# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_save
_database_code_depnum_ccdc_archive 'CCDC 1978046'
loop_
_audit_author_name
_audit_author_address
'Lanhua Chen'
;SCOOCHOW UNIVERSITY
China
;
_audit_update_record             
;
2020-03-04 deposited with the CCDC.	2020-03-10 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2017/1
_shelx_SHELXL_version_number     2017/1
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          N/A
_chemical_formula_moiety         
Ag2.7[(UO2)6Ag8[(C6H5(PO3)2]2[(C6H5(PO3)(PO3H)]4]
_chemical_formula_sum            'C36 H26 Ag10.70 O48 P12 U6'
_chemical_formula_weight         4180.60

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   10.5855(9)
_cell_length_b                   12.1032(10)
_cell_length_c                   15.3446(13)
_cell_angle_alpha                72.036(2)
_cell_angle_beta                 74.699(2)
_cell_angle_gamma                86.000(2)
_cell_volume                     1803.7(3)
_cell_formula_units_Z            1
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    7956
_cell_measurement_theta_min      2.683
_cell_measurement_theta_max      27.649

_exptl_crystal_description       lamellar
_exptl_crystal_colour            'dark blue'
_exptl_crystal_density_meas      N/A
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    3.849
_exptl_crystal_F_000             1861
_exptl_transmission_factor_min   0.258
_exptl_transmission_factor_max   0.608
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_exptl_absorpt_coefficient_mu    16.613
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   MULTI-SCAN
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   'SADABS, BRUKER'
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed tube'
_diffrn_measurement_device_type  graphite
_diffrn_measurement_method       BRUKER
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            64039
_diffrn_reflns_av_unetI/netI     0.0253
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         2.683
_diffrn_reflns_theta_max         27.649
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             8376
_reflns_number_gt                7956
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0466P)²+14.2242P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2017/1 (Sheldrick 2017)'
_refine_ls_extinction_coef       0.00046(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         8376
_refine_ls_number_parameters     587
_refine_ls_number_restraints     384
_refine_ls_R_factor_all          0.0302
_refine_ls_R_factor_gt           0.0284
_refine_ls_wR_factor_ref         0.0805
_refine_ls_wR_factor_gt          0.0792
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.020
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
U1 U 0.42414(2) 1.00850(2) 0.34491(2) 0.01198(7) Uani 1 1 d . U . . .
U2 U 1.32391(2) 0.49724(2) 0.34984(2) 0.01426(7) Uani 1 1 d . U . . .
U3 U 0.90583(2) 0.79087(2) 0.24128(2) 0.01415(7) Uani 1 1 d . U . . .
Ag4 Ag 1.01060(6) 0.65015(5) 0.45905(4) 0.03048(13) Uani 0.94 1 d . U P . .
Ag3 Ag 0.68028(6) 0.50620(5) 0.36586(5) 0.03756(15) Uani 1 1 d . U . . .
Ag2 Ag 0.34990(6) 1.16949(6) 0.52720(4) 0.04329(17) Uani 1 1 d . U . . .
Ag1 Ag 0.97455(7) 0.02983(6) 0.59980(6) 0.05161(18) Uani 1 1 d . U . . .
P3 P 0.55508(14) 0.74556(12) 0.27070(12) 0.0159(3) Uani 1 1 d . U . . .
P6 P 0.57995(15) 1.27719(13) 0.32522(11) 0.0187(3) Uani 1 1 d . U . . .
P5 P 0.78291(14) 1.05736(13) 0.27270(12) 0.0189(3) Uani 1 1 d . U . . .
P2 P 0.98974(15) 0.48483(13) 0.32812(12) 0.0188(3) Uani 1 1 d . U . . .
P1 P 1.15398(15) 0.22046(12) 0.38778(11) 0.0168(3) Uani 1 1 d . U . . .
O11 O 0.2517(4) 0.6909(4) 0.3510(3) 0.0192(8) Uani 1 1 d . U . . .
O7 O 0.5031(4) 0.8185(4) 0.3374(3) 0.0222(9) Uani 1 1 d . U . . .
O10 O 0.1038(4) 0.8231(4) 0.2609(4) 0.0268(10) Uani 1 1 d . U . . .
O22 O 1.3272(5) 0.4660(4) 0.4709(3) 0.0262(10) Uani 1 1 d . U . . .
O20 O 0.3891(5) 0.9399(4) 0.4691(3) 0.0239(9) Uani 1 1 d . U . . .
O24 O 0.8424(5) 0.7632(5) 0.3671(4) 0.0314(11) Uani 1 1 d . U . . .
O8 O 0.7034(4) 0.7520(4) 0.2348(4) 0.0279(10) Uani 1 1 d . U . . .
O2 O 1.2225(4) 0.1063(4) 0.3819(3) 0.0210(9) Uani 1 1 d . U . . .
O23 O 0.9677(5) 0.8187(4) 0.1174(4) 0.0290(10) Uani 1 1 d . U . . .
O12 O 0.2496(4) 0.9044(4) 0.3296(3) 0.0218(9) Uani 1 1 d . U . . .
O9 O 0.5123(4) 0.6183(4) 0.3200(3) 0.0205(9) Uani 1 1 d . U . . .
O1 O 1.0262(5) 0.1959(4) 0.4672(3) 0.0265(10) Uani 1 1 d . U . . .
O6 O 1.0913(4) 0.4990(4) 0.3795(3) 0.0213(9) Uani 1 1 d . U . . .
