# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_s
_database_code_depnum_ccdc_archive 'CCDC 1957959'
loop_
_audit_author_name
_audit_author_address
'Guangfan Zheng'
;SNNU
China
;
_audit_update_record             
;
2020-05-27 deposited with the CCDC.	2020-06-24 downloaded from the CCDC.
;
_audit_creation_date             2020-05-27
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C25 H28 N2 O Rh, Cl'
_chemical_formula_sum            'C25 H28 Cl N2 O Rh'
_chemical_formula_weight         510.85
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   11.9749(4)
_cell_length_b                   15.7608(5)
_cell_length_c                   23.8262(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     4496.8(2)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9710
_cell_measurement_temperature    153
_cell_measurement_theta_max      68.304
_cell_measurement_theta_min      3.362
_shelx_estimated_absorpt_T_max   0.216
_shelx_estimated_absorpt_T_min   0.120
_exptl_absorpt_coefficient_mu    7.375
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.5596
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.0945 before and 0.0605 after correction. The Ratio of minimum to maximum transmission is 0.7431. The λ/2 correction factor is Not present.'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic light red'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.509
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2096
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0405
_diffrn_reflns_av_unetI/netI     0.0133
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            76351
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.298
_diffrn_reflns_theta_min         3.710
_diffrn_ambient_temperature      153.02
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4050
_reflns_number_total             4120
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_refine_diff_density_max         0.402
_refine_diff_density_min         -0.714
_refine_diff_density_rms         0.064
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     373
_refine_ls_number_reflns         4120
_refine_ls_number_restraints     41
_refine_ls_R_factor_all          0.0241
_refine_ls_R_factor_gt           0.0237
_refine_ls_restrained_S_all      1.103
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0281P)²+4.3537P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0577
_refine_ls_wR_factor_ref         0.0580
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C1-C2 \\sim C1A-C2A
 with sigma of 0.02
 C1-C3 \\sim C1A-C3A
 with sigma of 0.02
 C1-C7 \\sim C1A-C7A
 with sigma of 0.02
 C2-C4 \\sim C2A-C4A
 with sigma of 0.02
 C2-C8 \\sim C2A-C8A
 with sigma of 0.02
 C3-C5 \\sim C3A-C5A
 with sigma of 0.02
 C3-C6 \\sim C3A-C6A
 with sigma of 0.02
 C4-C5 \\sim C4A-C5A
 with sigma of 0.02
 C4-C10 \\sim C4A-C10A
 with sigma of 0.02
 C5-C9 \\sim C5A-C9A
 with sigma of 0.02
 Rh01-C1 \\sim Rh01-C1A
 with sigma of 0.04
 Rh01-C2 \\sim Rh01-C2A
 with sigma of 0.04
 Rh01-C3 \\sim Rh01-C3A
 with sigma of 0.04
 Rh01-C4 \\sim Rh01-C4A
 with sigma of 0.04
 Rh01-C5 \\sim Rh01-C5A
 with sigma of 0.04
 Rh01-C6 \\sim Rh01-C6A
 with sigma of 0.04
 Rh01-C7 \\sim Rh01-C7A
 with sigma of 0.04
