# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Chud6_b_a
_database_code_depnum_ccdc_archive 'CCDC 2035334'
loop_
_audit_author_name
_audit_author_address
'Alexander D. Vasiliev'
;Institute of Physics, Krasnouarsk Federal Scientific Center SB RAS
Russia
;
_audit_update_record             
;
2020-10-05 deposited with the CCDC.	2020-11-20 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        
'[Cp(CO)₂Mn¹(μ-η¹(C~α~):η¹(C~α~)-C~α~=C~β~HPh)Au]{η²-Mn², C~α~-[Cp(CO)₂Mn²-C~α~-C~β~Ph]}'
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C30 H21 Au Mn2 O4, C2 H5 O0.5'
_chemical_formula_sum            'C32 H26 Au Mn2 O4.50'
_chemical_formula_weight         789.37

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.0448(2)
_cell_length_b                   10.1008(2)
_cell_length_c                   15.8343(3)
_cell_angle_alpha                89.0946(5)
_cell_angle_beta                 80.4186(5)
_cell_angle_gamma                67.9118(4)
_cell_volume                     1465.95(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9997
_cell_measurement_theta_min      2.374
_cell_measurement_theta_max      33.821

_exptl_crystal_description       prism
_exptl_crystal_colour            black
_exptl_crystal_density_meas      none
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.788
_exptl_crystal_F_000             766
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.280
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.130
_exptl_absorpt_coefficient_mu    5.876
_shelx_estimated_absorpt_T_min   0.290
_shelx_estimated_absorpt_T_max   0.515
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4787
_exptl_absorpt_correction_T_max  0.7477
_exptl_absorpt_process_details   SADABS-2016/2
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            28766
_diffrn_reflns_av_unetI/netI     0.0364
_diffrn_reflns_av_R_equivalents  0.0253
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_theta_min         2.179
_diffrn_reflns_theta_max         35.000
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measured_fraction_theta_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_point_group_measured_fraction_full 0.991
_reflns_number_total             12755
_reflns_number_gt                9558
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker PHOTON II'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0311P)²+0.1544P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         12755
_refine_ls_number_parameters     356
_refine_ls_number_restraints     19
_refine_ls_R_factor_all          0.0506
_refine_ls_R_factor_gt           0.0312
_refine_ls_wR_factor_ref         0.0724
_refine_ls_wR_factor_gt          0.0663
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au Au 0.54015(2) 0.72271(2) 0.68640(2) 0.04282(4) Uani 1 1 d . . . . .
Mn1 Mn 0.27806(4) 0.85685(4) 0.65674(2) 0.03970(7) Uani 1 1 d . . . . .
Mn2 Mn 0.82139(4) 0.59704(4) 0.70848(2) 0.04185(8) Uani 1 1 d . . . . .
C1 C 0.4565(2) 0.7615(3) 0.57692(17) 0.0436(5) Uani 1 1 d . . . . .
C2 C 0.5292(3) 0.7147(3) 0.49815(17) 0.0479(5) Uani 1 1 d . . . . .
H2 H 0.626168 0.653330 0.494568 0.066(9) Uiso 1 1 calc R . . . .
C3 C 0.2625(3) 0.7285(3) 0.7348(2) 0.0550(6) Uani 1 1 d . . . . .
O3 O 0.2423(3) 0.6509(3) 0.78349(18) 0.0829(7) Uani 1 1 d . . . . .
C4 C 0.2116(3) 0.7661(3) 0.5886(2) 0.0580(7) Uani 1 1 d . . . . .
O4 O 0.1702(3) 0.7063(4) 0.5456(2) 0.0964(9) Uani 1 1 d . . . . .
C5 C 0.8031(3) 0.7064(3) 0.61762(18) 0.0487(6) Uani 1 1 d . . . . .
O5 O 0.8142(2) 0.7676(3) 0.55623(15) 0.0716(6) Uani 1 1 d . . . . .
C6 C 0.8799(3) 0.7182(3) 0.7570(2) 0.0548(6) Uani 1 1 d . . . . .
O6 O 0.9145(3) 0.7995(3) 0.7881(2) 0.0846(7) Uani 1 1 d . . . . .
C7 C 0.6467(3) 0.6778(3) 0.79723(17) 0.0511(6) Uani 1 1 d . . . . .
C8 C 0.5400(3) 0.7293(4) 0.85341(19) 0.0622(7) Uani 1 1 d . . . . .
