# Electronic Supplementary Material (ESI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_bs200109_tptzn4pyp_uo_26600_b4_cut
_database_code_depnum_ccdc_archive 'CCDC 1977523'
loop_
_audit_author_name
_audit_author_address
'Bernhard Spingler'
;University of Zurich
Switzerland
;
_audit_update_record             
;
2020-01-14 deposited with the CCDC.	2020-10-19 downloaded from the CCDC.
;
_audit_creation_date             2020-01-10
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'C43 H55 Cl4 N17 O Pt4 Zn, 7(C3 H7 N O), 4(C24 H20 B)'
_chemical_formula_sum            'C160 H184 B4 Cl4 N24 O8 Pt4 Zn'
_chemical_formula_weight         3602.07
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C158 H140 B4 Cl4 N21 O11 Pt4 Zn '
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn -1.5491 0.6778 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.1513(2)
_cell_length_b                   17.9898(2)
_cell_length_c                   19.21888(13)
_cell_angle_alpha                77.5748(8)
_cell_angle_beta                 80.9900(10)
_cell_angle_gamma                89.3233(12)
_cell_volume                     4051.16(9)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    76318
_cell_measurement_temperature    160.00(10)
_cell_measurement_theta_max      79.1180
_cell_measurement_theta_min      3.6600
_shelx_estimated_absorpt_T_max   0.805
_shelx_estimated_absorpt_T_min   0.195
_exptl_absorpt_coefficient_mu    7.556
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.204
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.68a (Rigaku Oxford Diffraction, 2019)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.476
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             1806
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 0 1 0.0072
0 0 -1 0.0262
0 1 2 0.0127
7 4 4 0.1488
0 11 6 0.0167
0 -11 -5 0.0153
7 -4 0 0.1418
-7 4 -4 0.1533
-2 1 -12 0.0527
-4 -10 -3 0.0685
0 7 -8 0.0245
-1 9 -5 0.0415
0 -4 10 0.0031
2 -1 12 0.0324

_exptl_crystal_size_max          0.321
_exptl_crystal_size_mid          0.034
_exptl_crystal_size_min          0.03
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.0020 0.0029 0.9997 0.0319 0.0145 0.0753
0.0020 -0.0029 -0.9997 -0.0319 -0.0145 -0.0753
-0.0037 1.0037 1.9946 -0.0052 0.0829 0.1485
7.0038 4.0697 4.0189 0.3119 0.8871 -0.1780
-0.0096 10.9940 5.9451 -0.5677 0.6802 0.4282
0.0076 -10.9911 -4.9454 0.5996 -0.6657 -0.3529
7.0101 -3.9249 0.0588 0.7364 0.3977 -0.4620
-7.0022 3.9134 -4.0575 -0.8641 -0.4557 0.1608
-1.9792 0.9442 -12.0125 -0.5836 -0.2955 -0.7715
-4.0024 -10.0255 -2.9734 0.3314 -0.9333 0.0646
0.0173 6.9621 -8.0314 -0.7385 0.2614 -0.6177
-0.9898 8.9570 -5.0476 -0.8465 0.3251 -0.3288
-0.0206 -3.9627 10.0163 0.5953 -0.0706 0.7618
1.9792 -0.9442 12.0125 0.5836 0.2955 0.7715

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0697
_diffrn_reflns_av_unetI/netI     0.0270
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.972
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            144826
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.972
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         80.096
_diffrn_reflns_theta_min         3.684
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      160.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_detector_type            'Pilatus 200K'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     71.00  97.00   0.50    8.00    --  107.75 -94.00  60.00   52
  2  ω     83.00 106.50   0.50    8.00    --  107.75-111.00  60.00   47
  3  ω     84.00 109.00   0.50    8.00    --  107.75-111.00 120.00   50
  4  ω     70.00  96.00   0.50    8.00    --  107.75 -94.00 150.00   52
  5  ω     70.00 106.00   0.50    8.00    --  107.75 -94.00  90.00   72
  6  ω     73.00 106.00   0.50    8.00    --  107.75-111.00 150.00   66
  7  ω     73.00 105.00   0.50    8.00    --  107.75-111.00  90.00   64
  8  ω     67.00 102.00   0.50    8.00    --  107.75 -77.00  30.00   70
  9  ω     84.00 109.00   0.50    8.00    --  107.75-111.00   0.00   50
 10  ω     84.00 109.00   0.50    8.00    --  107.75-111.00 -30.00   50
 11  ω     66.00 109.00   0.50    8.00    --  107.75-111.00 -90.00   86
 12  ω     83.00 109.00   0.50    8.00    --  107.75-111.00-120.00   52
 13  ω     67.00 109.00   0.50    8.00    --  107.75-111.00-180.00   84
 14  ω     69.00  96.00   0.50    8.00    --  107.75 -77.00-180.00   54
 15  ω     70.00  96.00   0.50    8.00    --  107.75 -94.00-150.00   52
 16  ω     59.00 105.00   0.50    8.00    --  107.75 -77.00-150.00   92
 17  ω     61.00  95.00   0.50    8.00    --  107.75 -94.00-180.00   68
 18  ω     46.00 103.00   0.50    8.00    --  107.75 -77.00 -90.00  114
 19  ω     64.00 103.00   0.50    8.00    --  107.75 -77.00 -30.00   78
 20  ω     68.00 108.00   0.50    8.00    --  107.75-111.00 -60.00   80
 21  ω     55.00  81.00   0.50    8.00    --  107.75-111.00 -30.00   52
 22  ω     62.00 101.00   0.50    8.00    --  107.75 -94.00 -60.00   78
 23  ω     58.00  86.00   0.50    8.00    --  107.75 -77.00   0.00   56
 24  ω     56.00 106.00   0.50    8.00    --  107.75-112.00  62.14  100
 25  ω     39.00  67.00   0.50    8.00    --  107.75 -94.00  60.00   56
 26  ω     44.00  71.00   0.50    8.00    --  107.75 -61.00  60.00   54
 27  ω     40.00  70.00   0.50    8.00    --  107.75 -61.00  90.00   60
 28  ω     47.00  97.00   0.50    8.00    --  107.75 -94.00 120.00  100
 29  ω     31.00  73.00   0.50    2.00    --   51.06 -77.00 150.00   84
 30  ω     35.00  97.00   0.50    2.00    --   51.06-125.00  90.00  124
 31  ω     38.00  70.00   0.50    8.00    --  107.75 -61.00 150.00   64
 32  ω     37.00  75.00   0.50    8.00    --  107.75 -77.00 150.00   76
 33  ω     33.00  61.00   0.50    8.00    --  107.75-111.00 120.00   56
 34  ω     39.00  66.00   0.50    8.00    --  107.75-111.00 150.00   54
 35  ω     37.00  69.00   0.50    8.00    --  107.75 -61.00 120.00   64
 36  ω     33.00  62.00   0.50    8.00    --  107.75 -94.00  90.00   58
 37  ω     33.00  83.00   0.50    8.00    --  107.75 -94.00  30.00  100
 38  ω     37.00  70.00   0.50    8.00    --  107.75 -61.00 -60.00   66
 39  ω     63.00  99.00   0.50    8.00    --  107.75 -94.00 -90.00   72
 40  ω     32.00 100.00   0.50    8.00    --  107.75 -94.00-120.00  136
 41  ω     37.00  63.00   0.50    8.00    --  107.75-111.00-120.00   52
 42  ω     33.00 108.00   0.50    8.00    --  107.75-111.00-150.00  150
 43  ω     38.00  70.00   0.50    8.00    --  107.75 -61.00 -90.00   64
 44  ω     37.00 106.00   0.50    8.00    --  107.75 -94.00 -30.00  138
 45  ω    107.00 134.00   0.50    8.00    --  107.75  15.00-180.00   54
 46  ω    148.00 177.00   0.50    8.00    --  107.75  15.00-180.00   58
 47  ω    143.00 178.00   0.50    8.00    --  107.75  33.00 -76.00   70
 48  ω    143.00 174.00   0.50    8.00    --  107.75  30.00   0.00   62
 49  ω    125.00 176.00   0.50    8.00    --  107.75  15.00 -30.00  102
 50  ω    132.00 159.00   0.50    8.00    --  107.75  15.00-120.00   54
 51  ω    106.00 177.00   0.50    8.00    --  107.75  30.00 -90.00  142
 52  ω    110.00 138.00   0.50    8.00    --  107.75  30.00   0.00   56
 53  ω    114.00 162.00   0.50    8.00    --  107.75  61.00  30.00   96
 54  ω    109.00 150.00   0.50    8.00    --  107.75  15.00 120.00   82
 55  ω    103.00 167.00   0.50    8.00    --  107.75  15.00  60.00  128
 56  ω     99.00 138.00   0.50    8.00    --  107.75  33.00 -76.00   78
 57  ω     97.00 136.00   0.50    8.00    --  107.75  45.00   0.00   78
 58  ω    106.00 177.00   0.50    8.00    --  107.75  30.00 -60.00  142
 59  ω    126.00 151.00   0.50    8.00    --  107.75 111.00-120.00   50
 60  ω     94.00 178.00   0.50    8.00    --  107.75  61.00-150.00  168
 61  ω    102.00 129.00   0.50    8.00    --  107.75  15.00-120.00   54
 62  ω     65.00 125.00   0.50    2.00    --   51.06  33.00 -76.00  120
 63  ω    103.00 171.00   0.50    8.00    --  107.75 111.00 120.00  136
 64  ω    -12.00  25.00   0.50    2.00    --   51.06 -19.00 -30.00   74
 65  ω    -25.00  24.00   0.50    2.00    --   51.06 -33.00 125.00   98
 66  ω    -36.00  25.00   0.50    2.00    --  -51.06  33.00 -76.00  122
 67  ω    -37.00 -11.00   0.50    8.00    --  -86.25  33.00 -76.00   52
 68  ω    -65.00 -10.00   0.50    8.00    --  -86.25 111.00   0.00  110
 69  ω   -126.00 -43.00   0.50    2.00    --  -51.06 -33.00 125.00  166
 70  ω    -87.00 -36.00   0.50    2.00    --  -51.06 -77.00-180.00  102
 71  ω   -118.00 -93.00   0.50    2.00    --  -51.06 -77.00-180.00   50
 72  ω   -108.00 -32.00   0.50    2.00    --  -51.06 -77.00-120.00  152
 73  ω   -111.00 -86.00   0.50    2.00    --  -51.06-125.00-180.00   50
 74  ω   -115.00 -90.00   0.50    8.00    --  -86.25 -33.00 125.00   50
 75  ω    -38.00 -13.00   0.50    8.00    --  -86.25  33.00 -76.00   50
 76  ω    -63.00 -33.00   0.50    2.00    --    6.00 162.00-122.61   60
 77  ω    -63.00 -37.00   0.50    2.00    --   14.00 171.00 148.77   52
 78  ω    -13.00  22.00   0.50    2.00    --   18.00  99.00 112.58   70
 79  ω     -2.00  23.00   0.50    2.00    --   30.00  99.00 -10.30   50
 80  ω     -1.00  24.00   0.50    2.00    --   30.00  98.00-137.40   50
 81  ω     10.00  35.00   0.50    2.00    --   38.00  91.00-102.60   50
 82  ω     16.00  41.00   0.50    2.00    --   42.00  88.00 -22.30   50
 83  ω     16.00  41.00   0.50    2.00    --   42.00  87.00 160.33   50
 84  ω     16.00  41.00   0.50    2.00    --   42.00  87.00  60.15   50