 Rh01-C8 \\sim Rh01-C8A
 with sigma of 0.04
 Rh01-C9 \\sim Rh01-C9A
 with sigma of 0.04
 Rh01-C10 \\sim Rh01-C10A
 with sigma of 0.04
 C1-C4 \\sim C1A-C4A
 with sigma of 0.04
 C1-C5 \\sim C1A-C5A
 with sigma of 0.04
 C1-C6 \\sim C1A-C6A
 with sigma of 0.04
 C1-C8 \\sim C1A-C8A
 with sigma of 0.04
 C2-C3 \\sim C2A-C3A
 with sigma of 0.04
 C2-C5 \\sim C2A-C5A
 with sigma of 0.04
 C2-C7 \\sim C2A-C7A
 with sigma of 0.04
 C2-C10 \\sim C2A-C10A
 with sigma of 0.04
 C3-C4 \\sim C3A-C4A
 with sigma of 0.04
 C3-C7 \\sim C3A-C7A
 with sigma of 0.04
 C3-C9 \\sim C3A-C9A
 with sigma of 0.04
 C4-C8 \\sim C4A-C8A
 with sigma of 0.04
 C4-C9 \\sim C4A-C9A
 with sigma of 0.04
 C5-C6 \\sim C5A-C6A
 with sigma of 0.04
 C5-C10 \\sim C5A-C10A
 with sigma of 0.04
3. Uiso/Uaniso restraints and constraints
Uanis(C9A) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
4. Others
 Sof(C10A)=Sof(H10D)=Sof(H10E)=Sof(H10F)=Sof(C4A)=Sof(C2A)=Sof(C1A)=Sof(C3A)=
 Sof(C5A)=Sof(C9A)=Sof(H9AA)=Sof(H9AB)=Sof(H9AC)=Sof(C6A)=Sof(H6AA)=Sof(H6AB)=
 Sof(H6AC)=Sof(C7A)=Sof(H7AA)=Sof(H7AB)=Sof(H7AC)=Sof(C8A)=Sof(H8AA)=Sof(H8AB)=
 Sof(H8AC)=1-FVAR(1)
 Sof(C1)=Sof(C2)=Sof(C3)=Sof(C4)=Sof(C5)=Sof(C6)=Sof(H6A)=Sof(H6B)=Sof(H6C)=
 Sof(C7)=Sof(H7A)=Sof(H7B)=Sof(H7C)=Sof(C8)=Sof(H8A)=Sof(H8B)=Sof(H8C)=Sof(C9)=
 Sof(H9A)=Sof(H9B)=Sof(H9C)=Sof(C10)=Sof(H10A)=Sof(H10B)=Sof(H10C)=FVAR(1)
5.a Secondary CH2 refined with riding coordinates:
 C00B(H00B,H00A)
5.b Aromatic/amide H refined with riding coordinates:
 C008(H008), C00C(H00C), C00D(H00D), C00E(H00E), C00H(H00I), C00I(H00J),
 C00J(H00K), C00K(H00L)
5.c Idealised Me refined as rotating group:
 C00G(H00F,H00G,H00H), C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C),
 C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C10A(H10D,H10E,H10F), C9A(H9AA,H9AB,
 H9AC), C6A(H6AA,H6AB,H6AC), C7A(H7AA,H7AB,H7AC), C8A(H8AA,H8AB,H8AC)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh01 Rh 0.73695(2) 0.41924(2) 0.40959(2) 0.01501(6) Uani 1 1 d D . . . .
Cl02 Cl 0.87381(4) 0.33423(3) 0.45832(2) 0.02982(12) Uani 1 1 d . . . . .
O003 O 0.76219(13) 0.55358(9) 0.21630(6) 0.0270(3) Uani 1 1 d . . . . .
N004 N 0.87098(13) 0.48669(10) 0.37415(7) 0.0192(3) Uani 1 1 d . . . . .
N005 N 0.81506(13) 0.45462(9) 0.28323(6) 0.0161(3) Uani 1 1 d . . . . .
C006 C 0.87628(15) 0.50682(12) 0.31944(8) 0.0183(4) Uani 1 1 d . . . . .
C007 C 0.76210(14) 0.33287(11) 0.23660(8) 0.0154(4) Uani 1 1 d . . . . .
C008 C 0.69671(17) 0.24203(13) 0.16385(8) 0.0226(4) Uani 1 1 d . . . . .
H008 H 0.6841 0.1866 0.1495 0.027 Uiso 1 1 calc R . . . .
C009 C 0.73526(15) 0.40214(13) 0.20346(8) 0.0161(4) Uani 1 1 d . . . . .
C00A C 0.81098(15) 0.35999(11) 0.29205(7) 0.0151(4) Uani 1 1 d . . . . .
C00B C 0.73374(17) 0.33673(12) 0.34103(9) 0.0201(4) Uani 1 1 d . . . . .
H00B H 0.7540 0.2793 0.3543 0.024 Uiso 1 1 calc R . . . .
H00A H 0.6562 0.3339 0.3267 0.024 Uiso 1 1 calc R . . . .
C00C C 0.74191(15) 0.25135(13) 0.21720(8) 0.0192(4) Uani 1 1 d . . . . .
H00C H 0.7585 0.2033 0.2397 0.023 Uiso 1 1 calc R . . . .
C00D C 0.66945(17) 0.31227(14) 0.13090(8) 0.0240(4) Uani 1 1 d . . . . .
H00D H 0.6382 0.3042 0.0946 0.029 Uiso 1 1 calc R . . . .
C00E C 0.68786(16) 0.39365(13) 0.15084(8) 0.0210(4) Uani 1 1 d . . . . .
