# Electronic Supplementary Material (ESI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2021

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_spz0208
_database_code_depnum_ccdc_archive 'CCDC 2027312'
loop_
_audit_author_name
_audit_author_address
'Takanori Iwasaki'
;The University of Tokyo
Japan
;
_audit_update_record             
;
2020-09-04 deposited with the CCDC.	2021-01-04 downloaded from the CCDC.
;
_audit_creation_date             2020-06-08
_audit_creation_method           
;
Olex2 1.2-ac3
(compiled 2017.02.24 svn.r3390 for Rigaku Oxford Diffraction, GUI svn.r5318)
;
_shelx_SHELXL_version_number     2017/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C14 H19 N2 O2 Pt, C F3 O3 S'
_chemical_formula_sum            'C15 H19 F3 N2 O5 Pt S'
_chemical_formula_weight         591.47
_chemical_melting_point          ?
_chemical_oxdiff_formula         C15H20N2O2Pt1
_chemical_oxdiff_usercomment     '0.4 x 0.1 x 0.1 colorless block'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.3867(2)
_cell_length_b                   13.3132(3)
_cell_length_c                   12.4183(2)
_cell_angle_alpha                90
_cell_angle_beta                 92.717(2)
_cell_angle_gamma                90
_cell_volume                     1880.42(6)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    17474
_cell_measurement_temperature    123
_cell_measurement_theta_max      29.3150
_cell_measurement_theta_min      2.8190
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    7.631
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.39471
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.40.72a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.089
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1136
_exptl_crystal_recrystallization_method 'MeOH, THF, Et2O'
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0438
_diffrn_reflns_av_unetI/netI     0.0274
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.898
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            30286
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.898
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.260
_diffrn_reflns_theta_min         2.244
_diffrn_ambient_temperature      123
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 5.8140
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.898
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -93.00  47.00   0.50    0.50    --   -3.30  38.00 -92.00  280
  2  ω    -41.00   5.00   0.50    0.50    --    4.40  38.00 -92.00   92
  3  ω     28.00  89.00   0.50    0.50    --    4.40  28.00-150.00  122
  4  ω    -84.00  94.00   0.50    0.50    --    4.40  18.00   0.00  356
  5  ω    -79.00 -53.00   0.50    0.50    --    4.40  37.00  60.00   52
  6  ω    -18.00  12.00   0.50    0.50    --    4.40  28.00-150.00   60
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC10 (RCD3): quarter-chi single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0315599000
_diffrn_orient_matrix_UB_12      0.0327990000
_diffrn_orient_matrix_UB_13      0.0331028000
_diffrn_orient_matrix_UB_21      0.0468818000
_diffrn_orient_matrix_UB_22      -0.0013923000
_diffrn_orient_matrix_UB_23      0.0396096000
_diffrn_orient_matrix_UB_31      0.0262857000
_diffrn_orient_matrix_UB_32      0.0419922000
_diffrn_orient_matrix_UB_33      -0.0246032000
_diffrn_oxdiff_digest_frames     
;
011f59e626830665d3fbe21ee2504bead300041949a
;
_diffrn_oxdiff_digest_hkl        
;
015eccad37c9978280ee9f4d2b0b5c06726d89
;
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'Rotating-anode X-ray tube (dual wavelength)'
_diffrn_source_type              'Rigaku (Mo) X-ray DW Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4246
_reflns_number_total             4591
_reflns_odcompleteness_completeness 99.93
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.40.72a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.40.72a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.40.72a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max         0.870
_refine_diff_density_min         -1.279
_refine_diff_density_rms         0.109
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.195
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     262
_refine_ls_number_reflns         4591
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0259
_refine_ls_restrained_S_all      1.195
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0028P)²+4.6063P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0528
_refine_ls_wR_factor_ref         0.0536
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H,H,H,H) groups
2. Others
 Sof(H13D)=Sof(H13E)=Sof(H13F)=Sof(H12D)=Sof(H12E)=Sof(H12F)=Sof(H14D)=
 Sof(H14E)=Sof(H14F)=Sof(Pt2)=1-FVAR(1)
 Sof(Pt1)=Sof(H13A)=Sof(H13B)=Sof(H13C)=Sof(H12A)=Sof(H12B)=Sof(H12C)=
 Sof(H14A)=Sof(H14B)=Sof(H14C)=FVAR(1)
3.a Me refined with riding coordinates:
 C13(H13A,H13B,H13C), C13(H13D,H13E,H13F), C12(H12A,H12B,H12C), C12(H12D,H12E,
 H12F), C14(H14A,H14B,H14C), C14(H14D,H14E,H14F)
3.b Aromatic/amide H refined with riding coordinates:
 C10(H10), C2(H2A), C11(H11), C5(H5), C4(H4), C9(H9), C3(H3), C8(H8)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.50739(3) 0.77328(5) 0.65994(6) 0.02010(14) Uani 0.947(4) 1 d . . P A 1
S1 S 0.95825(8) 0.71872(7) 0.71163(7) 0.02617(19) Uani 1 1 d . . . . .
