File Name : scheme s1.tif Caption : scheme s1. schematic illustration of the bench-scale process. File Name : scheme s2.tif Caption : scheme s2. reaction mechanism of base-catalyzed transesterification reaction. File Name : figure s1.tiff Caption : figure s1. analysis of pbc by 1h-nmr. File Name : figure s2.tif Caption : figure s2. analysis of pbci40, oligomer and monomers by 1h-nmr. File Name : figure s3.tiff Caption : figure s3. analysis of pbi by 1h-nmr. File Name : figure s4.tiff Caption : figure s4. 1h-nmr spectroscopy analysis of dyad fractions in the copolymer. File Name : figure s5.tiff Caption : figure s5. analysis of pbci40 by 13c-nmr. File Name : figure s6.tiff Caption : figure s6. analysis of pbc, pbcis, pbi copolymers by 13c-nmr. File Name : figure s7.tiff Caption : figure s7. microstructure analysis of the pbcis. (black - 1h nmr, blue - 13c nmr)