# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_47521_0m
_database_code_depnum_ccdc_archive 'CCDC 2002761'
loop_
_audit_author_name
_audit_author_address
'Antonio Romerosa'
;Universidad de Almeria
Spain
;
_audit_update_record             
;
2020-05-08 deposited with the CCDC.	2020-07-02 downloaded from the CCDC.
;
_audit_creation_date             2020-02-25
_audit_creation_method           
;
Olex2 1.3
(compiled Nov 21 2019 18:26:39 for OlexSys, GUI svn.r6003)
;
_shelx_SHELXL_version_number     2018/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C43 H58 Au2 N21 P4 Ru2, 4(H2 O)'
_chemical_formula_sum            'C43 H66 Au2 N21 O4 P4 Ru2'
_chemical_formula_weight         1661.12
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.3590(11)
_cell_length_b                   13.2038(11)
_cell_length_c                   17.1923(14)
_cell_angle_alpha                90
_cell_angle_beta                 108.9750(10)
_cell_angle_gamma                90
_cell_volume                     2867.8(4)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9348
_cell_measurement_temperature    100
_cell_measurement_theta_max      28.36
_cell_measurement_theta_min      2.23
_shelx_estimated_absorpt_T_max   0.893
_shelx_estimated_absorpt_T_min   0.801
_exptl_absorpt_coefficient_mu    5.788
_exptl_absorpt_correction_T_max  0.2629
_exptl_absorpt_correction_T_min  0.1904
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2014/5 (Bruker,2014/5) was used for absorption correction.
wR2(int) was 0.0720 before and 0.0346 after correction.
The Ratio of minimum to maximum transmission is 0.7242.
The λ/2 correction factor is 0.00150.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.924
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       'rect. Prism'
_exptl_crystal_F_000             1618
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0190
_diffrn_reflns_av_unetI/netI     0.0221
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            17591
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.730
_diffrn_reflns_theta_min         2.231
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.2
_diffrn_source_voltage           40.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5702
_reflns_number_total             6045
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v6.28A (Bruker, 2002)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT v6.28A (Bruker, 2002)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/1 (Sheldrick, 2015)'
_computing_structure_solution    'XT  (Sheldrick, 2015)'
_refine_diff_density_max         1.628
_refine_diff_density_min         -0.548
_refine_diff_density_rms         0.101
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     353
_refine_ls_number_reflns         6045
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0226
_refine_ls_R_factor_gt           0.0209
_refine_ls_restrained_S_all      1.039
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0211P)²+4.1870P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0482
_refine_ls_wR_factor_ref         0.0491
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H) groups, All O(H,H) groups
2. Shared sites
{NCN, CCN}
3. Restrained distances
 H1WA-H1WB
 1.4 with sigma of 0.04
4. Uiso/Uaniso restraints and constraints
Uanis(NCN) = Uanis(CCN)
5. Others
 Fixed Sof: NCN(0.5) CCN(0.5)
6.a Free rotating group:
 O2W(H2W), O1W(H1WA,H1WB)
6.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C4(H4A,H4B), C8(H8A,H8B), C2(H2A,H2B), C6(H6A,H6B), C3(H3A,H3B),
 C9(H9A,H9B), C11(H11A,H11B), C7(H7A,H7B), C5(H5A,H5B), C12(H12A,H12B),
 C10(H10A,H10B)
6.c Aromatic/amide H refined with riding coordinates:
 C16(H16), C15(H15), C14(H14), C13(H13), C17(H17)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.54524(2) 0.99476(2) 0.27861(2) 0.01782(4) Uani 1 1 d . . . . .
Ru1 Ru 0.60108(2) 0.46638(2) 0.39726(2) 0.01123(5) Uani 1 1 d . . . . .
P1 P 0.67525(6) 0.62227(5) 0.42661(4) 0.01370(14) Uani 1 1 d . . . . .
P2 P 0.71825(6) 0.38274(5) 0.50273(4) 0.01224(14) Uani 1 1 d . . . . .
O2W O 0.9095(2) 0.05319(19) 0.47704(19) 0.0350(6) Uani 1 1 d G . . . .
