# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 1964728'
_audit_update_record             
;
2019-11-12 deposited with the CCDC.	2020-07-15 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2013
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C69 H71 Cu12 Eu3 I12 N14 O23'
_chemical_formula_weight         4205.55

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   15.168(2)
_cell_length_b                   25.268(4)
_cell_length_c                   28.983(4)
_cell_angle_alpha                90
_cell_angle_beta                 102.353(3)
_cell_angle_gamma                90
_cell_volume                     10851(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9986
_cell_measurement_theta_min      2.30
_cell_measurement_theta_max      27.88

_exptl_crystal_description       BLOCK
_exptl_crystal_colour            YELLOW
_exptl_crystal_density_meas      NONE
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    2.574
_exptl_crystal_F_000             7760
_exptl_transmission_factor_min   0.290
_exptl_transmission_factor_max   0.346
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.180
_exptl_absorpt_coefficient_mu    7.482
_shelx_estimated_absorpt_T_min   0.290
_shelx_estimated_absorpt_T_max   0.346
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            70798
_diffrn_reflns_av_unetI/netI     0.0650
_diffrn_reflns_av_R_equivalents  0.0636
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         1.438
_diffrn_reflns_theta_max         26.499
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             22477
_reflns_number_gt                16735
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 ? 
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
; 
 w=1/[σ²(Fo²)+(0.0211P)²] 
 where P=(Fo²+2Fc²)/3 
;
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         22477
_refine_ls_number_parameters     1214
_refine_ls_number_restraints     14
_refine_ls_R_factor_all          0.0601
_refine_ls_R_factor_gt           0.0385
_refine_ls_wR_factor_ref         0.0866
_refine_ls_wR_factor_gt          0.0802
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.54977(2) 0.42154(2) 0.51462(2) 0.02303(7) Uani 1 1 d . . . . .
Eu2 Eu 0.57779(2) 0.09906(2) 0.53512(2) 0.02144(7) Uani 1 1 d . . . . .
Eu3 Eu 0.45571(2) 0.25796(2) 0.49584(2) 0.02397(8) Uani 1 1 d . . . . .
Cu1 Cu 0.66091(6) 0.12016(3) 0.18035(3) 0.0465(2) Uani 1 1 d . . . . .
Cu2 Cu 0.60627(7) 0.11935(4) 0.25815(3) 0.0483(2) Uani 1 1 d . . . . .
Cu3 Cu 0.50734(6) 0.16999(3) 0.18661(3) 0.0514(3) Uani 1 1 d . . . . .
Cu4 Cu 0.65920(6) 0.21705(3) 0.22186(3) 0.0455(2) Uani 1 1 d . . . . .
Cu5 Cu 0.86300(7) 0.29198(4) 0.32763(3) 0.0537(3) Uani 1 1 d . . . . .
Cu6 Cu 0.84874(7) 0.39274(4) 0.28158(3) 0.0496(2) Uani 1 1 d . . . . .
Cu7 Cu 0.92225(7) 0.29378(4) 0.24974(3) 0.0504(2) Uani 1 1 d . . . . .
Cu8 Cu 1.00740(6) 0.35188(3) 0.32257(3) 0.0521(3) Uani 1 1 d . . . . .
Cu9 Cu 0.56128(7) 0.45668(4) 0.24319(3) 0.0508(2) Uani 1 1 d . . . . .
Cu10 Cu 0.45996(6) 0.51476(3) 0.16390(3) 0.0472(2) Uani 1 1 d . . . . .
Cu11 Cu 0.62553(7) 0.45430(4) 0.16514(3) 0.0493(2) Uani 1 1 d . . . . .
Cu12 Cu 0.61787(6) 0.55298(3) 0.21175(3) 0.0454(2) Uani 1 1 d . . . . .
I1 I 0.78265(3) 0.14178(2) 0.26215(2) 0.03201(10) Uani 1 1 d . . . . .
I2 I 0.61623(3) 0.21037(2) 0.12775(2) 0.04290(12) Uani 1 1 d . . . . .
I3 I 0.50800(3) 0.06692(2) 0.18281(2) 0.03787(11) Uani 1 1 d . . . . .
I4 I 0.53275(4) 0.21778(2) 0.27043(2) 0.04878(13) Uani 1 1 d . . . . .
I5 I 0.74461(3) 0.30827(2) 0.24306(2) 0.03619(11) Uani 1 1 d . . . . .
I6 I 1.02036(3) 0.24765(2) 0.33120(2) 0.03955(11) Uani 1 1 d . . . . .
I7 I 0.97857(3) 0.39351(2) 0.23534(2) 0.04659(13) Uani 1 1 d . . . . .
I8 I 0.88467(4) 0.39082(2) 0.37370(2) 0.04654(13) Uani 1 1 d . . . . .
I9 I 0.73725(3) 0.47539(2) 0.25077(2) 0.03461(11) Uani 1 1 d . . . . .
I10 I 0.59109(3) 0.55068(2) 0.11905(2) 0.04001(11) Uani 1 1 d . . . . .
I11 I 0.46661(3) 0.40949(2) 0.16338(2) 0.03811(11) Uani 1 1 d . . . . .
I12 I 0.47856(3) 0.55172(2) 0.25231(2) 0.04452(12) Uani 1 1 d . . . . .
C1 C 0.7698(7) 0.3982(4) 0.5356(4) 0.054(3) Uani 0.649(9) 1 d D . P A 1
H1 H 0.7803 0.4319 0.5485 0.065 Uiso 0.649(9) 1 calc R U P A 1
C2 C 0.9299(7) 0.3963(7) 0.5305(7) 0.110(6) Uani 0.649(9) 1 d D . P A 1
H2A H 0.9397 0.4054 0.4999 0.164 Uiso 0.649(9) 1 d R U P A 1
H2B H 0.9749 0.3714 0.5453 0.164 Uiso 0.649(9) 1 d R U P A 1
H2C H 0.9341 0.4277 0.5496 0.164 Uiso 0.649(9) 1 d R U P A 1
C3 C 0.8289(11) 0.3174(5) 0.5066(7) 0.109(6) Uani 0.649(9) 1 d D . P A 1
H3A H 0.7688 0.3048 0.5056 0.163 Uiso 0.649(9) 1 d R U P A 1
H3B H 0.8716 0.2947 0.5265 0.163 Uiso 0.649(9) 1 d R U P A 1
H3C H 0.8403 0.3173 0.4753 0.163 Uiso 0.649(9) 1 d R U P A 1
N1 N 0.8382(7) 0.3724(5) 0.5257(8) 0.069(5) Uani 0.649(9) 1 d D . P A 1
O1 O 0.6923(10) 0.3807(8) 0.5288(6) 0.041(4) Uani 0.649(9) 1 d D . P A 1
C1' C 0.7347(11) 0.3490(8) 0.5169(7) 0.054(3) Uani 0.351(9) 1 d D . P A 2
H1' H 0.6985 0.3257 0.4963 0.065 Uiso 0.351(9) 1 calc R U P A 2
C2' C 0.8836(16) 0.3910(12) 0.5432(15) 0.110(6) Uani 0.351(9) 1 d D . P A 2
H2'1 H 0.9162 0.4061 0.5214 0.164 Uiso 0.351(9) 1 d R U P A 2
H2'2 H 0.9255 0.3762 0.5696 0.164 Uiso 0.351(9) 1 d R U P A 2
H2'3 H 0.8487 0.4181 0.5541 0.164 Uiso 0.351(9) 1 d R U P A 2
C3' C 0.8681(19) 0.3047(12) 0.4989(14) 0.109(6) Uani 0.351(9) 1 d D . P A 2
H3'1 H 0.8273 0.2757 0.4899 0.163 Uiso 0.351(9) 1 d R U P A 2
H3'2 H 0.9193 0.2930 0.5222 0.163 Uiso 0.351(9) 1 d R U P A 2
H3'3 H 0.8880 0.3176 0.4717 0.163 Uiso 0.351(9) 1 d R U P A 2
N1' N 0.8215(13) 0.3483(13) 0.5193(18) 0.069(5) Uani 0.351(9) 1 d D . P A 2
O1' O 0.698(2) 0.3789(15) 0.5407(14) 0.041(4) Uani 0.351(9) 1 d D . P A 2
C4 C 0.6508(5) 0.1145(3) 0.6537(3) 0.051(2) Uani 1 1 d . . . . .
H4 H 0.6309 0.1490 0.6470 0.061 Uiso 1 1 calc R U . . .
C5 C 0.7179(6) 0.1487(4) 0.7313(3) 0.094(4) Uani 1 1 d . . . . .
H5A H 0.7815 0.1559 0.7371 0.142 Uiso 1 1 d R U . . .
H5B H 0.7016 0.1386 0.7603 0.142 Uiso 1 1 d R U . . .
H5C H 0.6850 0.1799 0.7190 0.142 Uiso 1 1 d R U . . .
C6 C 0.7276(7) 0.0508(4) 0.7104(3) 0.094(4) Uani 1 1 d . . . . .
H6A H 0.7034 0.0272 0.6849 0.141 Uiso 1 1 d R U . . .
H6B H 0.7072 0.0402 0.7381 0.141 Uiso 1 1 d R U . . .
H6C H 0.7923 0.0497 0.7166 0.141 Uiso 1 1 d R U . . .
C7 C 0.8038(6) 0.0956(4) 0.5421(3) 0.060(2) Uani 1 1 d . . . . .
H7 H 0.8116 0.1316 0.5484 0.072 Uiso 1 1 calc R U . . .
C8 C 0.9546(7) 0.0949(6) 0.5230(4) 0.134(6) Uani 1 1 d . . . . .
H8A H 0.9521 0.1322 0.5291 0.201 Uiso 1 1 d R U . . .
H8B H 0.9664 0.0895 0.4921 0.201 Uiso 1 1 d R U . . .
H8C H 1.0021 0.0792 0.5463 0.201 Uiso 1 1 d R U . . .
C9 C 0.8552(9) 0.0148(5) 0.5114(4) 0.125(5) Uani 1 1 d . . . . .
H9A H 0.8940 -0.0073 0.5340 0.188 Uiso 1 1 d R U . . .
H9B H 0.8687 0.0098 0.4808 0.188 Uiso 1 1 d R U . . .
H9C H 0.7934 0.0054 0.5101 0.188 Uiso 1 1 d R U . . .
C10 C 0.2320(7) 0.2738(4) 0.4760(3) 0.076(3) Uani 1 1 d . . . . .
H10 H 0.2255 0.2378 0.4691 0.092 Uiso 1 1 calc R U . . .
C11 C 0.1634(11) 0.3530(5) 0.4979(5) 0.167(7) Uani 1 1 d . . . . .
H11A H 0.1396 0.3554 0.5260 0.251 Uiso 1 1 d R U . . .
H11B H 0.1282 0.3747 0.4736 0.251 Uiso 1 1 d R U . . .
H11C H 0.2249 0.3649 0.5046 0.251 Uiso 1 1 d R U . . .
C12 C 0.0724(7) 0.2684(7) 0.4766(5) 0.194(9) Uani 1 1 d . . . . .
H12A H 0.0821 0.2330 0.4668 0.291 Uiso 1 1 d R U . . .
H12B H 0.0264 0.2850 0.4531 0.291 Uiso 1 1 d R U . . .
H12C H 0.0537 0.2675 0.5061 0.291 Uiso 1 1 d R U . . .
C13 C 0.8227(8) 0.2790(5) 0.8235(5) 0.105(4) Uani 1 1 d . . . . .
H13 H 0.8671 0.2771 0.8511 0.126 Uiso 1 1 calc R U . . .
C14 C 0.7471(10) 0.3287(7) 0.7596(5) 0.230(10) Uani 1 1 d . . . . .
H14A H 0.7370 0.2952 0.7438 0.345 Uiso 1 1 d R U . . .
H14B H 0.7692 0.3536 0.7398 0.345 Uiso 1 1 d R U . . .
