# Electronic Supplementary Material (ESI) for Nanoscale Horizons.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_P2(1)n
_database_code_depnum_ccdc_archive 'CCDC 2033397'
loop_
_audit_author_name
_audit_author_address
'Junmo Seong'
;UNIST
South Korea
;
_audit_update_record             
;
2020-09-23 deposited with the CCDC.	2021-02-17 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'H47 K10 O91.50 P2 W18 Zn4'
_chemical_formula_weight         5535.09

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 21/n'
_space_group_name_Hall           '-P 2yn'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.283(3)
_cell_length_b                   21.373(4)
_cell_length_c                   15.622(3)
_cell_angle_alpha                90
_cell_angle_beta                 92.27(3)
_cell_angle_gamma                90
_cell_volume                     4098.0(14)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    2235
_cell_measurement_theta_min      2.070
_cell_measurement_theta_max      27.487

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    4.486
_exptl_crystal_F_000             4902
_exptl_transmission_factor_min   0.464
_exptl_transmission_factor_max   0.833
_exptl_crystal_size_max          0.202
_exptl_crystal_size_mid          0.188
_exptl_crystal_size_min          0.183
_exptl_absorpt_coefficient_mu    26.967
_shelx_estimated_absorpt_T_min   0.074
_shelx_estimated_absorpt_T_max   0.083
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'Rigaku Rapid Auto'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'imaging plate'
_diffrn_measurement_method       'omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            29883
_diffrn_reflns_av_unetI/netI     0.0596
_diffrn_reflns_av_R_equivalents  0.0617
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_theta_min         2.070
_diffrn_reflns_theta_max         27.487
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measured_fraction_theta_full 0.975
_diffrn_reflns_Laue_measured_fraction_max 0.979
_diffrn_reflns_Laue_measured_fraction_full 0.975
_diffrn_reflns_point_group_measured_fraction_max 0.979
_diffrn_reflns_point_group_measured_fraction_full 0.975
_reflns_number_total             9199
_reflns_number_gt                8040
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Rigaku Rapid Auto'
_computing_cell_refinement       'Rigaku Rapid Auto'
_computing_data_reduction        'Rigaku Rapid Auto'
_computing_structure_solution    SHELXS
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ORTEP
_computing_publication_material  CIFTAB
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0364P)²+67.9152P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.000219(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         9199
_refine_ls_number_parameters     578
_refine_ls_number_restraints     282
_refine_ls_R_factor_all          0.0613
_refine_ls_R_factor_gt           0.0484
_refine_ls_wR_factor_ref         0.0977
_refine_ls_wR_factor_gt          0.0937
_refine_ls_goodness_of_fit_ref   1.164
_refine_ls_restrained_S_all      1.150
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.13088(4) 0.17018(2) 0.04764(3) 0.00476(11) Uani 1 1 d . . . . .
W2 W -0.13834(4) 0.20279(2) 0.00397(3) 0.00570(11) Uani 1 1 d . . . . .
W3 W -0.02005(4) 0.23940(2) 0.20250(3) 0.00523(11) Uani 1 1 d . . . . .
W4 W -0.34736(4) 0.11044(2) 0.10881(3) 0.00543(11) Uani 1 1 d . . . . .
W5 W -0.27899(4) -0.00716(2) 0.24569(3) 0.00647(12) Uani 1 1 d . . . . .
W6 W -0.23450(4) 0.14663(2) 0.30809(3) 0.00525(11) Uani 1 1 d . . . . .
W7 W 0.00974(4) -0.04256(2) 0.29313(3) 0.00631(11) Uani 1 1 d . . . . .
W8 W 0.20695(4) 0.04164(2) 0.19721(3) 0.00543(11) Uani 1 1 d . . . . .
W9 W 0.05847(4) 0.11156(2) 0.35463(3) 0.00563(11) Uani 1 1 d . . . . .
Zn1 Zn -0.03610(13) 0.05865(6) -0.06856(8) 0.0072(3) Uani 1 1 d . . . . .
Zn2 Zn 0.21445(13) 0.02367(7) -0.02501(8) 0.0070(3) Uani 1 1 d . . . . .
K1 K 0.2997(4) 0.17063(16) -0.1589(2) 0.0354(10) Uani 1 1 d . . . . .
K2 K 0.2778(3) 0.21222(14) 0.26666(17) 0.0133(6) Uani 1 1 d . . . . .
K3 K 0.3744(3) 0.31473(16) 0.02634(19) 0.0265(8) Uani 1 1 d . . . . .
K4 K 0.0906(3) 0.42108(15) 0.2167(2) 0.0248(8) Uani 1 1 d . . . . .
K5 K -0.2051(3) 0.37741(17) 0.0497(2) 0.0305(9) Uani 1 1 d . . . . .
P1 P -0.0685(3) 0.07560(14) 0.14139(18) 0.0065(6) Uani 1 1 d . . . . .
O1T O 0.0176(8) 0.2161(4) -0.0139(5) 0.0091(18) Uani 1 1 d . U . . .
O2T O -0.1021(8) 0.2596(4) 0.1023(5) 0.0093(18) Uani 1 1 d . U . . .
O3T O 0.1072(7) 0.2333(4) 0.1388(5) 0.0046(16) Uani 1 1 d . U . . .
O4T O -0.3863(8) 0.0433(4) 0.1840(5) 0.0078(17) Uani 1 1 d . U . . .
O5T O -0.2833(7) 0.0659(4) 0.3279(5) 0.0067(17) Uani 1 1 d . U . . .
O6T O -0.3402(7) 0.1577(4) 0.2205(5) 0.0065(17) Uani 1 1 d . U . . .
O7T O 0.1622(8) -0.0255(4) 0.2661(5) 0.0083(18) Uani 1 1 d . U . . .
O8T O 0.1901(7) 0.0931(4) 0.3035(5) 0.0048(16) Uani 1 1 d . U . . .
O9T O 0.0395(8) 0.0256(4) 0.3765(5) 0.0069(17) Uani 1 1 d . U . . .
O10T O 0.1963(7) 0.1212(4) 0.1387(5) 0.0050(17) Uani 1 1 d . U . . .
O11T O -0.2603(8) 0.1771(4) 0.0679(5) 0.0076(17) Uani 1 1 d . U . . .
