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{"sheet":"table ESI1","index":0,"n_rows":56,"n_cols":12,"rows_kept":56,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
["This journal is © The Owner Societies 1999. TABLE S1: Kinetics (Section a), Product Yields (Section b), Hydrolysis Yields (Section c) of the BrONO2/NaCl system"]
["Salt","Mass","Flow","Concentration","Dose","Orifice","kesc","kuni","g0",null,"Yields"]
["Type","[g]","[molec/s]","[molec/cm3]","[molec]","[mm]","[s-1]","[s-1]",null,"BrCl","Br2","HCl"]
[{"$nulls":5},"Section a"]
["Grain",6.1,910000000000000,202222222222.22223,null,14,2.5,20,0.4]
["Grain",6.1,1100000000000000,244444444444.44446,null,14,2.5,13,0.26]
["Grain",6.1,1200000000000000,266666666666.66666,null,14,2.5,30,0.59]
["Grain",12,1200000000000000,266666666666.66666,null,14,2.5,24,0.47]
["Grain",1.5,1300000000000000,288888888888.8889,null,14,2.5,21,0.46]
["Grain",2,1300000000000000,288888888888.8889,null,14,2.5,16,0.31]
["Grain",6.1,1300000000000000,288888888888.8889,null,14,2.5,18,0.35]
["Grain",4,1400000000000000,311111111111.1111,null,14,2.5,22,0.43]
["Grain",6,null,444444444444.44446,800000000000000,14,2.5,7,0.14]
["Grain",6.1,2400000000000000,533333333333.3333,null,14,2.5,19,0.37]
["Grain",6,2500000000000000,555555555555.5555,null,14,2.5,20,0.4]
["Grain",6.1,2600000000000000,577777777777.7778,null,14,2.5,16,0.32]
["Grain",6.1,3000000000000000,666666666666.6666,null,14,2.5,17,0.34]
["Grain",6.1,3700000000000000,822222222222.2222,null,14,2.5,14,0.28]
["Grain",8.1,"-","-",null,4,0.3,8.5,0.17]
["Grain",6,"-","-",null,14,2.5,13,0.26]
["Grain",8.1,"-","-",null,14,2.5,13,0.26]
["Powder a)",5,1400000000000000,311111111111.1111,null,14,2.5,15,0.3]
["Powder a)",10,"-","-",null,14,2.5,16.5,0.33]
["Powder a)",10,"-","-",null,14,2.5,16,0.32]
["Powder b)",5,1500000000000000,333333333333.3333,null,14,2.5,25,0.5]
["Thin Film",0.004,700000000000000,155555555555.55554,null,14,2.5,16,0.31]
["Thin Film",0.003,1400000000000000,311111111111.1111,null,14,2.5,18,0.36]
["Thin Film",0.007,"-","-",null,14,2.5,10.5,0.21]
["Thin Film",0.005,"-","-",null,14,2.5,23,0.46]
["Thin Film",0.003,"-","-",null,14,2.5,13.5,0.27]
["Thin Film",0.004,"-","-",null,14,2.5,15.5,0.31]
["Thin Film c)",0.008,950000000000000,211111111111.1111,null,14,2.5,20,0.4]
[{"$nulls":5},"Section b"]
["Grain",6,1100000000000000,509259259259.2593,null,8,1.2,14.5,0.29,1.1,0.03]
["Grain",6,4500000000000000,2083333333333.3333,null,8,1.2,19,0.38,0.92,0.08]
["Grain",6,1400000000000000,2592592592592.593,null,4,0.3,9.5,0.19,0.5,0.11]
["Grain",6,2500000000000000,4629629629629.63,null,4,0.3,8.5,0.17,0.45,0.05]
["Thin Film",0.002,1700000000000000,377777777777.7778,null,14,2.5,14,0.28,0.61,0.1]
["Thin Film c)",0.003,600000000000000,133333333333.33333,null,14,2.5,26,0.52,0.6,0.14]
["Thin Film c)",0.003,1700000000000000,377777777777.7778,null,14,2.5,9,0.18,0.65,0.2]
["Thin Film c)",0.003,1900000000000000,422222222222.2222,null,14,2.5,13,0.26,0.67,0.15]
[{"$nulls":5},"Section c"]
["Grain",7.5,1000000000000000,222222222222.22223,null,14,2.5,15,0.3,0.75,0.09,0.2]