O15 O 0.6532(4) 1.0004(4) 0.3346(3) 0.0213(9) Uani 1 1 d . U . . .
O16 O 0.4836(4) 1.1750(3) 0.3715(3) 0.0183(8) Uani 1 1 d . U . . .
O3 O 1.2432(5) 0.3033(4) 0.4024(4) 0.0237(9) Uani 1 1 d . U . . .
O21 O 1.3261(6) 0.5311(5) 0.2296(4) 0.0353(12) Uani 1 1 d . U . . .
O19 O 0.4591(5) 1.0759(4) 0.2219(3) 0.0248(10) Uani 1 1 d . U . . .
O5 O 0.9613(6) 0.6025(4) 0.2634(4) 0.0352(12) Uani 1 1 d . U . . .
O14 O 0.8639(5) 0.9815(4) 0.2164(4) 0.0339(12) Uani 1 1 d . U . . .
O4 O 0.8683(5) 0.4286(5) 0.4000(4) 0.0323(11) Uani 1 1 d . U . . .
O13 O 0.8632(5) 1.0858(5) 0.3336(4) 0.0376(12) Uani 1 1 d . U . . .
C8 C 0.3581(6) 0.8301(5) 0.1745(5) 0.0202(12) Uani 1 1 d . U . . .
C9 C 0.3206(7) 0.8718(7) 0.0900(5) 0.0330(16) Uani 1 1 d . U . . .
H9A H 0.234392 0.894639 0.092075 0.040 Uiso 1 1 calc R U . . .
C7 C 0.4910(6) 0.7988(5) 0.1683(5) 0.0209(12) Uani 1 1 d . U . . .
C14 C 0.6659(6) 1.2777(5) 0.2070(5) 0.0204(12) Uani 1 1 d . U . . .
C13 C 0.7523(6) 1.1900(5) 0.1871(5) 0.0224(12) Uani 1 1 d . U . . .
C1 C 1.1144(6) 0.2874(5) 0.2752(4) 0.0195(12) Uani 1 1 d . U . . .
C2 C 1.0524(6) 0.3955(5) 0.2503(5) 0.0216(12) Uani 1 1 d . U . . .
C15 C 0.6455(8) 1.3741(7) 0.1327(5) 0.0350(16) Uani 1 1 d . U . . .
H15A H 0.587624 1.431662 0.146089 0.042 Uiso 1 1 calc R U . . .
C3 C 1.0290(8) 0.4367(7) 0.1609(6) 0.0371(17) Uani 1 1 d . U . . .
H3A H 0.989369 0.508368 0.143555 0.045 Uiso 1 1 calc R U . . .
C5 C 1.1263(9) 0.2694(8) 0.1206(6) 0.0404(18) Uani 1 1 d . U . . .
H5A H 1.153139 0.228007 0.077075 0.049 Uiso 1 1 calc R U . . .
C18 C 0.8190(8) 1.2042(6) 0.0916(6) 0.0348(16) Uani 1 1 d . U . . .
H18A H 0.878282 1.148286 0.076677 0.042 Uiso 1 1 calc R U . . .
C4 C 1.0635(10) 0.3730(8) 0.0969(6) 0.045(2) Uani 1 1 d . U . . .
H4A H 1.044138 0.400547 0.038267 0.054 Uiso 1 1 calc R U . . .
C6 C 1.1495(7) 0.2271(6) 0.2081(5) 0.0303(15) Uani 1 1 d . U . . .
H6A H 1.190146 0.155589 0.223731 0.036 Uiso 1 1 calc R U . . .
C12 C 0.5776(8) 0.8074(8) 0.0813(6) 0.0391(17) Uani 1 1 d . U . . .
H12A H 0.664324 0.785923 0.078357 0.047 Uiso 1 1 calc R U . . .
C10 C 0.4074(9) 0.8806(9) 0.0028(6) 0.046(2) Uani 1 1 d . U . . .
H10A H 0.378784 0.908459 -0.052303 0.056 Uiso 1 1 calc R U . . .
C16 C 0.7113(10) 1.3836(8) 0.0396(6) 0.047(2) Uani 1 1 d . U . . .
H16A H 0.696901 1.446887 -0.009403 0.057 Uiso 1 1 calc R U . . .
C17 C 0.7980(10) 1.2992(8) 0.0202(6) 0.045(2) Uani 1 1 d . U . . .
H17A H 0.843032 1.306417 -0.042233 0.054 Uiso 1 1 calc R U . . .
C11 C 0.5359(9) 0.8482(9) -0.0026(6) 0.049(2) Uani 1 1 d . U . . .
H11A H 0.594152 0.853196 -0.060908 0.059 Uiso 1 1 calc R U . . .