O12T O -0.1382(8) -0.0228(4) 0.3032(5) 0.0103(18) Uani 1 1 d . U . . .
O13T O -0.1480(7) 0.2093(4) 0.2525(5) 0.0054(17) Uani 1 1 d . U . . .
O14T O -0.0947(8) 0.1215(4) 0.3579(5) 0.0084(18) Uani 1 1 d . U . . .
O15T O 0.0539(7) 0.1860(4) 0.2854(5) 0.0063(17) Uani 1 1 d . U . . .
O1TK O 0.2446(8) 0.2015(4) 0.0059(5) 0.0077(17) Uani 1 1 d . U . . .
O2TK O -0.1958(8) 0.2578(4) -0.0644(5) 0.0081(18) Uani 1 1 d . U . . .
O3TK O -0.0060(8) 0.3116(4) 0.2496(5) 0.0109(18) Uani 1 1 d . U . . .
O4TK O -0.4758(8) 0.1367(4) 0.0749(5) 0.0086(18) Uani 1 1 d . U . . .
O5TK O -0.3612(8) -0.0606(4) 0.2954(5) 0.0116(19) Uani 1 1 d . U . . .
O6TK O -0.2856(8) 0.1881(4) 0.3899(5) 0.0098(18) Uani 1 1 d . U . . .
O7TK O 0.0258(8) -0.1065(4) 0.3584(5) 0.014(2) Uani 1 1 d . U . . .
O8TK O 0.3462(8) 0.0316(4) 0.2035(5) 0.0124(19) Uani 1 1 d . U . . .
O9TK O 0.1025(9) 0.1395(4) 0.4529(6) 0.017(2) Uani 1 1 d . U . . .
O1Z O -0.1363(8) 0.1337(4) -0.0589(5) 0.0075(18) Uani 1 1 d . U . . .
O2Z O 0.1043(8) 0.0999(4) -0.0169(5) 0.0075(18) Uani 1 1 d . U . . .
O3Z O 0.0057(8) 0.0761(4) -0.1886(5) 0.0088(18) Uani 1 1 d . U . . .
O4Z O 0.1636(8) 0.0019(4) 0.0975(5) 0.0070(18) Uani 1 1 d . U . . .
O5Z O 0.3074(8) -0.0573(4) -0.0294(5) 0.0111(19) Uani 1 1 d . U . . .
O6Z O 0.2416(8) 0.0460(4) -0.1515(5) 0.0100(19) Uani 1 1 d . U . . .
O1ZW O 0.3534(9) 0.0736(5) 0.0011(6) 0.021(2) Uani 1 1 d . U . . .
O1K O 0.4826(10) 0.2233(5) -0.0620(6) 0.026(2) Uani 1 1 d . U . . .
O2K O 0.1973(12) 0.1903(6) -0.3311(8) 0.043(3) Uani 1 1 d . U . . .
O3K O 0.0497(10) 0.2032(5) -0.1921(6) 0.026(3) Uani 1 1 d . U . . .
O4K O 0.4438(10) 0.2448(5) 0.1630(6) 0.023(2) Uani 1 1 d . U . . .
O5K O 0.2642(10) 0.3426(5) 0.2740(6) 0.025(2) Uani 1 1 d . U . . .
O6K O 0.4580(9) 0.1312(5) 0.3052(6) 0.023(2) Uani 1 1 d . U . . .
O7K O 0.2000(16) 0.3911(8) 0.0726(11) 0.075(5) Uani 1 1 d . U . . .
O8K O 0.0226(9) 0.4464(4) 0.3974(6) 0.016(2) Uani 1 1 d . U . . .
O9K O -0.3079(11) 0.5060(6) 0.0102(7) 0.042(3) Uani 1 1 d . U . . .
O10K O 0.0054(13) 0.3569(6) -0.0141(8) 0.046(3) Uani 1 1 d . U . . .
O11K O -0.157(5) 0.468(2) -0.076(3) 0.088(15) Uani 0.3945 1 d . U P . .
O12K O -0.035(4) 0.5011(19) 0.072(3) 0.069(12) Uani 0.3968 1 d . U P . .
O1P O -0.0373(7) 0.1422(4) 0.1112(5) 0.0060(17) Uani 1 1 d . U . . .
O2P O -0.1818(7) 0.0797(4) 0.1817(5) 0.0048(16) Uani 1 1 d . U . . .
O3P O 0.0148(7) 0.0552(4) 0.2138(5) 0.0058(17) Uani 1 1 d . U . . .
O4P O -0.0699(7) 0.0295(4) 0.0668(5) 0.0056(17) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 O1TK 1.702(9) . ?
W1 O2Z 1.832(8) . ?
W1 O10T 1.917(8) . ?
W1 O1T 1.928(9) . ?
W1 O3T 1.992(8) . ?
W1 O1P 2.402(9) . ?
W2 O2TK 1.721(8) . ?
W2 O1Z 1.774(8) . ?
W2 O11T 1.914(9) . ?
W2 O1T 1.967(10) . ?
W2 O2T 1.995(8) . ?
W2 O1P 2.420(8) . ?
W3 O3TK 1.715(9) . ?
W3 O2T 1.878(8) . ?
W3 O3T 1.890(9) . ?
W3 O13T 1.895(9) . ?
W3 O15T 1.926(8) . ?
W3 O1P 2.525(8) . ?
W3 K1 3.697(3) 4_566 ?
W4 O4TK 1.738(9) . ?
W4 O5Z 1.766(8) 3 ?
W4 O11T 1.906(9) . ?
W4 O4T 1.927(8) . ?
W4 O6T 2.015(8) . ?
W4 O2P 2.383(9) . ?
W5 O5TK 1.729(9) . ?
W5 O6Z 1.766(8) 3 ?
W5 O4T 1.931(9) . ?
W5 O12T 1.946(9) . ?
W5 O5T 2.023(8) . ?
W5 O2P 2.443(8) . ?
W5 K1 3.753(3) 3 ?
W5 K5 4.048(3) 2_445 ?
W6 O6TK 1.696(8) . ?
W6 O5T 1.858(8) . ?
W6 O6T 1.863(8) . ?
W6 O14T 1.933(9) . ?
W6 O13T 1.936(8) . ?
