# Electronic Supplementary Material (ESI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2035795'
loop_
_audit_author_name
_audit_author_address
'Jianxin Ma'
;Bohai university
China
;
_audit_update_record             
;
2020-10-07 deposited with the CCDC.	2020-11-16 downloaded from the CCDC.
;
_audit_creation_date             2020-10-06
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.02.04 svn.rd84adfe8 for OlexSys, GUI svn.r6032)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H27 Ag N4 O11, H2 O'
_chemical_formula_sum            'C32 H29 Ag N4 O12'
_chemical_formula_weight         769.46
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.492(6)
_cell_length_b                   13.445(6)
_cell_length_c                   13.518(6)
_cell_angle_alpha                83.690(9)
_cell_angle_beta                 86.778(9)
_cell_angle_gamma                85.131(6)
_cell_volume                     1526.8(14)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    1899
_cell_measurement_temperature    296.15
_cell_measurement_theta_max      50.000
_cell_measurement_theta_min      1.953
_shelx_estimated_absorpt_T_max   0.54
_shelx_estimated_absorpt_T_min   0.21
_exptl_absorpt_coefficient_mu    0.735
_exptl_absorpt_correction_T_max  0.87
_exptl_absorpt_correction_T_min  0.86
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Krause et al., 2015) was used for absorption correction.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    green
_exptl_crystal_density_diffrn    1.674
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             784
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0529
_diffrn_reflns_av_unetI/netI     0.1154
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8525
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.278
_diffrn_reflns_theta_min         1.517
_diffrn_ambient_temperature      296.15
_diffrn_detector                 'charge-coupled device (CCD) area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker APEX II'
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       '0.5° ω and 0.5° φ scans'
_diffrn_radiation_collimation    'focusing mirrors'
_diffrn_radiation_detector       'Bruker APEX II'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_xray_symbol    K-L~3~
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.2
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           40.0
_diffrn_standards_number         .
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                2715
_reflns_number_total             5472
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT+ Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_collection       'APEX3 Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT+ Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_molecular_graphics    'OLEX2 (Dolomanov et al., 2009)'
_computing_publication_material  'OLEX2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2015b)'
_computing_structure_solution    'XT (Sheldrick, 2015a)'
_refine_diff_density_max         1.841
_refine_diff_density_min         -0.851
_refine_diff_density_rms         0.141
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.981
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         5472
_refine_ls_number_restraints     16
_refine_ls_R_factor_all          0.1548
_refine_ls_R_factor_gt           0.0842
_refine_ls_restrained_S_all      0.982
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1635P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2376
_refine_ls_wR_factor_ref         0.2803
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H) groups
 At 1.5 times of:
  All O(H) groups, All O(H,H) groups
2. Restrained distances
 C32-C29
 1.55 with sigma of 0.01
 C10-C15
 1.5 with sigma of 0.01
 C4-H4B
 1 with sigma of 0.02
 H12A-H30B_$1
 2.3 with sigma of 0.04
3. Uiso/Uaniso restraints and constraints
Uanis(C1) \\sim Ueq, Uanis(C33) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.01
4. Others
 Fixed Sof: C1(0.6) H1(0.6) H5A(0.6) H5B(0.4) C33(0.4) H33(0.4)
5.a Free rotating group:
 O12(H12A,H12B)
5.b Secondary CH2 refined with riding coordinates:
 C29(H29A,H29B), C30(H30A,H30B), C31(H31A,H31B), C32(H32A,H32B)
5.c Aromatic/amide H refined with riding coordinates:
 N3(H3), N4(H4A), C1(H1), C5(H5A), C5(H5B), C9(H9), C13(H13), C17(H17),
 C19(H19), C20(H20), C21(H21), C22(H22), C25(H25), C26(H26), C27(H27), C33(H33)
5.d Tetrahedral OH refined with riding coordinates:
 O8(H8), O5(H5), O4(H4)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.64202(11) 0.86266(7) 0.54994(6) 0.0722(4) Uani 1 1 d . . . . .
O7 O 0.6768(8) 0.9513(5) 0.2134(5) 0.0531(16) Uani 1 1 d . . . . .
