# Electronic Supplementary Material (ESI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx1_sq
_database_code_depnum_ccdc_archive 'CCDC 1814236'
loop_
_audit_author_name
_audit_author_address
'Haibin Song' 'Nankai University, Tianjin, China'
_audit_update_record             
;
2018-01-02 deposited with the CCDC.	2020-10-21 downloaded from the CCDC.
;
_audit_creation_date             2016-05-23
_audit_creation_method           
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         '3(C22 H15 Eu0.33 N O3 P)'
_chemical_formula_sum            'C66 H45 Eu N3 O9 P3'
_chemical_formula_weight         1268.92
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           143
_space_group_name_H-M_alt        'P 3'
_space_group_name_Hall           'P 3'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'

_cell_length_a                   19.351(4)
_cell_length_b                   19.351(4)
_cell_length_c                   13.859(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     4494.6(18)
_cell_formula_units_Z            3
_cell_measurement_reflns_used    14801
_cell_measurement_temperature    113
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.2
_shelx_estimated_absorpt_T_max   0.833
_shelx_estimated_absorpt_T_min   0.780
_exptl_absorpt_coefficient_mu    1.186
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.911
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.406
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    "'not measured'"
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1926
_exptl_crystal_preparation       Fiber,Luminescent
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_special_details           
;
 ?
;
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0419
_diffrn_reflns_av_unetI/netI     0.0345
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            57810
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.978
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         27.618
_diffrn_reflns_theta_min         3.181
_diffrn_ambient_temperature      113
_diffrn_detector                 PILT
_diffrn_detector_area_resol_mean 5.8140
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_details      
;
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 0.0000
	             XTD: 44.9845
	          2theta: -15.1003
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 90.0000
	             XTD: 44.9845
	          2theta: -15.1003
scan:
	Number of images: 360
	           Slice: -105.0000 - 75.0000
	     Image width: 0.5000
	        Exp time: 5.0000
	   Rotation axis: Omega
	           Omega: 0.0000
	             Chi: 45.0000
	             Phi: 180.0000
	             XTD: 44.9845
	          2theta: -15.1003
;
_diffrn_measurement_device       
;
AFC10: Fixed Chi 2 circle
;
_diffrn_measurement_device_type  'Rigaku Pilatus 200K'
_diffrn_measurement_method       'ω scans'
_diffrn_measurement_specimen_support Fiber
_diffrn_orient_matrix_type       d*Trek
_diffrn_orient_matrix_UB_11      -0.021835
_diffrn_orient_matrix_UB_12      -0.038482
_diffrn_orient_matrix_UB_13      -0.056997
_diffrn_orient_matrix_UB_21      0.045833
_diffrn_orient_matrix_UB_22      -0.037403
_diffrn_orient_matrix_UB_23      0.007823
_diffrn_orient_matrix_UB_31      -0.006259
_diffrn_orient_matrix_UB_32      -0.047960
_diffrn_orient_matrix_UB_33      0.034935
_diffrn_radiation_monochromator  Confocal
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating Anode'
_diffrn_source_current           24.0
_diffrn_source_power             1.2
_diffrn_source_voltage           50.0
_diffrn_special_details          
;
 ?
;
_reflns_Friedel_coverage         0.974
_reflns_Friedel_fraction_full    0.982
_reflns_Friedel_fraction_max     0.965
_reflns_number_gt                13043
_reflns_number_total             13646
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_collection       
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_reduction        
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         2.466
_refine_diff_density_min         -1.804
_refine_diff_density_rms         0.091
_refine_ls_abs_structure_details 
;
 Flack x determined using 5945 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.371(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     739
_refine_ls_number_reflns         13646
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0389
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0545P)²+8.0469P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0993
_refine_ls_wR_factor_ref         0.1005
_refine_special_details          SQUEEZE
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C4(H4), C7(H7), C8(H8), C9(H9), C10(H10), C12(H12), C13(H13), C14(H14),
 C15(H15), C16(H16), C18(H18), C19(H19), C20(H20), C21(H21), C22(H22), C26(H26),
  C29(H29), C30(H30), C31(H31), C32(H32), C34(H34), C35(H35), C36(H36),
 C37(H37), C38(H38), C40(H40), C41(H41), C42(H42), C43(H43), C44(H44), C48(H48),
  C51(H51), C52(H52), C53(H53), C54(H54), C56(H56), C57(H57), C58(H58),
 C59(H59), C60(H60), C62(H62), C63(H63), C64(H64), C65(H65), C66(H66)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.0000 0.0000 0.99565(3) 0.01764(14) Uani 1 3 d S T P . .
P1 P 0.16166(11) 0.14863(11) 0.85964(14) 0.0238(4) Uani 1 1 d . . . . .
O1 O 0.0735(3) 0.1046(3) 0.8781(4) 0.0243(10) Uani 1 1 d . . . . .
O2 O 0.0469(3) -0.0597(3) 1.1073(4) 0.0279(11) Uani 1 1 d . . . . .
O3 O 0.1370(4) -0.0647(6) 1.2003(7) 0.096(4) Uani 1 1 d . . . . .
N1 N 0.1568(3) 0.0549(3) 1.0029(4) 0.0201(11) Uani 1 1 d . . . . .
C1 C 0.1165(5) -0.0385(5) 1.1342(6) 0.040(2) Uani 1 1 d . . . . .
C2 C 0.1833(4) 0.0237(4) 1.0699(5) 0.0240(14) Uani 1 1 d . . . . .
C3 C 0.2088(4) 0.1157(4) 0.9473(5) 0.0211(13) Uani 1 1 d . . . . .
C4 C 0.2904(4) 0.1505(4) 0.9587(5) 0.0277(15) Uani 1 1 d . . . . .
H4 H 0.3256 0.1966 0.9225 0.033 Uiso 1 1 calc R . . . .
C5 C 0.3208(4) 0.1172(4) 1.0240(5) 0.0265(14) Uani 1 1 d . . . . .
C6 C 0.2665(4) 0.0494(4) 1.0801(5) 0.0238(15) Uani 1 1 d . . . . .
C7 C 0.2972(5) 0.0133(5) 1.1413(6) 0.0332(16) Uani 1 1 d . . . . .
H7 H 0.2619 -0.0323 1.1782 0.040 Uiso 1 1 calc R . . . .
C8 C 0.3781(5) 0.0437(5) 1.1480(6) 0.0398(19) Uani 1 1 d . . . . .
H8 H 0.3981 0.0181 1.1886 0.048 Uiso 1 1 calc R . . . .
C9 C 0.4315(5) 0.1116(6) 1.0962(6) 0.0382(19) Uani 1 1 d . . . . .
H9 H 0.4873 0.1324 1.1035 0.046 Uiso 1 1 calc R . . . .
C10 C 0.4049(5) 0.1482(5) 1.0354(6) 0.0344(17) Uani 1 1 d . . . . .
H10 H 0.4419 0.1943 1.0006 0.041 Uiso 1 1 calc R . . . .
C11 C 0.2066(5) 0.2543(4) 0.8733(6) 0.0324(17) Uani 1 1 d . . . . .
C12 C 0.2095(5) 0.2817(4) 0.9659(6) 0.0388(18) Uani 1 1 d . . . . .
H12 H 0.1899 0.2450 1.0181 0.047 Uiso 1 1 calc R . . . .
C13 C 0.2412(5) 0.3630(5) 0.9834(6) 0.044(2) Uani 1 1 d . . . . .
H13 H 0.2427 0.3822 1.0469 0.053 Uiso 1 1 calc R . . . .
C14 C 0.2703(6) 0.4151(6) 0.9058(8) 0.043(2) Uani 1 1 d . . . . .
H14 H 0.2930 0.4707 0.9170 0.052 Uiso 1 1 calc R . . . .
C15 C 0.2673(5) 0.3883(5) 0.8133(7) 0.0373(18) Uani 1 1 d . . . . .
H15 H 0.2863 0.4251 0.7611 0.045 Uiso 1 1 calc R . . . .
C16 C 0.2363(4) 0.3072(4) 0.7959(6) 0.0325(16) Uani 1 1 d . . . . .
H16 H 0.2353 0.2883 0.7324 0.039 Uiso 1 1 calc R . . . .
C17 C 0.1831(5) 0.1280(5) 0.7378(6) 0.0362(17) Uani 1 1 d . . . . .
C18 C 0.1209(6) 0.0945(6) 0.6751(6) 0.044(2) Uani 1 1 d . . . . .
H18 H 0.0689 0.0826 0.6942 0.053 Uiso 1 1 calc R . . . .
C19 C 0.1358(7) 0.0781(7) 0.5810(8) 0.057(3) Uani 1 1 d . . . . .
H19 H 0.0943 0.0592 0.5344 0.068 Uiso 1 1 calc R . . . .
C20 C 0.2079(7) 0.0886(6) 0.5550(7) 0.057(3) Uani 1 1 d . . . . .
H20 H 0.2151 0.0710 0.4939 0.068 Uiso 1 1 calc R . . . .
C21 C 0.2702(6) 0.1250(6) 0.6185(7) 0.051(2) Uani 1 1 d . . . . .
H21 H 0.3220 0.1362 0.5994 0.061 Uiso 1 1 calc R . . . .
C22 C 0.2587(5) 0.1454(5) 0.7097(6) 0.0421(19) Uani 1 1 d . . . . .
H22 H 0.3024 0.1714 0.7530 0.051 Uiso 1 1 calc R . . . .
Eu2 Eu 0.3333 0.6667 0.65456(5) 0.01941(12) Uani 1 3 d S T P . .
P2 P 0.16293(11) 0.52508(11) 0.78487(13) 0.0232(4) Uani 1 1 d . . . . .
O4 O 0.2511(3) 0.5638(3) 0.7696(3) 0.0267(10) Uani 1 1 d . . . . .
O5 O 0.2982(3) 0.7369(3) 0.5436(4) 0.0293(11) Uani 1 1 d . . . . .
O6 O 0.2174(3) 0.7573(4) 0.4496(5) 0.0477(16) Uani 1 1 d . . . . .
N2 N 0.1807(3) 0.6273(3) 0.6446(4) 0.0209(10) Uani 1 1 d . . . . .
C23 C 0.2318(5) 0.7259(4) 0.5198(5) 0.0304(15) Uani 1 1 d . . . . .
C24 C 0.1614(4) 0.6649(4) 0.5810(5) 0.0251(13) Uani 1 1 d . . . . .
C25 C 0.1230(4) 0.5674(4) 0.6986(5) 0.0231(13) Uani 1 1 d . . . . .
C26 C 0.0441(4) 0.5415(4) 0.6865(5) 0.0294(15) Uani 1 1 d . . . . .
H26 H 0.0055 0.4963 0.7213 0.035 Uiso 1 1 calc R . . . .
C27 C 0.0195(5) 0.5813(4) 0.6224(5) 0.0290(15) Uani 1 1 d . . . . .
C28 C 0.0804(4) 0.6476(4) 0.5687(5) 0.0242(14) Uani 1 1 d . . . . .
C29 C 0.0563(5) 0.6919(5) 0.5092(5) 0.0334(15) Uani 1 1 d . . . . .
H29 H 0.0954 0.7370 0.4747 0.040 Uiso 1 1 calc R . . . .
C30 C -0.0229(5) 0.6701(5) 0.5013(6) 0.0398(18) Uani 1 1 d . . . . .
H30 H -0.0378 0.7010 0.4623 0.048 Uiso 1 1 calc R . . . .
C31 C -0.0822(5) 0.6026(5) 0.5503(6) 0.0417(18) Uani 1 1 d . . . . .
H31 H -0.1369 0.5868 0.5418 0.050 Uiso 1 1 calc R . . . .
C32 C -0.0611(5) 0.5595(5) 0.6105(6) 0.0351(17) Uani 1 1 d . . . . .
H32 H -0.1013 0.5147 0.6443 0.042 Uiso 1 1 calc R . . . .
C33 C 0.1407(4) 0.5422(4) 0.9052(5) 0.0283(15) Uani 1 1 d . . . . .
C34 C 0.2038(5) 0.5814(5) 0.9678(6) 0.0359(17) Uani 1 1 d . . . . .
H34 H 0.2563 0.5969 0.9470 0.043 Uiso 1 1 calc R . . . .
C35 C 0.1908(6) 0.5986(6) 1.0615(6) 0.047(2) Uani 1 1 d . . . . .
H35 H 0.2343 0.6256 1.1048 0.056 Uiso 1 1 calc R . . . .
C36 C 0.1143(6) 0.5761(6) 1.0908(6) 0.047(2) Uani 1 1 d . . . . .
H36 H 0.1058 0.5892 1.1541 0.057 Uiso 1 1 calc R . . . .
C37 C 0.0501(6) 0.5353(6) 1.0305(6) 0.044(2) Uani 1 1 d . . . . .
H37 H -0.0025 0.5189 1.0521 0.053 Uiso 1 1 calc R . . . .
C38 C 0.0636(5) 0.5184(5) 0.9372(6) 0.0359(17) Uani 1 1 d . . . . .
H38 H 0.0197 0.4902 0.8946 0.043 Uiso 1 1 calc R . . . .
C39 C 0.1094(4) 0.4195(4) 0.7663(6) 0.0265(15) Uani 1 1 d . . . . .
C40 C 0.1043(5) 0.3915(5) 0.6701(6) 0.0338(16) Uani 1 1 d . . . . .
H40 H 0.1229 0.4281 0.6177 0.041 Uiso 1 1 calc R . . . .
C41 C 0.0719(5) 0.3105(5) 0.6537(7) 0.044(2) Uani 1 1 d . . . . .
H41 H 0.0678 0.2908 0.5899 0.053 Uiso 1 1 calc R . . . .
C42 C 0.0453(5) 0.2581(5) 0.7322(8) 0.045(2) Uani 1 1 d . . . . .
H42 H 0.0231 0.2025 0.7210 0.055 Uiso 1 1 calc R . . . .
C43 C 0.0503(5) 0.2850(5) 0.8247(7) 0.0414(19) Uani 1 1 d . . . . .
H43 H 0.0323 0.2483 0.8769 0.050 Uiso 1 1 calc R . . . .
C44 C 0.0816(4) 0.3656(5) 0.8422(6) 0.0352(17) Uani 1 1 d . . . . .
H44 H 0.0841 0.3841 0.9063 0.042 Uiso 1 1 calc R . . . .
Eu3 Eu 0.6667 0.3333 0.29333(3) 0.01411(12) Uani 1 3 d S T P . .
P3 P 0.52236(10) 0.16681(9) 0.43077(12) 0.0176(3) Uani 1 1 d . . . . .
O7 O 0.6086(3) 0.2241(3) 0.4089(3) 0.0170(9) Uani 1 1 d . . . . .
O8 O 0.6032(3) 0.3749(3) 0.1810(4) 0.0234(10) Uani 1 1 d . . . . .
O9 O 0.5023(3) 0.3606(3) 0.0916(4) 0.0406(14) Uani 1 1 d . . . . .
N3 N 0.5086(3) 0.2546(3) 0.2927(4) 0.0169(10) Uani 1 1 d . . . . .
C45 C 0.5293(4) 0.3448(4) 0.1628(5) 0.0216(14) Uani 1 1 d . . . . .
C46 C 0.4726(4) 0.2816(4) 0.2338(5) 0.0199(13) Uani 1 1 d . . . . .
C47 C 0.4621(4) 0.1939(4) 0.3549(4) 0.0183(12) Uani 1 1 d . . . . .