 85  ω    -55.00 -28.00   0.50    2.00    --  -50.00 -80.00  41.62   54
 86  ω     28.00  54.00   0.50    2.00    --   50.00  79.00-134.95   52
 87  ω    -77.00 -45.00   0.50    2.00    --  -51.06 -19.00 -30.00   64
 88  ω    -94.00 -48.00   0.50    2.00    --  -51.06 -19.00  30.00   92
 89  ω   -122.00 -87.00   0.50    2.00    --  -51.06 -19.00 -30.00   70
 90  ω    -80.00 -42.00   0.50    2.00    --  -51.06 -19.00 120.00   76
 91  ω    -57.00 -31.00   0.50    2.00    --  -54.00 -80.00   2.93   52
 92  ω   -108.00 -73.00   0.50    2.00    --  -54.00 -80.00   2.93   70
 93  ω     32.00  59.00   0.50    2.00    --   54.00  79.00 118.80   54
 94  ω    -87.00 -36.00   0.50    2.00    --  -58.00 -78.00 150.91  102
 95  ω    -63.00 -36.00   0.50    2.00    --  -58.00 -77.00 123.94   54
 96  ω     36.00  62.00   0.50    2.00    --   58.00  78.00-103.26   52
 97  ω     37.00  63.00   0.50    2.00    --   58.00  77.00  73.34   52
 98  ω     36.00  62.00   0.50    2.00    --   58.00  79.00 -84.45   52
 99  ω     41.00  68.00   0.50    2.00    --   62.00  79.00 123.79   54
100  ω     43.00  71.00   0.50    2.00    --   62.00  73.00-165.99   56
101  ω     44.00  71.00   0.50    2.00    --   66.00  79.00  94.51   54
102  ω     47.00  73.00   0.50    2.00    --   66.00  72.00 -50.30   52
103  ω     47.00  74.00   0.50    2.00    --   66.00  73.00 -17.84   54
104  ω     44.00  74.00   0.50    2.00    --   66.00  78.00  -9.83   60
105  ω     43.00  69.00   0.50    2.00    --   66.00  80.00  66.22   52
106  ω     47.00  73.00   0.50    2.00    --   66.00  72.00 -32.57   52
107  ω     44.00  70.00   0.50    2.00    --   66.00  79.00 147.24   52
108  ω     44.00  70.00   0.50    2.00    --   66.00  78.00   9.84   52
109  ω     48.00  76.00   0.50    2.00    --   70.00  78.00-151.77   56
110  ω     48.00  74.00   0.50    2.00    --   70.00  79.00 175.28   52
111  ω     48.00  74.00   0.50    2.00    --   70.00  78.00-167.47   52
112  ω    105.00 132.00   0.50    2.00    --   70.00  80.00 -83.04   54
113  ω     48.00  74.00   0.50    2.00    --   70.00  79.00-118.30   52
114  ω     48.00  74.00   0.50    2.00    --   70.00  79.00  20.19   52
115  ω     47.00  73.00   0.50    2.00    --   70.00  80.00 -83.04   52
116  ω    -78.00 -52.00   0.50    8.00    --  -74.00 -77.00  30.73   52
117  ω    -83.00 -57.00   0.50    8.00    --  -78.00 -75.00  67.10   52
118  ω    -83.00 -57.00   0.50    8.00    --  -78.00 -75.00-137.82   52
119  ω    -83.00 -57.00   0.50    8.00    --  -78.00 -76.00-106.81   52
120  ω    -86.00 -60.00   0.50    8.00    --  -82.00 -77.00 -79.81   52
121  ω    -89.00 -64.00   0.50    8.00    --  -86.00 -77.00  64.48   50
122  ω    -90.00 -64.00   0.50    8.00    --  -86.00 -77.00-104.79   52
123  ω   -157.00-131.00   0.50    8.00    --  -86.00 -77.00  64.48   52
124  ω    -91.00 -64.00   0.50    8.00    --  -86.00 -77.00 -82.43   54
125  ω    -90.00 -64.00   0.50    8.00    --  -86.00 -77.00  33.64   52
126  ω    -91.00 -65.00   0.50    8.00    --  -86.25 -77.00-150.00   52
127  ω    -90.00 -64.00   0.50    8.00    --  -86.25 -78.00 133.41   52
128  ω    -94.00 -65.00   0.50    8.00    --  -86.25 -76.00  -8.58   58
129  ω    -92.00 -65.00   0.50    8.00    --  -86.25 -77.00  90.00   54
130  ω   -146.00-121.00   0.50    8.00    --  -86.25 -73.00-142.94   50
131  ω    -92.00 -65.00   0.50    8.00    --  -86.25 -77.00 154.75   54
132  ω   -137.00-111.00   0.50    8.00    --  -86.25 -77.00 154.75   52
133  ω    -91.00 -66.00   0.50    8.00    --  -86.25 -73.00-142.94   50
134  ω    -92.00 -66.00   0.50    8.00    --  -86.25 -73.00-172.78   52
135  ω   -145.00-119.00   0.50    8.00    --  -86.25 -80.00 172.21   52
136  ω    -91.00 -65.00   0.50    8.00    --  -86.25 -77.00-180.00   52
137  ω    -88.00 -63.00   0.50    8.00    --  -86.25 -80.00 172.21   50
138  ω    -92.00 -66.00   0.50    8.00    --  -86.25 -75.00 -20.13   52
139  ω   -104.00 -65.00   0.50    8.00    --  -86.25 -76.00 -45.95   78
140  ω    -90.00 -64.00   0.50    8.00    --  -86.25 -80.00  49.42   52
141  ω    -92.00 -65.00   0.50    8.00    --  -86.25 -76.00   3.71   54
142  ω    -92.00 -65.00   0.50    8.00    --  -86.25 -76.00 104.00   54
143  ω   -158.00-130.00   0.50    8.00    --  -86.25 -76.00   3.71   56
144  ω    -88.00 -63.00   0.50    8.00    --  -86.25 -80.00 151.50   50
145  ω   -144.00-118.00   0.50    8.00    --  -86.25 -80.00 151.50   52
146  ω    -91.00 -65.00   0.50    8.00    --  -86.25 -77.00 -60.00   52
147  ω   -157.00-130.00   0.50    8.00    --  -86.25 -77.00 -60.00   54
148  ω    -91.00 -65.00   0.50    8.00    --  -86.25 -77.00 120.00   52
149  ω    -91.00 -65.00   0.50    8.00    --  -86.25 -77.00  19.48   52
150  ω    -92.00 -65.00   0.50    8.00    --  -86.25 -77.00 -30.00   54
151  ω    118.00 144.00   0.50    8.00    --   90.00  71.00 126.87   52
152  ω     71.00  97.00   0.50    8.00    --   90.00  71.00 126.87   52
153  ω    129.00 158.00   0.50    8.00    --   94.00  78.00 -37.08   58
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0661354000
_diffrn_orient_matrix_UB_12      -0.0690253000
_diffrn_orient_matrix_UB_13      0.0322587000
_diffrn_orient_matrix_UB_21      0.0868944000
_diffrn_orient_matrix_UB_22      0.0540895000
_diffrn_orient_matrix_UB_23      0.0145329000
_diffrn_orient_matrix_UB_31      -0.0675404000
_diffrn_orient_matrix_UB_32      -0.0017841000
_diffrn_orient_matrix_UB_33      0.0752163000
_diffrn_oxdiff_digest_frames     
;
01f7afafe5594fc725475cd3b9f546affd1286317d7
;
_diffrn_oxdiff_digest_hkl        
;
012ec15659bc2507053edc72d89e4196d5f3af
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15220
_reflns_number_total             17213
_reflns_odcompleteness_completeness 99.44
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     74.33
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.68a (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.68a (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.68a (Rigaku OD, 2019)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         6.611
_refine_diff_density_min         -2.481
_refine_diff_density_rms         0.173
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     950
_refine_ls_number_reflns         17213
_refine_ls_number_restraints     104
_refine_ls_R_factor_all          0.0736
_refine_ls_R_factor_gt           0.0684
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1131P)²+22.6984P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1917
_refine_ls_wR_factor_ref         0.1964
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All C(H,H,H,H,H,H) groups, All N(H,H,H) groups
2. Restrained distances
 N40B-C40B = N40B-C41B
 1.43 with sigma of 0.02
 N40-C42 = C41-N40
 1.43 with sigma of 0.02
 C39-O38
 1.28 with sigma of 0.02
 C41-C39
 2.35 with sigma of 0.02
 C32B-N30
 1.48 with sigma of 0.02
3. Restrained planarity
 O38, C39B, N40B, C40B, C41B
 with sigma of 0.1
 O38, C39, N40, C41, C42
 with sigma of 0.1
4. Uiso/Uaniso restraints and constraints
N30 \\sim N30B: within 2A with sigma of 0.04 and sigma for terminal atoms of
0.08
C41B \\sim C42: within 4A with sigma of 0.002 and sigma for terminal atoms of
0.004
C32 \\sim C32B: within 2A with sigma of 0.04 and sigma for terminal atoms of
0.08
5. Rigid body (RIGU) restrains
 C89, C90, C91, C92, C93, C94
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 N25, C24, C26, C27
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C77, C82, C81, C80, C79, C78
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
6. Others
 Sof(N30B)=Sof(H29A)=Sof(H31D)=Sof(H31E)=Sof(H31F)=Sof(C32B)=Sof(H32D)=
 Sof(H32E)=Sof(H32F)=1-FVAR(1)
 Sof(N30)=Sof(H29)=Sof(H31A)=Sof(H31B)=Sof(H31C)=Sof(C32)=Sof(H32A)=Sof(H32B)=
 Sof(H32C)=FVAR(1)
 Sof(C40B)=Sof(H40A)=Sof(H40B)=Sof(H40C)=Sof(C39B)=Sof(H39B)=Sof(C41B)=
 Sof(H41A)=Sof(H41B)=Sof(H41C)=Sof(N40B)=1-FVAR(2)
 Sof(N40)=Sof(C39)=Sof(H39)=Sof(C42)=Sof(H42A)=Sof(H42B)=Sof(H42C)=Sof(C41)=
 Sof(H41D)=Sof(H41E)=Sof(H41F)=FVAR(2)
 Fixed Sof: Zn1(0.5) O23(0.5) O101(0.5) N25(0.5) N103(0.5) C24(0.5) H24(0.5)
 C26(0.5) H26A(0.5) H26B(0.5) H26C(0.5) C27(0.5) H27A(0.5) H27B(0.5) H27C(0.5)
 C102(0.5) H102(0.5) C104(0.5) H10A(0.5) H10B(0.5) H10C(0.5) C105(0.5)
 H10D(0.5) H10E(0.5) H10F(0.5)
7.a Me refined with riding coordinates:
 C26(H26A,H26B,H26C), C27(H27A,H27B,H27C), C31(H31D,H31E,H31F), C31(H31A,H31B,
 H31C), C32(H32A,H32B,H32C), C32B(H32D,H32E,H32F), C40B(H40A,H40B,H40C),
 C42(H42A,H42B,H42C), C104(H10A,H10B,H10C), C105(H10D,H10E,H10F), C41B(H41A,
 H41B,H41C), C41(H41D,H41E,H41F)
7.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C7(H7), C8(H8), C12(H12), C13(H13), C15(H15), C16(H16),
 C18(H18), C19(H19), C21(H21), C22(H22), C24(H24), C29(H29), C29(H29A),
 C34(H34), C39(H39), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57), C59(H59),
  C60(H60), C61(H61), C62(H62), C63(H63), C65(H65), C66(H66), C67(H67),
 C68(H68), C69(H69), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75), C78(H78),
  C79(H79), C80(H80), C81(H81), C82(H82), C84(H84), C85(H85), C86(H86),
 C87(H87), C88(H88), C90(H90), C91(H91), C92(H92), C93(H93), C94(H94), C96(H96),
  C97(H97), C98(H98), C99(H99), C100(H100), C102(H102), C39B(H39B)
7.c Idealised Me refined as rotating group:
 N3(H3A,H3B,H3C), N4(H4A,H4B,H4C), N5(H5A,H5B,H5C), N6(H6A,H6B,H6C), C36(H36A,
 H36B,H36C), C37(H37A,H37B,H37C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.51658(3) 0.04055(2) 0.30836(2) 0.04054(10) Uani 1 1 d . . . . .
