# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_I
_database_code_depnum_ccdc_archive 'CCDC 1908429'
loop_
_audit_author_name
_audit_author_address
'qingfu zhang'
;liaocheng university
China
;
_audit_update_record             
;
2019-04-07 deposited with the CCDC.	2020-11-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C35 H28 N4 O7 Zn'
_chemical_formula_weight         681.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/c'
_space_group_name_Hall           '-P 2ybc'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   9.3019(7)
_cell_length_b                   11.1262(8)
_cell_length_c                   30.687(2)
_cell_angle_alpha                90
_cell_angle_beta                 94.0770(10)
_cell_angle_gamma                90
_cell_volume                     3167.9(4)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    2138
_cell_measurement_theta_min      2.65
_cell_measurement_theta_max      26.0

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.430
_exptl_crystal_F_000             1408
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.310
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.070
_exptl_absorpt_coefficient_mu    0.832
_shelx_estimated_absorpt_T_min   0.783
_shelx_estimated_absorpt_T_max   0.944
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.783
_exptl_absorpt_correction_T_max  0.944
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            15711
_diffrn_reflns_av_unetI/netI     0.1003
_diffrn_reflns_av_R_equivalents  0.0672
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_theta_min         2.647
_diffrn_reflns_theta_max         25.019
_diffrn_reflns_theta_full        25.019
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             5567
_reflns_number_gt                3182
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0537P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5567
_refine_ls_number_parameters     426
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1050
_refine_ls_R_factor_gt           0.0581
_refine_ls_wR_factor_ref         0.1510
_refine_ls_wR_factor_gt          0.1365
_refine_ls_goodness_of_fit_ref   1.077
_refine_ls_restrained_S_all      1.077
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 1.20080(7) 0.95284(5) 1.02807(2) 0.0359(2) Uani 1 1 d . . . . .
O1 O 1.1609(4) 0.8734(3) 0.97084(11) 0.0475(10) Uani 1 1 d . . . . .
O2 O 0.9865(4) 0.9989(3) 0.95009(11) 0.0412(9) Uani 1 1 d . . . . .
O3 O 1.0914(4) 0.4675(3) 0.80290(13) 0.0603(11) Uani 1 1 d . . . . .
O4 O 0.5138(4) 0.2702(3) 0.64117(13) 0.0608(11) Uani 1 1 d . . . . .
O5 O 0.1604(5) -0.2463(4) 0.55957(17) 0.0929(17) Uani 1 1 d . . . . .
O6 O 0.3494(5) -0.3672(3) 0.56491(12) 0.0596(11) Uani 1 1 d . . . . .
O7 O 0.6186(5) 0.6361(4) 0.76421(15) 0.0786(14) Uani 1 1 d . . . . .
N1 N 0.8877(5) 0.5808(4) 0.80685(14) 0.0462(12) Uani 1 1 d . . . . .
H1A H 0.789817 0.588025 0.792812 0.055 Uiso 1 1 d R U . . .
N2 N 0.6401(4) 0.0992(4) 0.65760(13) 0.0414(11) Uani 1 1 d . . . . .
H2A H 0.732851 0.073744 0.668639 0.050 Uiso 1 1 d R U . . .
N3 N 1.2986(5) 1.1157(4) 1.01849(14) 0.0427(11) Uani 1 1 d . . . . .
N4 N 0.4617(5) 0.5441(4) 0.71533(15) 0.0512(12) Uani 1 1 d . . . . .
C1 C 1.0531(6) 0.9016(5) 0.94662(16) 0.0349(12) Uani 1 1 d . . . . .
C2 C 1.0064(5) 0.8155(4) 0.91115(16) 0.0350(12) Uani 1 1 d . . . . .
C3 C 0.9091(6) 0.8494(5) 0.87688(17) 0.0457(14) Uani 1 1 d . . . . .
H3 H 0.867682 0.925458 0.877028 0.055 Uiso 1 1 calc R U . . .
