File Name : figure_s1.png Caption : atoms numeration to structures na–1–i and na–1–i + 127 ch2cl2. atoms color: sodium (purple); carbon (gray); oxygen (red); nitrogen (blue); and iodine (pink). File Name : figure_s2.png Caption : selected density flow channels: δρ2–6 and 8–10 for na+….1–i–, with their respective energy, δeoi,k, and charge transfer estimation, δqk. red and blue regions indicate the electronic density outflow and inflow, respectively. the isovalues used to represent these surfaces are equal to: * = 0.0010 and ө = 0.0005 a.u. File Name : figure_s3.png Caption : selected density flow channels: δρ1–10 for li+….2–i–, with their respective energy, δeoi,k, and charge transfer estimation, δqk. red and blue regions indicate the electronic density outflow and inflow, respectively. the isovalues used to represent these surfaces are equal to: * = 0.0010; ө = 0.0005; ֆ = 0.0003 and ժ = 0.0002 a.u. File Name : figure_s4.png Caption : selected density deformation channels surface plots: δρ1–10 for k+….3–i–, with their respective energy, δeoi,k, and charge transfer estimation, δqk. red and blue regions indicate the electronic density outflow and inflow, respectively. the isovalues used to represent these surfaces are equal to: * = 0.0010; ө = 0.0005; ֆ = 0.0003 and ժ = 0.0002 a.u. File Name : figure_s5.png Caption : selected density flow channels: δρ1–9,11 and 12 for na+….6–i–, with their respective energy, δeoi,k, and charge transfer estimation, δqk. red and blue regions indicate the electronic density outflow and inflow, respectively. the isovalues used to represent these surfaces are equal to: * = 0.0010; ө = 0.0005; ֆ = 0.0003 and ժ = 0.0002 a.u. File Name : figure_s6.png Caption : selected density flow channels: δρ1, 2 and 4–10 for na+….7–i–, with their respective energy, δeoi,k, and charge transfer estimation, δqk. red and blue regions indicate the electronic density outflow and inflow, respectively. the isovalues used to represent these surfaces are equal to: * = 0.0010; ө = 0.0005 and ֆ = 0.0003 a.u. File Name : figure_s7.png Caption : selected density flow channels: δρ1 for na–4+….f–, na–5+….cl–, na–6+….i– and na–7+….i–, with their respective energy, δeoi,k, and charge transfer estimation, δqk. red and blue regions indicate the electronic density outflow and inflow, respectively. the isovalue used to represent these surfaces is equal to 0.0010 a.u. File Name : figure_s8.png Caption : different perspective (top, bottom and lateral) of nci interactions in: na–1–i, li–2–i, k–3–i and na–4–f. red, blue and green surfaces represent repulsive, attractive and dispersion interactions, respectively. File Name : figure_s9.png Caption : different perspective (top, bottom and lateral) of nci interactions in: na–5–cl, na–6–i, and na–7–i. red, blue and green surfaces represent repulsive, attractive and dispersion interactions, respectively.