W6 K3 3.706(3) 4_566 ?
W6 K1 3.960(4) 4_566 ?
W7 O7TK 1.713(9) . ?
W7 O3Z 1.787(8) 3 ?
W7 O12T 1.878(10) . ?
W7 O7T 1.970(9) . ?
W7 O9T 1.979(8) . ?
W7 O3P 2.432(8) . ?
W8 O8TK 1.723(10) . ?
W8 O4Z 1.835(8) . ?
W8 O7T 1.889(8) . ?
W8 O10T 1.932(8) . ?
W8 O8T 2.009(8) . ?
W8 O3P 2.402(9) . ?
W8 K4 3.791(4) 2_545 ?
W9 O9TK 1.715(9) . ?
W9 O8T 1.874(9) . ?
W9 O9T 1.885(8) . ?
W9 O14T 1.896(10) . ?
W9 O15T 1.923(8) . ?
W9 K3 3.908(4) 4_566 ?
W9 K5 4.132(4) 4_666 ?
Zn1 O3Z 1.999(8) . ?
Zn1 O1Z 2.032(9) . ?
Zn1 O4Z 2.069(9) 3 ?
Zn1 O2Z 2.071(9) . ?
Zn1 O4P 2.258(8) . ?
Zn1 O4P 2.291(9) 3 ?
Zn2 O1ZW 2.041(10) . ?
Zn2 O6Z 2.072(8) . ?
Zn2 O5Z 2.076(9) . ?
Zn2 O4Z 2.088(8) . ?
Zn2 O2Z 2.124(9) . ?
Zn2 O4P 2.186(9) 3 ?
K1 O6Z 2.761(9) . ?
K1 O1TK 2.768(8) . ?
K1 O3TK 2.856(10) 4_665 ?
K1 O1K 2.887(13) . ?
K1 O2K 2.955(14) . ?
K1 O13T 2.997(9) 4_665 ?
K1 O3K 3.172(13) . ?
K1 O5TK 3.283(9) 3 ?
K1 O6TK 3.296(9) 4_665 ?
K2 O2TK 2.722(8) 4_666 ?
K2 O4K 2.743(11) . ?
K2 O5K 2.795(11) . ?
K2 O8T 2.832(9) . ?
K2 O15T 2.833(10) . ?
K2 O6K 2.856(11) . ?
K2 O3T 2.873(9) . ?
K2 O10T 2.937(8) . ?
K2 K5 4.816(4) 4_666 ?
K3 O4K 2.716(10) . ?
K3 O7TK 2.721(10) 2 ?
K3 O1K 2.764(12) . ?
K3 O7K 2.810(19) . ?
K3 O6TK 2.841(9) 4_665 ?
K3 O1TK 2.908(9) . ?
K3 O14T 3.001(9) 4_665 ?
K3 O9TK 3.222(11) 4_665 ?
K4 O3TK 2.683(9) . ?
K4 O7K 2.743(18) . ?
K4 O8TK 2.767(10) 2 ?
K4 O5K 2.830(12) . ?
K4 O5TK 2.844(11) 2_455 ?
K4 O8K 3.024(10) . ?
K4 O12K 3.19(4) . ?
K4 O7T 3.246(10) 2 ?
K4 O11K 3.36(5) 3_565 ?
K5 O2K 2.679(13) 4_566 ?
K5 O9TK 2.778(11) 4_565 ?
K5 O11K 2.83(5) . ?
K5 O10K 2.842(15) . ?
K5 O5TK 2.849(9) 2_455 ?
K5 O2T 2.921(9) . ?
K5 O9K 3.076(15) . ?
K5 O2TK 3.122(9) . ?
K5 O12K 3.38(4) . ?
P1 O4P 1.525(8) . ?
P1 O1P 1.552(9) . ?
P1 O2P 1.553(9) . ?
P1 O3P 1.557(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1TK W1 O2Z 104.1(4) . . ?
O1TK W1 O10T 99.9(4) . . ?
O2Z W1 O10T 91.2(3) . . ?
O1TK W1 O1T 101.3(4) . . ?
O2Z W1 O1T 91.9(4) . . ?
O10T W1 O1T 157.1(4) . . ?
O1TK W1 O3T 98.8(4) . . ?
O2Z W1 O3T 157.1(4) . . ?
O10T W1 O3T 84.8(3) . . ?
O1T W1 O3T 83.6(3) . . ?
O1TK W1 O1P 171.2(3) . . ?
O2Z W1 O1P 83.4(3) . . ?
O10T W1 O1P 84.2(3) . . ?
O1T W1 O1P 73.6(3) . . ?
O3T W1 O1P 73.8(3) . . ?
O2TK W2 O1Z 103.8(4) . . ?
O2TK W2 O11T 102.1(4) . . ?
O1Z W2 O11T 94.5(4) . . ?
O2TK W2 O1T 101.0(4) . . ?
O1Z W2 O1T 90.4(4) . . ?
O11T W2 O1T 154.5(3) . . ?
O2TK W2 O2T 97.8(4) . . ?
O1Z W2 O2T 157.7(4) . . ?
O11T W2 O2T 85.9(4) . . ?
O1T W2 O2T 80.4(4) . . ?
O2TK W2 O1P 169.0(3) . . ?
O1Z W2 O1P 85.4(3) . . ?
O11T W2 O1P 82.9(3) . . ?
O1T W2 O1P 72.5(3) . . ?
O2T W2 O1P 72.6(3) . . ?
O3TK W3 O2T 101.1(4) . . ?
O3TK W3 O3T 102.5(4) . . ?
O2T W3 O3T 90.3(4) . . ?
O3TK W3 O13T 101.5(4) . . ?
O2T W3 O13T 89.7(4) . . ?
O3T W3 O13T 155.6(3) . . ?
O3TK W3 O15T 102.0(4) . . ?
O2T W3 O15T 156.9(4) . . ?
O3T W3 O15T 86.3(3) . . ?
O13T W3 O15T 84.2(4) . . ?
O3TK W3 O1P 171.0(3) . . ?
O2T W3 O1P 71.8(3) . . ?
O3T W3 O1P 72.5(3) . . ?
O13T W3 O1P 84.4(3) . . ?
O15T W3 O1P 85.4(3) . . ?