H00E H 0.6686 0.4420 0.1291 0.025 Uiso 1 1 calc R . . . .
C00F C 0.76997(15) 0.48066(12) 0.23268(8) 0.0178(4) Uani 1 1 d . . . . .
C00G C 0.92845(17) 0.32499(13) 0.30073(9) 0.0245(4) Uani 1 1 d . . . . .
H00F H 0.9786 0.3487 0.2723 0.037 Uiso 1 1 calc GR . . . .
H00G H 0.9270 0.2630 0.2973 0.037 Uiso 1 1 calc GR . . . .
H00H H 0.9552 0.3407 0.3382 0.037 Uiso 1 1 calc GR . . . .
C00H C 0.94306(19) 0.57265(13) 0.29989(9) 0.0278(5) Uani 1 1 d . . . . .
H00I H 0.9434 0.5873 0.2612 0.033 Uiso 1 1 calc R . . . .
C00I C 0.93919(18) 0.52850(14) 0.41012(9) 0.0261(5) Uani 1 1 d . . . . .
H00J H 0.9392 0.5121 0.4485 0.031 Uiso 1 1 calc R . . . .
C00J C 1.00895(19) 0.61649(14) 0.33766(10) 0.0340(5) Uani 1 1 d . . . . .
H00K H 1.0544 0.6622 0.3253 0.041 Uiso 1 1 calc R . . . .
C00K C 1.00820(19) 0.59327(14) 0.39374(10) 0.0316(5) Uani 1 1 d . . . . .
H00L H 1.0544 0.6216 0.4202 0.038 Uiso 1 1 calc R . . . .
C1 C 0.5825(9) 0.4820(6) 0.3930(3) 0.0204(18) Uani 0.575(4) 1 d D . P A 1
C2 C 0.6424(6) 0.5327(3) 0.4332(4) 0.0248(16) Uani 0.575(4) 1 d D . P A 1
C3 C 0.5545(4) 0.4030(5) 0.4200(3) 0.0216(12) Uani 0.575(4) 1 d D . P A 1
C4 C 0.6587(6) 0.4850(6) 0.4824(3) 0.0236(18) Uani 0.575(4) 1 d D . P A 1
C5 C 0.6074(5) 0.4033(6) 0.4731(3) 0.0224(12) Uani 0.575(4) 1 d D . P A 1
C6 C 0.4825(3) 0.3332(3) 0.3976(2) 0.0428(12) Uani 0.575(4) 1 d D . P A 1
H6A H 0.4778 0.3377 0.3567 0.064 Uiso 0.575(4) 1 calc GR . P A 1
H6B H 0.4075 0.3378 0.4138 0.064 Uiso 0.575(4) 1 calc GR . P A 1
H6C H 0.5150 0.2782 0.4078 0.064 Uiso 0.575(4) 1 calc GR . P A 1
C7 C 0.5379(4) 0.5112(4) 0.33734(18) 0.0458(13) Uani 0.575(4) 1 d D . P A 1
H7A H 0.5878 0.5545 0.3217 0.069 Uiso 0.575(4) 1 calc GR . P A 1
H7B H 0.4632 0.5354 0.3425 0.069 Uiso 0.575(4) 1 calc GR . P A 1
H7C H 0.5336 0.4629 0.3115 0.069 Uiso 0.575(4) 1 calc GR . P A 1
C8 C 0.6825(4) 0.6211(3) 0.4220(3) 0.0535(15) Uani 0.575(4) 1 d D . P A 1
H8A H 0.7421 0.6355 0.4486 0.080 Uiso 0.575(4) 1 calc GR . P A 1
H8B H 0.6204 0.6610 0.4265 0.080 Uiso 0.575(4) 1 calc GR . P A 1
H8C H 0.7113 0.6247 0.3836 0.080 Uiso 0.575(4) 1 calc GR . P A 1
C9 C 0.6047(4) 0.3332(3) 0.5159(2) 0.0527(15) Uani 0.575(4) 1 d D . P A 1
H9A H 0.5692 0.2830 0.4995 0.079 Uiso 0.575(4) 1 calc GR . P A 1
H9B H 0.5619 0.3518 0.5487 0.079 Uiso 0.575(4) 1 calc GR . P A 1
H9C H 0.6811 0.3192 0.5273 0.079 Uiso 0.575(4) 1 calc GR . P A 1