H14C H 0.6914 0.3414 0.7662 0.345 Uiso 1 1 d R U . . .
C15 C 0.8679(9) 0.3657(4) 0.8180(5) 0.168(8) Uani 1 1 d . . . . .
H15A H 0.8336 0.3936 0.8284 0.253 Uiso 1 1 d R U . . .
H15B H 0.8943 0.3786 0.7928 0.253 Uiso 1 1 d R U . . .
H15C H 0.9148 0.3544 0.8438 0.253 Uiso 1 1 d R U . . .
C16 C 0.8181(5) 0.0832(2) 0.1478(2) 0.0362(16) Uani 1 1 d . . . . .
H16 H 0.8474 0.1049 0.1722 0.043 Uiso 1 1 calc R U . . .
C17 C 0.8688(5) 0.0598(2) 0.1195(2) 0.0333(15) Uani 1 1 d . . . . .
H17 H 0.9306 0.0659 0.1247 0.040 Uiso 1 1 calc R U . . .
C18 C 0.8271(4) 0.0269(2) 0.0829(2) 0.0290(14) Uani 1 1 d . . . . .
C19 C 0.7368(5) 0.0176(3) 0.0784(3) 0.048(2) Uani 1 1 d . . . . .
H19 H 0.7067 -0.0053 0.0552 0.058 Uiso 1 1 calc R U . . .
C20 C 0.6903(5) 0.0424(3) 0.1085(3) 0.053(2) Uani 1 1 d . . . . .
H20 H 0.6292 0.0352 0.1054 0.064 Uiso 1 1 calc R U . . .
C21 C 0.8796(4) 0.0019(2) 0.0509(2) 0.0319(15) Uani 1 1 d . . . . .
C22 C 0.3819(5) 0.2553(3) 0.1484(3) 0.055(2) Uani 1 1 d . . . . .
H22 H 0.4318 0.2764 0.1604 0.066 Uiso 1 1 calc R U . . .
C23 C 0.3040(5) 0.2791(3) 0.1243(3) 0.0461(19) Uani 1 1 d . . . . .
H23 H 0.3018 0.3155 0.1200 0.055 Uiso 1 1 calc R U . . .
C24 C 0.2298(4) 0.2487(2) 0.1067(2) 0.0313(15) Uani 1 1 d . . . . .
C25 C 0.2352(4) 0.1956(2) 0.1161(2) 0.0324(15) Uani 1 1 d . . . . .
H25 H 0.1848 0.1742 0.1062 0.039 Uiso 1 1 calc R U . . .
C26 C 0.3145(5) 0.1740(2) 0.1399(2) 0.0386(17) Uani 1 1 d . . . . .
H26 H 0.3165 0.1377 0.1456 0.046 Uiso 1 1 calc R U . . .
C27 C 0.1463(4) 0.2738(2) 0.0762(2) 0.0254(13) Uani 1 1 d . . . . .
C28 C 0.5292(5) 0.0415(3) 0.3160(2) 0.0387(17) Uani 1 1 d . . . . .
H28 H 0.4913 0.0320 0.2875 0.046 Uiso 1 1 calc R U . . .
C29 C 0.5138(4) 0.0195(2) 0.3571(2) 0.0335(15) Uani 1 1 d . . . . .
H29 H 0.4659 -0.0037 0.3563 0.040 Uiso 1 1 calc R U . . .
C30 C 0.5711(4) 0.0326(2) 0.3997(2) 0.0260(14) Uani 1 1 d . . . . .
C31 C 0.6425(4) 0.0652(2) 0.3986(2) 0.0330(15) Uani 1 1 d . . . . .
H31 H 0.6840 0.0731 0.4264 0.040 Uiso 1 1 calc R U . . .
C32 C 0.6525(5) 0.0865(2) 0.3559(2) 0.0343(16) Uani 1 1 d . . . . .
H32 H 0.7008 0.1091 0.3559 0.041 Uiso 1 1 calc R U . . .
C33 C 0.5555(4) 0.0094(2) 0.4456(2) 0.0289(14) Uani 1 1 d . . . . .
C34 C 1.0199(6) 0.2177(3) 0.2027(3) 0.064(3) Uani 1 1 d . . . . .
H34 H 1.0635 0.2217 0.2304 0.077 Uiso 1 1 calc R U . . .
C35 C 1.0402(5) 0.1861(3) 0.1670(2) 0.054(2) Uani 1 1 d . . . . .
H35 H 1.0954 0.1687 0.1712 0.065 Uiso 1 1 calc R U . . .
C36 C 0.9771(4) 0.1809(2) 0.1252(2) 0.0291(14) Uani 1 1 d . . . . .
C37 C 0.8946(5) 0.2055(2) 0.1224(2) 0.0340(16) Uani 1 1 d . . . . .
H37 H 0.8493 0.2017 0.0954 0.041 Uiso 1 1 calc R U . . .
C38 C 0.8795(5) 0.2352(2) 0.1591(2) 0.0370(16) Uani 1 1 d . . . . .
H38 H 0.8233 0.2512 0.1562 0.044 Uiso 1 1 calc R U . . .
C39 C 0.9988(5) 0.1503(2) 0.0846(2) 0.0317(15) Uani 1 1 d . . . . .
C40 C 1.1977(5) 0.3605(2) 0.3737(3) 0.0431(18) Uani 1 1 d . . . . .
H40 H 1.1971 0.3240 0.3701 0.052 Uiso 1 1 calc R U . . .
C41 C 1.2747(5) 0.3841(2) 0.3981(2) 0.0436(19) Uani 1 1 d . . . . .
H41 H 1.3245 0.3633 0.4109 0.052 Uiso 1 1 calc R U . . .
C42 C 1.2795(4) 0.4380(2) 0.4040(2) 0.0320(15) Uani 1 1 d . . . . .
C43 C 1.2069(5) 0.4662(3) 0.3824(3) 0.079(3) Uani 1 1 d . . . . .
H43 H 1.2088 0.5030 0.3827 0.094 Uiso 1 1 calc R U . . .
C44 C 1.1287(6) 0.4397(3) 0.3595(4) 0.095(4) Uani 1 1 d . . . . .
H44 H 1.0777 0.4596 0.3469 0.114 Uiso 1 1 calc R U . . .
C45 C 1.3623(4) 0.4637(2) 0.4328(2) 0.0305(15) Uani 1 1 d . . . . .
C46 C 0.8211(5) 0.2113(2) 0.3965(2) 0.0395(17) Uani 1 1 d . . . . .
H46 H 0.8775 0.1970 0.3962 0.047 Uiso 1 1 calc R U . . .
C47 C 0.7719(4) 0.1894(2) 0.4264(2) 0.0356(16) Uani 1 1 d . . . . .
H47 H 0.7954 0.1614 0.4461 0.043 Uiso 1 1 calc R U . . .
C48 C 0.6871(4) 0.2094(2) 0.4269(2) 0.0275(14) Uani 1 1 d . . . . .
C49 C 0.6554(5) 0.2490(3) 0.3955(2) 0.0408(17) Uani 1 1 d . . . . .
H49 H 0.5973 0.2621 0.3934 0.049 Uiso 1 1 calc R U . . .
C50 C 0.7083(5) 0.2696(3) 0.3673(2) 0.0436(18) Uani 1 1 d . . . . .
H50 H 0.6852 0.2970 0.3468 0.052 Uiso 1 1 calc R U . . .
C51 C 0.6297(4) 0.1884(2) 0.4593(2) 0.0290(14) Uani 1 1 d . . . . .
C52 C 0.6062(5) 0.4126(3) 0.3398(2) 0.0393(17) Uani 1 1 d . . . . .
H52 H 0.6591 0.4318 0.3414 0.047 Uiso 1 1 calc R U . . .
C53 C 0.5940(5) 0.3875(2) 0.3804(2) 0.0359(16) Uani 1 1 d . . . . .
H53 H 0.6383 0.3893 0.4081 0.043 Uiso 1 1 calc R U . . .
C54 C 0.5152(5) 0.3597(2) 0.3794(2) 0.0360(16) Uani 1 1 d . . . . .
C55 C 0.4546(5) 0.3557(3) 0.3367(2) 0.051(2) Uani 1 1 d . . . . .
H55 H 0.4018 0.3360 0.3339 0.061 Uiso 1 1 calc R U . . .
C56 C 0.4742(6) 0.3817(3) 0.2980(2) 0.061(2) Uani 1 1 d . . . . .
H56 H 0.4330 0.3784 0.2693 0.073 Uiso 1 1 calc R U . . .
C57 C 0.4965(5) 0.3323(2) 0.4224(2) 0.0332(16) Uani 1 1 d . . . . .
C58 C 0.6866(4) 0.3640(3) 0.1115(2) 0.0396(17) Uani 1 1 d . . . . .
H58 H 0.6319 0.3483 0.1132 0.047 Uiso 1 1 calc R U . . .
C59 C 0.7448(4) 0.3370(2) 0.0892(2) 0.0376(16) Uani 1 1 d . . . . .
H59 H 0.7275 0.3046 0.0748 0.045 Uiso 1 1 calc R U . . .
C60 C 0.8293(4) 0.3579(2) 0.0882(2) 0.0267(14) Uani 1 1 d . . . . .
C61 C 0.8497(5) 0.4065(2) 0.1101(2) 0.0381(17) Uani 1 1 d . . . . .
H61 H 0.9057 0.4218 0.1110 0.046 Uiso 1 1 calc R U . . .
C62 C 0.7889(5) 0.4319(3) 0.1304(3) 0.0469(19) Uani 1 1 d . . . . .
H62 H 0.8051 0.4645 0.1447 0.056 Uiso 1 1 calc R U . . .
C63 C 0.8960(5) 0.3297(2) 0.0651(2) 0.0330(15) Uani 1 1 d . . . . .
C64 C 0.2707(5) 0.5279(2) 0.1072(2) 0.0378(17) Uani 1 1 d . . . . .
H64 H 0.2678 0.4913 0.1103 0.045 Uiso 1 1 calc R U . . .
C65 C 0.1971(5) 0.5535(2) 0.0817(2) 0.0381(17) Uani 1 1 d . . . . .
H65 H 0.1460 0.5344 0.0677 0.046 Uiso 1 1 calc R U . . .
C66 C 0.1982(5) 0.6081(2) 0.0765(2) 0.0316(15) Uani 1 1 d . . . . .
C67 C 0.2746(5) 0.6338(2) 0.0983(2) 0.0424(18) Uani 1 1 d . . . . .
H67 H 0.2783 0.6704 0.0962 0.051 Uiso 1 1 calc R U . . .
C68 C 0.3464(5) 0.6052(3) 0.1234(3) 0.050(2) Uani 1 1 d . . . . .
H68 H 0.3978 0.6237 0.1381 0.060 Uiso 1 1 calc R U . . .
C69 C 0.1165(4) 0.6369(2) 0.0486(2) 0.0300(15) Uani 1 1 d . . . . .
N2 N 0.6961(5) 0.1056(3) 0.6970(2) 0.069(2) Uani 1 1 d . . . . .
N3 N 0.8701(5) 0.0703(4) 0.5255(2) 0.080(2) Uani 1 1 d . . . . .
N4 N 0.1594(6) 0.2996(5) 0.4823(3) 0.105(4) Uani 1 1 d . . . . .
N5 N 0.8106(6) 0.3232(3) 0.8019(3) 0.072(2) Uani 1 1 d . . . . .
N6 N 0.7305(4) 0.07652(19) 0.14228(18) 0.0331(13) Uani 1 1 d . . . . .
N7 N 0.3890(4) 0.2023(2) 0.1554(2) 0.0425(15) Uani 1 1 d . . . . .
N8 N 0.5962(4) 0.07601(19) 0.31490(17) 0.0314(12) Uani 1 1 d . . . . .
N9 N 0.9415(4) 0.2426(2) 0.19918(17) 0.0364(13) Uani 1 1 d . . . . .
