# Electronic Supplementary Material (ESI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_mx6667
_database_code_depnum_ccdc_archive 'CCDC 1970313'
_audit_update_record             
;
2019-12-05 deposited with the CCDC.	2020-03-09 downloaded from the CCDC.
;
_audit_creation_date             2018-01-02
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C48 H54 Ag3 Cu2 S6, C24 H20 P, C H2 Cl2'
_chemical_formula_sum            'C73 H76 Ag3 Cl2 Cu2 P S6'
_chemical_formula_weight         1698.25
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   14.5564(11)
_cell_length_b                   33.710(3)
_cell_length_c                   14.6416(11)
_cell_angle_alpha                90
_cell_angle_beta                 94.2190(10)
_cell_angle_gamma                90
_cell_volume                     7165.2(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    21759
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.4827
_cell_measurement_theta_min      1.2081
_shelx_estimated_absorpt_T_max   0.777
_shelx_estimated_absorpt_T_min   0.639
_exptl_absorpt_coefficient_mu    1.702
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.87228
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku Inc., 2007)'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.574
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3432
_exptl_crystal_size_max          0.289
_exptl_crystal_size_mid          0.163
_exptl_crystal_size_min          0.156
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0365
_diffrn_reflns_av_unetI/netI     0.0321
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       43
_diffrn_reflns_limit_k_min       -43
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            56439
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.486
_diffrn_reflns_theta_min         1.208
_diffrn_ambient_temperature      173.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'MM007-HF CCD(Saturn 724+)'
_diffrn_measurement_method       'ω scans at fixed χ = 45°'
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating Anode'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15406
_reflns_number_total             16363
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2007)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2007)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'CIFTAB (Sheldrick, 2013)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         1.431
_refine_diff_density_min         -1.181
_refine_diff_density_rms         0.095
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.134
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     796
_refine_ls_number_reflns         16363
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0494
_refine_ls_restrained_S_all      1.134
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0313P)²+19.2445P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1095
_refine_ls_wR_factor_ref         0.1117
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C73(H73A,H73B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C6(H6), C11(H11), C13(H13), C14(H14), C19(H19), C21(H21),
 C22(H22), C27(H27), C29(H29), C30(H30), C35(H35), C37(H37), C38(H38), C43(H43),
  C45(H45), C46(H46), C50(H50), C51(H51), C52(H52), C53(H53), C54(H54),
 C56(H56), C57(H57), C58(H58), C59(H59), C60(H60), C62(H62), C63(H63), C64(H64),
  C65(H65), C66(H66), C68(H68), C69(H69), C70(H70), C71(H71), C72(H72)
2.c Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C),
 C23(H23A,H23B,H23C), C24(H24A,H24B,H24C), C31(H31A,H31B,H31C), C32(H32A,H32B,
 H32C), C39(H39A,H39B,H39C), C40(H40A,H40B,H40C), C47(H47A,H47B,H47C), C48(H48A,
 H48B,H48C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.86514(2) 0.38132(2) 0.65877(2) 0.04323(9) Uani 1 1 d . . . . .
C1 C 0.9367(3) 0.38323(11) 0.8819(3) 0.0337(8) Uani 1 1 d . . . . .
Cu1 Cu 0.75732(3) 0.43000(2) 0.77605(3) 0.03136(10) Uani 1 1 d . . . . .
S1 S 0.91180(7) 0.41887(3) 0.79290(7) 0.0393(2) Uani 1 1 d . . . . .
S2 S 0.68116(7) 0.46972(3) 0.67217(8) 0.0404(2) Uani 1 1 d . . . . .
Ag2 Ag 0.64702(2) 0.40784(2) 0.59910(2) 0.04369(9) Uani 1 1 d . . . . .
Cu2 Cu 0.72157(3) 0.32516(2) 0.59372(3) 0.02664(9) Uani 1 1 d . . . . .
C2 C 1.0028(3) 0.35332(13) 0.8745(3) 0.0398(9) Uani 1 1 d . . . . .
Ag3 Ag 0.70952(2) 0.34758(2) 0.78667(2) 0.04399(9) Uani 1 1 d . . . . .
S3 S 0.85672(7) 0.34090(3) 0.52466(7) 0.0369(2) Uani 1 1 d . . . . .
C3 C 1.0211(3) 0.32771(12) 0.9486(3) 0.0448(10) Uani 1 1 d . . . . .
H3 H 1.064683 0.307023 0.943264 0.054 Uiso 1 1 calc R . . . .
S4 S 0.59273(7) 0.35030(3) 0.51797(7) 0.0370(2) Uani 1 1 d . . . . .
C4 C 0.9780(3) 0.33133(14) 1.0298(3) 0.0470(11) Uani 1 1 d . . . . .
S5 S 0.72377(7) 0.28404(3) 0.71714(7) 0.0364(2) Uani 1 1 d . . . . .
C5 C 0.9152(3) 0.36148(15) 1.0363(3) 0.0478(11) Uani 1 1 d . . . . .
H5 H 0.885946 0.365043 1.091618 0.057 Uiso 1 1 calc R . . . .
C6 C 0.8943(3) 0.38661(13) 0.9634(3) 0.0411(9) Uani 1 1 d . . . . .
H6 H 0.849627 0.406818 0.969096 0.049 Uiso 1 1 calc R . . . .
S6 S 0.66852(7) 0.40117(3) 0.88343(7) 0.0380(2) Uani 1 1 d . . . . .
C7 C 1.0539(4) 0.34825(19) 0.7895(4) 0.0647(15) Uani 1 1 d . . . . .
H7A H 1.010773 0.339904 0.738590 0.097 Uiso 1 1 calc GR . . . .
H7B H 1.101833 0.328035 0.800464 0.097 Uiso 1 1 calc GR . . . .
H7C H 1.082367 0.373502 0.774224 0.097 Uiso 1 1 calc GR . . . .
C8 C 0.9980(4) 0.30214(17) 1.1074(4) 0.0705(17) Uani 1 1 d . . . . .
H8A H 0.940650 0.289155 1.121975 0.106 Uiso 1 1 calc GR . . . .
H8B H 1.024588 0.316286 1.161560 0.106 Uiso 1 1 calc GR . . . .
H8C H 1.041741 0.282094 1.088921 0.106 Uiso 1 1 calc GR . . . .
C9 C 0.7578(3) 0.49590(11) 0.6031(3) 0.0384(9) Uani 1 1 d . . . . .
C10 C 0.7253(3) 0.51247(13) 0.5191(3) 0.0422(9) Uani 1 1 d . . . . .
C11 C 0.7848(3) 0.53570(14) 0.4726(3) 0.0491(11) Uani 1 1 d . . . . .
