Supplementary data for Symmetry breaking of the bending mode of CO2 in the presence of Ar T.A. Gartner, A.J. Barclay, A.R.W. McKellar, and N. Moazzen-Ahmadi 1 Department of Physics and Astronomy, University of Calgary, 2500 University Drive North West, Calgary, Alberta T2N 1N4, Canada 2 National Research Council of Canada, Ottawa, Ontario K1A 0R6, Canada Observed transitions for (011) <--- (010) bending bands of CO2-Ar (units of 1/cm) ********************************************************************************* v' J' Ka' Kc' v" J" Ka" Kc" Observed Calculated Obs-Calc ********************************************************************************* v=1 3 1 2 v=0 4 2 3 2334.3361 2334.3362 -0.0001 v=1 8 1 7 v=0o-p 9 1 9 2334.3964 2334.3968 -0.0004 v=1 7 1 7 v=0 8 2 6 2334.4078 2334.4076 0.0002 v=1o-p 5 2 4 v=0o-p 5 3 3 2334.4176 2334.4174 0.0002 v=1o-p 4 2 3 v=0o-p 4 3 2 2334.4380 2334.4382 -0.0003 v=1o-p 3 2 1 v=0o-p 3 3 0 2334.4601 2334.4600 0.0001 v=1 7 1 6 v=0o-p 8 1 8 2334.4934 2334.4937 -0.0003 v=1 8 1 8 v=0 8 2 7 2334.5311 2334.5307 0.0004 v=1 6 1 6 v=0 7 2 5 2334.5372 2334.5372 0.0000 v=1 2 1 2 v=0 3 2 1 2334.5691 2334.5690 0.0001 v=1 2 1 1 v=0 3 2 2 2334.5732 2334.5731 0.0001 v=1 6 1 5 v=0o-p 7 1 7 2334.5950 2334.5951 -0.0000 v=1 7 1 7 v=0 7 2 6 2334.6160 2334.6163 -0.0003 v=1o-p 8 0 8 v=0 9 2 8 2334.6286 2334.6286 -0.0001 v=1 4 1 3 v=0o-p 4 1 3 2334.6415 2334.6415 -0.0000 v=1 5 1 5 v=0 6 2 4 2334.6617 2334.6617 -0.0000 v=1 5 1 4 v=0o-p 6 1 6 2334.7002 2334.7001 0.0001 v=1o-p 7 0 7 v=0 8 2 7 2334.7527 2334.7531 -0.0004 v=1 4 1 4 v=0 5 2 3 2334.7802 2334.7803 -0.0001 v=1 5 1 5 v=0 5 2 4 2334.7914 2334.7913 0.0000 v=1 3 1 2 v=0 3 2 1 2334.8140 2334.8137 0.0003 v=1o-p 6 0 6 v=0 7 2 6 2334.8665 2334.8664 0.0000 v=1 4 1 4 v=0 4 2 3 2334.8792 2334.8791 0.0001 v=1 3 1 3 v=0 4 2 2 2334.8919 2334.8919 -0.0001 v=1 3 1 2 v=0o-p 4 1 4 2334.9155 2334.9155 -0.0000 v=1 3 1 3 v=0 3 2 2 2334.9662 2334.9662 -0.0000 v=1 2 1 2 v=0o-p 3 1 2 2334.9946 2334.9945 0.0001 v=1 2 1 1 v=0o-p 3 1 3 2335.0195 2335.0196 -0.0000 v=1o-p 4 0 4 v=0 5 2 4 2335.0707 2335.0706 0.0001 v=1 1 1 1 v=0o-p 2 1 1 2335.0848 2335.0848 -0.0000 v=1 1 1 0 v=0o-p 2 1 2 2335.1122 2335.1122 0.0000 v=1 9 1 8 v=0 9 2 7 2335.1230 2335.1228 0.0001 v=1 8 1 7 v=0 8 2 6 2335.1337 2335.1335 0.0002 v=1 7 1 6 v=0 7 2 5 2335.1490 2335.1487 0.0003 v=1 6 1 5 v=0 6 2 4 2335.1683 2335.1683 -0.0000 v=1o-p 3 0 3 v=0 4 2 