O6 O 0.8787(9) 0.6398(5) -0.4204(4) 0.0636(19) Uani 1 1 d . . . . .
O9 O 0.7882(9) 0.7094(5) -0.0784(4) 0.0618(19) Uani 1 1 d . . . . .
O8 O 0.4780(8) 0.8579(5) 0.2426(5) 0.0640(19) Uani 1 1 d . . . . .
H8 H 0.467851 0.797724 0.255763 0.096 Uiso 1 1 calc R U . . .
O11 O 0.1635(9) 1.1198(5) 1.2862(5) 0.0639(19) Uani 1 1 d . . . . .
O1 O 0.7431(11) 0.7810(6) 0.3798(5) 0.073(2) Uani 1 1 d . . . . .
O5 O 0.8008(11) 0.4967(6) -0.4400(5) 0.084(3) Uani 1 1 d . . . . .
H5 H 0.796507 0.521457 -0.498113 0.126 Uiso 1 1 calc R U . . .
O2 O 0.8952(10) 0.6395(6) 0.3822(5) 0.076(2) Uani 1 1 d . . . . .
O3 O 0.5996(12) 0.3078(7) -0.2041(6) 0.094(3) Uani 1 1 d . . . . .
O4 O 0.6795(13) 0.3588(6) -0.3531(6) 0.100(3) Uani 1 1 d . . . . .
H4 H 0.738222 0.400451 -0.379367 0.150 Uiso 1 1 calc R U . . .
O10 O 0.1609(12) 0.6217(7) 0.8786(7) 0.106(3) Uani 1 1 d . . . . .
N2 N -0.2602(10) 1.0017(6) 1.4938(5) 0.054(2) Uani 1 1 d . . . . .
N3 N 0.0065(11) 1.0209(7) 1.2232(6) 0.066(2) Uani 1 1 d . . . . .
H3 H -0.084349 0.996597 1.227404 0.079 Uiso 1 1 calc R U . . .
N4 N 0.2896(13) 0.7553(9) 0.8972(7) 0.087(3) Uani 1 1 d . . . . .
H4A H 0.365577 0.791900 0.876751 0.104 Uiso 1 1 calc R U . . .
C1 C 0.485(3) 0.6708(18) 0.5651(18) 0.039(6) Uani 0.6 1 d . U P A 1
H1 H 0.536306 0.667232 0.502969 0.047 Uiso 0.6 1 calc R U P A 1
N1 N 0.5020(9) 0.7450(7) 0.6103(5) 0.054(2) Uani 1 1 d . . . . .
C2 C 0.4338(12) 0.7478(9) 0.7026(7) 0.059(3) Uani 1 1 d . . . . .
H2 H 0.446(12) 0.814(8) 0.730(7) 0.071 Uiso 1 1 d . U . . .
C3 C 0.3416(11) 0.6741(9) 0.7464(7) 0.060(3) Uani 1 1 d . . . . .
C4 C 0.3186(15) 0.5931(10) 0.6965(10) 0.074(3) Uani 1 1 d D . . . .
H4B H 0.260(12) 0.536(6) 0.731(7) 0.089 Uiso 1 1 d D U . . .
C5 C 0.3887(17) 0.5899(10) 0.6042(9) 0.085(4) Uani 1 1 d . . . . .
H5A H 0.375561 0.537323 0.566909 0.102 Uiso 0.6 1 calc R U P A 1
H5B H 0.389223 0.528954 0.577649 0.102 Uiso 0.4 1 calc R U P A 2
C6 C 0.6223(10) 0.8711(6) 0.2135(6) 0.039(2) Uani 1 1 d . . . . .
C7 C 0.8070(10) 0.7105(7) 0.2272(6) 0.041(2) Uani 1 1 d . . . . .
C8 C 0.6981(10) 0.4664(7) -0.2245(6) 0.043(2) Uani 1 1 d . . . . .
C9 C -0.1644(11) 1.0033(6) 1.4134(6) 0.043(2) Uani 1 1 d . . . . .
H9 H -0.157416 0.948232 1.376888 0.052 Uiso 1 1 calc R U . . .
