# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_EuNDC
_audit_block_doi                 10.5517/ccdc.csd.cc26fd02
_database_code_depnum_ccdc_archive 'CCDC 2038653'
loop_
_audit_author_name
_audit_author_address
'Tifeng Xia'
;Zhejiang University
China
;
_audit_update_record             
;
2021-01-18 deposited with the CCDC.	2021-01-19 downloaded from the CCDC.
;
_audit_creation_date             2021-01-14
_audit_creation_method           
;
Olex2 1.2-beta
(compiled 2015.08.17 svn.r3210 for OlexSys, GUI svn.r5083)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ?
;
_chemical_formula_moiety         
'0.5(C76 H46 Eu6 O36), 1(O), 0.96(C O), 0.33(H6 O3)'
_chemical_formula_sum            'C38.96 H25 Eu3 O20.96'
_chemical_formula_weight         1284.35
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      hexagonal
_space_group_IT_number           176
_space_group_name_H-M_alt        'P 63/m'
_space_group_name_Hall           '-P 6c'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x-y, x, z+1/2'
'-y, x-y, z'
'-x, -y, z+1/2'
'-x+y, -x, z'
'y, -x+y, z+1/2'
'-x, -y, -z'
'-x+y, -x, -z-1/2'
'y, -x+y, -z'
'x, y, -z-1/2'
'x-y, x, -z'
'-y, x-y, -z-1/2'

_cell_length_a                   10.5738(4)
_cell_length_b                   10.5738(4)
_cell_length_c                   24.7974(10)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     2401.0(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7901
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      23.040
_cell_measurement_theta_min      2.224
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.944
_exptl_absorpt_correction_T_max  0.437
_exptl_absorpt_correction_T_min  0.345
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0648 before and 0.0340 after correction.
The Ratio of minimum to maximum transmission is 0.8506.
The λ/2 correction factor is 0.0015.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.776
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1231
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.21
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0309
_diffrn_reflns_av_unetI/netI     0.0108
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            19898
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        23.140
_diffrn_reflns_theta_max         23.140
_diffrn_reflns_theta_min         1.642
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1100
_reflns_number_total             1167
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       'SAINT v7.68A (Bruker, 2009)'
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SIR2004 (Burla et al., 2007)'
_refine_diff_density_max         1.285
_refine_diff_density_min         -1.621
_refine_diff_density_rms         0.124
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.175
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     182
_refine_ls_number_reflns         1167
_refine_ls_number_restraints     193
_refine_ls_R_factor_all          0.0428
_refine_ls_R_factor_gt           0.0405
_refine_ls_restrained_S_all      2.283
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0479P)²+15.6096P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1031
_refine_ls_wR_factor_ref         0.1043
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 C7-O3
 1.3 with sigma of 0.02
 C7-O4
 1.3 with sigma of 0.02
 C8-O6
 1.25 with sigma of 0.001
 O5-H5
 0.85 with sigma of 0.001
 H3AA-O3A
 0.85 with sigma of 0.001
 O3A-H3AB
 0.85 with sigma of 0.001
 O3-C7 \\sim C7-O4
 with sigma of 0.02
 Eu1-H5_$3 \\sim H5_$3-Eu1_$4
 with sigma of 0.02
 Eu1_$4-H5_$3 \\sim H5_$3-Eu1_$3
 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
O4 \\sim O3 \\sim C7 \\sim O3A \\sim O4A: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.01
Uanis(O4) \\sim Ueq: with sigma of 0.1 and sigma for terminal atoms of 0.2
Uanis(O2A) = Uanis(O2)
Uanis(C8) = Uanis(O6)
Uanis(C0AA) = Uanis(C2A)
Uanis(C6A) = Uanis(C1AA)
Uanis(C3) = Uanis(C3A)
Uanis(C4A) = Uanis(C4)
Uanis(C5) = Uanis(C5A)
4. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Sof(C0AA)=Sof(C1AA)=Sof(H1AA)=1-FVAR(1)
 Sof(C2A)=Sof(C6A)=Sof(H6A)=FVAR(1)
 Fixed Sof: O2(0.5) O1A(0.5) O1(0.5) O3(0.33333) O3A(0.16667) H3AA(0.16667)
 H3AB(0.16667) O4(0.33333) C1A(0.5) C1(0.5) C3(0.5) H3(0.5) C4(0.5) C5(0.5)
 H5A(0.5) C7(0.33333) H7(0.33333) O7(0.16667) O2A(0.5) O6(0.16) C8(0.16)
 O4A(0.16667) H4AA(0.16667) H4AB(0.16667) H5(0.16666) C3A(0.5) H3A(0.5)
 C4A(0.5) C5A(0.5) H5AA(0.5)
6.a Rotating group:
 O3A(H3AA,H3AB), O4A(H4AA,H4AB)
6.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5A), C6A(H6A), C7(H7), C1AA(H1AA), C3A(H3A), C5A(H5AA)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.82938(6) 0.58556(6) 0.7500 0.0400(3) Uani 1 2 d DS TU P . .