Pt2 Pt 0.50502(3) 0.15682(2) 0.96259(2) 0.04790(11) Uani 1 1 d . . . . .
Zn1 Zn 0.53209(12) 0.50022(10) 0.49586(9) 0.0312(4) Uani 0.5 1 d . . P . .
Cl1 Cl 0.51708(19) -0.07022(10) 0.26726(11) 0.0559(4) Uani 1 1 d . . . . .
Cl2 Cl 0.4745(2) 0.06460(13) 1.06597(10) 0.0685(6) Uani 1 1 d . . . . .
O23 O 0.7093(8) 0.5062(7) 0.4765(6) 0.054(3) Uani 0.5 1 d . . P . .
O28 O 0.5037(8) 0.2570(4) 0.1408(4) 0.091(2) Uani 1 1 d . . . . .
O33 O 0.7606(8) 0.1015(9) 0.0991(5) 0.141(5) Uani 1 1 d . . . . .
O38 O 0.6635(7) -0.0598(6) 0.4838(4) 0.103(3) Uani 1 1 d D . . . .
O101 O -0.343(2) 0.5593(15) 1.0843(15) 0.143(8) Uiso 0.5 1 d . . P . .
N1 N 0.5116(5) 0.3859(3) 0.5394(3) 0.0370(11) Uani 1 1 d . . . . .
N2 N 0.4954(5) 0.4799(3) 0.3994(3) 0.0364(11) Uani 1 1 d . . . . .
N3 N 0.5600(7) 0.1027(4) 0.2051(3) 0.0586(18) Uani 1 1 d . . . . .
H3A H 0.5578 0.1533 0.2053 0.088 Uiso 1 1 calc GR . . . .
H3B H 0.5114 0.0917 0.1771 0.088 Uiso 1 1 calc GR . . . .
H3C H 0.6302 0.0908 0.1871 0.088 Uiso 1 1 calc GR . . . .
N4 N 0.4730(6) -0.0222(4) 0.4120(3) 0.0546(16) Uani 1 1 d . . . . .
H4A H 0.5344 -0.0289 0.4342 0.082 Uiso 1 1 calc GR . . . .
H4B H 0.4446 -0.0683 0.4108 0.082 Uiso 1 1 calc GR . . . .
H4C H 0.4208 0.0030 0.4370 0.082 Uiso 1 1 calc GR . . . .
N5 N 0.4011(7) 0.0972(5) 0.9176(4) 0.070(2) Uani 1 1 d . . . . .
H5A H 0.3301 0.1136 0.9262 0.105 Uiso 1 1 calc GR . . . .
H5B H 0.4032 0.0466 0.9376 0.105 Uiso 1 1 calc GR . . . .
H5C H 0.4242 0.1051 0.8691 0.105 Uiso 1 1 calc GR . . . .
N6 N 0.6132(6) 0.2112(4) 1.0071(4) 0.0537(15) Uani 1 1 d . . . . .
H6A H 0.6488 0.2501 0.9729 0.081 Uiso 1 1 calc GR . . . .
H6B H 0.6643 0.1777 1.0243 0.081 Uiso 1 1 calc GR . . . .
H6C H 0.5749 0.2301 1.0438 0.081 Uiso 1 1 calc GR . . . .
N14 N 0.5144(5) 0.1377(3) 0.3459(3) 0.0421(12) Uani 1 1 d . . . . .
N20 N 0.5202(6) 0.2392(3) 0.8710(3) 0.0471(14) Uani 1 1 d . . . . .
N25 N 0.8749(14) 0.4676(15) 0.5129(13) 0.096(5) Uani 0.5 1 d . U P . .
N30 N 0.4076(13) 0.3644(9) 0.1403(8) 0.065(5) Uiso 0.58(3) 1 d D U P A 1
N30B N 0.364(4) 0.345(3) 0.122(3) 0.144(14) Uiso 0.42(3) 1 d . U P A 2
N35 N 0.8896(7) 0.0471(6) 0.1630(6) 0.079(2) Uani 1 1 d . . . . .
N40 N 0.8247(14) -0.0948(11) 0.4239(9) 0.069(5) Uiso 0.559(19) 1 d D . P B 1
N103 N -0.158(3) 0.5316(17) 1.0830(16) 0.120(8) Uiso 0.5 1 d . . P . .
C1 C 0.4892(6) 0.5332(4) 0.3380(3) 0.0384(13) Uani 1 1 d . . . . .
C2 C 0.4883(7) 0.4973(4) 0.2781(4) 0.0498(17) Uani 1 1 d . . . . .
H2 H 0.4847 0.5217 0.2295 0.060 Uiso 1 1 calc R . . . .
C3 C 0.4937(7) 0.4216(4) 0.3050(4) 0.0470(16) Uani 1 1 d . . . . .
H3 H 0.4948 0.3825 0.2786 0.056 Uiso 1 1 calc R . . . .
C4 C 0.4976(6) 0.4110(4) 0.3807(3) 0.0383(13) Uani 1 1 d . . . . .
C5 C 0.5050(6) 0.3402(4) 0.4280(4) 0.0383(13) Uani 1 1 d . . . . .
C6 C 0.5093(6) 0.3296(3) 0.5020(4) 0.0394(14) Uani 1 1 d . . . . .
C7 C 0.5086(7) 0.2569(4) 0.5493(4) 0.0494(17) Uani 1 1 d . . . . .
H7 H 0.5049 0.2087 0.5370 0.059 Uiso 1 1 calc R . . . .
C8 C 0.5143(7) 0.2702(4) 0.6172(4) 0.0431(15) Uani 1 1 d . . . . .
H8 H 0.5175 0.2330 0.6601 0.052 Uiso 1 1 calc R . . . .
C9 C 0.5142(6) 0.3511(4) 0.6095(3) 0.0393(14) Uani 1 1 d . . . . .
C10 C 0.5154(6) 0.3874(4) 0.6670(4) 0.0415(14) Uani 1 1 d . . . . .
C11 C 0.5093(6) 0.2704(4) 0.3984(4) 0.0431(14) Uani 1 1 d . . . . .
C12 C 0.4198(7) 0.2483(4) 0.3699(5) 0.0516(17) Uani 1 1 d . . . . .
H12 H 0.3551 0.2784 0.3682 0.062 Uiso 1 1 calc R . . . .
C13 C 0.4254(7) 0.1824(4) 0.3441(5) 0.0525(18) Uani 1 1 d . . . . .
H13 H 0.3640 0.1682 0.3243 0.063 Uiso 1 1 calc R . . . .
C15 C 0.6015(7) 0.1591(4) 0.3718(4) 0.0500(17) Uani 1 1 d . . . . .
H15 H 0.6660 0.1287 0.3714 0.060 Uiso 1 1 calc R . . . .
C16 C 0.6008(6) 0.2240(4) 0.3991(4) 0.0485(16) Uani 1 1 d . . . . .
H16 H 0.6635 0.2369 0.4184 0.058 Uiso 1 1 calc R . . . .
C17 C 0.5189(6) 0.3380(4) 0.7393(3) 0.0421(14) Uani 1 1 d . . . . .
C18 C 0.6108(7) 0.2950(5) 0.7540(4) 0.0504(17) Uani 1 1 d . . . . .
H18 H 0.6755 0.2989 0.7184 0.060 Uiso 1 1 calc R . . . .
C19 C 0.6087(6) 0.2463(4) 0.8204(4) 0.0482(16) Uani 1 1 d . . . . .
H19 H 0.6725 0.2171 0.8298 0.058 Uiso 1 1 calc R . . . .
C21 C 0.4305(7) 0.2824(6) 0.8589(4) 0.062(2) Uani 1 1 d . . . . .
H21 H 0.3680 0.2785 0.8961 0.075 Uiso 1 1 calc R . . . .
C22 C 0.4278(8) 0.3318(5) 0.7941(4) 0.060(2) Uani 1 1 d . . . . .
H22 H 0.3639 0.3616 0.7866 0.071 Uiso 1 1 calc R . . . .
C24 C 0.7668(16) 0.4617(16) 0.5142(13) 0.080(6) Uani 0.5 1 d . U P . .
H24 H 0.7289 0.4194 0.5472 0.096 Uiso 0.5 1 calc R . P . .
C26 C 0.928(2) 0.414(2) 0.5704(19) 0.119(8) Uani 0.5 1 d . U P . .
H26A H 1.0086 0.4249 0.5626 0.179 Uiso 0.5 1 calc R . P . .
H26B H 0.8951 0.4213 0.6183 0.179 Uiso 0.5 1 calc R . P . .
H26C H 0.9153 0.3611 0.5674 0.179 Uiso 0.5 1 calc R . P . .
C27 C 0.939(2) 0.529(3) 0.466(2) 0.153(14) Uani 0.5 1 d . U P . .
H27A H 1.0173 0.5235 0.4727 0.230 Uiso 0.5 1 calc R . P . .
H27B H 0.9327 0.5283 0.4160 0.230 Uiso 0.5 1 calc R . P . .
H27C H 0.9114 0.5770 0.4772 0.230 Uiso 0.5 1 calc R . P . .
C29 C 0.4268(12) 0.2941(7) 0.1652(6) 0.089(3) Uani 1 1 d . . . . .
H29 H 0.3771 0.2682 0.2063 0.106 Uiso 0.58(3) 1 calc R . P A 1
H29A H 0.4090 0.2874 0.2161 0.106 Uiso 0.42(3) 1 calc R . P A 2
C31 C 0.3067(16) 0.3999(11) 0.1712(12) 0.154(8) Uani 1 1 d . . . . .
