# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 1970633'
loop_
_audit_author_name
_audit_author_address
'SUDIP KUMAR BERA'
;Department of Chemistry, IIT Bombay
India
;
_audit_update_record             
;
2019-12-07 deposited with the CCDC.	2020-09-03 downloaded from the CCDC.
;
_audit_creation_date             2019-05-20
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C36 H51 O20 Ru4'
_chemical_formula_sum            'C36 H51 O20 Ru4'
_chemical_formula_weight         1208.04
_chemical_melting_point          ?
_chemical_oxdiff_formula         CHORu
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.8572(3)
_cell_length_b                   13.8306(3)
_cell_length_c                   14.3293(3)
_cell_angle_alpha                74.4373(18)
_cell_angle_beta                 89.4963(17)
_cell_angle_gamma                80.0332(19)
_cell_volume                     2227.82(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    16388
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.1830
_cell_measurement_theta_min      2.2800
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.405
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.75553
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.39.46 (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'metallic greenish green'
_exptl_crystal_colour_lustre     metallic
_exptl_crystal_colour_modifier   greenish
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.801
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1206
_exptl_crystal_size_max          0.161
_exptl_crystal_size_mid          0.036
_exptl_crystal_size_min          0.033
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0760
_diffrn_reflns_av_unetI/netI     0.0538
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            36439
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        24.998
_diffrn_reflns_theta_max         24.998
_diffrn_reflns_theta_min         2.330
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -110.00  70.00   0.50    8.00    --  -20.00   0.00-108.00  360
  2  ω    -70.00  19.00   0.50    8.00    --  -20.00 -72.00  36.00  178
  3  ω    -87.00   4.00   0.50    8.00    --  -20.00 -72.00-108.00  182
  4  ω    -44.50   2.00   0.50    8.00    --  -20.00  72.00-180.00   93
  5  ω    -59.00 -28.50   0.50    8.00    --  -20.00  72.00  36.00   61
  6  ω    -22.00   8.00   0.50    8.00    --  -20.00 -72.00 108.00   60
  7  ω   -110.00  70.00   0.50    8.00    --  -20.00   0.00-180.00  360
  8  ω    -67.50   8.00   0.50    8.00    --  -20.00 -72.00 -36.00  151
  9  ω    -81.00   5.00   0.50    8.00    --  -20.00 -72.00-180.00  172
 10  ω    -58.50  -1.50   0.50    8.00    --  -20.00  72.00 108.00  114
;
_diffrn_measurement_device       'abstract diffractometer'
_diffrn_measurement_device_type  
'dtrek-CrysAlisPro-abstract goniometer imported rigaku-d*trek images'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0265494000
_diffrn_orient_matrix_UB_12      0.0278774000
_diffrn_orient_matrix_UB_13      -0.0457247000
_diffrn_orient_matrix_UB_21      -0.0326200000
_diffrn_orient_matrix_UB_22      -0.0388496000
_diffrn_orient_matrix_UB_23      0.0018548000
_diffrn_orient_matrix_UB_31      -0.0438843000
_diffrn_orient_matrix_UB_32      0.0252906000
_diffrn_orient_matrix_UB_33      0.0234580000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                6451
_reflns_number_total             7823
_reflns_odcompleteness_completeness 91.10
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     31.16
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         0.741
_refine_diff_density_min         -0.759
_refine_diff_density_rms         0.135
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     556
_refine_ls_number_reflns         7823
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0582
_refine_ls_R_factor_gt           0.0438
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0405P)²+2.6351P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0910
_refine_ls_wR_factor_ref         0.0990
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C13(H13), C18(H18), C28(H28), C3(H3), C23(H23), C8(H8)
2.b Idealised Me refined as rotating group:
 C5(H5A,H5B,H5C), C11(H11A,H11B,H11C), C20(H20A,H20B,H20C), C30(H30A,H30B,
 H30C), C1(H1A,H1B,H1C), C15(H15A,H15B,H15C), C10(H10A,H10B,H10C), C32(H32A,
 H32B,H32C), C34(H34A,H34B,H34C), C21(H21A,H21B,H21C), C25(H25A,H25B,H25C),
 C16(H16A,H16B,H16C), C6(H6A,H6B,H6C), C26(H26A,H26B,H26C), C36(H36A,H36B,H36C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.70509(3) 0.77990(3) 0.47590(3) 0.02205(11) Uani 1 1 d . . . . .
