# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_c2221_a
_database_code_depnum_ccdc_archive 'CCDC 2022146'
loop_
_audit_author_name
_audit_author_address
'Yingjie Zhang'
;Australian Nuclear Science and Technology Organisation
Australia
;
_audit_update_record             
;
2020-08-07 deposited with the CCDC.	2020-10-23 downloaded from the CCDC.
;
_audit_creation_date             2020-03-02
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Eu O21.5 U5.5, O'
_chemical_formula_sum            'Eu O22.50 U5.50'
_chemical_formula_weight         1821.12
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           20
_space_group_name_H-M_alt        'C 2 2 21'
_space_group_name_Hall           'C 2c 2'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   11.629(2)
_cell_length_b                   20.973(4)
_cell_length_c                   14.170(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3456.0(12)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    18000
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.999
_cell_measurement_theta_min      1.942
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    55.042
_exptl_absorpt_correction_T_max  0.4360
_exptl_absorpt_correction_T_min  0.3329
_exptl_absorpt_correction_type   multi-scans
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.2070 before and 0.0487 after correction.
The Ratio of minimum to maximum transmission is 0.7635.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    7.000
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needles
_exptl_crystal_F_000             5992
_exptl_crystal_size_max          0.010
_exptl_crystal_size_mid          0.003
_exptl_crystal_size_min          0.003
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0445
_diffrn_reflns_av_unetI/netI     0.0220
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            22058
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         1.942
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_type           
'silicon double crystal monochromated synchrotron'
_diffrn_source                   'Australian Synchrotron MX2'
_diffrn_measurement_device_type  'Eiga Detector'
_diffrn_measurement_method       'π  scans'
_diffrn_radiation_wavelength     0.71089
_reflns_Friedel_coverage         0.782
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     0.999
_reflns_number_gt                2982
_reflns_number_total             3037
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_data_collection       'BlueIce (McPhillips, et al., 2002)'
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         4.310
_refine_diff_density_min         -5.204
_refine_diff_density_rms         0.611
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.57(4)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.122
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     141
_refine_ls_number_reflns         3037
_refine_ls_number_restraints     549
_refine_ls_R_factor_all          0.0390
_refine_ls_R_factor_gt           0.0384
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0525P)²+524.2377P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1028
_refine_ls_wR_factor_ref         0.1032
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.43(4)
 0.57(4)
2. Rigid bond restraints
 U1, U2, U3, U4, U5, U6, U7
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
3. Uiso/Uaniso restraints and constraints
U1 \\sim U2 \\sim U3 \\sim U4 \\sim U5 \\sim U6 \\sim U7: within 1.7A with
sigma of 0.04 and sigma for terminal atoms of 0.08
Uanis(O1) = Uanis(O2) = Uanis(O3) = Uanis(O4) = Uanis(O5) = Uanis(O6) =
Uanis(O7) = Uanis(O8) = Uanis(O9) = Uanis(O10) = Uanis(O11) = Uanis(O12) =
Uanis(O13) = Uanis(O14) = Uanis(O15) = Uanis(O16) = Uanis(O17) = Uanis(O18) =
Uanis(O19) = Uanis(O20) = Uanis(O21) = Uanis(O22)
4. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Fixed Sof: Eu1(0.65) Eu2(0.35)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
U1 U 0.98875(9) 0.32868(5) 0.48120(7) 0.0024(3) Uani 1 1 d . U . . .
U2 U 0.67544(9) 0.34027(4) 0.47962(7) 0.0029(2) Uani 1 1 d . U . . .
U3 U 0.35762(8) 0.32948(5) 0.47526(7) 0.0028(2) Uani 1 1 d . U . . .
U4 U 0.86824(13) 0.5000 0.5000 0.0040(3) Uani 1 2 d S TU P . .
U5 U 0.47707(14) 0.5000 0.5000 0.0039(3) Uani 1 2 d S TU P . .
U6 U 0.17192(15) 0.5000 0.5000 0.0042(3) Uani 1 2 d S TU P . .
U7 U 0.17080(10) 0.32085(5) 0.27381(7) 0.0084(3) Uani 1 1 d . U . . .
Eu1 Eu 0.3273(3) 0.41109(17) 0.7420(2) 0.0334(7) Uani 0.65 1 d . U . . .
Eu2 Eu 0.0000 0.41900(19) 0.7500 0.0239(8) Uani 0.7 2 d S TU P . .
O1 O 0.9753(19) 0.3192(11) 0.3445(16) 0.0144(9) Uani 1 1 d . U . . .
O2 O 1.0091(19) 0.3420(10) 0.6089(16) 0.0144(9) Uani 1 1 d . U . . .
O3 O 0.668(2) 0.3655(10) 0.6046(14) 0.0144(9) Uani 1 1 d . U . . .
O4 O 0.3620(18) 0.3204(11) 0.3455(15) 0.0144(9) Uani 1 1 d . U . . .
O5 O 0.3399(19) 0.3420(10) 0.6013(15) 0.0144(9) Uani 1 1 d . U . . .
O6 O 0.876(2) 0.5216(10) 0.3791(16) 0.0144(9) Uani 1 1 d . U . . .
O7 O 0.4683(19) 0.4705(11) 0.6203(17) 0.0144(9) Uani 1 1 d . U . . .
O8 O 0.162(2) 0.4659(10) 0.6519(15) 0.0144(9) Uani 1 1 d . U . . .
O9 O 0.166(2) 0.4074(10) 0.2669(15) 0.0144(9) Uani 1 1 d . U . . .
O10 O 0.168(2) 0.2372(9) 0.2761(15) 0.0144(9) Uani 1 1 d . U . . .
O11 O 0.834(2) 0.3948(10) 0.4661(14) 0.0144(9) Uani 1 1 d . U . . .
O12 O 0.5175(19) 0.3977(10) 0.4518(16) 0.0144(9) Uani 1 1 d . U . . .
O13 O 0.5279(19) 0.2759(10) 0.4986(17) 0.0144(9) Uani 1 1 d . U . . .
O14 O 0.3031(19) 0.4401(10) 0.4714(15) 0.0144(9) Uani 1 1 d . U . . .
O15 O 0.6718(19) 0.4926(9) 0.5366(14) 0.0144(9) Uani 1 1 d . U . . .
O16 O 0.326(2) 0.2251(10) 0.4933(15) 0.0144(9) Uani 1 1 d . U . . .
O17 O 0.1701(19) 0.3269(10) 0.4373(14) 0.0144(9) Uani 1 1 d . U . . .
O18 O 0.3085(19) 0.3197(10) 0.1481(15) 0.0144(9) Uani 1 1 d . U . . .
O19 O 0.0430(19) 0.4407(10) 0.4751(16) 0.0144(9) Uani 1 1 d . U . . .
O20 O 0.5000 0.3687(15) 0.7500 0.0144(9) Uani 1 2 d S TU P . .
O21 O 0.339(2) 0.5242(10) 0.7803(15) 0.0144(9) Uani 1 1 d . U . . .
O22 O 0.160(2) 0.3542(10) 0.7550(14) 0.0144(9) Uani 1 1 d . U . . .
O23 O 0.5000 0.5819(19) 0.7500 0.029(9) Uiso 1 2 d S TU P A 1
O24 O 0.5000 0.626(2) 0.7500 0.031(9) Uiso 1 2 d S TU P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
U1 U2 3.6517(15) . ?
U1 U3 3.7025(14) 8_556 ?
U1 U4 3.8660(13) . ?
U1 U7 4.0654(16) 3_655 ?
U1 U7 3.6256(16) 1_655 ?
U1 O1 1.95(2) . ?
U1 O2 1.85(2) . ?
U1 O11 2.28(2) . ?
U1 O13 2.26(2) 8_556 ?
U1 O16 2.23(2) 8_556 ?
U1 O17 2.20(2) 1_655 ?
U1 O19 2.43(2) 1_655 ?
U2 U3 3.7033(16) . ?
U2 U4 4.0415(14) . ?
U2 U5 4.0777(15) . ?
U2 U7 4.0323(15) 3_655 ?
U2 Eu1 4.215(3) 3_656 ?
U2 O3 1.85(2) . ?
U2 O11 2.18(2) . ?
U2 O12 2.23(2) . ?
U2 O13 2.20(2) . ?
U2 O16 2.25(2) 8_556 ?
U2 O18 1.87(2) 3_655 ?
U3 U1 3.7023(14) 8_456 ?
U3 U5 3.8527(13) . ?
U3 U7 3.5919(15) . ?
U3 Eu1 4.165(3) . ?
U3 O4 1.85(2) . ?
U3 O5 1.82(2) . ?
U3 O12 2.37(2) . ?
U3 O13 2.30(2) . ?
U3 O14 2.41(2) . ?
U3 O16 2.23(2) . ?
U3 O17 2.25(2) . ?
U4 U1 3.8661(13) 4_566 ?
U4 U2 4.0415(14) 4_566 ?
U4 U6 3.531(2) 1_655 ?
U4 O6 1.77(2) 4_566 ?
U4 O6 1.77(2) . ?
U4 O11 2.29(2) 4_566 ?
U4 O11 2.29(2) . ?
U4 O15 2.35(2) . ?
U4 O15 2.35(2) 4_566 ?
U4 O19 2.41(2) 4_666 ?
U4 O19 2.41(2) 1_655 ?
U5 U2 4.0777(15) 4_566 ?
U5 U3 3.8526(13) 4_566 ?
U5 U6 3.549(2) . ?
U5 O7 1.82(2) . ?
U5 O7 1.82(2) 4_566 ?
U5 O12 2.30(2) . ?
U5 O12 2.30(2) 4_566 ?
U5 O14 2.41(2) 4_566 ?
U5 O14 2.42(2) . ?
U5 O15 2.33(2) . ?
U5 O15 2.33(2) 4_566 ?
U6 U4 3.531(2) 1_455 ?
U6 O8 2.27(2) 4_566 ?
U6 O8 2.27(2) . ?
U6 O14 2.02(2) 4_566 ?
U6 O14 2.02(2) . ?
U6 O19 1.98(2) 4_566 ?
U6 O19 1.98(2) . ?
U7 U1 3.6256(16) 1_455 ?
U7 U1 4.0654(16) 3_655 ?
U7 U2 4.0323(15) 3_655 ?
U7 U7 4.029(2) 3 ?
U7 O1 2.39(2) 3_655 ?
U7 O1 2.48(2) 1_455 ?
U7 O4 2.44(2) . ?
U7 O9 1.82(2) . ?
U7 O10 1.76(2) . ?
U7 O17 2.32(2) . ?
U7 O18 2.39(2) . ?
Eu1 U2 4.215(3) 3_656 ?
Eu1 Eu1 4.022(7) 3_656 ?
Eu1 Eu2 3.812(4) . ?
Eu1 O3 2.37(2) 3_656 ?
Eu1 O5 2.47(2) . ?
Eu1 O7 2.69(2) . ?
Eu1 O8 2.58(2) . ?
Eu1 O10 3.15(2) 6 ?
Eu1 O20 2.199(13) . ?
Eu1 O21 2.44(2) . ?
Eu1 O22 2.29(2) . ?
Eu2 U4 4.2170(18) 1_455 ?
Eu2 U4 4.2170(18) 2_665 ?
Eu2 Eu1 3.812(4) 3_556 ?
Eu2 O2 2.57(2) 1_455 ?
Eu2 O2 2.57(2) 3_656 ?
Eu2 O6 2.64(2) 2_665 ?