C4 C 0.8728(6) 0.7723(5) 0.84268(17) 0.0499(15) Uani 1 1 d . . . . .
H4 H 0.808875 0.797027 0.819754 0.060 Uiso 1 1 calc R U . . .
C5 C 0.9322(5) 0.6574(4) 0.84252(17) 0.0392(13) Uani 1 1 d . . . . .
C6 C 1.0234(6) 0.6209(5) 0.87693(17) 0.0460(14) Uani 1 1 d . . . . .
H6 H 1.059837 0.543059 0.877697 0.055 Uiso 1 1 calc R U . . .
C7 C 1.0613(6) 0.6997(5) 0.91042(17) 0.0449(14) Uani 1 1 d . . . . .
H7 H 1.125527 0.674528 0.933202 0.054 Uiso 1 1 calc R U . . .
C8 C 0.9659(6) 0.4934(5) 0.79013(18) 0.0430(14) Uani 1 1 d . . . . .
C9 C 0.8849(5) 0.4225(4) 0.75381(16) 0.0381(13) Uani 1 1 d . . . . .
C10 C 0.8389(6) 0.3100(5) 0.76340(17) 0.0455(14) Uani 1 1 d . . . . .
H10 H 0.860383 0.277920 0.791085 0.055 Uiso 1 1 calc R U . . .
C11 C 0.7579(5) 0.2415(4) 0.73100(17) 0.0422(14) Uani 1 1 d . . . . .
H11 H 0.729705 0.163735 0.737548 0.051 Uiso 1 1 calc R U . . .
C12 C 0.7208(5) 0.2876(4) 0.69068(16) 0.0366(13) Uani 1 1 d . . . . .
C13 C 0.7684(5) 0.4038(4) 0.67940(16) 0.0372(13) Uani 1 1 d . . . . .
C14 C 0.7387(6) 0.4566(5) 0.63734(17) 0.0458(14) Uani 1 1 d . . . . .
H14 H 0.681413 0.415478 0.616213 0.055 Uiso 1 1 calc R U . . .
C15 C 0.7934(7) 0.5673(5) 0.62757(19) 0.0557(16) Uani 1 1 d . . . . .
H15 H 0.774913 0.598628 0.599632 0.067 Uiso 1 1 calc R U . . .
C16 C 0.8767(7) 0.6341(5) 0.6589(2) 0.0584(17) Uani 1 1 d . . . . .
H16 H 0.911965 0.709393 0.651873 0.070 Uiso 1 1 calc R U . . .
C17 C 0.9053(6) 0.5876(5) 0.6997(2) 0.0535(16) Uani 1 1 d . . . . .
H17 H 0.959978 0.632397 0.720380 0.064 Uiso 1 1 calc R U . . .
C18 C 0.8534(5) 0.4714(4) 0.71149(17) 0.0378(13) Uani 1 1 d . . . . .
C19 C 0.6148(6) 0.2200(5) 0.66008(17) 0.0429(14) Uani 1 1 d . . . . .
C20 C 0.5491(6) 0.0125(4) 0.63584(16) 0.0391(13) Uani 1 1 d . . . . .
C21 C 0.4049(6) 0.0320(5) 0.62304(18) 0.0519(15) Uani 1 1 d . . . . .
H21 H 0.363532 0.106419 0.628018 0.062 Uiso 1 1 calc R U . . .
C22 C 0.3229(6) -0.0573(5) 0.60312(19) 0.0556(16) Uani 1 1 d . . . . .
H22 H 0.226185 -0.042777 0.595021 0.067 Uiso 1 1 calc R U . . .
C23 C 0.3810(7) -0.1688(5) 0.59483(17) 0.0472(15) Uani 1 1 d . . . . .
C24 C 0.5253(6) -0.1898(5) 0.60767(18) 0.0501(15) Uani 1 1 d . . . . .
H24 H 0.565855 -0.264432 0.602605 0.060 Uiso 1 1 calc R U . . .
C25 C 0.6084(6) -0.1009(5) 0.62778(18) 0.0517(15) Uani 1 1 d . . . . .