C48 C 0.3819(4) 0.1578(4) 0.3567(5) 0.0254(14) Uani 1 1 d . . . . .
H48 H 0.3524 0.1131 0.3976 0.031 Uiso 1 1 calc R . . . .
C49 C 0.3415(4) 0.1859(4) 0.2983(5) 0.0243(13) Uani 1 1 d . . . . .
C50 C 0.3887(4) 0.2534(4) 0.2362(4) 0.0185(12) Uani 1 1 d . . . . .
C51 C 0.3500(4) 0.2879(5) 0.1870(6) 0.0325(16) Uani 1 1 d . . . . .
H51 H 0.3799 0.3329 0.1466 0.039 Uiso 1 1 calc R . . . .
C52 C 0.2700(5) 0.2574(5) 0.1970(6) 0.0385(18) Uani 1 1 d . . . . .
H52 H 0.2457 0.2845 0.1681 0.046 Uiso 1 1 calc R . . . .
C53 C 0.2232(5) 0.1878(6) 0.2482(6) 0.0385(19) Uani 1 1 d . . . . .
H53 H 0.1668 0.1645 0.2482 0.046 Uiso 1 1 calc R . . . .
C54 C 0.2584(4) 0.1522(5) 0.2992(5) 0.0312(15) Uani 1 1 d . . . . .
H54 H 0.2263 0.1049 0.3350 0.037 Uiso 1 1 calc R . . . .
C55 C 0.5023(4) 0.1747(4) 0.5560(5) 0.0211(12) Uani 1 1 d . . . . .
C56 C 0.5388(4) 0.2523(4) 0.5950(5) 0.0276(15) Uani 1 1 d . . . . .
H56 H 0.5685 0.2969 0.5539 0.033 Uiso 1 1 calc R . . . .
C57 C 0.5321(5) 0.2649(5) 0.6923(6) 0.0349(17) Uani 1 1 d . . . . .
H57 H 0.5576 0.3174 0.7181 0.042 Uiso 1 1 calc R . . . .
C58 C 0.4877(5) 0.1994(5) 0.7512(5) 0.0374(17) Uani 1 1 d . . . . .
H58 H 0.4843 0.2072 0.8183 0.045 Uiso 1 1 calc R . . . .
C59 C 0.4488(5) 0.1243(5) 0.7145(6) 0.0426(19) Uani 1 1 d . . . . .
H59 H 0.4158 0.0806 0.7552 0.051 Uiso 1 1 calc R . . . .
C60 C 0.4568(4) 0.1109(4) 0.6174(5) 0.0329(15) Uani 1 1 d . . . . .
H60 H 0.4311 0.0579 0.5931 0.039 Uiso 1 1 calc R . . . .
C61 C 0.4918(4) 0.0639(4) 0.4049(5) 0.0240(13) Uani 1 1 d . . . . .
C62 C 0.5474(4) 0.0480(4) 0.3673(5) 0.0276(14) Uani 1 1 d . . . . .
H62 H 0.6004 0.0899 0.3565 0.033 Uiso 1 1 calc R . . . .
C63 C 0.5254(5) -0.0305(5) 0.3450(5) 0.0350(16) Uani 1 1 d . . . . .
H63 H 0.5635 -0.0421 0.3175 0.042 Uiso 1 1 calc R . . . .
C64 C 0.4504(5) -0.0903(4) 0.3623(5) 0.0367(17) Uani 1 1 d . . . . .
H64 H 0.4370 -0.1436 0.3480 0.044 Uiso 1 1 calc R . . . .
C65 C 0.3949(6) -0.0769(5) 0.3985(7) 0.039(2) Uani 1 1 d . . . . .
H65 H 0.3428 -0.1204 0.4104 0.047 Uiso 1 1 calc R . . . .
C66 C 0.4127(5) 0.0015(4) 0.4194(5) 0.0315(15) Uani 1 1 d . . . . .
H66 H 0.3727 0.0121 0.4426 0.038 Uiso 1 1 calc R . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 P1 3.5516(18) 2 ?
Eu1 P1 3.5517(18) . ?
Eu1 P1 3.5516(18) 3 ?
Eu1 O1 2.427(5) 3 ?
Eu1 O1 2.427(5) . ?
Eu1 O1 2.427(5) 2 ?
Eu1 O2 2.367(5) 2 ?
Eu1 O2 2.367(5) 3 ?
Eu1 O2 2.367(5) . ?
Eu1 N1 2.669(6) 2 ?
Eu1 N1 2.669(6) 3 ?
Eu1 N1 2.669(6) . ?
P1 O1 1.499(5) . ?
P1 C3 1.816(7) . ?
P1 C11 1.787(8) . ?
P1 C17 1.830(8) . ?
O2 C1 1.253(10) . ?
O3 C1 1.205(10) . ?
N1 C2 1.343(8) . ?
N1 C3 1.344(8) . ?
C1 C2 1.536(10) . ?
C2 C6 1.434(10) . ?
C3 C4 1.382(9) . ?
C4 H4 0.9500 . ?
C4 C5 1.400(10) . ?
C5 C6 1.432(10) . ?
C5 C10 1.435(10) . ?
C6 C7 1.406(10) . ?
C7 H7 0.9500 . ?
C7 C8 1.372(11) . ?
C8 H8 0.9500 . ?
C8 C9 1.398(13) . ?
C9 H9 0.9500 . ?
C9 C10 1.357(12) . ?
C10 H10 0.9500 . ?
C11 C12 1.379(12) . ?
C11 C16 1.394(10) . ?
C12 H12 0.9500 . ?
C12 C13 1.395(11) . ?
C13 H13 0.9500 . ?
C13 C14 1.386(13) . ?
C14 H14 0.9500 . ?
C14 C15 1.374(14) . ?
C15 H15 0.9500 . ?
C15 C16 1.393(11) . ?
C16 H16 0.9500 . ?
C17 C18 1.359(12) . ?
C17 C22 1.383(12) . ?
C18 H18 0.9500 . ?
C18 C19 1.406(14) . ?
C19 H19 0.9500 . ?
C19 C20 1.354(15) . ?
C20 H20 0.9500 . ?
C20 C21 1.369(15) . ?
C21 H21 0.9500 . ?
C21 C22 1.374(13) . ?
C22 H22 0.9500 . ?
Eu2 P2 3.5507(19) 3_565 ?
Eu2 P2 3.5507(19) . ?
Eu2 P2 3.5507(19) 2_665 ?
Eu2 O4 2.423(5) 3_565 ?
Eu2 O4 2.423(5) . ?
Eu2 O4 2.423(5) 2_665 ?
Eu2 O5 2.366(5) 3_565 ?
Eu2 O5 2.366(5) 2_665 ?
Eu2 O5 2.366(5) . ?
Eu2 N2 2.659(5) 2_665 ?
Eu2 N2 2.659(5) . ?
Eu2 N2 2.659(5) 3_565 ?
P2 O4 1.496(5) . ?
P2 C25 1.824(7) . ?
P2 C33 1.795(8) . ?
P2 C39 1.788(7) . ?
O5 C23 1.237(9) . ?
O6 C23 1.251(9) . ?
N2 C24 1.313(9) . ?
N2 C25 1.362(8) . ?
C23 C24 1.537(10) . ?
C24 C28 1.439(9) . ?
C25 C26 1.358(10) . ?
C26 H26 0.9500 . ?
C26 C27 1.406(10) . ?
C27 C28 1.441(10) . ?
C27 C32 1.408(10) . ?
C28 C29 1.425(10) . ?
C29 H29 0.9500 . ?
C29 C30 1.376(11) . ?
C30 H30 0.9500 . ?
C30 C31 1.409(12) . ?
C31 H31 0.9500 . ?
C31 C32 1.378(12) . ?
C32 H32 0.9500 . ?
C33 C34 1.376(11) . ?
C33 C38 1.395(10) . ?
C34 H34 0.9500 . ?
C34 C35 1.394(12) . ?
C35 H35 0.9500 . ?
C35 C36 1.380(13) . ?
C36 H36 0.9500 . ?
C36 C37 1.372(14) . ?
C37 H37 0.9500 . ?
C37 C38 1.391(11) . ?
C38 H38 0.9500 . ?
C39 C40 1.424(11) . ?
C39 C44 1.386(10) . ?
C40 H40 0.9500 . ?
C40 C41 1.386(11) . ?
C41 H41 0.9500 . ?
C41 C42 1.398(14) . ?
C42 H42 0.9500 . ?
C42 C43 1.369(14) . ?
C43 H43 0.9500 . ?
C43 C44 1.384(11) . ?
C44 H44 0.9500 . ?
Eu3 P3 3.5794(16) 2_655 ?
Eu3 P3 3.5794(16) 3_665 ?
Eu3 P3 3.5794(16) . ?
Eu3 O7 2.434(4) 2_655 ?
Eu3 O7 2.434(4) . ?
Eu3 O7 2.434(4) 3_665 ?
Eu3 O8 2.360(5) . ?
Eu3 O8 2.360(5) 3_665 ?
Eu3 O8 2.360(5) 2_655 ?
Eu3 N3 2.649(5) 3_665 ?
Eu3 N3 2.649(5) . ?
Eu3 N3 2.649(5) 2_655 ?
P3 O7 1.502(5) . ?
P3 C47 1.831(6) . ?
P3 C55 1.802(7) . ?
P3 C61 1.808(7) . ?
O8 C45 1.271(8) . ?
O9 C45 1.225(8) . ?
N3 C46 1.337(8) . ?
N3 C47 1.369(8) . ?
C45 C46 1.526(9) . ?
C46 C50 1.431(9) . ?
C47 C48 1.346(9) . ?
C48 H48 0.9500 . ?
C48 C49 1.411(10) . ?
C49 C50 1.446(9) . ?
C49 C54 1.400(9) . ?
C50 C51 1.404(9) . ?
C51 H51 0.9500 . ?
C51 C52 1.360(11) . ?
C52 H52 0.9500 . ?
C52 C53 1.385(13) . ?
C53 H53 0.9500 . ?
C53 C54 1.381(11) . ?
C54 H54 0.9500 . ?
C55 C56 1.410(9) . ?
C55 C60 1.391(9) . ?
C56 H56 0.9500 . ?
C56 C57 1.388(11) . ?
C57 H57 0.9500 . ?
C57 C58 1.386(11) . ?
C58 H58 0.9500 . ?
C58 C59 1.358(12) . ?
C59 H59 0.9500 . ?
C59 C60 1.393(11) . ?
C60 H60 0.9500 . ?
C61 C62 1.361(10) . ?
C61 C66 1.412(10) . ?
C62 H62 0.9500 . ?
C62 C63 1.392(10) . ?
C63 H63 0.9500 . ?
C63 C64 1.351(12) . ?
C64 H64 0.9500 . ?
C64 C65 1.324(13) . ?
C65 H65 0.9500 . ?
C65 C66 1.408(11) . ?
C66 H66 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Eu1 P1 94.45(4) 3 . ?
P1 Eu1 P1 94.44(4) 2 . ?
P1 Eu1 P1 94.45(4) 3 2 ?
O1 Eu1 P1 19.45(12) 3 3 ?
O1 Eu1 P1 75.09(12) 2 3 ?
O1 Eu1 P1 97.60(12) . 3 ?
O1 Eu1 P1 75.08(12) . 2 ?
O1 Eu1 P1 19.45(12) . . ?
O1 Eu1 P1 75.08(12) 3 . ?
O1 Eu1 P1 97.60(12) 3 2 ?
O1 Eu1 P1 19.45(12) 2 2 ?
O1 Eu1 P1 97.60(12) 2 . ?
O1 Eu1 O1 79.91(18) 3 . ?
O1 Eu1 O1 79.92(18) 3 2 ?
O1 Eu1 O1 79.92(18) . 2 ?
O1 Eu1 N1 67.51(16) . . ?
O1 Eu1 N1 67.51(16) 2 2 ?
O1 Eu1 N1 72.12(17) 3 . ?
O1 Eu1 N1 72.12(17) 2 3 ?
O1 Eu1 N1 72.12(17) . 2 ?
O1 Eu1 N1 139.90(17) 3 2 ?
O1 Eu1 N1 139.90(17) 2 . ?
O1 Eu1 N1 139.90(17) . 3 ?
O1 Eu1 N1 67.51(17) 3 3 ?
O2 Eu1 P1 154.60(12) 2 3 ?
O2 Eu1 P1 78.03(14) 2 . ?
O2 Eu1 P1 110.19(13) 2 2 ?
O2 Eu1 P1 78.03(14) 3 2 ?
O2 Eu1 P1 110.19(13) 3 3 ?
O2 Eu1 P1 110.19(13) . . ?
O2 Eu1 P1 154.60(13) . 2 ?
O2 Eu1 P1 78.03(14) . 3 ?
O2 Eu1 P1 154.60(12) 3 . ?
O2 Eu1 O1 142.49(17) 2 3 ?
O2 Eu1 O1 83.38(19) 3 2 ?
O2 Eu1 O1 129.63(17) 3 3 ?
O2 Eu1 O1 83.38(19) 2 . ?
O2 Eu1 O1 142.49(17) 3 . ?
O2 Eu1 O1 83.38(19) . 3 ?
O2 Eu1 O1 129.63(17) . . ?
O2 Eu1 O1 129.63(17) 2 2 ?
O2 Eu1 O1 142.49(17) . 2 ?
O2 Eu1 O2 81.9(2) 2 . ?
O2 Eu1 O2 81.9(2) . 3 ?
O2 Eu1 O2 81.9(2) 2 3 ?
O2 Eu1 N1 70.48(17) 2 . ?
O2 Eu1 N1 136.69(19) . 2 ?
O2 Eu1 N1 70.48(17) 3 2 ?
O2 Eu1 N1 62.15(17) 2 2 ?
O2 Eu1 N1 136.69(19) 3 . ?
O2 Eu1 N1 62.15(17) 3 3 ?
O2 Eu1 N1 62.16(17) . . ?
O2 Eu1 N1 136.69(19) 2 3 ?
O2 Eu1 N1 70.48(17) . 3 ?
N1 Eu1 P1 86.35(12) 2 . ?
N1 Eu1 P1 48.06(12) . . ?
N1 Eu1 P1 142.33(12) . 2 ?
N1 Eu1 P1 142.33(12) 2 3 ?
N1 Eu1 P1 142.33(12) 3 . ?
N1 Eu1 P1 48.06(12) 2 2 ?
N1 Eu1 P1 86.35(12) . 3 ?
N1 Eu1 P1 48.06(12) 3 3 ?
N1 Eu1 P1 86.35(12) 3 2 ?
N1 Eu1 N1 119.862(17) . 3 ?
N1 Eu1 N1 119.860(18) . 2 ?
N1 Eu1 N1 119.861(17) 3 2 ?
O1 P1 Eu1 32.62(19) . . ?
O1 P1 C3 108.3(3) . . ?
O1 P1 C11 113.4(3) . . ?
O1 P1 C17 110.6(4) . . ?
C3 P1 Eu1 75.8(2) . . ?
C3 P1 C17 109.4(4) . . ?
C11 P1 Eu1 126.7(3) . . ?
C11 P1 C3 106.7(3) . . ?
C11 P1 C17 108.3(4) . . ?
C17 P1 Eu1 121.1(3) . . ?
P1 O1 Eu1 127.9(3) . . ?
