# Electronic Supplementary Material (ESI) for CrystEngComm.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AgNO3_a
_database_code_depnum_ccdc_archive 'CCDC 2043987'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H52 Ag2 N6 O6 Si4'
_chemical_formula_weight         968.91

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_H-M_alt        'C 2/m'
_space_group_name_Hall           '-C 2y'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'

_cell_length_a                   15.1093(7)
_cell_length_b                   17.6849(7)
_cell_length_c                   8.2597(3)
_cell_angle_alpha                90
_cell_angle_beta                 100.468(3)
_cell_angle_gamma                90
_cell_volume                     2170.31(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9810
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      28.14

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.483
_exptl_crystal_F_000             992
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.280
_exptl_crystal_size_min          0.250
_exptl_absorpt_coefficient_mu    1.059
_shelx_estimated_absorpt_T_min   0.742
_shelx_estimated_absorpt_T_max   0.778
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  0.6734
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            35640
_diffrn_reflns_av_unetI/netI     0.0176
_diffrn_reflns_av_R_equivalents  0.0458
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_theta_min         1.790
_diffrn_reflns_theta_max         28.256
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             2761
_reflns_number_gt                2581
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX software'
_computing_cell_refinement       'Bruker APEX software'
_computing_data_reduction        'Bruker APEX software'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0308P)²+2.0586P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         2761
_refine_ls_number_parameters     125
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0263
_refine_ls_R_factor_gt           0.0237
_refine_ls_wR_factor_ref         0.0623
_refine_ls_wR_factor_gt          0.0601
_refine_ls_goodness_of_fit_ref   1.140
_refine_ls_restrained_S_all      1.140
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.500000 0.41175(2) 0.500000 0.02771(7) Uani 1 2 d S T P . .
Si1 Si 0.87708(3) 0.34152(3) 0.17019(6) 0.02700(11) Uani 1 1 d . . . . .
C1 C 0.69927(12) 0.37792(12) 0.4950(2) 0.0340(4) Uani 1 1 d . . . . .
H1 H 0.702913 0.377349 0.611040 0.041 Uiso 1 1 calc R U . . .
O1 O 0.59720(10) 0.43871(9) 0.79754(17) 0.0436(3) Uani 1 1 d . . . . .
N1 N 0.63958(14) 0.500000 0.8100(2) 0.0293(4) Uani 1 2 d S T P . .
C2 C 0.77508(12) 0.35938(12) 0.4311(2) 0.0347(4) Uani 1 1 d . . . . .
H2 H 0.829084 0.345927 0.503487 0.042 Uiso 1 1 calc R U . . .
N2 N 0.62085(10) 0.39665(8) 0.39907(18) 0.0273(3) Uani 1 1 d . . . . .
O2 O 0.72221(12) 0.500000 0.8354(3) 0.0429(5) Uani 1 2 d S T P . .
C3 C 0.77296(11) 0.36026(9) 0.2614(2) 0.0260(3) Uani 1 1 d . . . . .
C5 C 0.61779(11) 0.39806(10) 0.2360(2) 0.0292(3) Uani 1 1 d . . . . .
H5 H 0.562875 0.411688 0.166582 0.035 Uiso 1 1 calc R U . . .
C4 C 0.69104(11) 0.38057(10) 0.1645(2) 0.0289(3) Uani 1 1 d . . . . .
H4 H 0.685519 0.382391 0.048144 0.035 Uiso 1 1 calc R U . . .
C8 C 0.94999(11) 0.42687(10) 0.2253(2) 0.0307(3) Uani 1 1 d . . . . .
H8A H 0.968291 0.429700 0.346436 0.037 Uiso 1 1 calc R U . . .
H8AB H 1.005190 0.421739 0.177372 0.037 Uiso 1 1 calc R U . . .
C7 C 0.93344(14) 0.25408(12) 0.2638(3) 0.0447(5) Uani 1 1 d . . . . .
H7A H 0.991939 0.248438 0.229806 0.067 Uiso 1 1 calc R U . . .
H7B H 0.895726 0.210083 0.226844 0.067 Uiso 1 1 calc R U . . .
H7C H 0.942297 0.257767 0.384090 0.067 Uiso 1 1 calc R U . . .
C6 C 0.84349(13) 0.33125(11) -0.0570(2) 0.0360(4) Uani 1 1 d . . . . .
H6A H 0.896264 0.317527 -0.104289 0.054 Uiso 1 1 calc R U . . .
H6B H 0.818779 0.379241 -0.104507 0.054 Uiso 1 1 calc R U . . .
H6C H 0.797749 0.291581 -0.081814 0.054 Uiso 1 1 calc R U . . .
C9 C 0.90124(18) 0.500000 0.1622(3) 0.0345(5) Uani 1 2 d S T P . .
H9A H 0.841179 0.500000 0.194170 0.041 Uiso 1 2 calc R U P . .
H9AB H 0.891792 0.500000 0.040454 0.041 Uiso 1 2 calc R U P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.1572(14) 2_656 ?
Ag1 N2 2.1572(14) . ?
Ag1 O1 2.6669(14) . ?
Ag1 Ag1 3.1212(4) 5_666 ?
Si1 C6 1.862(2) . ?
Si1 C7 1.8642(19) . ?
Si1 C8 1.8754(19) . ?
Si1 C3 1.8926(17) . ?
C1 N2 1.342(2) . ?
C1 C2 1.385(2) . ?
C1 H1 0.9500 . ?
O1 N1 1.2536(18) . ?
N1 O2 1.228(3) . ?
C2 C3 1.397(2) . ?
C2 H2 0.9500 . ?
N2 C5 1.339(2) . ?
C3 C4 1.393(2) . ?
C5 C4 1.381(2) . ?
C5 H5 0.9500 . ?
C4 H4 0.9500 . ?
C8 C9 1.532(2) . ?
C8 H8A 0.9900 . ?
C8 H8AB 0.9900 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C9 H9A 0.9900 . ?
C9 H9AB 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N2 165.78(8) 2_656 . ?
N2 Ag1 O1 91.67(5) 2_656 . ?
N2 Ag1 O1 90.87(5) . . ?
N2 Ag1 Ag1 97.11(4) 2_656 5_666 ?
N2 Ag1 Ag1 97.11(4) . 5_666 ?
O1 Ag1 Ag1 79.70(3) . 5_666 ?
C6 Si1 C7 110.95(10) . . ?
C6 Si1 C8 111.32(9) . . ?
C7 Si1 C8 111.29(9) . . ?
C6 Si1 C3 108.91(8) . . ?
C7 Si1 C3 109.28(8) . . ?
C8 Si1 C3 104.88(8) . . ?
N2 C1 C2 122.43(16) . . ?
N2 C1 H1 118.8 . . ?
C2 C1 H1 118.8 . . ?
N1 O1 Ag1 114.69(12) . . ?
O2 N1 O1 120.16(11) . . ?
O2 N1 O1 120.16(11) . 6_565 ?
O1 N1 O1 119.7(2) . 6_565 ?
C1 C2 C3 120.68(16) . . ?
C1 C2 H2 119.7 . . ?
C3 C2 H2 119.7 . . ?
C5 N2 C1 117.64(15) . . ?
C5 N2 Ag1 120.61(11) . . ?
C1 N2 Ag1 121.40(12) . . ?
C4 C3 C2 115.80(15) . . ?
C4 C3 Si1 122.18(12) . . ?
C2 C3 Si1 121.89(12) . . ?
N2 C5 C4 122.82(16) . . ?
N2 C5 H5 118.6 . . ?
C4 C5 H5 118.6 . . ?
C5 C4 C3 120.64(15) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
C9 C8 Si1 111.84(13) . . ?
C9 C8 H8A 109.2 . . ?
Si1 C8 H8A 109.2 . . ?
C9 C8 H8AB 109.2 . . ?
Si1 C8 H8AB 109.2 . . ?
H8A C8 H8AB 107.9 . . ?
Si1 C7 H7A 109.5 . . ?
Si1 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si1 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
Si1 C6 H6A 109.5 . . ?
Si1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C9 C8 115.2(2) . 6_565 ?
C8 C9 H9A 108.5 . . ?
C8 C9 H9A 108.5 6_565 . ?
C8 C9 H9AB 108.5 . . ?
C8 C9 H9AB 108.5 6_565 . ?
H9A C9 H9AB 107.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 O1 N1 O2 -114.1(2) . . . . ?
Ag1 O1 N1 O1 66.4(2) . . . 6_565 ?
N2 C1 C2 C3 0.7(3) . . . . ?
C2 C1 N2 C5 -0.9(3) . . . . ?
C2 C1 N2 Ag1 172.34(15) . . . . ?
C1 C2 C3 C4 -0.1(3) . . . . ?
C1 C2 C3 Si1 175.93(15) . . . . ?
C6 Si1 C3 C4 -13.90(17) . . . . ?
C7 Si1 C3 C4 -135.25(15) . . . . ?
C8 Si1 C3 C4 105.35(15) . . . . ?
C6 Si1 C3 C2 170.37(15) . . . . ?
C7 Si1 C3 C2 49.01(18) . . . . ?
C8 Si1 C3 C2 -70.39(16) . . . . ?
C1 N2 C5 C4 0.6(3) . . . . ?
Ag1 N2 C5 C4 -172.73(14) . . . . ?
N2 C5 C4 C3 0.0(3) . . . . ?
C2 C3 C4 C5 -0.3(3) . . . . ?
Si1 C3 C4 C5 -176.24(14) . . . . ?
C6 Si1 C8 C9 60.82(18) . . . . ?
C7 Si1 C8 C9 -174.85(16) . . . . ?
C3 Si1 C8 C9 -56.80(17) . . . . ?
Si1 C8 C9 C8 170.56(13) . . . 6_565 ?

_refine_diff_density_max         0.847
_refine_diff_density_min         -0.436
_refine_diff_density_rms         0.094

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_HH_PF6_a
_database_code_depnum_ccdc_archive 'CCDC 2043990'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C54 H92 Ag2 F12 N4 O10 P2 Si4'
_chemical_formula_weight         1575.35

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0024 0.0013 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0048 0.0026 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0137 0.0081 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0845 0.0751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -1.1793 0.9013 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0674 0.0561 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0085 0.0048 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.536(2)
_cell_length_b                   10.805(2)
_cell_length_c                   17.843(4)
_cell_angle_alpha                84.11(3)
_cell_angle_beta                 73.30(3)
_cell_angle_gamma                73.10(3)
_cell_volume                     1861.2(8)
_cell_formula_units_Z            1
_cell_measurement_temperature    253(2)
_cell_measurement_reflns_used    53915
_cell_measurement_theta_min      0.361
_cell_measurement_theta_max      33.548

