# Electronic Supplementary Material (ESI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_[Dy(Ph3PO)3(OPhCl2NO2)3]
_database_code_depnum_ccdc_archive 'CCDC 2041714'
loop_
_audit_author_name
_audit_author_address
'Lei Chen'
;Jiangsu University of Science and Technology
China
;
_audit_update_record             
;
2020-12-18 deposited with the CCDC.	2020-12-30 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2016/6
_shelx_SHELXL_version_number     2016/6
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H51 Cl6 Dy N3 O12 P3'
_chemical_formula_weight         1618.27

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.3202(2)
_cell_length_b                   15.2533(3)
_cell_length_c                   20.1701(4)
_cell_angle_alpha                88.5600(10)
_cell_angle_beta                 74.8800(10)
_cell_angle_gamma                76.9170(10)
_cell_volume                     3561.92(12)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    5465
_cell_measurement_theta_min      2.27
_cell_measurement_theta_max      18.91

_exptl_crystal_description       block
_exptl_crystal_colour            ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.509
_exptl_crystal_F_000             1626
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.410
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.350
_exptl_absorpt_coefficient_mu    1.404
_shelx_estimated_absorpt_T_min   0.597
_shelx_estimated_absorpt_T_max   0.639
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5968
_exptl_absorpt_correction_T_max  0.6391
_exptl_absorpt_process_details   sadabs
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            55664
_diffrn_reflns_av_unetI/netI     0.0924
_diffrn_reflns_av_R_equivalents  0.0869
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         1.046
_diffrn_reflns_theta_max         25.998
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measured_fraction_theta_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_point_group_measured_fraction_full 0.993
_reflns_number_total             13901
_reflns_number_gt                9467
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0492P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2016/6 (Sheldrick 2016)'
_refine_ls_extinction_coef       0.00146(18)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_number_reflns         13901
_refine_ls_number_parameters     875
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0906
_refine_ls_R_factor_gt           0.0462
_refine_ls_wR_factor_ref         0.1018
_refine_ls_wR_factor_gt          0.0864
_refine_ls_goodness_of_fit_ref   0.911
_refine_ls_restrained_S_all      0.911
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.16736(2) 0.74849(2) 0.24752(2) 0.03308(9) Uani 1 1 d . . . . .
Cl1 Cl -0.00439(14) 0.61505(12) 0.13967(9) 0.0861(5) Uani 1 1 d . . . . .
Cl2 Cl 0.36685(12) 0.75390(12) 0.03157(9) 0.0798(5) Uani 1 1 d . . . . .
Cl3 Cl 0.46125(11) 0.71810(10) 0.29405(7) 0.0623(4) Uani 1 1 d . . . . .
Cl4 Cl 0.05625(11) 0.85634(12) 0.47844(8) 0.0792(5) Uani 1 1 d . . . . .
Cl5 Cl -0.03902(14) 1.00628(13) 0.34782(9) 0.0948(6) Uani 1 1 d . . . . .
Cl6 Cl -0.05908(15) 0.84561(12) 0.11859(11) 0.0995(6) Uani 1 1 d . . . . .
N1 N 0.1313(5) 0.6595(4) -0.1172(3) 0.0723(15) Uani 1 1 d . . . . .
N2 N 0.4465(4) 0.8230(3) 0.5336(2) 0.0509(11) Uani 1 1 d . . . . .
N3 N -0.3232(4) 1.1486(4) 0.2086(3) 0.0718(15) Uani 1 1 d . . . . .
O1 O 0.2902(3) 0.6086(2) 0.24059(17) 0.0493(9) Uani 1 1 d . . . . .
O2 O 0.2801(3) 0.8495(2) 0.21260(17) 0.0480(8) Uani 1 1 d . . . . .
O3 O 0.0312(2) 0.6781(2) 0.31040(17) 0.0532(9) Uani 1 1 d . . . . .
O4 O 0.1876(3) 0.7008(2) 0.14227(19) 0.0649(10) Uani 1 1 d . . . . .
O5 O 0.1966(5) 0.6856(4) -0.1657(3) 0.1080(18) Uani 1 1 d . . . . .
O6 O 0.0512(5) 0.6296(3) -0.1221(3) 0.1028(17) Uani 1 1 d . . . . .
O7 O 0.2056(3) 0.7689(2) 0.34741(16) 0.0489(8) Uani 1 1 d . . . . .
O8 O 0.5510(3) 0.7980(3) 0.5171(2) 0.0737(12) Uani 1 1 d . . . . .
O9 O 0.3918(3) 0.8574(3) 0.5907(2) 0.0749(12) Uani 1 1 d . . . . .
O10 O 0.0243(3) 0.8619(2) 0.24180(19) 0.0615(10) Uani 1 1 d . . . . .
O11 O -0.3590(4) 1.2092(3) 0.2531(3) 0.1066(17) Uani 1 1 d . . . . .
O12 O -0.3613(4) 1.1484(3) 0.1589(3) 0.0979(16) Uani 1 1 d . . . . .
P1 P 0.38281(10) 0.52363(8) 0.22731(7) 0.0440(3) Uani 1 1 d . . . . .
P2 P 0.31357(10) 0.93718(9) 0.19427(7) 0.0453(3) Uani 1 1 d . . . . .
P3 P -0.08426(10) 0.67806(9) 0.35891(7) 0.0463(3) Uani 1 1 d . . . . .
C1 C 0.3427(4) 0.4381(3) 0.1855(3) 0.0506(13) Uani 1 1 d . . . . .
C2 C 0.2361(5) 0.4575(4) 0.1717(3) 0.079(2) Uani 1 1 d . . . . .
H2 H 0.185972 0.513306 0.185038 0.095 Uiso 1 1 calc R U . . .
C3 C 0.2045(5) 0.3949(5) 0.1385(4) 0.097(2) Uani 1 1 d . . . . .
H3 H 0.132400 0.408370 0.129473 0.116 Uiso 1 1 calc R U . . .
C4 C 0.2767(7) 0.3127(5) 0.1181(4) 0.095(2) Uani 1 1 d . . . . .
H4 H 0.253150 0.270210 0.096246 0.114 Uiso 1 1 calc R U . . .
C5 C 0.3823(7) 0.2934(4) 0.1298(4) 0.090(2) Uani 1 1 d . . . . .