["Grain",8,1200000000000000,266666666666.66666,null,14,2.5,10,0.2,0.84,0.03,0.2]
["Grain",8,1800000000000000,444444444444.44446,null,14,2.5,12.5,0.25,0.88,0.04,0.18]
["Grain",7.5,1100000000000000,509259259259.2593,null,8,1.2,10,0.2,1.1,0.03,0.21]
["Grain",8,1500000000000000,694444444444.4445,null,8,1.2,17,0.34,0.93,0.04,0.21]
["Grain",8,1900000000000000,879629629629.6296,null,8,1.2,14,0.28,1,0.03,0.25]
["Powder a)",6,null,261111111111.1111,470000000000000,14,2.5,15,0.3,0.45,0.06,0.22]
["Powder a)",6,null,611111111111.1111,1100000000000000,8,1.2,11,0.22,0.25,0.08,0.4]
["Window",null,1300000000000000,288888888888.8889,null,14,2.5,12.5,0.25,0.48,0.08,0.13]
["Window",null,1300000000000000,601851851851.8518,null,8,1.2,9.5,0.19,0.38,0.19,0.13]
["Window",null,2900000000000000,644444444444.4445,null,14,2.5,7.5,0.15,0.4,0.02,0.1]
["a) size of NaCl-particles between 36 and 100 mm"]
["b) size of NaCl-particles ≤ 36 mm"]
["c) after heating to 550 K"]

{"sheet":"table ESI2","index":1,"n_rows":11,"n_cols":9,"rows_kept":11,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
["TABLE S2: The heterogeneous interaction  of BrONO2 on non-reactive salts"]
["salt/type","mass","Flow","Orifice","kesc","kuni","g0","            Yields"]
[null,"[g]","[molecule/s]","[mm]","[s-1]","[s-1]",null,"Br2","BrCl"]
["NaNO3-grain",6.1,1100000000000000,14,2.5,19.5,0.39,0.35,0.04]
["NaNO3-grain",6.1,1200000000000000,14,2.5,19.5,0.39,0.3,0.01]
["NaNO3-grain",6,1000000000000000,14,2.5,26.5,0.53,0.43,"-"]
["NaNO3-grain",6,1400000000000000,14,2.5,12,0.24,0.38,"-"]
["NaNO3-grain",6,1900000000000000,14,2.5,10,0.2,0.35,"-"]
["NaNO3-grain",8,"-",14,2.5,10.5,0.21,"-","-"]
["Na2SO4-grain",6,2800000000000000,14,2.5,10.5,0.21]
["Na2SO4-grain",7,"-",14,2.5,10,0.2]

{"sheet":"table ESI3","index":2,"n_rows":40,"n_cols":11,"rows_kept":40,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
["TABLE S3: Kinetics (Section a), Product Yields (Section b),  Hydrolysis Yields (Section c) of BrONO2/KBr system"]
["Salt","Mass","Flow","Dose","Concentration","Orifice","kesc","kuni","g0","   Yields"]
["Type","[g]","[molec/s]","[molec]","[molec/cm3]","[mm]","[s-1]","[s-1]",null,"Br2","HBr"]
[{"$nulls":4},"Section a"]
["Grain",6,230000000000000,null,51111111111.111115,14,2.5,17,0.34]
["Grain",null,270000000000000,null,60000000000,14,2.5,12.5,0.25]
["Grain",8,"-",null,"-",14,2.5,25,0.5]
["Grain",7,"-",null,"-",14,2.5,15.5,0.31]
["Single Crystal",null,1300000000000000,null,288888888888.8889,14,2.5,10,0.2]
[{"$nulls":4},"Section b"]
["Grain",6,400000000000000,null,88888888888.88889,14,2.5,16,0.32,0.7]
["Grain",6,540000000000000,null,120000000000,14,2.5,20,0.4,0.72]
["Grain",6,640000000000000,null,142222222222.22223,14,2.5,24,0.48,0.66]
["Grain",6,1100000000000000,null,244444444444.44446,14,2.5,21,0.42,0.47]
["Grain",6,650000000000000,null,300925925925.9259,8,1.2,13,0.25,0.59]
["Grain",6,1500000000000000,null,333333333333.3333,14,2.5,19,0.38,0.6]
["Grain",6,1700000000000000,null,377777777777.7778,14,2.5,25,0.5,0.56]
["Grain",6,1150000000000000,null,532407407407.4074,8,1.2,15,0.3,0.56]