N10 N 1.1239(4) 0.3873(2) 0.3550(2) 0.0434(15) Uani 1 1 d . . . . .
N11 N 0.7921(4) 0.2522(2) 0.36765(18) 0.0361(13) Uani 1 1 d . . . . .
N12 N 0.7060(4) 0.4125(2) 0.13106(19) 0.0374(14) Uani 1 1 d . . . . .
N13 N 0.3472(3) 0.55281(19) 0.12800(18) 0.0324(13) Uani 1 1 d . . . . .
N14 N 0.5469(4) 0.4110(2) 0.29859(18) 0.0376(14) Uani 1 1 d . . . . .
O2 O 0.6319(3) 0.08274(18) 0.62106(15) 0.0464(13) Uani 1 1 d . . . . .
O3 O 0.7364(3) 0.07574(18) 0.54941(17) 0.0435(12) Uani 1 1 d . . . . .
O4 O 0.3057(4) 0.2929(2) 0.47843(19) 0.0533(14) Uani 1 1 d . . . . .
O5 O 0.7773(7) 0.2373(4) 0.8095(4) 0.176(5) Uani 1 1 d . . . . .
O6 O 0.9458(3) 0.02620(19) 0.04203(16) 0.0449(12) Uani 1 1 d . . . . .
O7 O 0.8546(3) -0.04186(17) 0.03329(16) 0.0433(12) Uani 1 1 d . . . . .
O8 O 0.1507(3) 0.32230(15) 0.06866(15) 0.0351(11) Uani 1 1 d . . . . .
O9 O 0.0810(3) 0.24381(16) 0.06067(14) 0.0352(11) Uani 1 1 d . . . . .
O10 O 0.5980(3) 0.03056(15) 0.48305(14) 0.0327(10) Uani 1 1 d . . . . .
O11 O 0.5047(3) -0.02958(16) 0.44213(14) 0.0364(11) Uani 1 1 d . . . . .
O12 O 0.9555(3) 0.15933(15) 0.04289(14) 0.0323(10) Uani 1 1 d . . . . .
O13 O 1.0582(3) 0.11480(17) 0.09366(15) 0.0389(11) Uani 1 1 d . . . . .
O14 O 1.3606(3) 0.51274(16) 0.43802(15) 0.0366(11) Uani 1 1 d . . . . .
O15 O 1.4272(3) 0.43301(17) 0.45033(15) 0.0399(12) Uani 1 1 d . . . . .
O16 O 0.6482(3) 0.14409(15) 0.47792(15) 0.0356(11) Uani 1 1 d . . . . .
O17 O 0.5675(3) 0.21801(16) 0.46636(15) 0.0389(11) Uani 1 1 d . . . . .
O18 O 0.9683(3) 0.35237(18) 0.06441(18) 0.0468(13) Uani 1 1 d . . . . .
O19 O 0.8745(3) 0.28533(17) 0.04723(16) 0.0422(12) Uani 1 1 d . . . . .
O20 O 0.0497(3) 0.61038(17) 0.02919(15) 0.0419(12) Uani 1 1 d . . . . .
O21 O 0.1240(3) 0.68654(17) 0.04705(16) 0.0442(12) Uani 1 1 d . . . . .
O22 O 0.4385(3) 0.29669(18) 0.41708(15) 0.0425(12) Uani 1 1 d . . . . .
O23 O 0.5427(3) 0.34464(16) 0.46300(14) 0.0393(12) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.323(5) 4_566 ?
Eu1 O1 2.351(16) . ?
Eu1 O15 2.351(4) 1_455 ?
Eu1 O14 2.386(4) 3_766 ?
Eu1 O7 2.397(4) 2_655 ?
Eu1 O23 2.441(4) . ?
Eu1 O13 2.446(4) 4_566 ?
Eu1 O1' 2.47(4) . ?
Eu1 O12 2.719(4) 4_566 ?
Eu1 C39 2.945(6) 4_566 ?
Eu1 O6 3.121(5) 2_655 ?
Eu1 C21 3.124(6) 2_655 ?
Eu2 O11 2.331(4) 3_656 ?
Eu2 O10 2.359(4) . ?
Eu2 O18 2.364(4) 4_566 ?
Eu2 O8 2.378(4) 4_666 ?
Eu2 O20 2.398(4) 2_545 ?
Eu2 O3 2.425(5) . ?
Eu2 O16 2.438(4) . ?
Eu2 O2 2.485(4) . ?
Eu2 Eu3 4.4660(6) . ?
Eu3 O17 2.290(4) . ?
Eu3 O9 2.370(4) 4_666 ?
Eu3 O21 2.371(4) 2_545 ?
Eu3 O19 2.391(4) 4_566 ?
Eu3 O4 2.392(5) . ?
Eu3 O22 2.446(4) . ?
Eu3 O12 2.496(4) 4_566 ?
Eu3 O23 2.825(4) . ?
Eu3 C57 3.000(6) . ?
Eu3 C63 3.247(6) 4_566 ?
Cu1 N6 2.011(5) . ?
Cu1 Cu2 2.5633(13) . ?
Cu1 Cu3 2.6879(13) . ?
Cu1 I3 2.6954(11) . ?
Cu1 Cu4 2.7305(12) . ?
Cu1 I1 2.7306(10) . ?
Cu1 I2 2.7453(11) . ?
Cu2 N8 2.009(5) . ?
Cu2 Cu3 2.6185(12) . ?
Cu2 I3 2.7114(10) . ?
Cu2 I1 2.7127(11) . ?
Cu2 I4 2.7797(11) . ?
Cu2 Cu4 2.8647(12) . ?
Cu3 N7 2.002(5) . ?
Cu3 Cu4 2.5993(13) . ?
Cu3 I3 2.6068(10) . ?
Cu3 I4 2.6661(11) . ?
Cu3 I2 2.8079(12) . ?
Cu4 I4 2.6106(11) . ?
Cu4 I5 2.6510(9) . ?
Cu4 I2 2.6705(11) . ?
Cu4 I1 2.7480(10) . ?
Cu5 N11 2.011(5) . ?
Cu5 Cu7 2.6025(13) . ?
Cu5 I6 2.6184(11) . ?
Cu5 Cu8 2.6920(13) . ?
Cu5 I5 2.7420(11) . ?
Cu5 I8 2.8182(12) . ?
Cu5 Cu6 2.8614(13) . ?
Cu6 I7 2.6084(11) . ?
Cu6 I8 2.6087(11) . ?
Cu6 Cu8 2.6542(13) . ?
Cu6 I9 2.7152(10) . ?
Cu6 I5 2.7465(11) . ?
Cu6 Cu7 2.9645(13) . ?
Cu7 N9 2.021(5) . ?
Cu7 Cu8 2.6671(13) . ?
Cu7 I5 2.6847(12) . ?
Cu7 I7 2.7217(11) . ?
Cu7 I6 2.7647(11) . ?
Cu8 N10 2.024(5) . ?
Cu8 I6 2.6490(10) . ?
Cu8 I7 2.6865(11) . ?
Cu8 I8 2.7946(12) . ?
Cu9 N14 2.027(5) . ?
Cu9 Cu11 2.6482(13) . ?
Cu9 I9 2.6730(11) . ?
Cu9 I11 2.7226(11) . ?
Cu9 I12 2.7484(11) . ?
Cu9 Cu12 2.7969(13) . ?
Cu9 Cu10 2.8784(12) . ?
Cu10 N13 2.042(5) . ?
Cu10 I11 2.6620(10) . ?
Cu10 Cu12 2.6780(13) . ?
Cu10 I12 2.6848(11) . ?
Cu10 I10 2.7523(11) . ?
Cu10 Cu11 2.9330(13) . ?
Cu11 N12 2.024(5) . ?
Cu11 I11 2.6536(11) . ?
Cu11 I9 2.7415(11) . ?
Cu11 I10 2.7732(11) . ?
Cu11 Cu12 2.8501(12) . ?
Cu12 I12 2.6288(11) . ?
Cu12 I10 2.6305(10) . ?
Cu12 I1 2.7196(10) 2_655 ?
Cu12 I9 2.7432(10) . ?
I1 Cu12 2.7195(10) 2_645 ?
C1 O1 1.232(10) . ?
C1 N1 1.309(8) . ?
C1 H1 0.9300 . ?
C2 N1 1.497(8) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 N1 1.489(8) . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C1' O1' 1.231(10) . ?
C1' N1' 1.305(9) . ?
C1' H1' 0.9300 . ?
C2' N1' 1.501(9) . ?
C2' H2'1 0.9600 . ?
C2' H2'2 0.9600 . ?
C2' H2'3 0.9600 . ?
C3' N1' 1.497(9) . ?
C3' H3'1 0.9600 . ?
C3' H3'2 0.9600 . ?
C3' H3'3 0.9600 . ?
C4 O2 1.226(8) . ?
C4 N2 1.315(9) . ?
C4 H4 0.9300 . ?
C5 N2 1.465(10) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 N2 1.488(11) . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 O3 1.196(9) . ?
C7 N3 1.363(10) . ?
C7 H7 0.9300 . ?
C8 N3 1.441(12) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 N3 1.467(13) . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 O4 1.206(10) . ?
C10 N4 1.327(11) . ?
C10 H10 0.9300 . ?
C11 N4 1.419(15) . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 N4 1.515(15) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 N5 1.274(12) . ?
C13 O5 1.278(12) . ?
C13 H13 0.9300 . ?
C14 N5 1.394(13) . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 N5 1.399(12) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 N6 1.315(8) . ?
C16 C17 1.372(9) . ?
C16 H16 0.9300 . ?
C17 C18 1.388(8) . ?
C17 H17 0.9300 . ?
C18 C19 1.368(9) . ?
C18 C21 1.485(8) . ?
C19 C20 1.384(9) . ?
C19 H19 0.9300 . ?
C20 N6 1.348(8) . ?
C20 H20 0.9300 . ?
C21 O7 1.243(7) . ?
C21 O6 1.251(7) . ?
C21 Eu1 3.124(6) 2_645 ?
C22 N7 1.355(8) . ?
C22 C23 1.376(9) . ?
C22 H22 0.9300 . ?
C23 C24 1.367(9) . ?
C23 H23 0.9300 . ?
C24 C25 1.368(8) . ?
C24 C27 1.518(8) . ?
C25 C26 1.367(8) . ?
C25 H25 0.9300 . ?
C26 N7 1.332(8) . ?
C26 H26 0.9300 . ?
C27 O8 1.250(7) . ?
C27 O9 1.252(7) . ?
C28 N8 1.345(8) . ?
C28 C29 1.379(8) . ?
C28 H28 0.9300 . ?
C29 C30 1.388(8) . ?
C29 H29 0.9300 . ?
C30 C31 1.365(8) . ?
C30 C33 1.519(8) . ?
C31 C32 1.388(8) . ?
C31 H31 0.9300 . ?
C32 N8 1.333(8) . ?
C32 H32 0.9300 . ?
C33 O11 1.242(7) . ?
C33 O10 1.258(7) . ?
C34 N9 1.330(9) . ?
C34 C35 1.393(9) . ?
C34 H34 0.9300 . ?
C35 C36 1.380(9) . ?
C35 H35 0.9300 . ?
C36 C37 1.384(9) . ?
C36 C39 1.501(8) . ?
C37 C38 1.360(8) . ?
C37 H37 0.9300 . ?
C38 N9 1.343(8) . ?
C38 H38 0.9300 . ?
C39 O13 1.259(7) . ?
C39 O12 1.266(7) . ?
C39 Eu1 2.945(6) 4_665 ?
C40 N10 1.321(8) . ?
C40 C41 1.365(9) . ?
C40 H40 0.9300 . ?
C41 C42 1.373(8) . ?
C41 H41 0.9300 . ?
C42 C43 1.349(9) . ?
C42 C45 1.499(8) . ?
C43 C44 1.400(10) . ?
C43 H43 0.9300 . ?
C44 N10 1.330(8) . ?
C44 H44 0.9300 . ?