H31D H 0.2736 0.3695 0.2184 0.231 Uiso 0.42(3) 1 calc R . P A 2
H31E H 0.3627 0.4356 0.1777 0.231 Uiso 0.42(3) 1 calc R . P A 2
H31F H 0.2483 0.4284 0.1478 0.231 Uiso 0.42(3) 1 calc R . P A 2
H31A H 0.3052 0.4533 0.1460 0.231 Uiso 0.58(3) 1 calc R . P A 1
H31B H 0.2403 0.3728 0.1656 0.231 Uiso 0.58(3) 1 calc R . P A 1
H31C H 0.3077 0.3971 0.2226 0.231 Uiso 0.58(3) 1 calc R . P A 1
C32 C 0.484(3) 0.414(2) 0.090(2) 0.146(14) Uiso 0.58(3) 1 d . U P A 1
H32A H 0.4519 0.4648 0.0789 0.220 Uiso 0.58(3) 1 calc R . P A 1
H32B H 0.5525 0.4182 0.1106 0.220 Uiso 0.58(3) 1 calc R . P A 1
H32C H 0.5024 0.3950 0.0459 0.220 Uiso 0.58(3) 1 calc R . P A 1
C32B C 0.412(7) 0.372(5) 0.0597(15) 0.22(3) Uiso 0.42(3) 1 d D U P A 2
H32D H 0.3623 0.4071 0.0337 0.337 Uiso 0.42(3) 1 calc R . P A 2
H32E H 0.4803 0.3992 0.0614 0.337 Uiso 0.42(3) 1 calc R . P A 2
H32F H 0.4303 0.3302 0.0347 0.337 Uiso 0.42(3) 1 calc R . P A 2
C34 C 0.8596(11) 0.1017(10) 0.1152(7) 0.103(4) Uani 1 1 d . . . . .
H34 H 0.9105 0.1423 0.0916 0.124 Uiso 1 1 calc R . . . .
C36 C 0.8115(15) -0.0146(10) 0.2016(15) 0.171(10) Uani 1 1 d . . . . .
H36A H 0.7535 -0.0192 0.1725 0.257 Uiso 1 1 calc GR . . . .
H36B H 0.7769 -0.0035 0.2478 0.257 Uiso 1 1 calc GR . . . .
H36C H 0.8515 -0.0625 0.2105 0.257 Uiso 1 1 calc GR . . . .
C37 C 0.9968(10) 0.0417(10) 0.1843(8) 0.113(5) Uani 1 1 d . . . . .
H37A H 1.0468 0.0809 0.1518 0.170 Uiso 1 1 calc GR . . . .
H37B H 1.0267 -0.0087 0.1819 0.170 Uiso 1 1 calc GR . . . .
H37C H 0.9908 0.0490 0.2338 0.170 Uiso 1 1 calc GR . . . .
C39 C 0.7738(13) -0.0546(13) 0.4623(11) 0.092(7) Uiso 0.559(19) 1 d D . P B 1
H39 H 0.8152 -0.0181 0.4774 0.110 Uiso 0.559(19) 1 calc R . P B 1
C40B C 0.903(3) -0.167(3) 0.422(3) 0.18(2) Uiso 0.441(19) 1 d D . P B 2
H40A H 0.9402 -0.1507 0.3716 0.265 Uiso 0.441(19) 1 calc R . P B 2
H40B H 0.9545 -0.1616 0.4545 0.265 Uiso 0.441(19) 1 calc R . P B 2
H40C H 0.8770 -0.2198 0.4305 0.265 Uiso 0.441(19) 1 calc R . P B 2
C42 C 0.754(4) -0.149(2) 0.405(2) 0.193(15) Uiso 0.559(19) 1 d D U P B 1
H42A H 0.7988 -0.1785 0.3750 0.289 Uiso 0.559(19) 1 calc R . P B 1
H42B H 0.7168 -0.1825 0.4496 0.289 Uiso 0.559(19) 1 calc R . P B 1
H42C H 0.6976 -0.1211 0.3790 0.289 Uiso 0.559(19) 1 calc R . P B 1
C52 C -0.0969(7) 0.1812(5) 0.8447(4) 0.0525(17) Uani 1 1 d . . . . .
C53 C -0.1042(8) 0.1771(6) 0.7748(5) 0.066(2) Uani 1 1 d . . . . .
H53 H -0.0567 0.2093 0.7365 0.080 Uiso 1 1 calc R . . . .
C54 C -0.1783(10) 0.1276(8) 0.7581(6) 0.083(3) Uani 1 1 d . . . . .
H54 H -0.1816 0.1266 0.7092 0.100 Uiso 1 1 calc R . . . .
C55 C -0.2469(9) 0.0800(6) 0.8133(7) 0.079(3) Uani 1 1 d . . . . .
H55 H -0.2972 0.0457 0.8025 0.095 Uiso 1 1 calc R . . . .
C56 C -0.2426(8) 0.0820(5) 0.8836(6) 0.064(2) Uani 1 1 d . . . . .
H56 H -0.2895 0.0489 0.9217 0.077 Uiso 1 1 calc R . . . .
C57 C -0.1703(7) 0.1320(5) 0.8989(5) 0.0557(19) Uani 1 1 d . . . . .
H57 H -0.1695 0.1337 0.9478 0.067 Uiso 1 1 calc R . . . .
C58 C -0.1053(7) 0.3008(5) 0.9029(5) 0.0582(19) Uani 1 1 d . . . . .
C59 C -0.1778(8) 0.3419(6) 0.8594(6) 0.067(2) Uani 1 1 d . . . . .
H59 H -0.1712 0.3373 0.8106 0.080 Uiso 1 1 calc R . . . .
C60 C -0.2585(11) 0.3888(7) 0.8847(7) 0.085(3) Uani 1 1 d . . . . .
H60 H -0.3078 0.4141 0.8540 0.101 Uiso 1 1 calc R . . . .
C61 C -0.2673(10) 0.3989(6) 0.9552(8) 0.087(3) Uani 1 1 d . . . . .
H61 H -0.3197 0.4329 0.9724 0.104 Uiso 1 1 calc R . . . .
C62 C -0.1997(11) 0.3592(7) 0.9987(7) 0.084(3) Uani 1 1 d . . . . .
H62 H -0.2056 0.3646 1.0472 0.101 Uiso 1 1 calc R . . . .
C63 C -0.1215(9) 0.3103(6) 0.9728(6) 0.068(2) Uani 1 1 d . . . . .
H63 H -0.0770 0.2821 1.0053 0.081 Uiso 1 1 calc R . . . .
C64 C 0.0698(8) 0.2901(7) 0.7986(5) 0.071(3) Uani 1 1 d . . . . .
C65 C 0.1506(10) 0.2500(10) 0.7624(7) 0.100(4) Uani 1 1 d . . . . .
H65 H 0.1567 0.1966 0.7787 0.120 Uiso 1 1 calc R . . . .
C66 C 0.2226(14) 0.2893(15) 0.7017(9) 0.138(8) Uani 1 1 d . . . . .
H66 H 0.2787 0.2607 0.6799 0.165 Uiso 1 1 calc R . . . .
C67 C 0.2195(14) 0.3599(18) 0.6732(10) 0.166(11) Uani 1 1 d . . . . .
H67 H 0.2646 0.3816 0.6286 0.199 Uiso 1 1 calc R . . . .
C68 C 0.1457(12) 0.4050(11) 0.7112(9) 0.120(6) Uani 1 1 d . . . . .
H68 H 0.1462 0.4589 0.6960 0.144 Uiso 1 1 calc R . . . .
C69 C 0.0717(10) 0.3670(8) 0.7720(7) 0.090(4) Uani 1 1 d . . . . .
H69 H 0.0200 0.3967 0.7961 0.108 Uiso 1 1 calc R . . . .
C70 C 0.0583(7) 0.1981(6) 0.9276(5) 0.062(2) Uani 1 1 d . . . . .
C71 C 0.0652(8) 0.1185(6) 0.9490(6) 0.072(3) Uani 1 1 d . . . . .
H71 H 0.0236 0.0875 0.9278 0.087 Uiso 1 1 calc R . . . .
C72 C 0.1298(9) 0.0833(7) 0.9993(7) 0.083(3) Uani 1 1 d . . . . .
H72 H 0.1321 0.0294 1.0124 0.099 Uiso 1 1 calc R . . . .
C73 C 0.1914(10) 0.1285(8) 1.0306(7) 0.089(3) Uani 1 1 d . . . . .
H73 H 0.2336 0.1052 1.0667 0.107 Uiso 1 1 calc R . . . .
C74 C 0.1914(9) 0.2058(8) 1.0097(6) 0.078(3) Uani 1 1 d . . . . .
H74 H 0.2358 0.2362 1.0298 0.094 Uiso 1 1 calc R . . . .
C75 C 0.1258(8) 0.2403(7) 0.9586(5) 0.071(3) Uani 1 1 d . . . . .
H75 H 0.1270 0.2943 0.9444 0.085 Uiso 1 1 calc R . . . .
C77 C 1.0858(9) 0.7830(8) 0.5711(6) 0.082(3) Uani 1 1 d . U . . .
C78 C 1.1176(11) 0.7434(10) 0.5174(7) 0.106(4) Uani 1 1 d . U . . .
H78 H 1.0892 0.6931 0.5236 0.127 Uiso 1 1 calc R . . . .
C79 C 1.1942(14) 0.7768(13) 0.4506(8) 0.122(5) Uani 1 1 d . U . . .
H79 H 1.2137 0.7476 0.4150 0.147 Uiso 1 1 calc R . . . .
C80 C 1.2363(12) 0.8472(13) 0.4397(8) 0.115(4) Uani 1 1 d . U . . .
H80 H 1.2853 0.8692 0.3968 0.138 Uiso 1 1 calc R . . . .
C81 C 1.2069(10) 0.8846(11) 0.4909(7) 0.108(4) Uani 1 1 d . U . . .
H81 H 1.2350 0.9352 0.4833 0.130 Uiso 1 1 calc R . . . .
C82 C 1.1368(9) 0.8551(9) 0.5562(7) 0.090(3) Uani 1 1 d . U . . .
H82 H 1.1235 0.8852 0.5915 0.108 Uiso 1 1 calc R . . . .
C83 C 1.1018(9) 0.7212(7) 0.7023(6) 0.082(3) Uani 1 1 d . . . . .
C84 C 1.1301(11) 0.7616(9) 0.7499(8) 0.099(4) Uani 1 1 d . . . . .
H84 H 1.0908 0.8065 0.7554 0.119 Uiso 1 1 calc R . . . .
C85 C 1.2163(13) 0.7385(11) 0.7915(9) 0.116(5) Uani 1 1 d . . . . .
H85 H 1.2340 0.7676 0.8242 0.139 Uiso 1 1 calc R . . . .
C86 C 1.2721(14) 0.6757(14) 0.7843(9) 0.141(8) Uani 1 1 d . . . . .
H86 H 1.3283 0.6598 0.8132 0.169 Uiso 1 1 calc R . . . .
C87 C 1.2500(13) 0.6321(12) 0.7350(10) 0.133(7) Uani 1 1 d . . . . .
H87 H 1.2907 0.5878 0.7295 0.160 Uiso 1 1 calc R . . . .
C88 C 1.1665(10) 0.6568(8) 0.6952(8) 0.099(4) Uani 1 1 d . . . . .
H88 H 1.1516 0.6289 0.6609 0.119 Uiso 1 1 calc R . . . .
C89 C 0.9320(10) 0.6755(10) 0.6453(13) 0.138(6) Uani 1 1 d . U . . .
C90 C 0.8652(12) 0.6818(12) 0.5897(14) 0.161(6) Uani 1 1 d . U . . .
H90 H 0.8664 0.7281 0.5547 0.193 Uiso 1 1 calc R . . . .
C91 C 0.7980(14) 0.6206(14) 0.5860(18) 0.185(7) Uani 1 1 d . U . . .
H91 H 0.7560 0.6263 0.5475 0.222 Uiso 1 1 calc R . . . .
