# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_a
_database_code_depnum_ccdc_archive 'CCDC 1972626'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2019-12-17 deposited with the CCDC.	2020-02-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C108 H90 Dy2 N12 O6, 3.5(C7 H8)'
_chemical_formula_sum            'C132.50 H118 Dy2 N12 O6'
_chemical_formula_weight         2299.38

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   13.328(3)
_cell_length_b                   14.307(3)
_cell_length_c                   29.016(6)
_cell_angle_alpha                90.480(5)
_cell_angle_beta                 91.743(5)
_cell_angle_gamma                94.143(5)
_cell_volume                     5515.7(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    9736
_cell_measurement_theta_min      2.22
_cell_measurement_theta_max      27.22

_exptl_crystal_description       block
_exptl_crystal_colour            red
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.384
_exptl_crystal_F_000             2354
_exptl_transmission_factor_min   0.661
_exptl_transmission_factor_max   0.793
_exptl_crystal_size_max          0.320
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.180
_exptl_absorpt_coefficient_mu    1.408
_shelx_estimated_absorpt_T_min   0.661
_shelx_estimated_absorpt_T_max   0.786
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  "Bruker APEX II CCD area detector'"
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            59999
_diffrn_reflns_av_unetI/netI     0.2228
_diffrn_reflns_av_R_equivalents  0.1170
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         0.702
_diffrn_reflns_theta_max         27.499
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             25321
_reflns_number_gt                11562
_reflns_threshold_expression     I>2σ(I)
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX II'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0810P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         25321
_refine_ls_number_parameters     1355
_refine_ls_number_restraints     225
_refine_ls_R_factor_all          0.1811
_refine_ls_R_factor_gt           0.0741
_refine_ls_wR_factor_ref         0.2079
_refine_ls_wR_factor_gt          0.1574
_refine_ls_goodness_of_fit_ref   0.941
_refine_ls_restrained_S_all      0.943
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 1.50020(3) -0.07064(3) 0.55552(2) 0.02697(14) Uani 1 1 d . . . . .
Dy2 Dy 1.50526(3) 0.57203(3) 0.05635(2) 0.02773(14) Uani 1 1 d . . . . .
O1 O 1.4785(4) -0.2200(4) 0.5474(2) 0.0286(15) Uani 1 1 d . . . . .
N1 N 1.5647(5) -0.2369(5) 0.6399(3) 0.0291(18) Uani 1 1 d . . . . .
N2 N 1.5541(6) -0.1525(5) 0.6284(3) 0.0278(18) Uani 1 1 d . . . . .
C1 C 1.4935(7) -0.3032(6) 0.5648(3) 0.028(2) Uani 1 1 d . . . . .
C2 C 1.5430(7) -0.3099(6) 0.6093(3) 0.028(2) Uani 1 1 d . . . . .
C3 C 1.5708(7) -0.4012(6) 0.6250(3) 0.028(2) Uani 1 1 d . . . . .
C4 C 1.6312(8) -0.4112(7) 0.6643(4) 0.040(3) Uani 1 1 d . . . . .
H4A H 1.652216 -0.357796 0.682734 0.048 Uiso 1 1 calc R U . . .
C5 C 1.6609(8) -0.4979(7) 0.6766(4) 0.045(3) Uani 1 1 d . . . . .
H5A H 1.704398 -0.502936 0.702873 0.054 Uiso 1 1 calc R U . . .
C6 C 1.6287(8) -0.5780(7) 0.6515(4) 0.041(3) Uani 1 1 d . . . . .
H6A H 1.649769 -0.637295 0.660731 0.049 Uiso 1 1 calc R U . . .
C7 C 1.5665(8) -0.5713(6) 0.6135(4) 0.039(3) Uani 1 1 d . . . . .
H7A H 1.543058 -0.625920 0.596476 0.047 Uiso 1 1 calc R U . . .
C8 C 1.5375(8) -0.4827(6) 0.5998(3) 0.035(2) Uani 1 1 d . . . . .
C9 C 1.4797(8) -0.4727(7) 0.5578(4) 0.037(3) Uani 1 1 d . . . . .
H9A H 1.456100 -0.526793 0.540359 0.044 Uiso 1 1 calc R U . . .
C10 C 1.4589(7) -0.3870(7) 0.5431(4) 0.035(2) Uani 1 1 d . . . . .
H10A H 1.417777 -0.383499 0.515909 0.042 Uiso 1 1 calc R U . . .
C11 C 1.5737(8) -0.0900(7) 0.6682(4) 0.035(2) Uani 1 1 d . . . . .
C12 C 1.5026(9) -0.0854(7) 0.7035(4) 0.041(3) Uani 1 1 d . . . . .
C13 C 1.5240(9) -0.0184(7) 0.7382(4) 0.048(3) Uani 1 1 d . . . . .
H13A H 1.476853 -0.013706 0.761833 0.057 Uiso 1 1 calc R U . . .
C14 C 1.6099(10) 0.0415(8) 0.7401(4) 0.056(3) Uani 1 1 d . . . . .
C15 C 1.6769(10) 0.0342(8) 0.7060(4) 0.058(3) Uani 1 1 d . . . . .
H15A H 1.737270 0.073883 0.707003 0.069 Uiso 1 1 calc R U . . .
C16 C 1.6595(9) -0.0305(7) 0.6694(4) 0.045(3) Uani 1 1 d . . . . .
H16A H 1.706696 -0.032957 0.645586 0.054 Uiso 1 1 calc R U . . .
C17 C 1.4088(8) -0.1492(8) 0.7036(4) 0.045(3) Uani 1 1 d . . . . .
H17A H 1.368066 -0.132814 0.729617 0.068 Uiso 1 1 calc R U . . .
H17B H 1.426618 -0.214191 0.706586 0.068 Uiso 1 1 calc R U . . .
H17C H 1.370220 -0.142448 0.674674 0.068 Uiso 1 1 calc R U . . .
C18 C 1.6247(13) 0.1163(10) 0.7754(6) 0.105(6) Uani 1 1 d . . . . .
H18A H 1.696272 0.125568 0.784269 0.158 Uiso 1 1 calc R U . . .
H18B H 1.585990 0.098454 0.802559 0.158 Uiso 1 1 calc R U . . .
H18C H 1.601545 0.174716 0.762893 0.158 Uiso 1 1 calc R U . . .
O1A O 1.4973(4) 0.0537(4) 0.5977(2) 0.0330(16) Uani 1 1 d . . . . .
N1A N 1.2943(5) -0.0139(5) 0.6233(3) 0.0272(18) Uani 1 1 d . . . . .
C1A C 1.4497(7) 0.0921(6) 0.6312(3) 0.028(2) Uani 1 1 d . . . . .
N2A N 1.3299(6) -0.0678(5) 0.5925(3) 0.0313(19) Uani 1 1 d . . . . .
C2A C 1.3532(7) 0.0583(6) 0.6442(3) 0.027(2) Uani 1 1 d . . . . .
C3A C 1.3031(7) 0.1041(6) 0.6806(3) 0.031(2) Uani 1 1 d . . . . .
C4A C 1.2112(7) 0.0692(7) 0.6979(3) 0.034(2) Uani 1 1 d . . . . .
H4AA H 1.179792 0.012003 0.685997 0.041 Uiso 1 1 calc R U . . .
C5A C 1.1656(8) 0.1168(7) 0.7322(4) 0.041(3) Uani 1 1 d . . . . .
H5AA H 1.103615 0.091555 0.743830 0.050 Uiso 1 1 calc R U . . .
C6A C 1.2093(8) 0.2011(7) 0.7499(4) 0.041(3) Uani 1 1 d . . . . .
H6AA H 1.175842 0.234488 0.772507 0.049 Uiso 1 1 calc R U . . .
C7A C 1.3003(8) 0.2361(8) 0.7347(4) 0.041(3) Uani 1 1 d . . . . .
H7AA H 1.330907 0.292695 0.747758 0.049 Uiso 1 1 calc R U . . .
C8A C 1.3498(7) 0.1889(7) 0.6996(3) 0.034(2) Uani 1 1 d . . . . .
C9A C 1.4435(8) 0.2240(6) 0.6838(4) 0.039(3) Uani 1 1 d . . . . .
H9AA H 1.473889 0.280880 0.696646 0.047 Uiso 1 1 calc R U . . .
C10A C 1.4921(8) 0.1789(7) 0.6507(3) 0.036(2) Uani 1 1 d . . . . .
H10B H 1.554809 0.205284 0.640411 0.043 Uiso 1 1 calc R U . . .
C11A C 1.2484(7) -0.1315(7) 0.5730(3) 0.033(2) Uani 1 1 d . . . . .
C12A C 1.1658(7) -0.0970(8) 0.5489(4) 0.039(3) Uani 1 1 d . . . . .
C13A C 1.0950(8) -0.1661(8) 0.5294(4) 0.045(3) Uani 1 1 d . . . . .
H13B H 1.037747 -0.145641 0.513203 0.054 Uiso 1 1 calc R U . . .
C14A C 1.1043(8) -0.2609(9) 0.5324(4) 0.050(3) Uani 1 1 d . . . . .
C15A C 1.1857(9) -0.2908(8) 0.5566(4) 0.053(3) Uani 1 1 d . . . . .
H15B H 1.192787 -0.356117 0.559382 0.064 Uiso 1 1 calc R U . . .
C16A C 1.2589(8) -0.2269(7) 0.5772(4) 0.045(3) Uani 1 1 d . . . . .
H16B H 1.314889 -0.248738 0.593898 0.054 Uiso 1 1 calc R U . . .
C17A C 1.0296(9) -0.3288(10) 0.5078(5) 0.075(4) Uani 1 1 d . . . . .
H17D H 0.961188 -0.312510 0.514166 0.112 Uiso 1 1 calc R U . . .
H17E H 1.038853 -0.392436 0.518606 0.112 Uiso 1 1 calc R U . . .
H17F H 1.040017 -0.325880 0.474544 0.112 Uiso 1 1 calc R U . . .
C18A C 1.1518(8) 0.0043(8) 0.5441(4) 0.045(3) Uani 1 1 d . . . . .
H18D H 1.217515 0.038794 0.541085 0.068 Uiso 1 1 calc R U . . .
H18E H 1.119189 0.027028 0.571416 0.068 Uiso 1 1 calc R U . . .
H18F H 1.109544 0.014100 0.516587 0.068 Uiso 1 1 calc R U . . .
O1B O 1.4109(4) -0.0468(4) 0.4871(2) 0.0289(15) Uani 1 1 d . . . . .
N1B N 1.2417(6) 0.0415(5) 0.4442(3) 0.0305(19) Uani 1 1 d . . . . .
N2B N 1.3153(6) 0.1029(5) 0.4553(3) 0.0285(18) Uani 1 1 d . . . . .
C1B C 1.3366(7) -0.0950(6) 0.4628(3) 0.030(2) Uani 1 1 d . . . . .
C2B C 1.2586(7) -0.0516(6) 0.4405(3) 0.029(2) Uani 1 1 d . . . . .
C3B C 1.1798(7) -0.1057(7) 0.4160(3) 0.030(2) Uani 1 1 d . . . . .
C4B C 1.0993(7) -0.0659(8) 0.3945(4) 0.047(3) Uani 1 1 d . . . . .
H4BA H 1.094337 -0.000117 0.396356 0.056 Uiso 1 1 calc R U . . .
C5B C 1.0259(9) -0.1215(9) 0.3704(4) 0.061(4) Uani 1 1 d . . . . .
H5BA H 0.971223 -0.092758 0.355933 0.074 Uiso 1 1 calc R U . . .
C6B C 1.0296(9) -0.2172(9) 0.3666(4) 0.062(4) Uani 1 1 d . . . . .
H6BA H 0.979508 -0.253373 0.348854 0.074 Uiso 1 1 calc R U . . .
C7B C 1.1047(9) -0.2592(8) 0.3882(4) 0.055(3) Uani 1 1 d . . . . .
H7BA H 1.105651 -0.325552 0.386968 0.066 Uiso 1 1 calc R U . . .
C8B C 1.1830(8) -0.2049(7) 0.4130(4) 0.040(3) Uani 1 1 d . . . . .
C9B C 1.2638(8) -0.2466(7) 0.4356(4) 0.042(3) Uani 1 1 d . . . . .
H9BA H 1.267406 -0.312580 0.434112 0.051 Uiso 1 1 calc R U . . .
C10B C 1.3356(8) -0.1931(7) 0.4592(4) 0.039(3) Uani 1 1 d . . . . .
H10C H 1.388496 -0.223406 0.474177 0.046 Uiso 1 1 calc R U . . .
C11B C 1.2826(7) 0.1954(6) 0.4566(3) 0.030(2) Uani 1 1 d . . . . .
C12B C 1.3081(7) 0.2545(7) 0.4940(4) 0.039(3) Uani 1 1 d . . . . .
C13B C 1.2802(7) 0.3468(7) 0.4924(4) 0.044(3) Uani 1 1 d . . . . .
H13C H 1.297831 0.387853 0.517694 0.053 Uiso 1 1 calc R U . . .
C14B C 1.2275(8) 0.3802(8) 0.4547(5) 0.049(3) Uani 1 1 d . . . . .
C15B C 1.2013(8) 0.3193(8) 0.4192(4) 0.049(3) Uani 1 1 d . . . . .
H15C H 1.165135 0.341259 0.393235 0.059 Uiso 1 1 calc R U . . .
C16B C 1.2248(8) 0.2282(7) 0.4195(4) 0.038(3) Uani 1 1 d . . . . .
H16C H 1.202495 0.187118 0.394776 0.046 Uiso 1 1 calc R U . . .
C17B C 1.2031(9) 0.4803(8) 0.4516(5) 0.065(4) Uani 1 1 d . . . . .
H17G H 1.220080 0.504531 0.421088 0.098 Uiso 1 1 calc R U . . .
H17H H 1.242103 0.517420 0.475380 0.098 Uiso 1 1 calc R U . . .
H17I H 1.131071 0.484739 0.456293 0.098 Uiso 1 1 calc R U . . .
C18B C 1.3649(8) 0.2208(7) 0.5357(4) 0.044(3) Uani 1 1 d . . . . .
H18G H 1.355130 0.152367 0.537247 0.067 Uiso 1 1 calc R U . . .
H18H H 1.339759 0.248731 0.563620 0.067 Uiso 1 1 calc R U . . .
H18I H 1.436739 0.239371 0.533184 0.067 Uiso 1 1 calc R U . . .
O1C O 1.4850(4) 0.7198(4) 0.0508(2) 0.0261(14) Uani 1 1 d . . . . .
N1C N 1.5803(6) 0.7486(5) 0.1413(3) 0.0318(19) Uani 1 1 d . . . . .
C1C C 1.5036(7) 0.8044(7) 0.0684(3) 0.031(2) Uani 1 1 d . . . . .
N2C N 1.5670(5) 0.6614(5) 0.1301(3) 0.0294(19) Uani 1 1 d . . . . .
C2C C 1.5569(7) 0.8174(6) 0.1110(3) 0.028(2) Uani 1 1 d . . . . .
C3C C 1.5880(7) 0.9125(6) 0.1266(4) 0.033(2) Uani 1 1 d . . . . .
C4C C 1.6526(8) 0.9303(7) 0.1660(4) 0.039(3) Uani 1 1 d . . . . .
H4CA H 1.673562 0.879509 0.183929 0.047 Uiso 1 1 calc R U . . .
C5C C 1.6848(8) 1.0202(7) 0.1782(4) 0.044(3) Uani 1 1 d . . . . .
H5CA H 1.730470 1.030646 0.203752 0.053 Uiso 1 1 calc R U . . .
C6C C 1.6528(8) 1.0965(7) 0.1543(4) 0.044(3) Uani 1 1 d . . . . .
H6CA H 1.675510 1.158320 0.163800 0.052 Uiso 1 1 calc R U . . .
C7C C 1.5880(8) 1.0820(7) 0.1169(4) 0.046(3) Uani 1 1 d . . . . .
H7CA H 1.563701 1.134136 0.101168 0.056 Uiso 1 1 calc R U . . .
C8C C 1.5569(7) 0.9891(7) 0.1014(4) 0.037(3) Uani 1 1 d . . . . .
C9C C 1.4938(8) 0.9715(7) 0.0616(4) 0.044(3) Uani 1 1 d . . . . .
H9CA H 1.468218 1.022818 0.045674 0.053 Uiso 1 1 calc R U . . .
C10C C 1.4691(8) 0.8826(7) 0.0458(4) 0.042(3) Uani 1 1 d . . . . .
H10D H 1.427441 0.873407 0.018733 0.050 Uiso 1 1 calc R U . . .
C11C C 1.5906(8) 0.6043(6) 0.1694(3) 0.032(2) Uani 1 1 d . . . . .
C12C C 1.5220(8) 0.5886(7) 0.2048(4) 0.038(3) Uani 1 1 d . . . . .
C13C C 1.5471(9) 0.5283(7) 0.2401(4) 0.044(3) Uani 1 1 d . . . . .
H13D H 1.501343 0.516315 0.264211 0.052 Uiso 1 1 calc R U . . .
C14C C 1.6382(9) 0.4847(7) 0.2410(4) 0.044(3) Uani 1 1 d . . . . .
C15C C 1.7040(8) 0.5031(7) 0.2060(4) 0.045(3) Uani 1 1 d . . . . .