C45 O14 1.249(7) . ?
C45 O15 1.271(7) . ?
C46 N11 1.343(8) . ?
C46 C47 1.376(8) . ?
C46 H46 0.9300 . ?
C47 C48 1.385(9) . ?
C47 H47 0.9300 . ?
C48 C49 1.370(8) . ?
C48 C51 1.506(8) . ?
C49 C50 1.366(9) . ?
C49 H49 0.9300 . ?
C50 N11 1.342(8) . ?
C50 H50 0.9300 . ?
C51 O16 1.249(7) . ?
C51 O17 1.255(7) . ?
C52 N14 1.333(8) . ?
C52 C53 1.385(8) . ?
C52 H52 0.9300 . ?
C53 C54 1.382(9) . ?
C53 H53 0.9300 . ?
C54 C55 1.379(9) . ?
C54 C57 1.505(8) . ?
C55 C56 1.385(9) . ?
C55 H55 0.9300 . ?
C56 N14 1.325(9) . ?
C56 H56 0.9300 . ?
C57 O22 1.245(8) . ?
C57 O23 1.272(7) . ?
C58 N12 1.355(8) . ?
C58 C59 1.383(8) . ?
C58 H58 0.9300 . ?
C59 C60 1.393(8) . ?
C59 H59 0.9300 . ?
C60 C61 1.387(8) . ?
C60 C63 1.504(8) . ?
C61 C62 1.357(9) . ?
C61 H61 0.9300 . ?
C62 N12 1.352(9) . ?
C62 H62 0.9300 . ?
C63 O18 1.241(8) . ?
C63 O19 1.250(7) . ?
C63 Eu3 3.247(6) 4_665 ?
C64 N13 1.345(8) . ?
C64 C65 1.364(9) . ?
C64 H64 0.9300 . ?
C65 C66 1.387(8) . ?
C65 H65 0.9300 . ?
C66 C67 1.360(9) . ?
C66 C69 1.513(8) . ?
C67 C68 1.379(9) . ?
C67 H67 0.9300 . ?
C68 N13 1.330(8) . ?
C68 H68 0.9300 . ?
C69 O20 1.244(7) . ?
C69 O21 1.262(7) . ?
O6 Eu1 2.323(5) 4_665 ?
O6 Eu1 3.121(5) 2_645 ?
O7 Eu1 2.397(4) 2_645 ?
O8 Eu2 2.378(4) 4_565 ?
O9 Eu3 2.370(4) 4_565 ?
O11 Eu2 2.331(4) 3_656 ?
O12 Eu3 2.496(4) 4_665 ?
O12 Eu1 2.719(4) 4_665 ?
O13 Eu1 2.445(4) 4_665 ?
O14 Eu1 2.386(4) 3_766 ?
O15 Eu1 2.352(4) 1_655 ?
O18 Eu2 2.364(4) 4_665 ?
O19 Eu3 2.391(4) 4_665 ?
O20 Eu2 2.398(4) 2 ?
O21 Eu3 2.371(4) 2 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O1 148.8(4) 4_566 . ?
O6 Eu1 O15 73.85(16) 4_566 1_455 ?
O1 Eu1 O15 137.2(4) . 1_455 ?
O6 Eu1 O14 75.67(16) 4_566 3_766 ?
O1 Eu1 O14 79.4(4) . 3_766 ?
O15 Eu1 O14 128.81(14) 1_455 3_766 ?
O6 Eu1 O7 121.17(16) 4_566 2_655 ?
O1 Eu1 O7 67.9(5) . 2_655 ?
O15 Eu1 O7 88.10(17) 1_455 2_655 ?
O14 Eu1 O7 73.97(16) 3_766 2_655 ?
O6 Eu1 O23 135.92(16) 4_566 . ?
O1 Eu1 O23 71.1(3) . . ?
O15 Eu1 O23 71.87(15) 1_455 . ?
O14 Eu1 O23 148.38(16) 3_766 . ?
O7 Eu1 O23 84.52(15) 2_655 . ?
O6 Eu1 O13 78.27(16) 4_566 4_566 ?
O1 Eu1 O13 79.0(5) . 4_566 ?
O15 Eu1 O13 131.51(16) 1_455 4_566 ?
O14 Eu1 O13 79.24(15) 3_766 4_566 ?
O7 Eu1 O13 140.38(16) 2_655 4_566 ?
O23 Eu1 O13 105.18(14) . 4_566 ?
O6 Eu1 O1' 141.8(7) 4_566 . ?
O15 Eu1 O1' 144.3(7) 1_455 . ?
O14 Eu1 O1' 75.9(7) 3_766 . ?
O7 Eu1 O1' 73.7(10) 2_655 . ?
O23 Eu1 O1' 76.0(6) . . ?
O13 Eu1 O1' 71.8(9) 4_566 . ?
O6 Eu1 O12 83.40(15) 4_566 4_566 ?
O1 Eu1 O12 98.1(5) . 4_566 ?
O15 Eu1 O12 87.35(14) 1_455 4_566 ?
O14 Eu1 O12 128.43(13) 3_766 4_566 ?
O7 Eu1 O12 152.46(14) 2_655 4_566 ?
O23 Eu1 O12 68.25(14) . 4_566 ?
O13 Eu1 O12 50.30(14) 4_566 4_566 ?
O1' Eu1 O12 94.8(10) . 4_566 ?
O6 Eu1 C39 79.49(17) 4_566 4_566 ?
O1 Eu1 C39 88.6(5) . 4_566 ?
O15 Eu1 C39 109.99(18) 1_455 4_566 ?
O14 Eu1 C39 103.55(17) 3_766 4_566 ?
O7 Eu1 C39 156.48(17) 2_655 4_566 ?
O23 Eu1 C39 87.01(16) . 4_566 ?
O13 Eu1 C39 24.87(16) 4_566 4_566 ?
O1' Eu1 C39 82.9(10) . 4_566 ?
O12 Eu1 C39 25.43(15) 4_566 4_566 ?
O6 Eu1 O6 77.91(15) 4_566 2_655 ?
O1 Eu1 O6 110.0(5) . 2_655 ?
O15 Eu1 O6 65.22(14) 1_455 2_655 ?
O14 Eu1 O6 68.85(13) 3_766 2_655 ?
O7 Eu1 O6 44.34(13) 2_655 2_655 ?
O23 Eu1 O6 110.80(13) . 2_655 ?
O13 Eu1 O6 143.92(13) 4_566 2_655 ?
O1' Eu1 O6 114.2(10) . 2_655 ?
O12 Eu1 O6 150.12(13) 4_566 2_655 ?
C39 Eu1 O6 157.32(14) 4_566 2_655 ?
O6 Eu1 C21 100.63(17) 4_566 2_655 ?
O1 Eu1 C21 88.3(5) . 2_655 ?
O15 Eu1 C21 75.75(16) 1_455 2_655 ?
O14 Eu1 C21 70.71(15) 3_766 2_655 ?
O7 Eu1 C21 21.26(15) 2_655 2_655 ?
O23 Eu1 C21 96.93(15) . 2_655 ?
O13 Eu1 C21 149.07(16) 4_566 2_655 ?
O1' Eu1 C21 93.5(10) . 2_655 ?
O12 Eu1 C21 160.57(14) 4_566 2_655 ?
C39 Eu1 C21 173.91(18) 4_566 2_655 ?
O6 Eu1 C21 23.10(14) 2_655 2_655 ?
O11 Eu2 O10 77.26(14) 3_656 . ?
O11 Eu2 O18 80.13(15) 3_656 4_566 ?
O10 Eu2 O18 143.91(16) . 4_566 ?
O11 Eu2 O8 138.10(14) 3_656 4_666 ?
O10 Eu2 O8 139.63(15) . 4_666 ?
O18 Eu2 O8 73.76(15) 4_566 4_666 ?
O11 Eu2 O20 85.27(15) 3_656 2_545 ?
O10 Eu2 O20 77.52(16) . 2_545 ?
O18 Eu2 O20 72.88(17) 4_566 2_545 ?
O8 Eu2 O20 116.41(15) 4_666 2_545 ?
O11 Eu2 O3 109.97(16) 3_656 . ?
O10 Eu2 O3 70.79(16) . . ?
O18 Eu2 O3 144.33(17) 4_566 . ?
O8 Eu2 O3 77.05(15) 4_666 . ?
O20 Eu2 O3 140.09(17) 2_545 . ?
O11 Eu2 O16 152.09(14) 3_656 . ?
O10 Eu2 O16 76.79(14) . . ?
O18 Eu2 O16 116.47(15) 4_566 . ?
O8 Eu2 O16 69.81(14) 4_666 . ?
O20 Eu2 O16 79.25(15) 2_545 . ?
O3 Eu2 O16 70.52(15) . . ?
O11 Eu2 O2 70.95(15) 3_656 . ?
O10 Eu2 O2 117.34(14) . . ?
O18 Eu2 O2 80.39(17) 4_566 . ?
O8 Eu2 O2 72.78(14) 4_666 . ?
O20 Eu2 O2 146.87(17) 2_545 . ?
O3 Eu2 O2 71.67(16) . . ?
O16 Eu2 O2 131.33(16) . . ?
O11 Eu2 Eu3 122.07(11) 3_656 . ?
O10 Eu2 Eu3 126.88(10) . . ?
O18 Eu2 Eu3 48.70(12) 4_566 . ?
O8 Eu2 Eu3 58.94(10) 4_666 . ?
O20 Eu2 Eu3 58.22(11) 2_545 . ?
O3 Eu2 Eu3 127.16(11) . . ?
O16 Eu2 Eu3 67.98(10) . . ?
O2 Eu2 Eu3 115.77(11) . . ?
O17 Eu3 O9 75.83(16) . 4_666 ?
O17 Eu3 O21 78.69(16) . 2_545 ?
O9 Eu3 O21 129.33(15) 4_666 2_545 ?
O17 Eu3 O19 123.51(15) . 4_566 ?
O9 Eu3 O19 86.00(16) 4_666 4_566 ?
O21 Eu3 O19 72.88(16) 2_545 4_566 ?
O17 Eu3 O4 146.20(17) . . ?
O9 Eu3 O4 137.70(17) 4_666 . ?
O21 Eu3 O4 79.33(17) 2_545 . ?
O19 Eu3 O4 72.92(17) 4_566 . ?
O17 Eu3 O22 76.59(15) . . ?
O9 Eu3 O22 130.93(16) 4_666 . ?
O21 Eu3 O22 82.78(16) 2_545 . ?
O19 Eu3 O22 142.93(16) 4_566 . ?
O4 Eu3 O22 75.44(17) . . ?
O17 Eu3 O12 131.34(15) . 4_566 ?
O9 Eu3 O12 71.17(14) 4_666 4_566 ?
O21 Eu3 O12 149.75(16) 2_545 4_566 ?
O19 Eu3 O12 88.95(14) 4_566 4_566 ?
O4 Eu3 O12 72.18(17) . 4_566 ?
O22 Eu3 O12 99.35(14) . 4_566 ?
O17 Eu3 O23 77.25(14) . . ?
O9 Eu3 O23 85.90(14) 4_666 . ?
O21 Eu3 O23 129.49(14) 2_545 . ?
O19 Eu3 O23 154.76(14) 4_566 . ?
O4 Eu3 O23 97.76(15) . . ?
O22 Eu3 O23 48.69(14) . . ?
O12 Eu3 O23 65.81(13) 4_566 . ?
O17 Eu3 C57 74.33(16) . . ?
O9 Eu3 C57 108.79(17) 4_666 . ?
O21 Eu3 C57 105.31(17) 2_545 . ?
O19 Eu3 C57 160.05(17) 4_566 . ?
O4 Eu3 C57 87.18(18) . . ?
O22 Eu3 C57 23.75(16) . . ?
O12 Eu3 C57 83.55(15) 4_566 . ?
O23 Eu3 C57 25.00(15) . . ?
O17 Eu3 C63 104.87(16) . 4_566 ?
