# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_082216a_beyond
_database_code_depnum_ccdc_archive 'CCDC 1982872'
loop_
_audit_author_name
_audit_author_address
'Xin Lian'
;Shantou University
China
;
_audit_update_record             
;
2020-10-10 deposited with the CCDC.	2020-10-13 downloaded from the CCDC.
;
_audit_creation_date             2020-10-07
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '2(C18 H14 Cl N3 O2 Os), 3(C H2 Cl2)'
_chemical_formula_sum            'C39 H34 Cl8 N6 O4 Os2'
_chemical_formula_weight         1314.72
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -4.9801 6.2216 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.1575(3)
_cell_length_b                   12.0799(5)
_cell_length_c                   12.5607(5)
_cell_angle_alpha                78.544(3)
_cell_angle_beta                 87.869(3)
_cell_angle_gamma                84.639(3)
_cell_volume                     1059.54(8)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    4202
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      71.6790
_cell_measurement_theta_min      10.1580
_shelx_estimated_absorpt_T_max   0.140
_shelx_estimated_absorpt_T_min   0.038
_exptl_absorpt_coefficient_mu    16.205
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.22152
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.35h (release 09-02-2015 CrysAlis171 .NET)
(compiled Feb  9 2015,16:26:32)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear reddish violet'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   reddish
_exptl_crystal_colour_primary    violet
_exptl_crystal_density_diffrn    2.060
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             630
_exptl_crystal_size_max          0.58
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0451
_diffrn_reflns_av_unetI/netI     0.0391
_diffrn_reflns_Laue_measured_fraction_full 0.974
_diffrn_reflns_Laue_measured_fraction_max 0.953
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            6725
_diffrn_reflns_point_group_measured_fraction_full 0.974
_diffrn_reflns_point_group_measured_fraction_max 0.953
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         71.451
_diffrn_reflns_theta_min         3.748
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   'Enhance Ultra (Cu) X-ray Source'
_diffrn_special_details          ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3877
_reflns_number_total             3935
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         1.973
_refine_diff_density_min         -3.151
_refine_diff_density_rms         0.217
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.066
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         3935
_refine_ls_number_restraints     357
_refine_ls_R_factor_all          0.0431
_refine_ls_R_factor_gt           0.0427
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0718P)²+6.0237P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1097
_refine_ls_wR_factor_ref         0.1103
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 C5-C4 = C4-C3 = C3-C2 = C2-C1
 1.39 with sigma of 0.02
 C5-N1 = C1-N1
 1.35 with sigma of 0.02
3. Rigid bond restraints
 N1, C5, C4, C3, C2, C1, N1B, C5B, C4B, C3B, C2B, C1B
 with sigma for 1-2 distances of 0.008 and sigma for 1-3 distances of 0.008
4. Uiso/Uaniso restraints and constraints
N1 \\sim C5 \\sim C4 \\sim C3 \\sim C2 \\sim C1 \\sim N1B \\sim C5B \\sim C4B
\\sim C3B \\sim C2B \\sim C1B: within 2A with sigma of 0.02 and sigma for
terminal atoms of 0.04
O2 \\sim C18 \\sim C17 \\sim C16 \\sim C15 \\sim C14 \\sim C13: within 1.7A
with sigma of 0.02 and sigma for terminal atoms of 0.04
Uanis(O2) \\sim Ueq, Uanis(C18) \\sim Ueq, Uanis(C17) \\sim Ueq, Uanis(C16)
\\sim Ueq, Uanis(C15) \\sim Ueq, Uanis(C14) \\sim Ueq, Uanis(C13) \\sim Ueq:
with sigma of 0.04 and sigma for terminal atoms of 0.12
5. Rigid body (RIGU) restrains
 O2, C18, C13, C14, C15, C16, C17
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
6. Same fragment restrains
{N1, C5, C4, C3, C2, C1} sigma for 1-2: 0.02, 1-3: 0.04
as
{N1B, C5B, C4B, C3B, C2B, C1B}
7. Others
 Sof(N1B)=Sof(C5B)=Sof(H5B)=Sof(C4B)=Sof(H4B)=Sof(C3B)=Sof(H3B)=Sof(C2B)=
 Sof(H2B)=Sof(C1B)=Sof(H1B)=1-FVAR(1)
 Sof(N1)=Sof(C5)=Sof(H5)=Sof(C4)=Sof(H4)=Sof(C3)=Sof(H3)=Sof(C2)=Sof(H2)=
 Sof(C1)=Sof(H1)=FVAR(1)
 Fixed Sof: Cl4(0.5) Cl5(0.5) C20(0.5) H20A(0.5) H20B(0.5)
8.a Secondary CH2 refined with riding coordinates:
 C19(H19A,H19B), C20(H20A,H20B)
8.b Aromatic/amide H refined with riding coordinates:
 C7(H7), C8(H8), C9(H9), C10(H10), C12(H12), C14(H14), C15(H15), C16(H16),
 C17(H17), C5(H5), C4(H4), C3(H3), C2(H2), C1(H1), C5B(H5B), C4B(H4B), C3B(H3B),
  C2B(H2B), C1B(H1B)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.54621(3) 0.68962(2) 0.61042(2) 0.01488(12) Uani 1 1 d . . . . .