["Grain",6,1900000000000000,null,879629629629.6296,8,1.2,22,0.44,0.5]
["Grain",6,null,7300000000000000,4055555555555.5557,14,2.5,13.5,0.27,0.5]
["Grain",6,null,1.1e+16,6111111111111.111,14,2.5,18,0.36,0.51]
["Grain",6,null,1.2e+16,6666666666666.667,14,2.5,19,0.38,0.52]
["Grain",6,null,1.4e+16,7777777777777.777,8,1.2,21.5,0.43,0.45]
["Grain",6,null,2.4e+16,13333333333333.334,8,1.2,14.5,0.29,0.4]
["Grain",6,null,3e+16,16666666666666.666,8,1.2,12.5,0.25,0.61]
["Grain",6,null,3e+16,16666666666666.666,8,1.2,11.5,0.23,0.5]
["Thin Film",0.006,620000000000000,null,137777777777.77777,14,2.5,15,0.3,0.75]
["Thin Film",0.003,null,3600000000000000,2000000000000,14,2.5,12,0.24,0.3]
["Thin Film a)",0.006,660000000000000,null,146666666666.66666,14,2.5,17.5,0.35,0.3]
[{"$nulls":4},"Section c"]
["Grain",10,900000000000000,null,200000000000,14,2.5,15,0.3,0.7,0.11]
["Grain",8.1,null,530000000000000,294444444444.44446,14,2.5,8,0.16,0.4,"n. o."]
["Grain",10,1500000000000000,null,333333333333.3333,14,2.5,20.5,0.41,0.66,0.1]
["Grain",7,2200000000000000,null,488888888888.8889,14,2.5,18.5,0.37,0.5,0.04]
["Grain",10,2600000000000000,null,577777777777.7778,14,2.5,14,0.28,0.6,0.06]
["Grain",7,1400000000000000,null,648148148148.1482,8,1.2,10.5,0.21,0.84,0.11]
["Grain",10,2100000000000000,null,1555555555555.5557,14,2.5,10,0.2,0.52,0.05]
["Thin Film",0.007,1600000000000000,null,355555555555.55554,14,2.5,14,0.28,0.5,0.1]
["Thin Film a)",0.006,1600000000000000,null,355555555555.55554,14,2.5,11,0.22,0.52,0.11]
["a) after heating up to 550 K"]

{"sheet":"table ESI4","index":3,"n_rows":35,"n_cols":12,"rows_kept":35,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
["TABLE S4: Results from steady-state experiments of ClONO2 interacting with NaCl and KBr"]
["salt/type","mass","Flow","Concentration","Dose","Orifice","kesc","kuni","g0",null,"Yields"]
[null,"[g]","[molec/s]","[molec/cm3]","[molec]","[mm]","[s-1]","[s-1]",null,"Cl2","HCl"]
["NaCl-grain",10,null,202222222222.22223,364000000000000,4,0.5,2.6,0.04,1.2,0.208]
["NaCl-grain",7,241800000000000,268666666666.66666,null,4,0.5,2.8,0.04,0.9,"n.d."]
["NaCl-grain",10,null,274444444444.44446,494000000000000,4,0.5,7.2,0.10588235294117647,1.14,0.2]
["NaCl-powder [1]",6,683800000000000,759777777777.7778,null,4,0.5,6.8,0.1,0.95,"n.d."]
["NaCl-grain",10,null,902777777777.7778,1625000000000000,4,0.5,2.6,0.03823529411764706,1.15,0.24]
["NaCl-grain",7,884000000000000,982222222222.2222,null,4,0.5,4.1,0.06,1.05,"n.d."]
["NaCl-grain",7,1300000000000000,1444444444444.4443,null,4,0.5,3.4000000000000004,0.05,1,"n.d."]
["NaCl-powder [1]",6,350000000000000,129629629629.62962,null,8,1.5,10.2,0.15,1.1,"n.d."]
["NaCl-powder [1]",6,495000000000000,91666666666.66667,null,14,3,20.4,0.3,0.8,"n.d."]
[{"$nulls":9},"Br2","Cl2","BrCl"]
["KBr-powder [2]",5.5,143000000000000,158888888888.8889,null,4,0.5,5.1,0.075,1.05,"n.o.","n.o."]
["KBr-powder [2]",5.5,260000000000000,288888888888.8889,null,4,0.5,6.5280000000000005,0.096,1.1,"n.o.","n.o."]
["KBr-powder [2]",5.5,442000000000000,491111111111.1111,null,4,0.5,5.44,0.08,0.8,"n.o.","n.o."]