C9 C 0.2758(3) 1.0657(3) 0.6215(2) 0.0595(7) Uani 1 1 d . . . . .
H9 H 0.336597 1.081181 0.574677 0.071 Uiso 1 1 calc R U . . .
C10 C 0.1387(3) 1.0602(3) 0.6214(2) 0.0625(8) Uani 1 1 d . . . . .
H10 H 0.092001 1.072063 0.574139 0.075 Uiso 1 1 calc R U . . .
C11 C 0.0836(3) 1.0337(3) 0.7046(2) 0.0633(8) Uani 1 1 d . . . . .
H11 H -0.005693 1.024941 0.721843 0.076 Uiso 1 1 calc R U . . .
C12 C 0.1855(4) 1.0227(3) 0.7568(2) 0.0665(8) Uani 1 1 d . . . . .
H12 H 0.176827 1.004833 0.814882 0.080 Uiso 1 1 calc R U . . .
C13 C 0.3045(4) 1.0437(3) 0.7054(2) 0.0636(8) Uani 1 1 d . . . . .
H13 H 0.387729 1.043054 0.724113 0.076 Uiso 1 1 calc R U . . .
C14 C 0.8316(5) 0.3901(3) 0.7496(3) 0.0835(11) Uani 1 1 d . . . . .
H14 H 0.764239 0.375571 0.792808 0.100 Uiso 1 1 calc R U . . .
C15 C 0.8233(4) 0.3941(3) 0.6652(3) 0.0729(9) Uani 1 1 d . . . . .
H15 H 0.749479 0.382322 0.641495 0.087 Uiso 1 1 calc R U . . .
C16 C 0.9389(4) 0.4178(3) 0.6204(3) 0.0790(11) Uani 1 1 d . U . . .
H16 H 0.957950 0.424962 0.561304 0.095 Uiso 1 1 calc R U . . .
C17 C 1.0253(4) 0.4297(4) 0.6799(5) 0.122(2) Uani 1 1 d . U . . .
H17 H 1.111216 0.446527 0.667776 0.147 Uiso 1 1 calc R U . . .
C18 C 0.9541(6) 0.4105(4) 0.7617(4) 0.1082(18) Uani 1 1 d . U . . .
H18 H 0.985040 0.411756 0.813771 0.130 Uiso 1 1 calc R U . . .
C19 C 0.4236(3) 0.7838(3) 0.92464(14) 0.0743(10) Uani 1 1 d G . . . .
C20 C 0.3837(4) 0.9235(3) 0.9561(2) 0.132(2) Uani 1 1 d G . . . .
H20 H 0.435467 0.978522 0.932561 0.159 Uiso 1 1 calc R U . . .
C21 C 0.2663(5) 0.9811(4) 1.0228(2) 0.190(4) Uani 1 1 d G . . . .
H21 H 0.239617 1.074583 1.043872 0.228 Uiso 1 1 calc R U . . .
C22 C 0.1889(3) 0.8989(6) 1.0580(2) 0.190(5) Uani 1 1 d G . . . .
H22 H 0.110360 0.937383 1.102639 0.228 Uiso 1 1 calc R U . . .
C23 C 0.2288(4) 0.7591(6) 1.0265(2) 0.226(6) Uani 1 1 d G . . . .
H23 H 0.176953 0.704123 1.050094 0.271 Uiso 1 1 calc R U . . .
C24 C 0.3461(4) 0.7016(4) 0.9598(2) 0.151(3) Uani 1 1 d G . . . .
H24 H 0.372804 0.608059 0.938784 0.182 Uiso 1 1 calc R U . . .
C25 C 0.4765(2) 0.74731(19) 0.41538(9) 0.0479(5) Uani 1 1 d G . . . .
C26 C 0.5486(2) 0.64990(17) 0.34602(12) 0.0615(7) Uani 1 1 d G . . . .
H26 H 0.622784 0.563720 0.353394 0.074 Uiso 1 1 calc R U . . .
C27 C 0.5097(3) 0.6813(2) 0.26565(10) 0.0769(10) Uani 1 1 d G . . . .
H27 H 0.557911 0.616113 0.219250 0.092 Uiso 1 1 calc R U . . .
C28 C 0.3988(3) 0.8101(3) 0.25464(11) 0.0771(10) Uani 1 1 d G . . . .
H28 H 0.372749 0.831099 0.200863 0.093 Uiso 1 1 calc R U . . .