H5 H 0.431815 0.237627 0.115495 0.108 Uiso 1 1 calc R U . . .
C6 C 0.4173(5) 0.3558(4) 0.1627(4) 0.084(2) Uani 1 1 d . . . . .
H6 H 0.490945 0.342706 0.169592 0.101 Uiso 1 1 calc R U . . .
C7 C 0.5154(4) 0.5379(3) 0.1705(3) 0.0489(13) Uani 1 1 d . . . . .
C8 C 0.6139(4) 0.5366(4) 0.1902(3) 0.0609(15) Uani 1 1 d . . . . .
H8 H 0.614407 0.526413 0.235823 0.073 Uiso 1 1 calc R U . . .
C9 C 0.7113(5) 0.5501(4) 0.1443(4) 0.085(2) Uani 1 1 d . . . . .
H9 H 0.777121 0.549499 0.158924 0.102 Uiso 1 1 calc R U . . .
C10 C 0.7126(6) 0.5642(4) 0.0775(5) 0.094(3) Uani 1 1 d . . . . .
H10 H 0.779415 0.572930 0.046364 0.113 Uiso 1 1 calc R U . . .
C11 C 0.6171(7) 0.5657(5) 0.0559(4) 0.103(3) Uani 1 1 d . . . . .
H11 H 0.617840 0.575346 0.010047 0.123 Uiso 1 1 calc R U . . .
C12 C 0.5192(5) 0.5530(4) 0.1024(4) 0.085(2) Uani 1 1 d . . . . .
H12 H 0.453479 0.554484 0.087499 0.102 Uiso 1 1 calc R U . . .
C13 C 0.4091(4) 0.4822(3) 0.3073(3) 0.0471(13) Uani 1 1 d . . . . .
C14 C 0.4831(5) 0.4000(4) 0.3114(3) 0.0667(16) Uani 1 1 d . . . . .
H14 H 0.522226 0.364867 0.271668 0.080 Uiso 1 1 calc R U . . .
C15 C 0.4986(5) 0.3706(4) 0.3736(4) 0.0742(18) Uani 1 1 d . . . . .
H15 H 0.547777 0.315134 0.375849 0.089 Uiso 1 1 calc R U . . .
C16 C 0.4431(6) 0.4215(4) 0.4324(3) 0.0752(18) Uani 1 1 d . . . . .
H16 H 0.454467 0.400727 0.474369 0.090 Uiso 1 1 calc R U . . .
C17 C 0.3700(5) 0.5038(4) 0.4294(3) 0.0711(17) Uani 1 1 d . . . . .
H17 H 0.332253 0.538998 0.469298 0.085 Uiso 1 1 calc R U . . .
C18 C 0.3535(4) 0.5336(4) 0.3670(3) 0.0601(15) Uani 1 1 d . . . . .
H18 H 0.304093 0.589009 0.365043 0.072 Uiso 1 1 calc R U . . .
C19 C 0.2108(4) 1.0097(3) 0.1577(3) 0.0474(13) Uani 1 1 d . . . . .
C20 C 0.1785(5) 0.9751(4) 0.1050(3) 0.0676(16) Uani 1 1 d . . . . .
H20 H 0.212018 0.915908 0.089072 0.081 Uiso 1 1 calc R U . . .
C21 C 0.0971(5) 1.0269(5) 0.0758(4) 0.0791(19) Uani 1 1 d . . . . .
H21 H 0.076895 1.002913 0.040036 0.095 Uiso 1 1 calc R U . . .
C22 C 0.0465(5) 1.1130(5) 0.0993(4) 0.082(2) Uani 1 1 d . . . . .
H22 H -0.008082 1.147905 0.079408 0.098 Uiso 1 1 calc R U . . .
C23 C 0.0758(6) 1.1487(4) 0.1525(4) 0.093(2) Uani 1 1 d . . . . .
H23 H 0.039834 1.207215 0.169206 0.112 Uiso 1 1 calc R U . . .
C24 C 0.1582(5) 1.0976(4) 0.1806(4) 0.0770(19) Uani 1 1 d . . . . .
H24 H 0.179072 1.122557 0.215681 0.092 Uiso 1 1 calc R U . . .
C25 C 0.3226(4) 0.9964(3) 0.2674(3) 0.0496(13) Uani 1 1 d . . . . .
C26 C 0.3936(5) 1.0575(4) 0.2634(3) 0.0715(17) Uani 1 1 d . . . . .
H26 H 0.442355 1.065567 0.221084 0.086 Uiso 1 1 calc R U . . .
C27 C 0.3934(5) 1.1055(4) 0.3195(4) 0.0785(19) Uani 1 1 d . . . . .
H27 H 0.440321 1.146283 0.315533 0.094 Uiso 1 1 calc R U . . .
C28 C 0.3227(6) 1.0924(4) 0.3818(4) 0.0748(18) Uani 1 1 d . . . . .
H28 H 0.322674 1.124347 0.420501 0.090 Uiso 1 1 calc R U . . .
C29 C 0.2525(5) 1.0338(4) 0.3886(3) 0.0743(18) Uani 1 1 d . . . . .
H29 H 0.205046 1.026024 0.431413 0.089 Uiso 1 1 calc R U . . .
C30 C 0.2519(5) 0.9858(4) 0.3316(3) 0.0597(15) Uani 1 1 d . . . . .
H30 H 0.203673 0.945849 0.336325 0.072 Uiso 1 1 calc R U . . .
C31 C 0.4525(4) 0.9189(3) 0.1335(3) 0.0493(13) Uani 1 1 d . . . . .
C32 C 0.4910(5) 0.9874(4) 0.0946(3) 0.0631(15) Uani 1 1 d . . . . .
H32 H 0.441754 1.043963 0.097062 0.076 Uiso 1 1 calc R U . . .
C33 C 0.6018(5) 0.9724(5) 0.0523(3) 0.0778(19) Uani 1 1 d . . . . .
H33 H 0.627719 1.019417 0.027820 0.093 Uiso 1 1 calc R U . . .
C34 C 0.6730(6) 0.8893(6) 0.0464(4) 0.085(2) Uani 1 1 d . . . . .
H34 H 0.746719 0.878965 0.016704 0.102 Uiso 1 1 calc R U . . .
C35 C 0.6363(5) 0.8208(5) 0.0840(4) 0.092(2) Uani 1 1 d . . . . .