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.406
_exptl_crystal_F_000             812
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.073
_exptl_crystal_size_min          0.066
_exptl_absorpt_coefficient_mu    0.510
_shelx_estimated_absorpt_T_min   0.941
_shelx_estimated_absorpt_T_max   0.967
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.938
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_process_details   'HKL3000sm Scalepack(Otwinowski et.al,2003)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      253(2)
_diffrn_radiation_wavelength     0.630
_diffrn_radiation_type           synchrotron
_diffrn_source                   'PLSII 2D bending magnet'
_diffrn_measurement_device_type  'Rayonix MX225HS CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            34189
_diffrn_reflns_av_unetI/netI     0.0247
_diffrn_reflns_av_R_equivalents  0.0147
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.746
_diffrn_reflns_theta_max         33.423
_diffrn_reflns_theta_full        22.210
_diffrn_measured_fraction_theta_max 0.834
_diffrn_measured_fraction_theta_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.834
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.834
_diffrn_reflns_point_group_measured_fraction_full 0.993
_reflns_number_total             17373
_reflns_number_gt                11631
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'PAL BL2D-SMDC Program (Shin et. al, 2016)'
_computing_cell_refinement       'HKL3000sm (Otwinowski & Minor, 1997)'
_computing_data_reduction        'HKL3000sm (Otwinowski & Minor, 1997)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1100P)²+0.0713P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         17373
_refine_ls_number_parameters     548
_refine_ls_number_restraints     197
_refine_ls_R_factor_all          0.0680
_refine_ls_R_factor_gt           0.0517
_refine_ls_wR_factor_ref         0.1826
_refine_ls_wR_factor_gt          0.1697
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_restrained_S_all      1.106
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.70784(2) 0.29334(2) 0.50272(2) 0.06636(7) Uani 1 1 d . . . . .
Si1 Si 0.51928(4) 0.23475(4) 0.90110(2) 0.04703(9) Uani 1 1 d . . . . .
Si2 Si 0.09356(6) 0.70586(5) 0.89673(3) 0.06241(14) Uani 1 1 d . . . . .
O1 O 0.5622(2) 0.0941(2) 0.50984(13) 0.0972(7) Uani 1 1 d . . . . .
O2 O 0.9014(2) 0.4394(2) 0.49537(13) 0.0916(6) Uani 1 1 d . . . . .
N4 N 0.24806(17) 0.70213(15) 0.62171(8) 0.0549(3) Uani 1 1 d . . . . .
N5 N 0.64411(16) 0.29395(16) 0.62750(8) 0.0542(3) Uani 1 1 d . . . . .
C1 C 0.4465(4) 0.1260(3) 0.4776(2) 0.0983(9) Uani 1 1 d . . . . .
H1A H 0.452158 0.198536 0.440125 0.118 Uiso 1 1 calc R U . . .
H1AB H 0.361257 0.153536 0.519601 0.118 Uiso 1 1 calc R U . . .
C2 C 0.5581(4) -0.0152(4) 0.56215(19) 0.0957(9) Uani 1 1 d . . . . .
H2A H 0.476492 0.007925 0.606906 0.115 Uiso 1 1 calc R U . . .
H2AB H 0.639821 -0.039298 0.581959 0.115 Uiso 1 1 calc R U . . .
C3 C 0.9681(4) 0.5818(3) 0.56021(19) 0.0950(9) Uani 1 1 d . . . . .
H3A H 0.939849 0.669688 0.580116 0.114 Uiso 1 1 calc R U . . .
H3AB H 0.975033 0.520884 0.604451 0.114 Uiso 1 1 calc R U . . .
C4 C 0.8626(3) 0.5650(4) 0.5255(2) 0.0950(8) Uani 1 1 d . . . . .
H4A H 0.773973 0.578968 0.565490 0.114 Uiso 1 1 calc R U . . .
H4AB H 0.851244 0.629485 0.483353 0.114 Uiso 1 1 calc R U . . .
C6 C 0.2374(2) 0.80503(18) 0.66081(10) 0.0607(4) Uani 1 1 d . . . . .
H6 H 0.261450 0.876783 0.632251 0.073 Uiso 1 1 calc R U . . .
C7 C 0.1926(2) 0.81081(16) 0.74155(10) 0.0580(4) Uani 1 1 d . . . . .
H7 H 0.186447 0.885744 0.766444 0.070 Uiso 1 1 calc R U . . .
C8 C 0.15659(18) 0.70644(14) 0.78633(8) 0.0490(3) Uani 1 1 d . . . . .
C9 C 0.1696(2) 0.59931(16) 0.74439(9) 0.0595(4) Uani 1 1 d . . . . .
H9 H 0.147806 0.525570 0.771365 0.071 Uiso 1 1 calc R U . . .
C10 C 0.2143(2) 0.60044(17) 0.66364(9) 0.0590(4) Uani 1 1 d . . . . .
H10 H 0.221341 0.527022 0.637010 0.071 Uiso 1 1 calc R U . . .
C11 C 0.0350(5) 0.8744(3) 0.93136(19) 0.1183(15) Uani 1 1 d . . . . .
H11A H -0.003550 0.874725 0.987701 0.178 Uiso 1 1 calc R U . . .
H11B H -0.034651 0.925645 0.906586 0.178 Uiso 1 1 calc R U . . .
H11C H 0.112736 0.911118 0.917916 0.178 Uiso 1 1 calc R U . . .
C12 C -0.0495(3) 0.6255(4) 0.92491(16) 0.0928(9) Uani 1 1 d . . . . .
H12A H -0.089184 0.629243 0.981147 0.139 Uiso 1 1 calc R U . . .
H12B H -0.013353 0.535890 0.909264 0.139 Uiso 1 1 calc R U . . .
H12C H -0.119881 0.669864 0.898896 0.139 Uiso 1 1 calc R U . . .
C13 C 0.2404(2) 0.61182(17) 0.93666(10) 0.0595(4) Uani 1 1 d . . . . .
H13A H 0.306483 0.663132 0.928016 0.071 Uiso 1 1 calc R U . . .
H13B H 0.204939 0.600882 0.993339 0.071 Uiso 1 1 calc R U . . .
C14 C 0.31736(18) 0.47865(15) 0.90192(8) 0.0506(3) Uani 1 1 d . . . . .
H14A H 0.358615 0.489401 0.845806 0.061 Uiso 1 1 calc R U . . .
H14B H 0.250977 0.428528 0.907711 0.061 Uiso 1 1 calc R U . . .
C15 C 0.43148(19) 0.40138(17) 0.93993(9) 0.0542(3) Uani 1 1 d . . . . .
H15A H 0.391179 0.394818 0.996487 0.065 Uiso 1 1 calc R U . . .
H15B H 0.500593 0.449237 0.931559 0.065 Uiso 1 1 calc R U . . .
C16 C 0.3969(2) 0.1334(2) 0.92991(13) 0.0684(5) Uani 1 1 d . . . . .
H16A H 0.445315 0.045000 0.914245 0.103 Uiso 1 1 calc R U . . .
H16B H 0.323665 0.166866 0.904328 0.103 Uiso 1 1 calc R U . . .
H16C H 0.357833 0.135526 0.986219 0.103 Uiso 1 1 calc R U . . .
C17 C 0.6764(2) 0.1601(2) 0.93533(14) 0.0714(5) Uani 1 1 d . . . . .
H17A H 0.726428 0.078877 0.909075 0.107 Uiso 1 1 calc R U . . .
H17B H 0.649780 0.144225 0.991418 0.107 Uiso 1 1 calc R U . . .
H17C H 0.734771 0.218256 0.923341 0.107 Uiso 1 1 calc R U . . .
C18 C 0.52611(17) 0.2655(2) 0.66535(9) 0.0584(4) Uani 1 1 d . . . . .
H18 H 0.466920 0.258959 0.636233 0.070 Uiso 1 1 calc R U . . .
C19 C 0.48781(16) 0.2455(2) 0.74547(9) 0.0558(4) Uani 1 1 d . . . . .
H19 H 0.403812 0.225955 0.769484 0.067 Uiso 1 1 calc R U . . .
C20 C 0.57205(14) 0.25393(14) 0.79091(8) 0.0427(2) Uani 1 1 d . . . . .
C21 C 0.69346(16) 0.2855(2) 0.75072(10) 0.0552(3) Uani 1 1 d . . . . .
H21 H 0.753924 0.294110 0.778416 0.066 Uiso 1 1 calc R U . . .
C22 C 0.72556(18) 0.3042(2) 0.67028(10) 0.0603(4) Uani 1 1 d . . . . .
H22 H 0.808339 0.324942 0.644682 0.072 Uiso 1 1 calc R U . . .
O1A O 0.9892(3) -0.1124(2) 0.54496(18) 0.0794(9) Uani 0.644(5) 1 d . U P A 1
C1A C 0.9639(7) -0.0946(6) 0.4724(4) 0.0767(13) Uani 0.644(5) 1 d . U P A 1
H1A1 H 0.865108 -0.055518 0.478724 0.092 Uiso 0.644(5) 1 calc R U P A 1
H1A2 H 0.989364 -0.178848 0.448092 0.092 Uiso 0.644(5) 1 calc R U P A 1
C2A C 0.9578(13) 0.0105(9) 0.5796(7) 0.0697(15) Uani 0.644(5) 1 d . U P A 1
H2A1 H 0.980839 -0.002383 0.629862 0.084 Uiso 0.644(5) 1 calc R U P A 1
H2A2 H 0.858887 0.052820 0.589701 0.084 Uiso 0.644(5) 1 calc R U P A 1
O1B O 0.8649(5) 0.0034(6) 0.5437(3) 0.0816(16) Uani 0.356(5) 1 d D U P A 2
C1B C 0.9217(12) -0.0542(12) 0.4695(6) 0.079(2) Uani 0.356(5) 1 d D U P A 2
H1BA H 0.848316 -0.046475 0.444394 0.095 Uiso 0.356(5) 1 calc R U P A 2
H1BB H 0.966604 -0.146331 0.475602 0.095 Uiso 0.356(5) 1 calc R U P A 2
C2B C 0.968(2) -0.016(2) 0.5843(15) 0.078(4) Uani 0.356(5) 1 d D U P A 2
H2BA H 1.010623 -0.108939 0.590461 0.094 Uiso 0.356(5) 1 calc R U P A 2
H2BB H 0.927546 0.022034 0.636177 0.094 Uiso 0.356(5) 1 calc R U P A 2
O1C O 0.7988(7) 0.7603(9) 0.7264(5) 0.152(3) Uani 0.463(6) 1 d D U P B 3
O2C O 0.5248(9) 0.7984(13) 0.8154(7) 0.202(4) Uani 0.463(6) 1 d D U P B 3
C1C C 0.7012(9) 0.7263(11) 0.6981(5) 0.089(2) Uani 0.463(6) 1 d D U P B 3
H1CA H 0.748292 0.645041 0.670122 0.107 Uiso 0.463(6) 1 calc R U P B 3
H1CB H 0.675508 0.792609 0.659189 0.107 Uiso 0.463(6) 1 calc R U P B 3
C2C C 0.5709(14) 0.7097(16) 0.7538(8) 0.141(4) Uani 0.463(6) 1 d D U P B 3
H2CA H 0.499958 0.723823 0.725921 0.169 Uiso 0.463(6) 1 calc R U P B 3
H2CB H 0.586738 0.621108 0.775356 0.169 Uiso 0.463(6) 1 calc R U P B 3
C3C C 0.6256(11) 0.8294(14) 0.8448(6) 0.123(3) Uani 0.463(6) 1 d D U P B 3
H3CA H 0.660291 0.757327 0.878198 0.147 Uiso 0.463(6) 1 calc R U P B 3
H3CB H 0.579954 0.905743 0.877579 0.147 Uiso 0.463(6) 1 calc R U P B 3
C4C C 0.7439(14) 0.8554(15) 0.7837(7) 0.140(4) Uani 0.463(6) 1 d D U P B 3
H4CA H 0.714146 0.940101 0.758963 0.167 Uiso 0.463(6) 1 calc R U P B 3
H4CB H 0.815528 0.858160 0.807858 0.167 Uiso 0.463(6) 1 calc R U P B 3
O1D O 0.6436(18) 0.8829(8) 0.7276(7) 0.272(8) Uani 0.537(6) 1 d D . P B 4
O2D O 0.6584(13) 0.6455(9) 0.8110(7) 0.210(4) Uani 0.537(6) 1 d D U P B 4
C1D C 0.6489(13) 0.7680(8) 0.6934(4) 0.096(2) Uani 0.537(6) 1 d D . P B 4
H1DA H 0.744630 0.729085 0.664310 0.115 Uiso 0.537(6) 1 calc R U P B 4
H1DB H 0.594338 0.792017 0.655338 0.115 Uiso 0.537(6) 1 calc R U P B 4
C2D C 0.5995(17) 0.6684(14) 0.7475(8) 0.157(4) Uani 0.537(6) 1 d D U P B 4
H2DA H 0.498918 0.697166 0.767045 0.189 Uiso 0.537(6) 1 calc R U P B 4
H2DB H 0.624203 0.587806 0.719340 0.189 Uiso 0.537(6) 1 calc R U P B 4
C3D C 0.6557(11) 0.7576(11) 0.8483(4) 0.121(3) Uani 0.537(6) 1 d D . P B 4
H3DA H 0.716009 0.731776 0.883271 0.145 Uiso 0.537(6) 1 calc R U P B 4
H3DB H 0.561845 0.795892 0.880163 0.145 Uiso 0.537(6) 1 calc R U P B 4
C4D C 0.7001(15) 0.8536(12) 0.7923(7) 0.136(3) Uani 0.537(6) 1 d D U P B 4
H4DA H 0.678190 0.933852 0.820242 0.163 Uiso 0.537(6) 1 calc R U P B 4
H4DB H 0.800625 0.823934 0.772240 0.163 Uiso 0.537(6) 1 calc R U P B 4
F1E F 0.9286(6) -0.1648(5) 0.3202(4) 0.171(2) Uani 0.715(6) 1 d . . P C 5
P1E P 0.8950(4) -0.2297(4) 0.2557(2) 0.0643(6) Uani 0.715(6) 1 d . . P C 5
F2E F 0.7913(5) -0.2936(5) 0.3203(3) 0.0994(13) Uani 0.715(6) 1 d . . P C 5
F3E F 1.0165(2) -0.3523(3) 0.2596(3) 0.1053(13) Uani 0.715(6) 1 d . . P C 5
F4E F 0.8577(3) -0.2952(3) 0.1942(2) 0.0958(9) Uani 0.715(6) 1 d . . P C 5
F5E F 0.9934(4) -0.1656(5) 0.1934(4) 0.1344(19) Uani 0.715(6) 1 d . . P C 5
F6E F 0.7673(3) -0.1080(2) 0.2558(4) 0.1097(15) Uani 0.715(6) 1 d . . P C 5
P1 P 0.8956(8) -0.2166(7) 0.2644(4) 0.0516(9) Uani 0.285(6) 1 d D . P C 6
F2 F 1.0087(15) -0.3136(12) 0.1984(7) 0.176(6) Uani 0.285(6) 1 d D . P C 6
F1 F 0.7969(12) -0.1120(9) 0.3264(9) 0.162(6) Uani 0.285(6) 1 d D . P C 6
F6 F 0.8007(12) -0.3145(9) 0.2855(12) 0.151(9) Uani 0.285(6) 1 d D . P C 6
F5 F 0.9926(8) -0.1291(8) 0.2395(8) 0.105(3) Uani 0.285(6) 1 d . . P C 6
F4 F 0.9836(10) -0.2928(13) 0.3209(8) 0.130(5) Uani 0.285(6) 1 d D . P C 6
F3 F 0.8137(13) -0.1332(16) 0.2047(8) 0.159(6) Uani 0.285(6) 1 d D . P C 6