H15D H 1.766644 0.475284 0.206295 0.054 Uiso 1 1 calc R U . . .
C16C C 1.6794(8) 0.5622(7) 0.1703(3) 0.039(3) Uani 1 1 d . . . . .
H16D H 1.724949 0.573401 0.146050 0.047 Uiso 1 1 calc R U . . .
C17C C 1.4239(8) 0.6337(8) 0.2058(4) 0.049(3) Uani 1 1 d . . . . .
H17J H 1.400765 0.646172 0.174260 0.074 Uiso 1 1 calc R U . . .
H17K H 1.433263 0.692877 0.223268 0.074 Uiso 1 1 calc R U . . .
H17L H 1.373641 0.591694 0.220707 0.074 Uiso 1 1 calc R U . . .
C18C C 1.6598(11) 0.4193(9) 0.2807(5) 0.077(5) Uani 1 1 d . . . . .
H18J H 1.732714 0.417562 0.285599 0.116 Uiso 1 1 calc R U . . .
H18K H 1.630213 0.356046 0.273221 0.116 Uiso 1 1 calc R U . . .
H18L H 1.630320 0.442078 0.308832 0.116 Uiso 1 1 calc R U . . .
O1D O 1.4118(4) 0.5353(4) -0.0106(2) 0.0304(15) Uani 1 1 d . . . . .
N1D N 1.2403(6) 0.4233(5) -0.0549(3) 0.031(2) Uani 1 1 d . . . . .
N2D N 1.3123(6) 0.3738(5) -0.0428(3) 0.0304(19) Uani 1 1 d . . . . .
C1D C 1.3367(7) 0.5756(7) -0.0349(4) 0.034(2) Uani 1 1 d . . . . .
C2D C 1.2585(7) 0.5196(6) -0.0586(3) 0.029(2) Uani 1 1 d . . . . .
C3D C 1.1831(7) 0.5641(6) -0.0861(3) 0.029(2) Uani 1 1 d . . . . .
C4D C 1.1047(7) 0.5115(7) -0.1112(4) 0.038(3) Uani 1 1 d . . . . .
H4DA H 1.098603 0.445038 -0.109514 0.045 Uiso 1 1 calc R U . . .
C5D C 1.0369(8) 0.5586(7) -0.1382(4) 0.047(3) Uani 1 1 d . . . . .
H5DA H 0.983359 0.524043 -0.154496 0.056 Uiso 1 1 calc R U . . .
C6D C 1.0468(8) 0.6555(8) -0.1415(4) 0.052(3) Uani 1 1 d . . . . .
H6DA H 1.001179 0.685985 -0.161009 0.062 Uiso 1 1 calc R U . . .
C7D C 1.1205(8) 0.7080(7) -0.1174(4) 0.047(3) Uani 1 1 d . . . . .
H7DA H 1.124946 0.774330 -0.119958 0.056 Uiso 1 1 calc R U . . .
C8D C 1.1903(7) 0.6639(7) -0.0887(4) 0.035(3) Uani 1 1 d . . . . .
C9D C 1.2663(7) 0.7151(7) -0.0628(4) 0.040(3) Uani 1 1 d . . . . .
H9DA H 1.269532 0.781547 -0.063951 0.048 Uiso 1 1 calc R U . . .
C10D C 1.3366(7) 0.6730(7) -0.0356(3) 0.034(2) Uani 1 1 d . . . . .
H10E H 1.384842 0.710375 -0.017418 0.041 Uiso 1 1 calc R U . . .
C11D C 1.2791(7) 0.2760(6) -0.0382(4) 0.031(2) Uani 1 1 d . . . . .
C12D C 1.3119(7) 0.2267(7) -0.0008(4) 0.037(2) Uani 1 1 d . . . . .
C13D C 1.2834(8) 0.1317(7) 0.0006(4) 0.051(3) Uani 1 1 d . . . . .
H13E H 1.303725 0.097216 0.026663 0.061 Uiso 1 1 calc R U . . .
C14D C 1.2279(8) 0.0857(7) -0.0335(4) 0.045(3) Uani 1 1 d . . . . .
C15D C 1.1956(8) 0.1372(8) -0.0716(5) 0.052(3) Uani 1 1 d . . . . .
H15E H 1.156868 0.106206 -0.095983 0.063 Uiso 1 1 calc R U . . .
C16D C 1.2201(8) 0.2326(7) -0.0738(4) 0.042(3) Uani 1 1 d . . . . .
H16E H 1.197020 0.267924 -0.099033 0.050 Uiso 1 1 calc R U . . .
C17D C 1.3741(9) 0.2712(7) 0.0378(4) 0.048(3) Uani 1 1 d . . . . .
H17M H 1.430528 0.233044 0.045100 0.073 Uiso 1 1 calc R U . . .
H17N H 1.332770 0.275955 0.064935 0.073 Uiso 1 1 calc R U . . .
H17O H 1.400123 0.334050 0.028785 0.073 Uiso 1 1 calc R U . . .
C18D C 1.2036(10) -0.0203(8) -0.0313(5) 0.075(4) Uani 1 1 d . . . . .
H18M H 1.260236 -0.049584 -0.016423 0.113 Uiso 1 1 calc R U . . .
H18N H 1.191912 -0.045831 -0.062595 0.113 Uiso 1 1 calc R U . . .
H18O H 1.143041 -0.033411 -0.013417 0.113 Uiso 1 1 calc R U . . .
O1E O 1.5080(5) 0.4515(4) 0.1006(2) 0.0332(16) Uani 1 1 d . . . . .
N1E N 1.3055(6) 0.4859(5) 0.1252(3) 0.034(2) Uani 1 1 d . . . . .
N2E N 1.3393(6) 0.5438(5) 0.0954(3) 0.0324(19) Uani 1 1 d . . . . .
C1E C 1.4626(7) 0.4060(6) 0.1323(3) 0.031(2) Uani 1 1 d . . . . .
C2E C 1.3643(7) 0.4234(6) 0.1462(3) 0.032(2) Uani 1 1 d . . . . .
C3E C 1.3179(8) 0.3700(7) 0.1825(4) 0.037(3) Uani 1 1 d . . . . .
C4E C 1.2200(7) 0.3835(7) 0.1971(4) 0.037(3) Uani 1 1 d . . . . .
H4EA H 1.183319 0.430998 0.183223 0.045 Uiso 1 1 calc R U . . .
C5E C 1.1777(8) 0.3302(8) 0.2304(4) 0.045(3) Uani 1 1 d . . . . .
H5EA H 1.111911 0.341101 0.239841 0.054 Uiso 1 1 calc R U . . .
C6E C 1.2292(9) 0.2588(8) 0.2513(4) 0.052(3) Uani 1 1 d . . . . .
H6EA H 1.198401 0.220889 0.274398 0.063 Uiso 1 1 calc R U . . .
C7E C 1.3233(9) 0.2447(8) 0.2381(4) 0.046(3) Uani 1 1 d . . . . .
H7EA H 1.358452 0.197281 0.252864 0.056 Uiso 1 1 calc R U . . .
C8E C 1.3706(8) 0.2967(7) 0.2038(3) 0.037(3) Uani 1 1 d . . . . .
C9E C 1.4678(9) 0.2821(7) 0.1887(4) 0.044(3) Uani 1 1 d . . . . .
H9EA H 1.503346 0.234205 0.202878 0.053 Uiso 1 1 calc R U . . .
C10E C 1.5137(8) 0.3338(7) 0.1547(4) 0.041(3) Uani 1 1 d . . . . .
H10F H 1.579598 0.321483 0.145955 0.049 Uiso 1 1 calc R U . . .
C11E C 1.2574(7) 0.5954(7) 0.0757(4) 0.036(3) Uani 1 1 d . . . . .
C12E C 1.1738(7) 0.5476(7) 0.0541(3) 0.034(2) Uani 1 1 d . . . . .
C13E C 1.1014(8) 0.6039(8) 0.0345(4) 0.046(3) Uani 1 1 d . . . . .
H13F H 1.042399 0.574028 0.020110 0.055 Uiso 1 1 calc R U . . .
C14E C 1.1125(8) 0.7003(8) 0.0352(4) 0.049(3) Uani 1 1 d . . . . .
C15E C 1.1947(9) 0.7451(8) 0.0595(5) 0.058(4) Uani 1 1 d . . . . .
H15F H 1.200584 0.811443 0.062722 0.069 Uiso 1 1 calc R U . . .
C16E C 1.2669(8) 0.6922(7) 0.0787(4) 0.052(3) Uani 1 1 d . . . . .
H16F H 1.324190 0.722520 0.094239 0.062 Uiso 1 1 calc R U . . .
C17E C 1.1587(8) 0.4448(7) 0.0502(4) 0.045(3) Uani 1 1 d . . . . .
H17P H 1.224182 0.418015 0.048949 0.068 Uiso 1 1 calc R U . . .
H17Q H 1.119035 0.427794 0.021940 0.068 Uiso 1 1 calc R U . . .
H17R H 1.122764 0.420259 0.076953 0.068 Uiso 1 1 calc R U . . .
C18E C 1.0328(9) 0.7568(9) 0.0123(5) 0.074(4) Uani 1 1 d . . . . .
H18P H 0.965984 0.725993 0.017225 0.112 Uiso 1 1 calc R U . . .
H18Q H 1.044348 0.760695 -0.020829 0.112 Uiso 1 1 calc R U . . .
H18R H 1.036869 0.820038 0.025780 0.112 Uiso 1 1 calc R U . . .
C1S C 0.1350(10) 0.7211(10) 0.2324(5) 0.072(4) Uani 1 1 d D . . . .
C2S C 0.1385(11) 0.6593(9) 0.1950(5) 0.078(4) Uani 1 1 d D . . . .
H2SA H 0.178879 0.607311 0.197244 0.094 Uiso 1 1 calc R U . . .
C3S C 0.0818(11) 0.6739(10) 0.1535(5) 0.081(5) Uani 1 1 d D . . . .
H3SA H 0.082029 0.631276 0.128251 0.098 Uiso 1 1 calc R U . . .
C4S C 0.0256(11) 0.7532(10) 0.1511(5) 0.085(5) Uani 1 1 d D . . . .
H4SA H -0.010680 0.766864 0.123593 0.102 Uiso 1 1 calc R U . . .
C5S C 0.0240(11) 0.8121(12) 0.1902(5) 0.094(5) Uani 1 1 d D . . . .
H5SA H -0.015940 0.864441 0.189220 0.113 Uiso 1 1 calc R U . . .
C6S C 0.0768(10) 0.7961(10) 0.2283(5) 0.076(4) Uani 1 1 d D . . . .
H6SA H 0.074446 0.838029 0.253725 0.092 Uiso 1 1 calc R U . . .
C7S C 0.1901(13) 0.7027(13) 0.2753(5) 0.120(7) Uani 1 1 d D . . . .
H7SA H 0.257599 0.684766 0.268306 0.179 Uiso 1 1 calc R U . . .
H7SB H 0.154006 0.651696 0.291751 0.179 Uiso 1 1 calc R U . . .
H7SC H 0.195669 0.759389 0.294728 0.179 Uiso 1 1 calc R U . . .
C8S C 0.004(5) 0.107(6) 0.2601(10) 0.21(3) Uiso 0.5 1 d D . P A 1
C9S C 0.0079(19) 0.1230(18) 0.3073(8) 0.058(7) Uiso 0.5 1 d D . P A 1
H9SA H 0.057113 0.092558 0.324798 0.069 Uiso 0.5 1 calc R U P A 1
C10S C -0.056(3) 0.182(3) 0.3321(8) 0.099(12) Uiso 0.5 1 d D . P A 1
H10G H -0.050800 0.190238 0.364603 0.119 Uiso 0.5 1 calc R U P A 1
C11S C -0.1273(18) 0.2261(16) 0.3035(9) 0.055(7) Uiso 0.5 1 d D . P A 1
H11A H -0.173899 0.266219 0.315780 0.065 Uiso 0.5 1 calc R U P A 1
C12S C -0.124(4) 0.206(4) 0.2550(10) 0.18(2) Uiso 0.5 1 d D . P A 1
H12A H -0.171127 0.235258 0.235809 0.211 Uiso 0.5 1 calc R U P A 1
C13S C -0.065(3) 0.153(3) 0.2340(8) 0.097(12) Uiso 0.5 1 d D . P A 1
H13G H -0.068411 0.145215 0.201441 0.116 Uiso 0.5 1 calc R U P A 1
C14S C 0.073(2) 0.0517(19) 0.2355(9) 0.081(9) Uiso 0.5 1 d D . P A 1
H14A H 0.117670 0.022803 0.257765 0.122 Uiso 0.5 1 calc R U P A 1
H14B H 0.034593 0.002654 0.217236 0.122 Uiso 0.5 1 calc R U P A 1
H14C H 0.113057 0.092492 0.215021 0.122 Uiso 0.5 1 calc R U P A 1
C15S C 0.885(2) 0.539(2) 0.3542(7) 0.069(8) Uiso 0.5 1 d D . P B 1
C16S C 0.8708(17) 0.5865(16) 0.3127(6) 0.042(6) Uiso 0.5 1 d D . P B 1
H16G H 0.819738 0.629292 0.309739 0.050 Uiso 0.5 1 calc R U P B 1
C17S C 0.9349(16) 0.5698(15) 0.2736(7) 0.053(6) Uiso 0.5 1 d D . P B 1
H17S H 0.924594 0.600045 0.245016 0.063 Uiso 0.5 1 calc R U P B 1
C18S C 1.0125(19) 0.508(2) 0.2795(9) 0.082(10) Uiso 0.5 1 d D . P B 1
H18S H 1.064803 0.503497 0.258216 0.099 Uiso 0.5 1 calc R U P B 1
C19S C 1.005(3) 0.452(3) 0.3204(11) 0.123(19) Uiso 0.5 1 d D . P B 1
H19A H 1.041038 0.396725 0.321834 0.148 Uiso 0.5 1 calc R U P B 1
C20S C 0.952(2) 0.472(2) 0.3555(9) 0.097(12) Uiso 0.5 1 d D . P B 1
H20A H 0.960558 0.438235 0.383255 0.116 Uiso 0.5 1 calc R U P B 1
C21S C 0.833(2) 0.5611(19) 0.3969(7) 0.078(9) Uiso 0.5 1 d D . P B 1
H21A H 0.787116 0.610475 0.390830 0.117 Uiso 0.5 1 calc R U P B 1
H21B H 0.794274 0.504640 0.407319 0.117 Uiso 0.5 1 calc R U P B 1
H21C H 0.882782 0.582444 0.420923 0.117 Uiso 0.5 1 calc R U P B 1
C22S C 0.2360(12) 0.0690(10) 0.1298(6) 0.033(5) Uiso 0.5 1 d D . P C 1
C23S C 0.1781(12) -0.0123(11) 0.1156(7) 0.040(5) Uiso 0.5 1 d D . P C 1
H23A H 0.203368 -0.072186 0.119875 0.048 Uiso 0.5 1 calc R U P C 1
C24S C 0.0815(13) -0.0045(12) 0.0947(7) 0.046(6) Uiso 0.5 1 d D . P C 1
H24A H 0.035127 -0.057691 0.090519 0.055 Uiso 0.5 1 calc R U P C 1
C25S C 0.0576(15) 0.0827(13) 0.0809(8) 0.058(7) Uiso 0.5 1 d D . P C 1
H25A H 0.000723 0.090114 0.061136 0.070 Uiso 0.5 1 calc R U P C 1
C26S C 0.1196(13) 0.1611(12) 0.0969(7) 0.041(5) Uiso 0.5 1 d D . P C 1
H26A H 0.100479 0.222168 0.089780 0.050 Uiso 0.5 1 calc R U P C 1
C27S C 0.2012(12) 0.1524(10) 0.1207(6) 0.030(4) Uiso 0.5 1 d D . P C 1
H27A H 0.238076 0.207337 0.132369 0.036 Uiso 0.5 1 calc R U P C 1
C28S C 0.3355(15) 0.0627(18) 0.1502(10) 0.085(9) Uiso 0.5 1 d D . P C 1
H28A H 0.348390 -0.003302 0.154346 0.127 Uiso 0.5 1 calc R U P C 1
H28B H 0.385635 0.092279 0.129857 0.127 Uiso 0.5 1 calc R U P C 1
H28C H 0.339988 0.094950 0.180190 0.127 Uiso 0.5 1 calc R U P C 1
C8X C -0.005(3) 0.113(3) 0.2485(7) 0.080 Uiso 0.5 1 d D U P D 2
C9X C 0.030(2) 0.094(2) 0.2925(8) 0.080 Uiso 0.5 1 d D U P D 2
H9XA H 0.079758 0.050710 0.297597 0.096 Uiso 0.5 1 calc R U P D 2
C10X C -0.013(2) 0.143(2) 0.3311(7) 0.080 Uiso 0.5 1 d D U P D 2
H10H H 0.007674 0.131034 0.361917 0.096 Uiso 0.5 1 calc R U P D 2
C11X C -0.085(3) 0.208(2) 0.3220(9) 0.080 Uiso 0.5 1 d D U P D 2
H11B H -0.110699 0.244927 0.345655 0.096 Uiso 0.5 1 calc R U P D 2
C12X C -0.116(2) 0.216(2) 0.2745(10) 0.080 Uiso 0.5 1 d D U P D 2
H12B H -0.165245 0.258474 0.267092 0.096 Uiso 0.5 1 calc R U P D 2
C13X C -0.083(3) 0.169(3) 0.2417(9) 0.080 Uiso 0.5 1 d D U P D 2
H13H H -0.112757 0.172235 0.211749 0.096 Uiso 0.5 1 calc R U P D 2
C14X C 0.025(2) 0.078(2) 0.2044(8) 0.080 Uiso 0.5 1 d D U P D 2
H14D H 0.081447 0.037880 0.209245 0.120 Uiso 0.5 1 calc R U P D 2
H14E H -0.031601 0.041025 0.189406 0.120 Uiso 0.5 1 calc R U P D 2
H14F H 0.046603 0.130464 0.184725 0.120 Uiso 0.5 1 calc R U P D 2
C15X C 0.864(2) 0.570(2) 0.3498(8) 0.080 Uiso 0.5 1 d D U P E 2
C16X C 0.897(2) 0.576(2) 0.3043(8) 0.080 Uiso 0.5 1 d D U P E 2
H16H H 0.870918 0.621326 0.284070 0.096 Uiso 0.5 1 calc R U P E 2
C17X C 0.970(2) 0.514(2) 0.2879(8) 0.080 Uiso 0.5 1 d D U P E 2
H17T H 0.982318 0.505856 0.256093 0.096 Uiso 0.5 1 calc R U P E 2
C18X C 1.022(3) 0.466(3) 0.3229(9) 0.080 Uiso 0.5 1 d D U P E 2
H18T H 1.080819 0.435491 0.316516 0.096 Uiso 0.5 1 calc R U P E 2
C19X C 0.982(2) 0.466(2) 0.3680(9) 0.080 Uiso 0.5 1 d D U P E 2
H19B H 1.009531 0.424756 0.390007 0.096 Uiso 0.5 1 calc R U P E 2
C20X C 0.9121(19) 0.5170(19) 0.3811(8) 0.080 Uiso 0.5 1 d D U P E 2
H20B H 0.894224 0.517651 0.412538 0.096 Uiso 0.5 1 calc R U P E 2
C21X C 0.7839(19) 0.6231(19) 0.3693(9) 0.080 Uiso 0.5 1 d D U P E 2
H21D H 0.752734 0.659412 0.345009 0.120 Uiso 0.5 1 calc R U P E 2
H21E H 0.732757 0.579220 0.382438 0.120 Uiso 0.5 1 calc R U P E 2
H21F H 0.813049 0.665674 0.393604 0.120 Uiso 0.5 1 calc R U P E 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.146(6) . ?