O3TK W3 K1 48.2(3) . 4_566 ?
O2T W3 K1 93.1(3) . 4_566 ?
O3T W3 K1 150.6(3) . 4_566 ?
O13T W3 K1 53.8(2) . 4_566 ?
O15T W3 K1 101.1(2) . 4_566 ?
O1P W3 K1 136.1(2) . 4_566 ?
O4TK W4 O5Z 105.5(4) . 3 ?
O4TK W4 O11T 99.9(4) . . ?
O5Z W4 O11T 94.0(4) 3 . ?
O4TK W4 O4T 100.5(4) . . ?
O5Z W4 O4T 91.8(4) 3 . ?
O11T W4 O4T 156.5(4) . . ?
O4TK W4 O6T 96.4(4) . . ?
O5Z W4 O6T 157.9(4) 3 . ?
O11T W4 O6T 84.8(3) . . ?
O4T W4 O6T 81.3(3) . . ?
O4TK W4 O2P 169.1(3) . . ?
O5Z W4 O2P 84.4(4) 3 . ?
O11T W4 O2P 83.5(3) . . ?
O4T W4 O2P 74.4(3) . . ?
O6T W4 O2P 73.5(3) . . ?
O5TK W5 O6Z 103.9(4) . 3 ?
O5TK W5 O4T 101.2(4) . . ?
O6Z W5 O4T 92.4(4) 3 . ?
O5TK W5 O12T 101.7(4) . . ?
O6Z W5 O12T 92.7(4) 3 . ?
O4T W5 O12T 154.6(4) . . ?
O5TK W5 O5T 101.2(4) . . ?
O6Z W5 O5T 154.9(4) 3 . ?
O4T W5 O5T 81.5(3) . . ?
O12T W5 O5T 83.4(4) . . ?
O5TK W5 O2P 171.7(4) . . ?
O6Z W5 O2P 82.5(3) 3 . ?
O4T W5 O2P 72.9(3) . . ?
O12T W5 O2P 83.1(3) . . ?
O5T W5 O2P 72.5(3) . . ?
O5TK W5 K1 61.0(3) . 3 ?
O6Z W5 K1 43.7(3) 3 3 ?
O4T W5 K1 107.7(3) . 3 ?
O12T W5 K1 93.1(3) . 3 ?
O5T W5 K1 160.8(2) . 3 ?
O2P W5 K1 125.96(19) . 3 ?
O5TK W5 K5 36.4(3) . 2_445 ?
O6Z W5 K5 113.2(3) 3 2_445 ?
O4T W5 K5 132.9(3) . 2_445 ?
O12T W5 K5 66.5(3) . 2_445 ?
O5T W5 K5 88.0(2) . 2_445 ?
O2P W5 K5 145.68(19) . 2_445 ?
K1 W5 K5 73.33(8) 3 2_445 ?
O6TK W6 O5T 103.2(4) . . ?
O6TK W6 O6T 102.7(4) . . ?
O5T W6 O6T 91.1(4) . . ?
O6TK W6 O14T 101.0(4) . . ?
O5T W6 O14T 87.8(4) . . ?
O6T W6 O14T 155.9(4) . . ?
O6TK W6 O13T 101.7(4) . . ?
O5T W6 O13T 154.7(4) . . ?
O6T W6 O13T 87.8(4) . . ?
O14T W6 O13T 83.0(4) . . ?
O6TK W6 K3 47.2(3) . 4_566 ?
O5T W6 K3 99.3(2) . 4_566 ?
O6T W6 K3 149.6(3) . 4_566 ?
O14T W6 K3 53.8(2) . 4_566 ?
O13T W6 K3 94.2(2) . 4_566 ?
O6TK W6 K1 55.0(3) . 4_566 ?
O5T W6 K1 158.2(3) . 4_566 ?
O6T W6 K1 92.2(3) . 4_566 ?
O14T W6 K1 97.7(3) . 4_566 ?
O13T W6 K1 47.0(2) . 4_566 ?
K3 W6 K1 68.15(7) 4_566 4_566 ?
O7TK W7 O3Z 103.2(4) . 3 ?
O7TK W7 O12T 102.7(4) . . ?
O3Z W7 O12T 95.7(4) 3 . ?
O7TK W7 O7T 100.8(4) . . ?
O3Z W7 O7T 86.9(4) 3 . ?
O12T W7 O7T 155.1(4) . . ?
O7TK W7 O9T 100.5(4) . . ?
O3Z W7 O9T 155.1(4) 3 . ?
O12T W7 O9T 86.2(4) . . ?
O7T W7 O9T 81.5(4) . . ?
O7TK W7 O3P 170.1(4) . . ?
O3Z W7 O3P 83.3(3) 3 . ?
O12T W7 O3P 83.9(3) . . ?
O7T W7 O3P 71.8(3) . . ?
O9T W7 O3P 72.2(3) . . ?
O8TK W8 O4Z 104.1(4) . . ?
O8TK W8 O7T 100.6(4) . . ?
O4Z W8 O7T 93.0(4) . . ?
O8TK W8 O10T 100.7(4) . . ?
O4Z W8 O10T 89.6(3) . . ?
O7T W8 O10T 157.3(4) . . ?
O8TK W8 O8T 99.0(4) . . ?
O4Z W8 O8T 156.8(4) . . ?
O7T W8 O8T 84.4(3) . . ?
O10T W8 O8T 84.4(3) . . ?
O8TK W8 O3P 170.6(3) . . ?
O4Z W8 O3P 83.9(3) . . ?
O7T W8 O3P 73.8(3) . . ?
O10T W8 O3P 84.0(3) . . ?
O8T W8 O3P 73.2(3) . . ?
O8TK W8 K4 42.2(3) . 2_545 ?
O4Z W8 K4 98.7(3) . 2_545 ?
O7T W8 K4 58.9(3) . 2_545 ?
O10T W8 K4 142.8(3) . 2_545 ?
O8T W8 K4 99.6(2) . 2_545 ?
O3P W8 K4 132.7(2) . 2_545 ?
O9TK W9 O8T 102.0(4) . . ?
O9TK W9 O9T 102.3(4) . . ?
O8T W9 O9T 89.2(4) . . ?
O9TK W9 O14T 102.4(4) . . ?