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.1322(15) 2_666 ?
Ag1 N5 2.1329(15) . ?
Ag1 Ag1 5.284(2) 2_666 ?
Si1 C16 1.857(2) . ?
Si1 C17 1.862(2) . ?
Si1 C15 1.8700(19) . ?
Si1 C20 1.8902(14) . ?
Si2 C11 1.854(3) . ?
Si2 C13 1.872(2) . ?
Si2 C12 1.874(3) . ?
Si2 C8 1.8894(16) . ?
O1 C2 1.430(4) . ?
O1 C1 1.434(5) . ?
O2 C4 1.414(5) . ?
O2 C3 1.417(4) 2_766 ?
N4 C6 1.333(3) . ?
N4 C10 1.341(2) . ?
N5 C22 1.334(2) . ?
N5 C18 1.339(2) . ?
C1 C2 1.472(5) 2_656 ?
C3 C4 1.479(5) . ?
C6 C7 1.383(3) . ?
C7 C8 1.394(2) . ?
C8 C9 1.395(2) . ?
C9 C10 1.381(2) . ?
C13 C14 1.526(2) . ?
C14 C15 1.540(2) . ?
C18 C19 1.382(2) . ?
C19 C20 1.389(2) . ?
C20 C21 1.394(2) . ?
C21 C22 1.384(2) . ?
O1A C1A 1.380(7) . ?
O1A C2A 1.432(10) . ?
C1A C2A 1.480(15) 2_756 ?
O1B C1B 1.412(9) . ?
O1B C2B 1.422(9) . ?
C1B C2B 1.61(3) 2_756 ?
O1C C4C 1.402(9) . ?
O1C C1C 1.416(8) . ?
O2C C2C 1.415(9) . ?
O2C C3C 1.442(9) . ?
C1C C2C 1.493(9) . ?
C3C C4C 1.477(9) . ?
O1D C4D 1.414(9) . ?
O1D C1D 1.418(8) . ?
O2D C2D 1.409(9) . ?
O2D C3D 1.431(9) . ?
C1D C2D 1.479(9) . ?
C3D C4D 1.446(9) . ?
F1E P1E 1.577(5) . ?
P1E F5E 1.545(6) . ?
P1E F4E 1.557(4) . ?
P1E F3E 1.564(4) . ?
P1E F6E 1.584(4) . ?
P1E F2E 1.597(4) . ?
P1 F5 1.534(12) . ?
P1 F4 1.574(7) . ?
P1 F1 1.580(8) . ?
P1 F3 1.603(8) . ?
P1 F6 1.605(7) . ?
P1 F2 1.621(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N5 174.72(6) 2_666 . ?
N4 Ag1 Ag1 86.42(6) 2_666 2_666 ?
N5 Ag1 Ag1 89.43(6) . 2_666 ?
C16 Si1 C17 111.27(11) . . ?
C16 Si1 C15 109.84(10) . . ?
C17 Si1 C15 111.11(10) . . ?
C16 Si1 C20 109.41(9) . . ?
C17 Si1 C20 108.90(10) . . ?
C15 Si1 C20 106.16(8) . . ?
C11 Si2 C13 109.26(15) . . ?
C11 Si2 C12 111.99(19) . . ?
C13 Si2 C12 110.66(11) . . ?
C11 Si2 C8 109.44(12) . . ?
C13 Si2 C8 108.28(8) . . ?
C12 Si2 C8 107.12(12) . . ?
C2 O1 C1 109.8(2) . . ?
C4 O2 C3 109.2(2) . 2_766 ?
C6 N4 C10 117.57(14) . . ?
C6 N4 Ag1 121.46(11) . 2_666 ?
C10 N4 Ag1 120.53(12) . 2_666 ?
C22 N5 C18 117.48(14) . . ?
C22 N5 Ag1 122.56(12) . . ?
C18 N5 Ag1 119.32(11) . . ?
O1 C1 C2 111.5(3) . 2_656 ?
O1 C2 C1 111.0(3) . 2_656 ?
O2 C3 C4 111.4(3) 2_766 . ?
O2 C4 C3 110.6(3) . . ?
N4 C6 C7 122.87(15) . . ?
C6 C7 C8 120.56(16) . . ?
C7 C8 C9 115.69(14) . . ?
C7 C8 Si2 123.54(13) . . ?
C9 C8 Si2 120.77(11) . . ?
C10 C9 C8 120.69(14) . . ?
N4 C10 C9 122.61(16) . . ?
C14 C13 Si2 115.67(13) . . ?
C13 C14 C15 113.91(14) . . ?
C14 C15 Si1 113.90(11) . . ?
N5 C18 C19 122.68(14) . . ?
C18 C19 C20 120.72(14) . . ?
C19 C20 C21 115.84(13) . . ?
C19 C20 Si1 121.88(11) . . ?
C21 C20 Si1 122.16(11) . . ?
C22 C21 C20 120.41(14) . . ?
N5 C22 C21 122.86(15) . . ?
C1A O1A C2A 109.8(5) . . ?
O1A C1A C2A 111.8(6) . 2_756 ?
O1A C2A C1A 110.9(10) . 2_756 ?
C1B O1B C2B 110.9(13) . . ?
O1B C1B C2B 109.7(12) . 2_756 ?
C4C O1C C1C 115.5(9) . . ?
C2C O2C C3C 118.8(9) . . ?
O1C C1C C2C 119.9(9) . . ?
O2C C2C C1C 110.4(10) . . ?
O2C C3C C4C 114.6(10) . . ?
O1C C4C C3C 111.6(10) . . ?
C4D O1D C1D 110.8(8) . . ?
C2D O2D C3D 116.2(9) . . ?
O1D C1D C2D 116.6(10) . . ?
O2D C2D C1D 110.6(10) . . ?
O2D C3D C4D 112.1(8) . . ?
O1D C4D C3D 116.9(9) . . ?
F5E P1E F4E 94.1(3) . . ?
F5E P1E F3E 91.0(3) . . ?
F4E P1E F3E 90.5(3) . . ?
F5E P1E F1E 87.9(4) . . ?
F4E P1E F1E 178.0(4) . . ?
F3E P1E F1E 89.8(3) . . ?
F5E P1E F6E 91.9(3) . . ?
F4E P1E F6E 90.1(3) . . ?
F3E P1E F6E 177.0(4) . . ?
F1E P1E F6E 89.5(3) . . ?
F5E P1E F2E 179.0(4) . . ?
F4E P1E F2E 86.2(3) . . ?
F3E P1E F2E 90.0(3) . . ?
F1E P1E F2E 91.8(4) . . ?
F6E P1E F2E 87.2(3) . . ?
F5 P1 F4 89.0(7) . . ?
F5 P1 F1 88.2(7) . . ?
F4 P1 F1 94.8(9) . . ?
F5 P1 F3 87.0(7) . . ?
F4 P1 F3 175.9(8) . . ?
F1 P1 F3 85.4(9) . . ?
F5 P1 F6 176.0(9) . . ?
F4 P1 F6 91.2(8) . . ?
F1 P1 F6 95.8(8) . . ?
F3 P1 F6 92.8(8) . . ?
F5 P1 F2 85.3(8) . . ?
F4 P1 F2 84.7(8) . . ?
F1 P1 F2 173.5(9) . . ?
F3 P1 F2 94.6(10) . . ?
F6 P1 F2 90.8(9) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 O1 C1 C2 -56.6(3) . . . 2_656 ?
C1 O1 C2 C1 56.3(4) . . . 2_656 ?
C3 O2 C4 C3 -57.0(4) 2_766 . . . ?
O2 C3 C4 O2 58.3(3) 2_766 . . . ?
C10 N4 C6 C7 -0.5(3) . . . . ?
Ag1 N4 C6 C7 171.89(16) 2_666 . . . ?
N4 C6 C7 C8 0.3(3) . . . . ?
C6 C7 C8 C9 0.3(3) . . . . ?
C6 C7 C8 Si2 -179.68(16) . . . . ?
C11 Si2 C8 C7 18.1(2) . . . . ?
C13 Si2 C8 C7 -100.92(17) . . . . ?
C12 Si2 C8 C7 139.70(19) . . . . ?
C11 Si2 C8 C9 -161.9(2) . . . . ?
C13 Si2 C8 C9 79.12(18) . . . . ?
C12 Si2 C8 C9 -40.3(2) . . . . ?
C7 C8 C9 C10 -0.7(3) . . . . ?
Si2 C8 C9 C10 179.29(16) . . . . ?
C6 N4 C10 C9 0.1(3) . . . . ?
Ag1 N4 C10 C9 -172.37(16) 2_666 . . . ?
C8 C9 C10 N4 0.5(3) . . . . ?
C11 Si2 C13 C14 -169.32(19) . . . . ?
C12 Si2 C13 C14 66.92(19) . . . . ?
C8 Si2 C13 C14 -50.20(17) . . . . ?
Si2 C13 C14 C15 -176.46(13) . . . . ?
C13 C14 C15 Si1 176.85(13) . . . . ?
C16 Si1 C15 C14 -67.42(15) . . . . ?
C17 Si1 C15 C14 169.03(14) . . . . ?
C20 Si1 C15 C14 50.78(14) . . . . ?
C22 N5 C18 C19 -0.7(3) . . . . ?
Ag1 N5 C18 C19 170.35(16) . . . . ?
N5 C18 C19 C20 -0.1(3) . . . . ?
C18 C19 C20 C21 1.1(3) . . . . ?
C18 C19 C20 Si1 177.13(15) . . . . ?
C16 Si1 C20 C19 26.29(17) . . . . ?
C17 Si1 C20 C19 148.11(16) . . . . ?
C15 Si1 C20 C19 -92.18(16) . . . . ?
C16 Si1 C20 C21 -157.88(15) . . . . ?
C17 Si1 C20 C21 -36.07(18) . . . . ?
C15 Si1 C20 C21 83.65(16) . . . . ?
C19 C20 C21 C22 -1.1(3) . . . . ?
Si1 C20 C21 C22 -177.19(15) . . . . ?
C18 N5 C22 C21 0.7(3) . . . . ?
Ag1 N5 C22 C21 -170.12(16) . . . . ?
C20 C21 C22 N5 0.3(3) . . . . ?
C2A O1A C1A C2A 56.5(11) . . . 2_756 ?
C1A O1A C2A C1A -56.0(8) . . . 2_756 ?
C2B O1B C1B C2B -64.5(15) . . . 2_756 ?
C1B O1B C2B C1B 61.6(16) . . . 2_756 ?
C4C O1C C1C C2C -42.2(17) . . . . ?
C3C O2C C2C C1C -36(2) . . . . ?
O1C C1C C2C O2C 35(2) . . . . ?
C2C O2C C3C C4C 45(2) . . . . ?
C1C O1C C4C C3C 46.2(16) . . . . ?
O2C C3C C4C O1C -47.7(18) . . . . ?
C4D O1D C1D C2D 47.9(18) . . . . ?
C3D O2D C2D C1D 46.9(18) . . . . ?
O1D C1D C2D O2D -48.3(19) . . . . ?
C2D O2D C3D C4D -46.6(16) . . . . ?
C1D O1D C4D C3D -46.9(19) . . . . ?
O2D C3D C4D O1D 46.4(17) . . . . ?

_refine_diff_density_max         1.011
_refine_diff_density_min         -1.023
_refine_diff_density_rms         0.070

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_BF4_exchanged_a
_database_code_depnum_ccdc_archive 'CCDC 2043991'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C17 H26 Ag B F4 N2 Si2'
_chemical_formula_weight         509.26

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.1079(3)
_cell_length_b                   12.2055(4)
_cell_length_c                   14.7073(4)
_cell_angle_alpha                90
_cell_angle_beta                 106.888(2)
_cell_angle_gamma                90
_cell_volume                     2251.52(11)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9946
_cell_measurement_theta_min      2.33
_cell_measurement_theta_max      26.46