H11 H 0.762080 0.547773 0.416796 0.059 Uiso 1 1 calc R . . . .
C12 C 0.8761(3) 0.54228(14) 0.5032(4) 0.0510(11) Uani 1 1 d . . . . .
C13 C 0.9072(3) 0.52461(14) 0.5841(4) 0.0546(12) Uani 1 1 d . . . . .
H13 H 0.969668 0.527937 0.606398 0.066 Uiso 1 1 calc R . . . .
C14 C 0.8491(3) 0.50201(13) 0.6338(4) 0.0495(11) Uani 1 1 d . . . . .
H14 H 0.872152 0.490458 0.690058 0.059 Uiso 1 1 calc R . . . .
C15 C 0.6281(3) 0.50522(17) 0.4791(4) 0.0568(13) Uani 1 1 d . . . . .
H15A H 0.619402 0.476835 0.466902 0.085 Uiso 1 1 calc GR . . . .
H15B H 0.617481 0.520095 0.421786 0.085 Uiso 1 1 calc GR . . . .
H15C H 0.584377 0.514038 0.522683 0.085 Uiso 1 1 calc GR . . . .
C16 C 0.9381(4) 0.56759(18) 0.4495(4) 0.0697(16) Uani 1 1 d . . . . .
H16A H 0.951107 0.553807 0.392945 0.105 Uiso 1 1 calc GR . . . .
H16B H 0.995988 0.572524 0.486280 0.105 Uiso 1 1 calc GR . . . .
H16C H 0.907637 0.592907 0.434315 0.105 Uiso 1 1 calc GR . . . .
C17 C 0.8259(2) 0.37124(11) 0.4272(3) 0.0312(8) Uani 1 1 d . . . . .
C18 C 0.8158(2) 0.35307(12) 0.3406(3) 0.0322(8) Uani 1 1 d . . . . .
C19 C 0.7928(3) 0.37655(13) 0.2647(3) 0.0381(9) Uani 1 1 d . . . . .
H19 H 0.782405 0.364004 0.206763 0.046 Uiso 1 1 calc R . . . .
C20 C 0.7842(3) 0.41765(14) 0.2691(3) 0.0417(9) Uani 1 1 d . . . . .
C21 C 0.7961(3) 0.43479(13) 0.3557(3) 0.0420(9) Uani 1 1 d . . . . .
H21 H 0.790208 0.462726 0.361466 0.050 Uiso 1 1 calc R . . . .
C22 C 0.8162(3) 0.41221(12) 0.4336(3) 0.0369(8) Uani 1 1 d . . . . .
H22 H 0.823429 0.424754 0.491835 0.044 Uiso 1 1 calc R . . . .
C23 C 0.8317(3) 0.30926(13) 0.3297(3) 0.0446(10) Uani 1 1 d . . . . .
H23A H 0.897005 0.303259 0.344093 0.067 Uiso 1 1 calc GR . . . .
H23B H 0.813856 0.301419 0.266372 0.067 Uiso 1 1 calc GR . . . .
H23C H 0.794470 0.294563 0.371387 0.067 Uiso 1 1 calc GR . . . .
C24 C 0.7626(4) 0.44179(18) 0.1845(4) 0.0648(15) Uani 1 1 d . . . . .
H24A H 0.812669 0.460703 0.177074 0.097 Uiso 1 1 calc GR . . . .
H24B H 0.704909 0.456266 0.189855 0.097 Uiso 1 1 calc GR . . . .
H24C H 0.756231 0.424193 0.131123 0.097 Uiso 1 1 calc GR . . . .
C25 C 0.4874(3) 0.33627(11) 0.5665(3) 0.0327(8) Uani 1 1 d . . . . .
C26 C 0.4044(3) 0.35258(12) 0.5304(3) 0.0394(9) Uani 1 1 d . . . . .
C27 C 0.3227(3) 0.33909(14) 0.5636(3) 0.0446(10) Uani 1 1 d . . . . .
H27 H 0.266257 0.350428 0.539479 0.054 Uiso 1 1 calc R . . . .
C28 C 0.3197(3) 0.30981(13) 0.6304(3) 0.0418(9) Uani 1 1 d . . . . .
C29 C 0.4037(3) 0.29481(13) 0.6666(3) 0.0409(9) Uani 1 1 d . . . . .
H29 H 0.404578 0.275324 0.713557 0.049 Uiso 1 1 calc R . . . .
C30 C 0.4861(3) 0.30788(11) 0.6353(3) 0.0362(8) Uani 1 1 d . . . . .
H30 H 0.542584 0.297259 0.661287 0.043 Uiso 1 1 calc R . . . .
C31 C 0.4016(4) 0.38378(16) 0.4569(4) 0.0572(13) Uani 1 1 d . . . . .
H31A H 0.438805 0.406610 0.478437 0.086 Uiso 1 1 calc GR . . . .
H31B H 0.337769 0.392250 0.442442 0.086 Uiso 1 1 calc GR . . . .
H31C H 0.426387 0.372813 0.401766 0.086 Uiso 1 1 calc GR . . . .
C32 C 0.2298(3) 0.29434(19) 0.6597(4) 0.0606(14) Uani 1 1 d . . . . .
H32A H 0.179749 0.311914 0.636570 0.091 Uiso 1 1 calc GR . . . .
H32B H 0.231957 0.293390 0.726691 0.091 Uiso 1 1 calc GR . . . .
H32C H 0.219027 0.267600 0.634880 0.091 Uiso 1 1 calc GR . . . .
C33 C 0.8369(3) 0.26601(11) 0.7498(3) 0.0321(8) Uani 1 1 d . . . . .
C34 C 0.8612(3) 0.25421(11) 0.8401(3) 0.0366(8) Uani 1 1 d . . . . .
C35 C 0.9478(3) 0.23717(12) 0.8597(3) 0.0413(9) Uani 1 1 d . . . . .
H35 H 0.964211 0.228437 0.920424 0.050 Uiso 1 1 calc R . . . .
C36 C 1.0109(3) 0.23250(12) 0.7939(3) 0.0405(9) Uani 1 1 d . . . . .
C37 C 0.9853(3) 0.24462(14) 0.7050(3) 0.0432(10) Uani 1 1 d . . . . .
H37 H 1.027109 0.241483 0.658643 0.052 Uiso 1 1 calc R . . . .
C38 C 0.8997(3) 0.26121(13) 0.6834(3) 0.0403(9) Uani 1 1 d . . . . .
H38 H 0.883447 0.269466 0.622276 0.048 Uiso 1 1 calc R . . . .
