# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_w1_sq
_database_code_depnum_ccdc_archive 'CCDC 1990100'
loop_
_audit_author_name
_audit_author_address
'Qiao-Hua Wei'
;College of Chemistry, Fuzhou University
China
;
_audit_update_record             
;
2020-03-13 deposited with the CCDC.	2020-05-08 downloaded from the CCDC.
;
_audit_creation_date             2018-09-08
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         
'0.5(C332 H228 Ag8 N4 P8 Pt8), 2(C H2 Cl2), C4 H10 O'
_chemical_formula_sum            'C172 H128 Ag4 Cl4 N2 O P4 Pt4'
_chemical_formula_weight         3716.28
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   24.901(5)
_cell_length_b                   24.480(5)
_cell_length_c                   26.342(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     16057(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    2019
_cell_measurement_temperature    193.15
_cell_measurement_theta_max      22
_cell_measurement_theta_min      2
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    4.103
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.537
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             7240
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0636
_diffrn_reflns_av_unetI/netI     0.0389
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            58954
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.372
_diffrn_reflns_theta_min         1.636
_diffrn_ambient_temperature      193.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_special_details          ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15920
_reflns_number_total             16416
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         4.535
_refine_diff_density_min         -3.143
_refine_diff_density_rms         0.209
_refine_ls_extinction_coef       0.00135(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.185
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     899
_refine_ls_number_reflns         16416
_refine_ls_number_restraints     106
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0618
_refine_ls_restrained_S_all      1.396
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0426P)²+325.0608P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1657
_refine_ls_wR_factor_ref         0.1664
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C12) \\sim Ueq, Uanis(C18) \\sim Ueq, Uanis(C69) \\sim Ueq, Uanis(C16)
\\sim Ueq, Uanis(C71) \\sim Ueq, Uanis(C201) \\sim Ueq, Uanis(C13) \\sim Ueq:
with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(N1) \\sim Ueq, Uanis(C63) \\sim Ueq, Uanis(C62) \\sim Ueq: with sigma of
0.005 and sigma for terminal atoms of 0.01
Uanis(C47) \\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C25) \\sim Ueq: with sigma of
0.01 and sigma for terminal atoms of 0.02
Uanis(Ag2) \\sim Ueq: with sigma of 0.0005 and sigma for terminal atoms of
0.0005
3. Rigid body (RIGU) restrains
 C23, C24, C26, C25
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 Pt1, Ag2, Pt2
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4. Others
 Sof(H46A)=Sof(C44A)=Sof(H44A)=Sof(C45A)=Sof(H45A)=Sof(C47A)=Sof(H47A)=
 Sof(C48A)=Sof(H48A)=1-FVAR(1)
 Sof(C44)=Sof(H44)=Sof(C45)=Sof(H45)=Sof(H46)=Sof(C47)=Sof(H47)=Sof(C48)=
 Sof(H48)=FVAR(1)
 Fixed Sof: O1(0.5) C01(0.5) H01A(0.5) H01B(0.5) H01C(0.5) C02(0.5) H02A(0.5)
 H02B(0.5) C03(0.5) H03A(0.5) H03B(0.5) C04(0.5) H04A(0.5) H04B(0.5) H04C(0.5)
5.a Secondary CH2 refined with riding coordinates:
 C05(H05A,H05B), C02(H02A,H02B), C03(H03A,H03B)
5.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C14(H14), C15(H15), C16(H16),
 C17(H17), C18(H18), C24(H24), C25(H25), C26(H26), C27(H27), C28(H28), C34(H34),
  C35(H35), C36(H36), C37(H37), C38(H38), C44(H44), C45(H45), C46(H46),
 C46(H46A), C47(H47), C48(H48), C44A(H44A), C45A(H45A), C47A(H47A), C48A(H48A),
 C54(H54), C55(H55), C56(H56), C57(H57), C58(H58), C62(H62), C64(H64), C66(H66),
  C67(H67), C69(H69), C70(H70), C71(H71), C102(H102), C103(H103), C104(H104),
 C105(H105), C106(H106), C112(H112), C113(H113), C114(H114), C115(H115),
 C116(H116), C202(H202), C203(H203), C204(H204), C205(H205), C206(H206),
 C212(H212), C213(H213), C214(H214), C215(H215), C216(H216)
5.c Fitted hexagon refined as free rotating group:
 C43(C44,C45,C46,C47,C48), C61(C62,C63,C64,C65,C66)
5.d Idealised Me refined as rotating group:
 C01(H01A,H01B,H01C), C04(H04A,H04B,H04C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.67097(2) 0.28359(2) 0.44516(2) 0.02326(12) Uani 1 1 d . U . . .
Pt2 Pt 0.49213(2) 0.24833(2) 0.43326(2) 0.02156(11) Uani 1 1 d . U . . .
Ag1 Ag 0.55828(3) 0.33764(3) 0.47182(3) 0.0361(2) Uani 1 1 d . . . . .
Ag2 Ag 0.59265(3) 0.24948(3) 0.36966(2) 0.03290(19) Uani 1 1 d . U . . .
P1 P 0.48544(9) 0.20480(10) 0.51068(7) 0.0217(4) Uani 1 1 d . . . . .
P2 P 0.70086(9) 0.21580(10) 0.49854(8) 0.0228(5) Uani 1 1 d . . . . .
N1 N 0.6005(3) 0.2388(3) 0.7837(2) 0.0225(15) Uani 1 1 d . U . . .
C1 C 0.6433(4) 0.3237(4) 0.5068(3) 0.0283(19) Uani 1 1 d . . . . .
C2 C 0.6230(4) 0.3447(4) 0.5442(3) 0.0267(19) Uani 1 1 d . . . . .
C3 C 0.6086(4) 0.3658(4) 0.5937(3) 0.031(2) Uani 1 1 d . . . . .
C4 C 0.5591(5) 0.3893(5) 0.6015(4) 0.040(2) Uani 1 1 d . . . . .
H4 H 0.534332 0.392083 0.574208 0.048 Uiso 1 1 calc R . . . .
C5 C 0.5454(5) 0.4090(5) 0.6493(4) 0.048(3) Uani 1 1 d . . . . .
H5 H 0.511469 0.425809 0.654490 0.057 Uiso 1 1 calc R . . . .
C6 C 0.5813(5) 0.4041(5) 0.6895(4) 0.046(3) Uani 1 1 d . . . . .
H6 H 0.571706 0.416739 0.722334 0.056 Uiso 1 1 calc R . . . .
C7 C 0.6303(5) 0.3811(5) 0.6815(4) 0.045(3) Uani 1 1 d . . . . .
H7 H 0.655060 0.378356 0.708779 0.054 Uiso 1 1 calc R . . . .
C8 C 0.6445(5) 0.3616(5) 0.6338(4) 0.039(2) Uani 1 1 d . . . . .
H8 H 0.678764 0.345353 0.628681 0.047 Uiso 1 1 calc R . . . .
C11 C 0.7000(4) 0.2475(4) 0.3825(3) 0.028(2) Uani 1 1 d . . . . .
C12 C 0.7202(4) 0.2300(5) 0.3447(3) 0.032(2) Uani 1 1 d . U . . .
C13 C 0.7416(4) 0.2089(6) 0.2978(4) 0.042(3) Uani 1 1 d . U . . .
C14 C 0.7501(5) 0.1541(7) 0.2920(5) 0.064(4) Uani 1 1 d . . . . .
H14 H 0.743269 0.129586 0.319284 0.077 Uiso 1 1 calc R . . . .
C15 C 0.7693(6) 0.1343(9) 0.2448(6) 0.082(6) Uani 1 1 d . . . . .
H15 H 0.776023 0.096421 0.240304 0.099 Uiso 1 1 calc R . . . .
C16 C 0.7781(7) 0.1707(8) 0.2051(6) 0.072(4) Uani 1 1 d . U . . .
H16 H 0.789953 0.156734 0.173328 0.087 Uiso 1 1 calc R . . . .
C17 C 0.7705(5) 0.2247(10) 0.2099(5) 0.086(7) Uani 1 1 d . . . . .
H17 H 0.777040 0.248965 0.182492 0.103 Uiso 1 1 calc R . . . .
C18 C 0.7522(5) 0.2442(6) 0.2580(4) 0.050(3) Uani 1 1 d . U . . .
H18 H 0.747278 0.282316 0.262766 0.060 Uiso 1 1 calc R . . . .
C21 C 0.6347(4) 0.3407(4) 0.4014(3) 0.030(2) Uani 1 1 d . . . . .
C22 C 0.6110(4) 0.3754(5) 0.3772(4) 0.037(2) Uani 1 1 d . . . . .
C23 C 0.5860(6) 0.4156(5) 0.3461(4) 0.053(3) Uani 1 1 d . U . . .
C24 C 0.6148(8) 0.4452(8) 0.3119(7) 0.089(5) Uani 1 1 d . U . . .
H24 H 0.652169 0.438519 0.308253 0.107 Uiso 1 1 calc R . . . .
C25 C 0.5901(9) 0.4852(9) 0.2821(8) 0.099(5) Uani 1 1 d . U . . .
H25 H 0.611215 0.507151 0.259999 0.119 Uiso 1 1 calc R . . . .
C26 C 0.5373(9) 0.4928(8) 0.2845(7) 0.090(5) Uani 1 1 d . U . . .
H26 H 0.520726 0.519586 0.263615 0.108 Uiso 1 1 calc R . . . .
C27 C 0.5078(8) 0.4633(6) 0.3157(7) 0.082(6) Uani 1 1 d . . . . .
H27 H 0.470031 0.468340 0.316995 0.098 Uiso 1 1 calc R . . . .
C28 C 0.5323(7) 0.4245(5) 0.3469(6) 0.064(4) Uani 1 1 d . . . . .
H28 H 0.510666 0.403699 0.369485 0.077 Uiso 1 1 calc R . . . .
C31 C 0.4852(4) 0.2824(4) 0.3633(4) 0.028(2) Uani 1 1 d . . . . .
C32 C 0.4721(4) 0.2978(4) 0.3234(3) 0.029(2) Uani 1 1 d . . . . .
C33 C 0.4556(4) 0.3173(4) 0.2738(3) 0.029(2) Uani 1 1 d . . . . .
C34 C 0.4910(5) 0.3468(4) 0.2426(3) 0.032(2) Uani 1 1 d . . . . .
H34 H 0.526378 0.354703 0.253920 0.038 Uiso 1 1 calc R . . . .
C35 C 0.4740(5) 0.3644(4) 0.1947(3) 0.037(2) Uani 1 1 d . . . . .
H35 H 0.498094 0.384057 0.173505 0.044 Uiso 1 1 calc R . . . .
C36 C 0.4225(5) 0.3537(5) 0.1777(4) 0.044(3) Uani 1 1 d . . . . .
H36 H 0.411180 0.366039 0.145208 0.053 Uiso 1 1 calc R . . . .
C37 C 0.3877(5) 0.3249(6) 0.2086(4) 0.049(3) Uani 1 1 d . . . . .
H37 H 0.352235 0.317550 0.197117 0.059 Uiso 1 1 calc R . . . .
C38 C 0.4038(5) 0.3062(5) 0.2564(4) 0.040(2) Uani 1 1 d . . . . .
H38 H 0.379599 0.286066 0.277034 0.048 Uiso 1 1 calc R . . . .
C41 C 0.4690(4) 0.3209(4) 0.4613(3) 0.030(2) Uani 1 1 d . . . . .
C42 C 0.4570(5) 0.3664(5) 0.4760(4) 0.039(2) Uani 1 1 d . . . . .
C43 C 0.4330(4) 0.4171(3) 0.4926(4) 0.043(3) Uani 1 1 d . . . . .
C44 C 0.4313(6) 0.4323(5) 0.5434(4) 0.065(7) Uani 0.607(17) 1 d G . P A 1
H44 H 0.446112 0.408945 0.568593 0.078 Uiso 0.607(17) 1 calc R . P A 1
C45 C 0.4080(7) 0.4816(5) 0.5574(4) 0.085(10) Uani 0.607(17) 1 d G . P A 1
H45 H 0.406826 0.492014 0.592096 0.102 Uiso 0.607(17) 1 calc R . P A 1
C46 C 0.3864(5) 0.5158(4) 0.5205(6) 0.076(5) Uani 1 1 d G . . A .
H46 H 0.370411 0.549520 0.530046 0.091 Uiso 0.607(17) 1 calc R . P A 1
H46A H 0.368996 0.547350 0.533592 0.091 Uiso 0.393(17) 1 calc R . P A 2
C47 C 0.3881(6) 0.5006(5) 0.4697(5) 0.084(9) Uani 0.607(17) 1 d G U P A 1
H47 H 0.373281 0.523956 0.444494 0.101 Uiso 0.607(17) 1 calc R . P A 1
C48 C 0.4114(6) 0.4513(5) 0.4557(3) 0.069(8) Uani 0.607(17) 1 d G . P A 1
H48 H 0.412567 0.440887 0.420990 0.083 Uiso 0.607(17) 1 calc R . P A 1
C44A C 0.4690(10) 0.4665(10) 0.5020(13) 0.042(8) Uani 0.393(17) 1 d . . P A 2
H44A H 0.506777 0.464611 0.497154 0.051 Uiso 0.393(17) 1 calc R . P A 2
C45A C 0.4448(14) 0.5136(12) 0.5178(14) 0.053(9) Uani 0.393(17) 1 d . . P A 2
H45A H 0.465807 0.544510 0.526871 0.064 Uiso 0.393(17) 1 calc R . P A 2
C47A C 0.3593(11) 0.4762(14) 0.506(2) 0.074(15) Uani 0.393(17) 1 d . . P A 2
H47A H 0.321588 0.480423 0.502228 0.089 Uiso 0.393(17) 1 calc R . P A 2
C48A C 0.3824(13) 0.4256(13) 0.4936(16) 0.060(11) Uani 0.393(17) 1 d . . P A 2
H48A H 0.359151 0.395957 0.485869 0.071 Uiso 0.393(17) 1 calc R . P A 2
C51 C 0.5250(3) 0.1831(4) 0.3999(3) 0.0242(19) Uani 1 1 d . . . . .
C52 C 0.5483(4) 0.1476(4) 0.3768(3) 0.0247(18) Uani 1 1 d . . . . .
C53 C 0.5706(4) 0.1003(4) 0.3518(3) 0.029(2) Uani 1 1 d . . . . .
C54 C 0.6215(6) 0.1001(7) 0.3327(6) 0.067(4) Uani 1 1 d . . . . .
H54 H 0.642507 0.132409 0.334995 0.080 Uiso 1 1 calc R . . . .
C55 C 0.6437(7) 0.0535(8) 0.3098(7) 0.083(5) Uani 1 1 d . . . . .
H55 H 0.679655 0.053570 0.297755 0.099 Uiso 1 1 calc R . . . .
C56 C 0.6113(7) 0.0065(6) 0.3053(5) 0.059(4) Uani 1 1 d . . . . .
H56 H 0.625604 -0.026330 0.291544 0.070 Uiso 1 1 calc R . . . .
C57 C 0.5608(7) 0.0086(5) 0.3202(6) 0.063(4) Uani 1 1 d . . . . .
H57 H 0.538199 -0.022052 0.314762 0.076 Uiso 1 1 calc R . . . .
C58 C 0.5398(5) 0.0548(5) 0.3439(5) 0.045(3) Uani 1 1 d . . . . .
H58 H 0.503424 0.054746 0.354673 0.055 Uiso 1 1 calc R . . . .
C61 C 0.54800(16) 0.2030(3) 0.54682(18) 0.0208(17) Uani 1 1 d . . . . .
C62 C 0.55118(17) 0.2084(3) 0.59926(17) 0.0232(17) Uani 1 1 d G U . . .
H62 H 0.519286 0.210021 0.618990 0.028 Uiso 1 1 calc R . . . .
C63 C 0.6010(2) 0.2113(3) 0.62284(13) 0.0199(16) Uani 1 1 d G U . . .
C64 C 0.64770(16) 0.2089(3) 0.59398(17) 0.0227(17) Uani 1 1 d G . . . .
H64 H 0.681776 0.210925 0.610098 0.027 Uiso 1 1 calc R . . . .
C65 C 0.64452(17) 0.2036(3) 0.54153(17) 0.0230(17) Uani 1 1 d G . . . .
C66 C 0.5947(2) 0.2006(3) 0.51795(13) 0.0265(19) Uani 1 1 d G . . . .
H66 H 0.592494 0.196953 0.482108 0.032 Uiso 1 1 calc R . . . .
C67 C 0.6357(4) 0.1923(4) 0.7107(3) 0.028(2) Uani 1 1 d . . . . .
H67 H 0.660371 0.166357 0.697379 0.033 Uiso 1 1 calc R . . . .
C68 C 0.6024(4) 0.2212(4) 0.6785(3) 0.0241(18) Uani 1 1 d . . . . .
C69 C 0.5692(4) 0.2596(4) 0.7001(3) 0.0279(19) Uani 1 1 d . U . . .
H69 H 0.545933 0.280487 0.679167 0.033 Uiso 1 1 calc R . . . .
C70 C 0.5692(4) 0.2682(4) 0.7520(3) 0.029(2) Uani 1 1 d . . . . .
H70 H 0.546579 0.295660 0.765818 0.035 Uiso 1 1 calc R . . . .
C71 C 0.6330(4) 0.2015(4) 0.7636(3) 0.0279(19) Uani 1 1 d . U . . .
H71 H 0.655084 0.180449 0.785473 0.033 Uiso 1 1 calc R . . . .
C101 C 0.7167(4) 0.1504(4) 0.4706(3) 0.031(2) Uani 1 1 d . . . . .
C102 C 0.7655(5) 0.1424(5) 0.4469(5) 0.050(3) Uani 1 1 d . . . . .
H102 H 0.791230 0.171079 0.447491 0.060 Uiso 1 1 calc R . . . .
C103 C 0.7781(6) 0.0953(6) 0.4228(6) 0.067(4) Uani 1 1 d . . . . .
H103 H 0.812467 0.090989 0.407692 0.080 Uiso 1 1 calc R . . . .
C104 C 0.7422(8) 0.0548(6) 0.4203(8) 0.097(7) Uani 1 1 d . . . . .
H104 H 0.751686 0.021643 0.403759 0.116 Uiso 1 1 calc R . . . .
C105 C 0.6925(7) 0.0601(7) 0.4409(7) 0.079(6) Uani 1 1 d . . . . .
H105 H 0.667016 0.031374 0.438627 0.095 Uiso 1 1 calc R . . . .
C106 C 0.6801(6) 0.1083(5) 0.4653(6) 0.060(4) Uani 1 1 d . . . . .
H106 H 0.645081 0.112814 0.478992 0.072 Uiso 1 1 calc R . . . .
C111 C 0.7592(4) 0.2326(4) 0.5372(3) 0.028(2) Uani 1 1 d . . . . .
C112 C 0.7741(4) 0.2873(5) 0.5416(4) 0.035(2) Uani 1 1 d . . . . .
H112 H 0.753640 0.314968 0.525262 0.042 Uiso 1 1 calc R . . . .
C113 C 0.8184(4) 0.3008(5) 0.5695(4) 0.040(3) Uani 1 1 d . . . . .
H113 H 0.827867 0.338176 0.572925 0.048 Uiso 1 1 calc R . . . .
C114 C 0.8500(4) 0.2613(6) 0.5932(4) 0.045(3) Uani 1 1 d . . . . .
H114 H 0.881133 0.271088 0.611935 0.055 Uiso 1 1 calc R . . . .
C115 C 0.8347(5) 0.2081(6) 0.5884(4) 0.047(3) Uani 1 1 d . . . . .
H115 H 0.855844 0.180633 0.604183 0.056 Uiso 1 1 calc R . . . .
C116 C 0.7899(4) 0.1928(5) 0.5615(4) 0.039(2) Uani 1 1 d . . . . .
H116 H 0.779887 0.155418 0.559474 0.047 Uiso 1 1 calc R . . . .
C201 C 0.4379(4) 0.2356(4) 0.5544(3) 0.029(2) Uani 1 1 d . U . . .
C202 C 0.4506(4) 0.2825(5) 0.5802(3) 0.033(2) Uani 1 1 d . . . . .
H202 H 0.484523 0.299247 0.574897 0.040 Uiso 1 1 calc R . . . .
C203 C 0.4141(5) 0.3062(6) 0.6144(4) 0.047(3) Uani 1 1 d . . . . .
H203 H 0.424320 0.336768 0.634443 0.057 Uiso 1 1 calc R . . . .
C204 C 0.3645(5) 0.2850(6) 0.6183(4) 0.050(3) Uani 1 1 d . . . . .
H204 H 0.339277 0.302241 0.640021 0.060 Uiso 1 1 calc R . . . .
C205 C 0.3488(5) 0.2389(5) 0.5918(4) 0.043(3) Uani 1 1 d . . . . .
H205 H 0.313686 0.224393 0.595614 0.052 Uiso 1 1 calc R . . . .
C206 C 0.3864(4) 0.2141(5) 0.5590(3) 0.032(2) Uani 1 1 d . . . . .
H206 H 0.376451 0.182636 0.540002 0.038 Uiso 1 1 calc R . . . .
C211 C 0.4646(4) 0.1341(4) 0.5069(3) 0.0270(19) Uani 1 1 d . . . . .
C212 C 0.4744(4) 0.0981(4) 0.5478(3) 0.034(2) Uani 1 1 d . . . . .
H212 H 0.493386 0.110612 0.576786 0.041 Uiso 1 1 calc R . . . .
C213 C 0.4564(5) 0.0449(5) 0.5458(4) 0.043(3) Uani 1 1 d . . . . .
H213 H 0.463026 0.021020 0.573473 0.052 Uiso 1 1 calc R . . . .
C214 C 0.4286(5) 0.0260(5) 0.5033(4) 0.042(2) Uani 1 1 d . . . . .
H214 H 0.416156 -0.010640 0.502075 0.050 Uiso 1 1 calc R . . . .
C215 C 0.4194(5) 0.0606(5) 0.4634(4) 0.040(2) Uani 1 1 d . . . . .
H215 H 0.400549 0.047709 0.434402 0.047 Uiso 1 1 calc R . . . .
C216 C 0.4374(4) 0.1148(5) 0.4648(4) 0.035(2) Uani 1 1 d . . . . .
H216 H 0.430891 0.138286 0.436779 0.042 Uiso 1 1 calc R . . . .
Cl1 Cl 0.44895(19) 0.14488(18) 0.24209(12) 0.0753(12) Uani 1 1 d . . . . .
Cl2 Cl 0.39537(14) 0.09979(14) 0.33058(11) 0.0525(7) Uani 1 1 d . . . . .
C05 C 0.4208(5) 0.1589(5) 0.3008(5) 0.047(3) Uani 1 1 d . . . . .
H05A H 0.391311 0.185604 0.296526 0.056 Uiso 1 1 calc R . . . .
H05B H 0.448328 0.175654 0.322998 0.056 Uiso 1 1 calc R . . . .
O1 O 0.6784(8) 0.0096(9) 0.6068(10) 0.077(7) Uani 0.5 1 d . . P . .
C01 C 0.6071(11) 0.0582(9) 0.6313(11) 0.054(7) Uani 0.5 1 d . . P . .
H01A H 0.584657 0.041368 0.605096 0.081 Uiso 0.5 1 calc GR . P . .
H01B H 0.596735 0.096499 0.635684 0.081 Uiso 0.5 1 calc GR . P . .
H01C H 0.602264 0.038636 0.663468 0.081 Uiso 0.5 1 calc GR . P . .
C02 C 0.6615(19) 0.0553(13) 0.6166(17) 0.098(14) Uani 0.5 1 d . . P . .
H02A H 0.666466 0.078696 0.586255 0.118 Uiso 0.5 1 calc R . P . .
H02B H 0.683681 0.070930 0.644170 0.118 Uiso 0.5 1 calc R . P . .
C03 C 0.7306(16) 0.0060(16) 0.5799(15) 0.086(10) Uani 0.5 1 d . . P . .
H03A H 0.728284 0.026401 0.547499 0.103 Uiso 0.5 1 calc R . P . .
H03B H 0.758860 0.023286 0.600886 0.103 Uiso 0.5 1 calc R . P . .
C04 C 0.7460(14) -0.0514(14) 0.569(2) 0.15(3) Uani 0.5 1 d . . P . .
H04A H 0.749903 -0.056474 0.532396 0.218 Uiso 0.5 1 calc GR . P . .
H04B H 0.718044 -0.076019 0.581933 0.218 Uiso 0.5 1 calc GR . P . .
H04C H 0.780138 -0.059712 0.585921 0.218 Uiso 0.5 1 calc GR . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ag1 3.1807(10) . ?
Pt1 Ag2 2.9078(8) . ?
Pt1 P2 2.299(2) . ?
Pt1 C1 2.019(10) . ?
Pt1 C11 2.007(9) . ?
Pt1 C21 2.023(9) . ?
Pt2 Ag1 2.9198(9) . ?
Pt2 Ag2 3.0122(9) . ?
Pt2 P1 2.307(2) . ?
Pt2 C31 2.030(10) . ?
Pt2 C41 2.008(10) . ?
Pt2 C51 1.998(10) . ?
Ag1 C1 2.334(9) . ?
Ag1 C2 2.501(9) . ?
Ag1 C21 2.658(9) . ?
Ag1 C41 2.277(10) . ?
Ag1 C42 2.622(11) . ?
Ag2 N1 2.290(7) 7_565 ?
Ag2 C11 2.696(9) . ?
Ag2 C21 2.604(10) . ?
Ag2 C51 2.473(9) . ?
P1 C61 1.826(4) . ?
P1 C201 1.815(10) . ?