Dy1 O1A 2.154(7) . ?
Dy1 O1B 2.324(6) . ?
Dy1 O1B 2.365(6) 2_856 ?
Dy1 N2 2.536(7) . ?
Dy1 N2A 2.543(8) . ?
Dy1 N2B 2.562(8) 2_856 ?
Dy1 Dy1 3.8181(11) 2_856 ?
Dy2 O1C 2.158(6) . ?
Dy2 O1E 2.159(6) . ?
Dy2 O1D 2.311(6) . ?
Dy2 O1D 2.375(7) 2_865 ?
Dy2 N2E 2.524(8) . ?
Dy2 N2D 2.541(8) 2_865 ?
Dy2 N2C 2.565(8) . ?
Dy2 Dy2 3.8441(11) 2_865 ?
O1 C1 1.323(10) . ?
N1 N2 1.271(10) . ?
N1 C2 1.374(11) . ?
N2 C11 1.460(12) . ?
C1 C10 1.391(13) . ?
C1 C2 1.438(13) . ?
C2 C3 1.456(12) . ?
C3 C4 1.391(13) . ?
C3 C8 1.408(13) . ?
C4 C5 1.375(13) . ?
C4 H4A 0.9500 . ?
C5 C6 1.387(14) . ?
C5 H5A 0.9500 . ?
C6 C7 1.368(14) . ?
C6 H6A 0.9500 . ?
C7 C8 1.408(13) . ?
C7 H7A 0.9500 . ?
C8 C9 1.435(13) . ?
C9 C10 1.348(13) . ?
C9 H9A 0.9500 . ?
C10 H10A 0.9500 . ?
C11 C16 1.375(14) . ?
C11 C12 1.421(15) . ?
C12 C13 1.394(14) . ?
C12 C17 1.494(15) . ?
C13 C14 1.379(16) . ?
C13 H13A 0.9500 . ?
C14 C15 1.361(17) . ?
C14 C18 1.474(16) . ?
C15 C16 1.406(15) . ?
C15 H15A 0.9500 . ?
C16 H16A 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
O1A C1A 1.314(11) . ?
N1A N2A 1.298(10) . ?
N1A C2A 1.377(11) . ?
C1A C2A 1.404(13) . ?
C1A C10A 1.432(12) . ?
N2A C11A 1.463(11) . ?
C2A C3A 1.443(13) . ?
C3A C4A 1.398(13) . ?
C3A C8A 1.423(13) . ?
C4A C5A 1.381(14) . ?
C4A H4AA 0.9500 . ?
C5A C6A 1.388(14) . ?
C5A H5AA 0.9500 . ?
C6A C7A 1.365(15) . ?
C6A H6AA 0.9500 . ?
C7A C8A 1.422(14) . ?
C7A H7AA 0.9500 . ?
C8A C9A 1.404(14) . ?
C9A C10A 1.358(14) . ?
C9A H9AA 0.9500 . ?
C10A H10B 0.9500 . ?
C11A C16A 1.389(14) . ?
C11A C12A 1.407(14) . ?
C12A C13A 1.419(14) . ?
C12A C18A 1.482(14) . ?
C13A C14A 1.373(16) . ?
C13A H13B 0.9500 . ?
C14A C15A 1.370(17) . ?
C14A C17A 1.500(14) . ?
C15A C16A 1.405(14) . ?
C15A H15B 0.9500 . ?
C16A H16B 0.9500 . ?
C17A H17D 0.9800 . ?
C17A H17E 0.9800 . ?
C17A H17F 0.9800 . ?
C18A H18D 0.9800 . ?
C18A H18E 0.9800 . ?
C18A H18F 0.9800 . ?
O1B C1B 1.343(10) . ?
N1B N2B 1.299(10) . ?
N1B C2B 1.371(11) . ?
N2B C11B 1.424(11) . ?
C1B C2B 1.395(13) . ?
C1B C10B 1.406(13) . ?
C2B C3B 1.425(12) . ?
C3B C4B 1.385(13) . ?
C3B C8B 1.425(14) . ?
C4B C5B 1.385(14) . ?
C4B H4BA 0.9500 . ?
C5B C6B 1.378(16) . ?
C5B H5BA 0.9500 . ?
C6B C7B 1.346(15) . ?
C6B H6BA 0.9500 . ?
C7B C8B 1.427(13) . ?
C7B H7BA 0.9500 . ?
C8B C9B 1.415(13) . ?
C9B C10B 1.347(13) . ?
C9B H9BA 0.9500 . ?
C10B H10C 0.9500 . ?
C11B C12B 1.389(14) . ?
C11B C16B 1.409(13) . ?
C12B C13B 1.398(14) . ?
C12B C18B 1.507(14) . ?
C13B C14B 1.388(16) . ?
C13B H13C 0.9500 . ?
C14B C15B 1.363(16) . ?
C14B C17B 1.496(15) . ?
C15B C16B 1.362(14) . ?
C15B H15C 0.9500 . ?
C16B H16C 0.9500 . ?
C17B H17G 0.9800 . ?
C17B H17H 0.9800 . ?
C17B H17I 0.9800 . ?
C18B H18G 0.9800 . ?
C18B H18H 0.9800 . ?
C18B H18I 0.9800 . ?
O1C C1C 1.314(10) . ?
N1C N2C 1.286(10) . ?
N1C C2C 1.371(11) . ?
C1C C10C 1.401(13) . ?
C1C C2C 1.409(13) . ?
N2C C11C 1.450(12) . ?
C2C C3C 1.459(12) . ?
C3C C8C 1.403(13) . ?
C3C C4C 1.420(14) . ?
C4C C5C 1.366(13) . ?
C4C H4CA 0.9500 . ?
C5C C6C 1.383(14) . ?
C5C H5CA 0.9500 . ?
C6C C7C 1.371(14) . ?
C6C H6CA 0.9500 . ?
C7C C8C 1.428(13) . ?
C7C H7CA 0.9500 . ?
C8C C9C 1.416(14) . ?
C9C C10C 1.364(14) . ?
C9C H9CA 0.9500 . ?
C10C H10D 0.9500 . ?
C11C C16C 1.365(13) . ?
C11C C12C 1.405(14) . ?
C12C C13C 1.394(14) . ?
C12C C17C 1.500(15) . ?
C13C C14C 1.404(15) . ?
C13C H13D 0.9500 . ?
C14C C15C 1.376(15) . ?
C14C C18C 1.525(14) . ?
C15C C16C 1.390(14) . ?
C15C H15D 0.9500 . ?
C16C H16D 0.9500 . ?
C17C H17J 0.9800 . ?
C17C H17K 0.9800 . ?
C17C H17L 0.9800 . ?
C18C H18J 0.9800 . ?
C18C H18K 0.9800 . ?
C18C H18L 0.9800 . ?
O1D C1D 1.371(10) . ?
N1D N2D 1.275(10) . ?
N1D C2D 1.387(11) . ?
N2D C11D 1.446(11) . ?
C1D C10D 1.393(13) . ?
C1D C2D 1.424(13) . ?
C2D C3D 1.450(12) . ?
C3D C4D 1.422(13) . ?
C3D C8D 1.427(13) . ?
C4D C5D 1.392(13) . ?
C4D H4DA 0.9500 . ?
C5D C6D 1.388(15) . ?
C5D H5DA 0.9500 . ?
C6D C7D 1.363(14) . ?
C6D H6DA 0.9500 . ?
C7D C8D 1.417(12) . ?
C7D H7DA 0.9500 . ?
C8D C9D 1.401(13) . ?
C9D C10D 1.381(13) . ?
C9D H9DA 0.9500 . ?
C10D H10E 0.9500 . ?
C11D C12D 1.375(13) . ?
C11D C16D 1.392(14) . ?
C12D C13D 1.387(14) . ?
C12D C17D 1.484(14) . ?
C13D C14D 1.353(15) . ?
C13D H13E 0.9500 . ?
C14D C15D 1.407(16) . ?
C14D C18D 1.531(14) . ?
C15D C16D 1.383(14) . ?
C15D H15E 0.9500 . ?
C16D H16E 0.9500 . ?
C17D H17M 0.9800 . ?
C17D H17N 0.9800 . ?
C17D H17O 0.9800 . ?
C18D H18M 0.9800 . ?
C18D H18N 0.9800 . ?
C18D H18O 0.9800 . ?
O1E C1E 1.276(11) . ?
N1E N2E 1.271(10) . ?
N1E C2E 1.367(11) . ?
N2E C11E 1.467(12) . ?
C1E C2E 1.421(14) . ?
C1E C10E 1.428(13) . ?
C2E C3E 1.435(14) . ?
C3E C4E 1.409(14) . ?
C3E C8E 1.437(14) . ?
C4E C5E 1.348(14) . ?
C4E H4EA 0.9500 . ?
C5E C6E 1.404(15) . ?
C5E H5EA 0.9500 . ?
C6E C7E 1.350(15) . ?
C6E H6EA 0.9500 . ?
C7E C8E 1.387(14) . ?
C7E H7EA 0.9500 . ?
C8E C9E 1.410(15) . ?
C9E C10E 1.371(14) . ?
C9E H9EA 0.9500 . ?
C10E H10F 0.9500 . ?
C11E C16E 1.383(14) . ?
C11E C12E 1.394(13) . ?
C12E C13E 1.412(13) . ?
C12E C17E 1.473(14) . ?
C13E C14E 1.376(15) . ?
C13E H13F 0.9500 . ?
C14E C15E 1.397(15) . ?
C14E C18E 1.520(14) . ?
C15E C16E 1.375(14) . ?
C15E H15F 0.9500 . ?
C16E H16F 0.9500 . ?
C17E H17P 0.9800 . ?
C17E H17Q 0.9800 . ?
C17E H17R 0.9800 . ?
C18E H18P 0.9800 . ?
C18E H18Q 0.9800 . ?
C18E H18R 0.9800 . ?
C1S C6S 1.371(14) . ?
C1S C2S 1.398(14) . ?
C1S C7S 1.463(15) . ?
C2S C3S 1.427(14) . ?
C2S H2SA 0.9500 . ?
C3S C4S 1.404(15) . ?
C3S H3SA 0.9500 . ?
C4S C5S 1.410(16) . ?
C4S H4SA 0.9500 . ?
C5S C6S 1.322(15) . ?
C5S H5SA 0.9500 . ?
C6S H6SA 0.9500 . ?
C7S H7SA 0.9800 . ?
C7S H7SB 0.9800 . ?
C7S H7SC 0.9800 . ?
C8S C13S 1.368(18) . ?
C8S C9S 1.384(17) . ?
C8S C14S 1.459(18) . ?
C9S C10S 1.441(18) . ?
C9S H9SA 0.9500 . ?
C10S C11S 1.431(19) . ?
C10S H10G 0.9500 . ?
C11S C12S 1.438(19) . ?
C11S H11A 0.9500 . ?
C12S C13S 1.299(19) . ?
C12S H12A 0.9500 . ?
C13S H13G 0.9500 . ?
C14S H14A 0.9800 . ?
C14S H14B 0.9800 . ?
C14S H14C 0.9800 . ?
C15S C20S 1.365(17) . ?
C15S C16S 1.401(16) . ?
C15S C21S 1.478(17) . ?
C16S C17S 1.467(17) . ?
C16S H16G 0.9500 . ?
C17S C18S 1.419(19) . ?
C17S H17S 0.9500 . ?
C18S C19S 1.44(2) . ?
C18S H18S 0.9500 . ?
C19S C20S 1.299(19) . ?
C19S H19A 0.9500 . ?
C20S H20A 0.9500 . ?
C21S H21A 0.9800 . ?
C21S H21B 0.9800 . ?
C21S H21C 0.9800 . ?
C22S C27S 1.337(16) . ?
C22S C28S 1.445(17) . ?
C22S C23S 1.400(16) . ?
C23S C24S 1.418(17) . ?
C23S H23A 0.9500 . ?
C24S C25S 1.369(18) . ?
C24S H24A 0.9500 . ?
C25S C26S 1.411(18) . ?
C25S H25A 0.9500 . ?
C26S C27S 1.285(17) . ?
C26S H26A 0.9500 . ?
C27S H27A 0.9500 . ?
C28S H28A 0.9800 . ?
C28S H28B 0.9800 . ?
C28S H28C 0.9800 . ?
C8X C13X 1.363(17) . ?
C8X C14X 1.452(17) . ?
C8X C9X 1.379(17) . ?
C9X C10X 1.470(18) . ?
C9X H9XA 0.9500 . ?
C10X C11X 1.402(19) . ?
C10X H10H 0.9500 . ?
C11X C12X 1.434(19) . ?
C11X H11B 0.9500 . ?
C12X C13X 1.270(19) . ?
C12X H12B 0.9500 . ?
C13X H13H 0.9500 . ?
C14X H14D 0.9800 . ?
C14X H14E 0.9800 . ?
C14X H14F 0.9800 . ?
C15X C20X 1.370(18) . ?
C15X C21X 1.471(17) . ?
C15X C16X 1.404(17) . ?
C16X C17X 1.459(18) . ?
C16X H16H 0.9500 . ?
C17X C18X 1.419(19) . ?
C17X H17T 0.9500 . ?
C18X C19X 1.424(19) . ?
C18X H18T 0.9500 . ?
C19X C20X 1.295(19) . ?
C19X H19B 0.9500 . ?
C20X H20B 0.9500 . ?
C21X H21D 0.9800 . ?
C21X H21E 0.9800 . ?
C21X H21F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O1A 150.2(2) . . ?
O1 Dy1 O1B 91.8(2) . . ?
O1A Dy1 O1B 108.1(2) . . ?
O1 Dy1 O1B 132.8(2) . 2_856 ?
O1A Dy1 O1B 75.9(2) . 2_856 ?
O1B Dy1 O1B 71.0(2) . 2_856 ?
O1 Dy1 N2 69.0(2) . . ?
O1A Dy1 N2 86.5(2) . . ?
O1B Dy1 N2 158.3(2) . . ?
O1B Dy1 N2 129.5(2) 2_856 . ?
O1 Dy1 N2A 90.2(2) . . ?
O1A Dy1 N2A 70.4(2) . . ?
O1B Dy1 N2A 84.7(2) . . ?
O1B Dy1 N2A 129.3(2) 2_856 . ?
N2 Dy1 N2A 85.3(2) . . ?
O1 Dy1 N2B 82.4(2) . 2_856 ?
O1A Dy1 N2B 107.9(2) . 2_856 ?
O1B Dy1 N2B 114.1(2) . 2_856 ?
O1B Dy1 N2B 67.0(2) 2_856 2_856 ?
N2 Dy1 N2B 74.5(2) . 2_856 ?
N2A Dy1 N2B 159.9(2) . 2_856 ?
O1 Dy1 Dy1 116.10(17) . 2_856 ?
O1A Dy1 Dy1 92.21(17) . 2_856 ?
O1B Dy1 Dy1 35.84(14) . 2_856 ?