F2 F 1.0022(3) 0.7842(2) 0.5195(2) 0.0504(7) Uani 1 1 d . . . . .
O1 O 0.6520(2) 0.72223(18) 0.7734(2) 0.0229(5) Uani 1 1 d . . . . .
O2 O 0.7170(2) 0.5638(2) 0.8321(2) 0.0281(6) Uani 1 1 d . . . . .
O4 O 0.8619(2) 0.7892(2) 0.7182(2) 0.0346(6) Uani 1 1 d . . . . .
O3 O 0.9299(3) 0.6200(2) 0.7516(2) 0.0384(7) Uani 1 1 d . . . . .
F1 F 0.8660(2) 0.6742(3) 0.5213(2) 0.0566(8) Uani 1 1 d . . . . .
N2 N 0.5882(3) 0.6482(2) 0.5774(2) 0.0232(6) Uani 1 1 d . . . . .
F3 F 1.0460(3) 0.6300(2) 0.5469(2) 0.0605(8) Uani 1 1 d . . . . .
O5 O 1.0707(3) 0.7578(3) 0.7441(3) 0.0450(8) Uani 1 1 d . . . . .
N1 N 0.4337(2) 0.6587(2) 0.7595(2) 0.0217(6) Uani 1 1 d . . . . .
C10 C 0.6420(4) 0.5467(4) 0.4311(3) 0.0391(10) Uani 1 1 d . . . . .
H10 H 0.641334 0.535390 0.355533 0.047 Uiso 1 1 calc R . . . .
C7 C 0.6455(3) 0.5845(3) 0.6460(3) 0.0210(7) Uani 1 1 d . . . . .
C13 C 0.5951(4) 0.8748(3) 0.5704(3) 0.0395(10) Uani 1 1 d . . . . .
H13A H 0.675657 0.882496 0.600684 0.059 Uiso 0.947(4) 1 calc R . P A 1
H13B H 0.597109 0.850895 0.495861 0.059 Uiso 0.947(4) 1 calc R . P A 1
H13C H 0.554697 0.939749 0.571633 0.059 Uiso 0.947(4) 1 calc R . P A 1
H13D H 0.676321 0.867083 0.598968 0.059 Uiso 0.053(4) 1 calc R . P A 2
H13E H 0.593747 0.875513 0.491428 0.059 Uiso 0.053(4) 1 calc R . P A 2
H13F H 0.562788 0.938052 0.596422 0.059 Uiso 0.053(4) 1 calc R . P A 2
C12 C 0.4439(4) 0.8855(3) 0.7531(4) 0.0390(10) Uani 1 1 d . . . . .
H12A H 0.496108 0.894546 0.817383 0.058 Uiso 0.947(4) 1 calc R . P A 1
H12B H 0.440134 0.948214 0.711662 0.058 Uiso 0.947(4) 1 calc R . P A 1
H12C H 0.364959 0.867740 0.774903 0.058 Uiso 0.947(4) 1 calc R . P A 1
H12D H 0.501469 0.884265 0.814280 0.058 Uiso 0.053(4) 1 calc R . P A 2
H12E H 0.447574 0.950606 0.716480 0.058 Uiso 0.053(4) 1 calc R . P A 2
H12F H 0.364816 0.875543 0.779109 0.058 Uiso 0.053(4) 1 calc R . P A 2
C6 C 0.6388(3) 0.6144(2) 0.7647(3) 0.0203(7) Uani 1 1 d . . . . .
C2 C 0.4861(3) 0.5110(3) 0.8605(3) 0.0256(7) Uani 1 1 d . . . . .