P1 C211 1.809(10) . ?
P2 C65 1.828(4) . ?
P2 C101 1.806(10) . ?
P2 C111 1.822(9) . ?
N1 C70 1.349(12) . ?
N1 C71 1.329(12) . ?
C1 C2 1.220(13) . ?
C2 C3 1.449(11) . ?
C3 C4 1.375(15) . ?
C3 C8 1.388(14) . ?
C4 C5 1.391(14) . ?
C5 C6 1.391(18) . ?
C6 C7 1.359(18) . ?
C7 C8 1.390(13) . ?
C11 C12 1.195(13) . ?
C12 C13 1.441(13) . ?
C13 C14 1.37(2) . ?
C13 C18 1.384(17) . ?
C14 C15 1.418(17) . ?
C15 C16 1.39(3) . ?
C16 C17 1.34(3) . ?
C17 C18 1.428(18) . ?
C21 C22 1.217(14) . ?
C22 C23 1.423(15) . ?
C23 C24 1.36(2) . ?
C23 C28 1.35(2) . ?
C24 C25 1.40(2) . ?
C25 C26 1.33(3) . ?
C26 C27 1.32(3) . ?
C27 C28 1.40(2) . ?
C31 C32 1.164(13) . ?
C32 C33 1.450(12) . ?
C33 C34 1.404(14) . ?
C33 C38 1.395(15) . ?
C34 C35 1.400(12) . ?
C35 C36 1.382(17) . ?
C36 C37 1.383(17) . ?
C37 C38 1.399(13) . ?
C41 C42 1.216(15) . ?
C42 C43 1.445(13) . ?
C43 C44 1.3900 . ?
C43 C48 1.3900 . ?
C43 C44A 1.53(3) . ?
C43 C48A 1.28(3) . ?
C44 C45 1.3900 . ?
C45 C46 1.3900 . ?
C46 C47 1.3900 . ?
C46 C45A 1.46(4) . ?
C46 C47A 1.24(4) . ?
C47 C48 1.3900 . ?
C44A C45A 1.36(4) . ?
C47A C48A 1.40(4) . ?
C51 C52 1.210(13) . ?
C52 C53 1.442(13) . ?
C53 C54 1.362(17) . ?
C53 C58 1.369(15) . ?
C54 C55 1.41(2) . ?
C55 C56 1.41(2) . ?
C56 C57 1.32(2) . ?
C57 C58 1.392(18) . ?
C61 C62 1.3900 . ?
C61 C66 1.3900 . ?
C62 C63 1.3900 . ?
C63 C64 1.3900 . ?
C63 C68 1.486(8) . ?
C64 C65 1.3900 . ?
C65 C66 1.3900 . ?
C67 C68 1.383(13) . ?
C67 C71 1.412(11) . ?
C68 C69 1.374(14) . ?
C69 C70 1.384(12) . ?
C101 C102 1.380(15) . ?
C101 C106 1.383(16) . ?
C102 C103 1.354(17) . ?
C103 C104 1.34(2) . ?
C104 C105 1.36(2) . ?
C105 C106 1.379(18) . ?
C111 C112 1.394(15) . ?
C111 C116 1.393(14) . ?
C112 C113 1.365(15) . ?
C113 C114 1.395(17) . ?
C114 C115 1.361(18) . ?
C115 C116 1.375(16) . ?
C201 C202 1.371(14) . ?
C201 C206 1.394(15) . ?
C202 C203 1.404(13) . ?
C203 C204 1.344(19) . ?
C204 C205 1.381(19) . ?
C205 C206 1.411(14) . ?
C211 C212 1.413(13) . ?
C211 C216 1.383(13) . ?
C212 C213 1.377(16) . ?
C213 C214 1.395(16) . ?
C214 C215 1.370(16) . ?
C215 C216 1.400(15) . ?
Cl1 C05 1.733(12) . ?
Cl2 C05 1.762(13) . ?
O1 C02 1.22(4) . ?
O1 C03 1.48(4) . ?
C01 C02 1.41(5) . ?
C03 C04 1.48(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag2 Pt1 Ag1 71.27(3) . . ?
P2 Pt1 Ag1 116.80(6) . . ?
P2 Pt1 Ag2 115.35(6) . . ?
C1 Pt1 Ag1 47.1(3) . . ?
C1 Pt1 Ag2 117.4(3) . . ?
C1 Pt1 P2 88.3(3) . . ?
C1 Pt1 C21 88.3(4) . . ?
C11 Pt1 Ag1 133.1(2) . . ?
C11 Pt1 Ag2 63.5(2) . . ?
C11 Pt1 P2 93.9(3) . . ?
C11 Pt1 C1 177.0(4) . . ?
C11 Pt1 C21 89.9(4) . . ?
C21 Pt1 Ag1 56.3(3) . . ?
C21 Pt1 Ag2 60.6(3) . . ?
C21 Pt1 P2 172.4(3) . . ?
Ag1 Pt2 Ag2 73.60(3) . . ?
P1 Pt2 Ag1 94.53(6) . . ?
P1 Pt2 Ag2 123.77(6) . . ?
C31 Pt2 Ag1 93.2(3) . . ?
C31 Pt2 Ag2 64.0(3) . . ?
C31 Pt2 P1 170.4(3) . . ?
C41 Pt2 Ag1 51.0(3) . . ?
C41 Pt2 Ag2 115.7(3) . . ?
C41 Pt2 P1 93.6(3) . . ?
C41 Pt2 C31 86.9(4) . . ?
C51 Pt2 Ag1 121.3(2) . . ?
C51 Pt2 Ag2 54.7(2) . . ?
C51 Pt2 P1 92.8(2) . . ?
C51 Pt2 C31 88.0(4) . . ?
C51 Pt2 C41 170.4(4) . . ?
Pt2 Ag1 Pt1 96.29(3) . . ?
C1 Ag1 Pt1 39.3(2) . . ?
C1 Ag1 Pt2 122.7(2) . . ?
C1 Ag1 C2 29.0(3) . . ?
C1 Ag1 C21 68.3(3) . . ?
C1 Ag1 C42 153.6(3) . . ?
C2 Ag1 Pt1 68.2(2) . . ?
C2 Ag1 Pt2 132.9(2) . . ?
C2 Ag1 C21 93.9(3) . . ?
C2 Ag1 C42 124.7(3) . . ?
C21 Ag1 Pt1 39.3(2) . . ?
C21 Ag1 Pt2 100.5(2) . . ?
C41 Ag1 Pt1 139.4(2) . . ?
C41 Ag1 Pt2 43.3(2) . . ?
C41 Ag1 C1 155.1(3) . . ?
C41 Ag1 C2 137.2(3) . . ?
C41 Ag1 C21 128.2(3) . . ?
C41 Ag1 C42 27.6(3) . . ?
C42 Ag1 Pt1 165.9(2) . . ?
C42 Ag1 Pt2 70.9(2) . . ?
C42 Ag1 C21 135.3(3) . . ?
Pt1 Ag2 Pt2 100.35(3) . . ?
N1 Ag2 Pt1 125.65(19) 7_565 . ?
N1 Ag2 Pt2 128.43(19) 7_565 . ?
N1 Ag2 C11 92.4(3) 7_565 . ?
N1 Ag2 C21 100.1(3) 7_565 . ?
N1 Ag2 C51 117.3(3) 7_565 . ?
C11 Ag2 Pt1 41.8(2) . . ?
C11 Ag2 Pt2 138.95(18) . . ?
C21 Ag2 Pt1 42.6(2) . . ?
C21 Ag2 Pt2 99.4(2) . . ?
C21 Ag2 C11 64.9(3) . . ?
C51 Ag2 Pt1 115.16(18) . . ?
C51 Ag2 Pt2 41.3(2) . . ?
C51 Ag2 C11 128.5(3) . . ?
C51 Ag2 C21 137.2(3) . . ?
C61 P1 Pt2 114.2(2) . . ?
C201 P1 Pt2 114.6(3) . . ?
C201 P1 C61 103.6(4) . . ?
C211 P1 Pt2 114.4(3) . . ?
C211 P1 C61 104.5(4) . . ?
C211 P1 C201 104.2(4) . . ?
C65 P2 Pt1 104.4(2) . . ?
C101 P2 Pt1 117.5(3) . . ?
C101 P2 C65 106.0(4) . . ?
C101 P2 C111 104.7(5) . . ?
C111 P2 Pt1 115.9(3) . . ?
C111 P2 C65 107.6(3) . . ?
C70 N1 Ag2 119.7(6) . 7_566 ?
C71 N1 Ag2 122.2(6) . 7_566 ?
C71 N1 C70 118.1(7) . . ?
Pt1 C1 Ag1 93.6(3) . . ?
C2 C1 Pt1 174.4(9) . . ?
C2 C1 Ag1 83.1(7) . . ?
C1 C2 Ag1 67.9(6) . . ?
C1 C2 C3 168.3(10) . . ?
C3 C2 Ag1 123.5(7) . . ?
C4 C3 C2 120.3(9) . . ?
C4 C3 C8 119.7(9) . . ?
C8 C3 C2 120.0(9) . . ?
C3 C4 C5 120.0(11) . . ?
C4 C5 C6 120.1(12) . . ?
C7 C6 C5 119.6(10) . . ?
C6 C7 C8 120.8(11) . . ?
C3 C8 C7 119.8(11) . . ?
Pt1 C11 Ag2 74.8(3) . . ?
C12 C11 Pt1 174.1(10) . . ?
C12 C11 Ag2 108.5(7) . . ?
C11 C12 C13 176.9(10) . . ?
C14 C13 C12 120.3(12) . . ?
C14 C13 C18 119.9(11) . . ?
C18 C13 C12 119.8(12) . . ?
C13 C14 C15 119.0(16) . . ?
C16 C15 C14 119.7(18) . . ?
C17 C16 C15 122.4(15) . . ?
C16 C17 C18 117.3(17) . . ?
C13 C18 C17 121.6(16) . . ?
Pt1 C21 Ag1 84.4(3) . . ?
Pt1 C21 Ag2 76.7(3) . . ?
Ag2 C21 Ag1 85.0(3) . . ?
C22 C21 Pt1 176.6(9) . . ?
C22 C21 Ag1 92.2(7) . . ?
C22 C21 Ag2 103.6(7) . . ?
C21 C22 C23 176.0(12) . . ?
C24 C23 C22 121.2(15) . . ?
C28 C23 C22 122.2(13) . . ?
C28 C23 C24 116.5(14) . . ?
C23 C24 C25 120.9(19) . . ?
C26 C25 C24 120(2) . . ?
C27 C26 C25 120.2(18) . . ?
C26 C27 C28 120(2) . . ?
C23 C28 C27 122.0(18) . . ?
C32 C31 Pt2 167.7(9) . . ?
C31 C32 C33 179.6(13) . . ?
C34 C33 C32 121.3(9) . . ?
C38 C33 C32 119.5(9) . . ?
C38 C33 C34 119.2(9) . . ?
C35 C34 C33 119.7(10) . . ?
C36 C35 C34 120.9(10) . . ?
C35 C36 C37 119.2(9) . . ?
C36 C37 C38 121.1(11) . . ?
C33 C38 C37 119.8(11) . . ?
Pt2 C41 Ag1 85.7(4) . . ?
C42 C41 Pt2 176.0(10) . . ?
C42 C41 Ag1 92.2(8) . . ?
C41 C42 Ag1 60.2(7) . . ?
C41 C42 C43 169.9(12) . . ?
C43 C42 Ag1 129.8(8) . . ?
C42 C43 C44A 119.2(13) . . ?
C44 C43 C42 122.3(8) . . ?
C44 C43 C48 120.0 . . ?
C48 C43 C42 117.7(8) . . ?
C48A C43 C42 123.6(16) . . ?
C48A C43 C44A 116.6(17) . . ?
C43 C44 C45 120.0 . . ?
C46 C45 C44 120.0 . . ?
C45 C46 C47 120.0 . . ?
C47A C46 C45A 119.7(18) . . ?
C46 C47 C48 120.0 . . ?
C47 C48 C43 120.0 . . ?
C45A C44A C43 117(2) . . ?
C44A C45A C46 119(2) . . ?
C46 C47A C48A 123(3) . . ?
C43 C48A C47A 124(3) . . ?
Pt2 C51 Ag2 84.0(3) . . ?
C52 C51 Pt2 172.8(8) . . ?
C52 C51 Ag2 89.0(6) . . ?
C51 C52 C53 172.2(10) . . ?
C54 C53 C52 121.9(10) . . ?
C54 C53 C58 117.5(11) . . ?
C58 C53 C52 120.5(9) . . ?
C53 C54 C55 121.8(15) . . ?
C54 C55 C56 118.3(15) . . ?
C57 C56 C55 119.2(13) . . ?
C56 C57 C58 121.6(14) . . ?
C53 C58 C57 121.2(12) . . ?
C62 C61 P1 124.4(3) . . ?
C62 C61 C66 120.0 . . ?
C66 C61 P1 115.4(3) . . ?
C61 C62 C63 120.0 . . ?
C62 C63 C68 118.0(5) . . ?
C64 C63 C62 120.0 . . ?
C64 C63 C68 121.8(5) . . ?
C65 C64 C63 120.0 . . ?
C64 C65 P2 123.8(3) . . ?
C64 C65 C66 120.0 . . ?
C66 C65 P2 114.6(3) . . ?
C65 C66 C61 120.0 . . ?
C68 C67 C71 119.6(9) . . ?
C67 C68 C63 122.3(8) . . ?
C69 C68 C63 120.5(8) . . ?
C69 C68 C67 117.2(8) . . ?
C68 C69 C70 120.9(9) . . ?
N1 C70 C69 122.0(9) . . ?
N1 C71 C67 122.2(8) . . ?
C102 C101 P2 120.2(9) . . ?
C102 C101 C106 115.5(10) . . ?
C106 C101 P2 123.8(8) . . ?
C103 C102 C101 122.4(12) . . ?
C104 C103 C102 120.1(13) . . ?
C103 C104 C105 121.2(13) . . ?
C104 C105 C106 118.3(14) . . ?
C105 C106 C101 122.4(12) . . ?
C112 C111 P2 118.4(8) . . ?
C116 C111 P2 122.4(8) . . ?
C116 C111 C112 119.2(9) . . ?
C113 C112 C111 119.4(11) . . ?
C112 C113 C114 122.0(12) . . ?
C115 C114 C113 117.6(11) . . ?
C114 C115 C116 122.4(12) . . ?
C115 C116 C111 119.4(12) . . ?
C202 C201 P1 120.9(8) . . ?
C202 C201 C206 119.0(9) . . ?
C206 C201 P1 119.9(7) . . ?
C201 C202 C203 121.1(10) . . ?
C204 C203 C202 118.8(11) . . ?
C203 C204 C205 122.5(10) . . ?
C204 C205 C206 118.3(11) . . ?
C201 C206 C205 120.0(11) . . ?
C212 C211 P1 120.4(7) . . ?
C216 C211 P1 120.8(8) . . ?
C216 C211 C212 118.8(9) . . ?
C213 C212 C211 120.3(9) . . ?
C212 C213 C214 120.4(10) . . ?
C215 C214 C213 119.6(10) . . ?
C214 C215 C216 120.8(10) . . ?
C211 C216 C215 120.2(10) . . ?
Cl1 C05 Cl2 112.3(7) . . ?
C02 O1 C03 117(3) . . ?
O1 C02 C01 116(3) . . ?
C04 C03 O1 112(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Pt1 P2 C65 C64 -121.4(3) . . . . ?
Pt1 P2 C65 C66 44.4(3) . . . . ?
Pt1 P2 C101 C102 80.9(10) . . . . ?
Pt1 P2 C101 C106 -90.4(11) . . . . ?
Pt1 P2 C111 C112 15.0(8) . . . . ?
Pt1 P2 C111 C116 -163.7(7) . . . . ?
Pt2 P1 C61 C62 142.8(3) . . . . ?
Pt2 P1 C61 C66 -31.8(4) . . . . ?
Pt2 P1 C201 C202 -76.8(8) . . . . ?
Pt2 P1 C201 C206 98.1(8) . . . . ?
Pt2 P1 C211 C212 160.5(7) . . . . ?
Pt2 P1 C211 C216 -21.6(9) . . . . ?
Ag1 C1 C2 C3 168(5) . . . . ?
Ag1 C2 C3 C4 -7.8(14) . . . . ?
Ag1 C2 C3 C8 171.2(8) . . . . ?
Ag1 C41 C42 C43 -176(6) . . . . ?
Ag1 C42 C43 C44 -72.0(12) . . . . ?
Ag1 C42 C43 C48 107.8(10) . . . . ?
Ag1 C42 C43 C44A 11(2) . . . . ?
Ag1 C42 C43 C48A -179(2) . . . . ?
Ag2 N1 C70 C69 -174.7(8) 7_566 . . . ?
Ag2 N1 C71 C67 176.6(7) 7_566 . . . ?
P1 C61 C62 C63 -174.3(5) . . . . ?
P1 C61 C66 C65 174.8(4) . . . . ?
P1 C201 C202 C203 -179.4(8) . . . . ?
P1 C201 C206 C205 -178.1(8) . . . . ?
P1 C211 C212 C213 177.1(9) . . . . ?
P1 C211 C216 C215 -177.1(8) . . . . ?
P2 C65 C66 C61 -166.4(4) . . . . ?
P2 C101 C102 C103 -176.1(12) . . . . ?
P2 C101 C106 C105 175.8(14) . . . . ?
P2 C111 C112 C113 -178.7(8) . . . . ?
P2 C111 C116 C115 177.3(8) . . . . ?
C1 C2 C3 C4 -175(5) . . . . ?
C1 C2 C3 C8 4(6) . . . . ?
C2 C3 C4 C5 179.4(10) . . . . ?
C2 C3 C8 C7 -179.0(10) . . . . ?
C3 C4 C5 C6 -1.1(19) . . . . ?
C4 C3 C8 C7 -0.1(17) . . . . ?
C4 C5 C6 C7 1.5(19) . . . . ?
C5 C6 C7 C8 -1.1(19) . . . . ?
C6 C7 C8 C3 0.4(19) . . . . ?
C8 C3 C4 C5 0.4(17) . . . . ?
C12 C13 C14 C15 177.6(11) . . . . ?
C12 C13 C18 C17 -176.3(11) . . . . ?
C13 C14 C15 C16 -1(2) . . . . ?
C14 C13 C18 C17 2.0(18) . . . . ?
C14 C15 C16 C17 2(3) . . . . ?
C15 C16 C17 C18 -1(2) . . . . ?
C16 C17 C18 C13 -1(2) . . . . ?
C18 C13 C14 C15 -0.7(19) . . . . ?
C22 C23 C24 C25 -178.9(17) . . . . ?
C22 C23 C28 C27 -178.8(12) . . . . ?
C23 C24 C25 C26 -4(3) . . . . ?
C24 C23 C28 C27 -2(2) . . . . ?
C24 C25 C26 C27 1(3) . . . . ?
C25 C26 C27 C28 1(3) . . . . ?
C26 C27 C28 C23 -1(2) . . . . ?
C28 C23 C24 C25 4(3) . . . . ?
C32 C33 C34 C35 179.2(9) . . . . ?
C32 C33 C38 C37 -179.9(11) . . . . ?
C33 C34 C35 C36 0.6(15) . . . . ?
C34 C33 C38 C37 -0.6(16) . . . . ?
C34 C35 C36 C37 -0.4(17) . . . . ?
C35 C36 C37 C38 -0.3(19) . . . . ?
C36 C37 C38 C33 0.8(19) . . . . ?
C38 C33 C34 C35 -0.1(15) . . . . ?
C41 C42 C43 C44 103(6) . . . . ?
C41 C42 C43 C48 -77(6) . . . . ?
C41 C42 C43 C44A -174(6) . . . . ?
C41 C42 C43 C48A -4(7) . . . . ?
C42 C43 C44 C45 179.8(11) . . . . ?
C42 C43 C48 C47 -179.8(10) . . . . ?
C42 C43 C44A C45A -180(3) . . . . ?
C42 C43 C48A C47A -174(3) . . . . ?
C43 C44 C45 C46 0.0 . . . . ?
C43 C44A C45A C46 -5(5) . . . . ?
C44 C43 C48 C47 0.0 . . . . ?
C44 C45 C46 C47 0.0 . . . . ?
C45 C46 C47 C48 0.0 . . . . ?
C46 C47 C48 C43 0.0 . . . . ?
C46 C47A C48A C43 -6(7) . . . . ?
C48 C43 C44 C45 0.0 . . . . ?
C44A C43 C48A C47A -4(5) . . . . ?
C45A C46 C47A C48A 10(6) . . . . ?
C47A C46 C45A C44A -4(5) . . . . ?
C48A C43 C44A C45A 9(4) . . . . ?
C52 C53 C54 C55 178.0(14) . . . . ?
C52 C53 C58 C57 -179.4(11) . . . . ?
C53 C54 C55 C56 2(3) . . . . ?
C54 C53 C58 C57 4.2(18) . . . . ?
C54 C55 C56 C57 3(2) . . . . ?
C55 C56 C57 C58 -5(2) . . . . ?
C56 C57 C58 C53 1(2) . . . . ?
C58 C53 C54 C55 -6(2) . . . . ?
C61 P1 C201 C202 48.3(9) . . . . ?
C61 P1 C201 C206 -136.8(7) . . . . ?
C61 P1 C211 C212 34.9(9) . . . . ?
C61 P1 C211 C216 -147.3(8) . . . . ?
C61 C62 C63 C64 0.0 . . . . ?
C61 C62 C63 C68 175.5(7) . . . . ?
C62 C61 C66 C65 0.0 . . . . ?
C62 C63 C64 C65 0.0 . . . . ?
C62 C63 C68 C67 135.6(8) . . . . ?
C62 C63 C68 C69 -43.3(10) . . . . ?
C63 C64 C65 P2 165.1(5) . . . . ?
C63 C64 C65 C66 0.0 . . . . ?
C63 C68 C69 C70 178.4(9) . . . . ?
C64 C63 C68 C67 -49.0(11) . . . . ?
C64 C63 C68 C69 132.1(8) . . . . ?
C64 C65 C66 C61 0.0 . . . . ?
C65 P2 C101 C102 -163.0(9) . . . . ?
C65 P2 C101 C106 25.7(12) . . . . ?
C65 P2 C111 C112 -101.4(7) . . . . ?
C65 P2 C111 C116 79.9(9) . . . . ?
C66 C61 C62 C63 0.0 . . . . ?
C67 C68 C69 C70 -0.5(15) . . . . ?
C68 C63 C64 C65 -175.3(7) . . . . ?
C68 C67 C71 N1 -2.4(16) . . . . ?
C68 C69 C70 N1 -1.7(16) . . . . ?
C70 N1 C71 C67 0.2(14) . . . . ?
C71 N1 C70 C69 1.8(14) . . . . ?
C71 C67 C68 C63 -176.5(8) . . . . ?
C71 C67 C68 C69 2.4(14) . . . . ?
C101 P2 C65 C64 113.9(5) . . . . ?
C101 P2 C65 C66 -80.3(5) . . . . ?
C101 P2 C111 C112 146.1(7) . . . . ?
C101 P2 C111 C116 -32.5(9) . . . . ?
C101 C102 C103 C104 2(3) . . . . ?
C102 C101 C106 C105 4(2) . . . . ?
C102 C103 C104 C105 1(3) . . . . ?
C103 C104 C105 C106 -1(3) . . . . ?
C104 C105 C106 C101 -2(3) . . . . ?
C106 C101 C102 C103 -4(2) . . . . ?
C111 P2 C65 C64 2.3(5) . . . . ?
C111 P2 C65 C66 168.1(4) . . . . ?
C111 P2 C101 C102 -49.3(10) . . . . ?
C111 P2 C101 C106 139.3(11) . . . . ?
C111 C112 C113 C114 1.3(16) . . . . ?
C112 C111 C116 C115 -1.3(15) . . . . ?
C112 C113 C114 C115 -1.3(16) . . . . ?
C113 C114 C115 C116 -0.1(17) . . . . ?
C114 C115 C116 C111 1.4(17) . . . . ?
C116 C111 C112 C113 0.0(14) . . . . ?
C201 P1 C61 C62 17.5(5) . . . . ?
C201 P1 C61 C66 -157.1(4) . . . . ?
C201 P1 C211 C212 -73.6(9) . . . . ?
C201 P1 C211 C216 104.3(8) . . . . ?
C201 C202 C203 C204 -5.8(17) . . . . ?
C202 C201 C206 C205 -3.1(14) . . . . ?
C202 C203 C204 C205 3.4(19) . . . . ?
C203 C204 C205 C206 -1.0(18) . . . . ?
C204 C205 C206 C201 0.8(16) . . . . ?
C206 C201 C202 C203 5.6(15) . . . . ?
C211 P1 C61 C62 -91.4(4) . . . . ?
C211 P1 C61 C66 94.0(4) . . . . ?
C211 P1 C201 C202 157.4(8) . . . . ?
C211 P1 C201 C206 -27.7(9) . . . . ?
C211 C212 C213 C214 0.2(18) . . . . ?
C212 C211 C216 C215 0.8(15) . . . . ?
C212 C213 C214 C215 0.3(18) . . . . ?
C213 C214 C215 C216 -0.2(18) . . . . ?
C214 C215 C216 C211 -0.3(17) . . . . ?
C216 C211 C212 C213 -0.8(16) . . . . ?
C02 O1 C03 C04 -179(4) . . . . ?
C03 O1 C02 C01 166(3) . . . . ?