H35 H 0.686103 0.764330 0.080838 0.111 Uiso 1 1 calc R U . . .
C36 C 0.5251(4) 0.8347(4) 0.1270(3) 0.0667(16) Uani 1 1 d . . . . .
H36 H 0.499778 0.787337 0.151333 0.080 Uiso 1 1 calc R U . . .
C37 C -0.1383(4) 0.5854(3) 0.3384(3) 0.0474(13) Uani 1 1 d . . . . .
C38 C -0.0641(5) 0.5158(4) 0.2960(3) 0.0625(15) Uani 1 1 d . . . . .
H38 H 0.011983 0.518918 0.276134 0.075 Uiso 1 1 calc R U . . .
C39 C -0.1024(7) 0.4411(5) 0.2830(3) 0.087(2) Uani 1 1 d . . . . .
H39 H -0.052224 0.394376 0.254018 0.105 Uiso 1 1 calc R U . . .
C40 C -0.2135(7) 0.4359(5) 0.3125(4) 0.085(2) Uani 1 1 d . . . . .
H40 H -0.239356 0.385781 0.303559 0.102 Uiso 1 1 calc R U . . .
C41 C -0.2862(6) 0.5038(5) 0.3551(4) 0.086(2) Uani 1 1 d . . . . .
H41 H -0.361987 0.500134 0.375297 0.103 Uiso 1 1 calc R U . . .
C42 C -0.2490(5) 0.5776(4) 0.3684(3) 0.0689(17) Uani 1 1 d . . . . .
H42 H -0.299517 0.623340 0.398238 0.083 Uiso 1 1 calc R U . . .
C43 C -0.1930(4) 0.7772(4) 0.3564(3) 0.0544(14) Uani 1 1 d . . . . .
C44 C -0.2489(5) 0.7859(4) 0.3048(3) 0.0731(18) Uani 1 1 d . . . . .
H44 H -0.231264 0.740088 0.271504 0.088 Uiso 1 1 calc R U . . .
C45 C -0.3322(5) 0.8643(6) 0.3032(4) 0.093(3) Uani 1 1 d . . . . .
H45 H -0.370175 0.871058 0.268523 0.112 Uiso 1 1 calc R U . . .
C46 C -0.3584(6) 0.9314(5) 0.3526(5) 0.096(3) Uani 1 1 d . . . . .
H46 H -0.415267 0.982936 0.351817 0.115 Uiso 1 1 calc R U . . .
C47 C -0.3019(6) 0.9232(5) 0.4027(4) 0.094(2) Uani 1 1 d . . . . .
H47 H -0.319275 0.969499 0.435562 0.113 Uiso 1 1 calc R U . . .
C48 C -0.2192(5) 0.8468(4) 0.4050(3) 0.0716(17) Uani 1 1 d . . . . .
H48 H -0.180640 0.841584 0.439384 0.086 Uiso 1 1 calc R U . . .
C49 C -0.0753(4) 0.6619(3) 0.4452(3) 0.0510(13) Uani 1 1 d . . . . .
C50 C -0.1723(5) 0.6732(4) 0.5007(3) 0.0673(16) Uani 1 1 d . . . . .
H50 H -0.245187 0.694015 0.493459 0.081 Uiso 1 1 calc R U . . .
C51 C -0.1622(6) 0.6543(5) 0.5655(4) 0.093(2) Uani 1 1 d . . . . .
H51 H -0.228258 0.661433 0.601902 0.111 Uiso 1 1 calc R U . . .
C52 C -0.0564(8) 0.6251(6) 0.5774(4) 0.121(3) Uani 1 1 d . . . . .
H52 H -0.049983 0.614030 0.621937 0.146 Uiso 1 1 calc R U . . .
C53 C 0.0406(7) 0.6121(6) 0.5234(5) 0.128(3) Uani 1 1 d . . . . .
H53 H 0.112835 0.590891 0.531429 0.154 Uiso 1 1 calc R U . . .
C54 C 0.0324(5) 0.6300(5) 0.4576(4) 0.088(2) Uani 1 1 d . . . . .
H54 H 0.098822 0.620785 0.421370 0.105 Uiso 1 1 calc R U . . .
C55 C 0.1782(4) 0.6870(3) 0.0817(3) 0.0466(13) Uani 1 1 d . . . . .
C56 C 0.0894(4) 0.6488(3) 0.0694(3) 0.0523(13) Uani 1 1 d . . . . .
C57 C 0.0762(5) 0.6394(3) 0.0056(3) 0.0562(14) Uani 1 1 d . . . . .
H57 H 0.017271 0.614160 -0.000320 0.067 Uiso 1 1 calc R U . . .
C58 C 0.1498(5) 0.6672(4) -0.0506(3) 0.0534(14) Uani 1 1 d . . . . .
C59 C 0.2403(4) 0.7018(3) -0.0428(3) 0.0527(14) Uani 1 1 d . . . . .
H59 H 0.291546 0.718870 -0.080780 0.063 Uiso 1 1 calc R U . . .
C60 C 0.2530(4) 0.7106(3) 0.0216(3) 0.0502(13) Uani 1 1 d . . . . .
C61 C 0.2611(4) 0.7823(3) 0.3902(2) 0.0412(11) Uani 1 1 d . . . . .
C62 C 0.3838(4) 0.7610(3) 0.3748(2) 0.0423(12) Uani 1 1 d . . . . .
C63 C 0.4430(4) 0.7745(3) 0.4204(2) 0.0431(12) Uani 1 1 d . . . . .
H63 H 0.523261 0.759680 0.408112 0.052 Uiso 1 1 calc R U . . .
C64 C 0.3828(4) 0.8104(3) 0.4848(3) 0.0437(12) Uani 1 1 d . . . . .
C65 C 0.2626(4) 0.8346(3) 0.5036(3) 0.0470(13) Uani 1 1 d . . . . .
H65 H 0.222365 0.860004 0.546910 0.056 Uiso 1 1 calc R U . . .
C66 C 0.2055(4) 0.8202(3) 0.4571(3) 0.0455(12) Uani 1 1 d . . . . .
C67 C -0.0550(4) 0.9296(3) 0.2341(3) 0.0490(13) Uani 1 1 d . . . . .