Ru2 Ru 0.67503(3) 0.64371(3) 0.30615(3) 0.02231(11) Uani 1 1 d . . . . .
Ru3 Ru 0.74491(3) 0.80335(3) 0.21451(3) 0.02224(11) Uani 1 1 d . . . . .
Ru4 Ru 0.74210(4) 0.65367(3) 0.05228(3) 0.02759(12) Uani 1 1 d . . . . .
O14 O 0.6259(3) 0.5215(3) 0.2797(2) 0.0307(8) Uani 1 1 d . . . . .
O16 O 0.7644(3) 0.9388(3) 0.2326(2) 0.0274(8) Uani 1 1 d . . . . .
O13 O 0.8322(3) 0.5683(3) 0.3544(2) 0.0282(8) Uani 1 1 d . . . . .
O10 O 0.6759(3) 0.9320(2) 0.4231(2) 0.0254(8) Uani 1 1 d . . . . .
O4 O 0.6210(3) 0.5794(3) 0.4394(2) 0.0257(8) Uani 1 1 d . . . . .
O9 O 0.5394(3) 0.7685(3) 0.4852(2) 0.0267(8) Uani 1 1 d . . . . .
O20 O 0.8480(3) 0.5211(3) 0.1175(3) 0.0347(9) Uani 1 1 d . . . . .
O3 O 0.7307(3) 0.6242(3) 0.5429(2) 0.0262(8) Uani 1 1 d . . . . .
O5 O 0.5115(3) 0.7236(3) 0.2614(2) 0.0278(8) Uani 1 1 d . . . . .
O12 O 0.8728(3) 0.7931(3) 0.4693(2) 0.0269(8) Uani 1 1 d . . . . .
O6 O 0.5749(3) 0.8648(3) 0.1784(2) 0.0281(8) Uani 1 1 d . . . . .
O2 O 0.7223(3) 0.6855(2) 0.1735(2) 0.0247(8) Uani 1 1 d . . . . .
O1 O 0.7066(3) 0.7580(2) 0.3500(2) 0.0212(7) Uani 1 1 d . . . . .
O18 O 0.6160(3) 0.5728(3) 0.0752(2) 0.0343(9) Uani 1 1 d . . . . .
O7 O 0.7940(3) 0.8696(3) 0.0783(2) 0.0300(8) Uani 1 1 d . . . . .
O17 O 0.6417(3) 0.7833(3) -0.0187(2) 0.0363(9) Uani 1 1 d . . . . .
O11 O 0.7006(3) 0.7970(3) 0.6110(2) 0.0269(8) Uani 1 1 d . . . . .
O19 O 0.7661(3) 0.6268(3) -0.0774(2) 0.0367(9) Uani 1 1 d . . . . .
O15 O 0.9110(3) 0.7436(3) 0.2432(2) 0.0286(8) Uani 1 1 d . . . . .
O8 O 0.8726(3) 0.7375(3) 0.0208(2) 0.0341(9) Uani 1 1 d . . . . .
C19 C 0.8620(5) 0.9628(4) 0.2405(4) 0.0317(12) Uani 1 1 d . . . . .
C13 C 0.7979(5) 0.4074(4) 0.3463(4) 0.0397(14) Uani 1 1 d . . . . .
H13 H 0.830543 0.338576 0.363662 0.048 Uiso 1 1 calc R . . . .
C12 C 0.8641(5) 0.4726(4) 0.3665(4) 0.0355(13) Uani 1 1 d . . . . .
C5 C 0.5735(5) 1.0922(4) 0.3481(4) 0.0343(13) Uani 1 1 d . . . . .
H5A H 0.629497 1.115851 0.380248 0.051 Uiso 1 1 calc GR . . . .