_platon_squeeze_details          ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.722 -0.063 0.288 259 39 ' '
2 0.222 -0.063 0.212 258 39 ' '
3 0.778 0.063 0.788 259 39 ' '
4 0.278 0.063 0.712 258 39 ' '
5 0.278 0.437 0.212 259 39 ' '
6 0.778 0.437 0.288 259 39 ' '
7 0.222 0.563 0.712 258 39 ' '
8 0.722 0.563 0.788 258 39 ' '

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1990106'
loop_
_audit_author_name
_audit_author_address
'Qiao-Hua Wei'
;College of Chemistry, Fuzhou University
China
;
_audit_update_record             
;
2020-03-13 deposited with the CCDC.	2020-05-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C179 H140 Ag4 Cl2 N2 P4 Pt4'
_chemical_formula_weight         3725.55

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P2(1)/c  '

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   18.249(4)
_cell_length_b                   14.605(3)
_cell_length_c                   27.333(6)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.31(3)
_cell_angle_gamma                90.00
_cell_volume                     7283(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    77(2)
_cell_measurement_reflns_used    4412
_cell_measurement_theta_min      2.6
_cell_measurement_theta_max      26.1

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3644
_exptl_absorpt_coefficient_mu    4.488
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4672
_exptl_absorpt_correction_T_max  0.6624
_exptl_absorpt_process_details   'HKL2000 Scalepack (Otwinowski & Minor, 1997)'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      77(2)
_diffrn_radiation_wavelength     0.72000
_diffrn_radiation_type           synchrotron
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device       'MarCCD 165 detector'
_diffrn_measurement_method       oscillation
_diffrn_standards_decay_%        0
_diffrn_reflns_number            33807
_diffrn_reflns_av_R_equivalents  0.0567
_diffrn_reflns_av_sigmaI/netI    0.0517
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_theta_min         1.81
_diffrn_reflns_theta_max         29.36
_reflns_number_total             18533
_reflns_number_gt                18442
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'MarCCD 165 detector'
_computing_cell_refinement       'HKL2000 Scalepack (Otwinowski & Minor, 1997)'
_computing_data_reduction        'HKL2000 Scalepack (Otwinowski & Minor, 1997)'
_computing_structure_solution    'shelxs-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0896P)²+14.5992P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         18533
_refine_ls_number_parameters     894
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0494
_refine_ls_R_factor_gt           0.0484
_refine_ls_wR_factor_ref         0.1451
_refine_ls_wR_factor_gt          0.1449
_refine_ls_goodness_of_fit_ref   1.143
_refine_ls_restrained_S_all      1.143
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.770797(18) 0.94793(4) 0.139200(12) 0.03990(11) Uani 1 1 d . . .
Ag2 Ag 0.756102(16) 0.83260(2) 0.255841(12) 0.02455(8) Uani 1 1 d . . .
Pt1 Pt 0.629299(7) 0.886348(10) 0.189191(5) 0.01845(6) Uani 1 1 d . . .
Pt2 Pt 0.857355(7) 0.989835(10) 0.231391(5) 0.01697(6) Uani 1 1 d . . .
P1 P 0.82581(5) 1.08063(7) 0.29604(3) 0.01723(18) Uani 1 1 d . . .
P2 P 0.56116(5) 1.01272(7) 0.20934(4) 0.01801(18) Uani 1 1 d . . .
C1 C 0.6976(2) 0.7808(3) 0.17740(15) 0.0217(7) Uani 1 1 d . . .
C2 C 0.7468(2) 0.7249(3) 0.17463(15) 0.0240(8) Uani 1 1 d . . .
C3 C 0.8017(2) 0.6558(3) 0.16941(15) 0.0230(8) Uani 1 1 d . . .
C4 C 0.8219(3) 0.6251(4) 0.12341(18) 0.0371(11) Uani 1 1 d . . .
H4 H 0.8004 0.6522 0.0949 0.044 Uiso 1 1 calc R . .
C5 C 0.8375(2) 0.6180(3) 0.21034(16) 0.0246(8) Uani 1 1 d . . .
H5 H 0.8264 0.6396 0.2421 0.029 Uiso 1 1 calc R . .
C6 C 0.8728(3) 0.5559(5) 0.11855(18) 0.0436(14) Uani 1 1 d . . .
H6 H 0.8851 0.5357 0.0867 0.052 Uiso 1 1 calc R . .
C7 C 0.8891(2) 0.5492(3) 0.20492(16) 0.0251(8) Uani 1 1 d . . .
H7 H 0.9131 0.5248 0.2332 0.030 Uiso 1 1 calc R . .
C8 C 0.9066(3) 0.5150(3) 0.15931(19) 0.0302(9) Uani 1 1 d . . .
C9 C 0.9582(3) 0.4348(4) 0.1540(2) 0.0411(12) Uani 1 1 d . . .
H9A H 0.9933 0.4340 0.1816 0.062 Uiso 1 1 d R . .
H9B H 0.9847 0.4409 0.1234 0.062 Uiso 1 1 d R . .
H9C H 0.9300 0.3777 0.1535 0.062 Uiso 1 1 d R . .
C11 C 0.8841(2) 0.9197(3) 0.17063(15) 0.0212(7) Uani 1 1 d . . .
C12 C 0.8969(2) 0.8803(3) 0.13250(16) 0.0243(8) Uani 1 1 d . . .
C13 C 0.9213(2) 0.8322(3) 0.08980(15) 0.0256(8) Uani 1 1 d . . .
C14 C 0.8736(3) 0.8084(4) 0.05153(17) 0.0330(10) Uani 1 1 d . . .
H14 H 0.8228 0.8217 0.0536 0.040 Uiso 1 1 calc R . .
C15 C 0.9962(3) 0.8111(4) 0.08576(16) 0.0300(9) Uani 1 1 d . . .
H15 H 1.0295 0.8252 0.1119 0.036 Uiso 1 1 calc R . .
C16 C 0.9001(3) 0.7649(4) 0.01001(19) 0.0408(12) Uani 1 1 d . . .
H16 H 0.8667 0.7476 -0.0155 0.049 Uiso 1 1 calc R . .
C17 C 1.0216(3) 0.7696(4) 0.04363(17) 0.0351(10) Uani 1 1 d . . .
H17 H 1.0724 0.7569 0.0411 0.042 Uiso 1 1 calc R . .
C18 C 0.9741(3) 0.7464(4) 0.00503(19) 0.0394(12) Uani 1 1 d . . .
C19 C 1.0033(4) 0.7020(5) -0.0407(2) 0.0489(15) Uani 1 1 d . . .
H19A H 1.0491 0.7322 -0.0498 0.073 Uiso 1 1 d R . .
H19B H 0.9671 0.7083 -0.0676 0.073 Uiso 1 1 d R . .
H19C H 1.0128 0.6370 -0.0345 0.073 Uiso 1 1 d R . .
C21 C 0.6488(2) 0.9310(3) 0.12114(15) 0.0214(7) Uani 1 1 d . . .
C22 C 0.6698(2) 0.9582(3) 0.08154(15) 0.0226(7) Uani 1 1 d . . .
C23 C 0.6779(3) 0.9902(3) 0.03205(16) 0.0236(8) Uani 1 1 d . . .
C24 C 0.6161(3) 1.0047(4) 0.00250(19) 0.0355(11) Uani 1 1 d . . .
H24 H 0.5688 0.9932 0.0150 0.043 Uiso 1 1 calc R . .
C25 C 0.7462(3) 1.0076(3) 0.01288(19) 0.0320(10) Uani 1 1 d . . .
H25 H 0.7894 0.9977 0.0323 0.038 Uiso 1 1 calc R . .
C26 C 0.6229(4) 1.0358(5) -0.0447(2) 0.0475(14) Uani 1 1 d . . .
H26 H 0.5800 1.0450 -0.0644 0.057 Uiso 1 1 calc R . .
C27 C 0.7514(3) 1.0398(4) -0.03507(19) 0.0386(11) Uani 1 1 d . . .
H27 H 0.7984 1.0523 -0.0478 0.046 Uiso 1 1 calc R . .
C28 C 0.6906(4) 1.0538(4) -0.06404(18) 0.0398(12) Uani 1 1 d . . .
C29 C 0.6989(6) 1.0872(5) -0.1164(2) 0.065(2) Uani 1 1 d . . .
H29A H 0.6949 1.1541 -0.1173 0.097 Uiso 1 1 d R . .
H29B H 0.6603 1.0603 -0.1373 0.097 Uiso 1 1 d R . .
H29C H 0.7470 1.0687 -0.1283 0.097 Uiso 1 1 d R . .
C31 C 0.8742(2) 0.8778(3) 0.27274(14) 0.0198(7) Uani 1 1 d . . .
C32 C 0.8804(2) 0.8091(3) 0.29815(16) 0.0241(8) Uani 1 1 d . . .
C33 C 0.8982(2) 0.7345(3) 0.33045(16) 0.0245(8) Uani 1 1 d . . .
C34 C 0.8467(3) 0.7019(4) 0.3632(2) 0.0344(10) Uani 1 1 d . . .
H34 H 0.7984 0.7260 0.3622 0.041 Uiso 1 1 calc R . .
C35 C 0.9683(3) 0.6956(3) 0.33100(17) 0.0294(9) Uani 1 1 d . . .
H35 H 1.0036 0.7152 0.3082 0.035 Uiso 1 1 calc R . .
C36 C 0.8653(3) 0.6349(4) 0.3970(2) 0.0412(12) Uani 1 1 d . . .
H36 H 0.8294 0.6137 0.4190 0.049 Uiso 1 1 calc R . .
C37 C 0.9861(3) 0.6282(4) 0.3650(2) 0.0362(11) Uani 1 1 d . . .
H37 H 1.0336 0.6017 0.3650 0.043 Uiso 1 1 calc R . .
C38 C 0.9358(3) 0.5980(4) 0.3995(2) 0.0431(13) Uani 1 1 d . . .
C39 C 0.9593(4) 0.5333(6) 0.4397(3) 0.066(2) Uani 1 1 d . . .
H39A H 0.9490 0.5607 0.4715 0.099 Uiso 1 1 d R . .
H39B H 1.0120 0.5213 0.4376 0.099 Uiso 1 1 d R . .
H39C H 0.9322 0.4756 0.4361 0.099 Uiso 1 1 d R . .
C41 C 0.8323(2) 1.0960(3) 0.18800(14) 0.0203(7) Uani 1 1 d . . .
C42 C 0.8121(2) 1.1567(3) 0.16074(15) 0.0242(8) Uani 1 1 d . . .
C43 C 0.7891(2) 1.2310(3) 0.12944(16) 0.0256(8) Uani 1 1 d . . .
C44 C 0.7711(4) 1.3153(4) 0.1497(2) 0.0397(12) Uani 1 1 d . . .
H44 H 0.7738 1.3239 0.1841 0.048 Uiso 1 1 calc R . .
C45 C 0.7843(4) 1.2207(4) 0.0789(2) 0.0414(12) Uani 1 1 d . . .
H45 H 0.7967 1.1637 0.0646 0.050 Uiso 1 1 calc R . .
C46 C 0.7489(5) 1.3869(4) 0.1191(3) 0.0561(19) Uani 1 1 d . . .
H46 H 0.7370 1.4444 0.1330 0.067 Uiso 1 1 calc R . .
C47 C 0.7615(4) 1.2928(4) 0.0492(2) 0.0438(13) Uani 1 1 d . . .
H47 H 0.7582 1.2840 0.0148 0.053 Uiso 1 1 calc R . .
C48 C 0.7438(4) 1.3757(4) 0.0682(2) 0.0451(14) Uani 1 1 d . . .
C49 C 0.7202(6) 1.4531(5) 0.0353(3) 0.068(2) Uani 1 1 d . . .
H49A H 0.7587 1.4998 0.0349 0.103 Uiso 1 1 d R . .
H49B H 0.6750 1.4802 0.0475 0.103 Uiso 1 1 d R . .
H49C H 0.7114 1.4298 0.0021 0.103 Uiso 1 1 d R . .
C51 C 0.6244(2) 0.8436(3) 0.25926(15) 0.0222(7) Uani 1 1 d . . .
C52 C 0.6318(2) 0.8233(3) 0.30216(16) 0.0241(8) Uani 1 1 d . . .
C53 C 0.6367(2) 0.8090(3) 0.35415(15) 0.0233(8) Uani 1 1 d . . .
C54 C 0.6255(3) 0.8824(3) 0.38650(18) 0.0285(9) Uani 1 1 d . . .
H54 H 0.6118 0.9407 0.3738 0.034 Uiso 1 1 calc R . .
C55 C 0.6560(3) 0.7242(3) 0.37432(16) 0.0266(8) Uani 1 1 d . . .
H55 H 0.6627 0.6730 0.3534 0.032 Uiso 1 1 calc R . .
C56 C 0.6342(3) 0.8709(3) 0.43637(17) 0.0293(9) Uani 1 1 d . . .
H56 H 0.6249 0.9209 0.4576 0.035 Uiso 1 1 calc R . .
C57 C 0.6657(3) 0.7139(3) 0.42454(16) 0.0276(8) Uani 1 1 d . . .
H57 H 0.6790 0.6557 0.4375 0.033 Uiso 1 1 calc R . .
C58 C 0.6563(2) 0.7873(3) 0.45615(16) 0.0263(8) Uani 1 1 d . . .
C59 C 0.6703(3) 0.7773(4) 0.51042(17) 0.0341(10) Uani 1 1 d . . .
H59A H 0.6641 0.7131 0.5198 0.051 Uiso 1 1 d R . .
H59B H 0.6354 0.8154 0.5281 0.051 Uiso 1 1 d R . .
H59C H 0.7204 0.7970 0.5186 0.051 Uiso 1 1 d R . .
C01 C 0.4318(6) -0.0026(8) 0.3911(5) 0.042(3) Uani 0.50 1 d P . .
H01A H 0.4704 -0.0183 0.3677 0.050 Uiso 0.50 1 calc PR . .
H01B H 0.3996 -0.0568 0.3943 0.050 Uiso 0.50 1 calc PR . .
C101 C 0.8464(2) 1.0409(3) 0.35811(14) 0.0206(7) Uani 1 1 d . . .
C102 C 0.8077(2) 0.9649(3) 0.37510(16) 0.0261(8) Uani 1 1 d . . .
H102 H 0.7718 0.9363 0.3546 0.031 Uiso 1 1 calc R . .
C103 C 0.8217(3) 0.9314(4) 0.42172(17) 0.0315(9) Uani 1 1 d . . .
H103 H 0.7952 0.8800 0.4331 0.038 Uiso 1 1 calc R . .
C104 C 0.8736(3) 0.9721(4) 0.45176(18) 0.0407(12) Uani 1 1 d . . .
H104 H 0.8827 0.9489 0.4838 0.049 Uiso 1 1 calc R . .
C105 C 0.9124(4) 1.0466(4) 0.4355(2) 0.0475(15) Uani 1 1 d . . .
H105 H 0.9487 1.0740 0.4562 0.057 Uiso 1 1 calc R . .
C106 C 0.8986(3) 1.0820(4) 0.38844(18) 0.0350(10) Uani 1 1 d . . .
H106 H 0.9249 1.1339 0.3774 0.042 Uiso 1 1 calc R . .
C111 C 0.8672(2) 1.1931(3) 0.29383(14) 0.0200(7) Uani 1 1 d . . .
C112 C 0.9431(2) 1.1958(3) 0.28794(15) 0.0234(8) Uani 1 1 d . . .
H112 H 0.9696 1.1404 0.2844 0.028 Uiso 1 1 calc R . .
C113 C 0.9797(2) 1.2790(3) 0.28728(16) 0.0269(8) Uani 1 1 d . . .
H113 H 1.0314 1.2805 0.2838 0.032 Uiso 1 1 calc R . .
C114 C 0.9406(2) 1.3599(3) 0.29174(16) 0.0270(8) Uani 1 1 d . . .
H114 H 0.9656 1.4169 0.2915 0.032 Uiso 1 1 calc R . .
C115 C 0.8653(3) 1.3581(3) 0.29654(18) 0.0295(9) Uani 1 1 d . . .
H115 H 0.8387 1.4137 0.2991 0.035 Uiso 1 1 calc R . .
C116 C 0.8285(2) 1.2743(3) 0.29758(17) 0.0258(8) Uani 1 1 d . . .
H116 H 0.7768 1.2730 0.3009 0.031 Uiso 1 1 calc R . .
C121 C 0.5542(2) 1.1038(3) 0.16440(15) 0.0209(7) Uani 1 1 d . . .
C122 C 0.5768(5) 1.1920(5) 0.1747(2) 0.063(2) Uani 1 1 d . . .
H122 H 0.5992 1.2055 0.2056 0.075 Uiso 1 1 calc R . .
C123 C 0.5670(5) 1.2620(5) 0.1401(3) 0.072(3) Uani 1 1 d . . .
H123 H 0.5798 1.3234 0.1480 0.086 Uiso 1 1 calc R . .
C124 C 0.5383(3) 1.2404(4) 0.09423(18) 0.0369(11) Uani 1 1 d . . .
H124 H 0.5346 1.2865 0.0698 0.044 Uiso 1 1 calc R . .
C125 C 0.5155(3) 1.1542(4) 0.08391(18) 0.0389(12) Uani 1 1 d . . .
H125 H 0.4942 1.1406 0.0527 0.047 Uiso 1 1 calc R . .
C126 C 0.5232(3) 1.0855(4) 0.11904(19) 0.0404(12) Uani 1 1 d . . .
H126 H 0.5069 1.0252 0.1116 0.049 Uiso 1 1 calc R . .
C131 C 0.4666(2) 0.9954(3) 0.22720(15) 0.0195(7) Uani 1 1 d . . .
C132 C 0.4193(2) 1.0705(3) 0.23013(15) 0.0230(8) Uani 1 1 d . . .
H132 H 0.4367 1.1301 0.2228 0.028 Uiso 1 1 calc R . .
C133 C 0.3470(2) 1.0583(3) 0.24368(17) 0.0269(8) Uani 1 1 d . . .
H133 H 0.3152 1.1096 0.2459 0.032 Uiso 1 1 calc R . .
C134 C 0.3212(2) 0.9710(4) 0.25392(17) 0.0292(9) Uani 1 1 d . . .
H134 H 0.2718 0.9625 0.2633 0.035 Uiso 1 1 calc R . .
C135 C 0.3677(3) 0.8959(3) 0.2503(2) 0.0315(10) Uani 1 1 d . . .
H135 H 0.3501 0.8361 0.2570 0.038 Uiso 1 1 calc R . .
C136 C 0.4409(2) 0.9088(3) 0.23682(17) 0.0263(8) Uani 1 1 d . . .
H136 H 0.4727 0.8576 0.2343 0.032 Uiso 1 1 calc R . .
C201 C 0.6841(2) 1.0647(3) 0.25968(14) 0.0196(7) Uani 1 1 d . . .
H201 H 0.7069 1.0396 0.2318 0.023 Uiso 1 1 calc R . .
C202 C 0.7272(2) 1.0981(3) 0.29805(14) 0.0184(7) Uani 1 1 d . . .
C203 C 0.6073(2) 1.0672(3) 0.26136(14) 0.0195(7) Uani 1 1 d . . .
C204 C 0.6934(2) 1.1383(3) 0.33832(14) 0.0194(7) Uani 1 1 d . . .
H204 H 0.7227 1.1615 0.3647 0.023 Uiso 1 1 calc R . .
C205 C 0.5746(2) 1.1078(3) 0.30114(15) 0.0212(7) Uani 1 1 d . . .
H205 H 0.5226 1.1110 0.3023 0.025 Uiso 1 1 calc R . .
C206 C 0.6176(2) 1.1446(3) 0.34001(13) 0.0197(7) Uani 1 1 d . . .
C207 C 0.5830(2) 1.1894(3) 0.38238(14) 0.0246(8) Uani 1 1 d . . .
C208 C 0.5178(2) 1.2375(4) 0.37802(16) 0.0288(9) Uani 1 1 d . . .
H208 H 0.4935 1.2428 0.3470 0.035 Uiso 1 1 calc R . .
C209 C 0.6157(3) 1.1852(5) 0.42902(16) 0.0372(12) Uani 1 1 d . . .
H209 H 0.6602 1.1523 0.4342 0.045 Uiso 1 1 calc R . .
C210 C 0.4879(3) 1.2778(4) 0.41901(18) 0.0371(11) Uani 1 1 d . . .
H210 H 0.4430 1.3100 0.4151 0.045 Uiso 1 1 calc R . .
C211 C 0.5829(3) 1.2291(6) 0.46756(18) 0.0513(18) Uani 1 1 d . . .
H211 H 0.6072 1.2276 0.4987 0.062 Uiso 1 1 calc R . .
Cl1 Cl 0.47370(15) 0.0217(2) 0.44925(13) 0.0487(7) Uani 0.50 1 d P . .
Cl2 Cl 0.38080(13) 0.08704(17) 0.36789(9) 0.0331(4) Uani 0.50 1 d P . .
N1 N 0.5190(3) 1.2736(4) 0.46371(16) 0.0463(13) Uani 1 1 d . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C11 2.259(4) . ?
Ag1 C21 2.283(4) . ?
Ag1 C22 2.402(4) . ?
Ag1 C12 2.514(4) . ?
Ag1 Pt2 3.0062(9) . ?
Ag1 Pt1 3.0831(9) . ?
Ag2 C31 2.291(4) . ?
Ag2 C51 2.413(4) . ?
Ag2 C1 2.490(4) . ?
Ag2 C32 2.545(4) . ?
Ag2 C52 2.626(4) . ?
Ag2 Pt1 3.0161(9) . ?
Ag2 Pt2 3.0317(6) . ?
Pt1 C21 2.010(4) . ?
Pt1 C1 2.013(4) . ?
Pt1 C51 2.018(4) . ?
Pt1 P2 2.2994(11) . ?
Pt2 C41 1.999(4) . ?
Pt2 C31 2.008(4) . ?
Pt2 C11 2.021(4) . ?
Pt2 P1 2.2933(10) . ?
P1 C111 1.810(4) . ?
P1 C202 1.820(4) . ?
P1 C101 1.824(4) . ?
P2 C121 1.813(4) . ?
P2 C203 1.819(4) . ?
P2 C131 1.822(4) . ?
C1 C2 1.217(6) . ?
C2 C3 1.431(6) . ?
C3 C4 1.393(6) . ?
C3 C5 1.396(6) . ?
C4 C6 1.381(7) . ?
C4 H4 0.9500 . ?
C5 C7 1.388(6) . ?
C5 H5 0.9500 . ?
C6 C8 1.395(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.387(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.512(7) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C11 C12 1.218(6) . ?
C12 C13 1.442(6) . ?
C13 C14 1.390(6) . ?
C13 C15 1.408(6) . ?
C14 C16 1.397(7) . ?
C14 H14 0.9500 . ?
C15 C17 1.390(6) . ?
C15 H15 0.9500 . ?
C16 C18 1.386(8) . ?
C16 H16 0.9500 . ?
C17 C18 1.392(7) . ?
C17 H17 0.9500 . ?
C18 C19 1.517(7) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C21 C22 1.223(6) . ?
C22 C23 1.442(6) . ?
C23 C25 1.387(7) . ?
C23 C24 1.389(6) . ?
C24 C26 1.376(7) . ?
C24 H24 0.9500 . ?
C25 C27 1.398(7) . ?
C25 H25 0.9500 . ?
C26 C28 1.380(9) . ?
C26 H26 0.9500 . ?
C27 C28 1.365(9) . ?
C27 H27 0.9500 . ?
C28 C29 1.524(8) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C31 C32 1.225(6) . ?
C32 C33 1.435(6) . ?
C33 C34 1.396(6) . ?
C33 C35 1.400(6) . ?
C34 C36 1.383(7) . ?
C34 H34 0.9500 . ?
C35 C37 1.388(7) . ?
C35 H35 0.9500 . ?
C36 C38 1.394(8) . ?
C36 H36 0.9500 . ?
C37 C38 1.402(7) . ?
C37 H37 0.9500 . ?
C38 C39 1.504(8) . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C41 C42 1.211(6) . ?
C42 C43 1.438(6) . ?
C43 C45 1.390(7) . ?
C43 C44 1.391(7) . ?
C44 C46 1.393(8) . ?
C44 H44 0.9500 . ?
C45 C47 1.388(8) . ?
C45 H45 0.9500 . ?
C46 C48 1.400(9) . ?
C46 H46 0.9500 . ?
C47 C48 1.360(9) . ?
C47 H47 0.9500 . ?
C48 C49 1.501(8) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C51 C52 1.214(6) . ?
C52 C53 1.437(6) . ?
C53 C55 1.398(6) . ?
C53 C54 1.408(6) . ?
C54 C56 1.379(7) . ?
C54 H54 0.9500 . ?
C55 C57 1.388(6) . ?
C55 H55 0.9500 . ?
C56 C58 1.392(7) . ?
C56 H56 0.9500 . ?
C57 C58 1.391(7) . ?
C57 H57 0.9500 . ?
C58 C59 1.506(6) . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C01 Cl2 1.719(13) . ?
C01 Cl1 1.784(14) . ?
C01 H01A 0.9900 . ?
C01 H01B 0.9900 . ?
C101 C106 1.385(6) . ?
C101 C102 1.400(6) . ?
C102 C103 1.383(6) . ?
C102 H102 0.9500 . ?
C103 C104 1.375(7) . ?
C103 H103 0.9500 . ?
C104 C105 1.377(8) . ?
C104 H104 0.9500 . ?
C105 C106 1.404(7) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C111 C116 1.386(6) . ?
C111 C112 1.397(5) . ?
C112 C113 1.387(6) . ?
C112 H112 0.9500 . ?
C113 C114 1.388(7) . ?