O2 O 0.963(2) 0.5259(18) 0.6916(9) 0.060(4) Uani 0.5 1 d . U . A 2
O1A O 0.7586(19) 0.580(2) 0.6575(8) 0.061(5) Uani 0.5 1 d . U . A 1
O1 O 0.705(3) 0.543(3) 0.6682(9) 0.072(6) Uani 0.5 1 d . U . A 2
O3 O 0.739(3) 0.753(2) 0.7620(13) 0.078(7) Uani 0.3333 1 d D U . A -1
O3A O 0.801(6) 0.790(5) 0.758(3) 0.078(8) Uani 0.1667 1 d D U . A -2
H3AA H 0.8439 0.8650 0.7793 0.118 Uiso 0.1667 1 d DGR . . A -2
H3AB H 0.7663 0.8268 0.7324 0.118 Uiso 0.1667 1 d DGR . . A -2
O4 O 0.721(4) 0.943(3) 0.7681(8) 0.078(7) Uani 0.3333 1 d D U . A -1
O5 O 0.6667 0.3333 0.7500 0.021(2) Uani 1 6 d DS TU P A .
C1A C 0.627(3) 0.523(3) 0.6546(11) 0.045(6) Uani 0.5 1 d . U . A 1
C1 C 0.572(3) 0.489(3) 0.6574(12) 0.053(6) Uani 0.5 1 d . U . A 2
C2A C 0.566(10) 0.509(8) 0.598(2) 0.051(4) Uani 0.41(19) 1 d . U . A 1
C3 C 0.643(6) 0.544(9) 0.557(2) 0.055(7) Uani 0.5 1 d . U . A 1
H3 H 0.7433 0.5832 0.5597 0.066 Uiso 0.5 1 calc R . . A 1
C4 C 0.567(6) 0.520(7) 0.4974(12) 0.053(3) Uani 0.5 1 d . U . A 1
C5 C 0.659(8) 0.550(8) 0.4621(17) 0.073(4) Uani 0.5 1 d . U . A 1
H5A H 0.7554 0.5734 0.4675 0.087 Uiso 0.5 1 calc R . . A 1
C6A C 0.415(12) 0.456(7) 0.595(3) 0.067(4) Uani 0.41(19) 1 d . U . A 1
H6A H 0.3588 0.4254 0.6267 0.080 Uiso 0.41(19) 1 calc R . . A 1
C7 C 0.748(4) 0.862(3) 0.7349(9) 0.077(6) Uani 0.3333 1 d D U . A -1
H7 H 0.7706 0.8804 0.6984 0.092 Uiso 0.3333 1 calc R . . A -1
O7 O 1.0000 1.0000 0.6107(13) 0.24(3) Uani 0.5 3 d S TU P . .
O2A O 0.925(2) 0.4550(19) 0.6957(9) 0.060(4) Uani 0.5 1 d . U . A 1
O6 O 1.306(6) 1.638(9) 0.7010(10) 0.066(11) Uani 0.16 1 d D U . B -1
C8 C 1.231(4) 1.592(5) 0.7431(14) 0.066(11) Uani 0.16 1 d D U . B -1
O4A O 0.712(9) 0.942(7) 0.789(2) 0.076(8) Uani 0.1667 1 d . U . C -3
H4AA H 0.6830 0.9363 0.8210 0.114 Uiso 0.1667 1 d GR . . C -3
H4AB H 0.7898 0.9373 0.7882 0.114 Uiso 0.1667 1 d GR . . C -3
H5 H 0.6667 0.3333 0.78428(4) 0.03(7) Uiso 0.5 3 d DS T P . .