O1B Dy1 Dy1 35.12(14) 2_856 2_856 ?
N2 Dy1 Dy1 163.57(17) . 2_856 ?
N2A Dy1 Dy1 109.68(18) . 2_856 ?
N2B Dy1 Dy1 90.36(17) 2_856 2_856 ?
O1C Dy2 O1E 147.2(2) . . ?
O1C Dy2 O1D 93.1(2) . . ?
O1E Dy2 O1D 110.6(2) . . ?
O1C Dy2 O1D 133.3(2) . 2_865 ?
O1E Dy2 O1D 77.8(2) . 2_865 ?
O1D Dy2 O1D 69.8(2) . 2_865 ?
O1C Dy2 N2E 91.4(2) . . ?
O1E Dy2 N2E 69.6(2) . . ?
O1D Dy2 N2E 84.6(2) . . ?
O1D Dy2 N2E 127.6(2) 2_865 . ?
O1C Dy2 N2D 82.6(2) . 2_865 ?
O1E Dy2 N2D 106.5(2) . 2_865 ?
O1D Dy2 N2D 113.8(2) . 2_865 ?
O1D Dy2 N2D 67.2(2) 2_865 2_865 ?
N2E Dy2 N2D 160.9(3) . 2_865 ?
O1C Dy2 N2C 68.6(2) . . ?
O1E Dy2 N2C 83.2(2) . . ?
O1D Dy2 N2C 159.3(2) . . ?
O1D Dy2 N2C 129.8(2) 2_865 . ?
N2E Dy2 N2C 86.2(2) . . ?
N2D Dy2 N2C 74.7(2) 2_865 . ?
O1C Dy2 Dy2 117.13(16) . 2_865 ?
O1E Dy2 Dy2 94.65(17) . 2_865 ?
O1D Dy2 Dy2 35.44(16) . 2_865 ?
O1D Dy2 Dy2 34.35(14) 2_865 2_865 ?
N2E Dy2 Dy2 108.67(18) . 2_865 ?
N2D Dy2 Dy2 90.16(18) 2_865 2_865 ?
N2C Dy2 Dy2 163.30(17) . 2_865 ?
C1 O1 Dy1 147.3(6) . . ?
N2 N1 C2 121.4(8) . . ?
N1 N2 C11 110.2(7) . . ?
N1 N2 Dy1 135.6(6) . . ?
C11 N2 Dy1 114.1(5) . . ?
O1 C1 C10 123.1(9) . . ?
O1 C1 C2 119.9(8) . . ?
C10 C1 C2 117.0(8) . . ?
N1 C2 C1 125.6(8) . . ?
N1 C2 C3 115.5(8) . . ?
C1 C2 C3 118.9(8) . . ?
C4 C3 C8 117.9(8) . . ?
C4 C3 C2 122.0(8) . . ?
C8 C3 C2 120.1(8) . . ?
C5 C4 C3 120.5(10) . . ?
C5 C4 H4A 119.7 . . ?
C3 C4 H4A 119.7 . . ?
C4 C5 C6 121.5(10) . . ?
C4 C5 H5A 119.3 . . ?
C6 C5 H5A 119.3 . . ?
C7 C6 C5 119.6(9) . . ?
C7 C6 H6A 120.2 . . ?
C5 C6 H6A 120.2 . . ?
C6 C7 C8 119.5(9) . . ?
C6 C7 H7A 120.2 . . ?
C8 C7 H7A 120.2 . . ?
C3 C8 C7 120.9(9) . . ?
C3 C8 C9 118.3(9) . . ?
C7 C8 C9 120.5(9) . . ?
C10 C9 C8 120.2(9) . . ?
C10 C9 H9A 119.9 . . ?
C8 C9 H9A 119.9 . . ?
C9 C10 C1 124.6(10) . . ?
C9 C10 H10A 117.7 . . ?
C1 C10 H10A 117.7 . . ?
C16 C11 C12 120.1(10) . . ?
C16 C11 N2 118.6(10) . . ?
C12 C11 N2 121.1(9) . . ?
C13 C12 C11 117.0(11) . . ?
C13 C12 C17 121.1(11) . . ?
C11 C12 C17 121.8(9) . . ?
C14 C13 C12 123.6(11) . . ?
C14 C13 H13A 118.2 . . ?
C12 C13 H13A 118.2 . . ?
C15 C14 C13 117.6(11) . . ?
C15 C14 C18 120.9(13) . . ?
C13 C14 C18 121.3(13) . . ?
C14 C15 C16 121.9(11) . . ?
C14 C15 H15A 119.0 . . ?
C16 C15 H15A 119.0 . . ?
C11 C16 C15 119.6(11) . . ?
C11 C16 H16A 120.2 . . ?
C15 C16 H16A 120.2 . . ?
C12 C17 H17A 109.5 . . ?
C12 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C12 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C14 C18 H18A 109.5 . . ?
C14 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C14 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C1A O1A Dy1 143.6(6) . . ?
N2A N1A C2A 121.5(8) . . ?
O1A C1A C2A 122.6(8) . . ?
O1A C1A C10A 118.2(9) . . ?
C2A C1A C10A 118.6(9) . . ?
N1A N2A C11A 109.4(7) . . ?
N1A N2A Dy1 133.3(6) . . ?
C11A N2A Dy1 116.8(6) . . ?
N1A C2A C1A 126.2(9) . . ?
N1A C2A C3A 113.1(8) . . ?
C1A C2A C3A 120.6(8) . . ?
C4A C3A C8A 118.6(9) . . ?
C4A C3A C2A 123.3(9) . . ?
C8A C3A C2A 118.1(9) . . ?
C5A C4A C3A 120.9(10) . . ?
C5A C4A H4AA 119.5 . . ?
C3A C4A H4AA 119.5 . . ?
C4A C5A C6A 120.7(10) . . ?
C4A C5A H5AA 119.6 . . ?
C6A C5A H5AA 119.6 . . ?
C7A C6A C5A 120.1(10) . . ?
C7A C6A H6AA 119.9 . . ?
C5A C6A H6AA 119.9 . . ?
C6A C7A C8A 120.8(10) . . ?
C6A C7A H7AA 119.6 . . ?
C8A C7A H7AA 119.6 . . ?
C9A C8A C3A 119.8(9) . . ?
C9A C8A C7A 121.4(9) . . ?
C3A C8A C7A 118.9(9) . . ?
C10A C9A C8A 121.9(9) . . ?
C10A C9A H9AA 119.1 . . ?
C8A C9A H9AA 119.1 . . ?
C9A C10A C1A 120.7(10) . . ?
C9A C10A H10B 119.6 . . ?
C1A C10A H10B 119.6 . . ?
C16A C11A C12A 121.7(9) . . ?
C16A C11A N2A 117.1(9) . . ?
C12A C11A N2A 121.1(9) . . ?
C11A C12A C13A 115.5(10) . . ?
C11A C12A C18A 123.1(9) . . ?
C13A C12A C18A 121.3(10) . . ?
C14A C13A C12A 124.0(11) . . ?
C14A C13A H13B 118.0 . . ?
C12A C13A H13B 118.0 . . ?
C15A C14A C13A 118.2(10) . . ?
C15A C14A C17A 121.4(12) . . ?
C13A C14A C17A 120.3(12) . . ?
C14A C15A C16A 121.4(11) . . ?
C14A C15A H15B 119.3 . . ?
C16A C15A H15B 119.3 . . ?
C11A C16A C15A 119.2(11) . . ?
C11A C16A H16B 120.4 . . ?
C15A C16A H16B 120.4 . . ?
C14A C17A H17D 109.5 . . ?
C14A C17A H17E 109.5 . . ?
H17D C17A H17E 109.5 . . ?
C14A C17A H17F 109.5 . . ?
H17D C17A H17F 109.5 . . ?
H17E C17A H17F 109.5 . . ?
C12A C18A H18D 109.5 . . ?
C12A C18A H18E 109.5 . . ?
H18D C18A H18E 109.5 . . ?
C12A C18A H18F 109.5 . . ?
H18D C18A H18F 109.5 . . ?
H18E C18A H18F 109.5 . . ?
C1B O1B Dy1 135.2(6) . . ?
C1B O1B Dy1 114.0(5) . 2_856 ?
Dy1 O1B Dy1 109.0(2) . 2_856 ?
N2B N1B C2B 120.3(8) . . ?
N1B N2B C11B 111.6(7) . . ?
N1B N2B Dy1 122.1(6) . 2_856 ?
C11B N2B Dy1 122.3(6) . 2_856 ?
O1B C1B C2B 122.6(8) . . ?
O1B C1B C10B 119.9(9) . . ?
C2B C1B C10B 117.5(9) . . ?
N1B C2B C1B 125.3(8) . . ?
N1B C2B C3B 113.4(8) . . ?
C1B C2B C3B 120.8(9) . . ?
C4B C3B C2B 122.8(9) . . ?
C4B C3B C8B 117.7(9) . . ?
C2B C3B C8B 119.5(8) . . ?
C3B C4B C5B 120.5(11) . . ?
C3B C4B H4BA 119.8 . . ?
C5B C4B H4BA 119.8 . . ?
C6B C5B C4B 122.0(11) . . ?
C6B C5B H5BA 119.0 . . ?
C4B C5B H5BA 119.0 . . ?
C7B C6B C5B 119.6(11) . . ?
C7B C6B H6BA 120.2 . . ?
C5B C6B H6BA 120.2 . . ?
C6B C7B C8B 120.5(11) . . ?
C6B C7B H7BA 119.8 . . ?
C8B C7B H7BA 119.8 . . ?
C9B C8B C3B 118.3(9) . . ?
C9B C8B C7B 122.0(10) . . ?
C3B C8B C7B 119.7(10) . . ?
C10B C9B C8B 120.4(9) . . ?
C10B C9B H9BA 119.8 . . ?
C8B C9B H9BA 119.8 . . ?
C9B C10B C1B 123.6(10) . . ?
C9B C10B H10C 118.2 . . ?
C1B C10B H10C 118.2 . . ?
C12B C11B C16B 119.3(9) . . ?
C12B C11B N2B 120.7(9) . . ?
C16B C11B N2B 119.9(9) . . ?
C11B C12B C13B 118.6(10) . . ?
C11B C12B C18B 121.2(9) . . ?
C13B C12B C18B 120.3(10) . . ?
C14B C13B C12B 121.8(10) . . ?
C14B C13B H13C 119.1 . . ?
C12B C13B H13C 119.1 . . ?
C15B C14B C13B 117.9(10) . . ?
C15B C14B C17B 120.2(12) . . ?
C13B C14B C17B 121.8(11) . . ?
C16B C15B C14B 122.7(12) . . ?
C16B C15B H15C 118.7 . . ?
C14B C15B H15C 118.7 . . ?
C15B C16B C11B 119.5(10) . . ?
C15B C16B H16C 120.2 . . ?
C11B C16B H16C 120.2 . . ?
C14B C17B H17G 109.5 . . ?
C14B C17B H17H 109.5 . . ?
H17G C17B H17H 109.5 . . ?
C14B C17B H17I 109.5 . . ?
H17G C17B H17I 109.5 . . ?
H17H C17B H17I 109.5 . . ?
C12B C18B H18G 109.5 . . ?
C12B C18B H18H 109.5 . . ?
H18G C18B H18H 109.5 . . ?
C12B C18B H18I 109.5 . . ?
H18G C18B H18I 109.5 . . ?
H18H C18B H18I 109.5 . . ?
C1C O1C Dy2 147.5(6) . . ?
N2C N1C C2C 121.3(8) . . ?
O1C C1C C10C 120.6(9) . . ?
O1C C1C C2C 120.3(8) . . ?
C10C C1C C2C 119.1(9) . . ?
N1C N2C C11C 109.7(8) . . ?
N1C N2C Dy2 134.2(6) . . ?
C11C N2C Dy2 116.0(5) . . ?
N1C C2C C1C 126.5(8) . . ?
N1C C2C C3C 114.6(8) . . ?
C1C C2C C3C 118.9(8) . . ?
C8C C3C C4C 118.6(9) . . ?
C8C C3C C2C 119.7(9) . . ?
C4C C3C C2C 121.7(9) . . ?
C5C C4C C3C 120.1(10) . . ?
C5C C4C H4CA 119.9 . . ?
C3C C4C H4CA 120.0 . . ?
C4C C5C C6C 122.0(10) . . ?
C4C C5C H5CA 119.0 . . ?
C6C C5C H5CA 119.0 . . ?
C7C C6C C5C 119.4(9) . . ?
C7C C6C H6CA 120.3 . . ?
C5C C6C H6CA 120.3 . . ?
C6C C7C C8C 120.5(10) . . ?
C6C C7C H7CA 119.7 . . ?
C8C C7C H7CA 119.7 . . ?
C3C C8C C9C 118.6(9) . . ?
C3C C8C C7C 119.3(10) . . ?
C9C C8C C7C 122.1(9) . . ?
C10C C9C C8C 121.5(10) . . ?
C10C C9C H9CA 119.3 . . ?
C8C C9C H9CA 119.3 . . ?
C9C C10C C1C 121.6(10) . . ?
C9C C10C H10D 119.2 . . ?
C1C C10C H10D 119.2 . . ?
C16C C11C C12C 120.5(9) . . ?
C16C C11C N2C 118.4(9) . . ?
C12C C11C N2C 121.0(9) . . ?
C13C C12C C11C 117.9(10) . . ?
C13C C12C C17C 119.4(10) . . ?
C11C C12C C17C 122.7(10) . . ?
C12C C13C C14C 121.7(11) . . ?
C12C C13C H13D 119.2 . . ?
C14C C13C H13D 119.2 . . ?
C15C C14C C13C 118.6(10) . . ?
C15C C14C C18C 123.0(11) . . ?
C13C C14C C18C 118.5(11) . . ?
C14C C15C C16C 120.3(10) . . ?
C14C C15C H15D 119.8 . . ?
C16C C15C H15D 119.8 . . ?
C11C C16C C15C 121.0(10) . . ?
C11C C16C H16D 119.5 . . ?
C15C C16C H16D 119.5 . . ?
C12C C17C H17J 109.5 . . ?
C12C C17C H17K 109.5 . . ?
H17J C17C H17K 109.5 . . ?
C12C C17C H17L 109.5 . . ?
H17J C17C H17L 109.5 . . ?
H17K C17C H17L 109.5 . . ?
C14C C18C H18J 109.5 . . ?
C14C C18C H18K 109.5 . . ?
H18J C18C H18K 109.5 . . ?
C14C C18C H18L 109.5 . . ?
H18J C18C H18L 109.5 . . ?
H18K C18C H18L 109.5 . . ?
C1D O1D Dy2 135.2(6) . . ?
C1D O1D Dy2 112.2(6) . 2_865 ?
Dy2 O1D Dy2 110.2(2) . 2_865 ?
N2D N1D C2D 119.4(8) . . ?
N1D N2D C11D 112.1(7) . . ?
N1D N2D Dy2 121.6(6) . 2_865 ?
C11D N2D Dy2 122.3(6) . 2_865 ?
O1D C1D C10D 119.0(8) . . ?
O1D C1D C2D 121.0(8) . . ?
C10D C1D C2D 119.9(8) . . ?
N1D C2D C1D 125.8(8) . . ?
N1D C2D C3D 114.1(8) . . ?
C1D C2D C3D 119.8(8) . . ?
C4D C3D C8D 119.5(8) . . ?
C4D C3D C2D 122.1(9) . . ?
C8D C3D C2D 118.3(8) . . ?
C5D C4D C3D 119.1(9) . . ?
C5D C4D H4DA 120.4 . . ?
C3D C4D H4DA 120.4 . . ?
C6D C5D C4D 120.6(10) . . ?
C6D C5D H5DA 119.7 . . ?
C4D C5D H5DA 119.7 . . ?
C7D C6D C5D 121.6(9) . . ?
C7D C6D H6DA 119.2 . . ?
C5D C6D H6DA 119.2 . . ?
C6D C7D C8D 120.2(10) . . ?
C6D C7D H7DA 119.9 . . ?
C8D C7D H7DA 119.9 . . ?
C9D C8D C7D 122.2(9) . . ?
C9D C8D C3D 118.9(8) . . ?
C7D C8D C3D 118.9(9) . . ?
C10D C9D C8D 122.8(9) . . ?
C10D C9D H9DA 118.6 . . ?
C8D C9D H9DA 118.6 . . ?
C9D C10D C1D 119.9(9) . . ?
C9D C10D H10E 120.1 . . ?
C1D C10D H10E 120.1 . . ?
C12D C11D C16D 121.7(9) . . ?
C12D C11D N2D 119.7(9) . . ?
C16D C11D N2D 118.4(9) . . ?
C11D C12D C13D 117.6(10) . . ?
C11D C12D C17D 122.9(9) . . ?
C13D C12D C17D 119.4(10) . . ?
C14D C13D C12D 123.0(11) . . ?
C14D C13D H13E 118.5 . . ?
C12D C13D H13E 118.5 . . ?
C13D C14D C15D 118.5(10) . . ?
C13D C14D C18D 120.6(11) . . ?
C15D C14D C18D 120.8(11) . . ?
C16D C15D C14D 120.3(11) . . ?
C16D C15D H15E 119.9 . . ?
C14D C15D H15E 119.9 . . ?
C15D C16D C11D 118.8(10) . . ?
