag1 C46 Ag4 -106.2(3) . . . . ? Ag6 Ag1 C46 Ag4 -83.34(19) 2_575 . . . ? Ag5 Ag1 C46 Ag4 62.4(3) 2_675 . . . ? Ag2 Ag1 C46 Ag4 -163.55(7) . . . . ? C16 Ag3 C46 C47 -42.3(11) 2_575 . . . ? C17 Ag3 C46 C47 -17.8(7) 2_575 . . . ? Ag1 Ag3 C46 C47 -160.0(7) . . . . ? Ag5 Ag3 C46 C47 169.0(4) 2_575 . . . ? C16 Ag3 C46 Ag1 117.7(8) 2_575 . . . ? C17 Ag3 C46 Ag1 142.2(3) 2_575 . . . ? C47 Ag3 C46 Ag1 160.0(7) . . . . ? Ag5 Ag3 C46 Ag1 -31.0(5) 2_575 . . . ? C16 Ag3 C46 Ag4 -154.2(7) 2_575 . . . ? C17 Ag3 C46 Ag4 -129.7(3) 2_575 . . . ? C47 Ag3 C46 Ag4 -111.9(6) . . . . ? Ag1 Ag3 C46 Ag4 88.1(3) . . . . ? Ag5 Ag3 C46 Ag4 57.1(5) 2_575 . . . ? C31 Ag4 C46 C47 -43.1(8) . . . . ? O8' Ag4 C46 C47 110.2(7) . . . . ? O8 Ag4 C46 C47 133.4(6) . . . . ? Ag1 Ag4 C46 C47 167.4(7) . . . . ? Ag5 Ag4 C46 C47 -136.5(5) . . . . ? C31 Ag4 C46 Ag1 149.5(3) . . . . ? O8' Ag4 C46 Ag1 -57.2(5) . . . . ? O8 Ag4 C46 Ag1 -34.0(4) . . . . ? Ag5 Ag4 C46 Ag1 56.1(7) . . . . ? C31 Ag4 C46 Ag3 62.5(5) . . . . ? O8' Ag4 C46 Ag3 -144.3(5) . . . . ? O8 Ag4 C46 Ag3 -121.0(3) . . . . ? Ag1 Ag4 C46 Ag3 -87.1(3) . . . . ? Ag5 Ag4 C46 Ag3 -31.0(7) . . . . ? Ag1 C46 C47 Ag3 -107.3(17) . . . . ? Ag4 C46 C47 Ag3 110.3(4) . . . . ? C16 Ag3 C47 C46 163.3(5) 2_575 . . . ? C17 Ag3 C47 C46 167.2(5) 2_575 . . . ? Ag1 Ag3 C47 C46 14.8(5) . . . . ? C46 Ag3 C47 C48 179.1(10) . . . . ? C16 Ag3 C47 C48 -17.6(8) 2_575 . . . ? C17 Ag3 C47 C48 -13.7(7) 2_575 . . . ? Ag1 Ag3 C47 C48 -166.1(7) . . . . ? C49 O4 C48 C47 175.4(6) . . . . ? Ag3 C47 C48 O4 93.9(7) . . . . ? C48 O4 C49 C54 -171.9(6) . . . . ? C48 O4 C49 C50 8.4(10) . . . . ? C54 C49 C50 C51 2.3(11) . . . . ? O4 C49 C50 C51 -177.9(7) . . . . ? C49 C50 C51 C52 -1.9(12) . . . . ? C50 C51 C52 C53 0.4(11) . . . . ? C50 C51 C52 C55 179.9(7) . . . . ? C51 C52 C53 C54 0.7(10) . . . . ? C55 C52 C53 C54 -178.8(6) . . . . ? C50 C49 C54 C53 -1.3(11) . . . . ? O4 C49 C54 C53 178.9(6) . . . . ? C52 C53 C54 C49 -0.2(11) . . . . ? C51 C52 C55 C56 19.7(10) . . . . ? C53 C52 C55 C56 -160.8(6) . . . . ? C51 C52 C55 C60 -157.8(7) . . . . ? C53 C52 C55 C60 21.7(10) . . . . ? C60 C55 C56 C57 -0.3(10) . . . . ? C52 C55 C56 C57 -177.9(6) . . . . ? C55 C56 C57 C58 0.1(12) . . . . ? C56 C57 C58 C59 -0.5(12) . . . . ? C57 C58 C59 C60 1.0(13) . . . . ? C58 C59 C60 C55 -1.1(13) . . . . ? C56 C55 C60 C59 0.8(11) . . . . ? C52 C55 C60 C59 178.3(7) . . . . ? O10 N2 O8 O8 136(6) . . . 2_675 ? O9 N2 O8 O8 -37(7) . . . 2_675 ? O10 N2 O8 Ag4 -9(2) . . . . ? O9 N2 O8 Ag4 177.9(14) . . . . ? C46 Ag4 O8 N2 -88.8(12) . . . . ? C31 Ag4 O8 N2 89.0(12) . . . . ? O8' Ag4 O8 N2 -14(2) . . . . ? Ag1 Ag4 O8 N2 -112.4(12) . . . . ? Ag5 Ag4 O8 N2 108.8(12) . . . . ? C46 Ag4 O8 O8 101.2(12) . . . 2_675 ? C31 Ag4 O8 O8 -80.9(12) . . . 2_675 ? O8' Ag4 O8 O8 176(3) . . . 2_675 ? Ag1 Ag4 O8 O8 77.7(12) . . . 2_675 ? Ag5 Ag4 O8 O8 -61.2(12) . . . 2_675 ? O9' N2' O8' Ag4 170(3) . . . . ? O10' N2' O8' Ag4 6(4) . . . . ? C46 Ag4 O8' N2' -99(3) . . . . ? C31 Ag4 O8' N2' 65(3) . . . . ? O8 Ag4 O8' N2' 150(4) . . . . ? Ag1 Ag4 O8' N2' -135(3) . . . . ? Ag5 Ag4 O8' N2' 96(3) . . . . ? _diffrn_measured_fraction_theta_max 0.998 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.998 _refine_diff_density_max 2.191 _refine_diff_density_min -1.142 _refine_diff_density_rms 0.138 data_4 _database_code_depnum_ccdc_archive 'CCDC 910773' #TrackingRef '4.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C23 H11 Ag5 F12 O10' _chemical_formula_weight 1214.67 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 21/c' _symmetry_space_group_name_Hall ' -P 2ybc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 9.0069(18) _cell_length_b 23.389(5) _cell_length_c 16.537(5) _cell_angle_alpha 90.00 _cell_angle_beta 118.56(2) _cell_angle_gamma 90.00 _cell_volume 3059.8(13) _cell_formula_units_Z 4 _cell_measurement_temperature 296 _cell_measurement_reflns_used 6762 _cell_measurement_theta_min 2.2357 _cell_measurement_theta_max 29.1423 _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.20 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.18 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.637 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2288 _exptl_absorpt_coefficient_mu 3.270 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.5608 _exptl_absorpt_correction_T_max 0.5906 _exptl_absorpt_process_details SADABS(2009) _exptl_special_details ; ? ; _diffrn_ambient_temperature 296 _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 30361 _diffrn_reflns_av_R_equivalents 0.0537 _diffrn_reflns_av_sigmaI/netI 0.0403 _diffrn_reflns_limit_h_min -10 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min -27 _diffrn_reflns_limit_k_max 27 _diffrn_reflns_limit_l_min -19 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 2.24 _diffrn_reflns_theta_max 25.00 _reflns_number_total 5381 _reflns_number_gt 4691 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0853P)^2^+21.4686P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 5381 _refine_ls_number_parameters 460 _refine_ls_number_restraints 40 _refine_ls_R_factor_all 0.0854 _refine_ls_R_factor_gt 0.0727 _refine_ls_wR_factor_ref 0.1855 _refine_ls_wR_factor_gt 0.1752 _refine_ls_goodness_of_fit_ref 1.101 _refine_ls_restrained_S_all 1.105 _refine_ls_shift/su_max 0.012 _refine_ls_shift/su_mean 0.001 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.25711(11) 0.93441(4) 0.58693(6) 0.0484(3) Uani 1 1 d . . . Ag2 Ag 0.43107(14) 0.94442(4) 0.48586(7) 0.0629(3) Uani 1 1 d . . . Ag3 Ag -0.21633(12) 0.94466(4) 0.47968(8) 0.0650(3) Uani 1 1 d . . . Ag4 Ag -0.37452(12) 0.92228(5) 0.70425(8) 0.0670(3) Uani 1 1 d U . . Ag5 Ag 0.01139(13) 0.80472(4) 0.51108(7) 0.0603(3) Uani 1 1 d . . . O1 O 0.5848(10) 1.0716(3) 0.8051(6) 0.053(2) Uani 1 1 d . . . O2 O 0.927(3) 0.8884(9) 1.0239(14) 0.093(7) Uani 0.74(4) 1 d P A 1 O2' O 0.853(10) 0.866(3) 0.988(4) 0.093(7) Uani 0.26(4) 1 d P A 2 O3 O 0.0260(9) 0.9503(4) 0.6171(6) 0.054(2) Uani 1 1 d . . . O4 O -0.1382(12) 0.9328(4) 0.6788(7) 0.0669(17) Uani 1 1 d U . . O5 O 0.2612(10) 0.8409(3) 0.6372(6) 0.059(2) Uani 1 1 d . . . O6 O 0.5320(11) 0.8441(4) 0.7438(6) 0.067(2) Uani 1 1 d . . . O7 O 0.5450(11) 0.8513(4) 0.5278(8) 0.080(3) Uani 1 1 d . . . O8 O 0.7708(11) 0.8446(3) 0.5063(6) 0.061(2) Uani 1 1 d . . . O9 O 0.1661(10) 0.9167(5) 0.3672(6) 0.069(3) Uani 1 1 d . . . O10 O 0.0196(9) 0.9047(3) 0.4443(5) 0.0472(18) Uani 1 1 d . . . C1 C 0.4506(12) 0.9993(4) 0.6066(7) 0.039(2) Uani 1 1 d . . . C2 C 0.5091(14) 1.0420(4) 0.6514(8) 0.043(2) Uani 1 1 d . . . C3 C 0.5966(16) 1.0851(5) 0.7252(9) 0.056(3) Uani 1 1 d . . . H3A H 0.7147 1.0871 0.7405 0.067 Uiso 1 1 calc R . . H3B H 0.5467 1.1224 0.7028 0.067 Uiso 1 1 calc R . . C4 C 0.6696(14) 1.0239(5) 0.8524(7) 0.049(3) Uani 1 1 d . A . C5 C 0.7947(16) 0.9962(5) 0.8424(9) 0.054(3) Uani 1 1 d . . . H5 H 0.8705 1.0219 0.8324 0.065 Uiso 1 1 calc R . . C6 C 0.8747(19) 0.9482(6) 0.8959(10) 0.069(4) Uani 1 1 d . A . H6 H 0.9571 0.9290 0.8878 0.083 Uiso 1 1 calc R . . C7 C 0.832(2) 0.9298(7) 0.9597(11) 0.078(4) Uani 1 1 d . . . C8 C 0.708(2) 0.9561(7) 0.9707(11) 0.088(5) Uani 1 1 d . A . H8 H 0.6788 0.9426 1.0140 0.106 Uiso 1 1 calc R . . C9 C 0.626(2) 1.0034(7) 0.9171(10) 0.077(4) Uani 1 1 d . . . H9 H 0.5411 1.0214 0.9244 0.092 Uiso 1 1 calc R A . C10 C 0.986(2) 0.8430(6) 0.9892(9) 0.077(4) Uani 1 1 d D . . C11 C 1.160(2) 0.8361(7) 1.0326(13) 0.115(7) Uani 1 1 d D A . H11 H 1.2303 0.8603 1.0801 0.138 Uiso 1 1 calc R . . C12 C 1.225(3) 0.7921(8) 1.0035(15) 0.132(6) Uani 1 1 d DU . . H12 H 1.3404 0.7851 1.0352 0.159 Uiso 1 1 calc R A . C13 C 1.124(3) 0.7583(9) 0.9293(14) 0.118(5) Uani 1 1 d DU . . H13 H 1.1753 0.7401 0.8950 0.142 Uiso 1 1 calc R . . C14 C 0.954(3) 0.7671(8) 0.8856(15) 0.120(6) Uani 1 1 d DU . . H14 H 0.8887 0.7545 0.8215 0.144 Uiso 1 1 calc R A . C15 C 0.886(2) 0.8090(7) 0.9161(9) 0.095(6) Uani 1 1 d D A . H15 H 0.7700 0.8144 0.8863 0.114 Uiso 1 1 calc R B 2 C16 C 0.0018(17) 0.9376(5) 0.6824(10) 0.059(3) Uani 1 1 d . . . C17 C 0.152(2) 0.9277(7) 0.7757(10) 0.071(4) Uani 1 1 d . . . C18 C 0.3923(17) 0.8227(5) 0.7049(9) 0.057(3) Uani 1 1 d . . . C19 C 0.3725(19) 0.7675(7) 0.7487(13) 0.079(5) Uani 1 1 d . . . C20 C 0.6736(15) 0.8283(5) 0.5351(9) 0.056(3) Uani 1 1 d . C . C21 C 0.7200(13) 0.7728(6) 0.5873(8) 0.068(4) Uani 1 1 d D . . C22 C 0.0400(13) 0.9063(5) 0.3731(8) 0.045(2) Uani 1 1 d . D . C23 C -0.1247(18) 0.8901(6) 0.2844(9) 0.081(5) Uani 1 1 d D . . F1 F 0.1578(13) 0.9639(5) 0.8376(6) 0.100(3) Uani 1 1 d . . . F2 F 0.1506(18) 0.8768(5) 0.8068(8) 0.144(5) Uani 1 1 d . . . F3 F 0.2989(11) 0.9342(5) 0.7747(6) 0.095(3) Uani 1 1 d . . . F4 F 0.418(2) 0.7750(6) 0.8363(9) 0.157(6) Uani 1 1 d . . . F5 F 0.4734(15) 0.7282(4) 0.7484(11) 0.144(5) Uani 1 1 d . . . F6 F 0.2226(12) 0.7466(5) 0.7126(9) 0.138(5) Uani 1 1 d . . . F7 F 0.8838(17) 0.7616(9) 0.6329(13) 0.139(12) Uani 0.669(12) 1 d PD C 1 F8 F 0.654(2) 0.7286(5) 0.5307(11) 0.122(6) Uani 0.669(12) 1 d PD C 1 F9 F 0.665(2) 0.7671(8) 0.6481(11) 0.118(6) Uani 0.669(12) 1 d PD C 1 F7' F 0.810(5) 0.741(3) 0.571(4) 0.139(12) Uani 0.331(12) 1 d P C 2 F8' F 0.608(6) 0.7503(13) 0.594(3) 0.122(6) Uani 0.331(12) 1 d P C 2 F9' F 0.832(5) 0.7865(16) 0.678(2) 0.118(6) Uani 0.331(12) 1 d P C 2 F10 F -0.094(2) 0.8705(10) 0.2230(13) 0.123(5) Uiso 0.646(9) 1 d PD D 1 F11 F -0.188(2) 0.9322(8) 0.2311(14) 0.121(5) Uiso 0.646(9) 1 d PD D 1 F12 F -0.2320(14) 0.8593(5) 0.2920(8) 0.069(3) Uiso 0.646(9) 1 d PD D 1 F12' F -0.237(3) 0.9418(9) 0.2711(16) 0.069(3) Uiso 0.354(9) 1 d PD D 2 F11' F -0.113(4) 0.9120(11) 0.212(2) 0.121(5) Uiso 0.354(9) 1 d PD D 2 F10' F -0.074(4) 0.8337(14) 0.254(2) 0.123(5) Uiso 0.354(9) 1 d PD D 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0423(5) 0.0526(5) 0.0564(6) 0.0024(4) 0.0286(4) -0.0075(4) Ag2 0.0742(7) 0.0673(6) 0.0682(7) -0.0179(5) 0.0509(6) -0.0217(5) Ag3 0.0439(5) 0.0600(6) 0.0798(7) 0.0195(5) 0.0205(5) 0.0095(4) Ag4 0.0516(6) 0.0653(6) 0.0866(8) 0.0174(5) 0.0350(6) 0.0027(5) Ag5 0.0624(6) 0.0489(6) 0.0749(7) -0.0026(5) 0.0371(5) -0.0025(4) O1 0.056(5) 0.057(5) 0.052(5) -0.008(4) 0.030(4) 0.006(4) O2 0.17(2) 0.066(12) 0.051(11) 0.007(8) 0.063(13) 0.030(12) O2' 0.17(2) 0.066(12) 0.051(11) 0.007(8) 0.063(13) 0.030(12) O3 0.039(4) 0.072(5) 0.055(5) 0.001(4) 0.026(4) 0.003(4) O4 0.0656(18) 0.070(2) 0.069(2) -0.0004(10) 0.0349(13) -0.0012(10) O5 0.059(5) 0.042(4) 0.063(5) 0.012(4) 0.018(4) 0.005(4) O6 0.059(5) 0.068(6) 0.069(6) 0.016(5) 0.026(5) -0.002(5) O7 0.061(6) 0.065(6) 0.124(9) 0.017(6) 0.052(6) 0.016(5) O8 0.068(5) 0.042(4) 0.093(6) 0.003(4) 0.053(5) 0.003(4) O9 0.048(5) 0.110(8) 0.060(6) -0.012(5) 0.034(4) -0.017(5) O10 0.042(4) 0.054(4) 0.047(4) -0.003(4) 0.023(4) -0.005(3) C1 0.037(5) 0.048(6) 0.037(6) 0.003(5) 0.022(5) 0.003(5) C2 0.046(6) 0.034(5) 0.056(7) -0.002(5) 0.030(5) 0.005(5) C3 0.069(8) 0.040(6) 0.065(8) -0.010(6) 0.038(7) -0.010(6) C4 0.044(6) 0.069(8) 0.039(6) -0.019(5) 0.025(5) -0.003(6) C5 0.059(7) 0.047(7) 0.063(8) -0.008(6) 0.035(6) -0.008(6) C6 0.078(9) 0.072(9) 0.077(9) 0.003(7) 0.053(8) 0.012(7) C7 0.107(12) 0.082(10) 0.066(9) 0.016(8) 0.058(9) 0.014(9) C8 0.135(15) 0.091(11) 0.077(11) 0.004(9) 0.081(11) 0.009(11) C9 0.081(10) 0.104(12) 0.072(9) -0.005(9) 0.058(8) 0.003(9) C10 0.112(13) 0.054(8) 0.064(9) -0.002(7) 0.041(10) -0.010(9) C11 0.115(15) 0.081(12) 0.093(13) -0.012(10) 0.004(12) -0.049(12) C12 0.165(16) 0.097(11) 0.143(14) 0.025(10) 0.080(13) 0.023(11) C13 0.177(15) 0.084(9) 0.122(13) 0.024(8) 0.095(13) 0.016(10) C14 0.189(16) 0.077(9) 0.111(13) 0.022(9) 0.085(14) 0.001(11) C15 0.074(10) 0.130(16) 0.058(10) 0.021(10) 0.012(8) -0.023(11) C16 0.066(8) 0.060(7) 0.082(9) -0.021(7) 0.060(8) -0.017(6) C17 0.086(11) 0.077(10) 0.053(8) -0.003(7) 0.037(8) -0.009(8) C18 0.064(8) 0.053(7) 0.055(8) 0.011(6) 0.029(7) 0.000(6) C19 0.064(9) 0.073(10) 0.099(13) 0.037(9) 0.037(9) 0.005(8) C20 0.052(7) 0.060(7) 0.062(8) -0.006(6) 0.032(6) -0.010(6) C21 0.062(8) 0.060(8) 0.094(11) 0.017(8) 0.047(8) 0.000(7) C22 0.040(6) 0.052(6) 0.044(6) -0.001(5) 0.022(5) 0.007(5) C23 0.085(10) 0.127(14) 0.045(8) 0.028(8) 0.042(8) 0.020(10) F1 0.111(7) 0.133(8) 0.076(6) -0.038(6) 0.062(6) -0.023(6) F2 0.207(14) 0.090(8) 0.111(8) 0.027(7) 0.057(9) 0.001(8) F3 0.065(5) 0.152(9) 0.063(5) -0.011(5) 0.026(4) 0.019(5) F4 0.216(15) 0.150(11) 0.098(9) 0.046(8) 0.070(9) -0.032(10) F5 0.126(9) 0.071(6) 0.254(16) 0.068(8) 0.107(10) 0.035(6) F6 0.078(6) 0.120(8) 0.190(12) 0.068(8) 0.044(7) -0.022(6) F7 0.072(13) 0.17(2) 0.19(3) 0.13(2) 0.077(14) 0.058(14) F8 0.197(19) 0.048(7) 0.126(13) 0.002(8) 0.080(12) -0.003(9) F9 0.152(15) 0.148(14) 0.110(11) 0.049(10) 0.108(13) 0.052(12) F7' 0.072(13) 0.17(2) 0.19(3) 0.13(2) 0.077(14) 0.058(14) F8' 0.197(19) 0.048(7) 0.126(13) 0.002(8) 0.080(12) -0.003(9) F9' 0.152(15) 0.148(14) 0.110(11) 0.049(10) 0.108(13) 0.052(12) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 C1 2.214(10) . ? Ag1 O5 2.334(8) . ? Ag1 O3 2.390(8) . ? Ag1 O10 2.408(7) . ? Ag1 Ag2 2.7941(14) . ? Ag1 Ag4 2.9492(16) 1_655 ? Ag1 Ag3 2.9937(14) 3_576 ? Ag2 C1 2.308(10) . ? Ag2 O9 2.343(9) . ? Ag2 O7 2.366(9) . ? Ag2 C2 2.591(11) 3_676 ? Ag2 C1 2.601(10) 3_676 ? Ag2 Ag2 2.822(2) 3_676 ? Ag2 Ag4 3.2142(19) 1_655 ? Ag2 Ag3 3.2258(16) 1_655 ? Ag3 O3 2.280(8) . ? Ag3 C1 2.309(10) 3_576 ? Ag3 O8 2.395(8) 1_455 ? Ag3 C2 2.507(11) 3_576 ? Ag3 Ag1 2.9937(14) 3_576 ? Ag3 Ag2 3.2258(16) 1_455 ? Ag4 O6 2.238(9) 1_455 ? Ag4 O4 2.372(10) . ? Ag4 C1 2.429(10) 1_455 ? Ag4 C5 2.683(12) 1_455 ? Ag4 Ag1 2.9492(16) 1_455 ? Ag4 Ag2 3.2142(19) 1_455 ? Ag5 O8 2.325(8) 1_455 ? Ag5 O5 2.375(8) . ? Ag5 C13 2.52(2) 4_475 ? Ag5 C14 2.523(18) 4_475 ? O1 C4 1.368(15) . ? O1 C3 1.411(14) . ? O2 C7 1.39(2) . ? O2 C10 1.42(2) . ? O2' C10 1.31(7) . ? O2' C7 1.54(6) . ? O2' C15 1.91(6) . ? O3 C16 1.235(14) . ? O4 C16 1.239(14) . ? O5 C18 1.251(14) . ? O6 C18 1.213(15) . ? O6 Ag4 2.238(9) 1_655 ? O7 C20 1.229(14) . ? O8 C20 1.241(14) . ? O8 Ag5 2.325(8) 1_655 ? O8 Ag3 2.395(8) 1_655 ? O9 C22 1.210(13) . ? O10 C22 1.277(13) . ? C1 C2 1.205(14) . ? C1 Ag3 2.309(10) 3_576 ? C1 Ag4 2.429(10) 1_655 ? C1 Ag2 2.601(10) 3_676 ? C2 C3 1.486(16) . ? C2 Ag3 2.507(11) 3_576 ? C2 Ag2 2.591(11) 3_676 ? C3 H3A 0.9700 . ? C3 H3B 0.9700 . ? C4 C9 1.389(17) . ? C4 C5 1.377(16) . ? C5 C6 1.398(18) . ? C5 Ag4 2.683(12) 1_655 ? C5 H5 0.9800 . ? C6 C7 1.356(19) . ? C6 H6 0.9300 . ? C7 C8 1.36(2) . ? C8 C9 1.39(2) . ? C8 H8 0.9300 . ? C9 H9 0.9300 . ? C12 H12 0.9300 . ? C13 Ag5 2.521(19) 4_676 ? C13 H13 0.9800 . ? C14 Ag5 2.523(18) 4_676 ? C14 H14 0.9800 . ? C15 H15 0.9300 . ? C16 C17 1.51(2) . ? C17 F2 1.300(17) . ? C17 F3 1.339(17) . ? C17 F1 1.311(16) . ? C18 C19 1.532(18) . ? C19 F6 1.283(16) . ? C19 F5 1.295(19) . ? C19 F4 1.31(2) . ? C20 C21 1.503(18) . ? C21 F8' 1.19(5) . ? C21 F7' 1.21(6) . ? C21 F9 1.322(12) . ? C21 F7 1.323(12) . ? C21 F8 1.328(12) . ? C21 F9' 1.39(4) . ? C22 C23 1.553(19) . ? C23 F10' 1.55(4) . ? C23 F10 1.260(13) . ? C23 F12 1.259(12) . ? C23 F11 1.261(12) . ? C23 F11' 1.35(4) . ? C23 F12' 1.52(3) . ? F12' F11' 1.93(3) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 Ag1 O5 135.4(3) . . ? C1 Ag1 O3 124.5(3) . . ? O5 Ag1 O3 86.5(3) . . ? C1 Ag1 O10 127.6(3) . . ? O5 Ag1 O10 86.2(3) . . ? O3 Ag1 O10 78.1(3) . . ? C1 Ag1 Ag2 53.4(3) . . ? O5 Ag1 Ag2 111.9(2) . . ? O3 Ag1 Ag2 154.8(2) . . ? O10 Ag1 Ag2 85.88(18) . . ? C1 Ag1 Ag4 53.9(3) . 