C92 C 0.7902(17) 0.5543(16) 0.6345(19) 0.201(8) Uani 1 1 d . U . . .
H92 H 0.7412 0.5147 0.6316 0.241 Uiso 1 1 calc R . . . .
C93 C 0.8529(17) 0.5449(14) 0.6873(19) 0.201(8) Uani 1 1 d . U . . .
H93 H 0.8497 0.4975 0.7209 0.241 Uiso 1 1 calc R . . . .
C94 C 0.9239(14) 0.6045(12) 0.6940(15) 0.167(6) Uani 1 1 d . U . . .
H94 H 0.9668 0.5960 0.7321 0.200 Uiso 1 1 calc R . . . .
C95 C 0.9219(8) 0.8099(6) 0.6776(6) 0.072(3) Uani 1 1 d . . . . .
C96 C 0.8658(10) 0.7929(9) 0.7484(7) 0.092(4) Uani 1 1 d . . . . .
H96 H 0.8802 0.7456 0.7783 0.110 Uiso 1 1 calc R . . . .
C97 C 0.7922(10) 0.8393(11) 0.7773(9) 0.103(5) Uani 1 1 d . . . . .
H97 H 0.7565 0.8239 0.8259 0.123 Uiso 1 1 calc R . . . .
C98 C 0.7693(10) 0.9076(10) 0.7369(10) 0.108(6) Uani 1 1 d . . . . .
H98 H 0.7194 0.9411 0.7573 0.129 Uiso 1 1 calc R . . . .
C99 C 0.8194(10) 0.9278(8) 0.6661(10) 0.099(4) Uani 1 1 d . . . . .
H99 H 0.8032 0.9750 0.6368 0.119 Uiso 1 1 calc R . . . .
C100 C 0.8946(9) 0.8785(7) 0.6374(8) 0.086(3) Uani 1 1 d . . . . .
H100 H 0.9280 0.8929 0.5882 0.104 Uiso 1 1 calc R . . . .
C102 C -0.257(4) 0.541(2) 1.100(2) 0.134(12) Uiso 0.5 1 d . . P . .
H102 H -0.2702 0.5245 1.1510 0.161 Uiso 0.5 1 calc R . P . .
C104 C -0.144(4) 0.569(3) 0.997(2) 0.153(14) Uiso 0.5 1 d . . P . .
H10A H -0.0665 0.5658 0.9752 0.229 Uiso 0.5 1 calc R . P . .
H10B H -0.1924 0.5411 0.9747 0.229 Uiso 0.5 1 calc R . P . .
H10C H -0.1657 0.6224 0.9901 0.229 Uiso 0.5 1 calc R . P . .
C105 C -0.076(4) 0.496(3) 1.109(2) 0.161(16) Uiso 0.5 1 d . . P . .
H10D H -0.0080 0.5065 1.0733 0.242 Uiso 0.5 1 calc R . P . .
H10E H -0.0647 0.5124 1.1528 0.242 Uiso 0.5 1 calc R . P . .
H10F H -0.0926 0.4408 1.1210 0.242 Uiso 0.5 1 calc R . P . .
B51 B -0.0174(8) 0.2424(6) 0.8683(5) 0.056(2) Uani 1 1 d . . . . .
B76 B 1.0103(10) 0.7476(8) 0.6492(8) 0.078(3) Uani 1 1 d . . . . .
C39B C 0.732(3) -0.110(2) 0.4802(19) 0.104(10) Uiso 0.441(19) 1 d . . P B 2
H39B H 0.7236 -0.1490 0.5226 0.125 Uiso 0.441(19) 1 calc R . P B 2
C41B C 0.805(5) -0.057(3) 0.373(3) 0.194(15) Uiso 0.441(19) 1 d D U P B 2
H41A H 0.8642 -0.0615 0.3329 0.291 Uiso 0.441(19) 1 calc R . P B 2
H41B H 0.7322 -0.0585 0.3566 0.291 Uiso 0.441(19) 1 calc R . P B 2
H41C H 0.8142 -0.0092 0.3874 0.291 Uiso 0.441(19) 1 calc R . P B 2
C41 C 0.9406(16) -0.0967(17) 0.4029(14) 0.111(9) Uiso 0.559(19) 1 d D . P B 1
H41D H 0.9575 -0.1339 0.3724 0.167 Uiso 0.559(19) 1 calc R . P B 1
H41E H 0.9685 -0.0462 0.3757 0.167 Uiso 0.559(19) 1 calc R . P B 1
H41F H 0.9766 -0.1114 0.4459 0.167 Uiso 0.559(19) 1 calc R . P B 1
N40B N 0.810(2) -0.1201(16) 0.4329(14) 0.079(7) Uiso 0.441(19) 1 d D . P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Cl1 2.2958(17) . ?
Pt1 N3 2.048(6) . ?
Pt1 N4 2.059(6) . ?
Pt1 N14 2.027(5) . ?
Pt2 Cl2 2.2810(19) . ?
Pt2 N5 2.065(8) . ?
Pt2 N6 2.040(6) . ?
Pt2 N20 2.028(6) . ?
Zn1 Zn1 0.771(3) 2_666 ?
Zn1 O23 2.127(10) . ?
Zn1 N1 2.104(5) 2_666 ?
Zn1 N1 2.049(5) . ?
Zn1 N2 2.079(5) . ?
Zn1 N2 2.095(5) 2_666 ?
O23 C24 1.24(3) . ?
O28 C29 1.234(14) . ?
O33 C34 1.288(16) . ?
O38 C39 1.337(15) . ?
O38 C39B 1.22(4) . ?
O101 C102 1.16(4) . ?
N1 Zn1 2.104(5) 2_666 ?
N1 C6 1.367(8) . ?
N1 C9 1.363(8) . ?
N2 Zn1 2.095(5) 2_666 ?
N2 C1 1.362(8) . ?
N2 C4 1.362(8) . ?
N3 H3A 0.9100 . ?
N3 H3B 0.9100 . ?
N3 H3C 0.9100 . ?
N4 H4A 0.9100 . ?
N4 H4B 0.9100 . ?
N4 H4C 0.9100 . ?
N5 H5A 0.9100 . ?
N5 H5B 0.9100 . ?
N5 H5C 0.9100 . ?
N6 H6A 0.9100 . ?
N6 H6B 0.9100 . ?
N6 H6C 0.9100 . ?
N14 C13 1.341(10) . ?
N14 C15 1.331(9) . ?
N20 C19 1.319(9) . ?
N20 C21 1.353(10) . ?
N25 C24 1.32(3) . ?
N25 C26 1.52(4) . ?
N25 C27 1.41(4) . ?
N30 C29 1.285(19) . ?
N30 C31 1.48(2) . ?
N30 C32 1.40(4) . ?
N30B C29 1.40(5) . ?
N30B C31 1.58(5) . ?
N30B C32B 1.25(6) . ?
N35 C34 1.284(16) . ?
N35 C36 1.46(2) . ?
N35 C37 1.421(14) . ?
N40 C39 1.24(3) . ?
N40 C42 1.438(19) . ?
N40 C41 1.405(16) . ?
N103 C102 1.21(4) . ?
N103 C104 1.62(5) . ?
N103 C105 1.29(5) . ?
C1 C2 1.439(9) . ?
C1 C10 1.411(9) 2_666 ?
C2 H2 0.9500 . ?
C2 C3 1.354(10) . ?
C3 H3 0.9500 . ?
C3 C4 1.435(9) . ?
C4 C5 1.408(9) . ?
C5 C6 1.403(9) . ?
C5 C11 1.483(9) . ?
C6 C7 1.423(9) . ?
C7 H7 0.9500 . ?
C7 C8 1.387(10) . ?
C8 H8 0.9500 . ?
C8 C9 1.431(9) . ?
C9 C10 1.401(10) . ?
C10 C1 1.411(9) 2_666 ?
C10 C17 1.485(9) . ?
C11 C12 1.390(11) . ?
C11 C16 1.382(10) . ?
C12 H12 0.9500 . ?
C12 C13 1.376(10) . ?
C13 H13 0.9500 . ?
C15 H15 0.9500 . ?
C15 C16 1.379(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.382(10) . ?
C17 C22 1.391(11) . ?
C18 H18 0.9500 . ?
C18 C19 1.380(10) . ?
C19 H19 0.9500 . ?
C21 H21 0.9500 . ?
C21 C22 1.370(10) . ?
C22 H22 0.9500 . ?
C24 H24 0.9500 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C29 H29 0.9500 . ?
C29 H29A 0.9500 . ?
C31 H31D 0.9800 . ?
C31 H31E 0.9800 . ?
C31 H31F 0.9800 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C32B H32D 0.9800 . ?
C32B H32E 0.9800 . ?
C32B H32F 0.9800 . ?
C34 H34 0.9500 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C39 H39 0.9500 . ?
C40B H40A 0.9800 . ?
C40B H40B 0.9800 . ?
C40B H40C 0.9800 . ?
C40B N40B 1.409(19) . ?
C42 H42A 0.9800 . ?
C42 H42B 0.9800 . ?
C42 H42C 0.9800 . ?
C52 C53 1.376(12) . ?
C52 C57 1.411(12) . ?
C52 B51 1.653(13) . ?
C53 H53 0.9500 . ?
C53 C54 1.394(15) . ?
C54 H54 0.9500 . ?
C54 C55 1.379(17) . ?
C55 H55 0.9500 . ?
C55 C56 1.369(16) . ?
C56 H56 0.9500 . ?
C56 C57 1.372(13) . ?
C57 H57 0.9500 . ?
C58 C59 1.404(13) . ?
C58 C63 1.374(13) . ?
C58 B51 1.655(14) . ?
C59 H59 0.9500 . ?
C59 C60 1.385(15) . ?
C60 H60 0.9500 . ?
C60 C61 1.394(18) . ?
C61 H61 0.9500 . ?
C61 C62 1.351(18) . ?
C62 H62 0.9500 . ?
C62 C63 1.394(15) . ?
C63 H63 0.9500 . ?
C64 C65 1.398(17) . ?
C64 C69 1.366(17) . ?
C64 B51 1.654(14) . ?
C65 H65 0.9500 . ?
C65 C66 1.40(2) . ?
C66 H66 0.9500 . ?
C66 C67 1.27(3) . ?
C67 H67 0.9500 . ?
C67 C68 1.42(3) . ?
C68 H68 0.9500 . ?
C68 C69 1.408(17) . ?
C69 H69 0.9500 . ?
C70 C71 1.406(14) . ?
C70 C75 1.403(13) . ?
C70 B51 1.643(14) . ?
C71 H71 0.9500 . ?
C71 C72 1.384(14) . ?
C72 H72 0.9500 . ?
C72 C73 1.396(17) . ?
C73 H73 0.9500 . ?
C73 C74 1.362(18) . ?
C74 H74 0.9500 . ?
C74 C75 1.399(15) . ?
C75 H75 0.9500 . ?
C77 C78 1.380(17) . ?
C77 C82 1.397(19) . ?
C77 B76 1.634(18) . ?
C78 H78 0.9500 . ?
C78 C79 1.48(2) . ?
C79 H79 0.9500 . ?
C79 C80 1.33(3) . ?
C80 H80 0.9500 . ?
C80 C81 1.31(2) . ?
C81 H81 0.9500 . ?
C81 C82 1.405(17) . ?
C82 H82 0.9500 . ?