H2W H 0.913953 0.098088 0.515048 0.052 Uiso 1 1 d G U . . .
N1 N 0.6607(2) 0.82583(17) 0.38157(16) 0.0193(5) Uani 1 1 d . . . . .
N2 N 0.8409(2) 0.75447(18) 0.43942(17) 0.0217(6) Uani 1 1 d . . . . .
NCN N 0.5227(2) 0.49403(18) 0.47708(16) 0.0141(5) Uani 0.5 1 d . . P A 1
N4 N 0.8410(2) 0.20951(18) 0.55312(16) 0.0210(5) Uani 1 1 d . . . . .
N3 N 0.73439(19) 0.78881(17) 0.52988(15) 0.0180(5) Uani 1 1 d . . . . .
C3G C 0.5272(3) 1.0635(2) 0.3772(2) 0.0224(6) Uani 1 1 d . . . . .
N3G N 0.5226(2) 1.1065(2) 0.43350(18) 0.0317(7) Uani 1 1 d . . . . .
N5 N 0.7415(2) 0.26726(19) 0.64152(16) 0.0213(5) Uani 1 1 d . . . . .
C1 C 0.6069(2) 0.7272(2) 0.35816(18) 0.0167(6) Uani 1 1 d . . . . .
H1A H 0.602889 0.711048 0.300987 0.020 Uiso 1 1 calc R U . . .
H1B H 0.533649 0.732719 0.359594 0.020 Uiso 1 1 calc R U . . .
N1G N 0.5706(2) 0.8952(2) 0.11948(18) 0.0325(7) Uani 1 1 d . . . . .
O1W O 0.8119(3) 0.8413(2) 0.70432(16) 0.0455(7) Uani 1 1 d G . . . .
H1WA H 0.780704 0.835668 0.652846 0.068 Uiso 1 1 d DG U . . .
H1WB H 0.813813 0.783917 0.727096 0.068 Uiso 1 1 d DG U . . .
C4 C 0.6673(2) 0.8551(2) 0.46592(18) 0.0188(6) Uani 1 1 d . . . . .
H4A H 0.694996 0.925125 0.476302 0.023 Uiso 1 1 calc R U . . .
H4B H 0.594997 0.855199 0.469959 0.023 Uiso 1 1 calc R U . . .
C8 C 0.6639(2) 0.3289(2) 0.57966(18) 0.0191(6) Uani 1 1 d . . . . .
H8A H 0.639716 0.384747 0.607582 0.023 Uiso 1 1 calc R U . . .
H8B H 0.601633 0.286500 0.551204 0.023 Uiso 1 1 calc R U . . .
N6 N 0.8984(2) 0.36127(18) 0.63838(16) 0.0213(5) Uani 1 1 d . . . . .
C16 C 0.6264(3) 0.3732(2) 0.29954(19) 0.0250(7) Uani 1 1 d . . . . .
H16 H 0.692744 0.342106 0.305724 0.030 Uiso 1 1 calc R U . . .
N2G N 0.7538(2) 1.1213(2) 0.30921(18) 0.0331(7) Uani 1 1 d . . . . .
N4G N 0.3249(2) 0.8877(2) 0.23822(18) 0.0346(7) Uani 1 1 d . . . . .
C15 C 0.5946(3) 0.4697(3) 0.26721(19) 0.0264(7) Uani 1 1 d . . . . .
H15 H 0.635646 0.515121 0.247177 0.032 Uiso 1 1 calc R U . . .
C4G C 0.4070(3) 0.9234(2) 0.25584(19) 0.0240(7) Uani 1 1 d . . . . .
C2 C 0.8099(2) 0.6470(2) 0.42352(19) 0.0192(6) Uani 1 1 d . . . . .
H2A H 0.860959 0.604214 0.465213 0.023 Uiso 1 1 calc R U . . .
H2B H 0.813238 0.627538 0.368811 0.023 Uiso 1 1 calc R U . . .
C14 C 0.4903(3) 0.4887(2) 0.26928(19) 0.0226(7) Uani 1 1 d . . . . .
H14 H 0.449574 0.548334 0.251059 0.027 Uiso 1 1 calc R U . . .