1_655 ? O5 Ag1 Ag4 81.6(2) . 1_655 ? O3 Ag1 Ag4 134.1(2) . 1_655 ? O10 Ag1 Ag4 144.08(18) . 1_655 ? Ag2 Ag1 Ag4 68.00(4) . 1_655 ? C1 Ag1 Ag3 49.9(3) . 3_576 ? O5 Ag1 Ag3 174.1(2) . 3_576 ? O3 Ag1 Ag3 87.9(2) . 3_576 ? O10 Ag1 Ag3 91.00(19) . 3_576 ? Ag2 Ag1 Ag3 72.90(4) . 3_576 ? Ag4 Ag1 Ag3 103.56(4) 1_655 3_576 ? C1 Ag2 O9 120.3(3) . . ? C1 Ag2 O7 114.5(4) . . ? O9 Ag2 O7 96.7(4) . . ? C1 Ag2 C2 136.7(3) . 3_676 ? O9 Ag2 C2 81.7(3) . 3_676 ? O7 Ag2 C2 97.3(3) . 3_676 ? C1 Ag2 C1 110.1(3) . 3_676 ? O9 Ag2 C1 100.8(3) . 3_676 ? O7 Ag2 C1 113.3(3) . 3_676 ? C2 Ag2 C1 26.8(3) 3_676 3_676 ? C1 Ag2 Ag1 50.3(3) . . ? O9 Ag2 Ag1 80.8(2) . . ? O7 Ag2 Ag1 92.1(3) . . ? C2 Ag2 Ag1 161.0(3) 3_676 . ? C1 Ag2 Ag1 154.0(2) 3_676 . ? C1 Ag2 Ag2 59.9(3) . 3_676 ? O9 Ag2 Ag2 125.8(3) . 3_676 ? O7 Ag2 Ag2 134.8(2) . 3_676 ? C2 Ag2 Ag2 76.9(2) 3_676 3_676 ? C1 Ag2 Ag2 50.2(2) 3_676 3_676 ? Ag1 Ag2 Ag2 107.83(5) . 3_676 ? C1 Ag2 Ag4 48.9(3) . 1_655 ? O9 Ag2 Ag4 133.3(2) . 1_655 ? O7 Ag2 Ag4 66.1(3) . 1_655 ? C2 Ag2 Ag4 140.7(3) 3_676 1_655 ? C1 Ag2 Ag4 125.9(2) 3_676 1_655 ? Ag1 Ag2 Ag4 58.29(4) . 1_655 ? Ag2 Ag2 Ag4 90.12(5) 3_676 1_655 ? C1 Ag2 Ag3 110.9(3) . 1_655 ? O9 Ag2 Ag3 126.7(2) . 1_655 ? O7 Ag2 Ag3 73.5(2) . 1_655 ? C2 Ag2 Ag3 49.6(2) 3_676 1_655 ? C1 Ag2 Ag3 45.1(2) 3_676 1_655 ? Ag1 Ag2 Ag3 149.45(5) . 1_655 ? Ag2 Ag2 Ag3 69.02(4) 3_676 1_655 ? Ag4 Ag2 Ag3 91.15(5) 1_655 1_655 ? O3 Ag3 C1 137.7(3) . 3_576 ? O3 Ag3 O8 88.9(3) . 1_455 ? C1 Ag3 O8 124.0(3) 3_576 1_455 ? O3 Ag3 C2 164.6(3) . 3_576 ? C1 Ag3 C2 28.6(3) 3_576 3_576 ? O8 Ag3 C2 99.1(3) 1_455 3_576 ? O3 Ag3 Ag1 101.7(2) . 3_576 ? C1 Ag3 Ag1 47.2(3) 3_576 3_576 ? O8 Ag3 Ag1 169.4(2) 1_455 3_576 ? C2 Ag3 Ag1 70.8(2) 3_576 3_576 ? O3 Ag3 Ag2 117.1(2) . 1_455 ? C1 Ag3 Ag2 53.0(2) 3_576 1_455 ? O8 Ag3 Ag2 81.8(2) 1_455 1_455 ? C2 Ag3 Ag2 51.9(2) 3_576 1_455 ? Ag1 Ag3 Ag2 93.66(4) 3_576 1_455 ? O6 Ag4 O4 129.2(3) 1_455 . ? O6 Ag4 C1 125.8(3) 1_455 1_455 ? O4 Ag4 C1 99.0(3) . 1_455 ? O6 Ag4 C5 114.7(4) 1_455 1_455 ? O4 Ag4 C5 83.8(3) . 1_455 ? C1 Ag4 C5 90.7(4) 1_455 1_455 ? O6 Ag4 Ag1 79.0(2) 1_455 1_455 ? O4 Ag4 Ag1 134.1(2) . 1_455 ? C1 Ag4 Ag1 47.4(2) 1_455 1_455 ? C5 Ag4 Ag1 120.0(3) 1_455 1_455 ? O6 Ag4 Ag2 112.4(2) 1_455 1_455 ? O4 Ag4 Ag2 80.6(2) . 1_455 ? C1 Ag4 Ag2 45.7(2) 1_455 1_455 ? C5 Ag4 Ag2 129.4(3) 1_455 1_455 ? Ag1 Ag4 Ag2 53.71(4) 1_455 1_455 ? O8 Ag5 O5 111.3(3) 1_455 . ? O8 Ag5 C13 145.6(5) 1_455 4_475 ? O5 Ag5 C13 102.9(5) . 4_475 ? O8 Ag5 C14 114.7(5) 1_455 4_475 ? O5 Ag5 C14 134.0(5) . 4_475 ? C13 Ag5 C14 31.4(3) 4_475 4_475 ? C4 O1 C3 116.6(9) . . ? C7 O2 C10 115.2(15) . . ? C10 O2' C7 113(5) . . ? C10 O2' C15 45.7(18) . . ? C7 O2' C15 122(3) . . ? C16 O3 Ag3 111.9(8) . . ? C16 O3 Ag1 132.8(8) . . ? Ag3 O3 Ag1 107.3(3) . . ? C16 O4 Ag4 168.6(10) . . ? C18 O5 Ag1 119.0(8) . . ? C18 O5 Ag5 139.2(8) . . ? Ag1 O5 Ag5 100.0(3) . . ? C18 O6 Ag4 128.4(8) . 1_655 ? C20 O7 Ag2 133.5(9) . . ? C20 O8 Ag5 132.9(8) . 1_655 ? C20 O8 Ag3 118.4(8) . 1_655 ? Ag5 O8 Ag3 105.8(3) 1_655 1_655 ? C22 O9 Ag2 127.4(8) . . ? C22 O10 Ag1 116.2(7) . . ? C2 C1 Ag1 137.8(9) . . ? C2 C1 Ag3 84.9(7) . 3_576 ? Ag1 C1 Ag3 82.9(3) . 3_576 ? C2 C1 Ag2 145.4(9) . . ? Ag1 C1 Ag2 76.3(3) . . ? Ag3 C1 Ag2 96.4(4) 3_576 . ? C2 C1 Ag4 104.6(8) . 1_655 ? Ag1 C1 Ag4 78.7(3) . 1_655 ? Ag3 C1 Ag4 160.5(5) 3_576 1_655 ? Ag2 C1 Ag4 85.4(3) . 1_655 ? C2 C1 Ag2 76.1(7) . 3_676 ? Ag1 C1 Ag2 140.8(5) . 3_676 ? Ag3 C1 Ag2 81.9(3) 3_576 3_676 ? Ag2 C1 Ag2 69.9(3) . 3_676 ? Ag4 C1 Ag2 116.6(4) 1_655 3_676 ? C1 C2 C3 166.5(12) . . ? C1 C2 Ag3 66.5(7) . 3_576 ? C3 C2 Ag3 123.4(8) . 3_576 ? C1 C2 Ag2 77.1(7) . 3_676 ? C3 C2 Ag2 112.6(7) . 3_676 ? Ag3 C2 Ag2 78.5(3) 3_576 3_676 ? O1 C3 C2 111.6(9) . . ? O1 C3 H3A 109.3 . . ? C2 C3 H3A 109.3 . . ? O1 C3 H3B 109.3 . . ? C2 C3 H3B 109.3 . . ? H3A C3 H3B 108.0 . . ? O1 C4 C9 115.9(11) . . ? O1 C4 C5 125.4(11) . . ? C9 C4 C5 118.7(13) . . ? C6 C5 C4 120.3(12) . . ? C6 C5 Ag4 86.1(8) . 1_655 ? C4 C5 Ag4 103.9(8) . 1_655 ? C6 C5 H5 114.1 . . ? C4 C5 H5 114.1 . . ? Ag4 C5 H5 114.1 1_655 . ? C7 C6 C5 119.6(13) . . ? C7 C6 H6 120.2 . . ? C5 C6 H6 120.2 . . ? C6 C7 C8 121.2(14) . . ? C6 C7 O2 120.7(16) . . ? C8 C7 O2 117.5(14) . . ? C6 C7 O2' 120(2) . . ? C8 C7 O2' 113(3) . . ? C7 C8 C9 119.7(14) . . ? C7 C8 H8 120.1 . . ? C9 C8 H8 120.1 . . ? C8 C9 C4 120.4(13) . . ? C8 C9 H9 119.8 . . ? C4 C9 H9 119.8 . . ? O2' C10 C15 91(3) . . ? O2' C10 C11 149(3) . . ? C15 C10 C11 119.7(15) . . ? C15 C10 O2 125.1(18) . . ? C11 C10 O2 115.1(17) . . ? C10 C11 C12 118.0(17) . . ? C10 C11 H11 121.0 . . ? C12 C11 H11 121.0 . . ? C13 C12 C11 122(2) . . ? C13 C12 H12 118.9 . . ? C11 C12 H12 118.9 . . ? C14 C13 C12 119(2) . . ? C14 C13 Ag5 74.4(12) . 4_676 ? C12 C13 Ag5 96.9(15) . 4_676 ? C14 C13 H13 118.5 . . ? C12 C13 H13 118.5 . . ? Ag5 C13 H13 118.5 4_676 . ? C13 C14 C15 120(2) . . ? C13 C14 Ag5 74.2(12) . 4_676 ? C15 C14 Ag5 97.2(12) . 4_676 ? C13 C14 H14 118.0 . . ? C15 C14 H14 118.0 . . ? Ag5 C14 H14 118.0 4_676 . ? C10 C15 C14 121.4(17) . . ? C14 C15 O2' 164(3) . . ? C10 C15 H15 119.3 . . ? C14 C15 H15 119.3 . . ? O2' C15 H15 76.0 . . ? O3 C16 O4 125.5(14) . . ? O3 C16 C17 119.0(11) . . ? O4 C16 C17 115.5(12) . . ? F2 C17 F3 107.8(15) . . ? F2 C17 F1 106.6(12) . . ? F3 C17 F1 105.4(12) . . ? F2 C17 C16 111.9(13) . . ? F3 C17 C16 112.2(11) . . ? F1 C17 C16 112.4(13) . . ? O6 C18 O5 129.0(12) . . ? O6 C18 C19 115.0(12) . . ? O5 C18 C19 115.9(12) . . ? F6 C19 F5 108.2(16) . . ? F6 C19 F4 105.5(15) . . ? F5 C19 F4 104.5(15) . . ? F6 C19 C18 115.8(13) . . ? F5 C19 C18 110.8(13) . . ? F4 C19 C18 111.4(14) . . ? O7 C20 O8 129.2(13) . . ? O7 C20 C21 115.2(11) . . ? O8 C20 C21 115.6(11) . . ? F8' C21 F7' 116(3) . . ? F7' C21 F9 130(3) . . ? F8' C21 F7 129(2) . . ? F7' C21 F7 48(3) . . ? F9 C21 F7 105.6(10) . . ? F8' C21 F8 66.9(19) . . ? F7' C21 F8 60(3) . . ? F9 C21 F8 104.6(10) . . ? F7 C21 F8 104.5(10) . . ? F8' C21 F9' 102(2) . . ? F7' C21 F9' 99(3) . . ? F9 C21 F9' 63.0(15) . . ? F7 C21 F9' 52.6(15) . . ? F8 C21 F9' 142(2) . . ? F8' C21 C20 115(2) . . ? F7' C21 C20 115(2) . . ? F9 C21 C20 114.9(12) . . ? F7 C21 C20 115.2(12) . . ? F8 C21 C20 111.0(11) . . ? F9' C21 C20 106.4(17) . . ? O9 C22 O10 129.5(11) . . ? O9 C22 C23 118.8(10) . . ? O10 C22 C23 111.7(9) . . ? F10' C23 F12 84.3(16) . . ? F10 C23 F12 110.2(17) . . ? F10' C23 F11 122.9(17) . . ? F10 C23 F11 85.5(14) . . ? F12 C23 F11 113.8(16) . . ? F10' C23 F11' 83.1(13) . . ? F12 C23 F11' 134(2) . . ? F10' C23 C22 102.5(16) . . ? F10 C23 C22 111.8(14) . . ? F12 C23 C22 118.6(11) . . ? F11 C23 C22 112.2(15) . . ? F11' C23 C22 107.6(18) . . ? F10' C23 F12' 154.6(19) . . ? F10 C23 F12' 124.0(16) . . ? F12 C23 F12' 88.9(13) . . ? F11' C23 F12' 84.1(12) . . ? C22 C23 F12' 102.2(13) . . ? C23 F11' F12' 51.8(13) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag O5 Ag1 Ag2 C1 -131.1(4) . . . . ? O3 Ag1 Ag2 C1 94.3(6) . . . . ? O10 Ag1 Ag2 C1 144.7(4) . . . . ? Ag4 Ag1 Ag2 C1 -60.5(3) 1_655 . . . ? Ag3 Ag1 Ag2 C1 52.4(3) 3_576 . . . ? C1 Ag1 Ag2 O9 -142.9(4) . . . . ? O5 Ag1 Ag2 O9 85.9(3) . . . . ? O3 Ag1 Ag2 O9 -48.6(6) . . . . ? O10 Ag1 Ag2 O9 1.7(3) . . . . ? Ag4 Ag1 Ag2 O9 156.5(3) 1_655 . . . ? Ag3 Ag1 Ag2 O9 -90.6(3) 3_576 . . . ? C1 Ag1 Ag2 O7 120.6(4) . . . . ? O5 Ag1 Ag2 O7 -10.5(3) . . . . ? O3 Ag1 Ag2 O7 -145.0(5) . . . . ? O10 Ag1 Ag2 O7 -94.7(3) . . . . ? Ag4 Ag1 Ag2 O7 60.1(3) 1_655 . . . ? Ag3 Ag1 Ag2 O7 173.0(3) 3_576 . . . ? C1 Ag1 Ag2 C2 -119.7(8) . . . 3_676 ? O5 Ag1 Ag2 C2 109.2(7) . . . 3_676 ? O3 Ag1 Ag2 C2 -25.4(9) . . . 3_676 ? O10 Ag1 Ag2 C2 25.0(7) . . . 3_676 ? Ag4 Ag1 Ag2 C2 179.8(7) 1_655 . . 3_676 ? Ag3 Ag1 Ag2 C2 -67.4(7) 3_576 . . 3_676 ? C1 Ag1 Ag2 C1 -47.2(8) . . . 3_676 ? O5 Ag1 Ag2 C1 -178.3(6) . . . 3_676 ? O3 Ag1 Ag2 C1 47.1(7) . . . 3_676 ? O10 Ag1 Ag2 C1 97.5(6) . . . 3_676 ? Ag4 Ag1 Ag2 C1 -107.7(5) 1_655 . . 3_676 ? Ag3 Ag1 Ag2 C1 5.2(5) 3_576 . . 3_676 ? C1 Ag1 Ag2 Ag2 -18.2(3) . . . 3_676 ? O5 Ag1 Ag2 Ag2 -149.3(2) . . . 3_676 ? O3 Ag1 Ag2 Ag2 76.2(5) . . . 3_676 ? O10 Ag1 Ag2 Ag2 126.52(19) . . . 3_676 ? Ag4 Ag1 Ag2 Ag2 -78.69(6) 1_655 . . 3_676 ? Ag3 Ag1 Ag2 Ag2 34.20(6) 3_576 . . 3_676 ? C1 Ag1 Ag2 Ag4 60.5(3) . . . 1_655 ? O5 Ag1 Ag2 Ag4 -70.6(2) . . . 1_655 ? O3 Ag1 Ag2 Ag4 154.9(5) . . . 1_655 ? O10 Ag1 Ag2 Ag4 -154.80(19) . . . 1_655 ? Ag3 Ag1 Ag2 Ag4 112.89(4) 3_576 . . 1_655 ? C1 Ag1 Ag2 Ag3 60.6(3) . . . 1_655 ? O5 Ag1 Ag2 Ag3 -70.5(2) . . . 1_655 ? O3 Ag1 Ag2 Ag3 154.9(5) . . . 1_655 ? O10 Ag1 Ag2 Ag3 -154.7(2) . . . 1_655 ? Ag4 Ag1 Ag2 Ag3 0.06(8) 1_655 . . 1_655 ? Ag3 Ag1 Ag2 Ag3 112.94(8) 3_576 . . 1_655 ? C1 Ag3 O3 C16 81.8(9) 3_576 . . . ? O8 Ag3 O3 C16 -62.2(8) 1_455 . . . ? C2 Ag3 O3 C16 59.4(16) 3_576 . . . ? Ag1 Ag3 O3 C16 118.3(8) 3_576 . . . ? Ag2 Ag3 O3 C16 18.0(9) 1_455 . . . ? C1 Ag3 O3 Ag1 -125.1(4) 3_576 . . . ? O8 Ag3 O3 Ag1 90.9(3) 1_455 . . . ? C2 Ag3 O3 Ag1 -147.5(11) 3_576 . . . ? Ag1 Ag3 O3 Ag1 -88.5(3) 3_576 . . . ? Ag2 Ag3 O3 Ag1 171.16(17) 1_455 . . . ? C1 Ag1 O3 C16 -100.1(11) . . . . ? O5 Ag1 O3 C16 45.3(11) . . . . ? O10 Ag1 O3 C16 132.1(11) . . . . ? Ag2 Ag1 O3 C16 -176.2(8) . . . . ? Ag4 Ag1 O3 C16 -29.5(12) 1_655 . . . ? Ag3 Ag1 O3 C16 -136.4(11) 3_576 . . . ? C1 Ag1 O3 Ag3 114.7(4) . . . . ? O5 Ag1 O3 Ag3 -99.9(4) . . . . ? O10 Ag1 O3 Ag3 -13.1(3) . . . . ? Ag2 Ag1 O3 Ag3 38.6(7) . . . . ? Ag4 Ag1 O3 Ag3 -174.64(10) 1_655 . . . ? Ag3 Ag1 O3 Ag3 78.4(3) 3_576 . . . ? O6 Ag4 O4 C16 -74(4) 1_455 . . . ? C1 Ag4 O4 C16 133(4) 1_455 . . . ? C5 Ag4 O4 C16 43(4) 1_455 . . . ? Ag1 Ag4 O4 C16 169(4) 1_455 . . . ? Ag2 Ag4 O4 C16 175(4) 1_455 . . . ? C1 Ag1 O5 C18 17.9(11) . . . . ? O3 Ag1 O5 C18 -120.2(9) . . . . ? O10 Ag1 O5 C18 161.4(9) . . . . ? Ag2 Ag1 O5 C18 77.4(9) . . . . ? Ag4 Ag1 O5 C18 15.3(9) 1_655 . . . ? C1 Ag1 O5 Ag5 -149.9(4) . . . . ? O3 Ag1 O5 Ag5 71.9(3) . . . . ? O10 Ag1 O5 Ag5 -6.4(3) . . . . ? Ag2 Ag1 O5 Ag5 -90.4(3) . . . . ? Ag4 Ag1 O5 Ag5 -152.5(3) 1_655 . . . ? O8 Ag5 O5 C18 125.9(13) 1_455 . . . ? C13 Ag5 O5 C18 -57.9(14) 4_475 . . . ? C14 Ag5 O5 C18 -53.1(15) 4_475 . . . ? O8 Ag5 O5 Ag1 -70.5(4) 1_455 . . . ? C13 Ag5 O5 Ag1 105.7(6) 4_475 . . . ? C14 Ag5 O5 Ag1 110.5(7) 4_475 . . . ? C1 Ag2 O7 C20 -107.0(13) . . . . ? O9 Ag2 O7 C20 125.3(13) . . . . ? C2 Ag2 O7 C20 42.9(14) 3_676 . . . ? C1 Ag2 O7 C20 20.5(14) 3_676 . . . ? Ag1 Ag2 O7 C20 -153.8(13) . . . . ? Ag2 Ag2 O7 C20 -35.9(15) 3_676 . . . ? Ag4 Ag2 O7 C20 -100.0(13) 1_655 . . . ? Ag3 Ag2 O7 C20 -1.1(12) 1_655 . . . ? C1 Ag2 O9 C22 -32.5(12) . . . . ? O7 Ag2 O9 C22 91.0(11) . . . . ? C2 Ag2 O9 C22 -172.6(11) 3_676 . . . ? C1 Ag2 O9 C22 -153.6(11) 3_676 . . . ? Ag1 Ag2 O9 C22 0.0(10) . . . . ? Ag2 Ag2 O9 C22 -105.4(11) 3_676 . . . ? Ag4 Ag2 O9 C22 27.7(13) 1_655 . . . ? Ag3 Ag2 O9 C22 165.3(9) 1_655 . . . ? C1 Ag1 O10 C22 31.5(9) . . . . ? O5 Ag1 O10 C22 -116.7(8) . . . . ? O3 Ag1 O10 C22 156.1(8) . . . . ? Ag2 Ag1 O10 C22 -4.4(7) . . . . ? Ag4 Ag1 O10 C22 -46.7(9) 1_655 . . . ? Ag3 Ag1 O10 C22 68.4(7) 3_576 . . . ? O5 Ag1 C1 C2 -102.6(13) . . . . ? O3 Ag1 C1 C2 23.6(14) . . . . ? O10 Ag1 C1 C2 125.9(12) . . . . ? Ag2 Ag1 C1 C2 172.6(14) . . . . ? Ag4 Ag1 C1 C2 -99.4(13) 1_655 . . . ? Ag3 Ag1 C1 C2 74.2(12) 3_576 . . . ? O5 Ag1 C1 Ag3 -176.8(3) . . . 3_576 ? O3 Ag1 C1 Ag3 -50.6(4) . . . 3_576 ? O10 Ag1 C1 Ag3 51.7(4) . . . 3_576 ? Ag2 Ag1 C1 Ag3 98.4(3) . . . 3_576 ? Ag4 Ag1 C1 Ag3 -173.6(4) 1_655 . . 3_576 ? O5 Ag1 C1 Ag2 84.8(5) . . . . ? O3 Ag1 C1 Ag2 -149.1(3) . . . . ? O10 Ag1 C1 Ag2 -46.7(4) . . . . ? Ag4 Ag1 C1 Ag2 88.0(3) 1_655 . . . ? Ag3 Ag1 C1 Ag2 -98.4(3) 3_576 . . . ? O5 Ag1 C1 Ag4 -3.2(6) . . . 1_655 ? O3 Ag1 C1 Ag4 123.0(3) . . . 1_655 ? O10 Ag1 C1 Ag4 -134.7(3) . . . 1_655 ? Ag2 Ag1 C1 Ag4 -88.0(3) . . . 1_655 ? Ag3 Ag1 C1 Ag4 173.6(4) 3_576 . . 1_655 ? O5 Ag1 C1 Ag2 115.4(7) . . . 3_676 ? O3 Ag1 C1 Ag2 -118.4(7) . . . 3_676 ? O10 Ag1 C1 Ag2 -16.0(9) . . . 3_676 ? Ag2 Ag1 C1 Ag2 30.7(5) . . . 3_676 ? Ag4 Ag1 C1 Ag2 118.6(8) 1_655 . . 3_676 ? Ag3 Ag1 C1 Ag2 -67.8(6) 3_576 . . 3_676 ? O9 Ag2 C1 C2 -127.7(15) . . . . ? O7 Ag2 C1 C2 117.8(15) . . . . ? C2 Ag2 C1 C2 -15.7(19) 3_676 . . . ? C1 Ag2 C1 C2 -11.3(14) 3_676 . . . ? Ag1 Ag2 C1 C2 -171.3(17) . . . . ? Ag2 Ag2 C1 C2 -11.3(14) 3_676 . . . ? Ag4 Ag2 C1 C2 109.2(16) 1_655 . . . ? Ag3 Ag2 C1 C2 37.0(16) 1_655 . . . ? O9 Ag2 C1 Ag1 43.6(4) . . . . ? O7 Ag2 C1 Ag1 -70.9(4) . . . . ? C2 Ag2 C1 Ag1 155.6(4) 3_676 . . . ? C1 Ag2 C1 Ag1 159.9(3) 3_676 . . . ? Ag2 Ag2 C1 Ag1 159.9(3) 3_676 . . . ? Ag4 Ag2 C1 Ag1 -79.5(3) 1_655 . . . ? Ag3 Ag2 C1 Ag1 -151.70(14) 1_655 . . . ? O9 Ag2 C1 Ag3 -37.5(5) . . . 3_576 ? O7 Ag2 C1 Ag3 -152.0(3) . . . 3_576 ? C2 Ag2 C1 Ag3 74.6(6) 3_676 . . 3_576 ? C1 Ag2 C1 Ag3 78.9(3) 3_676 . . 3_576 ? Ag1 Ag2 C1 Ag3 -81.0(3) . . . 3_576 ? Ag2 Ag2 C1 Ag3 78.9(3) 3_676 . . 3_576 ? Ag4 Ag2 C1 Ag3 -160.5(5) 1_655 . . 3_576 ? Ag3 Ag2 C1 Ag3 127.3(2) 1_655 . . 3_576 ? O9 Ag2 C1 Ag4 123.0(3) . . . 1_655 ? O7 Ag2 C1 Ag4 8.6(4) . . . 1_655 ? C2 Ag2 C1 Ag4 -124.9(4) 3_676 . . 1_655 ? C1 Ag2 C1 Ag4 -120.6(3) 3_676 . . 1_655 ? Ag1 Ag2 C1 Ag4 79.5(3) . . . 