C113 H113 0.9500 . ?
C114 C115 1.384(6) . ?
C114 H114 0.9500 . ?
C115 C116 1.396(6) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C121 C126 1.377(6) . ?
C121 C122 1.380(7) . ?
C122 C123 1.402(8) . ?
C122 H122 0.9500 . ?
C123 C124 1.384(9) . ?
C123 H123 0.9500 . ?
C124 C125 1.353(9) . ?
C124 H124 0.9500 . ?
C125 C126 1.394(7) . ?
C125 H125 0.9500 . ?
C126 H126 0.9500 . ?
C131 C136 1.376(6) . ?
C131 C132 1.400(6) . ?
C132 C133 1.390(5) . ?
C132 H132 0.9500 . ?
C133 C134 1.391(7) . ?
C133 H133 0.9500 . ?
C134 C135 1.391(7) . ?
C134 H134 0.9500 . ?
C135 C136 1.407(6) . ?
C135 H135 0.9500 . ?
C136 H136 0.9500 . ?
C201 C202 1.385(5) . ?
C201 C203 1.403(5) . ?
C201 H201 0.9500 . ?
C202 C204 1.402(5) . ?
C203 C205 1.387(5) . ?
C204 C206 1.388(5) . ?
C204 H204 0.9500 . ?
C205 C206 1.413(6) . ?
C205 H205 0.9500 . ?
C206 C207 1.483(5) . ?
C207 C208 1.385(6) . ?
C207 C209 1.396(6) . ?
C208 C210 1.388(6) . ?
C208 H208 0.9500 . ?
C209 C211 1.382(7) . ?
C209 H209 0.9500 . ?
C210 N1 1.336(7) . ?
C210 H210 0.9500 . ?
C211 N1 1.338(7) . ?
C211 H211 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Ag1 C21 160.43(16) . . ?
C11 Ag1 C22 160.53(14) . . ?
C21 Ag1 C22 30.13(15) . . ?
C11 Ag1 C12 28.93(14) . . ?
C21 Ag1 C12 146.22(15) . . ?
C22 Ag1 C12 131.79(14) . . ?
C11 Ag1 Pt2 42.22(10) . . ?
C21 Ag1 Pt2 133.98(10) . . ?
C22 Ag1 Pt2 156.61(10) . . ?
C12 Ag1 Pt2 71.15(10) . . ?
C11 Ag1 Pt1 123.16(11) . . ?
C21 Ag1 Pt1 40.68(10) . . ?
C22 Ag1 Pt1 70.80(11) . . ?
C12 Ag1 Pt1 134.00(11) . . ?
Pt2 Ag1 Pt1 96.73(2) . . ?
C31 Ag2 C51 155.00(14) . . ?
C31 Ag2 C1 130.07(14) . . ?
C51 Ag2 C1 69.26(14) . . ?
C31 Ag2 C32 28.72(15) . . ?
C51 Ag2 C32 150.39(14) . . ?
C1 Ag2 C32 135.23(14) . . ?
C31 Ag2 C52 137.44(14) . . ?
C51 Ag2 C52 27.47(14) . . ?
C1 Ag2 C52 92.38(13) . . ?
C32 Ag2 C52 122.98(14) . . ?
C31 Ag2 Pt1 138.76(10) . . ?
C51 Ag2 Pt1 41.83(10) . . ?
C1 Ag2 Pt1 41.53(9) . . ?
C32 Ag2 Pt1 166.62(10) . . ?
C52 Ag2 Pt1 69.24(10) . . ?
C31 Ag2 Pt2 41.48(10) . . ?
C51 Ag2 Pt2 124.81(11) . . ?
C1 Ag2 Pt2 106.95(10) . . ?
C32 Ag2 Pt2 70.19(10) . . ?
C52 Ag2 Pt2 133.08(10) . . ?
Pt1 Ag2 Pt2 97.629(16) . . ?
C21 Pt1 C1 88.68(17) . . ?
C21 Pt1 C51 172.27(16) . . ?
C1 Pt1 C51 87.48(17) . . ?
C21 Pt1 P2 93.97(12) . . ?
C1 Pt1 P2 173.32(12) . . ?
C51 Pt1 P2 89.15(13) . . ?
C21 Pt1 Ag2 119.59(12) . . ?
C1 Pt1 Ag2 55.10(11) . . ?
C51 Pt1 Ag2 52.87(12) . . ?
P2 Pt1 Ag2 118.42(3) . . ?
C21 Pt1 Ag1 47.76(12) . . ?
C1 Pt1 Ag1 67.93(12) . . ?
C51 Pt1 Ag1 124.51(12) . . ?
P2 Pt1 Ag1 109.57(3) . . ?
Ag2 Pt1 Ag1 72.833(17) . . ?
C41 Pt2 C31 174.84(16) . . ?
C41 Pt2 C11 87.81(16) . . ?
C31 Pt2 C11 90.75(16) . . ?
C41 Pt2 P1 87.17(11) . . ?
C31 Pt2 P1 94.31(12) . . ?
C11 Pt2 P1 174.94(12) . . ?
C41 Pt2 Ag1 63.37(12) . . ?
C31 Pt2 Ag1 112.13(12) . . ?
C11 Pt2 Ag1 48.71(11) . . ?
P1 Pt2 Ag1 128.85(3) . . ?
C41 Pt2 Ag2 125.88(12) . . ?
C31 Pt2 Ag2 49.08(11) . . ?
C11 Pt2 Ag2 87.56(12) . . ?
P1 Pt2 Ag2 95.92(3) . . ?
Ag1 Pt2 Ag2 73.702(17) . . ?
C111 P1 C202 106.71(18) . . ?
C111 P1 C101 104.03(19) . . ?
C202 P1 C101 101.49(18) . . ?
C111 P1 Pt2 112.74(13) . . ?
C202 P1 Pt2 111.74(13) . . ?
C101 P1 Pt2 118.88(14) . . ?
C121 P2 C203 103.46(19) . . ?
C121 P2 C131 103.41(18) . . ?
C203 P2 C131 106.02(18) . . ?
C121 P2 Pt1 117.15(14) . . ?
C203 P2 Pt1 107.14(13) . . ?
C131 P2 Pt1 118.25(14) . . ?
C2 C1 Pt1 169.8(4) . . ?
C2 C1 Ag2 87.4(3) . . ?
Pt1 C1 Ag2 83.37(14) . . ?
C1 C2 C3 176.4(5) . . ?
C4 C3 C5 117.9(4) . . ?
C4 C3 C2 121.2(4) . . ?
C5 C3 C2 121.0(4) . . ?
C6 C4 C3 121.0(4) . . ?
C6 C4 H4 119.5 . . ?
C3 C4 H4 119.5 . . ?
C7 C5 C3 120.5(4) . . ?
C7 C5 H5 119.8 . . ?
C3 C5 H5 119.8 . . ?
C4 C6 C8 121.5(5) . . ?
C4 C6 H6 119.3 . . ?
C8 C6 H6 119.3 . . ?
C8 C7 C5 121.8(4) . . ?
C8 C7 H7 119.1 . . ?
C5 C7 H7 119.1 . . ?
C7 C8 C6 117.2(4) . . ?
C7 C8 C9 121.5(4) . . ?
C6 C8 C9 121.3(5) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C12 C11 Pt2 176.0(4) . . ?
C12 C11 Ag1 87.2(3) . . ?
Pt2 C11 Ag1 89.06(15) . . ?
C11 C12 C13 172.7(5) . . ?
C11 C12 Ag1 63.8(3) . . ?
C13 C12 Ag1 123.4(3) . . ?
C14 C13 C15 118.6(4) . . ?
C14 C13 C12 122.1(4) . . ?
C15 C13 C12 119.3(4) . . ?
C13 C14 C16 120.1(5) . . ?
C13 C14 H14 119.9 . . ?
C16 C14 H14 119.9 . . ?
C17 C15 C13 120.2(4) . . ?
C17 C15 H15 119.9 . . ?
C13 C15 H15 119.9 . . ?
C18 C16 C14 121.7(5) . . ?
C18 C16 H16 119.1 . . ?
C14 C16 H16 119.1 . . ?
C15 C17 C18 121.4(5) . . ?
C15 C17 H17 119.3 . . ?
C18 C17 H17 119.3 . . ?
C16 C18 C17 117.9(5) . . ?
C16 C18 C19 121.8(5) . . ?
C17 C18 C19 120.3(5) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C22 C21 Pt1 171.9(4) . . ?
C22 C21 Ag1 80.3(3) . . ?
Pt1 C21 Ag1 91.57(16) . . ?
C21 C22 C23 167.6(4) . . ?
C21 C22 Ag1 69.6(3) . . ?
C23 C22 Ag1 122.8(3) . . ?
C25 C23 C24 118.5(4) . . ?
C25 C23 C22 121.8(4) . . ?
C24 C23 C22 119.7(4) . . ?
C26 C24 C23 120.5(5) . . ?
C26 C24 H24 119.8 . . ?
C23 C24 H24 119.8 . . ?
C23 C25 C27 119.8(5) . . ?
C23 C25 H25 120.1 . . ?
C27 C25 H25 120.1 . . ?
C24 C26 C28 121.5(5) . . ?
C24 C26 H26 119.3 . . ?
C28 C26 H26 119.3 . . ?
C28 C27 C25 121.5(5) . . ?
C28 C27 H27 119.3 . . ?
C25 C27 H27 119.3 . . ?
C27 C28 C26 118.3(5) . . ?
C27 C28 C29 119.7(6) . . ?
C26 C28 C29 122.0(6) . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C32 C31 Pt2 176.5(4) . . ?
C32 C31 Ag2 87.2(3) . . ?
Pt2 C31 Ag2 89.45(14) . . ?
C31 C32 C33 171.1(4) . . ?
C31 C32 Ag2 64.0(3) . . ?
C33 C32 Ag2 124.7(3) . . ?
C34 C33 C35 118.9(4) . . ?
C34 C33 C32 120.5(4) . . ?
C35 C33 C32 120.6(4) . . ?
C36 C34 C33 120.8(4) . . ?
C36 C34 H34 119.6 . . ?
C33 C34 H34 119.6 . . ?
C37 C35 C33 119.6(4) . . ?
C37 C35 H35 120.2 . . ?
C33 C35 H35 120.2 . . ?
C34 C36 C38 121.2(5) . . ?
C34 C36 H36 119.4 . . ?
C38 C36 H36 119.4 . . ?
C35 C37 C38 121.8(5) . . ?
C35 C37 H37 119.1 . . ?
C38 C37 H37 119.1 . . ?
C36 C38 C37 117.6(5) . . ?
C36 C38 C39 121.7(5) . . ?
C37 C38 C39 120.5(5) . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C42 C41 Pt2 174.9(4) . . ?
C41 C42 C43 178.2(5) . . ?
C45 C43 C44 118.7(4) . . ?
C45 C43 C42 121.4(4) . . ?
C44 C43 C42 119.9(4) . . ?
C43 C44 C46 119.6(5) . . ?
C43 C44 H44 120.2 . . ?
C46 C44 H44 120.2 . . ?
C47 C45 C43 120.7(5) . . ?
C47 C45 H45 119.6 . . ?
C43 C45 H45 119.6 . . ?
C44 C46 C48 121.3(6) . . ?
C44 C46 H46 119.3 . . ?
C48 C46 H46 119.3 . . ?
C48 C47 C45 121.5(5) . . ?
C48 C47 H47 119.3 . . ?
C45 C47 H47 119.3 . . ?
C47 C48 C46 118.2(5) . . ?
C47 C48 C49 120.6(6) . . ?
C46 C48 C49 121.2(6) . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C52 C51 Pt1 170.3(4) . . ?
C52 C51 Ag2 86.1(3) . . ?
Pt1 C51 Ag2 85.30(15) . . ?
C51 C52 C53 173.5(5) . . ?
C51 C52 Ag2 66.4(3) . . ?
C53 C52 Ag2 116.7(3) . . ?
C55 C53 C54 117.8(4) . . ?
C55 C53 C52 121.8(4) . . ?
C54 C53 C52 120.3(4) . . ?
C56 C54 C53 120.9(4) . . ?
C56 C54 H54 119.6 . . ?
C53 C54 H54 119.6 . . ?
C57 C55 C53 120.8(4) . . ?
C57 C55 H55 119.6 . . ?
C53 C55 H55 119.6 . . ?
C54 C56 C58 121.1(4) . . ?
C54 C56 H56 119.5 . . ?
C58 C56 H56 119.5 . . ?
C55 C57 C58 121.1(4) . . ?
C55 C57 H57 119.5 . . ?
C58 C57 H57 119.5 . . ?
C57 C58 C56 118.3(4) . . ?
C57 C58 C59 121.1(4) . . ?
C56 C58 C59 120.6(4) . . ?
C58 C59 H59A 109.5 . . ?
C58 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C58 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
Cl2 C01 Cl1 113.2(6) . . ?
Cl2 C01 H01A 108.9 . . ?
Cl1 C01 H01A 108.9 . . ?
Cl2 C01 H01B 108.9 . . ?
Cl1 C01 H01B 108.9 . . ?
H01A C01 H01B 107.7 . . ?
C106 C101 C102 119.3(4) . . ?
C106 C101 P1 122.9(3) . . ?
C102 C101 P1 117.8(3) . . ?
C103 C102 C101 120.1(4) . . ?
C103 C102 H102 119.9 . . ?
C101 C102 H102 119.9 . . ?
C104 C103 C102 120.5(5) . . ?
C104 C103 H103 119.8 . . ?
C102 C103 H103 119.8 . . ?
C103 C104 C105 120.1(5) . . ?
C103 C104 H104 119.9 . . ?
C105 C104 H104 119.9 . . ?
C104 C105 C106 120.2(5) . . ?
C104 C105 H105 119.9 . . ?
C106 C105 H105 119.9 . . ?
C101 C106 C105 119.7(5) . . ?
C101 C106 H106 120.1 . . ?
C105 C106 H106 120.1 . . ?
C116 C111 C112 119.5(4) . . ?
C116 C111 P1 124.1(3) . . ?
C112 C111 P1 116.4(3) . . ?
C113 C112 C111 120.4(4) . . ?
C113 C112 H112 119.8 . . ?
C111 C112 H112 119.8 . . ?
C112 C113 C114 119.7(4) . . ?
C112 C113 H113 120.2 . . ?
C114 C113 H113 120.2 . . ?
C115 C114 C113 120.4(4) . . ?
C115 C114 H114 119.8 . . ?
C113 C114 H114 119.8 . . ?
C114 C115 C116 119.8(4) . . ?
C114 C115 H115 120.1 . . ?
C116 C115 H115 120.1 . . ?
C111 C116 C115 120.1(4) . . ?
C111 C116 H116 119.9 . . ?
C115 C116 H116 119.9 . . ?
C126 C121 C122 118.7(4) . . ?
C126 C121 P2 119.2(4) . . ?
C122 C121 P2 122.0(3) . . ?
C121 C122 C123 120.6(6) . . ?
C121 C122 H122 119.7 . . ?
C123 C122 H122 119.7 . . ?
C124 C123 C122 119.0(7) . . ?
C124 C123 H123 120.5 . . ?
C122 C123 H123 120.5 . . ?
C125 C124 C123 120.6(5) . . ?
C125 C124 H124 119.7 . . ?
C123 C124 H124 119.7 . . ?
C124 C125 C126 120.0(5) . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C121 C126 C125 120.9(5) . . ?
C121 C126 H126 119.6 . . ?
C125 C126 H126 119.6 . . ?
C136 C131 C132 119.8(4) . . ?
C136 C131 P2 120.5(3) . . ?
C132 C131 P2 119.7(3) . . ?
C133 C132 C131 120.4(4) . . ?
C133 C132 H132 119.8 . . ?
C131 C132 H132 119.8 . . ?
C132 C133 C134 119.9(4) . . ?
C132 C133 H133 120.0 . . ?
C134 C133 H133 120.0 . . ?
C133 C134 C135 119.9(4) . . ?
C133 C134 H134 120.1 . . ?
C135 C134 H134 120.1 . . ?
C134 C135 C136 119.9(4) . . ?
C134 C135 H135 120.0 . . ?
C136 C135 H135 120.0 . . ?
C131 C136 C135 120.1(4) . . ?
C131 C136 H136 119.9 . . ?
C135 C136 H136 119.9 . . ?
C202 C201 C203 121.1(3) . . ?
C202 C201 H201 119.5 . . ?
C203 C201 H201 119.5 . . ?
C201 C202 C204 119.3(3) . . ?
C201 C202 P1 118.2(3) . . ?
C204 C202 P1 122.3(3) . . ?
C205 C203 C201 119.0(4) . . ?
C205 C203 P2 126.9(3) . . ?
C201 C203 P2 114.1(3) . . ?
C206 C204 C202 120.6(4) . . ?
C206 C204 H204 119.7 . . ?
C202 C204 H204 119.7 . . ?
C203 C205 C206 120.7(4) . . ?
C203 C205 H205 119.7 . . ?
C206 C205 H205 119.7 . . ?
C204 C206 C205 119.2(3) . . ?
C204 C206 C207 119.8(4) . . ?
C205 C206 C207 121.0(3) . . ?
C208 C207 C209 116.7(4) . . ?
C208 C207 C206 122.5(4) . . ?
C209 C207 C206 120.8(4) . . ?
C207 C208 C210 119.9(4) . . ?
C207 C208 H208 120.1 . . ?
C210 C208 H208 120.1 . . ?
C211 C209 C207 119.4(5) . . ?
C211 C209 H209 120.3 . . ?
C207 C209 H209 120.3 . . ?
N1 C210 C208 123.6(5) . . ?
N1 C210 H210 118.2 . . ?
C208 C210 H210 118.2 . . ?
N1 C211 C209 124.0(5) . . ?
N1 C211 H211 118.0 . . ?
C209 C211 H211 118.0 . . ?
C210 N1 C211 116.4(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C31 Ag2 Pt1 C21 36.0(2) . . . . ?
C51 Ag2 Pt1 C21 177.9(2) . . . . ?
C1 Ag2 Pt1 C21 -64.6(2) . . . . ?
C32 Ag2 Pt1 C21 18.5(5) . . . . ?
C52 Ag2 Pt1 C21 175.70(17) . . . . ?
Pt2 Ag2 Pt1 C21 42.37(14) . . . . ?
C31 Ag2 Pt1 C1 100.6(2) . . . . ?
C51 Ag2 Pt1 C1 -117.4(2) . . . . ?
C32 Ag2 Pt1 C1 83.1(5) . . . . ?
C52 Ag2 Pt1 C1 -119.67(18) . . . . ?
Pt2 Ag2 Pt1 C1 107.00(15) . . . . ?
C31 Ag2 Pt1 C51 -141.9(2) . . . . ?
C1 Ag2 Pt1 C51 117.4(2) . . . . ?
C32 Ag2 Pt1 C51 -159.5(5) . . . . ?
C52 Ag2 Pt1 C51 -2.23(19) . . . . ?
Pt2 Ag2 Pt1 C51 -135.56(16) . . . . ?
C31 Ag2 Pt1 P2 -77.43(16) . . . . ?
C51 Ag2 Pt1 P2 64.49(16) . . . . ?
C1 Ag2 Pt1 P2 -178.07(15) . . . . ?
C32 Ag2 Pt1 P2 -95.0(4) . . . . ?
C52 Ag2 Pt1 P2 62.26(11) . . . . ?
Pt2 Ag2 Pt1 P2 -71.08(4) . . . . ?
C31 Ag2 Pt1 Ag1 25.96(15) . . . . ?
C51 Ag2 Pt1 Ag1 167.87(16) . . . . ?
C1 Ag2 Pt1 Ag1 -74.69(15) . . . . ?
C32 Ag2 Pt1 Ag1 8.4(4) . . . . ?
C52 Ag2 Pt1 Ag1 165.64(10) . . . . ?
Pt2 Ag2 Pt1 Ag1 32.308(12) . . . . ?
C11 Ag1 Pt1 C21 -165.1(2) . . . . ?
C22 Ag1 Pt1 C21 -0.34(19) . . . . ?
C12 Ag1 Pt1 C21 -130.5(2) . . . . ?
Pt2 Ag1 Pt1 C21 159.30(16) . . . . ?
C11 Ag1 Pt1 C1 -55.60(18) . . . . ?
C21 Ag1 Pt1 C1 109.5(2) . . . . ?
C22 Ag1 Pt1 C1 109.21(16) . . . . ?
C12 Ag1 Pt1 C1 -20.93(19) . . . . ?
Pt2 Ag1 Pt1 C1 -91.15(12) . . . . ?
C11 Ag1 Pt1 C51 14.7(2) . . . . ?
C21 Ag1 Pt1 C51 179.9(2) . . . . ?
C22 Ag1 Pt1 C51 179.55(19) . . . . ?
C12 Ag1 Pt1 C51 49.4(2) . . . . ?
Pt2 Ag1 Pt1 C51 -20.81(15) . . . . ?
C11 Ag1 Pt1 P2 117.76(13) . . . . ?
C21 Ag1 Pt1 P2 -77.09(16) . . . . ?
C22 Ag1 Pt1 P2 -77.43(11) . . . . ?
C12 Ag1 Pt1 P2 152.44(14) . . . . ?
Pt2 Ag1 Pt1 P2 82.21(3) . . . . ?
C11 Ag1 Pt1 Ag2 3.01(13) . . . . ?
C21 Ag1 Pt1 Ag2 168.16(16) . . . . ?
C22 Ag1 Pt1 Ag2 167.82(11) . . . . ?
C12 Ag1 Pt1 Ag2 37.68(14) . . . . ?
Pt2 Ag1 Pt1 Ag2 -32.544(16) . . . . ?
C11 Ag1 Pt2 C41 112.5(2) . . . . ?
C21 Ag1 Pt2 C41 -95.19(19) . . . . ?
C22 Ag1 Pt2 C41 -58.0(3) . . . . ?
C12 Ag1 Pt2 C41 111.80(16) . . . . ?
Pt1 Ag1 Pt2 C41 -113.87(12) . . . . ?
C11 Ag1 Pt2 C31 -70.2(2) . . . . ?
C21 Ag1 Pt2 C31 82.04(19) . . . . ?
C22 Ag1 Pt2 C31 119.2(3) . . . . ?
C12 Ag1 Pt2 C31 -70.97(16) . . . . ?
Pt1 Ag1 Pt2 C31 63.36(12) . . . . ?
C21 Ag1 Pt2 C11 152.3(2) . . . . ?
C22 Ag1 Pt2 C11 -170.5(3) . . . . ?
C12 Ag1 Pt2 C11 -0.74(19) . . . . ?
Pt1 Ag1 Pt2 C11 133.59(16) . . . . ?
C11 Ag1 Pt2 P1 174.20(16) . . . . ?
C21 Ag1 Pt2 P1 -33.54(16) . . . . ?
C22 Ag1 Pt2 P1 3.6(3) . . . . ?
C12 Ag1 Pt2 P1 173.46(11) . . . . ?
Pt1 Ag1 Pt2 P1 -52.21(4) . . . . ?
C11 Ag1 Pt2 Ag2 -101.40(16) . . . . ?
C21 Ag1 Pt2 Ag2 50.86(15) . . . . ?
C22 Ag1 Pt2 Ag2 88.1(3) . . . . ?
C12 Ag1 Pt2 Ag2 -102.14(11) . . . . ?
Pt1 Ag1 Pt2 Ag2 32.191(13) . . . . ?
C31 Ag2 Pt2 C41 178.6(2) . . . . ?
C51 Ag2 Pt2 C41 -29.71(18) . . . . ?
C1 Ag2 Pt2 C41 46.47(17) . . . . ?
C32 Ag2 Pt2 C41 179.24(17) . . . . ?
C52 Ag2 Pt2 C41 -63.68(19) . . . . ?
Pt1 Ag2 Pt2 C41 4.96(14) . . . . ?
C51 Ag2 Pt2 C31 151.66(19) . . . . ?
C1 Ag2 Pt2 C31 -132.17(18) . . . . ?
C32 Ag2 Pt2 C31 0.60(19) . . . . ?
C52 Ag2 Pt2 C31 117.7(2) . . . . ?
Pt1 Ag2 Pt2 C31 -173.68(15) . . . . ?
C31 Ag2 Pt2 C11 93.11(19) . . . . ?
C51 Ag2 Pt2 C11 -115.23(17) . . . . ?
C1 Ag2 Pt2 C11 -39.06(15) . . . . ?
C32 Ag2 Pt2 C11 93.71(15) . . . . ?
C52 Ag2 Pt2 C11 -149.20(17) . . . . ?
Pt1 Ag2 Pt2 C11 -80.57(11) . . . . ?
C31 Ag2 Pt2 P1 -90.58(15) . . . . ?
C51 Ag2 Pt2 P1 61.07(12) . . . . ?
C1 Ag2 Pt2 P1 137.25(10) . . . . ?
C32 Ag2 Pt2 P1 -89.98(11) . . . . ?
C52 Ag2 Pt2 P1 27.11(13) . . . . ?
Pt1 Ag2 Pt2 P1 95.74(3) . . . . ?
C31 Ag2 Pt2 Ag1 140.61(15) . . . . ?
C51 Ag2 Pt2 Ag1 -67.73(12) . . . . ?
C1 Ag2 Pt2 Ag1 8.44(10) . . . . ?
C32 Ag2 Pt2 Ag1 141.21(11) . . . . ?
C52 Ag2 Pt2 Ag1 -101.70(13) . . . . ?
Pt1 Ag2 Pt2 Ag1 -33.070(17) . . . . ?
C41 Pt2 P1 C111 -48.14(18) . . . . ?
