# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Saida
_database_code_depnum_ccdc_archive 'CCDC 1909744'
loop_
_audit_author_name
_audit_author_address
'Ben Ali Saida and Joan Josep sunol and Mohamed Belhouchet'
;Physico Chemistry of Solid State Laboratory, Department of Chemistry, Faculty of Sciences of Sfax
Tunisia
;
#Added by publCIF



_audit_update_record             
;
2019-04-12 deposited with the CCDC.	2020-09-24 downloaded from the CCDC.
;


_cell_measurement_pressure       ?

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
 ?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C24 H36 Bi4 I16 N4 O8 S2'
_chemical_formula_weight         3439.01

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   12.0453(14)
_cell_length_b                   20.437(2)
_cell_length_c                   13.1306(16)
_cell_angle_alpha                90.00
_cell_angle_beta                 96.880(2)
_cell_angle_gamma                90.00
_cell_volume                     3209.1(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    100(2)
_cell_measurement_reflns_used    48812
_cell_measurement_theta_min      2
_cell_measurement_theta_max      28.5

_exptl_crystal_description       Prism
_exptl_crystal_colour            red
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.559
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2968
_exptl_absorpt_coefficient_mu    18.733
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.008
_exptl_absorpt_correction_T_max  0.034
_exptl_absorpt_process_details   'SASDABS v2.10 BRUKER 2001'

_exptl_special_details           
;
 ?
;

_diffrn_ambient_temperature      100(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            48812
_diffrn_reflns_av_R_equivalents  0.0769
_diffrn_reflns_av_sigmaI/netI    0.0474
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_theta_min         1.99
_diffrn_reflns_theta_max         28.54
_reflns_number_total             8017
_reflns_number_gt                7328
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and
 goodness of fit S are based on F², conventional R-factors R are based
 on F, with F set to zero for negative F². The threshold expression of
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is
 not relevant to the choice of reflections for refinement.  R-factors based
 on F² are statistically about twice as large as those based on F, and R-
 factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0647P)²+40.8556P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8017
_refine_ls_number_parameters     274
_refine_ls_number_restraints     4
_refine_ls_R_factor_all          0.0559
_refine_ls_R_factor_gt           0.0507
_refine_ls_wR_factor_ref         0.1278
_refine_ls_wR_factor_gt          0.1241
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_restrained_S_all      1.099
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
S1 S 0.2393(2) 0.48988(12) 0.0095(2) 0.0205(5) Uani 1 1 d . . .
O1 O 0.2453(7) 0.4442(4) 0.0944(7) 0.0303(19) Uani 1 1 d . . .
N1 N 0.5966(8) 0.6888(4) 0.0755(8) 0.0223(19) Uani 1 1 d . . .
H1A H 0.6041 0.7096 0.0155 0.034 Uiso 1 1 calc R . .
H1B H 0.6646 0.6742 0.1041 0.034 Uiso 1 1 calc R . .
H1C H 0.5683 0.7171 0.1193 0.034 Uiso 1 1 calc R . .
C1 C 0.3608(8) 0.5391(5) 0.0255(8) 0.0153(18) Uani 1 1 d . . .
O2 O 0.2231(8) 0.4653(4) -0.0949(7) 0.0316(19) Uani 1 1 d . . .
C2 C 0.3858(10) 0.5761(5) -0.0595(8) 0.021(2) Uani 1 1 d . . .
H2A H 0.3473 0.5688 -0.1260 0.025 Uiso 1 1 calc R . .
N2 N -0.0720(9) 0.7117(5) 0.0502(9) 0.031(2) Uani 1 1 d . . .
H2B H -0.1087 0.7224 -0.0122 0.046 Uiso 1 1 calc R . .
H2C H -0.0280 0.7459 0.0747 0.046 Uiso 1 1 calc R . .
H2D H -0.1225 0.7029 0.0946 0.046 Uiso 1 1 calc R . .