O9 Eu3 C63 77.24(16) 4_666 4_566 ?
O21 Eu3 C63 68.06(16) 2_545 4_566 ?
O19 Eu3 C63 18.83(16) 4_566 4_566 ?
O4 Eu3 C63 90.20(18) . 4_566 ?
O22 Eu3 C63 149.55(16) . 4_566 ?
O12 Eu3 C63 101.57(14) 4_566 4_566 ?
O23 Eu3 C63 161.75(14) . 4_566 ?
C57 Eu3 C63 173.24(17) . 4_566 ?
O17 Eu3 Eu1 102.44(11) . . ?
O9 Eu3 Eu1 74.57(10) 4_666 . ?
O21 Eu3 Eu1 154.40(11) 2_545 . ?
O19 Eu3 Eu1 123.59(11) 4_566 . ?
O4 Eu3 Eu1 87.02(13) . . ?
O22 Eu3 Eu1 72.82(11) . . ?
O12 Eu3 Eu1 34.73(9) 4_566 . ?
O23 Eu3 Eu1 31.22(8) . . ?
C57 Eu3 Eu1 52.02(13) . . ?
C63 Eu3 Eu1 134.08(11) 4_566 . ?
O17 Eu3 Eu2 53.06(10) . . ?
O9 Eu3 Eu2 64.05(10) 4_666 . ?
O21 Eu3 Eu2 65.56(11) 2_545 . ?
O19 Eu3 Eu2 70.78(11) 4_566 . ?
O4 Eu3 Eu2 135.18(12) . . ?
O22 Eu3 Eu2 123.60(11) . . ?
O12 Eu3 Eu2 131.49(9) 4_566 . ?
O23 Eu3 Eu2 125.78(9) . . ?
C57 Eu3 Eu2 127.34(12) . . ?
C63 Eu3 Eu2 51.98(12) 4_566 . ?
Eu1 Eu3 Eu2 135.426(12) . . ?
N6 Cu1 Cu2 141.67(15) . . ?
N6 Cu1 Cu3 149.08(16) . . ?
Cu2 Cu1 Cu3 59.77(4) . . ?
N6 Cu1 I3 107.24(16) . . ?
Cu2 Cu1 I3 62.02(3) . . ?
Cu3 Cu1 I3 57.93(3) . . ?
N6 Cu1 Cu4 142.08(16) . . ?
Cu2 Cu1 Cu4 65.43(3) . . ?
Cu3 Cu1 Cu4 57.33(3) . . ?
I3 Cu1 Cu4 110.27(4) . . ?
N6 Cu1 I1 104.43(16) . . ?
Cu2 Cu1 I1 61.55(3) . . ?
Cu3 Cu1 I1 106.41(4) . . ?
I3 Cu1 I1 120.18(4) . . ?
Cu4 Cu1 I1 60.42(3) . . ?
N6 Cu1 I2 104.29(15) . . ?
Cu2 Cu1 I2 114.03(4) . . ?
Cu3 Cu1 I2 62.22(3) . . ?
I3 Cu1 I2 108.51(4) . . ?
Cu4 Cu1 I2 58.38(3) . . ?
I1 Cu1 I2 110.90(3) . . ?
N8 Cu2 Cu1 145.10(15) . . ?
N8 Cu2 Cu3 141.59(16) . . ?
Cu1 Cu2 Cu3 62.48(4) . . ?
N8 Cu2 I3 105.54(15) . . ?
Cu1 Cu2 I3 61.39(3) . . ?
Cu3 Cu2 I3 58.53(3) . . ?
N8 Cu2 I1 109.03(16) . . ?
Cu1 Cu2 I1 62.26(3) . . ?
Cu3 Cu2 I1 108.94(4) . . ?
I3 Cu2 I1 120.26(4) . . ?
N8 Cu2 I4 106.26(15) . . ?
Cu1 Cu2 I4 108.64(4) . . ?
Cu3 Cu2 I4 59.10(3) . . ?
I3 Cu2 I4 111.95(4) . . ?
I1 Cu2 I4 103.09(3) . . ?
N8 Cu2 Cu4 147.86(15) . . ?
Cu1 Cu2 Cu4 60.10(3) . . ?
Cu3 Cu2 Cu4 56.38(3) . . ?
I3 Cu2 Cu4 105.93(3) . . ?
I1 Cu2 Cu4 58.96(3) . . ?
I4 Cu2 Cu4 55.07(3) . . ?
N7 Cu3 Cu4 128.63(16) . . ?
N7 Cu3 I3 113.53(16) . . ?
Cu4 Cu3 I3 117.55(4) . . ?
N7 Cu3 Cu2 149.68(18) . . ?
Cu4 Cu3 Cu2 66.60(4) . . ?
I3 Cu3 Cu2 62.51(3) . . ?
N7 Cu3 I4 99.67(17) . . ?
Cu4 Cu3 I4 59.43(3) . . ?
I3 Cu3 I4 119.33(4) . . ?
Cu2 Cu3 I4 63.46(3) . . ?
N7 Cu3 Cu1 150.01(18) . . ?
Cu4 Cu3 Cu1 62.16(4) . . ?
I3 Cu3 Cu1 61.18(3) . . ?
Cu2 Cu3 Cu1 57.75(3) . . ?
I4 Cu3 Cu1 108.38(4) . . ?
N7 Cu3 I2 99.45(18) . . ?
Cu4 Cu3 I2 59.04(3) . . ?
I3 Cu3 I2 109.23(4) . . ?
Cu2 Cu3 I2 110.28(4) . . ?
I4 Cu3 I2 113.57(3) . . ?
Cu1 Cu3 I2 59.89(3) . . ?
Cu3 Cu4 I4 61.56(3) . . ?
Cu3 Cu4 I5 146.81(4) . . ?
I4 Cu4 I5 104.35(3) . . ?
Cu3 Cu4 I2 64.38(3) . . ?
I4 Cu4 I2 120.28(4) . . ?
I5 Cu4 I2 106.98(3) . . ?
Cu3 Cu4 Cu1 60.51(3) . . ?
I4 Cu4 Cu1 108.74(4) . . ?
I5 Cu4 Cu1 146.25(4) . . ?
I2 Cu4 Cu1 61.09(3) . . ?
Cu3 Cu4 I1 108.44(4) . . ?
I4 Cu4 I1 106.75(3) . . ?
I5 Cu4 I1 104.39(3) . . ?
I2 Cu4 I1 112.67(3) . . ?
Cu1 Cu4 I1 59.79(3) . . ?
Cu3 Cu4 Cu2 57.02(3) . . ?
I4 Cu4 Cu2 60.81(3) . . ?
I5 Cu4 Cu2 145.65(4) . . ?
I2 Cu4 Cu2 107.10(3) . . ?
Cu1 Cu4 Cu2 54.47(3) . . ?
I1 Cu4 Cu2 57.76(3) . . ?
N11 Cu5 Cu7 146.66(16) . . ?
N11 Cu5 I6 111.04(16) . . ?
Cu7 Cu5 I6 63.95(3) . . ?
N11 Cu5 Cu8 148.64(16) . . ?
Cu7 Cu5 Cu8 60.47(4) . . ?
I6 Cu5 Cu8 59.83(3) . . ?
N11 Cu5 I5 105.17(16) . . ?
Cu7 Cu5 I5 60.24(3) . . ?
I6 Cu5 I5 121.11(4) . . ?
Cu8 Cu5 I5 104.58(4) . . ?
N11 Cu5 I8 101.06(15) . . ?
Cu7 Cu5 I8 111.63(4) . . ?
I6 Cu5 I8 110.33(4) . . ?
Cu8 Cu5 I8 60.90(3) . . ?
I5 Cu5 I8 106.15(3) . . ?
N11 Cu5 Cu6 135.80(16) . . ?
Cu7 Cu5 Cu6 65.52(3) . . ?
I6 Cu5 Cu6 112.11(4) . . ?
Cu8 Cu5 Cu6 57.00(3) . . ?
I5 Cu5 Cu6 58.65(3) . . ?
I8 Cu5 Cu6 54.68(3) . . ?
I7 Cu6 I8 120.71(4) . . ?
I7 Cu6 Cu8 61.38(3) . . ?
I8 Cu6 Cu8 64.14(3) . . ?
I7 Cu6 I9 108.11(4) . . ?
I8 Cu6 I9 109.26(4) . . ?
Cu8 Cu6 I9 152.57(4) . . ?
I7 Cu6 I5 103.21(4) . . ?
I8 Cu6 I5 112.19(4) . . ?
Cu8 Cu6 I5 105.49(4) . . ?
I9 Cu6 I5 101.57(3) . . ?
I7 Cu6 Cu5 104.85(4) . . ?
I8 Cu6 Cu5 61.82(3) . . ?
Cu8 Cu6 Cu5 58.28(3) . . ?
I9 Cu6 Cu5 144.83(4) . . ?
I5 Cu6 Cu5 58.50(3) . . ?
I7 Cu6 Cu7 58.05(3) . . ?
I8 Cu6 Cu7 107.03(4) . . ?
Cu8 Cu6 Cu7 56.35(3) . . ?
I9 Cu6 Cu7 142.72(4) . . ?
I5 Cu6 Cu7 55.92(3) . . ?
Cu5 Cu6 Cu7 53.03(3) . . ?
N9 Cu7 Cu5 138.40(16) . . ?
N9 Cu7 Cu8 143.63(17) . . ?
Cu5 Cu7 Cu8 61.43(4) . . ?
N9 Cu7 I5 109.46(17) . . ?
Cu5 Cu7 I5 62.46(3) . . ?
Cu8 Cu7 I5 106.89(4) . . ?
N9 Cu7 I7 112.47(16) . . ?
Cu5 Cu7 I7 109.10(4) . . ?
Cu8 Cu7 I7 59.80(3) . . ?
I5 Cu7 I7 101.87(3) . . ?
N9 Cu7 I6 102.40(16) . . ?
Cu5 Cu7 I6 58.30(3) . . ?
Cu8 Cu7 I6 58.34(3) . . ?
I5 Cu7 I6 117.88(4) . . ?
I7 Cu7 I6 113.08(4) . . ?
N9 Cu7 Cu6 152.53(16) . . ?
Cu5 Cu7 Cu6 61.45(3) . . ?
Cu8 Cu7 Cu6 55.94(3) . . ?
I5 Cu7 Cu6 57.92(3) . . ?
I7 Cu7 Cu6 54.41(3) . . ?
I6 Cu7 Cu6 105.03(3) . . ?
N10 Cu8 I6 110.86(15) . . ?
N10 Cu8 Cu6 130.82(16) . . ?
I6 Cu8 Cu6 118.09(4) . . ?
N10 Cu8 Cu7 146.93(18) . . ?
I6 Cu8 Cu7 62.67(3) . . ?
Cu6 Cu8 Cu7 67.71(4) . . ?
N10 Cu8 I7 102.38(17) . . ?
I6 Cu8 I7 118.16(4) . . ?
Cu6 Cu8 I7 58.47(3) . . ?
Cu7 Cu8 I7 61.11(3) . . ?
N10 Cu8 Cu5 149.64(18) . . ?
I6 Cu8 Cu5 58.71(3) . . ?
Cu6 Cu8 Cu5 64.71(4) . . ?
Cu7 Cu8 Cu5 58.11(4) . . ?
I7 Cu8 Cu5 107.51(4) . . ?
N10 Cu8 I8 102.25(18) . . ?
I6 Cu8 I8 110.15(4) . . ?
Cu6 Cu8 I8 57.14(3) . . ?
Cu7 Cu8 I8 110.41(4) . . ?
I7 Cu8 I8 111.62(4) . . ?
Cu5 Cu8 I8 61.78(3) . . ?
N14 Cu9 Cu11 141.72(17) . . ?
N14 Cu9 I9 108.06(17) . . ?
Cu11 Cu9 I9 62.02(3) . . ?
N14 Cu9 I11 107.27(16) . . ?