Eu2 O6 2.64(2) 4_466 ?
Eu2 O8 2.54(2) . ?
Eu2 O8 2.54(2) 3_556 ?
Eu2 O22 2.31(2) 3_556 ?
Eu2 O22 2.31(2) . ?
O1 U7 2.48(2) 1_655 ?
O1 U7 2.39(2) 3_655 ?
O2 Eu2 2.57(2) 1_655 ?
O3 Eu1 2.37(2) 3_656 ?
O6 Eu2 2.64(2) 2_664 ?
O10 Eu1 3.15(2) 6_554 ?
O13 U1 2.26(2) 8_456 ?
O15 O15 1.08(4) 4_566 ?
O16 U1 2.23(2) 8_456 ?
O16 U2 2.25(2) 8_456 ?
O17 U1 2.20(2) 1_455 ?
O18 U2 1.87(2) 3_655 ?
O19 U1 2.43(2) 1_455 ?
O19 U4 2.41(2) 1_455 ?
O20 Eu1 2.199(13) 3_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
U2 U1 U3 69.50(3) . 8_556 ?
U2 U1 U4 64.97(3) . . ?
U2 U1 U7 62.73(3) . 3_655 ?
U3 U1 U4 132.21(4) 8_556 . ?
U3 U1 U7 85.64(3) 8_556 3_655 ?
U4 U1 U7 86.18(3) . 3_655 ?
U7 U1 U2 125.49(4) 1_655 . ?
U7 U1 U3 109.57(3) 1_655 8_556 ?
U7 U1 U4 108.04(3) 1_655 . ?
U7 U1 U7 62.88(4) 1_655 3_655 ?
O1 U1 U2 85.4(6) . . ?
O1 U1 U3 92.4(7) . 8_556 ?
O1 U1 U4 97.7(7) . . ?
O1 U1 U7 22.8(6) . 3_655 ?
O1 U1 U7 40.4(6) . 1_655 ?
O1 U1 O11 84.6(8) . . ?
O1 U1 O13 92.5(9) . 8_556 ?
O1 U1 O16 92.3(8) . 8_556 ?
O1 U1 O17 78.1(8) . 1_655 ?
O1 U1 O19 94.8(9) . 1_655 ?
O2 U1 U2 97.1(7) . . ?
O2 U1 U3 91.4(7) . 8_556 ?
O2 U1 U4 80.7(7) . . ?
O2 U1 U7 159.4(7) . 3_655 ?
O2 U1 U7 136.6(7) . 1_655 ?
O2 U1 O1 176.0(10) . . ?
O2 U1 O11 95.8(9) . . ?
O2 U1 O13 89.8(9) . 8_556 ?
O2 U1 O16 91.5(9) . 8_556 ?
O2 U1 O17 99.1(9) . 1_655 ?
O2 U1 O19 81.7(8) . 1_655 ?
O11 U1 U2 34.2(5) . . ?
O11 U1 U3 103.7(5) . 8_556 ?
O11 U1 U4 32.3(5) . . ?
O11 U1 U7 114.3(5) . 1_655 ?
O11 U1 U7 65.3(5) . 3_655 ?
O11 U1 O19 67.3(7) . 1_655 ?
O13 U1 U2 105.5(6) 8_556 . ?
O13 U1 U3 36.1(6) 8_556 8_556 ?
O13 U1 U4 165.3(6) 8_556 . ?
O13 U1 U7 86.6(6) 8_556 1_655 ?
O13 U1 U7 99.5(6) 8_556 3_655 ?
O13 U1 O11 139.6(8) 8_556 . ?
O13 U1 O19 152.8(7) 8_556 1_655 ?
O16 U1 U2 35.8(5) 8_556 . ?
O16 U1 U3 34.1(5) 8_556 8_556 ?
O16 U1 U4 98.7(5) 8_556 . ?
O16 U1 U7 127.1(5) 8_556 1_655 ?
O16 U1 U7 74.7(5) 8_556 3_655 ?
O16 U1 O11 69.8(8) 8_556 . ?
O16 U1 O13 70.2(7) 8_556 8_556 ?
O16 U1 O19 135.5(7) 8_556 1_655 ?
O17 U1 U2 163.0(5) 1_655 . ?
O17 U1 U3 115.3(5) 1_655 8_556 ?
O17 U1 U4 112.5(5) 1_655 . ?
O17 U1 U7 37.8(5) 1_655 1_655 ?
O17 U1 U7 100.7(5) 1_655 3_655 ?
O17 U1 O11 137.7(7) 1_655 . ?
O17 U1 O13 80.0(8) 1_655 8_556 ?
O17 U1 O16 148.2(8) 1_655 8_556 ?
O17 U1 O19 76.0(7) 1_655 1_655 ?
O19 U1 U2 101.2(5) 1_655 . ?
O19 U1 U3 167.8(5) 1_655 8_556 ?
O19 U1 U4 36.8(5) 1_655 . ?
O19 U1 U7 82.2(5) 1_655 1_655 ?
O19 U1 U7 97.2(5) 1_655 3_655 ?
U1 U2 U3 172.66(3) . . ?
U1 U2 U4 60.08(3) . . ?
U1 U2 U5 128.22(4) . . ?
U1 U2 U7 63.66(3) . 3_655 ?
U1 U2 Eu1 91.45(6) . 3_656 ?
U3 U2 U4 127.26(3) . . ?
U3 U2 U5 59.12(3) . . ?
U3 U2 U7 114.93(3) . 3_655 ?
U3 U2 Eu1 91.69(5) . 3_656 ?
U4 U2 U5 68.15(3) . . ?
U4 U2 Eu1 69.22(5) . 3_656 ?
U5 U2 Eu1 68.89(5) . 3_656 ?
U7 U2 U4 84.34(3) 3_655 . ?
U7 U2 U5 113.39(3) 3_655 . ?
U7 U2 Eu1 150.74(6) 3_655 3_656 ?
O3 U2 U1 93.5(7) . . ?
O3 U2 U3 89.1(7) . . ?
O3 U2 U4 73.8(7) . . ?
O3 U2 U5 70.7(7) . . ?
O3 U2 U7 154.5(7) . 3_655 ?
O3 U2 Eu1 4.6(6) . 3_656 ?
O3 U2 O11 88.6(9) . . ?
O3 U2 O12 88.5(9) . . ?
O3 U2 O13 91.2(9) . . ?
O3 U2 O16 92.8(9) . 8_556 ?
O3 U2 O18 175.6(10) . 3_655 ?
O11 U2 U1 35.9(6) . . ?
O11 U2 U3 151.1(6) . . ?
O11 U2 U4 26.1(6) . . ?
O11 U2 U5 93.1(6) . . ?
O11 U2 U7 66.4(5) . 3_655 ?
O11 U2 Eu1 84.5(5) . 3_656 ?
O11 U2 O12 113.5(8) . . ?
O11 U2 O13 173.3(8) . . ?
O11 U2 O16 71.2(8) . 8_556 ?
O12 U2 U1 149.1(6) . . ?
O12 U2 U3 37.7(6) . . ?
O12 U2 U4 91.2(6) . . ?
O12 U2 U5 26.3(6) . . ?
O12 U2 U7 105.2(6) . 3_655 ?
O12 U2 Eu1 88.2(6) . 3_656 ?
O12 U2 O16 175.2(8) . 8_556 ?
O13 U2 U1 137.4(6) . . ?
O13 U2 U3 35.5(6) . . ?
O13 U2 U4 158.9(6) . . ?
O13 U2 U5 93.1(6) . . ?
O13 U2 U7 113.1(6) . 3_655 ?
O13 U2 Eu1 95.5(6) . 3_656 ?
O13 U2 O12 73.2(8) . . ?
O13 U2 O16 102.2(7) . 8_556 ?
O16 U2 U1 35.4(6) 8_556 . ?
O16 U2 U3 137.7(6) 8_556 . ?
O16 U2 U4 93.5(6) 8_556 . ?
O16 U2 U5 157.8(5) 8_556 . ?
O16 U2 U7 75.3(5) 8_556 3_655 ?
O16 U2 Eu1 93.5(5) 8_556 3_656 ?
O18 U2 U1 83.7(7) 3_655 . ?
O18 U2 U3 94.0(7) 3_655 . ?
O18 U2 U4 101.8(7) 3_655 . ?
O18 U2 U5 108.3(7) 3_655 . ?
O18 U2 U7 21.6(7) 3_655 3_655 ?
O18 U2 Eu1 171.0(7) 3_655 3_656 ?
O18 U2 O11 87.2(9) 3_655 . ?
O18 U2 O12 92.0(9) 3_655 . ?
O18 U2 O13 93.2(9) 3_655 . ?
O18 U2 O16 87.0(8) 3_655 8_556 ?
U1 U3 U2 68.96(3) 8_456 . ?
U1 U3 U5 131.91(4) 8_456 . ?
U1 U3 Eu1 104.59(5) 8_456 . ?
U2 U3 U5 65.29(3) . . ?
U2 U3 Eu1 92.53(6) . . ?
U5 U3 Eu1 64.30(5) . . ?
U7 U3 U1 109.66(3) . 8_456 ?
U7 U3 U2 128.31(3) . . ?
U7 U3 U5 109.70(3) . . ?
U7 U3 Eu1 133.70(6) . . ?
O4 U3 U1 93.5(7) . 8_456 ?
O4 U3 U2 89.7(7) . . ?
O4 U3 U5 100.2(7) . . ?
O4 U3 U7 38.9(7) . . ?
O4 U3 Eu1 161.3(7) . . ?
O4 U3 O12 84.3(9) . . ?
O4 U3 O13 93.9(9) . . ?
O4 U3 O14 94.9(9) . . ?
O4 U3 O16 91.0(9) . . ?
O4 U3 O17 77.6(8) . . ?
O5 U3 U1 90.7(7) . 8_456 ?
O5 U3 U2 95.0(7) . . ?
O5 U3 U5 79.5(7) . . ?
O5 U3 U7 136.0(7) . . ?
O5 U3 Eu1 16.0(7) . . ?
O5 U3 O4 174.5(10) . . ?
O5 U3 O12 98.0(9) . . ?
O5 U3 O13 91.5(9) . . ?
O5 U3 O14 81.6(8) . . ?
O5 U3 O16 90.6(8) . . ?
O5 U3 O17 97.4(9) . . ?
O12 U3 U1 104.0(5) . 8_456 ?
O12 U3 U2 35.2(5) . . ?
O12 U3 U5 33.8(5) . . ?
O12 U3 U7 113.2(6) . . ?
O12 U3 Eu1 86.9(6) . . ?
O12 U3 O14 67.7(7) . . ?
O13 U3 U1 35.3(5) . 8_456 ?
O13 U3 U2 33.7(5) . . ?
O13 U3 U5 97.5(5) . . ?
O13 U3 U7 127.6(6) . . ?
O13 U3 Eu1 98.2(6) . . ?
O13 U3 O12 68.9(7) . . ?
O13 U3 O14 134.5(7) . . ?
O14 U3 U1 167.5(5) . 8_456 ?
O14 U3 U2 101.8(5) . . ?
O14 U3 U5 37.0(5) . . ?
O14 U3 U7 82.6(5) . . ?
O14 U3 Eu1 66.5(5) . . ?
O16 U3 U1 34.1(6) . 8_456 ?
O16 U3 U2 102.9(6) . . ?
O16 U3 U5 163.5(6) . . ?
O16 U3 U7 86.6(6) . . ?