1_655 ? Ag2 Ag2 C1 Ag4 -120.6(3) 3_676 . . 1_655 ? Ag3 Ag2 C1 Ag4 -72.2(3) 1_655 . . 1_655 ? O9 Ag2 C1 Ag2 -116.4(3) . . . 3_676 ? O7 Ag2 C1 Ag2 129.1(3) . . . 3_676 ? C2 Ag2 C1 Ag2 -4.3(5) 3_676 . . 3_676 ? C1 Ag2 C1 Ag2 0.0 3_676 . . 3_676 ? Ag1 Ag2 C1 Ag2 -159.9(3) . . . 3_676 ? Ag4 Ag2 C1 Ag2 120.6(3) 1_655 . . 3_676 ? Ag3 Ag2 C1 Ag2 48.4(2) 1_655 . . 3_676 ? Ag1 C1 C2 C3 66(5) . . . . ? Ag3 C1 C2 C3 140(5) 3_576 . . . ? Ag2 C1 C2 C3 -126(4) . . . . ? Ag4 C1 C2 C3 -23(5) 1_655 . . . ? Ag2 C1 C2 C3 -137(5) 3_676 . . . ? Ag1 C1 C2 Ag3 -73.5(11) . . . 3_576 ? Ag2 C1 C2 Ag3 93.9(14) . . . 3_576 ? Ag4 C1 C2 Ag3 -162.7(6) 1_655 . . 3_576 ? Ag2 C1 C2 Ag3 82.9(3) 3_676 . . 3_576 ? Ag1 C1 C2 Ag2 -156.4(11) . . . 3_676 ? Ag3 C1 C2 Ag2 -82.9(3) 3_576 . . 3_676 ? Ag2 C1 C2 Ag2 11.0(14) . . . 3_676 ? Ag4 C1 C2 Ag2 114.4(4) 1_655 . . 3_676 ? C4 O1 C3 C2 67.6(13) . . . . ? C1 C2 C3 O1 -36(5) . . . . ? Ag3 C2 C3 O1 98.6(11) 3_576 . . . ? Ag2 C2 C3 O1 -170.5(7) 3_676 . . . ? C3 O1 C4 C9 -165.4(11) . . . . ? C3 O1 C4 C5 16.2(16) . . . . ? O1 C4 C5 C6 178.9(12) . . . . ? C9 C4 C5 C6 0.5(18) . . . . ? O1 C4 C5 Ag4 -87.4(11) . . . 1_655 ? C9 C4 C5 Ag4 94.2(12) . . . 1_655 ? C4 C5 C6 C7 -2(2) . . . . ? Ag4 C5 C6 C7 -105.6(14) 1_655 . . . ? C5 C6 C7 C8 2(3) . . . . ? C5 C6 C7 O2 -169.3(19) . . . . ? C5 C6 C7 O2' 153(4) . . . . ? C10 O2 C7 C6 -40(3) . . . . ? C10 O2 C7 C8 148.3(19) . . . . ? C10 O2 C7 O2' 58(5) . . . . ? C10 O2' C7 C6 36(6) . . . . ? C15 O2' C7 C6 -15(7) . . . . ? C10 O2' C7 C8 -171(3) . . . . ? C15 O2' C7 C8 138(4) . . . . ? C10 O2' C7 O2 -65(6) . . . . ? C15 O2' C7 O2 -116(9) . . . . ? C6 C7 C8 C9 -1(3) . . . . ? O2 C7 C8 C9 171(2) . . . . ? O2' C7 C8 C9 -154(3) . . . . ? C7 C8 C9 C4 0(3) . . . . ? O1 C4 C9 C8 -178.1(14) . . . . ? C5 C4 C9 C8 0(2) . . . . ? C7 O2' C10 C15 -113(4) . . . . ? C7 O2' C10 C11 76(6) . . . . ? C15 O2' C10 C11 -172(5) . . . . ? C7 O2' C10 O2 56(5) . . . . ? C15 O2' C10 O2 169(4) . . . . ? C7 O2 C10 O2' -69(4) . . . . ? C7 O2 C10 C15 -55(3) . . . . ? C7 O2 C10 C11 122(2) . . . . ? O2' C10 C11 C12 166(5) . . . . ? C15 C10 C11 C12 -4(3) . . . . ? O2 C10 C11 C12 178.7(18) . . . . ? C10 C11 C12 C13 5(3) . . . . ? C11 C12 C13 C14 -3(3) . . . . ? C11 C12 C13 Ag5 -79(2) . . . 4_676 ? C12 C13 C14 C15 0(3) . . . . ? Ag5 C13 C14 C15 89.4(17) 4_676 . . . ? C12 C13 C14 Ag5 -89.3(19) . . . 4_676 ? O2' C10 C15 C14 -174(3) . . . . ? C11 C10 C15 C14 1(3) . . . . ? O2 C10 C15 C14 178.4(16) . . . . ? C11 C10 C15 O2' 175(3) . . . . ? O2 C10 C15 O2' -8(3) . . . . ? C13 C14 C15 C10 1(3) . . . . ? Ag5 C14 C15 C10 76.7(17) 4_676 . . . ? C13 C14 C15 O2' -15(10) . . . . ? Ag5 C14 C15 O2' 61(9) 4_676 . . . ? C7 O2' C15 C10 92(6) . . . . ? C10 O2' C15 C14 20(10) . . . . ? C7 O2' C15 C14 112(7) . . . . ? Ag3 O3 C16 O4 -12.9(16) . . . . ? Ag1 O3 C16 O4 -156.9(9) . . . . ? Ag3 O3 C16 C17 168.1(9) . . . . ? Ag1 O3 C16 C17 24.0(17) . . . . ? Ag4 O4 C16 O3 -171(4) . . . . ? Ag4 O4 C16 C17 8(5) . . . . ? O3 C16 C17 F2 -121.6(15) . . . . ? O4 C16 C17 F2 59.3(18) . . . . ? O3 C16 C17 F3 -0.2(18) . . . . ? O4 C16 C17 F3 -179.3(12) . . . . ? O3 C16 C17 F1 118.5(14) . . . . ? O4 C16 C17 F1 -60.6(16) . . . . ? Ag4 O6 C18 O5 -6(2) 1_655 . . . ? Ag4 O6 C18 C19 177.8(10) 1_655 . . . ? Ag1 O5 C18 O6 -10.9(19) . . . . ? Ag5 O5 C18 O6 150.6(11) . . . . ? Ag1 O5 C18 C19 165.2(10) . . . . ? Ag5 O5 C18 C19 -33(2) . . . . ? O6 C18 C19 F6 175.1(15) . . . . ? O5 C18 C19 F6 -2(2) . . . . ? O6 C18 C19 F5 -61(2) . . . . ? O5 C18 C19 F5 122.1(15) . . . . ? O6 C18 C19 F4 54.5(19) . . . . ? O5 C18 C19 F4 -122.1(15) . . . . ? Ag2 O7 C20 O8 -15(2) . . . . ? Ag2 O7 C20 C21 164.6(9) . . . . ? Ag5 O8 C20 O7 -177.8(10) 1_655 . . . ? Ag3 O8 C20 O7 24.2(19) 1_655 . . . ? Ag5 O8 C20 C21 2.9(17) 1_655 . . . ? Ag3 O8 C20 C21 -155.1(8) 1_655 . . . ? O7 C20 C21 F8' 19(3) . . . . ? O8 C20 C21 F8' -162(2) . . . . ? O7 C20 C21 F7' 158(3) . . . . ? O8 C20 C21 F7' -23(3) . . . . ? O7 C20 C21 F9 -26.1(16) . . . . ? O8 C20 C21 F9 153.3(13) . . . . ? O7 C20 C21 F7 -149.2(13) . . . . ? O8 C20 C21 F7 30.2(16) . . . . ? O7 C20 C21 F8 92.3(15) . . . . ? O8 C20 C21 F8 -88.3(14) . . . . ? O7 C20 C21 F9' -93.4(19) . . . . ? O8 C20 C21 F9' 86.0(19) . . . . ? Ag2 O9 C22 O10 -4(2) . . . . ? Ag2 O9 C22 C23 178.4(8) . . . . ? Ag1 O10 C22 O9 6.2(17) . . . . ? Ag1 O10 C22 C23 -176.2(7) . . . . ? O9 C22 C23 F10' 62.9(18) . . . . ? O10 C22 C23 F10' -114.9(15) . . . . ? O9 C22 C23 F10 23(2) . . . . ? O10 C22 C23 F10 -154.6(15) . . . . ? O9 C22 C23 F12 153.2(13) . . . . ? O10 C22 C23 F12 -24.6(17) . . . . ? O9 C22 C23 F11 -70.9(18) . . . . ? O10 C22 C23 F11 111.3(15) . . . . ? O9 C22 C23 F11' -23.7(18) . . . . ? O10 C22 C23 F11' 158.4(13) . . . . ? O9 C22 C23 F12' -111.3(15) . . . . ? O10 C22 C23 F12' 70.8(14) . . . . ? F10' C23 F12' F11' -60(4) . . . . ? F10 C23 F12' F11' -20(2) . . . . ? F12 C23 F12' F11' -134(2) . . . . ? F11 C23 F12' F11' -3(3) . . . . ? C22 C23 F12' F11' 106.7(18) . . . . ? F10' C23 F11' F12' 158.0(19) . . . . ? F10 C23 F11' F12' 155(3) . . . . ? F12 C23 F11' F12' 83(2) . . . . ? F11 C23 F11' F12' 3(2) . . . . ? C22 C23 F11' F12' -101.0(15) . . . . ? _diffrn_measured_fraction_theta_max 0.999 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.999 _refine_diff_density_max 1.361 _refine_diff_density_min -1.101 _refine_diff_density_rms 0.135 data_5 _database_code_depnum_ccdc_archive 'CCDC 910774' #TrackingRef '5.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C36 H22 Ag5 F9 O10' _chemical_formula_weight 1324.89 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'C 2/c' _symmetry_space_group_name_Hall '-C 2yc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' _cell_length_a 32.536(6) _cell_length_b 11.670(2) _cell_length_c 26.226(5) _cell_angle_alpha 90.00 _cell_angle_beta 127.60(3) _cell_angle_gamma 90.00 _cell_volume 7890(4) _cell_formula_units_Z 8 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.20 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.17 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.231 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 5072 _exptl_absorpt_coefficient_mu 2.537 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.6309 _exptl_absorpt_correction_T_max 0.6723 _exptl_absorpt_process_details SADABS _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 38968 _diffrn_reflns_av_R_equivalents 0.0993 _diffrn_reflns_av_sigmaI/netI 0.0753 _diffrn_reflns_limit_h_min -38 _diffrn_reflns_limit_h_max 38 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 13 _diffrn_reflns_limit_l_min -31 _diffrn_reflns_limit_l_max 31 _diffrn_reflns_theta_min 1.92 _diffrn_reflns_theta_max 25.00 _reflns_number_total 6954 _reflns_number_gt 5691 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.3573P)^2^+37.4474P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6954 _refine_ls_number_parameters 552 _refine_ls_number_restraints 96 _refine_ls_R_factor_all 0.1495 _refine_ls_R_factor_gt 0.1255 _refine_ls_wR_factor_ref 0.4614 _refine_ls_wR_factor_gt 0.4347 _refine_ls_goodness_of_fit_ref 1.082 _refine_ls_restrained_S_all 1.087 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.24377(6) -0.08949(15) 0.20089(8) 0.0557(6) Uani 1 1 d . . . Ag2 Ag 0.27768(9) -0.03868(17) 0.33774(11) 0.0735(7) Uani 1 1 d U . . Ag3 Ag 0.34435(8) 0.03415(14) 0.26332(10) 0.0623(6) Uani 1 1 d . . . Ag4 Ag 0.33494(7) 0.19810(16) 0.34962(9) 0.0591(6) Uani 1 1 d . . . Ag5 Ag 0.23086(8) 0.17174(16) 0.23046(8) 0.0630(6) Uani 1 1 d . . . C1 C 0.2628(10) 0.149(2) 0.3307(12) 0.064(7) Uani 1 1 d D . . C2 C 0.2440(8) 0.1441(17) 0.3584(9) 0.051(5) Uani 1 1 d D . . C3 C 0.2197(9) 0.160(2) 0.3901(12) 0.059(6) Uani 1 1 d . . . H3A H 0.1918 0.1045 0.3730 0.070 Uiso 1 1 calc R . . H3B H 0.2451 0.1452 0.4359 0.070 Uiso 1 1 calc R . . C4 C 0.1531(8) 0.2954(17) 0.3214(9) 0.044(4) Uani 1 1 d U . . C5 C 0.1200(8) 0.2222(17) 0.2679(10) 0.048(5) Uani 1 1 d . . . H5 H 0.1301 0.1469 0.2694 0.058 Uiso 1 1 calc R . . C6 C 0.0744(10) 0.260(2) 0.2152(13) 0.065(6) Uani 1 1 d . . . H6 H 0.0526 0.2088 0.1819 0.078 Uiso 1 1 calc R . . C7 C 0.0589(11) 0.374(2) 0.2091(13) 0.069(7) Uani 1 1 d . . . C8 C 0.0895(9) 0.449(2) 0.2593(12) 0.055(5) Uani 1 1 d . . . H8 H 0.0789 0.5248 0.2561 0.066 Uiso 1 1 calc R . . C9 C 0.1367(9) 0.411(2) 0.3151(11) 0.064(7) Uani 1 1 d . . . H9 H 0.1578 0.4619 0.3487 0.077 Uiso 1 1 calc R . . C10 C -0.0084(8) 0.517(2) 0.1373(13) 0.074(8) Uani 1 1 d D . . C11 C 0.0032(9) 0.589(3) 0.1076(11) 0.070(8) Uani 1 1 d . . . H11 H 0.0235 0.5639 0.0960 0.084 Uiso 1 1 calc R . . C12 C -0.0147(10) 0.697(2) 0.0947(11) 0.066(7) Uani 1 1 d . . . H12 H -0.0054 0.7472 0.0759 0.079 Uiso 1 1 calc R . . C24 C 0.3759(8) -0.0519(18) 0.4698(12) 0.056(6) Uani 1 1 d . . . H13 H 0.3696 -0.1303 0.4630 0.067 Uiso 1 1 calc R . . C14 C -0.0558(14) 0.665(3) 0.1398(19) 0.094(10) Uani 1 1 d . . . H14 H -0.0752 0.6933 0.1523 0.112 Uiso 1 1 calc R . . C15 C -0.0384(12) 0.553(3) 0.1551(14) 0.082(9) Uani 1 1 d D . . H15 H -0.0465 0.5053 0.1761 0.099 Uiso 1 1 calc R . . C16 C 0.3177(8) -0.1082(15) 0.2914(11) 0.048(5) Uani 1 1 d . . . C17 C 0.3581(9) -0.1330(18) 0.3407(9) 0.056(6) Uani 1 1 d . . . C18 C 0.4088(10) -0.159(2) 0.4030(11) 0.063(6) Uani 1 1 d . . . H18A H 0.4036 -0.2135 0.4266 0.075 Uiso 1 1 calc R . . H18B H 0.4312 -0.1952 0.3949 0.075 Uiso 1 1 calc R . . C19 C 0.4069(6) 0.0029(18) 0.4585(7) 0.038(4) Uani 1 1 d . . . C20 C 0.4181(9) 0.121(2) 0.4731(10) 0.066(7) Uani 1 1 d . . . H20 H 0.4409 0.1565 0.4680 0.079 Uiso 1 1 calc R . . C21 C 0.3965(8) 0.183(2) 0.4940(11) 0.054(5) Uani 1 1 d U . . H21 H 0.4026 0.2609 0.5011 0.065 Uiso 1 1 calc R . . C22 C 0.3656(8) 0.1284(19) 0.5048(10) 0.052(5) Uani 1 1 d . . . C23 C 0.3556(9) 0.0097(19) 0.4905(11) 0.057(6) Uani 1 1 d . . . H23 H 0.3331 -0.0260 0.4962 0.068 Uiso 1 1 calc R . . C25 C 0.3603(12) 0.290(2) 0.5560(12) 0.073(8) Uani 1 1 d . . . C26 C 0.321(2) 0.380(3) 0.514(2) 0.130(17) Uani 1 1 d . . . H26 H 0.2899 0.3657 0.4734 0.156 Uiso 1 1 calc R . . C27 C 0.336(2) 0.489(4) 0.545(2) 0.139(15) Uani 1 1 d U . . H27 H 0.3143 0.5512 0.5236 0.167 Uiso 1 1 calc R . . C28 C 0.3787(12) 0.502(3) 0.5992(16) 0.087(8) Uani 1 1 d U . . H28 H 0.3849 0.5754 0.6157 0.104 Uiso 1 1 calc R . . C29 C 0.420(2) 0.419(4) 0.642(3) 0.143(15) Uani 1 1 d U . . H29 H 0.4523 0.4374 0.6800 0.171 Uiso 1 1 calc R . . C30 C 0.4053(13) 0.306(3) 0.6160(16) 0.100(11) Uani 1 1 d . . . H30 H 0.4262 0.2439 0.6402 0.121 Uiso 1 1 calc R . . C31 C 0.1398(10) 0.010(2) 0.1104(14) 0.066(7) Uani 1 1 d . A . C32 C 0.0803(12) 0.0092(15) 0.0491(15) 0.089(5) Uani 1 1 d DU . . C33 C 0.2556(10) 0.2039(19) 0.1395(11) 0.058(6) Uani 1 1 d . A . C34 C 0.2600(16) 0.250(3) 0.0876(17) 0.093(10) Uani 1 1 d . . . C35 C 0.3873(8) 0.281(2) 0.2911(12) 0.056(6) Uani 1 1 d . . . C36 C 0.4043(13) 0.383(3) 0.2718(16) 0.083(8) Uani 1 1 d U . . C13 C -0.0464(13) 0.733(3) 0.1089(14) 0.085(9) Uani 1 1 d . . . H36 H -0.0613 0.8055 0.0966 0.101 Uiso 1 1 calc R . . F1 F 0.0501(9) 0.067(2) 0.0587(12) 0.089(5) Uani 0.689(19) 1 d PDU A 1 F2 F 0.0603(8) -0.0959(16) 0.0296(12) 0.094(9) Uani 0.689(19) 1 d PD A 1 F2' F 0.0685(17) -0.040(3) -0.0025(19) 0.094(9) Uani 0.311(19) 1 d PD A 2 F1' F 0.0533(19) 0.099(4) 0.017(2) 0.089(5) Uani 0.311(19) 1 d PDU A 2 F3 F 0.0800(15) 0.061(3) 0.0033(18) 0.166(13) Uani 0.82(4) 1 d PDU A 1 F3' F 0.049(5) -0.037(3) 0.057(6) 0.166(13) Uani 0.18(4) 1 d PD A 2 F4 F 0.2130(10) 0.253(2) 0.0307(9) 0.138(9) Uani 1 1 d . . . F5 F 0.2715(13) 0.361(2) 0.0957(14) 0.149(9) Uani 1 1 d . . . F6 F 0.2893(15) 0.196(2) 0.0822(17) 0.199(18) Uani 1 1 d . . . F7 F 0.3645(9) 0.4471(19) 0.2341(15) 0.194(17) Uani 1 1 d . . . F8 F 0.4272(12) 0.358(2) 0.2496(14) 0.151(10) Uani 1 1 d . . . F9 F 0.4416(11) 0.4449(19) 0.3273(13) 0.143(9) Uani 1 1 d . . . O1 O 0.4345(6) -0.0550(15) 0.4427(8) 0.062(4) Uani 1 1 d . . . O2 O 0.3439(8) 0.1805(17) 0.5308(11) 0.091(6) Uani 1 1 d . . . O3 O 0.1997(6) 0.2718(15) 0.3806(8) 0.061(4) Uani 1 1 d . . . O4 O 0.0105(7) 0.4018(15) 0.1505(8) 0.080(6) Uani 1 1 d . . . O5 O 0.1527(7) 0.0960(14) 0.1433(10) 0.097(8) Uani 1 1 d . . . O6 O 0.1639(6) -0.0726(13) 0.1150(7) 0.056(4) Uani 1 1 d . . . O7 O 0.2632(8) 0.0980(17) 0.1476(10) 0.083(6) Uani 1 1 d . . . O8 O 0.2444(7) 0.2677(15) 0.1638(9) 0.067(4) Uani 1 1 d . . . O9 O 0.3738(9) 0.1964(16) 0.2550(10) 0.081(5) Uani 1 1 d . . . O10 O 0.3864(7) 0.2868(16) 0.3356(11) 0.080(5) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.0481(10) 0.0566(11) 0.0472(10) 0.0050(7) 0.0212(8) 0.0008(7) Ag2 0.0860(12) 0.0549(11) 0.0805(12) 0.0001(8) 0.0512(10) 0.0095(8) Ag3 0.0763(13) 0.0418(10) 0.0817(13) 0.0110(8) 0.0548(11) -0.0034(8) Ag4 0.0527(10) 0.0561(11) 0.0740(13) -0.0014(8) 0.0415(10) -0.0031(7) Ag5 0.0762(13) 0.0573(12) 0.0477(11) -0.0007(8) 0.0338(10) -0.0073(9) C1 0.101(18) 0.064(15) 0.079(16) 0.035(12) 0.082(16) 0.048(13) C2 0.057(12) 0.031(10) 0.044(11) 0.011(8) 0.020(10) 0.017(9) C3 0.069(14) 0.062(14) 0.075(15) 0.039(12) 0.060(13) 0.031(11) C4 0.044(4) 0.044(4) 0.044(4) 0.0000(9) 0.027(3) 0.0000(9) C5 0.045(11) 0.035(10) 0.065(13) -0.015(9) 0.034(10) 0.009(8) C6 0.078(17) 0.056(15) 0.078(17) -0.007(12) 0.057(15) -0.001(12) C7 0.10(2) 0.040(13) 0.073(16) -0.014(11) 0.060(16) -0.024(13) C8 0.067(14) 0.050(13) 0.071(15) 0.008(11) 0.054(13) 0.003(10) C9 0.062(14) 0.10(2) 0.043(12) -0.006(12) 0.038(12) -0.023(13) C10 0.079(17) 0.047(14) 0.11(2) -0.024(14) 0.066(17) 0.008(12) C11 0.057(14) 0.11(2) 0.058(14) -0.033(14) 0.041(12) -0.052(15) C12 0.070(16) 0.047(14) 0.046(13) -0.021(10) 0.018(12) -0.024(12) C24 0.053(12) 0.037(11) 0.081(16) 0.001(10) 0.042(12) -0.002(9) C14 0.12(3) 0.09(2) 0.14(3) 0.02(2) 0.11(3) 0.034(18) C15 0.13(2) 0.079(19) 0.080(18) 0.001(15) 0.08(2) 0.026(17) C16 0.059(13) 0.020(9) 0.069(14) 0.006(9) 0.042(12) 0.005(8) C17 0.064(13) 0.043(12) 0.027(10) 0.016(8) 0.010(10) 0.031(10) C18 0.093(18) 0.052(13) 0.052(13) -0.023(10) 0.049(13) -0.022(12) C19 0.034(9) 0.071(13) 0.013(7) -0.006(8) 0.016(7) -0.016(9) C20 0.062(14) 0.085(18) 0.028(10) -0.007(11) 0.015(10) -0.004(13) C21 0.054(5) 0.054(5) 0.054(5) 0.0001(10) 0.033(3) 0.0000(10) C22 0.058(12) 0.052(13) 0.050(12) -0.002(10) 0.034(11) -0.010(10) C23 0.064(13) 