C29 C 0.3267(2) 0.90751(19) 0.32399(14) 0.0724(9) Uani 1 1 d G . . . .
H29 H 0.252459 0.993692 0.316622 0.087 Uiso 1 1 calc R U . . .
C30 C 0.3656(2) 0.87612(17) 0.40436(12) 0.0623(7) Uani 1 1 d G . . . .
H30 H 0.317331 0.941301 0.450767 0.075 Uiso 1 1 calc R U . . .
OE O 0.0058(14) 0.5275(13) 0.0197(8) 0.157(5) Uani 0.5 1 d D . P . .
C1E1 C -0.1456(14) 0.5421(16) 0.0326(13) 0.226(15) Uani 0.5 1 d D . P . .
H1E1 H -0.164475 0.481742 0.077445 0.272 Uiso 0.5 1 calc R U P . .
H1E2 H -0.169438 0.515354 -0.019827 0.272 Uiso 0.5 1 calc R U P . .
C1E2 C 0.1073(16) 0.3798(14) 0.0079(9) 0.188(8) Uani 0.5 1 d D . P . .
H1E3 H 0.061174 0.319224 -0.010811 0.225 Uiso 0.5 1 calc R U P . .
H1E4 H 0.141035 0.345672 0.061089 0.225 Uiso 0.5 1 calc R U P . .
C2E C -0.2346(16) 0.6987(15) 0.0583(16) 0.205(10) Uani 0.5 1 d D . P . .
H2E1 H -0.336578 0.714966 0.067778 0.307 Uiso 0.5 1 calc R U P . .
H2E2 H -0.209320 0.723380 0.110050 0.307 Uiso 0.5 1 calc R U P . .
H2E3 H -0.214254 0.756797 0.013343 0.307 Uiso 0.5 1 calc R U P . .
C3E C 0.233(2) 0.3785(16) -0.0602(17) 0.237(15) Uani 0.5 1 d D . P . .
H3E1 H 0.304503 0.282635 -0.070670 0.356 Uiso 0.5 1 calc R U P . .
H3E2 H 0.197974 0.412932 -0.112210 0.356 Uiso 0.5 1 calc R U P . .
H3E3 H 0.277381 0.439229 -0.040720 0.356 Uiso 0.5 1 calc R U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au C1 2.020(2) . ?
Au C7 2.160(3) . ?
Au Mn1 2.5877(3) . ?
Au C5 2.629(3) . ?
Au C8 2.646(3) . ?
Au Mn2 2.7078(3) . ?
Mn1 C4 1.784(3) . ?
Mn1 C3 1.808(3) . ?
Mn1 C1 1.930(2) . ?
Mn1 C11 2.122(3) . ?
Mn1 C10 2.134(3) . ?
Mn1 C12 2.146(3) . ?
Mn1 C9 2.167(3) . ?
Mn1 C13 2.172(3) . ?
Mn2 C6 1.776(3) . ?
Mn2 C5 1.791(3) . ?
Mn2 C7 1.964(3) . ?
Mn2 C17 2.091(3) . ?
Mn2 C18 2.114(3) . ?
Mn2 C16 2.131(3) . ?
Mn2 C14 2.150(3) . ?
Mn2 C15 2.164(3) . ?
C1 C2 1.330(4) . ?
C2 C25 1.481(3) . ?
C2 H2 0.9300 . ?
C3 O3 1.139(3) . ?
C4 O4 1.139(4) . ?
C5 O5 1.156(3) . ?
C6 O6 1.150(4) . ?
C7 C8 1.220(4) . ?
C8 C19 1.428(4) . ?
C9 C10 1.399(4) . ?
C9 C13 1.403(5) . ?
C9 H9 0.9300 . ?
C10 C11 1.404(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.392(5) . ?
C11 H11 0.9300 . ?
C12 C13 1.413(5) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 C15 1.352(6) . ?
C14 C18 1.365(6) . ?
C14 H14 0.9300 . ?
C15 C16 1.356(5) . ?
C15 H15 0.9300 . ?
C16 C17 1.418(7) . ?
C16 H16 0.9300 . ?
C17 C18 1.419(8) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 C21 1.3900 . ?
C20 H20 0.9300 . ?
C21 C22 1.3900 . ?
C21 H21 0.9300 . ?
C22 C23 1.3900 . ?
C22 H22 0.9300 . ?