C0AA C 0.529(8) 0.491(6) 0.6006(14) 0.051(4) Uani 0.59(19) 1 d . U . A 2
C1AA C 0.380(7) 0.454(4) 0.5898(17) 0.067(4) Uani 0.59(19) 1 d . U . A 2
H1AA H 0.3173 0.4342 0.6190 0.080 Uiso 0.59(19) 1 calc R . . A 2
C3A C 0.616(6) 0.516(9) 0.557(2) 0.055(7) Uani 0.5 1 d . U . A 2
H3A H 0.7093 0.5295 0.5629 0.066 Uiso 0.5 1 calc R . . A 2
C4A C 0.578(6) 0.522(7) 0.5076(11) 0.053(3) Uani 0.5 1 d . U . A 2
C5A C 0.667(8) 0.554(9) 0.4534(17) 0.073(4) Uani 0.5 1 d . U . A 2
H5AA H 0.7649 0.5806 0.4561 0.087 Uiso 0.5 1 calc R . . A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.318(19) 10_557 ?
Eu1 O2 2.318(19) . ?
Eu1 O1A 2.405(19) . ?
Eu1 O1A 2.405(19) 10_557 ?
Eu1 O1 2.33(2) 10_557 ?
Eu1 O1 2.33(2) . ?
Eu1 O3 2.41(2) . ?
Eu1 O3A 2.34(5) . ?
Eu1 O5 2.3419(5) . ?
Eu1 O2A 2.48(2) 10_557 ?
Eu1 O2A 2.48(2) . ?
Eu1 O4A 2.41(6) 3_765 ?
Eu1 H5 2.4913(6) . ?
O2 C1 1.23(4) 5_665 ?
O1A C1A 1.21(3) . ?
O1 C1 1.26(3) . ?
O3 C7 1.298(16) . ?
O3A H3AA 0.8702 . ?
O3A H3AB 0.9103 . ?
O4 Eu1 2.29(3) 8_677 ?
O4 C7 1.320(15) . ?
O5 Eu1 2.3419(5) 8_667 ?
O5 Eu1 2.3419(5) 3_655 ?
O5 H5 0.8500(11) . ?
C1A C2A 1.53(5) . ?
C1A O2A 1.27(3) 3_655 ?
C1 Eu1 3.23(3) 3_655 ?
C1 O2 1.23(4) 3_655 ?
C1 C0AA 1.48(4) . ?
C2A C3 1.24(9) . ?
C2A C6A 1.40(5) . ?
C3 H3 0.9300 . ?
C3 C4 1.63(7) . ?
C4 C4 1.27(11) 7_666 ?
C4 C5 1.23(8) . ?
C5 H5A 0.9300 . ?
C5 C6A 1.61(11) 7_666 ?
C6A C5 1.61(11) 7_666 ?
C6A H6A 0.9300 . ?
C7 H7 0.9300 . ?
O2A Eu1 2.945(16) 8_667 ?
O2A C1A 1.27(3) 5_665 ?
O6 C8 1.2500(12) . ?
O4A H4AA 0.8499 . ?
O4A H4AB 0.8501 . ?
C0AA C1AA 1.45(3) . ?
C0AA C3A 1.36(7) . ?
C1AA H1AA 0.9300 . ?
C1AA C5A 1.17(7) 7_666 ?
C3A H3A 0.9300 . ?
C3A C4A 1.30(7) . ?
C4A C4A 1.53(10) 7_666 ?
C4A C5A 1.57(7) . ?
C5A C1AA 1.17(7) 7_666 ?
C5A H5AA 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O2 77.4(11) 10_557 . ?
O2 Eu1 O1 148.3(8) . 10_557 ?
O2 Eu1 O1 76.4(9) . . ?
O2 Eu1 O1 76.4(9) 10_557 10_557 ?