C3 C 0.4683(9) 0.6235(5) -0.0431(8) 0.021(2) Uani 1 1 d . . .
H3A H 0.4887 0.6490 -0.0985 0.026 Uiso 1 1 calc R . .
C4 C 0.5202(8) 0.6329(5) 0.0555(8) 0.0151(18) Uani 1 1 d . . .
C5 C 0.4979(8) 0.5949(5) 0.1371(8) 0.0164(19) Uani 1 1 d . . .
H5A H 0.5379 0.6017 0.2032 0.020 Uiso 1 1 calc R . .
C6 C 0.4179(8) 0.5473(5) 0.1223(8) 0.020(2) Uani 1 1 d . . .
H6A H 0.4018 0.5203 0.1777 0.024 Uiso 1 1 calc R . .
C7 C 0.1379(9) 0.5493(5) 0.0222(7) 0.0174(19) Uani 1 1 d . . .
C8 C 0.1289(10) 0.5771(6) 0.1188(8) 0.024(2) Uani 1 1 d . . .
H8A H 0.1702 0.5592 0.1785 0.029 Uiso 1 1 calc R . .
C9 C 0.0599(10) 0.6307(6) 0.1271(9) 0.026(2) Uani 1 1 d . . .
H9A H 0.0557 0.6508 0.1918 0.032 Uiso 1 1 calc R . .
C10 C -0.0022(9) 0.6541(5) 0.0401(9) 0.022(2) Uani 1 1 d . . .
C11 C 0.0026(10) 0.6265(5) -0.0554(9) 0.024(2) Uani 1 1 d . . .
H11A H -0.0425 0.6435 -0.1137 0.029 Uiso 1 1 calc R . .
C12 C 0.0734(9) 0.5742(5) -0.0658(8) 0.021(2) Uani 1 1 d . . .
H12A H 0.0783 0.5554 -0.1313 0.026 Uiso 1 1 calc R . .
Bi1 Bi 0.23279(3) 0.360733(18) 0.45374(3) 0.01637(10) Uani 1 1 d . . .
Bi2 Bi 0.15858(3) 0.577374(17) 0.51928(3) 0.01469(10) Uani 1 1 d . . .
I3 I -0.01873(5) 0.67950(3) 0.41443(5) 0.01700(14) Uani 1 1 d . . .
I4 I 0.05302(6) 0.47035(3) 0.34747(5) 0.01759(14) Uani 1 1 d . . .
I5 I 0.30855(6) 0.47437(3) 0.62335(5) 0.02330(16) Uani 1 1 d . . .
I6 I 0.14432(7) 0.25598(4) 0.31426(5) 0.02599(17) Uani 1 1 d . . .
I7 I 0.23507(6) 0.66832(3) 0.68529(5) 0.02107(15) Uani 1 1 d . . .
I8 I 0.36359(6) 0.27836(3) 0.60430(5) 0.02223(15) Uani 1 1 d . . .
I9 I 0.32136(6) 0.62037(4) 0.38963(5) 0.02407(16) Uani 1 1 d . . .
I10 I 0.42185(7) 0.37991(5) 0.33738(6) 0.03194(19) Uani 1 1 d . . .
O1W O 0.2048(7) 0.3469(4) 0.8102(6) 0.0221(15) Uani 1 1 d D . .
O2W O 0.2696(8) 0.3059(4) 0.0885(6) 0.0275(18) Uani 1 1 d D . .
H11 H 0.247(11) 0.317(5) 0.827(12) 0.041 Uiso 1 1 d D . .
H12 H 0.206(13) 0.3863(17) 0.821(12) 0.041 Uiso 1 1 d D . .
H21 H 0.277(13) 0.286(7) 0.143(6) 0.041 Uiso 1 1 d D . .
H22 H 0.274(14) 0.3460(14) 0.094(12) 0.041 Uiso 1 1 d D . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
S1 O1 1.449(9) . ?
S1 O2 1.451(9) . ?
S1 C7 1.744(11) . ?
S1 C1 1.767(10) . ?