C31 Pt2 P1 C111 136.82(18) . . . . ?
C11 Pt2 P1 C111 -40.7(13) . . . . ?
Ag1 Pt2 P1 C111 -100.11(14) . . . . ?
Ag2 Pt2 P1 C111 -173.92(14) . . . . ?
C41 Pt2 P1 C202 72.05(18) . . . . ?
C31 Pt2 P1 C202 -103.00(18) . . . . ?
C11 Pt2 P1 C202 79.5(13) . . . . ?
Ag1 Pt2 P1 C202 20.08(15) . . . . ?
Ag2 Pt2 P1 C202 -53.73(14) . . . . ?
C41 Pt2 P1 C101 -170.25(19) . . . . ?
C31 Pt2 P1 C101 14.70(19) . . . . ?
C11 Pt2 P1 C101 -162.8(13) . . . . ?
Ag1 Pt2 P1 C101 137.78(15) . . . . ?
Ag2 Pt2 P1 C101 63.97(15) . . . . ?
C21 Pt1 P2 C121 -4.13(19) . . . . ?
C1 Pt1 P2 C121 109.1(11) . . . . ?
C51 Pt1 P2 C121 168.79(19) . . . . ?
Ag2 Pt1 P2 C121 122.77(15) . . . . ?
Ag1 Pt1 P2 C121 42.20(15) . . . . ?
C21 Pt1 P2 C203 -119.72(18) . . . . ?
C1 Pt1 P2 C203 -6.5(11) . . . . ?
C51 Pt1 P2 C203 53.20(18) . . . . ?
Ag2 Pt1 P2 C203 7.18(14) . . . . ?
Ag1 Pt1 P2 C203 -73.39(14) . . . . ?
C21 Pt1 P2 C131 120.71(19) . . . . ?
C1 Pt1 P2 C131 -126.1(11) . . . . ?
C51 Pt1 P2 C131 -66.37(19) . . . . ?
Ag2 Pt1 P2 C131 -112.39(15) . . . . ?
Ag1 Pt1 P2 C131 167.04(15) . . . . ?
C21 Pt1 C1 C2 102(2) . . . . ?
C51 Pt1 C1 C2 -71(2) . . . . ?
P2 Pt1 C1 C2 -12(3) . . . . ?
Ag2 Pt1 C1 C2 -26(2) . . . . ?
Ag1 Pt1 C1 C2 58(2) . . . . ?
C21 Pt1 C1 Ag2 128.20(15) . . . . ?
C51 Pt1 C1 Ag2 -45.09(14) . . . . ?
P2 Pt1 C1 Ag2 14.7(11) . . . . ?
Ag1 Pt1 C1 Ag2 83.94(9) . . . . ?
C31 Ag2 C1 C2 53.3(4) . . . . ?
C51 Ag2 C1 C2 -145.3(3) . . . . ?
C32 Ag2 C1 C2 14.5(4) . . . . ?
C52 Ag2 C1 C2 -130.1(3) . . . . ?
Pt1 Ag2 C1 C2 175.5(4) . . . . ?
Pt2 Ag2 C1 C2 93.2(3) . . . . ?
C31 Ag2 C1 Pt1 -122.15(16) . . . . ?
C51 Ag2 C1 Pt1 39.27(14) . . . . ?
C32 Ag2 C1 Pt1 -160.96(15) . . . . ?
C52 Ag2 C1 Pt1 54.41(15) . . . . ?
Pt2 Ag2 C1 Pt1 -82.25(12) . . . . ?
Pt1 C1 C2 C3 -177(100) . . . . ?
Ag2 C1 C2 C3 157(8) . . . . ?
C1 C2 C3 C4 51(8) . . . . ?
C1 C2 C3 C5 -130(8) . . . . ?
C5 C3 C4 C6 3.5(8) . . . . ?
C2 C3 C4 C6 -177.4(6) . . . . ?
C4 C3 C5 C7 -2.8(7) . . . . ?
C2 C3 C5 C7 178.1(4) . . . . ?
C3 C4 C6 C8 -0.8(10) . . . . ?
C3 C5 C7 C8 -0.6(7) . . . . ?
C5 C7 C8 C6 3.2(8) . . . . ?
C5 C7 C8 C9 -174.9(5) . . . . ?
C4 C6 C8 C7 -2.5(9) . . . . ?
C4 C6 C8 C9 175.6(6) . . . . ?
C41 Pt2 C11 C12 -34(6) . . . . ?
C31 Pt2 C11 C12 141(6) . . . . ?
P1 Pt2 C11 C12 -42(7) . . . . ?
Ag1 Pt2 C11 C12 21(6) . . . . ?
Ag2 Pt2 C11 C12 92(6) . . . . ?
C41 Pt2 C11 Ag1 -55.72(16) . . . . ?
C31 Pt2 C11 Ag1 119.33(15) . . . . ?
P1 Pt2 C11 Ag1 -63.1(14) . . . . ?
Ag2 Pt2 C11 Ag1 70.34(11) . . . . ?
C21 Ag1 C11 C12 92.3(5) . . . . ?
C22 Ag1 C11 C12 -9.8(6) . . . . ?
Pt2 Ag1 C11 C12 -178.6(4) . . . . ?
Pt1 Ag1 C11 C12 122.2(3) . . . . ?
C21 Ag1 C11 Pt2 -89.1(4) . . . . ?
C22 Ag1 C11 Pt2 168.7(4) . . . . ?
C12 Ag1 C11 Pt2 178.6(4) . . . . ?
Pt1 Ag1 C11 Pt2 -59.23(17) . . . . ?
Pt2 C11 C12 C13 154(4) . . . . ?
Ag1 C11 C12 C13 176(4) . . . . ?
Pt2 C11 C12 Ag1 -21(6) . . . . ?
C21 Ag1 C12 C11 -143.0(3) . . . . ?
C22 Ag1 C12 C11 175.6(3) . . . . ?
Pt2 Ag1 C12 C11 1.0(3) . . . . ?
Pt1 Ag1 C12 C11 -79.9(3) . . . . ?
C11 Ag1 C12 C13 -179.4(6) . . . . ?
C21 Ag1 C12 C13 37.6(5) . . . . ?
C22 Ag1 C12 C13 -3.7(5) . . . . ?
Pt2 Ag1 C12 C13 -178.3(4) . . . . ?
Pt1 Ag1 C12 C13 100.7(4) . . . . ?
C11 C12 C13 C14 175(4) . . . . ?
Ag1 C12 C13 C14 -9.2(6) . . . . ?
C11 C12 C13 C15 -7(4) . . . . ?
Ag1 C12 C13 C15 168.7(3) . . . . ?
C15 C13 C14 C16 -0.4(8) . . . . ?
C12 C13 C14 C16 177.5(5) . . . . ?
C14 C13 C15 C17 1.8(8) . . . . ?
C12 C13 C15 C17 -176.2(5) . . . . ?
C13 C14 C16 C18 -1.6(9) . . . . ?
C13 C15 C17 C18 -1.3(8) . . . . ?
C14 C16 C18 C17 2.1(9) . . . . ?
C14 C16 C18 C19 -177.9(6) . . . . ?
C15 C17 C18 C16 -0.7(9) . . . . ?
C15 C17 C18 C19 179.4(6) . . . . ?
C1 Pt1 C21 C22 -56(3) . . . . ?
C51 Pt1 C21 C22 4(3) . . . . ?
P2 Pt1 C21 C22 117(3) . . . . ?
Ag2 Pt1 C21 C22 -9(3) . . . . ?
Ag1 Pt1 C21 C22 4(3) . . . . ?
C1 Pt1 C21 Ag1 -60.87(16) . . . . ?
C51 Pt1 C21 Ag1 -0.7(13) . . . . ?
P2 Pt1 C21 Ag1 112.98(11) . . . . ?
Ag2 Pt1 C21 Ag1 -13.03(17) . . . . ?
C11 Ag1 C21 C22 -139.5(4) . . . . ?
C12 Ag1 C21 C22 -79.1(4) . . . . ?
Pt2 Ag1 C21 C22 151.4(2) . . . . ?
Pt1 Ag1 C21 C22 -179.4(4) . . . . ?
C11 Ag1 C21 Pt1 39.8(5) . . . . ?
C22 Ag1 C21 Pt1 179.4(4) . . . . ?
C12 Ag1 C21 Pt1 100.2(3) . . . . ?
Pt2 Ag1 C21 Pt1 -29.2(2) . . . . ?
Pt1 C21 C22 C23 -179(100) . . . . ?
Ag1 C21 C22 C23 -175(2) . . . . ?
Pt1 C21 C22 Ag1 -5(3) . . . . ?
C11 Ag1 C22 C21 139.3(4) . . . . ?
C12 Ag1 C22 C21 132.9(3) . . . . ?
Pt2 Ag1 C22 C21 -60.1(4) . . . . ?
Pt1 Ag1 C22 C21 0.4(2) . . . . ?
C11 Ag1 C22 C23 -42.0(6) . . . . ?
C21 Ag1 C22 C23 178.7(5) . . . . ?
C12 Ag1 C22 C23 -48.4(4) . . . . ?
Pt2 Ag1 C22 C23 118.6(3) . . . . ?
Pt1 Ag1 C22 C23 179.1(4) . . . . ?
C21 C22 C23 C25 -178.5(19) . . . . ?
Ag1 C22 C23 C25 7.2(6) . . . . ?
C21 C22 C23 C24 2(2) . . . . ?
Ag1 C22 C23 C24 -172.3(4) . . . . ?
C25 C23 C24 C26 0.0(8) . . . . ?
C22 C23 C24 C26 179.6(5) . . . . ?
C24 C23 C25 C27 0.5(7) . . . . ?
C22 C23 C25 C27 -179.0(4) . . . . ?
C23 C24 C26 C28 -0.4(10) . . . . ?
C23 C25 C27 C28 -0.7(8) . . . . ?
C25 C27 C28 C26 0.4(9) . . . . ?
C25 C27 C28 C29 -178.8(6) . . . . ?
C24 C26 C28 C27 0.1(10) . . . . ?
C24 C26 C28 C29 179.3(6) . . . . ?
C41 Pt2 C31 C32 -32(7) . . . . ?
C11 Pt2 C31 C32 -106(6) . . . . ?
P1 Pt2 C31 C32 74(6) . . . . ?
Ag1 Pt2 C31 C32 -61(6) . . . . ?
Ag2 Pt2 C31 C32 -20(6) . . . . ?
C41 Pt2 C31 Ag2 -12.4(18) . . . . ?
C11 Pt2 C31 Ag2 -86.12(15) . . . . ?
P1 Pt2 C31 Ag2 94.10(10) . . . . ?
Ag1 Pt2 C31 Ag2 -41.11(14) . . . . ?
C51 Ag2 C31 C32 111.5(4) . . . . ?
C1 Ag2 C31 C32 -113.3(3) . . . . ?
C52 Ag2 C31 C32 71.8(3) . . . . ?
Pt1 Ag2 C31 C32 -171.7(2) . . . . ?
Pt2 Ag2 C31 C32 178.8(4) . . . . ?
C51 Ag2 C31 Pt2 -67.3(4) . . . . ?
C1 Ag2 C31 Pt2 67.9(2) . . . . ?
C32 Ag2 C31 Pt2 -178.8(4) . . . . ?
C52 Ag2 C31 Pt2 -107.0(2) . . . . ?
Pt1 Ag2 C31 Pt2 9.5(2) . . . . ?
Pt2 C31 C32 C33 -151(4) . . . . ?
Ag2 C31 C32 C33 -170(3) . . . . ?
Pt2 C31 C32 Ag2 20(6) . . . . ?
C51 Ag2 C32 C31 -127.3(3) . . . . ?
C1 Ag2 C32 C31 93.6(3) . . . . ?
C52 Ag2 C32 C31 -130.0(3) . . . . ?
Pt1 Ag2 C32 C31 24.4(6) . . . . ?
Pt2 Ag2 C32 C31 -0.8(3) . . . . ?
C31 Ag2 C32 C33 178.2(6) . . . . ?
C51 Ag2 C32 C33 50.9(5) . . . . ?
C1 Ag2 C32 C33 -88.2(4) . . . . ?
C52 Ag2 C32 C33 48.2(4) . . . . ?
Pt1 Ag2 C32 C33 -157.4(3) . . . . ?
Pt2 Ag2 C32 C33 177.4(4) . . . . ?
C31 C32 C33 C34 131(3) . . . . ?
Ag2 C32 C33 C34 -38.2(6) . . . . ?
C31 C32 C33 C35 -46(3) . . . . ?
Ag2 C32 C33 C35 144.3(4) . . . . ?
C35 C33 C34 C36 2.7(8) . . . . ?
C32 C33 C34 C36 -175.0(5) . . . . ?
C34 C33 C35 C37 -2.4(8) . . . . ?
C32 C33 C35 C37 175.2(5) . . . . ?
C33 C34 C36 C38 0.0(10) . . . . ?
C33 C35 C37 C38 -0.6(9) . . . . ?
C34 C36 C38 C37 -2.9(10) . . . . ?
C34 C36 C38 C39 172.9(7) . . . . ?
C35 C37 C38 C36 3.2(10) . . . . ?
C35 C37 C38 C39 -172.6(7) . . . . ?
C31 Pt2 C41 C42 3(5) . . . . ?
C11 Pt2 C41 C42 77(4) . . . . ?
P1 Pt2 C41 C42 -104(4) . . . . ?
Ag1 Pt2 C41 C42 33(4) . . . . ?
Ag2 Pt2 C41 C42 -9(4) . . . . ?
Pt2 C41 C42 C43 143(13) . . . . ?
C41 C42 C43 C45 149(15) . . . . ?
C41 C42 C43 C44 -31(15) . . . . ?
C45 C43 C44 C46 -0.2(9) . . . . ?
C42 C43 C44 C46 180.0(6) . . . . ?
C44 C43 C45 C47 -0.4(9) . . . . ?
C42 C43 C45 C47 179.5(5) . . . . ?
C43 C44 C46 C48 0.5(12) . . . . ?
C43 C45 C47 C48 0.6(10) . . . . ?
C45 C47 C48 C46 -0.2(11) . . . . ?
C45 C47 C48 C49 179.3(7) . . . . ?
C44 C46 C48 C47 -0.3(12) . . . . ?
C44 C46 C48 C49 -179.8(8) . . . . ?
C21 Pt1 C51 C52 14(3) . . . . ?
C1 Pt1 C51 C52 75(2) . . . . ?
P2 Pt1 C51 C52 -100(2) . . . . ?
Ag2 Pt1 C51 C52 28(2) . . . . ?
Ag1 Pt1 C51 C52 14(2) . . . . ?
C21 Pt1 C51 Ag2 -13.5(13) . . . . ?
C1 Pt1 C51 Ag2 46.77(15) . . . . ?
P2 Pt1 C51 Ag2 -127.45(10) . . . . ?
Ag1 Pt1 C51 Ag2 -14.10(18) . . . . ?
C31 Ag2 C51 C52 -69.7(5) . . . . ?
C1 Ag2 C51 C52 145.5(3) . . . . ?
C32 Ag2 C51 C52 -4.9(5) . . . . ?
Pt1 Ag2 C51 C52 -175.5(4) . . . . ?
Pt2 Ag2 C51 C52 -117.8(3) . . . . ?
C31 Ag2 C51 Pt1 105.8(3) . . . . ?
C1 Ag2 C51 Pt1 -38.98(14) . . . . ?
C32 Ag2 C51 Pt1 170.5(2) . . . . ?
C52 Ag2 C51 Pt1 175.5(4) . . . . ?
Pt2 Ag2 C51 Pt1 57.70(16) . . . . ?
Pt1 C51 C52 C53 93(4) . . . . ?
Ag2 C51 C52 C53 120(4) . . . . ?
Pt1 C51 C52 Ag2 -28(2) . . . . ?
C31 Ag2 C52 C51 144.1(3) . . . . ?
C1 Ag2 C52 C51 -32.0(3) . . . . ?
C32 Ag2 C52 C51 177.1(3) . . . . ?
Pt1 Ag2 C52 C51 3.2(3) . . . . ?
Pt2 Ag2 C52 C51 84.0(3) . . . . ?
C31 Ag2 C52 C53 -29.6(4) . . . . ?
C51 Ag2 C52 C53 -173.7(5) . . . . ?
C1 Ag2 C52 C53 154.3(3) . . . . ?
C32 Ag2 C52 C53 3.4(4) . . . . ?
Pt1 Ag2 C52 C53 -170.5(3) . . . . ?
Pt2 Ag2 C52 C53 -89.7(3) . . . . ?
C51 C52 C53 C55 169(4) . . . . ?
Ag2 C52 C53 C55 -73.6(5) . . . . ?
C51 C52 C53 C54 -14(4) . . . . ?
Ag2 C52 C53 C54 103.2(4) . . . . ?
C55 C53 C54 C56 0.7(7) . . . . ?
C52 C53 C54 C56 -176.2(4) . . . . ?
C54 C53 C55 C57 -1.7(6) . . . . ?
C52 C53 C55 C57 175.2(4) . . . . ?
C53 C54 C56 C58 1.9(7) . . . . ?
C53 C55 C57 C58 0.1(7) . . . . ?
C55 C57 C58 C56 2.4(7) . . . . ?
C55 C57 C58 C59 -177.0(4) . . . . ?
C54 C56 C58 C57 -3.4(7) . . . . ?
C54 C56 C58 C59 176.0(5) . . . . ?
C111 P1 C101 C106 -15.0(4) . . . . ?
C202 P1 C101 C106 -125.7(4) . . . . ?
Pt2 P1 C101 C106 111.4(4) . . . . ?
C111 P1 C101 C102 165.7(3) . . . . ?
C202 P1 C101 C102 55.0(4) . . . . ?
Pt2 P1 C101 C102 -68.0(4) . . . . ?
C106 C101 C102 C103 0.0(7) . . . . ?
P1 C101 C102 C103 179.4(4) . . . . ?
C101 C102 C103 C104 -0.2(8) . . . . ?
C102 C103 C104 C105 -0.3(10) . . . . ?
C103 C104 C105 C106 0.8(11) . . . . ?
C102 C101 C106 C105 0.5(8) . . . . ?
P1 C101 C106 C105 -178.8(5) . . . . ?
C104 C105 C106 C101 -1.0(10) . . . . ?
C202 P1 C111 C116 5.2(4) . . . . ?
C101 P1 C111 C116 -101.6(4) . . . . ?
Pt2 P1 C111 C116 128.2(3) . . . . ?
C202 P1 C111 C112 -174.8(3) . . . . ?
C101 P1 C111 C112 78.4(3) . . . . ?
Pt2 P1 C111 C112 -51.8(3) . . . . ?
C116 C111 C112 C113 1.9(6) . . . . ?
P1 C111 C112 C113 -178.1(3) . . . . ?
C111 C112 C113 C114 -1.0(6) . . . . ?
C112 C113 C114 C115 -0.4(7) . . . . ?
C113 C114 C115 C116 0.9(7) . . . . ?
C112 C111 C116 C115 -1.4(6) . . . . ?
P1 C111 C116 C115 178.6(4) . . . . ?
C114 C115 C116 C111 0.0(7) . . . . ?
C203 P2 C121 C126 178.2(4) . . . . ?
C131 P2 C121 C126 -71.4(4) . . . . ?
Pt1 P2 C121 C126 60.6(4) . . . . ?
C203 P2 C121 C122 -4.0(6) . . . . ?
C131 P2 C121 C122 106.4(6) . . . . ?
Pt1 P2 C121 C122 -121.6(5) . . . . ?
C126 C121 C122 C123 1.3(12) . . . . ?
P2 C121 C122 C123 -176.4(7) . . . . ?
C121 C122 C123 C124 -3.8(14) . . . . ?
C122 C123 C124 C125 4.4(13) . . . . ?
C123 C124 C125 C126 -2.4(10) . . . . ?
C122 C121 C126 C125 0.8(9) . . . . ?
P2 C121 C126 C125 178.6(4) . . . . ?
C124 C125 C126 C121 -0.3(9) . . . . ?
C121 P2 C131 C136 142.8(4) . . . . ?
C203 P2 C131 C136 -108.7(4) . . . . ?
Pt1 P2 C131 C136 11.4(4) . . . . ?
C121 P2 C131 C132 -35.8(4) . . . . ?
C203 P2 C131 C132 72.7(4) . . . . ?
Pt1 P2 C131 C132 -167.2(3) . . . . ?
C136 C131 C132 C133 1.4(6) . . . . ?
P2 C131 C132 C133 180.0(3) . . . . ?
C131 C132 C133 C134 -0.7(7) . . . . ?
C132 C133 C134 C135 -0.3(7) . . . . ?
C133 C134 C135 C136 0.6(8) . . . . ?
C132 C131 C136 C135 -1.1(7) . . . . ?
P2 C131 C136 C135 -179.7(4) . . . . ?
C134 C135 C136 C131 0.1(7) . . . . ?
C203 C201 C202 C204 -2.5(6) . . . . ?
C203 C201 C202 P1 173.2(3) . . . . ?
C111 P1 C202 C201 117.5(3) . . . . ?
C101 P1 C202 C201 -133.9(3) . . . . ?
Pt2 P1 C202 C201 -6.2(4) . . . . ?
C111 P1 C202 C204 -67.0(4) . . . . ?
C101 P1 C202 C204 41.6(4) . . . . ?
Pt2 P1 C202 C204 169.3(3) . . . . ?
C202 C201 C203 C205 3.1(6) . . . . ?
C202 C201 C203 P2 -175.9(3) . . . . ?
C121 P2 C203 C205 93.9(4) . . . . ?
C131 P2 C203 C205 -14.6(4) . . . . ?
Pt1 P2 C203 C205 -141.7(3) . . . . ?
C121 P2 C203 C201 -87.2(3) . . . . ?
C131 P2 C203 C201 164.4(3) . . . . ?
Pt1 P2 C203 C201 37.2(3) . . . . ?
C201 C202 C204 C206 0.1(6) . . . . ?
P1 C202 C204 C206 -175.4(3) . . . . ?
C201 C203 C205 C206 -1.4(6) . . . . ?
P2 C203 C205 C206 177.6(3) . . . . ?
C202 C204 C206 C205 1.6(6) . . . . ?
C202 C204 C206 C207 -178.5(4) . . . . ?
C203 C205 C206 C204 -1.0(6) . . . . ?
C203 C205 C206 C207 179.1(4) . . . . ?
C204 C206 C207 C208 147.7(5) . . . . ?
C205 C206 C207 C208 -32.4(7) . . . . ?
C204 C206 C207 C209 -31.9(7) . . . . ?
C205 C206 C207 C209 148.0(5) . . . . ?
C209 C207 C208 C210 -0.5(8) . . . . ?
C206 C207 C208 C210 179.8(5) . . . . ?
C208 C207 C209 C211 -0.9(9) . . . . ?
C206 C207 C209 C211 178.7(6) . . . . ?
C207 C208 C210 N1 0.4(9) . . . . ?
C207 C209 C211 N1 2.7(11) . . . . ?
C208 C210 N1 C211 1.2(10) . . . . ?
C209 C211 N1 C210 -2.8(11) . . . . ?

_diffrn_measured_fraction_theta_max 0.962
_diffrn_reflns_theta_full        29.36
_diffrn_measured_fraction_theta_full 0.962
_refine_diff_density_max         2.728
_refine_diff_density_min         -4.426
_refine_diff_density_rms         0.466
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_w1
_database_code_depnum_ccdc_archive 'CCDC 1990102'
loop_
_audit_author_name
_audit_author_address
'Qiao-Hua Wei'
;College of Chemistry, Fuzhou University
China
;
_audit_update_record             
;
2020-03-13 deposited with the CCDC.	2020-05-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C208 H148 Cl4 Cu0 N4 O2 P8 Pt4'
_chemical_formula_weight         3905.18

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   Pnna

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z'
'x, -y+1/2, -z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z'
'-x, y-1/2, z-1/2'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   23.599(5)
_cell_length_b                   37.492(7)
_cell_length_c                   19.730(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     17457(6)
_cell_formula_units_Z            4
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    25996
_cell_measurement_theta_min      1.47
_cell_measurement_theta_max      30.71

_exptl_crystal_description       prism
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.486
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             7758
_exptl_absorpt_coefficient_mu    0.000
_exptl_absorpt_correction_type   sphere
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   
'spherical harmonics expansion of the absorption surface (Katayama, et al. 1986)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.72000
_diffrn_radiation_type           synchrotron
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Mar CCD 165 nm'
_diffrn_measurement_method       oscillation
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_decay_%        none
_diffrn_reflns_number            92068
_diffrn_reflns_av_R_equivalents  0.0261
_diffrn_reflns_av_sigmaI/netI    0.0205
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_k_min       -53
_diffrn_reflns_limit_k_max       53
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       0
_diffrn_reflns_theta_min         1.47
_diffrn_reflns_theta_max         30.71
_reflns_number_total             25996
_reflns_number_gt                24185
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Mar CCD'
_computing_cell_refinement       HKL2000
_computing_data_reduction        HKL2000
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 

Structure factors included contributions from the .fab file.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1011P)²+89.6415P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00436(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         25996
_refine_ls_number_parameters     1046
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0685
_refine_ls_R_factor_gt           0.0627
_refine_ls_wR_factor_ref         0.1762
_refine_ls_wR_factor_gt          0.1729
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_restrained_S_all      1.077
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.220815(7) 0.193285(4) 0.172015(8) 0.02403(7) Uani 1 1 d . . .
Pt2 Pt 0.2500 0.0000 0.620079(11) 0.02527(7) Uani 1 2 d S . .
Pt3 Pt 0.2500 0.0000 0.882199(11) 0.02545(7) Uani 1 2 d S . .