C10 C 0.7189(4) 0.5106(4) 0.53461(19) 0.0556(16) Uani 0.575(4) 1 d D . P A 1
H10A H 0.7733 0.4666 0.5446 0.083 Uiso 0.575(4) 1 calc GR . P A 1
H10B H 0.6651 0.5174 0.5653 0.083 Uiso 0.575(4) 1 calc GR . P A 1
H10C H 0.7579 0.5644 0.5282 0.083 Uiso 0.575(4) 1 calc GR . P A 1
C10A C 0.7341(5) 0.5991(5) 0.4946(3) 0.052(2) Uani 0.425(4) 1 d D . P A 2
H10D H 0.7796 0.5756 0.5250 0.078 Uiso 0.425(4) 1 calc GR . P A 2
H10E H 0.6809 0.6402 0.5100 0.078 Uiso 0.425(4) 1 calc GR . P A 2
H10F H 0.7827 0.6274 0.4673 0.078 Uiso 0.425(4) 1 calc GR . P A 2
C4A C 0.6713(6) 0.5284(6) 0.4660(4) 0.0219(14) Uani 0.425(4) 1 d D . P A 2
C2A C 0.6308(9) 0.5313(6) 0.4094(4) 0.0213(19) Uani 0.425(4) 1 d D . P A 2
C1A C 0.5667(11) 0.4566(8) 0.3987(5) 0.019(3) Uani 0.425(4) 1 d D . P A 2
C3A C 0.5782(7) 0.4019(4) 0.4459(5) 0.0245(18) Uani 0.425(4) 1 d D . P A 2
C5A C 0.6408(10) 0.4480(8) 0.4877(4) 0.026(2) Uani 0.425(4) 1 d D . P A 2
C9A C 0.6681(7) 0.4155(5) 0.5455(2) 0.057(2) Uani 0.425(4) 1 d D U P A 2
H9AA H 0.7038 0.3597 0.5424 0.086 Uiso 0.425(4) 1 calc GR . P A 2
H9AB H 0.5992 0.4104 0.5674 0.086 Uiso 0.425(4) 1 calc GR . P A 2
H9AC H 0.7190 0.4551 0.5642 0.086 Uiso 0.425(4) 1 calc GR . P A 2
C6A C 0.5244(6) 0.3167(4) 0.4544(4) 0.067(3) Uani 0.425(4) 1 d D . P A 2
H6AA H 0.5092 0.2908 0.4178 0.101 Uiso 0.425(4) 1 calc GR . P A 2
H6AB H 0.4543 0.3238 0.4750 0.101 Uiso 0.425(4) 1 calc GR . P A 2
H6AC H 0.5749 0.2800 0.4758 0.101 Uiso 0.425(4) 1 calc GR . P A 2
C7A C 0.4990(5) 0.4419(6) 0.3466(3) 0.053(2) Uani 0.425(4) 1 d D . P A 2
H7AA H 0.5438 0.4565 0.3135 0.080 Uiso 0.425(4) 1 calc GR . P A 2
H7AB H 0.4321 0.4776 0.3476 0.080 Uiso 0.425(4) 1 calc GR . P A 2
H7AC H 0.4770 0.3821 0.3446 0.080 Uiso 0.425(4) 1 calc GR . P A 2
C8A C 0.6409(6) 0.6062(4) 0.3706(3) 0.0465(18) Uani 0.425(4) 1 d D . P A 2
H8AA H 0.7152 0.6316 0.3747 0.070 Uiso 0.425(4) 1 calc GR . P A 2
H8AB H 0.5838 0.6483 0.3801 0.070 Uiso 0.425(4) 1 calc GR . P A 2
H8AC H 0.6305 0.5874 0.3317 0.070 Uiso 0.425(4) 1 calc GR . P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh01 N004 2.1021(16) . ?
Rh01 C00B 2.088(2) . ?
Rh01 C1 2.134(10) . ?
Rh01 C2 2.190(6) . ?
Rh01 C3 2.214(5) . ?
Rh01 C4 2.228(6) . ?
Rh01 C5 2.182(5) . ?
Rh01 C4A 2.320(7) . ?
Rh01 C2A 2.176(9) . ?
Rh01 C1A 2.138(13) . ?
Rh01 C3A 2.106(6) . ?
Rh01 C5A 2.235(10) . ?
O003 C00F 1.217(2) . ?
N004 C006 1.343(3) . ?
N004 C00I 1.355(3) . ?