C39 C 0.7995(3) 0.26157(16) 0.9168(3) 0.0515(11) Uani 1 1 d . . . . .
H39A H 0.797053 0.290092 0.929422 0.077 Uiso 1 1 calc GR . . . .
H39B H 0.824141 0.247589 0.972017 0.077 Uiso 1 1 calc GR . . . .
H39C H 0.737386 0.251819 0.898941 0.077 Uiso 1 1 calc GR . . . .
C40 C 1.1055(3) 0.21586(16) 0.8176(4) 0.0547(12) Uani 1 1 d . . . . .
H40A H 1.141017 0.234471 0.857610 0.082 Uiso 1 1 calc GR . . . .
H40B H 1.136829 0.211819 0.761339 0.082 Uiso 1 1 calc GR . . . .
H40C H 1.100213 0.190432 0.849236 0.082 Uiso 1 1 calc GR . . . .
C41 C 0.5508(3) 0.41311(11) 0.8536(3) 0.0325(8) Uani 1 1 d . . . . .
C42 C 0.5026(3) 0.43607(11) 0.9142(3) 0.0329(8) Uani 1 1 d . . . . .
C43 C 0.4117(3) 0.44563(12) 0.8902(3) 0.0371(9) Uani 1 1 d . . . . .
H43 H 0.380374 0.462195 0.930162 0.045 Uiso 1 1 calc R . . . .
C44 C 0.3637(3) 0.43220(13) 0.8102(3) 0.0407(9) Uani 1 1 d . . . . .
C45 C 0.4116(3) 0.40880(14) 0.7518(3) 0.0435(10) Uani 1 1 d . . . . .
H45 H 0.381167 0.399138 0.696676 0.052 Uiso 1 1 calc R . . . .
C46 C 0.5035(3) 0.39933(13) 0.7731(3) 0.0401(9) Uani 1 1 d . . . . .
H46 H 0.534875 0.383189 0.732276 0.048 Uiso 1 1 calc R . . . .
C47 C 0.5483(3) 0.44975(14) 1.0041(3) 0.0456(10) Uani 1 1 d . . . . .
H47A H 0.572893 0.426771 1.038840 0.068 Uiso 1 1 calc GR . . . .
H47B H 0.503078 0.463433 1.039218 0.068 Uiso 1 1 calc GR . . . .
H47C H 0.598698 0.467971 0.992835 0.068 Uiso 1 1 calc GR . . . .
C48 C 0.2634(3) 0.44142(18) 0.7904(4) 0.0588(13) Uani 1 1 d . . . . .
H48A H 0.233425 0.443067 0.848055 0.088 Uiso 1 1 calc GR . . . .
H48B H 0.234336 0.420395 0.752095 0.088 Uiso 1 1 calc GR . . . .
H48C H 0.256811 0.466833 0.758034 0.088 Uiso 1 1 calc GR . . . .
P1 P 0.25858(6) 0.38972(3) 0.14168(7) 0.02839(19) Uani 1 1 d . . . . .
C49 C 0.1854(3) 0.37530(11) 0.2297(3) 0.0335(8) Uani 1 1 d . . . . .
C50 C 0.2150(3) 0.34519(14) 0.2897(3) 0.0419(9) Uani 1 1 d . . . . .
H50 H 0.272931 0.332740 0.284341 0.050 Uiso 1 1 calc R . . . .
C51 C 0.1589(3) 0.33353(15) 0.3578(3) 0.0503(11) Uani 1 1 d . . . . .
H51 H 0.177982 0.312655 0.398394 0.060 Uiso 1 1 calc R . . . .
C52 C 0.0752(3) 0.35223(15) 0.3665(3) 0.0491(11) Uani 1 1 d . . . . .
H52 H 0.037351 0.344094 0.413226 0.059 Uiso 1 1 calc R . . . .
C53 C 0.0468(3) 0.38229(15) 0.3085(3) 0.0487(11) Uani 1 1 d . . . . .
H53 H -0.010380 0.395122 0.315397 0.058 Uiso 1 1 calc R . . . .
C54 C 0.1014(3) 0.39415(13) 0.2392(3) 0.0403(9) Uani 1 1 d . . . . .
H54 H 0.081528 0.414971 0.198745 0.048 Uiso 1 1 calc R . . . .
C55 C 0.2098(2) 0.43182(10) 0.0801(2) 0.0281(7) Uani 1 1 d . . . . .
C56 C 0.2483(3) 0.46965(11) 0.0859(3) 0.0315(8) Uani 1 1 d . . . . .
H56 H 0.303644 0.474176 0.122859 0.038 Uiso 1 1 calc R . . . .
C57 C 0.2055(3) 0.50057(11) 0.0375(3) 0.0353(8) Uani 1 1 d . . . . .
H57 H 0.231845 0.526356 0.041253 0.042 Uiso 1 1 calc R . . . .
C58 C 0.1246(3) 0.49431(12) -0.0163(3) 0.0358(8) Uani 1 1 d . . . . .
H58 H 0.094971 0.515850 -0.048271 0.043 Uiso 1 1 calc R . . . .
C59 C 0.0869(3) 0.45681(12) -0.0235(3) 0.0360(8) Uani 1 1 d . . . . .
H59 H 0.032095 0.452469 -0.061447 0.043 Uiso 1 1 calc R . . . .
C60 C 0.1287(3) 0.42547(11) 0.0244(3) 0.0339(8) Uani 1 1 d . . . . .
H60 H 0.102389 0.399692 0.019602 0.041 Uiso 1 1 calc R . . . .
C61 C 0.2686(3) 0.35090(11) 0.0593(3) 0.0310(8) Uani 1 1 d . . . . .
C62 C 0.3026(3) 0.36156(12) -0.0239(3) 0.0406(9) Uani 1 1 d . . . . .
H62 H 0.317613 0.388461 -0.035127 0.049 Uiso 1 1 calc R . . . .
C63 C 0.3144(3) 0.33308(13) -0.0904(3) 0.0468(10) Uani 1 1 d . . . . .
H63 H 0.337800 0.340448 -0.146896 0.056 Uiso 1 1 calc R . . . .
C64 C 0.2922(3) 0.29419(13) -0.0745(3) 0.0473(11) Uani 1 1 d . . . . .
H64 H 0.300674 0.274656 -0.119869 0.057 Uiso 1 1 calc R . . . .
C65 C 0.2577(3) 0.28339(12) 0.0073(3) 0.0454(10) Uani 1 1 d . . . . .
H65 H 0.241695 0.256504 0.017289 0.054 Uiso 1 1 calc R . . . .
C66 C 0.2462(3) 0.31140(11) 0.0753(3) 0.0371(9) Uani 1 1 d . . . . .