Cl1 Cl 0.2433(2) 0.0605(3) 0.0656(2) 0.253(5) Uani 1 1 d . . .
Cl2 Cl 0.25529(15) 0.07120(17) 0.2026(3) 0.162(3) Uani 1 1 d . . .
P1 P 0.30580(5) 0.21231(3) 0.13017(6) 0.0265(2) Uani 1 1 d . . .
P2 P 0.13553(5) 0.17854(3) 0.21908(5) 0.02235(19) Uani 1 1 d . . .
P3 P 0.17065(5) 0.03492(3) 0.62621(5) 0.0266(2) Uani 1 1 d . . .
P4 P 0.16275(5) -0.02621(3) 0.87835(5) 0.0254(2) Uani 1 1 d . . .
O1 O 0.2475(6) 0.0384(3) 0.4418(4) 0.136(5) Uani 1 1 d . . .
N1 N 0.6156(4) 0.2378(4) 0.2594(8) 0.066(5) Uani 0.50 1 d P . .
N2 N -0.1766(3) 0.2500 0.2500 0.053(2) Uani 1 2 d S . .
N3 N -0.1451(2) 0.0080(2) 0.7351(3) 0.0553(14) Uani 1 1 d . . .
C1 C 0.2652(2) 0.16765(13) 0.2433(3) 0.0327(9) Uani 1 1 d . . .
C01 C 0.2080(5) 0.0862(2) 0.1310(7) 0.088(3) Uani 1 1 d . . .
H01A H 0.1681 0.0789 0.1376 0.106 Uiso 1 1 calc R . .
H01B H 0.2103 0.1122 0.1229 0.106 Uiso 1 1 calc R . .
C2 C 0.2940(2) 0.15246(15) 0.2852(3) 0.0403(11) Uani 1 1 d . . .
C3 C 0.3298(3) 0.13526(17) 0.3344(4) 0.0523(17) Uani 1 1 d . . .
C03 C 0.2430(5) 0.0278(3) 0.3769(7) 0.085(3) Uani 1 1 d . . .
C4 C 0.3881(3) 0.1409(2) 0.3333(5) 0.071(3) Uani 1 1 d . . .
H4A H 0.4046 0.1563 0.3005 0.085 Uiso 1 1 calc R . .
C5 C 0.4227(4) 0.1233(3) 0.3824(6) 0.091(4) Uani 1 1 d . . .
H5A H 0.4626 0.1267 0.3819 0.109 Uiso 1 1 calc R . .
C6 C 0.3983(6) 0.1013(3) 0.4309(6) 0.098(4) Uani 1 1 d . . .
H6A H 0.4212 0.0900 0.4642 0.118 Uiso 1 1 calc R . .
C7 C 0.3427(5) 0.0961(2) 0.4302(5) 0.085(3) Uani 1 1 d . . .
H7A H 0.3262 0.0807 0.4630 0.102 Uiso 1 1 calc R . .
C8 C 0.3082(4) 0.1125(2) 0.3828(4) 0.062(2) Uani 1 1 d . . .
H8A H 0.2686 0.1080 0.3837 0.075 Uiso 1 1 calc R . .
C11 C 0.1738(2) 0.21899(12) 0.1029(2) 0.0273(8) Uani 1 1 d . . .
C12 C 0.1406(2) 0.23340(13) 0.0649(2) 0.0326(9) Uani 1 1 d . . .
C13 C 0.0981(3) 0.24967(13) 0.0228(3) 0.0402(12) Uani 1 1 d . . .
C14 C 0.1111(4) 0.2640(2) -0.0404(4) 0.066(2) Uani 1 1 d . . .
H14A H 0.1489 0.2629 -0.0569 0.079 Uiso 1 1 calc R . .
C15 C 0.0692(6) 0.2798(3) -0.0794(5) 0.092(4) Uani 1 1 d . . .
H15A H 0.0785 0.2899 -0.1221 0.111 Uiso 1 1 calc R . .
C16 C 0.0146(5) 0.2809(2) -0.0566(6) 0.089(4) Uani 1 1 d . . .
H16A H -0.0138 0.2919 -0.0837 0.107 Uiso 1 1 calc R . .
C17 C 0.0003(4) 0.2665(2) 0.0045(5) 0.077(3) Uani 1 1 d . . .
H17A H -0.0379 0.2673 0.0198 0.093 Uiso 1 1 calc R . .
C18 C 0.0419(3) 0.25065(17) 0.0444(4) 0.0524(16) Uani 1 1 d . . .
H18A H 0.0319 0.2404 0.0868 0.063 Uiso 1 1 calc R . .
C31 C 0.3026(2) 0.04183(13) 0.6205(2) 0.0273(8) Uani 1 1 d . . .
C32 C 0.3379(2) 0.06520(13) 0.6213(2) 0.0302(9) Uani 1 1 d . . .
C33 C 0.3831(2) 0.09076(14) 0.6226(2) 0.0311(9) Uani 1 1 d . . .
C34 C 0.4363(2) 0.08136(15) 0.6475(3) 0.0366(10) Uani 1 1 d . . .
H34A H 0.4419 0.0582 0.6659 0.044 Uiso 1 1 calc R . .
C35 C 0.4810(2) 0.10522(18) 0.6459(3) 0.0458(13) Uani 1 1 d . . .
H35A H 0.5171 0.0982 0.6626 0.055 Uiso 1 1 calc R . .
C36 C 0.4734(3) 0.1392(2) 0.6202(3) 0.0505(15) Uani 1 1 d . . .
H36A H 0.5040 0.1556 0.6188 0.061 Uiso 1 1 calc R . .
C37 C 0.4201(3) 0.14889(19) 0.5963(4) 0.0552(16) Uani 1 1 d . . .
H37A H 0.4144 0.1722 0.5788 0.066 Uiso 1 1 calc R . .
C38 C 0.3755(3) 0.12525(17) 0.5977(3) 0.0474(14) Uani 1 1 d . . .
H38A H 0.3393 0.1324 0.5815 0.057 Uiso 1 1 calc R . .
C41 C 0.2099(2) 0.04674(13) 0.8833(2) 0.0286(9) Uani 1 1 d . . .
C42 C 0.1829(2) 0.07450(14) 0.8865(2) 0.0339(10) Uani 1 1 d . . .
C43 C 0.1500(2) 0.10639(15) 0.8922(3) 0.0358(10) Uani 1 1 d . . .
C44 C 0.1724(3) 0.13693(15) 0.9218(3) 0.0415(12) Uani 1 1 d . . .
H44A H 0.2106 0.1370 0.9367 0.050 Uiso 1 1 calc R . .
C45 C 0.1396(3) 0.16731(17) 0.9298(3) 0.0504(15) Uani 1 1 d . . .
H45A H 0.1552 0.1878 0.9513 0.060 Uiso 1 1 calc R . .
C46 C 0.0849(3) 0.1680(2) 0.9069(4) 0.0590(19) Uani 1 1 d . . .
H46A H 0.0626 0.1889 0.9120 0.071 Uiso 1 1 calc R . .
C47 C 0.0620(3) 0.1377(2) 0.8762(4) 0.0596(19) Uani 1 1 d . . .
H47A H 0.0239 0.1381 0.8604 0.072 Uiso 1 1 calc R . .
C48 C 0.0942(3) 0.10702(18) 0.8684(3) 0.0448(13) Uani 1 1 d . . .
H48A H 0.0785 0.0866 0.8471 0.054 Uiso 1 1 calc R . .
C101 C 0.3042(2) 0.24474(14) 0.0621(3) 0.0349(10) Uani 1 1 d . . .
C102 C 0.2838(3) 0.2333(2) -0.0012(3) 0.0502(15) Uani 1 1 d . . .
H10A H 0.2702 0.2096 -0.0065 0.060 Uiso 1 1 calc R . .
C103 C 0.2834(3) 0.2558(2) -0.0541(3) 0.0527(16) Uani 1 1 d . . .
H10B H 0.2699 0.2478 -0.0968 0.063 Uiso 1 1 calc R . .
C104 C 0.3024(3) 0.2908(2) -0.0473(4) 0.0562(17) Uani 1 1 d . . .
H10C H 0.3025 0.3063 -0.0854 0.067 Uiso 1 1 calc R . .
C105 C 0.3210(4) 0.30275(18) 0.0151(4) 0.0578(18) Uani 1 1 d . . .
H10D H 0.3334 0.3267 0.0202 0.069 Uiso 1 1 calc R . .
C106 C 0.3217(3) 0.27972(15) 0.0707(3) 0.0449(13) Uani 1 1 d . . .
H10E H 0.3341 0.2879 0.1138 0.054 Uiso 1 1 calc R . .
C111 C 0.3536(2) 0.17875(16) 0.0953(3) 0.0450(14) Uani 1 1 d . . .
C112 C 0.3971(3) 0.1887(2) 0.0521(4) 0.061(2) Uani 1 1 d . . .
H11A H 0.4005 0.2129 0.0384 0.073 Uiso 1 1 calc R . .
C113 C 0.4357(3) 0.1637(3) 0.0289(6) 0.092(4) Uani 1 1 d . . .
H11B H 0.4658 0.1707 -0.0002 0.110 Uiso 1 1 calc R . .
C114 C 0.4302(3) 0.1285(3) 0.0482(7) 0.099(4) Uani 1 1 d . . .
H11C H 0.4562 0.1112 0.0320 0.119 Uiso 1 1 calc R . .
C115 C 0.3875(4) 0.1186(2) 0.0903(6) 0.084(3) Uani 1 1 d . . .
H11D H 0.3840 0.0943 0.1034 0.101 Uiso 1 1 calc R . .
C116 C 0.3493(3) 0.14334(19) 0.1143(4) 0.059(2) Uani 1 1 d . . .
H11E H 0.3198 0.1361 0.1440 0.071 Uiso 1 1 calc R . .
C131 C 0.3176(3) 0.2500 0.2500 0.0275(12) Uani 1 2 d S . .
H13A H 0.2773 0.2500 0.2500 0.033 Uiso 1 2 calc SR . .
C132 C 0.34708(18) 0.23327(11) 0.1978(2) 0.0272(8) Uani 1 1 d . . .
C133 C 0.4055(2) 0.23353(13) 0.1977(3) 0.0327(9) Uani 1 1 d . . .
H13B H 0.4256 0.2224 0.1618 0.039 Uiso 1 1 calc R . .
C134 C 0.4352(3) 0.2500 0.2500 0.0390(17) Uani 1 2 d S . .
C135 C 0.4974(4) 0.2500 0.2500 0.070(4) Uani 1 2 d S . .
C136 C 0.5278(3) 0.2193(4) 0.2304(5) 0.099(5) Uani 1 1 d . . .
C137 C 0.5877(4) 0.2234(6) 0.2290(7) 0.165(10) Uani 1 1 d . . .
C201 C 0.13641(19) 0.15710(12) 0.3011(2) 0.0275(8) Uani 1 1 d . . .
C202 C 0.1328(3) 0.17651(17) 0.3603(3) 0.0456(13) Uani 1 1 d . . .
H20A H 0.1288 0.2017 0.3583 0.055 Uiso 1 1 calc R . .
C203 C 0.1349(4) 0.1594(2) 0.4230(3) 0.0615(19) Uani 1 1 d . . .
H20B H 0.1337 0.1730 0.4635 0.074 Uiso 1 1 calc R . .
C204 C 0.1389(3) 0.1231(2) 0.4263(3) 0.0566(17) Uani 1 1 d . . .
H20C H 0.1389 0.1115 0.4691 0.068 Uiso 1 1 calc R . .
C205 C 0.1428(3) 0.10324(17) 0.3675(3) 0.0503(15) Uani 1 1 d . . .
H20D H 0.1461 0.0780 0.3698 0.060 Uiso 1 1 calc R . .
C206 C 0.1420(3) 0.12030(14) 0.3051(3) 0.0400(11) Uani 1 1 d . . .
H20E H 0.1452 0.1067 0.2647 0.048 Uiso 1 1 calc R . .
C211 C 0.0929(2) 0.14858(12) 0.1677(2) 0.0264(8) Uani 1 1 d . . .
C212 C 0.1118(3) 0.13981(19) 0.1037(3) 0.0554(19) Uani 1 1 d . . .
H21A H 0.1447 0.1510 0.0859 0.066 Uiso 1 1 calc R . .
C213 C 0.0830(5) 0.1146(3) 0.0653(4) 0.098(4) Uani 1 1 d . . .
H21B H 0.0969 0.1081 0.0219 0.117 Uiso 1 1 calc R . .
C214 C 0.0347(4) 0.0994(3) 0.0898(4) 0.086(4) Uani 1 1 d . . .
H21C H 0.0160 0.0815 0.0640 0.103 Uiso 1 1 calc R . .
C215 C 0.0124(3) 0.10960(19) 0.1523(3) 0.0499(15) Uani 1 1 d . . .
H21D H -0.0231 0.1005 0.1674 0.060 Uiso 1 1 calc R . .
C216 C 0.0431(2) 0.13340(13) 0.1922(3) 0.0313(9) Uani 1 1 d . . .
H21E H 0.0300 0.1393 0.2363 0.038 Uiso 1 1 calc R . .
C231 C 0.1231(3) 0.2500 0.2500 0.0236(11) Uani 1 2 d S . .
H23A H 0.1633 0.2500 0.2500 0.028 Uiso 1 2 calc SR . .
C232 C 0.09345(18) 0.21868(11) 0.2348(2) 0.0247(7) Uani 1 1 d . . .
C233 C 0.0350(2) 0.21895(12) 0.2352(2) 0.0289(8) Uani 1 1 d . . .
H23B H 0.0147 0.1977 0.2252 0.035 Uiso 1 1 calc R . .
C234 C 0.0054(3) 0.2500 0.2500 0.0275(12) Uani 1 2 d S . .
C235 C -0.0577(3) 0.2500 0.2500 0.0334(14) Uani 1 2 d S . .
C236 C -0.0885(2) 0.27935(16) 0.2268(3) 0.0425(12) Uani 1 1 d . . .
H23C H -0.0697 0.3000 0.2104 0.051 Uiso 1 1 calc R . .
C237 C -0.1474(3) 0.2777(2) 0.2280(4) 0.0523(16) Uani 1 1 d . . .
H23D H -0.1679 0.2979 0.2120 0.063 Uiso 1 1 calc R . .
C301 C 0.1236(2) 0.03371(14) 0.5530(2) 0.0318(9) Uani 1 1 d . . .
C302 C 0.0818(2) 0.05955(15) 0.5444(3) 0.0366(10) Uani 1 1 d . . .
H30A H 0.0793 0.0790 0.5751 0.044 Uiso 1 1 calc R . .
C303 C 0.0437(2) 0.05701(18) 0.4908(3) 0.0428(12) Uani 1 1 d . . .
H30B H 0.0149 0.0745 0.4853 0.051 Uiso 1 1 calc R . .
C304 C 0.0477(3) 0.02887(18) 0.4453(3) 0.0471(13) Uani 1 1 d . . .
H30C H 0.0217 0.0271 0.4087 0.057 Uiso 1 1 calc R . .
C305 C 0.0897(3) 0.00323(19) 0.4533(3) 0.0515(16) Uani 1 1 d . . .
H30D H 0.0924 -0.0161 0.4223 0.062 Uiso 1 1 calc R . .
C306 C 0.1277(3) 0.00594(17) 0.5067(3) 0.0450(13) Uani 1 1 d . . .
H30E H 0.1568 -0.0114 0.5117 0.054 Uiso 1 1 calc R . .
C311 C 0.1815(2) 0.08194(13) 0.6428(2) 0.0320(9) Uani 1 1 d . . .
C312 C 0.1749(3) 0.09675(16) 0.7066(3) 0.0460(13) Uani 1 1 d . . .
H31A H 0.1637 0.0822 0.7436 0.055 Uiso 1 1 calc R . .
C313 C 0.1847(4) 0.13301(18) 0.7166(4) 0.0561(17) Uani 1 1 d . . .
H31B H 0.1812 0.1429 0.7607 0.067 Uiso 1 1 calc R . .
C314 C 0.1995(3) 0.15468(18) 0.6626(4) 0.0526(15) Uani 1 1 d . . .
H31C H 0.2038 0.1797 0.6688 0.063 Uiso 1 1 calc R . .
C315 C 0.2081(3) 0.13937(17) 0.5995(3) 0.0459(13) Uani 1 1 d . . .
H31D H 0.2195 0.1539 0.5626 0.055 Uiso 1 1 calc R . .
C316 C 0.2004(3) 0.10311(15) 0.5895(3) 0.0389(11) Uani 1 1 d . . .
H31E H 0.2079 0.0928 0.5465 0.047 Uiso 1 1 calc R . .
C331 C 0.1538(2) 0.00576(13) 0.7532(2) 0.0271(8) Uani 1 1 d . . .
H33A H 0.1941 0.0058 0.7553 0.032 Uiso 1 1 calc R . .
C332 C 0.1264(2) 0.01967(13) 0.6963(2) 0.0280(8) Uani 1 1 d . . .
C333 C 0.0679(2) 0.02060(13) 0.6948(2) 0.0292(8) Uani 1 1 d . . .
H33B H 0.0491 0.0310 0.6571 0.035 Uiso 1 1 calc R . .
C334 C 0.0362(2) 0.00638(14) 0.7480(2) 0.0280(8) Uani 1 1 d . . .
C335 C -0.0267(2) 0.00670(15) 0.7435(2) 0.0315(9) Uani 1 1 d . . .
C336 C -0.0559(3) 0.03752(18) 0.7254(3) 0.0454(13) Uani 1 1 d . . .
H33C H -0.0358 0.0588 0.7150 0.054 Uiso 1 1 calc R . .
C337 C -0.1145(3) 0.0370(2) 0.7227(4) 0.0547(17) Uani 1 1 d . . .
H33D H -0.1337 0.0584 0.7115 0.066 Uiso 1 1 calc R . .
C338 C -0.1172(3) -0.0215(2) 0.7519(3) 0.0483(15) Uani 1 1 d . . .
H33E H -0.1385 -0.0424 0.7613 0.058 Uiso 1 1 calc R . .
C339 C -0.0585(2) -0.02350(16) 0.7567(3) 0.0387(11) Uani 1 1 d . . .
H33F H -0.0405 -0.0453 0.7689 0.046 Uiso 1 1 calc R . .
C340 C 0.0639(2) -0.00843(13) 0.8035(2) 0.0284(8) Uani 1 1 d . . .
H34B H 0.0425 -0.0188 0.8391 0.034 Uiso 1 1 calc R . .
C341 C 0.12232(19) -0.00817(12) 0.8072(2) 0.0268(8) Uani 1 1 d . . .
C401 C 0.1610(2) -0.07394(13) 0.8647(2) 0.0296(8) Uani 1 1 d . . .
C402 C 0.1575(3) -0.08815(15) 0.7999(3) 0.0476(14) Uani 1 1 d . . .
H40A H 0.1534 -0.0727 0.7621 0.057 Uiso 1 1 calc R . .
C403 C 0.1598(4) -0.12460(18) 0.7901(3) 0.065(2) Uani 1 1 d . . .
H40B H 0.1579 -0.1341 0.7456 0.078 Uiso 1 1 calc R . .
C404 C 0.1649(4) -0.14735(17) 0.8455(4) 0.0561(17) Uani 1 1 d . . .
H40C H 0.1652 -0.1725 0.8390 0.067 Uiso 1 1 calc R . .
C405 C 0.1694(3) -0.13333(16) 0.9096(3) 0.0496(15) Uani 1 1 d . . .
H40D H 0.1733 -0.1489 0.9474 0.060 Uiso 1 1 calc R . .
C406 C 0.1684(3) -0.09654(15) 0.9198(3) 0.0436(13) Uani 1 1 d . . .
H40E H 0.1727 -0.0870 0.9641 0.052 Uiso 1 1 calc R . .
C411 C 0.1209(2) -0.01964(14) 0.9546(2) 0.0318(9) Uani 1 1 d . . .
C412 C 0.1382(4) 0.0058(2) 1.0015(3) 0.0561(18) Uani 1 1 d . . .
H41A H 0.1705 0.0202 0.9927 0.067 Uiso 1 1 calc R . .
C413 C 0.1079(4) 0.0101(2) 1.0615(3) 0.065(2) Uani 1 1 d . . .
H41B H 0.1191 0.0278 1.0932 0.078 Uiso 1 1 calc R . .
C414 C 0.0616(3) -0.0113(2) 1.0751(3) 0.0502(15) Uani 1 1 d . . .
H41C H 0.0424 -0.0094 1.1173 0.060 Uiso 1 1 calc R . .
C415 C 0.0435(3) -0.0352(2) 1.0281(3) 0.0511(15) Uani 1 1 d . . .
H41D H 0.0102 -0.0488 1.0359 0.061 Uiso 1 1 calc R . .
C416 C 0.0742(3) -0.03971(19) 0.9680(3) 0.0459(13) Uani 1 1 d . . .
H41E H 0.0622 -0.0571 0.9360 0.055 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.999(5) . ?
Pt1 C11 2.004(5) . ?
Pt1 P1 2.2831(12) . ?
Pt1 P2 2.2845(11) . ?
Pt2 C31 2.000(5) . ?
Pt2 C31 2.000(5) 2 ?
Pt2 P3 2.2880(13) . ?
Pt2 P3 2.2880(13) 2 ?
Pt3 C41 1.991(4) . ?
Pt3 C41 1.991(4) 2 ?
Pt3 P4 2.2828(13) . ?
Pt3 P4 2.2828(13) 2 ?
Cl1 C01 1.814(12) . ?
Cl2 C01 1.886(14) . ?
P1 C101 1.813(6) . ?
P1 C111 1.824(5) . ?
P1 C132 1.829(5) . ?
P2 C201 1.807(4) . ?
P2 C211 1.817(4) . ?
P2 C232 1.829(4) . ?
P3 C311 1.811(5) . ?
P3 C301 1.822(5) . ?
P3 C332 1.826(5) . ?
P4 C401 1.810(5) . ?
P4 C411 1.816(4) . ?
P4 C341 1.827(4) . ?
O1 C03 1.344(16) . ?
N1 N1 0.98(3) 3 ?
N1 C137 1.04(2) . ?
N1 C137 1.61(3) 3 ?
N2 C237 1.321(9) . ?
N2 C237 1.321(9) 3 ?
N3 C338 1.327(10) . ?
N3 C337 1.328(11) . ?
C1 C2 1.213(7) . ?
C01 H01A 0.9900 . ?
C01 H01B 0.9900 . ?
C2 C3 1.439(8) . ?
C3 C8 1.377(12) . ?
C3 C4 1.393(11) . ?
C4 C5 1.427(13) . ?
C4 H4A 0.9500 . ?
C5 C6 1.391(18) . ?
C5 H5A 0.9500 . ?
C6 C7 1.326(18) . ?
C6 H6A 0.9500 . ?
C7 C8 1.385(9) . ?
C7 H7A 0.9500 . ?
C8 H8A 0.9500 . ?
C11 C12 1.212(7) . ?
C12 C13 1.438(8) . ?
C13 C14 1.392(9) . ?
C13 C18 1.394(11) . ?
C14 C15 1.387(12) . ?
C14 H14A 0.9500 . ?
C15 C16 1.365(18) . ?
C15 H15A 0.9500 . ?
C16 C17 1.365(16) . ?
C16 H16A 0.9500 . ?
C17 C18 1.393(9) . ?
C17 H17A 0.9500 . ?
C18 H18A 0.9500 . ?
C31 C32 1.210(7) . ?
C32 C33 1.435(7) . ?
C33 C34 1.392(7) . ?
C33 C38 1.395(8) . ?
C34 C35 1.384(8) . ?
C34 H34A 0.9500 . ?
C35 C36 1.383(10) . ?
C35 H35A 0.9500 . ?
C36 C37 1.391(10) . ?
C36 H36A 0.9500 . ?
C37 C38 1.377(9) . ?
C37 H37A 0.9500 . ?
C38 H38A 0.9500 . ?
C41 C42 1.222(6) . ?
C42 C43 1.430(7) . ?
C43 C44 1.389(8) . ?
C43 C48 1.398(8) . ?
C44 C45 1.386(8) . ?
C44 H44A 0.9500 . ?
C45 C46 1.368(11) . ?
C45 H45A 0.9500 . ?
C46 C47 1.395(12) . ?
C46 H46A 0.9500 . ?
C47 C48 1.388(9) . ?
C47 H47A 0.9500 . ?
C48 H48A 0.9500 . ?
C101 C106 1.386(7) . ?
C101 C102 1.404(8) . ?
C102 C103 1.343(10) . ?
C102 H10A 0.9500 . ?
C103 C104 1.390(11) . ?
C103 H10B 0.9500 . ?
C104 C105 1.383(11) . ?
C104 H10C 0.9500 . ?
C105 C106 1.395(9) . ?
C105 H10D 0.9500 . ?
C106 H10E 0.9500 . ?
C111 C116 1.383(10) . ?
C111 C112 1.386(9) . ?
C112 C113 1.387(9) . ?
C112 H11A 0.9500 . ?
C113 C114 1.378(17) . ?
C113 H11B 0.9500 . ?
C114 C115 1.357(16) . ?
C114 H11C 0.9500 . ?
C115 C116 1.378(9) . ?
C115 H11D 0.9500 . ?
C116 H11E 0.9500 . ?
C131 C132 1.393(5) 3 ?
C131 C132 1.393(5) . ?
C131 H13A 0.9500 . ?
C132 C133 1.378(6) . ?
C133 C134 1.391(6) . ?
C133 H13B 0.9500 . ?
C134 C133 1.391(6) 3 ?