C10 C 0.7728(10) 0.5479(6) -0.2751(5) 0.0387(19) Uani 1 1 d D . . . .
C11 C 0.7176(10) 0.7871(6) 0.1715(6) 0.039(2) Uani 1 1 d . . . . .
C12 C 0.8125(12) 0.7137(8) 0.3375(6) 0.048(2) Uani 1 1 d . . . . .
C13 C 0.8002(11) 0.6261(7) -0.2217(6) 0.049(2) Uani 1 1 d . . . . .
H13 H 0.847465 0.681176 -0.254473 0.058 Uiso 1 1 calc R U . . .
C14 C 0.7595(11) 0.6253(7) -0.1209(6) 0.046(2) Uani 1 1 d . . . . .
C15 C 0.8221(11) 0.5649(7) -0.3845(5) 0.047(2) Uani 1 1 d D . . . .
C16 C -0.0745(11) 1.0816(7) 1.3808(6) 0.047(2) Uani 1 1 d . . . . .
C17 C 0.8919(11) 0.6353(7) 0.1813(6) 0.048(2) Uani 1 1 d . . . . .
H17 H 0.954181 0.586331 0.218529 0.057 Uiso 1 1 calc R U . . .
C18 C 0.7937(12) 0.7054(7) 0.0253(6) 0.048(2) Uani 1 1 d . . . . .
C19 C 0.6874(12) 0.5476(7) -0.0718(7) 0.053(2) Uani 1 1 d . . . . .
H19 H 0.658881 0.546680 -0.004341 0.063 Uiso 1 1 calc R U . . .
C20 C 0.8848(12) 0.6326(7) 0.0801(7) 0.054(2) Uani 1 1 d . . . . .
H20 H 0.941658 0.581596 0.048966 0.065 Uiso 1 1 calc R U . . .
C21 C 0.7106(11) 0.7825(7) 0.0687(6) 0.045(2) Uani 1 1 d . . . . .
H21 H 0.649875 0.831360 0.030296 0.054 Uiso 1 1 calc R U . . .
C22 C -0.0803(13) 1.1635(7) 1.4352(8) 0.060(3) Uani 1 1 d . . . . .
H22 H -0.018504 1.216834 1.415912 0.072 Uiso 1 1 calc R U . . .
C23 C 0.6552(13) 0.3706(8) -0.2628(8) 0.059(3) Uani 1 1 d . . . . .
C24 C 0.0415(12) 1.0763(7) 1.2925(7) 0.054(2) Uani 1 1 d . . . . .
C25 C 0.6577(12) 0.4712(8) -0.1232(7) 0.060(3) Uani 1 1 d . . . . .
H25 H 0.607072 0.418108 -0.088993 0.071 Uiso 1 1 calc R U . . .
C26 C -0.2615(15) 1.0820(8) 1.5471(7) 0.068(3) Uani 1 1 d . . . . .
H26 H -0.321958 1.080691 1.606707 0.082 Uiso 1 1 calc R U . . .
C27 C -0.1809(15) 1.1632(9) 1.5189(8) 0.070(3) Uani 1 1 d . . . . .
H27 H -0.192793 1.218347 1.555430 0.085 Uiso 1 1 calc R U . . .
C28 C 0.2585(14) 0.6779(9) 0.8471(9) 0.072(3) Uani 1 1 d . . . . .
C29 C 0.2172(14) 0.8770(9) 1.0184(8) 0.077(3) Uani 1 1 d D . . . .
H29A H 0.195073 0.928629 0.963841 0.093 Uiso 1 1 calc R U . . .
H29B H 0.326720 0.878749 1.034561 0.093 Uiso 1 1 calc R U . . .
C30 C 0.1175(16) 0.9991(10) 1.1385(8) 0.084(4) Uani 1 1 d . . . . .
H30A H 0.094084 1.048164 1.082064 0.101 Uiso 1 1 calc R U . . .
H30B H 0.224433 1.006439 1.156742 0.101 Uiso 1 1 calc R U . . .
C31 C 0.1098(15) 0.8984(10) 1.1085(9) 0.081(4) Uani 1 1 d . . . . .