3 2335.1715 2335.1714 0.0001 v=1 5 1 4 v=0 5 2 3 2335.1913 2335.1915 -0.0002 v=1 4 1 3 v=0 4 2 2 2335.2162 2335.2163 -0.0001 v=1 3 1 2 v=0o-p 3 1 2 2335.2391 2335.2393 -0.0002 v=1 2 1 1 v=0o-p 2 1 1 2335.2537 2335.2537 -0.0000 v=1o-p 2 0 2 v=0 3 2 2 2335.2805 2335.2803 0.0001 v=1o-p 8 0 8 v=0o-p 8 1 7 2335.2844 2335.2843 0.0001 v=1 2 1 2 v=0o-p 2 1 2 2335.3586 2335.3585 0.0000 v=1o-p 7 0 7 v=0o-p 7 1 6 2335.3968 2335.3969 -0.0001 v=1o-p 1 0 1 v=0 2 2 1 2335.4075 2335.4072 0.0002 v=1 3 1 3 v=0o-p 3 1 3 2335.4126 2335.4127 -0.0001 v=1 4 1 4 v=0o-p 4 1 4 2335.4585 2335.4585 0.0000 v=1o-p 6 0 6 v=0o-p 6 1 5 2335.4883 2335.4882 0.0000 v=1 5 1 5 v=0o-p 5 1 5 2335.4974 2335.4974 0.0000 v=1 8 1 8 v=0 9 0 9 2335.5139 2335.5139 -0.0001 v=1 6 1 6 v=0o-p 6 1 6 2335.5301 2335.5302 -0.0001 v=1o-p 5 0 5 v=0o-p 5 1 4 2335.5583 2335.5585 -0.0002 v=1 7 1 7 v=0o-p 7 1 7 2335.5583 2335.5576 0.0007 v=1 8 1 8 v=0o-p 8 1 8 2335.5799 2335.5799 0.0000 v=1 3 1 2 v=0o-p 2 1 2 2335.6034 2335.6033 0.0001 v=1o-p 4 0 4 v=0o-p 4 1 3 2335.6105 2335.6105 0.0001 v=1 7 1 7 v=0 8 0 8 2335.6398 2335.6396 0.0001 v=1o-p 3 0 3 v=0 3 2 1 2335.6489 2335.6489 0.0000 v=1o-p 2 0 2 v=0 2 2 0 2335.6812 2335.6812 0.0000 v=1o-p 2 0 2 v=0o-p 3 1 3 2335.7267 2335.7268 -0.0001 v=1 4 1 3 v=0o-p 3 1 3 2335.7370 2335.7371 -0.0001 v=1 6 1 6 v=0 7 0 7 2335.7597 2335.7598 -0.0001 v=1o-p 4 0 4 v=0o-p 5 1 5 2335.7766 2335.7767 -0.0001 v=1 4 1 4 v=0o-p 3 1 2 2335.7818 2335.7822 -0.0004 v=1o-p 5 0 5 v=0o-p 6 1 6 2335.7978 2335.7976 0.0002 v=1o-p 7 0 7 v=0o-p 8 1 8 2335.8025 2335.8023 0.0002 v=1o-p 6 0 6 v=0o-p 7 1 7 2335.8077 2335.8077 0.0000 v=1o-p 1 0 1 v=0o-p 1 1 0 2335.8441 2335.8444 -0.0003 v=1 5 1 4 v=0o-p 4 1 4 2335.8698 2335.8696 0.0001 v=1 5 1 5 v=0 6 0 6 2335.8747 2335.8745 0.0001 v=1 5 1 5 v=0 4 2 2 2335.9058 2335.9060 -0.0002 v=1o-p 2 0 2 v=0o-p 2 1 1 2335.9606 2335.9610 -0.0004 v=1 4 1 4 v=0 5 0 5 2335.9842 2335.9843 -0.0001 v=1 6 1 5 v=0o-p 5 1 5 2336.0037 2336.0040 -0.0003 v=1 6 1 6 v=0 5 2 3 2336.0212 2336.0216 -0.0004 v=1o-p 3 0 3 v=0o-p 3 1 2 2336.0744 2336.0745 -0.0001 v=1 3 1 3 v=0 4 0 4 2336.0901 2336.0901 -0.0000 v=1 7 1 6 v=0o-p 6 1 6 2336.1418 2336.1417 0.0000 v=1o-p 4 0 4 v=0 4 2 2 2336.1858 2336.1853 0.0005 v=1 2 1 2 v=0 3 0 3 2336.1935 2336.1934 0.0001 v=1o-p 8 2 6 v=0o-p 8 1 7 2336.2515 2336.2512 0.0003 v=1o-p 4 0 4 v=0 3 2 2 2336.2598 2336.2595 0.0003 v=1 8 1 7 v=0o-p 7 1 7 2336.2833 2336.2834 -0.0001 v=1o-p 5 0 5 v=0 5 2 3 2336.2887 2336.2889 -0.0003 v=1 1 1 1 v=0 2 0 2 2336.2962 2336.2960 0.0002 v=1 9 1 9 v=0 8 2 6 2336.3345 2336.3344 0.0001 v=1o-p 7 2 5 v=0o-p 7 1 6 2336.3566 2336.3569 -0.0003 v=1 7 1 6 v=0 7 0 7 2336.3714 2336.3713 0.0001 v=1 6 1 5 v=0 6 0 6 2336.3813 2336.3812 0.0001 v=1o-p 5 0 5 v=0 4 2 3 2336.3879 2336.3877 0.0002 v=1 5 1 4 v=0 5 0 5 2336.3956 2336.3955 0.0001 v=1 4 1 3 v=0 4 0 4 2336.4145 2336.4145 0.0000 v=1 9 1 8 v=0o-p 8 1 8 2336.4296 2336.4294 0.0002 v=1 3 1 2 v=0 3 0 3 2336.4381 2336.4381 0.0000 v=1 2 1 1 v=0 2 0 2 2336.4649 2336.4649 -0.0000 v=1o-p 6 2 4 v=0o-p 6 1 5 2336.4707 2336.4707 -0.0001 v=1 1 1 0 v=0 1 0 1 2336.4906 2336.4907 -0.0000 v=1o-p 6 0 6 v=0 5 2 4 2336.5108 2336.5106 0.0003 v=1o-p 5 2 3 v=0o-p 5 1 4 2336.5899 2336.5901 -0.0001 v=1 1 1 1 v=0 0 0 0 2336.6203 2336.6199 0.0004 v=1o-p 4 0 4 v=0o-p 3 1 3 2336.7060 2336.7060 0.0000 v=1o-p 4 2 2 v=0o-p 4 1 3 2336.7106 2336.7107 -0.0002 v=1o-p 8 0 8 v=0 7 2 6 2336.7245 2336.7244 0.0000 v=1 2 1 2 v=0 1 0 1 2336.7369 2336.7370 -0.0002 v=1o-p 3 2 2 v=0 4 2 2 2336.8082 2336.8087 -0.0006 v=1o-p 9 0 9 v=0 8 2 7 2336.8131 2336.8137 -0.0007 v=1o-p 3 2 1 v=0 3 2 1 2336.8282 2336.8280 0.0002 v=1 3 1 3 v=0 2 0 2 2336.8578 2336.8580 -0.0002 v=1o-p 4 2 2 v=0o-p 5 1 5 2336.8768 2336.8770 -0.0001 v=1o-p 3 2 2 v=0 3 2 2 2336.8830 2336.8830 -0.0000 v=1o-p 3 2 1 v=0o-p 4 1 4 2336.9300 2336.9299 0.0001 v=1o-p 2 2 0 v=0 2 2 0 2336.9384 2336.9385 -0.0000 v=1o-p 2 2 1 v=0 2 2 1 2336.9603 2336.9605 -0.0002 v=1o-p 5 0 5 v=0o-p 4 1 4 2336.9670 2336.9671 -0.0001 v=1 4 1 4 v=0 3 0 3 2336.9808 2336.9811 -0.0002 v=1 5 1 5 v=0 4 0 4 2337.1042 2337.1042 0.0000 v=1o-p 2 0 2 v=0 2 0 2 2337.1719 2337.1721 -0.0002 v=1 6 1 6 v=0 5 0 5 2337.2256 2337.2256 0.0000 v=1o-p 3 2 1 v=0o-p 3 1 2 2337.2536 2337.2536 -0.0000 v=1o-p 2 2 1 v=0o-p 2 1 2 2337.2665 2337.2663 0.0002 v=1o-p 4 2 2 v=0 4 2 2 2337.2855 2337.2856 -0.0001 v=1o-p 5 2 3 v=0 5 2 3 2337.3205 2337.3205 0.0000 v=1o-p 3 2 2 v=0o-p 3 1 3 2337.3297 2337.3295 0.0002 v=1 7 1 7 v=0 6 0 6 2337.3437 2337.3437 0.0000 v=1o-p 6 2 4 v=0 6 2 4 2337.3633 2337.3634 -0.0001 v=1o-p 4 0 4 v=0 4 0 4 2337.3836 2337.3835 0.0001 v=1o-p 4 2 3 v=0o-p 4 1 4 2337.3875 2337.3873 0.0002 v=1 7 3 4 v=0o-p 7 1 6 2337.3926 2337.3924 0.0002 v=1o-p 2 2 1 v=0o-p 1 1 0 2337.3976 2337.3976 0.0000 v=1o-p 7 2 5 v=0 7 2 5 2337.4171 2337.4173 -0.0002 v=1o-p 2 2 0 v=0o-p 1 1 1 2337.4231 