O17B O 0.5197(13) 1.3877(8) 0.3303(13) 0.024(3) Uani 0.63(5) 1 d . U P A 1
O17A O 0.490(2) 1.3931(12) 0.3007(17) 0.017(5) Uani 0.37(5) 1 d . U P A 2
O18B O 0.658(2) 1.296(2) 0.3826(11) 0.025(5) Uani 0.37(4) 1 d . U P A 1
O18A O 0.6999(13) 1.2559(12) 0.3732(7) 0.026(3) Uani 0.63(4) 1 d . U P A 2
Ag6A Ag 0.8374(2) 1.1996(2) 0.4237(3) 0.0525(10) Uani 0.414(5) 1 d . U P A 1
Ag6C Ag 0.8728(16) 1.2324(14) 0.3697(18) 0.037(5) Uani 0.053(5) 1 d . U P A 2
Ag5 Ag 0.2874(18) 0.7274(6) 0.4870(4) 0.026(2) Uani 0.248(16) 1 d . U P B 3
Ag7 Ag 0.601(3) 1.3152(8) 0.5263(5) 0.028(3) Uani 0.177(16) 1 d . U P C 4
Ag9 Ag 0.649(3) 1.2991(13) 0.5240(6) 0.030(3) Uani 0.198(15) 1 d . U P D 5
Ag8 Ag 0.7643(15) 1.2522(8) 0.5040(4) 0.0339(18) Uani 0.253(15) 1 d . U P E 6
Ag10 Ag 0.459(3) 0.6700(14) 0.4764(9) 0.047(5) Uani 0.070(7) 1 d . U P F 7
P4 P 0.23622(13) 0.81201(12) 0.28351(11) 0.0142(3) Uani 1 1 d . U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
U1 O19 1.758(4) . ?
U1 O20 1.775(4) . ?
U1 O16 2.334(4) . ?
U1 O15 2.385(4) . ?
U1 O2 2.387(4) 1_465 ?
U1 O12 2.407(4) . ?
U1 O7 2.417(4) . ?
U1 Ag5 3.587(4) . ?
U1 Ag8 3.638(5) 2_676 ?
U1 Ag2 3.6556(6) 2_676 ?
U1 Ag9 3.671(9) 2_676 ?
U2 O21 1.757(5) . ?
U2 O22 1.788(5) . ?
U2 O17A 2.196(14) 1_645 ?
U2 O3 2.374(4) . ?
U2 O6 2.383(4) . ?
U2 O17B 2.383(12) 1_645 ?
U2 O11 2.418(4) 1_655 ?
U2 O9 2.418(4) 1_655 ?
U2 Ag7 3.620(10) 2_776 ?
U2 Ag9 3.638(11) 2_776 ?
U3 O23 1.770(5) . ?
U3 O24 1.800(5) . ?
U3 O14 2.251(5) . ?
U3 O5 2.258(5) . ?
U3 O8 2.260(4) . ?
U3 O10 2.270(4) 1_655 ?
U3 Ag4 3.6713(7) . ?
Ag4 O1 2.424(5) 2_766 ?
Ag4 O6 2.485(4) . ?
Ag4 O6 2.582(5) 2_766 ?
Ag4 Ag8 2.986(8) 2_776 ?
Ag4 Ag5 3.307(14) 1_655 ?
Ag3 O4 2.259(5) . ?
Ag3 O9 2.287(4) . ?
Ag3 O18B 2.49(2) 1_545 ?
Ag3 O17B 2.561(17) 1_545 ?
Ag3 Ag7 2.789(6) 1_545 ?
Ag3 Ag10 2.819(14) 2_666 ?
Ag3 Ag9 2.867(9) 1_545 ?
Ag3 Ag5 3.089(8) 2_666 ?
Ag3 Ag8 3.365(11) 1_545 ?
Ag2 O16 2.417(4) . ?
Ag2 O15 2.451(4) 2_676 ?
Ag2 O24 2.506(5) 2_676 ?
Ag2 O3 2.557(5) 1_465 ?
Ag2 Ag10 2.88(2) 2_676 ?
Ag2 Ag7 3.29(2) . ?
Ag1 O1 2.350(5) . ?
Ag1 O13 2.380(6) 2_766 ?
Ag1 O12 2.519(4) 2_666 ?
Ag1 Ag1 3.2605(18) 2_756 ?
Ag1 Ag6A 3.357(2) 2_766 ?
P3 O8 1.519(5) . ?
P3 O7 1.524(5) . ?
P3 O9 1.532(4) . ?
P3 C7 1.795(7) . ?
P3 Ag10 2.913(13) . ?
P3 Ag7 3.003(9) 2_676 ?
P6 O18B 1.428(14) . ?
P6 O17B 1.456(9) . ?
P6 O16 1.525(4) . ?
P6 O18A 1.598(11) . ?
P6 O17A 1.642(19) . ?
P6 C14 1.800(7) . ?
P5 O15 1.517(4) . ?
P5 O14 1.521(5) . ?
P5 O13 1.540(5) . ?
P5 C13 1.805(7) . ?
P2 O4 1.497(5) . ?
P2 O5 1.526(5) . ?
P2 O6 1.537(4) . ?
P2 C2 1.820(7) . ?
P1 O3 1.527(5) . ?
P1 O2 1.532(4) . ?
P1 O1 1.538(5) . ?
P1 C1 1.813(6) . ?
O11 P4 1.539(4) . ?
O11 Ag5 2.388(6) . ?
O11 Ag9 2.452(11) 2_676 ?
O11 Ag8 2.486(9) 2_676 ?
O7 Ag7 2.270(9) 2_676 ?
O7 Ag10 2.286(14) . ?
O7 Ag9 2.408(14) 2_676 ?
O10 P4 1.518(4) . ?
O12 P4 1.527(4) . ?
O9 Ag10 2.574(15) . ?
O1 Ag6A 2.261(5) 1_545 ?
O1 Ag6C 2.417(16) 1_545 ?
O4 Ag8 2.370(7) 1_545 ?
O4 Ag5 2.489(10) 2_666 ?
O4 Ag6C 2.552(13) 1_545 ?
O13 Ag6C 2.032(13) . ?
O13 Ag6A 2.193(6) . ?