C23 C24 1.3900 . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C26 1.3900 . ?
C25 C30 1.3900 . ?
C26 C27 1.3900 . ?
C26 H26 0.9300 . ?
C27 C28 1.3900 . ?
C27 H27 0.9300 . ?
C28 C29 1.3900 . ?
C28 H28 0.9300 . ?
C29 C30 1.3900 . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
OE OE 0.891(17) 2_565 ?
OE C1E2 1.31(2) 2_565 ?
OE C1E1 1.43(2) 2_565 ?
OE C1E2 1.450(2) . ?
OE C1E1 1.451(2) . ?
C1E1 C2E 1.517(2) . ?
C1E1 H1E1 0.9700 . ?
C1E1 H1E2 0.9700 . ?
C1E2 C3E 1.517(2) . ?
C1E2 H1E3 0.9700 . ?
C1E2 H1E4 0.9700 . ?
C2E H2E1 0.9600 . ?
C2E H2E2 0.9600 . ?
C2E H2E3 0.9600 . ?
C2E H3E1 0.65(3) 2_565 ?
C3E H3E1 0.9600 . ?
C3E H3E2 0.9600 . ?
C3E H3E3 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au C7 175.38(9) . . ?
C1 Au Mn1 47.57(7) . . ?
C7 Au Mn1 136.78(7) . . ?
C1 Au C5 96.13(9) . . ?
C7 Au C5 79.30(10) . . ?
Mn1 Au C5 136.18(6) . . ?
C1 Au C8 157.34(10) . . ?
C7 Au C8 27.08(10) . . ?
Mn1 Au C8 109.77(7) . . ?
C5 Au C8 103.93(9) . . ?
C1 Au Mn2 129.61(7) . . ?
C7 Au Mn2 45.91(7) . . ?
Mn1 Au Mn2 175.224(11) . . ?
C5 Au Mn2 39.19(6) . . ?
C8 Au Mn2 72.98(7) . . ?
C4 Mn1 C3 85.84(15) . . ?
C4 Mn1 C1 81.18(12) . . ?
C3 Mn1 C1 106.68(12) . . ?
C4 Mn1 C11 100.68(14) . . ?
C3 Mn1 C11 99.45(13) . . ?
C1 Mn1 C11 153.87(12) . . ?
C4 Mn1 C10 91.35(14) . . ?
C3 Mn1 C10 136.45(13) . . ?
C1 Mn1 C10 115.80(12) . . ?
C11 Mn1 C10 38.52(13) . . ?
C4 Mn1 C12 136.71(14) . . ?
C3 Mn1 C12 89.21(14) . . ?
C1 Mn1 C12 140.75(12) . . ?
C11 Mn1 C12 38.06(13) . . ?
C10 Mn1 C12 63.99(14) . . ?
C4 Mn1 C9 117.77(14) . . ?
C3 Mn1 C9 152.40(14) . . ?
C1 Mn1 C9 91.82(11) . . ?
C11 Mn1 C9 64.02(12) . . ?
C10 Mn1 C9 37.97(12) . . ?
C12 Mn1 C9 64.00(13) . . ?
C4 Mn1 C13 153.96(14) . . ?
C3 Mn1 C13 115.99(14) . . ?
C1 Mn1 C13 104.03(12) . . ?
C11 Mn1 C13 63.51(13) . . ?
C10 Mn1 C13 63.22(13) . . ?
C12 Mn1 C13 38.20(13) . . ?
C9 Mn1 C13 37.73(13) . . ?
C4 Mn1 Au 117.03(10) . . ?
C3 Mn1 Au 74.95(9) . . ?
C1 Mn1 Au 50.60(7) . . ?
C11 Mn1 Au 140.97(10) . . ?
C10 Mn1 Au 141.34(9) . . ?
C12 Mn1 Au 102.92(10) . . ?
C9 Mn1 Au 103.40(8) . . ?
C13 Mn1 Au 83.95(9) . . ?
C6 Mn2 C5 87.88(13) . . ?
C6 Mn2 C7 83.90(13) . . ?
C5 Mn2 C7 109.94(11) . . ?
C6 Mn2 C17 97.05(18) . . ?
C5 Mn2 C17 106.6(2) . . ?
C7 Mn2 C17 143.4(2) . . ?
C6 Mn2 C18 96.57(16) . . ?
C5 Mn2 C18 146.0(2) . . ?
C7 Mn2 C18 104.0(2) . . ?