H5B H 0.498669 1.129527 0.353650 0.051 Uiso 1 1 calc GR . . . .
H5C H 0.590398 1.102479 0.280916 0.051 Uiso 1 1 calc GR . . . .
C4 C 0.5763(4) 0.9819(4) 0.3940(3) 0.0265(11) Uani 1 1 d . . . . .
C31 C 0.6698(4) 0.5671(4) 0.5209(3) 0.0224(11) Uani 1 1 d . . . . .
C29 C 0.8819(5) 0.4510(4) 0.0771(4) 0.0356(13) Uani 1 1 d . . . . .
C11 C 0.9852(5) 0.4340(4) 0.4056(4) 0.0443(16) Uani 1 1 d . . . . .
H11A H 1.027154 0.489284 0.391263 0.066 Uiso 1 1 calc GR . . . .
H11B H 1.020526 0.382318 0.375954 0.066 Uiso 1 1 calc GR . . . .
H11C H 0.985298 0.405533 0.474489 0.066 Uiso 1 1 calc GR . . . .
C33 C 0.4966(5) 0.8146(4) 0.2088(4) 0.0313(12) Uani 1 1 d . . . . .
C14 C 0.6885(5) 0.4318(4) 0.3033(4) 0.0369(14) Uani 1 1 d . . . . .
C18 C 0.9684(5) 0.8992(4) 0.2464(4) 0.0355(13) Uani 1 1 d . . . . .
H18 H 1.032938 0.929045 0.246316 0.043 Uiso 1 1 calc R . . . .
C2 C 0.4606(4) 0.8434(4) 0.4445(4) 0.0279(12) Uani 1 1 d . . . . .
C28 C 0.8691(5) 0.4586(5) -0.0215(4) 0.0418(15) Uani 1 1 d . . . . .
H28 H 0.898495 0.400798 -0.041240 0.050 Uiso 1 1 calc R . . . .
C20 C 0.8577(5) 1.0692(4) 0.2476(4) 0.0432(15) Uani 1 1 d . . . . .
H20A H 0.812238 1.116299 0.194036 0.065 Uiso 1 1 calc GR . . . .
H20B H 0.933987 1.083971 0.246132 0.065 Uiso 1 1 calc GR . . . .
H20C H 0.824083 1.075794 0.307324 0.065 Uiso 1 1 calc GR . . . .
C30 C 0.9420(5) 0.3519(4) 0.1428(4) 0.0464(16) Uani 1 1 d . . . . .
H30A H 0.967278 0.363222 0.201848 0.070 Uiso 1 1 calc GR . . . .
H30B H 1.006920 0.324932 0.111277 0.070 Uiso 1 1 calc GR . . . .
H30C H 0.890099 0.304187 0.157404 0.070 Uiso 1 1 calc GR . . . .
C1 C 0.3443(4) 0.8161(5) 0.4466(4) 0.0394(14) Uani 1 1 d . . . . .
H1A H 0.337569 0.779921 0.398960 0.059 Uiso 1 1 calc GR . . . .
H1B H 0.287485 0.877188 0.432454 0.059 Uiso 1 1 calc GR . . . .
H1C H 0.332901 0.773725 0.509746 0.059 Uiso 1 1 calc GR . . . .
C15 C 0.6338(6) 0.3519(5) 0.2778(5) 0.0593(19) Uani 1 1 d . . . . .
H15A H 0.563349 0.346970 0.310844 0.089 Uiso 1 1 calc GR . . . .
H15B H 0.684678 0.287383 0.297251 0.089 Uiso 1 1 calc GR . . . .
H15C H 0.618265 0.370243 0.209090 0.089 Uiso 1 1 calc GR . . . .
C10 C 1.0394(5) 0.8526(5) 0.4949(4) 0.0416(14) Uani 1 1 d . . . . .
H10A H 1.082619 0.794963 0.477634 0.062 Uiso 1 1 calc GR . . . .
H10B H 1.078447 0.865144 0.547688 0.062 Uiso 1 1 calc GR . . . .