H66 H 0.223293 0.303737 0.131838 0.045 Uiso 1 1 calc R . . . .
C67 C 0.3708(2) 0.40091(11) 0.1943(3) 0.0307(7) Uani 1 1 d . . . . .
C68 C 0.4465(3) 0.37728(14) 0.1788(3) 0.0422(9) Uani 1 1 d . . . . .
H68 H 0.439618 0.355052 0.138966 0.051 Uiso 1 1 calc R . . . .
C69 C 0.5316(3) 0.38626(16) 0.2213(3) 0.0509(12) Uani 1 1 d . . . . .
H69 H 0.582993 0.369771 0.211938 0.061 Uiso 1 1 calc R . . . .
C70 C 0.5425(3) 0.41917(15) 0.2776(3) 0.0471(11) Uani 1 1 d . . . . .
H70 H 0.601548 0.425437 0.306022 0.057 Uiso 1 1 calc R . . . .
C71 C 0.4679(3) 0.44285(13) 0.2926(3) 0.0411(9) Uani 1 1 d . . . . .
H71 H 0.475898 0.465729 0.330197 0.049 Uiso 1 1 calc R . . . .
C72 C 0.3813(3) 0.43342(12) 0.2530(3) 0.0352(8) Uani 1 1 d . . . . .
H72 H 0.329438 0.449003 0.265818 0.042 Uiso 1 1 calc R . . . .
Cl1 Cl 0.47213(14) 0.74151(7) 0.05395(17) 0.1060(7) Uani 1 1 d . . . . .
Cl2 Cl 0.36100(15) 0.68449(5) -0.05645(13) 0.0878(5) Uani 1 1 d . . . . .
C73 C 0.4399(5) 0.6929(3) 0.0366(8) 0.153(5) Uani 1 1 d . . . . .
H73A H 0.413137 0.683080 0.092547 0.183 Uiso 1 1 calc R . . . .
H73B H 0.495873 0.677021 0.028133 0.183 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Cu1 2.9156(6) . ?
Ag1 S1 2.3925(11) . ?
Ag1 Ag2 3.3519(6) . ?
Ag1 Cu2 2.9269(6) . ?
Ag1 Ag3 3.2490(5) . ?
Ag1 S3 2.3860(11) . ?
C1 S1 1.790(4) . ?
C1 C2 1.403(6) . ?
C1 C6 1.388(6) . ?
Cu1 S1 2.2752(12) . ?
Cu1 S2 2.2553(12) . ?
Cu1 Ag2 3.0390(6) . ?
Cu1 Ag3 2.8711(6) . ?
Cu1 S6 2.3209(12) . ?
S2 Ag2 2.3800(11) . ?
S2 C9 1.793(4) . ?
Ag2 Cu2 2.9944(6) . ?
Ag2 S4 2.3791(10) . ?
Cu2 Ag3 2.9423(6) . ?
Cu2 S3 2.3381(11) . ?
Cu2 S4 2.2715(12) . ?
Cu2 S5 2.2758(11) . ?
C2 C3 1.397(6) . ?
C2 C7 1.505(7) . ?
Ag3 S5 2.3874(10) . ?
Ag3 S6 2.3979(10) . ?
S3 C17 1.786(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.390(7) . ?
S4 C25 1.799(4) . ?
C4 C5 1.375(7) . ?
C4 C8 1.515(7) . ?
S5 C33 1.787(4) . ?
C5 H5 0.9500 . ?
C5 C6 1.380(6) . ?
C6 H6 0.9500 . ?
S6 C41 1.783(4) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.401(6) . ?
C9 C14 1.386(6) . ?
C10 C11 1.383(6) . ?
C10 C15 1.511(6) . ?
C11 H11 0.9500 . ?
C11 C12 1.389(7) . ?
C12 C13 1.372(7) . ?
C12 C16 1.505(7) . ?
C13 H13 0.9500 . ?
C13 C14 1.384(7) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.406(5) . ?
C17 C22 1.392(5) . ?
C18 C19 1.385(6) . ?
C18 C23 1.505(6) . ?
C19 H19 0.9500 . ?
C19 C20 1.393(6) . ?
C20 C21 1.392(6) . ?
C20 C24 1.496(6) . ?
C21 H21 0.9500 . ?
C21 C22 1.385(6) . ?
C22 H22 0.9500 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.396(6) . ?
C25 C30 1.391(6) . ?
C26 C27 1.394(6) . ?
C26 C31 1.504(6) . ?
C27 H27 0.9500 . ?
C27 C28 1.393(7) . ?
C28 C29 1.391(6) . ?
C28 C32 1.500(6) . ?
C29 H29 0.9500 . ?
C29 C30 1.388(6) . ?
C30 H30 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 C34 1.400(6) . ?
C33 C38 1.393(6) . ?
C34 C35 1.396(6) . ?
C34 C39 1.509(6) . ?
C35 H35 0.9500 . ?
C35 C36 1.388(6) . ?
C36 C37 1.389(6) . ?
C36 C40 1.504(6) . ?
C37 H37 0.9500 . ?
C37 C38 1.381(6) . ?
C38 H38 0.9500 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 C42 1.403(5) . ?
C41 C46 1.400(6) . ?
C42 C43 1.382(6) . ?
C42 C47 1.503(5) . ?
C43 H43 0.9500 . ?
C43 C44 1.394(6) . ?
C44 C45 1.388(6) . ?
C44 C48 1.501(6) . ?
C45 H45 0.9500 . ?
C45 C46 1.388(6) . ?
C46 H46 0.9500 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
P1 C49 1.798(4) . ?
P1 C55 1.799(4) . ?
P1 C61 1.793(4) . ?
P1 C67 1.794(4) . ?
C49 C50 1.390(6) . ?
C49 C54 1.394(6) . ?
C50 H50 0.9500 . ?
C50 C51 1.391(6) . ?
C51 H51 0.9500 . ?
C51 C52 1.385(7) . ?
C52 H52 0.9500 . ?
C52 C53 1.367(7) . ?
C53 H53 0.9500 . ?
C53 C54 1.392(6) . ?
C54 H54 0.9500 . ?
C55 C56 1.393(5) . ?
C55 C60 1.401(5) . ?
C56 H56 0.9500 . ?
C56 C57 1.382(5) . ?
C57 H57 0.9500 . ?
C57 C58 1.384(6) . ?
C58 H58 0.9500 . ?
C58 C59 1.379(6) . ?
C59 H59 0.9500 . ?
C59 C60 1.384(5) . ?
C60 H60 0.9500 . ?
C61 C62 1.396(6) . ?
C61 C66 1.395(5) . ?