0.044(12) 0.057(13) 0.016(10) 0.034(12) 0.017(10) C25 0.10(2) 0.047(13) 0.054(14) 0.000(11) 0.037(14) -0.020(13) C26 0.25(5) 0.047(17) 0.16(4) 0.00(2) 0.16(4) 0.03(2) C27 0.139(15) 0.139(15) 0.139(15) 0.000(2) 0.085(9) 0.000(2) C28 0.087(8) 0.087(8) 0.087(8) 0.000(2) 0.053(5) 0.000(2) C29 0.143(15) 0.143(15) 0.143(15) 0.000(2) 0.087(9) 0.000(2) C30 0.10(2) 0.09(2) 0.08(2) -0.013(17) 0.040(18) -0.050(19) C31 0.068(15) 0.043(13) 0.11(2) 0.025(14) 0.066(16) 0.034(12) C32 0.089(5) 0.089(5) 0.089(5) -0.0001(10) 0.054(3) 0.0001(10) C33 0.072(15) 0.038(12) 0.056(13) 0.007(10) 0.034(12) 0.005(10) C34 0.16(3) 0.068(19) 0.09(2) 0.020(16) 0.10(2) 0.04(2) C35 0.043(11) 0.072(16) 0.074(15) -0.003(12) 0.047(11) -0.024(11) C36 0.083(8) 0.083(8) 0.083(8) 0.0001(10) 0.050(5) 0.0000(10) C13 0.10(2) 0.065(18) 0.069(17) -0.020(14) 0.043(17) 0.008(16) F1 0.089(5) 0.089(5) 0.089(5) -0.0001(7) 0.054(3) 0.0001(7) F2 0.049(10) 0.048(13) 0.098(18) -0.024(11) 0.001(10) -0.006(9) F2' 0.049(10) 0.048(13) 0.098(18) -0.024(11) 0.001(10) -0.006(9) F1' 0.089(5) 0.089(5) 0.089(5) -0.0001(7) 0.054(3) 0.0001(7) F3 0.166(14) 0.166(14) 0.166(14) 0.000(2) 0.101(8) 0.000(2) F3' 0.166(14) 0.166(14) 0.166(14) 0.000(2) 0.101(8) 0.000(2) F4 0.15(2) 0.17(2) 0.063(12) 0.040(13) 0.051(13) 0.026(17) F5 0.21(3) 0.115(18) 0.16(2) -0.001(16) 0.14(2) -0.031(18) F6 0.36(5) 0.15(2) 0.30(4) 0.11(2) 0.32(4) 0.12(3) F7 0.106(16) 0.091(15) 0.23(3) 0.082(18) 0.023(18) -0.020(12) F8 0.23(3) 0.109(17) 0.18(2) -0.005(16) 0.16(3) -0.043(18) F9 0.19(2) 0.106(15) 0.18(2) -0.033(15) 0.14(2) -0.090(16) O1 0.064(9) 0.066(10) 0.057(9) 0.001(8) 0.038(8) -0.002(8) O2 0.077(13) 0.087(15) 0.115(17) -0.017(12) 0.063(13) -0.009(10) O3 0.061(9) 0.068(11) 0.062(10) -0.002(8) 0.041(8) 0.010(8) O4 0.064(11) 0.067(12) 0.051(10) -0.006(8) 0.005(8) -0.004(8) O5 0.073(11) 0.036(9) 0.088(13) -0.036(9) 0.001(10) -0.005(8) O6 0.051(8) 0.054(9) 0.051(8) -0.007(7) 0.024(7) -0.014(7) O7 0.100(14) 0.074(14) 0.088(14) 0.028(10) 0.064(12) 0.018(11) O8 0.088(12) 0.054(10) 0.084(12) -0.004(9) 0.066(10) 0.003(8) O9 0.112(15) 0.059(12) 0.094(14) 0.021(10) 0.074(13) 0.011(10) O10 0.079(12) 0.075(12) 0.122(16) 0.018(11) 0.080(13) -0.004(9) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 C16 2.12(2) . ? Ag1 O6 2.173(15) . ? Ag1 Ag3 2.989(3) . ? Ag1 Ag2 3.101(3) . ? Ag1 Ag5 3.142(3) 4_545 ? Ag1 Ag4 3.212(3) 4_545 ? Ag1 Ag5 3.236(3) . ? Ag2 C1 2.22(2) . ? Ag2 O8 2.364(17) 4_545 ? Ag2 C16 2.40(2) . ? Ag2 C2 2.603(19) . ? Ag2 Ag4 3.240(3) . ? Ag2 Ag5 3.322(3) . ? Ag3 C16 2.20(2) . ? Ag3 O9 2.192(19) . ? Ag3 C17 2.65(2) . ? Ag3 Ag4 3.118(3) . ? Ag4 C1 2.16(2) . ? Ag4 O10 2.181(15) . ? Ag4 Ag5 2.901(3) . ? Ag4 Ag1 3.212(3) 4 ? Ag5 C1 2.17(2) . ? Ag5 O8 2.334(17) . ? Ag5 O5 2.320(16) . ? Ag5 Ag1 3.142(3) 4 ? C1 C2 1.206(10) . ? C2 C3 1.47(3) . ? C3 O3 1.42(3) . ? C3 H3A 0.9700 . ? C3 H3B 0.9700 . ? C4 C5 1.42(3) . ? C4 O3 1.38(3) . ? C4 C9 1.42(3) . ? C5 C6 1.34(3) . ? C5 H5 0.9300 . ? C6 C7 1.40(4) . ? C6 H6 0.9300 . ? C7 C8 1.38(3) . ? C7 O4 1.41(3) . ? C8 C9 1.40(3) . ? C8 H8 0.9300 . ? C9 H9 0.9300 . ? C10 C11 1.34(4) . ? C10 C15 1.3800(11) . ? C10 O4 1.43(3) . ? C11 C12 1.34(4) . ? C11 H11 0.9300 . ? C12 C13 1.36(4) . ? C12 H12 0.9300 . ? C24 C23 1.30(3) . ? C24 C19 1.37(3) . ? C24 H13 0.9300 . ? C14 C13 1.29(4) . ? C14 C15 1.38(4) . ? C14 H14 0.9300 . ? C15 H15 0.9300 . ? C16 C17 1.19(3) . ? C17 C18 1.48(3) . ? C18 O1 1.49(3) . ? C18 H18A 0.9700 . ? C18 H18B 0.9700 . ? C19 O1 1.38(2) . ? C19 C20 1.42(3) . ? C20 C21 1.33(3) . ? C20 H20 0.9300 . ? C21 C22 1.36(3) . ? C21 H21 0.9300 . ? C22 O2 1.39(3) . ? C22 C23 1.42(3) . ? C23 H23 0.9300 . ? C25 C30 1.36(4) . ? C25 O2 1.38(3) . ? C25 C26 1.50(5) . ? C26 C27 1.42(6) . ? C26 H26 0.9300 . ? C27 C28 1.25(5) . ? C27 H27 0.9300 . ? C28 C29 1.47(6) . ? C28 H28 0.9300 . ? C29 C30 1.42(6) . ? C29 H29 0.9300 . ? C30 H30 0.9300 . ? C31 O6 1.20(3) . ? C31 O5 1.22(3) . ? C31 C32 1.59(4) . ? C32 F2' 1.29(4) . ? C32 F3' 1.29(4) . ? C32 F1' 1.29(4) . ? C32 F1 1.34(2) . ? C32 F3 1.34(2) . ? C32 F2 1.34(2) . ? C33 O8 1.17(3) . ? C33 O7 1.25(3) . ? C33 C34 1.55(4) . ? C34 F6 1.22(4) . ? C34 F5 1.32(4) . ? C34 F4 1.34(4) . ? C35 O10 1.19(3) . ? C35 O9 1.24(3) . ? C35 C36 1.53(4) . ? C36 F8 1.23(4) . ? C36 F7 1.28(4) . ? C36 F9 1.40(4) . ? C13 H36 0.9300 . ? O8 Ag2 2.364(17) 4 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C16 Ag1 O6 172.5(7) . . ? C16 Ag1 Ag3 47.3(5) . . ? O6 Ag1 Ag3 137.9(4) . . ? C16 Ag1 Ag2 50.6(6) . . ? O6 Ag1 Ag2 122.5(4) . . ? Ag3 Ag1 Ag2 77.07(7) . . ? C16 Ag1 Ag5 63.0(5) . 4_545 ? O6 Ag1 Ag5 113.8(4) . 4_545 ? Ag3 Ag1 Ag5 107.29(7) . 4_545 ? Ag2 Ag1 Ag5 73.91(6) . 4_545 ? C16 Ag1 Ag4 117.1(5) . 4_545 ? O6 Ag1 Ag4 59.6(4) . 4_545 ? Ag3 Ag1 Ag4 158.35(8) . 4_545 ? Ag2 Ag1 Ag4 104.83(8) . 4_545 ? Ag5 Ag1 Ag4 54.31(6) 4_545 4_545 ? C16 Ag1 Ag5 93.1(5) . . ? O6 Ag1 Ag5 85.1(4) . . ? Ag3 Ag1 Ag5 70.90(6) . . ? Ag2 Ag1 Ag5 63.19(6) . . ? Ag5 Ag1 Ag5 136.49(6) 4_545 . ? Ag4 Ag1 Ag5 129.67(7) 4_545 . ? C1 Ag2 O8 152.9(7) . 4_545 ? C1 Ag2 C16 116.6(6) . . ? O8 Ag2 C16 85.5(6) 4_545 . ? O8 Ag2 C2 128.6(6) 4_545 . ? C16 Ag2 C2 144.2(6) . . ? C1 Ag2 Ag1 100.7(6) . . ? O8 Ag2 Ag1 84.7(4) 4_545 . ? C16 Ag2 Ag1 43.1(5) . . ? C2 Ag2 Ag1 120.0(4) . . ? C1 Ag2 Ag4 41.6(6) . . ? O8 Ag2 Ag4 165.5(4) 4_545 . ? C16 Ag2 Ag4 83.1(5) . . ? C2 Ag2 Ag4 64.6(4) . . ? Ag1 Ag2 Ag4 92.98(8) . . ? C1 Ag2 Ag5 40.4(6) . . ? O8 Ag2 Ag5 135.6(5) 4_545 . ? C16 Ag2 Ag5 86.1(5) . . ? C2 Ag2 Ag5 62.4(4) . . ? Ag1 Ag2 Ag5 60.38(6) . . ? Ag4 Ag2 Ag5 52.46(6) . . ? C16 Ag3 O9 166.3(8) . . ? C16 Ag3 C17 26.3(8) . . ? O9 Ag3 C17 146.4(8) . . ? C16 Ag3 Ag1 45.2(6) . . ? O9 Ag3 Ag1 139.6(6) . . ? C17 Ag3 Ag1 71.4(5) . . ? C16 Ag3 Ag4 89.3(6) . . ? O9 Ag3 Ag4 77.6(5) . . ? C17 Ag3 Ag4 86.6(5) . . ? Ag1 Ag3 Ag4 97.72(7) . . ? C1 Ag4 O10 157.8(8) . . ? C1 Ag4 Ag5 48.2(6) . . ? O10 Ag4 Ag5 112.3(6) . . ? C1 Ag4 Ag3 104.1(7) . . ? O10 Ag4 Ag3 75.2(6) . . ? Ag5 Ag4 Ag3 73.74(7) . . ? C1 Ag4 Ag1 68.3(6) . 4 ? O10 Ag4 Ag1 93.7(5) . 4 ? Ag5 Ag4 Ag1 61.61(6) . 4 ? Ag3 Ag4 Ag1 125.51(8) . 4 ? C1 Ag4 Ag2 43.0(6) . . ? O10 Ag4 Ag2 147.6(5) . . ? Ag5 Ag4 Ag2 65.23(6) . . ? Ag3 Ag4 Ag2 73.27(6) . . ? Ag1 Ag4 Ag2 110.58(7) 4 . ? C1 Ag5 O8 142.7(9) . . ? C1 Ag5 O5 124.9(10) . . ? O8 Ag5 O5 92.3(8) . . ? C1 Ag5 Ag4 47.8(7) . . ? O8 Ag5 Ag4 97.2(5) . . ? O5 Ag5 Ag4 163.6(4) . . ? C1 Ag5 Ag1 69.7(7) . 4 ? O8 Ag5 Ag1 84.3(4) . 4 ? O5 Ag5 Ag1 130.5(4) . 4 ? Ag4 Ag5 Ag1 64.08(6) . 4 ? C1 Ag5 Ag1 97.8(6) . . ? O8 Ag5 Ag1 99.3(4) . . ? O5 Ag5 Ag1 68.3(4) . . ? Ag4 Ag5 Ag1 96.96(7) . . ? Ag1 Ag5 Ag1 161.03(7) 4 . ? C1 Ag5 Ag2 41.4(6) . . ? O8 Ag5 Ag2 142.2(4) . . ? O5 Ag5 Ag2 102.3(5) . . ? Ag4 Ag5 Ag2 62.31(7) . . ? Ag1 Ag5 Ag2 110.23(7) 4 . ? Ag1 Ag5 Ag2 56.43(6) . . ? C2 C1 Ag4 139(2) . . ? C2 C1 Ag5 134(2) . . ? Ag4 C1 Ag5 84.0(6) . . ? C2 C1 Ag2 94.1(16) . . ? Ag4 C1 Ag2 95.4(7) . . ? Ag5 C1 Ag2 98.2(10) . . ? C1 C2 C3 170(2) . . ? C1 C2 Ag2 58.3(14) . . ? C3 C2 Ag2 131.4(14) . . ? O3 C3 C2 111.3(16) . . ? O3 C3 H3A 109.4 . . ? C2 C3 H3A 109.4 . . ? O3 C3 H3B 109.4 . . ? C2 C3 H3B 109.4 . . ? H3A C3 H3B 108.0 . . ? C5 C4 O3 129.8(19) . . ? C5 C4 C9 116.8(18) . . ? O3 C4 C9 113.4(18) . . ? C6 C5 C4 121(2) . . ? C6 C5 H5 119.5 . . ? C4 C5 H5 119.5 . . ? C5 C6 C7 122(2) . . ? C5 C6 H6 119.2 . . ? C7 C6 H6 119.2 . . ? C8 C7 C6 120(3) . . ? C8 C7 O4 125(2) . . ? C6 C7 O4 115(2) . . ? C7 C8 C9 119(2) . . ? C7 C8 H8 120.5 . . ? C9 C8 H8 120.5 . . ? C4 C9 C8 121(2) . . ? C4 C9 H9 119.3 . . ? C8 C9 H9 119.3 . . ? C11 C10 C15 121(3) . . ? C11 C10 O4 120(2) . . ? C15 C10 O4 120(3) . . ? C12 C11 C10 120(3) . . ? C12 C11 H11 120.0 . . ? C10 C11 H11 120.0 . . ? C11 C12 C13 120(3) . . ? C11 C12 H12 119.8 . . ? C13 C12 H12 119.8 . . ? C23 C24 C19 117(2) . . ? C23 C24 H13 121.3 . . ? C19 C24 H13 121.3 . . ? C13 C14 C15 123(3) . . ? C13 C14 H14 118.4 . . ? C15 C14 H14 118.4 . . ? C10 C15 C14 116(3) . . ? C10 C15 H15 122.0 . . ? C14 C15 H15 122.0 . . ? C17 C16 Ag1 171.8(18) . . ? C17 C16 Ag3 98.5(17) . . ? Ag1 C16 Ag3 87.5(8) . . ? C17 C16 Ag2 96.5(17) . . ? Ag1 C16 Ag2 86.4(7) . . ? Ag3 C16 Ag2 111.1(8) . . ? C16 C17 C18 178(2) . . ? C16 C17 Ag3 55.2(13) . . ? C18 C17 Ag3 123.5(17) . . ? O1 C18 C17 112.0(19) . . ? O1 C18 H18A 109.2 . . ? C17 C18 H18A 109.2 . . ? O1 C18 H18B 109.2 . . ? C17 C18 H18B 109.2 . . ? H18A C18 H18B 107.9 . . ? O1 C19 C24 122.6(19) . . ? O1 C19 C20 116.9(17) . . ? C24 C19 C20 120(2) . . ? C21 C20 C19 121(2) . . ? C21 C20 H20 119.3 . . ? C19 C20 H20 119.3 . . ? C20 C21 C22 119(2) . . ? C20 C21 H21 120.7 . . ? C22 C21 H21 120.7 . . ? C21 C22 O2 124(2) . . ? C21 C22 C23 119(2) . . ? O2 C22 C23 117.2(19) . . ? C24 C23 C22 124(2) . . ? C24 C23 H23 117.9 . . ? C22 C23 H23 117.9 . . ? C30 C25 O2 121(3) . . ? C30 C25 C26 126(3) . . ? O2 C25 C26 113(3) . . ? C27 C26 C25 111(4) . . ? C27 C26 H26 124.3 . . ? C25 C26 H26 124.3 . . ? C28 C27 C26 121(5) . . ? C28 C27 H27 119.5 . . ? C26 C27 H27 119.5 . . ? C29 C28 C27 130(4) . . ? C29 C28 H28 114.8 . . ? C27 C28 H28 114.8 . . ? C28 C29 C30 111(4) . . ? C28 C29 H29 124.5 . . ? C30 C29 H29 124.5 . . ? C25 C30 C29 120(4) . . ? C25 C30 H30 120.2 . . ? C29 C30 H30 120.2 . . ? O6 C31 O5 132(3) . . ? O6 C31 C32 114(2) . . ? O5 C31 C32 113.7(17) . . ? F2' C32 F3' 103(4) . . ? F2' C32 F1' 92(3) . . ? F3' C32 F1' 98(5) . . ? F2' C32 F1 130(4) . . ? F3' C32 F1 55.0(9) . . ? F1' C32 F1 54.8(9) . . ? F2' C32 F3 55.1(9) . . ? F3' C32 F3 140(8) . . ? F1' C32 F3 55.0(9) . . ? F1 C32 F3 109.7(17) . . ? F2' C32 F2 55.1(9) . . ? F3' C32 F2 55.0(9) . . ? F1' C32 F2 121(4) . . ? F1 C32 F2 107(2) . . ? F3 C32 F2 109.7(19) . . ? F2' C32 C31 118(3) . . ? F3' C32 C31 116(7) . . ? F1' C32 C31 125(3) . . ? F1 C32 C31 113(2) . . ? F3 C32 C31 104(3) . . ? F2 C32 C31 114(2) . . ? O8 C33 O7 129(2) . . ? O8 C33 C34 119(2) . . ? O7 C33 C34 112(2) . . ? F6 C34 F5 111(4) . . ? F6 C34 F4 109(3) . . ? F5 C34 F4 100(3) . . ? F6 C34 C33 115(3) . . ? F5 C34 C33 112(2) . . ? F4 C34 C33 109(3) . . ? O10 C35 O9 126(2) . . ? O10 C35 C36 121(3) . . ? O9 C35 C36 113(2) . . ? F8 C36 F7 113(4) . . ? F8 C36 F9 103(3) . . ? F7 C36 F9 109(3) . . ? F8 C36 C35 115(3) . . ? F7 C36 C35 108(3) . . ? F9 C36 C35 109(3) . . ? C14 C13 C12 119(3) . . ? C14 C13 H36 120.3 . . ? C12 C13 H36 120.3 . . ? C19 O1 C18 114.9(17) . . ? C22 O2 C25 118(2) . . ? C4 O3 C3 117.0(18) . . ? C7 O4 C10 120.5(18) . . ? C31 O5 Ag5 135.1(17) . . ? C31 O6 Ag1 118.2(17) . . ? C33 O8 Ag5 111.4(16) . . ? C33 O8 Ag2 142.1(17) . 4 ? Ag5 O8 Ag2 106.1(6) . 4 ? C35 O9 Ag3 125.4(15) . . ? C35 O10 Ag4 128.2(17) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C16 Ag1 Ag2 C1 117.7(9) . . . . ? O6 Ag1 Ag2 C1 -66.0(8) . . . . ? Ag3 Ag1 Ag2 C1 73.1(7) . . . . ? Ag5 Ag1 Ag2 C1 -174.3(7) 4_545 . . . ? Ag4 Ag1 Ag2 C1 -129.1(7) 4_545 . . . ? Ag5 Ag1 Ag2 C1 -1.8(7) . . . . ? C16 Ag1 Ag2 O8 -89.1(8) . . . 4_545 ? O6 Ag1 Ag2 O8 87.2(7) . . . 4_545 ? Ag3 Ag1 Ag2 O8 -133.7(4) . . . 4_545 ? Ag5 Ag1 Ag2 O8 -21.1(4) 4_545 . . 4_545 ? Ag4 Ag1 Ag2 O8 24.1(4) 4_545 . . 4_545 ? Ag5 Ag1 Ag2 O8 151.4(4) . . . 4_545 ? O6 Ag1 Ag2 C16 176.3(8) . . . . ? Ag3 Ag1 Ag2 C16 -44.6(6) . . . . ? Ag5 Ag1 Ag2 C16 67.9(6) 4_545 . . . ? Ag4 Ag1 Ag2 C16 113.2(6) 4_545 . . . ? Ag5 Ag1 Ag2 C16 -119.5(6) . . . . ? C16 Ag1 Ag2 C2 138.8(8) . . . . ? O6 Ag1 Ag2 C2 -44.9(7) . . . . ? Ag3 Ag1 Ag2 C2 94.2(5) . . . . ? Ag5 Ag1 Ag2 C2 -153.2(5) 4_545 . . . ? Ag4 Ag1 Ag2 C2 -108.0(5) 4_545 . . . ? Ag5 Ag1 Ag2 C2 19.3(5) . . . . ? C16 Ag1 Ag2 Ag4 76.5(6) . . . . ? O6 Ag1 Ag2 Ag4 -107.2(5) . . . . ? Ag3 Ag1 Ag2 Ag4 31.93(6) . . . . ? Ag5 Ag1 Ag2 Ag4 144.49(8) 4_545 . . . ? Ag4 Ag1 Ag2 Ag4 -170.29(6) 4_545 . . . ? Ag5 Ag1 Ag2 Ag4 -42.98(6) . . . . ? C16 Ag1 Ag2 Ag5 119.5(6) . . . . ? O6 Ag1 Ag2 Ag5 -64.2(5) . . . . ? Ag3 Ag1 Ag2 Ag5 74.92(7) . . . . ? Ag5 Ag1 Ag2 Ag5 -172.53(5) 4_545 . . . ? Ag4 Ag1 Ag2 Ag5 -127.31(8) 4_545 . . . ? O6 Ag1 Ag3 C16 172.2(10) . . . . ? Ag2 Ag1 Ag3 C16 47.6(8) . . . . ? Ag5 Ag1 Ag3 C16 -20.8(8) 4_545 . . . ? Ag4 Ag1 Ag3 C16 -50.1(8) 4_545 . . . ? Ag5 Ag1 Ag3 C16 113.4(8) . . . . ? C16 Ag1 Ag3 O9 -161.1(11) . . . . ? O6 Ag1 Ag3 O9 11.1(11) . . . . ? Ag2 Ag1 Ag3 O9 -113.5(8) . . . . ? Ag5 Ag1 Ag3 O9 178.2(8) 4_545 . . . ? Ag4 Ag1 Ag3 O9 148.8(8) 4_545 . . . ? Ag5 Ag1 Ag3 O9 -47.7(8) . . . . ? C16 Ag1 Ag3 C17 2.6(9) . . . . ? O6 Ag1 Ag3 C17 174.8(8) . . . . ? Ag2 Ag1 Ag3 C17 50.2(5) . . . . ? Ag5 Ag1 Ag3 C17 -18.2(5) 4_545 . . . ? Ag4 Ag1 Ag3 C17 -47.5(6) 4_545 . . . ? Ag5 Ag1 Ag3 C17 115.9(5) . . . . ? C16 Ag1 Ag3 Ag4 -81.2(8) . . . . ? O6 Ag1 Ag3 Ag4 91.0(6) . . . . ? Ag2 Ag1 Ag3 Ag4 -33.63(7) . . . . ? Ag5 Ag1 Ag3 Ag4 -101.96(8) 4_545 . . . ? Ag4 Ag1 Ag3 Ag4 -131.3(2) 4_545 . . . ? Ag5 Ag1 Ag3 Ag4 32.15(6) . . . . ? C16 Ag3 Ag4 C1 -42.3(8) . . . . ? O9 Ag3 Ag4 C1 141.4(8) . . . . ? C17 Ag3 Ag4 C1 -68.5(8) . . . . ? Ag1 Ag3 Ag4 C1 2.2(6) . . . . ? C16 Ag3 Ag4 O10 160.6(8) . . . . ? O9 Ag3 Ag4 O10 -15.7(8) . . . . ? C17 Ag3 Ag4 O10 134.4(8) . . . . ? Ag1 Ag3 Ag4 O10 -154.9(5) . . . . ? C16 Ag3 Ag4 Ag5 -80.3(6) . . . . ? O9 Ag3 Ag4 Ag5 103.4(6) . . . . ? C17 Ag3 Ag4 Ag5 -106.5(5) . . . . ? Ag1 Ag3 Ag4 Ag5 -35.75(7) . . . . ? C16 Ag3 Ag4 Ag1 -115.5(6) . . . 4 ? O9 Ag3 Ag4 Ag1 68.2(6) . . . 4 ? C17 Ag3 Ag4 Ag1 -141.7(5) . . . 4 ? Ag1 Ag3 Ag4 Ag1 -71.02(9) . . . 4 ? C16 Ag3 Ag4 Ag2 -11.9(6) . . . . ? O9 Ag3 Ag4 Ag2 171.8(6) . . . . ? C17 Ag3 Ag4 Ag2 -38.1(5) . . . . ? Ag1 Ag3 Ag4 Ag2 32.66(7) . . . . ? O8 Ag2 Ag4 C1 -177(2) 4_545 . . . ? C16 Ag2 Ag4 C1 144.8(10) . . . . ? C2 Ag2 Ag4 C1 -19.2(10) . . . . ? Ag1 Ag2 Ag4 C1 102.8(9) . . . . ? Ag5 Ag2 Ag4 C1 54.4(9) . . . . ? C1 Ag2 Ag4 O10 -147.5(14) . . . . ? O8 Ag2 Ag4 O10 36(2) 4_545 . . . ? C16 Ag2 Ag4 O10 -2.7(12) . . . . ? C2 Ag2 Ag4 O10 -166.7(11) . . . . ? Ag1 Ag2 Ag4 O10 -44.7(10) . . . . ? Ag5 Ag2 Ag4 O10 -93.1(10) . . . . ? C1 Ag2 Ag4 Ag5 -54.4(9) . . . . ? O8 Ag2 Ag4 Ag5 128.8(18) 4_545 . . . ? C16 Ag2 Ag4 Ag5 90.4(5) . . . . ? C2 Ag2 Ag4 Ag5 -73.6(5) . . . . ? Ag1 Ag2 Ag4 Ag5 48.38(7) . . . . ? C1 Ag2 Ag4 Ag3 -133.9(9) . . . . ? O8 Ag2 Ag4 Ag3 49.3(18) 4_545 . . . ? C16 Ag2 Ag4 Ag3 10.9(5) . . . . ? C2 Ag2 Ag4 Ag3 -153.1(5) . . . . ? Ag1 Ag2 Ag4 Ag3 -31.06(6) . . . . ? Ag5 Ag2 Ag4 Ag3 -79.44(7) . . . . ? C1 Ag2 Ag4 Ag1 -11.5(9) . . . 