C68 C -0.0980(4) 1.0055(4) 0.2788(3) 0.0545(14) Uani 1 1 d . . . . .
C69 C -0.1836(4) 1.0768(4) 0.2705(3) 0.0623(16) Uani 1 1 d . . . . .
H69 H -0.209483 1.125956 0.301492 0.075 Uiso 1 1 calc R U . . .
C70 C -0.2301(4) 1.0747(4) 0.2166(3) 0.0555(15) Uani 1 1 d . . . . .
C71 C -0.1923(4) 1.0039(4) 0.1699(3) 0.0607(15) Uani 1 1 d . . . . .
H71 H -0.224375 1.003633 0.132981 0.073 Uiso 1 1 calc R U . . .
C72 C -0.1066(4) 0.9333(3) 0.1783(3) 0.0566(15) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O4 2.195(4) . ?
Dy1 O10 2.197(3) . ?
Dy1 O7 2.230(3) . ?
Dy1 O2 2.281(3) . ?
Dy1 O3 2.284(3) . ?
Dy1 O1 2.303(3) . ?
Cl1 C56 1.728(5) . ?
Cl2 C60 1.738(5) . ?
Cl3 C62 1.718(4) . ?
Cl4 C66 1.735(5) . ?
Cl5 C68 1.731(6) . ?
Cl6 C72 1.715(5) . ?
N1 O6 1.204(6) . ?
N1 O5 1.216(6) . ?
N1 C58 1.432(7) . ?
N2 O8 1.215(5) . ?
N2 O9 1.233(5) . ?
N2 C64 1.450(6) . ?
N3 O12 1.213(6) . ?
N3 O11 1.227(6) . ?
N3 C70 1.453(7) . ?
O1 P1 1.497(3) . ?
O2 P2 1.497(3) . ?
O3 P3 1.501(3) . ?
O4 C55 1.285(6) . ?
O7 C61 1.278(5) . ?
O10 C67 1.288(5) . ?
P1 C7 1.789(5) . ?
P1 C1 1.796(5) . ?
P1 C13 1.799(5) . ?
P2 C19 1.784(5) . ?
P2 C25 1.789(5) . ?
P2 C31 1.794(5) . ?
P3 C49 1.781(5) . ?
P3 C43 1.788(5) . ?
P3 C37 1.793(5) . ?
C1 C6 1.384(7) . ?
C1 C2 1.379(7) . ?
C2 C3 1.359(8) . ?
C2 H2 0.9300 . ?
C3 C4 1.365(9) . ?
C3 H3 0.9300 . ?
C4 C5 1.348(9) . ?
C4 H4 0.9300 . ?
C5 C6 1.379(8) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 C8 1.368(7) . ?
C7 C12 1.377(8) . ?
C8 C9 1.365(8) . ?
C8 H8 0.9300 . ?
C9 C10 1.357(10) . ?
C9 H9 0.9300 . ?
C10 C11 1.352(10) . ?
C10 H10 0.9300 . ?
C11 C12 1.371(8) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 C14 1.388(7) . ?
C13 C18 1.381(7) . ?
C14 C15 1.368(8) . ?
C14 H14 0.9300 . ?
C15 C16 1.363(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.380(8) . ?
C16 H16 0.9300 . ?
C17 C18 1.376(8) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.382(7) . ?
C19 C24 1.384(7) . ?
C20 C21 1.380(8) . ?
C20 H20 0.9300 . ?
C21 C22 1.357(9) . ?
C21 H21 0.9300 . ?
C22 C23 1.378(9) . ?
C22 H22 0.9300 . ?
C23 C24 1.371(8) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C30 1.389(7) . ?
C25 C26 1.403(7) . ?
C26 C27 1.361(8) . ?
C26 H26 0.9300 . ?
C27 C28 1.369(8) . ?
C27 H27 0.9300 . ?
C28 C29 1.359(8) . ?
C28 H28 0.9300 . ?
C29 C30 1.380(7) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 C36 1.376(7) . ?
C31 C32 1.385(7) . ?
C32 C33 1.380(7) . ?
C32 H32 0.9300 . ?
C33 C34 1.356(9) . ?
C33 H33 0.9300 . ?
C34 C35 1.367(9) . ?
C34 H34 0.9300 . ?
C35 C36 1.390(7) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 C42 1.371(7) . ?
C37 C38 1.375(7) . ?
C38 C39 1.383(8) . ?
C38 H38 0.9300 . ?
C39 C40 1.363(9) . ?
C39 H39 0.9300 . ?
C40 C41 1.355(9) . ?
C40 H40 0.9300 . ?
C41 C42 1.365(8) . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C43 C48 1.386(8) . ?
C43 C44 1.379(8) . ?
C44 C45 1.394(8) . ?
C44 H44 0.9300 . ?
C45 C46 1.371(10) . ?
C45 H45 0.9300 . ?
C46 C47 1.357(10) . ?
C46 H46 0.9300 . ?
C47 C48 1.372(8) . ?
C47 H47 0.9300 . ?
C48 H48 0.9300 . ?
C49 C54 1.391(7) . ?
C49 C50 1.389(7) . ?
C50 C51 1.363(8) . ?
C50 H50 0.9300 . ?
C51 C52 1.360(10) . ?
C51 H51 0.9300 . ?
C52 C53 1.371(10) . ?
C52 H52 0.9300 . ?
C53 C54 1.373(10) . ?
C53 H53 0.9300 . ?
C54 H54 0.9300 . ?
C55 C60 1.410(7) . ?
C55 C56 1.426(7) . ?
C56 C57 1.354(7) . ?
C57 C58 1.378(7) . ?
C57 H57 0.9300 . ?
C58 C59 1.382(7) . ?
C59 C60 1.362(7) . ?
C59 H59 0.9300 . ?
C61 C66 1.413(6) . ?
C61 C62 1.424(6) . ?
C62 C63 1.359(6) . ?
C63 C64 1.374(6) . ?
C63 H63 0.9300 . ?
C64 C65 1.392(6) . ?
C65 C66 1.359(6) . ?
C65 H65 0.9300 . ?
C67 C68 1.400(7) . ?
C67 C72 1.423(7) . ?
C68 C69 1.374(7) . ?
C69 C70 1.359(8) . ?
C69 H69 0.9300 . ?
C70 C71 1.366(7) . ?
C71 C72 1.370(7) . ?