C15D C16D H16E 120.6 . . ?
C11D C16D H16E 120.6 . . ?
C12D C17D H17M 109.5 . . ?
C12D C17D H17N 109.5 . . ?
H17M C17D H17N 109.5 . . ?
C12D C17D H17O 109.5 . . ?
H17M C17D H17O 109.5 . . ?
H17N C17D H17O 109.5 . . ?
C14D C18D H18M 109.5 . . ?
C14D C18D H18N 109.5 . . ?
H18M C18D H18N 109.5 . . ?
C14D C18D H18O 109.5 . . ?
H18M C18D H18O 109.5 . . ?
H18N C18D H18O 109.5 . . ?
C1E O1E Dy2 144.8(6) . . ?
N2E N1E C2E 122.4(8) . . ?
N1E N2E C11E 110.1(8) . . ?
N1E N2E Dy2 134.5(6) . . ?
C11E N2E Dy2 114.7(6) . . ?
O1E C1E C2E 123.4(8) . . ?
O1E C1E C10E 117.8(9) . . ?
C2E C1E C10E 118.8(10) . . ?
N1E C2E C1E 124.0(9) . . ?
N1E C2E C3E 115.4(9) . . ?
C1E C2E C3E 120.5(9) . . ?
C4E C3E C2E 122.7(9) . . ?
C4E C3E C8E 117.9(10) . . ?
C2E C3E C8E 119.4(10) . . ?
C5E C4E C3E 121.0(10) . . ?
C5E C4E H4EA 119.5 . . ?
C3E C4E H4EA 119.5 . . ?
C4E C5E C6E 121.1(11) . . ?
C4E C5E H5EA 119.4 . . ?
C6E C5E H5EA 119.4 . . ?
C7E C6E C5E 119.0(11) . . ?
C7E C6E H6EA 120.5 . . ?
C5E C6E H6EA 120.5 . . ?
C6E C7E C8E 122.6(11) . . ?
C6E C7E H7EA 118.7 . . ?
C8E C7E H7EA 118.7 . . ?
C7E C8E C9E 123.7(10) . . ?
C7E C8E C3E 118.3(10) . . ?
C9E C8E C3E 117.9(10) . . ?
C10E C9E C8E 123.2(10) . . ?
C10E C9E H9EA 118.4 . . ?
C8E C9E H9EA 118.4 . . ?
C9E C10E C1E 120.2(10) . . ?
C9E C10E H10F 119.9 . . ?
C1E C10E H10F 119.9 . . ?
C16E C11E C12E 121.6(9) . . ?
C16E C11E N2E 117.9(9) . . ?
C12E C11E N2E 120.5(9) . . ?
C11E C12E C13E 116.0(9) . . ?
C11E C12E C17E 124.3(9) . . ?
C13E C12E C17E 119.7(9) . . ?
C14E C13E C12E 122.8(10) . . ?
C14E C13E H13F 118.6 . . ?
C12E C13E H13F 118.6 . . ?
C13E C14E C15E 119.1(10) . . ?
C13E C14E C18E 120.1(11) . . ?
C15E C14E C18E 120.7(11) . . ?
C16E C15E C14E 119.3(11) . . ?
C16E C15E H15F 120.4 . . ?
C14E C15E H15F 120.4 . . ?
C15E C16E C11E 121.0(11) . . ?
C15E C16E H16F 119.5 . . ?
C11E C16E H16F 119.5 . . ?
C12E C17E H17P 109.5 . . ?
C12E C17E H17Q 109.5 . . ?
H17P C17E H17Q 109.5 . . ?
C12E C17E H17R 109.5 . . ?
H17P C17E H17R 109.5 . . ?
H17Q C17E H17R 109.5 . . ?
C14E C18E H18P 109.5 . . ?
C14E C18E H18Q 109.5 . . ?
H18P C18E H18Q 109.5 . . ?
C14E C18E H18R 109.5 . . ?
H18P C18E H18R 109.5 . . ?
H18Q C18E H18R 109.5 . . ?
C6S C1S C2S 118.9(12) . . ?
C6S C1S C7S 121.6(13) . . ?
C2S C1S C7S 119.5(13) . . ?
C3S C2S C1S 120.2(12) . . ?
C3S C2S H2SA 119.9 . . ?
C1S C2S H2SA 119.9 . . ?
C4S C3S C2S 118.1(13) . . ?
C4S C3S H3SA 121.0 . . ?
C2S C3S H3SA 121.0 . . ?
C5S C4S C3S 118.8(13) . . ?
C5S C4S H4SA 120.6 . . ?
C3S C4S H4SA 120.6 . . ?
C6S C5S C4S 121.5(14) . . ?
C6S C5S H5SA 119.3 . . ?
C4S C5S H5SA 119.3 . . ?
C5S C6S C1S 122.4(13) . . ?
C5S C6S H6SA 118.8 . . ?
C1S C6S H6SA 118.8 . . ?
C1S C7S H7SA 109.5 . . ?
C1S C7S H7SB 109.5 . . ?
H7SA C7S H7SB 109.5 . . ?
C1S C7S H7SC 109.5 . . ?
H7SA C7S H7SC 109.5 . . ?
H7SB C7S H7SC 109.5 . . ?
C13S C8S C9S 118.2(18) . . ?
C13S C8S C14S 117(2) . . ?
C9S C8S C14S 124(2) . . ?
C10S C9S C8S 125.6(18) . . ?
C10S C9S H9SA 117.2 . . ?
C8S C9S H9SA 117.2 . . ?
C11S C10S C9S 114.2(17) . . ?
C11S C10S H10G 122.9 . . ?
C9S C10S H10G 122.9 . . ?
C12S C11S C10S 115.5(17) . . ?
C12S C11S H11A 122.3 . . ?
C10S C11S H11A 122.2 . . ?
C13S C12S C11S 128(2) . . ?
C13S C12S H12A 115.9 . . ?
C11S C12S H12A 115.9 . . ?
C12S C13S C8S 118(2) . . ?
C12S C13S H13G 120.8 . . ?
C8S C13S H13G 120.9 . . ?
C8S C14S H14A 109.5 . . ?
C8S C14S H14B 109.5 . . ?
H14A C14S H14B 109.5 . . ?
C8S C14S H14C 109.5 . . ?
H14A C14S H14C 109.5 . . ?
H14B C14S H14C 109.5 . . ?
C20S C15S C16S 117.9(16) . . ?
C20S C15S C21S 118.6(18) . . ?
C16S C15S C21S 123.5(18) . . ?
C17S C16S C15S 120.1(15) . . ?
C17S C16S H16G 119.9 . . ?
C15S C16S H16G 119.9 . . ?
C18S C17S C16S 118.7(16) . . ?
C18S C17S H17S 120.7 . . ?
C16S C17S H17S 120.7 . . ?
C17S C18S C19S 114.2(18) . . ?
C17S C18S H18S 122.9 . . ?
C19S C18S H18S 122.9 . . ?
C20S C19S C18S 124(2) . . ?
C20S C19S H19A 118.1 . . ?
C18S C19S H19A 118.1 . . ?
C19S C20S C15S 123(2) . . ?
C19S C20S H20A 118.5 . . ?
C15S C20S H20A 118.5 . . ?
C15S C21S H21A 109.5 . . ?
C15S C21S H21B 109.5 . . ?
H21A C21S H21B 109.5 . . ?
C15S C21S H21C 109.5 . . ?
H21A C21S H21C 109.5 . . ?
H21B C21S H21C 109.5 . . ?
C27S C22S C28S 120.5(15) . . ?
C27S C22S C23S 119.0(14) . . ?
C28S C22S C23S 120.3(15) . . ?
C24S C23S C22S 119.4(14) . . ?
C24S C23S H23A 120.3 . . ?
C22S C23S H23A 120.3 . . ?
C25S C24S C23S 117.5(15) . . ?
C25S C24S H24A 121.3 . . ?
C23S C24S H24A 121.3 . . ?
C24S C25S C26S 118.3(16) . . ?
C24S C25S H25A 120.8 . . ?
C26S C25S H25A 120.9 . . ?
C27S C26S C25S 122.0(16) . . ?
C27S C26S H26A 119.0 . . ?
C25S C26S H26A 119.0 . . ?
C26S C27S C22S 122.4(15) . . ?
C26S C27S H27A 118.8 . . ?
C22S C27S H27A 118.8 . . ?
C22S C28S H28A 109.5 . . ?
C22S C28S H28B 109.5 . . ?
H28A C28S H28B 109.5 . . ?
C22S C28S H28C 109.5 . . ?
H28A C28S H28C 109.5 . . ?
H28B C28S H28C 109.5 . . ?
C13X C8X C14X 109.4(18) . . ?
C13X C8X C9X 120.8(17) . . ?
C14X C8X C9X 130(2) . . ?
C8X C9X C10X 117.5(17) . . ?
C8X C9X H9XA 121.2 . . ?
C10X C9X H9XA 121.3 . . ?
C11X C10X C9X 119.5(17) . . ?
C11X C10X H10H 120.3 . . ?
C9X C10X H10H 120.2 . . ?
C10X C11X C12X 115.5(17) . . ?
C10X C11X H11B 122.2 . . ?
C12X C11X H11B 122.3 . . ?
C13X C12X C11X 124(2) . . ?
C13X C12X H12B 117.9 . . ?
C11X C12X H12B 117.8 . . ?
C12X C13X C8X 121.6(19) . . ?
C12X C13X H13H 119.2 . . ?
C8X C13X H13H 119.3 . . ?
C8X C14X H14D 109.5 . . ?
C8X C14X H14E 109.5 . . ?
H14D C14X H14E 109.5 . . ?
C8X C14X H14F 109.5 . . ?
H14D C14X H14F 109.5 . . ?
H14E C14X H14F 109.5 . . ?
C20X C15X C21X 114.1(17) . . ?
C20X C15X C16X 119.7(17) . . ?
C21X C15X C16X 125.9(19) . . ?
C15X C16X C17X 120.5(18) . . ?
C15X C16X H16H 119.7 . . ?
C17X C16X H16H 119.7 . . ?
C18X C17X C16X 115.1(18) . . ?
C18X C17X H17T 122.4 . . ?
C16X C17X H17T 122.4 . . ?
C17X C18X C19X 117.8(19) . . ?
C17X C18X H18T 121.1 . . ?
C19X C18X H18T 121.1 . . ?
C20X C19X C18X 125(2) . . ?
C20X C19X H19B 117.7 . . ?
C18X C19X H19B 117.7 . . ?
C19X C20X C15X 120.2(19) . . ?
C19X C20X H20B 119.9 . . ?
C15X C20X H20B 119.9 . . ?
C15X C21X H21D 109.5 . . ?
C15X C21X H21E 109.5 . . ?
H21D C21X H21E 109.5 . . ?
C15X C21X H21F 109.5 . . ?
H21D C21X H21F 109.5 . . ?
H21E C21X H21F 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N1 N2 C11 175.1(8) . . . . ?
C2 N1 N2 Dy1 -1.3(13) . . . . ?
Dy1 O1 C1 C10 179.4(7) . . . . ?
Dy1 O1 C1 C2 2.7(16) . . . . ?
N2 N1 C2 C1 -9.7(15) . . . . ?
N2 N1 C2 C3 172.3(8) . . . . ?
O1 C1 C2 N1 10.3(15) . . . . ?
C10 C1 C2 N1 -166.6(9) . . . . ?
O1 C1 C2 C3 -171.8(8) . . . . ?
C10 C1 C2 C3 11.3(13) . . . . ?
N1 C2 C3 C4 -11.3(14) . . . . ?
C1 C2 C3 C4 170.6(9) . . . . ?
N1 C2 C3 C8 169.5(9) . . . . ?
C1 C2 C3 C8 -8.6(14) . . . . ?
C8 C3 C4 C5 3.0(16) . . . . ?
C2 C3 C4 C5 -176.2(10) . . . . ?
C3 C4 C5 C6 -2.5(18) . . . . ?
C4 C5 C6 C7 0.3(18) . . . . ?
C5 C6 C7 C8 1.2(17) . . . . ?
C4 C3 C8 C7 -1.5(15) . . . . ?
C2 C3 C8 C7 177.7(9) . . . . ?
C4 C3 C8 C9 -176.6(10) . . . . ?
C2 C3 C8 C9 2.6(15) . . . . ?
C6 C7 C8 C3 -0.6(16) . . . . ?
C6 C7 C8 C9 174.4(10) . . . . ?
C3 C8 C9 C10 0.3(16) . . . . ?
C7 C8 C9 C10 -174.8(10) . . . . ?
C8 C9 C10 C1 3.0(17) . . . . ?
O1 C1 C10 C9 174.4(10) . . . . ?
C2 C1 C10 C9 -8.9(15) . . . . ?
N1 N2 C11 C16 109.9(10) . . . . ?
Dy1 N2 C11 C16 -72.9(10) . . . . ?
N1 N2 C11 C12 -74.7(11) . . . . ?
Dy1 N2 C11 C12 102.5(9) . . . . ?
C16 C11 C12 C13 0.4(15) . . . . ?
N2 C11 C12 C13 -174.9(9) . . . . ?
C16 C11 C12 C17 -179.6(10) . . . . ?
N2 C11 C12 C17 5.0(14) . . . . ?
C11 C12 C13 C14 -0.9(17) . . . . ?
C17 C12 C13 C14 179.2(11) . . . . ?
C12 C13 C14 C15 0.1(19) . . . . ?
C12 C13 C14 C18 174.7(13) . . . . ?
C13 C14 C15 C16 1.2(19) . . . . ?
C18 C14 C15 C16 -173.5(13) . . . . ?
C12 C11 C16 C15 0.8(16) . . . . ?
N2 C11 C16 C15 176.3(9) . . . . ?
C14 C15 C16 C11 -1.7(18) . . . . ?
Dy1 O1A C1A C2A -16.8(15) . . . . ?
Dy1 O1A C1A C10A 171.8(7) . . . . ?
C2A N1A N2A C11A -174.2(8) . . . . ?
C2A N1A N2A Dy1 -2.0(12) . . . . ?
N2A N1A C2A C1A 10.2(14) . . . . ?
N2A N1A C2A C3A -174.3(8) . . . . ?
O1A C1A C2A N1A -3.5(14) . . . . ?
C10A C1A C2A N1A 167.9(9) . . . . ?
O1A C1A C2A C3A -178.7(8) . . . . ?
C10A C1A C2A C3A -7.3(13) . . . . ?
N1A C2A C3A C4A 10.1(13) . . . . ?
C1A C2A C3A C4A -174.1(9) . . . . ?
N1A C2A C3A C8A -170.0(8) . . . . ?
C1A C2A C3A C8A 5.8(13) . . . . ?
C8A C3A C4A C5A 1.3(14) . . . . ?
C2A C3A C4A C5A -178.8(9) . . . . ?
C3A C4A C5A C6A 0.8(15) . . . . ?
C4A C5A C6A C7A -2.6(16) . . . . ?
C5A C6A C7A C8A 2.3(16) . . . . ?
C4A C3A C8A C9A 178.1(9) . . . . ?
C2A C3A C8A C9A -1.9(13) . . . . ?
C4A C3A C8A C7A -1.5(14) . . . . ?
C2A C3A C8A C7A 178.5(8) . . . . ?
C6A C7A C8A C9A -179.8(10) . . . . ?
C6A C7A C8A C3A -0.2(15) . . . . ?
C3A C8A C9A C10A -0.4(15) . . . . ?
C7A C8A C9A C10A 179.2(10) . . . . ?
C8A C9A C10A C1A -1.2(16) . . . . ?
O1A C1A C10A C9A 176.8(9) . . . . ?
C2A C1A C10A C9A 5.0(14) . . . . ?
N1A N2A C11A C16A -121.1(9) . . . . ?
Dy1 N2A C11A C16A 65.2(10) . . . . ?
N1A N2A C11A C12A 62.1(12) . . . . ?
Dy1 N2A C11A C12A -111.6(9) . . . . ?
C16A C11A C12A C13A -0.2(15) . . . . ?
N2A C11A C12A C13A 176.4(9) . . . . ?
C16A C11A C12A C18A 179.5(10) . . . . ?
N2A C11A C12A C18A -3.9(15) . . . . ?
C11A C12A C13A C14A -0.8(16) . . . . ?
C18A C12A C13A C14A 179.5(11) . . . . ?
C12A C13A C14A C15A 1.3(17) . . . . ?
C12A C13A C14A C17A -175.6(10) . . . . ?
C13A C14A C15A C16A -0.8(17) . . . . ?
C17A C14A C15A C16A 176.0(11) . . . . ?
C12A C11A C16A C15A 0.6(15) . . . . ?
N2A C11A C16A C15A -176.1(9) . . . . ?
C14A C15A C16A C11A -0.1(16) . . . . ?
C2B N1B N2B C11B 179.1(8) . . . . ?
C2B N1B N2B Dy1 21.1(11) . . . 2_856 ?
Dy1 O1B C1B C2B 141.2(8) . . . . ?
Dy1 O1B C1B C2B -56.4(11) 2_856 . . . ?
Dy1 O1B C1B C10B -38.8(13) . . . . ?
Dy1 O1B C1B C10B 123.7(8) 2_856 . . . ?
N2B N1B C2B C1B 24.9(15) . . . . ?
N2B N1B C2B C3B -163.3(8) . . . . ?