O2 Eu1 O1 148.3(8) 10_557 . ?
O2 Eu1 O3A 125(2) 10_557 . ?
O2 Eu1 O3A 133.1(17) . . ?
O2 Eu1 O5 83.7(4) 10_557 . ?
O2 Eu1 O5 83.7(4) . . ?
O2 Eu1 H5 96.3(4) . . ?
O2 Eu1 H5 71.6(5) 10_557 . ?
O1A Eu1 O1A 145.1(9) 10_557 . ?
O1A Eu1 O3 70.6(9) 10_557 . ?
O1A Eu1 O3 84.4(10) . . ?
O1A Eu1 O2A 71.2(8) . . ?
O1A Eu1 O2A 135.6(7) 10_557 . ?
O1A Eu1 O2A 71.2(8) 10_557 10_557 ?
O1A Eu1 O2A 135.6(7) . 10_557 ?
O1A Eu1 H5 105.1(5) . . ?
O1A Eu1 H5 67.0(5) 10_557 . ?
O1 Eu1 O1 120.7(12) 10_557 . ?
O1 Eu1 O3A 77.5(19) 10_557 . ?
O1 Eu1 O3A 86(2) . . ?
O1 Eu1 O5 76.0(5) . . ?
O1 Eu1 O5 76.0(5) 10_557 . ?
O1 Eu1 H5 94.0(5) . . ?
O1 Eu1 H5 58.5(6) 10_557 . ?
O3 Eu1 O2A 153.8(9) . . ?
O3 Eu1 O2A 139.8(9) . 10_557 ?
O3 Eu1 H5 115.3(6) . . ?
O3A Eu1 O5 133.8(13) . . ?
O3A Eu1 H5 128.4(13) . . ?
O5 Eu1 O1A 86.0(5) . 10_557 ?
O5 Eu1 O1A 86.0(5) . . ?
O5 Eu1 O3 120.0(6) . . ?
O5 Eu1 O2A 68.8(4) . 10_557 ?
O5 Eu1 O2A 68.8(4) . . ?
O5 Eu1 O4A 141.9(15) . 3_765 ?
O5 Eu1 H5 19.95(2) . . ?
O2A Eu1 O2A 65.8(10) 10_557 . ?
O2A Eu1 H5 81.1(4) . . ?
O2A Eu1 H5 58.3(4) 10_557 . ?
O4A Eu1 H5 127.2(12) 3_765 . ?
C1 O2 Eu1 128.6(18) 5_665 . ?
C1A O1A Eu1 109.5(17) . . ?
C1 O1 Eu1 131.9(18) . . ?
C7 O3 Eu1 135(2) . . ?
Eu1 O3A H3AA 130.0 . . ?
Eu1 O3A H3AB 127.0 . . ?
H3AA O3A H3AB 100.1 . . ?
C7 O4 Eu1 125.9(19) . 8_677 ?
Eu1 O5 Eu1 120.000(1) 8_667 . ?
Eu1 O5 Eu1 120.0 . 3_655 ?
Eu1 O5 Eu1 120.0 8_667 3_655 ?
Eu1 O5 H5 90.0 8_667 . ?
Eu1 O5 H5 90.0 3_655 . ?
Eu1 O5 H5 90.0 . . ?
O1A C1A Eu1 48.4(15) . . ?
O1A C1A C2A 115(4) . . ?
O1A C1A O2A 122(3) . 3_655 ?
C2A C1A Eu1 164(4) . . ?
O2A C1A Eu1 73.9(16) 3_655 . ?
O2A C1A C2A 122(4) 3_655 . ?
O2 C1 Eu1 34.1(13) 3_655 3_655 ?
O2 C1 O1 124(3) 3_655 . ?
O2 C1 C0AA 118(3) 3_655 . ?
O1 C1 Eu1 102.9(17) . 3_655 ?
O1 C1 C0AA 119(4) . . ?
C0AA C1 Eu1 130(3) . 3_655 ?
C3 C2A C1A 123(6) . . ?
C3 C2A C6A 122(4) . . ?
C6A C2A C1A 115(7) . . ?
C2A C3 H3 120.2 . . ?
C2A C3 C4 120(5) . . ?