C8 C9 1.390(9) . ?
C8 C7 1.417(8) . ?
C8 P4 1.785(7) . ?
C9 C10 1.388(12) . ?
C9 H9A 0.9300 . ?
C7 C12 1.383(10) . ?
C14 C13 1.405(8) . ?
C14 C15 1.408(10) . ?
C13 C18 1.412(10) . ?
C1 C6 1.398(9) . ?
C1 C2 1.412(8) . ?
C1 Ag6C 2.60(2) 1_545 ?
C2 C3 1.390(10) . ?
C15 C16 1.387(12) . ?
C15 H15A 0.9300 . ?
C3 C4 1.390(12) . ?
C3 H3A 0.9300 . ?
C5 C6 1.363(11) . ?
C5 C4 1.370(13) . ?
C5 H5A 0.9300 . ?
C18 C17 1.374(12) . ?
C18 H18A 0.9300 . ?
C4 H4A 0.9300 . ?
C6 H6A 0.9300 . ?
C12 C11 1.405(12) . ?
C12 H12A 0.9300 . ?
C10 C11 1.377(13) . ?
C10 H10A 0.9300 . ?
C16 C17 1.374(13) . ?
C16 H16A 0.9300 . ?
C17 H17A 0.9300 . ?
C11 H11A 0.9300 . ?
O18B Ag6A 2.29(3) . ?
O18A Ag6C 1.82(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O19 U1 O20 179.8(2) . . ?
O19 U1 O16 92.10(19) . . ?
O20 U1 O16 88.07(19) . . ?
O19 U1 O15 89.38(19) . . ?
O20 U1 O15 90.53(19) . . ?
O16 U1 O15 71.94(15) . . ?
O19 U1 O2 95.7(2) . 1_465 ?
O20 U1 O2 84.50(19) . 1_465 ?
O16 U1 O2 75.53(14) . 1_465 ?
O15 U1 O2 147.23(15) . 1_465 ?
O19 U1 O12 87.8(2) . . ?
O20 U1 O12 92.19(19) . . ?
O16 U1 O12 145.99(14) . . ?
O15 U1 O12 142.02(15) . . ?
O2 U1 O12 70.66(14) 1_465 . ?
O19 U1 O7 96.5(2) . . ?
O20 U1 O7 83.31(19) . . ?
O16 U1 O7 141.74(15) . . ?
O15 U1 O7 70.94(15) . . ?
O2 U1 O7 139.89(15) 1_465 . ?
O12 U1 O7 71.79(14) . . ?
O19 U1 Ag5 130.96(17) . . ?
O20 U1 Ag5 48.88(16) . . ?
O16 U1 Ag5 136.75(14) . . ?
O15 U1 Ag5 107.2(3) . . ?
O2 U1 Ag5 93.7(3) 1_465 . ?
O12 U1 Ag5 50.9(2) . . ?
O7 U1 Ag5 50.7(3) . . ?
O19 U1 Ag8 131.57(18) . 2_676 ?
O20 U1 Ag8 48.31(17) . 2_676 ?
O16 U1 Ag8 133.78(18) . 2_676 ?
O15 U1 Ag8 115.7(3) . 2_676 ?
O2 U1 Ag8 84.5(3) 1_465 2_676 ?
O12 U1 Ag8 46.57(17) . 2_676 ?
O7 U1 Ag8 59.2(3) . 2_676 ?
O19 U1 Ag2 125.68(16) . 2_676 ?
O20 U1 Ag2 54.16(15) . 2_676 ?
O16 U1 Ag2 91.76(11) . 2_676 ?
O15 U1 Ag2 41.59(11) . 2_676 ?
O2 U1 Ag2 137.44(11) 1_465 2_676 ?
O12 U1 Ag2 115.66(11) . 2_676 ?
O7 U1 Ag2 53.45(11) . 2_676 ?
O19 U1 Ag9 128.4(2) . 2_676 ?
O20 U1 Ag9 51.4(2) . 2_676 ?
O16 U1 Ag9 138.49(15) . 2_676 ?
O15 U1 Ag9 96.7(5) . 2_676 ?
O2 U1 Ag9 105.1(5) 1_465 2_676 ?
O12 U1 Ag9 57.4(3) . 2_676 ?
O7 U1 Ag9 40.4(4) . 2_676 ?
Ag2 U1 Ag9 59.2(4) 2_676 2_676 ?
O21 U2 O22 177.8(2) . . ?
O21 U2 O17A 79.1(8) . 1_645 ?
O22 U2 O17A 100.2(8) . 1_645 ?
O21 U2 O3 98.8(2) . . ?
O22 U2 O3 82.92(19) . . ?
O17A U2 O3 74.3(4) 1_645 . ?
O21 U2 O6 86.0(2) . . ?
O22 U2 O6 95.8(2) . . ?
O17A U2 O6 139.1(7) 1_645 . ?
O3 U2 O6 70.69(15) . . ?
O21 U2 O17B 92.4(5) . 1_645 ?
O22 U2 O17B 86.7(5) . 1_645 ?
O3 U2 O17B 77.4(2) . 1_645 ?
O6 U2 O17B 147.4(3) . 1_645 ?
O21 U2 O11 90.9(2) . 1_655 ?
O22 U2 O11 88.49(19) . 1_655 ?
O3 U2 O11 140.73(15) . 1_655 ?
O6 U2 O11 72.19(14) . 1_655 ?
O17B U2 O11 140.4(3) 1_645 1_655 ?