N1 C4 1.469(13) . ?
N1 H1A 0.9100 . ?
N1 H1B 0.9100 . ?
N1 H1C 0.9100 . ?
C1 C6 1.382(14) . ?
C1 C2 1.410(14) . ?
C2 C3 1.386(15) . ?
C2 H2A 0.9500 . ?
N2 C10 1.462(15) . ?
N2 H2B 0.9100 . ?
N2 H2C 0.9100 . ?
N2 H2D 0.9100 . ?
C3 C4 1.382(14) . ?
C3 H3A 0.9500 . ?
C4 C5 1.376(14) . ?
C5 C6 1.368(14) . ?
C5 H5A 0.9500 . ?
C6 H6A 0.9500 . ?
C7 C8 1.406(14) . ?
C7 C12 1.408(14) . ?
C8 C9 1.386(17) . ?
C8 H8A 0.9500 . ?
C9 C10 1.376(16) . ?
C9 H9A 0.9500 . ?
C10 C11 1.381(16) . ?
C11 C12 1.385(16) . ?
C11 H11A 0.9500 . ?
C12 H12A 0.9500 . ?
Bi1 I8 2.9118(8) . ?
Bi1 I10 2.9168(9) . ?
Bi1 I6 2.9335(8) . ?
Bi1 I5 3.2710(8) . ?
Bi1 I4 3.3062(8) . ?
Bi1 I3 3.3750(8) 3_566 ?
Bi2 I9 2.8835(8) . ?
Bi2 I7 2.9281(8) . ?
Bi2 I5 2.9950(8) . ?
Bi2 I3 3.1793(8) . ?
Bi2 I4 3.2869(8) . ?
Bi2 I4 3.4025(8) 3_566 ?
I3 Bi1 3.3750(8) 3_566 ?
I4 Bi2 3.4025(8) 3_566 ?
O1W H11 0.81(2) . ?
O1W H12 0.82(2) . ?
O2W H21 0.82(2) . ?
O2W H22 0.82(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 S1 O2 119.5(5) . . ?
O1 S1 C7 110.2(5) . . ?
O2 S1 C7 108.4(5) . . ?
O1 S1 C1 108.1(5) . . ?
O2 S1 C1 109.0(5) . . ?
C7 S1 C1 99.9(5) . . ?
C4 N1 H1A 109.5 . . ?
C4 N1 H1B 109.5 . . ?
H1A N1 H1B 109.5 . . ?
C4 N1 H1C 109.5 . . ?
H1A N1 H1C 109.5 . . ?
H1B N1 H1C 109.5 . . ?
C6 C1 C2 122.2(9) . . ?
C6 C1 S1 119.5(8) . . ?
C2 C1 S1 117.7(8) . . ?
C3 C2 C1 118.0(9) . . ?
C3 C2 H2A 121.0 . . ?
C1 C2 H2A 121.0 . . ?
C10 N2 H2B 109.5 . . ?
C10 N2 H2C 109.5 . . ?
H2B N2 H2C 109.5 . . ?
C10 N2 H2D 109.5 . . ?
H2B N2 H2D 109.5 . . ?
H2C N2 H2D 109.5 . . ?
C4 C3 C2 118.6(10) . . ?
C4 C3 H3A 120.7 . . ?
C2 C3 H3A 120.7 . . ?
C5 C4 C3 122.9(9) . . ?
C5 C4 N1 118.4(9) . . ?
C3 C4 N1 118.6(9) . . ?
C6 C5 C4 119.4(10) . . ?
C6 C5 H5A 120.3 . . ?
C4 C5 H5A 120.3 . . ?
C5 C6 C1 118.8(10) . . ?
C5 C6 H6A 120.6 . . ?
C1 C6 H6A 120.6 . . ?
C8 C7 C12 120.0(10) . . ?
C8 C7 S1 119.9(8) . . ?
C12 C7 S1 119.8(8) . . ?
C9 C8 C7 120.2(10) . . ?
C9 C8 H8A 119.9 . . ?