H10C H 1.031628 0.911546 0.440100 0.062 Uiso 1 1 calc GR . . . .
C22 C 0.5329(5) 0.7934(5) -0.0268(4) 0.0398(14) Uani 1 1 d . . . . .
C32 C 0.6520(5) 0.4754(4) 0.5985(4) 0.0397(14) Uani 1 1 d . . . . .
H32A H 0.571849 0.479834 0.611088 0.060 Uiso 1 1 calc GR . . . .
H32B H 0.693942 0.472100 0.656572 0.060 Uiso 1 1 calc GR . . . .
H32C H 0.678647 0.415175 0.577776 0.060 Uiso 1 1 calc GR . . . .
C9 C 0.9231(4) 0.8310(4) 0.5249(4) 0.0305(12) Uani 1 1 d . . . . .
C17 C 0.9875(4) 0.7953(4) 0.2523(4) 0.0313(12) Uani 1 1 d . . . . .
C34 C 0.3759(4) 0.8675(5) 0.1789(4) 0.0402(14) Uani 1 1 d . . . . .
H34A H 0.329266 0.817918 0.176428 0.060 Uiso 1 1 calc GR . . . .
H34B H 0.374809 0.914844 0.116025 0.060 Uiso 1 1 calc GR . . . .
H34C H 0.346371 0.903534 0.225072 0.060 Uiso 1 1 calc GR . . . .
C27 C 0.8179(5) 0.5420(5) -0.0917(4) 0.0394(14) Uani 1 1 d . . . . .
C3 C 0.4755(4) 0.9425(4) 0.4005(4) 0.0314(12) Uani 1 1 d . . . . .
H3 H 0.410070 0.988107 0.371819 0.038 Uiso 1 1 calc R . . . .
C21 C 0.4738(6) 0.8986(5) -0.0784(4) 0.0521(17) Uani 1 1 d . . . . .
H21A H 0.486657 0.945231 -0.042248 0.078 Uiso 1 1 calc GR . . . .
H21B H 0.393047 0.899394 -0.084313 0.078 Uiso 1 1 calc GR . . . .
H21C H 0.503750 0.918815 -0.141781 0.078 Uiso 1 1 calc GR . . . .
C23 C 0.4697(5) 0.7172(5) 0.0119(4) 0.0437(15) Uani 1 1 d . . . . .
H23 H 0.390415 0.736504 0.004821 0.052 Uiso 1 1 calc R . . . .
C7 C 0.7762(4) 0.8289(4) 0.6507(4) 0.0295(12) Uani 1 1 d . . . . .
C25 C 0.4279(6) 0.5465(6) 0.1004(5) 0.0573(18) Uani 1 1 d . . . . .
H25A H 0.454980 0.480001 0.091900 0.086 Uiso 1 1 calc GR . . . .
H25B H 0.354771 0.574160 0.066928 0.086 Uiso 1 1 calc GR . . . .
H25C H 0.420070 0.541393 0.168239 0.086 Uiso 1 1 calc GR . . . .
C8 C 0.8785(5) 0.8503(4) 0.6102(4) 0.0346(13) Uani 1 1 d . . . . .
H8 H 0.922436 0.880954 0.643355 0.042 Uiso 1 1 calc R . . . .
C16 C 1.1067(5) 0.7336(5) 0.2706(5) 0.0585(19) Uani 1 1 d . . . . .
H16A H 1.107572 0.675317 0.325180 0.088 Uiso 1 1 calc GR . . . .
H16B H 1.158571 0.774893 0.283822 0.088 Uiso 1 1 calc GR . . . .
H16C H 1.130138 0.711311 0.214310 0.088 Uiso 1 1 calc GR . . . .
C6 C 0.7514(5) 0.8430(5) 0.7496(4) 0.0439(15) Uani 1 1 d . . . . .
H6A H 0.670036 0.859569 0.755362 0.066 Uiso 1 1 calc GR . . . .
H6B H 0.786799 0.897378 0.758680 0.066 Uiso 1 1 calc GR . . . .
H6C H 0.781402 0.781076 0.798004 0.066 Uiso 1 1 calc GR . . . .