O16 U3 Eu1 106.5(5) . . ?
O16 U3 O12 137.5(8) . . ?
O16 U3 O13 69.4(8) . . ?
O16 U3 O14 154.6(8) . . ?
O16 U3 O17 81.0(8) . . ?
O17 U3 U1 114.7(5) . 8_456 ?
O17 U3 U2 166.9(5) . . ?
O17 U3 U5 113.2(5) . . ?
O17 U3 U7 38.9(5) . . ?
O17 U3 Eu1 98.4(5) . . ?
O17 U3 O12 137.9(7) . . ?
O17 U3 O13 149.1(7) . . ?
O17 U3 O14 76.3(7) . . ?
U1 U4 U1 137.49(6) . 4_566 ?
U1 U4 U2 167.54(5) . 4_566 ?
U1 U4 U2 54.95(2) 4_566 4_566 ?
U6 U4 U1 68.75(3) 1_655 . ?
U6 U4 U1 68.75(3) 1_655 4_566 ?
U6 U4 U2 123.70(2) 1_655 4_566 ?
O6 U4 U1 98.8(7) 4_566 4_566 ?
O6 U4 U1 98.8(7) . . ?
O6 U4 U1 79.1(7) . 4_566 ?
O6 U4 U1 79.1(7) 4_566 . ?
O6 U4 U2 83.4(7) . 4_566 ?
O6 U4 U2 99.8(7) 4_566 4_566 ?
O6 U4 U6 87.1(7) 4_566 1_655 ?
O6 U4 U6 87.1(7) . 1_655 ?
O6 U4 O6 174.2(15) 4_566 . ?
O6 U4 O11 88.0(9) . 4_566 ?
O6 U4 O11 93.0(9) . . ?
O6 U4 O11 93.0(9) 4_566 4_566 ?
O6 U4 O11 88.0(9) 4_566 . ?
O6 U4 O15 106.2(9) . . ?
O6 U4 O15 79.6(9) 4_566 . ?
O6 U4 O15 79.6(9) . 4_566 ?
O6 U4 O15 106.2(9) 4_566 4_566 ?
O6 U4 O19 87.0(9) 4_566 4_666 ?
O6 U4 O19 87.0(9) . 1_655 ?
O6 U4 O19 88.1(9) . 4_666 ?
O6 U4 O19 88.1(9) 4_566 1_655 ?
O11 U4 U1 166.3(6) . 4_566 ?
O11 U4 U1 166.3(6) 4_566 . ?
O11 U4 U1 32.1(6) 4_566 4_566 ?
O11 U4 U1 32.1(6) . . ?
O11 U4 U2 135.8(6) . 4_566 ?
O11 U4 U2 24.7(6) 4_566 4_566 ?
O11 U4 U6 99.9(6) . 1_655 ?
O11 U4 U6 99.9(6) 4_566 1_655 ?
O11 U4 O11 160.2(12) 4_566 . ?
O11 U4 O15 79.4(8) 4_566 4_566 ?
O11 U4 O15 81.4(8) . 4_566 ?
O11 U4 O15 81.4(8) 4_566 . ?
O11 U4 O15 79.4(8) . . ?
O11 U4 O19 132.3(8) . 4_666 ?
O11 U4 O19 67.5(8) 4_566 4_666 ?
O11 U4 O19 67.5(8) . 1_655 ?
O11 U4 O19 132.3(8) 4_566 1_655 ?
O15 U4 U1 107.9(5) . . ?
O15 U4 U1 107.9(5) 4_566 4_566 ?
O15 U4 U1 113.5(5) . 4_566 ?
O15 U4 U1 113.5(5) 4_566 . ?
O15 U4 U2 59.9(5) . 4_566 ?
O15 U4 U2 54.6(5) 4_566 4_566 ?
O15 U4 U6 166.7(5) 4_566 1_655 ?
O15 U4 U6 166.7(5) . 1_655 ?
O15 U4 O15 26.6(10) 4_566 . ?
O15 U4 O19 145.0(7) . 1_655 ?
O15 U4 O19 145.4(7) 4_566 1_655 ?
O15 U4 O19 145.4(7) . 4_666 ?
O15 U4 O19 145.0(7) 4_566 4_666 ?
O19 U4 U1 100.6(5) 4_666 . ?
O19 U4 U1 100.6(5) 1_655 4_566 ?
O19 U4 U1 37.3(5) 4_666 4_566 ?
O19 U4 U1 37.3(5) 1_655 . ?
O19 U4 U2 91.7(5) 4_666 4_566 ?
O19 U4 U2 155.0(5) 1_655 4_566 ?
O19 U4 U6 32.4(5) 4_666 1_655 ?
O19 U4 U6 32.4(5) 1_655 1_655 ?
O19 U4 O19 64.9(10) 4_666 1_655 ?
U3 U5 U2 55.59(2) 4_566 4_566 ?
U3 U5 U2 166.67(5) . 4_566 ?
U3 U5 U3 137.73(5) 4_566 . ?
U6 U5 U2 124.45(3) . 4_566 ?
U6 U5 U3 68.87(3) . . ?
U6 U5 U3 68.87(3) . 4_566 ?
O7 U5 U2 79.5(7) 4_566 4_566 ?
O7 U5 U2 104.2(7) . 4_566 ?
O7 U5 U3 102.2(7) 4_566 . ?
O7 U5 U3 102.2(7) . 4_566 ?
O7 U5 U3 75.5(7) 4_566 4_566 ?
O7 U5 U3 75.5(7) . . ?
O7 U5 U6 86.8(7) 4_566 . ?
O7 U5 U6 86.8(7) . . ?
O7 U5 O7 173.6(14) 4_566 . ?
O7 U5 O12 92.9(9) 4_566 . ?
O7 U5 O12 88.4(9) 4_566 4_566 ?
O7 U5 O12 88.4(9) . . ?
O7 U5 O12 92.9(9) . 4_566 ?
O7 U5 O14 86.2(9) . . ?
O7 U5 O14 86.2(9) 4_566 4_566 ?
O7 U5 O14 88.4(9) 4_566 . ?
O7 U5 O14 88.4(9) . 4_566 ?
O7 U5 O15 106.6(9) . 4_566 ?
O7 U5 O15 106.6(9) 4_566 . ?
O7 U5 O15 79.8(9) 4_566 4_566 ?
O7 U5 O15 79.8(9) . . ?
O12 U5 U2 25.5(6) 4_566 4_566 ?
O12 U5 U2 132.2(6) . 4_566 ?
O12 U5 U3 35.0(6) 4_566 4_566 ?
O12 U5 U3 165.1(6) . 4_566 ?
O12 U5 U3 35.0(6) . . ?
O12 U5 U3 165.1(6) 4_566 . ?
O12 U5 U6 101.8(6) 4_566 . ?
O12 U5 U6 101.8(6) . . ?
O12 U5 O12 156.4(11) . 4_566 ?
O12 U5 O14 134.9(8) 4_566 . ?
O12 U5 O14 68.7(8) . . ?
O12 U5 O14 134.9(8) . 4_566 ?
O12 U5 O14 68.7(7) 4_566 4_566 ?
O12 U5 O15 78.3(7) . 4_566 ?
O12 U5 O15 78.8(7) 4_566 4_566 ?
O12 U5 O15 78.3(7) 4_566 . ?
O12 U5 O15 78.8(7) . . ?
O14 U5 U2 155.9(5) . 4_566 ?
O14 U5 U2 92.0(5) 4_566 4_566 ?
O14 U5 U3 36.9(5) 4_566 4_566 ?
O14 U5 U3 101.3(5) 4_566 . ?
O14 U5 U3 101.3(5) . 4_566 ?
O14 U5 U3 36.9(5) . . ?
O14 U5 U6 33.1(5) 4_566 . ?
O14 U5 U6 33.1(5) . . ?
O14 U5 O14 66.2(10) 4_566 . ?
O15 U5 U2 59.2(5) . 4_566 ?
O15 U5 U2 53.9(5) 4_566 4_566 ?
O15 U5 U3 113.1(5) 4_566 . ?
O15 U5 U3 108.0(5) . . ?
O15 U5 U3 113.1(5) . 4_566 ?
O15 U5 U3 108.0(5) 4_566 4_566 ?
O15 U5 U6 166.6(5) . . ?
O15 U5 U6 166.6(5) 4_566 . ?
O15 U5 O14 144.3(7) 4_566 . ?
O15 U5 O14 144.8(7) . . ?
O15 U5 O14 144.3(7) . 4_566 ?
O15 U5 O14 144.8(7) 4_566 4_566 ?
O15 U5 O15 26.9(10) . 4_566 ?
U4 U6 U5 180.0 1_455 . ?
O8 U6 U4 87.0(6) 4_566 1_455 ?
O8 U6 U4 87.0(6) . 1_455 ?
O8 U6 U5 93.0(6) . . ?
O8 U6 U5 93.0(6) 4_566 . ?
O8 U6 O8 174.0(12) . 4_566 ?
O14 U6 U4 139.2(6) . 1_455 ?
O14 U6 U4 139.2(6) 4_566 1_455 ?
O14 U6 U5 40.8(6) . . ?
O14 U6 U5 40.8(6) 4_566 . ?
O14 U6 O8 91.9(8) 4_566 4_566 ?
O14 U6 O8 92.6(8) 4_566 . ?
O14 U6 O8 92.6(8) . 4_566 ?
O14 U6 O8 91.9(8) . . ?
O14 U6 O14 81.7(12) . 4_566 ?
O19 U6 U4 40.8(6) 4_566 1_455 ?
O19 U6 U4 40.8(6) . 1_455 ?
O19 U6 U5 139.2(6) 4_566 . ?
O19 U6 U5 139.2(6) . . ?
O19 U6 O8 89.4(9) . 4_566 ?
O19 U6 O8 86.1(9) 4_566 4_566 ?
O19 U6 O8 89.4(9) 4_566 . ?
O19 U6 O8 86.1(9) . . ?
O19 U6 O14 98.4(8) 4_566 4_566 ?
O19 U6 O14 178.7(10) . 4_566 ?
O19 U6 O14 178.7(10) 4_566 . ?
O19 U6 O14 98.4(8) . . ?
O19 U6 O19 81.5(13) 4_566 . ?
U1 U7 U1 116.88(4) 1_455 3_655 ?
U1 U7 U2 167.48(4) 1_455 3_655 ?
U1 U7 U7 63.90(3) 1_455 3 ?
U2 U7 U1 53.61(3) 3_655 3_655 ?
U3 U7 U1 168.65(4) . 3_655 ?
U3 U7 U1 72.95(3) . 1_455 ?
U3 U7 U2 115.75(4) . 3_655 ?
U3 U7 U7 136.84(5) . 3 ?
U7 U7 U1 53.22(3) 3 3_655 ?
U7 U7 U2 106.74(4) 3 3_655 ?
O1 U7 U1 18.5(5) 3_655 3_655 ?
O1 U7 U1 30.6(5) 1_455 1_455 ?
O1 U7 U1 98.9(5) 3_655 1_455 ?
O1 U7 U1 86.6(5) 1_455 3_655 ?
O1 U7 U2 72.0(5) 3_655 3_655 ?
O1 U7 U2 140.0(5) 1_455 3_655 ?
O1 U7 U3 171.6(5) 3_655 . ?
O1 U7 U3 103.5(5) 1_455 . ?
O1 U7 U7 35.0(5) 3_655 3 ?
O1 U7 U7 33.4(5) 1_455 3 ?