C134 C135 1.469(12) . ?
C135 C136 1.410(11) 3 ?
C135 C136 1.410(11) . ?
C136 C137 1.422(14) . ?
C137 N1 1.61(3) 3 ?
C201 C202 1.379(7) . ?
C201 C206 1.388(7) . ?
C202 C203 1.395(8) . ?
C202 H20A 0.9500 . ?
C203 C204 1.367(11) . ?
C203 H20B 0.9500 . ?
C204 C205 1.381(11) . ?
C204 H20C 0.9500 . ?
C205 C206 1.388(8) . ?
C205 H20D 0.9500 . ?
C206 H20E 0.9500 . ?
C211 C212 1.379(7) . ?
C211 C216 1.391(6) . ?
C212 C213 1.388(9) . ?
C212 H21A 0.9500 . ?
C213 C214 1.364(11) . ?
C213 H21B 0.9500 . ?
C214 C215 1.394(11) . ?
C214 H21C 0.9500 . ?
C215 C216 1.393(8) . ?
C215 H21D 0.9500 . ?
C216 H21E 0.9500 . ?
C231 C232 1.399(5) 3 ?
C231 C232 1.399(5) . ?
C231 H23A 0.9500 . ?
C232 C233 1.380(6) . ?
C233 C234 1.388(6) . ?
C233 H23B 0.9500 . ?
C234 C233 1.388(6) 3 ?
C234 C235 1.490(10) . ?
C235 C236 1.396(7) . ?
C235 C236 1.396(7) 3 ?
C236 C237 1.390(8) . ?
C236 H23C 0.9500 . ?
C237 H23D 0.9500 . ?
C301 C306 1.389(8) . ?
C301 C302 1.392(7) . ?
C302 C303 1.392(7) . ?
C302 H30A 0.9500 . ?
C303 C304 1.388(9) . ?
C303 H30B 0.9500 . ?
C304 C305 1.390(10) . ?
C304 H30C 0.9500 . ?
C305 C306 1.388(8) . ?
C305 H30D 0.9500 . ?
C306 H30E 0.9500 . ?
C311 C312 1.385(7) . ?
C311 C316 1.389(7) . ?
C312 C313 1.393(9) . ?
C312 H31A 0.9500 . ?
C313 C314 1.385(10) . ?
C313 H31B 0.9500 . ?
C314 C315 1.386(10) . ?
C314 H31C 0.9500 . ?
C315 C316 1.386(9) . ?
C315 H31D 0.9500 . ?
C316 H31E 0.9500 . ?
C331 C332 1.398(6) . ?
C331 C341 1.400(6) . ?
C331 H33A 0.9500 . ?
C332 C333 1.380(6) . ?
C333 C334 1.395(6) . ?
C333 H33B 0.9500 . ?
C334 C340 1.390(6) . ?
C334 C335 1.488(7) . ?
C335 C339 1.383(8) . ?
C335 C336 1.392(8) . ?
C336 C337 1.383(9) . ?
C336 H33C 0.9500 . ?
C337 H33D 0.9500 . ?
C338 C339 1.390(8) . ?
C338 H33E 0.9500 . ?
C339 H33F 0.9500 . ?
C340 C341 1.380(6) . ?
C340 H34B 0.9500 . ?
C401 C402 1.387(7) . ?
C401 C406 1.389(7) . ?
C402 C403 1.381(8) . ?
C402 H40A 0.9500 . ?
C403 C404 1.391(10) . ?
C403 H40B 0.9500 . ?
C404 C405 1.374(9) . ?
C404 H40C 0.9500 . ?
C405 C406 1.394(8) . ?
C405 H40D 0.9500 . ?
C406 H40E 0.9500 . ?
C411 C416 1.360(8) . ?
C411 C412 1.391(9) . ?
C412 C413 1.392(9) . ?
C412 H41A 0.9500 . ?
C413 C414 1.383(12) . ?
C413 H41B 0.9500 . ?
C414 C415 1.358(10) . ?
C414 H41C 0.9500 . ?
C415 C416 1.399(7) . ?
C415 H41D 0.9500 . ?
C416 H41E 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C11 177.8(2) . . ?
C1 Pt1 P1 86.83(16) . . ?
C11 Pt1 P1 95.14(14) . . ?
C1 Pt1 P2 93.38(16) . . ?
C11 Pt1 P2 84.58(13) . . ?
P1 Pt1 P2 175.21(4) . . ?
C31 Pt2 C31 179.5(2) . 2 ?
C31 Pt2 P3 93.37(14) . . ?
C31 Pt2 P3 86.60(14) 2 . ?
C31 Pt2 P3 86.60(14) . 2 ?
C31 Pt2 P3 93.37(14) 2 2 ?
P3 Pt2 P3 173.94(5) . 2 ?
C41 Pt3 C41 178.8(3) . 2 ?
C41 Pt3 P4 87.17(15) . . ?
C41 Pt3 P4 92.87(15) 2 . ?
C41 Pt3 P4 92.87(15) . 2 ?
C41 Pt3 P4 87.17(15) 2 2 ?
P4 Pt3 P4 176.19(5) . 2 ?
C101 P1 C111 101.3(3) . . ?
C101 P1 C132 105.3(2) . . ?
C111 P1 C132 104.0(2) . . ?
C101 P1 Pt1 117.36(18) . . ?
C111 P1 Pt1 117.6(2) . . ?
C132 P1 Pt1 109.78(15) . . ?
C201 P2 C211 103.3(2) . . ?
C201 P2 C232 102.8(2) . . ?
C211 P2 C232 107.6(2) . . ?
C201 P2 Pt1 117.48(15) . . ?
C211 P2 Pt1 114.27(15) . . ?
C232 P2 Pt1 110.36(14) . . ?
C311 P3 C301 104.7(2) . . ?
C311 P3 C332 104.4(2) . . ?
C301 P3 C332 104.1(2) . . ?
C311 P3 Pt2 116.79(17) . . ?
C301 P3 Pt2 116.30(17) . . ?
C332 P3 Pt2 109.24(15) . . ?
C401 P4 C411 104.2(2) . . ?
C401 P4 C341 103.8(2) . . ?
C411 P4 C341 107.6(2) . . ?
C401 P4 Pt3 116.82(17) . . ?
C411 P4 Pt3 113.87(18) . . ?
C341 P4 Pt3 109.70(16) . . ?
N1 N1 C137 105(2) 3 . ?
N1 N1 C137 38.5(13) 3 3 ?
C137 N1 C137 106.9(14) . 3 ?
C237 N2 C237 117.1(8) . 3 ?
C338 N3 C337 117.2(6) . . ?
C2 C1 Pt1 177.4(5) . . ?
Cl1 C01 Cl2 95.9(6) . . ?
Cl1 C01 H01A 112.6 . . ?
Cl2 C01 H01A 112.6 . . ?
Cl1 C01 H01B 112.6 . . ?
Cl2 C01 H01B 112.6 . . ?
H01A C01 H01B 110.1 . . ?
C1 C2 C3 178.1(7) . . ?
C8 C3 C4 118.0(7) . . ?
C8 C3 C2 121.9(7) . . ?
C4 C3 C2 120.0(8) . . ?
C3 C4 C5 118.9(11) . . ?
C3 C4 H4A 120.5 . . ?
C5 C4 H4A 120.5 . . ?
C6 C5 C4 120.4(10) . . ?
C6 C5 H5A 119.8 . . ?
C4 C5 H5A 119.8 . . ?
C7 C6 C5 119.3(8) . . ?
C7 C6 H6A 120.4 . . ?
C5 C6 H6A 120.4 . . ?
C6 C7 C8 121.6(11) . . ?
C6 C7 H7A 119.2 . . ?
C8 C7 H7A 119.2 . . ?
C3 C8 C7 121.8(10) . . ?
C3 C8 H8A 119.1 . . ?
C7 C8 H8A 119.1 . . ?
C12 C11 Pt1 173.3(4) . . ?
C11 C12 C13 176.1(6) . . ?
C14 C13 C18 118.3(7) . . ?
C14 C13 C12 121.8(7) . . ?
C18 C13 C12 119.9(6) . . ?
C15 C14 C13 120.4(10) . . ?
C15 C14 H14A 119.8 . . ?
C13 C14 H14A 119.8 . . ?
C16 C15 C14 120.2(9) . . ?
C16 C15 H15A 119.9 . . ?
C14 C15 H15A 119.9 . . ?
C17 C16 C15 120.8(8) . . ?
C17 C16 H16A 119.6 . . ?
C15 C16 H16A 119.6 . . ?
C16 C17 C18 119.7(10) . . ?
C16 C17 H17A 120.2 . . ?
C18 C17 H17A 120.2 . . ?
C17 C18 C13 120.6(8) . . ?
C17 C18 H18A 119.7 . . ?
C13 C18 H18A 119.7 . . ?
C32 C31 Pt2 174.7(4) . . ?
C31 C32 C33 175.5(5) . . ?
C34 C33 C38 118.4(5) . . ?
C34 C33 C32 120.5(5) . . ?
C38 C33 C32 121.1(5) . . ?
C35 C34 C33 121.0(6) . . ?
C35 C34 H34A 119.5 . . ?
C33 C34 H34A 119.5 . . ?
C36 C35 C34 120.3(6) . . ?
C36 C35 H35A 119.8 . . ?
C34 C35 H35A 119.8 . . ?
C35 C36 C37 118.8(6) . . ?
C35 C36 H36A 120.6 . . ?
C37 C36 H36A 120.6 . . ?
C38 C37 C36 121.1(6) . . ?
C38 C37 H37A 119.4 . . ?
C36 C37 H37A 119.4 . . ?
C37 C38 C33 120.3(6) . . ?
C37 C38 H38A 119.9 . . ?
C33 C38 H38A 119.9 . . ?
C42 C41 Pt3 176.1(5) . . ?
C41 C42 C43 177.9(6) . . ?
C44 C43 C48 119.0(5) . . ?
C44 C43 C42 121.1(5) . . ?
C48 C43 C42 119.9(5) . . ?
C45 C44 C43 120.9(6) . . ?
C45 C44 H44A 119.5 . . ?
C43 C44 H44A 119.5 . . ?
C46 C45 C44 120.3(6) . . ?
C46 C45 H45A 119.9 . . ?
C44 C45 H45A 119.9 . . ?
C45 C46 C47 119.6(6) . . ?
C45 C46 H46A 120.2 . . ?
C47 C46 H46A 120.2 . . ?
C48 C47 C46 120.6(7) . . ?
C48 C47 H47A 119.7 . . ?
C46 C47 H47A 119.7 . . ?
C47 C48 C43 119.6(6) . . ?
C47 C48 H48A 120.2 . . ?
C43 C48 H48A 120.2 . . ?
C106 C101 C102 120.0(6) . . ?
C106 C101 P1 122.5(4) . . ?
C102 C101 P1 117.5(4) . . ?
C103 C102 C101 120.1(6) . . ?
C103 C102 H10A 119.9 . . ?
C101 C102 H10A 119.9 . . ?
C102 C103 C104 121.0(7) . . ?
C102 C103 H10B 119.5 . . ?
C104 C103 H10B 119.5 . . ?
C105 C104 C103 119.6(6) . . ?
C105 C104 H10C 120.2 . . ?
C103 C104 H10C 120.2 . . ?
C104 C105 C106 120.2(6) . . ?
C104 C105 H10D 119.9 . . ?
C106 C105 H10D 119.9 . . ?
C101 C106 C105 119.1(6) . . ?
C101 C106 H10E 120.5 . . ?
C105 C106 H10E 120.5 . . ?
C116 C111 C112 118.7(6) . . ?
C116 C111 P1 120.9(5) . . ?
C112 C111 P1 120.2(5) . . ?
C111 C112 C113 120.5(9) . . ?
C111 C112 H11A 119.8 . . ?
C113 C112 H11A 119.8 . . ?
C114 C113 C112 119.6(9) . . ?
C114 C113 H11B 120.2 . . ?
C112 C113 H11B 120.2 . . ?
C115 C114 C113 120.1(7) . . ?
C115 C114 H11C 119.9 . . ?
C113 C114 H11C 119.9 . . ?
C114 C115 C116 120.7(10) . . ?
C114 C115 H11D 119.6 . . ?
C116 C115 H11D 119.6 . . ?
C115 C116 C111 120.3(9) . . ?
C115 C116 H11E 119.8 . . ?
C111 C116 H11E 119.8 . . ?
C132 C131 C132 120.0(6) 3 . ?
C132 C131 H13A 120.0 3 . ?
C132 C131 H13A 120.0 . . ?
C133 C132 C131 119.8(5) . . ?
C133 C132 P1 122.4(4) . . ?
C131 C132 P1 117.8(3) . . ?
C132 C133 C134 120.5(5) . . ?
C132 C133 H13B 119.8 . . ?
C134 C133 H13B 119.8 . . ?
C133 C134 C133 119.5(6) 3 . ?
C133 C134 C135 120.3(3) 3 . ?
C133 C134 C135 120.3(3) . . ?
C136 C135 C136 119.0(11) 3 . ?
C136 C135 C134 120.5(6) 3 . ?
C136 C135 C134 120.5(6) . . ?
C135 C136 C137 114.9(13) . . ?
N1 C137 C136 132.5(12) . . ?
N1 C137 N1 36.1(16) . 3 ?
C136 C137 N1 120.1(13) . 3 ?
C202 C201 C206 118.8(5) . . ?
C202 C201 P2 121.5(4) . . ?
C206 C201 P2 119.7(4) . . ?
C201 C202 C203 120.4(6) . . ?
C201 C202 H20A 119.8 . . ?
C203 C202 H20A 119.8 . . ?
C204 C203 C202 120.3(7) . . ?
C204 C203 H20B 119.9 . . ?
C202 C203 H20B 119.9 . . ?
C203 C204 C205 120.0(6) . . ?
C203 C204 H20C 120.0 . . ?
C205 C204 H20C 120.0 . . ?
C204 C205 C206 119.7(6) . . ?
C204 C205 H20D 120.1 . . ?
C206 C205 H20D 120.1 . . ?
C205 C206 C201 120.7(6) . . ?
C205 C206 H20E 119.6 . . ?
C201 C206 H20E 119.6 . . ?
C212 C211 C216 119.6(5) . . ?
C212 C211 P2 118.6(4) . . ?
C216 C211 P2 121.8(4) . . ?
C211 C212 C213 120.2(6) . . ?
C211 C212 H21A 119.9 . . ?
C213 C212 H21A 119.9 . . ?
C214 C213 C212 120.0(7) . . ?
C214 C213 H21B 120.0 . . ?
C212 C213 H21B 120.0 . . ?
C213 C214 C215 120.9(6) . . ?
C213 C214 H21C 119.5 . . ?
C215 C214 H21C 119.5 . . ?
C216 C215 C214 118.6(6) . . ?
C216 C215 H21D 120.7 . . ?
C214 C215 H21D 120.7 . . ?
C211 C216 C215 120.4(5) . . ?
C211 C216 H21E 119.8 . . ?
C215 C216 H21E 119.8 . . ?
C232 C231 C232 120.1(6) 3 . ?
C232 C231 H23A 120.0 3 . ?
C232 C231 H23A 120.0 . . ?
C233 C232 C231 119.5(4) . . ?
C233 C232 P2 123.4(3) . . ?
C231 C232 P2 117.1(3) . . ?
C232 C233 C234 120.7(5) . . ?
C232 C233 H23B 119.7 . . ?
C234 C233 H23B 119.7 . . ?
C233 C234 C233 119.6(6) 3 . ?
C233 C234 C235 120.2(3) 3 . ?
C233 C234 C235 120.2(3) . . ?
C236 C235 C236 117.3(7) . 3 ?
C236 C235 C234 121.4(4) . . ?
C236 C235 C234 121.4(4) 3 . ?
C237 C236 C235 118.7(7) . . ?
C237 C236 H23C 120.6 . . ?
C235 C236 H23C 120.6 . . ?
N2 C237 C236 124.1(7) . . ?
N2 C237 H23D 117.9 . . ?
C236 C237 H23D 117.9 . . ?
C306 C301 C302 119.4(5) . . ?
C306 C301 P3 119.8(4) . . ?
C302 C301 P3 120.8(4) . . ?
C303 C302 C301 120.2(5) . . ?
C303 C302 H30A 119.9 . . ?
C301 C302 H30A 119.9 . . ?
C304 C303 C302 119.9(5) . . ?
C304 C303 H30B 120.0 . . ?
C302 C303 H30B 120.0 . . ?
C303 C304 C305 120.1(5) . . ?
C303 C304 H30C 119.9 . . ?
C305 C304 H30C 119.9 . . ?
C306 C305 C304 119.8(6) . . ?
C306 C305 H30D 120.1 . . ?
C304 C305 H30D 120.1 . . ?
C305 C306 C301 120.6(6) . . ?
C305 C306 H30E 119.7 . . ?
C301 C306 H30E 119.7 . . ?
C312 C311 C316 119.6(5) . . ?
C312 C311 P3 122.6(4) . . ?
C316 C311 P3 117.7(4) . . ?
C311 C312 C313 120.1(6) . . ?
C311 C312 H31A 119.9 . . ?
C313 C312 H31A 119.9 . . ?
C314 C313 C312 120.3(6) . . ?
C314 C313 H31B 119.8 . . ?
C312 C313 H31B 119.8 . . ?
C313 C314 C315 119.0(6) . . ?
C313 C314 H31C 120.5 . . ?
C315 C314 H31C 120.5 . . ?
C316 C315 C314 121.0(6) . . ?
C316 C315 H31D 119.5 . . ?
C314 C315 H31D 119.5 . . ?
C315 C316 C311 119.7(5) . . ?
C315 C316 H31E 120.2 . . ?
C311 C316 H31E 120.2 . . ?
C332 C331 C341 120.2(5) . . ?
C332 C331 H33A 119.9 . . ?
C341 C331 H33A 119.9 . . ?
C333 C332 C331 119.4(4) . . ?
C333 C332 P3 123.2(3) . . ?
C331 C332 P3 117.4(3) . . ?
C332 C333 C334 120.6(4) . . ?
C332 C333 H33B 119.7 . . ?
C334 C333 H33B 119.7 . . ?
C340 C334 C333 119.6(4) . . ?
C340 C334 C335 121.3(4) . . ?
C333 C334 C335 119.1(4) . . ?
C339 C335 C336 117.3(5) . . ?
C339 C335 C334 121.6(5) . . ?
C336 C335 C334 121.1(5) . . ?
C337 C336 C335 119.5(6) . . ?
C337 C336 H33C 120.2 . . ?
C335 C336 H33C 120.2 . . ?
N3 C337 C336 123.2(6) . . ?
N3 C337 H33D 118.4 . . ?
C336 C337 H33D 118.4 . . ?
N3 C338 C339 123.8(7) . . ?
N3 C338 H33E 118.1 . . ?
C339 C338 H33E 118.1 . . ?
C335 C339 C338 118.9(6) . . ?
C335 C339 H33F 120.6 . . ?
C338 C339 H33F 120.6 . . ?
C341 C340 C334 120.5(4) . . ?
C341 C340 H34B 119.7 . . ?
C334 C340 H34B 119.7 . . ?
C340 C341 C331 119.5(4) . . ?
C340 C341 P4 124.0(3) . . ?
C331 C341 P4 116.4(3) . . ?
C402 C401 C406 119.6(5) . . ?
C402 C401 P4 121.2(4) . . ?
C406 C401 P4 118.9(4) . . ?
C403 C402 C401 120.4(5) . . ?
C403 C402 H40A 119.8 . . ?
C401 C402 H40A 119.8 . . ?
C402 C403 C404 120.0(6) . . ?
C402 C403 H40B 120.0 . . ?
C404 C403 H40B 120.0 . . ?
C405 C404 C403 119.7(6) . . ?
C405 C404 H40C 120.2 . . ?
C403 C404 H40C 120.2 . . ?
C404 C405 C406 120.7(6) . . ?
C404 C405 H40D 119.7 . . ?
C406 C405 H40D 119.7 . . ?
C401 C406 C405 119.5(5) . . ?
C401 C406 H40E 120.2 . . ?
C405 C406 H40E 120.2 . . ?
C416 C411 C412 119.2(5) . . ?
C416 C411 P4 121.8(4) . . ?
C412 C411 P4 119.0(4) . . ?
C411 C412 C413 119.6(7) . . ?
C411 C412 H41A 120.2 . . ?
C413 C412 H41A 120.2 . . ?
C414 C413 C412 120.3(7) . . ?
C414 C413 H41B 119.9 . . ?
C412 C413 H41B 119.9 . . ?
C415 C414 C413 119.9(6) . . ?
C415 C414 H41C 120.0 . . ?
C413 C414 H41C 120.0 . . ?
C414 C415 C416 119.7(6) . . ?
C414 C415 H41D 120.2 . . ?
C416 C415 H41D 120.2 . . ?
C411 C416 C415 121.2(6) . . ?
C411 C416 H41E 119.4 . . ?
C415 C416 H41E 119.4 . . ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        30.71
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         9.479
_refine_diff_density_min         -4.851
_refine_diff_density_rms         0.493

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_w1_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 1990103'
loop_
_audit_author_name
_audit_author_address
'Qiao-Hua Wei'
;College of Chemistry, Fuzhou University
China
;
_audit_update_record             
;
2020-03-13 deposited with the CCDC.	2020-05-08 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C123 H112 Au0 Cl2 N4 O0 P4 Pt2'
_chemical_formula_weight         2231.13

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   32.222(6)
_cell_length_b                   16.172(3)
_cell_length_c                   20.802(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 92.77(3)
_cell_angle_gamma                90.00
_cell_volume                     10827(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    193(2)
_cell_measurement_reflns_used    18050
_cell_measurement_theta_min      1.43
_cell_measurement_theta_max      31.98

_exptl_crystal_description       prism
_exptl_crystal_colour            pale
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.369
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4512
_exptl_absorpt_coefficient_mu    2.740
_exptl_absorpt_correction_type   sphere
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   
'spherical harmonics expansion of the absorption surface (Katayama, et al. 1986)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      193(2)
_diffrn_radiation_wavelength     0.72000
_diffrn_radiation_type           synchrotron
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Mar CCD 165 nm'
_diffrn_measurement_method       oscillation
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_decay_%        none
_diffrn_reflns_number            32284
_diffrn_reflns_av_R_equivalents  0.0148
_diffrn_reflns_av_sigmaI/netI    0.0202
_diffrn_reflns_limit_h_min       -47
_diffrn_reflns_limit_h_max       47
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.43
_diffrn_reflns_theta_max         31.98
_reflns_number_total             18050
_reflns_number_gt                17500
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Mar CCD'
_computing_cell_refinement       HKL2000
_computing_data_reduction        HKL2000
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0699P)²+40.2493P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.00324(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         18050
_refine_ls_number_parameters     605
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0382
_refine_ls_R_factor_gt           0.0375
_refine_ls_wR_factor_ref         0.1081
_refine_ls_wR_factor_gt          0.1068
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_restrained_S_all      1.056
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.741001(2) 0.318454(5) 1.120151(4) 0.01382(4) Uani 1 1 d . . .
P2 P 0.778216(18) 0.20949(4) 1.16255(3) 0.01539(10) Uani 1 1 d . . .
P1 P 0.705151(17) 0.42769(3) 1.07458(3) 0.01382(10) Uani 1 1 d . . .
C1 C 0.68026(7) 0.40122(14) 0.99674(10) 0.0151(3) Uani 1 1 d . . .
C2 C 0.81339(7) 0.16002(15) 1.10854(11) 0.0169(4) Uani 1 1 d . . .
C3 C 0.78486(7) 0.33945(16) 1.05805(11) 0.0179(4) Uani 1 1 d . . .
C4 C 0.73704(7) 0.51677(14) 1.05648(12) 0.0176(4) Uani 1 1 d . . .
C5 C 0.80934(8) 0.24477(15) 1.23212(11) 0.0184(4) Uani 1 1 d . . .
C6 C 0.75108(8) 0.11870(14) 1.18968(11) 0.0192(4) Uani 1 1 d . . .
C7 C 0.62905(8) 0.41631(15) 1.12960(12) 0.0200(4) Uani 1 1 d . . .
H7A H 0.6307 0.3593 1.1190 0.024 Uiso 1 1 calc R . .
C8 C 0.58463(8) 0.45535(17) 0.89250(12) 0.0214(4) Uani 1 1 d . . .
C9 C 0.79764(7) 0.14652(14) 1.04570(11) 0.0164(4) Uani 1 1 d . . .
H9A H 0.7717 0.1700 1.0318 0.020 Uiso 1 1 calc R . .
C10 C 0.62523(7) 0.41950(15) 0.91425(11) 0.0187(4) Uani 1 1 d . . .
C11 C 0.85180(7) 0.12656(15) 1.12851(11) 0.0188(4) Uani 1 1 d . . .
H11A H 0.8624 0.1351 1.1714 0.023 Uiso 1 1 calc R . .
C12 C 0.68067(8) 0.29853(17) 1.23727(12) 0.0217(4) Uani 1 1 d . . .
C13 C 0.66228(7) 0.46914(14) 1.11750(10) 0.0161(4) Uani 1 1 d . . .
C14 C 0.81275(8) 0.35532(16) 1.02217(13) 0.0223(4) Uani 1 1 d . . .
C15 C 0.64144(7) 0.43315(15) 0.97662(11) 0.0174(4) Uani 1 1 d . . .
H15A H 0.6260 0.4645 1.0058 0.021 Uiso 1 1 calc R . .
C16 C 0.70157(8) 0.30385(16) 1.18990(12) 0.0178(4) Uani 1 1 d . . .
