# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_nh-34
_database_code_depnum_ccdc_archive 'CCDC 1997669'
_audit_update_record             
;
2020-04-17 deposited with the CCDC.	2020-06-03 downloaded from the CCDC.
;
_audit_creation_date             2020-04-16
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C18 H32 N2 O4 Sn'
_chemical_formula_sum            'C18 H32 N2 O4 Sn'
_chemical_formula_weight         459.14
_chemical_melting_point          ?
_chemical_oxdiff_formula         C18H32N2O4Sn
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn 0.0259 5.4591 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   8.28458(9)
_cell_length_b                   15.15852(17)
_cell_length_c                   16.5128(2)
_cell_angle_alpha                90
_cell_angle_beta                 94.1801(11)
_cell_angle_gamma                90
_cell_volume                     2068.19(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    8332
_cell_measurement_temperature    99.99(10)
_cell_measurement_theta_max      75.9140
_cell_measurement_theta_min      3.9670
_shelx_estimated_absorpt_T_max   0.434
_shelx_estimated_absorpt_T_min   0.289
_exptl_absorpt_coefficient_mu    10.019
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.496
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.20a (Rigaku Oxford Diffraction, 2018)
Numerical absorption correction based on gaussian integration over
			a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear yellowish'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_density_diffrn    1.475
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             944
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
2 6 -7 0.0671
3 8 0 0.0650
-3 3 8 0.0089
-4 6 2 0.0500
4 -6 -2 0.0500
5 5 1 0.0833
-3 -7 -2 0.0725
3 7 2 0.0725
-1 -3 -10 0.0960
-1 -10 2 0.0805
-3 4 -7 0.0670
3 -4 7 0.0670

_exptl_crystal_size_max          0.165
_exptl_crystal_size_mid          0.145
_exptl_crystal_size_min          0.1
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
1.9509 6.3709 -7.4518 0.5025 0.0408 0.8636
2.8335 8.3609 -0.1414 -0.0422 0.5455 0.8371
-3.4649 2.7171 8.1258 -0.0630 0.7840 -0.6175
-4.2510 5.9110 1.8790 0.5719 0.7458 -0.3415
4.2510 -5.9110 -1.8790 -0.5719 -0.7458 0.3415
4.6890 4.5530 1.0330 -0.4719 0.2258 0.8523
-3.4210 -7.2470 -1.9640 0.2956 -0.5421 -0.7866
3.4210 7.2470 1.9640 -0.2956 0.5421 0.7866
-1.3450 -3.0060 -9.6250 0.7258 -0.6879 -0.0107
-1.1630 -9.5110 1.6580 -0.2995 -0.6269 -0.7193
-2.9070 4.2530 -7.2940 0.9941 0.0790 0.0749
2.9070 -4.2530 7.2940 -0.9941 -0.0790 -0.0749

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0406
_diffrn_reflns_av_unetI/netI     0.0389
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.969
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            13580
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.969
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.870
_diffrn_reflns_theta_min         3.964
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      99.99(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -102.00 -23.00   0.50    0.05    --  -47.45 -80.00-174.00  158
  2  ω     12.00  47.00   0.50    0.05    --   47.45 -80.00-174.00   70
  3  ω     57.00  83.00   0.50    0.07    --  106.49 -80.00-174.00   52
  4  ω     51.00 101.00   0.50    0.07    --  106.49 -94.00 -90.00  100
  5  ω     36.00  69.00   0.50    0.07    --  106.49 -61.00-150.00   66
  6  ω     34.00  74.00   0.50    0.07    --  106.49 -61.00-180.00   80
  7  ω     97.00 175.00   0.50    0.07    --  106.49  15.00-120.00  156
  8  ω    153.00 178.00   0.50    0.07    --  106.49  77.00  30.00   50
  9  ω    135.00 161.00   0.50    0.07    --  106.49  61.00  60.00   52
 10  ω     93.00 131.00   0.50    0.07    --  106.49  61.00  60.00   76
 11  ω    102.00 128.00   0.50    0.07    --  106.49  77.00  30.00   52