["KBr-powder [2]",5.5,850000000000000,944444444444.4445,null,4,0.5,8.16,0.12,0.71,"n.o.",0.06]
["KBr-powder [2]",5.5,2080000000000000,2311111111111.1113,null,4,0.5,7.48,0.11,0.5,0.2,0.06]
["KBr-powder [2]",5.5,2500000000000000,2777777777777.778,null,4,0.5,8.84,0.13,0.35,0.4,0.15]
["KBr-powder [2]",5.5,2600000000000000,2888888888888.8887,null,4,0.5,8.84,0.13,0.44,0.34,0.14]
["KBr-powder [2]",5.5,221250000000000,81944444444.44444,null,8,1.5,12.24,0.18,0.64,0.19,0.08]
["KBr-powder [2]",5.5,312500000000000,115740740740.74074,null,8,1.5,17.408,0.256,0.66,"n.o.",0.12]
["KBr-powder [2]",5.5,800000000000000,296296296296.2963,null,8,1.5,14.96,0.22,0.5,0.22,0.15]
["KBr-powder [2]",5.5,1875000000000000,694444444444.4445,null,8,1.5,11.56,0.17,0.4,0.48,0.24]
["KBr-powder [2]",5.5,2300000000000000,851851851851.8518,null,8,1.5,14.28,0.21,0.37,0.4,0.21]
["KBr-powder [2]",5.5,84329500000000,15616574074.074074,null,14,3,12.24,0.18,0.6,0.15,0.17]
["KBr-powder [2]",5.5,410648000000000,76045925925.92592,null,14,3,15.64,0.23,0.52,0.18,0.24]
["KBr-powder [2]",5.5,439980000000000,81477777777.77777,null,14,3,21.08,0.31,0.46,"n.o.",0.13]
["KBr-powder [2]",5.5,1010000000000000,187037037037.03705,null,14,3,19.72,0.29,0.44,0.18,0.2]
["KBr-powder [2]",5.5,1466600000000000,271592592592.5926,null,14,3,14.96,0.22,0.37,0.17,0.28]
["KBr-powder [2]",5.5,2770000000000000,512962962962.96295,null,14,3,17,0.25,0.35,0.2,0.26]
["[1] NaCl-powder of average size range 35-160 mm"]
["[2] KBr-powder of average size range 160-250 mm"]
["n.d. = not determined"]
["n.o. = not observed"]

{"sheet":"table ESI5","index":4,"n_rows":15,"n_cols":10,"rows_kept":15,"cut":false,"hidden":false,"merged":[],"flags":["formulas_cached_only"]}
["TABLE S5: Results of steady-state experiments of ClONO2 interacting with non-reactive salts"]
["salt/type","mass","Flow","Concentration","Orifice","kesc","kuni","g0","        Yields"]
[null,"[g]","[molec/s]","[molec/cm3]","[mm]","[s-1]","[s-1]",null,"Cl2","HOCl"]
["Na2SO4-grain",7,500000000000000,555555555555.5555,4,0.5,4.76,0.07,0.22,"n.o."]
["Na2SO4-grain",7,800000000000000,148148148148.14816,14,3,19.72,0.29,0.25,"n.o."]
["Na2SO4-grain [1]",6,960000000000000,1066666666666.6666,4,0.5,6.8,0.1,0.33,0.12]
["Na2SO4-grain [1]",10,102000000000000,18888888888.88889,14,3,24.5,0.36,0.25,"n. d. "]
["Na2SO4-grain [1]",8,580000000000000,107407407407.40741,14,3,16.32,0.24,0.24,"n. d. "]
["Na2SO4-grain [1]",8,740000000000000,137037037037.03703,14,3,12.24,0.18,0.3,"n. d. "]
["Na2SO4-grain [1]",6,800000000000000,148148148148.14816,14,3,25.84,0.38,0.35,0.1]
["NaNO3-powder",6,180000000000000,33333333333.333332,14,3,25.16,0.37,"n. o. ","n. o. "]
["NaNO3-powder",15,320000000000000,59259259259.25926,14,3,11.56,0.17,"n. o.","n. o."]
["NaNO3-powder [1]",7,1200000000000000,1333333333333.3333,4,0.5,1.36,0.02,0.3,"n. o."]
["NaNO3-powder [1]",12,450000000000000,83333333333.33333,14,3,16.32,0.24,0.21,"n. o."]
["[1] salt has been pumped for 5 minutes prior to experiment"]