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.502
_exptl_crystal_F_000             1032
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    1.038
_shelx_estimated_absorpt_T_min   0.860
_shelx_estimated_absorpt_T_max   0.903
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  0.6705
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            48582
_diffrn_reflns_av_unetI/netI     0.0360
_diffrn_reflns_av_R_equivalents  0.0565
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.834
_diffrn_reflns_theta_max         28.166
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5520
_reflns_number_gt                3850
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX software'
_computing_cell_refinement       'Bruker APEX software'
_computing_data_reduction        'Bruker APEX software'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0892P)²+6.2746P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5520
_refine_ls_number_parameters     248
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0908
_refine_ls_R_factor_gt           0.0596
_refine_ls_wR_factor_ref         0.1756
_refine_ls_wR_factor_gt          0.1513
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
B1 B 0.7485(6) 1.0253(6) 0.5869(5) 0.0539(16) Uani 1 1 d . . . . .
F1 F 0.7647(6) 0.9309(5) 0.6277(6) 0.157(3) Uani 1 1 d . . . . .
C1 C 0.5437(4) 0.7557(5) 0.5735(4) 0.0459(13) Uani 1 1 d . . . . .
H1 H 0.569659 0.823504 0.557510 0.055 Uiso 1 1 calc R U . . .
N1 N 0.6097(3) 0.6921(4) 0.6391(3) 0.0395(9) Uani 1 1 d . . . . .
Si1 Si 0.17952(10) 0.23046(11) 0.64917(10) 0.0334(3) Uani 1 1 d . . . . .
Ag1 Ag 0.77492(3) 0.72540(4) 0.70065(3) 0.04560(17) Uani 1 1 d . . . . .
F2 F 0.6580(12) 1.0197(7) 0.5212(7) 0.330(10) Uani 1 1 d . . . . .
C2 C 0.4392(4) 0.7265(4) 0.5281(4) 0.0425(12) Uani 1 1 d . . . . .
H2 H 0.395181 0.774436 0.482374 0.051 Uiso 1 1 calc R U . . .
N2 N 0.5550(3) 0.2318(4) 0.7471(3) 0.0363(9) Uani 1 1 d . . . . .
Si2 Si 0.25407(9) 0.58619(11) 0.49274(9) 0.0322(3) Uani 1 1 d . . . . .
C3 C 0.3981(3) 0.6275(4) 0.5489(3) 0.0332(10) Uani 1 1 d . . . . .
F3 F 0.7387(4) 1.1109(4) 0.6363(3) 0.108(2) Uani 1 1 d . . . . .
F4 F 0.8153(16) 1.0339(9) 0.5502(15) 0.401(13) Uani 1 1 d . . . . .
C4 C 0.4677(4) 0.5627(5) 0.6165(4) 0.0450(12) Uani 1 1 d . . . . .
H4 H 0.444528 0.493773 0.632977 0.054 Uiso 1 1 calc R U . . .
C5 C 0.5707(4) 0.5976(5) 0.6600(4) 0.0466(13) Uani 1 1 d . . . . .
H5 H 0.615903 0.552005 0.707184 0.056 Uiso 1 1 calc R U . . .
C6 C 0.1699(4) 0.6729(5) 0.5450(5) 0.0516(14) Uani 1 1 d . . . . .
H6A H 0.094582 0.659521 0.511714 0.077 Uiso 1 1 calc R U . . .
H6B H 0.186642 0.750236 0.538491 0.077 Uiso 1 1 calc R U . . .
H6C H 0.183918 0.654886 0.612438 0.077 Uiso 1 1 calc R U . . .
C7 C 0.2157(5) 0.6066(5) 0.3612(4) 0.0542(15) Uani 1 1 d . . . . .
H7A H 0.151519 0.563696 0.331127 0.081 Uiso 1 1 calc R U . . .
H7B H 0.274090 0.582279 0.336871 0.081 Uiso 1 1 calc R U . . .
H7C H 0.201326 0.684372 0.346506 0.081 Uiso 1 1 calc R U . . .
C8 C 0.2442(4) 0.4398(4) 0.5257(3) 0.0351(10) Uani 1 1 d . . . . .
H8A H 0.290947 0.395808 0.497612 0.042 Uiso 1 1 calc R U . . .
H8AB H 0.272578 0.433262 0.595596 0.042 Uiso 1 1 calc R U . . .
C9 C 0.1321(4) 0.3890(4) 0.4948(4) 0.0370(10) Uani 1 1 d . . . . .
H9A H 0.085670 0.429447 0.525625 0.044 Uiso 1 1 calc R U . . .
H9AB H 0.101757 0.397410 0.425212 0.044 Uiso 1 1 calc R U . . .
C10 C 0.1318(4) 0.2677(4) 0.5203(3) 0.0362(10) Uani 1 1 d . . . . .
H10A H 0.176595 0.228110 0.487217 0.043 Uiso 1 1 calc R U . . .
H10B H 0.058091 0.239969 0.494413 0.043 Uiso 1 1 calc R U . . .
C11 C 0.1369(4) 0.0883(5) 0.6647(5) 0.0512(14) Uani 1 1 d . . . . .
H11A H 0.158329 0.069744 0.732416 0.077 Uiso 1 1 calc R U . . .
H11B H 0.170698 0.037396 0.630699 0.077 Uiso 1 1 calc R U . . .
H11C H 0.059234 0.082766 0.639074 0.077 Uiso 1 1 calc R U . . .
C12 C 0.1284(4) 0.3295(5) 0.7225(4) 0.0514(13) Uani 1 1 d . . . . .
H12A H 0.152770 0.307346 0.789340 0.077 Uiso 1 1 calc R U . . .
H12B H 0.050275 0.330100 0.700810 0.077 Uiso 1 1 calc R U . . .
H12C H 0.155308 0.403038 0.715641 0.077 Uiso 1 1 calc R U . . .
C13 C 0.4992(4) 0.1581(5) 0.6862(4) 0.0418(11) Uani 1 1 d . . . . .
H13 H 0.536973 0.104566 0.661941 0.050 Uiso 1 1 calc R U . . .
C14 C 0.3890(4) 0.1551(4) 0.6562(3) 0.0399(11) Uani 1 1 d . . . . .
H14 H 0.353078 0.101107 0.611940 0.048 Uiso 1 1 calc R U . . .
C15 C 0.3308(3) 0.2313(4) 0.6909(3) 0.0296(9) Uani 1 1 d . . . . .
C16 C 0.3906(4) 0.3081(4) 0.7553(3) 0.0341(10) Uani 1 1 d . . . . .
H16 H 0.355016 0.362261 0.781203 0.041 Uiso 1 1 calc R U . . .
C17 C 0.5004(4) 0.3061(4) 0.7816(3) 0.0354(10) Uani 1 1 d . . . . .
H17 H 0.538741 0.359221 0.825564 0.042 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
B1 F4 1.159(10) . ?
B1 F1 1.289(9) . ?
B1 F2 1.296(12) . ?
B1 F3 1.300(8) . ?
C1 N1 1.341(7) . ?
C1 C2 1.384(7) . ?
C1 H1 0.9500 . ?
N1 C5 1.333(7) . ?
N1 Ag1 2.130(4) . ?
Si1 C11 1.857(6) . ?
Si1 C12 1.869(6) . ?
Si1 C10 1.871(5) . ?
Si1 C15 1.897(4) . ?
Ag1 N2 2.137(4) 2_656 ?
Ag1 Ag1 6.3505(3) 2_646 ?
C2 C3 1.393(7) . ?
C2 H2 0.9500 . ?
N2 C13 1.330(7) . ?
N2 C17 1.343(7) . ?
Si2 C6 1.849(6) . ?
Si2 C8 1.866(5) . ?
Si2 C7 1.869(5) . ?
Si2 C3 1.896(5) . ?
C3 C4 1.385(7) . ?
C4 C5 1.383(7) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 C9 1.537(6) . ?
C8 H8A 0.9900 . ?
C8 H8AB 0.9900 . ?
C9 C10 1.527(7) . ?
C9 H9A 0.9900 . ?
C9 H9AB 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.382(7) . ?
C13 H13 0.9500 . ?
C14 C15 1.391(7) . ?
C14 H14 0.9500 . ?
C15 C16 1.399(7) . ?
C16 C17 1.378(6) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F4 B1 F1 104.7(10) . . ?
F4 B1 F2 108.0(13) . . ?
F1 B1 F2 106.9(9) . . ?
F4 B1 F3 113.5(9) . . ?
F1 B1 F3 119.2(7) . . ?
F2 B1 F3 104.0(7) . . ?
N1 C1 C2 122.6(5) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C5 N1 C1 117.2(4) . . ?
C5 N1 Ag1 118.5(3) . . ?
C1 N1 Ag1 124.0(4) . . ?
C11 Si1 C12 111.3(3) . . ?
C11 Si1 C10 109.1(3) . . ?
C12 Si1 C10 110.9(3) . . ?
C11 Si1 C15 106.8(2) . . ?
C12 Si1 C15 109.0(2) . . ?
C10 Si1 C15 109.7(2) . . ?
N1 Ag1 N2 170.11(17) . 2_656 ?
N1 Ag1 Ag1 75.77(13) . 2_646 ?
N2 Ag1 Ag1 96.83(12) 2_656 2_646 ?
C1 C2 C3 120.6(5) . . ?
C1 C2 H2 119.7 . . ?
C3 C2 H2 119.7 . . ?
C13 N2 C17 117.5(4) . . ?
C13 N2 Ag1 122.0(3) . 2_646 ?
C17 N2 Ag1 120.3(3) . 2_646 ?
C6 Si2 C8 110.2(3) . . ?
C6 Si2 C7 109.9(3) . . ?
C8 Si2 C7 112.2(3) . . ?
C6 Si2 C3 107.8(2) . . ?
C8 Si2 C3 106.1(2) . . ?
C7 Si2 C3 110.5(2) . . ?
C4 C3 C2 115.9(4) . . ?
C4 C3 Si2 121.7(4) . . ?
C2 C3 Si2 122.3(4) . . ?
C5 C4 C3 120.5(5) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
N1 C5 C4 123.2(5) . . ?
N1 C5 H5 118.4 . . ?
C4 C5 H5 118.4 . . ?
Si2 C6 H6A 109.5 . . ?
Si2 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si2 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si2 C7 H7A 109.5 . . ?
Si2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 Si2 116.2(3) . . ?
C9 C8 H8A 108.2 . . ?
Si2 C8 H8A 108.2 . . ?
C9 C8 H8AB 108.2 . . ?
Si2 C8 H8AB 108.2 . . ?
H8A C8 H8AB 107.4 . . ?
C10 C9 C8 112.9(4) . . ?
C10 C9 H9A 109.0 . . ?
C8 C9 H9A 109.0 . . ?
C10 C9 H9AB 109.0 . . ?
C8 C9 H9AB 109.0 . . ?
H9A C9 H9AB 107.8 . . ?
C9 C10 Si1 117.4(3) . . ?
C9 C10 H10A 108.0 . . ?
Si1 C10 H10A 108.0 . . ?
C9 C10 H10B 108.0 . . ?
Si1 C10 H10B 108.0 . . ?
H10A C10 H10B 107.2 . . ?
Si1 C11 H11A 109.5 . . ?
Si1 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si1 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si1 C12 H12A 109.5 . . ?
Si1 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si1 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N2 C13 C14 123.5(5) . . ?
N2 C13 H13 118.2 . . ?
C14 C13 H13 118.2 . . ?
C13 C14 C15 120.0(5) . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C14 C15 C16 115.9(4) . . ?
C14 C15 Si1 120.7(4) . . ?
C16 C15 Si1 123.4(4) . . ?
C17 C16 C15 120.8(4) . . ?
C17 C16 H16 119.6 . . ?
C15 C16 H16 119.6 . . ?
N2 C17 C16 122.3(5) . . ?
N2 C17 H17 118.8 . . ?
C16 C17 H17 118.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 C1 N1 C5 -0.1(9) . . . . ?
C2 C1 N1 Ag1 173.6(5) . . . . ?
N1 C1 C2 C3 -0.5(10) . . . . ?
C1 C2 C3 C4 0.1(8) . . . . ?
C1 C2 C3 Si2 177.4(5) . . . . ?
C6 Si2 C3 C4 105.5(5) . . . . ?
C8 Si2 C3 C4 -12.6(5) . . . . ?
C7 Si2 C3 C4 -134.4(5) . . . . ?
C6 Si2 C3 C2 -71.7(5) . . . . ?
C8 Si2 C3 C2 170.3(4) . . . . ?
C7 Si2 C3 C2 48.5(5) . . . . ?
C2 C3 C4 C5 0.8(8) . . . . ?
Si2 C3 C4 C5 -176.5(4) . . . . ?
C1 N1 C5 C4 1.1(8) . . . . ?
Ag1 N1 C5 C4 -172.9(4) . . . . ?
C3 C4 C5 N1 -1.5(9) . . . . ?
C6 Si2 C8 C9 59.0(4) . . . . ?
C7 Si2 C8 C9 -63.9(4) . . . . ?
C3 Si2 C8 C9 175.4(4) . . . . ?
Si2 C8 C9 C10 177.2(4) . . . . ?
C8 C9 C10 Si1 61.6(5) . . . . ?
C11 Si1 C10 C9 164.2(4) . . . . ?
C12 Si1 C10 C9 41.3(5) . . . . ?
C15 Si1 C10 C9 -79.1(4) . . . . ?
C17 N2 C13 C14 0.7(8) . . . . ?
Ag1 N2 C13 C14 175.2(4) 2_646 . . . ?
N2 C13 C14 C15 -0.7(8) . . . . ?
C13 C14 C15 C16 0.4(7) . . . . ?
C13 C14 C15 Si1 178.9(4) . . . . ?
C11 Si1 C15 C14 51.7(5) . . . . ?
C12 Si1 C15 C14 172.0(4) . . . . ?
C10 Si1 C15 C14 -66.4(4) . . . . ?
C11 Si1 C15 C16 -129.9(4) . . . . ?
C12 Si1 C15 C16 -9.6(5) . . . . ?
C10 Si1 C15 C16 112.0(4) . . . . ?
C14 C15 C16 C17 -0.2(7) . . . . ?
Si1 C15 C16 C17 -178.6(4) . . . . ?
C13 N2 C17 C16 -0.5(7) . . . . ?
Ag1 N2 C17 C16 -175.1(3) 2_646 . . . ?
C15 C16 C17 N2 0.2(7) . . . . ?

_refine_diff_density_max         1.655
_refine_diff_density_min         -1.432
_refine_diff_density_rms         0.124

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_BF4_a
_database_code_depnum_ccdc_archive 'CCDC 2043988'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H52 Ag2 B2 F8 N4 Si4'
_chemical_formula_weight         1018.51

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.3612(4)
_cell_length_b                   16.6277(8)
_cell_length_c                   14.6315(7)
_cell_angle_alpha                90
_cell_angle_beta                 99.4530(10)
_cell_angle_gamma                90
_cell_volume                     2246.54(18)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9247
_cell_measurement_theta_min      2.45
_cell_measurement_theta_max      28.09