C17 Mn2 C18 39.5(2) . . ?
C6 Mn2 C16 131.06(15) . . ?
C5 Mn2 C16 87.25(14) . . ?
C7 Mn2 C16 142.62(14) . . ?
C17 Mn2 C16 39.2(2) . . ?
C18 Mn2 C16 64.54(19) . . ?
C6 Mn2 C14 127.93(16) . . ?
C5 Mn2 C14 142.68(15) . . ?
C7 Mn2 C14 86.81(15) . . ?
C17 Mn2 C14 63.77(19) . . ?
C18 Mn2 C14 37.33(18) . . ?
C16 Mn2 C14 62.27(16) . . ?
C6 Mn2 C15 158.29(14) . . ?
C5 Mn2 C15 106.19(14) . . ?
C7 Mn2 C15 105.85(14) . . ?
C17 Mn2 C15 63.45(17) . . ?
C18 Mn2 C15 62.51(16) . . ?
C16 Mn2 C15 36.79(15) . . ?
C14 Mn2 C15 36.52(15) . . ?
C6 Mn2 Au 111.75(9) . . ?
C5 Mn2 Au 68.01(8) . . ?
C7 Mn2 Au 52.17(8) . . ?
C17 Mn2 Au 150.09(18) . . ?
C18 Mn2 Au 138.09(18) . . ?
C16 Mn2 Au 111.20(13) . . ?
C14 Mn2 Au 101.79(13) . . ?
C15 Mn2 Au 89.13(10) . . ?
C2 C1 Mn1 151.8(2) . . ?
C2 C1 Au 126.25(18) . . ?
Mn1 C1 Au 81.83(10) . . ?
C1 C2 C25 128.7(2) . . ?
C1 C2 H2 115.7 . . ?
C25 C2 H2 115.7 . . ?
O3 C3 Mn1 175.0(3) . . ?
O4 C4 Mn1 179.0(3) . . ?
O5 C5 Mn2 169.6(2) . . ?
O5 C5 Au 117.5(2) . . ?
Mn2 C5 Au 72.79(9) . . ?
O6 C6 Mn2 178.2(3) . . ?
C8 C7 Mn2 178.5(3) . . ?
C8 C7 Au 99.2(2) . . ?
Mn2 C7 Au 81.92(10) . . ?
C7 C8 C19 174.8(3) . . ?
C7 C8 Au 53.68(17) . . ?
C19 C8 Au 131.4(2) . . ?
C10 C9 C13 107.3(3) . . ?
C10 C9 Mn1 69.76(15) . . ?
C13 C9 Mn1 71.35(16) . . ?
C10 C9 H9 126.3 . . ?
C13 C9 H9 126.3 . . ?
Mn1 C9 H9 124.2 . . ?
C9 C10 C11 108.4(3) . . ?
C9 C10 Mn1 72.27(16) . . ?
C11 C10 Mn1 70.28(16) . . ?
C9 C10 H10 125.8 . . ?
C11 C10 H10 125.8 . . ?
Mn1 C10 H10 123.3 . . ?
C12 C11 C10 108.4(3) . . ?
C12 C11 Mn1 71.88(16) . . ?
C10 C11 Mn1 71.19(16) . . ?
C12 C11 H11 125.8 . . ?
C10 C11 H11 125.8 . . ?
Mn1 C11 H11 122.8 . . ?
C11 C12 C13 107.4(3) . . ?
C11 C12 Mn1 70.06(18) . . ?
C13 C12 Mn1 71.91(17) . . ?
C11 C12 H12 126.3 . . ?
C13 C12 H12 126.3 . . ?
Mn1 C12 H12 123.4 . . ?
C9 C13 C12 108.5(3) . . ?
C9 C13 Mn1 70.92(16) . . ?
C12 C13 Mn1 69.89(17) . . ?
C9 C13 H13 125.8 . . ?
C12 C13 H13 125.8 . . ?
Mn1 C13 H13 125.0 . . ?
C15 C14 C18 109.6(5) . . ?
C15 C14 Mn2 72.3(2) . . ?
C18 C14 Mn2 69.9(2) . . ?
C15 C14 H14 125.2 . . ?
C18 C14 H14 125.2 . . ?
Mn2 C14 H14 124.2 . . ?
C14 C15 C16 109.7(4) . . ?
C14 C15 Mn2 71.2(2) . . ?