4 ? O8 Ag2 Ag4 Ag1 171.7(18) 4_545 . . 4 ? C16 Ag2 Ag4 Ag1 133.3(5) . . . 4 ? C2 Ag2 Ag4 Ag1 -30.7(5) . . . 4 ? Ag1 Ag2 Ag4 Ag1 91.28(9) . . . 4 ? Ag5 Ag2 Ag4 Ag1 42.90(7) . . . 4 ? O10 Ag4 Ag5 C1 -167.2(10) . . . . ? Ag3 Ag4 Ag5 C1 126.9(8) . . . . ? Ag1 Ag4 Ag5 C1 -85.4(8) 4 . . . ? Ag2 Ag4 Ag5 C1 48.2(8) . . . . ? C1 Ag4 Ag5 O8 165.4(9) . . . . ? O10 Ag4 Ag5 O8 -1.8(7) . . . . ? Ag3 Ag4 Ag5 O8 -67.7(4) . . . . ? Ag1 Ag4 Ag5 O8 80.0(4) 4 . . . ? Ag2 Ag4 Ag5 O8 -146.4(4) . . . . ? C1 Ag4 Ag5 O5 -70(3) . . . . ? O10 Ag4 Ag5 O5 123(2) . . . . ? Ag3 Ag4 Ag5 O5 57(2) . . . . ? Ag1 Ag4 Ag5 O5 -155(2) 4 . . . ? Ag2 Ag4 Ag5 O5 -21(2) . . . . ? C1 Ag4 Ag5 Ag1 85.4(8) . . . 4 ? O10 Ag4 Ag5 Ag1 -81.8(6) . . . 4 ? Ag3 Ag4 Ag5 Ag1 -147.71(7) . . . 4 ? Ag2 Ag4 Ag5 Ag1 133.58(8) . . . 4 ? C1 Ag4 Ag5 Ag1 -94.3(8) . . . . ? O10 Ag4 Ag5 Ag1 98.5(6) . . . . ? Ag3 Ag4 Ag5 Ag1 32.60(6) . . . . ? Ag1 Ag4 Ag5 Ag1 -179.70(7) 4 . . . ? Ag2 Ag4 Ag5 Ag1 -46.12(6) . . . . ? C1 Ag4 Ag5 Ag2 -48.2(8) . . . . ? O10 Ag4 Ag5 Ag2 144.6(6) . . . . ? Ag3 Ag4 Ag5 Ag2 78.72(6) . . . . ? Ag1 Ag4 Ag5 Ag2 -133.58(8) 4 . . . ? C16 Ag1 Ag5 C1 -40.5(9) . . . . ? O6 Ag1 Ag5 C1 132.2(8) . . . . ? Ag3 Ag1 Ag5 C1 -83.0(7) . . . . ? Ag2 Ag1 Ag5 C1 1.8(7) . . . . ? Ag5 Ag1 Ag5 C1 12.3(7) 4_545 . . . ? Ag4 Ag1 Ag5 C1 89.2(7) 4_545 . . . ? C16 Ag1 Ag5 O8 106.2(7) . . . . ? O6 Ag1 Ag5 O8 -81.1(6) . . . . ? Ag3 Ag1 Ag5 O8 63.7(5) . . . . ? Ag2 Ag1 Ag5 O8 148.5(5) . . . . ? Ag5 Ag1 Ag5 O8 159.0(5) 4_545 . . . ? Ag4 Ag1 Ag5 O8 -124.1(5) 4_545 . . . ? C16 Ag1 Ag5 O5 -165.0(9) . . . . ? O6 Ag1 Ag5 O5 7.7(8) . . . . ? Ag3 Ag1 Ag5 O5 152.5(7) . . . . ? Ag2 Ag1 Ag5 O5 -122.7(7) . . . . ? Ag5 Ag1 Ag5 O5 -112.2(7) 4_545 . . . ? Ag4 Ag1 Ag5 O5 -35.4(7) 4_545 . . . ? C16 Ag1 Ag5 Ag4 7.7(6) . . . . ? O6 Ag1 Ag5 Ag4 -179.6(4) . . . . ? Ag3 Ag1 Ag5 Ag4 -34.82(7) . . . . ? Ag2 Ag1 Ag5 Ag4 50.00(7) . . . . ? Ag5 Ag1 Ag5 Ag4 60.46(10) 4_545 . . . ? Ag4 Ag1 Ag5 Ag4 137.33(8) 4_545 . . . ? C16 Ag1 Ag5 Ag1 6.9(6) . . . 4 ? O6 Ag1 Ag5 Ag1 179.5(5) . . . 4 ? Ag3 Ag1 Ag5 Ag1 -35.7(2) . . . 4 ? Ag2 Ag1 Ag5 Ag1 49.2(2) . . . 4 ? Ag5 Ag1 Ag5 Ag1 59.6(2) 4_545 . . 4 ? Ag4 Ag1 Ag5 Ag1 136.5(2) 4_545 . . 4 ? C16 Ag1 Ag5 Ag2 -42.3(6) . . . . ? O6 Ag1 Ag5 Ag2 130.4(4) . . . . ? Ag3 Ag1 Ag5 Ag2 -84.82(8) . . . . ? Ag5 Ag1 Ag5 Ag2 10.46(8) 4_545 . . . ? Ag4 Ag1 Ag5 Ag2 87.33(11) 4_545 . . . ? O8 Ag2 Ag5 C1 139.8(12) 4_545 . . . ? C16 Ag2 Ag5 C1 -140.7(11) . . . . ? C2 Ag2 Ag5 C1 21.6(10) . . . . ? Ag1 Ag2 Ag5 C1 -177.3(10) . . . . ? Ag4 Ag2 Ag5 C1 -56.4(10) . . . . ? C1 Ag2 Ag5 O8 120.0(12) . . . . ? O8 Ag2 Ag5 O8 -100.2(10) 4_545 . . . ? C16 Ag2 Ag5 O8 -20.7(9) . . . . ? C2 Ag2 Ag5 O8 141.6(9) . . . . ? Ag1 Ag2 Ag5 O8 -57.3(7) . . . . ? Ag4 Ag2 Ag5 O8 63.6(7) . . . . ? C1 Ag2 Ag5 O5 -129.6(12) . . . . ? O8 Ag2 Ag5 O5 10.2(9) 4_545 . . . ? C16 Ag2 Ag5 O5 89.7(8) . . . . ? C2 Ag2 Ag5 O5 -108.0(8) . . . . ? Ag1 Ag2 Ag5 O5 53.1(6) . . . . ? Ag4 Ag2 Ag5 O5 174.0(6) . . . . ? C1 Ag2 Ag5 Ag4 56.4(10) . . . . ? O8 Ag2 Ag5 Ag4 -163.8(6) 4_545 . . . ? C16 Ag2 Ag5 Ag4 -84.3(5) . . . . ? C2 Ag2 Ag5 Ag4 78.0(5) . . . . ? Ag1 Ag2 Ag5 Ag4 -120.83(8) . . . . ? C1 Ag2 Ag5 Ag1 12.5(10) . . . 4 ? O8 Ag2 Ag5 Ag1 152.3(6) 4_545 . . 4 ? C16 Ag2 Ag5 Ag1 -128.3(5) . . . 4 ? C2 Ag2 Ag5 Ag1 34.0(5) . . . 4 ? Ag1 Ag2 Ag5 Ag1 -164.81(8) . . . 4 ? Ag4 Ag2 Ag5 Ag1 -43.98(7) . . . 4 ? C1 Ag2 Ag5 Ag1 177.3(10) . . . . ? O8 Ag2 Ag5 Ag1 -42.9(6) 4_545 . . . ? C16 Ag2 Ag5 Ag1 36.5(5) . . . . ? C2 Ag2 Ag5 Ag1 -161.2(5) . . . . ? Ag4 Ag2 Ag5 Ag1 120.83(8) . . . . ? O10 Ag4 C1 C2 -127(3) . . . . ? Ag5 Ag4 C1 C2 -160(3) . . . . ? Ag3 Ag4 C1 C2 148(3) . . . . ? Ag1 Ag4 C1 C2 -89(3) 4 . . . ? Ag2 Ag4 C1 C2 103(3) . . . . ? O10 Ag4 C1 Ag5 33(3) . . . . ? Ag3 Ag4 C1 Ag5 -52.3(6) . . . . ? Ag1 Ag4 C1 Ag5 70.7(5) 4 . . . ? Ag2 Ag4 C1 Ag5 -97.7(10) . . . . ? O10 Ag4 C1 Ag2 130.4(19) . . . . ? Ag5 Ag4 C1 Ag2 97.7(10) . . . . ? Ag3 Ag4 C1 Ag2 45.4(8) . . . . ? Ag1 Ag4 C1 Ag2 168.4(9) 4 . . . ? O8 Ag5 C1 C2 137(3) . . . . ? O5 Ag5 C1 C2 -37(3) . . . . ? Ag4 Ag5 C1 C2 162(3) . . . . ? Ag1 Ag5 C1 C2 89(3) 4 . . . ? Ag1 Ag5 C1 C2 -106(3) . . . . ? Ag2 Ag5 C1 C2 -104(3) . . . . ? O8 Ag5 C1 Ag4 -24.4(14) . . . . ? O5 Ag5 C1 Ag4 161.2(6) . . . . ? Ag1 Ag5 C1 Ag4 -72.9(6) 4 . . . ? Ag1 Ag5 C1 Ag4 92.3(6) . . . . ? Ag2 Ag5 C1 Ag4 94.6(7) . . . . ? O8 Ag5 C1 Ag2 -119.0(11) . . . . ? O5 Ag5 C1 Ag2 66.6(10) . . . . ? Ag4 Ag5 C1 Ag2 -94.6(7) . . . . ? Ag1 Ag5 C1 Ag2 -167.5(10) 4 . . . ? Ag1 Ag5 C1 Ag2 -2.3(8) . . . . ? O8 Ag2 C1 C2 38(3) 4_545 . . . ? C16 Ag2 C1 C2 -179.8(16) . . . . ? Ag1 Ag2 C1 C2 137.6(17) . . . . ? Ag4 Ag2 C1 C2 -140(2) . . . . ? Ag5 Ag2 C1 C2 135(2) . . . . ? O8 Ag2 C1 Ag4 178.2(11) 4_545 . . . ? C16 Ag2 C1 Ag4 -39.8(12) . . . . ? C2 Ag2 C1 Ag4 140(2) . . . . ? Ag1 Ag2 C1 Ag4 -82.3(8) . . . . ? Ag5 Ag2 C1 Ag4 -84.7(6) . . . . ? O8 Ag2 C1 Ag5 -97.0(14) 4_545 . . . ? C16 Ag2 C1 Ag5 45.0(12) . . . . ? C2 Ag2 C1 Ag5 -135(2) . . . . ? Ag1 Ag2 C1 Ag5 2.4(9) . . . . ? Ag4 Ag2 C1 Ag5 84.7(6) . . . . ? Ag4 C1 C2 C3 79(15) . . . . ? Ag5 C1 C2 C3 -72(16) . . . . ? Ag2 C1 C2 C3 -178(14) . . . . ? Ag4 C1 C2 Ag2 -103(2) . . . . ? Ag5 C1 C2 Ag2 105(3) . . . . ? O8 Ag2 C2 C1 -158.9(18) 4_545 . . . ? C16 Ag2 C2 C1 0(2) . . . . ? Ag1 Ag2 C2 C1 -50(2) . . . . ? Ag4 Ag2 C2 C1 28.1(18) . . . . ? Ag5 Ag2 C2 C1 -31.0(18) . . . . ? C1 Ag2 C2 C3 180(3) . . . . ? O8 Ag2 C2 C3 21(2) 4_545 . . . ? C16 Ag2 C2 C3 179.8(19) . . . . ? Ag1 Ag2 C2 C3 130(2) . . . . ? Ag4 Ag2 C2 C3 -152(2) . . . . ? Ag5 Ag2 C2 C3 149(2) . . . . ? C1 C2 C3 O3 8(16) . . . . ? Ag2 C2 C3 O3 -170.0(14) . . . . ? O3 C4 C5 C6 176(2) . . . . ? C9 C4 C5 C6 -3(3) . . . . ? C4 C5 C6 C7 4(4) . . . . ? C5 C6 C7 C8 -3(4) . . . . ? C5 C6 C7 O4 179(2) . . . . ? C6 C7 C8 C9 2(3) . . . . ? O4 C7 C8 C9 180(2) . . . . ? C5 C4 C9 C8 2(3) . . . . ? O3 C4 C9 C8 -177.7(18) . . . . ? C7 C8 C9 C4 -1(3) . . . . ? C15 C10 C11 C12 0(4) . . . . ? O4 C10 C11 C12 179(2) . . . . ? C10 C11 C12 C13 -3(3) . . . . ? C11 C10 C15 C14 1(4) . . . . ? O4 C10 C15 C14 -179(3) . . . . ? C13 C14 C15 C10 2(6) . . . . ? Ag2 Ag1 C16 Ag3 -111.4(7) . . . . ? Ag5 Ag1 C16 Ag3 157.7(8) 4_545 . . . ? Ag4 Ag1 C16 Ag3 161.5(3) 4_545 . . . ? Ag5 Ag1 C16 Ag3 -60.3(5) . . . . ? Ag3 Ag1 C16 Ag2 111.4(7) . . . . ? Ag5 Ag1 C16 Ag2 -91.0(5) 4_545 . . . ? Ag4 Ag1 C16 Ag2 -87.2(5) 4_545 . . . ? Ag5 Ag1 C16 Ag2 51.0(4) . . . . ? O9 Ag3 C16 C17 -68(4) . . . . ? Ag1 Ag3 C16 C17 174.4(19) . . . . ? Ag4 Ag3 C16 C17 -83.9(15) . . . . ? O9 Ag3 C16 Ag1 117(3) . . . . ? C17 Ag3 C16 Ag1 -174.4(19) . . . . ? Ag4 Ag3 C16 Ag1 101.7(5) . . . . ? O9 Ag3 C16 Ag2 32(4) . . . . ? C17 Ag3 C16 Ag2 100.4(19) . . . . ? Ag1 Ag3 C16 Ag2 -85.1(9) . . . . ? Ag4 Ag3 C16 Ag2 16.5(8) . . . . ? C1 Ag2 C16 C17 111.1(17) . . . . ? O8 Ag2 C16 C17 -85.3(16) 4_545 . . . ? C2 Ag2 C16 C17 110.9(17) . . . . ? Ag1 Ag2 C16 C17 -172.3(18) . . . . ? Ag4 Ag2 C16 C17 85.7(15) . . . . ? Ag5 Ag2 C16 C17 138.4(15) . . . . ? C1 Ag2 C16 Ag1 -76.6(10) . . . . ? O8 Ag2 C16 Ag1 87.1(7) 4_545 . . . ? C2 Ag2 C16 Ag1 -76.7(13) . . . . ? Ag4 Ag2 C16 Ag1 -101.9(5) . . . . ? Ag5 Ag2 C16 Ag1 -49.3(5) . . . . ? C1 Ag2 C16 Ag3 9.3(14) . . . . ? O8 Ag2 C16 Ag3 173.0(10) 4_545 . . . ? C2 Ag2 C16 Ag3 9.2(18) . . . . ? Ag1 Ag2 C16 Ag3 85.9(9) . . . . ? Ag4 Ag2 C16 Ag3 -16.0(8) . . . . ? Ag5 Ag2 C16 Ag3 36.6(8) . . . . ? Ag2 C16 C17 Ag3 -112.6(10) . . . . ? O9 Ag3 C17 C16 156.6(16) . . . . ? Ag1 Ag3 C17 C16 -4.2(15) . . . . ? Ag4 Ag3 C17 C16 95.2(16) . . . . ? C16 Ag3 C17 C18 -178(3) . . . . ? O9 Ag3 C17 C18 -21(2) . . . . ? Ag1 Ag3 C17 C18 177.9(18) . . . . ? Ag4 Ag3 C17 C18 -82.8(17) . . . . ? Ag3 C17 C18 O1 48(2) . . . . ? C23 C24 C19 O1 173.4(19) . . . . ? C23 C24 C19 C20 4(3) . . . . ? O1 C19 C20 C21 -174.5(19) . . . . ? C24 C19 C20 C21 -4(3) . . . . ? C19 C20 C21 C22 4(3) . . . . ? C20 C21 C22 O2 175(2) . . . . ? C20 C21 C22 C23 -3(3) . . . . ? C19 C24 C23 C22 -3(4) . . . . ? C21 C22 C23 C24 3(4) . . . . ? O2 C22 C23 C24 -175(2) . . . . ? C30 C25 C26 C27 1(6) . . . . ? O2 C25 C26 C27 173(3) . . . . ? C25 C26 C27 C28 1(6) . . . . ? C26 C27 C28 C29 2(7) . . . . ? C27 C28 C29 C30 -6(7) . . . . ? O2 C25 C30 C29 -178(3) . . . . ? C26 C25 C30 C29 -6(6) . . . . ? C28 C29 C30 C25 8(6) . . . . ? O6 C31 C32 F2' -32(3) . . . . ? O5 C31 C32 F2' 146(2) . . . . ? O6 C31 C32 F3' 90(2) . . . . ? O5 C31 C32 F3' -91(3) . . . . ? O6 C31 C32 F1' -147(2) . . . . ? O5 C31 C32 F1' 32(3) . . . . ? O6 C31 C32 F1 151(2) . . . . ? O5 C31 C32 F1 -30(3) . . . . ? O6 C31 C32 F3 -90(2) . . . . ? O5 C31 C32 F3 89(3) . . . . ? O6 C31 C32 F2 29(3) . . . . ? O5 C31 C32 F2 -152(2) . . . . ? O8 C33 C34 F6 154(4) . . . . ? O7 C33 C34 F6 -29(5) . . . . ? O8 C33 C34 F5 26(4) . . . . ? O7 C33 C34 F5 -156(3) . . . . ? O8 C33 C34 F4 -84(3) . . . . ? O7 C33 C34 F4 94(3) . . . . ? O10 C35 C36 F8 147(3) . . . . ? O9 C35 C36 F8 -35(4) . . . . ? O10 C35 C36 F7 -86(4) . . . . ? O9 C35 C36 F7 92(3) . . . . ? O10 C35 C36 F9 32(4) . . . . ? O9 C35 C36 F9 -150(3) . . . . ? C15 C14 C13 C12 -5(6) . . . . ? C11 C12 C13 C14 6(4) . . . . ? C24 C19 O1 C18 34(3) . . . . ? C20 C19 O1 C18 -155.9(18) . . . . ? C17 C18 O1 C19 60(2) . . . . ? C21 C22 O2 C25 -10(4) . . . . ? C23 C22 O2 C25 168(2) . . . . ? C30 C25 O2 C22 -81(4) . . . . ? C26 C25 O2 C22 107(3) . . . . ? C5 C4 O3 C3 3(3) . . . . ? C9 C4 O3 C3 -177.9(17) . . . . ? C2 C3 O3 C4 78(3) . . . . ? C8 C7 O4 C10 5(4) . . . . ? C6 C7 O4 C10 -177(2) . . . . ? C11 C10 O4 C7 90(3) . . . . ? C15 C10 O4 C7 -90(3) . . . . ? O6 C31 O5 Ag5 7(5) . . . . ? C32 C31 O5 Ag5 -171.6(19) . . . . ? C1 Ag5 O5 C31 -95(3) . . . . ? O8 Ag5 O5 C31 88(3) . . . . ? Ag4 Ag5 O5 C31 -38(5) . . . . ? Ag1 Ag5 O5 C31 173(3) 4 . . . ? Ag1 Ag5 O5 C31 -11(3) . . . . ? Ag2 Ag5 O5 C31 -57(3) . . . . ? O5 C31 O6 Ag1 7(4) . . . . ? C32 C31 O6 Ag1 -174.8(14) . . . . ? Ag3 Ag1 O6 C31 -64.7(19) . . . . ? Ag2 Ag1 O6 C31 43.3(19) . . . . ? Ag5 Ag1 O6 C31 128.9(17) 4_545 . . . ? Ag4 Ag1 O6 C31 132.1(18) 4_545 . . . ? Ag5 Ag1 O6 C31 -10.4(17) . . . . ? O7 C33 O8 Ag5 -4(4) . . . . ? C34 C33 O8 Ag5 173(2) . . . . ? O7 C33 O8 Ag2 -175.6(19) . . . 4 ? C34 C33 O8 Ag2 2(4) . . . 4 ? C1 Ag5 O8 C33 111.8(19) . . . . ? O5 Ag5 O8 C33 -72.8(18) . . . . ? Ag4 Ag5 O8 C33 93.9(18) . . . . ? Ag1 Ag5 O8 C33 156.8(18) 4 . . . ? Ag1 Ag5 O8 C33 -4.4(18) . . . . ? Ag2 Ag5 O8 C33 41(2) . . . . ? C1 Ag5 O8 Ag2 -73.6(13) . . . 4 ? O5 Ag5 O8 Ag2 101.8(8) . . . 4 ? Ag4 Ag5 O8 Ag2 -91.5(6) . . . 4 ? Ag1 Ag5 O8 Ag2 -28.6(6) 4 . . 4 ? Ag1 Ag5 O8 Ag2 170.2(5) . . . 4 ? Ag2 Ag5 O8 Ag2 -144.6(4) . . . 4 ? O10 C35 O9 Ag3 0(4) . . . . ? C36 C35 O9 Ag3 -177.8(17) . . . . ? C16 Ag3 O9 C35 0(5) . . . . ? C17 Ag3 O9 C35 -48(3) . . . . ? Ag1 Ag3 O9 C35 103(2) . . . . ? Ag4 Ag3 O9 C35 16(2) . . . . ? O9 C35 O10 Ag4 -28(4) . . . . ? C36 C35 O10 Ag4 149.5(19) . . . . ? C1 Ag4 O10 C35 -62(3) . . . . ? Ag5 Ag4 O10 C35 -36(2) . . . . ? Ag3 Ag4 O10 C35 29(2) . . . . ? Ag1 Ag4 O10 C35 -97(2) 4 . . . ? Ag2 Ag4 O10 C35 42(3) . . . . ? _diffrn_measured_fraction_theta_max 0.999 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.999 _refine_diff_density_max 2.460 _refine_diff_density_min -1.221 _refine_diff_density_rms 0.186 data_6 _database_code_depnum_ccdc_archive 'CCDC 910775' #TrackingRef '6.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C82 H54 Ag8 F18 N8 O14' _chemical_formula_weight 2580.29 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 21/c' _symmetry_space_group_name_Hall '-P 2ybc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 13.8833(14) _cell_length_b 24.923(3) _cell_length_c 13.0817(13) _cell_angle_alpha 90.00 _cell_angle_beta 114.308(2) _cell_angle_gamma 90.00 _cell_volume 4125.1(7) _cell_formula_units_Z 2 _cell_measurement_temperature 173 _cell_measurement_reflns_used 9934 _cell_measurement_theta_min 2.294 _cell_measurement_theta_max 27.854 _exptl_crystal_description ? _exptl_crystal_colour ? _exptl_crystal_size_max 0.20 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.16 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.077 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2504 _exptl_absorpt_coefficient_mu 1.968 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.6943 _exptl_absorpt_correction_T_max 0.7436 _exptl_absorpt_process_details SADABS(2009) _exptl_special_details ; ? ; _diffrn_ambient_temperature 173 _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ? _diffrn_measurement_method ? _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 76780 _diffrn_reflns_av_R_equivalents 0.0886 _diffrn_reflns_av_sigmaI/netI 0.0381 _diffrn_reflns_limit_h_min -16 _diffrn_reflns_limit_h_max 16 _diffrn_reflns_limit_k_min -29 _diffrn_reflns_limit_k_max 29 _diffrn_reflns_limit_l_min -15 _diffrn_reflns_limit_l_max 15 _diffrn_reflns_theta_min 1.61 _diffrn_reflns_theta_max 25.00 _reflns_number_total 7277 _reflns_number_gt 6311 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0360P)^2^+1.4470P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 7277 _refine_ls_number_parameters 590 _refine_ls_number_restraints 1 _refine_ls_R_factor_all 0.0345 _refine_ls_R_factor_gt 0.0270 _refine_ls_wR_factor_ref 0.0671 _refine_ls_wR_factor_gt 0.0645 _refine_ls_goodness_of_fit_ref 1.003 _refine_ls_restrained_S_all 1.004 _refine_ls_shift/su_max 0.003 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.243729(18) 0.541807(9) 0.778337(18) 0.02688(7) Uani 1 1 d . . . Ag2 Ag 0.045593(19) 0.484464(9) 0.65465(2) 0.03047(7) Uani 1 1 d . . . Ag3 Ag 0.107443(19) 0.579047(10) 0.551085(19) 0.03189(7) Uani 1 1 d . . . Ag4 Ag 0.08917(3) 0.52870(3) 0.86826(3) 0.03050(14) Uani 0.8243(19) 1 d P A 1 Ag4' Ag 0.07517(17) 0.55118(13) 0.87038(16) 0.03050(14) Uani 0.1757(19) 1 d P A 2 N1 N 0.3313(2) 0.47119(10) 0.8991(2) 0.0258(5) Uani 1 1 d . A . N2 N 0.33006(19) 0.57401(10) 0.9660(2) 0.0266(5) Uani 1 1 d . A . N3 N 0.1304(2) 0.46834(12) 1.0006(2) 0.0348(6) Uani 1 1 d . . . N4 N 0.1115(2) 0.57455(11) 1.0353(2) 0.0363(6) Uani 1 1 d . . . O1 O 0.0477(2) 0.70276(10) 0.7708(2) 0.0520(7) Uani 1 1 d . . . O2 O 0.04947(18) 0.39669(8) 0.71118(18) 0.0342(5) Uani 1 1 d . . . O3 O -0.01993(19) 0.34712(9) 0.55407(19) 0.0425(6) Uani 1 1 d . . . O4 O 0.15467(19) 0.44266(10) 0.5814(2) 0.0405(6) Uani 