O21 U2 O9 94.3(2) . 1_655 ?
O22 U2 O9 83.57(19) . 1_655 ?
O3 U2 O9 144.98(15) . 1_655 ?
O6 U2 O9 142.93(14) . 1_655 ?
O17B U2 O9 69.7(3) 1_645 1_655 ?
O11 U2 O9 70.74(14) 1_655 1_655 ?
O21 U2 Ag7 128.5(2) . 2_776 ?
O22 U2 Ag7 49.9(2) . 2_776 ?
O3 U2 Ag7 132.50(16) . 2_776 ?
O6 U2 Ag7 105.0(4) . 2_776 ?
O17B U2 Ag7 101.3(6) 1_645 2_776 ?
O11 U2 Ag7 48.8(4) 1_655 2_776 ?
O9 U2 Ag7 47.8(3) 1_655 2_776 ?
O21 U2 Ag9 126.8(2) . 2_776 ?
O22 U2 Ag9 51.8(2) . 2_776 ?
O3 U2 Ag9 132.37(16) . 2_776 ?
O6 U2 Ag9 97.0(5) . 2_776 ?
O17B U2 Ag9 109.7(6) 1_645 2_776 ?
O11 U2 Ag9 42.0(4) 1_655 2_776 ?
O9 U2 Ag9 54.0(4) 1_655 2_776 ?
O23 U3 O24 179.7(2) . . ?
O23 U3 O14 89.0(2) . . ?
O24 U3 O14 90.8(2) . . ?
O23 U3 O5 89.8(2) . . ?
O24 U3 O5 90.5(2) . . ?
O14 U3 O5 176.4(2) . . ?
O23 U3 O8 91.7(2) . . ?
O24 U3 O8 88.2(2) . . ?
O14 U3 O8 92.41(19) . . ?
O5 U3 O8 90.95(19) . . ?
O23 U3 O10 92.8(2) . 1_655 ?
O24 U3 O10 87.3(2) . 1_655 ?
O14 U3 O10 88.85(19) . 1_655 ?
O5 U3 O10 87.88(18) . 1_655 ?
O8 U3 O10 175.29(19) . 1_655 ?
O23 U3 Ag4 138.73(16) . . ?
O24 U3 Ag4 41.54(17) . . ?
O14 U3 Ag4 114.21(15) . . ?
O5 U3 Ag4 64.93(14) . . ?
O8 U3 Ag4 119.16(14) . . ?
O10 U3 Ag4 56.28(13) 1_655 . ?
O1 Ag4 O6 169.54(15) 2_766 . ?
O1 Ag4 O6 90.13(15) 2_766 2_766 ?
O6 Ag4 O6 93.81(15) . 2_766 ?
O1 Ag4 Ag8 60.3(3) 2_766 2_776 ?
O6 Ag4 Ag8 109.3(3) . 2_776 ?
O6 Ag4 Ag8 102.77(13) 2_766 2_776 ?
O1 Ag4 Ag5 69.2(3) 2_766 1_655 ?
O6 Ag4 Ag5 100.5(3) . 1_655 ?
O6 Ag4 Ag5 103.25(11) 2_766 1_655 ?
O1 Ag4 U3 100.89(12) 2_766 . ?
O6 Ag4 U3 83.03(11) . . ?
O6 Ag4 U3 135.48(9) 2_766 . ?
Ag8 Ag4 U3 120.24(10) 2_776 . ?
Ag5 Ag4 U3 121.05(6) 1_655 . ?
O4 Ag3 O9 168.79(17) . . ?
O4 Ag3 O18B 76.4(5) . 1_545 ?
O9 Ag3 O18B 114.1(5) . 1_545 ?
O4 Ag3 O17B 121.3(3) . 1_545 ?
O9 Ag3 O17B 68.6(3) . 1_545 ?
O18B Ag3 O17B 45.6(6) 1_545 1_545 ?
O4 Ag3 Ag7 75.1(6) . 1_545 ?
O9 Ag3 Ag7 114.4(6) . 1_545 ?
O18B Ag3 Ag7 49.0(4) 1_545 1_545 ?
O17B Ag3 Ag7 73.1(5) 1_545 1_545 ?
O4 Ag3 Ag10 88.5(6) . 2_666 ?
O9 Ag3 Ag10 101.1(6) . 2_666 ?
O18B Ag3 Ag10 51.6(6) 1_545 2_666 ?
O17B Ag3 Ag10 65.0(6) 1_545 2_666 ?
O4 Ag3 Ag9 64.7(6) . 1_545 ?
O9 Ag3 Ag9 125.0(6) . 1_545 ?
O18B Ag3 Ag9 46.9(4) 1_545 1_545 ?
O17B Ag3 Ag9 78.5(5) 1_545 1_545 ?
O4 Ag3 Ag5 52.7(3) . 2_666 ?
O9 Ag3 Ag5 137.6(4) . 2_666 ?
O18B Ag3 Ag5 43.9(3) 1_545 2_666 ?
O17B Ag3 Ag5 83.1(4) 1_545 2_666 ?
O4 Ag3 Ag8 44.7(2) . 1_545 ?
O9 Ag3 Ag8 146.0(2) . 1_545 ?
O18B Ag3 Ag8 43.9(4) 1_545 1_545 ?
O17B Ag3 Ag8 86.6(4) 1_545 1_545 ?
O16 Ag2 O15 121.33(15) . 2_676 ?