O1 U7 O1 68.4(9) 3_655 1_455 ?
O1 U7 O4 159.9(7) 3_655 . ?
O1 U7 O18 87.3(7) 3_655 . ?
O4 U7 U1 101.2(5) . 1_455 ?
O4 U7 U1 141.7(5) . 3_655 ?
O4 U7 U2 88.1(5) . 3_655 ?
O4 U7 U3 28.3(5) . . ?
O4 U7 U7 165.1(5) . 3 ?
O4 U7 O1 131.6(7) . 1_455 ?
O9 U7 U1 84.2(7) . 3_655 ?
O9 U7 U1 89.0(7) . 1_455 ?
O9 U7 U2 82.1(7) . 3_655 ?
O9 U7 U3 90.5(7) . . ?
O9 U7 U7 87.9(8) . 3 ?
O9 U7 O1 90.6(9) . 1_455 ?
O9 U7 O1 87.5(9) . 3_655 ?
O9 U7 O4 93.0(9) . . ?
O9 U7 O17 90.0(8) . . ?
O9 U7 O18 89.3(9) . . ?
O10 U7 U1 92.7(7) . 3_655 ?
O10 U7 U1 91.1(7) . 1_455 ?
O10 U7 U2 97.3(7) . 3_655 ?
O10 U7 U3 92.8(7) . . ?
O10 U7 U7 89.0(8) . 3 ?
O10 U7 O1 87.7(9) . 1_455 ?
O10 U7 O1 89.1(9) . 3_655 ?
O10 U7 O4 90.4(9) . . ?
O10 U7 O9 176.6(10) . . ?
O10 U7 O17 92.1(8) . . ?
O10 U7 O18 91.0(9) . . ?
O17 U7 U1 35.5(5) . 1_455 ?
O17 U7 U1 152.1(5) . 3_655 ?
O17 U7 U2 152.3(5) . 3_655 ?
O17 U7 U3 37.4(5) . . ?
O17 U7 U7 99.4(5) . 3 ?
O17 U7 O1 134.4(8) . 3_655 ?
O17 U7 O1 66.1(7) . 1_455 ?
O17 U7 O4 65.7(7) . . ?
O17 U7 O18 138.2(7) . . ?
O18 U7 U1 69.2(5) . 3_655 ?
O18 U7 U1 173.5(5) . 1_455 ?
O18 U7 U2 16.7(5) . 3_655 ?
O18 U7 U3 100.8(5) . . ?
O18 U7 U7 122.3(5) . 3 ?
O18 U7 O1 155.7(7) . 1_455 ?
O18 U7 O4 72.6(7) . . ?
U3 Eu1 U2 134.85(9) . 3_656 ?
Eu1 Eu1 U2 87.43(9) 3_656 3_656 ?
Eu1 Eu1 U3 88.08(9) 3_656 . ?
Eu2 Eu1 U2 88.85(7) . 3_656 ?
Eu2 Eu1 U3 97.42(8) . . ?
Eu2 Eu1 Eu1 174.49(12) . 3_656 ?
O3 Eu1 U2 3.6(5) 3_656 3_656 ?
O3 Eu1 U3 131.5(5) 3_656 . ?
O3 Eu1 Eu1 85.7(6) 3_656 3_656 ?
O3 Eu1 Eu2 90.9(6) 3_656 . ?
O3 Eu1 O5 120.1(7) 3_656 . ?
O3 Eu1 O7 139.4(8) 3_656 . ?
O3 Eu1 O8 130.6(8) 3_656 . ?
O3 Eu1 O10 57.4(6) 3_656 6 ?
O3 Eu1 O21 100.7(7) 3_656 . ?
O5 Eu1 U2 123.3(5) . 3_656 ?
O5 Eu1 U3 11.7(5) . . ?
O5 Eu1 Eu1 89.2(5) . 3_656 ?
O5 Eu1 Eu2 96.2(5) . . ?
O5 Eu1 O7 73.6(7) . . ?
O5 Eu1 O8 84.6(7) . . ?
O5 Eu1 O10 62.8(6) . 6 ?
O7 Eu1 U2 140.3(5) . 3_656 ?
O7 Eu1 U3 63.7(5) . . ?
O7 Eu1 Eu1 55.0(5) . 3_656 ?
O7 Eu1 Eu2 127.5(5) . . ?
O7 Eu1 O10 123.1(6) . 6 ?
O8 Eu1 U2 127.9(5) . 3_656 ?
O8 Eu1 U3 78.3(5) . . ?
O8 Eu1 Eu1 140.6(5) . 3_656 ?
O8 Eu1 Eu2 41.4(5) . . ?
O8 Eu1 O7 86.1(7) . . ?
O8 Eu1 O10 122.0(7) . 6 ?
O10 Eu1 U2 60.6(4) 6 3_656 ?
O10 Eu1 U3 74.4(4) 6 . ?
O10 Eu1 Eu1 88.5(4) 6 3_656 ?
O10 Eu1 Eu2 93.2(5) 6 . ?
O20 Eu1 U2 79.4(2) . 3_656 ?
O20 Eu1 U3 78.7(3) . . ?
O20 Eu1 Eu1 23.8(8) . 3_656 ?
O20 Eu1 Eu2 158.1(7) . . ?
O20 Eu1 O3 76.6(6) . 3_656 ?
O20 Eu1 O5 75.5(7) . . ?
O20 Eu1 O7 70.3(7) . . ?
O20 Eu1 O8 152.5(5) . . ?
O20 Eu1 O10 64.9(9) . 6 ?
O20 Eu1 O21 109.2(9) . . ?
O20 Eu1 O22 124.1(9) . . ?
O21 Eu1 U2 97.8(5) . 3_656 ?
O21 Eu1 U3 126.7(5) . . ?
O21 Eu1 Eu1 86.0(5) . 3_656 ?
O21 Eu1 Eu2 90.5(6) . . ?
O21 Eu1 O5 138.4(7) . . ?
O21 Eu1 O7 69.9(7) . . ?
O21 Eu1 O8 73.8(7) . . ?
O21 Eu1 O10 157.9(6) . 6 ?
O22 Eu1 U2 74.6(5) . 3_656 ?
O22 Eu1 U3 86.0(5) . . ?
O22 Eu1 Eu1 147.5(5) . 3_656 ?
O22 Eu1 Eu2 34.1(5) . . ?
O22 Eu1 O3 74.8(7) . 3_656 ?
O22 Eu1 O5 79.0(7) . . ?
O22 Eu1 O7 144.3(7) . . ?
O22 Eu1 O8 68.8(7) . . ?
O22 Eu1 O10 59.2(7) . 6 ?
O22 Eu1 O21 122.6(8) . . ?
U4 Eu2 U4 132.49(10) 2_665 1_455 ?
Eu1 Eu2 U4 110.82(6) . 1_455 ?
Eu1 Eu2 U4 110.82(6) 3_556 2_665 ?
Eu1 Eu2 U4 71.31(6) . 2_665 ?
Eu1 Eu2 U4 71.31(6) 3_556 1_455 ?
Eu1 Eu2 Eu1 175.01(17) 3_556 . ?
O2 Eu2 U4 153.0(5) 1_455 2_665 ?
O2 Eu2 U4 67.3(5) 1_455 1_455 ?
O2 Eu2 U4 67.3(5) 3_656 2_665 ?
O2 Eu2 U4 153.0(5) 3_656 1_455 ?
O2 Eu2 Eu1 84.8(5) 1_455 . ?
O2 Eu2 Eu1 92.1(5) 3_656 . ?
O2 Eu2 Eu1 92.1(5) 1_455 3_556 ?
O2 Eu2 Eu1 84.8(5) 3_656 3_556 ?
O2 Eu2 O2 102.2(10) 1_455 3_656 ?
O2 Eu2 O6 77.3(7) 1_455 4_466 ?
O2 Eu2 O6 77.3(7) 3_656 2_665 ?
O2 Eu2 O6 144.3(7) 3_656 4_466 ?
O2 Eu2 O6 144.3(7) 1_455 2_665 ?
O6 Eu2 U4 14.1(5) 2_665 2_665 ?
O6 Eu2 U4 14.1(5) 4_466 1_455 ?
O6 Eu2 U4 126.2(5) 2_665 1_455 ?
O6 Eu2 U4 126.2(5) 4_466 2_665 ?
O6 Eu2 Eu1 59.7(5) 4_466 3_556 ?
O6 Eu2 Eu1 123.0(5) 4_466 . ?
O6 Eu2 Eu1 123.0(5) 2_665 3_556 ?
O6 Eu2 Eu1 59.7(5) 2_665 . ?
O6 Eu2 O6 123.7(10) 2_665 4_466 ?
O8 Eu2 U4 92.0(5) . 2_665 ?
O8 Eu2 U4 69.7(5) . 1_455 ?
O8 Eu2 U4 92.0(5) 3_556 1_455 ?
O8 Eu2 U4 69.7(5) 3_556 2_665 ?
O8 Eu2 Eu1 140.7(5) . 3_556 ?
O8 Eu2 Eu1 42.3(5) . . ?
O8 Eu2 Eu1 42.3(5) 3_556 3_556 ?
O8 Eu2 Eu1 140.7(5) 3_556 . ?
O8 Eu2 O2 134.4(7) . 3_656 ?
O8 Eu2 O2 77.7(7) . 1_455 ?
O8 Eu2 O2 77.7(7) 3_556 3_656 ?
O8 Eu2 O2 134.4(7) 3_556 1_455 ?
O8 Eu2 O6 80.9(7) . 4_466 ?
O8 Eu2 O6 78.0(7) . 2_665 ?
O8 Eu2 O6 80.9(7) 3_556 2_665 ?
O8 Eu2 O6 78.0(7) 3_556 4_466 ?
O8 Eu2 O8 134.4(10) . 3_556 ?
O22 Eu2 U4 85.3(5) 3_556 1_455 ?
O22 Eu2 U4 85.3(5) . 2_665 ?
O22 Eu2 U4 123.8(5) 3_556 2_665 ?
O22 Eu2 U4 123.8(5) . 1_455 ?
O22 Eu2 Eu1 141.3(6) 3_556 . ?
O22 Eu2 Eu1 33.8(5) 3_556 3_556 ?
O22 Eu2 Eu1 33.8(5) . . ?
O22 Eu2 Eu1 141.3(6) . 3_556 ?
O22 Eu2 O2 68.9(7) . 3_656 ?
O22 Eu2 O2 68.9(7) 3_556 1_455 ?
O22 Eu2 O2 67.7(7) . 1_455 ?
O22 Eu2 O2 67.7(7) 3_556 3_656 ?
O22 Eu2 O6 137.7(7) 3_556 2_665 ?
O22 Eu2 O6 79.4(7) 3_556 4_466 ?
O22 Eu2 O6 79.4(7) . 2_665 ?
O22 Eu2 O6 137.7(7) . 4_466 ?
O22 Eu2 O8 144.1(7) 3_556 . ?
O22 Eu2 O8 69.3(7) . . ?
O22 Eu2 O8 69.3(7) 3_556 3_556 ?
O22 Eu2 O8 144.1(7) . 3_556 ?
O22 Eu2 O22 107.9(11) . 3_556 ?
U1 O1 U7 138.8(11) . 3_655 ?
U1 O1 U7 109.0(9) . 1_655 ?
U7 O1 U7 111.6(9) 3_655 1_655 ?
U1 O2 Eu2 148.4(11) . 1_655 ?