O8T W9 O14T 155.4(3) . . ?
O9T W9 O14T 88.5(4) . . ?
O9TK W9 O15T 102.5(4) . . ?
O8T W9 O15T 86.6(4) . . ?
O9T W9 O15T 155.1(3) . . ?
O14T W9 O15T 85.2(4) . . ?
O9TK W9 K3 54.3(4) . 4_566 ?
O8T W9 K3 155.5(2) . 4_566 ?
O9T W9 K3 100.9(3) . 4_566 ?
O14T W9 K3 48.3(2) . 4_566 ?
O15T W9 K3 92.7(2) . 4_566 ?
O9TK W9 K5 29.8(4) . 4_666 ?
O8T W9 K5 74.6(2) . 4_666 ?
O9T W9 K5 90.6(3) . 4_666 ?
O14T W9 K5 130.0(2) . 4_666 ?
O15T W9 K5 111.8(3) . 4_666 ?
K3 W9 K5 83.08(8) 4_566 4_666 ?
O3Z Zn1 O1Z 95.8(3) . . ?
O3Z Zn1 O4Z 97.6(3) . 3 ?
O1Z Zn1 O4Z 93.1(4) . 3 ?
O3Z Zn1 O2Z 92.6(4) . . ?
O1Z Zn1 O2Z 97.6(3) . . ?
O4Z Zn1 O2Z 164.3(3) 3 . ?
O3Z Zn1 O4P 173.4(3) . . ?
O1Z Zn1 O4P 90.8(3) . . ?
O4Z Zn1 O4P 82.3(3) 3 . ?
O2Z Zn1 O4P 86.2(3) . . ?
O3Z Zn1 O4P 89.9(3) . 3 ?
O1Z Zn1 O4P 174.2(3) . 3 ?
O4Z Zn1 O4P 85.0(3) 3 3 ?
O2Z Zn1 O4P 83.2(3) . 3 ?
O4P Zn1 O4P 83.6(3) . 3 ?
O1ZW Zn2 O6Z 84.5(4) . . ?
O1ZW Zn2 O5Z 89.2(4) . . ?
O6Z Zn2 O5Z 92.9(3) . . ?
O1ZW Zn2 O4Z 102.2(4) . . ?
O6Z Zn2 O4Z 171.9(4) . . ?
O5Z Zn2 O4Z 91.7(3) . . ?
O1ZW Zn2 O2Z 96.7(4) . . ?
O6Z Zn2 O2Z 90.4(3) . . ?
O5Z Zn2 O2Z 173.5(4) . . ?
O4Z Zn2 O2Z 84.4(3) . . ?
O1ZW Zn2 O4P 174.1(3) . 3 ?
O6Z Zn2 O4P 89.7(3) . 3 ?
O5Z Zn2 O4P 89.8(3) . 3 ?
O4Z Zn2 O4P 83.6(3) . 3 ?
O2Z Zn2 O4P 84.5(3) . 3 ?
O6Z K1 O1TK 96.8(3) . . ?
O6Z K1 O3TK 111.9(3) . 4_665 ?
O1TK K1 O3TK 132.4(3) . 4_665 ?
O6Z K1 O1K 123.4(3) . . ?
O1TK K1 O1K 68.5(3) . . ?
O3TK K1 O1K 64.0(3) 4_665 . ?
O6Z K1 O2K 94.2(3) . . ?
O1TK K1 O2K 134.6(4) . . ?
O3TK K1 O2K 81.9(3) 4_665 . ?
O1K K1 O2K 135.8(4) . . ?
O6Z K1 O13T 154.9(3) . 4_665 ?
O1TK K1 O13T 106.9(2) . 4_665 ?
O3TK K1 O13T 57.1(2) 4_665 4_665 ?
O1K K1 O13T 74.5(3) . 4_665 ?
O2K K1 O13T 63.2(3) . 4_665 ?
O6Z K1 O3K 88.2(3) . . ?
O1TK K1 O3K 80.2(3) . . ?
O3TK K1 O3K 135.4(3) 4_665 . ?
O1K K1 O3K 136.8(3) . . ?
O2K K1 O3K 56.3(3) . . ?
O13T K1 O3K 87.7(3) 4_665 . ?
O6Z K1 O5TK 53.3(2) . 3 ?
O1TK K1 O5TK 147.8(3) . 3 ?
O3TK K1 O5TK 63.4(3) 4_665 3 ?
O1K K1 O5TK 115.2(3) . 3 ?
O2K K1 O5TK 67.1(3) . 3 ?
O13T K1 O5TK 104.7(2) 4_665 3 ?
O3K K1 O5TK 107.3(3) . 3 ?
O6Z K1 O6TK 142.1(3) . 4_665 ?
O1TK K1 O6TK 58.3(2) . 4_665 ?
O3TK K1 O6TK 105.9(3) 4_665 4_665 ?
O1K K1 O6TK 76.7(3) . 4_665 ?
O2K K1 O6TK 87.3(3) . 4_665 ?
O13T K1 O6TK 53.0(2) 4_665 4_665 ?
O3K K1 O6TK 61.5(3) . 4_665 ?
O5TK K1 O6TK 152.9(2) 3 4_665 ?
O6Z K1 W3 133.5(2) . 4_665 ?
O1TK K1 W3 126.5(2) . 4_665 ?
O3TK K1 W3 26.59(18) 4_665 4_665 ?
O1K K1 W3 68.5(2) . 4_665 ?
O2K K1 W3 68.6(3) . 4_665 ?
O13T K1 W3 30.69(17) 4_665 4_665 ?
O3K K1 W3 112.9(2) . 4_665 ?
O5TK K1 W3 80.43(17) 3 4_665 ?
O6TK K1 W3 82.08(17) 4_665 4_665 ?
O6Z K1 W5 26.25(17) . 3 ?
O1TK K1 W5 122.9(2) . 3 ?
O3TK K1 W5 89.39(19) 4_665 3 ?
O1K K1 W5 126.3(3) . 3 ?
O2K K1 W5 77.5(3) . 3 ?
O13T K1 W5 130.02(18) 4_665 3 ?
O3K K1 W5 95.4(2) . 3 ?
O5TK K1 W5 27.42(16) 3 3 ?