C71 H71 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Dy1 O10 92.24(14) . . ?
O4 Dy1 O7 161.07(12) . . ?
O10 Dy1 O7 105.59(13) . . ?
O4 Dy1 O2 93.49(13) . . ?
O10 Dy1 O2 84.58(12) . . ?
O7 Dy1 O2 82.16(12) . . ?
O4 Dy1 O3 102.31(14) . . ?
O10 Dy1 O3 87.15(12) . . ?
O7 Dy1 O3 85.19(12) . . ?
O2 Dy1 O3 162.43(12) . . ?
O4 Dy1 O1 77.11(12) . . ?
O10 Dy1 O1 164.61(12) . . ?
O7 Dy1 O1 86.49(11) . . ?
O2 Dy1 O1 106.88(11) . . ?
O3 Dy1 O1 84.37(11) . . ?
O6 N1 O5 123.6(6) . . ?
O6 N1 C58 118.8(6) . . ?
O5 N1 C58 117.6(6) . . ?
O8 N2 O9 122.7(4) . . ?
O8 N2 C64 118.9(4) . . ?
O9 N2 C64 118.4(4) . . ?
O12 N3 O11 123.0(5) . . ?
O12 N3 C70 119.5(6) . . ?
O11 N3 C70 117.5(6) . . ?
P1 O1 Dy1 171.0(2) . . ?
P2 O2 Dy1 160.05(19) . . ?
P3 O3 Dy1 152.8(2) . . ?
C55 O4 Dy1 166.8(3) . . ?
C61 O7 Dy1 160.0(3) . . ?
C67 O10 Dy1 175.8(3) . . ?
O1 P1 C7 113.0(2) . . ?
O1 P1 C1 111.4(2) . . ?
C7 P1 C1 104.6(2) . . ?
O1 P1 C13 109.7(2) . . ?
C7 P1 C13 109.2(2) . . ?
C1 P1 C13 108.8(2) . . ?
O2 P2 C19 111.0(2) . . ?
O2 P2 C25 112.3(2) . . ?
C19 P2 C25 107.2(2) . . ?
O2 P2 C31 110.6(2) . . ?
C19 P2 C31 108.5(2) . . ?
C25 P2 C31 107.0(2) . . ?
O3 P3 C49 112.0(2) . . ?
O3 P3 C43 113.8(2) . . ?
C49 P3 C43 109.0(3) . . ?
O3 P3 C37 110.6(2) . . ?
C49 P3 C37 104.9(2) . . ?
C43 P3 C37 106.0(2) . . ?
C6 C1 C2 118.8(5) . . ?
C6 C1 P1 122.6(4) . . ?
C2 C1 P1 118.4(4) . . ?
C3 C2 C1 119.8(6) . . ?
C3 C2 H2 120.1 . . ?
C1 C2 H2 120.1 . . ?
C2 C3 C4 121.3(6) . . ?
C2 C3 H3 119.4 . . ?
C4 C3 H3 119.4 . . ?
C5 C4 C3 119.7(6) . . ?
C5 C4 H4 120.2 . . ?
C3 C4 H4 120.2 . . ?
C4 C5 C6 120.4(6) . . ?
C4 C5 H5 119.8 . . ?
C6 C5 H5 119.8 . . ?
C1 C6 C5 119.9(6) . . ?
C1 C6 H6 120.0 . . ?
C5 C6 H6 120.0 . . ?
C8 C7 C12 117.1(5) . . ?
C8 C7 P1 124.4(5) . . ?
C12 C7 P1 118.5(4) . . ?
C9 C8 C7 121.2(6) . . ?
C9 C8 H8 119.4 . . ?
C7 C8 H8 119.4 . . ?
C8 C9 C10 120.3(7) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 H9 119.9 . . ?
C11 C10 C9 120.3(6) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C10 C11 C12 119.1(7) . . ?
C10 C11 H11 120.4 . . ?
C12 C11 H11 120.4 . . ?
C11 C12 C7 122.0(7) . . ?
C11 C12 H12 119.0 . . ?
C7 C12 H12 119.0 . . ?
C14 C13 C18 118.6(5) . . ?
C14 C13 P1 122.3(4) . . ?
C18 C13 P1 119.1(4) . . ?
C15 C14 C13 120.2(6) . . ?
C15 C14 H14 119.9 . . ?
C13 C14 H14 119.9 . . ?
C16 C15 C14 120.9(6) . . ?
C16 C15 H15 119.5 . . ?
C14 C15 H15 119.5 . . ?
C15 C16 C17 119.8(6) . . ?
C15 C16 H16 120.1 . . ?
C17 C16 H16 120.1 . . ?
C16 C17 C18 119.6(6) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C17 C18 C13 120.9(5) . . ?
C17 C18 H18 119.5 . . ?
C13 C18 H18 119.5 . . ?
C20 C19 C24 117.9(5) . . ?
C20 C19 P2 118.1(4) . . ?
C24 C19 P2 123.9(4) . . ?
C19 C20 C21 121.0(6) . . ?
C19 C20 H20 119.5 . . ?
C21 C20 H20 119.5 . . ?
C22 C21 C20 120.0(7) . . ?
C22 C21 H21 120.0 . . ?
C20 C21 H21 120.0 . . ?
C21 C22 C23 120.2(6) . . ?
C21 C22 H22 119.9 . . ?
C23 C22 H22 119.9 . . ?
C24 C23 C22 119.7(6) . . ?
C24 C23 H23 120.2 . . ?
C22 C23 H23 120.2 . . ?
C23 C24 C19 121.2(6) . . ?
C23 C24 H24 119.4 . . ?
C19 C24 H24 119.4 . . ?
C30 C25 C26 117.1(5) . . ?
C30 C25 P2 119.2(4) . . ?
C26 C25 P2 123.7(4) . . ?
C27 C26 C25 122.1(6) . . ?
C27 C26 H26 118.9 . . ?
C25 C26 H26 118.9 . . ?
C26 C27 C28 118.7(6) . . ?
C26 C27 H27 120.7 . . ?
C28 C27 H27 120.7 . . ?
C29 C28 C27 121.6(6) . . ?
C29 C28 H28 119.2 . . ?
C27 C28 H28 119.2 . . ?
C28 C29 C30 119.8(6) . . ?
C28 C29 H29 120.1 . . ?