C17 C 0.62527(8) 0.58165(16) 1.16560(13) 0.0235(5) Uani 1 1 d . . .
H17A H 0.6243 0.6375 1.1796 0.028 Uiso 1 1 calc R . .
C18 C 0.79394(9) 0.23823(17) 1.29337(12) 0.0233(5) Uani 1 1 d . . .
H18A H 0.7681 0.2115 1.2991 0.028 Uiso 1 1 calc R . .
C19 C 0.66028(8) 0.55189(15) 1.13623(12) 0.0197(4) Uani 1 1 d . . .
H19A H 0.6828 0.5880 1.1289 0.024 Uiso 1 1 calc R . .
C20 C 0.65661(8) 0.29352(18) 1.29281(12) 0.0234(4) Uani 1 1 d . . .
C21 C 0.73175(10) 0.55982(19) 0.99928(16) 0.0311(6) Uani 1 1 d . . .
H21A H 0.7118 0.5416 0.9673 0.037 Uiso 1 1 calc R . .
C22 C 0.59376(8) 0.44672(17) 1.15691(12) 0.0225(4) Uani 1 1 d . . .
H22A H 0.5710 0.4110 1.1637 0.027 Uiso 1 1 calc R . .
N1 N 0.50783(8) 0.5216(2) 0.84827(13) 0.0358(6) Uani 1 1 d . . .
C24 C 0.77472(9) 0.05607(16) 1.22002(13) 0.0243(5) Uani 1 1 d . . .
H24A H 0.8037 0.0638 1.2287 0.029 Uiso 1 1 calc R . .
C25 C 0.58083(8) 0.50025(19) 0.83549(12) 0.0251(5) Uani 1 1 d . . .
H25A H 0.6043 0.5093 0.8104 0.030 Uiso 1 1 calc R . .
C26 C 0.86928(12) 0.31792(18) 1.27734(18) 0.0328(7) Uani 1 1 d . . .
H26A H 0.8951 0.3449 1.2719 0.039 Uiso 1 1 calc R . .
C27 C 0.84677(9) 0.28594(17) 1.22431(13) 0.0255(5) Uani 1 1 d . . .
H27A H 0.8570 0.2922 1.1825 0.031 Uiso 1 1 calc R . .
C28 C 0.84619(8) 0.37416(17) 0.98219(13) 0.0242(5) Uani 1 1 d . . .
C29 C 0.76700(9) 0.54368(18) 1.10262(14) 0.0280(5) Uani 1 1 d . . .
H29A H 0.7714 0.5140 1.1418 0.034 Uiso 1 1 calc R . .
C30 C 0.66707(10) 0.3377(2) 1.34860(14) 0.0277(5) Uani 1 1 d . . .
H30A H 0.6907 0.3728 1.3497 0.033 Uiso 1 1 calc R . .
C31 C 0.75599(11) -0.01749(17) 1.23752(14) 0.0301(6) Uani 1 1 d . . .
H31A H 0.7721 -0.0601 1.2578 0.036 Uiso 1 1 calc R . .
C32 C 0.54911(9) 0.4459(2) 0.92752(14) 0.0310(6) Uani 1 1 d . . .
H32A H 0.5503 0.4167 0.9672 0.037 Uiso 1 1 calc R . .
C33 C 0.59172(8) 0.52939(17) 1.17438(12) 0.0230(4) Uani 1 1 d . . .
H33A H 0.5673 0.5504 1.1924 0.028 Uiso 1 1 calc R . .
C34 C 0.70874(9) 0.10712(17) 1.17706(16) 0.0296(6) Uani 1 1 d . . .
H34A H 0.6924 0.1491 1.1563 0.035 Uiso 1 1 calc R . .
C35 C 0.85398(12) 0.31037(19) 1.33815(16) 0.0337(7) Uani 1 1 d . . .
H35A H 0.8693 0.3324 1.3744 0.040 Uiso 1 1 calc R . .
C36 C 0.60922(9) 0.2807(2) 1.40409(13) 0.0293(5) Uani 1 1 d . . .
C37 C 0.58584(15) 0.1800(2) 1.4861(2) 0.0429(9) Uani 1 1 d . . .
H37A H 0.5753 0.1438 1.4512 0.064 Uiso 1 1 calc R . .
H37B H 0.5689 0.1730 1.5235 0.064 Uiso 1 1 calc R . .
H37C H 0.6148 0.1656 1.4978 0.064 Uiso 1 1 calc R . .
C38 C 0.79049(10) 0.6141(2) 1.09124(17) 0.0351(6) Uani 1 1 d . . .
H38A H 0.8105 0.6328 1.1230 0.042 Uiso 1 1 calc R . .
C39 C 0.81659(11) 0.27102(19) 1.34631(13) 0.0303(6) Uani 1 1 d . . .
H39A H 0.8062 0.2662 1.3881 0.036 Uiso 1 1 calc R . .
C40 C 0.64365(10) 0.3315(2) 1.40289(14) 0.0282(5) Uani 1 1 d . . .
H40A H 0.6515 0.3630 1.4401 0.034 Uiso 1 1 calc R . .
C41 C 0.54202(9) 0.5318(2) 0.81586(14) 0.0305(6) Uani 1 1 d . . .
H41A H 0.5399 0.5624 0.7769 0.037 Uiso 1 1 calc R . .
C42 C 0.91479(10) 0.4120(3) 0.90709(17) 0.0380(7) Uani 1 1 d . . .
C43 C 0.69048(12) 0.0332(2) 1.1952(2) 0.0411(8) Uani 1 1 d . . .
H43A H 0.6615 0.0251 1.1868 0.049 Uiso 1 1 calc R . .
C44 C 0.51212(9) 0.4798(3) 0.90347(16) 0.0377(7) Uani 1 1 d . . .
H44A H 0.4882 0.4728 0.9279 0.045 Uiso 1 1 calc R . .
C45 C 0.60002(17) 0.3244(3) 1.52004(19) 0.0486(11) Uani 1 1 d . . .
H45A H 0.5987 0.3828 1.5075 0.073 Uiso 1 1 calc R . .
H45B H 0.6289 0.3092 1.5316 0.073 Uiso 1 1 calc R . .
H45C H 0.5829 0.3155 1.5571 0.073 Uiso 1 1 calc R . .
C46 C 0.71377(13) -0.02846(19) 1.22533(18) 0.0387(7) Uani 1 1 d . . .
H46A H 0.7008 -0.0784 1.2377 0.046 Uiso 1 1 calc R . .
C47 C 0.78486(11) 0.6568(2) 1.0340(2) 0.0397(8) Uani 1 1 d . . .
H47A H 0.8011 0.7045 1.0261 0.048 Uiso 1 1 calc R . .
C48 C 0.58357(10) 0.2705(2) 1.46349(14) 0.0336(6) Uani 1 1 d . . .
C49 C 0.59943(14) 0.2348(3) 1.34903(17) 0.0555(13) Uani 1 1 d . . .
H49A H 0.5765 0.1979 1.3488 0.067 Uiso 1 1 calc R . .
C50 C 0.86823(15) 0.3126(2) 0.9531(3) 0.0506(12) Uani 1 1 d . . .
H50A H 0.8601 0.2566 0.9581 0.061 Uiso 1 1 calc R . .
C51 C 0.75555(12) 0.6297(2) 0.9884(2) 0.0464(10) Uani 1 1 d . . .
H51A H 0.7515 0.6592 0.9491 0.056 Uiso 1 1 calc R . .
C52 C 0.85766(15) 0.4549(2) 0.9700(3) 0.0555(13) Uani 1 1 d . . .
H52A H 0.8423 0.4991 0.9873 0.067 Uiso 1 1 calc R . .
C54 C 0.53809(15) 0.2930(4) 1.4471(2) 0.0641(14) Uani 1 1 d . . .
H54A H 0.5364 0.3507 1.4328 0.096 Uiso 1 1 calc R . .
H54B H 0.5219 0.2859 1.4854 0.096 Uiso 1 1 calc R . .
H54C H 0.5269 0.2568 1.4126 0.096 Uiso 1 1 calc R . .
C55 C 0.95328(11) 0.4341(3) 0.8705(2) 0.0537(12) Uani 1 1 d . . .
C56 C 0.62231(14) 0.2414(3) 1.29424(16) 0.0562(13) Uani 1 1 d . . .
H56A H 0.6144 0.2098 1.2572 0.067 Uiso 1 1 calc R . .
C57 C 0.90197(17) 0.3309(3) 0.9168(3) 0.0642(16) Uani 1 1 d . . .
H57A H 0.9168 0.2870 0.8980 0.077 Uiso 1 1 calc R . .
C59 C 0.89111(15) 0.4725(3) 0.9330(3) 0.0565(12) Uani 1 1 d . . .
H59A H 0.8979 0.5287 0.9253 0.068 Uiso 1 1 calc R . .
C62 C 0.98867(15) 0.4509(4) 0.9184(4) 0.0768(18) Uani 1 1 d . . .
H62A H 0.9817 0.4980 0.9455 0.115 Uiso 1 1 calc R . .
H62B H 1.0138 0.4638 0.8955 0.115 Uiso 1 1 calc R . .
H62C H 0.9937 0.4020 0.9454 0.115 Uiso 1 1 calc R . .
C63 C 0.96689(19) 0.3609(6) 0.8284(3) 0.097(3) Uani 1 1 d . . .
H63A H 0.9915 0.3767 0.8055 0.146 Uiso 1 1 calc R . .
H63B H 0.9443 0.3465 0.7972 0.146 Uiso 1 1 calc R . .
H63C H 0.9735 0.3130 0.8560 0.146 Uiso 1 1 calc R . .
C64 C 0.9471(3) 0.5135(6) 0.8331(5) 0.114(3) Uiso 1 1 d . . .
H64A H 0.9386 0.5575 0.8621 0.170 Uiso 1 1 calc R . .
H64B H 0.9254 0.5055 0.7989 0.170 Uiso 1 1 calc R . .
H64C H 0.9731 0.5291 0.8139 0.170 Uiso 1 1 calc R . .
C02 C 0.9187(3) 0.4250(5) 1.1415(3) 0.091(3) Uani 1 1 d . . .
C01 C 0.89581(17) 0.5182(4) 1.1706(3) 0.0663(14) Uani 1 1 d . . .
H01A H 0.8927 0.5584 1.1354 0.100 Uiso 1 1 calc R . .
H01B H 0.9138 0.5414 1.2054 0.100 Uiso 1 1 calc R . .
H01C H 0.8684 0.5057 1.1868 0.100 Uiso 1 1 calc R . .
N01 N 0.9311(2) 0.3703(5) 1.1301(4) 0.118(3) Uani 1 1 d . . .
Cl1 Cl 1.0309(3) 0.2251(4) 1.2031(8) 0.576(12) Uani 1 1 d . . .
C03 C 1.0000 0.1774(10) 1.2500 0.192(12) Uani 1 2 d S . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C16 1.988(2) . ?
Pt1 C3 1.989(2) . ?
Pt1 P2 2.2845(7) . ?
Pt1 P1 2.2908(7) . ?
P2 C5 1.813(2) . ?
P2 C6 1.813(3) . ?
P2 C2 1.819(2) . ?
P1 C13 1.809(2) . ?
P1 C4 1.819(2) . ?
P1 C1 1.823(2) . ?
C1 C9 1.394(3) 7_657 ?
C1 C15 1.399(3) . ?
C2 C11 1.396(3) . ?
C2 C9 1.396(3) . ?
C3 C14 1.223(3) . ?
C4 C21 1.382(4) . ?
C4 C29 1.398(4) . ?
C5 C18 1.393(3) . ?
C5 C27 1.394(4) . ?
C6 C34 1.390(4) . ?
C6 C24 1.399(3) . ?
C7 C22 1.385(3) . ?
C7 C13 1.402(3) . ?
C7 H7A 0.9500 . ?
C8 C25 1.391(4) . ?
C8 C32 1.395(4) . ?
C8 C10 1.482(3) . ?
C9 C1 1.394(3) 7_657 ?
C9 H9A 0.9500 . ?
C10 C15 1.393(3) . ?
C10 C11 1.399(3) 7_657 ?
C11 C10 1.399(3) 7_657 ?
C11 H11A 0.9500 . ?
C12 C16 1.223(3) . ?
C12 C20 1.424(3) . ?
C13 C19 1.396(3) . ?
C14 C28 1.425(4) . ?
C15 H15A 0.9500 . ?
C17 C33 1.391(4) . ?
C17 C19 1.394(3) . ?
C17 H17A 0.9500 . ?
C18 C39 1.396(4) . ?
C18 H18A 0.9500 . ?
C19 H19A 0.9500 . ?
C20 C30 1.390(4) . ?
C20 C56 1.391(4) . ?
C21 C51 1.391(4) . ?
C21 H21A 0.9500 . ?
C22 C33 1.388(4) . ?
C22 H22A 0.9500 . ?
N1 C41 1.329(4) . ?
N1 C44 1.334(4) . ?
C24 C31 1.390(4) . ?
C24 H24A 0.9500 . ?
C25 C41 1.393(4) . ?
C25 H25A 0.9500 . ?
C26 C35 1.385(5) . ?
C26 C27 1.390(4) . ?
C26 H26A 0.9500 . ?
C27 H27A 0.9500 . ?
C28 C50 1.379(4) . ?
C28 C52 1.384(4) . ?
C29 C38 1.394(4) . ?
C29 H29A 0.9500 . ?
C30 C40 1.392(4) . ?
C30 H30A 0.9500 . ?
C31 C46 1.383(5) . ?
C31 H31A 0.9500 . ?
C32 C44 1.383(4) . ?
C32 H32A 0.9500 . ?
C33 H33A 0.9500 . ?
C34 C43 1.393(4) . ?
C34 H34A 0.9500 . ?
C35 C39 1.380(5) . ?
C35 H35A 0.9500 . ?
C36 C40 1.381(4) . ?
C36 C49 1.388(5) . ?
C36 C48 1.528(4) . ?
C37 C48 1.537(5) . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 C47 1.381(5) . ?
C38 H38A 0.9500 . ?
C39 H39A 0.9500 . ?
C40 H40A 0.9500 . ?
C41 H41A 0.9500 . ?
C42 C59 1.367(6) . ?
C42 C57 1.393(6) . ?
C42 C55 1.529(5) . ?
C43 C46 1.379(5) . ?
C43 H43A 0.9500 . ?
C44 H44A 0.9500 . ?
C45 C48 1.537(5) . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9500 . ?
C47 C51 1.377(5) . ?
C47 H47A 0.9500 . ?
C48 C54 1.532(6) . ?
C49 C56 1.391(5) . ?
C49 H49A 0.9500 . ?
C50 C57 1.386(5) . ?
C50 H50A 0.9500 . ?
C51 H51A 0.9500 . ?
C52 C59 1.384(5) . ?
C52 H52A 0.9500 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
C55 C62 1.503(8) . ?
C55 C64 1.509(11) . ?
C55 C63 1.548(10) . ?
C56 H56A 0.9500 . ?
C57 H57A 0.9500 . ?
C59 H59A 0.9500 . ?
C62 H62A 0.9800 . ?
C62 H62B 0.9800 . ?
C62 H62C 0.9800 . ?
C63 H63A 0.9800 . ?
C63 H63B 0.9800 . ?
C63 H63C 0.9800 . ?
C64 H64A 0.9800 . ?
C64 H64B 0.9800 . ?
C64 H64C 0.9800 . ?
C02 N01 1.005(11) . ?
C02 C01 1.795(11) . ?
C01 H01A 0.9800 . ?
C01 H01B 0.9800 . ?
C01 H01C 0.9800 . ?
Cl1 C03 1.623(11) . ?
C03 Cl1 1.623(11) 2_757 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C16 Pt1 C3 173.29(10) . . ?
C16 Pt1 P2 88.20(7) . . ?
C3 Pt1 P2 90.36(7) . . ?
C16 Pt1 P1 93.80(7) . . ?
C3 Pt1 P1 87.68(7) . . ?
P2 Pt1 P1 177.98(2) . . ?
C5 P2 C6 105.25(11) . . ?
C5 P2 C2 107.12(11) . . ?
C6 P2 C2 99.22(11) . . ?
C5 P2 Pt1 108.98(8) . . ?
C6 P2 Pt1 119.53(8) . . ?
C2 P2 Pt1 115.58(8) . . ?
C13 P1 C4 105.13(11) . . ?
C13 P1 C1 102.21(10) . . ?
C4 P1 C1 103.34(11) . . ?
C13 P1 Pt1 117.60(8) . . ?
C4 P1 Pt1 114.69(8) . . ?
C1 P1 Pt1 112.21(8) . . ?
C9 C1 C15 119.5(2) 7_657 . ?
C9 C1 P1 118.44(16) 7_657 . ?
C15 C1 P1 121.87(17) . . ?
C11 C2 C9 119.7(2) . . ?
C11 C2 P2 123.83(18) . . ?
C9 C2 P2 115.96(17) . . ?
C14 C3 Pt1 176.6(2) . . ?
C21 C4 C29 119.1(2) . . ?
C21 C4 P1 122.0(2) . . ?
C29 C4 P1 118.86(19) . . ?
C18 C5 C27 119.4(2) . . ?
C18 C5 P2 119.9(2) . . ?
C27 C5 P2 120.38(19) . . ?
C34 C6 C24 119.7(2) . . ?
C34 C6 P2 122.29(19) . . ?
C24 C6 P2 117.8(2) . . ?
C22 C7 C13 120.4(2) . . ?
C22 C7 H7A 119.8 . . ?
C13 C7 H7A 119.8 . . ?
C25 C8 C32 117.5(2) . . ?
C25 C8 C10 120.3(2) . . ?
C32 C8 C10 122.2(2) . . ?
C1 C9 C2 120.4(2) 7_657 . ?
C1 C9 H9A 119.8 7_657 . ?
C2 C9 H9A 119.8 . . ?
C15 C10 C11 119.4(2) . 7_657 ?
C15 C10 C8 120.6(2) . . ?
C11 C10 C8 120.0(2) 7_657 . ?
C2 C11 C10 120.4(2) . 7_657 ?
C2 C11 H11A 119.8 . . ?
C10 C11 H11A 119.8 7_657 . ?
C16 C12 C20 179.1(3) . . ?
C19 C13 C7 119.2(2) . . ?
C19 C13 P1 122.64(18) . . ?
C7 C13 P1 118.08(17) . . ?
C3 C14 C28 178.1(3) . . ?
C10 C15 C1 120.7(2) . . ?
C10 C15 H15A 119.7 . . ?
C1 C15 H15A 119.7 . . ?
C12 C16 Pt1 172.9(2) . . ?
C33 C17 C19 119.9(2) . . ?
C33 C17 H17A 120.1 . . ?
C19 C17 H17A 120.1 . . ?
C5 C18 C39 119.8(3) . . ?
C5 C18 H18A 120.1 . . ?
C39 C18 H18A 120.1 . . ?
C17 C19 C13 120.2(2) . . ?
C17 C19 H19A 119.9 . . ?
C13 C19 H19A 119.9 . . ?
C30 C20 C56 117.0(3) . . ?
C30 C20 C12 121.9(3) . . ?
C56 C20 C12 121.0(3) . . ?
C4 C21 C51 120.2(3) . . ?
C4 C21 H21A 119.9 . . ?
C51 C21 H21A 119.9 . . ?
C7 C22 C33 120.0(2) . . ?
C7 C22 H22A 120.0 . . ?
C33 C22 H22A 120.0 . . ?
C41 N1 C44 116.4(3) . . ?
C31 C24 C6 120.3(3) . . ?
C31 C24 H24A 119.9 . . ?
C6 C24 H24A 119.9 . . ?
C8 C25 C41 118.8(3) . . ?
C8 C25 H25A 120.6 . . ?
C41 C25 H25A 120.6 . . ?
C35 C26 C27 119.8(3) . . ?
C35 C26 H26A 120.1 . . ?
C27 C26 H26A 120.1 . . ?
C26 C27 C5 120.4(3) . . ?
C26 C27 H27A 119.8 . . ?
C5 C27 H27A 119.8 . . ?
C50 C28 C52 116.9(3) . . ?
C50 C28 C14 121.4(3) . . ?
C52 C28 C14 121.7(3) . . ?
C38 C29 C4 120.0(3) . . ?
C38 C29 H29A 120.0 . . ?
C4 C29 H29A 120.0 . . ?
C20 C30 C40 121.4(3) . . ?
C20 C30 H30A 119.3 . . ?
C40 C30 H30A 119.3 . . ?
C46 C31 C24 119.8(3) . . ?
C46 C31 H31A 120.1 . . ?
C24 C31 H31A 120.1 . . ?
C44 C32 C8 118.8(3) . . ?
C44 C32 H32A 120.6 . . ?
C8 C32 H32A 120.6 . . ?
C22 C33 C17 120.3(2) . . ?
C22 C33 H33A 119.9 . . ?
C17 C33 H33A 119.9 . . ?
C6 C34 C43 119.2(3) . . ?
C6 C34 H34A 120.4 . . ?
C43 C34 H34A 120.4 . . ?
C39 C35 C26 120.3(3) . . ?
C39 C35 H35A 119.9 . . ?
C26 C35 H35A 119.9 . . ?
C40 C36 C49 117.0(3) . . ?
C40 C36 C48 123.0(3) . . ?
C49 C36 C48 120.0(3) . . ?
C48 C37 H37A 109.5 . . ?
C48 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C48 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C47 C38 C29 120.4(3) . . ?
C47 C38 H38A 119.8 . . ?
C29 C38 H38A 119.8 . . ?
C35 C39 C18 120.3(3) . . ?
C35 C39 H39A 119.9 . . ?
C18 C39 H39A 119.9 . . ?
C36 C40 C30 121.7(3) . . ?
C36 C40 H40A 119.2 . . ?
C30 C40 H40A 119.2 . . ?
N1 C41 C25 124.1(3) . . ?
N1 C41 H41A 118.0 . . ?
C25 C41 H41A 118.0 . . ?
C59 C42 C57 116.2(3) . . ?
C59 C42 C55 120.7(4) . . ?
C57 C42 C55 123.1(4) . . ?
C46 C43 C34 121.1(3) . . ?
C46 C43 H43A 119.5 . . ?
C34 C43 H43A 119.5 . . ?
N1 C44 C32 124.3(3) . . ?
N1 C44 H44A 117.8 . . ?
C32 C44 H44A 117.8 . . ?
C48 C45 H45A 109.5 . . ?
C48 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C48 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C43 C46 C31 120.0(3) . . ?
C43 C46 H46A 120.0 . . ?
C31 C46 H46A 120.0 . . ?
C51 C47 C38 119.4(3) . . ?
C51 C47 H47A 120.3 . . ?
C38 C47 H47A 120.3 . . ?
C36 C48 C54 110.1(3) . . ?
C36 C48 C45 112.2(3) . . ?
C54 C48 C45 109.0(4) . . ?
C36 C48 C37 109.2(3) . . ?
C54 C48 C37 109.0(4) . . ?
C45 C48 C37 107.2(3) . . ?
C36 C49 C56 121.8(3) . . ?
C36 C49 H49A 119.1 . . ?
C56 C49 H49A 119.1 . . ?
C28 C50 C57 121.3(3) . . ?
C28 C50 H50A 119.4 . . ?
C57 C50 H50A 119.4 . . ?
C47 C51 C21 120.8(3) . . ?
C47 C51 H51A 119.6 . . ?
C21 C51 H51A 119.6 . . ?
C59 C52 C28 121.2(3) . . ?
C59 C52 H52A 119.4 . . ?
C28 C52 H52A 119.4 . . ?
C48 C54 H54A 109.5 . . ?
C48 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C48 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
C62 C55 C64 105.4(6) . . ?
C62 C55 C42 108.6(4) . . ?
C64 C55 C42 111.4(5) . . ?
C62 C55 C63 106.6(4) . . ?
C64 C55 C63 113.2(6) . . ?
C42 C55 C63 111.2(4) . . ?
C49 C56 C20 121.1(3) . . ?
C49 C56 H56A 119.4 . . ?
C20 C56 H56A 119.4 . . ?
C50 C57 C42 121.7(4) . . ?
C50 C57 H57A 119.1 . . ?
C42 C57 H57A 119.1 . . ?
C42 C59 C52 122.5(4) . . ?
C42 C59 H59A 118.7 . . ?
C52 C59 H59A 118.7 . . ?
C55 C62 H62A 109.5 . . ?
C55 C62 H62B 109.5 . . ?
H62A C62 H62B 109.5 . . ?
C55 C62 H62C 109.5 . . ?
H62A C62 H62C 109.5 . . ?
H62B C62 H62C 109.5 . . ?
C55 C63 H63A 109.5 . . ?
C55 C63 H63B 109.5 . . ?
H63A C63 H63B 109.5 . . ?
C55 C63 H63C 109.5 . . ?
H63A C63 H63C 109.5 . . ?
H63B C63 H63C 109.5 . . ?
C55 C64 H64A 109.5 . . ?
C55 C64 H64B 109.5 . . ?
H64A C64 H64B 109.5 . . ?
C55 C64 H64C 109.5 . . ?
H64A C64 H64C 109.5 . . ?
H64B C64 H64C 109.5 . . ?
N01 C02 C01 173.6(8) . . ?
C02 C01 H01A 109.5 . . ?
C02 C01 H01B 109.5 . . ?
H01A C01 H01B 109.5 . . ?
C02 C01 H01C 109.5 . . ?
H01A C01 H01C 109.5 . . ?
H01B C01 H01C 109.5 . . ?
Cl1 C03 Cl1 123.3(10) . 2_757 ?

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        31.98
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         2.270
_refine_diff_density_min         -2.172
_refine_diff_density_rms         0.151