Cu11 Cu9 I11 59.20(3) . . ?
I9 Cu9 I11 118.89(4) . . ?
N14 Cu9 I12 107.06(17) . . ?
Cu11 Cu9 I12 111.16(4) . . ?
I9 Cu9 I12 107.81(3) . . ?
I11 Cu9 I12 107.20(4) . . ?
N14 Cu9 Cu12 147.81(16) . . ?
Cu11 Cu9 Cu12 63.06(3) . . ?
I9 Cu9 Cu12 60.15(3) . . ?
I11 Cu9 Cu12 104.31(3) . . ?
I12 Cu9 Cu12 56.59(3) . . ?
N14 Cu9 Cu10 142.52(17) . . ?
Cu11 Cu9 Cu10 63.95(4) . . ?
I9 Cu9 Cu10 109.19(4) . . ?
I11 Cu9 Cu10 56.67(3) . . ?
I12 Cu9 Cu10 56.94(3) . . ?
Cu12 Cu9 Cu10 56.29(3) . . ?
N13 Cu10 I11 119.75(14) . . ?
N13 Cu10 Cu12 130.75(14) . . ?
I11 Cu10 Cu12 109.42(4) . . ?
N13 Cu10 I12 103.17(15) . . ?
I11 Cu10 I12 110.89(3) . . ?
Cu12 Cu10 I12 58.70(3) . . ?
N13 Cu10 I10 102.43(16) . . ?
I11 Cu10 I10 107.15(4) . . ?
Cu12 Cu10 I10 57.93(3) . . ?
I12 Cu10 I10 113.39(4) . . ?
N13 Cu10 Cu9 153.21(16) . . ?
I11 Cu10 Cu9 58.71(3) . . ?
Cu12 Cu10 Cu9 60.32(3) . . ?
I12 Cu10 Cu9 59.09(3) . . ?
I10 Cu10 Cu9 103.23(4) . . ?
N13 Cu10 Cu11 150.81(16) . . ?
I11 Cu10 Cu11 56.37(3) . . ?
Cu12 Cu10 Cu11 60.85(3) . . ?
I12 Cu10 Cu11 104.75(3) . . ?
I10 Cu10 Cu11 58.28(3) . . ?
Cu9 Cu10 Cu11 54.21(3) . . ?
N12 Cu11 Cu9 143.08(16) . . ?
N12 Cu11 I11 114.11(16) . . ?
Cu9 Cu11 I11 61.80(3) . . ?
N12 Cu11 I9 102.86(17) . . ?
Cu9 Cu11 I9 59.43(3) . . ?
I11 Cu11 I9 118.91(4) . . ?
N12 Cu11 I10 107.09(15) . . ?
Cu9 Cu11 I10 109.01(4) . . ?
I11 Cu11 I10 106.79(4) . . ?
I9 Cu11 I10 106.35(3) . . ?
N12 Cu11 Cu12 141.03(16) . . ?
Cu9 Cu11 Cu12 61.02(3) . . ?
I11 Cu11 Cu12 104.68(4) . . ?
I9 Cu11 Cu12 58.72(3) . . ?
I10 Cu11 Cu12 55.76(3) . . ?
N12 Cu11 Cu10 150.45(17) . . ?
Cu9 Cu11 Cu10 61.84(3) . . ?
I11 Cu11 Cu10 56.65(3) . . ?
I9 Cu11 Cu10 105.76(3) . . ?
I10 Cu11 Cu10 57.60(3) . . ?
Cu12 Cu11 Cu10 55.15(3) . . ?
I12 Cu12 I10 119.55(4) . . ?
I12 Cu12 Cu10 60.78(3) . . ?
I10 Cu12 Cu10 62.45(3) . . ?
I12 Cu12 I1 109.69(3) . 2_655 ?
I10 Cu12 I1 104.92(3) . 2_655 ?
Cu10 Cu12 I1 145.40(4) . 2_655 ?
I12 Cu12 I9 109.26(3) . . ?
I10 Cu12 I9 110.45(4) . . ?
Cu10 Cu12 I9 113.21(4) . . ?
I1 Cu12 I9 101.36(3) 2_655 . ?
I12 Cu12 Cu9 60.78(3) . . ?
I10 Cu12 Cu9 108.81(4) . . ?
Cu10 Cu12 Cu9 63.39(3) . . ?
I1 Cu12 Cu9 144.88(4) 2_655 . ?
I9 Cu12 Cu9 57.69(3) . . ?
I12 Cu12 Cu11 108.63(4) . . ?
I10 Cu12 Cu11 60.64(3) . . ?
Cu10 Cu12 Cu11 64.00(3) . . ?
I1 Cu12 Cu11 141.01(4) 2_655 . ?
I9 Cu12 Cu11 58.66(3) . . ?
Cu9 Cu12 Cu11 55.92(3) . . ?
Cu2 I1 Cu12 108.84(3) . 2_645 ?
Cu2 I1 Cu1 56.18(3) . . ?
Cu12 I1 Cu1 107.95(3) 2_645 . ?
Cu2 I1 Cu4 63.28(3) . . ?
Cu12 I1 Cu4 167.51(3) 2_645 . ?
Cu1 I1 Cu4 59.79(3) . . ?
Cu4 I2 Cu1 60.53(3) . . ?
Cu4 I2 Cu3 56.58(3) . . ?
Cu1 I2 Cu3 57.88(3) . . ?
Cu3 I3 Cu1 60.89(3) . . ?
Cu3 I3 Cu2 58.95(3) . . ?
Cu1 I3 Cu2 56.60(3) . . ?
Cu4 I4 Cu3 59.01(3) . . ?
Cu4 I4 Cu2 64.12(3) . . ?
Cu3 I4 Cu2 57.43(3) . . ?
Cu4 I5 Cu7 109.35(3) . . ?
Cu4 I5 Cu5 105.71(3) . . ?
Cu7 I5 Cu5 57.30(3) . . ?
Cu4 I5 Cu6 168.51(3) . . ?
Cu7 I5 Cu6 66.15(3) . . ?
Cu5 I5 Cu6 62.84(3) . . ?
Cu5 I6 Cu8 61.47(3) . . ?
Cu5 I6 Cu7 57.75(3) . . ?
Cu8 I6 Cu7 58.98(3) . . ?
Cu6 I7 Cu8 60.15(3) . . ?
Cu6 I7 Cu7 67.55(3) . . ?
Cu8 I7 Cu7 59.09(3) . . ?
Cu6 I8 Cu8 58.72(3) . . ?
Cu6 I8 Cu5 63.50(3) . . ?
Cu8 I8 Cu5 57.32(3) . . ?
Cu9 I9 Cu6 115.57(3) . . ?
Cu9 I9 Cu11 58.55(3) . . ?
Cu6 I9 Cu11 111.66(3) . . ?
Cu9 I9 Cu12 62.17(3) . . ?
Cu6 I9 Cu12 174.27(3) . . ?
Cu11 I9 Cu12 62.62(3) . . ?
Cu12 I10 Cu10 59.62(3) . . ?
Cu12 I10 Cu11 63.60(3) . . ?
Cu10 I10 Cu11 64.12(3) . . ?
Cu11 I11 Cu10 66.98(3) . . ?
Cu11 I11 Cu9 59.00(3) . . ?
Cu10 I11 Cu9 64.62(3) . . ?
Cu12 I12 Cu10 60.52(3) . . ?
Cu12 I12 Cu9 62.64(3) . . ?
Cu10 I12 Cu9 63.97(3) . . ?
O1 C1 N1 124.1(11) . . ?
O1 C1 H1 118.0 . . ?
N1 C1 H1 118.0 . . ?
N1 C2 H2A 109.5 . . ?
N1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
N1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N1 C3 H3A 109.5 . . ?
N1 C3 H3B 109.6 . . ?
H3A C3 H3B 109.5 . . ?
N1 C3 H3C 109.3 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 N1 C3 122.0(8) . . ?
C1 N1 C2 122.8(8) . . ?
C3 N1 C2 115.1(7) . . ?
C1 O1 Eu1 132.9(13) . . ?
O1' C1' N1' 123(2) . . ?
O1' C1' H1' 118.4 . . ?
N1' C1' H1' 118.4 . . ?
N1' C2' H2'1 110.0 . . ?
N1' C2' H2'2 109.2 . . ?
H2'1 C2' H2'2 109.5 . . ?
N1' C2' H2'3 109.2 . . ?
H2'1 C2' H2'3 109.5 . . ?
H2'2 C2' H2'3 109.5 . . ?
N1' C3' H3'1 109.8 . . ?
N1' C3' H3'2 109.1 . . ?
H3'1 C3' H3'2 109.5 . . ?
N1' C3' H3'3 109.5 . . ?
H3'1 C3' H3'3 109.5 . . ?
H3'2 C3' H3'3 109.5 . . ?
C1' N1' C3' 123.0(9) . . ?
C1' N1' C2' 122.8(9) . . ?
C3' N1' C2' 114.1(8) . . ?
C1' O1' Eu1 126(3) . . ?
O2 C4 N2 127.7(8) . . ?
O2 C4 H4 116.2 . . ?
N2 C4 H4 116.2 . . ?
N2 C5 H5A 109.4 . . ?
N2 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
N2 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
N2 C6 H6A 109.2 . . ?
N2 C6 H6B 109.6 . . ?
H6A C6 H6B 109.5 . . ?
N2 C6 H6C 109.6 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
O3 C7 N3 126.1(9) . . ?
O3 C7 H7 117.0 . . ?
N3 C7 H7 117.0 . . ?
N3 C8 H8A 110.0 . . ?
N3 C8 H8B 109.3 . . ?
H8A C8 H8B 109.5 . . ?
N3 C8 H8C 109.1 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N3 C9 H9A 109.3 . . ?
N3 C9 H9B 109.4 . . ?
H9A C9 H9B 109.5 . . ?
N3 C9 H9C 109.7 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
O4 C10 N4 125.5(11) . . ?
O4 C10 H10 117.2 . . ?
N4 C10 H10 117.2 . . ?
N4 C11 H11A 109.4 . . ?
N4 C11 H11B 109.3 . . ?
H11A C11 H11B 109.5 . . ?
N4 C11 H11C 109.7 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N4 C12 H12A 109.5 . . ?
N4 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
N4 C12 H12C 109.4 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
N5 C13 O5 123.7(13) . . ?
N5 C13 H13 118.1 . . ?
O5 C13 H13 118.1 . . ?
N5 C14 H14A 110.0 . . ?
N5 C14 H14B 109.0 . . ?
H14A C14 H14B 109.5 . . ?
N5 C14 H14C 109.4 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
N5 C15 H15A 109.2 . . ?
N5 C15 H15B 109.7 . . ?
H15A C15 H15B 109.5 . . ?
N5 C15 H15C 109.6 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N6 C16 C17 123.6(6) . . ?
N6 C16 H16 118.2 . . ?
C17 C16 H16 118.2 . . ?
C16 C17 C18 119.5(6) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C19 C18 C17 117.3(6) . . ?
C19 C18 C21 121.9(6) . . ?
C17 C18 C21 120.9(6) . . ?
C18 C19 C20 119.8(6) . . ?
C18 C19 H19 120.1 . . ?
C20 C19 H19 120.1 . . ?
N6 C20 C19 122.4(7) . . ?
N6 C20 H20 118.8 . . ?
C19 C20 H20 118.8 . . ?
O7 C21 O6 122.6(6) . . ?
O7 C21 C18 118.5(6) . . ?
O6 C21 C18 118.9(6) . . ?
O7 C21 Eu1 44.3(3) . 2_645 ?
O6 C21 Eu1 78.3(4) . 2_645 ?
C18 C21 Eu1 162.7(4) . 2_645 ?
N7 C22 C23 122.7(6) . . ?
N7 C22 H22 118.7 . . ?
C23 C22 H22 118.7 . . ?
C24 C23 C22 119.6(6) . . ?
C24 C23 H23 120.2 . . ?