C1 O2 Eu1 130.3(5) . . ?
C2 N1 Eu1 117.5(4) . . ?
C2 N1 C3 120.2(6) . . ?
C3 N1 Eu1 122.1(4) . . ?
O2 C1 C2 115.5(7) . . ?
O3 C1 O2 127.9(8) . . ?
O3 C1 C2 116.4(7) . . ?
N1 C2 C1 113.1(6) . . ?
N1 C2 C6 121.8(6) . . ?
C6 C2 C1 125.0(6) . . ?
N1 C3 P1 113.8(5) . . ?
N1 C3 C4 122.3(6) . . ?
C4 C3 P1 123.9(5) . . ?
C3 C4 H4 120.3 . . ?
C3 C4 C5 119.3(6) . . ?
C5 C4 H4 120.3 . . ?
C4 C5 C6 119.3(6) . . ?
C4 C5 C10 121.9(7) . . ?
C6 C5 C10 118.9(7) . . ?
C5 C6 C2 116.5(6) . . ?
C7 C6 C2 124.5(7) . . ?
C7 C6 C5 119.0(7) . . ?
C6 C7 H7 119.9 . . ?
C8 C7 C6 120.1(8) . . ?
C8 C7 H7 119.9 . . ?
C7 C8 H8 119.4 . . ?
C7 C8 C9 121.2(7) . . ?
C9 C8 H8 119.4 . . ?
C8 C9 H9 119.5 . . ?
C10 C9 C8 121.0(7) . . ?
C10 C9 H9 119.5 . . ?
C5 C10 H10 120.1 . . ?
C9 C10 C5 119.8(8) . . ?
C9 C10 H10 120.1 . . ?
C12 C11 P1 116.3(6) . . ?
C12 C11 C16 120.7(7) . . ?
C16 C11 P1 123.0(7) . . ?
C11 C12 H12 119.8 . . ?
C11 C12 C13 120.5(7) . . ?
C13 C12 H12 119.8 . . ?
C12 C13 H13 120.8 . . ?
C14 C13 C12 118.3(8) . . ?
C14 C13 H13 120.8 . . ?
C13 C14 H14 119.2 . . ?
C15 C14 C13 121.6(8) . . ?
C15 C14 H14 119.2 . . ?
C14 C15 H15 120.0 . . ?
C14 C15 C16 120.0(8) . . ?
C16 C15 H15 120.0 . . ?
C11 C16 H16 120.6 . . ?
C15 C16 C11 118.8(8) . . ?
C15 C16 H16 120.6 . . ?
C18 C17 P1 116.8(7) . . ?
C18 C17 C22 120.9(8) . . ?
C22 C17 P1 122.3(7) . . ?
C17 C18 H18 121.1 . . ?
C17 C18 C19 117.8(10) . . ?
C19 C18 H18 121.1 . . ?
C18 C19 H19 119.2 . . ?
C20 C19 C18 121.7(10) . . ?
C20 C19 H19 119.2 . . ?
C19 C20 H20 120.6 . . ?
C19 C20 C21 118.9(9) . . ?
C21 C20 H20 120.6 . . ?
C20 C21 H21 119.6 . . ?
C20 C21 C22 120.7(9) . . ?
C22 C21 H21 119.6 . . ?
C17 C22 H22 120.2 . . ?
C21 C22 C17 119.5(9) . . ?
C21 C22 H22 120.2 . . ?
P2 Eu2 P2 96.43(4) 3_565 2_665 ?
P2 Eu2 P2 96.43(4) . 2_665 ?
P2 Eu2 P2 96.43(4) 3_565 . ?
O4 Eu2 P2 99.33(12) 3_565 2_665 ?
O4 Eu2 P2 77.17(12) . 2_665 ?
O4 Eu2 P2 99.33(12) . 3_565 ?
O4 Eu2 P2 19.28(12) 2_665 2_665 ?
O4 Eu2 P2 19.28(12) 3_565 3_565 ?
O4 Eu2 P2 99.33(12) 2_665 . ?
O4 Eu2 P2 77.17(12) 2_665 3_565 ?
O4 Eu2 P2 77.17(12) 3_565 . ?
O4 Eu2 P2 19.28(12) . . ?
O4 Eu2 O4 81.41(17) . 2_665 ?
O4 Eu2 O4 81.41(17) 3_565 . ?
O4 Eu2 O4 81.42(17) 3_565 2_665 ?
O4 Eu2 N2 141.70(17) 2_665 . ?
O4 Eu2 N2 72.43(16) 3_565 . ?
O4 Eu2 N2 141.69(17) . 3_565 ?
O4 Eu2 N2 72.43(16) 2_665 3_565 ?
O4 Eu2 N2 67.61(16) 3_565 3_565 ?
O4 Eu2 N2 141.69(17) 3_565 2_665 ?
O4 Eu2 N2 72.43(16) . 2_665 ?
O4 Eu2 N2 67.61(16) 2_665 2_665 ?
O4 Eu2 N2 67.62(16) . . ?
O5 Eu2 P2 75.74(13) . 3_565 ?
O5 Eu2 P2 152.46(12) 3_565 . ?
O5 Eu2 P2 110.56(12) 2_665 2_665 ?
O5 Eu2 P2 75.74(13) 2_665 . ?
O5 Eu2 P2 75.74(13) 3_565 2_665 ?
O5 Eu2 P2 152.46(12) . 2_665 ?
O5 Eu2 P2 110.56(12) . . ?
O5 Eu2 P2 152.46(12) 2_665 3_565 ?
O5 Eu2 P2 110.56(12) 3_565 3_565 ?
O5 Eu2 O4 82.00(17) 3_565 2_665 ?
O5 Eu2 O4 82.00(17) 2_665 . ?
O5 Eu2 O4 141.39(16) 2_665 3_565 ?
O5 Eu2 O4 129.81(16) . . ?
O5 Eu2 O4 129.81(16) 3_565 3_565 ?
O5 Eu2 O4 82.00(17) . 3_565 ?
O5 Eu2 O4 129.81(16) 2_665 2_665 ?
O5 Eu2 O4 141.39(16) 3_565 . ?
O5 Eu2 O4 141.39(17) . 2_665 ?
O5 Eu2 O5 82.34(18) . 2_665 ?
O5 Eu2 O5 82.34(18) . 3_565 ?
O5 Eu2 O5 82.34(18) 2_665 3_565 ?
O5 Eu2 N2 136.30(17) 2_665 3_565 ?
O5 Eu2 N2 136.30(17) 3_565 . ?
O5 Eu2 N2 69.03(16) . 3_565 ?
O5 Eu2 N2 62.24(16) 3_565 3_565 ?
O5 Eu2 N2 69.03(16) 3_565 2_665 ?
O5 Eu2 N2 62.23(17) . . ?
O5 Eu2 N2 69.03(16) 2_665 . ?
O5 Eu2 N2 62.24(16) 2_665 2_665 ?
O5 Eu2 N2 136.30(17) . 2_665 ?
N2 Eu2 P2 48.34(12) . . ?
N2 Eu2 P2 85.91(12) 3_565 2_665 ?
N2 Eu2 P2 85.91(12) 2_665 . ?
N2 Eu2 P2 144.58(12) . 2_665 ?
N2 Eu2 P2 144.58(12) 3_565 . ?
N2 Eu2 P2 48.34(12) 2_665 2_665 ?
N2 Eu2 P2 48.34(12) 3_565 3_565 ?
N2 Eu2 P2 144.58(12) 2_665 3_565 ?
N2 Eu2 P2 85.91(12) . 3_565 ?
N2 Eu2 N2 119.73(2) . 2_665 ?
N2 Eu2 N2 119.74(2) 3_565 2_665 ?
N2 Eu2 N2 119.74(2) . 3_565 ?
O4 P2 Eu2 32.34(18) . . ?
O4 P2 C25 108.4(3) . . ?
O4 P2 C33 111.0(3) . . ?
O4 P2 C39 114.5(3) . . ?
C25 P2 Eu2 76.0(2) . . ?
C33 P2 Eu2 123.1(3) . . ?
C33 P2 C25 109.4(3) . . ?
C39 P2 Eu2 126.3(2) . . ?
C39 P2 C25 106.6(3) . . ?
C39 P2 C33 106.8(3) . . ?
P2 O4 Eu2 128.4(3) . . ?
C23 O5 Eu2 130.3(5) . . ?
C24 N2 Eu2 117.4(4) . . ?
C24 N2 C25 120.1(6) . . ?
C25 N2 Eu2 122.4(4) . . ?
O5 C23 O6 126.1(7) . . ?
O5 C23 C24 115.6(6) . . ?
O6 C23 C24 118.3(7) . . ?
N2 C24 C23 114.0(6) . . ?
N2 C24 C28 122.0(6) . . ?
C28 C24 C23 123.9(6) . . ?
N2 C25 P2 113.0(5) . . ?
C26 C25 P2 124.4(5) . . ?
C26 C25 N2 122.6(6) . . ?
C25 C26 H26 119.9 . . ?
C25 C26 C27 120.1(7) . . ?
C27 C26 H26 119.9 . . ?
C26 C27 C28 117.6(7) . . ?
C26 C27 C32 122.6(7) . . ?
C32 C27 C28 119.7(7) . . ?
C24 C28 C27 117.2(6) . . ?
C29 C28 C24 125.0(7) . . ?
C29 C28 C27 117.8(6) . . ?
C28 C29 H29 119.6 . . ?
C30 C29 C28 120.7(7) . . ?
C30 C29 H29 119.6 . . ?
C29 C30 H30 119.6 . . ?
C29 C30 C31 120.8(7) . . ?
C31 C30 H30 119.6 . . ?
C30 C31 H31 119.9 . . ?
C32 C31 C30 120.2(7) . . ?
C32 C31 H31 119.9 . . ?
C27 C32 H32 119.7 . . ?
C31 C32 C27 120.6(8) . . ?
C31 C32 H32 119.7 . . ?
C34 C33 P2 117.3(6) . . ?
C34 C33 C38 119.3(7) . . ?
C38 C33 P2 123.4(6) . . ?
C33 C34 H34 119.9 . . ?
C33 C34 C35 120.2(8) . . ?
C35 C34 H34 119.9 . . ?
C34 C35 H35 120.3 . . ?
C36 C35 C34 119.5(9) . . ?
C36 C35 H35 120.3 . . ?
C35 C36 H36 119.3 . . ?
C37 C36 C35 121.5(8) . . ?
C37 C36 H36 119.3 . . ?
C36 C37 H37 120.7 . . ?
C36 C37 C38 118.6(8) . . ?
C38 C37 H37 120.7 . . ?
C33 C38 H38 119.6 . . ?
C37 C38 C33 120.9(8) . . ?
C37 C38 H38 119.6 . . ?
C40 C39 P2 117.3(6) . . ?
C44 C39 P2 122.4(6) . . ?
C44 C39 C40 119.9(7) . . ?
C39 C40 H40 120.3 . . ?
C41 C40 C39 119.3(8) . . ?
C41 C40 H40 120.3 . . ?
C40 C41 H41 120.4 . . ?
C40 C41 C42 119.2(9) . . ?
C42 C41 H41 120.4 . . ?
C41 C42 H42 119.2 . . ?
C43 C42 C41 121.5(8) . . ?
C43 C42 H42 119.2 . . ?
C42 C43 H43 120.0 . . ?
C42 C43 C44 120.0(8) . . ?
C44 C43 H43 120.0 . . ?
C39 C44 H44 120.0 . . ?
C43 C44 C39 120.1(8) . . ?
C43 C44 H44 120.0 . . ?
P3 Eu3 P3 94.31(4) . 3_665 ?
P3 Eu3 P3 94.31(4) 2_655 3_665 ?
P3 Eu3 P3 94.31(4) 2_655 . ?
O7 Eu3 P3 75.58(10) 2_655 3_665 ?
O7 Eu3 P3 18.94(10) 2_655 2_655 ?
O7 Eu3 P3 75.58(10) . 2_655 ?
O7 Eu3 P3 98.30(11) 2_655 . ?
O7 Eu3 P3 98.30(11) . 3_665 ?
O7 Eu3 P3 18.94(10) . . ?
O7 Eu3 P3 98.30(11) 3_665 2_655 ?
O7 Eu3 P3 18.94(10) 3_665 3_665 ?
O7 Eu3 P3 75.58(10) 3_665 . ?
O7 Eu3 O7 81.40(16) 2_655 . ?
O7 Eu3 O7 81.40(16) 2_655 3_665 ?
O7 Eu3 O7 81.40(16) . 3_665 ?
O7 Eu3 N3 66.66(15) . . ?
O7 Eu3 N3 69.37(15) . 2_655 ?
O7 Eu3 N3 66.66(15) 2_655 2_655 ?
O7 Eu3 N3 66.66(15) 3_665 3_665 ?
O7 Eu3 N3 69.38(15) 2_655 3_665 ?
O7 Eu3 N3 138.99(15) 3_665 2_655 ?
O7 Eu3 N3 138.99(15) . 3_665 ?
O7 Eu3 N3 69.37(15) 3_665 . ?
O7 Eu3 N3 138.99(15) 2_655 . ?
O8 Eu3 P3 154.28(12) 2_655 3_665 ?
O8 Eu3 P3 78.38(13) . 3_665 ?
O8 Eu3 P3 110.69(12) . . ?
O8 Eu3 P3 154.28(12) . 2_655 ?
O8 Eu3 P3 154.28(12) 3_665 . ?
O8 Eu3 P3 78.38(13) 2_655 . ?
O8 Eu3 P3 110.69(12) 2_655 2_655 ?
O8 Eu3 P3 78.38(13) 3_665 2_655 ?
O8 Eu3 P3 110.69(11) 3_665 3_665 ?
O8 Eu3 O7 129.61(15) 3_665 3_665 ?
O8 Eu3 O7 129.61(15) 2_655 2_655 ?
O8 Eu3 O7 82.81(16) 3_665 2_655 ?
O8 Eu3 O7 82.81(16) 2_655 . ?
O8 Eu3 O7 142.14(15) 2_655 3_665 ?
O8 Eu3 O7 129.61(15) . . ?
O8 Eu3 O7 142.14(15) . 2_655 ?
O8 Eu3 O7 142.14(15) 3_665 . ?
O8 Eu3 O7 82.81(16) . 3_665 ?
O8 Eu3 O8 81.23(18) 2_655 3_665 ?
O8 Eu3 O8 81.23(18) 3_665 . ?
O8 Eu3 O8 81.23(18) 2_655 . ?
O8 Eu3 N3 138.08(17) 2_655 3_665 ?
O8 Eu3 N3 62.98(16) 3_665 3_665 ?
O8 Eu3 N3 72.78(16) . 3_665 ?
O8 Eu3 N3 62.98(16) . . ?
O8 Eu3 N3 138.08(17) . 2_655 ?
O8 Eu3 N3 72.79(16) 3_665 2_655 ?
O8 Eu3 N3 72.79(16) 2_655 . ?
O8 Eu3 N3 138.08(17) 3_665 . ?
O8 Eu3 N3 62.98(16) 2_655 2_655 ?
N3 Eu3 P3 141.45(11) 2_655 3_665 ?
N3 Eu3 P3 84.01(11) 3_665 2_655 ?
N3 Eu3 P3 84.01(11) 2_655 . ?
N3 Eu3 P3 47.72(11) 3_665 3_665 ?
N3 Eu3 P3 47.72(11) . . ?