C62 H62 0.9500 . ?
C62 C63 1.387(6) . ?
C63 H63 0.9500 . ?
C63 C64 1.374(6) . ?
C64 H64 0.9500 . ?
C64 C65 1.381(7) . ?
C65 H65 0.9500 . ?
C65 C66 1.391(6) . ?
C66 H66 0.9500 . ?
C67 C68 1.392(5) . ?
C67 C72 1.395(5) . ?
C68 H68 0.9500 . ?
C68 C69 1.378(6) . ?
C69 H69 0.9500 . ?
C69 C70 1.385(7) . ?
C70 H70 0.9500 . ?
C70 C71 1.379(6) . ?
C71 H71 0.9500 . ?
C71 C72 1.384(6) . ?
C72 H72 0.9500 . ?
Cl1 C73 1.718(10) . ?
Cl2 C73 1.739(11) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu1 Ag1 Ag2 57.505(13) . . ?
Cu1 Ag1 Cu2 98.821(17) . . ?
Cu1 Ag1 Ag3 55.196(13) . . ?
S1 Ag1 Cu1 49.57(3) . . ?
S1 Ag1 Ag2 106.21(3) . . ?
S1 Ag1 Cu2 139.66(3) . . ?
S1 Ag1 Ag3 83.11(3) . . ?
Cu2 Ag1 Ag2 56.479(12) . . ?
Cu2 Ag1 Ag3 56.613(13) . . ?
Ag3 Ag1 Ag2 63.664(12) . . ?
S3 Ag1 Cu1 143.99(3) . . ?
S3 Ag1 S1 166.42(4) . . ?
S3 Ag1 Ag2 86.99(3) . . ?
S3 Ag1 Cu2 50.98(3) . . ?
S3 Ag1 Ag3 106.18(3) . . ?
C2 C1 S1 122.0(3) . . ?
C6 C1 S1 119.5(3) . . ?
C6 C1 C2 118.4(4) . . ?
Ag1 Cu1 Ag2 68.479(14) . . ?
S1 Cu1 Ag1 53.17(3) . . ?
S1 Cu1 Ag2 120.52(3) . . ?
S1 Cu1 Ag3 94.36(3) . . ?
S1 Cu1 S6 116.92(4) . . ?
S2 Cu1 Ag1 101.31(3) . . ?
S2 Cu1 S1 127.15(4) . . ?
S2 Cu1 Ag2 50.83(3) . . ?
S2 Cu1 Ag3 120.13(3) . . ?
S2 Cu1 S6 115.78(4) . . ?
Ag3 Cu1 Ag1 68.309(14) . . ?
Ag3 Cu1 Ag2 72.146(14) . . ?
S6 Cu1 Ag1 120.93(3) . . ?
S6 Cu1 Ag2 100.89(3) . . ?
S6 Cu1 Ag3 53.75(3) . . ?
C1 S1 Ag1 105.81(13) . . ?
C1 S1 Cu1 109.60(13) . . ?
Cu1 S1 Ag1 77.26(3) . . ?
Cu1 S2 Ag2 81.89(4) . . ?
C9 S2 Cu1 112.16(15) . . ?
C9 S2 Ag2 107.21(14) . . ?
Cu1 Ag2 Ag1 54.016(12) . . ?
S2 Ag2 Ag1 87.37(3) . . ?
S2 Ag2 Cu1 47.28(3) . . ?
S2 Ag2 Cu2 139.78(3) . . ?
Cu2 Ag2 Ag1 54.577(12) . . ?
Cu2 Ag2 Cu1 94.672(16) . . ?
S4 Ag2 Ag1 100.73(3) . . ?
S4 Ag2 Cu1 139.58(3) . . ?
S4 Ag2 S2 171.79(4) . . ?
S4 Ag2 Cu2 48.36(3) . . ?
Ag1 Cu2 Ag2 68.944(14) . . ?
Ag1 Cu2 Ag3 67.225(13) . . ?
Ag3 Cu2 Ag2 71.831(14) . . ?
S3 Cu2 Ag1 52.46(3) . . ?
S3 Cu2 Ag2 96.79(3) . . ?
S3 Cu2 Ag3 117.94(3) . . ?
S4 Cu2 Ag1 117.49(3) . . ?
S4 Cu2 Ag2 51.51(3) . . ?
S4 Cu2 Ag3 105.51(3) . . ?
S4 Cu2 S3 113.26(4) . . ?
S4 Cu2 S5 125.30(4) . . ?
S5 Cu2 Ag1 99.65(3) . . ?
S5 Cu2 Ag2 122.01(3) . . ?
S5 Cu2 Ag3 52.59(3) . . ?
S5 Cu2 S3 121.23(4) . . ?
C1 C2 C7 121.9(4) . . ?
C3 C2 C1 118.5(4) . . ?
C3 C2 C7 119.6(4) . . ?
Cu1 Ag3 Ag1 56.494(13) . . ?
Cu1 Ag3 Cu2 99.486(17) . . ?
Cu2 Ag3 Ag1 56.162(12) . . ?
S5 Ag3 Ag1 88.98(3) . . ?
S5 Ag3 Cu1 144.70(3) . . ?
S5 Ag3 Cu2 49.21(3) . . ?
S5 Ag3 S6 163.96(4) . . ?
S6 Ag3 Ag1 106.93(3) . . ?
S6 Ag3 Cu1 51.31(3) . . ?
S6 Ag3 Cu2 142.74(3) . . ?
Cu2 S3 Ag1 76.56(3) . . ?
C17 S3 Ag1 108.96(13) . . ?
C17 S3 Cu2 107.77(12) . . ?
C2 C3 H3 118.7 . . ?
C4 C3 C2 122.5(4) . . ?
C4 C3 H3 118.7 . . ?
Cu2 S4 Ag2 80.12(4) . . ?
C25 S4 Ag2 106.17(12) . . ?
C25 S4 Cu2 113.94(14) . . ?
C3 C4 C8 120.7(5) . . ?
C5 C4 C3 117.9(4) . . ?
C5 C4 C8 121.3(5) . . ?
Cu2 S5 Ag3 78.20(3) . . ?
C33 S5 Cu2 112.25(13) . . ?
C33 S5 Ag3 107.34(13) . . ?
C4 C5 H5 119.7 . . ?
C4 C5 C6 120.7(4) . . ?
C6 C5 H5 119.7 . . ?
C1 C6 H6 119.0 . . ?
C5 C6 C1 121.9(4) . . ?
C5 C6 H6 119.0 . . ?
Cu1 S6 Ag3 74.93(3) . . ?
C41 S6 Cu1 108.22(13) . . ?
C41 S6 Ag3 107.57(13) . . ?