Cl1 Cl 0.8424(2) 0.80337(12) 0.57291(11) 0.0201(3) Uani 1 1 d . . . . .
O1 O 0.5774(6) 0.6825(4) 0.4523(3) 0.0221(9) Uani 1 1 d . . . . .
N3 N 0.3683(7) 0.6118(5) 0.6414(4) 0.0201(10) Uani 1 1 d . . . . .
N2 N 0.4014(7) 0.8457(5) 0.5854(4) 0.0202(11) Uani 1 1 d . . . . .
O2 O 0.5708(7) 0.7291(4) 0.7582(3) 0.0210(9) Uani 1 1 d . U . . .
C6 C 0.4686(8) 0.7507(5) 0.3772(5) 0.0168(11) Uani 1 1 d . . . . .
C7 C 0.4721(9) 0.7221(5) 0.2750(5) 0.0178(12) Uani 1 1 d . . . . .
H7 H 0.549057 0.657240 0.262553 0.021 Uiso 1 1 calc R . . . .
C8 C 0.3664(9) 0.7860(6) 0.1918(5) 0.0222(13) Uani 1 1 d . . . . .
H8 H 0.370692 0.764646 0.122795 0.027 Uiso 1 1 calc R . . . .
C9 C 0.2523(10) 0.8823(6) 0.2078(5) 0.0241(13) Uani 1 1 d . . . . .
H9 H 0.177887 0.925749 0.150591 0.029 Uiso 1 1 calc R . . . .
C10 C 0.2496(9) 0.9127(6) 0.3067(5) 0.0236(13) Uani 1 1 d . . . . .
H10 H 0.175330 0.979390 0.316779 0.028 Uiso 1 1 calc R . . . .
C11 C 0.3537(9) 0.8484(6) 0.3946(5) 0.0197(12) Uani 1 1 d . . . . .
C12 C 0.3312(10) 0.8943(6) 0.4909(5) 0.0240(13) Uani 1 1 d . . . . .
H12 H 0.260006 0.965464 0.486221 0.029 Uiso 1 1 calc R . . . .
C13 C 0.3765(9) 0.8942(5) 0.6795(5) 0.0185(10) Uani 1 1 d . U . . .
C14 C 0.2757(9) 0.9957(5) 0.6913(5) 0.0212(11) Uani 1 1 d . U . . .
H14 H 0.212754 1.042384 0.631035 0.025 Uiso 1 1 calc R . . . .
C15 C 0.2678(9) 1.0281(5) 0.7904(5) 0.0204(11) Uani 1 1 d . U . . .
H15 H 0.200114 1.097612 0.798281 0.025 Uiso 1 1 calc R . . . .
C16 C 0.3590(9) 0.9592(5) 0.8798(5) 0.0187(10) Uani 1 1 d . U . . .
H16 H 0.350898 0.981220 0.948402 0.022 Uiso 1 1 calc R . . . .
C17 C 0.4607(8) 0.8590(5) 0.8682(5) 0.0182(10) Uani 1 1 d . U . . .
H17 H 0.523972 0.813056 0.928770 0.022 Uiso 1 1 calc R . . . .