N3 Eu3 P3 141.45(11) . 2_655 ?
N3 Eu3 P3 141.45(11) 3_665 . ?
N3 Eu3 P3 84.01(11) . 3_665 ?
N3 Eu3 P3 47.72(11) 2_655 2_655 ?
N3 Eu3 N3 119.999(2) 2_655 . ?
N3 Eu3 N3 119.997(2) . 3_665 ?
N3 Eu3 N3 120.001(2) 2_655 3_665 ?
O7 P3 Eu3 31.73(17) . . ?
O7 P3 C47 107.8(3) . . ?
O7 P3 C55 109.8(3) . . ?
O7 P3 C61 113.8(3) . . ?
C47 P3 Eu3 76.0(2) . . ?
C55 P3 Eu3 122.7(2) . . ?
C55 P3 C47 109.5(3) . . ?
C55 P3 C61 108.6(3) . . ?
C61 P3 Eu3 124.4(2) . . ?
C61 P3 C47 107.3(3) . . ?
P3 O7 Eu3 129.3(2) . . ?
C45 O8 Eu3 129.3(4) . . ?
C46 N3 Eu3 117.0(4) . . ?
C46 N3 C47 118.1(5) . . ?
C47 N3 Eu3 124.5(4) . . ?
O8 C45 C46 115.6(6) . . ?
O9 C45 O8 124.7(7) . . ?
O9 C45 C46 119.6(6) . . ?
N3 C46 C45 113.7(5) . . ?
N3 C46 C50 123.4(6) . . ?
C50 C46 C45 122.9(6) . . ?
N3 C47 P3 111.5(4) . . ?
C48 C47 P3 125.1(5) . . ?
C48 C47 N3 123.4(6) . . ?
C47 C48 H48 119.8 . . ?
C47 C48 C49 120.5(6) . . ?
C49 C48 H48 119.8 . . ?
C48 C49 C50 117.9(6) . . ?
C54 C49 C48 123.0(7) . . ?
C54 C49 C50 119.1(7) . . ?
C46 C50 C49 116.2(6) . . ?
C51 C50 C46 125.5(6) . . ?
C51 C50 C49 118.2(6) . . ?
C50 C51 H51 119.8 . . ?
C52 C51 C50 120.4(8) . . ?
C52 C51 H51 119.8 . . ?
C51 C52 H52 119.2 . . ?
C51 C52 C53 121.5(7) . . ?
C53 C52 H52 119.2 . . ?
C52 C53 H53 119.9 . . ?
C54 C53 C52 120.1(7) . . ?
C54 C53 H53 119.9 . . ?
C49 C54 H54 120.0 . . ?
C53 C54 C49 120.0(7) . . ?
C53 C54 H54 120.0 . . ?
C56 C55 P3 116.4(5) . . ?
C60 C55 P3 125.6(5) . . ?
C60 C55 C56 118.0(6) . . ?
C55 C56 H56 119.4 . . ?
C57 C56 C55 121.2(7) . . ?
C57 C56 H56 119.4 . . ?
C56 C57 H57 120.6 . . ?
C58 C57 C56 118.8(8) . . ?
C58 C57 H57 120.6 . . ?
C57 C58 H58 119.5 . . ?
C59 C58 C57 121.1(7) . . ?
C59 C58 H58 119.5 . . ?
C58 C59 H59 119.8 . . ?
C58 C59 C60 120.5(7) . . ?
C60 C59 H59 119.8 . . ?
C55 C60 C59 120.4(7) . . ?
C55 C60 H60 119.8 . . ?
C59 C60 H60 119.8 . . ?
C62 C61 P3 117.7(5) . . ?
C62 C61 C66 120.2(6) . . ?
C66 C61 P3 122.1(6) . . ?
C61 C62 H62 120.4 . . ?
C61 C62 C63 119.2(7) . . ?
C63 C62 H62 120.4 . . ?
C62 C63 H63 119.8 . . ?
C64 C63 C62 120.4(7) . . ?
C64 C63 H63 119.8 . . ?
C63 C64 H64 119.0 . . ?
C65 C64 C63 122.0(7) . . ?
C65 C64 H64 119.0 . . ?
C64 C65 H65 119.9 . . ?
C64 C65 C66 120.3(8) . . ?
C66 C65 H65 119.9 . . ?
C61 C66 H66 121.0 . . ?
C65 C66 C61 117.9(7) . . ?
C65 C66 H66 121.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 P1 C3 N1 4.1(4) . . . . ?
Eu1 P1 C3 C4 -174.3(7) . . . . ?
Eu1 P1 C11 C12 33.9(8) . . . . ?
Eu1 P1 C11 C16 -145.0(6) . . . . ?
Eu1 P1 C17 C18 50.0(8) . . . . ?
Eu1 P1 C17 C22 -130.2(6) . . . . ?
Eu1 O2 C1 O3 169.4(10) . . . . ?
Eu1 O2 C1 C2 -16.1(12) . . . . ?
Eu1 N1 C2 C1 -1.6(8) . . . . ?
Eu1 N1 C2 C6 -179.6(5) . . . . ?
Eu1 N1 C3 P1 -6.2(7) . . . . ?
Eu1 N1 C3 C4 172.2(5) . . . . ?
P1 C3 C4 C5 -175.8(5) . . . . ?
P1 C11 C12 C13 -177.9(7) . . . . ?
P1 C11 C16 C15 177.4(6) . . . . ?
P1 C17 C18 C19 180.0(7) . . . . ?
P1 C17 C22 C21 176.9(7) . . . . ?
O1 P1 C3 N1 6.2(6) . . . . ?
O1 P1 C3 C4 -172.1(6) . . . . ?
O1 P1 C11 C12 68.6(7) . . . . ?
O1 P1 C11 C16 -110.3(7) . . . . ?
O1 P1 C17 C18 15.5(8) . . . . ?
O1 P1 C17 C22 -164.7(6) . . . . ?
O2 C1 C2 N1 9.9(11) . . . . ?
O2 C1 C2 C6 -172.2(8) . . . . ?
O3 C1 C2 N1 -174.9(10) . . . . ?
O3 C1 C2 C6 3.0(14) . . . . ?
N1 C2 C6 C5 7.9(10) . . . . ?
N1 C2 C6 C7 -172.7(7) . . . . ?
N1 C3 C4 C5 6.0(11) . . . . ?
C1 C2 C6 C5 -169.8(7) . . . . ?
C1 C2 C6 C7 9.5(12) . . . . ?
C2 N1 C3 P1 179.0(5) . . . . ?
C2 N1 C3 C4 -2.6(10) . . . . ?
C2 C6 C7 C8 -178.3(7) . . . . ?
C3 P1 O1 Eu1 -3.9(5) . . . . ?
C3 P1 C11 C12 -50.6(8) . . . . ?
C3 P1 C11 C16 130.5(7) . . . . ?
C3 P1 C17 C18 134.8(7) . . . . ?
C3 P1 C17 C22 -45.5(8) . . . . ?
C3 N1 C2 C1 173.4(7) . . . . ?
C3 N1 C2 C6 -4.6(10) . . . . ?
C3 C4 C5 C6 -2.2(10) . . . . ?
C3 C4 C5 C10 176.9(7) . . . . ?
C4 C5 C6 C2 -4.4(10) . . . . ?
C4 C5 C6 C7 176.3(7) . . . . ?
C4 C5 C10 C9 -176.8(7) . . . . ?
C5 C6 C7 C8 1.1(11) . . . . ?
C6 C5 C10 C9 2.3(11) . . . . ?
C6 C7 C8 C9 1.3(12) . . . . ?
C7 C8 C9 C10 -1.9(12) . . . . ?
C8 C9 C10 C5 0.0(12) . . . . ?
C10 C5 C6 C2 176.5(7) . . . . ?
C10 C5 C6 C7 -2.9(10) . . . . ?
C11 P1 O1 Eu1 -122.2(4) . . . . ?
C11 P1 C3 N1 128.7(5) . . . . ?
C11 P1 C3 C4 -49.7(7) . . . . ?
C11 P1 C17 C18 -109.3(7) . . . . ?
C11 P1 C17 C22 70.5(8) . . . . ?
C11 C12 C13 C14 -0.9(14) . . . . ?
C12 C11 C16 C15 -1.5(12) . . . . ?
C12 C13 C14 C15 1.2(14) . . . . ?
C13 C14 C15 C16 -1.7(14) . . . . ?
C14 C15 C16 C11 1.8(12) . . . . ?
C16 C11 C12 C13 1.0(13) . . . . ?
C17 P1 O1 Eu1 116.0(4) . . . . ?
C17 P1 C3 N1 -114.4(5) . . . . ?
C17 P1 C3 C4 67.3(7) . . . . ?
C17 P1 C11 C12 -168.2(7) . . . . ?
C17 P1 C11 C16 12.9(8) . . . . ?
C17 C18 C19 C20 5.6(16) . . . . ?
C18 C17 C22 C21 -3.3(13) . . . . ?
C18 C19 C20 C21 -8.0(16) . . . . ?
C19 C20 C21 C22 4.6(15) . . . . ?
C20 C21 C22 C17 0.9(13) . . . . ?
C22 C17 C18 C19 0.2(14) . . . . ?
Eu2 P2 C25 N2 -3.7(4) . . . . ?
Eu2 P2 C25 C26 174.8(6) . . . . ?
Eu2 P2 C33 C34 -38.7(7) . . . . ?
Eu2 P2 C33 C38 141.0(5) . . . . ?
Eu2 P2 C39 C40 -33.9(7) . . . . ?
Eu2 P2 C39 C44 138.6(5) . . . . ?
Eu2 O5 C23 O6 -167.5(6) . . . . ?
Eu2 O5 C23 C24 9.5(9) . . . . ?
Eu2 N2 C24 C23 1.2(7) . . . . ?
Eu2 N2 C24 C28 179.2(5) . . . . ?
Eu2 N2 C25 P2 5.6(6) . . . . ?
Eu2 N2 C25 C26 -172.9(5) . . . . ?
P2 C25 C26 C27 175.9(5) . . . . ?
P2 C33 C34 C35 178.2(6) . . . . ?
P2 C33 C38 C37 -178.2(6) . . . . ?
P2 C39 C40 C41 172.3(6) . . . . ?
P2 C39 C44 C43 -171.2(6) . . . . ?
O4 P2 C25 N2 -4.2(6) . . . . ?
O4 P2 C25 C26 174.3(6) . . . . ?
O4 P2 C33 C34 -4.8(7) . . . . ?
O4 P2 C33 C38 174.8(6) . . . . ?
O4 P2 C39 C40 -69.1(6) . . . . ?
O4 P2 C39 C44 103.4(6) . . . . ?
O5 C23 C24 N2 -6.1(9) . . . . ?
O5 C23 C24 C28 175.9(7) . . . . ?
O6 C23 C24 N2 171.2(7) . . . . ?
O6 C23 C24 C28 -6.7(11) . . . . ?
N2 C24 C28 C27 -6.1(10) . . . . ?
N2 C24 C28 C29 172.5(7) . . . . ?
N2 C25 C26 C27 -5.8(11) . . . . ?
C23 C24 C28 C27 171.7(6) . . . . ?
C23 C24 C28 C29 -9.7(11) . . . . ?
C24 N2 C25 P2 -178.3(5) . . . . ?
C24 N2 C25 C26 3.2(10) . . . . ?
C24 C28 C29 C30 179.3(8) . . . . ?
C25 P2 O4 Eu2 0.9(4) . . . . ?
C25 P2 C33 C34 -124.3(6) . . . . ?
C25 P2 C33 C38 55.3(7) . . . . ?
C25 P2 C39 C40 50.7(6) . . . . ?
C25 P2 C39 C44 -136.8(6) . . . . ?
C25 N2 C24 C23 -175.1(6) . . . . ?
C25 N2 C24 C28 3.0(10) . . . . ?
C25 C26 C27 C28 2.3(10) . . . . ?
C25 C26 C27 C32 -176.8(7) . . . . ?
C26 C27 C28 C24 3.3(10) . . . . ?
C26 C27 C28 C29 -175.3(7) . . . . ?
C26 C27 C32 C31 176.9(8) . . . . ?
C27 C28 C29 C30 -2.1(11) . . . . ?
C28 C27 C32 C31 -2.2(12) . . . . ?
C28 C29 C30 C31 -1.2(13) . . . . ?
C29 C30 C31 C32 2.9(13) . . . . ?
C30 C31 C32 C27 -1.2(13) . . . . ?
C32 C27 C28 C24 -177.5(7) . . . . ?
C32 C27 C28 C29 3.8(11) . . . . ?
C33 P2 O4 Eu2 -119.2(4) . . . . ?
C33 P2 C25 N2 116.9(5) . . . . ?
C33 P2 C25 C26 -64.6(7) . . . . ?
C33 P2 C39 C40 167.5(6) . . . . ?
C33 P2 C39 C44 -19.9(7) . . . . ?
C33 C34 C35 C36 -0.2(13) . . . . ?
C34 C33 C38 C37 1.4(11) . . . . ?
C34 C35 C36 C37 1.7(14) . . . . ?
C35 C36 C37 C38 -1.7(13) . . . . ?
C36 C37 C38 C33 0.1(12) . . . . ?
C38 C33 C34 C35 -1.4(12) . . . . ?
C39 P2 O4 Eu2 119.7(4) . . . . ?
C39 P2 C25 N2 -127.9(5) . . . . ?
C39 P2 C25 C26 50.6(7) . . . . ?
C39 P2 C33 C34 120.7(6) . . . . ?
C39 P2 C33 C38 -59.6(7) . . . . ?
C39 C40 C41 C42 -0.2(12) . . . . ?
C40 C39 C44 C43 1.2(11) . . . . ?
C40 C41 C42 C43 0.1(13) . . . . ?
C41 C42 C43 C44 0.6(13) . . . . ?
C42 C43 C44 C39 -1.3(12) . . . . ?
C44 C39 C40 C41 -0.4(11) . . . . ?
Eu3 P3 C47 N3 3.6(4) . . . . ?
Eu3 P3 C47 C48 -178.4(6) . . . . ?
Eu3 P3 C55 C56 8.0(6) . . . . ?
Eu3 P3 C55 C60 -169.3(5) . . . . ?
Eu3 P3 C61 C62 33.2(6) . . . . ?
Eu3 P3 C61 C66 -144.6(5) . . . . ?
Eu3 O8 C45 O9 -165.6(6) . . . . ?
Eu3 O8 C45 C46 11.3(9) . . . . ?
Eu3 N3 C46 C45 10.6(7) . . . . ?
Eu3 N3 C46 C50 -170.0(5) . . . . ?
Eu3 N3 C47 P3 -5.8(6) . . . . ?
Eu3 N3 C47 C48 176.2(5) . . . . ?
P3 C47 C48 C49 177.0(5) . . . . ?
P3 C55 C56 C57 -175.2(6) . . . . ?
P3 C55 C60 C59 176.7(6) . . . . ?
P3 C61 C62 C63 -178.9(5) . . . . ?
P3 C61 C66 C65 -179.1(6) . . . . ?
O7 P3 C47 N3 4.4(5) . . . . ?
O7 P3 C47 C48 -177.6(6) . . . . ?
O7 P3 C55 C56 40.6(6) . . . . ?
O7 P3 C55 C60 -136.7(6) . . . . ?
O7 P3 C61 C62 -1.2(6) . . . . ?
O7 P3 C61 C66 -179.1(5) . . . . ?