O6TK K1 W5 156.8(2) 4_665 3 ?
W3 K1 W5 107.83(8) 4_665 3 ?
O6Z K1 W6 158.5(3) . 4_665 ?
O1TK K1 W6 81.80(19) . 4_665 ?
O3TK K1 W6 83.68(19) 4_665 4_665 ?
O1K K1 W6 76.1(2) . 4_665 ?
O2K K1 W6 72.6(3) . 4_665 ?
O13T K1 W6 28.23(16) 4_665 4_665 ?
O3K K1 W6 70.4(2) . 4_665 ?
O5TK K1 W6 130.39(18) 3 4_665 ?
O6TK K1 W6 24.95(15) 4_665 4_665 ?
W3 K1 W6 58.24(5) 4_665 4_665 ?
W5 K1 W6 149.98(11) 3 4_665 ?
O2TK K2 O4K 116.7(3) 4_666 . ?
O2TK K2 O5K 74.4(3) 4_666 . ?
O4K K2 O5K 79.5(3) . . ?
O2TK K2 O8T 92.7(2) 4_666 . ?
O4K K2 O8T 130.2(3) . . ?
O5K K2 O8T 149.8(3) . . ?
O2TK K2 O15T 91.4(3) 4_666 . ?
O4K K2 O15T 149.1(3) . . ?
O5K K2 O15T 97.7(3) . . ?
O8T K2 O15T 54.7(3) . . ?
O2TK K2 O6K 82.9(3) 4_666 . ?
O4K K2 O6K 72.0(3) . . ?
O5K K2 O6K 130.0(3) . . ?
O8T K2 O6K 73.1(3) . . ?
O15T K2 O6K 127.3(3) . . ?
O2TK K2 O3T 133.8(3) 4_666 . ?
O4K K2 O3T 95.1(3) . . ?
O5K K2 O3T 80.1(3) . . ?
O8T K2 O3T 90.5(2) . . ?
O15T K2 O3T 54.4(2) . . ?
O6K K2 O3T 141.3(3) . . ?
O2TK K2 O10T 147.2(3) 4_666 . ?
O4K K2 O10T 90.4(3) . . ?
O5K K2 O10T 132.0(3) . . ?
O8T K2 O10T 54.6(2) . . ?
O15T K2 O10T 68.5(2) . . ?
O6K K2 O10T 89.0(3) . . ?
O3T K2 O10T 53.9(2) . . ?
O2TK K2 K5 37.30(18) 4_666 4_666 ?
O4K K2 K5 129.5(2) . 4_666 ?
O5K K2 K5 111.1(2) . 4_666 ?
O8T K2 K5 57.26(16) . 4_666 ?
O15T K2 K5 80.42(18) . 4_666 ?
O6K K2 K5 63.9(2) . 4_666 ?
O3T K2 K5 134.81(19) . 4_666 ?
O10T K2 K5 111.27(17) . 4_666 ?
O4K K3 O7TK 72.6(3) . 2 ?
O4K K3 O1K 82.0(3) . . ?
O7TK K3 O1K 123.7(4) 2 . ?
O4K K3 O7K 109.7(4) . . ?
O7TK K3 O7K 78.4(4) 2 . ?
O1K K3 O7K 157.8(5) . . ?
O4K K3 O6TK 139.8(3) . 4_665 ?
O7TK K3 O6TK 142.1(3) 2 4_665 ?
O1K K3 O6TK 86.7(3) . 4_665 ?
O7K K3 O6TK 72.2(4) . 4_665 ?
O4K K3 O1TK 77.4(3) . . ?
O7TK K3 O1TK 144.9(3) 2 . ?
O1K K3 O1TK 68.2(3) . . ?
O7K K3 O1TK 95.3(4) . . ?
O6TK K3 O1TK 62.6(2) 4_665 . ?
O4K K3 O14T 153.2(3) . 4_665 ?
O7TK K3 O14T 103.3(3) 2 4_665 ?
O1K K3 O14T 78.7(3) . 4_665 ?
O7K K3 O14T 94.9(4) . 4_665 ?
O6TK K3 O14T 57.3(3) 4_665 4_665 ?
O1TK K3 O14T 111.7(2) . 4_665 ?
O4K K3 O9TK 101.3(3) . 4_665 ?
O7TK K3 O9TK 70.9(3) 2 4_665 ?
O1K K3 O9TK 66.1(3) . 4_665 ?
O7K K3 O9TK 126.7(4) . 4_665 ?
O6TK K3 O9TK 109.0(3) 4_665 4_665 ?
O1TK K3 O9TK 134.0(3) . 4_665 ?
O14T K3 O9TK 53.7(3) 4_665 4_665 ?
O4K K3 W6 159.5(2) . 4_665 ?
O7TK K3 W6 127.4(2) 2 4_665 ?
O1K K3 W6 82.0(2) . 4_665 ?
O7K K3 W6 81.7(4) . 4_665 ?
O6TK K3 W6 25.99(18) 4_665 4_665 ?
O1TK K3 W6 84.74(17) . 4_665 ?
O14T K3 W6 31.32(18) 4_665 4_665 ?
O9TK K3 W6 83.80(18) 4_665 4_665 ?
O4K K3 W9 126.1(3) . 4_665 ?
O7TK K3 W9 87.0(2) 2 4_665 ?
O1K K3 W9 68.9(2) . 4_665 ?
O7K K3 W9 114.2(4) . 4_665 ?
O6TK K3 W9 84.00(19) 4_665 4_665 ?
O1TK K3 W9 126.14(18) . 4_665 ?
O14T K3 W9 28.14(18) 4_665 4_665 ?
O9TK K3 W9 25.59(17) 4_665 4_665 ?
W6 K3 W9 58.41(5) 4_665 4_665 ?
O3TK K4 O7K 100.9(4) . . ?
O3TK K4 O8TK 141.0(3) . 2 ?
O7K K4 O8TK 115.5(4) . 2 ?
O3TK K4 O5K 75.9(3) . . ?
O7K K4 O5K 74.5(5) . . ?
O8TK K4 O5K 99.7(3) 2 . ?
O3TK K4 O5TK 71.9(3) . 2_455 ?
O7K K4 O5TK 119.6(5) . 2_455 ?