H25 H 0.704761 -0.115953 0.636142 0.062 Uiso 1 1 calc R U . . .
C26 C 0.2874(8) -0.2659(6) 0.57121(18) 0.0586(18) Uani 1 1 d . . . . .
C27 C 1.2323(7) 1.2052(5) 0.99733(19) 0.0575(17) Uani 1 1 d . . . . .
H27 H 1.139271 1.193421 0.984854 0.069 Uiso 1 1 calc R U . . .
C28 C 1.2983(8) 1.3181(5) 0.9931(2) 0.071(2) Uani 1 1 d . . . . .
H28 H 1.248544 1.380439 0.978540 0.085 Uiso 1 1 calc R U . . .
C29 C 1.4399(8) 1.3360(6) 1.0110(2) 0.066(2) Uani 1 1 d . . . . .
C30 C 1.5060(8) 1.2412(6) 1.0321(2) 0.072(2) Uani 1 1 d . . . . .
H30 H 1.599942 1.248314 1.044371 0.087 Uiso 1 1 calc R U . . .
C31 C 1.4327(7) 1.1358(5) 1.03511(19) 0.0580(17) Uani 1 1 d . . . . .
H31 H 1.480168 1.072782 1.049942 0.070 Uiso 1 1 calc R U . . .
C32 C 1.5209(10) 1.4541(5) 1.0075(2) 0.085(2) Uani 1 1 d . . . . .
H32 H 1.616375 1.453459 1.018768 0.102 Uiso 1 1 calc R U . . .
C33 C 0.5510(7) 0.6322(6) 0.7283(2) 0.0604(17) Uani 1 1 d . . . . .
H33 H 0.563202 0.695194 0.708950 0.072 Uiso 1 1 calc R U . . .
C34 C 0.4379(8) 0.4413(5) 0.7435(2) 0.080(2) Uani 1 1 d . . . . .
H34A H 0.501778 0.446258 0.769366 0.119 Uiso 1 1 calc R U . . .
H34B H 0.456293 0.368282 0.728119 0.119 Uiso 1 1 calc R U . . .
H34C H 0.339867 0.441615 0.751372 0.119 Uiso 1 1 calc R U . . .
C35 C 0.3820(7) 0.5482(6) 0.6733(2) 0.076(2) Uani 1 1 d . . . . .
H35A H 0.406940 0.619887 0.658165 0.114 Uiso 1 1 calc R U . . .
H35B H 0.280584 0.548428 0.677326 0.114 Uiso 1 1 calc R U . . .
H35C H 0.405424 0.479065 0.656510 0.114 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O6 1.968(4) 4_666 ?
Zn1 O1 1.977(3) . ?
Zn1 O2 1.984(3) 3_777 ?
Zn1 N3 2.058(4) . ?
Zn1 C26 2.564(6) 4_666 ?
O1 C1 1.245(6) . ?
O2 C1 1.256(5) . ?
O3 C8 1.239(6) . ?
O4 C19 1.206(6) . ?
O5 C26 1.228(8) . ?
O6 C26 1.287(7) . ?
O7 C33 1.231(7) . ?
N1 C8 1.338(6) . ?
N1 C5 1.426(6) . ?
N1 H1A 0.9827 . ?
N2 C19 1.368(6) . ?
N2 C20 1.419(6) . ?
N2 H2A 0.9477 . ?
N3 C27 1.318(7) . ?
N3 C31 1.333(7) . ?
N4 C33 1.328(7) . ?
N4 C35 1.441(7) . ?
N4 C34 1.459(7) . ?
C1 C2 1.491(7) . ?
C2 C7 1.386(6) . ?
C2 C3 1.390(7) . ?
C3 C4 1.378(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.393(7) . ?
C4 H4 0.9300 . ?
C5 C6 1.369(7) . ?
C6 C7 1.377(7) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C8 C9 1.521(7) . ?
C9 C10 1.361(7) . ?
C9 C18 1.419(7) . ?