U2 O3 Eu1 171.8(12) . 3_656 ?
U3 O4 U7 112.8(10) . . ?
U3 O5 Eu1 152.3(11) . . ?
U4 O6 Eu2 144.8(12) . 2_664 ?
U5 O7 Eu1 142.7(11) . . ?
U6 O8 Eu1 124.8(10) . . ?
U6 O8 Eu2 132.8(10) . . ?
Eu2 O8 Eu1 96.3(7) . . ?
U7 O10 Eu1 169.9(11) . 6_554 ?
U1 O11 U4 115.5(10) . . ?
U2 O11 U1 109.9(9) . . ?
U2 O11 U4 129.2(10) . . ?
U2 O12 U3 107.1(9) . . ?
U2 O12 U5 128.3(10) . . ?
U5 O12 U3 111.2(9) . . ?
U1 O13 U3 108.6(9) 8_456 . ?
U2 O13 U1 140.3(11) . 8_456 ?
U2 O13 U3 110.7(9) . . ?
U3 O14 U5 106.1(8) . . ?
U6 O14 U3 142.7(11) . . ?
U6 O14 U5 106.0(9) . . ?
U5 O15 U4 153.2(9) . . ?
O15 O15 U4 76.7(5) 4_566 . ?
O15 O15 U5 76.6(5) 4_566 . ?
U1 O16 U2 108.9(8) 8_456 8_456 ?
U1 O16 U3 111.9(10) 8_456 . ?
U3 O16 U2 138.0(11) . 8_456 ?
U1 O17 U3 149.6(10) 1_455 . ?
U1 O17 U7 106.7(9) 1_455 . ?
U3 O17 U7 103.7(8) . . ?
U2 O18 U7 141.7(11) 3_655 . ?
U4 O19 U1 105.9(8) 1_455 1_455 ?
U6 O19 U1 142.8(11) . 1_455 ?
U6 O19 U4 106.8(9) . 1_455 ?
Eu1 O20 Eu1 132.3(15) 3_656 . ?
Eu1 O22 Eu2 112.1(9) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.43(4)
2 0.57(4)

# start Validation Reply Form
_vrf_PLAT213_c2221_a             
;
PROBLEM: Atom U3              has ADP max/min Ratio .....        5.8 prolat
RESPONSE: The alert arises due to the very strong absorption around U atoms 
which could not be corrected properly as the result of only one-circle data 
collected on the MX2 beamline at the Australian Synchrotron.
;
_vrf_PLAT306_c2221_a             
;
PROBLEM: Isolated Oxygen Atom (H-atoms Missing ?) .......        O23 Check 
RESPONSE: The alert arises due to no hydrogen atoms being added to the 
lattice water molecule.
;
# end Validation Reply Form
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_c2221_a_CCDC1
_database_code_depnum_ccdc_archive 'CCDC 2022147'
loop_
_audit_author_name
_audit_author_address
'Yingjie Zhang'
;Australian Nuclear Science and Technology Organisation
Australia
;
_audit_update_record             
;
2020-08-07 deposited with the CCDC.	2020-10-23 downloaded from the CCDC.
;
_audit_creation_date             2020-02-28
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Gd O21.5 U5.5, 0.5(O)'
_chemical_formula_sum            'Gd O22 U5.50'
_chemical_formula_weight         1818.42
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           20
_space_group_name_H-M_alt        'C 2 2 21'
_space_group_name_Hall           'C 2c 2'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z+1/2'
'-x, y, -z+1/2'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   11.624(2)
_cell_length_b                   20.972(4)
_cell_length_c                   14.181(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3457.1(12)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    18000
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      24.996
_cell_measurement_theta_min      1.943
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    55.230
_exptl_absorpt_correction_T_max  0.4345
_exptl_absorpt_correction_T_min  0.2692
_exptl_absorpt_correction_type   multi-scans
_exptl_absorpt_process_details   
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.1542 before and 0.0666 after correction.
The Ratio of minimum to maximum transmission is 0.6196.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    6.988
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needles
_exptl_crystal_F_000             5968
_exptl_crystal_size_max          0.008
_exptl_crystal_size_mid          0.003
_exptl_crystal_size_min          0.003
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0564
_diffrn_reflns_av_unetI/netI     0.0341
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            20979
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        24.996
_diffrn_reflns_theta_max         24.996
_diffrn_reflns_theta_min         1.943
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_type           
'silicon double crystal monochromated synchrotron'
_diffrn_source                   'Australian Synchrotron MX2'
_diffrn_measurement_device_type  'Eiga Detector'
_diffrn_measurement_method       'π  scans'
_diffrn_radiation_wavelength     0.71089
_reflns_Friedel_coverage         0.779
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                2999
_reflns_number_total             3047
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_data_collection       'BlueIce (McPhillips, et al., 2002)'
_computing_cell_refinement       'XDS (Kabsch, 1993)'
_computing_data_reduction        'XDS (Kabsch, 1993)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         9.829
_refine_diff_density_min         -4.234
_refine_diff_density_rms         0.749
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.51(4)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     139
_refine_ls_number_reflns         3047
_refine_ls_number_restraints     504
_refine_ls_R_factor_all          0.0435
_refine_ls_R_factor_gt           0.0431
_refine_ls_restrained_S_all      1.022
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0605P)²+459.9814P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1129
_refine_ls_wR_factor_ref         0.1136
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.49(4)
 0.51(4)
2. Uiso/Uaniso restraints and constraints
Uanis(O1) = Uanis(O2) = Uanis(O3) = Uanis(O4) = Uanis(O5) = Uanis(O6) =
Uanis(O7) = Uanis(O8) = Uanis(O9) = Uanis(O10) = Uanis(O11) = Uanis(O12) =
Uanis(O13) = Uanis(O14) = Uanis(O15) = Uanis(O16) = Uanis(O17) = Uanis(O18) =
Uanis(O19) = Uanis(O20) = Uanis(O21) = Uanis(O22)
3. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Fixed Sof: Gd1(0.65) Gd2(0.35)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
U1 U 0.98888(9) 0.32908(5) 0.48102(7) 0.0039(3) Uani 1 1 d . U . . .
U2 U 0.67580(9) 0.33983(4) 0.48004(7) 0.0042(3) Uani 1 1 d . U . . .
U3 U 0.35807(9) 0.32939(5) 0.47515(7) 0.0055(3) Uani 1 1 d . U . . .
U4 U 0.86947(13) 0.5000 0.5000 0.0076(4) Uani 1 2 d S TU P . .
U5 U 0.47773(13) 0.5000 0.5000 0.0060(4) Uani 1 2 d S TU P . .
U6 U 0.17334(14) 0.5000 0.5000 0.0052(3) Uani 1 2 d S TU P . .
U7 U 0.17127(9) 0.32084(5) 0.27368(7) 0.0082(3) Uani 1 1 d . U . . .
Gd1 Gd 0.3277(3) 0.40942(13) 0.74054(18) 0.0254(6) Uani 0.65 1 d . U . . .
Gd2 Gd 0.0000 0.41784(18) 0.7500 0.0257(8) Uani 0.7 2 d S TU P . .
O1 O 0.9773(19) 0.3178(11) 0.3441(16) 0.0157(9) Uani 1 1 d . U . . .
O2 O 1.0087(19) 0.3416(10) 0.6076(16) 0.0157(9) Uani 1 1 d . U . . .
O3 O 0.669(2) 0.3650(10) 0.6056(14) 0.0157(9) Uani 1 1 d . U . . .
O4 O 0.3626(18) 0.3215(11) 0.3448(15) 0.0157(9) Uani 1 1 d . U . . .
O5 O 0.3425(19) 0.3406(10) 0.6022(15) 0.0157(9) Uani 1 1 d . U . . .
O6 O 0.8741(19) 0.5229(11) 0.3780(16) 0.0157(9) Uani 1 1 d . U . . .
O7 O 0.4687(19) 0.4704(11) 0.6194(17) 0.0157(9) Uani 1 1 d . U . . .
O8 O 0.178(2) 0.4628(10) 0.6496(15) 0.0157(9) Uani 1 1 d . U . . .
O9 O 0.169(2) 0.4072(10) 0.2698(15) 0.0157(9) Uani 1 1 d . U . . .
O10 O 0.169(2) 0.2372(9) 0.2731(15) 0.0157(9) Uani 1 1 d . U . . .
O11 O 0.834(2) 0.3955(10) 0.4654(15) 0.0157(9) Uani 1 1 d . U . . .
O12 O 0.5174(19) 0.3971(10) 0.4517(17) 0.0157(9) Uani 1 1 d . U . . .
O13 O 0.5281(19) 0.2752(10) 0.4984(17) 0.0157(9) Uani 1 1 d . U . . .
O14 O 0.3043(19) 0.4407(10) 0.4714(15) 0.0157(9) Uani 1 1 d . U . . .
O15 O 0.6763(19) 0.4944(10) 0.5355(14) 0.0157(9) Uani 1 1 d . U . . .
O16 O 0.323(2) 0.2249(10) 0.4916(15) 0.0157(9) Uani 1 1 d . U . . .
O17 O 0.1722(19) 0.3279(10) 0.4383(14) 0.0157(9) Uani 1 1 d . U . . .
O18 O 0.3097(19) 0.3207(11) 0.1473(15) 0.0157(9) Uani 1 1 d . U . . .
O19 O 0.0460(19) 0.4416(10) 0.4753(16) 0.0157(9) Uani 1 1 d . U . . .
O20 O 0.5000 0.3696(15) 0.7500 0.0157(9) Uani 1 2 d S TU P . .
O21 O 0.338(2) 0.5101(10) 0.7900(15) 0.0157(9) Uani 1 1 d . U . . .
O22 O 0.163(2) 0.3532(10) 0.7554(14) 0.0157(9) Uani 1 1 d . U . . .
O23 O 0.5000 0.5837(18) 0.7500 0.031(9) Uiso 1 2 d S TU P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
U1 U2 3.6462(15) . ?
U1 U3 3.7073(14) 8_556 ?
U1 U4 3.8533(13) . ?
U1 U7 4.0671(17) 3_655 ?
U1 U7 3.6290(15) 1_655 ?
U1 O1 1.96(2) . ?
U1 O2 1.83(2) . ?
U1 O11 2.28(2) . ?
U1 O13 2.25(2) 8_556 ?
U1 O16 2.27(2) 8_556 ?
U1 O17 2.22(2) 1_655 ?
U1 O19 2.45(2) 1_655 ?
U2 U3 3.7004(16) . ?
U2 U4 4.0537(14) . ?
U2 U5 4.0823(15) . ?
U2 U7 4.0330(15) 3_655 ?
U2 O3 1.86(2) . ?
U2 O11 2.19(2) . ?
U2 O12 2.24(2) . ?
U2 O13 2.20(2) . ?
U2 O16 2.23(2) 8_556 ?
U2 O18 1.86(2) 3_655 ?
U3 U1 3.7072(14) 8_456 ?
U3 U5 3.8550(13) . ?
U3 U7 3.5930(15) . ?
U3 O4 1.86(2) . ?
U3 O5 1.83(2) . ?
U3 O12 2.36(2) . ?
U3 O13 2.30(2) . ?
U3 O14 2.42(2) . ?
U3 O16 2.24(2) . ?
U3 O17 2.22(2) . ?
U4 U1 3.8533(13) 4_566 ?
U4 U6 3.532(2) 1_655 ?
U4 O6 1.80(2) . ?
U4 O6 1.80(2) 4_566 ?