O8 C45 C46 N3 -13.8(8) . . . . ?
O8 C45 C46 C50 166.8(6) . . . . ?
O9 C45 C46 N3 163.2(7) . . . . ?
O9 C45 C46 C50 -16.2(10) . . . . ?
N3 C46 C50 C49 -7.6(9) . . . . ?
N3 C46 C50 C51 169.5(7) . . . . ?
N3 C47 C48 C49 -5.2(10) . . . . ?
C45 C46 C50 C49 171.7(6) . . . . ?
C45 C46 C50 C51 -11.2(11) . . . . ?
C46 N3 C47 P3 -178.9(5) . . . . ?
C46 N3 C47 C48 3.0(9) . . . . ?
C46 C50 C51 C52 -178.0(7) . . . . ?
C47 P3 O7 Eu3 -1.4(4) . . . . ?
C47 P3 C55 C56 -77.5(5) . . . . ?
C47 P3 C55 C60 105.1(6) . . . . ?
C47 P3 C61 C62 117.9(5) . . . . ?
C47 P3 C61 C66 -60.0(6) . . . . ?
C47 N3 C46 C45 -175.7(5) . . . . ?
C47 N3 C46 C50 3.7(9) . . . . ?
C47 C48 C49 C50 0.8(10) . . . . ?
C47 C48 C49 C54 -178.0(7) . . . . ?
C48 C49 C50 C46 5.1(9) . . . . ?
C48 C49 C50 C51 -172.2(6) . . . . ?
C48 C49 C54 C53 173.0(7) . . . . ?
C49 C50 C51 C52 -0.9(11) . . . . ?
C50 C49 C54 C53 -5.9(11) . . . . ?
C50 C51 C52 C53 -5.9(13) . . . . ?
C51 C52 C53 C54 6.9(13) . . . . ?
C52 C53 C54 C49 -0.8(12) . . . . ?
C54 C49 C50 C46 -176.0(6) . . . . ?
C54 C49 C50 C51 6.7(10) . . . . ?
C55 P3 O7 Eu3 -120.6(3) . . . . ?
C55 P3 C47 N3 123.8(5) . . . . ?
C55 P3 C47 C48 -58.2(6) . . . . ?
C55 P3 C61 C62 -123.9(5) . . . . ?
C55 P3 C61 C66 58.3(6) . . . . ?
C55 C56 C57 C58 -0.9(11) . . . . ?
C56 C55 C60 C59 -0.6(11) . . . . ?
C56 C57 C58 C59 -2.3(12) . . . . ?
C57 C58 C59 C60 4.1(12) . . . . ?
C58 C59 C60 C55 -2.6(12) . . . . ?
C60 C55 C56 C57 2.3(10) . . . . ?
C61 P3 O7 Eu3 117.4(3) . . . . ?
C61 P3 C47 N3 -118.5(5) . . . . ?
C61 P3 C47 C48 59.5(6) . . . . ?
C61 P3 C55 C56 165.6(5) . . . . ?
C61 P3 C55 C60 -11.7(7) . . . . ?
C61 C62 C63 C64 -1.3(10) . . . . ?
C62 C61 C66 C65 3.1(11) . . . . ?
C62 C63 C64 C65 1.6(12) . . . . ?
C63 C64 C65 C66 0.6(13) . . . . ?
C64 C65 C66 C61 -2.9(12) . . . . ?
C66 C61 C62 C63 -1.0(10) . . . . ?

_shelx_SHELXL_version_number     2014/8
_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Methanol and CH2Cl2'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelxl_sq
_database_code_depnum_ccdc_archive 'CCDC 2009015'
loop_
_audit_author_name
_audit_author_address
'Jie Su'
;Peking University
China
;
_audit_update_record             
;
2020-06-10 deposited with the CCDC.	2020-10-21 downloaded from the CCDC.
;
_audit_creation_date             2017-11-30
_audit_creation_method           
;
Olex2 1.2
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_shelx_SHELXL_version_number     2014/8
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C66 H45 Eu N3 O9 P3, 5(C H4 O)'
_chemical_formula_sum            'C71 H65 Eu N3 O14 P3'
_chemical_formula_weight         1429.13
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.452(2)
_cell_length_b                   15.657(3)
_cell_length_c                   20.993(4)
_cell_angle_alpha                77.41(3)
_cell_angle_beta                 89.17(3)
_cell_angle_gamma                75.35(3)
_cell_volume                     3551.0(14)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    12029
_cell_measurement_temperature    113.15
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      2.0
_shelx_estimated_absorpt_T_max   0.778
_shelx_estimated_absorpt_T_min   0.737
_exptl_absorpt_coefficient_mu    1.014
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8639
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear(Rigaku. 2008)'
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.337
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1464
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.26
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0429
_diffrn_reflns_av_unetI/netI     0.0525
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            42716
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.882
_diffrn_reflns_theta_min         1.840
_diffrn_ambient_temperature      113.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Rigaku Saturn 70 CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  confocal
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'rotating anode'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15127
_reflns_number_total             16850
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrystalClear(Rigaku. 2008)'
_computing_data_collection       'CrystalClear(Rigaku. 2008)'
_computing_data_reduction        'CrystalClear(Rigaku. 2008)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_refine_diff_density_max         1.571
_refine_diff_density_min         -1.134
_refine_diff_density_rms         0.107
_refine_ls_extinction_coef       0.0062(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/8 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     840
_refine_ls_number_reflns         16850
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0377
_refine_ls_R_factor_gt           0.0338
_refine_ls_restrained_S_all      1.061
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0461P)²+1.2189P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0902
_refine_ls_wR_factor_ref         0.0926
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C6(H6), C7(H7), C8(H8), C12(H12), C13(H13), C14(H14),
 C15(H15), C16(H16), C18(H18), C19(H19), C20(H20), C21(H21), C22(H22), C25(H25),
  C27(H27), C28(H28), C29(H29), C30(H30), C34(H34), C35(H35), C36(H36),
 C37(H37), C38(H38), C40(H40), C41(H41), C42(H42), C43(H43), C44(H44), C47(H47),
  C49(H49), C50(H50), C51(H51), C52(H52), C56(H56), C57(H57), C58(H58),
 C59(H59), C60(H60), C62(H62), C63(H63), C64(H64), C65(H65), C66(H66)
2.b Idealised Me refined as rotating group:
 C67(H67A,H67B,H67C), C68(H68A,H68B,H68C), C70(H70A,H70B,H70C), C71(H71A,H71B,
 H71C), C73(H73A,H73B,H73C)
2.c Idealised tetrahedral OH refined as rotating group:
 O10(H10), O11(H11), O13(H13A), O14(H14A), O16(H16A)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.45830(2) 0.68617(2) 0.70634(2) 0.01333(5) Uani 1 1 d . . . . .
P1 P 0.23256(6) 0.84869(4) 0.76242(3) 0.01646(13) Uani 1 1 d . . . . .
P2 P 0.24262(5) 0.69723(4) 0.58214(3) 0.01444(12) Uani 1 1 d . . . . .
P3 P 0.37936(5) 0.49236(4) 0.80195(3) 0.01447(12) Uani 1 1 d . . . . .
O1 O 0.56272(15) 0.75235(11) 0.62051(8) 0.0190(4) Uani 1 1 d . . . . .
O2 O 0.61305(19) 0.86810(13) 0.55322(10) 0.0363(5) Uani 1 1 d . . . . .
O3 O 0.31080(15) 0.75327(11) 0.77612(8) 0.0184(3) Uani 1 1 d . . . . .
O4 O 0.63261(15) 0.56349(11) 0.70506(8) 0.0195(4) Uani 1 1 d . . . . .
O5 O 0.74305(16) 0.44326(13) 0.67159(9) 0.0255(4) Uani 1 1 d . . . . .
O6 O 0.28583(14) 0.73932(11) 0.63185(8) 0.0167(3) Uani 1 1 d . . . . .
O7 O 0.58631(17) 0.73815(12) 0.76952(9) 0.0227(4) Uani 1 1 d . . . . .
O8 O 0.6835(2) 0.73928(15) 0.86029(10) 0.0392(6) Uani 1 1 d . . . . .
O9 O 0.35310(15) 0.57073(11) 0.74377(8) 0.0164(3) Uani 1 1 d . . . . .
N1 N 0.39122(18) 0.86350(13) 0.67249(9) 0.0146(4) Uani 1 1 d . . . . .
N2 N 0.44954(17) 0.58251(13) 0.62048(9) 0.0141(4) Uani 1 1 d . . . . .
N3 N 0.52338(18) 0.58673(13) 0.82712(10) 0.0161(4) Uani 1 1 d . . . . .
C1 C 0.5522(2) 0.83581(17) 0.59579(12) 0.0194(5) Uani 1 1 d . . . . .
C2 C 0.4516(2) 0.90138(16) 0.62214(12) 0.0165(5) Uani 1 1 d . . . . .
C3 C 0.4185(2) 0.99210(17) 0.59422(12) 0.0203(5) Uani 1 1 d . . . . .
H3 H 0.4631 1.0166 0.5596 0.024 Uiso 1 1 calc R . . . .
C4 C 0.3189(2) 1.04899(16) 0.61671(12) 0.0200(5) Uani 1 1 d . . . . .
C5 C 0.2778(3) 1.14291(17) 0.58739(13) 0.0265(6) Uani 1 1 d . . . . .
H5 H 0.3205 1.1695 0.5527 0.032 Uiso 1 1 calc R . . . .
C6 C 0.1780(3) 1.19440(18) 0.60874(14) 0.0292(6) Uani 1 1 d . . . . .
H6 H 0.1502 1.2567 0.5882 0.035 Uiso 1 1 calc R . . . .
C7 C 0.1146(3) 1.15647(18) 0.66147(14) 0.0277(6) Uani 1 1 d . . . . .
H7 H 0.0456 1.1938 0.6763 0.033 Uiso 1 1 calc R . . . .
C8 C 0.1521(2) 1.06670(17) 0.69100(13) 0.0238(5) Uani 1 1 d . . . . .
H8 H 0.1090 1.0420 0.7263 0.029 Uiso 1 1 calc R . . . .
C9 C 0.2549(2) 1.01026(16) 0.66930(12) 0.0189(5) Uani 1 1 d . . . . .
C10 C 0.2974(2) 0.91536(16) 0.69513(11) 0.0157(5) Uani 1 1 d . . . . .
C11 C 0.2353(2) 0.89700(16) 0.83240(12) 0.0205(5) Uani 1 1 d . . . . .
C12 C 0.3487(3) 0.88442(18) 0.86133(14) 0.0272(6) Uani 1 1 d . . . . .
H12 H 0.4187 0.8513 0.8443 0.033 Uiso 1 1 calc R . . . .
C13 C 0.3592(3) 0.9205(2) 0.91525(15) 0.0374(7) Uani 1 1 d . . . . .
H13 H 0.4367 0.9125 0.9348 0.045 Uiso 1 1 calc R . . . .
C14 C 0.2576(4) 0.9677(2) 0.94038(16) 0.0422(8) Uani 1 1 d . . . . .
H14 H 0.2651 0.9917 0.9775 0.051 Uiso 1 1 calc R . . . .
C15 C 0.1450(4) 0.9805(2) 0.91191(16) 0.0448(9) Uani 1 1 d . . . . .
H15 H 0.0753 1.0129 0.9297 0.054 Uiso 1 1 calc R . . . .
C16 C 0.1328(3) 0.9463(2) 0.85721(14) 0.0327(6) Uani 1 1 d . . . . .
H16 H 0.0554 0.9565 0.8369 0.039 Uiso 1 1 calc R . . . .
C17 C 0.0803(2) 0.85620(18) 0.73947(14) 0.0237(5) Uani 1 1 d . . . . .
C18 C 0.0080(3) 0.8201(2) 0.78682(17) 0.0360(7) Uani 1 1 d . . . . .
H18 H 0.0382 0.7978 0.8308 0.043 Uiso 1 1 calc R . . . .
C19 C -0.1064(3) 0.8166(2) 0.7702(2) 0.0500(10) Uani 1 1 d . . . . .
H19 H -0.1552 0.7925 0.8027 0.060 Uiso 1 1 calc R . . . .
C20 C -0.1493(3) 0.8483(2) 0.7063(2) 0.0545(11) Uani 1 1 d . . . . .
H20 H -0.2280 0.8457 0.6948 0.065 Uiso 1 1 calc R . . . .
C21 C -0.0793(3) 0.8841(2) 0.6586(2) 0.0444(9) Uani 1 1 d . . . . .
H21 H -0.1102 0.9059 0.6147 0.053 Uiso 1 1 calc R . . . .
C22 C 0.0357(3) 0.8879(2) 0.67492(16) 0.0321(6) Uani 1 1 d . . . . .
H22 H 0.0841 0.9120 0.6422 0.039 Uiso 1 1 calc R . . . .
C23 C 0.6489(2) 0.50508(17) 0.67106(12) 0.0185(5) Uani 1 1 d . . . . .
C24 C 0.5441(2) 0.50790(15) 0.62730(11) 0.0155(5) Uani 1 1 d . . . . .
C25 C 0.5421(2) 0.43723(16) 0.59907(12) 0.0179(5) Uani 1 1 d . . . . .
H25 H 0.6106 0.3869 0.6039 0.021 Uiso 1 1 calc R . . . .
C26 C 0.4387(2) 0.43923(16) 0.56305(12) 0.0175(5) Uani 1 1 d . . . . .
C27 C 0.4325(2) 0.36784(16) 0.53248(12) 0.0209(5) Uani 1 1 d . . . . .
H27 H 0.4994 0.3164 0.5367 0.025 Uiso 1 1 calc R . . . .
C28 C 0.3314(3) 0.37255(18) 0.49727(13) 0.0245(6) Uani 1 1 d . . . . .
H28 H 0.3289 0.3254 0.4759 0.029 Uiso 1 1 calc R . . . .
C29 C 0.2302(2) 0.44751(18) 0.49245(13) 0.0237(5) Uani 1 1 d . . . . .
H29 H 0.1592 0.4493 0.4689 0.028 Uiso 1 1 calc R . . . .
C30 C 0.2326(2) 0.51763(17) 0.52109(12) 0.0201(5) Uani 1 1 d . . . . .
H30 H 0.1634 0.5673 0.5174 0.024 Uiso 1 1 calc R . . . .
C31 C 0.3381(2) 0.51636(16) 0.55634(11) 0.0155(5) Uani 1 1 d . . . . .
C32 C 0.3516(2) 0.58754(15) 0.58600(11) 0.0145(4) Uani 1 1 d . . . . .
C33 C 0.2431(2) 0.76631(16) 0.50114(12) 0.0192(5) Uani 1 1 d . . . . .
C34 C 0.2877(3) 0.8420(2) 0.49676(15) 0.0330(7) Uani 1 1 d . . . . .
H34 H 0.3157 0.8550 0.5351 0.040 Uiso 1 1 calc R . . . .
C35 C 0.2913(3) 0.8989(2) 0.43598(17) 0.0447(9) Uani 1 1 d . . . . .
H35 H 0.3222 0.9504 0.4331 0.054 Uiso 1 1 calc R . . . .
C36 C 0.2507(3) 0.8810(2) 0.38031(16) 0.0397(8) Uani 1 1 d . . . . .
H36 H 0.2526 0.9202 0.3391 0.048 Uiso 1 1 calc R . . . .