C10 C11 1.426(7) . ?
C10 H10 0.9300 . ?
C11 C12 1.361(7) . ?
C11 H11 0.9300 . ?
C12 C13 1.418(7) . ?
C12 C19 1.512(7) . ?
C13 C14 1.427(7) . ?
C13 C18 1.431(7) . ?
C14 C15 1.374(7) . ?
C14 H14 0.9300 . ?
C15 C16 1.404(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.363(7) . ?
C16 H16 0.9300 . ?
C17 C18 1.437(7) . ?
C17 H17 0.9300 . ?
C20 C21 1.388(7) . ?
C20 C25 1.406(7) . ?
C21 C22 1.370(7) . ?
C21 H21 0.9300 . ?
C22 C23 1.384(7) . ?
C22 H22 0.9300 . ?
C23 C24 1.392(8) . ?
C23 C26 1.537(7) . ?
C24 C25 1.373(7) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C27 C28 1.409(8) . ?
C27 H27 0.9300 . ?
C28 C29 1.404(9) . ?
C28 H28 0.9300 . ?
C29 C30 1.361(9) . ?
C29 C32 1.522(8) . ?
C30 C31 1.363(7) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C32 C32 1.176(12) 3_887 ?
C32 H32 0.9300 . ?
C33 H33 0.9300 . ?
C34 H34A 0.9600 . ?
C34 H34B 0.9600 . ?
C34 H34C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Zn1 O1 111.92(15) 4_666 . ?
O6 Zn1 O2 122.30(15) 4_666 3_777 ?
O1 Zn1 O2 107.88(15) . 3_777 ?
O6 Zn1 N3 102.06(18) 4_666 . ?
O1 Zn1 N3 108.89(16) . . ?
O2 Zn1 N3 102.58(16) 3_777 . ?
O6 Zn1 C26 29.40(19) 4_666 4_666 ?
O1 Zn1 C26 97.35(17) . 4_666 ?
O2 Zn1 C26 107.22(18) 3_777 4_666 ?
N3 Zn1 C26 131.5(2) . 4_666 ?
C1 O1 Zn1 120.7(3) . . ?
C1 O2 Zn1 135.4(3) . 3_777 ?
C26 O6 Zn1 101.9(4) . 4_465 ?
C8 N1 C5 126.4(5) . . ?
C8 N1 H1A 113.8 . . ?
C5 N1 H1A 119.8 . . ?
C19 N2 C20 126.5(5) . . ?
C19 N2 H2A 115.4 . . ?
C20 N2 H2A 117.6 . . ?
C27 N3 C31 117.0(5) . . ?
C27 N3 Zn1 122.6(4) . . ?
C31 N3 Zn1 120.3(4) . . ?
C33 N4 C35 121.0(5) . . ?
C33 N4 C34 121.3(6) . . ?
C35 N4 C34 117.6(5) . . ?
O1 C1 O2 123.2(5) . . ?
O1 C1 C2 117.0(5) . . ?
O2 C1 C2 119.7(5) . . ?
C7 C2 C3 117.4(5) . . ?
C7 C2 C1 121.3(5) . . ?
C3 C2 C1 121.2(5) . . ?
C4 C3 C2 121.2(5) . . ?
C4 C3 H3 119.4 . . ?
C2 C3 H3 119.4 . . ?
C3 C4 C5 119.9(5) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
C6 C5 C4 119.6(5) . . ?
C6 C5 N1 123.0(5) . . ?
C4 C5 N1 117.3(5) . . ?
C5 C6 C7 119.9(5) . . ?
C5 C6 H6 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 C2 121.9(5) . . ?
C6 C7 H7 119.0 . . ?
C2 C7 H7 119.0 . . ?
O3 C8 N1 125.0(5) . . ?
O3 C8 C9 121.2(5) . . ?
N1 C8 C9 113.8(5) . . ?
C10 C9 C18 120.2(5) . . ?
C10 C9 C8 117.7(5) . . ?