C83 C84 1.368(19) . ?
C83 C88 1.411(17) . ?
C83 B76 1.625(18) . ?
C84 H84 0.9500 . ?
C84 C85 1.420(19) . ?
C85 H85 0.9500 . ?
C85 C86 1.33(3) . ?
C86 H86 0.9500 . ?
C86 C87 1.41(3) . ?
C87 H87 0.9500 . ?
C87 C88 1.38(2) . ?
C88 H88 0.9500 . ?
C89 C90 1.43(3) . ?
C89 C94 1.41(3) . ?
C89 B76 1.639(19) . ?
C90 H90 0.9500 . ?
C90 C91 1.40(2) . ?
C91 H91 0.9500 . ?
C91 C92 1.34(4) . ?
C92 H92 0.9500 . ?
C92 C93 1.34(4) . ?
C93 H93 0.9500 . ?
C93 C94 1.42(3) . ?
C94 H94 0.9500 . ?
C95 C96 1.394(16) . ?
C95 C100 1.375(17) . ?
C95 B76 1.661(16) . ?
C96 H96 0.9500 . ?
C96 C97 1.353(18) . ?
C97 H97 0.9500 . ?
C97 C98 1.36(2) . ?
C98 H98 0.9500 . ?
C98 C99 1.37(2) . ?
C99 H99 0.9500 . ?
C99 C100 1.401(18) . ?
C100 H100 0.9500 . ?
C102 H102 0.9500 . ?
C104 H10A 0.9800 . ?
C104 H10B 0.9800 . ?
C104 H10C 0.9800 . ?
C105 H10D 0.9800 . ?
C105 H10E 0.9800 . ?
C105 H10F 0.9800 . ?
C39B H39B 0.9500 . ?
C39B N40B 1.25(4) . ?
C41B H41A 0.9800 . ?
C41B H41B 0.9800 . ?
C41B H41C 0.9800 . ?
C41B N40B 1.44(2) . ?
C41 H41D 0.9800 . ?
C41 H41E 0.9800 . ?
C41 H41F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt1 Cl1 90.9(2) . . ?
N3 Pt1 N4 179.9(3) . . ?
N4 Pt1 Cl1 88.9(2) . . ?
N14 Pt1 Cl1 179.17(19) . . ?
N14 Pt1 N3 89.8(3) . . ?
N14 Pt1 N4 90.3(3) . . ?
N5 Pt2 Cl2 89.2(2) . . ?
N6 Pt2 Cl2 89.6(2) . . ?
N6 Pt2 N5 177.0(3) . . ?
N20 Pt2 Cl2 175.9(2) . . ?
N20 Pt2 N5 88.2(3) . . ?
N20 Pt2 N6 93.1(3) . . ?
Zn1 Zn1 O23 176.8(5) 2_666 . ?
Zn1 Zn1 N1 75.3(3) 2_666 2_666 ?
Zn1 Zn1 N1 83.3(3) 2_666 . ?
Zn1 Zn1 N2 78.2(3) 2_666 2_666 ?
Zn1 Zn1 N2 80.5(3) 2_666 . ?
N1 Zn1 O23 102.9(4) 2_666 . ?
N1 Zn1 O23 98.4(4) . . ?
N1 Zn1 N1 158.66(9) . 2_666 ?
N1 Zn1 N2 88.7(2) . 2_666 ?
N1 Zn1 N2 88.8(2) . . ?
N2 Zn1 O23 99.1(4) 2_666 . ?
N2 Zn1 O23 102.2(4) . . ?
N2 Zn1 N1 86.9(2) 2_666 2_666 ?
N2 Zn1 N1 87.7(2) . 2_666 ?
N2 Zn1 N2 158.72(9) . 2_666 ?
C24 O23 Zn1 122.3(13) . . ?
Zn1 N1 Zn1 21.34(9) . 2_666 ?
C6 N1 Zn1 125.6(4) . 2_666 ?
C6 N1 Zn1 126.2(4) . . ?
C9 N1 Zn1 124.9(4) . 2_666 ?
C9 N1 Zn1 126.3(4) . . ?
C9 N1 C6 106.9(5) . . ?
Zn1 N2 Zn1 21.28(9) . 2_666 ?
C1 N2 Zn1 125.3(4) . 2_666 ?
C1 N2 Zn1 126.4(4) . . ?
C4 N2 Zn1 126.7(4) . 2_666 ?
C4 N2 Zn1 125.7(4) . . ?
C4 N2 C1 106.5(5) . . ?
Pt1 N3 H3A 109.5 . . ?
Pt1 N3 H3B 109.5 . . ?
Pt1 N3 H3C 109.5 . . ?
H3A N3 H3B 109.5 . . ?
H3A N3 H3C 109.5 . . ?
H3B N3 H3C 109.5 . . ?
Pt1 N4 H4A 109.5 . . ?
Pt1 N4 H4B 109.5 . . ?
Pt1 N4 H4C 109.5 . . ?
H4A N4 H4B 109.5 . . ?
H4A N4 H4C 109.5 . . ?
H4B N4 H4C 109.5 . . ?
Pt2 N5 H5A 109.5 . . ?
Pt2 N5 H5B 109.5 . . ?
Pt2 N5 H5C 109.5 . . ?
H5A N5 H5B 109.5 . . ?
H5A N5 H5C 109.5 . . ?
H5B N5 H5C 109.5 . . ?
Pt2 N6 H6A 109.5 . . ?
Pt2 N6 H6B 109.5 . . ?
Pt2 N6 H6C 109.5 . . ?
H6A N6 H6B 109.5 . . ?
H6A N6 H6C 109.5 . . ?
H6B N6 H6C 109.5 . . ?
C13 N14 Pt1 120.4(5) . . ?
C15 N14 Pt1 121.0(5) . . ?
C15 N14 C13 118.5(6) . . ?
C19 N20 Pt2 122.5(5) . . ?
C19 N20 C21 119.6(6) . . ?
C21 N20 Pt2 117.5(5) . . ?
C24 N25 C26 119(3) . . ?
C24 N25 C27 121(3) . . ?
C27 N25 C26 119(2) . . ?
C29 N30 C31 120.2(15) . . ?
C29 N30 C32 124(2) . . ?
C32 N30 C31 116(2) . . ?
C29 N30B C31 107(4) . . ?
C32B N30B C29 115(5) . . ?
C32B N30B C31 121(5) . . ?
C34 N35 C36 120.8(13) . . ?
C34 N35 C37 124.6(13) . . ?
C37 N35 C36 114.6(13) . . ?
C39 N40 C42 113(2) . . ?
C39 N40 C41 127(2) . . ?
C41 N40 C42 119(3) . . ?
C102 N103 C104 100(3) . . ?
C102 N103 C105 140(4) . . ?
C105 N103 C104 119(3) . . ?
N2 C1 C2 110.3(6) . . ?
N2 C1 C10 125.5(6) . 2_666 ?
C10 C1 C2 124.2(6) 2_666 . ?
C1 C2 H2 127.0 . . ?
C3 C2 C1 106.0(6) . . ?
C3 C2 H2 127.0 . . ?
C2 C3 H3 126.3 . . ?
C2 C3 C4 107.5(6) . . ?
C4 C3 H3 126.3 . . ?
N2 C4 C3 109.7(6) . . ?
N2 C4 C5 125.4(6) . . ?
C5 C4 C3 125.0(6) . . ?
C4 C5 C11 118.5(6) . . ?
C6 C5 C4 125.3(6) . . ?
C6 C5 C11 116.2(6) . . ?
N1 C6 C5 125.9(6) . . ?
N1 C6 C7 110.2(6) . . ?
C5 C6 C7 123.9(6) . . ?
C6 C7 H7 126.7 . . ?
C8 C7 C6 106.5(6) . . ?
C8 C7 H7 126.7 . . ?
C7 C8 H8 126.8 . . ?
C7 C8 C9 106.3(6) . . ?
C9 C8 H8 126.8 . . ?
N1 C9 C8 110.0(6) . . ?
N1 C9 C10 126.2(6) . . ?
C10 C9 C8 123.8(6) . . ?
C1 C10 C17 117.6(6) 2_666 . ?
C9 C10 C1 125.2(6) . 2_666 ?
C9 C10 C17 117.1(6) . . ?
C12 C11 C5 120.9(7) . . ?
C16 C11 C5 121.8(7) . . ?
C16 C11 C12 117.3(6) . . ?
C11 C12 H12 120.2 . . ?
C13 C12 C11 119.6(7) . . ?
C13 C12 H12 120.2 . . ?
N14 C13 C12 122.4(7) . . ?
N14 C13 H13 118.8 . . ?
C12 C13 H13 118.8 . . ?
N14 C15 H15 119.0 . . ?
N14 C15 C16 122.0(7) . . ?
C16 C15 H15 119.0 . . ?
C11 C16 H16 119.9 . . ?
C15 C16 C11 120.2(7) . . ?
C15 C16 H16 119.9 . . ?
C18 C17 C10 121.6(6) . . ?
C18 C17 C22 117.6(6) . . ?
C22 C17 C10 120.8(7) . . ?
C17 C18 H18 120.0 . . ?
C19 C18 C17 120.1(7) . . ?
C19 C18 H18 120.0 . . ?
N20 C19 C18 121.6(7) . . ?
N20 C19 H19 119.2 . . ?
C18 C19 H19 119.2 . . ?
N20 C21 H21 119.3 . . ?
N20 C21 C22 121.4(7) . . ?
C22 C21 H21 119.3 . . ?
C17 C22 H22 120.1 . . ?
C21 C22 C17 119.7(8) . . ?
C21 C22 H22 120.1 . . ?
O23 C24 N25 126(3) . . ?
O23 C24 H24 116.8 . . ?
N25 C24 H24 116.8 . . ?
N25 C26 H26A 109.5 . . ?
N25 C26 H26B 109.5 . . ?
N25 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N25 C27 H27A 109.5 . . ?
N25 C27 H27B 109.5 . . ?
N25 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
O28 C29 N30 126.0(13) . . ?
O28 C29 N30B 124(2) . . ?
O28 C29 H29 117.0 . . ?
O28 C29 H29A 118.0 . . ?
N30 C29 H29 117.0 . . ?
N30B C29 H29A 118.0 . . ?
N30 C31 H31A 109.5 . . ?
N30 C31 H31B 109.5 . . ?
N30 C31 H31C 109.5 . . ?
N30B C31 H31D 109.5 . . ?
N30B C31 H31E 109.5 . . ?
N30B C31 H31F 109.5 . . ?
H31D C31 H31E 109.5 . . ?
H31D C31 H31F 109.5 . . ?
H31E C31 H31F 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N30 C32 H32A 109.5 . . ?
N30 C32 H32B 109.5 . . ?
N30 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
N30B C32B H32D 109.5 . . ?
N30B C32B H32E 109.5 . . ?
N30B C32B H32F 109.5 . . ?
H32D C32B H32E 109.5 . . ?
H32D C32B H32F 109.5 . . ?
H32E C32B H32F 109.5 . . ?
O33 C34 H34 119.9 . . ?
N35 C34 O33 120.2(15) . . ?
N35 C34 H34 119.9 . . ?
N35 C36 H36A 109.5 . . ?
N35 C36 H36B 109.5 . . ?
N35 C36 H36C 109.5 . . ?
H36A C36 H36B 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N35 C37 H37A 109.5 . . ?