C6 C 0.8405(2) 0.7855(2) 0.5211(2) 0.0229(6) Uani 1 1 d . . . . .
H6A H 0.872985 0.853572 0.533396 0.027 Uiso 1 1 calc R U . . .
H6B H 0.885199 0.737941 0.562423 0.027 Uiso 1 1 calc R U . . .
C13 C 0.4593(2) 0.4018(2) 0.30365(18) 0.0212(6) Uani 1 1 d . . . . .
H13 H 0.393643 0.393300 0.313176 0.025 Uiso 1 1 calc R U . . .
C3 C 0.6880(2) 0.6867(2) 0.52476(18) 0.0171(6) Uani 1 1 d . . . . .
H3A H 0.617137 0.692054 0.531089 0.020 Uiso 1 1 calc R U . . .
H3B H 0.732986 0.645032 0.570771 0.020 Uiso 1 1 calc R U . . .
C17 C 0.5415(3) 0.3297(2) 0.32153(18) 0.0222(6) Uani 1 1 d . . . . .
H17 H 0.540580 0.264217 0.344109 0.027 Uiso 1 1 calc R U . . .
C9 C 0.8424(2) 0.4340(2) 0.57418(18) 0.0200(6) Uani 1 1 d . . . . .
H9A H 0.889371 0.453841 0.542585 0.024 Uiso 1 1 calc R U . . .
H9B H 0.826256 0.495641 0.600641 0.024 Uiso 1 1 calc R U . . .
C1G C 0.5632(2) 0.9299(2) 0.1785(2) 0.0225(6) Uani 1 1 d . . . . .
C2G C 0.6788(3) 1.0742(2) 0.29758(19) 0.0232(7) Uani 1 1 d . . . . .
C11 C 0.7758(3) 0.1802(2) 0.60593(19) 0.0228(6) Uani 1 1 d . . . . .
H11A H 0.712984 0.141799 0.572333 0.027 Uiso 1 1 calc R U . . .
H11B H 0.818104 0.135186 0.650618 0.027 Uiso 1 1 calc R U . . .
C7 C 0.7751(2) 0.2648(2) 0.47751(18) 0.0195(6) Uani 1 1 d . . . . .
H7A H 0.717064 0.220090 0.445098 0.023 Uiso 1 1 calc R U . . .
H7B H 0.819611 0.281288 0.443052 0.023 Uiso 1 1 calc R U . . .
C5 C 0.7697(2) 0.8211(2) 0.3780(2) 0.0223(7) Uani 1 1 d . . . . .
H5A H 0.766583 0.797576 0.322544 0.027 Uiso 1 1 calc R U . . .
H5B H 0.799806 0.890322 0.385412 0.027 Uiso 1 1 calc R U . . .
C12 C 0.8327(3) 0.3286(2) 0.68767(19) 0.0233(7) Uani 1 1 d . . . . .
H12A H 0.877034 0.288827 0.735249 0.028 Uiso 1 1 calc R U . . .
H12B H 0.807181 0.389242 0.709375 0.028 Uiso 1 1 calc R U . . .
C10 C 0.9318(2) 0.2728(2) 0.6031(2) 0.0231(6) Uani 1 1 d . . . . .
H10A H 0.978747 0.230927 0.647964 0.028 Uiso 1 1 calc R U . . .
H10B H 0.973250 0.295124 0.567760 0.028 Uiso 1 1 calc R U . . .
CCN C 0.5227(2) 0.49403(18) 0.47708(16) 0.0141(5) Uani 0.5 1 d . . P A 2
H2WA H 0.894(4) 0.073(4) 0.434(3) 0.056(16) Uiso 1 1 d . . . B 1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 N1 2.952(2) . ?
Au1 C3G 2.006(3) . ?
Au1 N6 3.193(3) 4_575 ?
Au1 C4G 1.995(3) . ?
Au1 C1G 2.005(3) . ?
Au1 C2G 2.003(3) . ?
Ru1 P1 2.2689(7) . ?
Ru1 P2 2.2610(7) . ?
Ru1 NCN 2.012(3) . ?