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.506
_exptl_crystal_F_000             1032
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_exptl_absorpt_coefficient_mu    1.040
_shelx_estimated_absorpt_T_min   0.624
_shelx_estimated_absorpt_T_max   0.819
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  0.6590
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            37467
_diffrn_reflns_av_unetI/netI     0.0150
_diffrn_reflns_av_R_equivalents  0.0250
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         2.450
_diffrn_reflns_theta_max         28.114
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5478
_reflns_number_gt                4687
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX software'
_computing_cell_refinement       'Bruker APEX software'
_computing_data_reduction        'Bruker APEX software'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0587P)²+4.6788P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5478
_refine_ls_number_parameters     248
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0492
_refine_ls_R_factor_gt           0.0408
_refine_ls_wR_factor_ref         0.1173
_refine_ls_wR_factor_gt          0.1084
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
B1 B 0.1715(5) 0.5112(3) 0.3557(4) 0.0559(13) Uani 1 1 d . . . . .
F1 F 0.2821(3) 0.47236(17) 0.4087(2) 0.0674(7) Uani 1 1 d . . . . .
C1 C 0.5310(4) 0.3826(2) 0.3157(2) 0.0392(7) Uani 1 1 d . . . . .
H1 H 0.428760 0.386196 0.311076 0.047 Uiso 1 1 calc R U . . .
N1 N 0.6132(3) 0.39201(15) 0.39867(17) 0.0276(5) Uani 1 1 d . . . . .
Si1 Si 0.82251(9) 0.35086(5) 0.13092(6) 0.02707(17) Uani 1 1 d . . . . .
Ag1 Ag 0.51804(2) 0.40582(2) 0.52099(2) 0.03054(9) Uani 1 1 d . . . . .
C2 C 0.5889(4) 0.3677(3) 0.2363(2) 0.0413(8) Uani 1 1 d . . . . .
H2 H 0.525881 0.360284 0.178994 0.050 Uiso 1 1 calc R U . . .
F2 F 0.1953(3) 0.59204(13) 0.35544(19) 0.0552(6) Uani 1 1 d . . . . .
N2 N 0.5821(3) 0.60529(16) 0.35851(18) 0.0284(5) Uani 1 1 d . . . . .
Si2 Si 0.80373(9) 0.65680(5) 0.09794(6) 0.02857(18) Uani 1 1 d . . . . .
F3 F 0.1132(5) 0.4793(2) 0.2797(2) 0.1119(15) Uani 1 1 d . . . . .
C3 C 0.7373(3) 0.36353(17) 0.2389(2) 0.0269(6) Uani 1 1 d . . . . .
F4 F 0.0576(4) 0.5020(3) 0.4147(3) 0.1122(14) Uani 1 1 d . . . . .
C4 C 0.8212(3) 0.3741(2) 0.3260(2) 0.0316(6) Uani 1 1 d . . . . .
H4 H 0.923786 0.371627 0.332429 0.038 Uiso 1 1 calc R U . . .
C5 C 0.7573(3) 0.3880(2) 0.4031(2) 0.0309(6) Uani 1 1 d . . . . .
H5 H 0.817632 0.394957 0.461476 0.037 Uiso 1 1 calc R U . . .
C6 C 0.5062(4) 0.6331(2) 0.2791(2) 0.0402(8) Uani 1 1 d . . . . .
H6 H 0.405120 0.641787 0.275463 0.048 Uiso 1 1 calc R U . . .
C7 C 0.5702(4) 0.6497(2) 0.2023(2) 0.0418(8) Uani 1 1 d . . . . .
H7 H 0.512840 0.670153 0.147621 0.050 Uiso 1 1 calc R U . . .
C8 C 0.7175(3) 0.63668(18) 0.2043(2) 0.0279(6) Uani 1 1 d . . . . .
C9 C 0.7940(3) 0.60661(18) 0.2867(2) 0.0290(6) Uani 1 1 d . . . . .
H9 H 0.894523 0.595580 0.291664 0.035 Uiso 1 1 calc R U . . .
C10 C 0.7239(3) 0.59267(17) 0.3615(2) 0.0274(6) Uani 1 1 d . . . . .
H10 H 0.779101 0.573275 0.417469 0.033 Uiso 1 1 calc R U . . .
C11 C 0.6977(4) 0.2881(2) 0.0471(3) 0.0437(8) Uani 1 1 d . . . . .
H11A H 0.736156 0.283592 -0.011047 0.066 Uiso 1 1 calc R U . . .
H11B H 0.601874 0.313446 0.035092 0.066 Uiso 1 1 calc R U . . .
H11C H 0.689415 0.234402 0.073305 0.066 Uiso 1 1 calc R U . . .
C12 C 1.0027(4) 0.3019(2) 0.1606(3) 0.0452(9) Uani 1 1 d . . . . .
H12A H 1.047090 0.297095 0.104713 0.068 Uiso 1 1 calc R U . . .
H12B H 0.990933 0.248255 0.186141 0.068 Uiso 1 1 calc R U . . .
H12C H 1.065031 0.334528 0.206724 0.068 Uiso 1 1 calc R U . . .
C13 C 0.8435(3) 0.45402(17) 0.0835(2) 0.0281(6) Uani 1 1 d . . . . .
H13A H 0.893656 0.488264 0.134129 0.034 Uiso 1 1 calc R U . . .
H13B H 0.906780 0.450238 0.035690 0.034 Uiso 1 1 calc R U . . .
C14 C 0.7029(3) 0.49592(18) 0.0407(2) 0.0324(6) Uani 1 1 d . . . . .
H14A H 0.637130 0.497619 0.087202 0.039 Uiso 1 1 calc R U . . .
H14B H 0.655087 0.463672 -0.012508 0.039 Uiso 1 1 calc R U . . .
C15 C 0.7251(4) 0.58163(19) 0.0076(2) 0.0333(6) Uani 1 1 d . . . . .
H15A H 0.630192 0.602277 -0.023330 0.040 Uiso 1 1 calc R U . . .
H15B H 0.789228 0.578981 -0.039769 0.040 Uiso 1 1 calc R U . . .
C16 C 0.7499(5) 0.7595(2) 0.0550(3) 0.0491(9) Uani 1 1 d . . . . .
H16A H 0.782555 0.768560 -0.004473 0.074 Uiso 1 1 calc R U . . .
H16B H 0.794438 0.799510 0.100070 0.074 Uiso 1 1 calc R U . . .
H16C H 0.644235 0.764672 0.046742 0.074 Uiso 1 1 calc R U . . .
C17 C 1.0059(4) 0.6522(2) 0.1279(2) 0.0376(7) Uani 1 1 d . . . . .
H17A H 1.048325 0.656998 0.071172 0.056 Uiso 1 1 calc R U . . .
H17B H 1.034617 0.600688 0.158010 0.056 Uiso 1 1 calc R U . . .
H17C H 1.040512 0.696351 0.170044 0.056 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
B1 F3 1.272(6) . ?
B1 F1 1.351(5) . ?
B1 F2 1.363(5) . ?
B1 F4 1.486(7) . ?
F1 Ag1 2.759(2) . ?
C1 N1 1.336(4) . ?
C1 C2 1.383(5) . ?
C1 H1 0.9500 . ?
N1 C5 1.342(4) . ?
N1 Ag1 2.139(2) . ?
Si1 C12 1.859(4) . ?
Si1 C11 1.867(4) . ?
Si1 C13 1.873(3) . ?
Si1 C3 1.894(3) . ?
Ag1 N2 2.136(2) 3_666 ?
Ag1 Ag1 3.1988(5) 3_666 ?
C2 C3 1.386(4) . ?
C2 H2 0.9500 . ?
N2 C10 1.338(4) . ?
N2 C6 1.340(4) . ?
Si2 C16 1.861(4) . ?
Si2 C17 1.873(4) . ?
Si2 C15 1.879(3) . ?
Si2 C8 1.897(3) . ?
C3 C4 1.394(4) . ?
C4 C5 1.380(4) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.386(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.392(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.389(4) . ?
C9 C10 1.385(4) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.529(4) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.530(4) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F3 B1 F1 118.7(4) . . ?
F3 B1 F2 117.1(4) . . ?
F1 B1 F2 111.3(3) . . ?
F3 B1 F4 102.6(4) . . ?
F1 B1 F4 100.0(4) . . ?
F2 B1 F4 103.6(4) . . ?
B1 F1 Ag1 175.1(3) . . ?
N1 C1 C2 122.5(3) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C1 N1 C5 117.6(3) . . ?
C1 N1 Ag1 121.1(2) . . ?
C5 N1 Ag1 121.2(2) . . ?
C12 Si1 C11 110.79(19) . . ?
C12 Si1 C13 109.98(16) . . ?
C11 Si1 C13 111.13(16) . . ?
C12 Si1 C3 110.10(15) . . ?
C11 Si1 C3 107.81(15) . . ?
C13 Si1 C3 106.93(13) . . ?
N2 Ag1 N1 168.80(10) 3_666 . ?
N2 Ag1 F1 96.26(10) 3_666 . ?
N1 Ag1 F1 87.00(10) . . ?
N2 Ag1 Ag1 101.32(7) 3_666 3_666 ?
N1 Ag1 Ag1 89.41(7) . 3_666 ?
F1 Ag1 Ag1 56.22(6) . 3_666 ?
C1 C2 C3 121.0(3) . . ?
C1 C2 H2 119.5 . . ?
C3 C2 H2 119.5 . . ?
C10 N2 C6 117.7(3) . . ?
C10 N2 Ag1 121.8(2) . 3_666 ?
C6 N2 Ag1 120.2(2) . 3_666 ?
C16 Si2 C17 108.91(18) . . ?
C16 Si2 C15 108.66(18) . . ?
C17 Si2 C15 113.65(15) . . ?
C16 Si2 C8 108.10(15) . . ?
C17 Si2 C8 110.53(14) . . ?
C15 Si2 C8 106.82(14) . . ?
C2 C3 C4 115.5(3) . . ?
C2 C3 Si1 122.7(2) . . ?
C4 C3 Si1 121.7(2) . . ?
C5 C4 C3 120.9(3) . . ?
C5 C4 H4 119.5 . . ?
C3 C4 H4 119.5 . . ?
N1 C5 C4 122.4(3) . . ?
N1 C5 H5 118.8 . . ?
C4 C5 H5 118.8 . . ?
N2 C6 C7 122.2(3) . . ?
N2 C6 H6 118.9 . . ?
C7 C6 H6 118.9 . . ?
C6 C7 C8 120.7(3) . . ?
C6 C7 H7 119.7 . . ?
C8 C7 H7 119.7 . . ?
C9 C8 C7 116.2(3) . . ?
C9 C8 Si2 123.2(2) . . ?
C7 C8 Si2 120.6(2) . . ?
C10 C9 C8 120.2(3) . . ?
C10 C9 H9 119.9 . . ?
C8 C9 H9 119.9 . . ?
N2 C10 C9 123.0(3) . . ?
N2 C10 H10 118.5 . . ?
C9 C10 H10 118.5 . . ?
Si1 C11 H11A 109.5 . . ?
Si1 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si1 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si1 C12 H12A 109.5 . . ?
Si1 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si1 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C13 Si1 115.7(2) . . ?
C14 C13 H13A 108.4 . . ?
Si1 C13 H13A 108.4 . . ?
C14 C13 H13B 108.4 . . ?
Si1 C13 H13B 108.4 . . ?
H13A C13 H13B 107.4 . . ?
C13 C14 C15 113.7(3) . . ?
C13 C14 H14A 108.8 . . ?
C15 C14 H14A 108.8 . . ?
C13 C14 H14B 108.8 . . ?
C15 C14 H14B 108.8 . . ?
H14A C14 H14B 107.7 . . ?
C14 C15 Si2 117.1(2) . . ?
C14 C15 H15A 108.0 . . ?
Si2 C15 H15A 108.0 . . ?
C14 C15 H15B 108.0 . . ?
Si2 C15 H15B 108.0 . . ?
H15A C15 H15B 107.3 . . ?
Si2 C16 H16A 109.5 . . ?
Si2 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si2 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si2 C17 H17A 109.5 . . ?
Si2 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si2 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 C1 N1 C5 1.1(5) . . . . ?
C2 C1 N1 Ag1 -175.2(3) . . . . ?
N1 C1 C2 C3 -1.3(6) . . . . ?
C1 C2 C3 C4 0.9(5) . . . . ?
C1 C2 C3 Si1 -175.5(3) . . . . ?
C12 Si1 C3 C2 -154.0(3) . . . . ?
C11 Si1 C3 C2 -33.0(3) . . . . ?
C13 Si1 C3 C2 86.6(3) . . . . ?
C12 Si1 C3 C4 29.9(3) . . . . ?
C11 Si1 C3 C4 150.9(3) . . . . ?
C13 Si1 C3 C4 -89.5(3) . . . . ?
C2 C3 C4 C5 -0.3(5) . . . . ?
Si1 C3 C4 C5 176.1(2) . . . . ?
C1 N1 C5 C4 -0.5(5) . . . . ?
Ag1 N1 C5 C4 175.9(2) . . . . ?
C3 C4 C5 N1 0.1(5) . . . . ?
C10 N2 C6 C7 -0.8(5) . . . . ?
Ag1 N2 C6 C7 172.8(3) 3_666 . . . ?
N2 C6 C7 C8 1.0(6) . . . . ?
C6 C7 C8 C9 0.1(5) . . . . ?
C6 C7 C8 Si2 178.4(3) . . . . ?
C16 Si2 C8 C9 -131.3(3) . . . . ?
C17 Si2 C8 C9 -12.2(3) . . . . ?
C15 Si2 C8 C9 111.9(3) . . . . ?
C16 Si2 C8 C7 50.5(3) . . . . ?
C17 Si2 C8 C7 169.6(3) . . . . ?
C15 Si2 C8 C7 -66.3(3) . . . . ?
C7 C8 C9 C10 -1.2(5) . . . . ?
Si2 C8 C9 C10 -179.5(2) . . . . ?
C6 N2 C10 C9 -0.4(5) . . . . ?
Ag1 N2 C10 C9 -173.9(2) 3_666 . . . ?
C8 C9 C10 N2 1.4(5) . . . . ?
C12 Si1 C13 C14 170.0(2) . . . . ?
C11 Si1 C13 C14 46.9(3) . . . . ?
C3 Si1 C13 C14 -70.5(2) . . . . ?
Si1 C13 C14 C15 176.9(2) . . . . ?
C13 C14 C15 Si2 -62.3(3) . . . . ?
C16 Si2 C15 C14 -156.4(2) . . . . ?
C17 Si2 C15 C14 82.2(3) . . . . ?
C8 Si2 C15 C14 -39.9(3) . . . . ?

_refine_diff_density_max         2.572
_refine_diff_density_min         -0.861
_refine_diff_density_rms         0.107

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AgClO4_Exchanged_a
_database_code_depnum_ccdc_archive 'CCDC 2043992'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C17 H26 Ag Cl N2 O4 Si2'
_chemical_formula_weight         521.90

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0026 0.0014 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0052 0.0028 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0092 0.0051 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0715 0.0599 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1308 0.1347 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -1.0930 0.9537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.055(3)
_cell_length_b                   12.393(3)
_cell_length_c                   14.789(3)
_cell_angle_alpha                90
_cell_angle_beta                 106.13(3)
_cell_angle_gamma                90
_cell_volume                     2298.5(9)
_cell_formula_units_Z            4
_cell_measurement_temperature    253(2)
_cell_measurement_reflns_used    59298
_cell_measurement_theta_min      0.372
_cell_measurement_theta_max      33.425