C30 C29 H29 120.1 . . ?
C25 C30 C29 120.7(5) . . ?
C25 C30 H30 119.6 . . ?
C29 C30 H30 119.6 . . ?
C36 C31 C32 118.8(5) . . ?
C36 C31 P2 118.8(4) . . ?
C32 C31 P2 122.3(4) . . ?
C33 C32 C31 120.6(6) . . ?
C33 C32 H32 119.7 . . ?
C31 C32 H32 119.7 . . ?
C34 C33 C32 120.2(6) . . ?
C34 C33 H33 119.9 . . ?
C32 C33 H33 119.9 . . ?
C33 C34 C35 120.0(6) . . ?
C33 C34 H34 120.0 . . ?
C35 C34 H34 120.0 . . ?
C34 C35 C36 120.5(6) . . ?
C34 C35 H35 119.7 . . ?
C36 C35 H35 119.7 . . ?
C31 C36 C35 119.8(6) . . ?
C31 C36 H36 120.1 . . ?
C35 C36 H36 120.1 . . ?
C42 C37 C38 118.6(5) . . ?
C42 C37 P3 121.9(4) . . ?
C38 C37 P3 119.2(4) . . ?
C37 C38 C39 120.1(5) . . ?
C37 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C40 C39 C38 120.1(7) . . ?
C40 C39 H39 119.9 . . ?
C38 C39 H39 119.9 . . ?
C39 C40 C41 119.8(6) . . ?
C39 C40 H40 120.1 . . ?
C41 C40 H40 120.1 . . ?
C42 C41 C40 120.5(6) . . ?
C42 C41 H41 119.8 . . ?
C40 C41 H41 119.8 . . ?
C41 C42 C37 120.9(6) . . ?
C41 C42 H42 119.5 . . ?
C37 C42 H42 119.5 . . ?
C48 C43 C44 119.6(5) . . ?
C48 C43 P3 120.4(5) . . ?
C44 C43 P3 120.0(5) . . ?
C45 C44 C43 119.1(7) . . ?
C45 C44 H44 120.5 . . ?
C43 C44 H44 120.5 . . ?
C46 C45 C44 120.3(7) . . ?
C46 C45 H45 119.9 . . ?
C44 C45 H45 119.9 . . ?
C47 C46 C45 120.4(7) . . ?
C47 C46 H46 119.8 . . ?
C45 C46 H46 119.8 . . ?
C46 C47 C48 120.2(7) . . ?
C46 C47 H47 119.9 . . ?
C48 C47 H47 119.9 . . ?
C47 C48 C43 120.4(7) . . ?
C47 C48 H48 119.8 . . ?
C43 C48 H48 119.8 . . ?
C54 C49 C50 118.1(5) . . ?
C54 C49 P3 119.1(4) . . ?
C50 C49 P3 122.6(4) . . ?
C51 C50 C49 120.9(6) . . ?
C51 C50 H50 119.5 . . ?
C49 C50 H50 119.5 . . ?
C52 C51 C50 120.6(7) . . ?
C52 C51 H51 119.7 . . ?
C50 C51 H51 119.7 . . ?
C51 C52 C53 119.6(7) . . ?
C51 C52 H52 120.2 . . ?
C53 C52 H52 120.2 . . ?
C52 C53 C54 120.8(7) . . ?
C52 C53 H53 119.6 . . ?
C54 C53 H53 119.6 . . ?
C53 C54 C49 120.0(6) . . ?
C53 C54 H54 120.0 . . ?
C49 C54 H54 120.0 . . ?
O4 C55 C60 122.9(5) . . ?
O4 C55 C56 122.8(5) . . ?
C60 C55 C56 114.3(5) . . ?
C57 C56 C55 122.3(5) . . ?
C57 C56 Cl1 119.9(4) . . ?
C55 C56 Cl1 117.8(4) . . ?
C56 C57 C58 120.3(5) . . ?
C56 C57 H57 119.9 . . ?
C58 C57 H57 119.9 . . ?
C59 C58 C57 120.5(5) . . ?
C59 C58 N1 120.5(6) . . ?
C57 C58 N1 119.1(5) . . ?
C60 C59 C58 118.7(5) . . ?
C60 C59 H59 120.7 . . ?
C58 C59 H59 120.7 . . ?
C59 C60 C55 123.9(5) . . ?
C59 C60 Cl2 118.8(4) . . ?
C55 C60 Cl2 117.3(4) . . ?
O7 C61 C66 122.8(4) . . ?
O7 C61 C62 123.1(4) . . ?
C66 C61 C62 114.1(4) . . ?
C63 C62 C61 123.2(4) . . ?
C63 C62 Cl3 118.3(3) . . ?
C61 C62 Cl3 118.5(4) . . ?
C62 C63 C64 119.2(4) . . ?
C62 C63 H63 120.4 . . ?
C64 C63 H63 120.4 . . ?
C63 C64 C65 121.1(4) . . ?
C63 C64 N2 118.9(4) . . ?
C65 C64 N2 120.0(4) . . ?
C66 C65 C64 118.5(4) . . ?
C66 C65 H65 120.8 . . ?
C64 C65 H65 120.8 . . ?
C65 C66 C61 123.8(4) . . ?
C65 C66 Cl4 118.5(4) . . ?
C61 C66 Cl4 117.5(4) . . ?
O10 C67 C68 123.8(5) . . ?
O10 C67 C72 122.2(5) . . ?
C68 C67 C72 114.1(4) . . ?
C69 C68 C67 123.3(5) . . ?
C69 C68 Cl5 119.9(5) . . ?
C67 C68 Cl5 116.8(4) . . ?
C70 C69 C68 119.3(5) . . ?
C70 C69 H69 120.4 . . ?
C68 C69 H69 120.4 . . ?
C69 C70 C71 121.4(5) . . ?
C69 C70 N3 119.6(5) . . ?
C71 C70 N3 118.9(6) . . ?
C72 C71 C70 119.0(6) . . ?
C72 C71 H71 120.5 . . ?
C70 C71 H71 120.5 . . ?
C71 C72 C67 123.0(5) . . ?
C71 C72 Cl6 118.3(5) . . ?
C67 C72 Cl6 118.7(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O2 P2 C19 -33.1(7) . . . . ?
Dy1 O2 P2 C25 86.9(6) . . . . ?