1 1 d . . . O5 O 0.15302(16) 0.50607(9) 0.45775(17) 0.0305(5) Uani 1 1 d . . . O6 O 0.35055(17) 0.54900(9) 0.68123(17) 0.0322(5) Uani 1 1 d . A . O7 O 0.26935(17) 0.61426(9) 0.55595(19) 0.0359(5) Uani 1 1 d . . . C1 C 0.0636(2) 0.56877(12) 0.7106(3) 0.0298(7) Uani 1 1 d D A . C2 C 0.0293(3) 0.61342(14) 0.6928(3) 0.0373(8) Uani 1 1 d D . . C3 C -0.0112(3) 0.66938(15) 0.6758(3) 0.0523(10) Uani 1 1 d . A . H3A H -0.0067 0.6842 0.6093 0.063 Uiso 1 1 calc R . . H3B H -0.0851 0.6692 0.6636 0.063 Uiso 1 1 calc R . . C4 C 0.1485(3) 0.71663(13) 0.7872(3) 0.0409(8) Uani 1 1 d . . . C5 C 0.2018(3) 0.74990(13) 0.8795(3) 0.0432(9) Uani 1 1 d . . . H5 H 0.1671 0.7628 0.9220 0.052 Uiso 1 1 calc R . . C6 C 0.3053(3) 0.76352(13) 0.9073(3) 0.0411(8) Uani 1 1 d . . . H6 H 0.3395 0.7860 0.9684 0.049 Uiso 1 1 calc R . . C7 C 0.3611(3) 0.74435(13) 0.8458(3) 0.0375(8) Uani 1 1 d . . . C8 C 0.3040(3) 0.71286(13) 0.7516(3) 0.0407(8) Uani 1 1 d . . . H8 H 0.3376 0.7004 0.7077 0.049 Uiso 1 1 calc R . . C9 C 0.1994(3) 0.69975(13) 0.7220(3) 0.0416(9) Uani 1 1 d . . . H9 H 0.1631 0.6795 0.6579 0.050 Uiso 1 1 calc R . . C10 C 0.4752(3) 0.75464(12) 0.8805(3) 0.0385(8) Uani 1 1 d . . . C11 C 0.5424(3) 0.76535(14) 0.9920(3) 0.0470(9) Uani 1 1 d . . . H11 H 0.5146 0.7673 1.0456 0.056 Uiso 1 1 calc R . . C12 C 0.6503(4) 0.77318(15) 1.0243(4) 0.0562(11) Uani 1 1 d . . . H12 H 0.6935 0.7805 1.0990 0.067 Uiso 1 1 calc R . . C13 C 0.6936(4) 0.77024(17) 0.9473(4) 0.0599(11) Uani 1 1 d . . . H13 H 0.7656 0.7755 0.9692 0.072 Uiso 1 1 calc R . . C14 C 0.6282(4) 0.75934(17) 0.8365(4) 0.0599(11) Uani 1 1 d . . . H14 H 0.6568 0.7567 0.7837 0.072 Uiso 1 1 calc R . . C15 C 0.5209(3) 0.75232(15) 0.8036(3) 0.0502(10) Uani 1 1 d . . . H15 H 0.4782 0.7459 0.7284 0.060 Uiso 1 1 calc R . . C16 C 0.3349(3) 0.42144(12) 0.8624(3) 0.0320(7) Uani 1 1 d . . . H16 H 0.2992 0.4145 0.7861 0.038 Uiso 1 1 calc R A . C17 C 0.3891(3) 0.37986(13) 0.9324(3) 0.0381(8) Uani 1 1 d . A . H17 H 0.3894 0.3457 0.9040 0.046 Uiso 1 1 calc R . . C18 C 0.4425(3) 0.39045(14) 1.0449(3) 0.0407(8) Uani 1 1 d . . . H18 H 0.4797 0.3634 1.0942 0.049 Uiso 1 1 calc R A . C19 C 0.4404(3) 0.44180(13) 1.0840(3) 0.0349(7) Uani 1 1 d . A . H19 H 0.4764 0.4496 1.1599 0.042 Uiso 1 1 calc R . . C20 C 0.3842(2) 0.48154(12) 1.0090(2) 0.0239(6) Uani 1 1 d . . . C21 C 0.3789(2) 0.53769(12) 1.0466(2) 0.0243(6) Uani 1 1 d . A . C22 C 0.4220(3) 0.55188(14) 1.1598(3) 0.0356(8) Uani 1 1 d . . . H22 H 0.4560 0.5263 1.2146 0.043 Uiso 1 1 calc R A . C23 C 0.4136(3) 0.60409(15) 1.1895(3) 0.0425(8) Uani 1 1 d . A . H23 H 0.4414 0.6141 1.2646 0.051 Uiso 1 1 calc R . . C24 C 0.3637(3) 0.64138(14) 1.1071(3) 0.0395(8) Uani 1 1 d . . . H24 H 0.3573 0.6769 1.1252 0.047 Uiso 1 1 calc R A . C25 C 0.3234(3) 0.62467(13) 0.9963(3) 0.0341(7) Uani 1 1 d . A . H25 H 0.2901 0.6499 0.9403 0.041 Uiso 1 1 calc R . . C26 C 0.1423(3) 0.41611(16) 0.9814(3) 0.0442(9) Uani 1 1 d . A . H26 H 0.1240 0.4051 0.9078 0.053 Uiso 1 1 calc R . . C27 C 0.1799(3) 0.37869(17) 1.0648(3) 0.0542(10) Uani 1 1 d . . . H27 H 0.1887 0.3431 1.0489 0.065 Uiso 1 1 calc R A . C28 C 0.2044(5) 0.39510(19) 1.1725(4) 0.0795(16) Uani 1 1 d . A . H28 H 0.2303 0.3706 1.2312 0.095 Uiso 1 1 calc R . . C29 C 0.1907(5) 0.44814(17) 1.1935(3) 0.0697(14) Uani 1 1 d . . . H29 H 0.2054 0.4593 1.2663 0.084 Uiso 1 1 calc R A . C30 C 0.1551(3) 0.48446(14) 1.1066(3) 0.0340(7) Uani 1 1 d . A . C31 C 0.1438(2) 0.54289(13) 1.1256(3) 0.0320(7) Uani 1 1 d . A . C32 C 0.1681(3) 0.56313(15) 1.2324(3) 0.0379(8) Uani 1 1 d . . . H32 H 0.1909 0.5404 1.2943 0.045 Uiso 1 1 calc R A . C33 C 0.1579(3) 0.61753(16) 1.2450(3) 0.0465(9) Uani 1 1 d . A . H33 H 0.1734 0.6319 1.3157 0.056 Uiso 1 1 calc R . . C34 C 0.1246(3) 0.65043(16) 1.1525(3) 0.0494(10) Uani 1 1 d . . . H34 H 0.1174 0.6872 1.1590 0.059 Uiso 1 1 calc R A . C35 C 0.1021(3) 0.62687(16) 1.0492(3) 0.0458(9) Uani 1 1 d . A . H35 H 0.0791 0.6488 0.9862 0.055 Uiso 1 1 calc R . . C36 C 0.0380(2) 0.35595(13) 0.6537(3) 0.0290(7) Uani 1 1 d . A . C37 C 0.1086(3) 0.30868(13) 0.7176(3) 0.0377(8) Uani 1 1 d . . . C38 C 0.1874(2) 0.46553(13) 0.5183(3) 0.0287(7) Uani 1 1 d . A . C39 C 0.2833(3) 0.43795(15) 0.5097(3) 0.0376(8) Uani 1 1 d . . . C40 C 0.3434(2) 0.58390(12) 0.6100(2) 0.0276(7) Uani 1 1 d . A . C41 C 0.4431(3) 0.59123(14) 0.5874(3) 0.0381(8) Uani 1 1 d . . . F1 F 0.09194(17) 0.26371(8) 0.65810(18) 0.0479(5) Uani 1 1 d . A . F2 F 0.0965(2) 0.29658(9) 0.80988(18) 0.0741(8) Uani 1 1 d . A . F3 F 0.20966(17) 0.32062(10) 0.7454(3) 0.0906(10) Uani 1 1 d . A . F4 F 0.35112(18) 0.41813(11) 0.60788(17) 0.0612(7) Uani 1 1 d . A . F5 F 0.33742(17) 0.47031(9) 0.47202(18) 0.0512(6) Uani 1 1 d . A . F6 F 0.25068(18) 0.39658(9) 0.43791(18) 0.0525(5) Uani 1 1 d . A . F7 F 0.51121(18) 0.55119(10) 0.6244(2) 0.0570(6) Uani 1 1 d . A . F8 F 0.49502(19) 0.63557(10) 0.6421(2) 0.0706(7) Uani 1 1 d . A . F9 F 0.4215(2) 0.59848(12) 0.48029(19) 0.0709(8) Uani 1 1 d . A . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.02365(12) 0.03701(13) 0.01811(12) 0.00505(9) 0.00672(10) 0.00435(9) Ag2 0.02654(13) 0.03239(13) 0.02932(14) -0.00254(10) 0.00831(11) -0.00013(9) Ag3 0.03100(14) 0.04039(14) 0.02205(13) 0.00430(10) 0.00867(11) 0.00324(10) Ag4 0.03299(17) 0.0405(4) 0.01972(15) 0.00050(17) 0.01260(13) -0.00210(19) Ag4' 0.03299(17) 0.0405(4) 0.01972(15) 0.00050(17) 0.01260(13) -0.00210(19) N1 0.0246(13) 0.0278(13) 0.0230(14) 0.0025(10) 0.0079(11) 0.0009(10) N2 0.0222(13) 0.0340(14) 0.0207(13) 0.0003(10) 0.0060(11) 0.0018(10) N3 0.0283(15) 0.0551(18) 0.0244(15) -0.0048(13) 0.0143(12) -0.0088(12) N4 0.0365(16) 0.0452(17) 0.0304(16) 0.0014(12) 0.0169(13) -0.0065(13) O1 0.0455(16) 0.0479(15) 0.0555(17) -0.0181(13) 0.0137(13) 0.0134(12) O2 0.0459(14) 0.0299(12) 0.0341(13) -0.0003(10) 0.0238(11) -0.0003(10) O3 0.0379(14) 0.0425(14) 0.0325(14) 0.0001(11) -0.0002(11) 0.0036(11) O4 0.0434(14) 0.0457(14) 0.0423(14) 0.0130(11) 0.0276(12) 0.0084(11) O5 0.0251(11) 0.0404(13) 0.0229(11) 0.0060(10) 0.0067(9) 0.0017(9) O6 0.0263(11) 0.0472(13) 0.0239(12) 0.0072(10) 0.0111(10) 0.0017(10) O7 0.0322(12) 0.0379(12) 0.0363(13) 0.0069(10) 0.0129(11) 0.0033(10) C1 0.0248(16) 0.0350(18) 0.0255(17) 0.0043(13) 0.0063(14) 0.0030(13) C2 0.0254(17) 0.049(2) 0.0327(19) -0.0069(15) 0.0071(15) 0.0065(15) C3 0.041(2) 0.047(2) 0.057(3) -0.0066(18) 0.0069(19) 0.0201(17) C4 0.051(2) 0.0283(17) 0.037(2) -0.0009(14) 0.0113(17) 0.0129(15) C5 0.057(2) 0.0333(18) 0.037(2) -0.0028(15) 0.0172(18) 0.0155(16) C6 0.058(2) 0.0287(17) 0.0313(19) -0.0038(14) 0.0131(17) 0.0064(16) C7 0.056(2) 0.0265(16) 0.0291(18) 0.0021(14) 0.0164(17) 0.0049(15) C8 0.057(2) 0.0307(17) 0.0344(19) -0.0010(14) 0.0190(18) 0.0066(16) C9 0.061(2) 0.0292(17) 0.0296(19) -0.0064(14) 0.0139(18) 0.0054(16) C10 0.056(2) 0.0213(16) 0.0348(19) 0.0012(14) 0.0153(17) 0.0052(14) C11 0.064(3) 0.0350(19) 0.041(2) -0.0068(16) 0.020(2) -0.0051(17) C12 0.068(3) 0.043(2) 0.049(2) -0.0056(18) 0.014(2) -0.0060(19) C13 0.061(3) 0.053(2) 0.062(3) -0.001(2) 0.021(2) -0.006(2) C14 0.071(3) 0.060(3) 0.056(3) -0.007(2) 0.033(2) -0.001(2) C15 0.064(3) 0.044(2) 0.042(2) -0.0015(17) 0.022(2) 0.0039(19) C16 0.0307(17) 0.0353(17) 0.0273(17) -0.0011(13) 0.0093(14) -0.0017(13) C17 0.0374(19) 0.0306(17) 0.045(2) 0.0024(15) 0.0152(17) 0.0002(14) C18 0.0369(19) 0.0361(19) 0.042(2) 0.0162(16) 0.0086(17) 0.0093(15) C19 0.0281(17) 0.0416(19) 0.0258(18) 0.0109(14) 0.0019(14) 0.0023(14) C20 0.0179(14) 0.0323(16) 0.0215(16) 0.0052(12) 0.0083(13) -0.0001(12) C21 0.0166(14) 0.0348(16) 0.0211(16) 0.0025(12) 0.0072(12) -0.0009(12) C22 0.0355(18) 0.0432(19) 0.0219(17) 0.0024(14) 0.0055(14) 0.0001(15) C23 0.039(2) 0.056(2) 0.0257(18) -0.0102(16) 0.0062(16) -0.0032(17) C24 0.0371(19) 0.0386(19) 0.038(2) -0.0073(16) 0.0104(16) 0.0034(15) C25 0.0308(17) 0.0345(17) 0.0326(18) 0.0018(14) 0.0084(15) 0.0038(14) C26 0.041(2) 0.062(2) 0.035(2) -0.0180(18) 0.0210(17) -0.0139(18) C27 0.067(3) 0.049(2) 0.049(2) -0.0035(19) 0.026(2) 0.001(2) C28 0.130(5) 0.057(3) 0.042(3) 0.010(2) 0.025(3) 0.013(3) C29 0.117(4) 0.056(3) 0.028(2) 0.0002(19) 0.022(2) 0.009(3) C30 0.0318(18) 0.050(2) 0.0219(17) -0.0047(14) 0.0128(15) -0.0086(15) C31 0.0264(16) 0.0494(19) 0.0244(17) -0.0045(14) 0.0147(14) -0.0089(14) C32 0.0390(19) 0.054(2) 0.0258(18) -0.0047(15) 0.0183(16) -0.0069(16) C33 0.047(2) 0.061(2) 0.042(2) -0.0174(19) 0.0290(19) -0.0111(18) C34 0.049(2) 0.046(2) 0.065(3) -0.0107(19) 0.035(2) -0.0068(17) C35 0.042(2) 0.055(2) 0.045(2) 0.0067(18) 0.0229(18) -0.0025(17) C36 0.0208(15) 0.0357(18) 0.0323(19) 0.0027(14) 0.0127(14) -0.0025(13) C37 0.0302(18) 0.0306(17) 0.043(2) -0.0023(15) 0.0053(16) -0.0069(14) C38 0.0252(16) 0.0411(18) 0.0193(16) -0.0045(14) 0.0086(13) -0.0029(13) C39 0.0340(18) 0.053(2) 0.0243(18) 0.0021(15) 0.0109(15) 0.0073(16) C40 0.0270(16) 0.0350(17) 0.0200(16) -0.0039(13) 0.0087(13) -0.0029(13) C41 0.0352(19) 0.051(2) 0.0323(19) 0.0092(16) 0.0180(16) 0.0025(16) F1 0.0543(13) 0.0318(10) 0.0591(14) -0.0015(9) 0.0248(11) 0.0017(9) F2 0.129(2) 0.0477(13) 0.0347(13) 0.0126(10) 0.0222(14) 0.0078(14) F3 0.0249(12) 0.0472(14) 0.163(3) 0.0107(16) 0.0015(15) 0.0004(10) F4 0.0460(13) 0.1008(19) 0.0319(12) 0.0146(12) 0.0113(10) 0.0349(12) F5 0.0375(12) 0.0775(15) 0.0485(13) 0.0017(11) 0.0279(11) 0.0019(11) F6 0.0618(14) 0.0538(13) 0.0445(13) -0.0063(10) 0.0242(11) 0.0128(11) F7 0.0446(13) 0.0738(15) 0.0681(16) 0.0260(12) 0.0389(12) 0.0198(11) F8 0.0525(15) 0.0700(16) 0.097(2) -0.0059(14) 0.0378(14) -0.0250(13) F9 0.0649(16) 0.120(2) 0.0452(14) 0.0281(14) 0.0402(13) 0.0162(15) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 O6 2.323(2) . ? Ag1 N1 2.343(2) . ? Ag1 C1 2.381(3) . ? Ag1 N2 2.384(2) . ? Ag1 Ag4 2.8588(5) . ? Ag1 Ag2 2.9263(4) . ? Ag1 Ag3 2.9408(4) . ? Ag1 Ag4' 3.050(2) . ? Ag2 C1 2.205(3) . ? Ag2 O2 2.303(2) . ? Ag2 O4 2.344(2) . ? Ag2 O5 2.546(2) 3_566 ? Ag2 Ag4 2.8282(6) . ? Ag2 Ag3 3.0145(4) . ? Ag2 Ag3 3.0911(4) 3_566 ? Ag2 Ag4' 3.153(3) . ? Ag3 O3 2.319(2) 3_566 ? Ag3 O7 2.389(2) . ? Ag3 C1 2.417(3) . ? Ag3 O5 2.416(2) . ? Ag3 C2 2.646(3) . ? Ag3 Ag2 3.0911(4) 3_566 ? Ag4 C1 2.184(3) . ? Ag4 N3 2.185(3) . ? Ag4 N4 2.371(3) . ? Ag4' C1 2.075(4) . ? Ag4' N4 2.087(4) . ? Ag4' N3 2.584(4) . ? Ag4' C2 2.644(4) . ? N1 C16 1.338(4) . ? N1 C20 1.343(4) . ? N2 C25 1.338(4) . ? N2 C21 1.342(4) . ? N3 C30 1.345(4) . ? N3 C26 1.349(5) . ? N4 C35 1.331(5) . ? N4 C31 1.335(4) . ? O1 C4 1.371(5) . ? O1 C3 1.438(4) . ? O2 C36 1.234(4) . ? O3 C36 1.238(4) . ? O3 Ag3 2.319(2) 3_566 ? O4 C38 1.233(4) . ? O5 C38 1.251(4) . ? O5 Ag2 2.546(2) 3_566 ? O6 C40 1.248(4) . ? O7 C40 1.237(4) . ? C1 C2 1.195(4) . ? C2 C3 1.486(5) . ? C4 C9 1.377(5) . ? C4 C5 1.399(5) . ? C5 C6 1.371(5) . ? C6 C7 1.411(5) . ? C7 C8 1.399(5) . ? C7 C10 1.480(5) . ? C8 C9 1.380(5) . ? C10 C15 1.394(5) . ? C10 C11 1.396(5) . ? C11 C12 1.393(6) . ? C12 C13 1.371(6) . ? C13 C14 1.384(6) . ? C14 C15 1.380(6) . ? C16 C17 1.382(5) . ? C17 C18 1.374(5) . ? C18 C19 1.383(5) . ? C19 C20 1.387(4) . ? C20 C21 1.495(4) . ? C21 C22 1.395(4) . ? C22 C23 1.376(5) . ? C23 C24 1.375(5) . ? C24 C25 1.386(5) . ? C26 C27 1.366(5) . ? C27 C28 1.368(6) . ? C28 C29 1.379(6) . ? C29 C30 1.376(5) . ? C30 C31 1.496(5) . ? C31 C32 1.390(4) . ? C32 C33 1.380(5) . ? C33 C34 1.374(5) . ? C34 C35 1.386(5) . ? C36 C37 1.540(4) . ? C37 F2 1.321(4) . ? C37 F1 1.329(4) . ? C37 F3 1.330(4) . ? C38 C39 1.543(4) . ? C39 F5 1.328(4) . ? C39 F4 1.336(4) . ? C39 F6 1.342(4) . ? C40 C41 1.541(4) . ? C41 F9 1.319(4) . ? C41 F7 1.322(4) . ? C41 F8 1.352(4) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag O6 Ag1 N1 98.96(8) . . ? O6 Ag1 C1 125.75(9) . . ? N1 Ag1 C1 129.56(10) . . ? O6 Ag1 N2 111.94(8) . . ? N1 Ag1 N2 69.95(8) . . ? C1 Ag1 N2 107.08(10) . . ? O6 Ag1 Ag4 171.94(5) . . ? N1 Ag1 Ag4 84.60(6) . . ? C1 Ag1 Ag4 48.22(8) . . ? N2 Ag1 Ag4 76.06(6) . . ? O6 Ag1 Ag2 113.69(6) . . ? N1 Ag1 Ag2 96.59(6) . . ? C1 Ag1 Ag2 47.75(8) . . ? N2 Ag1 Ag2 133.90(6) . . ? Ag4 Ag1 Ag2 58.518(13) . . ? O6 Ag1 Ag3 73.31(5) . . ? N1 Ag1 Ag3 149.09(6) . . ? C1 Ag1 Ag3 52.75(7) . . ? N2 Ag1 Ag3 140.91(6) . . ? Ag4 Ag1 Ag3 99.930(14) . . ? Ag2 Ag1 Ag3 61.833(9) . . ? O6 Ag1 Ag4' 167.52(8) . . ? N1 Ag1 Ag4' 93.49(8) . . ? C1 Ag1 Ag4' 42.76(9) . . ? N2 Ag1 Ag4' 73.14(7) . . ? Ag4 Ag1 Ag4' 11.00(5) . . ? Ag2 Ag1 Ag4' 63.66(5) . . ? Ag3 Ag1 Ag4' 95.51(4) . . ? C1 Ag2 O2 144.48(10) . . ? C1 Ag2 O4 123.76(10) . . ? O2 Ag2 O4 77.03(8) . . ? C1 Ag2 O5 92.92(9) . 3_566 ? O2 Ag2 O5 98.63(8) . 3_566 ? O4 Ag2 O5 122.24(8) . 3_566 ? C1 Ag2 Ag4 49.56(8) . . ? O2 Ag2 Ag4 94.92(6) . . ? O4 Ag2 Ag4 131.76(6) . . ? O5 Ag2 Ag4 105.95(5) 3_566 . ? C1 Ag2 Ag1 53.06(8) . . ? O2 Ag2 Ag1 113.20(6) . . ? O4 Ag2 Ag1 79.90(6) . . ? O5 Ag2 Ag1 145.30(5) 3_566 . ? Ag4 Ag2 Ag1 59.549(10) . . ? C1 Ag2 Ag3 52.42(8) . . ? O2 Ag2 Ag3 156.05(5) . . ? O4 Ag2 Ag3 79.18(6) . . ? O5 Ag2 Ag3 96.26(5) 3_566 . ? Ag4 Ag2 Ag3 98.892(16) . . ? Ag1 Ag2 Ag3 59.320(9) . . ? C1 Ag2 Ag3 136.08(8) . 3_566 ? O2 Ag2 Ag3 73.14(6) . 3_566 ? O4 Ag2 Ag3 75.20(6) . 3_566 ? O5 Ag2 Ag3 49.60(5) 3_566 3_566 ? Ag4 Ag2 Ag3 148.288(12) . 3_566 ? Ag1 Ag2 Ag3 152.162(11) . 3_566 ? Ag3 Ag2 Ag3 103.296(11) . 3_566 ? C1 Ag2 Ag4' 40.98(9) . . ? O2 Ag2 Ag4' 103.67(8) . . ? O4 Ag2 Ag4' 137.09(8) . . ? O5 Ag2 Ag4' 100.31(7) 3_566 . ? Ag4 Ag2 Ag4' 9.63(4) . . ? Ag1 Ag2 Ag4' 60.08(4) . . ? Ag3 Ag2 Ag4' 91.93(5) . . ? Ag3 Ag2 Ag4' 147.02(4) 3_566 . ? O3 Ag3 O7 88.96(8) 3_566 . ? O3 Ag3 C1 109.85(10) 3_566 . ? O7 Ag3 C1 125.79(9) . . ? O3 Ag3 O5 118.68(8) 3_566 . ? O7 Ag3 O5 81.42(7) . . ? C1 Ag3 O5 124.64(9) . . ? O3 Ag3 C2 83.86(10) 3_566 . ? O7 Ag3 C2 120.99(9) . . ? C1 Ag3 C2 26.80(10) . . ? O5 Ag3 C2 150.00(9) . . ? O3 Ag3 Ag1 144.29(6) 3_566 . ? O7 Ag3 Ag1 83.24(5) . . ? C1 Ag3 Ag1 51.65(7) . . ? O5 Ag3 Ag1 94.58(5) . . ? C2 Ag3 Ag1 70.89(7) . . ? O3 Ag3 Ag2 135.27(6) 3_566 . ? O7 Ag3 Ag2 135.57(5) . . ? C1 Ag3 Ag2 46.31(7) . . ? O5 Ag3 Ag2 79.67(5) . . ? C2 Ag3 Ag2 70.34(8) . . ? Ag1 Ag3 Ag2 58.846(9) . . ? O3 Ag3 Ag2 83.42(6) 3_566 3_566 ? O7 Ag3 Ag2 120.88(5) . 3_566 ? C1 Ag3 Ag2 111.74(8) . 3_566 ? O5 Ag3 Ag2 53.39(5) . 3_566 ? C2 Ag3 Ag2 116.28(7) . 3_566 ? Ag1 Ag3 Ag2 130.103(12) . 3_566 ? Ag2 Ag3 Ag2 76.704(11) . 