N35 C37 H37B 109.5 . . ?
N35 C37 H37C 109.5 . . ?
H37A C37 H37B 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
O38 C39 H39 118.3 . . ?
N40 C39 O38 123(2) . . ?
N40 C39 H39 118.3 . . ?
H40A C40B H40B 109.5 . . ?
H40A C40B H40C 109.5 . . ?
H40B C40B H40C 109.5 . . ?
N40B C40B H40A 109.5 . . ?
N40B C40B H40B 109.5 . . ?
N40B C40B H40C 109.5 . . ?
N40 C42 H42A 109.5 . . ?
N40 C42 H42B 109.5 . . ?
N40 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C53 C52 C57 115.7(8) . . ?
C53 C52 B51 125.2(8) . . ?
C57 C52 B51 118.9(7) . . ?
C52 C53 H53 118.7 . . ?
C52 C53 C54 122.6(10) . . ?
C54 C53 H53 118.7 . . ?
C53 C54 H54 120.4 . . ?
C55 C54 C53 119.2(10) . . ?
C55 C54 H54 120.4 . . ?
C54 C55 H55 119.9 . . ?
C56 C55 C54 120.3(9) . . ?
C56 C55 H55 119.9 . . ?
C55 C56 H56 120.2 . . ?
C55 C56 C57 119.6(10) . . ?
C57 C56 H56 120.2 . . ?
C52 C57 H57 118.7 . . ?
C56 C57 C52 122.6(9) . . ?
C56 C57 H57 118.7 . . ?
C59 C58 B51 118.4(8) . . ?
C63 C58 C59 114.6(9) . . ?
C63 C58 B51 126.9(9) . . ?
C58 C59 H59 118.6 . . ?
C60 C59 C58 122.7(10) . . ?
C60 C59 H59 118.6 . . ?
C59 C60 H60 120.1 . . ?
C59 C60 C61 119.9(12) . . ?
C61 C60 H60 120.1 . . ?
C60 C61 H61 120.7 . . ?
C62 C61 C60 118.6(11) . . ?
C62 C61 H61 120.7 . . ?
C61 C62 H62 119.8 . . ?
C61 C62 C63 120.5(11) . . ?
C63 C62 H62 119.8 . . ?
C58 C63 C62 123.6(11) . . ?
C58 C63 H63 118.2 . . ?
C62 C63 H63 118.2 . . ?
C65 C64 B51 118.7(11) . . ?
C69 C64 C65 115.1(11) . . ?
C69 C64 B51 126.1(10) . . ?
C64 C65 H65 120.3 . . ?
C64 C65 C66 119.4(17) . . ?
C66 C65 H65 120.3 . . ?
C65 C66 H66 117.0 . . ?
C67 C66 C65 126(2) . . ?
C67 C66 H66 117.0 . . ?
C66 C67 H67 121.5 . . ?
C66 C67 C68 117.1(15) . . ?
C68 C67 H67 121.5 . . ?
C67 C68 H68 121.1 . . ?
C69 C68 C67 117.7(18) . . ?
C69 C68 H68 121.1 . . ?
C64 C69 C68 124.1(15) . . ?
C64 C69 H69 117.9 . . ?
C68 C69 H69 117.9 . . ?
C71 C70 B51 124.9(8) . . ?
C75 C70 C71 115.3(9) . . ?
C75 C70 B51 119.8(9) . . ?
C70 C71 H71 118.4 . . ?
C72 C71 C70 123.2(11) . . ?
C72 C71 H71 118.4 . . ?
C71 C72 H72 120.6 . . ?
C71 C72 C73 118.8(12) . . ?
C73 C72 H72 120.6 . . ?
C72 C73 H73 119.8 . . ?
C74 C73 C72 120.5(10) . . ?
C74 C73 H73 119.8 . . ?
C73 C74 H74 120.1 . . ?
C73 C74 C75 119.8(11) . . ?
C75 C74 H74 120.1 . . ?
C70 C75 H75 118.8 . . ?
C74 C75 C70 122.3(11) . . ?
C74 C75 H75 118.8 . . ?
C78 C77 C82 112.9(13) . . ?
C78 C77 B76 125.1(14) . . ?
C82 C77 B76 121.6(10) . . ?
C77 C78 H78 118.9 . . ?
C77 C78 C79 122.2(17) . . ?
C79 C78 H78 118.9 . . ?
C78 C79 H79 119.5 . . ?
C80 C79 C78 121.0(16) . . ?
C80 C79 H79 119.5 . . ?
C79 C80 H80 121.6 . . ?
C81 C80 C79 116.8(17) . . ?
C81 C80 H80 121.6 . . ?
C80 C81 H81 117.7 . . ?
C80 C81 C82 124.6(19) . . ?
C82 C81 H81 117.7 . . ?
C77 C82 C81 122.3(14) . . ?
C77 C82 H82 118.8 . . ?
C81 C82 H82 118.8 . . ?
C84 C83 C88 115.8(13) . . ?
C84 C83 B76 124.5(12) . . ?
C88 C83 B76 119.4(12) . . ?
C83 C84 H84 119.0 . . ?
C83 C84 C85 122.1(15) . . ?
C85 C84 H84 119.0 . . ?
C84 C85 H85 120.2 . . ?
C86 C85 C84 119.6(19) . . ?
C86 C85 H85 120.2 . . ?
C85 C86 H86 119.1 . . ?
C85 C86 C87 121.7(17) . . ?
C87 C86 H86 119.1 . . ?
C86 C87 H87 121.5 . . ?
C88 C87 C86 116.9(17) . . ?
C88 C87 H87 121.5 . . ?
C83 C88 H88 118.1 . . ?
C87 C88 C83 123.8(17) . . ?
C87 C88 H88 118.1 . . ?
C90 C89 B76 120.3(19) . . ?
C94 C89 C90 114.7(16) . . ?
C94 C89 B76 124.9(19) . . ?
C89 C90 H90 119.6 . . ?
C91 C90 C89 121(3) . . ?
C91 C90 H90 119.6 . . ?
C90 C91 H91 118.6 . . ?
C92 C91 C90 123(3) . . ?
C92 C91 H91 118.6 . . ?
C91 C92 H92 120.6 . . ?
C91 C92 C93 119(3) . . ?
C93 C92 H92 120.6 . . ?
C92 C93 H93 119.3 . . ?
C92 C93 C94 121(3) . . ?
C94 C93 H93 119.3 . . ?
C89 C94 C93 121(3) . . ?
C89 C94 H94 119.3 . . ?
C93 C94 H94 119.3 . . ?
C96 C95 B76 119.3(11) . . ?
C100 C95 C96 114.3(11) . . ?
C100 C95 B76 126.4(11) . . ?
C95 C96 H96 117.8 . . ?
C97 C96 C95 124.3(15) . . ?
C97 C96 H96 117.8 . . ?
C96 C97 H97 119.9 . . ?
C96 C97 C98 120.1(15) . . ?
C98 C97 H97 119.9 . . ?
C97 C98 H98 120.5 . . ?
C97 C98 C99 119.1(12) . . ?
C99 C98 H98 120.5 . . ?
C98 C99 H99 120.2 . . ?
C98 C99 C100 119.6(14) . . ?
C100 C99 H99 120.2 . . ?
C95 C100 C99 122.5(14) . . ?
C95 C100 H100 118.7 . . ?
C99 C100 H100 118.7 . . ?
O101 C102 N103 150(5) . . ?
O101 C102 H102 104.9 . . ?
N103 C102 H102 104.9 . . ?
N103 C104 H10A 109.5 . . ?
N103 C104 H10B 109.5 . . ?
N103 C104 H10C 109.5 . . ?
H10A C104 H10B 109.5 . . ?
H10A C104 H10C 109.5 . . ?
H10B C104 H10C 109.5 . . ?
N103 C105 H10D 109.5 . . ?
N103 C105 H10E 109.5 . . ?
N103 C105 H10F 109.5 . . ?
H10D C105 H10E 109.5 . . ?
H10D C105 H10F 109.5 . . ?
H10E C105 H10F 109.5 . . ?
C52 B51 C58 105.0(7) . . ?
C52 B51 C64 112.0(7) . . ?
C64 B51 C58 110.6(8) . . ?
C70 B51 C52 110.7(8) . . ?
C70 B51 C58 111.4(7) . . ?
C70 B51 C64 107.2(7) . . ?
C77 B76 C89 111.6(12) . . ?
C77 B76 C95 112.7(11) . . ?
C83 B76 C77 103.8(9) . . ?
C83 B76 C89 111.4(13) . . ?
C83 B76 C95 112.5(10) . . ?
C89 B76 C95 105.1(9) . . ?
O38 C39B H39B 113.0 . . ?
O38 C39B N40B 134(3) . . ?
N40B C39B H39B 113.0 . . ?
H41A C41B H41B 109.5 . . ?
H41A C41B H41C 109.5 . . ?
H41B C41B H41C 109.5 . . ?
N40B C41B H41A 109.5 . . ?
N40B C41B H41B 109.5 . . ?
N40B C41B H41C 109.5 . . ?
N40 C41 H41D 109.5 . . ?
N40 C41 H41E 109.5 . . ?
N40 C41 H41F 109.5 . . ?
H41D C41 H41E 109.5 . . ?
H41D C41 H41F 109.5 . . ?
H41E C41 H41F 109.5 . . ?
C40B N40B C41B 113(4) . . ?
C39B N40B C40B 142(4) . . ?
C39B N40B C41B 104(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 N14 C13 C12 179.1(7) . . . . ?
Pt1 N14 C15 C16 -178.5(6) . . . . ?
Pt2 N20 C19 C18 170.2(6) . . . . ?
Pt2 N20 C21 C22 -170.6(8) . . . . ?
Zn1 O23 C24 N25 -169.9(16) . . . . ?
Zn1 N1 C6 C5 -9.6(10) . . . . ?
Zn1 N1 C6 C5 16.9(10) 2_666 . . . ?
Zn1 N1 C6 C7 -161.3(5) 2_666 . . . ?
Zn1 N1 C6 C7 172.3(5) . . . . ?
Zn1 N1 C9 C8 162.8(5) 2_666 . . . ?
Zn1 N1 C9 C8 -170.9(5) . . . . ?
Zn1 N1 C9 C10 9.8(10) . . . . ?
Zn1 N1 C9 C10 -16.5(10) 2_666 . . . ?
Zn1 N2 C1 C2 166.4(5) . . . . ?
Zn1 N2 C1 C2 -167.3(5) 2_666 . . . ?
Zn1 N2 C1 C10 -13.4(10) . . . 2_666 ?
Zn1 N2 C1 C10 12.9(10) 2_666 . . 2_666 ?
Zn1 N2 C4 C3 167.1(5) 2_666 . . . ?
Zn1 N2 C4 C3 -166.4(5) . . . . ?
Zn1 N2 C4 C5 -14.2(10) 2_666 . . . ?
Zn1 N2 C4 C5 12.2(10) . . . . ?
O38 C39B N40B C40B 170(4) . . . . ?
O38 C39B N40B C41B -3(3) . . . . ?
N1 C6 C7 C8 -2.0(9) . . . . ?
N1 C9 C10 C1 2.0(12) . . . 2_666 ?
N1 C9 C10 C17 -179.7(7) . . . . ?
N2 C1 C2 C3 0.2(9) . . . . ?
N2 C4 C5 C6 1.2(12) . . . . ?