 12  ω     83.00 172.00   0.50    0.07    --  106.49  80.00 -51.00  178
 13  ω     48.00  73.00   0.50    0.05    --   47.45  80.00 -51.00   50
 14  ω     34.00  62.00   0.50    0.07    --  106.49 -61.00 -90.00   56
 15  ω     38.00  63.00   0.50    0.07    --  106.49 -61.00 -30.00   50
 16  ω     34.00  72.00   0.50    0.07    --  106.49 -94.00  30.00   76
 17  ω     38.00  74.00   0.50    0.07    --  106.49 -61.00   0.00   72
 18  ω     37.00  62.00   0.50    0.07    --  106.49 -61.00 120.00   50
 19  ω    -71.00  24.00   0.50    0.05    --  -47.45  80.00 -51.00  190
 20  ω    -40.00 -14.00   0.50    0.07    --  -86.25  45.00 150.00   52
 21  ω    -68.00 -21.00   0.50    0.07    --  -86.25  61.00 150.00   94
 22  ω    -85.00 -59.00   0.50    0.07    --  -86.25  80.00 -51.00   52
 23  ω   -115.00 -77.00   0.50    0.05    --  -47.45-125.00 -30.00   76
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.1181929000
_diffrn_orient_matrix_UB_12      0.0338298000
_diffrn_orient_matrix_UB_13      -0.0694591000
_diffrn_orient_matrix_UB_21      -0.0410657000
_diffrn_orient_matrix_UB_22      0.0800397000
_diffrn_orient_matrix_UB_23      0.0522095000
_diffrn_orient_matrix_UB_31      0.1382559000
_diffrn_orient_matrix_UB_32      0.0526766000
_diffrn_orient_matrix_UB_33      -0.0346585000
_diffrn_oxdiff_ac4_digest_frames 
;
01ea1d5671da5fe16deb314286e1015dda019083f5f
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3922
_reflns_number_total             4240
_reflns_odcompleteness_completeness 99.97
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.20a (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.40.20a (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.40.20a (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.012
_refine_diff_density_min         -1.233
_refine_diff_density_rms         0.110
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     232
_refine_ls_number_reflns         4240
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0331
_refine_ls_R_factor_gt           0.0310
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0494P)²+0.9532P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0818
_refine_ls_wR_factor_ref         0.0833
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C7(H7A,H7B), C8(H8A,H8B), C15(H15A,H15B), C16(H16A,H16B),
 C17(H17A,H17B)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C11(H11)
2.c Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C5(H5A,H5B,H5C), C9(H9A,H9B,H9C), C13(H13A,H13B,H13C),
 C14(H14A,H14B,H14C), C18(H18A,H18B,H18C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5119(3) 0.38884(17) 0.32433(17) 0.0132(5) Uani 1 1 d . . . . .
C2 C 0.4044(3) 0.40969(17) 0.26078(17) 0.0150(5) Uani 1 1 d . . . . .
H2 H 0.3761 0.4702 0.2553 0.018 Uiso 1 1 calc R . . . .
C3 C 0.3285(3) 0.35098(17) 0.20093(16) 0.0128(5) Uani 1 1 d . . . . .
C4 C 0.5845(3) 0.46062(17) 0.37834(17) 0.0176(5) Uani 1 1 d . . . . .
H4A H 0.5694 0.4462 0.4352 0.026 Uiso 1 1 calc GR . . . .
H4B H 0.5310 0.5168 0.3643 0.026 Uiso 1 1 calc GR . . . .
H4C H 0.7004 0.4656 0.3708 0.026 Uiso 1 1 calc GR . . . .
C5 C 0.2345(3) 0.39764(18) 0.13134(18) 0.0191(6) Uani 1 1 d . . . . .
H5A H 0.3084 0.4146 0.0903 0.029 Uiso 1 1 calc GR . . . .
H5B H 0.1830 0.4506 0.1518 0.029 Uiso 1 1 calc GR . . . .
H5C H 0.1512 0.3580 0.1069 0.029 Uiso 1 1 calc GR . . . .
C6 C 0.2598(3) 0.20965(17) 0.14279(16) 0.0144(5) Uani 1 1 d . . . . .
H6A H 0.1484 0.2322 0.1310 0.017 Uiso 1 1 calc R . . . .
H6B H 0.2515 0.1491 0.1647 0.017 Uiso 1 1 calc R . . . .
C7 C 0.3434(3) 0.20532(19) 0.06349(17) 0.0167(5) Uani 1 1 d . . . . .
H7A H 0.3525 0.2656 0.0413 0.020 Uiso 1 1 calc R . . . .
H7B H 0.4543 0.1817 0.0746 0.020 Uiso 1 1 calc R . . . .
C8 C 0.2517(3) 0.14755(19) 0.00098(17) 0.0183(5) Uani 1 1 d . . . . .
H8A H 0.3141 0.1417 -0.0477 0.022 Uiso 1 1 calc R . . . .