N005 C006 1.399(2) . ?
N005 C00A 1.507(2) . ?
N005 C00F 1.382(2) . ?
C006 C00H 1.390(3) . ?
C007 C009 1.385(3) . ?
C007 C00A 1.507(3) . ?
C007 C00C 1.387(3) . ?
C008 C00C 1.389(3) . ?
C008 C00D 1.396(3) . ?
C009 C00E 1.383(3) . ?
C009 C00F 1.480(3) . ?
C00A C00B 1.534(3) . ?
C00A C00G 1.525(3) . ?
C00D C00E 1.385(3) . ?
C00H C00J 1.382(3) . ?
C00I C00K 1.370(3) . ?
C00J C00K 1.385(3) . ?
C1 C2 1.440(10) . ?
C1 C3 1.440(9) . ?
C1 C7 1.503(8) . ?
C2 C4 1.405(9) . ?
C2 C8 1.499(7) . ?
C3 C5 1.416(7) . ?
C3 C6 1.496(7) . ?
C4 C5 1.444(8) . ?
C4 C10 1.493(7) . ?
C5 C9 1.503(7) . ?
C10A C4A 1.506(9) . ?
C4A C2A 1.435(9) . ?
C4A C5A 1.416(9) . ?
C2A C1A 1.429(11) . ?
C2A C8A 1.503(9) . ?
C1A C3A 1.423(11) . ?
C1A C7A 1.500(9) . ?
C3A C5A 1.443(12) . ?
C3A C6A 1.502(8) . ?
C5A C9A 1.504(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N004 Rh01 C1 110.7(3) . . ?
N004 Rh01 C2 94.89(18) . . ?
N004 Rh01 C3 149.0(2) . . ?
N004 Rh01 C4 113.5(3) . . ?
N004 Rh01 C5 151.6(3) . . ?
N004 Rh01 C4A 96.7(2) . . ?
N004 Rh01 C2A 92.0(2) . . ?
N004 Rh01 C1A 122.7(3) . . ?
N004 Rh01 C3A 156.87(18) . . ?
N004 Rh01 C5A 128.7(3) . . ?
C00B Rh01 N004 90.84(7) . . ?
C00B Rh01 C1 97.3(3) . . ?
C00B Rh01 C2 134.4(3) . . ?
C00B Rh01 C3 89.85(16) . . ?
C00B Rh01 C4 153.0(2) . . ?
C00B Rh01 C5 117.3(3) . . ?
C00B Rh01 C4A 155.3(2) . . ?
C00B Rh01 C2A 119.5(3) . . ?
C00B Rh01 C1A 93.4(3) . . ?
C00B Rh01 C3A 102.9(3) . . ?
C00B Rh01 C5A 140.2(3) . . ?
C1 Rh01 C2 38.9(3) . . ?
C1 Rh01 C3 38.6(2) . . ?
C1 Rh01 C4 64.1(3) . . ?
C1 Rh01 C5 64.3(3) . . ?
C2 Rh01 C3 63.6(2) . . ?
C2 Rh01 C4 37.1(2) . . ?
C3 Rh01 C4 63.3(2) . . ?
C5 Rh01 C2 63.1(3) . . ?
C5 Rh01 C3 37.58(18) . . ?
C5 Rh01 C4 38.2(2) . . ?
C2A Rh01 C4A 37.0(2) . . ?
C2A Rh01 C5A 62.4(3) . . ?
C1A Rh01 C4A 62.8(4) . . ?
C1A Rh01 C2A 38.7(3) . . ?
C1A Rh01 C5A 63.5(4) . . ?
C3A Rh01 C4A 63.4(3) . . ?
C3A Rh01 C2A 65.1(3) . . ?
C3A Rh01 C1A 39.2(3) . . ?
C3A Rh01 C5A 38.7(3) . . ?
C5A Rh01 C4A 36.2(2) . . ?
C006 N004 Rh01 123.05(13) . . ?
C006 N004 C00I 118.06(17) . . ?
C00I N004 Rh01 116.88(14) . . ?
C006 N005 C00A 120.86(15) . . ?
C00F N005 C006 124.55(16) . . ?
C00F N005 C00A 113.74(15) . . ?
N004 C006 N005 115.76(16) . . ?
N004 C006 C00H 121.91(18) . . ?
C00H C006 N005 122.25(18) . . ?
C009 C007 C00A 111.49(16) . . ?