O1B C1B C2B N1B -7.1(16) . . . . ?
C10B C1B C2B N1B 172.8(9) . . . . ?
O1B C1B C2B C3B -178.4(9) . . . . ?
C10B C1B C2B C3B 1.6(15) . . . . ?
N1B C2B C3B C4B 5.8(14) . . . . ?
C1B C2B C3B C4B 178.0(10) . . . . ?
N1B C2B C3B C8B -174.6(9) . . . . ?
C1B C2B C3B C8B -2.4(15) . . . . ?
C2B C3B C4B C5B 178.6(11) . . . . ?
C8B C3B C4B C5B -1.0(17) . . . . ?
C3B C4B C5B C6B 0(2) . . . . ?
C4B C5B C6B C7B 2(2) . . . . ?
C5B C6B C7B C8B -3(2) . . . . ?
C4B C3B C8B C9B -178.7(10) . . . . ?
C2B C3B C8B C9B 1.7(15) . . . . ?
C4B C3B C8B C7B 0.1(16) . . . . ?
C2B C3B C8B C7B -179.5(10) . . . . ?
C6B C7B C8B C9B -179.2(12) . . . . ?
C6B C7B C8B C3B 2.0(18) . . . . ?
C3B C8B C9B C10B -0.2(17) . . . . ?
C7B C8B C9B C10B -179.1(11) . . . . ?
C8B C9B C10B C1B -0.5(18) . . . . ?
O1B C1B C10B C9B 179.8(10) . . . . ?
C2B C1B C10B C9B -0.1(16) . . . . ?
N1B N2B C11B C12B 131.6(10) . . . . ?
Dy1 N2B C11B C12B -70.4(11) 2_856 . . . ?
N1B N2B C11B C16B -49.3(12) . . . . ?
Dy1 N2B C11B C16B 108.6(9) 2_856 . . . ?
C16B C11B C12B C13B -3.5(15) . . . . ?
N2B C11B C12B C13B 175.5(9) . . . . ?
C16B C11B C12B C18B 176.7(9) . . . . ?
N2B C11B C12B C18B -4.3(15) . . . . ?
C11B C12B C13B C14B 0.5(16) . . . . ?
C18B C12B C13B C14B -179.7(10) . . . . ?
C12B C13B C14B C15B 1.4(17) . . . . ?
C12B C13B C14B C17B -176.3(10) . . . . ?
C13B C14B C15B C16B -0.1(18) . . . . ?
C17B C14B C15B C16B 177.6(11) . . . . ?
C14B C15B C16B C11B -3.0(17) . . . . ?
C12B C11B C16B C15B 4.8(16) . . . . ?
N2B C11B C16B C15B -174.3(9) . . . . ?
Dy2 O1C C1C C10C 177.5(8) . . . . ?
Dy2 O1C C1C C2C -3.7(18) . . . . ?
C2C N1C N2C C11C -175.8(8) . . . . ?
C2C N1C N2C Dy2 2.2(13) . . . . ?
N2C N1C C2C C1C 10.2(15) . . . . ?
N2C N1C C2C C3C -172.6(8) . . . . ?
O1C C1C C2C N1C -11.0(16) . . . . ?
C10C C1C C2C N1C 167.8(10) . . . . ?
O1C C1C C2C C3C 171.8(9) . . . . ?
C10C C1C C2C C3C -9.4(15) . . . . ?
N1C C2C C3C C8C -171.8(9) . . . . ?
C1C C2C C3C C8C 5.7(15) . . . . ?
N1C C2C C3C C4C 10.6(14) . . . . ?
C1C C2C C3C C4C -171.9(10) . . . . ?
C8C C3C C4C C5C -1.3(16) . . . . ?
C2C C3C C4C C5C 176.4(10) . . . . ?
C3C C4C C5C C6C 2.9(17) . . . . ?
C4C C5C C6C C7C -1.0(18) . . . . ?
C5C C6C C7C C8C -2.5(18) . . . . ?
C4C C3C C8C C9C 178.9(10) . . . . ?
C2C C3C C8C C9C 1.3(15) . . . . ?
C4C C3C C8C C7C -2.1(15) . . . . ?
C2C C3C C8C C7C -179.8(10) . . . . ?
C6C C7C C8C C3C 4.1(17) . . . . ?
C6C C7C C8C C9C -177.0(11) . . . . ?
C3C C8C C9C C10C -4.7(17) . . . . ?
C7C C8C C9C C10C 176.4(11) . . . . ?
C8C C9C C10C C1C 1.0(18) . . . . ?
O1C C1C C10C C9C -175.0(10) . . . . ?
C2C C1C C10C C9C 6.3(17) . . . . ?
N1C N2C C11C C16C -104.4(10) . . . . ?
Dy2 N2C C11C C16C 77.1(9) . . . . ?
N1C N2C C11C C12C 78.7(10) . . . . ?
Dy2 N2C C11C C12C -99.7(9) . . . . ?
C16C C11C C12C C13C -0.7(14) . . . . ?
N2C C11C C12C C13C 176.0(9) . . . . ?
C16C C11C C12C C17C 179.4(10) . . . . ?
N2C C11C C12C C17C -3.9(14) . . . . ?
C11C C12C C13C C14C 0.6(15) . . . . ?
C17C C12C C13C C14C -179.5(10) . . . . ?
C12C C13C C14C C15C 0.4(16) . . . . ?
C12C C13C C14C C18C -179.7(10) . . . . ?
C13C C14C C15C C16C -1.2(16) . . . . ?
C18C C14C C15C C16C 178.9(11) . . . . ?
C12C C11C C16C C15C -0.1(15) . . . . ?
N2C C11C C16C C15C -176.9(9) . . . . ?
C14C C15C C16C C11C 1.1(16) . . . . ?
C2D N1D N2D C11D 176.8(8) . . . . ?
C2D N1D N2D Dy2 -25.3(11) . . . 2_865 ?
Dy2 O1D C1D C10D 33.5(14) . . . . ?
Dy2 O1D C1D C10D -126.8(9) 2_865 . . . ?
Dy2 O1D C1D C2D -145.4(8) . . . . ?
Dy2 O1D C1D C2D 54.4(11) 2_865 . . . ?
N2D N1D C2D C1D -25.0(15) . . . . ?
N2D N1D C2D C3D 161.2(9) . . . . ?
O1D C1D C2D N1D 9.7(16) . . . . ?
C10D C1D C2D N1D -169.1(10) . . . . ?
O1D C1D C2D C3D -176.8(9) . . . . ?
C10D C1D C2D C3D 4.4(15) . . . . ?
N1D C2D C3D C4D -7.1(14) . . . . ?
C1D C2D C3D C4D 178.7(10) . . . . ?
N1D C2D C3D C8D 174.7(9) . . . . ?
C1D C2D C3D C8D 0.5(15) . . . . ?
C8D C3D C4D C5D 0.5(16) . . . . ?
C2D C3D C4D C5D -177.6(10) . . . . ?
C3D C4D C5D C6D 1.5(17) . . . . ?
C4D C5D C6D C7D -2(2) . . . . ?
C5D C6D C7D C8D 1.0(19) . . . . ?
C6D C7D C8D C9D -179.0(11) . . . . ?
C6D C7D C8D C3D 1.0(17) . . . . ?
C4D C3D C8D C9D 178.2(10) . . . . ?
C2D C3D C8D C9D -3.5(15) . . . . ?
C4D C3D C8D C7D -1.7(16) . . . . ?
C2D C3D C8D C7D 176.5(10) . . . . ?
C7D C8D C9D C10D -178.2(11) . . . . ?
C3D C8D C9D C10D 1.9(17) . . . . ?
C8D C9D C10D C1D 3.1(17) . . . . ?
O1D C1D C10D C9D 175.0(10) . . . . ?
C2D C1D C10D C9D -6.2(16) . . . . ?
N1D N2D C11D C12D -136.1(10) . . . . ?
Dy2 N2D C11D C12D 66.2(11) 2_865 . . . ?
N1D N2D C11D C16D 48.6(12) . . . . ?
Dy2 N2D C11D C16D -109.1(9) 2_865 . . . ?
C16D C11D C12D C13D -0.7(16) . . . . ?
N2D C11D C12D C13D -175.8(9) . . . . ?
C16D C11D C12D C17D -179.4(10) . . . . ?
N2D C11D C12D C17D 5.4(16) . . . . ?
C11D C12D C13D C14D 2.1(17) . . . . ?
C17D C12D C13D C14D -179.1(11) . . . . ?
C12D C13D C14D C15D -1.6(18) . . . . ?
C12D C13D C14D C18D 176.6(11) . . . . ?
C13D C14D C15D C16D -0.3(17) . . . . ?
C18D C14D C15D C16D -178.5(11) . . . . ?
C14D C15D C16D C11D 1.6(17) . . . . ?
C12D C11D C16D C15D -1.1(16) . . . . ?
N2D C11D C16D C15D 174.1(9) . . . . ?
C2E N1E N2E C11E 174.6(9) . . . . ?
C2E N1E N2E Dy2 4.8(14) . . . . ?
Dy2 O1E C1E C2E 10.8(16) . . . . ?
Dy2 O1E C1E C10E -169.4(7) . . . . ?
N2E N1E C2E C1E -10.4(15) . . . . ?
N2E N1E C2E C3E 173.5(9) . . . . ?
O1E C1E C2E N1E 4.6(15) . . . . ?
C10E C1E C2E N1E -175.2(9) . . . . ?
O1E C1E C2E C3E -179.5(9) . . . . ?
C10E C1E C2E C3E 0.7(14) . . . . ?
N1E C2E C3E C4E -2.8(14) . . . . ?
C1E C2E C3E C4E -179.0(9) . . . . ?
N1E C2E C3E C8E 174.4(9) . . . . ?
C1E C2E C3E C8E -1.8(14) . . . . ?
C2E C3E C4E C5E 178.1(10) . . . . ?
C8E C3E C4E C5E 0.8(15) . . . . ?
C3E C4E C5E C6E -0.7(16) . . . . ?
C4E C5E C6E C7E 1.0(17) . . . . ?
C5E C6E C7E C8E -1.5(17) . . . . ?
C6E C7E C8E C9E -178.6(10) . . . . ?
C6E C7E C8E C3E 1.7(16) . . . . ?
C4E C3E C8E C7E -1.3(14) . . . . ?
C2E C3E C8E C7E -178.6(9) . . . . ?
C4E C3E C8E C9E 179.0(9) . . . . ?
C2E C3E C8E C9E 1.7(14) . . . . ?
C7E C8E C9E C10E 179.7(10) . . . . ?
C3E C8E C9E C10E -0.6(16) . . . . ?
C8E C9E C10E C1E -0.5(16) . . . . ?
O1E C1E C10E C9E -179.4(9) . . . . ?
C2E C1E C10E C9E 0.4(15) . . . . ?
N1E N2E C11E C16E 123.5(10) . . . . ?
Dy2 N2E C11E C16E -64.5(11) . . . . ?
N1E N2E C11E C12E -57.6(12) . . . . ?
Dy2 N2E C11E C12E 114.5(9) . . . . ?
C16E C11E C12E C13E 1.6(16) . . . . ?
N2E C11E C12E C13E -177.3(9) . . . . ?
C16E C11E C12E C17E -179.4(11) . . . . ?
N2E C11E C12E C17E 1.7(16) . . . . ?
C11E C12E C13E C14E 1.6(17) . . . . ?
C17E C12E C13E C14E -177.4(11) . . . . ?
C12E C13E C14E C15E -5.2(19) . . . . ?
C12E C13E C14E C18E 178.3(11) . . . . ?
C13E C14E C15E C16E 5(2) . . . . ?
C18E C14E C15E C16E -178.1(12) . . . . ?
C14E C15E C16E C11E -2(2) . . . . ?
C12E C11E C16E C15E -1.3(19) . . . . ?
N2E C11E C16E C15E 177.7(11) . . . . ?
C6S C1S C2S C3S 0(2) . . . . ?
C7S C1S C2S C3S 177.3(15) . . . . ?
C1S C2S C3S C4S 2(2) . . . . ?
C2S C3S C4S C5S -3(2) . . . . ?
C3S C4S C5S C6S 2(3) . . . . ?
C4S C5S C6S C1S -1(3) . . . . ?
C2S C1S C6S C5S 0(2) . . . . ?
C7S C1S C6S C5S -177.8(16) . . . . ?
C13S C8S C9S C10S 2(11) . . . . ?
C14S C8S C9S C10S 176(6) . . . . ?
C8S C9S C10S C11S -1(7) . . . . ?
C9S C10S C11S C12S 0(5) . . . . ?
C10S C11S C12S C13S 0(8) . . . . ?
C11S C12S C13S C8S 1(10) . . . . ?
C9S C8S C13S C12S -2(11) . . . . ?
C14S C8S C13S C12S -177(6) . . . . ?
C20S C15S C16S C17S -6(5) . . . . ?
C21S C15S C16S C17S 172(3) . . . . ?
C15S C16S C17S C18S -2(4) . . . . ?
C16S C17S C18S C19S 13(4) . . . . ?
C17S C18S C19S C20S -19(7) . . . . ?
C18S C19S C20S C15S 11(8) . . . . ?
C16S C15S C20S C19S 2(6) . . . . ?
C21S C15S C20S C19S -176(4) . . . . ?
C27S C22S C23S C24S -4(3) . . . . ?
C28S C22S C23S C24S -179(2) . . . . ?
C22S C23S C24S C25S 13(3) . . . . ?
C23S C24S C25S C26S -14(3) . . . . ?
C24S C25S C26S C27S 5(3) . . . . ?
C25S C26S C27S C22S 4(3) . . . . ?
C28S C22S C27S C26S 170(2) . . . . ?
C23S C22S C27S C26S -5(3) . . . . ?
C13X C8X C9X C10X -6(5) . . . . ?
C14X C8X C9X C10X 178(4) . . . . ?
C8X C9X C10X C11X -1(4) . . . . ?
C9X C10X C11X C12X 5(4) . . . . ?
C10X C11X C12X C13X -1(6) . . . . ?
C11X C12X C13X C8X -7(7) . . . . ?
C14X C8X C13X C12X -173(4) . . . . ?
C9X C8X C13X C12X 11(7) . . . . ?
C20X C15X C16X C17X 11(5) . . . . ?
C21X C15X C16X C17X -174(3) . . . . ?
C15X C16X C17X C18X -15(5) . . . . ?
C16X C17X C18X C19X 14(6) . . . . ?
C17X C18X C19X C20X -11(6) . . . . ?
C18X C19X C20X C15X 6(6) . . . . ?
C21X C15X C20X C19X 178(3) . . . . ?
C16X C15X C20X C19X -6(5) . . . . ?

_refine_diff_density_max         2.389
_refine_diff_density_min         -2.370
_refine_diff_density_rms         0.167




_exptl_crystal_preparation       'Magnetic properties,Luminescent'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_a
_database_code_depnum_ccdc_archive 'CCDC 1972627'
loop_
_audit_author_name
_audit_author_address
'Konstantin Lyssenko'
;Chemical Department MSU
Russia
;
_audit_update_record             
;
2019-12-17 deposited with the CCDC.	2020-02-06 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C57 H42 Dy N3 O3'
_chemical_formula_sum            'C57 H42 Dy N3 O3'
_chemical_formula_weight         979.43

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.3117(6)
_cell_length_b                   23.0212(12)
_cell_length_c                   17.7515(10)
_cell_angle_alpha                90
_cell_angle_beta                 107.3737(14)
_cell_angle_gamma                90
_cell_volume                     4411.8(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    120(2)
_cell_measurement_reflns_used    3697
_cell_measurement_theta_min      2.621
_cell_measurement_theta_max      26.63


_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.475
_exptl_crystal_F_000             1980
_exptl_transmission_factor_min   0.615
_exptl_transmission_factor_max   0.721
_exptl_crystal_size_max          0.320
_exptl_crystal_size_mid          0.250
_exptl_crystal_size_min          0.210
_exptl_absorpt_coefficient_mu    1.744
_shelx_estimated_absorpt_T_min   0.605
_shelx_estimated_absorpt_T_max   0.711
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      120(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  "Bruker APEX II CCD area detector'"
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            41712
_diffrn_reflns_av_unetI/netI     0.1005
_diffrn_reflns_av_R_equivalents  0.1005
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.886
_diffrn_reflns_theta_max         28.998
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             11729
_reflns_number_gt                7758
_reflns_threshold_expression     I>2σ(I)
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX II'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0376P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         11729
_refine_ls_number_parameters     577
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0900
_refine_ls_R_factor_gt           0.0464
_refine_ls_wR_factor_ref         0.1032
_refine_ls_wR_factor_gt          0.0870
_refine_ls_goodness_of_fit_ref   0.978
_refine_ls_restrained_S_all      0.978
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.46334(2) 0.30275(2) 0.34206(2) 0.01528(6) Uani 1 1 d . . . . .
O1 O 0.4467(3) 0.22215(12) 0.39851(18) 0.0180(7) Uani 1 1 d . . . . .
C1 C 0.4701(4) 0.17476(18) 0.4449(3) 0.0171(9) Uani 1 1 d . . . . .
C2 C 0.5927(4) 0.15336(17) 0.4735(2) 0.0163(9) Uani 1 1 d . . . . .
C3 C 0.6931(4) 0.18194(19) 0.4572(3) 0.0209(10) Uani 1 1 d . . . . .