H31A H 0.001572 0.889933 1.093746 0.097 Uiso 1 1 calc R U . . .
H31B H 0.138399 0.849369 1.164035 0.097 Uiso 1 1 calc R U . . .
C32 C 0.192(2) 0.7760(10) 0.9866(9) 0.110(5) Uani 1 1 d D . . . .
H32A H 0.218763 0.724356 1.040407 0.132 Uiso 1 1 calc R U . . .
H32B H 0.081817 0.773434 0.973581 0.132 Uiso 1 1 calc R U . . .
O12 O 0.4514(11) 1.1115(7) 0.1501(7) 0.089(2) Uani 1 1 d G . . . .
H12A H 0.376988 1.129478 0.190672 0.134 Uiso 1 1 d DG U . . .
H12B H 0.478989 1.051081 0.171609 0.134 Uiso 1 1 d G U . . .
C33 C 0.450(4) 0.655(3) 0.552(3) 0.029(8) Uani 0.4 1 d . U P A 2
H33 H 0.466560 0.654158 0.483665 0.035 Uiso 0.4 1 calc R U P A 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.721(7) . ?
Ag1 N2 2.155(8) 1_654 ?
Ag1 N1 2.123(8) . ?
O7 C6 1.210(10) . ?
O6 C15 1.196(11) . ?
O9 C14 1.369(11) . ?
O9 C18 1.400(10) . ?
O8 H8 0.8200 . ?
O8 C6 1.286(10) . ?
O11 C24 1.226(11) . ?
O1 C12 1.216(12) . ?
O5 H5 0.8200 . ?
O5 C15 1.279(11) . ?
O2 C12 1.284(12) . ?
O3 C23 1.201(12) . ?
O4 H4 0.8200 . ?
O4 C23 1.253(12) . ?
O10 C28 1.197(13) . ?
N2 C9 1.319(11) . ?
N2 C26 1.361(13) . ?
N3 H3 0.8600 . ?
N3 C24 1.320(12) . ?
N3 C30 1.480(13) . ?
N4 H4A 0.8600 . ?
N4 C28 1.355(15) . ?
N4 C32 1.463(14) . ?
C1 H1 0.9300 . ?
C1 N1 1.25(2) . ?
C1 C5 1.45(3) . ?
N1 C2 1.348(12) . ?
N1 C33 1.62(3) . ?
C2 H2 1.02(11) . ?
C2 C3 1.378(14) . ?
C3 C4 1.374(16) . ?
C3 C28 1.502(15) . ?
C4 H4B 1.00(2) . ?
C4 C5 1.356(17) . ?
C5 H5A 0.9300 . ?
C5 H5B 0.9300 . ?
C5 C33 1.20(3) . ?
C6 C11 1.478(12) . ?
C7 C11 1.403(12) . ?
C7 C12 1.500(12) . ?
C7 C17 1.375(13) . ?
C8 C10 1.406(12) . ?
C8 C23 1.519(13) . ?
C8 C25 1.400(13) . ?
C9 H9 0.9300 . ?
C9 C16 1.372(12) . ?
C10 C13 1.380(12) . ?
C10 C15 1.512(8) . ?
C11 C21 1.402(11) . ?
C13 H13 0.9300 . ?
C13 C14 1.386(12) . ?
C14 C19 1.347(13) . ?
C16 C22 1.386(13) . ?
C16 C24 1.508(13) . ?
C17 H17 0.9300 . ?
C17 C20 1.377(12) . ?
C18 C20 1.372(13) . ?
C18 C21 1.371(13) . ?
C19 H19 0.9300 . ?
C19 C25 1.350(14) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C22 C27 1.379(16) . ?
C25 H25 0.9300 . ?
C26 H26 0.9300 . ?
C26 C27 1.346(16) . ?
C27 H27 0.9300 . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C29 C31 1.519(15) . ?
C29 C32 1.504(9) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C30 C31 1.464(16) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
O12 H12A 0.8503 . ?
O12 H12B 0.8499 . ?
C33 H33 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 O1 90.6(3) 1_654 . ?
N1 Ag1 O1 96.7(3) . . ?