3_566 ? C1 Ag4 N3 161.94(12) . . ? C1 Ag4 N4 123.95(11) . . ? N3 Ag4 N4 73.08(10) . . ? C1 Ag4 Ag2 50.22(8) . . ? N3 Ag4 Ag2 113.23(8) . . ? N4 Ag4 Ag2 172.92(8) . . ? C1 Ag4 Ag1 54.37(8) . . ? N3 Ag4 Ag1 114.12(7) . . ? N4 Ag4 Ag1 119.26(7) . . ? Ag2 Ag4 Ag1 61.932(12) . . ? C1 Ag4' N4 150.2(2) . . ? C1 Ag4' N3 135.37(18) . . ? N4 Ag4' N3 70.20(12) . . ? C1 Ag4' C2 25.92(11) . . ? N4 Ag4' C2 127.82(18) . . ? N3 Ag4' C2 161.23(16) . . ? C1 Ag4' Ag1 51.16(10) . . ? N4 Ag4' Ag1 122.10(11) . . ? N3 Ag4' Ag1 97.56(11) . . ? C2 Ag4' Ag1 69.17(8) . . ? C1 Ag4' Ag2 44.18(10) . . ? N4 Ag4' Ag2 163.67(16) . . ? N3 Ag4' Ag2 93.60(12) . . ? C2 Ag4' Ag2 68.13(8) . . ? Ag1 Ag4' Ag2 56.26(4) . . ? C16 N1 C20 118.5(3) . . ? C16 N1 Ag1 122.7(2) . . ? C20 N1 Ag1 118.74(19) . . ? C25 N2 C21 118.6(3) . . ? C25 N2 Ag1 123.8(2) . . ? C21 N2 Ag1 117.32(19) . . ? C30 N3 C26 118.8(3) . . ? C30 N3 Ag4 118.9(2) . . ? C26 N3 Ag4 121.9(2) . . ? C30 N3 Ag4' 108.8(2) . . ? C26 N3 Ag4' 132.4(2) . . ? C35 N4 C31 118.3(3) . . ? C35 N4 Ag4' 114.8(2) . . ? C31 N4 Ag4' 126.9(2) . . ? C35 N4 Ag4 128.0(2) . . ? C31 N4 Ag4 113.5(2) . . ? C4 O1 C3 117.5(3) . . ? C36 O2 Ag2 127.3(2) . . ? C36 O3 Ag3 116.0(2) . 3_566 ? C38 O4 Ag2 123.1(2) . . ? C38 O5 Ag3 113.55(19) . . ? C38 O5 Ag2 118.74(19) . 3_566 ? Ag3 O5 Ag2 77.02(6) . 3_566 ? C40 O6 Ag1 126.10(19) . . ? C40 O7 Ag3 109.97(19) . . ? C2 C1 Ag4' 104.7(3) . . ? C2 C1 Ag4 120.5(3) . . ? C2 C1 Ag2 147.3(3) . . ? Ag4' C1 Ag2 94.85(15) . . ? Ag4 C1 Ag2 80.22(10) . . ? C2 C1 Ag1 127.5(3) . . ? Ag4' C1 Ag1 86.08(13) . . ? Ag4 C1 Ag1 77.41(9) . . ? Ag2 C1 Ag1 79.19(10) . . ? C2 C1 Ag3 87.4(2) . . ? Ag4' C1 Ag3 161.67(17) . . ? Ag4 C1 Ag3 149.62(15) . . ? Ag2 C1 Ag3 81.27(10) . . ? Ag1 C1 Ag3 75.60(9) . . ? C1 C2 C3 177.6(4) . . ? C1 C2 Ag4' 49.4(2) . . ? C3 C2 Ag4' 128.4(3) . . ? C1 C2 Ag3 65.8(2) . . ? C3 C2 Ag3 116.0(3) . . ? Ag4' C2 Ag3 113.94(13) . . ? O1 C3 C2 111.6(3) . . ? O1 C4 C9 125.2(3) . . ? O1 C4 C5 115.3(3) . . ? C9 C4 C5 119.5(4) . . ? C6 C5 C4 120.0(3) . . ? C5 C6 C7 121.7(3) . . ? C8 C7 C6 116.6(3) . . ? C8 C7 C10 120.9(3) . . ? C6 C7 C10 122.5(3) . . ? C9 C8 C7 121.9(3) . . ? C4 C9 C8 120.2(3) . . ? C15 C10 C11 117.1(4) . . ? C15 C10 C7 121.3(3) . . ? C11 C10 C7 121.6(3) . . ? C12 C11 C10 121.1(4) . . ? C13 C12 C11 120.7(4) . . ? C12 C13 C14 118.9(4) . . ? C15 C14 C13 120.6(4) . . ? C14 C15 C10 121.5(4) . . ? N1 C16 C17 123.2(3) . . ? C18 C17 C16 118.2(3) . . ? C17 C18 C19 119.4(3) . . ? C18 C19 C20 119.3(3) . . ? N1 C20 C19 121.4(3) . . ? N1 C20 C21 116.9(2) . . ? C19 C20 C21 121.7(3) . . ? N2 C21 C22 121.3(3) . . ? N2 C21 C20 116.7(3) . . ? C22 C21 C20 121.9(3) . . ? C23 C22 C21 119.3(3) . . ? C22 C23 C24 119.4(3) . . ? C23 C24 C25 118.2(3) . . ? N2 C25 C24 123.1(3) . . ? N3 C26 C27 123.1(3) . . ? C26 C27 C28 118.0(4) . . ? C27 C28 C29 119.7(4) . . ? C28 C29 C30 119.8(4) . . ? N3 C30 C29 120.5(3) . . ? N3 C30 C31 117.5(3) . . ? C29 C30 C31 122.0(3) . . ? N4 C31 C32 121.9(3) . . ? N4 C31 C30 116.6(3) . . ? C32 C31 C30 121.4(3) . . ? C33 C32 C31 118.8(3) . . ? C34 C33 C32 119.7(3) . . ? C33 C34 C35 117.7(4) . . ? N4 C35 C34 123.6(4) . . ? O3 C36 O2 130.7(3) . . ? O3 C36 C37 115.3(3) . . ? O2 C36 C37 113.9(3) . . ? F2 C37 F1 106.6(3) . . ? F2 C37 F3 108.5(3) . . ? F1 C37 F3 105.0(3) . . ? F2 C37 C36 112.2(3) . . ? F1 C37 C36 114.1(3) . . ? F3 C37 C36 110.0(3) . . ? O4 C38 O5 130.3(3) . . ? O4 C38 C39 114.2(3) . . ? O5 C38 C39 115.5(3) . . ? F5 C39 F4 107.4(3) . . ? F5 C39 F6 106.7(3) . . ? F4 C39 F6 106.9(3) . . ? F5 C39 C38 113.2(3) . . ? F4 C39 C38 112.5(3) . . ? F6 C39 C38 109.9(3) . . ? O7 C40 O6 130.2(3) . . ? O7 C40 C41 114.7(3) . . ? O6 C40 C41 115.1(3) . . ? F9 C41 F7 107.9(3) . . ? F9 C41 F8 106.8(3) . . ? F7 C41 F8 106.1(3) . . ? F9 C41 C40 113.0(3) . . ? F7 C41 C40 113.8(3) . . ? F8 C41 C40 108.7(3) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag O6 Ag1 Ag2 C1 -117.61(12) . . . . ? N1 Ag1 Ag2 C1 139.57(12) . . . . ? N2 Ag1 Ag2 C1 71.14(13) . . . . ? Ag4 Ag1 Ag2 C1 60.05(10) . . . . ? Ag3 Ag1 Ag2 C1 -63.82(10) . . . . ? Ag4' Ag1 Ag2 C1 48.92(12) . . . . ? O6 Ag1 Ag2 O2 100.61(8) . . . . ? N1 Ag1 Ag2 O2 -2.21(8) . . . . ? C1 Ag1 Ag2 O2 -141.78(12) . . . . ? N2 Ag1 Ag2 O2 -70.64(10) . . . . ? Ag4 Ag1 Ag2 O2 -81.73(6) . . . . ? Ag3 Ag1 Ag2 O2 154.40(6) . . . . ? Ag4' Ag1 Ag2 O2 -92.86(9) . . . . ? O6 Ag1 Ag2 O4 29.54(8) . . . . ? N1 Ag1 Ag2 O4 -73.28(8) . . . . ? C1 Ag1 Ag2 O4 147.15(11) . . . . ? N2 Ag1 Ag2 O4 -141.71(10) . . . . ? Ag4 Ag1 Ag2 O4 -152.80(6) . . . . ? Ag3 Ag1 Ag2 O4 83.33(6) . . . . ? Ag4' Ag1 Ag2 O4 -163.93(8) . . . . ? O6 Ag1 Ag2 O5 -104.46(10) . . . 3_566 ? N1 Ag1 Ag2 O5 152.72(10) . . . 3_566 ? C1 Ag1 Ag2 O5 13.16(13) . . . 3_566 ? N2 Ag1 Ag2 O5 84.29(12) . . . 3_566 ? Ag4 Ag1 Ag2 O5 73.20(8) . . . 3_566 ? Ag3 Ag1 Ag2 O5 -50.66(8) . . . 3_566 ? Ag4' Ag1 Ag2 O5 62.08(10) . . . 3_566 ? O6 Ag1 Ag2 Ag4 -177.66(6) . . . . ? N1 Ag1 Ag2 Ag4 79.52(6) . . . . ? C1 Ag1 Ag2 Ag4 -60.05(10) . . . . ? N2 Ag1 Ag2 Ag4 11.09(8) . . . . ? Ag3 Ag1 Ag2 Ag4 -123.87(2) . . . . ? Ag4' Ag1 Ag2 Ag4 -11.12(5) . . . . ? O6 Ag1 Ag2 Ag3 -53.79(6) . . . . ? N1 Ag1 Ag2 Ag3 -156.61(6) . . . . ? C1 Ag1 Ag2 Ag3 63.82(10) . . . . ? N2 Ag1 Ag2 Ag3 134.96(8) . . . . ? Ag4 Ag1 Ag2 Ag3 123.87(2) . . . . ? Ag4' Ag1 Ag2 Ag3 112.74(6) . . . . ? O6 Ag1 Ag2 Ag3 2.79(6) . . . 3_566 ? N1 Ag1 Ag2 Ag3 -100.03(6) . . . 3_566 ? C1 Ag1 Ag2 Ag3 120.40(10) . . . 3_566 ? N2 Ag1 Ag2 Ag3 -168.46(8) . . . 3_566 ? Ag4 Ag1 Ag2 Ag3 -179.56(3) . . . 3_566 ? Ag3 Ag1 Ag2 Ag3 56.58(2) . . . 3_566 ? Ag4' Ag1 Ag2 Ag3 169.32(7) . . . 3_566 ? O6 Ag1 Ag2 Ag4' -166.53(9) . . . . ? N1 Ag1 Ag2 Ag4' 90.64(9) . . . . ? C1 Ag1 Ag2 Ag4' -48.92(12) . . . . ? N2 Ag1 Ag2 Ag4' 22.21(10) . . . . ? Ag4 Ag1 Ag2 Ag4' 11.12(5) . . . . ? Ag3 Ag1 Ag2 Ag4' -112.74(6) . . . . ? O6 Ag1 Ag3 O3 -104.94(12) . . . 3_566 ? N1 Ag1 Ag3 O3 175.69(16) . . . 3_566 ? C1 Ag1 Ag3 O3 68.97(14) . . . 3_566 ? N2 Ag1 Ag3 O3 -0.50(15) . . . 3_566 ? Ag4 Ag1 Ag3 O3 79.58(11) . . . 3_566 ? Ag2 Ag1 Ag3 O3 125.54(11) . . . 3_566 ? Ag4' Ag1 Ag3 O3 69.41(12) . . . 3_566 ? O6 Ag1 Ag3 O7 -26.27(8) . . . . ? N1 Ag1 Ag3 O7 -105.64(13) . . . . ? C1 Ag1 Ag3 O7 147.64(11) . . . . ? N2 Ag1 Ag3 O7 78.17(11) . . . . ? Ag4 Ag1 Ag3 O7 158.25(6) . . . . ? Ag2 Ag1 Ag3 O7 -155.79(5) . . . . ? Ag4' Ag1 Ag3 O7 148.08(8) . . . . ? O6 Ag1 Ag3 C1 -173.91(11) . . . . ? N1 Ag1 Ag3 C1 106.71(15) . . . . ? N2 Ag1 Ag3 C1 -69.47(13) . . . . ? Ag4 Ag1 Ag3 C1 10.61(10) . . . . ? Ag2 Ag1 Ag3 C1 56.57(10) . . . . ? Ag4' Ag1 Ag3 C1 0.44(11) . . . . ? O6 Ag1 Ag3 O5 54.51(8) . . . . ? N1 Ag1 Ag3 O5 -24.87(13) . . . . ? C1 Ag1 Ag3 O5 -131.58(11) . . . . ? N2 Ag1 Ag3 O5 158.95(11) . . . . ? Ag4 Ag1 Ag3 O5 -120.97(5) . . . . ? Ag2 Ag1 Ag3 O5 -75.01(5) . . . . ? Ag4' Ag1 Ag3 O5 -131.14(8) . . . . ? O6 Ag1 Ag3 C2 -152.41(10) . . . . ? N1 Ag1 Ag3 C2 128.22(14) . . . . ? C1 Ag1 Ag3 C2 21.50(12) . . . . ? N2 Ag1 Ag3 C2 -47.97(12) . . . . ? Ag4 Ag1 Ag3 C2 32.11(8) . . . . ? Ag2 Ag1 Ag3 C2 78.07(8) . . . . ? Ag4' Ag1 Ag3 C2 21.94(10) . . . . ? O6 Ag1 Ag3 Ag2 129.52(6) . . . . ? N1 Ag1 Ag3 Ag2 50.14(12) . . . . ? C1 Ag1 Ag3 Ag2 -56.57(9) . . . . ? N2 Ag1 Ag3 Ag2 -126.04(9) . . . . ? Ag4 Ag1 Ag3 Ag2 -45.963(18) . . . . ? Ag4' Ag1 Ag3 Ag2 -56.13(6) . . . . ? O6 Ag1 Ag3 Ag2 98.89(6) . . . 3_566 ? N1 Ag1 Ag3 Ag2 19.51(12) . . . 3_566 ? C1 Ag1 Ag3 Ag2 -87.20(10) . . . 3_566 ? N2 Ag1 Ag3 Ag2 -156.67(9) . . . 3_566 ? Ag4 Ag1 Ag3 Ag2 -76.60(2) . . . 3_566 ? Ag2 Ag1 Ag3 Ag2 -30.634(14) . . . 3_566 ? Ag4' Ag1 Ag3 Ag2 -86.77(6) . . . 3_566 ? C1 Ag2 Ag3 O3 -72.73(13) . . . 3_566 ? O2 Ag2 Ag3 O3 144.39(17) . . . 3_566 ? O4 Ag2 Ag3 O3 137.84(10) . . . 3_566 ? O5 Ag2 Ag3 O3 16.14(10) 3_566 . . 3_566 ? Ag4 Ag2 Ag3 O3 -91.13(8) . . . 3_566 ? Ag1 Ag2 Ag3 O3 -137.56(8) . . . 3_566 ? Ag3 Ag2 Ag3 O3 66.05(8) 3_566 . . 3_566 ? Ag4' Ag2 Ag3 O3 -84.45(9) . . . 3_566 ? C1 Ag2 Ag3 O7 100.41(13) . . . . ? O2 Ag2 Ag3 O7 -42.47(17) . . . . ? O4 Ag2 Ag3 O7 -49.02(10) . . . . ? O5 Ag2 Ag3 O7 -170.72(9) 3_566 . . . ? Ag4 Ag2 Ag3 O7 82.01(8) . . . . ? Ag1 Ag2 Ag3 O7 35.58(8) . . . . ? Ag3 Ag2 Ag3 O7 -120.81(8) 3_566 . . . ? Ag4' Ag2 Ag3 O7 88.69(9) . . . . ? O2 Ag2 Ag3 C1 -142.88(18) . . . . ? O4 Ag2 Ag3 C1 -149.43(12) . . . . ? O5 Ag2 Ag3 C1 88.87(11) 3_566 . . . ? Ag4 Ag2 Ag3 C1 -18.41(10) . . . . ? Ag1 Ag2 Ag3 C1 -64.84(10) . . . . ? Ag3 Ag2 Ag3 C1 138.77(10) 3_566 . . . ? Ag4' Ag2 Ag3 C1 -11.73(11) . . . . ? C1 Ag2 Ag3 O5 166.67(11) . . . . ? O2 Ag2 Ag3 O5 23.79(15) . . . . ? O4 Ag2 Ag3 O5 17.24(8) . . . . ? O5 Ag2 Ag3 O5 -104.46(6) 3_566 . . . ? Ag4 Ag2 Ag3 O5 148.26(5) . . . . ? Ag1 Ag2 Ag3 O5 101.83(5) . . . . ? Ag3 Ag2 Ag3 O5 -54.56(5) 3_566 . . . ? Ag4' Ag2 Ag3 O5 154.94(7) . . . . ? C1 Ag2 Ag3 C2 -14.20(12) . . . . ? O2 Ag2 Ag3 C2 -157.08(16) . . . . ? O4 Ag2 Ag3 C2 -163.63(10) . . . . ? O5 Ag2 Ag3 C2 74.67(9) 3_566 . . . ? Ag4 Ag2 Ag3 C2 -32.61(8) . . . . ? Ag1 Ag2 Ag3 C2 -79.03(8) . . . . ? Ag3 Ag2 Ag3 C2 124.58(8) 3_566 . . . ? Ag4' Ag2 Ag3 C2 -25.93(9) . . . . ? C1 Ag2 Ag3 Ag1 64.84(10) . . . . ? O2 Ag2 Ag3 Ag1 -78.05(14) . . . . ? O4 Ag2 Ag3 Ag1 -84.60(6) . . . . ? O5 Ag2 Ag3 Ag1 153.71(5) 3_566 . . . ? Ag4 Ag2 Ag3 Ag1 46.428(15) . . . . ? Ag3 Ag2 Ag3 Ag1 -156.391(11) 3_566 . . . ? Ag4' Ag2 Ag3 Ag1 53.11(5) . . . . ? C1 Ag2 Ag3 Ag2 -138.77(10) . . . 3_566 ? O2 Ag2 Ag3 Ag2 78.35(14) . . . 3_566 ? O4 Ag2 Ag3 Ag2 71.79(6) . . . 3_566 ? O5 Ag2 Ag3 Ag2 -49.90(5) 3_566 . . 3_566 ? Ag4 Ag2 Ag3 Ag2 -157.181(17) . . . 3_566 ? Ag1 Ag2 Ag3 Ag2 156.391(11) . . . 3_566 ? Ag3 Ag2 Ag3 Ag2 0.0 3_566 . . 3_566 ? Ag4' Ag2 Ag3 Ag2 -150.50(5) . . . 3_566 ? O2 Ag2 Ag4 C1 179.57(12) . . . . ? O4 Ag2 Ag4 C1 102.58(13) . . . . ? O5 Ag2 Ag4 C1 -79.99(12) 3_566 . . . ? Ag1 Ag2 Ag4 C1 65.48(10) . . . . ? Ag3 Ag2 Ag4 C1 19.19(11) . . . . ? Ag3 Ag2 Ag4 C1 -114.91(11) 3_566 . . . ? Ag4' Ag2 Ag4 C1 -24.8(3) . . . . ? C1 Ag2 Ag4 N3 -171.45(13) . . . . ? O2 Ag2 Ag4 N3 8.12(10) . . . . ? O4 Ag2 Ag4 N3 -68.87(11) . . . . ? O5 Ag2 Ag4 N3 108.56(9) 3_566 . . . ? Ag1 Ag2 Ag4 N3 -105.97(8) . . . . ? Ag3 Ag2 Ag4 N3 -152.26(8) . . . . ? Ag3 Ag2 Ag4 N3 73.64(9) 3_566 . . . ? Ag4' Ag2 Ag4 N3 163.7(3) . . . . ? C1 Ag2 Ag4 Ag1 -65.48(10) . . . . ? O2 Ag2 Ag4 Ag1 114.09(6) . . . . ? O4 Ag2 Ag4 Ag1 37.10(8) . . . . ? O5 Ag2 Ag4 Ag1 -145.47(5) 3_566 . . . ? Ag3 Ag2 Ag4 Ag1 -46.286(14) . . . . ? Ag3 Ag2 Ag4 Ag1 179.60(3) 3_566 . . . ? Ag4' Ag2 Ag4 Ag1 -90.3(2) . . . . ? N1 Ag1 Ag4 C1 -160.47(12) . . . . ? N2 Ag1 Ag4 C1 128.88(12) . . . . ? Ag2 Ag1 Ag4 C1 -59.33(10) . . . . ? Ag3 Ag1 Ag4 C1 -11.33(10) . . . . ? Ag4' Ag1 Ag4 C1 55.7(2) . . . . ? N1 Ag1 Ag4 N3 3.40(10) . . . . ? C1 Ag1 Ag4 N3 163.87(13) . . . . ? N2 Ag1 Ag4 N3 -67.25(10) . . . . ? Ag2 Ag1 Ag4 N3 104.54(9) . . . . ? Ag3 Ag1 Ag4 N3 152.54(8) . . . . ? Ag4' Ag1 Ag4 N3 -140.4(2) . . . . ? N1 Ag1 Ag4 N4 86.82(10) . . . . ? C1 Ag1 Ag4 N4 -112.71(14) . . . . ? N2 Ag1 Ag4 N4 16.16(10) . . . . ? Ag2 Ag1 Ag4 N4 -172.05(9) . . . . ? Ag3 Ag1 Ag4 N4 -124.05(8) . . . . ? Ag4' Ag1 Ag4 N4 -57.0(2) . . . . ? N1 Ag1 Ag4 Ag2 -101.14(6) . . . . ? C1 Ag1 Ag4 Ag2 59.33(10) . . . . ? N2 Ag1 Ag4 Ag2 -171.79(6) . . . . ? Ag3 Ag1 Ag4 Ag2 48.000(16) . . . . ? Ag4' Ag1 Ag4 Ag2 115.0(2) . . . . ? O6 Ag1 Ag4' C1 25.4(4) . . . . ? N1 Ag1 Ag4' C1 -150.91(14) . . . . ? N2 Ag1 Ag4' C1 141.26(15) . . . . ? Ag4 Ag1 Ag4' C1 -114.8(3) . . . . ? Ag2 Ag1 Ag4' C1 -55.28(12) . . . . ? Ag3 Ag1 Ag4' C1 -0.51(13) . . . . ? O6 Ag1 Ag4' N4 -118.7(3) . . . . ? N1 Ag1 Ag4' N4 64.99(18) . . . . ? C1 Ag1 Ag4' N4 -144.1(2) . . . . ? N2 Ag1 Ag4' N4 -2.84(17) . . . . ? Ag4 Ag1 Ag4' N4 101.1(3) . . . . ? Ag2 Ag1 Ag4' N4 160.62(19) . . . . ? Ag3 Ag1 Ag4' N4 -144.61(16) . . . . ? O6 Ag1 Ag4' N3 169.9(3) . . . . ? N1 Ag1 Ag4' N3 -6.34(11) . . . . ? C1 Ag1 Ag4' N3 144.57(17) . . . . ? N2 Ag1 Ag4' N3 -74.17(10) . . . . ? Ag4 Ag1 Ag4' N3 29.74(19) . . . . ? Ag2 Ag1 Ag4' N3 89.29(10) . . . . ? Ag3 Ag1 Ag4' N3 144.06(8) . . . . ? O6 Ag1 Ag4' C2 3.7(4) . . . . ? N1 Ag1 Ag4' C2 -172.62(11) . . . . ? C1 Ag1 Ag4' C2 -21.70(14) . . . . ? N2 Ag1 Ag4' C2 119.55(12) . . . . ? Ag4 Ag1 Ag4' C2 -136.5(3) . . . . ? Ag2 Ag1 Ag4' C2 -76.98(9) . . . . ? Ag3 Ag1 Ag4' C2 -22.22(9) . . . . ? O6 Ag1 Ag4' Ag2 80.6(4) . . . . ? N1 Ag1 Ag4' Ag2 -95.63(7) . . . . ? C1 Ag1 Ag4' Ag2 55.28(12) . . . . ? N2 Ag1 Ag4' Ag2 -163.46(8) . . . . ? Ag4 Ag1 Ag4' Ag2 -59.6(2) . . . . ? Ag3 Ag1 Ag4' Ag2 54.77(3) . . . . ? O2 Ag2 Ag4' C1 175.88(14) . . . . ? O4 Ag2 Ag4' C1 90.35(17) . . . . ? O5 Ag2 Ag4' C1 -82.51(14) 3_566 . . . ? Ag4 Ag2 Ag4' C1 150.8(3) . . . . ? Ag1 Ag2 Ag4' C1 66.74(13) . . . . ? Ag3 Ag2 Ag4' C1 14.22(13) . . . . ? Ag3 Ag2 Ag4' C1 -104.11(14) 3_566 . . . ? C1 Ag2 Ag4' N4 -156.4(5) . . . . ? O2 Ag2 Ag4' N4 19.5(4) . . . . ? O4 Ag2 Ag4' N4 -66.0(4) . . . . ? O5 Ag2 Ag4' N4 121.1(4) 3_566 . . . ? Ag4 Ag2 Ag4' N4 -5.6(3) . . . . ? Ag1 Ag2 Ag4' N4 -89.6(4) . . . . ? Ag3 Ag2 Ag4' N4 -142.2(4) . . . . ? Ag3 Ag2 Ag4' N4 99.5(4) 3_566 . . . ? C1 Ag2 Ag4' N3 -163.43(16) . . . . ? O2 Ag2 Ag4' N3 12.46(10) . . . . ? O4 Ag2 Ag4' N3 -73.08(12) . . . . ? O5 Ag2 Ag4' N3 114.07(9) 3_566 . . . ? Ag4 Ag2 Ag4' N3 -12.6(2) . . . . ? Ag1 Ag2 Ag4' N3 -96.68(9) . . . . ? Ag3 Ag2 Ag4' N3 -149.21(7) . . . . ? Ag3 Ag2 Ag4' N3 92.46(12) 3_566 . . . ? C1 Ag2 Ag4' C2 12.15(14) . . . . ? O2 Ag2 Ag4' C2 -171.97(10) . . . . ? O4 Ag2 Ag4' C2 102.49(13) . . . . ? O5 Ag2 Ag4' C2 -70.36(10) 3_566 . . . ? Ag4 Ag2 Ag4' C2 163.0(3) . . . . ? Ag1 Ag2 Ag4' C2 78.89(8) . . . . ? Ag3 Ag2 Ag4' C2 26.37(8) . . . . ? Ag3 Ag2 Ag4' C2 -91.96(11) 3_566 . . . ? C1 Ag2 Ag4' Ag1 -66.74(13) . . . . ? O2 Ag2 Ag4' Ag1 109.14(7) . . . . ? O4 Ag2 Ag4' Ag1 23.60(12) . . . . ? O5 Ag2 Ag4' Ag1 -149.25(5) 3_566 . . . ? Ag4 Ag2 Ag4' Ag1 84.1(2) . . . . ? Ag3 Ag2 Ag4' Ag1 -52.52(3) . . . . ? Ag3 Ag2 Ag4' Ag1 -170.85(6) 3_566 . . . ? O6 Ag1 N1 C16 -66.2(2) . . . . ? C1 Ag1 N1 C16 87.6(3) . . . . ? N2 Ag1 N1 C16 -176.4(3) . . . . ? Ag4 Ag1 N1 C16 106.5(2) . . . . ? Ag2 Ag1 N1 C16 49.1(2) . . . . ? Ag3 Ag1 N1 C16 6.1(3) . . . . ? Ag4' Ag1 N1 C16 113.0(2) . . . . ? O6 Ag1 N1 C20 110.6(2) . . . . ? C1 Ag1 N1 C20 -95.6(2) . . . . ? N2 Ag1 N1 C20 0.41(19) . . . . ? Ag4 Ag1 N1 C20 -76.7(2) . . . . ? Ag2 Ag1 N1 C20 -134.09(19) . . . . ? Ag3 Ag1 N1 C20 -177.03(14) . . . . ? Ag4' Ag1 