C24 C 0.5111(5) 0.6146(5) 0.0605(4) 0.0402(14) Uani 1 1 d . . . . .
C35 C 0.8613(5) 0.8279(5) 0.0259(4) 0.0371(14) Uani 1 1 d . . . . .
C26 C 0.8189(6) 0.5417(6) -0.1967(4) 0.0593(19) Uani 1 1 d . . . . .
H26A H 0.752535 0.517363 -0.212664 0.089 Uiso 1 1 calc GR . . . .
H26B H 0.886862 0.497818 -0.207691 0.089 Uiso 1 1 calc GR . . . .
H26C H 0.818079 0.609734 -0.236760 0.089 Uiso 1 1 calc GR . . . .
C36 C 0.9372(7) 0.8937(6) -0.0349(5) 0.066(2) Uani 1 1 d . . . . .
H36A H 0.898284 0.963264 -0.053281 0.099 Uiso 1 1 calc GR . . . .
H36B H 0.955513 0.871403 -0.092077 0.099 Uiso 1 1 calc GR . . . .
H36C H 1.006527 0.888470 0.001611 0.099 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 O10 2.004(3) . ?
Ru1 O9 1.998(3) . ?
Ru1 O3 2.078(3) . ?
Ru1 O12 2.027(3) . ?
Ru1 O1 1.906(3) . ?
Ru1 O11 2.011(3) . ?
Ru2 Ru3 2.5187(6) . ?
Ru2 O14 2.007(3) . ?
Ru2 O13 2.000(3) . ?
Ru2 O4 2.028(3) . ?
Ru2 O5 2.072(3) . ?
Ru2 O2 1.940(3) . ?
Ru2 O1 1.944(3) . ?
Ru3 O16 2.011(3) . ?
Ru3 O6 2.060(3) . ?
Ru3 O2 1.934(3) . ?
Ru3 O1 1.950(3) . ?
Ru3 O7 2.048(3) . ?
Ru3 O15 2.000(3) . ?
Ru4 O20 2.029(4) . ?
Ru4 O2 1.907(3) . ?
Ru4 O18 1.992(4) . ?
Ru4 O17 1.993(4) . ?
Ru4 O19 1.999(3) . ?
Ru4 O8 2.066(4) . ?
O14 C14 1.291(6) . ?
O16 C19 1.271(6) . ?
O13 C12 1.277(6) . ?
O10 C4 1.272(6) . ?
O4 C31 1.265(6) . ?
O9 C2 1.280(6) . ?
O20 C29 1.265(6) . ?
O3 C31 1.258(6) . ?
O5 C33 1.265(6) . ?
O12 C9 1.267(6) . ?
O6 C33 1.260(6) . ?
O18 C24 1.272(7) . ?
O7 C35 1.263(6) . ?
O17 C22 1.276(7) . ?
O11 C7 1.266(6) . ?
O19 C27 1.293(7) . ?
O15 C17 1.275(6) . ?
O8 C35 1.256(7) . ?
C19 C18 1.397(7) . ?
C19 C20 1.496(7) . ?
C13 C12 1.379(8) . ?
C13 C14 1.388(8) . ?
C12 C11 1.499(7) . ?
C5 C4 1.485(7) . ?
C4 C3 1.389(7) . ?
C31 C32 1.491(7) . ?
C29 C28 1.395(8) . ?
C29 C30 1.502(8) . ?
C33 C34 1.499(7) . ?
C14 C15 1.498(8) . ?
C18 C17 1.395(7) . ?
C2 C1 1.490(7) . ?
C2 C3 1.388(7) . ?
C28 C27 1.363(8) . ?
C10 C9 1.496(7) . ?
C22 C21 1.494(8) . ?
C22 C23 1.390(8) . ?
C9 C8 1.400(7) . ?
C17 C16 1.505(7) . ?
C27 C26 1.506(8) . ?
C23 C24 1.405(8) . ?
C7 C8 1.383(7) . ?
C7 C6 1.502(7) . ?