C18 C 0.4710(8) 0.8252(5) 0.7685(5) 0.0173(10) Uani 1 1 d . U . . .
N1 N 0.756(2) 0.5527(13) 0.6365(12) 0.015(3) Uani 0.66(3) 1 d D U P A 1
C5 C 0.769(3) 0.4818(16) 0.5650(14) 0.015(2) Uani 0.66(3) 1 d D U P A 1
H5 H 0.688317 0.497149 0.504635 0.018 Uiso 0.66(3) 1 calc R . P A 1
C4 C 0.898(2) 0.3877(12) 0.5775(13) 0.016(2) Uani 0.66(3) 1 d D U P A 1
H4 H 0.910248 0.340944 0.524664 0.020 Uiso 0.66(3) 1 calc R . P A 1
C3 C 1.0106(18) 0.3628(10) 0.6686(14) 0.020(3) Uani 0.66(3) 1 d D U P A 1
H3 H 1.098420 0.297733 0.679486 0.024 Uiso 0.66(3) 1 calc R . P A 1
C2 C 0.9934(19) 0.4334(11) 0.7436(14) 0.027(3) Uani 0.66(3) 1 d D U P A 1
H2 H 1.068820 0.417431 0.806372 0.032 Uiso 0.66(3) 1 calc R . P A 1
C1 C 0.863(2) 0.5287(10) 0.7253(13) 0.022(3) Uani 0.66(3) 1 d D U P A 1
H1 H 0.849720 0.577260 0.776476 0.026 Uiso 0.66(3) 1 calc R . P A 1
N1B N 0.731(5) 0.544(3) 0.652(2) 0.016(4) Uani 0.34(3) 1 d D U P A 2
C5B C 0.798(6) 0.479(4) 0.580(3) 0.016(4) Uani 0.34(3) 1 d D U P A 2
H5B H 0.754463 0.497256 0.507832 0.020 Uiso 0.34(3) 1 calc R . P A 2
C4B C 0.930(4) 0.387(2) 0.609(2) 0.018(4) Uani 0.34(3) 1 d D U P A 2
H4B H 0.964974 0.338201 0.559181 0.022 Uiso 0.34(3) 1 calc R . P A 2
C3B C 1.009(4) 0.367(2) 0.710(3) 0.019(4) Uani 0.34(3) 1 d D U P A 2
H3B H 1.103371 0.306229 0.730561 0.023 Uiso 0.34(3) 1 calc R . P A 2
C2B C 0.947(4) 0.437(2) 0.782(2) 0.023(4) Uani 0.34(3) 1 d D U P A 2
H2B H 1.002320 0.426074 0.851229 0.027 Uiso 0.34(3) 1 calc R . P A 2
C1B C 0.805(4) 0.5231(19) 0.752(2) 0.018(4) Uani 0.34(3) 1 d D U P A 2
H1B H 0.759102 0.568268 0.802752 0.021 Uiso 0.34(3) 1 calc R . P A 2
Cl3 Cl -0.0770(3) 0.8340(2) 0.99366(17) 0.0442(5) Uani 1 1 d . . . . .
Cl2 Cl 0.1048(3) 0.65545(19) 0.8934(2) 0.0558(6) Uani 1 1 d . . . . .
C19 C -0.0243(10) 0.7888(6) 0.8702(6) 0.0279(14) Uani 1 1 d . . . . .
H19A H -0.142305 0.784116 0.833267 0.034 Uiso 1 1 calc R . . . .
H19B H 0.049251 0.844777 0.822055 0.034 Uiso 1 1 calc R . . . .
Cl4 Cl 0.3619(10) 0.4127(6) 0.9647(5) 0.0407(14) Uani 0.5 1 d . . P B -1
Cl5 Cl 0.5684(11) 0.5634(6) 1.0604(7) 0.0538(17) Uani 0.5 1 d . . P B -1
C20 C 0.547(3) 0.5017(14) 0.9445(12) 0.038(4) Uani 0.5 1 d . . P B -1
H20A H 0.522302 0.562290 0.879657 0.046 Uiso 0.5 1 calc R . P B -1
H20B H 0.665810 0.457107 0.931453 0.046 Uiso 0.5 1 calc R . P B -1


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Os1 Cl1 2.6109(14) . ?