N1 Ag1 N2 168.1(3) . 1_654 ?
C14 O9 C18 119.8(7) . . ?
C6 O8 H8 109.5 . . ?
C12 O1 Ag1 150.7(6) . . ?
C15 O5 H5 109.5 . . ?
C23 O4 H4 109.5 . . ?
C9 N2 Ag1 118.6(6) . 1_456 ?
C9 N2 C26 116.1(9) . . ?
C26 N2 Ag1 123.7(7) . 1_456 ?
C24 N3 H3 118.7 . . ?
C24 N3 C30 122.6(9) . . ?
C30 N3 H3 118.7 . . ?
C28 N4 H4A 120.4 . . ?
C28 N4 C32 119.3(10) . . ?
C32 N4 H4A 120.4 . . ?
N1 C1 H1 118.2 . . ?
N1 C1 C5 124(2) . . ?
C5 C1 H1 118.2 . . ?
C1 N1 Ag1 122.5(12) . . ?
C1 N1 C2 118.2(13) . . ?
C2 N1 Ag1 119.2(7) . . ?
C2 N1 C33 114.0(14) . . ?
C33 N1 Ag1 126.4(13) . . ?
N1 C2 H2 112(6) . . ?
N1 C2 C3 122.3(10) . . ?
C3 C2 H2 125(6) . . ?
C2 C3 C28 123.3(10) . . ?
C4 C3 C2 120.1(10) . . ?
C4 C3 C28 116.6(10) . . ?
C3 C4 H4B 120(7) . . ?
C5 C4 C3 117.5(11) . . ?
C5 C4 H4B 122(7) . . ?
C1 C5 H5A 120.9 . . ?
C4 C5 C1 118.2(14) . . ?
C4 C5 H5A 120.9 . . ?
C4 C5 H5B 115.6 . . ?
C33 C5 C4 129(2) . . ?
C33 C5 H5B 115.6 . . ?
O7 C6 O8 121.8(8) . . ?
O7 C6 C11 120.0(8) . . ?
O8 C6 C11 118.0(8) . . ?
C11 C7 C12 118.8(8) . . ?
C17 C7 C11 120.6(8) . . ?
C17 C7 C12 120.5(8) . . ?
C10 C8 C23 129.6(8) . . ?
C25 C8 C10 116.9(8) . . ?
C25 C8 C23 113.4(9) . . ?
N2 C9 H9 118.2 . . ?
N2 C9 C16 123.6(8) . . ?
C16 C9 H9 118.2 . . ?
C8 C10 C15 128.2(7) . . ?
C13 C10 C8 117.9(7) . . ?
C13 C10 C15 113.8(8) . . ?
C7 C11 C6 124.9(7) . . ?
C21 C11 C6 116.6(8) . . ?
C21 C11 C7 118.4(8) . . ?
O1 C12 O2 123.8(8) . . ?
O1 C12 C7 122.0(9) . . ?
O2 C12 C7 114.2(9) . . ?
C10 C13 H13 118.9 . . ?
C10 C13 C14 122.3(8) . . ?
C14 C13 H13 118.9 . . ?
O9 C14 C13 115.9(8) . . ?
C19 C14 O9 123.7(8) . . ?
C19 C14 C13 120.2(8) . . ?
O6 C15 O5 119.3(7) . . ?
O6 C15 C10 122.4(8) . . ?
O5 C15 C10 118.3(8) . . ?
C9 C16 C22 119.2(9) . . ?
C9 C16 C24 121.3(8) . . ?
C22 C16 C24 119.2(9) . . ?
C7 C17 H17 120.0 . . ?
C7 C17 C20 120.0(9) . . ?
C20 C17 H17 120.0 . . ?
C20 C18 O9 122.3(9) . . ?
C21 C18 O9 116.1(8) . . ?
C21 C18 C20 121.5(8) . . ?
C14 C19 H19 120.8 . . ?
C14 C19 C25 118.3(9) . . ?
C25 C19 H19 120.8 . . ?
C17 C20 H20 120.1 . . ?
C18 C20 C17 119.8(9) . . ?
C18 C20 H20 120.1 . . ?