C009 C007 C00C 119.98(18) . . ?
C00C C007 C00A 128.53(17) . . ?
C00C C008 C00D 121.45(18) . . ?
C007 C009 C00F 109.02(17) . . ?
C00E C009 C007 122.40(19) . . ?
C00E C009 C00F 128.53(18) . . ?
N005 C00A C00B 111.24(14) . . ?
N005 C00A C00G 110.30(15) . . ?
C007 C00A N005 99.86(14) . . ?
C007 C00A C00B 111.41(15) . . ?
C007 C00A C00G 112.00(15) . . ?
C00G C00A C00B 111.50(16) . . ?
C00A C00B Rh01 115.81(12) . . ?
C007 C00C C008 118.10(18) . . ?
C00E C00D C008 120.27(18) . . ?
C009 C00E C00D 117.77(18) . . ?
O003 C00F N005 126.13(18) . . ?
O003 C00F C009 128.13(19) . . ?
N005 C00F C009 105.74(16) . . ?
C00J C00H C006 118.9(2) . . ?
N004 C00I C00K 123.1(2) . . ?
C00H C00J C00K 119.5(2) . . ?
C00I C00K C00J 118.4(2) . . ?
C2 C1 Rh01 72.7(4) . . ?
C2 C1 C3 107.4(6) . . ?
C2 C1 C7 126.4(8) . . ?
C3 C1 Rh01 73.7(4) . . ?
C3 C1 C7 125.2(7) . . ?
C7 C1 Rh01 127.8(7) . . ?
C1 C2 Rh01 68.5(5) . . ?
C1 C2 C8 123.9(9) . . ?
C4 C2 Rh01 72.9(4) . . ?
C4 C2 C1 109.1(5) . . ?
C4 C2 C8 127.0(9) . . ?
C8 C2 Rh01 123.2(4) . . ?
C1 C3 Rh01 67.7(5) . . ?
C1 C3 C6 127.7(7) . . ?
C5 C3 Rh01 70.0(3) . . ?
C5 C3 C1 107.0(7) . . ?
C5 C3 C6 125.3(9) . . ?
C6 C3 Rh01 127.9(4) . . ?
C2 C4 Rh01 70.0(4) . . ?
C2 C4 C5 106.9(6) . . ?
C2 C4 C10 128.1(9) . . ?
C5 C4 Rh01 69.2(3) . . ?
C5 C4 C10 125.0(8) . . ?
C10 C4 Rh01 124.8(4) . . ?
C3 C5 Rh01 72.4(4) . . ?
C3 C5 C4 109.3(7) . . ?
C3 C5 C9 126.4(9) . . ?
C4 C5 Rh01 72.6(4) . . ?
C4 C5 C9 124.2(7) . . ?
C9 C5 Rh01 124.8(4) . . ?
C10A C4A Rh01 129.9(5) . . ?
C2A C4A Rh01 66.0(5) . . ?
C2A C4A C10A 124.7(11) . . ?
C5A C4A Rh01 68.7(6) . . ?
C5A C4A C10A 128.7(10) . . ?
C5A C4A C2A 106.6(9) . . ?
C4A C2A Rh01 76.9(5) . . ?
C4A C2A C8A 125.2(11) . . ?
C1A C2A Rh01 69.2(6) . . ?
C1A C2A C4A 108.8(8) . . ?
C1A C2A C8A 125.5(10) . . ?
C8A C2A Rh01 126.3(6) . . ?
C2A C1A Rh01 72.1(6) . . ?
C2A C1A C7A 124.3(9) . . ?
C3A C1A Rh01 69.2(5) . . ?
C3A C1A C2A 107.8(7) . . ?
C3A C1A C7A 127.8(10) . . ?
C7A C1A Rh01 125.0(9) . . ?
C1A C3A Rh01 71.6(6) . . ?
C1A C3A C5A 106.9(6) . . ?
C1A C3A C6A 127.2(11) . . ?
C5A C3A Rh01 75.5(5) . . ?
C5A C3A C6A 125.5(12) . . ?
C6A C3A Rh01 123.9(4) . . ?
C4A C5A Rh01 75.2(6) . . ?
C4A C5A C3A 109.4(8) . . ?
C4A C5A C9A 125.7(11) . . ?
C3A C5A Rh01 65.8(4) . . ?
C3A C5A C9A 124.9(11) . . ?
C9A C5A Rh01 125.5(6) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