C2 C7 H7A 109.5 . . ?
C2 C7 H7B 109.5 . . ?
C2 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C4 C8 H8A 109.5 . . ?
C4 C8 H8B 109.5 . . ?
C4 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C10 C9 S2 120.5(3) . . ?
C14 C9 S2 120.8(4) . . ?
C14 C9 C10 118.6(4) . . ?
C9 C10 C15 121.5(4) . . ?
C11 C10 C9 118.3(4) . . ?
C11 C10 C15 120.2(4) . . ?
C10 C11 H11 118.3 . . ?
C10 C11 C12 123.4(5) . . ?
C12 C11 H11 118.3 . . ?
C11 C12 C16 121.2(5) . . ?
C13 C12 C11 117.2(4) . . ?
C13 C12 C16 121.7(5) . . ?
C12 C13 H13 119.4 . . ?
C12 C13 C14 121.1(5) . . ?
C14 C13 H13 119.4 . . ?
C9 C14 H14 119.3 . . ?
C13 C14 C9 121.3(5) . . ?
C13 C14 H14 119.3 . . ?
C10 C15 H15A 109.5 . . ?
C10 C15 H15B 109.5 . . ?
C10 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C12 C16 H16A 109.5 . . ?
C12 C16 H16B 109.5 . . ?
C12 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C18 C17 S3 118.3(3) . . ?
C22 C17 S3 122.3(3) . . ?
C22 C17 C18 119.3(4) . . ?
C17 C18 C23 121.1(4) . . ?
C19 C18 C17 118.5(4) . . ?
C19 C18 C23 120.3(4) . . ?
C18 C19 H19 118.4 . . ?
C18 C19 C20 123.2(4) . . ?
C20 C19 H19 118.4 . . ?
C19 C20 C24 121.1(4) . . ?
C21 C20 C19 116.7(4) . . ?
C21 C20 C24 122.2(5) . . ?
C20 C21 H21 119.1 . . ?
C22 C21 C20 121.8(4) . . ?
C22 C21 H21 119.1 . . ?
C17 C22 H22 119.8 . . ?
C21 C22 C17 120.4(4) . . ?
C21 C22 H22 119.8 . . ?
C18 C23 H23A 109.5 . . ?
C18 C23 H23B 109.5 . . ?
C18 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C20 C24 H24A 109.5 . . ?
C20 C24 H24B 109.5 . . ?
C20 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 S4 119.1(3) . . ?
C30 C25 S4 121.6(3) . . ?
C30 C25 C26 119.2(4) . . ?
C25 C26 C31 121.6(4) . . ?
C27 C26 C25 118.5(4) . . ?
C27 C26 C31 119.9(4) . . ?
C26 C27 H27 118.4 . . ?
C28 C27 C26 123.2(4) . . ?
C28 C27 H27 118.4 . . ?
C27 C28 C32 121.3(4) . . ?
C29 C28 C27 117.0(4) . . ?
C29 C28 C32 121.7(4) . . ?
C28 C29 H29 119.5 . . ?
C30 C29 C28 121.0(4) . . ?
C30 C29 H29 119.5 . . ?
C25 C30 H30 119.5 . . ?
C29 C30 C25 121.1(4) . . ?
C29 C30 H30 119.5 . . ?
C26 C31 H31A 109.5 . . ?
C26 C31 H31B 109.5 . . ?
C26 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C28 C32 H32A 109.5 . . ?
C28 C32 H32B 109.5 . . ?
C28 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C34 C33 S5 120.9(3) . . ?
C38 C33 S5 119.4(3) . . ?
C38 C33 C34 119.6(4) . . ?
C33 C34 C39 122.2(4) . . ?
C35 C34 C33 118.2(4) . . ?
C35 C34 C39 119.5(4) . . ?
C34 C35 H35 118.8 . . ?
C36 C35 C34 122.5(4) . . ?
C36 C35 H35 118.8 . . ?
C35 C36 C37 118.2(4) . . ?
C35 C36 C40 121.6(4) . . ?
C37 C36 C40 120.2(4) . . ?
C36 C37 H37 119.7 . . ?
C38 C37 C36 120.6(4) . . ?
C38 C37 H37 119.7 . . ?
C33 C38 H38 119.5 . . ?
C37 C38 C33 121.0(4) . . ?
C37 C38 H38 119.5 . . ?
C34 C39 H39A 109.5 . . ?
C34 C39 H39B 109.5 . . ?
C34 C39 H39C 109.5 . . ?
H39A C39 H39B 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C36 C40 H40A 109.5 . . ?
C36 C40 H40B 109.5 . . ?
C36 C40 H40C 109.5 . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C42 C41 S6 119.1(3) . . ?
C46 C41 S6 122.4(3) . . ?
C46 C41 C42 118.5(4) . . ?
C41 C42 C47 120.9(4) . . ?
C43 C42 C41 118.8(4) . . ?
C43 C42 C47 120.3(4) . . ?
C42 C43 H43 118.3 . . ?
C42 C43 C44 123.3(4) . . ?
C44 C43 H43 118.3 . . ?
C43 C44 C48 121.0(4) . . ?
C45 C44 C43 117.2(4) . . ?
C45 C44 C48 121.7(4) . . ?
C44 C45 H45 119.6 . . ?
C46 C45 C44 120.8(4) . . ?
C46 C45 H45 119.6 . . ?
C41 C46 H46 119.4 . . ?
C45 C46 C41 121.3(4) . . ?
C45 C46 H46 119.4 . . ?
C42 C47 H47A 109.5 . . ?
C42 C47 H47B 109.5 . . ?
C42 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C44 C48 H48A 109.5 . . ?
C44 C48 H48B 109.5 . . ?
C44 C48 H48C 109.5 . . ?
H48A C48 H48B 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C49 P1 C55 109.85(18) . . ?
C61 P1 C49 111.51(18) . . ?
C61 P1 C55 106.69(17) . . ?
C61 P1 C67 108.98(18) . . ?
C67 P1 C49 108.56(18) . . ?
C67 P1 C55 111.26(17) . . ?
C50 C49 P1 118.5(3) . . ?
C50 C49 C54 120.2(4) . . ?
C54 C49 P1 121.3(3) . . ?
C49 C50 H50 120.4 . . ?
C49 C50 C51 119.2(4) . . ?
C51 C50 H50 120.4 . . ?
C50 C51 H51 119.8 . . ?
C52 C51 C50 120.3(4) . . ?
C52 C51 H51 119.8 . . ?
C51 C52 H52 119.7 . . ?
C53 C52 C51 120.5(4) . . ?
C53 C52 H52 119.7 . . ?