H8B H 0.2366 0.0880 0.0238 0.022 Uiso 1 1 calc R . . . .
C9 C 0.0086(4) 0.1358(2) -0.0802(2) 0.0281(7) Uani 1 1 d . . . . .
H9A H 0.0709 0.1287 -0.1280 0.042 Uiso 1 1 calc GR . . . .
H9B H -0.0935 0.1660 -0.0958 0.042 Uiso 1 1 calc GR . . . .
H9C H -0.0143 0.0776 -0.0578 0.042 Uiso 1 1 calc GR . . . .
C10 C 0.7757(3) 0.13190(16) 0.20161(16) 0.0140(5) Uani 1 1 d . . . . .
C11 C 0.8891(3) 0.11480(16) 0.26344(17) 0.0144(5) Uani 1 1 d . . . . .
H11 H 0.9883 0.0905 0.2485 0.017 Uiso 1 1 calc R . . . .
C12 C 0.8762(3) 0.12930(16) 0.34897(17) 0.0133(5) Uani 1 1 d . . . . .
C13 C 0.8154(3) 0.11611(19) 0.11487(17) 0.0204(6) Uani 1 1 d . . . . .
H13A H 0.7367 0.0748 0.0888 0.031 Uiso 1 1 calc GR . . . .
H13B H 0.9244 0.0911 0.1144 0.031 Uiso 1 1 calc GR . . . .
H13C H 0.8107 0.1721 0.0852 0.031 Uiso 1 1 calc GR . . . .
C14 C 1.0280(3) 0.10985(18) 0.40307(18) 0.0180(5) Uani 1 1 d . . . . .
H14A H 1.0810 0.1654 0.4197 0.027 Uiso 1 1 calc GR . . . .
H14B H 1.1020 0.0740 0.3731 0.027 Uiso 1 1 calc GR . . . .
H14C H 0.9989 0.0776 0.4513 0.027 Uiso 1 1 calc GR . . . .
C15 C 0.7393(3) 0.17332(17) 0.46551(17) 0.0149(5) Uani 1 1 d . . . . .
H15A H 0.6656 0.2232 0.4744 0.018 Uiso 1 1 calc R . . . .
H15B H 0.8489 0.1899 0.4884 0.018 Uiso 1 1 calc R . . . .
C16 C 0.6821(3) 0.09188(18) 0.50965(16) 0.0167(5) Uani 1 1 d . . . . .
H16A H 0.5703 0.0773 0.4887 0.020 Uiso 1 1 calc R . . . .
H16B H 0.7523 0.0412 0.4982 0.020 Uiso 1 1 calc R . . . .
C17 C 0.6857(3) 0.10590(19) 0.60074(17) 0.0184(5) Uani 1 1 d . . . . .
H17A H 0.6172 0.1570 0.6132 0.022 Uiso 1 1 calc R . . . .
H17B H 0.6438 0.0530 0.6274 0.022 Uiso 1 1 calc R . . . .
C18 C 0.8661(4) 0.1310(2) 0.71517(18) 0.0261(6) Uani 1 1 d . . . . .
H18A H 0.7959 0.1787 0.7318 0.039 Uiso 1 1 calc GR . . . .
H18B H 0.9790 0.1450 0.7323 0.039 Uiso 1 1 calc GR . . . .
H18C H 0.8354 0.0757 0.7407 0.039 Uiso 1 1 calc GR . . . .
N2 N 0.7434(3) 0.15731(14) 0.37779(13) 0.0123(4) Uani 1 1 d . . . . .
N6 N 0.3431(3) 0.26575(14) 0.20539(14) 0.0127(4) Uani 1 1 d . . . . .
O3 O 0.5663(2) 0.31014(11) 0.34484(13) 0.0159(4) Uani 1 1 d . . . . .
O4 O 0.0990(3) 0.18630(11) -0.02087(13) 0.0182(4) Uani 1 1 d . . . . .
O5 O 0.6295(2) 0.16218(13) 0.20760(12) 0.0167(4) Uani 1 1 d . . . . .
O6 O 0.8489(2) 0.12174(15) 0.62946(12) 0.0227(4) Uani 1 1 d . . . . .
Sn1 Sn 0.48920(2) 0.18250(2) 0.30792(2) 0.01076(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.363(4) . ?
C1 C4 1.504(3) . ?
C1 O3 1.311(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.440(4) . ?
C3 C5 1.516(4) . ?
C3 N6 1.299(3) . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C6 C7 1.527(4) . ?
C6 N6 1.471(3) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C7 C8 1.515(4) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C8 O4 1.418(3) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C9 O4 1.414(3) . ?