N2 C4 C5 C11 -178.4(6) . . . . ?
N14 C15 C16 C11 -1.8(13) . . . . ?
N20 C21 C22 C17 -0.1(16) . . . . ?
C1 N2 C4 C3 0.6(8) . . . . ?
C1 N2 C4 C5 179.3(7) . . . . ?
C1 C2 C3 C4 0.2(9) . . . . ?
C1 C10 C17 C18 -114.9(8) 2_666 . . . ?
C1 C10 C17 C22 67.1(10) 2_666 . . . ?
C2 C3 C4 N2 -0.5(9) . . . . ?
C2 C3 C4 C5 -179.2(7) . . . . ?
C3 C4 C5 C6 179.6(7) . . . . ?
C3 C4 C5 C11 0.0(11) . . . . ?
C4 N2 C1 C2 -0.5(8) . . . . ?
C4 N2 C1 C10 179.7(7) . . . 2_666 ?
C4 C5 C6 N1 -2.7(12) . . . . ?
C4 C5 C6 C7 175.2(7) . . . . ?
C4 C5 C11 C12 -64.2(10) . . . . ?
C4 C5 C11 C16 117.0(8) . . . . ?
C5 C6 C7 C8 179.8(7) . . . . ?
C5 C11 C12 C13 -178.8(7) . . . . ?
C5 C11 C16 C15 179.3(7) . . . . ?
C6 N1 C9 C8 0.3(8) . . . . ?
C6 N1 C9 C10 -179.0(7) . . . . ?
C6 C5 C11 C12 116.2(8) . . . . ?
C6 C5 C11 C16 -62.7(10) . . . . ?
C6 C7 C8 C9 2.1(9) . . . . ?
C7 C8 C9 N1 -1.5(9) . . . . ?
C7 C8 C9 C10 177.8(7) . . . . ?
C8 C9 C10 C1 -177.2(7) . . . 2_666 ?
C8 C9 C10 C17 1.1(11) . . . . ?
C9 N1 C6 C5 179.2(7) . . . . ?
C9 N1 C6 C7 1.0(8) . . . . ?
C9 C10 C17 C18 66.6(10) . . . . ?
C9 C10 C17 C22 -111.3(9) . . . . ?
C10 C1 C2 C3 -180.0(7) 2_666 . . . ?
C10 C17 C18 C19 -176.1(7) . . . . ?
C10 C17 C22 C21 176.1(9) . . . . ?
C11 C5 C6 N1 176.9(7) . . . . ?
C11 C5 C6 C7 -5.2(11) . . . . ?
C11 C12 C13 N14 0.6(13) . . . . ?
C12 C11 C16 C15 0.5(12) . . . . ?
C13 N14 C15 C16 2.4(12) . . . . ?
C15 N14 C13 C12 -1.9(12) . . . . ?
C16 C11 C12 C13 0.1(12) . . . . ?
C17 C18 C19 N20 0.2(13) . . . . ?
C18 C17 C22 C21 -1.9(13) . . . . ?
C19 N20 C21 C22 2.3(14) . . . . ?
C21 N20 C19 C18 -2.3(13) . . . . ?
C22 C17 C18 C19 1.9(12) . . . . ?
C26 N25 C24 O23 171(2) . . . . ?
C27 N25 C24 O23 1(4) . . . . ?
C31 N30 C29 O28 174.8(17) . . . . ?
C31 N30B C29 O28 -160.5(19) . . . . ?
C32 N30 C29 O28 -14(3) . . . . ?
C32B N30B C29 O28 -24(6) . . . . ?
C36 N35 C34 O33 -2(2) . . . . ?
C37 N35 C34 O33 179.6(13) . . . . ?
C42 N40 C39 O38 -1(2) . . . . ?
C52 C53 C54 C55 -0.6(17) . . . . ?
C53 C52 C57 C56 1.4(12) . . . . ?
C53 C52 B51 C58 110.7(9) . . . . ?
C53 C52 B51 C64 -9.4(13) . . . . ?
C53 C52 B51 C70 -129.0(9) . . . . ?
C53 C54 C55 C56 0.6(17) . . . . ?
C54 C55 C56 C57 0.4(15) . . . . ?
C55 C56 C57 C52 -1.5(13) . . . . ?
C57 C52 C53 C54 -0.3(14) . . . . ?
C57 C52 B51 C58 -64.4(10) . . . . ?
C57 C52 B51 C64 175.4(8) . . . . ?
C57 C52 B51 C70 55.9(10) . . . . ?
C58 C59 C60 C61 2.4(17) . . . . ?
C59 C58 C63 C62 -2.7(14) . . . . ?
C59 C58 B51 C52 -58.8(10) . . . . ?
C59 C58 B51 C64 62.2(10) . . . . ?
C59 C58 B51 C70 -178.7(8) . . . . ?
C59 C60 C61 C62 -3.3(18) . . . . ?
C60 C61 C62 C63 1.2(17) . . . . ?
C61 C62 C63 C58 2.0(17) . . . . ?
C63 C58 C59 C60 0.5(14) . . . . ?
C63 C58 B51 C52 116.3(9) . . . . ?
C63 C58 B51 C64 -122.6(9) . . . . ?
C63 C58 B51 C70 -3.6(13) . . . . ?
C64 C65 C66 C67 -3(3) . . . . ?
C65 C64 C69 C68 2.2(19) . . . . ?
C65 C64 B51 C52 -63.3(12) . . . . ?
C65 C64 B51 C58 179.9(9) . . . . ?
C65 C64 B51 C70 58.3(12) . . . . ?
C65 C66 C67 C68 8(3) . . . . ?
C66 C67 C68 C69 -8(3) . . . . ?
C67 C68 C69 C64 3(2) . . . . ?
C69 C64 C65 C66 -2.5(19) . . . . ?
C69 C64 B51 C52 117.1(11) . . . . ?
C69 C64 B51 C58 0.3(14) . . . . ?
C69 C64 B51 C70 -121.3(11) . . . . ?
C70 C71 C72 C73 -0.1(18) . . . . ?
C71 C70 C75 C74 -2.9(15) . . . . ?
C71 C70 B51 C52 7.3(12) . . . . ?
C71 C70 B51 C58 123.7(10) . . . . ?
C71 C70 B51 C64 -115.2(10) . . . . ?
C71 C72 C73 C74 -2.6(19) . . . . ?
C72 C73 C74 C75 2.5(19) . . . . ?
C73 C74 C75 C70 0.3(17) . . . . ?
C75 C70 C71 C72 2.7(15) . . . . ?
C75 C70 B51 C52 -175.4(8) . . . . ?
C75 C70 B51 C58 -58.9(11) . . . . ?
C75 C70 B51 C64 62.2(11) . . . . ?
C77 C78 C79 C80 0(2) . . . . ?
C78 C77 C82 C81 3.8(18) . . . . ?
C78 C77 B76 C83 95.2(13) . . . . ?
C78 C77 B76 C89 -24.9(17) . . . . ?
C78 C77 B76 C95 -142.8(11) . . . . ?
C78 C79 C80 C81 0(2) . . . . ?
C79 C80 C81 C82 1(2) . . . . ?
C80 C81 C82 C77 -4(2) . . . . ?
C82 C77 C78 C79 -2.2(19) . . . . ?
C82 C77 B76 C83 -76.5(13) . . . . ?
C82 C77 B76 C89 163.5(12) . . . . ?
C82 C77 B76 C95 45.5(14) . . . . ?
C83 C84 C85 C86 0(2) . . . . ?
C84 C83 C88 C87 3.0(19) . . . . ?
C84 C83 B76 C77 101.0(13) . . . . ?
C84 C83 B76 C89 -138.7(13) . . . . ?
C84 C83 B76 C95 -21.0(17) . . . . ?
C84 C85 C86 C87 2(3) . . . . ?
C85 C86 C87 C88 -1(3) . . . . ?
C86 C87 C88 C83 -1(2) . . . . ?
C88 C83 C84 C85 -2(2) . . . . ?
C88 C83 B76 C77 -71.9(14) . . . . ?
C88 C83 B76 C89 48.3(15) . . . . ?
C88 C83 B76 C95 166.0(10) . . . . ?
C89 C90 C91 C92 2(3) . . . . ?
C90 C89 C94 C93 -1(2) . . . . ?
C90 C89 B76 C77 -49.5(15) . . . . ?
C90 C89 B76 C83 -164.9(12) . . . . ?
C90 C89 B76 C95 73.0(15) . . . . ?
C90 C91 C92 C93 -3(3) . . . . ?
C91 C92 C93 C94 2(3) . . . . ?
C92 C93 C94 C89 0(3) . . . . ?
C94 C89 C90 C91 0(2) . . . . ?
C94 C89 B76 C77 130.5(15) . . . . ?
C94 C89 B76 C83 15.0(18) . . . . ?
C94 C89 B76 C95 -107.1(15) . . . . ?
C95 C96 C97 C98 0(2) . . . . ?
C96 C95 C100 C99 2.0(16) . . . . ?
C96 C95 B76 C77 -169.0(10) . . . . ?
C96 C95 B76 C83 -52.1(14) . . . . ?
C96 C95 B76 C89 69.3(15) . . . . ?
C96 C97 C98 C99 1.8(19) . . . . ?
C97 C98 C99 C100 -1.3(18) . . . . ?
C98 C99 C100 C95 -0.7(18) . . . . ?
C100 C95 C96 C97 -1.5(18) . . . . ?
C100 C95 B76 C77 12.6(15) . . . . ?
C100 C95 B76 C83 129.5(12) . . . . ?
C100 C95 B76 C89 -109.1(15) . . . . ?
C104 N103 C102 O101 6(10) . . . . ?
C105 N103 C102 O101 -163(7) . . . . ?
B51 C52 C53 C54 -175.6(9) . . . . ?
B51 C52 C57 C56 177.0(8) . . . . ?
B51 C58 C59 C60 176.3(10) . . . . ?
B51 C58 C63 C62 -178.1(9) . . . . ?
B51 C64 C65 C66 177.8(12) . . . . ?
B51 C64 C69 C68 -178.2(12) . . . . ?
B51 C70 C71 C72 -179.8(10) . . . . ?
B51 C70 C75 C74 179.5(9) . . . . ?
B76 C77 C78 C79 -174.5(12) . . . . ?
B76 C77 C82 C81 176.4(11) . . . . ?
B76 C83 C84 C85 -175.5(13) . . . . ?
B76 C83 C88 C87 176.6(12) . . . . ?
B76 C89 C90 C91 -179.9(13) . . . . ?
B76 C89 C94 C93 179.3(15) . . . . ?
B76 C95 C96 C97 179.9(11) . . . . ?
B76 C95 C100 C99 -179.6(10) . . . . ?
C41 N40 C39 O38 -175.4(19) . . . . ?

# start Validation Reply Form
_vrf_PLAT971_bs200109_tptzn4pyp_uo_26600_b4_cut 
;
PROBLEM: Check Calcd Resid. Dens. 0.91A From Pt2 6.58 eA-3
RESPONSE: We assume that the high residual electron density is caused by low
quality of the crystal and the needed use of copper radiation for this 
platinium containing crystal.
;
# end Validation Reply Form

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.214
_oxdiff_exptl_absorpt_empirical_full_min 0.433
_exptl_crystal_recrystallization_method 'under oil'
_chemical_properties_physical    Light-sensitive