C52 C53 H53 119.9 . . ?
C52 C53 C54 120.2(4) . . ?
C54 C53 H53 119.9 . . ?
C49 C54 H54 120.2 . . ?
C53 C54 C49 119.6(4) . . ?
C53 C54 H54 120.2 . . ?
C56 C55 P1 123.3(3) . . ?
C56 C55 C60 119.5(3) . . ?
C60 C55 P1 117.1(3) . . ?
C55 C56 H56 120.1 . . ?
C57 C56 C55 119.7(3) . . ?
C57 C56 H56 120.1 . . ?
C56 C57 H57 119.7 . . ?
C56 C57 C58 120.6(4) . . ?
C58 C57 H57 119.7 . . ?
C57 C58 H58 120.0 . . ?
C59 C58 C57 120.0(4) . . ?
C59 C58 H58 120.0 . . ?
C58 C59 H59 119.9 . . ?
C58 C59 C60 120.3(4) . . ?
C60 C59 H59 119.9 . . ?
C55 C60 H60 120.1 . . ?
C59 C60 C55 119.9(3) . . ?
C59 C60 H60 120.1 . . ?
C62 C61 P1 116.8(3) . . ?
C66 C61 P1 123.5(3) . . ?
C66 C61 C62 119.7(4) . . ?
C61 C62 H62 119.8 . . ?
C63 C62 C61 120.3(4) . . ?
C63 C62 H62 119.8 . . ?
C62 C63 H63 120.1 . . ?
C64 C63 C62 119.9(4) . . ?
C64 C63 H63 120.1 . . ?
C63 C64 H64 119.9 . . ?
C63 C64 C65 120.2(4) . . ?
C65 C64 H64 119.9 . . ?
C64 C65 H65 119.6 . . ?
C64 C65 C66 120.8(4) . . ?
C66 C65 H65 119.6 . . ?
C61 C66 H66 120.5 . . ?
C65 C66 C61 119.0(4) . . ?
C65 C66 H66 120.5 . . ?
C68 C67 P1 121.1(3) . . ?
C68 C67 C72 119.9(4) . . ?
C72 C67 P1 119.0(3) . . ?
C67 C68 H68 120.1 . . ?
C69 C68 C67 119.8(4) . . ?
C69 C68 H68 120.1 . . ?
C68 C69 H69 119.8 . . ?
C68 C69 C70 120.4(4) . . ?
C70 C69 H69 119.8 . . ?
C69 C70 H70 120.0 . . ?
C71 C70 C69 120.1(4) . . ?
C71 C70 H70 120.0 . . ?
C70 C71 H71 119.9 . . ?
C70 C71 C72 120.3(4) . . ?
C72 C71 H71 119.9 . . ?
C67 C72 H72 120.2 . . ?
C71 C72 C67 119.6(4) . . ?
C71 C72 H72 120.2 . . ?
Cl1 C73 Cl2 115.4(4) . . ?
Cl1 C73 H73A 108.4 . . ?
Cl1 C73 H73B 108.4 . . ?
Cl2 C73 H73A 108.4 . . ?
Cl2 C73 H73B 108.4 . . ?
H73A C73 H73B 107.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 S3 C17 C18 -179.1(2) . . . . ?
Ag1 S3 C17 C22 4.2(4) . . . . ?
C1 C2 C3 C4 -1.5(6) . . . . ?
Cu1 S2 C9 C10 161.0(3) . . . . ?
Cu1 S2 C9 C14 -22.5(4) . . . . ?
Cu1 S6 C41 C42 -116.8(3) . . . . ?
Cu1 S6 C41 C46 65.3(3) . . . . ?
S1 C1 C2 C3 177.2(3) . . . . ?
S1 C1 C2 C7 -2.7(6) . . . . ?
S1 C1 C6 C5 -175.9(4) . . . . ?
S2 C9 C10 C11 173.7(3) . . . . ?
S2 C9 C10 C15 -6.7(6) . . . . ?
S2 C9 C14 C13 -175.3(4) . . . . ?
Ag2 S2 C9 C10 73.0(3) . . . . ?
Ag2 S2 C9 C14 -110.6(3) . . . . ?
Ag2 S4 C25 C26 88.6(3) . . . . ?
Ag2 S4 C25 C30 -95.3(3) . . . . ?
Cu2 S3 C17 C18 -97.6(3) . . . . ?
Cu2 S3 C17 C22 85.7(3) . . . . ?
Cu2 S4 C25 C26 174.8(3) . . . . ?
Cu2 S4 C25 C30 -9.1(4) . . . . ?
Cu2 S5 C33 C34 154.3(3) . . . . ?
Cu2 S5 C33 C38 -29.9(4) . . . . ?
C2 C1 S1 Ag1 57.9(3) . . . . ?
C2 C1 S1 Cu1 139.7(3) . . . . ?
C2 C1 C6 C5 -0.2(6) . . . . ?
C2 C3 C4 C5 -0.1(7) . . . . ?
C2 C3 C4 C8 178.2(4) . . . . ?
Ag3 S5 C33 C34 70.3(3) . . . . ?
Ag3 S5 C33 C38 -114.0(3) . . . . ?
Ag3 S6 C41 C42 163.7(3) . . . . ?
Ag3 S6 C41 C46 -14.1(4) . . . . ?
S3 C17 C18 C19 -179.3(3) . . . . ?
S3 C17 C18 C23 -0.7(5) . . . . ?
S3 C17 C22 C21 177.2(3) . . . . ?
C3 C4 C5 C6 1.6(7) . . . . ?
S4 C25 C26 C27 174.9(3) . . . . ?
S4 C25 C26 C31 -4.6(6) . . . . ?
S4 C25 C30 C29 -174.4(3) . . . . ?
C4 C5 C6 C1 -1.5(7) . . . . ?
S5 C33 C34 C35 174.5(3) . . . . ?
S5 C33 C34 C39 -9.3(6) . . . . ?
S5 C33 C38 C37 -175.2(3) . . . . ?
C6 C1 S1 Ag1 -126.5(3) . . . . ?
C6 C1 S1 Cu1 -44.7(4) . . . . ?
C6 C1 C2 C3 1.6(6) . . . . ?
C6 C1 C2 C7 -178.3(4) . . . . ?
S6 C41 C42 C43 179.2(3) . . . . ?
S6 C41 C42 C47 -1.4(5) . . . . ?
S6 C41 C46 C45 179.5(3) . . . . ?
C7 C2 C3 C4 178.4(4) . . . . ?
C8 C4 C5 C6 -176.7(5) . . . . ?
C9 C10 C11 C12 2.4(7) . . . . ?