Ru1 C16 2.196(3) . ?
Ru1 C15 2.209(3) . ?
Ru1 C14 2.236(3) . ?
Ru1 C13 2.218(3) . ?
Ru1 C17 2.216(3) . ?
Ru1 CCN 2.012(3) . ?
P1 C1 1.855(3) . ?
P1 C2 1.845(3) . ?
P1 C3 1.847(3) . ?
P2 C8 1.846(3) . ?
P2 C9 1.841(3) . ?
P2 C7 1.845(3) . ?
O2W H2W 0.8699 . ?
O2W H2WA 0.75(5) . ?
N1 C1 1.478(4) . ?
N1 C4 1.476(4) . ?
N1 C5 1.479(4) . ?
N2 C2 1.479(4) . ?
N2 C6 1.465(4) . ?
N2 C5 1.464(4) . ?
NCN NCN 1.151(5) 3_666 ?
N4 C11 1.498(4) . ?
N4 C7 1.501(4) . ?
N4 C10 1.494(4) . ?
N3 C4 1.463(4) . ?
N3 C6 1.474(4) . ?
N3 C3 1.475(3) . ?
C3G N3G 1.140(4) . ?
N5 C8 1.466(4) . ?
N5 C11 1.446(4) . ?
N5 C12 1.464(4) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
N1G C1G 1.147(4) . ?
O1W H1WA 0.8500 . ?
O1W H1WB 0.8497 . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
N6 C9 1.471(4) . ?
N6 C12 1.469(4) . ?
N6 C10 1.452(4) . ?
C16 H16 0.9500 . ?
C16 C15 1.401(5) . ?
C16 C17 1.428(4) . ?
N2G C2G 1.140(4) . ?
N4G C4G 1.141(4) . ?
C15 H15 0.9500 . ?
C15 C14 1.427(5) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C14 H14 0.9500 . ?
C14 C13 1.413(4) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C13 H13 0.9500 . ?
C13 C17 1.409(4) . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C17 H17 0.9500 . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Au1 N6 167.29(7) . 4_575 ?
C3G Au1 N1 91.04(10) . . ?
C3G Au1 N6 98.95(10) . 4_575 ?
C4G Au1 N1 91.75(10) . . ?
C4G Au1 C3G 91.24(13) . . ?
C4G Au1 N6 80.27(10) . 4_575 ?
C4G Au1 C1G 89.49(13) . . ?
C4G Au1 C2G 176.27(13) . . ?
C1G Au1 N1 90.42(10) . . ?
C1G Au1 C3G 178.35(12) . . ?
C1G Au1 N6 79.72(10) . 4_575 ?
C2G Au1 N1 91.96(10) . . ?
C2G Au1 C3G 88.33(12) . . ?
C2G Au1 N6 96.14(10) . 4_575 ?
C2G Au1 C1G 90.84(12) . . ?
P2 Ru1 P1 97.26(3) . . ?
NCN Ru1 P1 88.29(7) . . ?
NCN Ru1 P2 85.40(8) . . ?
NCN Ru1 C16 150.17(11) . . ?
NCN Ru1 C15 145.96(12) . . ?
NCN Ru1 C14 108.81(12) . . ?
NCN Ru1 C13 93.07(11) . . ?
NCN Ru1 C17 112.42(11) . . ?
C16 Ru1 P1 120.91(9) . . ?
C16 Ru1 P2 95.80(9) . . ?
C16 Ru1 C15 37.07(12) . . ?
C16 Ru1 C14 62.53(12) . . ?
C16 Ru1 C13 62.44(11) . . ?
C16 Ru1 C17 37.76(12) . . ?
C15 Ru1 P1 94.46(9) . . ?
C15 Ru1 P2 127.62(10) . . ?
C15 Ru1 C14 37.44(13) . . ?
C15 Ru1 C13 61.97(12) . . ?
C15 Ru1 C17 62.17(12) . . ?
C14 Ru1 P1 101.57(8) . . ?
C14 Ru1 P2 156.59(8) . . ?
C13 Ru1 P1 135.90(8) . . ?
C13 Ru1 P2 126.81(8) . . ?