U4 O11 2.28(2) 4_566 ?
U4 O11 2.28(2) . ?
U4 O15 2.30(2) . ?
U4 O15 2.30(2) 4_566 ?
U4 O19 2.41(2) 1_655 ?
U4 O19 2.41(2) 4_666 ?
U5 U2 4.0823(15) 4_566 ?
U5 U3 3.8550(13) 4_566 ?
U5 U6 3.538(2) . ?
U5 O7 1.81(2) 4_566 ?
U5 O7 1.81(2) . ?
U5 O12 2.31(2) . ?
U5 O12 2.31(2) 4_566 ?
U5 O14 2.40(2) 4_566 ?
U5 O14 2.40(2) . ?
U5 O15 2.37(2) . ?
U5 O15 2.37(2) 4_566 ?
U6 U4 3.532(2) 1_455 ?
U6 O8 2.26(2) . ?
U6 O8 2.26(2) 4_566 ?
U6 O14 2.01(2) . ?
U6 O14 2.01(2) 4_566 ?
U6 O19 1.95(2) . ?
U6 O19 1.95(2) 4_566 ?
U7 U1 3.6290(15) 1_455 ?
U7 U1 4.0670(17) 3_655 ?
U7 U2 4.0330(15) 3_655 ?
U7 U7 4.038(2) 3 ?
U7 O1 2.40(2) 3_655 ?
U7 O1 2.47(2) 1_455 ?
U7 O4 2.44(2) . ?
U7 O9 1.81(2) . ?
U7 O10 1.75(2) . ?
U7 O17 2.34(2) . ?
U7 O18 2.41(2) . ?
Gd1 Gd1 4.014(6) 3_656 ?
Gd1 Gd2 3.816(3) . ?
Gd1 O3 2.37(2) 3_656 ?
Gd1 O5 2.44(2) . ?
Gd1 O7 2.70(2) . ?
Gd1 O8 2.44(2) . ?
Gd1 O20 2.174(13) . ?
Gd1 O21 2.23(2) . ?
Gd1 O22 2.26(2) . ?
Gd2 Gd1 3.816(3) 3_556 ?
Gd2 O2 2.58(2) 1_455 ?
Gd2 O2 2.58(2) 3_656 ?
Gd2 O6 2.64(2) 2_665 ?
Gd2 O6 2.64(2) 4_466 ?
Gd2 O8 2.68(2) 3_556 ?
Gd2 O8 2.68(2) . ?
Gd2 O22 2.33(2) 3_556 ?
Gd2 O22 2.33(2) . ?
O1 U7 2.40(2) 3_655 ?
O1 U7 2.47(2) 1_655 ?
O2 Gd2 2.58(2) 1_655 ?
O3 Gd1 2.37(2) 3_656 ?
O6 Gd2 2.64(2) 2_664 ?
O13 U1 2.25(2) 8_456 ?
O15 O15 1.03(4) 4_566 ?
O16 U1 2.27(2) 8_456 ?
O16 U2 2.23(2) 8_456 ?
O17 U1 2.22(2) 1_455 ?
O18 U2 1.86(2) 3_655 ?
O19 U1 2.45(2) 1_455 ?
O19 U4 2.41(2) 1_455 ?
O20 Gd1 2.174(12) 3_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
U2 U1 U3 69.31(3) . 8_556 ?
U2 U1 U4 65.37(3) . . ?
U2 U1 U7 62.77(3) . 3_655 ?
U3 U1 U4 132.42(4) 8_556 . ?
U3 U1 U7 85.59(3) 8_556 3_655 ?
U4 U1 U7 86.37(3) . 3_655 ?
U7 U1 U2 125.66(4) 1_655 . ?
U7 U1 U3 109.44(3) 1_655 8_556 ?
U7 U1 U4 108.14(3) 1_655 . ?
U7 U1 U7 62.99(4) 1_655 3_655 ?
O1 U1 U2 86.3(6) . . ?
O1 U1 U3 91.7(7) . 8_556 ?
O1 U1 U4 99.0(6) . . ?
O1 U1 U7 39.8(7) . 1_655 ?
O1 U1 U7 23.6(6) . 3_655 ?
O1 U1 O11 85.6(8) . . ?
O1 U1 O13 91.5(9) . 8_556 ?
O1 U1 O16 92.9(8) . 8_556 ?
O1 U1 O17 78.1(8) . 1_655 ?
O1 U1 O19 95.8(9) . 1_655 ?
O2 U1 U2 96.9(7) . . ?
O2 U1 U3 90.9(7) . 8_556 ?
O2 U1 U4 81.0(7) . . ?
O2 U1 U7 136.8(7) . 1_655 ?
O2 U1 U7 159.3(7) . 3_655 ?
O2 U1 O1 176.4(10) . . ?
O2 U1 O11 96.1(9) . . ?
O2 U1 O13 89.2(9) . 8_556 ?
O2 U1 O16 90.6(9) . 8_556 ?
O2 U1 O17 98.6(9) . 1_655 ?
O2 U1 O19 82.0(9) . 1_655 ?
O11 U1 U2 34.6(6) . . ?
O11 U1 U3 103.9(6) . 8_556 ?
O11 U1 U4 32.4(5) . . ?
O11 U1 U7 114.2(5) . 1_655 ?
O11 U1 U7 65.2(5) . 3_655 ?
O11 U1 O19 67.8(7) . 1_655 ?
O13 U1 U2 105.2(6) 8_556 . ?
O13 U1 U3 36.0(6) 8_556 8_556 ?
O13 U1 U4 165.2(6) 8_556 . ?
O13 U1 U7 99.6(6) 8_556 3_655 ?
O13 U1 U7 86.6(6) 8_556 1_655 ?
O13 U1 O11 139.8(8) 8_556 . ?
O13 U1 O16 70.4(8) 8_556 8_556 ?
O13 U1 O19 152.1(8) 8_556 1_655 ?
O16 U1 U2 35.3(5) 8_556 . ?
O16 U1 U3 34.4(5) 8_556 8_556 ?
O16 U1 U4 98.5(5) 8_556 . ?
O16 U1 U7 127.7(5) 8_556 1_655 ?
O16 U1 U7 75.1(5) 8_556 3_655 ?
O16 U1 O11 69.7(8) 8_556 . ?
O16 U1 O19 135.8(8) 8_556 1_655 ?
O17 U1 U2 163.7(5) 1_655 . ?
O17 U1 U3 115.5(5) 1_655 8_556 ?
O17 U1 U4 112.1(5) 1_655 . ?
O17 U1 U7 38.4(5) 1_655 1_655 ?
O17 U1 U7 101.4(5) 1_655 3_655 ?
O17 U1 O11 137.5(8) 1_655 . ?
O17 U1 O13 80.2(8) 1_655 8_556 ?
O17 U1 O16 149.1(8) 1_655 8_556 ?
O17 U1 O19 75.0(7) 1_655 1_655 ?
O19 U1 U2 102.1(5) 1_655 . ?
O19 U1 U3 168.3(5) 1_655 8_556 ?
O19 U1 U4 37.3(5) 1_655 . ?
O19 U1 U7 97.8(5) 1_655 3_655 ?
O19 U1 U7 82.0(5) 1_655 1_655 ?
U1 U2 U3 173.01(4) . . ?
U1 U2 U4 59.78(3) . . ?
U1 U2 U5 127.84(4) . . ?
U1 U2 U7 63.73(3) . 3_655 ?
U3 U2 U4 127.20(4) . . ?
U3 U2 U5 59.14(3) . . ?
U3 U2 U7 114.67(3) . 3_655 ?
U4 U2 U5 68.07(3) . . ?
U7 U2 U4 84.22(3) 3_655 . ?
U7 U2 U5 113.06(3) 3_655 . ?
O3 U2 U1 93.2(7) . . ?
O3 U2 U3 89.6(7) . . ?
O3 U2 U4 73.8(7) . . ?
O3 U2 U5 71.2(7) . . ?
O3 U2 U7 154.3(7) . 3_655 ?
O3 U2 O11 88.5(9) . . ?
O3 U2 O12 89.2(9) . . ?
O3 U2 O13 91.7(9) . . ?
O3 U2 O16 91.8(9) . 8_556 ?
O11 U2 U1 36.3(6) . . ?
O11 U2 U3 150.3(6) . . ?
O11 U2 U4 25.6(6) . . ?
O11 U2 U5 92.4(6) . . ?
O11 U2 U7 66.3(6) . 3_655 ?
O11 U2 O12 112.9(8) . . ?
O11 U2 O13 174.0(8) . . ?
O11 U2 O16 72.2(8) . 8_556 ?
O12 U2 U1 148.9(6) . . ?
O12 U2 U3 37.5(6) . . ?
O12 U2 U4 91.4(6) . . ?
O12 U2 U5 26.6(6) . . ?
O12 U2 U7 104.8(6) . 3_655 ?
O13 U2 U1 137.7(6) . . ?
O13 U2 U3 35.7(6) . . ?
O13 U2 U4 159.1(6) . . ?
O13 U2 U5 93.4(6) . . ?
O13 U2 U7 112.8(6) . 3_655 ?
O13 U2 O12 73.1(8) . . ?
O13 U2 O16 101.8(8) . 8_556 ?
O16 U2 U1 36.1(6) 8_556 . ?
O16 U2 U3 137.5(6) 8_556 . ?
O16 U2 U4 93.7(6) 8_556 . ?
O16 U2 U5 157.6(6) 8_556 . ?
O16 U2 U7 76.2(5) 8_556 3_655 ?
O16 U2 O12 174.8(8) 8_556 . ?
O18 U2 U1 84.2(7) 3_655 . ?
O18 U2 U3 93.4(7) 3_655 . ?
O18 U2 U4 101.3(7) 3_655 . ?
O18 U2 U5 107.2(7) 3_655 . ?
O18 U2 U7 21.8(7) 3_655 3_655 ?
O18 U2 O3 175.1(10) 3_655 . ?
O18 U2 O11 86.9(9) 3_655 . ?
O18 U2 O12 90.9(9) 3_655 . ?
O18 U2 O13 93.0(9) 3_655 . ?
O18 U2 O16 88.5(9) 3_655 8_556 ?
U1 U3 U5 131.97(4) 8_456 . ?
U2 U3 U1 68.93(3) . 8_456 ?
U2 U3 U5 65.37(3) . . ?
U7 U3 U1 109.66(3) . 8_456 ?
U7 U3 U2 128.39(4) . . ?
U7 U3 U5 109.70(3) . . ?
O4 U3 U1 94.3(7) . 8_456 ?
O4 U3 U2 89.7(7) . . ?
O4 U3 U5 99.4(7) . . ?
O4 U3 U7 38.8(7) . . ?
O4 U3 O12 83.7(9) . . ?
O4 U3 O13 94.2(9) . . ?
O4 U3 O14 94.1(9) . . ?
O4 U3 O16 91.3(9) . . ?
O4 U3 O17 78.0(8) . . ?
O5 U3 U1 89.5(7) . 8_456 ?
O5 U3 U2 94.2(7) . . ?
O5 U3 U5 80.0(7) . . ?
O5 U3 U7 137.0(7) . . ?
O5 U3 O4 175.3(10) . . ?
O5 U3 O12 98.0(9) . . ?
O5 U3 O13 90.4(9) . . ?
O5 U3 O14 82.6(8) . . ?
O5 U3 O16 90.3(9) . . ?
O5 U3 O17 97.9(9) . . ?
O12 U3 U1 104.0(5) . 8_456 ?