C7 C8 H8A 119.9 . . ?
C10 C9 C8 118.8(10) . . ?
C10 C9 H9A 120.6 . . ?
C8 C9 H9A 120.6 . . ?
C9 C10 C11 122.2(11) . . ?
C9 C10 N2 117.8(10) . . ?
C11 C10 N2 119.9(10) . . ?
C10 C11 C12 119.9(10) . . ?
C10 C11 H11A 120.0 . . ?
C12 C11 H11A 120.0 . . ?
C11 C12 C7 118.9(10) . . ?
C11 C12 H12A 120.5 . . ?
C7 C12 H12A 120.5 . . ?
I8 Bi1 I10 92.32(3) . . ?
I8 Bi1 I6 97.38(3) . . ?
I10 Bi1 I6 91.09(2) . . ?
I8 Bi1 I5 82.19(2) . . ?
I10 Bi1 I5 95.14(3) . . ?
I6 Bi1 I5 173.76(2) . . ?
I8 Bi1 I4 162.19(2) . . ?
I10 Bi1 I4 101.59(2) . . ?
I6 Bi1 I4 93.47(2) . . ?
I5 Bi1 I4 85.49(2) . . ?
I8 Bi1 I3 83.99(2) . 3_566 ?
I10 Bi1 I3 173.62(3) . 3_566 ?
I6 Bi1 I3 84.24(2) . 3_566 ?
I5 Bi1 I3 89.52(2) . 3_566 ?
I4 Bi1 I3 83.079(19) . 3_566 ?
I9 Bi2 I7 94.04(2) . . ?
I9 Bi2 I5 93.90(3) . . ?
I7 Bi2 I5 89.30(2) . . ?
I9 Bi2 I3 90.76(2) . . ?
I7 Bi2 I3 92.34(2) . . ?
I5 Bi2 I3 174.94(2) . . ?
I9 Bi2 I4 91.84(2) . . ?
I7 Bi2 I4 174.12(2) . . ?
I5 Bi2 I4 90.46(2) . . ?
I3 Bi2 I4 87.42(2) . . ?
I9 Bi2 I4 174.37(2) . 3_566 ?
I7 Bi2 I4 89.28(2) . 3_566 ?
I5 Bi2 I4 90.68(2) . 3_566 ?
I3 Bi2 I4 84.56(2) . 3_566 ?
I4 Bi2 I4 84.845(19) . 3_566 ?
Bi2 I3 Bi1 97.63(2) . 3_566 ?
Bi2 I4 Bi1 88.927(19) . . ?
Bi2 I4 Bi2 95.155(19) . 3_566 ?
Bi1 I4 Bi2 94.696(19) . 3_566 ?
Bi2 I5 Bi1 94.85(2) . . ?
H11 O1W H12 134(10) . . ?
H21 O2W H22 114(10) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 S1 C1 C6 -23.9(10) . . . . ?
O2 S1 C1 C6 -155.2(8) . . . . ?
C7 S1 C1 C6 91.4(9) . . . . ?
O1 S1 C1 C2 165.3(8) . . . . ?
O2 S1 C1 C2 34.0(10) . . . . ?
C7 S1 C1 C2 -79.5(9) . . . . ?
C6 C1 C2 C3 -2.1(16) . . . . ?
S1 C1 C2 C3 168.5(8) . . . . ?
C1 C2 C3 C4 -1.2(16) . . . . ?
C2 C3 C4 C5 3.7(16) . . . . ?
C2 C3 C4 N1 -171.9(10) . . . . ?
C3 C4 C5 C6 -2.8(16) . . . . ?
N1 C4 C5 C6 172.8(9) . . . . ?
C4 C5 C6 C1 -0.5(15) . . . . ?
C2 C1 C6 C5 3.0(15) . . . . ?
S1 C1 C6 C5 -167.4(8) . . . . ?
O1 S1 C7 C8 42.1(10) . . . . ?
O2 S1 C7 C8 174.5(9) . . . . ?