2337.4230 0.0001 v=1o-p 5 2 4 v=0o-p 5 1 5 2337.4414 2337.4413 0.0001 v=1o-p 7 0 7 v=0o-p 6 1 6 2337.4505 2337.4503 0.0002 v=1 8 1 8 v=0 7 0 7 2337.4574 2337.4575 -0.0001 v=1o-p 8 2 6 v=0 8 2 6 2337.4828 2337.4827 0.0001 v=1o-p 6 2 5 v=0o-p 6 1 6 2337.4926 2337.4921 0.0004 v=1 5 3 2 v=0o-p 5 1 4 2337.5224 2337.5224 0.0000 v=1o-p 7 2 6 v=0o-p 7 1 7 2337.5404 2337.5403 0.0001 v=1o-p 9 2 7 v=0 9 2 7 2337.5575 2337.5575 0.0000 v=1o-p 3 2 2 v=0o-p 2 1 1 2337.5640 2337.5636 0.0004 v=1o-p 8 2 7 v=0o-p 8 1 8 2337.5863 2337.5861 0.0002 v=1 4 3 1 - o-p 4 1 3 2337.5918 2337.5915 0.0003 v=1o-p 3 2 1 v=0o-p 2 1 2 2337.6178 2337.6176 0.0002 v=1o-p 9 2 8 v=0o-p 9 1 9 2337.6299 2337.6300 -0.0001 v=1 10 1 10 v=0 9 0 9 2337.6701 2337.6702 -0.0001 v=1 5 3 3 v=0 5 2 4 2337.6968 2337.6970 -0.0002 v=1o-p 4 2 3 v=0o-p 3 1 2 2337.7108 2337.7111 -0.0003 v=1 11 1 11 v=0 10 0 10 2337.7686 2337.7689 -0.0002 v=1o-p 4 2 2 v=0o-p 3 1 3 2337.8062 2337.8063 -0.0001 v=1o-p 5 2 4 v=0 4 2 2 2337.8498 2337.8499 -0.0001 v=1o-p 9 0 9 v=0o-p 8 1 8 2337.8629 2337.8629 0.0000 v=1o-p 6 2 5 v=0 5 2 3 2337.9834 2337.9835 -0.0001 v=1o-p 5 2 3 v=0o-p 4 1 4 2337.9987 2337.9987 0.0000 v=1o-p 10 0 10 v=0o-p 9 1 9 2338.0445 2338.0443 0.0002 v=1 3 3 0 v=0o-p 3 1 2 2338.0863 2338.0865 -0.0002 v=1o-p 7 2 6 v=0 6 2 4 2338.1135 2338.1135 -0.0000 v=1 3 3 1 v=0 2 2 0 2338.1217 2338.1215 0.0002 v=1 3 3 0 v=0 2 2 1 2338.1449 2338.1447 0.0002 v=1o-p 6 2 4 v=0o-p 5 1 5 2338.1992 2338.1991 0.0001 v=1 5 3 3 v=0o-p 4 1 3 2338.2367 2338.2368 -0.0001 v=1 5 3 2 v=0 5 2 3 2338.2527 2338.2528 -0.0002 v=1 4 3 2 v=0o-p 4 1 4 2338.2813 2338.2816 -0.0003 v=1 6 3 4 v=0o-p 5 1 4 2338.2912 2338.2914 -0.0002 v=1 7 3 5 v=0o-p 6 1 5 2338.3436 2338.3435 0.0001 v=1 6 3 3 v=0 6 2 4 2338.3475 2338.3478 -0.0004 v=1 5 3 2 v=0 4 2 3 2338.3517 2338.3516 0.0000 v=1o-p 9 2 8 v=0 8 2 6 2338.3670 2338.3667 0.0003 v=1 8 3 6 v=0o-p 7 1 6 2338.3937 2338.3938 -0.0001 v=1 3 3 1 v=0o-p 2 1 1 2338.4014 2338.4013 0.0001 v=1o-p 7 2 5 v=0o-p 6 1 6 2338.4100 2338.4103 -0.0003 v=1 3 3 0 v=0o-p 2 1 2 2338.4506 2338.4505 0.0001 v=1 6 3 3 v=0 5 2 4 2338.4778 2338.4775 0.0003 v=1 4 3 2 v=0o-p 3 1 2 2338.6054 2338.6054 0.0000 v=1 7 3 4 v=0 6 2 5 2338.6189 2338.6191 -0.0001 v=1o-p 8 2 6 v=0o-p 7 1 7 2338.6323 2338.6326 -0.0004 v=1 4 3 1 v=0o-p 3 1 3 2338.6872 2338.6871 0.0001 v=1 8 3 5 v=0 7 2 6 2338.7780 2338.7778 0.0002 v=1 5 3 3 v=0 4 2 2 2338.8115 2338.8116 -0.0001