C10 C11 1.361(4) . ?
C10 C13 1.512(4) . ?
C10 O5 1.306(3) . ?
C11 H11 0.9500 . ?
C11 C12 1.441(4) . ?
C12 C14 1.517(4) . ?
C12 N2 1.301(3) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C15 C16 1.527(4) . ?
C15 N2 1.472(4) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C17 1.517(4) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 O6 1.421(3) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C18 O6 1.419(4) . ?
N2 Sn1 2.358(2) . ?
N6 Sn1 2.372(2) . ?
O3 Sn1 2.1133(17) . ?
O5 Sn1 2.1146(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C4 119.9(2) . . ?
O3 C1 C2 127.1(2) . . ?
O3 C1 C4 113.0(2) . . ?
C1 C2 H2 116.1 . . ?
C1 C2 C3 127.8(2) . . ?
C3 C2 H2 116.1 . . ?
C2 C3 C5 114.0(2) . . ?
N6 C3 C2 122.8(2) . . ?
N6 C3 C5 123.2(2) . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5B 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
H6A C6 H6B 107.6 . . ?
C7 C6 H6A 108.7 . . ?
C7 C6 H6B 108.7 . . ?
N6 C6 H6A 108.7 . . ?
N6 C6 H6B 108.7 . . ?
N6 C6 C7 114.1(2) . . ?
C6 C7 H7A 109.2 . . ?
C6 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
C8 C7 C6 111.9(2) . . ?
C8 C7 H7A 109.2 . . ?
C8 C7 H7B 109.2 . . ?
C7 C8 H8A 109.9 . . ?
C7 C8 H8B 109.9 . . ?
H8A C8 H8B 108.3 . . ?
O4 C8 C7 109.1(2) . . ?
O4 C8 H8A 109.9 . . ?
O4 C8 H8B 109.9 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
O4 C9 H9A 109.5 . . ?
O4 C9 H9B 109.5 . . ?
O4 C9 H9C 109.5 . . ?
C11 C10 C13 119.7(2) . . ?
O5 C10 C11 127.1(2) . . ?
O5 C10 C13 113.2(2) . . ?
C10 C11 H11 116.2 . . ?
C10 C11 C12 127.6(2) . . ?
C12 C11 H11 116.2 . . ?
C11 C12 C14 115.5(2) . . ?
N2 C12 C11 122.2(2) . . ?
N2 C12 C14 122.3(2) . . ?
C10 C13 H13A 109.5 . . ?
C10 C13 H13B 109.5 . . ?
C10 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
H15A C15 H15B 108.0 . . ?
C16 C15 H15A 109.3 . . ?
C16 C15 H15B 109.3 . . ?
N2 C15 H15A 109.3 . . ?
N2 C15 H15B 109.3 . . ?
N2 C15 C16 111.5(2) . . ?
C15 C16 H16A 109.2 . . ?
C15 C16 H16B 109.2 . . ?
H16A C16 H16B 107.9 . . ?
C17 C16 C15 112.1(2) . . ?
C17 C16 H16A 109.2 . . ?
C17 C16 H16B 109.2 . . ?
C16 C17 H17A 110.2 . . ?
C16 C17 H17B 110.2 . . ?
H17A C17 H17B 108.5 . . ?
O6 C17 C16 107.7(2) . . ?
O6 C17 H17A 110.2 . . ?
O6 C17 H17B 110.2 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
O6 C18 H18A 109.5 . . ?
O6 C18 H18B 109.5 . . ?
O6 C18 H18C 109.5 . . ?
C12 N2 C15 119.6(2) . . ?
C12 N2 Sn1 128.53(18) . . ?
C15 N2 Sn1 111.77(16) . . ?
C3 N6 C6 119.9(2) . . ?
C3 N6 Sn1 127.60(17) . . ?
C6 N6 Sn1 112.51(15) . . ?
C1 O3 Sn1 131.89(18) . . ?
C9 O4 C8 111.7(2) . . ?
C10 O5 Sn1 132.58(18) . . ?
C18 O6 C17 111.9(2) . . ?
N2 Sn1 N6 145.77(7) . . ?
O3 Sn1 N2 76.51(8) . . ?
O3 Sn1 N6 81.18(7) . . ?
O3 Sn1 O5 100.81(8) . . ?
O5 Sn1 N2 80.63(7) . . ?
O5 Sn1 N6 78.43(7) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.434
_oxdiff_exptl_absorpt_empirical_full_min 0.684



#=================================END