C4 C3 H3 120.2 . . ?
C4 C4 C3 110(4) 7_666 . ?
C5 C4 C3 110(5) . . ?
C5 C4 C4 140(5) . 7_666 ?
C4 C5 H5A 125.8 . . ?
C4 C5 C6A 108(6) . 7_666 ?
C6A C5 H5A 125.8 7_666 . ?
C2A C6A C5 119(5) . 7_666 ?
C2A C6A H6A 120.5 . . ?
C5 C6A H6A 120.5 7_666 . ?
O3 C7 O4 108(2) . . ?
O3 C7 H7 126.0 . . ?
O4 C7 H7 126.0 . . ?
Eu1 O2A Eu1 96.4(6) . 8_667 ?
C1A O2A Eu1 141.9(19) 5_665 . ?
C1A O2A Eu1 81.6(16) 5_665 8_667 ?
H4AA O4A H4AB 109.4 . . ?
C1AA C0AA C1 118(5) . . ?
C3A C0AA C1 125(5) . . ?
C3A C0AA C1AA 117(3) . . ?
C0AA C1AA H1AA 118.2 . . ?
C5A C1AA C0AA 124(4) 7_666 . ?
C5A C1AA H1AA 118.2 7_666 . ?
C0AA C3A H3A 117.9 . . ?
C4A C3A C0AA 124(6) . . ?
C4A C3A H3A 117.9 . . ?
C3A C4A C4A 122(6) . 7_666 ?
C3A C4A C5A 131(6) . . ?
C4A C4A C5A 107(4) 7_666 . ?
C1AA C5A C4A 126(7) 7_666 . ?
C1AA C5A H5AA 117.1 7_666 . ?
C4A C5A H5AA 117.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1A C1A C2A -179(3) . . . . ?
Eu1 O1A C1A O2A -3(3) . . . 3_655 ?
Eu1 O1 C1 Eu1 -35(2) . . . 3_655 ?
Eu1 O1 C1 O2 -5(4) . . . 3_655 ?
Eu1 O1 C1 C0AA 174(2) . . . . ?
Eu1 O3 C7 O4 -159(3) . . . . ?
Eu1 O4 C7 O3 169(2) 8_677 . . . ?
Eu1 C1A C2A C3 2(14) . . . . ?
Eu1 C1A C2A C6A -177(7) . . . . ?
Eu1 C1 C0AA C1AA 49(4) 3_655 . . . ?
Eu1 C1 C0AA C3A -127(6) 3_655 . . . ?
O2 C1 C0AA C1AA 10(5) 3_655 . . . ?
O2 C1 C0AA C3A -166(5) 3_655 . . . ?
O1A C1A C2A C3 5(7) . . . . ?
O1A C1A C2A C6A -174(4) . . . . ?
O1 C1 C0AA C1AA -169(3) . . . . ?
O1 C1 C0AA C3A 15(6) . . . . ?
C1A C2A C3 C4 178(6) . . . . ?
C1A C2A C6A C5 175(5) . . . 7_666 ?
C1 C0AA C1AA C5A -177(6) . . . 7_666 ?
C1 C0AA C3A C4A -178(7) . . . . ?
C2A C3 C4 C4 7(12) . . . 7_666 ?
C2A C3 C4 C5 -175(7) . . . . ?
C3 C2A C6A C5 -4(9) . . . 7_666 ?
C3 C4 C5 C6A -173(5) . . . 7_666 ?
C4 C4 C5 C6A 3(18) 7_666 . . 7_666 ?
C6A C2A C3 C4 -3(10) . . . . ?
O2A C1A C2A C3 -171(6) 3_655 . . . ?
O2A C1A C2A C6A 10(6) 3_655 . . . ?
C0AA C3A C4A C4A -9(14) . . . 7_666 ?
C0AA C3A C4A C5A 178(6) . . . . ?
C1AA C0AA C3A C4A 7(10) . . . . ?
C3A C0AA C1AA C5A -1(8) . . . 7_666 ?
C3A C4A C5A C1AA 174(7) . . . 7_666 ?
C4A C4A C5A C1AA 0(12) 7_666 . . 7_666 ?

_shelx_SHELXL_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