C13 Ru1 C14 36.99(11) . . ?
C17 Ru1 P1 156.46(8) . . ?
C17 Ru1 P2 95.52(8) . . ?
C17 Ru1 C14 62.16(11) . . ?
C17 Ru1 C13 37.06(11) . . ?
CCN Ru1 P1 88.29(7) . . ?
CCN Ru1 P2 85.40(8) . . ?
CCN Ru1 C16 150.17(11) . . ?
CCN Ru1 C15 145.96(12) . . ?
CCN Ru1 C14 108.81(12) . . ?
CCN Ru1 C13 93.07(11) . . ?
CCN Ru1 C17 112.42(11) . . ?
C1 P1 Ru1 116.59(10) . . ?
C2 P1 Ru1 120.87(9) . . ?
C2 P1 C1 97.63(13) . . ?
C2 P1 C3 98.26(14) . . ?
C3 P1 Ru1 121.64(9) . . ?
C3 P1 C1 96.65(13) . . ?
C8 P2 Ru1 115.59(10) . . ?
C9 P2 Ru1 126.44(9) . . ?
C9 P2 C8 98.17(14) . . ?
C9 P2 C7 96.69(14) . . ?
C7 P2 Ru1 117.02(10) . . ?
C7 P2 C8 97.54(13) . . ?
H2W O2W H2WA 115.2 . . ?
C1 N1 Au1 112.93(17) . . ?
C1 N1 C5 110.4(2) . . ?
C4 N1 Au1 104.11(15) . . ?
C4 N1 C1 111.5(2) . . ?
C4 N1 C5 107.9(2) . . ?
C5 N1 Au1 109.65(16) . . ?
C6 N2 C2 111.0(2) . . ?
C5 N2 C2 111.5(2) . . ?
C5 N2 C6 108.6(2) . . ?
NCN NCN Ru1 177.4(3) 3_666 . ?
C11 N4 C7 111.0(2) . . ?
C10 N4 C11 108.6(2) . . ?
C10 N4 C7 111.3(2) . . ?
C4 N3 C6 108.4(2) . . ?
C4 N3 C3 111.1(2) . . ?
C6 N3 C3 111.5(2) . . ?
N3G C3G Au1 175.4(3) . . ?
C11 N5 C8 112.4(2) . . ?
C11 N5 C12 110.3(2) . . ?
C12 N5 C8 110.7(2) . . ?
P1 C1 H1A 109.0 . . ?
P1 C1 H1B 109.0 . . ?
N1 C1 P1 113.0(2) . . ?
N1 C1 H1A 109.0 . . ?
N1 C1 H1B 109.0 . . ?
H1A C1 H1B 107.8 . . ?
H1WA O1W H1WB 109.4 . . ?
N1 C4 H4A 108.7 . . ?
N1 C4 H4B 108.7 . . ?
N3 C4 N1 114.1(2) . . ?
N3 C4 H4A 108.7 . . ?
N3 C4 H4B 108.7 . . ?
H4A C4 H4B 107.6 . . ?
P2 C8 H8A 109.1 . . ?
P2 C8 H8B 109.1 . . ?
N5 C8 P2 112.57(19) . . ?
N5 C8 H8A 109.1 . . ?
N5 C8 H8B 109.1 . . ?
H8A C8 H8B 107.8 . . ?
C12 N6 C9 111.8(2) . . ?
C10 N6 C9 111.2(2) . . ?
C10 N6 C12 109.1(2) . . ?
Ru1 C16 H16 121.8 . . ?
C15 C16 Ru1 71.98(17) . . ?
C15 C16 H16 126.1 . . ?
C15 C16 C17 107.8(3) . . ?
C17 C16 Ru1 71.87(16) . . ?
C17 C16 H16 126.1 . . ?
Ru1 C15 H15 122.8 . . ?
C16 C15 Ru1 70.95(17) . . ?
C16 C15 H15 125.6 . . ?
C16 C15 C14 108.9(3) . . ?
C14 C15 Ru1 72.30(17) . . ?
C14 C15 H15 125.6 . . ?
N4G C4G Au1 174.9(3) . . ?