O8TK K4 O5TK 99.9(3) 2 2_455 ?
O5K K4 O5TK 146.6(3) . 2_455 ?
O3TK K4 O8K 80.6(3) . . ?
O7K K4 O8K 166.0(5) . . ?
O8TK K4 O8K 60.6(3) 2 . ?
O5K K4 O8K 92.5(3) . . ?
O5TK K4 O8K 74.2(3) 2_455 . ?
O3TK K4 O12K 113.5(9) . . ?
O7K K4 O12K 77.4(9) . . ?
O8TK K4 O12K 89.0(8) 2 . ?
O5K K4 O12K 151.7(9) . . ?
O5TK K4 O12K 55.1(9) 2_455 . ?
O8K K4 O12K 115.0(8) . . ?
O3TK K4 O7T 135.3(3) . 2 ?
O7K K4 O7T 70.3(4) . 2 ?
O8TK K4 O7T 54.4(3) 2 2 ?
O5K K4 O7T 59.4(3) . 2 ?
O5TK K4 O7T 151.5(3) 2_455 2 ?
O8K K4 O7T 98.7(3) . 2 ?
O12K K4 O7T 107.2(9) . 2 ?
O3TK K4 O11K 149.7(9) . 3_565 ?
O7K K4 O11K 59.3(10) . 3_565 ?
O8TK K4 O11K 67.6(9) 2 3_565 ?
O5K K4 O11K 115.2(10) . 3_565 ?
O5TK K4 O11K 97.2(10) 2_455 3_565 ?
O8K K4 O11K 124.5(9) . 3_565 ?
O12K K4 O11K 43.9(13) . 3_565 ?
O7T K4 O11K 63.5(10) 2 3_565 ?
O3TK K4 W8 144.5(2) . 2 ?
O7K K4 W8 96.5(4) . 2 ?
O8TK K4 W8 24.7(2) 2 2 ?
O5K K4 W8 79.3(2) . 2 ?
O5TK K4 W8 124.4(2) 2_455 2 ?
O8K K4 W8 75.4(2) . 2 ?
O12K K4 W8 100.4(8) . 2 ?
O7T K4 W8 29.88(15) 2 2 ?
O11K K4 W8 65.0(9) 3_565 2 ?
O3TK K4 K1 35.5(2) . 4_566 ?
O7K K4 K1 131.7(4) . 4_566 ?
O8TK K4 K1 112.6(2) 2 4_566 ?
O5K K4 K1 101.7(2) . 4_566 ?
O5TK K4 K1 45.50(19) 2_455 4_566 ?
O8K K4 K1 55.3(2) . 4_566 ?
O12K K4 K1 99.6(9) . 4_566 ?
O7T K4 K1 149.27(18) 2 4_566 ?
O11K K4 K1 142.7(10) 3_565 4_566 ?
W8 K4 K1 130.78(9) 2 4_566 ?
O2K K5 O9TK 85.1(4) 4_566 4_565 ?
O2K K5 O11K 164.1(12) 4_566 . ?
O9TK K5 O11K 84.6(11) 4_565 . ?
O2K K5 O10K 126.8(4) 4_566 . ?
O9TK K5 O10K 123.7(4) 4_565 . ?
O11K K5 O10K 69.2(12) . . ?
O2K K5 O5TK 77.4(3) 4_566 2_455 ?
O9TK K5 O5TK 137.0(3) 4_565 2_455 ?
O11K K5 O5TK 102.3(10) . 2_455 ?
O10K K5 O5TK 97.8(4) . 2_455 ?
O2K K5 O2T 62.6(4) 4_566 . ?
O9TK K5 O2T 113.0(3) 4_565 . ?
O11K K5 O2T 133.0(11) . . ?
O10K K5 O2T 64.9(3) . . ?
O5TK K5 O2T 93.2(3) 2_455 . ?
O2K K5 O9K 115.5(4) 4_566 . ?
O9TK K5 O9K 70.9(3) 4_565 . ?
O11K K5 O9K 49.3(11) . . ?
O10K K5 O9K 116.0(4) . . ?
O5TK K5 O9K 81.7(3) 2_455 . ?
O2T K5 O9K 174.9(3) . . ?
O2K K5 O2TK 89.0(3) 4_566 . ?
O9TK K5 O2TK 68.4(3) 4_565 . ?
O11K K5 O2TK 98.5(10) . . ?
O10K K5 O2TK 67.6(3) . . ?
O5TK K5 O2TK 148.2(3) 2_455 . ?
O2T K5 O2TK 55.2(2) . . ?
O9K K5 O2TK 129.9(3) . . ?
O2K K5 O12K 130.2(8) 4_566 . ?
O9TK K5 O12K 131.7(8) 4_565 . ?
O11K K5 O12K 52.6(13) . . ?
O10K K5 O12K 65.7(8) . . ?
O5TK K5 O12K 52.8(7) 2_455 . ?
O2T K5 O12K 112.8(8) . . ?
O9K K5 O12K 64.4(8) . . ?
O2TK K5 O12K 131.5(8) . . ?
O2K K5 W5 75.2(3) 4_566 2_455 ?
O9TK K5 W5 116.3(2) 4_565 2_455 ?
O11K K5 W5 98.7(10) . 2_455 ?
O10K K5 W5 116.3(3) . 2_455 ?
O5TK K5 W5 21.1(2) 2_455 2_455 ?
O2T K5 W5 109.70(18) . 2_455 ?
O9K K5 W5 65.3(2) . 2_455 ?
O2TK K5 W5 162.57(19) . 2_455 ?
O12K K5 W5 59.5(7) . 2_455 ?
O2K K5 W9 102.9(3) 4_566 4_565 ?
O9TK K5 W9 17.85(19) 4_565 4_565 ?
O11K K5 W9 67.0(11) . 4_565 ?
O10K K5 W9 111.9(3) . 4_565 ?
O5TK K5 W9 140.2(2) 2_455 4_565 ?
O2T K5 W9 122.7(2) . 4_565 ?
O9K K5 W9 62.0(2) . 4_565 ?
O2TK K5 W9 70.49(17) . 4_565 ?
O12K K5 W9 116.3(7) . 4_565 ?
W5 K5 W9 119.55(9) 2_455 4_565 ?