Dy1 O2 P2 C31 -153.6(6) . . . . ?
Dy1 O3 P3 C49 -97.3(5) . . . . ?
Dy1 O3 P3 C43 26.9(6) . . . . ?
Dy1 O3 P3 C37 146.1(4) . . . . ?
O1 P1 C1 C6 174.6(5) . . . . ?
C7 P1 C1 C6 52.3(6) . . . . ?
C13 P1 C1 C6 -64.3(6) . . . . ?
O1 P1 C1 C2 -1.0(6) . . . . ?
C7 P1 C1 C2 -123.4(5) . . . . ?
C13 P1 C1 C2 120.0(5) . . . . ?
C6 C1 C2 C3 2.5(10) . . . . ?
P1 C1 C2 C3 178.3(6) . . . . ?
C1 C2 C3 C4 -0.3(12) . . . . ?
C2 C3 C4 C5 -1.3(12) . . . . ?
C3 C4 C5 C6 0.6(12) . . . . ?
C2 C1 C6 C5 -3.1(10) . . . . ?
P1 C1 C6 C5 -178.8(5) . . . . ?
C4 C5 C6 C1 1.6(12) . . . . ?
O1 P1 C7 C8 109.2(5) . . . . ?
C1 P1 C7 C8 -129.5(5) . . . . ?
C13 P1 C7 C8 -13.2(5) . . . . ?
O1 P1 C7 C12 -69.5(5) . . . . ?
C1 P1 C7 C12 51.8(5) . . . . ?
C13 P1 C7 C12 168.1(4) . . . . ?
C12 C7 C8 C9 0.2(8) . . . . ?
P1 C7 C8 C9 -178.5(4) . . . . ?
C7 C8 C9 C10 -0.6(10) . . . . ?
C8 C9 C10 C11 0.4(11) . . . . ?
C9 C10 C11 C12 0.1(12) . . . . ?
C10 C11 C12 C7 -0.5(11) . . . . ?
C8 C7 C12 C11 0.3(9) . . . . ?
P1 C7 C12 C11 179.1(6) . . . . ?
O1 P1 C13 C14 174.0(4) . . . . ?
C7 P1 C13 C14 -61.7(5) . . . . ?
C1 P1 C13 C14 51.9(5) . . . . ?
O1 P1 C13 C18 -5.7(5) . . . . ?
C7 P1 C13 C18 118.6(4) . . . . ?
C1 P1 C13 C18 -127.8(4) . . . . ?
C18 C13 C14 C15 0.9(8) . . . . ?
P1 C13 C14 C15 -178.8(5) . . . . ?
C13 C14 C15 C16 -0.7(9) . . . . ?
C14 C15 C16 C17 0.0(10) . . . . ?
C15 C16 C17 C18 0.4(9) . . . . ?
C16 C17 C18 C13 -0.1(9) . . . . ?
C14 C13 C18 C17 -0.5(8) . . . . ?
P1 C13 C18 C17 179.2(4) . . . . ?
O2 P2 C19 C20 -49.5(5) . . . . ?
C25 P2 C19 C20 -172.5(4) . . . . ?
C31 P2 C19 C20 72.2(5) . . . . ?
O2 P2 C19 C24 127.9(5) . . . . ?
C25 P2 C19 C24 4.9(5) . . . . ?
C31 P2 C19 C24 -110.4(5) . . . . ?
C24 C19 C20 C21 0.7(8) . . . . ?
P2 C19 C20 C21 178.2(4) . . . . ?
C19 C20 C21 C22 -0.8(9) . . . . ?
C20 C21 C22 C23 -0.3(10) . . . . ?
C21 C22 C23 C24 1.5(11) . . . . ?
C22 C23 C24 C19 -1.6(11) . . . . ?
C20 C19 C24 C23 0.6(9) . . . . ?
P2 C19 C24 C23 -176.9(5) . . . . ?
O2 P2 C25 C30 -30.3(5) . . . . ?
C19 P2 C25 C30 92.0(4) . . . . ?
C31 P2 C25 C30 -151.8(4) . . . . ?
O2 P2 C25 C26 153.1(4) . . . . ?
C19 P2 C25 C26 -84.7(5) . . . . ?
C31 P2 C25 C26 31.5(5) . . . . ?
C30 C25 C26 C27 -0.6(8) . . . . ?
P2 C25 C26 C27 176.1(5) . . . . ?
C25 C26 C27 C28 1.0(10) . . . . ?
C26 C27 C28 C29 -0.7(10) . . . . ?
C27 C28 C29 C30 0.1(10) . . . . ?
C26 C25 C30 C29 0.1(8) . . . . ?
P2 C25 C30 C29 -176.8(4) . . . . ?
C28 C29 C30 C25 0.2(9) . . . . ?
O2 P2 C31 C36 -19.5(5) . . . . ?
C19 P2 C31 C36 -141.5(4) . . . . ?
C25 P2 C31 C36 103.1(5) . . . . ?
O2 P2 C31 C32 162.8(4) . . . . ?
C19 P2 C31 C32 40.8(5) . . . . ?
C25 P2 C31 C32 -74.6(5) . . . . ?
C36 C31 C32 C33 -2.7(9) . . . . ?
P2 C31 C32 C33 175.0(4) . . . . ?
C31 C32 C33 C34 2.5(10) . . . . ?
C32 C33 C34 C35 -2.1(11) . . . . ?
C33 C34 C35 C36 1.9(11) . . . . ?
C32 C31 C36 C35 2.5(9) . . . . ?
P2 C31 C36 C35 -175.3(5) . . . . ?
C34 C35 C36 C31 -2.1(10) . . . . ?
O3 P3 C37 C42 -170.3(4) . . . . ?
C49 P3 C37 C42 68.7(5) . . . . ?
C43 P3 C37 C42 -46.6(5) . . . . ?
O3 P3 C37 C38 15.6(5) . . . . ?
C49 P3 C37 C38 -105.3(5) . . . . ?
C43 P3 C37 C38 139.4(4) . . . . ?
C42 C37 C38 C39 1.7(8) . . . . ?
P3 C37 C38 C39 176.0(5) . . . . ?
C37 C38 C39 C40 -0.6(10) . . . . ?
C38 C39 C40 C41 -0.4(11) . . . . ?
C39 C40 C41 C42 0.2(11) . . . . ?