C1 S1 C7 C8 -71.6(9) . . . . ?
O1 S1 C7 C12 -144.6(8) . . . . ?
O2 S1 C7 C12 -12.1(10) . . . . ?
C1 S1 C7 C12 101.8(9) . . . . ?
C12 C7 C8 C9 -2.5(16) . . . . ?
S1 C7 C8 C9 170.8(9) . . . . ?
C7 C8 C9 C10 2.5(17) . . . . ?
C8 C9 C10 C11 -0.6(17) . . . . ?
C8 C9 C10 N2 -178.3(10) . . . . ?
C9 C10 C11 C12 -1.2(17) . . . . ?
N2 C10 C11 C12 176.4(10) . . . . ?
C10 C11 C12 C7 1.1(16) . . . . ?
C8 C7 C12 C11 0.7(16) . . . . ?
S1 C7 C12 C11 -172.6(8) . . . . ?
I9 Bi2 I3 Bi1 178.30(2) . . . 3_566 ?
I7 Bi2 I3 Bi1 -87.63(2) . . . 3_566 ?
I5 Bi2 I3 Bi1 21.2(2) . . . 3_566 ?
I4 Bi2 I3 Bi1 86.49(2) . . . 3_566 ?
I4 Bi2 I3 Bi1 1.427(17) 3_566 . . 3_566 ?
I9 Bi2 I4 Bi1 89.94(2) . . . . ?
I7 Bi2 I4 Bi1 -91.5(2) . . . . ?
I5 Bi2 I4 Bi1 -3.97(2) . . . . ?
I3 Bi2 I4 Bi1 -179.380(19) . . . . ?
I4 Bi2 I4 Bi1 -94.619(19) 3_566 . . . ?
I9 Bi2 I4 Bi2 -175.44(2) . . . 3_566 ?
I7 Bi2 I4 Bi2 3.1(2) . . . 3_566 ?
I5 Bi2 I4 Bi2 90.64(2) . . . 3_566 ?
I3 Bi2 I4 Bi2 -84.76(2) . . . 3_566 ?
I4 Bi2 I4 Bi2 0.0 3_566 . . 3_566 ?
I8 Bi1 I4 Bi2 49.95(8) . . . . ?
I10 Bi1 I4 Bi2 -90.69(2) . . . . ?
I6 Bi1 I4 Bi2 177.48(2) . . . . ?
I5 Bi1 I4 Bi2 3.650(19) . . . . ?
I3 Bi1 I4 Bi2 93.717(19) 3_566 . . . ?
I8 Bi1 I4 Bi2 -45.13(8) . . . 3_566 ?
I10 Bi1 I4 Bi2 174.23(2) . . . 3_566 ?
I6 Bi1 I4 Bi2 82.40(2) . . . 3_566 ?
I5 Bi1 I4 Bi2 -91.44(2) . . . 3_566 ?
I3 Bi1 I4 Bi2 -1.368(17) 3_566 . . 3_566 ?
I9 Bi2 I5 Bi1 -87.85(2) . . . . ?
I7 Bi2 I5 Bi1 178.15(2) . . . . ?
I3 Bi2 I5 Bi1 69.2(2) . . . . ?
I4 Bi2 I5 Bi1 4.03(2) . . . . ?
I4 Bi2 I5 Bi1 88.88(2) 3_566 . . . ?
I8 Bi1 I5 Bi2 -171.12(3) . . . . ?
I10 Bi1 I5 Bi2 97.24(3) . . . . ?
I6 Bi1 I5 Bi2 -84.7(2) . . . . ?
I4 Bi1 I5 Bi2 -4.02(2) . . . . ?
I3 Bi1 I5 Bi2 -87.11(2) 3_566 . . . ?

_diffrn_measured_fraction_theta_max 0.980
_diffrn_reflns_theta_full        28.54
_diffrn_measured_fraction_theta_full 0.980
_refine_diff_density_max         7.224
_refine_diff_density_min         -2.722
_refine_diff_density_rms         0.417