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.508
_exptl_crystal_F_000             1064
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.083
_exptl_crystal_size_min          0.066
_exptl_absorpt_coefficient_mu    0.868
_shelx_estimated_absorpt_T_min   0.903
_shelx_estimated_absorpt_T_max   0.945
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_correction_T_min  0.952
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_process_details   'HKL3000sm Scalepack(Otwinowski et.al,2003)'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      253(2)
_diffrn_radiation_wavelength     0.650
_diffrn_radiation_type           synchrotron
_diffrn_source                   'PLSII 2D bending magnet'
_diffrn_measurement_device_type  'Rayonix MX225HS CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            37227
_diffrn_reflns_av_unetI/netI     0.0286
_diffrn_reflns_av_R_equivalents  0.0409
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_theta_min         1.994
_diffrn_reflns_theta_max         33.309
_diffrn_reflns_theta_full        22.955
_diffrn_measured_fraction_theta_max 0.837
_diffrn_measured_fraction_theta_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.837
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.837
_diffrn_reflns_point_group_measured_fraction_full 0.997
_reflns_number_total             9718
_reflns_number_gt                7267
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'PAL BL2D-SMDC Program (Shin et. al, 2016)'
_computing_cell_refinement       'HKL3000sm (Otwinowski & Minor, 1997)'
_computing_data_reduction        'HKL3000sm (Otwinowski & Minor, 1997)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1218P)²+0.2972P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         9718
_refine_ls_number_parameters     269
_refine_ls_number_restraints     10
_refine_ls_R_factor_all          0.0634
_refine_ls_R_factor_gt           0.0525
_refine_ls_wR_factor_ref         0.1881
_refine_ls_wR_factor_gt          0.1785
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.27494(2) 0.22794(2) 0.19925(2) 0.05745(9) Uani 1 1 d . . . . .
Si02 Si 0.74387(4) 0.58467(4) 0.50539(4) 0.03957(12) Uani 1 1 d . . . . .
Si04 Si 0.82113(5) 0.23547(4) 0.34805(5) 0.04244(13) Uani 1 1 d . . . . .
N1 N 0.44539(16) 0.23555(16) 0.24936(15) 0.0478(4) Uani 1 1 d . . . . .
N2 N 0.39023(14) 0.69196(19) 0.36237(15) 0.0499(4) Uani 1 1 d . . . . .
C1 C 0.50083(18) 0.1624(2) 0.31092(18) 0.0546(5) Uani 1 1 d . . . . .
H1 H 0.463127 0.110232 0.334991 0.066 Uiso 1 1 calc R U . . .
C2 C 0.61105(17) 0.16068(19) 0.34022(17) 0.0498(4) Uani 1 1 d . . . . .
H2 H 0.646359 0.107741 0.383167 0.060 Uiso 1 1 calc R U . . .
C3 C 0.67025(15) 0.23644(14) 0.30685(14) 0.0372(3) Uani 1 1 d . . . . .
C4 C 0.61105(16) 0.31165(15) 0.24219(15) 0.0417(3) Uani 1 1 d . . . . .
H4 H 0.646662 0.364084 0.216320 0.050 Uiso 1 1 calc R U . . .
C5 C 0.50097(16) 0.30932(17) 0.21623(15) 0.0450(4) Uani 1 1 d . . . . .
H5 H 0.463471 0.361520 0.173632 0.054 Uiso 1 1 calc R U . . .
C6 C 0.8638(3) 0.0949(2) 0.3329(3) 0.0672(7) Uani 1 1 d . . . . .
H6A H 0.940789 0.089621 0.356713 0.101 Uiso 1 1 calc R U . . .
H6B H 0.842145 0.076064 0.266600 0.101 Uiso 1 1 calc R U . . .
H6C H 0.830830 0.045634 0.367409 0.101 Uiso 1 1 calc R U . . .
C7 C 0.8745(2) 0.3334(3) 0.2760(2) 0.0673(7) Uani 1 1 d . . . . .
H7A H 0.951865 0.332029 0.296209 0.101 Uiso 1 1 calc R U . . .
H7B H 0.849649 0.405448 0.284308 0.101 Uiso 1 1 calc R U . . .
H7C H 0.849785 0.313355 0.210070 0.101 Uiso 1 1 calc R U . . .
C8 C 0.86729(18) 0.27099(16) 0.47654(18) 0.0477(4) Uani 1 1 d . . . . .
H8A H 0.822536 0.231691 0.508762 0.057 Uiso 1 1 calc R U . . .
H8B H 0.940314 0.244174 0.501620 0.057 Uiso 1 1 calc R U . . .
C9 C 0.86621(16) 0.39054(17) 0.50283(17) 0.0477(4) Uani 1 1 d . . . . .
H9A H 0.912497 0.430739 0.472760 0.057 Uiso 1 1 calc R U . . .
H9B H 0.895478 0.398146 0.571118 0.057 Uiso 1 1 calc R U . . .
C10 C 0.75407(16) 0.43989(16) 0.47296(16) 0.0444(4) Uani 1 1 d . . . . .
H10A H 0.707778 0.397093 0.501151 0.053 Uiso 1 1 calc R U . . .
H10B H 0.726271 0.433208 0.404466 0.053 Uiso 1 1 calc R U . . .
C11 C 0.7817(3) 0.6041(3) 0.63538(19) 0.0678(7) Uani 1 1 d . . . . .
H11A H 0.795968 0.679939 0.649892 0.102 Uiso 1 1 calc R U . . .
H11B H 0.845052 0.562203 0.664221 0.102 Uiso 1 1 calc R U . . .
H11C H 0.723642 0.580447 0.659708 0.102 Uiso 1 1 calc R U . . .
C12 C 0.8288(2) 0.6705(2) 0.4531(2) 0.0630(6) Uani 1 1 d . . . . .
H12A H 0.817815 0.745778 0.465842 0.094 Uiso 1 1 calc R U . . .
H12B H 0.809892 0.658894 0.385632 0.094 Uiso 1 1 calc R U . . .
H12C H 0.903112 0.651807 0.480518 0.094 Uiso 1 1 calc R U . . .
C13 C 0.42792(18) 0.5979(2) 0.34092(18) 0.0556(5) Uani 1 1 d . . . . .
H13 H 0.382933 0.553960 0.294828 0.067 Uiso 1 1 calc R U . . .
C14 C 0.53026(17) 0.5627(2) 0.38377(18) 0.0533(5) Uani 1 1 d . . . . .
H14 H 0.552820 0.495325 0.367255 0.064 Uiso 1 1 calc R U . . .
C15 C 0.60058(14) 0.62604(16) 0.45132(14) 0.0401(3) Uani 1 1 d . . . . .
C16 C 0.55987(19) 0.72307(18) 0.4724(2) 0.0555(6) Uani 1 1 d . . . . .
H16 H 0.602911 0.768772 0.518158 0.067 Uiso 1 1 calc R U . . .
C17 C 0.4559(2) 0.7535(2) 0.4264(2) 0.0579(6) Uani 1 1 d . . . . .
H17 H 0.431005 0.820554 0.441350 0.069 Uiso 1 1 calc R U . . .
Cl1 Cl 0.2577(5) 0.5238(6) 0.0893(5) 0.0494(12) Uiso 0.231(7) 1 d D . P A 1
O1 O 0.2116(8) 0.5819(9) 0.1526(6) 0.071(3) Uiso 0.231(7) 1 d D . P A 1
O2 O 0.2063(7) 0.5543(7) -0.0130(5) 0.065(3) Uiso 0.231(7) 1 d D . P A 1
O3 O 0.2413(11) 0.4041(6) 0.0949(9) 0.094(4) Uiso 0.231(7) 1 d D . P A 1
O4 O 0.3746(5) 0.5443(8) 0.1068(7) 0.074(3) Uiso 0.231(7) 1 d D . P A 1
Cl1A Cl 0.2442(2) 0.52588(15) 0.08351(16) 0.0611(5) Uani 0.769(7) 1 d . . P A 2
O1A O 0.3016(11) 0.5290(9) 0.0248(9) 0.287(8) Uani 0.769(7) 1 d . . P A 2
O2A O 0.2690(5) 0.4337(4) 0.1383(6) 0.161(3) Uani 0.769(7) 1 d . . P A 2
O3A O 0.1358(5) 0.5104(4) 0.0268(4) 0.145(3) Uani 0.769(7) 1 d . . P A 2
O4A O 0.2468(4) 0.6223(3) 0.1320(3) 0.0936(16) Uani 0.769(7) 1 d . . P A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.1416(19) 2_545 ?
Ag1 N1 2.143(2) . ?
Si02 C12 1.853(3) . ?
Si02 C11 1.863(3) . ?
Si02 C10 1.872(2) . ?
Si02 C15 1.890(2) . ?
Si04 C6 1.862(3) . ?
Si04 C7 1.873(3) . ?
Si04 C8 1.879(3) . ?
Si04 C3 1.893(2) . ?
N1 C5 1.342(3) . ?
N1 C1 1.345(3) . ?
N2 C17 1.328(3) . ?
N2 C13 1.337(3) . ?
C1 C2 1.383(3) . ?
C1 H1 0.9400 . ?
C2 C3 1.391(3) . ?
C2 H2 0.9400 . ?
C3 C4 1.404(3) . ?
C4 C5 1.381(3) . ?
C4 H4 0.9400 . ?
C5 H5 0.9400 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C6 H6C 0.9700 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 H7C 0.9700 . ?
C8 C9 1.533(3) . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C9 C10 1.534(3) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 H11C 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 H12C 0.9700 . ?
C13 C14 1.381(3) . ?
C13 H13 0.9400 . ?
C14 C15 1.395(3) . ?
C14 H14 0.9400 . ?
C15 C16 1.385(3) . ?
C16 C17 1.391(3) . ?
C16 H16 0.9400 . ?
C17 H17 0.9400 . ?
Cl1 O1 1.439(7) . ?
Cl1 O4 1.497(7) . ?
Cl1 O3 1.504(7) . ?
Cl1 O2 1.522(7) . ?
Cl1A O1A 1.296(6) . ?
Cl1A O2A 1.386(5) . ?
Cl1A O4A 1.389(3) . ?
Cl1A O3A 1.443(6) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N1 169.16(8) 2_545 . ?
C12 Si02 C11 109.78(16) . . ?
C12 Si02 C10 110.49(12) . . ?
C11 Si02 C10 111.80(13) . . ?
C12 Si02 C15 107.71(11) . . ?
C11 Si02 C15 110.42(13) . . ?
C10 Si02 C15 106.51(9) . . ?
C6 Si04 C7 111.49(15) . . ?
C6 Si04 C8 108.57(13) . . ?
C7 Si04 C8 110.99(13) . . ?
C6 Si04 C3 106.66(12) . . ?
C7 Si04 C3 109.35(12) . . ?
C8 Si04 C3 109.67(10) . . ?
C5 N1 C1 117.57(19) . . ?
C5 N1 Ag1 121.24(16) . . ?
C1 N1 Ag1 121.07(15) . . ?
C17 N2 C13 117.6(2) . . ?
C17 N2 Ag1 123.90(17) . 2 ?
C13 N2 Ag1 118.29(16) . 2 ?
N1 C1 C2 122.7(2) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C1 C2 C3 120.7(2) . . ?
C1 C2 H2 119.6 . . ?
C3 C2 H2 119.6 . . ?
C2 C3 C4 115.78(18) . . ?
C2 C3 Si04 120.83(15) . . ?
C4 C3 Si04 123.38(14) . . ?
C5 C4 C3 120.60(19) . . ?
C5 C4 H4 119.7 . . ?
C3 C4 H4 119.7 . . ?
N1 C5 C4 122.6(2) . . ?
N1 C5 H5 118.7 . . ?
C4 C5 H5 118.7 . . ?
Si04 C6 H6A 109.5 . . ?
Si04 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si04 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si04 C7 H7A 109.5 . . ?
Si04 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si04 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 Si04 117.39(16) . . ?
C9 C8 H8A 108.0 . . ?
Si04 C8 H8A 108.0 . . ?
C9 C8 H8B 108.0 . . ?
Si04 C8 H8B 108.0 . . ?
H8A C8 H8B 107.2 . . ?
C8 C9 C10 112.81(17) . . ?
C8 C9 H9A 109.0 . . ?
C10 C9 H9A 109.0 . . ?
C8 C9 H9B 109.0 . . ?
C10 C9 H9B 109.0 . . ?
H9A C9 H9B 107.8 . . ?
C9 C10 Si02 116.02(14) . . ?
C9 C10 H10A 108.3 . . ?
Si02 C10 H10A 108.3 . . ?
C9 C10 H10B 108.3 . . ?
Si02 C10 H10B 108.3 . . ?
H10A C10 H10B 107.4 . . ?
Si02 C11 H11A 109.5 . . ?
Si02 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si02 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si02 C12 H12A 109.5 . . ?
Si02 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si02 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N2 C13 C14 122.6(2) . . ?
N2 C13 H13 118.7 . . ?
C14 C13 H13 118.7 . . ?
C13 C14 C15 120.7(2) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 H14 119.6 . . ?
C16 C15 C14 115.61(19) . . ?
C16 C15 Si02 122.49(15) . . ?
C14 C15 Si02 121.83(15) . . ?
C15 C16 C17 120.6(2) . . ?
C15 C16 H16 119.7 . . ?
C17 C16 H16 119.7 . . ?
N2 C17 C16 122.8(2) . . ?
N2 C17 H17 118.6 . . ?
C16 C17 H17 118.6 . . ?
O1 Cl1 O4 113.2(6) . . ?
O1 Cl1 O3 111.5(6) . . ?
O4 Cl1 O3 108.1(6) . . ?
O1 Cl1 O2 112.0(6) . . ?
O4 Cl1 O2 106.0(5) . . ?
O3 Cl1 O2 105.6(6) . . ?
O1A Cl1A O2A 109.4(7) . . ?
O1A Cl1A O4A 112.6(5) . . ?
O2A Cl1A O4A 116.0(4) . . ?
O1A Cl1A O3A 105.7(7) . . ?
O2A Cl1A O3A 105.2(4) . . ?
O4A Cl1A O3A 107.1(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 -0.2(4) . . . . ?
Ag1 N1 C1 C2 175.8(2) . . . . ?
N1 C1 C2 C3 0.3(4) . . . . ?
C1 C2 C3 C4 -0.7(3) . . . . ?
C1 C2 C3 Si04 179.2(2) . . . . ?
C6 Si04 C3 C2 50.7(2) . . . . ?
C7 Si04 C3 C2 171.4(2) . . . . ?
C8 Si04 C3 C2 -66.7(2) . . . . ?
C6 Si04 C3 C4 -129.44(19) . . . . ?
C7 Si04 C3 C4 -8.8(2) . . . . ?
C8 Si04 C3 C4 113.17(17) . . . . ?
C2 C3 C4 C5 1.1(3) . . . . ?
Si04 C3 C4 C5 -178.80(16) . . . . ?
C1 N1 C5 C4 0.6(3) . . . . ?
Ag1 N1 C5 C4 -175.41(16) . . . . ?
C3 C4 C5 N1 -1.1(3) . . . . ?
C6 Si04 C8 C9 164.94(19) . . . . ?
C7 Si04 C8 C9 42.1(2) . . . . ?
C3 Si04 C8 C9 -78.87(19) . . . . ?
Si04 C8 C9 C10 61.7(3) . . . . ?
C8 C9 C10 Si02 178.15(17) . . . . ?
C12 Si02 C10 C9 58.6(2) . . . . ?
C11 Si02 C10 C9 -64.0(2) . . . . ?
C15 Si02 C10 C9 175.35(16) . . . . ?
C17 N2 C13 C14 1.2(4) . . . . ?
Ag1 N2 C13 C14 -173.6(2) 2 . . . ?
N2 C13 C14 C15 -1.2(4) . . . . ?
C13 C14 C15 C16 1.1(4) . . . . ?
C13 C14 C15 Si02 -175.8(2) . . . . ?
C12 Si02 C15 C16 -71.4(2) . . . . ?
C11 Si02 C15 C16 48.5(3) . . . . ?
C10 Si02 C15 C16 170.1(2) . . . . ?
C12 Si02 C15 C14 105.4(2) . . . . ?
C11 Si02 C15 C14 -134.8(2) . . . . ?
C10 Si02 C15 C14 -13.2(2) . . . . ?
C14 C15 C16 C17 -1.1(4) . . . . ?
Si02 C15 C16 C17 175.8(2) . . . . ?
C13 N2 C17 C16 -1.3(5) . . . . ?
Ag1 N2 C17 C16 173.3(2) 2 . . . ?
C15 C16 C17 N2 1.3(5) . . . . ?

_refine_diff_density_max         2.119
_refine_diff_density_min         -0.798
_refine_diff_density_rms         0.100

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_AgClO4_a
_database_code_depnum_ccdc_archive 'CCDC 2043989'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H52 Ag2 Cl2 N4 O8 Si4'
_chemical_formula_weight         1043.79

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.4780(2)
_cell_length_b                   16.6234(4)
_cell_length_c                   14.6344(4)
_cell_angle_alpha                90
_cell_angle_beta                 98.9380(10)
_cell_angle_gamma                90
_cell_volume                     2277.75(10)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9896
_cell_measurement_theta_min      2.18
_cell_measurement_theta_max      28.01