H2A H 0.544704 0.464476 0.885152 0.031 Uiso 1 1 calc R . . . .
C1 C 0.5141(3) 0.5933(2) 0.7984(3) 0.0201(7) Uani 1 1 d . . . . .
C14 C 0.3675(4) 0.7986(3) 0.5564(4) 0.0383(10) Uani 1 1 d . . . . .
H14A H 0.300955 0.757388 0.577249 0.057 Uiso 0.947(4) 1 calc R . P A 1
H14B H 0.345713 0.869758 0.558844 0.057 Uiso 0.947(4) 1 calc R . P A 1
H14C H 0.388125 0.780903 0.483071 0.057 Uiso 0.947(4) 1 calc R . P A 1
H14D H 0.332376 0.850552 0.600622 0.057 Uiso 0.053(4) 1 calc R . P A 2
H14E H 0.390915 0.828240 0.488448 0.057 Uiso 0.053(4) 1 calc R . P A 2
H14F H 0.309864 0.745167 0.541182 0.057 Uiso 0.053(4) 1 calc R . P A 2
C11 C 0.5875(3) 0.6294(3) 0.4715(3) 0.0324(9) Uani 1 1 d . . . . .
H11 H 0.548168 0.674701 0.422985 0.039 Uiso 1 1 calc R . . . .
C15 C 0.9685(3) 0.7003(3) 0.5670(3) 0.0290(8) Uani 1 1 d . . . . .
C5 C 0.3216(3) 0.6471(3) 0.7855(3) 0.0270(7) Uani 1 1 d . . . . .
H5 H 0.264488 0.694489 0.759750 0.032 Uiso 1 1 calc R . . . .
C4 C 0.2870(3) 0.5680(3) 0.8487(3) 0.0302(8) Uani 1 1 d . . . . .
H4 H 0.207186 0.561385 0.866520 0.036 Uiso 1 1 calc R . . . .
C9 C 0.6979(4) 0.4802(3) 0.5015(4) 0.0395(10) Uani 1 1 d . . . . .
H9 H 0.735011 0.421866 0.474957 0.047 Uiso 1 1 calc R . . . .
C3 C 0.3693(4) 0.4990(3) 0.8855(3) 0.0301(8) Uani 1 1 d . . . . .
H3 H 0.346377 0.443496 0.927740 0.036 Uiso 1 1 calc R . . . .
C8 C 0.6994(3) 0.4991(3) 0.6117(3) 0.0293(8) Uani 1 1 d . . . . .
H8 H 0.736751 0.454102 0.661751 0.035 Uiso 1 1 calc R . . . .
H2 H 0.786(4) 0.572(4) 0.815(4) 0.038(13) Uiso 1 1 d . . . . .
Pt2 Pt 0.4890(8) 0.7492(7) 0.6248(13) 0.0299(15) Uani 0.053(4) 1 d . . P A 2
H1 H 0.712(5) 0.739(4) 0.760(5) 0.052(17) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 O1 2.222(3) . ?
Pt1 N2 2.182(3) . ?
Pt1 N1 2.158(3) . ?
Pt1 C13 2.041(4) . ?
Pt1 C12 2.043(4) . ?
Pt1 C14 2.028(4) . ?
S1 O4 1.449(3) . ?
S1 O3 1.446(3) . ?
S1 O5 1.423(3) . ?
S1 C15 1.822(4) . ?
F2 C15 1.329(5) . ?
O1 C6 1.447(4) . ?
O1 H1 0.74(6) . ?
O2 C6 1.370(4) . ?
O2 H2 0.83(5) . ?
F1 C15 1.320(5) . ?
N2 C7 1.348(4) . ?
N2 C11 1.338(5) . ?
N2 Pt2 1.869(8) . ?
F3 C15 1.318(5) . ?
N1 C1 1.336(4) . ?
N1 C5 1.340(4) . ?
N1 Pt2 2.179(7) . ?
C10 H10 0.9500 . ?
C10 C11 1.371(6) . ?
C10 C9 1.379(7) . ?
C7 C6 1.532(5) . ?
C7 C8 1.369(5) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C13 H13D 0.9800 . ?
C13 H13E 0.9800 . ?
C13 H13F 0.9800 . ?
C13 Pt2 2.188(8) . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C12 H12D 0.9800 . ?
C12 H12E 0.9800 . ?