C40 C41 C42 C37 1.0(10) . . . . ?
C38 C37 C42 C41 -2.0(9) . . . . ?
P3 C37 C42 C41 -176.0(5) . . . . ?
O3 P3 C43 C48 -98.2(5) . . . . ?
C49 P3 C43 C48 27.6(5) . . . . ?
C37 P3 C43 C48 140.1(4) . . . . ?
O3 P3 C43 C44 80.0(5) . . . . ?
C49 P3 C43 C44 -154.2(4) . . . . ?
C37 P3 C43 C44 -41.7(5) . . . . ?
C48 C43 C44 C45 -0.9(8) . . . . ?
P3 C43 C44 C45 -179.1(4) . . . . ?
C43 C44 C45 C46 -0.4(9) . . . . ?
C44 C45 C46 C47 1.4(11) . . . . ?
C45 C46 C47 C48 -1.1(11) . . . . ?
C46 C47 C48 C43 -0.2(10) . . . . ?
C44 C43 C48 C47 1.2(9) . . . . ?
P3 C43 C48 C47 179.4(5) . . . . ?
O3 P3 C49 C54 -15.4(6) . . . . ?
C43 P3 C49 C54 -142.2(5) . . . . ?
C37 P3 C49 C54 104.6(5) . . . . ?
O3 P3 C49 C50 169.7(4) . . . . ?
C43 P3 C49 C50 42.9(5) . . . . ?
C37 P3 C49 C50 -70.3(5) . . . . ?
C54 C49 C50 C51 0.5(9) . . . . ?
P3 C49 C50 C51 175.5(5) . . . . ?
C49 C50 C51 C52 1.0(11) . . . . ?
C50 C51 C52 C53 -1.9(14) . . . . ?
C51 C52 C53 C54 1.4(15) . . . . ?
C52 C53 C54 C49 0.1(14) . . . . ?
C50 C49 C54 C53 -1.1(10) . . . . ?
P3 C49 C54 C53 -176.2(6) . . . . ?
Dy1 O4 C55 C60 108.2(16) . . . . ?
Dy1 O4 C55 C56 -70.0(18) . . . . ?
O4 C55 C56 C57 176.0(5) . . . . ?
C60 C55 C56 C57 -2.4(7) . . . . ?
O4 C55 C56 Cl1 -3.2(7) . . . . ?
C60 C55 C56 Cl1 178.4(4) . . . . ?
C55 C56 C57 C58 0.0(8) . . . . ?
Cl1 C56 C57 C58 179.2(4) . . . . ?
C56 C57 C58 C59 2.3(8) . . . . ?
C56 C57 C58 N1 -177.8(5) . . . . ?
O6 N1 C58 C59 -179.5(5) . . . . ?
O5 N1 C58 C59 -1.1(8) . . . . ?
O6 N1 C58 C57 0.6(8) . . . . ?
O5 N1 C58 C57 179.0(5) . . . . ?
C57 C58 C59 C60 -2.0(7) . . . . ?
N1 C58 C59 C60 178.1(5) . . . . ?
C58 C59 C60 C55 -0.6(7) . . . . ?
C58 C59 C60 Cl2 179.9(4) . . . . ?
O4 C55 C60 C59 -175.7(5) . . . . ?
C56 C55 C60 C59 2.7(7) . . . . ?
O4 C55 C60 Cl2 3.8(6) . . . . ?
C56 C55 C60 Cl2 -177.8(3) . . . . ?
Dy1 O7 C61 C66 156.1(7) . . . . ?
Dy1 O7 C61 C62 -23.6(12) . . . . ?
O7 C61 C62 C63 -179.5(5) . . . . ?
C66 C61 C62 C63 0.8(7) . . . . ?
O7 C61 C62 Cl3 1.9(7) . . . . ?
C66 C61 C62 Cl3 -177.8(4) . . . . ?
C61 C62 C63 C64 0.1(8) . . . . ?
Cl3 C62 C63 C64 178.7(4) . . . . ?
C62 C63 C64 C65 -1.3(8) . . . . ?
C62 C63 C64 N2 178.8(4) . . . . ?
O8 N2 C64 C63 -3.1(7) . . . . ?
O9 N2 C64 C63 178.1(5) . . . . ?
O8 N2 C64 C65 177.0(5) . . . . ?
O9 N2 C64 C65 -1.8(7) . . . . ?
C63 C64 C65 C66 1.4(8) . . . . ?
N2 C64 C65 C66 -178.7(4) . . . . ?
C64 C65 C66 C61 -0.4(8) . . . . ?
C64 C65 C66 Cl4 -176.2(4) . . . . ?
O7 C61 C66 C65 179.6(5) . . . . ?
C62 C61 C66 C65 -0.7(7) . . . . ?
O7 C61 C66 Cl4 -4.5(7) . . . . ?
C62 C61 C66 Cl4 175.2(4) . . . . ?
O10 C67 C68 C69 -179.1(5) . . . . ?
C72 C67 C68 C69 1.0(7) . . . . ?
O10 C67 C68 Cl5 0.1(7) . . . . ?
C72 C67 C68 Cl5 -179.7(4) . . . . ?
C67 C68 C69 C70 0.1(8) . . . . ?
Cl5 C68 C69 C70 -179.2(4) . . . . ?
C68 C69 C70 C71 -1.0(8) . . . . ?
C68 C69 C70 N3 178.1(5) . . . . ?
O12 N3 C70 C69 176.9(6) . . . . ?
O11 N3 C70 C69 -2.5(8) . . . . ?
O12 N3 C70 C71 -3.9(8) . . . . ?
O11 N3 C70 C71 176.6(5) . . . . ?
C69 C70 C71 C72 0.7(8) . . . . ?
N3 C70 C71 C72 -178.4(5) . . . . ?
C70 C71 C72 C67 0.5(8) . . . . ?
C70 C71 C72 Cl6 -179.2(4) . . . . ?
O10 C67 C72 C71 178.8(5) . . . . ?
C68 C67 C72 C71 -1.3(7) . . . . ?
O10 C67 C72 Cl6 -1.4(7) . . . . ?
C68 C67 C72 Cl6 178.4(4) . . . . ?

_refine_diff_density_max         0.526
_refine_diff_density_min         -0.767
_refine_diff_density_rms         0.091