H3A H 0.6781 0.2163 0.4261 0.025 Uiso 1 1 calc R U . . .
C4 C 0.8104(5) 0.1612(2) 0.4853(3) 0.0288(11) Uani 1 1 d . . . . .
H4A H 0.8764 0.1814 0.4740 0.035 Uiso 1 1 calc R U . . .
C5 C 0.8359(5) 0.1095(2) 0.5314(3) 0.0350(13) Uani 1 1 d . . . . .
H5A H 0.9181 0.0951 0.5507 0.042 Uiso 1 1 calc R U . . .
C6 C 0.7401(5) 0.0808(2) 0.5475(3) 0.0301(12) Uani 1 1 d . . . . .
H6A H 0.7570 0.0461 0.5780 0.036 Uiso 1 1 calc R U . . .
C7 C 0.6160(5) 0.10148(19) 0.5198(3) 0.0240(11) Uani 1 1 d . . . . .
C8 C 0.5196(5) 0.0732(2) 0.5383(3) 0.0285(12) Uani 1 1 d . . . . .
H8A H 0.5363 0.0391 0.5699 0.034 Uiso 1 1 calc R U . . .
C9 C 0.3983(5) 0.09433(19) 0.5109(3) 0.0232(10) Uani 1 1 d . . . . .
C10 C 0.2974(5) 0.0653(2) 0.5277(3) 0.0316(13) Uani 1 1 d . . . . .
H10A H 0.3130 0.0312 0.5594 0.038 Uiso 1 1 calc R U . . .
C11 C 0.1808(5) 0.0852(2) 0.4997(3) 0.0338(13) Uani 1 1 d . . . . .
H11A H 0.1155 0.0646 0.5113 0.041 Uiso 1 1 calc R U . . .
C12 C 0.1534(5) 0.1364(2) 0.4531(3) 0.0272(11) Uani 1 1 d . . . . .
H12A H 0.0703 0.1496 0.4332 0.033 Uiso 1 1 calc R U . . .
C13 C 0.2472(5) 0.1668(2) 0.4368(3) 0.0244(11) Uani 1 1 d . . . . .
H13A H 0.2289 0.2017 0.4070 0.029 Uiso 1 1 calc R U . . .
C14 C 0.3711(5) 0.14671(18) 0.4639(3) 0.0203(10) Uani 1 1 d . . . . .
O2 O 0.6532(3) 0.32211(13) 0.40816(19) 0.0222(7) Uani 1 1 d . . . . .
C1A C 0.7623(4) 0.34678(18) 0.4363(3) 0.0193(10) Uani 1 1 d . . . . .
C2A C 0.8613(4) 0.33274(19) 0.4049(3) 0.0210(10) Uani 1 1 d . . . . .
C3A C 0.8519(5) 0.2864(2) 0.3507(3) 0.0270(11) Uani 1 1 d . . . . .
H3AA H 0.7786 0.2636 0.3353 0.032 Uiso 1 1 calc R U . . .
C4A C 0.9468(5) 0.2740(2) 0.3204(3) 0.0361(13) Uani 1 1 d . . . . .
H4AA H 0.9398 0.2423 0.2852 0.043 Uiso 1 1 calc R U . . .
C5A C 1.0559(5) 0.3085(2) 0.3416(3) 0.0360(13) Uani 1 1 d . . . . .
H5AA H 1.1204 0.3006 0.3189 0.043 Uiso 1 1 calc R U . . .
C6A C 1.0681(5) 0.3518(2) 0.3931(3) 0.0351(13) Uani 1 1 d . . . . .
H6AA H 1.1416 0.3745 0.4061 0.042 Uiso 1 1 calc R U . . .
C7A C 0.9740(5) 0.3654(2) 0.4296(3) 0.0255(11) Uani 1 1 d . . . . .
C8A C 0.9910(4) 0.4075(2) 0.4882(3) 0.0306(12) Uani 1 1 d . . . . .
H8AA H 1.0662 0.4289 0.5039 0.037 Uiso 1 1 calc R U . . .
C9A C 0.8995(4) 0.41871(19) 0.5240(3) 0.0234(10) Uani 1 1 d . . . . .
C10A C 0.9176(5) 0.4589(2) 0.5884(3) 0.0352(13) Uani 1 1 d . . . . .
H10B H 0.9943 0.4788 0.6072 0.042 Uiso 1 1 calc R U . . .
C11A C 0.8282(5) 0.4687(2) 0.6225(3) 0.0338(13) Uani 1 1 d . . . . .
H11B H 0.8422 0.4957 0.6647 0.041 Uiso 1 1 calc R U . . .
C12A C 0.7136(5) 0.4394(2) 0.5962(3) 0.0309(12) Uani 1 1 d . . . . .
H12B H 0.6517 0.4468 0.6212 0.037 Uiso 1 1 calc R U . . .
C13A C 0.6902(5) 0.40036(19) 0.5351(3) 0.0260(11) Uani 1 1 d . . . . .
H13B H 0.6122 0.3814 0.5178 0.031 Uiso 1 1 calc R U . . .
C14A C 0.7833(4) 0.38823(18) 0.4975(3) 0.0204(10) Uani 1 1 d . . . . .
O3 O 0.4164(3) 0.38357(12) 0.28206(19) 0.0210(7) Uani 1 1 d . . . . .
C1B C 0.3983(4) 0.43664(18) 0.2512(3) 0.0179(9) Uani 1 1 d . . . . .
C2B C 0.2771(4) 0.45984(18) 0.2228(3) 0.0183(9) Uani 1 1 d . . . . .
C3B C 0.1720(4) 0.42758(19) 0.2286(3) 0.0220(10) Uani 1 1 d . . . . .
H3BA H 0.1837 0.3902 0.2524 0.026 Uiso 1 1 calc R U . . .
C4B C 0.0555(5) 0.4498(2) 0.2005(3) 0.0263(11) Uani 1 1 d . . . . .
H4BA H -0.0130 0.4278 0.2053 0.032 Uiso 1 1 calc R U . . .
C5B C 0.0351(5) 0.5050(2) 0.1644(3) 0.0291(11) Uani 1 1 d . . . . .
H5BA H -0.0467 0.5199 0.1444 0.035 Uiso 1 1 calc R U . . .
C6B C 0.1336(5) 0.5370(2) 0.1583(3) 0.0254(11) Uani 1 1 d . . . . .
H6BA H 0.1191 0.5742 0.1343 0.030 Uiso 1 1 calc R U . . .
C7B C 0.2580(4) 0.51592(19) 0.1870(3) 0.0212(10) Uani 1 1 d . . . . .
C8B C 0.3592(5) 0.54778(19) 0.1798(3) 0.0227(10) Uani 1 1 d . . . . .
H8BA H 0.3459 0.5850 0.1557 0.027 Uiso 1 1 calc R U . . .
C9B C 0.4794(5) 0.52584(18) 0.2075(3) 0.0209(10) Uani 1 1 d . . . . .
C10B C 0.5842(5) 0.55642(19) 0.1978(3) 0.0250(11) Uani 1 1 d . . . . .
H10C H 0.5720 0.5928 0.1713 0.030 Uiso 1 1 calc R U . . .
C11B C 0.7006(5) 0.5345(2) 0.2255(3) 0.0297(12) Uani 1 1 d . . . . .
H11C H 0.7685 0.5557 0.2183 0.036 Uiso 1 1 calc R U . . .
C12B C 0.7217(5) 0.4801(2) 0.2651(3) 0.0298(12) Uani 1 1 d . . . . .
H12C H 0.8036 0.4653 0.2847 0.036 Uiso 1 1 calc R U . . .
C13B C 0.6256(5) 0.4493(2) 0.2751(3) 0.0248(11) Uani 1 1 d . . . . .
H13C H 0.6412 0.4131 0.3019 0.030 Uiso 1 1 calc R U . . .
C14B C 0.5017(4) 0.46996(18) 0.2461(3) 0.0189(10) Uani 1 1 d . . . . .
N1S N 0.5486(4) 0.26104(16) 0.2397(2) 0.0228(9) Uani 1 1 d . . . . .
N2S N 0.3851(3) 0.34853(15) 0.4475(2) 0.0193(8) Uani 1 1 d . . . . .
N3S N 0.2754(4) 0.26072(15) 0.2337(2) 0.0206(8) Uani 1 1 d . . . . .
C1S C 0.5829(5) 0.20532(19) 0.2452(3) 0.0250(11) Uani 1 1 d . . . . .
H1SA H 0.5543 0.1808 0.2792 0.030 Uiso 1 1 calc R U . . .
C2S C 0.6571(5) 0.1814(2) 0.2047(3) 0.0319(12) Uani 1 1 d . . . . .
H2SA H 0.6789 0.1414 0.2105 0.038 Uiso 1 1 calc R U . . .
C3S C 0.6993(5) 0.2167(2) 0.1552(3) 0.0341(13) Uani 1 1 d . . . . .
H3SA H 0.7505 0.2013 0.1262 0.041 Uiso 1 1 calc R U . . .
C4S C 0.6664(5) 0.2741(2) 0.1486(3) 0.0331(13) Uani 1 1 d . . . . .
H4SA H 0.6953 0.2994 0.1157 0.040 Uiso 1 1 calc R U . . .
C5S C 0.5901(5) 0.2946(2) 0.1909(3) 0.0291(11) Uani 1 1 d . . . . .
H5SA H 0.5660 0.3343 0.1852 0.035 Uiso 1 1 calc R U . . .
C6S C 0.3783(4) 0.4068(2) 0.4542(3) 0.0235(10) Uani 1 1 d . . . . .
H6SA H 0.3859 0.4303 0.4118 0.028 Uiso 1 1 calc R U . . .
C7S C 0.3610(5) 0.4339(2) 0.5188(3) 0.0291(12) Uani 1 1 d . . . . .
H7SA H 0.3575 0.4751 0.5208 0.035 Uiso 1 1 calc R U . . .
C8S C 0.3486(5) 0.4007(2) 0.5812(3) 0.0310(12) Uani 1 1 d . . . . .
H8SA H 0.3372 0.4185 0.6268 0.037 Uiso 1 1 calc R U . . .
C9S C 0.3533(5) 0.3411(2) 0.5749(3) 0.0294(12) Uani 1 1 d . . . . .
H9SA H 0.3434 0.3170 0.6160 0.035 Uiso 1 1 calc R U . . .
C10S C 0.3729(4) 0.31629(19) 0.5077(3) 0.0206(10) Uani 1 1 d . . . . .
H10D H 0.3778 0.2752 0.5046 0.025 Uiso 1 1 calc R U . . .
C11S C 0.2248(4) 0.20857(19) 0.2391(3) 0.0226(10) Uani 1 1 d . . . . .
H11D H 0.2616 0.1857 0.2847 0.027 Uiso 1 1 calc R U . . .
C12S C 0.1229(5) 0.1860(2) 0.1828(3) 0.0301(12) Uani 1 1 d . . . . .
H12D H 0.0900 0.1492 0.1902 0.036 Uiso 1 1 calc R U . . .
C13S C 0.0701(5) 0.2181(2) 0.1157(3) 0.0314(12) Uani 1 1 d . . . . .
H13D H -0.0006 0.2042 0.0761 0.038 Uiso 1 1 calc R U . . .
C14S C 0.1224(5) 0.2710(2) 0.1074(3) 0.0304(12) Uani 1 1 d . . . . .
H14A H 0.0889 0.2937 0.0613 0.036 Uiso 1 1 calc R U . . .
C15S C 0.2235(5) 0.29065(19) 0.1665(3) 0.0251(11) Uani 1 1 d . . . . .
H15A H 0.2585 0.3271 0.1597 0.030 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O3 2.131(3) . ?
Dy1 O1 2.144(3) . ?
Dy1 O2 2.164(3) . ?
Dy1 N1S 2.490(4) . ?
Dy1 N2S 2.527(4) . ?
Dy1 N3S 2.591(4) . ?
O1 C1 1.345(5) . ?
C1 C2 1.415(6) . ?
C1 C14 1.418(6) . ?
C2 C3 1.415(6) . ?
C2 C7 1.429(6) . ?
C3 C4 1.358(6) . ?
C3 H3A 0.9500 . ?
C4 C5 1.424(7) . ?
C4 H4A 0.9500 . ?
C5 C6 1.370(7) . ?
C5 H5A 0.9500 . ?
C6 C7 1.425(7) . ?
C6 H6A 0.9500 . ?
C7 C8 1.391(7) . ?
C8 C9 1.398(7) . ?
C8 H8A 0.9500 . ?
C9 C10 1.430(7) . ?
C9 C14 1.446(6) . ?
C10 C11 1.343(8) . ?
C10 H10A 0.9500 . ?
C11 C12 1.420(7) . ?
C11 H11A 0.9500 . ?
C12 C13 1.372(7) . ?
C12 H12A 0.9500 . ?
C13 C14 1.417(7) . ?
C13 H13A 0.9500 . ?
O2 C1A 1.314(5) . ?
C1A C14A 1.413(6) . ?
C1A C2A 1.428(6) . ?
C2A C3A 1.419(6) . ?
C2A C7A 1.433(6) . ?
C3A C4A 1.366(7) . ?
C3A H3AA 0.9500 . ?
C4A C5A 1.420(8) . ?
C4A H4AA 0.9500 . ?
C5A C6A 1.333(7) . ?
C5A H5AA 0.9500 . ?
C6A C7A 1.435(7) . ?
C6A H6AA 0.9500 . ?
C7A C8A 1.393(7) . ?
C8A C9A 1.392(7) . ?
C8A H8AA 0.9500 . ?
C9A C10A 1.436(7) . ?
C9A C14A 1.439(6) . ?
C10A C11A 1.345(8) . ?
C10A H10B 0.9500 . ?
C11A C12A 1.412(7) . ?
C11A H11B 0.9500 . ?
C12A C13A 1.371(7) . ?
C12A H12B 0.9500 . ?
C13A C14A 1.433(7) . ?
C13A H13B 0.9500 . ?
O3 C1B 1.329(5) . ?
C1B C2B 1.416(6) . ?
C1B C14B 1.423(6) . ?
C2B C7B 1.426(6) . ?
C2B C3B 1.432(6) . ?
C3B C4B 1.362(7) . ?
C3B H3BA 0.9500 . ?
C4B C5B 1.412(7) . ?
C4B H4BA 0.9500 . ?
C5B C6B 1.366(7) . ?
C5B H5BA 0.9500 . ?
C6B C7B 1.430(6) . ?
C6B H6BA 0.9500 . ?
C7B C8B 1.397(7) . ?
C8B C9B 1.396(7) . ?
C8B H8BA 0.9500 . ?
C9B C10B 1.433(7) . ?
C9B C14B 1.443(6) . ?
C10B C11B 1.358(7) . ?
C10B H10C 0.9500 . ?
C11B C12B 1.422(7) . ?
C11B H11C 0.9500 . ?
C12B C13B 1.353(7) . ?
C12B H12C 0.9500 . ?
C13B C14B 1.423(6) . ?
C13B H13C 0.9500 . ?
N1S C1S 1.335(5) . ?
N1S C5S 1.346(6) . ?
N2S C10S 1.342(5) . ?
N2S C6S 1.352(6) . ?
N3S C11S 1.346(5) . ?
N3S C15S 1.350(6) . ?
C1S C2S 1.374(7) . ?
C1S H1SA 0.9500 . ?
C2S C3S 1.383(7) . ?
C2S H2SA 0.9500 . ?
C3S C4S 1.368(7) . ?
C3S H3SA 0.9500 . ?
C4S C5S 1.386(7) . ?
C4S H4SA 0.9500 . ?
C5S H5SA 0.9500 . ?
C6S C7S 1.369(7) . ?
C6S H6SA 0.9500 . ?
C7S C8S 1.387(7) . ?
C7S H7SA 0.9500 . ?
C8S C9S 1.379(7) . ?
C8S H8SA 0.9500 . ?
C9S C10S 1.398(7) . ?
C9S H9SA 0.9500 . ?
C10S H10D 0.9500 . ?
C11S C12S 1.382(7) . ?
C11S H11D 0.9500 . ?
C12S C13S 1.376(7) . ?
C12S H12D 0.9500 . ?
C13S C14S 1.382(7) . ?
C13S H13D 0.9500 . ?
C14S C15S 1.377(7) . ?
C14S H14A 0.9500 . ?
C15S H15A 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Dy1 O1 161.07(12) . . ?
O3 Dy1 O2 98.62(12) . . ?
O1 Dy1 O2 97.83(11) . . ?
O3 Dy1 N1S 93.73(12) . . ?
O1 Dy1 N1S 96.57(12) . . ?
O2 Dy1 N1S 86.38(12) . . ?
O3 Dy1 N2S 85.18(12) . . ?
O1 Dy1 N2S 85.16(11) . . ?
O2 Dy1 N2S 91.32(12) . . ?
N1S Dy1 N2S 177.28(12) . . ?
O3 Dy1 N3S 85.89(12) . . ?
O1 Dy1 N3S 81.76(11) . . ?
O2 Dy1 N3S 160.19(12) . . ?
N1S Dy1 N3S 74.04(13) . . ?
N2S Dy1 N3S 108.33(12) . . ?
C1 O1 Dy1 163.7(3) . . ?
O1 C1 C2 119.7(4) . . ?
O1 C1 C14 119.3(4) . . ?