Os1 O1 2.008(4) . ?
Os1 N3 1.642(5) . ?
Os1 N2 2.038(5) . ?
Os1 O2 2.024(4) . ?
Os1 N1 2.110(12) . ?
Os1 N1B 2.09(2) . ?
O1 C6 1.343(8) . ?
N2 C12 1.311(9) . ?
N2 C13 1.418(8) . ?
O2 C18 1.332(7) . ?
C6 C7 1.392(8) . ?
C6 C11 1.423(9) . ?
C7 H7 0.9500 . ?
C7 C8 1.375(9) . ?
C8 H8 0.9500 . ?
C8 C9 1.402(10) . ?
C9 H9 0.9500 . ?
C9 C10 1.362(9) . ?
C10 H10 0.9500 . ?
C10 C11 1.410(9) . ?
C11 C12 1.425(9) . ?
C12 H12 0.9500 . ?
C13 C14 1.395(9) . ?
C13 C18 1.408(9) . ?
C14 H14 0.9500 . ?
C14 C15 1.374(9) . ?
C15 H15 0.9500 . ?
C15 C16 1.401(9) . ?
C16 H16 0.9500 . ?
C16 C17 1.383(9) . ?
C17 H17 0.9500 . ?
C17 C18 1.389(8) . ?
N1 C5 1.353(11) . ?
N1 C1 1.345(10) . ?
C5 H5 0.9500 . ?
C5 C4 1.383(11) . ?
C4 H4 0.9500 . ?
C4 C3 1.390(12) . ?
C3 H3 0.9500 . ?
C3 C2 1.386(13) . ?
C2 H2 0.9500 . ?
C2 C1 1.400(11) . ?
C1 H1 0.9500 . ?
N1B C5B 1.355(17) . ?
N1B C1B 1.349(16) . ?
C5B H5B 0.9500 . ?
C5B C4B 1.385(17) . ?
C4B H4B 0.9500 . ?
C4B C3B 1.38(2) . ?
C3B H3B 0.9500 . ?
C3B C2B 1.39(2) . ?
C2B H2B 0.9500 . ?
C2B C1B 1.394(17) . ?
C1B H1B 0.9500 . ?
Cl3 C19 1.760(7) . ?
Cl2 C19 1.758(7) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
Cl4 C20 1.762(18) . ?
Cl5 C20 1.780(17) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Os1 Cl1 83.33(14) . . ?
O1 Os1 N2 95.4(2) . . ?
O1 Os1 O2 163.5(2) . . ?
O1 Os1 N1 85.7(4) . . ?
O1 Os1 N1B 90.6(8) . . ?
N3 Os1 Cl1 175.76(19) . . ?
N3 Os1 O1 99.2(2) . . ?
N3 Os1 N2 98.7(2) . . ?
N3 Os1 O2 97.2(2) . . ?
N3 Os1 N1 95.7(6) . . ?
N3 Os1 N1B 89.4(12) . . ?
N2 Os1 Cl1 84.46(16) . . ?
N2 Os1 N1 165.2(5) . . ?
N2 Os1 N1B 169.0(10) . . ?
O2 Os1 Cl1 80.45(14) . . ?
O2 Os1 N2 80.10(19) . . ?
O2 Os1 N1 94.7(4) . . ?
O2 Os1 N1B 91.6(8) . . ?
N1 Os1 Cl1 81.0(5) . . ?
N1B Os1 Cl1 87.1(12) . . ?
C6 O1 Os1 121.1(4) . . ?
C12 N2 Os1 122.3(5) . . ?
C12 N2 C13 123.3(6) . . ?
C13 N2 Os1 114.4(4) . . ?
C18 O2 Os1 112.9(4) . . ?
O1 C6 C7 116.2(6) . . ?
O1 C6 C11 124.9(5) . . ?
C7 C6 C11 118.9(6) . . ?
C6 C7 H7 119.4 . . ?
C8 C7 C6 121.2(6) . . ?
C8 C7 H7 119.4 . . ?
C7 C8 H8 119.7 . . ?
C7 C8 C9 120.5(6) . . ?
C9 C8 H8 119.7 . . ?