C25 C24 1.487(8) . ?
C35 C36 1.497(8) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O10 Ru1 O3 174.70(12) . . ?
O10 Ru1 O12 84.67(13) . . ?
O10 Ru1 O11 89.19(13) . . ?
O9 Ru1 O10 94.87(13) . . ?
O9 Ru1 O3 83.62(13) . . ?
O9 Ru1 O12 178.55(13) . . ?
O9 Ru1 O11 88.03(13) . . ?
O12 Ru1 O3 96.71(13) . . ?
O1 Ru1 O10 93.08(13) . . ?
O1 Ru1 O9 90.41(13) . . ?
O1 Ru1 O3 92.02(13) . . ?
O1 Ru1 O12 90.98(13) . . ?
O1 Ru1 O11 177.36(13) . . ?
O11 Ru1 O3 85.68(13) . . ?
O11 Ru1 O12 90.59(13) . . ?
O14 Ru2 Ru3 138.87(10) . . ?
O14 Ru2 O4 80.82(13) . . ?
O14 Ru2 O5 87.94(14) . . ?
O13 Ru2 Ru3 93.92(10) . . ?
O13 Ru2 O14 93.45(14) . . ?
O13 Ru2 O4 87.01(13) . . ?
O13 Ru2 O5 177.65(13) . . ?
O4 Ru2 Ru3 139.96(9) . . ?
O4 Ru2 O5 91.34(13) . . ?
O5 Ru2 Ru3 86.26(10) . . ?
O2 Ru2 Ru3 49.35(10) . . ?
O2 Ru2 O14 89.92(13) . . ?
O2 Ru2 O13 92.61(13) . . ?
O2 Ru2 O4 170.69(13) . . ?
O2 Ru2 O5 89.28(13) . . ?
O2 Ru2 O1 99.05(13) . . ?
O1 Ru2 Ru3 49.79(9) . . ?
O1 Ru2 O14 170.52(13) . . ?
O1 Ru2 O13 89.20(13) . . ?
O1 Ru2 O4 90.24(13) . . ?
O1 Ru2 O5 89.13(13) . . ?
O16 Ru3 Ru2 139.25(9) . . ?
O16 Ru3 O6 87.71(14) . . ?
O16 Ru3 O7 80.91(13) . . ?
O6 Ru3 Ru2 86.13(10) . . ?
O2 Ru3 Ru2 49.54(9) . . ?
O2 Ru3 O16 170.09(13) . . ?
O2 Ru3 O6 88.66(13) . . ?
O2 Ru3 O1 99.03(13) . . ?
O2 Ru3 O7 90.02(13) . . ?
O2 Ru3 O15 90.03(14) . . ?
O1 Ru3 Ru2 49.59(9) . . ?
O1 Ru3 O16 90.17(13) . . ?
O1 Ru3 O6 89.58(13) . . ?
O1 Ru3 O7 170.82(13) . . ?
O1 Ru3 O15 92.86(13) . . ?
O7 Ru3 Ru2 139.52(10) . . ?
O7 Ru3 O6 92.19(14) . . ?
O15 Ru3 Ru2 94.74(10) . . ?
O15 Ru3 O16 93.21(14) . . ?
O15 Ru3 O6 177.39(13) . . ?
O15 Ru3 O7 85.55(14) . . ?
O20 Ru4 O8 94.39(15) . . ?
O2 Ru4 O20 90.50(13) . . ?
O2 Ru4 O18 92.17(14) . . ?
O2 Ru4 O17 92.44(14) . . ?
O2 Ru4 O19 177.09(14) . . ?
O2 Ru4 O8 90.80(14) . . ?
O18 Ru4 O20 86.31(15) . . ?
O18 Ru4 O17 94.61(16) . . ?
O18 Ru4 O19 90.43(14) . . ?
O18 Ru4 O8 176.94(13) . . ?
O17 Ru4 O20 176.88(14) . . ?
O17 Ru4 O19 86.04(15) . . ?
O17 Ru4 O8 84.53(15) . . ?
O19 Ru4 O20 90.97(15) . . ?