C18 C9 C8 122.0(4) . . ?
C9 C10 C11 120.0(5) . . ?
C9 C10 H10 120.0 . . ?
C11 C10 H10 120.0 . . ?
C12 C11 C10 121.3(5) . . ?
C12 C11 H11 119.3 . . ?
C10 C11 H11 119.3 . . ?
C11 C12 C13 120.2(5) . . ?
C11 C12 C19 119.3(5) . . ?
C13 C12 C19 120.2(5) . . ?
C12 C13 C14 123.5(5) . . ?
C12 C13 C18 118.5(5) . . ?
C14 C13 C18 117.9(5) . . ?
C15 C14 C13 121.0(5) . . ?
C15 C14 H14 119.5 . . ?
C13 C14 H14 119.5 . . ?
C14 C15 C16 121.4(5) . . ?
C14 C15 H15 119.3 . . ?
C16 C15 H15 119.3 . . ?
C17 C16 C15 119.3(5) . . ?
C17 C16 H16 120.3 . . ?
C15 C16 H16 120.3 . . ?
C16 C17 C18 121.8(5) . . ?
C16 C17 H17 119.1 . . ?
C18 C17 H17 119.1 . . ?
C9 C18 C13 119.7(5) . . ?
C9 C18 C17 121.7(5) . . ?
C13 C18 C17 118.6(5) . . ?
O4 C19 N2 124.0(5) . . ?
O4 C19 C12 121.4(5) . . ?
N2 C19 C12 114.6(5) . . ?
C21 C20 C25 118.3(5) . . ?
C21 C20 N2 124.0(5) . . ?
C25 C20 N2 117.7(5) . . ?
C22 C21 C20 120.6(5) . . ?
C22 C21 H21 119.7 . . ?
C20 C21 H21 119.7 . . ?
C21 C22 C23 121.3(6) . . ?
C21 C22 H22 119.3 . . ?
C23 C22 H22 119.3 . . ?
C22 C23 C24 118.7(5) . . ?
C22 C23 C26 120.0(6) . . ?
C24 C23 C26 121.3(5) . . ?
C25 C24 C23 120.5(5) . . ?
C25 C24 H24 119.8 . . ?
C23 C24 H24 119.8 . . ?
C24 C25 C20 120.6(5) . . ?
C24 C25 H25 119.7 . . ?
C20 C25 H25 119.7 . . ?
O5 C26 O6 122.9(6) . . ?
O5 C26 C23 120.9(6) . . ?
O6 C26 C23 116.2(6) . . ?
O5 C26 Zn1 74.5(4) . 4_465 ?
O6 C26 Zn1 48.7(3) . 4_465 ?
C23 C26 Zn1 163.8(5) . 4_465 ?
N3 C27 C28 121.8(6) . . ?
N3 C27 H27 119.1 . . ?
C28 C27 H27 119.1 . . ?
C29 C28 C27 119.5(6) . . ?
C29 C28 H28 120.2 . . ?
C27 C28 H28 120.2 . . ?
C30 C29 C28 117.1(6) . . ?
C30 C29 C32 119.5(7) . . ?
C28 C29 C32 123.3(7) . . ?
C29 C30 C31 119.2(7) . . ?
C29 C30 H30 120.4 . . ?
C31 C30 H30 120.4 . . ?
N3 C31 C30 125.3(6) . . ?
N3 C31 H31 117.4 . . ?
C30 C31 H31 117.4 . . ?
C32 C32 C29 128.8(12) 3_887 . ?
C32 C32 H32 115.6 3_887 . ?
C29 C32 H32 115.6 . . ?
O7 C33 N4 124.2(6) . . ?
O7 C33 H33 117.9 . . ?
N4 C33 H33 117.9 . . ?
N4 C34 H34A 109.5 . . ?
N4 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
N4 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
N4 C35 H35A 109.5 . . ?
N4 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
N4 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?

_refine_diff_density_max         1.468
_refine_diff_density_min         -0.386
_refine_diff_density_rms         0.092