O2K K5 K1 36.1(3) 4_566 4_566 ?
O9TK K5 K1 118.7(2) 4_565 4_566 ?
O11K K5 K1 146.3(10) . 4_566 ?
O10K K5 K1 109.4(3) . 4_566 ?
O5TK K5 K1 44.07(19) 2_455 4_566 ?
O2T K5 K1 63.07(18) . 4_566 ?
O9K K5 K1 112.4(2) . 4_566 ?
O2TK K5 K1 112.20(18) . 4_566 ?
O12K K5 K1 95.2(7) . 4_566 ?
W5 K5 K1 50.42(6) 2_455 4_566 ?
W9 K5 K1 135.55(12) 4_565 4_566 ?
O4P P1 O1P 110.8(4) . . ?
O4P P1 O2P 111.3(5) . . ?
O1P P1 O2P 107.9(5) . . ?
O4P P1 O3P 111.2(5) . . ?
O1P P1 O3P 108.3(5) . . ?
O2P P1 O3P 107.2(5) . . ?
W1 O1T W2 122.9(4) . . ?
W3 O2T W2 126.7(5) . . ?
W3 O2T K5 130.2(4) . . ?
W2 O2T K5 103.1(3) . . ?
W3 O3T W1 124.8(4) . . ?
W3 O3T K2 103.9(3) . . ?
W1 O3T K2 105.5(3) . . ?
W4 O4T W5 122.6(5) . . ?
W6 O5T W5 126.5(4) . . ?
W6 O6T W4 125.3(5) . . ?
W8 O7T W7 124.3(5) . . ?
W8 O7T K4 91.2(3) . 2_545 ?
W7 O7T K4 144.3(4) . 2_545 ?
W9 O8T W8 125.9(4) . . ?
W9 O8T K2 103.8(3) . . ?
W8 O8T K2 105.8(3) . . ?
W9 O9T W7 128.3(4) . . ?
W1 O10T W8 148.2(5) . . ?
W1 O10T K2 105.3(3) . . ?
W8 O10T K2 104.2(3) . . ?
W4 O11T W2 148.2(5) . . ?
W7 O12T W5 147.7(5) . . ?
W3 O13T W6 153.9(5) . . ?
W3 O13T K1 95.5(3) . 4_566 ?
W6 O13T K1 104.7(3) . 4_566 ?
W9 O14T W6 152.5(5) . . ?
W9 O14T K3 103.6(3) . 4_566 ?
W6 O14T K3 94.9(3) . 4_566 ?
W9 O15T W3 150.5(5) . . ?
W9 O15T K2 102.4(4) . . ?
W3 O15T K2 104.3(3) . . ?
W1 O1TK K1 119.8(4) . . ?
W1 O1TK K3 137.7(4) . . ?
K1 O1TK K3 98.5(3) . . ?
W2 O2TK K2 142.4(4) . 4_565 ?
W2 O2TK K5 103.2(3) . . ?
K2 O2TK K5 110.8(3) 4_565 . ?
W3 O3TK K4 137.8(4) . . ?
W3 O3TK K1 105.2(4) . 4_566 ?
K4 O3TK K1 111.3(3) . 4_566 ?
W5 O5TK K4 131.0(4) . 2_445 ?
W5 O5TK K5 122.4(5) . 2_445 ?
K4 O5TK K5 104.0(3) 2_445 2_445 ?
W5 O5TK K1 91.6(3) . 3 ?
K4 O5TK K1 96.3(3) 2_445 3 ?
K5 O5TK K1 98.8(3) 2_445 3 ?
W6 O6TK K3 106.8(4) . 4_566 ?
W6 O6TK K1 100.0(4) . 4_566 ?
K3 O6TK K1 88.6(3) 4_566 4_566 ?
W7 O7TK K3 157.9(5) . 2_545 ?
W8 O8TK K4 113.1(4) . 2_545 ?
W9 O9TK K5 132.4(5) . 4_666 ?
W9 O9TK K3 100.2(4) . 4_566 ?
K5 O9TK K3 125.3(3) 4_666 4_566 ?
W2 O1Z Zn1 136.1(5) . . ?
W1 O2Z Zn1 133.7(5) . . ?
W1 O2Z Zn2 124.2(5) . . ?
Zn1 O2Z Zn2 100.0(3) . . ?
W7 O3Z Zn1 139.5(5) 3 . ?
W8 O4Z Zn1 131.8(5) . 3 ?
W8 O4Z Zn2 126.0(4) . . ?
Zn1 O4Z Zn2 101.0(3) 3 . ?
W4 O5Z Zn2 136.7(5) 3 . ?
W5 O6Z Zn2 138.0(5) 3 . ?
W5 O6Z K1 110.0(4) 3 . ?
Zn2 O6Z K1 108.3(3) . . ?
K3 O1K K1 99.1(4) . . ?
K5 O2K K1 111.7(5) 4_665 . ?
K3 O4K K2 112.7(4) . . ?
K2 O5K K4 128.6(4) . . ?
K4 O7K K3 138.6(7) . . ?
K5 O11K K4 176.6(19) . 3_565 ?
K4 O12K K5 86.1(10) . . ?
P1 O1P W1 125.5(5) . . ?
P1 O1P W2 125.1(5) . . ?
W1 O1P W2 90.4(3) . . ?
P1 O1P W3 126.8(4) . . ?
W1 O1P W3 88.5(3) . . ?
W2 O1P W3 88.8(3) . . ?
P1 O2P W4 125.7(4) . . ?
P1 O2P W5 125.7(5) . . ?
W4 O2P W5 89.0(3) . . ?
P1 O3P W8 125.1(4) . . ?
P1 O3P W7 125.5(5) . . ?
W8 O3P W7 89.8(3) . . ?
P1 O4P Zn2 123.3(5) . 3 ?
P1 O4P Zn1 122.7(5) . . ?
Zn2 O4P Zn1 92.4(3) 3 . ?
P1 O4P Zn1 122.2(5) . 3 ?
Zn2 O4P Zn1 91.7(3) 3 3 ?
Zn1 O4P Zn1 96.4(3) . 3 ?

_refine_diff_density_max         3.772
_refine_diff_density_min         -3.134
_refine_diff_density_rms         0.468


_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: water'