C37 C 0.2069(3) 0.8051(2) 0.38478(14) 0.0322(7) Uani 1 1 d . . . . .
H37 H 0.1794 0.7924 0.3463 0.039 Uiso 1 1 calc R . . . .
C38 C 0.2026(2) 0.74782(19) 0.44454(13) 0.0252(6) Uani 1 1 d . . . . .
H38 H 0.1722 0.6961 0.4470 0.030 Uiso 1 1 calc R . . . .
C39 C 0.0951(2) 0.68209(16) 0.59947(12) 0.0173(5) Uani 1 1 d . . . . .
C40 C 0.0820(2) 0.63206(18) 0.66205(13) 0.0238(5) Uani 1 1 d . . . . .
H40 H 0.1508 0.6029 0.6907 0.029 Uiso 1 1 calc R . . . .
C41 C -0.0319(3) 0.6253(2) 0.68188(15) 0.0292(6) Uani 1 1 d . . . . .
H41 H -0.0410 0.5916 0.7243 0.035 Uiso 1 1 calc R . . . .
C42 C -0.1329(2) 0.66758(19) 0.64024(15) 0.0283(6) Uani 1 1 d . . . . .
H42 H -0.2105 0.6619 0.6539 0.034 Uiso 1 1 calc R . . . .
C43 C -0.1202(2) 0.71781(19) 0.57898(14) 0.0273(6) Uani 1 1 d . . . . .
H43 H -0.1895 0.7475 0.5509 0.033 Uiso 1 1 calc R . . . .
C44 C -0.0066(2) 0.72530(18) 0.55805(13) 0.0235(5) Uani 1 1 d . . . . .
H44 H 0.0016 0.7597 0.5157 0.028 Uiso 1 1 calc R . . . .
C45 C 0.6269(2) 0.70454(18) 0.82755(13) 0.0227(5) Uani 1 1 d . . . . .
C46 C 0.6020(2) 0.61488(17) 0.86061(12) 0.0185(5) Uani 1 1 d . . . . .
C47 C 0.6535(2) 0.56639(18) 0.92021(12) 0.0211(5) Uani 1 1 d . . . . .
H47 H 0.7060 0.5892 0.9427 0.025 Uiso 1 1 calc R . . . .
C48 C 0.6291(2) 0.48274(18) 0.94839(12) 0.0211(5) Uani 1 1 d . . . . .
C49 C 0.6807(3) 0.42969(19) 1.00963(13) 0.0275(6) Uani 1 1 d . . . . .
H49 H 0.7357 0.4496 1.0328 0.033 Uiso 1 1 calc R . . . .
C50 C 0.6523(3) 0.3502(2) 1.03568(14) 0.0329(7) Uani 1 1 d . . . . .
H50 H 0.6863 0.3156 1.0772 0.039 Uiso 1 1 calc R . . . .
C51 C 0.5724(3) 0.3193(2) 1.00122(14) 0.0310(6) Uani 1 1 d . . . . .
H51 H 0.5532 0.2637 1.0197 0.037 Uiso 1 1 calc R . . . .
C52 C 0.5225(3) 0.36827(18) 0.94173(13) 0.0244(5) Uani 1 1 d . . . . .
H52 H 0.4700 0.3460 0.9188 0.029 Uiso 1 1 calc R . . . .
C53 C 0.5482(2) 0.45227(17) 0.91366(12) 0.0197(5) Uani 1 1 d . . . . .
C54 C 0.4964(2) 0.50915(16) 0.85288(11) 0.0160(5) Uani 1 1 d . . . . .
C55 C 0.2450(2) 0.49290(17) 0.84767(12) 0.0188(5) Uani 1 1 d . . . . .
C56 C 0.1613(2) 0.57602(18) 0.84109(13) 0.0232(5) Uani 1 1 d . . . . .
H56 H 0.1760 0.6284 0.8131 0.028 Uiso 1 1 calc R . . . .
C57 C 0.0560(3) 0.5825(2) 0.87560(14) 0.0312(6) Uani 1 1 d . . . . .
H57 H -0.0017 0.6392 0.8710 0.037 Uiso 1 1 calc R . . . .
C58 C 0.0355(3) 0.5064(2) 0.91656(14) 0.0342(7) Uani 1 1 d . . . . .
H58 H -0.0362 0.5111 0.9403 0.041 Uiso 1 1 calc R . . . .
C59 C 0.1184(3) 0.4235(2) 0.92327(14) 0.0339(7) Uani 1 1 d . . . . .
H59 H 0.1037 0.3716 0.9518 0.041 Uiso 1 1 calc R . . . .
C60 C 0.2228(3) 0.41584(19) 0.88852(13) 0.0256(6) Uani 1 1 d . . . . .
H60 H 0.2790 0.3586 0.8924 0.031 Uiso 1 1 calc R . . . .
C61 C 0.4308(2) 0.38705(16) 0.77773(12) 0.0185(5) Uani 1 1 d . . . . .
C62 C 0.5530(2) 0.34326(18) 0.77895(13) 0.0251(6) Uani 1 1 d . . . . .
H62 H 0.6107 0.3634 0.7999 0.030 Uiso 1 1 calc R . . . .
C63 C 0.5905(3) 0.2703(2) 0.74957(15) 0.0340(7) Uani 1 1 d . . . . .
H63 H 0.6740 0.2406 0.7503 0.041 Uiso 1 1 calc R . . . .
C64 C 0.5074(3) 0.2407(2) 0.71927(15) 0.0378(7) Uani 1 1 d . . . . .
H64 H 0.5339 0.1907 0.6992 0.045 Uiso 1 1 calc R . . . .
C65 C 0.3857(3) 0.2833(2) 0.71780(16) 0.0385(7) Uani 1 1 d . . . . .
H65 H 0.3287 0.2626 0.6967 0.046 Uiso 1 1 calc R . . . .
C66 C 0.3471(3) 0.35584(19) 0.74703(14) 0.0290(6) Uani 1 1 d . . . . .
H66 H 0.2634 0.3848 0.7463 0.035 Uiso 1 1 calc R . . . .
O10 O 0.95530(19) 0.37235(16) 0.61530(12) 0.0401(5) Uani 1 1 d . . . . .
H10 H 0.8844 0.3960 0.6242 0.060 Uiso 1 1 calc GR . . . .
C67 C 1.0357(3) 0.4108(3) 0.6418(2) 0.0486(9) Uani 1 1 d . . . . .
H67A H 1.1175 0.3872 0.6282 0.073 Uiso 1 1 calc GR . . . .
H67B H 1.0344 0.3954 0.6896 0.073 Uiso 1 1 calc GR . . . .
H67C H 1.0114 0.4767 0.6263 0.073 Uiso 1 1 calc GR . . . .
O11 O 0.8478(3) 0.3680(2) 0.78875(14) 0.0713(9) Uani 1 1 d . . . . .
H11 H 0.8097 0.3928 0.7528 0.107 Uiso 1 1 calc GR . . . .
C68 C 0.8598(4) 0.4338(3) 0.8209(2) 0.0640(12) Uani 1 1 d . . . . .
H68A H 0.7967 0.4895 0.8044 0.096 Uiso 1 1 calc GR . . . .
H68B H 0.9394 0.4457 0.8132 0.096 Uiso 1 1 calc GR . . . .
H68C H 0.8517 0.4127 0.8679 0.096 Uiso 1 1 calc GR . . . .
O13 O 0.0050(3) 0.2091(2) 0.8156(2) 0.0783(10) Uani 1 1 d . . . . .
H13A H -0.0417 0.2609 0.8120 0.117 Uiso 1 1 calc GR . . . .
C70 C 0.1243(4) 0.2140(3) 0.8211(2) 0.0661(12) Uani 1 1 d . . . . .
H70A H 0.1361 0.2667 0.7893 0.099 Uiso 1 1 calc GR . . . .
H70B H 0.1790 0.1588 0.8126 0.099 Uiso 1 1 calc GR . . . .
H70C H 0.1414 0.2198 0.8654 0.099 Uiso 1 1 calc GR . . . .
O14 O 0.3976(4) 0.2017(2) 0.9400(2) 0.0908(11) Uani 1 1 d . . . . .
H14A H 0.3631 0.1753 0.9709 0.136 Uiso 1 1 calc GR . . . .
C71 C 0.4723(5) 0.1354(3) 0.9078(2) 0.0747(14) Uani 1 1 d . . . . .
H71A H 0.4214 0.1185 0.8780 0.112 Uiso 1 1 calc GR . . . .
H71B H 0.5129 0.0816 0.9406 0.112 Uiso 1 1 calc GR . . . .
H71C H 0.5328 0.1615 0.8829 0.112 Uiso 1 1 calc GR . . . .
O16 O 0.8751(4) 0.1029(3) 0.7802(2) 0.1003(12) Uani 1 1 d . . . . .
H16A H 0.9080 0.1395 0.7920 0.150 Uiso 1 1 calc GR . . . .
C73 C 0.8131(5) 0.0643(5) 0.8324(4) 0.155(4) Uani 1 1 d . . . . .
H73A H 0.7475 0.0447 0.8153 0.233 Uiso 1 1 calc GR . . . .
H73B H 0.7794 0.1093 0.8582 0.233 Uiso 1 1 calc GR . . . .
H73C H 0.8692 0.0120 0.8602 0.233 Uiso 1 1 calc GR . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 P1 3.5264(14) . ?
Eu1 P2 3.5641(12) . ?
Eu1 P3 3.5684(13) . ?
Eu1 O1 2.3452(18) . ?
Eu1 O3 2.4094(18) . ?
Eu1 O4 2.3993(19) . ?
Eu1 O6 2.3938(18) . ?
Eu1 O7 2.3876(18) . ?
Eu1 O9 2.4063(17) . ?
Eu1 N1 2.623(2) . ?
Eu1 N2 2.693(2) . ?
Eu1 N3 2.675(2) . ?
P1 O3 1.5036(18) . ?
P1 C10 1.832(2) . ?
P1 C11 1.797(3) . ?
P1 C17 1.784(3) . ?
P2 O6 1.4993(18) . ?
P2 C32 1.837(2) . ?
P2 C33 1.806(3) . ?
P2 C39 1.786(2) . ?
P3 O9 1.5028(18) . ?
P3 C54 1.831(2) . ?
P3 C55 1.801(3) . ?
P3 C61 1.786(3) . ?
O1 C1 1.272(3) . ?
O2 C1 1.226(3) . ?
O4 C23 1.255(3) . ?
O5 C23 1.252(3) . ?
O7 C45 1.261(3) . ?
O8 C45 1.242(3) . ?
N1 C2 1.364(3) . ?
N1 C10 1.323(3) . ?
N2 C24 1.360(3) . ?
N2 C32 1.320(3) . ?
N3 C46 1.362(3) . ?
N3 C54 1.327(3) . ?
C1 C2 1.523(3) . ?
C2 C3 1.370(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.404(4) . ?
C4 C5 1.423(3) . ?
C4 C9 1.426(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.354(4) . ?
C6 H6 0.9500 . ?
C6 C7 1.419(4) . ?
C7 H7 0.9500 . ?
C7 C8 1.366(4) . ?
C8 H8 0.9500 . ?
C8 C9 1.417(3) . ?
C9 C10 1.425(3) . ?
C11 C12 1.391(4) . ?
C11 C16 1.395(4) . ?
C12 H12 0.9500 . ?
C12 C13 1.390(4) . ?
C13 H13 0.9500 . ?
C13 C14 1.378(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.378(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.391(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.400(4) . ?
C17 C22 1.393(4) . ?
C18 H18 0.9500 . ?
C18 C19 1.378(5) . ?
C19 H19 0.9500 . ?
C19 C20 1.377(6) . ?
C20 H20 0.9500 . ?
C20 C21 1.385(6) . ?
C21 H21 0.9500 . ?
C21 C22 1.386(4) . ?
C22 H22 0.9500 . ?
C23 C24 1.507(3) . ?
C24 C25 1.370(3) . ?
C25 H25 0.9500 . ?
C25 C26 1.404(3) . ?
C26 C27 1.422(3) . ?
C26 C31 1.426(3) . ?
C27 H27 0.9500 . ?
C27 C28 1.360(4) . ?
C28 H28 0.9500 . ?
C28 C29 1.412(4) . ?
C29 H29 0.9500 . ?
C29 C30 1.368(4) . ?
C30 H30 0.9500 . ?
C30 C31 1.420(3) . ?
C31 C32 1.431(3) . ?
C33 C34 1.390(4) . ?
C33 C38 1.395(4) . ?
C34 H34 0.9500 . ?
C34 C35 1.395(4) . ?
C35 H35 0.9500 . ?
C35 C36 1.373(5) . ?
C36 H36 0.9500 . ?
C36 C37 1.386(5) . ?
C37 H37 0.9500 . ?
C37 C38 1.383(4) . ?
C38 H38 0.9500 . ?
C39 C40 1.402(4) . ?
C39 C44 1.395(4) . ?
C40 H40 0.9500 . ?
C40 C41 1.385(4) . ?
C41 H41 0.9500 . ?
C41 C42 1.389(4) . ?
C42 H42 0.9500 . ?
C42 C43 1.380(4) . ?
C43 H43 0.9500 . ?
C43 C44 1.391(4) . ?
C44 H44 0.9500 . ?
C45 C46 1.518(3) . ?
C46 C47 1.368(4) . ?
C47 H47 0.9500 . ?
C47 C48 1.409(4) . ?
C48 C49 1.414(4) . ?
C48 C53 1.419(3) . ?
C49 H49 0.9500 . ?
C49 C50 1.362(4) . ?
C50 H50 0.9500 . ?
C50 C51 1.411(4) . ?
C51 H51 0.9500 . ?
C51 C52 1.362(4) . ?
C52 H52 0.9500 . ?
C52 C53 1.420(3) . ?
C53 C54 1.426(3) . ?
C55 C56 1.388(4) . ?
C55 C60 1.398(3) . ?
C56 H56 0.9500 . ?
C56 C57 1.391(4) . ?
C57 H57 0.9500 . ?
C57 C58 1.379(4) . ?
C58 H58 0.9500 . ?
C58 C59 1.381(5) . ?
C59 H59 0.9500 . ?
C59 C60 1.384(4) . ?
C60 H60 0.9500 . ?
C61 C62 1.392(4) . ?
C61 C66 1.402(4) . ?
C62 H62 0.9500 . ?
C62 C63 1.386(4) . ?
C63 H63 0.9500 . ?
C63 C64 1.376(5) . ?
C64 H64 0.9500 . ?
C64 C65 1.382(5) . ?
C65 H65 0.9500 . ?
C65 C66 1.380(4) . ?
C66 H66 0.9500 . ?
O10 H10 0.8400 . ?
O10 C67 1.400(4) . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
O11 H11 0.8400 . ?
O11 C68 1.383(5) . ?
C68 H68A 0.9800 . ?
C68 H68B 0.9800 . ?
C68 H68C 0.9800 . ?
O13 H13A 0.8400 . ?
O13 C70 1.395(5) . ?
C70 H70A 0.9800 . ?
C70 H70B 0.9800 . ?
C70 H70C 0.9800 . ?
O14 H14A 0.8400 . ?
O14 C71 1.451(6) . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
O16 H16A 0.8400 . ?
O16 C73 1.406(7) . ?
C73 H73A 0.9800 . ?
C73 H73B 0.9800 . ?
C73 H73C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Eu1 P2 86.77(3) . . ?