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.522
_exptl_crystal_F_000             1064
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.300
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.130
_exptl_absorpt_coefficient_mu    1.131
_shelx_estimated_absorpt_T_min   0.728
_shelx_estimated_absorpt_T_max   0.867
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  0.6774
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            75525
_diffrn_reflns_av_unetI/netI     0.0137
_diffrn_reflns_av_R_equivalents  0.0320
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.867
_diffrn_reflns_theta_max         28.137
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5577
_reflns_number_gt                4738
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX software'
_computing_cell_refinement       'Bruker APEX software'
_computing_data_reduction        'Bruker APEX software'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0277P)²+2.3343P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5577
_refine_ls_number_parameters     274
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0373
_refine_ls_R_factor_gt           0.0288
_refine_ls_wR_factor_ref         0.0704
_refine_ls_wR_factor_gt          0.0650
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_restrained_S_all      1.080
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.51978(2) 0.40464(2) 0.51973(2) 0.03043(6) Uani 1 1 d . . . . .
Si1 Si 0.81791(6) 0.35055(3) 0.12602(4) 0.02658(12) Uani 1 1 d . . . . .
Si2 Si 0.80373(7) 0.65799(4) 0.09891(4) 0.02909(13) Uani 1 1 d . . . . .
N1 N 0.61254(19) 0.38935(11) 0.39586(12) 0.0274(4) Uani 1 1 d . . . . .
N2 N 0.58144(19) 0.60742(11) 0.35947(12) 0.0282(4) Uani 1 1 d . . . . .
C1 C 0.5312(2) 0.38104(17) 0.31331(16) 0.0388(5) Uani 1 1 d . . . . .
H1 H 0.430404 0.384843 0.309530 0.047 Uiso 1 1 calc R U . . .
C2 C 0.5877(2) 0.36713(17) 0.23311(15) 0.0399(5) Uani 1 1 d . . . . .
H2 H 0.525310 0.360959 0.176104 0.048 Uiso 1 1 calc R U . . .
C3 C 0.7344(2) 0.36205(12) 0.23476(14) 0.0267(4) Uani 1 1 d . . . . .
C4 C 0.8171(2) 0.37139(14) 0.32116(15) 0.0325(4) Uani 1 1 d . . . . .
H4 H 0.918194 0.368640 0.326860 0.039 Uiso 1 1 calc R U . . .
C5 C 0.7543(2) 0.38464(14) 0.39893(15) 0.0329(5) Uani 1 1 d . . . . .
H5 H 0.814091 0.390647 0.456955 0.039 Uiso 1 1 calc R U . . .
C6 C 0.9932(3) 0.29964(16) 0.15374(17) 0.0417(6) Uani 1 1 d . . . . .
H6A H 1.037029 0.295196 0.097548 0.063 Uiso 1 1 calc R U . . .
H6B H 0.979639 0.245758 0.178124 0.063 Uiso 1 1 calc R U . . .
H6C H 1.055679 0.331034 0.200215 0.063 Uiso 1 1 calc R U . . .
C7 C 0.6934(3) 0.29025(15) 0.04139(17) 0.0416(6) Uani 1 1 d . . . . .
H7A H 0.729430 0.288258 -0.017800 0.062 Uiso 1 1 calc R U . . .
H7B H 0.598612 0.315300 0.032360 0.062 Uiso 1 1 calc R U . . .
H7C H 0.686570 0.235491 0.065144 0.062 Uiso 1 1 calc R U . . .
C8 C 0.8416(2) 0.45458(12) 0.08123(15) 0.0287(4) Uani 1 1 d . . . . .
H8A H 0.891407 0.487670 0.132577 0.034 Uiso 1 1 calc R U . . .
H8AB H 0.904294 0.451368 0.033215 0.034 Uiso 1 1 calc R U . . .
C9 C 0.7038(2) 0.49770(13) 0.04009(16) 0.0342(5) Uani 1 1 d . . . . .
H9A H 0.639106 0.499137 0.087053 0.041 Uiso 1 1 calc R U . . .
H9AB H 0.655960 0.466184 -0.013276 0.041 Uiso 1 1 calc R U . . .
C10 C 0.7264(3) 0.58386(13) 0.00798(15) 0.0341(5) Uani 1 1 d . . . . .
H10A H 0.633035 0.604879 -0.022381 0.041 Uiso 1 1 calc R U . . .
H10B H 0.789983 0.581631 -0.039605 0.041 Uiso 1 1 calc R U . . .
C11 C 1.0024(2) 0.65250(15) 0.12879(16) 0.0361(5) Uani 1 1 d . . . . .
H11A H 1.035939 0.694001 0.174621 0.054 Uiso 1 1 calc R U . . .
H11B H 1.045560 0.661291 0.072925 0.054 Uiso 1 1 calc R U . . .
H11C H 1.030077 0.599340 0.154483 0.054 Uiso 1 1 calc R U . . .
C12 C 0.7526(3) 0.76143(15) 0.05723(19) 0.0492(7) Uani 1 1 d . . . . .
H12A H 0.794451 0.800789 0.103499 0.074 Uiso 1 1 calc R U . . .
H12B H 0.648369 0.766567 0.047421 0.074 Uiso 1 1 calc R U . . .
H12C H 0.788204 0.771325 -0.001160 0.074 Uiso 1 1 calc R U . . .
C13 C 0.5084(2) 0.63553(17) 0.28059(16) 0.0411(6) Uani 1 1 d . . . . .
H13 H 0.408769 0.644759 0.277119 0.049 Uiso 1 1 calc R U . . .
C14 C 0.5720(3) 0.65173(17) 0.20371(16) 0.0423(6) Uani 1 1 d . . . . .
H14 H 0.516053 0.672629 0.149422 0.051 Uiso 1 1 calc R U . . .
C15 C 0.7170(2) 0.63782(13) 0.20493(14) 0.0287(4) Uani 1 1 d . . . . .
C16 C 0.7909(2) 0.60735(13) 0.28702(15) 0.0289(4) Uani 1 1 d . . . . .
H16 H 0.890061 0.596049 0.291839 0.035 Uiso 1 1 calc R U . . .
C17 C 0.7210(2) 0.59330(13) 0.36199(14) 0.0278(4) Uani 1 1 d . . . . .
H17 H 0.774383 0.572814 0.417419 0.033 Uiso 1 1 calc R U . . .
Cl1 Cl 0.17023(11) 0.50998(5) 0.36281(10) 0.0343(3) Uani 0.769(4) 1 d . . P A
-1
O2 O 0.0591(3) 0.4965(2) 0.4178(2) 0.0779(11) Uani 0.769(4) 1 d . . P A -1
O1 O 0.2882(4) 0.4733(2) 0.4163(2) 0.0476(8) Uani 0.769(4) 1 d . . P A -1
O3 O 0.1911(15) 0.5979(6) 0.3592(6) 0.0414(13) Uani 0.769(4) 1 d . . P A -1
O4 O 0.1293(4) 0.4745(2) 0.2753(2) 0.0752(11) Uani 0.769(4) 1 d . . P A -1
ClA Cl 0.1968(4) 0.51279(19) 0.3305(3) 0.0343(8) Uiso 0.231(4) 1 d . . P A 2
O2A O 0.2594(10) 0.4999(5) 0.2532(6) 0.054(3) Uiso 0.231(4) 1 d . . P A 2
O3A O 0.0518(12) 0.4824(6) 0.3215(8) 0.066(3) Uiso 0.231(4) 1 d . . P A 2
O1A O 0.3105(13) 0.4796(7) 0.3916(8) 0.038(3) Uiso 0.231(4) 1 d . . P A 2
O4A O 0.190(5) 0.585(2) 0.340(2) 0.043(5) Uani 0.231(4) 1 d . . P A 2


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.1477(17) 3_666 ?
Ag1 N1 2.1492(17) . ?
Ag1 O1 2.716(3) . ?
Ag1 Ag1 3.2338(3) 3_666 ?
Si1 C6 1.852(2) . ?
Si1 C7 1.865(2) . ?
Si1 C8 1.875(2) . ?
Si1 C3 1.894(2) . ?
Si2 C12 1.863(2) . ?
Si2 C11 1.868(2) . ?
Si2 C10 1.877(2) . ?
Si2 C15 1.895(2) . ?
N1 C1 1.336(3) . ?
N1 C5 1.340(3) . ?
N2 C13 1.335(3) . ?
N2 C17 1.338(3) . ?
C1 C2 1.383(3) . ?
C1 H1 0.9500 . ?
C2 C3 1.390(3) . ?
C2 H2 0.9500 . ?
C3 C4 1.389(3) . ?
C4 C5 1.381(3) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 C9 1.528(3) . ?
C8 H8A 0.9900 . ?
C8 H8AB 0.9900 . ?
C9 C10 1.533(3) . ?
C9 H9A 0.9900 . ?
C9 H9AB 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.383(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.390(3) . ?
C14 H14 0.9500 . ?
C15 C16 1.389(3) . ?
C16 C17 1.387(3) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
Cl1 O1 1.402(3) . ?
Cl1 O4 1.408(3) . ?
Cl1 O2 1.440(3) . ?
Cl1 O3 1.477(11) . ?
ClA O4A 1.21(3) . ?
ClA O2A 1.374(10) . ?
ClA O1A 1.402(13) . ?
ClA O3A 1.451(12) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N1 167.64(7) 3_666 . ?
N2 Ag1 O1 94.15(9) 3_666 . ?
N1 Ag1 O1 88.89(9) . . ?
N2 Ag1 Ag1 100.62(5) 3_666 3_666 ?
N1 Ag1 Ag1 90.95(5) . 3_666 ?
O1 Ag1 Ag1 55.07(8) . 3_666 ?
C6 Si1 C7 110.70(12) . . ?
C6 Si1 C8 110.24(11) . . ?
C7 Si1 C8 111.18(11) . . ?
C6 Si1 C3 109.86(10) . . ?
C7 Si1 C3 107.96(10) . . ?
C8 Si1 C3 106.79(9) . . ?
C12 Si2 C11 108.84(12) . . ?
C12 Si2 C10 108.70(12) . . ?
C11 Si2 C10 113.72(11) . . ?
C12 Si2 C15 107.91(11) . . ?
C11 Si2 C15 110.46(10) . . ?
C10 Si2 C15 107.03(10) . . ?
C1 N1 C5 117.36(18) . . ?
C1 N1 Ag1 121.38(14) . . ?
C5 N1 Ag1 121.21(14) . . ?
C13 N2 C17 117.58(18) . . ?
C13 N2 Ag1 120.43(14) . 3_666 ?
C17 N2 Ag1 121.80(14) . 3_666 ?
N1 C1 C2 122.6(2) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C1 C2 C3 120.9(2) . . ?
C1 C2 H2 119.5 . . ?
C3 C2 H2 119.5 . . ?
C4 C3 C2 115.49(18) . . ?
C4 C3 Si1 121.75(16) . . ?
C2 C3 Si1 122.62(16) . . ?
C5 C4 C3 120.9(2) . . ?
C5 C4 H4 119.5 . . ?
C3 C4 H4 119.5 . . ?
N1 C5 C4 122.7(2) . . ?
N1 C5 H5 118.7 . . ?
C4 C5 H5 118.7 . . ?
Si1 C6 H6A 109.5 . . ?
Si1 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
Si1 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
Si1 C7 H7A 109.5 . . ?
Si1 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
Si1 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C9 C8 Si1 115.41(15) . . ?
C9 C8 H8A 108.4 . . ?
Si1 C8 H8A 108.4 . . ?
C9 C8 H8AB 108.4 . . ?
Si1 C8 H8AB 108.4 . . ?
H8A C8 H8AB 107.5 . . ?
C8 C9 C10 114.06(19) . . ?
C8 C9 H9A 108.7 . . ?
C10 C9 H9A 108.7 . . ?
C8 C9 H9AB 108.7 . . ?
C10 C9 H9AB 108.7 . . ?
H9A C9 H9AB 107.6 . . ?
C9 C10 Si2 116.99(15) . . ?
C9 C10 H10A 108.1 . . ?
Si2 C10 H10A 108.1 . . ?
C9 C10 H10B 108.1 . . ?
Si2 C10 H10B 108.1 . . ?
H10A C10 H10B 107.3 . . ?
Si2 C11 H11A 109.5 . . ?
Si2 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si2 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si2 C12 H12A 109.5 . . ?
Si2 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si2 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N2 C13 C14 122.6(2) . . ?
N2 C13 H13 118.7 . . ?
C14 C13 H13 118.7 . . ?
C13 C14 C15 120.8(2) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 H14 119.6 . . ?
C16 C15 C14 115.88(19) . . ?
C16 C15 Si2 123.21(16) . . ?
C14 C15 Si2 120.90(16) . . ?
C17 C16 C15 120.44(19) . . ?
C17 C16 H16 119.8 . . ?
C15 C16 H16 119.8 . . ?
N2 C17 C16 122.71(19) . . ?
N2 C17 H17 118.6 . . ?
C16 C17 H17 118.6 . . ?
O1 Cl1 O4 114.1(2) . . ?
O1 Cl1 O2 102.1(2) . . ?
O4 Cl1 O2 108.8(2) . . ?
O1 Cl1 O3 110.5(5) . . ?
O4 Cl1 O3 113.7(4) . . ?
O2 Cl1 O3 106.8(5) . . ?
Cl1 O1 Ag1 178.9(2) . . ?
O4A ClA O2A 106(2) . . ?
O4A ClA O1A 112(2) . . ?
O2A ClA O1A 94.4(6) . . ?
O4A ClA O3A 107(2) . . ?
O2A ClA O3A 113.3(7) . . ?
O1A ClA O3A 122.9(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.8(4) . . . . ?
Ag1 N1 C1 C2 -176.7(2) . . . . ?
N1 C1 C2 C3 -0.8(4) . . . . ?
C1 C2 C3 C4 0.3(4) . . . . ?
C1 C2 C3 Si1 -175.5(2) . . . . ?
C6 Si1 C3 C4 30.8(2) . . . . ?
C7 Si1 C3 C4 151.64(19) . . . . ?
C8 Si1 C3 C4 -88.73(19) . . . . ?
C6 Si1 C3 C2 -153.6(2) . . . . ?
C7 Si1 C3 C2 -32.8(2) . . . . ?
C8 Si1 C3 C2 86.9(2) . . . . ?
C2 C3 C4 C5 0.1(3) . . . . ?
Si1 C3 C4 C5 175.99(18) . . . . ?
C1 N1 C5 C4 -0.3(3) . . . . ?
Ag1 N1 C5 C4 177.17(18) . . . . ?
C3 C4 C5 N1 -0.1(4) . . . . ?
C6 Si1 C8 C9 169.80(16) . . . . ?
C7 Si1 C8 C9 46.64(19) . . . . ?
C3 Si1 C8 C9 -70.90(18) . . . . ?
Si1 C8 C9 C10 177.50(15) . . . . ?
C8 C9 C10 Si2 -62.8(2) . . . . ?
C12 Si2 C10 C9 -156.79(18) . . . . ?
C11 Si2 C10 C9 81.8(2) . . . . ?
C15 Si2 C10 C9 -40.5(2) . . . . ?
C17 N2 C13 C14 -1.4(4) . . . . ?
Ag1 N2 C13 C14 173.6(2) 3_666 . . . ?
N2 C13 C14 C15 1.2(4) . . . . ?
C13 C14 C15 C16 -0.1(4) . . . . ?
C13 C14 C15 Si2 178.8(2) . . . . ?
C12 Si2 C15 C16 -131.0(2) . . . . ?
C11 Si2 C15 C16 -12.1(2) . . . . ?
C10 Si2 C15 C16 112.20(19) . . . . ?
C12 Si2 C15 C14 50.3(2) . . . . ?
C11 Si2 C15 C14 169.2(2) . . . . ?
C10 Si2 C15 C14 -66.5(2) . . . . ?
C14 C15 C16 C17 -0.7(3) . . . . ?
Si2 C15 C16 C17 -179.49(16) . . . . ?
C13 N2 C17 C16 0.6(3) . . . . ?
Ag1 N2 C17 C16 -174.31(16) 3_666 . . . ?
C15 C16 C17 N2 0.5(3) . . . . ?
O4A ClA O1A Ag1 -9(2) . . . 3_666 ?
O2A ClA O1A Ag1 101.0(5) . . . 3_666 ?
O3A ClA O1A Ag1 -137.5(7) . . . 3_666 ?