O16 Ag2 O24 151.17(15) . 2_676 ?
O15 Ag2 O24 85.61(15) 2_676 2_676 ?
O16 Ag2 O3 71.10(15) . 1_465 ?
O15 Ag2 O3 152.06(15) 2_676 1_465 ?
O24 Ag2 O3 80.16(16) 2_676 1_465 ?
O16 Ag2 Ag10 85.1(3) . 2_676 ?
O15 Ag2 Ag10 106.7(4) 2_676 2_676 ?
O24 Ag2 Ag10 97.4(5) 2_676 2_676 ?
O3 Ag2 Ag10 98.9(5) 1_465 2_676 ?
O16 Ag2 Ag7 81.89(19) . . ?
O15 Ag2 Ag7 100.6(3) 2_676 . ?
O24 Ag2 Ag7 104.6(3) 2_676 . ?
O3 Ag2 Ag7 106.2(3) 1_465 . ?
O16 Ag2 U1 95.17(10) . 2_676 ?
O15 Ag2 U1 40.22(10) 2_676 2_676 ?
O24 Ag2 U1 113.25(11) 2_676 2_676 ?
O3 Ag2 U1 165.49(11) 1_465 2_676 ?
O1 Ag1 O13 122.81(18) . 2_766 ?
O1 Ag1 O12 95.82(16) . 2_666 ?
O13 Ag1 O12 133.42(19) 2_766 2_666 ?
O1 Ag1 Ag1 67.37(12) . 2_756 ?
O13 Ag1 Ag1 101.01(15) 2_766 2_756 ?
O12 Ag1 Ag1 118.68(11) 2_666 2_756 ?
O1 Ag1 Ag6A 113.82(14) . 2_766 ?
O13 Ag1 Ag6A 40.63(15) 2_766 2_766 ?
O12 Ag1 Ag6A 145.56(12) 2_666 2_766 ?
Ag1 Ag1 Ag6A 62.69(6) 2_756 2_766 ?
O8 P3 O7 112.5(3) . . ?
O8 P3 O9 109.0(3) . . ?
O7 P3 O9 110.5(3) . . ?
O8 P3 C7 106.6(3) . . ?
O7 P3 C7 109.5(3) . . ?
O9 P3 C7 108.5(3) . . ?
O8 P3 Ag10 114.4(7) . . ?
O7 P3 Ag10 51.0(4) . . ?
O9 P3 Ag10 61.9(3) . . ?
C7 P3 Ag10 138.7(7) . . ?
O8 P3 Ag7 126.7(5) . 2_676 ?
O7 P3 Ag7 47.5(2) . 2_676 ?
O9 P3 Ag7 63.0(2) . 2_676 ?
C7 P3 Ag7 126.2(6) . 2_676 ?
O18B P6 O17B 85.7(15) . . ?
O18B P6 O16 116.0(6) . . ?
O17B P6 O16 112.9(4) . . ?
O16 P6 O18A 110.2(4) . . ?
O16 P6 O17A 105.6(7) . . ?
O18A P6 O17A 129.6(12) . . ?
O18B P6 C14 116.4(9) . . ?
O17B P6 C14 113.6(7) . . ?
O16 P6 C14 110.3(3) . . ?
O18A P6 C14 99.7(5) . . ?
O17A P6 C14 99.9(8) . . ?
O15 P5 O14 112.3(3) . . ?
O15 P5 O13 110.4(3) . . ?
O14 P5 O13 109.1(3) . . ?
O15 P5 C13 109.2(3) . . ?
O14 P5 C13 106.5(3) . . ?
O13 P5 C13 109.2(3) . . ?
O4 P2 O5 111.8(3) . . ?
O4 P2 O6 109.2(3) . . ?
O5 P2 O6 110.2(3) . . ?
O4 P2 C2 109.0(3) . . ?
O5 P2 C2 105.4(3) . . ?
O6 P2 C2 111.3(3) . . ?
O3 P1 O2 111.7(2) . . ?
O3 P1 O1 110.9(3) . . ?
O2 P1 O1 110.1(3) . . ?
O3 P1 C1 108.6(3) . . ?
O2 P1 C1 106.6(3) . . ?
O1 P1 C1 108.9(3) . . ?
P4 O11 Ag5 104.7(3) . . ?
P4 O11 U2 141.3(3) . 1_455 ?
P4 O11 Ag9 112.0(4) . 2_676 ?
U2 O11 Ag9 96.7(6) 1_455 2_676 ?
P4 O11 Ag8 98.4(3) . 2_676 ?
U2 O11 Ag8 118.7(3) 1_455 2_676 ?
P3 O7 Ag7 102.9(3) . 2_676 ?
P3 O7 Ag10 97.8(5) . . ?
P3 O7 U1 144.1(3) . . ?
Ag7 O7 U1 108.2(5) 2_676 . ?
Ag10 O7 U1 116.9(5) . . ?
P3 O7 Ag9 108.2(5) . 2_676 ?
U1 O7 Ag9 99.1(6) . 2_676 ?
P4 O10 U3 165.7(3) . 1_455 ?
U3 O24 Ag2 135.7(3) . 2_676 ?
P3 O8 U3 153.1(3) . . ?
P1 O2 U1 147.5(3) . 1_645 ?
P4 O12 U1 137.3(3) . . ?
P4 O12 Ag1 109.6(2) . 2_666 ?
U1 O12 Ag1 113.03(16) . 2_666 ?
P3 O9 Ag3 111.6(2) . . ?