P1 Eu1 P3 96.27(3) . . ?
P2 Eu1 P3 89.59(3) . . ?
O1 Eu1 P1 112.23(5) . . ?
O1 Eu1 P2 85.25(5) . . ?
O1 Eu1 P3 150.62(4) . . ?
O1 Eu1 O3 131.01(6) . . ?
O1 Eu1 O4 78.91(6) . . ?
O1 Eu1 O6 85.95(6) . . ?
O1 Eu1 O7 81.78(6) . . ?
O1 Eu1 O9 145.65(6) . . ?
O1 Eu1 N1 64.65(7) . . ?
O1 Eu1 N2 79.69(6) . . ?
O1 Eu1 N3 134.00(6) . . ?
O3 Eu1 P1 19.88(4) . . ?
O3 Eu1 P2 94.85(5) . . ?
O3 Eu1 P3 78.20(5) . . ?
O3 Eu1 N1 66.61(6) . . ?
O3 Eu1 N2 132.67(6) . . ?
O3 Eu1 N3 74.52(6) . . ?
O4 Eu1 P1 161.26(4) . . ?
O4 Eu1 P2 109.75(5) . . ?
O4 Eu1 P3 75.71(5) . . ?
O4 Eu1 O3 143.63(6) . . ?
O4 Eu1 O9 85.80(6) . . ?
O4 Eu1 N1 139.87(6) . . ?
O4 Eu1 N2 63.27(6) . . ?
O4 Eu1 N3 69.16(7) . . ?
O6 Eu1 P1 69.63(5) . . ?
O6 Eu1 P2 18.46(4) . . ?
O6 Eu1 P3 98.02(5) . . ?
O6 Eu1 O3 80.58(6) . . ?
O6 Eu1 O4 127.73(6) . . ?
O6 Eu1 O9 79.40(6) . . ?
O6 Eu1 N1 67.99(6) . . ?
O6 Eu1 N2 64.89(6) . . ?
O6 Eu1 N3 139.89(6) . . ?
O7 Eu1 P1 81.98(5) . . ?
O7 Eu1 P2 158.14(4) . . ?
O7 Eu1 P3 110.18(5) . . ?
O7 Eu1 O3 80.74(6) . . ?
O7 Eu1 O4 84.95(7) . . ?
O7 Eu1 O6 141.91(6) . . ?
O7 Eu1 O9 127.56(6) . . ?
O7 Eu1 N1 74.17(7) . . ?
O7 Eu1 N2 145.66(6) . . ?
O7 Eu1 N3 63.67(6) . . ?
O9 Eu1 P1 91.56(5) . . ?
O9 Eu1 P2 71.20(5) . . ?
O9 Eu1 P3 18.71(4) . . ?
O9 Eu1 O3 77.07(6) . . ?
O9 Eu1 N1 134.02(6) . . ?
O9 Eu1 N2 65.96(6) . . ?
O9 Eu1 N3 64.80(6) . . ?
N1 Eu1 P1 47.60(5) . . ?
N1 Eu1 P2 84.40(5) . . ?
N1 Eu1 P3 143.56(5) . . ?
N1 Eu1 N2 121.79(6) . . ?
N1 Eu1 N3 126.07(7) . . ?
N2 Eu1 P1 131.92(5) . . ?
N2 Eu1 P2 46.58(5) . . ?
N2 Eu1 P3 75.86(4) . . ?
N3 Eu1 P1 92.92(5) . . ?
N3 Eu1 P2 135.97(5) . . ?
N3 Eu1 P3 46.63(5) . . ?
N3 Eu1 N2 111.95(6) . . ?
O3 P1 Eu1 33.02(7) . . ?
O3 P1 C10 107.63(11) . . ?
O3 P1 C11 110.17(11) . . ?
O3 P1 C17 112.82(11) . . ?
C10 P1 Eu1 75.83(8) . . ?
C11 P1 Eu1 129.76(9) . . ?
C11 P1 C10 107.60(11) . . ?
C17 P1 Eu1 116.35(9) . . ?
C17 P1 C10 108.66(12) . . ?
C17 P1 C11 109.80(13) . . ?
O6 P2 Eu1 30.37(6) . . ?
O6 P2 C32 106.80(10) . . ?
O6 P2 C33 110.16(11) . . ?
O6 P2 C39 110.74(11) . . ?
C32 P2 Eu1 76.42(8) . . ?
C33 P2 Eu1 121.00(9) . . ?
C33 P2 C32 108.01(11) . . ?
C39 P2 Eu1 122.89(9) . . ?
C39 P2 C32 110.52(11) . . ?
C39 P2 C33 110.52(12) . . ?
O9 P3 Eu1 30.91(6) . . ?
O9 P3 C54 106.97(10) . . ?
O9 P3 C55 109.41(11) . . ?
O9 P3 C61 111.34(11) . . ?
C54 P3 Eu1 76.55(8) . . ?
C55 P3 Eu1 126.06(9) . . ?
C55 P3 C54 109.16(11) . . ?
C61 P3 Eu1 118.22(8) . . ?
C61 P3 C54 110.04(12) . . ?
C61 P3 C55 109.85(12) . . ?
C1 O1 Eu1 128.88(15) . . ?
P1 O3 Eu1 127.09(10) . . ?
C23 O4 Eu1 128.61(15) . . ?
P2 O6 Eu1 131.16(10) . . ?
C45 O7 Eu1 128.37(16) . . ?
P3 O9 Eu1 130.37(10) . . ?
C2 N1 Eu1 114.97(15) . . ?
C10 N1 Eu1 125.13(15) . . ?
C10 N1 C2 119.4(2) . . ?
C24 N2 Eu1 114.07(15) . . ?
C32 N2 Eu1 124.31(15) . . ?
C32 N2 C24 119.5(2) . . ?
C46 N3 Eu1 115.05(15) . . ?
C54 N3 Eu1 125.55(15) . . ?
C54 N3 C46 118.9(2) . . ?
O1 C1 C2 115.4(2) . . ?
O2 C1 O1 127.1(2) . . ?
O2 C1 C2 117.5(2) . . ?
N1 C2 C1 115.9(2) . . ?
N1 C2 C3 122.0(2) . . ?
C3 C2 C1 122.0(2) . . ?
C2 C3 H3 119.9 . . ?
C2 C3 C4 120.1(2) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 C5 122.2(2) . . ?
C3 C4 C9 118.5(2) . . ?
C5 C4 C9 119.3(2) . . ?
C4 C5 H5 119.9 . . ?
C6 C5 C4 120.2(2) . . ?
C6 C5 H5 119.9 . . ?
C5 C6 H6 119.6 . . ?
C5 C6 C7 120.8(2) . . ?
C7 C6 H6 119.6 . . ?
C6 C7 H7 119.8 . . ?
C8 C7 C6 120.5(3) . . ?
C8 C7 H7 119.8 . . ?
C7 C8 H8 119.8 . . ?
C7 C8 C9 120.4(2) . . ?
C9 C8 H8 119.8 . . ?
C8 C9 C4 118.9(2) . . ?
C8 C9 C10 124.3(2) . . ?
C10 C9 C4 116.8(2) . . ?
N1 C10 P1 110.97(17) . . ?
N1 C10 C9 123.2(2) . . ?
C9 C10 P1 125.86(18) . . ?
C12 C11 P1 116.0(2) . . ?
C12 C11 C16 120.0(3) . . ?
C16 C11 P1 124.0(2) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 C11 119.8(3) . . ?
C13 C12 H12 120.1 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 C12 120.1(3) . . ?
C14 C13 H13 120.0 . . ?
C13 C14 H14 119.8 . . ?
C13 C14 C15 120.4(3) . . ?
C15 C14 H14 119.8 . . ?
C14 C15 H15 119.8 . . ?
C14 C15 C16 120.3(3) . . ?
C16 C15 H15 119.8 . . ?
C11 C16 H16 120.3 . . ?
C15 C16 C11 119.4(3) . . ?
C15 C16 H16 120.3 . . ?
C18 C17 P1 118.4(2) . . ?
C22 C17 P1 122.0(2) . . ?
C22 C17 C18 119.2(3) . . ?
C17 C18 H18 119.7 . . ?
C19 C18 C17 120.7(3) . . ?
C19 C18 H18 119.7 . . ?
C18 C19 H19 120.3 . . ?
C20 C19 C18 119.5(3) . . ?
C20 C19 H19 120.3 . . ?
C19 C20 H20 119.6 . . ?
C19 C20 C21 120.9(3) . . ?
C21 C20 H20 119.6 . . ?
C20 C21 H21 120.0 . . ?
C20 C21 C22 119.9(4) . . ?
C22 C21 H21 120.0 . . ?
C17 C22 H22 120.1 . . ?
C21 C22 C17 119.8(3) . . ?
C21 C22 H22 120.1 . . ?
O4 C23 C24 117.0(2) . . ?
O5 C23 O4 125.9(2) . . ?
O5 C23 C24 117.2(2) . . ?
N2 C24 C23 116.0(2) . . ?
N2 C24 C25 122.2(2) . . ?
C25 C24 C23 121.7(2) . . ?
C24 C25 H25 120.0 . . ?
C24 C25 C26 120.0(2) . . ?
C26 C25 H25 120.0 . . ?
C25 C26 C27 122.1(2) . . ?
C25 C26 C31 118.4(2) . . ?
C27 C26 C31 119.5(2) . . ?
C26 C27 H27 119.7 . . ?
C28 C27 C26 120.5(2) . . ?
C28 C27 H27 119.7 . . ?
C27 C28 H28 120.0 . . ?
C27 C28 C29 120.0(2) . . ?
C29 C28 H28 120.0 . . ?
C28 C29 H29 119.4 . . ?
C30 C29 C28 121.3(2) . . ?
C30 C29 H29 119.4 . . ?
C29 C30 H30 119.9 . . ?
C29 C30 C31 120.2(2) . . ?
C31 C30 H30 119.9 . . ?
C26 C31 C32 116.9(2) . . ?
C30 C31 C26 118.5(2) . . ?
C30 C31 C32 124.7(2) . . ?
N2 C32 P2 109.87(17) . . ?
N2 C32 C31 123.0(2) . . ?
C31 C32 P2 127.17(18) . . ?
C34 C33 P2 116.2(2) . . ?
C34 C33 C38 119.6(2) . . ?
C38 C33 P2 124.2(2) . . ?
C33 C34 H34 120.1 . . ?
C33 C34 C35 119.8(3) . . ?
C35 C34 H34 120.1 . . ?
C34 C35 H35 119.7 . . ?
C36 C35 C34 120.6(3) . . ?
C36 C35 H35 119.7 . . ?
C35 C36 H36 120.3 . . ?
C35 C36 C37 119.5(3) . . ?
C37 C36 H36 120.3 . . ?
C36 C37 H37 119.5 . . ?
C38 C37 C36 120.9(3) . . ?
C38 C37 H37 119.5 . . ?
C33 C38 H38 120.2 . . ?
C37 C38 C33 119.6(3) . . ?
C37 C38 H38 120.2 . . ?
C40 C39 P2 115.99(19) . . ?
C44 C39 P2 123.8(2) . . ?
C44 C39 C40 119.8(2) . . ?
C39 C40 H40 120.2 . . ?
C41 C40 C39 119.6(3) . . ?
C41 C40 H40 120.2 . . ?
C40 C41 H41 119.7 . . ?
C40 C41 C42 120.5(3) . . ?
C42 C41 H41 119.7 . . ?
C41 C42 H42 120.1 . . ?
C43 C42 C41 119.9(2) . . ?
C43 C42 H42 120.1 . . ?
C42 C43 H43 119.7 . . ?
C42 C43 C44 120.5(3) . . ?
C44 C43 H43 119.7 . . ?
C39 C44 H44 120.2 . . ?
C43 C44 C39 119.7(3) . . ?
C43 C44 H44 120.2 . . ?
O7 C45 C46 117.1(2) . . ?
O8 C45 O7 125.6(2) . . ?
O8 C45 C46 117.3(2) . . ?
N3 C46 C45 115.2(2) . . ?
N3 C46 C47 122.3(2) . . ?
C47 C46 C45 122.4(2) . . ?
C46 C47 H47 119.8 . . ?
C46 C47 C48 120.3(2) . . ?
C48 C47 H47 119.8 . . ?
C47 C48 C49 122.5(2) . . ?
C47 C48 C53 117.9(2) . . ?
C49 C48 C53 119.6(2) . . ?
C48 C49 H49 119.8 . . ?
C50 C49 C48 120.5(3) . . ?
C50 C49 H49 119.8 . . ?
C49 C50 H50 119.9 . . ?
C49 C50 C51 120.2(3) . . ?
C51 C50 H50 119.9 . . ?
C50 C51 H51 119.7 . . ?
C52 C51 C50 120.7(3) . . ?
C52 C51 H51 119.7 . . ?
C51 C52 H52 119.7 . . ?
C51 C52 C53 120.7(3) . . ?
C53 C52 H52 119.7 . . ?
C48 C53 C52 118.4(2) . . ?
C48 C53 C54 117.4(2) . . ?
C52 C53 C54 124.2(2) . . ?
N3 C54 P3 110.07(17) . . ?
N3 C54 C53 123.1(2) . . ?
C53 C54 P3 126.76(18) . . ?
C56 C55 P3 116.25(19) . . ?
C56 C55 C60 120.0(2) . . ?
C60 C55 P3 123.8(2) . . ?
C55 C56 H56 120.1 . . ?
C55 C56 C57 119.8(3) . . ?
C57 C56 H56 120.1 . . ?
C56 C57 H57 120.0 . . ?
C58 C57 C56 119.9(3) . . ?
C58 C57 H57 120.0 . . ?
C57 C58 H58 119.7 . . ?
C57 C58 C59 120.5(3) . . ?
C59 C58 H58 119.7 . . ?
C58 C59 H59 119.9 . . ?
C58 C59 C60 120.2(3) . . ?
C60 C59 H59 119.9 . . ?
C55 C60 H60 120.2 . . ?
C59 C60 C55 119.6(3) . . ?
C59 C60 H60 120.2 . . ?
C62 C61 P3 121.9(2) . . ?
C62 C61 C66 119.1(2) . . ?
C66 C61 P3 118.2(2) . . ?
C61 C62 H62 120.0 . . ?
C63 C62 C61 120.0(3) . . ?
C63 C62 H62 120.0 . . ?
C62 C63 H63 119.8 . . ?
C64 C63 C62 120.3(3) . . ?
C64 C63 H63 119.8 . . ?
C63 C64 H64 119.8 . . ?
C63 C64 C65 120.5(3) . . ?
C65 C64 H64 119.8 . . ?
C64 C65 H65 120.1 . . ?
C66 C65 C64 119.8(3) . . ?
C66 C65 H65 120.1 . . ?
C61 C66 H66 119.8 . . ?
C65 C66 C61 120.4(3) . . ?
C65 C66 H66 119.8 . . ?
C67 O10 H10 109.5 . . ?
O10 C67 H67A 109.5 . . ?
O10 C67 H67B 109.5 . . ?
O10 C67 H67C 109.5 . . ?
H67A C67 H67B 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
C68 O11 H11 109.5 . . ?
O11 C68 H68A 109.5 . . ?
O11 C68 H68B 109.5 . . ?
O11 C68 H68C 109.5 . . ?
H68A C68 H68B 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C70 O13 H13A 109.5 . . ?