P1 C2 H2A 109.1 . . ?
P1 C2 H2B 109.1 . . ?
N2 C2 P1 112.43(19) . . ?
N2 C2 H2A 109.1 . . ?
N2 C2 H2B 109.1 . . ?
H2A C2 H2B 107.8 . . ?
Ru1 C14 H14 124.0 . . ?
C15 C14 Ru1 70.26(17) . . ?
C15 C14 H14 126.6 . . ?
C13 C14 Ru1 70.82(17) . . ?
C13 C14 C15 106.8(3) . . ?
C13 C14 H14 126.6 . . ?
N2 C6 N3 114.2(2) . . ?
N2 C6 H6A 108.7 . . ?
N2 C6 H6B 108.7 . . ?
N3 C6 H6A 108.7 . . ?
N3 C6 H6B 108.7 . . ?
H6A C6 H6B 107.6 . . ?
Ru1 C13 H13 122.6 . . ?
C14 C13 Ru1 72.19(17) . . ?
C14 C13 H13 125.5 . . ?
C17 C13 Ru1 71.36(17) . . ?
C17 C13 C14 109.0(3) . . ?
C17 C13 H13 125.5 . . ?
P1 C3 H3A 109.0 . . ?
P1 C3 H3B 109.0 . . ?
N3 C3 P1 112.81(19) . . ?
N3 C3 H3A 109.0 . . ?
N3 C3 H3B 109.0 . . ?
H3A C3 H3B 107.8 . . ?
Ru1 C17 H17 123.5 . . ?
C16 C17 Ru1 70.38(16) . . ?
C16 C17 H17 126.2 . . ?
C13 C17 Ru1 71.57(16) . . ?
C13 C17 C16 107.5(3) . . ?
C13 C17 H17 126.2 . . ?
P2 C9 H9A 109.0 . . ?
P2 C9 H9B 109.0 . . ?
N6 C9 P2 112.91(19) . . ?
N6 C9 H9A 109.0 . . ?
N6 C9 H9B 109.0 . . ?
H9A C9 H9B 107.8 . . ?
N1G C1G Au1 177.5(3) . . ?
N2G C2G Au1 178.3(3) . . ?
N4 C11 H11A 109.2 . . ?
N4 C11 H11B 109.2 . . ?
N5 C11 N4 112.2(2) . . ?
N5 C11 H11A 109.2 . . ?
N5 C11 H11B 109.2 . . ?
H11A C11 H11B 107.9 . . ?
P2 C7 H7A 109.2 . . ?
P2 C7 H7B 109.2 . . ?
N4 C7 P2 112.16(19) . . ?
N4 C7 H7A 109.2 . . ?
N4 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
N1 C5 H5A 108.7 . . ?
N1 C5 H5B 108.7 . . ?
N2 C5 N1 114.4(2) . . ?
N2 C5 H5A 108.7 . . ?
N2 C5 H5B 108.7 . . ?
H5A C5 H5B 107.6 . . ?
N5 C12 N6 113.5(2) . . ?
N5 C12 H12A 108.9 . . ?
N5 C12 H12B 108.9 . . ?
N6 C12 H12A 108.9 . . ?
N6 C12 H12B 108.9 . . ?
H12A C12 H12B 107.7 . . ?
N4 C10 H10A 109.0 . . ?
N4 C10 H10B 109.0 . . ?
N6 C10 N4 112.8(2) . . ?
N6 C10 H10A 109.0 . . ?
N6 C10 H10B 109.0 . . ?
H10A C10 H10B 107.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 N1 C1 P1 -176.65(11) . . . . ?
Au1 N1 C4 N3 -172.08(18) . . . . ?
Au1 N1 C5 N2 167.90(19) . . . . ?
Ru1 P1 C1 N1 -179.86(16) . . . . ?
Ru1 P1 C2 N2 176.40(16) . . . . ?
Ru1 P1 C3 N3 -177.66(15) . . . . ?
Ru1 P2 C8 N5 174.23(17) . . . . ?
Ru1 P2 C9 N6 177.43(15) . . . . ?
Ru1 P2 C7 N4 -172.90(16) . . . . ?