_refine_diff_density_max         0.929
_refine_diff_density_min         -0.501
_refine_diff_density_rms         0.067

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_PF6_exchanged_a
_database_code_depnum_ccdc_archive 'CCDC 2043993'
loop_
_audit_author_name
_audit_author_address
'Dongwon Kim'
;Pusan National University
South Korea
;
_audit_update_record             
;
2020-11-12 deposited with the CCDC.	2021-01-07 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C17 H26 Ag F6 N2 P Si2'
_chemical_formula_weight         567.42

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.6000(5)
_cell_length_b                   13.2029(6)
_cell_length_c                   14.6341(6)
_cell_angle_alpha                90
_cell_angle_beta                 101.204(2)
_cell_angle_gamma                90
_cell_volume                     2388.08(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    9846
_cell_measurement_theta_min      2.26
_cell_measurement_theta_max      28.27

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.578
_exptl_crystal_F_000             1144
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.180
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    1.064
_shelx_estimated_absorpt_T_min   0.832
_shelx_estimated_absorpt_T_max   0.892
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  0.6508
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_process_details   SADABS
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'CCD detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            50928
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.954
_diffrn_reflns_theta_max         28.392
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             5965
_reflns_number_gt                4443
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX software'
_computing_cell_refinement       'Bruker APEX software'
_computing_data_reduction        'Bruker APEX software'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  SHELXL
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0460P)²+4.2747P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5965
_refine_ls_number_parameters     266
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0627
_refine_ls_R_factor_gt           0.0427
_refine_ls_wR_factor_ref         0.1143
_refine_ls_wR_factor_gt          0.1018
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_restrained_S_all      1.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
N1 N 0.5533(2) 0.2605(2) 0.76496(18) 0.0375(6) Uani 1 1 d . . . . .
P1 P 0.75126(8) 0.52842(6) 0.92597(6) 0.0402(2) Uani 1 1 d . . . . .
F2 F 0.7561(2) 0.41906(17) 0.97057(17) 0.0661(7) Uani 1 1 d . . . . .
Si1 Si 0.17560(7) 0.25641(7) 0.65766(6) 0.03313(19) Uani 1 1 d . . . . .
C1 C 0.5043(3) 0.1926(3) 0.7024(2) 0.0448(8) Uani 1 1 d . . . . .
H1 H 0.547584 0.143332 0.679579 0.054 Uiso 1 1 calc R U . . .
Ag1 Ag 0.72316(2) 0.25344(2) 0.81356(2) 0.04253(10) Uani 1 1 d . . . . .
N2 N 0.6132(2) 0.7111(2) 0.63589(18) 0.0362(6) Uani 1 1 d . . . . .
F1 F 0.7480(5) 0.4764(2) 0.8295(2) 0.146(2) Uani 1 1 d . . . . .
C2 C 0.3943(3) 0.1910(3) 0.6700(2) 0.0409(7) Uani 1 1 d . . . . .
H2 H 0.363793 0.141664 0.625250 0.049 Uiso 1 1 calc R U . . .
Si2 Si 0.26756(7) 0.58678(6) 0.50335(6) 0.03014(18) Uani 1 1 d . . . . .
C3 C 0.3272(3) 0.2606(2) 0.7017(2) 0.0308(6) Uani 1 1 d . . . . .
F3 F 0.6276(2) 0.5260(3) 0.9036(4) 0.150(2) Uani 1 1 d . . . . .
C4 C 0.3786(2) 0.3308(2) 0.7670(2) 0.0341(6) Uani 1 1 d . . . . .
H4 H 0.336955 0.380326 0.791357 0.041 Uiso 1 1 calc R U . . .
F4 F 0.7549(3) 0.5809(2) 1.0214(2) 0.0944(10) Uani 1 1 d . . . . .
C5 C 0.4897(3) 0.3288(2) 0.7964(2) 0.0374(7) Uani 1 1 d . . . . .
H5 H 0.522471 0.377701 0.840624 0.045 Uiso 1 1 calc R U . . .
F5 F 0.7532(3) 0.63658(18) 0.8780(2) 0.0852(9) Uani 1 1 d . . . . .
C6 C 0.5809(3) 0.6197(3) 0.6591(2) 0.0389(7) Uani 1 1 d . . . . .
H6 H 0.628666 0.580962 0.704028 0.047 Uiso 1 1 calc R U . . .
F6 F 0.8778(2) 0.5311(3) 0.9468(3) 0.1123(13) Uani 1 1 d . . . . .
C7 C 0.4818(3) 0.5797(3) 0.6207(2) 0.0372(7) Uani 1 1 d . . . . .
H7 H 0.463105 0.514096 0.639045 0.045 Uiso 1 1 calc R U . . .
C8 C 0.4080(2) 0.6337(2) 0.5552(2) 0.0303(6) Uani 1 1 d . . . . .
C9 C 0.4435(3) 0.7288(3) 0.5326(3) 0.0407(8) Uani 1 1 d . . . . .
H9 H 0.397294 0.769709 0.488417 0.049 Uiso 1 1 calc R U . . .
C10 C 0.5442(3) 0.7644(3) 0.5731(3) 0.0416(8) Uani 1 1 d . . . . .
H10 H 0.565621 0.829549 0.555817 0.050 Uiso 1 1 calc R U . . .
C11 C 0.1690(3) 0.6611(3) 0.5548(3) 0.0463(8) Uani 1 1 d . . . . .
H11A H 0.095467 0.638065 0.528655 0.069 Uiso 1 1 calc R U . . .
H11B H 0.175816 0.733098 0.540566 0.069 Uiso 1 1 calc R U . . .
H11C H 0.183650 0.651591 0.622546 0.069 Uiso 1 1 calc R U . . .
C12 C 0.2426(3) 0.6074(3) 0.3754(2) 0.0461(8) Uani 1 1 d . . . . .
H12A H 0.179259 0.568042 0.345696 0.069 Uiso 1 1 calc R U . . .
H12B H 0.306006 0.585453 0.351015 0.069 Uiso 1 1 calc R U . . .
H12C H 0.229309 0.679488 0.361957 0.069 Uiso 1 1 calc R U . . .
C13 C 0.2600(2) 0.4505(2) 0.5354(2) 0.0343(6) Uani 1 1 d . . . . .
H13A H 0.312784 0.411937 0.507146 0.041 Uiso 1 1 calc R U . . .
H13B H 0.281858 0.444095 0.603917 0.041 Uiso 1 1 calc R U . . .
C14 C 0.1479(3) 0.4022(2) 0.5048(2) 0.0386(7) Uani 1 1 d . . . . .
H14A H 0.095131 0.439766 0.533981 0.046 Uiso 1 1 calc R U . . .
H14B H 0.125357 0.409227 0.436444 0.046 Uiso 1 1 calc R U . . .
C15 C 0.1442(3) 0.2900(2) 0.5306(2) 0.0357(7) Uani 1 1 d . . . . .
H15A H 0.195775 0.253123 0.499575 0.043 Uiso 1 1 calc R U . . .
H15B H 0.070936 0.264079 0.504113 0.043 Uiso 1 1 calc R U . . .
C16 C 0.1100(3) 0.3454(4) 0.7275(3) 0.0618(11) Uani 1 1 d . . . . .
H16A H 0.031190 0.338373 0.710059 0.093 Uiso 1 1 calc R U . . .
H16B H 0.130622 0.415027 0.715581 0.093 Uiso 1 1 calc R U . . .
H16C H 0.133367 0.329939 0.793888 0.093 Uiso 1 1 calc R U . . .
C17 C 0.1338(3) 0.1225(3) 0.6711(3) 0.0511(9) Uani 1 1 d . . . . .
H17A H 0.055007 0.116960 0.652374 0.077 Uiso 1 1 calc R U . . .
H17B H 0.156052 0.101845 0.736283 0.077 Uiso 1 1 calc R U . . .
H17C H 0.168389 0.078488 0.631547 0.077 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N1 C1 1.343(4) . ?
N1 C5 1.345(4) . ?
N1 Ag1 2.122(3) . ?
P1 F3 1.529(3) . ?
P1 F4 1.552(3) . ?
P1 F1 1.563(3) . ?
P1 F6 1.565(3) . ?
P1 F2 1.581(2) . ?
P1 F5 1.594(2) . ?
Si1 C16 1.855(4) . ?
Si1 C17 1.865(4) . ?
Si1 C15 1.877(3) . ?
Si1 C3 1.894(3) . ?
C1 C2 1.375(5) . ?
C1 H1 0.9500 . ?
Ag1 N2 2.126(3) 2_646 ?
Ag1 F1 2.964(3) . ?
Ag1 Ag1 6.9272(3) 2_656 ?
N2 C10 1.335(4) . ?
N2 C6 1.338(4) . ?
C2 C3 1.389(5) . ?
C2 H2 0.9500 . ?
Si2 C11 1.854(4) . ?
Si2 C12 1.857(3) . ?
Si2 C13 1.867(3) . ?
Si2 C8 1.889(3) . ?
C3 C4 1.397(4) . ?
C4 C5 1.382(4) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 C7 1.372(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.395(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.394(4) . ?
C9 C10 1.376(5) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.535(4) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.532(4) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 N1 C5 117.1(3) . . ?
C1 N1 Ag1 119.9(2) . . ?
C5 N1 Ag1 123.0(2) . . ?
F3 P1 F4 93.0(3) . . ?
F3 P1 F1 87.2(3) . . ?
F4 P1 F1 179.5(2) . . ?
F3 P1 F6 178.9(3) . . ?
F4 P1 F6 87.9(2) . . ?
F1 P1 F6 91.9(3) . . ?
F3 P1 F2 91.43(18) . . ?
F4 P1 F2 92.52(16) . . ?
F1 P1 F2 87.92(16) . . ?
F6 P1 F2 89.12(17) . . ?
F3 P1 F5 91.5(2) . . ?
F4 P1 F5 89.81(17) . . ?
F1 P1 F5 89.75(17) . . ?
F6 P1 F5 87.87(18) . . ?
F2 P1 F5 176.13(18) . . ?
C16 Si1 C17 112.2(2) . . ?
C16 Si1 C15 111.45(18) . . ?
C17 Si1 C15 108.55(16) . . ?
C16 Si1 C3 108.78(17) . . ?
C17 Si1 C3 106.19(16) . . ?
C15 Si1 C3 109.55(14) . . ?
N1 C1 C2 123.0(3) . . ?
N1 C1 H1 118.5 . . ?
C2 C1 H1 118.5 . . ?
N1 Ag1 N2 167.21(11) . 2_646 ?
N1 Ag1 F1 93.82(13) . . ?
N2 Ag1 F1 98.81(13) 2_646 . ?
N1 Ag1 Ag1 90.73(7) . 2_656 ?
N2 Ag1 Ag1 101.83(8) 2_646 2_656 ?
F1 Ag1 Ag1 20.04(6) . 2_656 ?
C10 N2 C6 117.5(3) . . ?
C10 N2 Ag1 123.9(2) . 2_656 ?
C6 N2 Ag1 118.1(2) . 2_656 ?
P1 F1 Ag1 119.42(16) . . ?
C1 C2 C3 120.9(3) . . ?
C1 C2 H2 119.6 . . ?
C3 C2 H2 119.6 . . ?
C11 Si2 C12 109.67(18) . . ?
C11 Si2 C13 109.71(16) . . ?
C12 Si2 C13 112.81(16) . . ?
C11 Si2 C8 108.19(15) . . ?
C12 Si2 C8 108.59(15) . . ?
C13 Si2 C8 107.73(13) . . ?
C2 C3 C4 115.9(3) . . ?
C2 C3 Si1 120.4(2) . . ?
C4 C3 Si1 123.7(2) . . ?
C5 C4 C3 120.5(3) . . ?
C5 C4 H4 119.8 . . ?
C3 C4 H4 119.8 . . ?
N1 C5 C4 122.8(3) . . ?
N1 C5 H5 118.6 . . ?
C4 C5 H5 118.6 . . ?
N2 C6 C7 122.7(3) . . ?
N2 C6 H6 118.6 . . ?
C7 C6 H6 118.6 . . ?
C6 C7 C8 121.1(3) . . ?
C6 C7 H7 119.4 . . ?
C8 C7 H7 119.4 . . ?
C9 C8 C7 114.9(3) . . ?
C9 C8 Si2 121.3(2) . . ?
C7 C8 Si2 123.8(2) . . ?
C10 C9 C8 121.2(3) . . ?
C10 C9 H9 119.4 . . ?
C8 C9 H9 119.4 . . ?
N2 C10 C9 122.6(3) . . ?
N2 C10 H10 118.7 . . ?
C9 C10 H10 118.7 . . ?
Si2 C11 H11A 109.5 . . ?
Si2 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
Si2 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si2 C12 H12A 109.5 . . ?
Si2 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
Si2 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C13 Si2 114.6(2) . . ?
C14 C13 H13A 108.6 . . ?
Si2 C13 H13A 108.6 . . ?
C14 C13 H13B 108.6 . . ?
Si2 C13 H13B 108.6 . . ?
H13A C13 H13B 107.6 . . ?
C15 C14 C13 113.6(3) . . ?
C15 C14 H14A 108.8 . . ?
C13 C14 H14A 108.8 . . ?
C15 C14 H14B 108.8 . . ?
C13 C14 H14B 108.8 . . ?
H14A C14 H14B 107.7 . . ?
C14 C15 Si1 117.5(2) . . ?
C14 C15 H15A 107.9 . . ?
Si1 C15 H15A 107.9 . . ?
C14 C15 H15B 107.9 . . ?
Si1 C15 H15B 107.9 . . ?
H15A C15 H15B 107.2 . . ?
Si1 C16 H16A 109.5 . . ?
Si1 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Si1 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
Si1 C17 H17A 109.5 . . ?
Si1 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
Si1 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.4(5) . . . . ?
Ag1 N1 C1 C2 178.1(3) . . . . ?
F3 P1 F1 Ag1 -83.3(3) . . . . ?
F6 P1 F1 Ag1 97.2(3) . . . . ?
F2 P1 F1 Ag1 8.2(3) . . . . ?
F5 P1 F1 Ag1 -174.9(3) . . . . ?
N1 C1 C2 C3 -0.6(6) . . . . ?
C1 C2 C3 C4 0.3(5) . . . . ?
C1 C2 C3 Si1 -179.1(3) . . . . ?
C16 Si1 C3 C2 171.1(3) . . . . ?
C17 Si1 C3 C2 50.2(3) . . . . ?
C15 Si1 C3 C2 -66.9(3) . . . . ?
C16 Si1 C3 C4 -8.3(3) . . . . ?
C17 Si1 C3 C4 -129.2(3) . . . . ?
C15 Si1 C3 C4 113.7(3) . . . . ?
C2 C3 C4 C5 0.1(4) . . . . ?
Si1 C3 C4 C5 179.5(2) . . . . ?
C1 N1 C5 C4 0.0(5) . . . . ?
Ag1 N1 C5 C4 -177.6(2) . . . . ?
C3 C4 C5 N1 -0.3(5) . . . . ?
C10 N2 C6 C7 0.5(5) . . . . ?
Ag1 N2 C6 C7 -171.3(3) 2_656 . . . ?
N2 C6 C7 C8 -0.7(5) . . . . ?
C6 C7 C8 C9 0.4(5) . . . . ?
C6 C7 C8 Si2 -177.0(3) . . . . ?
C11 Si2 C8 C9 -70.5(3) . . . . ?
C12 Si2 C8 C9 48.5(3) . . . . ?
C13 Si2 C8 C9 171.0(3) . . . . ?
C11 Si2 C8 C7 106.7(3) . . . . ?
C12 Si2 C8 C7 -134.3(3) . . . . ?
C13 Si2 C8 C7 -11.8(3) . . . . ?
C7 C8 C9 C10 0.0(5) . . . . ?
Si2 C8 C9 C10 177.5(3) . . . . ?
C6 N2 C10 C9 -0.1(5) . . . . ?
Ag1 N2 C10 C9 171.2(3) 2_656 . . . ?
C8 C9 C10 N2 -0.2(6) . . . . ?
C11 Si2 C13 C14 58.1(3) . . . . ?
C12 Si2 C13 C14 -64.5(3) . . . . ?
C8 Si2 C13 C14 175.6(2) . . . . ?
Si2 C13 C14 C15 179.1(2) . . . . ?
C13 C14 C15 Si1 62.1(4) . . . . ?
C16 Si1 C15 C14 42.6(3) . . . . ?
C17 Si1 C15 C14 166.6(3) . . . . ?
C3 Si1 C15 C14 -77.8(3) . . . . ?

_refine_diff_density_max         0.812
_refine_diff_density_min         -0.602
_refine_diff_density_rms         0.084