C11 C21 H21 120.2 . . ?
C18 C21 C11 119.6(8) . . ?
C18 C21 H21 120.2 . . ?
C16 C22 H22 121.1 . . ?
C27 C22 C16 117.7(10) . . ?
C27 C22 H22 121.1 . . ?
O3 C23 O4 122.0(10) . . ?
O3 C23 C8 118.2(9) . . ?
O4 C23 C8 119.8(10) . . ?
O11 C24 N3 121.6(9) . . ?
O11 C24 C16 121.8(8) . . ?
N3 C24 C16 116.6(9) . . ?
C8 C25 H25 117.8 . . ?
C19 C25 C8 124.4(9) . . ?
C19 C25 H25 117.8 . . ?
N2 C26 H26 118.0 . . ?
C27 C26 N2 124.1(10) . . ?
C27 C26 H26 118.0 . . ?
C22 C27 H27 120.5 . . ?
C26 C27 C22 119.1(10) . . ?
C26 C27 H27 120.5 . . ?
O10 C28 N4 121.2(11) . . ?
O10 C28 C3 122.9(11) . . ?
N4 C28 C3 115.7(9) . . ?
H29A C29 H29B 108.1 . . ?
C31 C29 H29A 109.5 . . ?
C31 C29 H29B 109.5 . . ?
C32 C29 H29A 109.5 . . ?
C32 C29 H29B 109.5 . . ?
C32 C29 C31 110.8(9) . . ?
N3 C30 H30A 108.9 . . ?
N3 C30 H30B 108.9 . . ?
H30A C30 H30B 107.7 . . ?
C31 C30 N3 113.4(9) . . ?
C31 C30 H30A 108.9 . . ?
C31 C30 H30B 108.9 . . ?
C29 C31 H31A 108.8 . . ?
C29 C31 H31B 108.8 . . ?
C30 C31 C29 113.8(10) . . ?
C30 C31 H31A 108.8 . . ?
C30 C31 H31B 108.8 . . ?
H31A C31 H31B 107.7 . . ?
N4 C32 C29 111.9(10) . . ?
N4 C32 H32A 109.2 . . ?
N4 C32 H32B 109.2 . . ?
C29 C32 H32A 109.2 . . ?
C29 C32 H32B 109.2 . . ?
H32A C32 H32B 107.9 . . ?
H12A O12 H12B 104.5 . . ?
N1 C33 H33 122.6 . . ?
C5 C33 N1 115(3) . . ?
C5 C33 H33 122.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 O1 C12 O2 -8(2) . . . . ?
Ag1 O1 C12 C7 171.7(9) . . . . ?
Ag1 N2 C9 C16 -168.5(7) 1_456 . . . ?
Ag1 N2 C26 C27 169.7(8) 1_456 . . . ?
Ag1 N1 C2 C3 -179.9(8) . . . . ?
Ag1 N1 C33 C5 170.6(16) . . . . ?
O7 C6 C11 C7 96.6(11) . . . . ?
O7 C6 C11 C21 -86.6(10) . . . . ?
O9 C14 C19 C25 176.3(9) . . . . ?
O9 C18 C20 C17 176.7(9) . . . . ?
O9 C18 C21 C11 -176.3(8) . . . . ?
O8 C6 C11 C7 -88.5(11) . . . . ?
O8 C6 C11 C21 88.3(10) . . . . ?
N2 C9 C16 C22 1.4(14) . . . . ?
N2 C9 C16 C24 175.7(8) . . . . ?
N2 C26 C27 C22 -5.3(17) . . . . ?
N3 C30 C31 C29 177.1(11) . . . . ?
C1 N1 C2 C3 -2.6(19) . . . . ?
N1 C1 C5 C4 -3(3) . . . . ?
N1 C2 C3 C4 1.1(16) . . . . ?
N1 C2 C3 C28 -177.1(10) . . . . ?
C2 N1 C33 C5 -16(3) . . . . ?
C2 C3 C4 C5 -0.4(17) . . . . ?
C2 C3 C28 O10 168.9(12) . . . . ?
C2 C3 C28 N4 -5.2(17) . . . . ?