O12 U3 U2 35.2(5) . . ?
O12 U3 U5 33.9(5) . . ?
O12 U3 U7 113.1(6) . . ?
O12 U3 O14 67.6(7) . . ?
O13 U3 U1 35.1(5) . 8_456 ?
O13 U3 U2 33.9(6) . . ?
O13 U3 U5 97.8(6) . . ?
O13 U3 U7 127.4(6) . . ?
O13 U3 O12 69.1(8) . . ?
O13 U3 O14 134.6(8) . . ?
O14 U3 U1 167.3(5) . 8_456 ?
O14 U3 U2 101.6(5) . . ?
O14 U3 U5 36.8(5) . . ?
O14 U3 U7 82.8(5) . . ?
O16 U3 U1 34.8(6) . 8_456 ?
O16 U3 U2 103.6(6) . . ?
O16 U3 U5 164.4(6) . . ?
O16 U3 U7 85.7(6) . . ?
O16 U3 O12 138.2(8) . . ?
O16 U3 O13 69.9(8) . . ?
O16 U3 O14 154.2(8) . . ?
O17 U3 U1 115.2(5) . 8_456 ?
O17 U3 U2 167.2(5) . . ?
O17 U3 U5 112.7(5) . . ?
O17 U3 U7 39.2(5) . . ?
O17 U3 O12 137.6(7) . . ?
O17 U3 O13 149.4(8) . . ?
O17 U3 O14 75.9(7) . . ?
O17 U3 O16 80.6(8) . . ?
U1 U4 U1 137.78(6) . 4_566 ?
U1 U4 U2 167.37(5) 4_566 . ?
U1 U4 U2 54.85(2) . . ?
U6 U4 U1 68.89(3) 1_655 . ?
U6 U4 U1 68.89(3) 1_655 4_566 ?
U6 U4 U2 123.74(2) 1_655 . ?
O6 U4 U1 99.9(7) . . ?
O6 U4 U1 78.9(7) . 4_566 ?
O6 U4 U1 99.9(7) 4_566 4_566 ?
O6 U4 U1 78.9(7) 4_566 . ?
O6 U4 U2 82.1(7) 4_566 . ?
O6 U4 U2 99.9(7) . . ?
O6 U4 U6 88.3(7) . 1_655 ?
O6 U4 U6 88.3(7) 4_566 1_655 ?
O6 U4 O6 176.6(14) . 4_566 ?
O6 U4 O11 93.2(9) . . ?
O6 U4 O11 87.4(9) . 4_566 ?
O6 U4 O11 87.4(9) 4_566 . ?
O6 U4 O11 93.2(9) 4_566 4_566 ?
O6 U4 O15 104.7(9) 4_566 4_566 ?
O6 U4 O15 78.7(9) . 4_566 ?
O6 U4 O15 104.7(9) . . ?
O6 U4 O15 78.7(9) 4_566 . ?
O6 U4 O19 88.3(9) 4_566 4_666 ?
O6 U4 O19 88.8(9) 4_566 1_655 ?
O6 U4 O19 88.8(9) . 4_666 ?
O6 U4 O19 88.3(9) . 1_655 ?
O11 U4 U1 32.5(6) . . ?
O11 U4 U1 32.5(6) 4_566 4_566 ?
O11 U4 U1 166.6(6) 4_566 . ?
O11 U4 U1 166.6(6) . 4_566 ?
O11 U4 U2 24.5(6) . . ?
O11 U4 U2 135.3(6) 4_566 . ?
O11 U4 U6 100.3(6) . 1_655 ?
O11 U4 U6 100.3(6) 4_566 1_655 ?
O11 U4 O11 159.4(12) . 4_566 ?
O11 U4 O15 79.8(8) . . ?
O11 U4 O15 79.8(8) 4_566 4_566 ?
O11 U4 O15 80.1(8) . 4_566 ?
O11 U4 O15 80.1(8) 4_566 . ?
O11 U4 O19 132.1(8) . 4_666 ?
O11 U4 O19 132.1(8) 4_566 1_655 ?
O11 U4 O19 68.5(8) 4_566 4_666 ?
O11 U4 O19 68.5(8) . 1_655 ?
O15 U4 U1 112.5(5) . 4_566 ?
O15 U4 U1 108.6(5) . . ?
O15 U4 U1 112.5(5) 4_566 . ?
O15 U4 U1 108.6(5) 4_566 4_566 ?
O15 U4 U2 55.4(5) . . ?
O15 U4 U2 59.1(5) 4_566 . ?
O15 U4 U6 167.0(5) . 1_655 ?
O15 U4 U6 167.0(5) 4_566 1_655 ?
O15 U4 O15 25.9(10) 4_566 . ?
O15 U4 O19 145.3(7) 4_566 1_655 ?
O15 U4 O19 146.5(7) . 1_655 ?
O15 U4 O19 145.3(7) . 4_666 ?
O15 U4 O19 146.5(7) 4_566 4_666 ?
O19 U4 U1 100.1(5) 1_655 4_566 ?
O19 U4 U1 38.0(5) 4_666 4_566 ?
O19 U4 U1 38.0(5) 1_655 . ?
O19 U4 U1 100.1(5) 4_666 . ?
O19 U4 U2 154.4(5) 4_666 . ?
O19 U4 U2 92.4(5) 1_655 . ?
O19 U4 U6 31.8(5) 1_655 1_655 ?
O19 U4 U6 31.8(5) 4_666 1_655 ?
O19 U4 O19 63.7(10) 4_666 1_655 ?
U3 U5 U2 166.80(5) . 4_566 ?
U3 U5 U2 55.49(2) 4_566 4_566 ?
U3 U5 U3 137.70(5) 4_566 . ?
U6 U5 U2 124.33(3) . 4_566 ?
U6 U5 U3 68.85(3) . 4_566 ?
U6 U5 U3 68.85(3) . . ?
O7 U5 U2 104.5(7) . 4_566 ?
O7 U5 U2 79.3(7) 4_566 4_566 ?
O7 U5 U3 75.3(7) 4_566 4_566 ?
O7 U5 U3 75.3(7) . . ?
O7 U5 U3 102.2(7) 4_566 . ?
O7 U5 U3 102.2(7) . 4_566 ?
O7 U5 U6 86.7(7) 4_566 . ?
O7 U5 U6 86.7(7) . . ?
O7 U5 O7 173.4(14) 4_566 . ?
O7 U5 O12 88.2(9) . . ?
O7 U5 O12 93.1(9) 4_566 . ?
O7 U5 O12 93.1(9) . 4_566 ?
O7 U5 O12 88.2(9) 4_566 4_566 ?
O7 U5 O14 86.1(9) . . ?
O7 U5 O14 86.1(9) 4_566 4_566 ?
O7 U5 O14 88.3(9) 4_566 . ?
O7 U5 O14 88.3(9) . 4_566 ?
O7 U5 O15 105.8(9) . 4_566 ?
O7 U5 O15 80.8(9) 4_566 4_566 ?
O7 U5 O15 80.8(9) . . ?
O7 U5 O15 105.8(9) 4_566 . ?
O12 U5 U2 132.6(6) . 4_566 ?
O12 U5 U2 25.6(6) 4_566 4_566 ?
O12 U5 U3 165.0(6) 4_566 . ?
O12 U5 U3 34.7(6) . . ?
O12 U5 U3 165.0(6) . 4_566 ?
O12 U5 U3 34.7(6) 4_566 4_566 ?
O12 U5 U6 101.5(6) . . ?
O12 U5 U6 101.5(6) 4_566 . ?
O12 U5 O12 157.0(11) 4_566 . ?
O12 U5 O14 134.5(8) 4_566 . ?
O12 U5 O14 68.5(8) 4_566 4_566 ?
O12 U5 O14 68.5(8) . . ?
O12 U5 O14 134.5(8) . 4_566 ?
O12 U5 O15 77.8(8) 4_566 . ?
O12 U5 O15 79.7(8) . . ?
O12 U5 O15 77.8(7) . 4_566 ?
O12 U5 O15 79.7(8) 4_566 4_566 ?
O14 U5 U2 155.6(5) . 4_566 ?
O14 U5 U2 92.0(5) 4_566 4_566 ?
O14 U5 U3 37.0(5) 4_566 4_566 ?
O14 U5 U3 101.1(5) . 4_566 ?
O14 U5 U3 101.1(5) 4_566 . ?
O14 U5 U3 37.0(5) . . ?
O14 U5 U6 33.0(5) . . ?
O14 U5 U6 33.0(5) 4_566 . ?
O14 U5 O14 66.0(10) 4_566 . ?
O15 U5 U2 54.8(5) 4_566 4_566 ?
O15 U5 U2 58.4(5) . 4_566 ?
O15 U5 U3 109.0(5) 4_566 4_566 ?
O15 U5 U3 112.3(5) 4_566 . ?
O15 U5 U3 109.0(5) . . ?
O15 U5 U3 112.3(5) . 4_566 ?
O15 U5 U6 167.4(5) . . ?
O15 U5 U6 167.4(5) 4_566 . ?
O15 U5 O14 146.0(7) . . ?
O15 U5 O14 143.9(7) 4_566 . ?
O15 U5 O14 146.0(7) 4_566 4_566 ?
O15 U5 O14 143.9(7) . 4_566 ?
O15 U5 O15 25.3(10) . 4_566 ?
U4 U6 U5 180.0 1_455 . ?
O8 U6 U4 91.4(6) 4_566 1_455 ?
O8 U6 U4 91.4(6) . 1_455 ?
O8 U6 U5 88.6(6) 4_566 . ?
O8 U6 U5 88.6(6) . . ?
O8 U6 O8 177.2(12) 4_566 . ?
O14 U6 U4 139.3(6) . 1_455 ?
O14 U6 U4 139.3(6) 4_566 1_455 ?
O14 U6 U5 40.7(6) 4_566 . ?
O14 U6 U5 40.7(6) . . ?
O14 U6 O8 90.3(8) . 4_566 ?
O14 U6 O8 90.3(8) 4_566 . ?
O14 U6 O8 87.6(9) . . ?
O14 U6 O8 87.6(9) 4_566 4_566 ?
O14 U6 O14 81.4(12) . 4_566 ?
O19 U6 U4 40.7(6) . 1_455 ?
O19 U6 U4 40.7(6) 4_566 1_455 ?
O19 U6 U5 139.3(6) 4_566 . ?
O19 U6 U5 139.3(6) . . ?
O19 U6 O8 88.3(9) 4_566 4_566 ?
O19 U6 O8 88.3(9) . . ?
O19 U6 O8 93.8(9) 4_566 . ?
O19 U6 O8 93.8(9) . 4_566 ?
O19 U6 O14 98.6(9) 4_566 4_566 ?
O19 U6 O14 178.6(10) . 4_566 ?
O19 U6 O14 178.6(10) 4_566 . ?
O19 U6 O14 98.6(9) . . ?
O19 U6 O19 81.4(13) . 4_566 ?
U1 U7 U1 116.75(4) 1_455 3_655 ?
U1 U7 U2 167.33(4) 1_455 3_655 ?
U1 U7 U7 63.81(3) 1_455 3 ?
U2 U7 U1 53.50(3) 3_655 3_655 ?
U2 U7 U7 106.63(4) 3_655 3 ?
U3 U7 U1 72.93(3) . 1_455 ?
U3 U7 U1 168.71(4) . 3_655 ?
U3 U7 U2 115.98(4) . 3_655 ?