O13 C70 H70A 109.5 . . ?
O13 C70 H70B 109.5 . . ?
O13 C70 H70C 109.5 . . ?
H70A C70 H70B 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C71 O14 H14A 109.5 . . ?
O14 C71 H71A 109.5 . . ?
O14 C71 H71B 109.5 . . ?
O14 C71 H71C 109.5 . . ?
H71A C71 H71B 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C73 O16 H16A 109.5 . . ?
O16 C73 H73A 109.5 . . ?
O16 C73 H73B 109.5 . . ?
O16 C73 H73C 109.5 . . ?
H73A C73 H73B 109.5 . . ?
H73A C73 H73C 109.5 . . ?
H73B C73 H73C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 P1 C10 N1 -5.21(15) . . . . ?
Eu1 P1 C10 C9 174.7(2) . . . . ?
Eu1 P1 C11 C12 15.3(2) . . . . ?
Eu1 P1 C11 C16 -166.04(19) . . . . ?
Eu1 P1 C17 C18 105.2(2) . . . . ?
Eu1 P1 C17 C22 -67.9(2) . . . . ?
Eu1 P2 C32 N2 -12.77(14) . . . . ?
Eu1 P2 C32 C31 168.1(2) . . . . ?
Eu1 P2 C33 C34 -28.3(2) . . . . ?
Eu1 P2 C33 C38 151.45(19) . . . . ?
Eu1 P2 C39 C40 -24.1(2) . . . . ?
Eu1 P2 C39 C44 148.09(19) . . . . ?
Eu1 P3 C54 N3 8.26(15) . . . . ?
Eu1 P3 C54 C53 -175.5(2) . . . . ?
Eu1 P3 C55 C56 4.7(2) . . . . ?
Eu1 P3 C55 C60 -174.73(18) . . . . ?
Eu1 P3 C61 C62 65.1(2) . . . . ?
Eu1 P3 C61 C66 -104.6(2) . . . . ?
Eu1 O1 C1 O2 175.7(2) . . . . ?
Eu1 O1 C1 C2 -5.1(3) . . . . ?
Eu1 O4 C23 O5 178.61(18) . . . . ?
Eu1 O4 C23 C24 -3.5(3) . . . . ?
Eu1 O7 C45 O8 -172.5(2) . . . . ?
Eu1 O7 C45 C46 6.1(3) . . . . ?
Eu1 N1 C2 C1 -3.0(3) . . . . ?
Eu1 N1 C2 C3 172.93(19) . . . . ?
Eu1 N1 C10 P1 8.3(2) . . . . ?
Eu1 N1 C10 C9 -171.56(17) . . . . ?
Eu1 N2 C24 C23 -11.9(2) . . . . ?
Eu1 N2 C24 C25 164.64(18) . . . . ?
Eu1 N2 C32 P2 20.1(2) . . . . ?
Eu1 N2 C32 C31 -160.66(16) . . . . ?
Eu1 N3 C46 C45 7.6(3) . . . . ?
Eu1 N3 C46 C47 -173.25(19) . . . . ?
Eu1 N3 C54 P3 -13.2(2) . . . . ?
Eu1 N3 C54 C53 170.34(18) . . . . ?
P1 C11 C12 C13 179.3(2) . . . . ?
P1 C11 C16 C15 179.7(2) . . . . ?
P1 C17 C18 C19 -174.0(2) . . . . ?
P1 C17 C22 C21 173.6(2) . . . . ?
P2 C33 C34 C35 179.9(3) . . . . ?
P2 C33 C38 C37 -180.0(2) . . . . ?
P2 C39 C40 C41 173.1(2) . . . . ?
P2 C39 C44 C43 -172.4(2) . . . . ?
P3 C55 C56 C57 -179.0(2) . . . . ?
P3 C55 C60 C59 178.0(2) . . . . ?
P3 C61 C62 C63 -169.0(2) . . . . ?
P3 C61 C66 C65 169.2(2) . . . . ?
O1 C1 C2 N1 5.1(3) . . . . ?
O1 C1 C2 C3 -170.9(2) . . . . ?
O2 C1 C2 N1 -175.7(2) . . . . ?
O2 C1 C2 C3 8.4(4) . . . . ?
O3 P1 C10 N1 3.8(2) . . . . ?
O3 P1 C10 C9 -176.3(2) . . . . ?
O3 P1 C11 C12 46.4(2) . . . . ?
O3 P1 C11 C16 -134.9(2) . . . . ?
O3 P1 C17 C18 69.0(2) . . . . ?
O3 P1 C17 C22 -104.1(2) . . . . ?
O4 C23 C24 N2 10.8(3) . . . . ?
O4 C23 C24 C25 -165.8(2) . . . . ?
O5 C23 C24 N2 -171.1(2) . . . . ?
O5 C23 C24 C25 12.3(3) . . . . ?
O6 P2 C32 N2 -12.65(19) . . . . ?
O6 P2 C32 C31 168.2(2) . . . . ?
O6 P2 C33 C34 3.3(2) . . . . ?
O6 P2 C33 C38 -176.9(2) . . . . ?
O6 P2 C39 C40 -55.5(2) . . . . ?
O6 P2 C39 C44 116.7(2) . . . . ?
O7 C45 C46 N3 -9.1(3) . . . . ?
O7 C45 C46 C47 171.8(2) . . . . ?
O8 C45 C46 N3 169.6(2) . . . . ?
O8 C45 C46 C47 -9.5(4) . . . . ?
O9 P3 C54 N3 2.7(2) . . . . ?
O9 P3 C54 C53 178.9(2) . . . . ?
O9 P3 C55 C56 -25.0(2) . . . . ?
O9 P3 C55 C60 155.6(2) . . . . ?
O9 P3 C61 C62 98.4(2) . . . . ?
O9 P3 C61 C66 -71.3(2) . . . . ?
N1 C2 C3 C4 -0.8(4) . . . . ?
N2 C24 C25 C26 -1.7(4) . . . . ?
N3 C46 C47 C48 2.0(4) . . . . ?
C1 C2 C3 C4 174.9(2) . . . . ?
C2 N1 C10 P1 -179.94(17) . . . . ?
C2 N1 C10 C9 0.2(3) . . . . ?
C2 C3 C4 C5 -177.2(3) . . . . ?
C2 C3 C4 C9 0.7(4) . . . . ?
C3 C4 C5 C6 177.0(3) . . . . ?
C3 C4 C9 C8 -178.1(2) . . . . ?
C3 C4 C9 C10 -0.2(4) . . . . ?
C4 C5 C6 C7 1.5(5) . . . . ?
C4 C9 C10 P1 179.88(19) . . . . ?
C4 C9 C10 N1 -0.3(4) . . . . ?
C5 C4 C9 C8 -0.2(4) . . . . ?
C5 C4 C9 C10 177.8(2) . . . . ?
C5 C6 C7 C8 -1.1(5) . . . . ?
C6 C7 C8 C9 0.0(4) . . . . ?
C7 C8 C9 C4 0.6(4) . . . . ?
C7 C8 C9 C10 -177.1(3) . . . . ?
C8 C9 C10 P1 -2.3(4) . . . . ?
C8 C9 C10 N1 177.6(2) . . . . ?
C9 C4 C5 C6 -0.9(4) . . . . ?
C10 P1 O3 Eu1 -16.20(15) . . . . ?
C10 P1 C11 C12 -70.7(2) . . . . ?
C10 P1 C11 C16 108.0(2) . . . . ?
C10 P1 C17 C18 -171.7(2) . . . . ?
C10 P1 C17 C22 15.2(3) . . . . ?
C10 N1 C2 C1 -175.6(2) . . . . ?
C10 N1 C2 C3 0.4(4) . . . . ?
C11 P1 O3 Eu1 -133.24(12) . . . . ?
C11 P1 C10 N1 122.52(18) . . . . ?
C11 P1 C10 C9 -57.6(2) . . . . ?
C11 P1 C17 C18 -54.3(2) . . . . ?
C11 P1 C17 C22 132.6(2) . . . . ?
C11 C12 C13 C14 0.7(4) . . . . ?
C12 C11 C16 C15 -1.7(4) . . . . ?
C12 C13 C14 C15 -0.7(5) . . . . ?
C13 C14 C15 C16 -0.4(5) . . . . ?
C14 C15 C16 C11 1.6(5) . . . . ?
C16 C11 C12 C13 0.5(4) . . . . ?
C17 P1 O3 Eu1 103.66(14) . . . . ?
C17 P1 C10 N1 -118.66(18) . . . . ?
C17 P1 C10 C9 61.2(2) . . . . ?
C17 P1 C11 C12 171.25(19) . . . . ?
C17 P1 C11 C16 -10.1(3) . . . . ?
C17 C18 C19 C20 0.5(5) . . . . ?
C18 C17 C22 C21 0.6(4) . . . . ?
C18 C19 C20 C21 -0.3(5) . . . . ?
C19 C20 C21 C22 0.3(5) . . . . ?
C20 C21 C22 C17 -0.4(5) . . . . ?
C22 C17 C18 C19 -0.7(4) . . . . ?
C23 C24 C25 C26 174.7(2) . . . . ?
C24 N2 C32 P2 -177.41(16) . . . . ?
C24 N2 C32 C31 1.8(3) . . . . ?
C24 C25 C26 C27 179.6(2) . . . . ?
C24 C25 C26 C31 0.7(3) . . . . ?
C25 C26 C27 C28 -179.2(2) . . . . ?
C25 C26 C31 C30 -178.7(2) . . . . ?
C25 C26 C31 C32 1.4(3) . . . . ?
C26 C27 C28 C29 -1.9(4) . . . . ?
C26 C31 C32 P2 176.36(17) . . . . ?
C26 C31 C32 N2 -2.7(3) . . . . ?
C27 C26 C31 C30 2.4(3) . . . . ?
C27 C26 C31 C32 -177.6(2) . . . . ?
C27 C28 C29 C30 1.9(4) . . . . ?
C28 C29 C30 C31 0.2(4) . . . . ?
C29 C30 C31 C26 -2.3(4) . . . . ?
C29 C30 C31 C32 177.6(2) . . . . ?
C30 C31 C32 P2 -3.5(3) . . . . ?
C30 C31 C32 N2 177.4(2) . . . . ?
C31 C26 C27 C28 -0.3(4) . . . . ?
C32 P2 O6 Eu1 -0.23(15) . . . . ?
C32 P2 C33 C34 -113.0(2) . . . . ?
C32 P2 C33 C38 66.8(2) . . . . ?
C32 P2 C39 C40 62.7(2) . . . . ?
C32 P2 C39 C44 -125.1(2) . . . . ?
C32 N2 C24 C23 -176.1(2) . . . . ?
C32 N2 C24 C25 0.5(3) . . . . ?
C33 P2 O6 Eu1 -117.29(13) . . . . ?
C33 P2 C32 N2 105.82(18) . . . . ?
C33 P2 C32 C31 -73.3(2) . . . . ?
C33 P2 C39 C40 -177.85(19) . . . . ?
C33 P2 C39 C44 -5.6(3) . . . . ?
C33 C34 C35 C36 0.3(5) . . . . ?
C34 C33 C38 C37 -0.2(4) . . . . ?
C34 C35 C36 C37 -0.6(5) . . . . ?
C35 C36 C37 C38 0.6(5) . . . . ?
C36 C37 C38 C33 -0.1(4) . . . . ?
C38 C33 C34 C35 0.2(4) . . . . ?
C39 P2 O6 Eu1 120.15(13) . . . . ?
C39 P2 C32 N2 -133.17(17) . . . . ?
C39 P2 C32 C31 47.7(2) . . . . ?
C39 P2 C33 C34 126.0(2) . . . . ?
C39 P2 C33 C38 -54.2(2) . . . . ?
C39 C40 C41 C42 0.1(4) . . . . ?
C40 C39 C44 C43 -0.5(4) . . . . ?
C40 C41 C42 C43 -1.0(4) . . . . ?
C41 C42 C43 C44 1.1(4) . . . . ?
C42 C43 C44 C39 -0.4(4) . . . . ?
C44 C39 C40 C41 0.6(4) . . . . ?
C45 C46 C47 C48 -178.9(2) . . . . ?
C46 N3 C54 P3 174.92(17) . . . . ?
C46 N3 C54 C53 -1.5(4) . . . . ?
C46 C47 C48 C49 179.5(3) . . . . ?
C46 C47 C48 C53 -1.3(4) . . . . ?
C47 C48 C49 C50 178.4(3) . . . . ?
C47 C48 C53 C52 -179.7(2) . . . . ?
C47 C48 C53 C54 -0.6(4) . . . . ?
C48 C49 C50 C51 1.1(5) . . . . ?
C48 C53 C54 P3 -173.76(19) . . . . ?
C48 C53 C54 N3 2.0(4) . . . . ?
C49 C48 C53 C52 -0.6(4) . . . . ?
C49 C48 C53 C54 178.6(2) . . . . ?
C49 C50 C51 C52 -0.2(5) . . . . ?
C50 C51 C52 C53 -1.1(5) . . . . ?
C51 C52 C53 C48 1.4(4) . . . . ?
C51 C52 C53 C54 -177.6(3) . . . . ?
C52 C53 C54 P3 5.3(4) . . . . ?
C52 C53 C54 N3 -178.9(2) . . . . ?
C53 C48 C49 C50 -0.7(4) . . . . ?
C54 P3 O9 Eu1 10.65(15) . . . . ?
C54 P3 C55 C56 91.7(2) . . . . ?
C54 P3 C55 C60 -87.7(2) . . . . ?
C54 P3 C61 C62 -20.1(2) . . . . ?
C54 P3 C61 C66 170.3(2) . . . . ?
C54 N3 C46 C45 -179.7(2) . . . . ?
C54 N3 C46 C47 -0.6(4) . . . . ?
C55 P3 O9 Eu1 128.77(13) . . . . ?
C55 P3 C54 N3 -115.63(18) . . . . ?
C55 P3 C54 C53 60.6(2) . . . . ?
C55 P3 C61 C62 -140.3(2) . . . . ?
C55 P3 C61 C66 50.1(2) . . . . ?
C55 C56 C57 C58 0.4(4) . . . . ?
C56 C55 C60 C59 -1.4(4) . . . . ?
C56 C57 C58 C59 -0.5(5) . . . . ?
C57 C58 C59 C60 -0.4(5) . . . . ?
C58 C59 C60 C55 1.3(4) . . . . ?
C60 C55 C56 C57 0.5(4) . . . . ?
C61 P3 O9 Eu1 -109.61(14) . . . . ?
C61 P3 C54 N3 123.74(18) . . . . ?
C61 P3 C54 C53 -60.0(2) . . . . ?
C61 P3 C55 C56 -147.5(2) . . . . ?
C61 P3 C55 C60 33.1(3) . . . . ?
C61 C62 C63 C64 -0.2(4) . . . . ?
C62 C61 C66 C65 -0.7(4) . . . . ?
C62 C63 C64 C65 0.0(5) . . . . ?
C63 C64 C65 C66 -0.1(5) . . . . ?
C64 C65 C66 C61 0.5(5) . . . . ?
C66 C61 C62 C63 0.5(4) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 0.000 0.500 78.4 20.4 ?
2 0.166 0.129 0.079 204.7 48.6 ?
3 -0.166 0.871 -0.079 204.7 48.2 ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: methanol/dichloromethane solutions'
_chemical_compound_source        None
_exptl_crystal_preparation       Luminescent