P3 O9 U2 138.0(2) . 1_455 ?
Ag3 O9 U2 110.03(16) . 1_455 ?
P3 O9 Ag10 86.5(4) . . ?
Ag3 O9 Ag10 88.9(7) . . ?
U2 O9 Ag10 99.6(5) 1_455 . ?
P1 O1 Ag6A 117.2(3) . 1_545 ?
P1 O1 Ag1 127.0(3) . . ?
Ag6A O1 Ag1 96.6(2) 1_545 . ?
P1 O1 Ag6C 98.5(6) . 1_545 ?
Ag6A O1 Ag6C 19.3(5) 1_545 1_545 ?
Ag1 O1 Ag6C 113.7(6) . 1_545 ?
P1 O1 Ag4 109.6(3) . 2_766 ?
Ag6A O1 Ag4 101.05(18) 1_545 2_766 ?
Ag1 O1 Ag4 101.65(18) . 2_766 ?
P2 O6 U2 136.7(3) . . ?
P2 O6 Ag4 107.7(2) . . ?
U2 O6 Ag4 107.21(16) . . ?
P2 O6 Ag4 97.3(2) . 2_766 ?
U2 O6 Ag4 109.73(17) . 2_766 ?
Ag4 O6 Ag4 86.19(15) . 2_766 ?
P5 O15 U1 141.9(3) . . ?
P5 O15 Ag2 119.7(2) . 2_676 ?
U1 O15 Ag2 98.19(15) . 2_676 ?
P6 O16 U1 140.6(3) . . ?
P6 O16 Ag2 114.3(2) . . ?
U1 O16 Ag2 105.09(16) . . ?
P1 O3 U2 144.6(3) . . ?
P1 O3 Ag2 102.9(2) . 1_645 ?
U2 O3 Ag2 112.41(17) . 1_645 ?
P2 O5 U3 150.1(4) . . ?
P5 O14 U3 136.8(3) . . ?
P2 O4 Ag3 114.1(3) . . ?
P2 O4 Ag8 146.2(5) . 1_545 ?
Ag3 O4 Ag8 93.2(4) . 1_545 ?
P2 O4 Ag5 159.4(5) . 2_666 ?
Ag3 O4 Ag5 81.0(4) . 2_666 ?
P2 O4 Ag6C 100.7(6) . 1_545 ?
Ag3 O4 Ag6C 102.6(4) . 1_545 ?
P5 O13 Ag6C 130.8(6) . . ?
P5 O13 Ag6A 135.2(3) . . ?
P5 O13 Ag1 127.8(3) . 2_766 ?
Ag6A O13 Ag1 94.4(2) . 2_766 ?
C9 C8 C7 117.2(6) . . ?
C9 C8 P4 118.7(5) . . ?
C7 C8 P4 124.0(5) . . ?
C10 C9 C8 122.2(7) . . ?
C10 C9 H9A 118.9 . . ?
C8 C9 H9A 118.9 . . ?
C12 C7 C8 120.6(6) . . ?
C12 C7 P3 116.9(5) . . ?
C8 C7 P3 122.5(5) . . ?
C13 C14 C15 120.1(6) . . ?
C13 C14 P6 123.4(5) . . ?
C15 C14 P6 116.4(5) . . ?
C14 C13 C18 117.7(6) . . ?
C14 C13 P5 125.9(5) . . ?
C18 C13 P5 116.4(5) . . ?
C6 C1 C2 118.0(6) . . ?
C6 C1 P1 117.0(5) . . ?
C2 C1 P1 125.0(5) . . ?
C6 C1 Ag6C 108.0(5) . 1_545 ?
C2 C1 Ag6C 78.7(5) . 1_545 ?
P1 C1 Ag6C 85.4(5) . 1_545 ?
C3 C2 C1 118.8(6) . . ?
C3 C2 P2 115.5(5) . . ?
C1 C2 P2 125.6(5) . . ?
C16 C15 C14 120.3(7) . . ?
C16 C15 H15A 119.9 . . ?
C14 C15 H15A 119.9 . . ?
C4 C3 C2 121.4(7) . . ?
C4 C3 H3A 119.3 . . ?
C2 C3 H3A 119.3 . . ?
C6 C5 C4 120.0(8) . . ?
C6 C5 H5A 120.0 . . ?
C4 C5 H5A 120.0 . . ?
C17 C18 C13 121.2(7) . . ?
C17 C18 H18A 119.4 . . ?
C13 C18 H18A 119.4 . . ?
C5 C4 C3 119.6(8) . . ?
C5 C4 H4A 120.2 . . ?
C3 C4 H4A 120.2 . . ?
C5 C6 C1 122.3(7) . . ?
C5 C6 H6A 118.9 . . ?
C1 C6 H6A 118.9 . . ?
C7 C12 C11 120.7(8) . . ?
C7 C12 H12A 119.6 . . ?
C11 C12 H12A 119.6 . . ?
C11 C10 C9 120.2(8) . . ?
C11 C10 H10A 119.9 . . ?
C9 C10 H10A 119.9 . . ?
C17 C16 C15 119.7(8) . . ?
C17 C16 H16A 120.1 . . ?
C15 C16 H16A 120.1 . . ?
C18 C17 C16 120.9(8) . . ?
C18 C17 H17A 119.5 . . ?
C16 C17 H17A 119.5 . . ?
C10 C11 C12 119.0(8) . . ?
C10 C11 H11A 120.5 . . ?
C12 C11 H11A 120.5 . . ?