N1 C20 -70.2(2) . . . . ? O6 Ag1 N2 C25 91.4(2) . . . . ? N1 Ag1 N2 C25 -176.8(3) . . . . ? C1 Ag1 N2 C25 -50.1(3) . . . . ? Ag4 Ag1 N2 C25 -87.5(2) . . . . ? Ag2 Ag1 N2 C25 -97.2(2) . . . . ? Ag3 Ag1 N2 C25 1.1(3) . . . . ? Ag4' Ag1 N2 C25 -76.5(2) . . . . ? O6 Ag1 N2 C21 -95.6(2) . . . . ? N1 Ag1 N2 C21 -3.80(19) . . . . ? C1 Ag1 N2 C21 122.9(2) . . . . ? Ag4 Ag1 N2 C21 85.5(2) . . . . ? Ag2 Ag1 N2 C21 75.7(2) . . . . ? Ag3 Ag1 N2 C21 174.12(15) . . . . ? Ag4' Ag1 N2 C21 96.5(2) . . . . ? C1 Ag4 N3 C30 156.9(3) . . . . ? N4 Ag4 N3 C30 -4.9(2) . . . . ? Ag2 Ag4 N3 C30 178.6(2) . . . . ? Ag1 Ag4 N3 C30 110.2(2) . . . . ? C1 Ag4 N3 C26 -16.2(5) . . . . ? N4 Ag4 N3 C26 -178.0(3) . . . . ? Ag2 Ag4 N3 C26 5.5(3) . . . . ? Ag1 Ag4 N3 C26 -62.9(3) . . . . ? C1 Ag4 N3 Ag4' 176.3(5) . . . . ? N4 Ag4 N3 Ag4' 14.5(3) . . . . ? Ag2 Ag4 N3 Ag4' -162.1(3) . . . . ? Ag1 Ag4 N3 Ag4' 129.6(3) . . . . ? C1 Ag4' N3 C30 160.4(2) . . . . ? N4 Ag4' N3 C30 -1.0(2) . . . . ? C2 Ag4' N3 C30 164.0(4) . . . . ? Ag1 Ag4' N3 C30 120.4(2) . . . . ? Ag2 Ag4' N3 C30 176.9(2) . . . . ? C1 Ag4' N3 C26 -16.1(4) . . . . ? N4 Ag4' N3 C26 -177.5(3) . . . . ? C2 Ag4' N3 C26 -12.5(6) . . . . ? Ag1 Ag4' N3 C26 -56.1(3) . . . . ? Ag2 Ag4' N3 C26 0.4(3) . . . . ? C1 Ag4' N3 Ag4 -1.7(2) . . . . ? N4 Ag4' N3 Ag4 -163.2(3) . . . . ? C2 Ag4' N3 Ag4 1.9(3) . . . . ? Ag1 Ag4' N3 Ag4 -41.7(2) . . . . ? Ag2 Ag4' N3 Ag4 14.7(2) . . . . ? C1 Ag4' N4 C35 26.3(5) . . . . ? N3 Ag4' N4 C35 179.6(3) . . . . ? C2 Ag4' N4 C35 5.6(3) . . . . ? Ag1 Ag4' N4 C35 93.0(3) . . . . ? Ag2 Ag4' N4 C35 172.1(3) . . . . ? C1 Ag4' N4 C31 -152.7(3) . . . . ? N3 Ag4' N4 C31 0.6(3) . . . . ? C2 Ag4' N4 C31 -173.4(2) . . . . ? Ag1 Ag4' N4 C31 -85.9(3) . . . . ? Ag2 Ag4' N4 C31 -6.9(6) . . . . ? C1 Ag4' N4 Ag4 -141.1(5) . . . . ? N3 Ag4' N4 Ag4 12.2(2) . . . . ? C2 Ag4' N4 Ag4 -161.7(4) . . . . ? Ag1 Ag4' N4 Ag4 -74.3(3) . . . . ? Ag2 Ag4' N4 Ag4 4.7(2) . . . . ? C1 Ag4 N4 C35 6.3(3) . . . . ? N3 Ag4 N4 C35 179.6(3) . . . . ? Ag1 Ag4 N4 C35 71.0(3) . . . . ? C1 Ag4 N4 C31 -169.2(2) . . . . ? N3 Ag4 N4 C31 4.1(2) . . . . ? Ag1 Ag4 N4 C31 -104.5(2) . . . . ? C1 Ag4 N4 Ag4' 21.0(3) . . . . ? N3 Ag4 N4 Ag4' -165.8(3) . . . . ? Ag1 Ag4 N4 Ag4' 85.6(3) . . . . ? C1 Ag2 O2 C36 -177.4(2) . . . . ? O4 Ag2 O2 C36 -46.2(2) . . . . ? O5 Ag2 O2 C36 75.0(3) 3_566 . . . ? Ag4 Ag2 O2 C36 -178.0(2) . . . . ? Ag1 Ag2 O2 C36 -119.1(2) . . . . ? Ag3 Ag2 O2 C36 -52.8(3) . . . . ? Ag3 Ag2 O2 C36 32.0(2) 3_566 . . . ? Ag4' Ag2 O2 C36 177.9(2) . . . . ? C1 Ag2 O4 C38 -38.6(3) . . . . ? O2 Ag2 O4 C38 173.1(3) . . . . ? O5 Ag2 O4 C38 81.0(3) 3_566 . . . ? Ag4 Ag2 O4 C38 -101.9(2) . . . . ? Ag1 Ag2 O4 C38 -70.1(2) . . . . ? Ag3 Ag2 O4 C38 -9.6(2) . . . . ? Ag3 Ag2 O4 C38 97.4(3) 3_566 . . . ? Ag4' Ag2 O4 C38 -90.7(3) . . . . ? O3 Ag3 O5 C38 -171.3(2) 3_566 . . . ? O7 Ag3 O5 C38 104.7(2) . . . . ? C1 Ag3 O5 C38 -23.2(2) . . . . ? C2 Ag3 O5 C38 -36.6(3) . . . . ? Ag1 Ag3 O5 C38 22.2(2) . . . . ? Ag2 Ag3 O5 C38 -34.93(19) . . . . ? Ag2 Ag3 O5 C38 -116.0(2) 3_566 . . . ? O3 Ag3 O5 Ag2 -55.30(9) 3_566 . . 3_566 ? O7 Ag3 O5 Ag2 -139.36(7) . . . 3_566 ? C1 Ag3 O5 Ag2 92.73(10) . . . 3_566 ? C2 Ag3 O5 Ag2 79.40(17) . . . 3_566 ? Ag1 Ag3 O5 Ag2 138.20(3) . . . 3_566 ? Ag2 Ag3 O5 Ag2 81.04(4) . . . 3_566 ? N1 Ag1 O6 C40 -174.7(2) . . . . ? C1 Ag1 O6 C40 30.1(3) . . . . ? N2 Ag1 O6 C40 -102.8(2) . . . . ? Ag2 Ag1 O6 C40 84.0(2) . . . . ? Ag3 Ag1 O6 C40 36.1(2) . . . . ? Ag4' Ag1 O6 C40 9.1(5) . . . . ? O3 Ag3 O7 C40 179.7(2) 3_566 . . . ? C1 Ag3 O7 C40 65.8(2) . . . . ? O5 Ag3 O7 C40 -61.1(2) . . . . ? C2 Ag3 O7 C40 97.5(2) . . . . ? Ag1 Ag3 O7 C40 34.61(19) . . . . ? Ag2 Ag3 O7 C40 4.5(2) . . . . ? Ag2 Ag3 O7 C40 -98.6(2) 3_566 . . . ? N4 Ag4' C1 C2 -39.6(5) . . . . ? N3 Ag4' C1 C2 177.4(2) . . . . ? Ag1 Ag4' C1 C2 -127.7(3) . . . . ? Ag2 Ag4' C1 C2 153.5(3) . . . . ? N4 Ag4' C1 Ag4 144.2(5) . . . . ? N3 Ag4' C1 Ag4 1.17(16) . . . . ? C2 Ag4' C1 Ag4 -176.2(3) . . . . ? Ag1 Ag4' C1 Ag4 56.1(2) . . . . ? Ag2 Ag4' C1 Ag4 -22.7(2) . . . . ? N4 Ag4' C1 Ag2 166.9(3) . . . . ? N3 Ag4' C1 Ag2 23.9(2) . . . . ? C2 Ag4' C1 Ag2 -153.5(3) . . . . ? Ag1 Ag4' C1 Ag2 78.78(10) . . . . ? N4 Ag4' C1 Ag1 88.1(3) . . . . ? N3 Ag4' C1 Ag1 -54.9(2) . . . . ? C2 Ag4' C1 Ag1 127.7(3) . . . . ? Ag2 Ag4' C1 Ag1 -78.78(10) . . . . ? N4 Ag4' C1 Ag3 90.1(7) . . . . ? N3 Ag4' C1 Ag3 -52.9(6) . . . . ? C2 Ag4' C1 Ag3 129.7(7) . . . . ? Ag1 Ag4' C1 Ag3 2.0(5) . . . . ? Ag2 Ag4' C1 Ag3 -76.8(5) . . . . ? N3 Ag4 C1 C2 178.9(3) . . . . ? N4 Ag4 C1 C2 -22.2(3) . . . . ? Ag2 Ag4 C1 C2 152.7(3) . . . . ? Ag1 Ag4 C1 C2 -126.3(3) . . . . ? N3 Ag4 C1 Ag4' -176.9(4) . . . . ? N4 Ag4 C1 Ag4' -18.0(2) . . . . ? Ag2 Ag4 C1 Ag4' 157.0(2) . . . . ? Ag1 Ag4 C1 Ag4' -122.0(2) . . . . ? N3 Ag4 C1 Ag2 26.1(4) . . . . ? N4 Ag4 C1 Ag2 -174.98(8) . . . . ? Ag1 Ag4 C1 Ag2 80.99(8) . . . . ? N3 Ag4 C1 Ag1 -54.9(4) . . . . ? N4 Ag4 C1 Ag1 104.02(11) . . . . ? Ag2 Ag4 C1 Ag1 -80.99(8) . . . . ? N3 Ag4 C1 Ag3 -27.1(6) . . . . ? N4 Ag4 C1 Ag3 131.8(3) . . . . ? Ag2 Ag4 C1 Ag3 -53.2(3) . . . . ? Ag1 Ag4 C1 Ag3 27.8(2) . . . . ? O2 Ag2 C1 C2 -133.9(5) . . . . ? O4 Ag2 C1 C2 108.0(5) . . . . ? O5 Ag2 C1 C2 -24.6(5) 3_566 . . . ? Ag4 Ag2 C1 C2 -133.1(5) . . . . ? Ag1 Ag2 C1 C2 148.0(6) . . . . ? Ag3 Ag2 C1 C2 71.1(5) . . . . ? Ag3 Ag2 C1 C2 3.5(6) 3_566 . . . ? Ag4' Ag2 C1 C2 -127.0(6) . . . . ? O2 Ag2 C1 Ag4' -6.9(2) . . . . ? O4 Ag2 C1 Ag4' -125.03(12) . . . . ? O5 Ag2 C1 Ag4' 102.39(12) 3_566 . . . ? Ag4 Ag2 C1 Ag4' -6.15(7) . . . . ? Ag1 Ag2 C1 Ag4' -85.06(12) . . . . ? Ag3 Ag2 C1 Ag4' -161.95(16) . . . . ? Ag3 Ag2 C1 Ag4' 130.43(10) 3_566 . . . ? O2 Ag2 C1 Ag4 -0.7(2) . . . . ? O4 Ag2 C1 Ag4 -118.88(10) . . . . ? O5 Ag2 C1 Ag4 108.54(8) 3_566 . . . ? Ag1 Ag2 C1 Ag4 -78.91(8) . . . . ? Ag3 Ag2 C1 Ag4 -155.80(13) . . . . ? Ag3 Ag2 C1 Ag4 136.58(6) 3_566 . . . ? Ag4' Ag2 C1 Ag4 6.15(7) . . . . ? O2 Ag2 C1 Ag1 78.17(17) . . . . ? O4 Ag2 C1 Ag1 -39.96(13) . . . . ? O5 Ag2 C1 Ag1 -172.55(7) 3_566 . . . ? Ag4 Ag2 C1 Ag1 78.91(8) . . . . ? Ag3 Ag2 C1 Ag1 -76.89(8) . . . . ? Ag3 Ag2 C1 Ag1 -144.50(5) 3_566 . . . ? Ag4' Ag2 C1 Ag1 85.06(12) . . . . ? O2 Ag2 C1 Ag3 155.06(12) . . . . ? O4 Ag2 C1 Ag3 36.92(13) . . . . ? O5 Ag2 C1 Ag3 -95.66(8) 3_566 . . . ? Ag4 Ag2 C1 Ag3 155.80(13) . . . . ? Ag1 Ag2 C1 Ag3 76.89(8) . . . . ? Ag3 Ag2 C1 Ag3 -67.61(12) 3_566 . . . ? Ag4' Ag2 C1 Ag3 161.95(16) . . . . ? O6 Ag1 C1 C2 -68.0(4) . . . . ? N1 Ag1 C1 C2 144.5(3) . . . . ? N2 Ag1 C1 C2 66.7(3) . . . . ? Ag4 Ag1 C1 C2 118.9(4) . . . . ? Ag2 Ag1 C1 C2 -158.8(4) . . . . ? Ag3 Ag1 C1 C2 -75.1(3) . . . . ? Ag4' Ag1 C1 C2 105.5(4) . . . . ? O6 Ag1 C1 Ag4' -173.45(12) . . . . ? N1 Ag1 C1 Ag4' 39.01(18) . . . . ? N2 Ag1 C1 Ag4' -38.80(15) . . . . ? Ag4 Ag1 C1 Ag4' 13.43(8) . . . . ? Ag2 Ag1 C1 Ag4' 95.70(14) . . . . ? Ag3 Ag1 C1 Ag4' 179.36(16) . . . . ? O6 Ag1 C1 Ag4 173.12(7) . . . . ? N1 Ag1 C1 Ag4 25.58(15) . . . . ? N2 Ag1 C1 Ag4 -52.23(11) . . . . ? Ag2 Ag1 C1 Ag4 82.27(9) . . . . ? Ag3 Ag1 C1 Ag4 165.93(13) . . . . ? Ag4' Ag1 C1 Ag4 -13.43(8) . . . . ? O6 Ag1 C1 Ag2 90.85(11) . . . . ? N1 Ag1 C1 Ag2 -56.69(14) . . . . ? N2 Ag1 C1 Ag2 -134.49(8) . . . . ? Ag4 Ag1 C1 Ag2 -82.27(9) . . . . ? Ag3 Ag1 C1 Ag2 83.66(9) . . . . ? Ag4' Ag1 C1 Ag2 -95.70(14) . . . . ? O6 Ag1 C1 Ag3 7.19(13) . . . . ? N1 Ag1 C1 Ag3 -140.35(9) . . . . ? N2 Ag1 C1 Ag3 141.85(8) . . . . ? Ag4 Ag1 C1 Ag3 -165.93(13) . . . . ? Ag2 Ag1 C1 Ag3 -83.66(9) . . . . ? Ag4' Ag1 C1 Ag3 -179.36(16) . . . . ? O3 Ag3 C1 C2 -14.8(2) 3_566 . . . ? O7 Ag3 C1 C2 88.9(2) . . . . ? O5 Ag3 C1 C2 -165.2(2) . . . . ? Ag1 Ag3 C1 C2 129.8(3) . . . . ? Ag2 Ag3 C1 C2 -149.2(3) . . . . ? Ag2 Ag3 C1 C2 -105.5(2) 3_566 . . . ? O3 Ag3 C1 Ag4' -146.6(6) 3_566 . . . ? O7 Ag3 C1 Ag4' -43.0(6) . . . . ? O5 Ag3 C1 Ag4' 62.9(6) . . . . ? C2 Ag3 C1 Ag4' -131.9(7) . . . . ? Ag1 Ag3 C1 Ag4' -2.0(5) . . . . ? Ag2 Ag3 C1 Ag4' 79.0(6) . . . . ? Ag2 Ag3 C1 Ag4' 122.6(6) 3_566 . . . ? O3 Ag3 C1 Ag4 -172.6(3) 3_566 . . . ? O7 Ag3 C1 Ag4 -68.9(3) . . . . ? O5 Ag3 C1 Ag4 37.0(3) . . . . ? C2 Ag3 C1 Ag4 -157.8(5) . . . . ? Ag1 Ag3 C1 Ag4 -28.0(2) . . . . ? Ag2 Ag3 C1 Ag4 53.0(3) . . . . ? Ag2 Ag3 C1 Ag4 96.7(3) 3_566 . . . ? O3 Ag3 C1 Ag2 134.40(8) 3_566 . . . ? O7 Ag3 C1 Ag2 -121.93(9) . . . . ? O5 Ag3 C1 Ag2 -16.00(13) . . . . ? C2 Ag3 C1 Ag2 149.2(3) . . . . ? Ag1 Ag3 C1 Ag2 -81.00(8) . . . . ? Ag2 Ag3 C1 Ag2 43.67(9) 3_566 . . . ? O3 Ag3 C1 Ag1 -144.61(7) 3_566 . . . ? O7 Ag3 C1 Ag1 -40.93(12) . . . . ? O5 Ag3 C1 Ag1 64.99(11) . . . . ? C2 Ag3 C1 Ag1 -129.8(3) . . . . ? Ag2 Ag3 C1 Ag1 81.00(8) . . . . ? Ag2 Ag3 C1 Ag1 124.66(5) 3_566 . . . ? Ag4 C1 C2 Ag4' 1.20(10) . . . . ? Ag2 C1 C2 Ag4' 124.6(6) . . . . ? Ag1 C1 C2 Ag4' -96.4(3) . . . . ? Ag3 C1 C2 Ag4' -166.0(2) . . . . ? Ag4' C1 C2 Ag3 166.0(2) . . . . ? Ag4 C1 C2 Ag3 167.2(3) . . . . ? Ag2 C1 C2 Ag3 -69.4(4) . . . . ? Ag1 C1 C2 Ag3 69.6(2) . . . . ? N4 Ag4' C2 C1 156.3(3) . . . . ? N3 Ag4' C2 C1 -5.7(5) . . . . ? Ag1 Ag4' C2 C1 41.2(2) . . . . ? Ag2 Ag4' C2 C1 -19.6(2) . . . . ? C1 Ag4' C2 C3 -178.6(5) . . . . ? N4 Ag4' C2 C3 -22.3(4) . . . . ? N3 Ag4' C2 C3 175.7(4) . . . . ? Ag1 Ag4' C2 C3 -137.4(3) . . . . ? Ag2 Ag4' C2 C3 161.8(3) . . . . ? C1 Ag4' C2 Ag3 -14.0(2) . . . . ? N4 Ag4' C2 Ag3 142.35(16) . . . . ? N3 Ag4' C2 Ag3 -19.7(5) . . . . ? Ag1 Ag4' C2 Ag3 27.24(10) . . . . ? Ag2 Ag4' C2 Ag3 -33.58(10) . . . . ? O3 Ag3 C2 C1 166.0(2) 3_566 . . . ? O7 Ag3 C2 C1 -108.9(2) . . . . ? O5 Ag3 C2 C1 24.9(3) . . . . ? Ag1 Ag3 C2 C1 -39.6(2) . . . . ? Ag2 Ag3 C2 C1 23.2(2) . . . . ? Ag2 Ag3 C2 C1 86.5(2) 3_566 . . . ? O3 Ag3 C2 C3 -15.7(3) 3_566 . . . ? O7 Ag3 C2 C3 69.3(3) . . . . ? C1 Ag3 C2 C3 178.2(4) . . . . ? O5 Ag3 C2 C3 -156.9(2) . . . . ? Ag1 Ag3 C2 C3 138.6(3) . . . . ? Ag2 Ag3 C2 C3 -158.6(3) . . . . ? Ag2 Ag3 C2 C3 -95.3(3) 3_566 . . . ? O3 Ag3 C2 Ag4' 177.63(14) 3_566 . . . ? O7 Ag3 C2 Ag4' -97.30(14) . . . . ? C1 Ag3 C2 Ag4' 11.61(18) . . . . ? O5 Ag3 C2 Ag4' 36.5(2) . . . . ? Ag1 Ag3 C2 Ag4' -28.00(10) . . . . ? Ag2 Ag3 C2 Ag4' 34.77(11) . . . . ? Ag2 Ag3 C2 Ag4' 98.10(12) 3_566 . . . ? C4 O1 C3 C2 71.9(4) . . . . ? Ag4' C2 C3 O1 47.3(5) . . . . ? Ag3 C2 C3 O1 -117.0(3) . . . . ? C3 O1 C4 C9 -2.2(5) . . . . ? C3 O1 C4 C5 178.9(3) . . . . ? O1 C4 C5 C6 176.1(3) . . . . ? C9 C4 C5 C6 -2.9(5) . . . . ? C4 C5 C6 C7 -0.7(5) . . . . ? C5 C6 C7 C8 3.0(5) . . . . ? C5 C6 C7 C10 -174.4(3) . . . . ? C6 C7 C8 C9 -1.9(5) . . . . ? C10 C7 C8 C9 175.6(3) . . . . ? O1 C4 C9 C8 -174.9(3) . . . . ? C5 C4 C9 C8 4.0(5) . . . . ? C7 C8 C9 C4 -1.6(5) . . . . ? C8 C7 C10 C15 24.9(5) . . . . ? C6 C7 C10 C15 -157.7(3) . . . . ? C8 C7 C10 C11 -152.9(3) . . . . ? C6 C7 C10 C11 24.4(5) . . . . ? C15 C10 C11 C12 -0.2(5) . . . . ? C7 C10 C11 C12 177.8(3) . . . . ? C10 C11 C12 C13 -0.4(6) . . . . ? C11 C12 C13 C14 0.0(6) . . . . ? C12 C13 C14 C15 1.0(7) . . . . ? C13 C14 C15 C10 -1.6(6) . . . . ? C11 C10 C15 C14 1.1(5) . . . . ? C7 C10 C15 C14 -176.8(3) . . . . ? C20 N1 C16 C17 1.0(5) . . . . ? Ag1 N1 C16 C17 177.9(2) . . . . ? N1 C16 C17 C18 -0.6(5) . . . . ? C16 C17 C18 C19 -0.1(5) . . . . ? C17 C18 C19 C20 0.2(5) . . . . ? C16 N1 C20 C19 -0.9(4) . . . . ? Ag1 N1 C20 C19 -177.9(2) . . . . ? C16 N1 C20 C21 179.6(3) . . . . ? Ag1 N1 C20 C21 2.7(3) . . . . ? C18 C19 C20 N1 0.3(5) . . . . ? C18 C19 C20 C21 179.8(3) . . . . ? C25 N2 C21 C22 0.1(4) . . . . ? Ag1 N2 C21 C22 -173.3(2) . . . . ? C25 N2 C21 C20 179.8(3) . . . . ? Ag1 N2 C21 C20 6.5(3) . . . . ? N1 C20 C21 N2 -6.1(4) . . . . ? C19 C20 C21 N2 174.4(3) . . . . ? N1 C20 C21 C22 173.7(3) . . . . ? C19 C20 C21 C22 -5.8(4) . . . . ? N2 C21 C22 C23 0.5(5) . . . . ? C20 C21 C22 C23 -179.3(3) . . . . ? C21 C22 C23 C24 -0.6(5) . . . . ? C22 C23 C24 C25 0.1(5) . . . . ? C21 N2 C25 C24 -0.6(5) . . . . ? Ag1 N2 C25 C24 172.3(2) . . . . ? C23 C24 C25 N2 0.5(5) . . . . ? C30 N3 C26 C27 -1.0(5) . . . . ? Ag4 N3 C26 C27 172.1(3) . . . . ? Ag4' N3 C26 C27 175.2(3) . . . . ? N3 C26 C27 C28 1.4(6) . . . . ? C26 C27 C28 C29 0.0(8) . . . . ? C27 C28 C29 C30 -1.8(9) . . . . ? C26 N3 C30 C29 -0.8(5) . . . . ? Ag4 N3 C30 C29 -174.1(3) . . . . ? Ag4' N3 C30 C29 -177.9(3) . . . . ? C26 N3 C30 C31 178.4(3) . . . . ? Ag4 N3 C30 C31 5.1(4) . . . . ? Ag4' N3 C30 C31 1.3(3) . . . . ? C28 C29 C30 N3 2.2(7) . . . . ? C28 C29 C30 C31 -177.0(4) . . . . ? C35 N4 C31 C32 -0.4(5) . . . . ? Ag4' N4 C31 C32 178.6(2) . . . . ? Ag4 N4 C31 C32 175.6(2) . . . . ? C35 N4 C31 C30 -179.0(3) . . . . ? Ag4' N4 C31 C30 -0.1(4) . . . . ? Ag4 N4 C31 C30 -3.0(3) . . . . ? N3 C30 C31 N4 -1.0(4) . . . . ? C29 C30 C31 N4 178.2(4) . . . . ? N3 C30 C31 C32 -179.7(3) . . . . ? C29 C30 C31 C32 -0.5(5) . . . . ? N4 C31 C32 C33 0.3(5) . . . . ? C30 C31 C32 C33 178.9(3) . . . . ? C31 C32 C33 C34 -0.3(5) . . . . ? C32 C33 C34 C35 0.3(5) . . . . ? C31 N4 C35 C34 0.4(5) . . . . ? Ag4' N4 C35 C34 -178.7(3) . . . . ? Ag4 N4 C35 C34 -174.9(3) . . . . ? C33 C34 C35 N4 -0.4(6) . . . . ? Ag3 O3 C36 O2 8.7(4) 3_566 . . . ? Ag3 O3 C36 C37 -170.9(2) 3_566 . . . ? Ag2 O2 C36 O3 -36.6(5) . . . . ? Ag2 O2 C36 C37 143.0(2) . . . . ? O3 C36 C37 F2 -125.7(3) . . . . ? O2 C36 C37 F2 54.6(4) . . . . ? O3 C36 C37 F1 -4.2(4) . . . . ? O2 C36 C37 F1 176.1(3) . . . . ? O3 C36 C37 F3 113.4(3) . . . . ? O2 C36 C37 F3 -66.3(4) . . . . ? Ag2 O4 C38 O5 -21.0(5) . . . . ? Ag2 O4 C38 C39 161.9(2) . . . . ? Ag3 O5 C38 O4 45.0(4) . . . . ? Ag2 O5 C38 O4 -42.7(4) 3_566 . . . ? Ag3 O5 C38 C39 -137.9(2) . . . . ? Ag2 O5 C38 C39 134.5(2) 3_566 . . . ? O4 C38 C39 F5 -160.1(3) . . . . ? O5 C38 C39 F5 22.3(4) . . . . ? O4 C38 C39 F4 -38.1(4) . . . . ? O5 C38 C39 F4 144.3(3) . . . . ? O4 C38 C39 F6 80.8(3) . . . . ? O5 C38 C39 F6 -96.8(3) . . . . ? Ag3 O7 C40 O6 -20.8(4) . . . . ? Ag3 O7 C40 C41 160.6(2) . . . . ? Ag1 O6 C40 O7 -17.9(5) . . . . ? Ag1 O6 C40 C41 160.7(2) . . . . ? O7 C40 C41 F9 -41.5(4) . . . . ? O6 C40 C41 F9 139.7(3) . . . . ? O7 C40 C41 F7 -165.0(3) . . . . ? O6 C40 C41 F7 16.1(4) . . . . ? O7 C40 C41 F8 76.9(3) . . . . ? O6 C40 C41 F8 -101.9(3) . . . . ? _diffrn_measured_fraction_theta_max 1.000 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 1.000 _refine_diff_density_max 0.506 _refine_diff_density_min -0.722 _refine_diff_density_rms 0.099