O19 Ru4 O8 86.59(14) . . ?
C14 O14 Ru2 123.0(4) . . ?
C19 O16 Ru3 122.9(3) . . ?
C12 O13 Ru2 123.8(4) . . ?
C4 O10 Ru1 121.6(3) . . ?
C31 O4 Ru2 127.9(3) . . ?
C2 O9 Ru1 121.6(3) . . ?
C29 O20 Ru4 124.1(4) . . ?
C31 O3 Ru1 121.8(3) . . ?
C33 O5 Ru2 120.6(3) . . ?
C9 O12 Ru1 124.2(3) . . ?
C33 O6 Ru3 121.5(3) . . ?
Ru3 O2 Ru2 81.11(12) . . ?
Ru4 O2 Ru2 147.02(19) . . ?
Ru4 O2 Ru3 131.84(17) . . ?
Ru1 O1 Ru2 131.24(17) . . ?
Ru1 O1 Ru3 147.83(18) . . ?
Ru2 O1 Ru3 80.61(11) . . ?
C24 O18 Ru4 122.2(4) . . ?
C35 O7 Ru3 127.3(3) . . ?
C22 O17 Ru4 123.3(4) . . ?
C7 O11 Ru1 125.3(3) . . ?
C27 O19 Ru4 125.2(4) . . ?
C17 O15 Ru3 123.8(3) . . ?
C35 O8 Ru4 122.4(3) . . ?
O16 C19 C18 126.6(5) . . ?
O16 C19 C20 114.5(5) . . ?
C18 C19 C20 118.9(5) . . ?
C12 C13 C14 128.0(5) . . ?
O13 C12 C13 125.6(5) . . ?
O13 C12 C11 113.5(5) . . ?
C13 C12 C11 120.9(5) . . ?
O10 C4 C5 113.9(5) . . ?
O10 C4 C3 126.4(5) . . ?
C3 C4 C5 119.7(5) . . ?
O4 C31 C32 116.0(5) . . ?
O3 C31 O4 126.8(5) . . ?
O3 C31 C32 117.2(4) . . ?
O20 C29 C28 125.9(5) . . ?
O20 C29 C30 115.6(5) . . ?
C28 C29 C30 118.4(5) . . ?
O5 C33 C34 117.7(5) . . ?
O6 C33 O5 125.5(5) . . ?
O6 C33 C34 116.8(5) . . ?
O14 C14 C13 125.5(5) . . ?
O14 C14 C15 113.8(5) . . ?
C13 C14 C15 120.7(5) . . ?
C17 C18 C19 126.4(5) . . ?
O9 C2 C1 113.8(5) . . ?
O9 C2 C3 126.2(5) . . ?
C3 C2 C1 120.1(5) . . ?
C27 C28 C29 126.7(5) . . ?
O17 C22 C21 114.4(6) . . ?
O17 C22 C23 125.1(6) . . ?
C23 C22 C21 120.4(6) . . ?
O12 C9 C10 115.1(5) . . ?
O12 C9 C8 124.7(5) . . ?
C8 C9 C10 120.2(5) . . ?
O15 C17 C18 125.9(5) . . ?
O15 C17 C16 113.7(5) . . ?
C18 C17 C16 120.4(5) . . ?
O19 C27 C28 125.5(5) . . ?
O19 C27 C26 113.7(6) . . ?
C28 C27 C26 120.7(6) . . ?
C2 C3 C4 127.8(5) . . ?
C22 C23 C24 127.8(6) . . ?
O11 C7 C8 125.0(5) . . ?
O11 C7 C6 116.3(5) . . ?
C8 C7 C6 118.6(5) . . ?
C7 C8 C9 127.1(5) . . ?
O18 C24 C23 125.7(6) . . ?
O18 C24 C25 115.2(6) . . ?
C23 C24 C25 119.1(6) . . ?
O7 C35 C36 115.8(5) . . ?
O8 C35 O7 127.2(5) . . ?
O8 C35 C36 117.0(5) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.803
_oxdiff_exptl_absorpt_empirical_full_min 0.710