P6 O17B U2 147.6(8) . 1_465 ?
P6 O17B Ag3 108.3(9) . 1_565 ?
U2 O17B Ag3 102.5(4) 1_465 1_565 ?
P6 O17A U2 148.3(12) . 1_465 ?
P6 O18B Ag6A 130.3(17) . . ?
P6 O18B Ag3 112.8(13) . 1_565 ?
Ag6A O18B Ag3 109.0(5) . 1_565 ?
P6 O18A Ag6C 152.3(11) . . ?
O13 Ag6A O1 107.1(2) . 1_565 ?
O13 Ag6A O18B 97.3(6) . . ?
O1 Ag6A O18B 150.8(5) 1_565 . ?
O13 Ag6A Ag1 44.98(15) . 2_766 ?
O1 Ag6A Ag1 66.21(13) 1_565 2_766 ?
O18B Ag6A Ag1 141.5(5) . 2_766 ?
O18A Ag6C O13 89.0(7) . . ?
O13 Ag6C O1 106.9(6) . 1_565 ?
O13 Ag6C O4 172.8(9) . 1_565 ?
O1 Ag6C O4 80.2(4) 1_565 1_565 ?
O13 Ag6C C1 96.7(7) . 1_565 ?
O1 Ag6C C1 65.8(4) 1_565 1_565 ?
O4 Ag6C C1 85.1(5) 1_565 1_565 ?
O11 Ag5 O4 93.3(3) . 2_666 ?
O11 Ag5 Ag3 109.2(3) . 2_666 ?
O4 Ag5 Ag3 46.25(15) 2_666 2_666 ?
O11 Ag5 Ag4 52.1(3) . 1_455 ?
O4 Ag5 Ag4 53.1(3) 2_666 1_455 ?
Ag3 Ag5 Ag4 94.67(16) 2_666 1_455 ?
O11 Ag5 U1 90.73(15) . . ?
O4 Ag5 U1 161.6(7) 2_666 . ?
Ag3 Ag5 U1 147.2(5) 2_666 . ?
Ag4 Ag5 U1 118.0(3) 1_455 . ?
O7 Ag7 Ag3 167.8(11) 2_676 1_565 ?
O7 Ag7 P3 29.66(17) 2_676 2_676 ?
Ag3 Ag7 P3 141.1(5) 1_565 2_676 ?
O7 Ag7 Ag2 60.8(4) 2_676 . ?
Ag3 Ag7 Ag2 114.4(6) 1_565 . ?
P3 Ag7 Ag2 77.2(4) 2_676 . ?
O7 Ag7 U2 93.1(3) 2_676 2_776 ?
Ag3 Ag7 U2 84.1(2) 1_565 2_776 ?
P3 Ag7 U2 67.21(15) 2_676 2_776 ?
Ag2 Ag7 U2 138.9(6) . 2_776 ?
O7 Ag9 O11 79.2(2) 2_676 2_676 ?
O7 Ag9 Ag3 144.9(13) 2_676 1_565 ?
O11 Ag9 Ag3 114.7(2) 2_676 1_565 ?
O7 Ag9 U2 90.4(5) 2_676 2_776 ?
O11 Ag9 U2 41.3(2) 2_676 2_776 ?
Ag3 Ag9 U2 82.8(3) 1_565 2_776 ?
O7 Ag9 U1 40.6(2) 2_676 2_676 ?
O11 Ag9 U1 87.8(3) 2_676 2_676 ?
Ag3 Ag9 U1 156.8(2) 1_565 2_676 ?
U2 Ag9 U1 119.87(17) 2_776 2_676 ?
O4 Ag8 O11 93.8(3) 1_565 2_676 ?
O4 Ag8 Ag4 59.0(2) 1_565 2_776 ?
O11 Ag8 Ag4 56.69(15) 2_676 2_776 ?
O4 Ag8 Ag3 42.1(2) 1_565 1_565 ?
O11 Ag8 Ag3 98.9(4) 2_676 1_565 ?
Ag4 Ag8 Ag3 95.44(14) 2_776 1_565 ?
O4 Ag8 U1 174.3(6) 1_565 2_676 ?
O11 Ag8 U1 88.0(2) 2_676 2_676 ?
Ag4 Ag8 U1 126.1(2) 2_776 2_676 ?
Ag3 Ag8 U1 132.3(4) 1_565 2_676 ?
O7 Ag10 O9 61.9(4) . . ?
O7 Ag10 Ag3 160.4(14) . 2_666 ?
O9 Ag10 Ag3 113.8(5) . 2_666 ?
O7 Ag10 Ag2 68.4(4) . 2_676 ?
O9 Ag10 Ag2 111.0(7) . 2_676 ?
Ag3 Ag10 Ag2 127.6(7) 2_666 2_676 ?
O7 Ag10 P3 31.2(2) . . ?
O9 Ag10 P3 31.66(18) . . ?
Ag3 Ag10 P3 144.7(6) 2_666 . ?
Ag2 Ag10 P3 85.4(5) 2_676 . ?
O10 P4 O12 109.3(3) . . ?
O10 P4 O11 111.1(3) . . ?
O12 P4 O11 109.3(3) . . ?
O10 P4 C8 107.2(3) . . ?
O12 P4 C8 111.6(3) . . ?
O11 P4 C8 108.4(3) . . ?

_refine_diff_density_max         3.666
_refine_diff_density_min         -3.497
_refine_diff_density_rms         0.239