C2 C1 C14 121.0(4) . . ?
C3 C2 C1 121.7(4) . . ?
C3 C2 C7 119.0(4) . . ?
C1 C2 C7 119.4(4) . . ?
C4 C3 C2 121.2(4) . . ?
C4 C3 H3A 119.4 . . ?
C2 C3 H3A 119.4 . . ?
C3 C4 C5 120.9(5) . . ?
C3 C4 H4A 119.6 . . ?
C5 C4 H4A 119.6 . . ?
C6 C5 C4 119.1(5) . . ?
C6 C5 H5A 120.4 . . ?
C4 C5 H5A 120.4 . . ?
C5 C6 C7 121.7(5) . . ?
C5 C6 H6A 119.2 . . ?
C7 C6 H6A 119.2 . . ?
C8 C7 C6 121.6(4) . . ?
C8 C7 C2 120.3(4) . . ?
C6 C7 C2 118.2(5) . . ?
C7 C8 C9 120.8(4) . . ?
C7 C8 H8A 119.6 . . ?
C9 C8 H8A 119.6 . . ?
C8 C9 C10 121.8(4) . . ?
C8 C9 C14 120.6(4) . . ?
C10 C9 C14 117.7(5) . . ?
C11 C10 C9 121.3(5) . . ?
C11 C10 H10A 119.3 . . ?
C9 C10 H10A 119.3 . . ?
C10 C11 C12 121.2(5) . . ?
C10 C11 H11A 119.4 . . ?
C12 C11 H11A 119.4 . . ?
C13 C12 C11 119.9(5) . . ?
C13 C12 H12A 120.1 . . ?
C11 C12 H12A 120.1 . . ?
C12 C13 C14 120.7(5) . . ?
C12 C13 H13A 119.7 . . ?
C14 C13 H13A 119.7 . . ?
C13 C14 C1 122.8(4) . . ?
C13 C14 C9 119.1(4) . . ?
C1 C14 C9 118.0(4) . . ?
C1A O2 Dy1 164.2(3) . . ?
O2 C1A C14A 120.5(4) . . ?
O2 C1A C2A 120.7(4) . . ?
C14A C1A C2A 118.8(4) . . ?
C3A C2A C1A 121.7(4) . . ?
C3A C2A C7A 118.8(4) . . ?
C1A C2A C7A 119.5(4) . . ?
C4A C3A C2A 121.0(5) . . ?
C4A C3A H3AA 119.5 . . ?
C2A C3A H3AA 119.5 . . ?
C3A C4A C5A 120.2(5) . . ?
C3A C4A H4AA 119.9 . . ?
C5A C4A H4AA 119.9 . . ?
C6A C5A C4A 120.2(5) . . ?
C6A C5A H5AA 119.9 . . ?
C4A C5A H5AA 119.9 . . ?
C5A C6A C7A 122.3(5) . . ?
C5A C6A H6AA 118.9 . . ?
C7A C6A H6AA 118.9 . . ?
C8A C7A C2A 120.4(5) . . ?
C8A C7A C6A 122.2(5) . . ?
C2A C7A C6A 117.4(5) . . ?
C7A C8A C9A 121.0(4) . . ?
C7A C8A H8AA 119.5 . . ?
C9A C8A H8AA 119.5 . . ?
C8A C9A C10A 122.2(5) . . ?
C8A C9A C14A 119.5(4) . . ?
C10A C9A C14A 118.2(5) . . ?
C11A C10A C9A 121.3(5) . . ?
C11A C10A H10B 119.4 . . ?
C9A C10A H10B 119.4 . . ?
C10A C11A C12A 120.7(5) . . ?
C10A C11A H11B 119.7 . . ?
C12A C11A H11B 119.7 . . ?
C13A C12A C11A 121.1(5) . . ?
C13A C12A H12B 119.4 . . ?
C11A C12A H12B 119.4 . . ?
C12A C13A C14A 120.0(5) . . ?
C12A C13A H13B 120.0 . . ?
C14A C13A H13B 120.0 . . ?
C1A C14A C13A 120.8(4) . . ?
C1A C14A C9A 120.5(4) . . ?
C13A C14A C9A 118.7(4) . . ?
C1B O3 Dy1 173.2(3) . . ?
O3 C1B C2B 120.4(4) . . ?
O3 C1B C14B 119.6(4) . . ?
C2B C1B C14B 120.0(4) . . ?
C1B C2B C7B 120.2(4) . . ?
C1B C2B C3B 121.0(4) . . ?
C7B C2B C3B 118.9(4) . . ?
C4B C3B C2B 120.9(4) . . ?
C4B C3B H3BA 119.6 . . ?
C2B C3B H3BA 119.6 . . ?
C3B C4B C5B 120.9(5) . . ?
C3B C4B H4BA 119.6 . . ?
C5B C4B H4BA 119.6 . . ?
C6B C5B C4B 119.7(5) . . ?
C6B C5B H5BA 120.2 . . ?
C4B C5B H5BA 120.2 . . ?
C5B C6B C7B 121.9(4) . . ?
C5B C6B H6BA 119.1 . . ?
C7B C6B H6BA 119.1 . . ?
C8B C7B C2B 119.7(4) . . ?
C8B C7B C6B 122.4(4) . . ?
C2B C7B C6B 117.9(4) . . ?
C7B C8B C9B 121.1(4) . . ?
C7B C8B H8BA 119.4 . . ?
C9B C8B H8BA 119.4 . . ?
C8B C9B C10B 122.3(4) . . ?
C8B C9B C14B 120.2(4) . . ?
C10B C9B C14B 117.5(4) . . ?
C11B C10B C9B 121.4(4) . . ?
C11B C10B H10C 119.3 . . ?
C9B C10B H10C 119.3 . . ?
C10B C11B C12B 120.5(5) . . ?
C10B C11B H11C 119.7 . . ?
C12B C11B H11C 119.7 . . ?
C13B C12B C11B 120.3(5) . . ?
C13B C12B H12C 119.9 . . ?
C11B C12B H12C 119.9 . . ?
C12B C13B C14B 121.4(4) . . ?
C12B C13B H13C 119.3 . . ?
C14B C13B H13C 119.3 . . ?
C1B C14B C13B 122.4(4) . . ?
C1B C14B C9B 118.7(4) . . ?
C13B C14B C9B 118.9(4) . . ?
C1S N1S C5S 116.7(4) . . ?
C1S N1S Dy1 119.0(3) . . ?
C5S N1S Dy1 122.2(3) . . ?
C10S N2S C6S 117.2(4) . . ?
C10S N2S Dy1 120.1(3) . . ?
C6S N2S Dy1 121.4(3) . . ?
C11S N3S C15S 115.9(4) . . ?
C11S N3S Dy1 123.5(3) . . ?
C15S N3S Dy1 120.6(3) . . ?
N1S C1S C2S 123.8(5) . . ?
N1S C1S H1SA 118.1 . . ?
C2S C1S H1SA 118.1 . . ?
C1S C2S C3S 118.5(5) . . ?
C1S C2S H2SA 120.7 . . ?
C3S C2S H2SA 120.7 . . ?
C4S C3S C2S 119.0(5) . . ?
C4S C3S H3SA 120.5 . . ?
C2S C3S H3SA 120.5 . . ?
C3S C4S C5S 118.8(5) . . ?
C3S C4S H4SA 120.6 . . ?
C5S C4S H4SA 120.6 . . ?
N1S C5S C4S 123.1(5) . . ?
N1S C5S H5SA 118.5 . . ?
C4S C5S H5SA 118.5 . . ?
N2S C6S C7S 123.5(4) . . ?
N2S C6S H6SA 118.3 . . ?
C7S C6S H6SA 118.3 . . ?
C6S C7S C8S 119.5(5) . . ?
C6S C7S H7SA 120.2 . . ?
C8S C7S H7SA 120.2 . . ?
C9S C8S C7S 117.8(5) . . ?
C9S C8S H8SA 121.1 . . ?
C7S C8S H8SA 121.1 . . ?
C8S C9S C10S 119.7(5) . . ?
C8S C9S H9SA 120.1 . . ?
C10S C9S H9SA 120.1 . . ?
N2S C10S C9S 122.2(4) . . ?
N2S C10S H10D 118.9 . . ?
C9S C10S H10D 118.9 . . ?
N3S C11S C12S 124.3(4) . . ?
N3S C11S H11D 117.8 . . ?
C12S C11S H11D 117.8 . . ?
C13S C12S C11S 118.5(5) . . ?
C13S C12S H12D 120.8 . . ?
C11S C12S H12D 120.8 . . ?
C14S C13S C12S 118.5(5) . . ?
C14S C13S H13D 120.8 . . ?
C12S C13S H13D 120.8 . . ?
C13S C14S C15S 119.5(5) . . ?
C13S C14S H14A 120.2 . . ?
C15S C14S H14A 120.2 . . ?
N3S C15S C14S 123.3(4) . . ?
N3S C15S H15A 118.4 . . ?
C14S C15S H15A 118.4 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O1 C1 C2 -25.8(12) . . . . ?
Dy1 O1 C1 C14 154.6(8) . . . . ?
O1 C1 C2 C3 2.6(6) . . . . ?
C14 C1 C2 C3 -177.9(4) . . . . ?
O1 C1 C2 C7 -177.2(4) . . . . ?
C14 C1 C2 C7 2.4(6) . . . . ?
C1 C2 C3 C4 179.7(4) . . . . ?
C7 C2 C3 C4 -0.5(7) . . . . ?
C2 C3 C4 C5 0.7(7) . . . . ?
C3 C4 C5 C6 -0.2(8) . . . . ?
C4 C5 C6 C7 -0.4(8) . . . . ?
C5 C6 C7 C8 -178.0(5) . . . . ?
C5 C6 C7 C2 0.5(7) . . . . ?
C3 C2 C7 C8 178.5(4) . . . . ?
C1 C2 C7 C8 -1.7(6) . . . . ?
C3 C2 C7 C6 -0.1(6) . . . . ?
C1 C2 C7 C6 179.7(4) . . . . ?
C6 C7 C8 C9 179.7(5) . . . . ?
C2 C7 C8 C9 1.1(7) . . . . ?
C7 C8 C9 C10 178.6(4) . . . . ?
C7 C8 C9 C14 -1.2(7) . . . . ?
C8 C9 C10 C11 -178.5(5) . . . . ?
C14 C9 C10 C11 1.3(7) . . . . ?
C9 C10 C11 C12 -0.9(8) . . . . ?
C10 C11 C12 C13 -0.8(7) . . . . ?
C11 C12 C13 C14 2.0(7) . . . . ?
C12 C13 C14 C1 176.3(4) . . . . ?
C12 C13 C14 C9 -1.5(7) . . . . ?
O1 C1 C14 C13 -0.7(6) . . . . ?
C2 C1 C14 C13 179.8(4) . . . . ?
O1 C1 C14 C9 177.2(4) . . . . ?
C2 C1 C14 C9 -2.4(6) . . . . ?
C8 C9 C14 C13 179.7(4) . . . . ?
C10 C9 C14 C13 -0.1(6) . . . . ?
C8 C9 C14 C1 1.8(6) . . . . ?
C10 C9 C14 C1 -178.1(4) . . . . ?
Dy1 O2 C1A C14A 85.1(12) . . . . ?
Dy1 O2 C1A C2A -94.1(11) . . . . ?
O2 C1A C2A C3A -9.0(7) . . . . ?
C14A C1A C2A C3A 171.7(4) . . . . ?
O2 C1A C2A C7A 172.2(4) . . . . ?
C14A C1A C2A C7A -7.1(6) . . . . ?
C1A C2A C3A C4A 179.1(5) . . . . ?
C7A C2A C3A C4A -2.1(7) . . . . ?
C2A C3A C4A C5A -1.4(8) . . . . ?
C3A C4A C5A C6A 2.3(9) . . . . ?
C4A C5A C6A C7A 0.4(9) . . . . ?
C3A C2A C7A C8A -173.9(5) . . . . ?
C1A C2A C7A C8A 4.9(7) . . . . ?
C3A C2A C7A C6A 4.6(7) . . . . ?
C1A C2A C7A C6A -176.6(4) . . . . ?
C5A C6A C7A C8A 174.6(5) . . . . ?
C5A C6A C7A C2A -3.8(8) . . . . ?
C2A C7A C8A C9A 0.1(7) . . . . ?
C6A C7A C8A C9A -178.2(5) . . . . ?
C7A C8A C9A C10A 175.5(5) . . . . ?
C7A C8A C9A C14A -2.9(7) . . . . ?
C8A C9A C10A C11A -179.6(5) . . . . ?
C14A C9A C10A C11A -1.1(7) . . . . ?
C9A C10A C11A C12A 0.5(8) . . . . ?
C10A C11A C12A C13A -0.3(8) . . . . ?
C11A C12A C13A C14A 0.8(7) . . . . ?
O2 C1A C14A C13A 5.7(7) . . . . ?
C2A C1A C14A C13A -175.0(4) . . . . ?
O2 C1A C14A C9A -174.9(4) . . . . ?
C2A C1A C14A C9A 4.3(6) . . . . ?
C12A C13A C14A C1A 177.9(4) . . . . ?
C12A C13A C14A C9A -1.4(7) . . . . ?
C8A C9A C14A C1A 0.7(7) . . . . ?
C10A C9A C14A C1A -177.8(4) . . . . ?
C8A C9A C14A C13A -180.0(4) . . . . ?
C10A C9A C14A C13A 1.6(7) . . . . ?
O3 C1B C2B C7B -177.6(4) . . . . ?
C14B C1B C2B C7B 1.7(6) . . . . ?
O3 C1B C2B C3B 1.9(7) . . . . ?
C14B C1B C2B C3B -178.8(4) . . . . ?
C1B C2B C3B C4B -179.4(4) . . . . ?
C7B C2B C3B C4B 0.1(7) . . . . ?
C2B C3B C4B C5B 0.4(7) . . . . ?
C3B C4B C5B C6B -0.8(7) . . . . ?
C4B C5B C6B C7B 0.5(7) . . . . ?
C1B C2B C7B C8B 0.2(6) . . . . ?
C3B C2B C7B C8B -179.2(4) . . . . ?
C1B C2B C7B C6B 179.2(4) . . . . ?
C3B C2B C7B C6B -0.3(6) . . . . ?
C5B C6B C7B C8B 178.9(5) . . . . ?
C5B C6B C7B C2B 0.0(7) . . . . ?
C2B C7B C8B C9B -0.3(7) . . . . ?
C6B C7B C8B C9B -179.2(4) . . . . ?
C7B C8B C9B C10B 177.1(4) . . . . ?
C7B C8B C9B C14B -1.5(7) . . . . ?
C8B C9B C10B C11B 179.7(5) . . . . ?
C14B C9B C10B C11B -1.7(7) . . . . ?
C9B C10B C11B C12B 0.1(8) . . . . ?
C10B C11B C12B C13B 0.6(8) . . . . ?
C11B C12B C13B C14B 0.3(8) . . . . ?
O3 C1B C14B C13B -1.9(7) . . . . ?
C2B C1B C14B C13B 178.8(4) . . . . ?
O3 C1B C14B C9B 175.8(4) . . . . ?
C2B C1B C14B C9B -3.5(6) . . . . ?
C12B C13B C14B C1B 175.8(5) . . . . ?
C12B C13B C14B C9B -1.9(7) . . . . ?
C8B C9B C14B C1B 3.4(6) . . . . ?
C10B C9B C14B C1B -175.2(4) . . . . ?
C8B C9B C14B C13B -178.8(4) . . . . ?
C10B C9B C14B C13B 2.5(6) . . . . ?
C5S N1S C1S C2S 0.3(7) . . . . ?
Dy1 N1S C1S C2S -163.8(4) . . . . ?
N1S C1S C2S C3S 0.1(8) . . . . ?
C1S C2S C3S C4S 0.3(8) . . . . ?
C2S C3S C4S C5S -1.0(8) . . . . ?
C1S N1S C5S C4S -1.1(7) . . . . ?
Dy1 N1S C5S C4S 162.5(4) . . . . ?
C3S C4S C5S N1S 1.4(8) . . . . ?
C10S N2S C6S C7S 0.6(7) . . . . ?
Dy1 N2S C6S C7S -166.3(4) . . . . ?
N2S C6S C7S C8S -0.5(8) . . . . ?
C6S C7S C8S C9S -0.5(7) . . . . ?
C7S C8S C9S C10S 1.4(7) . . . . ?
C6S N2S C10S C9S 0.3(7) . . . . ?
Dy1 N2S C10S C9S 167.4(4) . . . . ?
C8S C9S C10S N2S -1.3(7) . . . . ?
C15S N3S C11S C12S -2.7(7) . . . . ?
Dy1 N3S C11S C12S 178.5(4) . . . . ?
N3S C11S C12S C13S 1.2(8) . . . . ?
C11S C12S C13S C14S 0.8(8) . . . . ?
C12S C13S C14S C15S -1.2(8) . . . . ?
C11S N3S C15S C14S 2.2(7) . . . . ?
Dy1 N3S C15S C14S -178.9(4) . . . . ?
C13S C14S C15S N3S -0.3(8) . . . . ?

_refine_diff_density_max         0.758
_refine_diff_density_min         -1.255
_refine_diff_density_rms         0.139

_shelxl_version_number           2014/6


_exptl_crystal_preparation       'Magnetic properties,Luminescent'