Ru1 C16 C15 C14 -62.7(2) . . . . ?
Ru1 C16 C17 C13 62.3(2) . . . . ?
Ru1 C15 C14 C13 -61.8(2) . . . . ?
Ru1 C14 C13 C17 -62.2(2) . . . . ?
Ru1 C13 C17 C16 -61.5(2) . . . . ?
C1 P1 C2 N2 49.1(2) . . . . ?
C1 P1 C3 N3 -50.7(2) . . . . ?
C1 N1 C4 N3 65.8(3) . . . . ?
C1 N1 C5 N2 -67.0(3) . . . . ?
C4 N1 C1 P1 -59.8(3) . . . . ?
C4 N1 C5 N2 55.1(3) . . . . ?
C4 N3 C6 N2 -55.5(3) . . . . ?
C4 N3 C3 P1 62.1(3) . . . . ?
C8 P2 C9 N6 47.0(2) . . . . ?
C8 P2 C7 N4 -49.1(2) . . . . ?
C8 N5 C11 N4 68.5(3) . . . . ?
C8 N5 C12 N6 -68.9(3) . . . . ?
C16 C15 C14 Ru1 61.9(2) . . . . ?
C16 C15 C14 C13 0.1(3) . . . . ?
C15 C16 C17 Ru1 -63.5(2) . . . . ?
C15 C16 C17 C13 -1.1(3) . . . . ?
C15 C14 C13 Ru1 61.4(2) . . . . ?
C15 C14 C13 C17 -0.8(3) . . . . ?
C2 P1 C1 N1 -49.6(2) . . . . ?
C2 P1 C3 N3 48.0(2) . . . . ?
C2 N2 C6 N3 -67.9(3) . . . . ?
C2 N2 C5 N1 67.5(3) . . . . ?
C14 C13 C17 Ru1 62.8(2) . . . . ?
C14 C13 C17 C16 1.2(3) . . . . ?
C6 N2 C2 P1 60.7(3) . . . . ?
C6 N2 C5 N1 -55.0(3) . . . . ?
C6 N3 C4 N1 56.0(3) . . . . ?
C6 N3 C3 P1 -58.9(3) . . . . ?
C3 P1 C1 N1 49.7(2) . . . . ?
C3 P1 C2 N2 -48.8(2) . . . . ?
C3 N3 C4 N1 -66.9(3) . . . . ?
C3 N3 C6 N2 67.0(3) . . . . ?
C17 C16 C15 Ru1 63.4(2) . . . . ?
C17 C16 C15 C14 0.7(3) . . . . ?
C9 P2 C8 N5 -48.5(2) . . . . ?
C9 P2 C7 N4 50.1(2) . . . . ?
C9 N6 C12 N5 67.6(3) . . . . ?
C9 N6 C10 N4 -67.6(3) . . . . ?
C11 N4 C7 P2 60.6(3) . . . . ?
C11 N4 C10 N6 -56.1(3) . . . . ?
C11 N5 C8 P2 -62.4(3) . . . . ?
C11 N5 C12 N6 56.1(3) . . . . ?
C7 P2 C8 N5 49.4(2) . . . . ?
C7 P2 C9 N6 -51.6(2) . . . . ?
C7 N4 C11 N5 -67.3(3) . . . . ?
C7 N4 C10 N6 66.4(3) . . . . ?
C5 N1 C1 P1 60.2(3) . . . . ?
C5 N1 C4 N3 -55.6(3) . . . . ?
C5 N2 C2 P1 -60.5(3) . . . . ?
C5 N2 C6 N3 55.0(3) . . . . ?
C12 N5 C8 P2 61.4(3) . . . . ?
C12 N5 C11 N4 -55.6(3) . . . . ?
C12 N6 C9 P2 -58.7(3) . . . . ?
C12 N6 C10 N4 56.1(3) . . . . ?
C10 N4 C11 N5 55.4(3) . . . . ?
C10 N4 C7 P2 -60.5(3) . . . . ?
C10 N6 C9 P2 63.5(3) . . . . ?
C10 N6 C12 N5 -55.8(3) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