C10 C9 C14 C13 1.3(7) . . . . ?
C10 C11 C12 C13 -0.2(8) . . . . ?
C10 C11 C12 C16 179.5(5) . . . . ?
C11 C12 C13 C14 -1.5(8) . . . . ?
C12 C13 C14 C9 1.0(8) . . . . ?
C14 C9 C10 C11 -2.9(6) . . . . ?
C14 C9 C10 C15 176.8(4) . . . . ?
C15 C10 C11 C12 -177.2(5) . . . . ?
C16 C12 C13 C14 178.8(5) . . . . ?
C17 C18 C19 C20 3.8(6) . . . . ?
C18 C17 C22 C21 0.6(6) . . . . ?
C18 C19 C20 C21 -2.7(6) . . . . ?
C18 C19 C20 C24 177.7(4) . . . . ?
C19 C20 C21 C22 0.5(6) . . . . ?
C20 C21 C22 C17 0.5(6) . . . . ?
C22 C17 C18 C19 -2.6(5) . . . . ?
C22 C17 C18 C23 176.0(4) . . . . ?
C23 C18 C19 C20 -174.9(4) . . . . ?
C24 C20 C21 C22 -179.9(4) . . . . ?
C25 C26 C27 C28 -0.7(6) . . . . ?
C26 C25 C30 C29 1.8(6) . . . . ?
C26 C27 C28 C29 2.2(6) . . . . ?
C26 C27 C28 C32 -176.0(4) . . . . ?
C27 C28 C29 C30 -1.7(6) . . . . ?
C28 C29 C30 C25 -0.2(6) . . . . ?
C30 C25 C26 C27 -1.3(6) . . . . ?
C30 C25 C26 C31 179.1(4) . . . . ?
C31 C26 C27 C28 178.8(4) . . . . ?
C32 C28 C29 C30 176.4(4) . . . . ?
C33 C34 C35 C36 1.6(6) . . . . ?
C34 C33 C38 C37 0.6(6) . . . . ?
C34 C35 C36 C37 -1.3(7) . . . . ?
C34 C35 C36 C40 177.0(4) . . . . ?
C35 C36 C37 C38 0.6(7) . . . . ?
C36 C37 C38 C33 -0.3(7) . . . . ?
C38 C33 C34 C35 -1.3(6) . . . . ?
C38 C33 C34 C39 175.0(4) . . . . ?
C39 C34 C35 C36 -174.7(4) . . . . ?
C40 C36 C37 C38 -177.7(4) . . . . ?
C41 C42 C43 C44 2.8(6) . . . . ?
C42 C41 C46 C45 1.6(6) . . . . ?
C42 C43 C44 C45 -1.4(6) . . . . ?
C42 C43 C44 C48 176.2(4) . . . . ?
C43 C44 C45 C46 0.1(7) . . . . ?
C44 C45 C46 C41 -0.2(7) . . . . ?
C46 C41 C42 C43 -2.8(6) . . . . ?
C46 C41 C42 C47 176.5(4) . . . . ?
C47 C42 C43 C44 -176.5(4) . . . . ?
C48 C44 C45 C46 -177.5(4) . . . . ?
P1 C49 C50 C51 -179.6(3) . . . . ?
P1 C49 C54 C53 -179.7(3) . . . . ?
P1 C55 C56 C57 -178.8(3) . . . . ?
P1 C55 C60 C59 178.9(3) . . . . ?
P1 C61 C62 C63 178.5(4) . . . . ?
P1 C61 C66 C65 -179.1(3) . . . . ?
P1 C67 C68 C69 -178.9(4) . . . . ?
P1 C67 C72 C71 -178.7(3) . . . . ?
C49 P1 C55 C56 110.4(3) . . . . ?
C49 P1 C55 C60 -69.2(3) . . . . ?
C49 P1 C61 C62 163.6(3) . . . . ?
C49 P1 C61 C66 -17.6(4) . . . . ?
C49 P1 C67 C68 112.9(4) . . . . ?
C49 P1 C67 C72 -65.8(4) . . . . ?
C49 C50 C51 C52 -1.2(7) . . . . ?
C50 C49 C54 C53 -0.9(6) . . . . ?
C50 C51 C52 C53 0.1(7) . . . . ?
C51 C52 C53 C54 0.6(7) . . . . ?
C52 C53 C54 C49 -0.2(7) . . . . ?
C54 C49 C50 C51 1.6(6) . . . . ?
C55 P1 C49 C50 -174.9(3) . . . . ?
C55 P1 C49 C54 3.9(4) . . . . ?
C55 P1 C61 C62 43.6(4) . . . . ?
C55 P1 C61 C66 -137.6(3) . . . . ?
C55 P1 C67 C68 -126.1(3) . . . . ?
C55 P1 C67 C72 55.2(4) . . . . ?
C55 C56 C57 C58 0.3(6) . . . . ?
C56 C55 C60 C59 -0.7(6) . . . . ?
C56 C57 C58 C59 -1.3(6) . . . . ?
C57 C58 C59 C60 1.3(6) . . . . ?
C58 C59 C60 C55 -0.3(6) . . . . ?
C60 C55 C56 C57 0.7(6) . . . . ?
C61 P1 C49 C50 67.0(4) . . . . ?
C61 P1 C49 C54 -114.2(3) . . . . ?
C61 P1 C55 C56 -128.6(3) . . . . ?
C61 P1 C55 C60 51.9(3) . . . . ?
C61 P1 C67 C68 -8.7(4) . . . . ?
C61 P1 C67 C72 172.6(3) . . . . ?
C61 C62 C63 C64 0.3(7) . . . . ?
C62 C61 C66 C65 -0.3(6) . . . . ?
C62 C63 C64 C65 0.4(7) . . . . ?
C63 C64 C65 C66 -1.0(7) . . . . ?
C64 C65 C66 C61 1.0(7) . . . . ?
C66 C61 C62 C63 -0.3(6) . . . . ?
C67 P1 C49 C50 -53.1(4) . . . . ?
C67 P1 C49 C54 125.8(3) . . . . ?
C67 P1 C55 C56 -9.8(4) . . . . ?
C67 P1 C55 C60 170.6(3) . . . . ?
C67 P1 C61 C62 -76.6(3) . . . . ?
C67 P1 C61 C66 102.2(4) . . . . ?
C67 C68 C69 C70 -1.5(7) . . . . ?
C68 C67 C72 C71 2.6(6) . . . . ?
C68 C69 C70 C71 1.0(8) . . . . ?
C69 C70 C71 C72 1.4(7) . . . . ?
C70 C71 C72 C67 -3.1(6) . . . . ?
C72 C67 C68 C69 -0.2(7) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