C8 C9 H9 120.5 . . ?
C10 C9 C8 119.1(6) . . ?
C10 C9 H9 120.5 . . ?
C9 C10 H10 119.0 . . ?
C9 C10 C11 122.1(6) . . ?
C11 C10 H10 119.0 . . ?
C6 C11 C12 128.4(6) . . ?
C10 C11 C6 118.2(5) . . ?
C10 C11 C12 113.3(6) . . ?
N2 C12 C11 124.9(6) . . ?
N2 C12 H12 117.5 . . ?
C11 C12 H12 117.5 . . ?
C14 C13 N2 128.6(6) . . ?
C14 C13 C18 120.2(5) . . ?
C18 C13 N2 111.2(5) . . ?
C13 C14 H14 120.1 . . ?
C15 C14 C13 119.8(6) . . ?
C15 C14 H14 120.1 . . ?
C14 C15 H15 119.8 . . ?
C14 C15 C16 120.3(6) . . ?
C16 C15 H15 119.8 . . ?
C15 C16 H16 120.0 . . ?
C17 C16 C15 120.1(5) . . ?
C17 C16 H16 120.0 . . ?
C16 C17 H17 119.8 . . ?
C16 C17 C18 120.4(6) . . ?
C18 C17 H17 119.8 . . ?
O2 C18 C13 121.0(5) . . ?
O2 C18 C17 119.8(5) . . ?
C17 C18 C13 119.2(6) . . ?
C5 N1 Os1 117.6(9) . . ?
C1 N1 Os1 122.4(9) . . ?
C1 N1 C5 119.7(10) . . ?
N1 C5 H5 119.2 . . ?
N1 C5 C4 121.7(10) . . ?
C4 C5 H5 119.2 . . ?
C5 C4 H4 120.6 . . ?
C5 C4 C3 118.9(9) . . ?
C3 C4 H4 120.6 . . ?
C4 C3 H3 120.2 . . ?
C2 C3 C4 119.5(9) . . ?
C2 C3 H3 120.2 . . ?
C3 C2 H2 120.6 . . ?
C3 C2 C1 118.9(10) . . ?
C1 C2 H2 120.6 . . ?
N1 C1 C2 121.2(10) . . ?
N1 C1 H1 119.4 . . ?
C2 C1 H1 119.4 . . ?
C5B N1B Os1 123.7(17) . . ?
C1B N1B Os1 117.0(18) . . ?
C1B N1B C5B 118.6(17) . . ?
N1B C5B H5B 118.9 . . ?
N1B C5B C4B 122.2(19) . . ?
C4B C5B H5B 118.9 . . ?
C5B C4B H4B 120.4 . . ?
C3B C4B C5B 119.2(16) . . ?
C3B C4B H4B 120.4 . . ?
C4B C3B H3B 120.8 . . ?
C4B C3B C2B 118.5(15) . . ?
C2B C3B H3B 120.8 . . ?
C3B C2B H2B 120.0 . . ?
C3B C2B C1B 120.0(16) . . ?
C1B C2B H2B 120.0 . . ?
N1B C1B C2B 121.2(17) . . ?
N1B C1B H1B 119.4 . . ?
C2B C1B H1B 119.4 . . ?
Cl3 C19 H19A 109.5 . . ?
Cl3 C19 H19B 109.5 . . ?
Cl2 C19 Cl3 110.5(4) . . ?
Cl2 C19 H19A 109.5 . . ?
Cl2 C19 H19B 109.5 . . ?
H19A C19 H19B 108.1 . . ?
Cl4 C20 Cl5 110.3(9) . . ?
Cl4 C20 H20A 109.6 . . ?
Cl4 C20 H20B 109.6 . . ?
Cl5 C20 H20A 109.6 . . ?
Cl5 C20 H20B 109.6 . . ?
H20A C20 H20B 108.1 . . ?

_olex2_submission_special_instructions 'No special instructions were received'

# start Validation Reply Form
_vrf_PLAT972_082216a_beyond      
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PROBLEM: Check Calcd Resid. Dens.  0.80A   From Os1            -3.11 eA-3  
RESPONSE: Shadow peaks in the final difference Fourier map near Os.
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# end Validation Reply Form