C16 C15 Mn2 70.3(2) . . ?
C14 C15 H15 125.2 . . ?
C16 C15 H15 125.2 . . ?
Mn2 C15 H15 125.0 . . ?
C15 C16 C17 107.5(4) . . ?
C15 C16 Mn2 72.9(2) . . ?
C17 C16 Mn2 68.8(2) . . ?
C15 C16 H16 126.2 . . ?
C17 C16 H16 126.2 . . ?
Mn2 C16 H16 123.6 . . ?
C16 C17 C18 106.0(4) . . ?
C16 C17 Mn2 71.9(2) . . ?
C18 C17 Mn2 71.2(2) . . ?
C16 C17 H17 127.0 . . ?
C18 C17 H17 127.0 . . ?
Mn2 C17 H17 121.7 . . ?
C14 C18 C17 107.1(4) . . ?
C14 C18 Mn2 72.7(2) . . ?
C17 C18 Mn2 69.4(2) . . ?
C14 C18 H18 126.4 . . ?
C17 C18 H18 126.4 . . ?
Mn2 C18 H18 123.1 . . ?
C20 C19 C24 120.0 . . ?
C20 C19 C8 119.0(3) . . ?
C24 C19 C8 121.0(3) . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 120.0 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 C23 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 H22 120.0 . . ?
C24 C23 C22 120.0 . . ?
C24 C23 H23 120.0 . . ?
C22 C23 H23 120.0 . . ?
C23 C24 C19 120.0 . . ?
C23 C24 H24 120.0 . . ?
C19 C24 H24 120.0 . . ?
C26 C25 C30 120.0 . . ?
C26 C25 C2 118.16(15) . . ?
C30 C25 C2 121.66(15) . . ?
C27 C26 C25 120.0 . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C28 C27 C26 120.0 . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C27 C28 C29 120.0 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 H28 120.0 . . ?
C28 C29 C30 120.0 . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C29 C30 C25 120.0 . . ?
C29 C30 H30 120.0 . . ?
C25 C30 H30 120.0 . . ?
OE OE C1E2 80.1(14) 2_565 2_565 ?
OE OE C1E1 73.3(14) 2_565 2_565 ?
C1E2 OE C1E1 124.2(12) 2_565 2_565 ?
OE OE C1E2 62.7(16) 2_565 . ?
C1E2 OE C1E2 142.7(8) 2_565 . ?
C1E1 OE C1E2 46.9(9) 2_565 . ?
OE OE C1E1 70.6(15) 2_565 . ?
C1E2 OE C1E1 48.7(9) 2_565 . ?
C1E1 OE C1E1 143.9(7) 2_565 . ?
C1E2 OE C1E1 113.0(2) . . ?
OE C1E1 C2E 105.67(19) . . ?
OE C1E1 H1E1 110.6 . . ?
C2E C1E1 H1E1 110.6 . . ?
OE C1E1 H1E2 110.6 . . ?
C2E C1E1 H1E2 110.6 . . ?
H1E1 C1E1 H1E2 108.7 . . ?
OE C1E2 C3E 105.80(19) . . ?
OE C1E2 H1E3 110.6 . . ?
C3E C1E2 H1E3 110.6 . . ?
OE C1E2 H1E4 110.6 . . ?
C3E C1E2 H1E4 110.6 . . ?
H1E3 C1E2 H1E4 108.7 . . ?
C1E1 C2E H2E1 109.5 . . ?
C1E1 C2E H2E2 109.5 . . ?
H2E1 C2E H2E2 109.5 . . ?
C1E1 C2E H2E3 109.5 . . ?
H2E1 C2E H2E3 109.5 . . ?
H2E2 C2E H2E3 109.5 . . ?
C1E1 C2E H3E1 117(2) . 2_565 ?
H2E1 C2E H3E1 10.6 . 2_565 ?
H2E2 C2E H3E1 99.5 . 2_565 ?
H2E3 C2E H3E1 111.0 . 2_565 ?
C1E2 C3E H3E1 109.5 . . ?
C1E2 C3E H3E2 109.5 . . ?
H3E1 C3E H3E2 109.5 . . ?
C1E2 C3E H3E3 109.5 . . ?
H3E1 C3E H3E3 109.5 . . ?
H3E2 C3E H3E3 109.5 . . ?

_refine_diff_density_max         0.726
_refine_diff_density_min         -0.671
_refine_diff_density_rms         0.080