U3 U7 U7 136.74(5) . 3 ?
U7 U7 U1 53.20(3) 3 3_655 ?
O1 U7 U1 98.3(5) 3_655 1_455 ?
O1 U7 U1 86.7(5) 1_455 3_655 ?
O1 U7 U1 19.1(5) 3_655 3_655 ?
O1 U7 U1 30.6(5) 1_455 1_455 ?
O1 U7 U2 140.0(5) 1_455 3_655 ?
O1 U7 U2 72.5(5) 3_655 3_655 ?
O1 U7 U3 171.2(5) 3_655 . ?
O1 U7 U3 103.4(5) 1_455 . ?
O1 U7 U7 33.5(5) 1_455 3 ?
O1 U7 U7 34.5(5) 3_655 3 ?
O1 U7 O1 67.9(9) 3_655 1_455 ?
O1 U7 O4 160.3(7) 3_655 . ?
O1 U7 O18 87.9(7) 3_655 . ?
O4 U7 U1 101.4(5) . 1_455 ?
O4 U7 U1 141.6(5) . 3_655 ?
O4 U7 U2 88.1(5) . 3_655 ?
O4 U7 U3 28.5(5) . . ?
O4 U7 U7 165.2(5) . 3 ?
O4 U7 O1 131.7(7) . 1_455 ?
O9 U7 U1 85.7(7) . 3_655 ?
O9 U7 U1 88.2(7) . 1_455 ?
O9 U7 U2 83.1(7) . 3_655 ?
O9 U7 U3 89.0(7) . . ?
O9 U7 U7 88.9(8) . 3 ?
O9 U7 O1 89.7(9) . 3_655 ?
O9 U7 O1 91.5(9) . 1_455 ?
O9 U7 O4 91.1(9) . . ?
O9 U7 O17 88.1(8) . . ?
O9 U7 O18 89.3(9) . . ?
O10 U7 U1 92.3(7) . 1_455 ?
O10 U7 U1 91.7(7) . 3_655 ?
O10 U7 U2 95.9(7) . 3_655 ?
O10 U7 U3 93.7(7) . . ?
O10 U7 U7 88.9(8) . 3 ?
O10 U7 O1 87.6(9) . 3_655 ?
O10 U7 O1 87.7(9) . 1_455 ?
O10 U7 O4 91.4(10) . . ?
O10 U7 O9 177.3(10) . . ?
O10 U7 O17 93.9(9) . . ?
O10 U7 O18 90.4(9) . . ?
O17 U7 U1 36.0(5) . 1_455 ?
O17 U7 U1 152.4(5) . 3_655 ?
O17 U7 U2 151.9(5) . 3_655 ?
O17 U7 U3 36.9(5) . . ?
O17 U7 U7 99.8(5) . 3 ?
O17 U7 O1 134.3(8) . 3_655 ?
O17 U7 O1 66.6(7) . 1_455 ?
O17 U7 O4 65.4(7) . . ?
O17 U7 O18 137.7(7) . . ?
O18 U7 U1 69.2(5) . 3_655 ?
O18 U7 U1 173.3(5) . 1_455 ?
O18 U7 U2 16.6(5) . 3_655 ?
O18 U7 U3 100.8(5) . . ?
O18 U7 U7 122.3(5) . 3 ?
O18 U7 O1 155.7(7) . 1_455 ?
O18 U7 O4 72.5(7) . . ?
Gd2 Gd1 Gd1 173.58(11) . 3_656 ?
O3 Gd1 Gd1 85.6(6) 3_656 3_656 ?
O3 Gd1 Gd2 90.1(6) 3_656 . ?
O3 Gd1 O5 120.4(7) 3_656 . ?
O3 Gd1 O7 139.7(8) 3_656 . ?
O3 Gd1 O8 132.7(8) 3_656 . ?
O5 Gd1 Gd1 89.1(5) . 3_656 ?
O5 Gd1 Gd2 97.2(5) . . ?
O5 Gd1 O7 74.1(7) . . ?
O7 Gd1 Gd1 55.7(5) . 3_656 ?
O7 Gd1 Gd2 127.4(5) . . ?
O8 Gd1 Gd1 138.4(5) . 3_656 ?
O8 Gd1 Gd2 44.4(5) . . ?
O8 Gd1 O5 84.0(7) . . ?
O8 Gd1 O7 83.0(7) . . ?
O20 Gd1 Gd1 22.6(8) . 3_656 ?
O20 Gd1 Gd2 159.3(7) . . ?
O20 Gd1 O3 77.2(6) . 3_656 ?
O20 Gd1 O5 76.0(7) . . ?
O20 Gd1 O7 70.2(7) . . ?
O20 Gd1 O8 150.0(6) . . ?
O20 Gd1 O21 107.2(9) . . ?
O20 Gd1 O22 125.1(9) . . ?
O21 Gd1 Gd1 85.7(6) . 3_656 ?
O21 Gd1 Gd2 89.9(6) . . ?
O21 Gd1 O3 94.7(7) . 3_656 ?
O21 Gd1 O5 144.0(7) . . ?
O21 Gd1 O7 73.6(7) . . ?
O21 Gd1 O8 76.7(8) . . ?
O21 Gd1 O22 120.7(8) . . ?
O22 Gd1 Gd1 147.2(5) . 3_656 ?
O22 Gd1 Gd2 34.3(5) . . ?
O22 Gd1 O3 73.9(7) . 3_656 ?
O22 Gd1 O5 80.0(7) . . ?
O22 Gd1 O7 145.3(7) . . ?
O22 Gd1 O8 71.5(7) . . ?
Gd1 Gd2 Gd1 174.69(15) . 3_556 ?
O2 Gd2 Gd1 92.2(5) 3_656 . ?
O2 Gd2 Gd1 92.2(5) 1_455 3_556 ?
O2 Gd2 Gd1 84.5(5) 1_455 . ?
O2 Gd2 Gd1 84.5(5) 3_656 3_556 ?
O2 Gd2 O2 103.3(10) 1_455 3_656 ?
O2 Gd2 O6 143.9(7) 3_656 4_466 ?
O2 Gd2 O6 77.0(7) 3_656 2_665 ?
O2 Gd2 O6 143.9(7) 1_455 2_665 ?
O2 Gd2 O6 77.0(7) 1_455 4_466 ?
O2 Gd2 O8 76.8(7) 1_455 . ?
O2 Gd2 O8 76.8(7) 3_656 3_556 ?
O2 Gd2 O8 131.6(7) 1_455 3_556 ?
O2 Gd2 O8 131.6(7) 3_656 . ?
O6 Gd2 Gd1 123.4(5) 4_466 . ?
O6 Gd2 Gd1 59.5(5) 4_466 3_556 ?
O6 Gd2 Gd1 123.4(5) 2_665 3_556 ?
O6 Gd2 Gd1 59.5(5) 2_665 . ?
O6 Gd2 O6 123.9(10) 2_665 4_466 ?
O6 Gd2 O8 76.8(7) 4_466 3_556 ?
O6 Gd2 O8 84.1(7) 4_466 . ?
O6 Gd2 O8 76.8(7) 2_665 . ?
O6 Gd2 O8 84.1(7) 2_665 3_556 ?
O8 Gd2 Gd1 143.6(5) . 3_556 ?
O8 Gd2 Gd1 39.4(5) 3_556 3_556 ?
O8 Gd2 Gd1 39.4(5) . . ?
O8 Gd2 Gd1 143.6(5) 3_556 . ?
O8 Gd2 O8 138.9(9) 3_556 . ?
O22 Gd2 Gd1 141.5(6) . 3_556 ?
O22 Gd2 Gd1 33.2(5) . . ?
O22 Gd2 Gd1 33.2(5) 3_556 3_556 ?
O22 Gd2 Gd1 141.5(6) 3_556 . ?
O22 Gd2 O2 68.5(7) 3_556 3_656 ?
O22 Gd2 O2 69.2(7) . 3_656 ?
O22 Gd2 O2 69.2(7) 3_556 1_455 ?
O22 Gd2 O2 68.4(7) . 1_455 ?
O22 Gd2 O6 78.5(7) 3_556 4_466 ?
O22 Gd2 O6 78.5(7) . 2_665 ?
O22 Gd2 O6 138.3(7) . 4_466 ?
O22 Gd2 O6 138.3(7) 3_556 2_665 ?
O22 Gd2 O8 144.5(7) 3_556 . ?
O22 Gd2 O8 66.1(7) . . ?
O22 Gd2 O8 66.1(7) 3_556 3_556 ?
O22 Gd2 O8 144.5(7) . 3_556 ?
O22 Gd2 O22 108.8(11) 3_556 . ?
U1 O1 U7 137.3(11) . 3_655 ?
U1 O1 U7 109.6(9) . 1_655 ?
U7 O1 U7 112.0(9) 3_655 1_655 ?
U1 O2 Gd2 148.6(11) . 1_655 ?
U2 O3 Gd1 172.6(12) . 3_656 ?
U3 O4 U7 112.7(10) . . ?
U3 O5 Gd1 151.2(11) . . ?
U4 O6 Gd2 143.5(11) . 2_664 ?
U5 O7 Gd1 142.7(11) . . ?
U6 O8 Gd1 132.3(11) . . ?
U6 O8 Gd2 126.9(10) . . ?
Gd1 O8 Gd2 96.2(7) . . ?
U2 O11 U1 109.1(9) . . ?
U2 O11 U4 129.9(11) . . ?
U4 O11 U1 115.1(10) . . ?
U2 O12 U3 107.3(9) . . ?
U2 O12 U5 127.8(10) . . ?
U5 O12 U3 111.3(9) . . ?
U1 O13 U3 108.9(9) 8_456 . ?
U2 O13 U1 140.4(11) . 8_456 ?
U2 O13 U3 110.4(9) . . ?
U5 O14 U3 106.2(8) . . ?
U6 O14 U3 142.2(11) . . ?
U6 O14 U5 106.3(9) . . ?
U4 O15 U5 154.4(9) . . ?
O15 O15 U4 77.0(5) 4_566 . ?
O15 O15 U5 77.4(5) 4_566 . ?
U2 O16 U1 108.6(9) 8_456 8_456 ?
U2 O16 U3 139.0(11) 8_456 . ?
U3 O16 U1 110.8(10) . 8_456 ?
U1 O17 U3 150.5(10) 1_455 . ?
U1 O17 U7 105.6(8) 1_455 . ?
U3 O17 U7 103.9(8) . . ?
U2 O18 U7 141.6(11) 3_655 . ?
U4 O19 U1 104.7(8) 1_455 1_455 ?
U6 O19 U1 143.3(11) . 1_455 ?
U6 O19 U4 107.5(9) . 1_455 ?
Gd1 O20 Gd1 134.8(15) . 3_656 ?
Gd1 O22 Gd2 112.5(9) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.49(4)
2 0.51(4)

# start Validation Reply Form
_vrf_PLAT097_c2221_a             
;
PROBLEM: Large Reported Max.  (Positive) Residual Density       9.83 eA-3  
RESPONSE: The alert arises due to the very strong absorption nature of the 
material. The one-circle goniometer set up at the Australian Synchrotron 
allows poor data redundancy to address absorption corrections effectively.
;
_vrf_PLAT306_c2221_a             
;
PROBLEM: Isolated Oxygen Atom (H-atoms Missing ?) .......        O23 Check 
RESPONSE: The alert arises due to no hydrogen fixed on the lattice water
molecule with partial occupancies.
;
# end Validation Reply Form