C22 C23 H23 120.2 . . ?
C23 C24 C25 117.8(6) . . ?
C23 C24 C27 120.1(5) . . ?
C25 C24 C27 122.1(6) . . ?
C26 C25 C24 120.1(6) . . ?
C26 C25 H25 119.9 . . ?
C24 C25 H25 119.9 . . ?
N7 C26 C25 123.2(6) . . ?
N7 C26 H26 118.4 . . ?
C25 C26 H26 118.4 . . ?
O8 C27 O9 126.7(5) . . ?
O8 C27 C24 116.2(5) . . ?
O9 C27 C24 117.0(5) . . ?
N8 C28 C29 123.3(6) . . ?
N8 C28 H28 118.3 . . ?
C29 C28 H28 118.3 . . ?
C28 C29 C30 118.8(6) . . ?
C28 C29 H29 120.6 . . ?
C30 C29 H29 120.6 . . ?
C31 C30 C29 118.3(6) . . ?
C31 C30 C33 121.7(5) . . ?
C29 C30 C33 120.0(6) . . ?
C30 C31 C32 119.4(6) . . ?
C30 C31 H31 120.3 . . ?
C32 C31 H31 120.3 . . ?
N8 C32 C31 123.2(6) . . ?
N8 C32 H32 118.4 . . ?
C31 C32 H32 118.4 . . ?
O11 C33 O10 126.9(6) . . ?
O11 C33 C30 116.5(5) . . ?
O10 C33 C30 116.5(5) . . ?
N9 C34 C35 123.4(6) . . ?
N9 C34 H34 118.3 . . ?
C35 C34 H34 118.3 . . ?
C36 C35 C34 119.0(7) . . ?
C36 C35 H35 120.5 . . ?
C34 C35 H35 120.5 . . ?
C35 C36 C37 117.1(6) . . ?
C35 C36 C39 120.7(6) . . ?
C37 C36 C39 122.3(6) . . ?
C38 C37 C36 120.4(6) . . ?
C38 C37 H37 119.8 . . ?
C36 C37 H37 119.8 . . ?
N9 C38 C37 123.3(6) . . ?
N9 C38 H38 118.4 . . ?
C37 C38 H38 118.4 . . ?
O13 C39 O12 122.0(5) . . ?
O13 C39 C36 118.0(6) . . ?
O12 C39 C36 119.9(6) . . ?
O13 C39 Eu1 54.8(3) . 4_665 ?
O12 C39 Eu1 67.3(3) . 4_665 ?
C36 C39 Eu1 172.0(5) . 4_665 ?
N10 C40 C41 123.1(6) . . ?
N10 C40 H40 118.5 . . ?
C41 C40 H40 118.5 . . ?
C40 C41 C42 120.9(6) . . ?
C40 C41 H41 119.5 . . ?
C42 C41 H41 119.5 . . ?
C43 C42 C41 116.8(6) . . ?
C43 C42 C45 122.1(6) . . ?
C41 C42 C45 121.1(6) . . ?
C42 C43 C44 119.4(6) . . ?
C42 C43 H43 120.3 . . ?
C44 C43 H43 120.3 . . ?
N10 C44 C43 123.2(7) . . ?
N10 C44 H44 118.4 . . ?
C43 C44 H44 118.4 . . ?
O14 C45 O15 126.3(6) . . ?
O14 C45 C42 117.5(6) . . ?
O15 C45 C42 116.3(5) . . ?
N11 C46 C47 123.5(6) . . ?
N11 C46 H46 118.3 . . ?
C47 C46 H46 118.3 . . ?
C46 C47 C48 119.4(6) . . ?
C46 C47 H47 120.3 . . ?
C48 C47 H47 120.3 . . ?
C49 C48 C47 117.0(6) . . ?
C49 C48 C51 120.2(6) . . ?
C47 C48 C51 122.8(5) . . ?
C50 C49 C48 120.5(6) . . ?
C50 C49 H49 119.7 . . ?
C48 C49 H49 119.7 . . ?
N11 C50 C49 123.3(6) . . ?
N11 C50 H50 118.4 . . ?
C49 C50 H50 118.4 . . ?
O16 C51 O17 124.8(6) . . ?
O16 C51 C48 118.6(6) . . ?
O17 C51 C48 116.6(5) . . ?
N14 C52 C53 124.0(6) . . ?
N14 C52 H52 118.0 . . ?
C53 C52 H52 118.0 . . ?
C54 C53 C52 119.2(6) . . ?
C54 C53 H53 120.4 . . ?
C52 C53 H53 120.4 . . ?
C55 C54 C53 117.7(6) . . ?
C55 C54 C57 120.2(6) . . ?
C53 C54 C57 122.0(6) . . ?
C54 C55 C56 118.3(7) . . ?
C54 C55 H55 120.8 . . ?
C56 C55 H55 120.8 . . ?
N14 C56 C55 125.2(6) . . ?
N14 C56 H56 117.4 . . ?
C55 C56 H56 117.4 . . ?
O22 C57 O23 121.8(6) . . ?
O22 C57 C54 118.8(6) . . ?
O23 C57 C54 119.3(6) . . ?
O22 C57 Eu3 52.3(3) . . ?
O23 C57 Eu3 69.8(3) . . ?
C54 C57 Eu3 168.3(4) . . ?
N12 C58 C59 122.6(6) . . ?
N12 C58 H58 118.7 . . ?
C59 C58 H58 118.7 . . ?
C58 C59 C60 120.3(6) . . ?
C58 C59 H59 119.8 . . ?
C60 C59 H59 119.8 . . ?
C61 C60 C59 116.2(6) . . ?
C61 C60 C63 121.2(6) . . ?
C59 C60 C63 122.6(6) . . ?
C62 C61 C60 120.9(6) . . ?
C62 C61 H61 119.5 . . ?
C60 C61 H61 119.5 . . ?
N12 C62 C61 123.6(6) . . ?
N12 C62 H62 118.2 . . ?
C61 C62 H62 118.2 . . ?
O18 C63 O19 124.1(6) . . ?
O18 C63 C60 118.0(6) . . ?
O19 C63 C60 117.9(6) . . ?
O18 C63 Eu3 86.6(4) . 4_665 ?
O19 C63 Eu3 38.1(3) . 4_665 ?
C60 C63 Eu3 154.2(5) . 4_665 ?
N13 C64 C65 123.2(6) . . ?
N13 C64 H64 118.4 . . ?
C65 C64 H64 118.4 . . ?
C64 C65 C66 120.3(6) . . ?
C64 C65 H65 119.9 . . ?
C66 C65 H65 119.9 . . ?
C67 C66 C65 117.0(6) . . ?
C67 C66 C69 122.5(5) . . ?
C65 C66 C69 120.5(6) . . ?
C66 C67 C68 119.5(6) . . ?
C66 C67 H67 120.2 . . ?
C68 C67 H67 120.2 . . ?
N13 C68 C67 124.3(6) . . ?
N13 C68 H68 117.8 . . ?
C67 C68 H68 117.8 . . ?
O20 C69 O21 126.1(6) . . ?
O20 C69 C66 118.6(5) . . ?
O21 C69 C66 115.3(6) . . ?
C4 N2 C5 121.1(9) . . ?
C4 N2 C6 118.8(7) . . ?
C5 N2 C6 120.1(7) . . ?
C7 N3 C8 123.2(10) . . ?
C7 N3 C9 117.8(9) . . ?
C8 N3 C9 119.0(9) . . ?
C10 N4 C11 122.1(12) . . ?
C10 N4 C12 117.2(12) . . ?
C11 N4 C12 120.5(11) . . ?
C13 N5 C14 121.4(12) . . ?
C13 N5 C15 119.7(12) . . ?
C14 N5 C15 118.6(11) . . ?
C16 N6 C20 117.3(6) . . ?
C16 N6 Cu1 119.9(4) . . ?
C20 N6 Cu1 122.7(5) . . ?
C26 N7 C22 116.5(5) . . ?
C26 N7 Cu3 123.2(4) . . ?
C22 N7 Cu3 120.3(5) . . ?
C32 N8 C28 116.8(5) . . ?
C32 N8 Cu2 118.4(4) . . ?
C28 N8 Cu2 124.2(4) . . ?
C34 N9 C38 116.7(5) . . ?
C34 N9 Cu7 120.9(4) . . ?
C38 N9 Cu7 122.2(5) . . ?
C40 N10 C44 116.4(6) . . ?
C40 N10 Cu8 122.9(4) . . ?
C44 N10 Cu8 120.7(5) . . ?
C50 N11 C46 116.1(6) . . ?
C50 N11 Cu5 117.0(4) . . ?
C46 N11 Cu5 126.7(5) . . ?
C62 N12 C58 116.2(6) . . ?
C62 N12 Cu11 118.5(4) . . ?
C58 N12 Cu11 125.1(5) . . ?
C68 N13 C64 115.7(5) . . ?
C68 N13 Cu10 120.5(4) . . ?
C64 N13 Cu10 123.8(4) . . ?
C56 N14 C52 115.4(6) . . ?
C56 N14 Cu9 122.5(4) . . ?
C52 N14 Cu9 121.7(5) . . ?
C4 O2 Eu2 129.5(5) . . ?
C7 O3 Eu2 136.2(5) . . ?
C10 O4 Eu3 133.9(6) . . ?
C21 O6 Eu1 169.6(5) . 4_665 ?
C21 O6 Eu1 78.6(4) . 2_645 ?
Eu1 O6 Eu1 102.09(15) 4_665 2_645 ?
C21 O7 Eu1 114.4(4) . 2_645 ?
C27 O8 Eu2 148.7(4) . 4_565 ?
C27 O9 Eu3 137.3(4) . 4_565 ?
C33 O10 Eu2 138.7(4) . . ?
C33 O11 Eu2 159.4(4) . 3_656 ?
C39 O12 Eu3 127.7(4) . 4_665 ?
C39 O12 Eu1 87.3(4) . 4_665 ?
Eu3 O12 Eu1 113.74(15) 4_665 4_665 ?
C39 O13 Eu1 100.4(4) . 4_665 ?
C45 O14 Eu1 137.4(4) . 3_766 ?
C45 O15 Eu1 143.6(4) . 1_655 ?
C51 O16 Eu2 128.5(4) . . ?
C51 O17 Eu3 165.1(4) . . ?
C63 O18 Eu2 159.5(5) . 4_665 ?
C63 O19 Eu3 123.0(4) . 4_665 ?
C69 O20 Eu2 149.2(4) . 2 ?
C69 O21 Eu3 137.4(4) . 2 ?
C57 O22 Eu3 104.0(4) . . ?
C57 O23 Eu1 134.8(4) . . ?
C57 O23 Eu3 85.2(4) . . ?
Eu1 O23 Eu3 111.90(16) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C1 N1 C3 -2(3) . . . . ?
O1 C1 N1 C2 175(2) . . . . ?
N1 C1 O1 Eu1 -153.2(16) . . . . ?
O1' C1' N1' C3' 166(5) . . . . ?
O1' C1' N1' C2' -13(8) . . . . ?
N1' C1' O1' Eu1 144(3) . . . . ?
N6 C16 C17 C18 -0.4(10) . . . . ?
C16 C17 C18 C19 -2.9(9) . . . . ?
C16 C17 C18 C21 178.6(6) . . . . ?
C17 C18 C19 C20 2.5(11) . . . . ?
C21 C18 C19 C20 -179.0(7) . . . . ?
C18 C19 C20 N6 1.1(13) . . . . ?
C19 C18 C21 O7 -28.9(9) . . . . ?
C17 C18 C21 O7 149.6(6) . . . . ?
C19 C18 C21 O6 149.7(7) . . . . ?
C17 C18 C21 O6 -31.9(9) . . . . ?
C19 C18 C21 Eu1 -35.1(18) . . . 2_645 ?
C17 C18 C21 Eu1 143.4(12) . . . 2_645 ?
N7 C22 C23 C24 0.5(13) . . . . ?