C3 C4 C5 C1 1(2) . . . . ?
C3 C4 C5 C33 -12(3) . . . . ?
C4 C3 C28 O10 -9.4(18) . . . . ?
C4 C3 C28 N4 176.5(11) . . . . ?
C4 C5 C33 N1 20(4) . . . . ?
C5 C1 N1 Ag1 -179.4(13) . . . . ?
C5 C1 N1 C2 3(3) . . . . ?
C6 C11 C21 C18 -178.7(8) . . . . ?
C7 C11 C21 C18 -1.7(13) . . . . ?
C7 C17 C20 C18 0.4(15) . . . . ?
C8 C10 C13 C14 1.4(14) . . . . ?
C8 C10 C15 O6 176.5(9) . . . . ?
C8 C10 C15 O5 -3.0(15) . . . . ?
C9 N2 C26 C27 4.7(16) . . . . ?
C9 C16 C22 C27 -1.8(14) . . . . ?
C9 C16 C24 O11 -148.9(9) . . . . ?
C9 C16 C24 N3 29.9(13) . . . . ?
C10 C8 C23 O3 175.5(10) . . . . ?
C10 C8 C23 O4 -3.8(17) . . . . ?
C10 C8 C25 C19 -0.7(15) . . . . ?
C10 C13 C14 O9 -177.6(8) . . . . ?
C10 C13 C14 C19 -1.6(15) . . . . ?
C11 C7 C12 O1 -0.6(14) . . . . ?
C11 C7 C12 O2 178.9(8) . . . . ?
C11 C7 C17 C20 -2.6(14) . . . . ?
C12 C7 C11 C6 -2.0(13) . . . . ?
C12 C7 C11 C21 -178.8(8) . . . . ?
C12 C7 C17 C20 179.4(9) . . . . ?
C13 C10 C15 O6 -0.3(14) . . . . ?
C13 C10 C15 O5 -179.8(9) . . . . ?
C13 C14 C19 C25 0.6(15) . . . . ?
C14 O9 C18 C20 50.7(13) . . . . ?
C14 O9 C18 C21 -133.4(9) . . . . ?
C14 C19 C25 C8 0.6(16) . . . . ?
C15 C10 C13 C14 178.5(8) . . . . ?
C16 C22 C27 C26 3.6(15) . . . . ?
C17 C7 C11 C6 179.9(8) . . . . ?
C17 C7 C11 C21 3.2(12) . . . . ?
C17 C7 C12 O1 177.4(9) . . . . ?
C17 C7 C12 O2 -3.0(13) . . . . ?
C18 O9 C14 C13 -162.1(9) . . . . ?
C18 O9 C14 C19 22.0(14) . . . . ?
C20 C18 C21 C11 -0.3(14) . . . . ?
C21 C18 C20 C17 1.0(15) . . . . ?
C22 C16 C24 O11 25.4(14) . . . . ?
C22 C16 C24 N3 -155.8(9) . . . . ?
C23 C8 C10 C13 -179.1(9) . . . . ?
C23 C8 C10 C15 4.2(16) . . . . ?
C23 C8 C25 C19 178.3(10) . . . . ?
C24 N3 C30 C31 144.4(12) . . . . ?
C24 C16 C22 C27 -176.2(9) . . . . ?
C25 C8 C10 C13 -0.2(13) . . . . ?
C25 C8 C10 C15 -176.9(9) . . . . ?
C25 C8 C23 O3 -3.4(15) . . . . ?
C25 C8 C23 O4 177.2(11) . . . . ?
C26 N2 C9 C16 -2.6(14) . . . . ?
C28 N4 C32 C29 -166.5(13) . . . . ?
C28 C3 C4 C5 178.0(11) . . . . ?
C30 N3 C24 O11 6.1(17) . . . . ?
C30 N3 C24 C16 -172.7(9) . . . . ?
C31 C29 C32 N4 177.5(12) . . . . ?
C32 N4 C28 O10 -6(2) . . . . ?
C32 N4 C28 C3 168.6(11) . . . . ?
C32 C29 C31 C30 -175.0(13) . . . . ?
C33 N1 C2 C3 6.5(19) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