C22 C23 C24 C25 3.2(11) . . . . ?
C22 C23 C24 C27 -174.4(7) . . . . ?
C23 C24 C25 C26 -3.8(10) . . . . ?
C27 C24 C25 C26 173.8(6) . . . . ?
C24 C25 C26 N7 0.5(11) . . . . ?
C23 C24 C27 O8 0.2(9) . . . . ?
C25 C24 C27 O8 -177.3(6) . . . . ?
C23 C24 C27 O9 179.2(6) . . . . ?
C25 C24 C27 O9 1.7(9) . . . . ?
N8 C28 C29 C30 -1.3(10) . . . . ?
C28 C29 C30 C31 -2.5(9) . . . . ?
C28 C29 C30 C33 179.5(6) . . . . ?
C29 C30 C31 C32 3.7(9) . . . . ?
C33 C30 C31 C32 -178.4(6) . . . . ?
C30 C31 C32 N8 -1.1(10) . . . . ?
C31 C30 C33 O11 -161.9(6) . . . . ?
C29 C30 C33 O11 16.1(9) . . . . ?
C31 C30 C33 O10 15.6(9) . . . . ?
C29 C30 C33 O10 -166.5(6) . . . . ?
N9 C34 C35 C36 1.6(14) . . . . ?
C34 C35 C36 C37 -3.5(11) . . . . ?
C34 C35 C36 C39 175.6(7) . . . . ?
C35 C36 C37 C38 2.8(10) . . . . ?
C39 C36 C37 C38 -176.4(6) . . . . ?
C36 C37 C38 N9 0.1(11) . . . . ?
C35 C36 C39 O13 25.4(9) . . . . ?
C37 C36 C39 O13 -155.6(6) . . . . ?
C35 C36 C39 O12 -157.0(7) . . . . ?
C37 C36 C39 O12 22.0(9) . . . . ?
N10 C40 C41 C42 -0.7(12) . . . . ?
C40 C41 C42 C43 -3.7(12) . . . . ?
C40 C41 C42 C45 176.9(7) . . . . ?
C41 C42 C43 C44 6.3(14) . . . . ?
C45 C42 C43 C44 -174.3(9) . . . . ?
C42 C43 C44 N10 -4.9(17) . . . . ?
C43 C42 C45 O14 3.1(11) . . . . ?
C41 C42 C45 O14 -177.5(6) . . . . ?
C43 C42 C45 O15 -178.1(8) . . . . ?
C41 C42 C45 O15 1.3(9) . . . . ?
N11 C46 C47 C48 1.1(11) . . . . ?
C46 C47 C48 C49 2.7(9) . . . . ?
C46 C47 C48 C51 -178.7(6) . . . . ?
C47 C48 C49 C50 -3.9(10) . . . . ?
C51 C48 C49 C50 177.6(6) . . . . ?
C48 C49 C50 N11 1.3(11) . . . . ?
C49 C48 C51 O16 160.9(6) . . . . ?
C47 C48 C51 O16 -17.6(9) . . . . ?
C49 C48 C51 O17 -20.8(9) . . . . ?
C47 C48 C51 O17 160.7(6) . . . . ?
N14 C52 C53 C54 -1.5(11) . . . . ?
C52 C53 C54 C55 3.9(10) . . . . ?
C52 C53 C54 C57 -178.8(6) . . . . ?
C53 C54 C55 C56 -2.9(11) . . . . ?
C57 C54 C55 C56 179.7(7) . . . . ?
C54 C55 C56 N14 -0.6(14) . . . . ?
C55 C54 C57 O22 16.8(10) . . . . ?
C53 C54 C57 O22 -160.5(6) . . . . ?
C55 C54 C57 O23 -166.0(6) . . . . ?
C53 C54 C57 O23 16.7(9) . . . . ?
C55 C54 C57 Eu3 55(3) . . . . ?
C53 C54 C57 Eu3 -122(2) . . . . ?
N12 C58 C59 C60 3.5(11) . . . . ?
C58 C59 C60 C61 -0.5(10) . . . . ?
C58 C59 C60 C63 178.9(6) . . . . ?
C59 C60 C61 C62 -1.3(10) . . . . ?
C63 C60 C61 C62 179.3(6) . . . . ?
C60 C61 C62 N12 0.2(11) . . . . ?
C61 C60 C63 O18 -3.3(9) . . . . ?
C59 C60 C63 O18 177.4(6) . . . . ?
C61 C60 C63 O19 177.8(6) . . . . ?
C59 C60 C63 O19 -1.6(9) . . . . ?
C61 C60 C63 Eu3 -163.9(7) . . . 4_665 ?
C59 C60 C63 Eu3 16.7(13) . . . 4_665 ?
N13 C64 C65 C66 -0.7(11) . . . . ?
C64 C65 C66 C67 -0.6(10) . . . . ?
C64 C65 C66 C69 -179.6(6) . . . . ?
C65 C66 C67 C68 0.8(11) . . . . ?
C69 C66 C67 C68 179.7(7) . . . . ?
C66 C67 C68 N13 0.3(12) . . . . ?
C67 C66 C69 O20 179.0(6) . . . . ?
C65 C66 C69 O20 -2.1(9) . . . . ?
C67 C66 C69 O21 -0.5(9) . . . . ?
C65 C66 C69 O21 178.4(6) . . . . ?
O2 C4 N2 C5 176.3(8) . . . . ?
O2 C4 N2 C6 -1.7(13) . . . . ?
O3 C7 N3 C8 -172.1(8) . . . . ?
O3 C7 N3 C9 5.4(13) . . . . ?
O4 C10 N4 C11 -6.9(17) . . . . ?
O4 C10 N4 C12 178.6(10) . . . . ?
O5 C13 N5 C14 -1.8(19) . . . . ?
O5 C13 N5 C15 -175.4(11) . . . . ?
C17 C16 N6 C20 3.9(10) . . . . ?
C17 C16 N6 Cu1 -172.0(5) . . . . ?
C19 C20 N6 C16 -4.3(11) . . . . ?
C19 C20 N6 Cu1 171.5(6) . . . . ?
C25 C26 N7 C22 3.1(11) . . . . ?
C25 C26 N7 Cu3 -175.9(5) . . . . ?
C23 C22 N7 C26 -3.6(12) . . . . ?
C23 C22 N7 Cu3 175.4(6) . . . . ?
C31 C32 N8 C28 -2.6(10) . . . . ?
C31 C32 N8 Cu2 169.3(5) . . . . ?
C29 C28 N8 C32 3.8(10) . . . . ?
C29 C28 N8 Cu2 -167.6(5) . . . . ?
C35 C34 N9 C38 1.3(13) . . . . ?
C35 C34 N9 Cu7 -173.6(7) . . . . ?
C37 C38 N9 C34 -2.1(11) . . . . ?
C37 C38 N9 Cu7 172.7(5) . . . . ?
C41 C40 N10 C44 2.4(12) . . . . ?
C41 C40 N10 Cu8 -176.0(6) . . . . ?
C43 C44 N10 C40 0.4(15) . . . . ?
C43 C44 N10 Cu8 178.8(9) . . . . ?
C49 C50 N11 C46 2.5(10) . . . . ?
C49 C50 N11 Cu5 -174.7(6) . . . . ?
C47 C46 N11 C50 -3.6(10) . . . . ?
C47 C46 N11 Cu5 173.2(5) . . . . ?
C61 C62 N12 C58 2.6(11) . . . . ?
C61 C62 N12 Cu11 177.6(6) . . . . ?
C59 C58 N12 C62 -4.4(10) . . . . ?
C59 C58 N12 Cu11 -179.1(5) . . . . ?
C67 C68 N13 C64 -1.6(11) . . . . ?
C67 C68 N13 Cu10 177.4(6) . . . . ?
C65 C64 N13 C68 1.8(10) . . . . ?
C65 C64 N13 Cu10 -177.2(5) . . . . ?
C55 C56 N14 C52 3.1(13) . . . . ?
C55 C56 N14 Cu9 -170.3(7) . . . . ?
C53 C52 N14 C56 -2.0(11) . . . . ?
C53 C52 N14 Cu9 171.5(5) . . . . ?
N2 C4 O2 Eu2 -165.0(6) . . . . ?
N3 C7 O3 Eu2 -136.9(7) . . . . ?
N4 C10 O4 Eu3 154.7(7) . . . . ?
O7 C21 O6 Eu1 92(3) . . . 4_665 ?
C18 C21 O6 Eu1 -87(3) . . . 4_665 ?
Eu1 C21 O6 Eu1 95(3) 2_645 . . 4_665 ?
O7 C21 O6 Eu1 -2.9(6) . . . 2_645 ?
C18 C21 O6 Eu1 178.6(6) . . . 2_645 ?
O6 C21 O7 Eu1 4.1(8) . . . 2_645 ?
C18 C21 O7 Eu1 -177.4(4) . . . 2_645 ?
O9 C27 O8 Eu2 5.4(12) . . . 4_565 ?
C24 C27 O8 Eu2 -175.7(5) . . . 4_565 ?
O8 C27 O9 Eu3 24.0(10) . . . 4_565 ?
C24 C27 O9 Eu3 -154.9(4) . . . 4_565 ?
O11 C33 O10 Eu2 -92.0(8) . . . . ?
C30 C33 O10 Eu2 90.8(7) . . . . ?
O10 C33 O11 Eu2 3.5(17) . . . 3_656 ?
C30 C33 O11 Eu2 -179.4(9) . . . 3_656 ?
O13 C39 O12 Eu3 -116.8(6) . . . 4_665 ?
C36 C39 O12 Eu3 65.7(7) . . . 4_665 ?
Eu1 C39 O12 Eu3 -118.2(4) 4_665 . . 4_665 ?
O13 C39 O12 Eu1 1.5(6) . . . 4_665 ?
C36 C39 O12 Eu1 -176.0(5) . . . 4_665 ?
O12 C39 O13 Eu1 -1.7(7) . . . 4_665 ?
C36 C39 O13 Eu1 175.9(5) . . . 4_665 ?
O15 C45 O14 Eu1 -10.0(11) . . . 3_766 ?
C42 C45 O14 Eu1 168.8(4) . . . 3_766 ?
O14 C45 O15 Eu1 29.4(12) . . . 1_655 ?
C42 C45 O15 Eu1 -149.3(5) . . . 1_655 ?
O17 C51 O16 Eu2 -1.9(9) . . . . ?
C48 C51 O16 Eu2 176.2(4) . . . . ?
O16 C51 O17 Eu3 17(2) . . . . ?
C48 C51 O17 Eu3 -161.5(14) . . . . ?
O19 C63 O18 Eu2 76.8(15) . . . 4_665 ?
C60 C63 O18 Eu2 -102.1(13) . . . 4_665 ?
Eu3 C63 O18 Eu2 69.6(13) 4_665 . . 4_665 ?
O18 C63 O19 Eu3 -11.6(9) . . . 4_665 ?
C60 C63 O19 Eu3 167.2(4) . . . 4_665 ?
O21 C69 O20 Eu2 31.9(13) . . . 2 ?
C66 C69 O20 Eu2 -147.6(6) . . . 2 ?
O20 C69 O21 Eu3 -11.2(11) . . . 2 ?
C66 C69 O21 Eu3 168.2(4) . . . 2 ?
O23 C57 O22 Eu3 -6.3(7) . . . . ?
C54 C57 O22 Eu3 170.9(5) . . . . ?
O22 C57 O23 Eu1 -111.1(6) . . . . ?
C54 C57 O23 Eu1 71.8(8) . . . . ?
Eu3 C57 O23 Eu1 -116.4(5) . . . . ?
O22 C57 O23 Eu3 5.3(6) . . . . ?
C54 C57 O23 Eu3 -171.9(5) . . . . ?

_refine_diff_density_max         1.409
_refine_diff_density_min         -1.231
_refine_diff_density_rms         0.174

_shelxl_version_number           2013-2