C12 H12F 0.9800 . ?
C12 Pt2 2.485(15) . ?
C6 C1 1.525(5) . ?
C2 H2A 0.9500 . ?
C2 C1 1.386(5) . ?
C2 C3 1.390(5) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C14 H14D 0.9800 . ?
C14 H14E 0.9800 . ?
C14 H14F 0.9800 . ?
C14 Pt2 1.720(12) . ?
C11 H11 0.9500 . ?
C5 H5 0.9500 . ?
C5 C4 1.382(5) . ?
C4 H4 0.9500 . ?
C4 C3 1.375(6) . ?
C9 H9 0.9500 . ?
C9 C8 1.391(6) . ?
C3 H3 0.9500 . ?
C8 H8 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Pt1 O1 75.42(10) . . ?
N1 Pt1 O1 73.54(10) . . ?
N1 Pt1 N2 85.03(11) . . ?
C13 Pt1 O1 100.44(15) . . ?
C13 Pt1 N2 91.23(16) . . ?
C13 Pt1 N1 173.55(15) . . ?
C13 Pt1 C12 91.12(19) . . ?
C12 Pt1 O1 97.82(15) . . ?
C12 Pt1 N2 173.14(15) . . ?
C12 Pt1 N1 92.01(15) . . ?
C14 Pt1 O1 171.59(15) . . ?
C14 Pt1 N2 99.51(16) . . ?
C14 Pt1 N1 99.54(15) . . ?
C14 Pt1 C13 86.25(18) . . ?
C14 Pt1 C12 87.07(19) . . ?
O4 S1 C15 103.09(18) . . ?
O3 S1 O4 112.76(17) . . ?
O3 S1 C15 103.99(18) . . ?
O5 S1 O4 114.92(18) . . ?
O5 S1 O3 116.6(2) . . ?
O5 S1 C15 103.28(18) . . ?
Pt1 O1 H1 116(4) . . ?
C6 O1 Pt1 100.65(19) . . ?
C6 O1 H1 112(4) . . ?
C6 O2 H2 112(3) . . ?
C7 N2 Pt1 112.7(2) . . ?
C7 N2 Pt2 122.4(5) . . ?
C11 N2 Pt1 128.4(3) . . ?
C11 N2 C7 118.9(3) . . ?
C11 N2 Pt2 117.9(6) . . ?
C1 N1 Pt1 112.9(2) . . ?
C1 N1 C5 118.8(3) . . ?
C1 N1 Pt2 114.8(3) . . ?
C5 N1 Pt1 128.3(2) . . ?
C5 N1 Pt2 124.1(4) . . ?
C11 C10 H10 120.4 . . ?
C11 C10 C9 119.2(4) . . ?
C9 C10 H10 120.4 . . ?
N2 C7 C6 113.6(3) . . ?
N2 C7 C8 122.4(3) . . ?
C8 C7 C6 124.0(3) . . ?
Pt1 C13 H13A 109.5 . . ?
Pt1 C13 H13B 109.5 . . ?
Pt1 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
H13D C13 H13E 109.5 . . ?
H13D C13 H13F 109.5 . . ?
H13E C13 H13F 109.5 . . ?
Pt2 C13 H13D 109.5 . . ?
Pt2 C13 H13E 109.5 . . ?
Pt2 C13 H13F 109.5 . . ?
Pt1 C12 H12A 109.5 . . ?
Pt1 C12 H12B 109.5 . . ?
Pt1 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
H12D C12 H12E 109.5 . . ?
H12D C12 H12F 109.5 . . ?
H12E C12 H12F 109.5 . . ?
Pt2 C12 H12D 109.5 . . ?
Pt2 C12 H12E 109.5 . . ?
Pt2 C12 H12F 109.5 . . ?
O1 C6 C7 108.7(3) . . ?
O1 C6 C1 104.9(3) . . ?
O2 C6 O1 112.3(3) . . ?
O2 C6 C7 113.5(3) . . ?
O2 C6 C1 109.2(3) . . ?
C1 C6 C7 107.8(3) . . ?
C1 C2 H2A 121.2 . . ?
C1 C2 C3 117.6(3) . . ?
C3 C2 H2A 121.2 . . ?
N1 C1 C6 114.3(3) . . ?
N1 C1 C2 123.0(3) . . ?
C2 C1 C6 122.6(3) . . ?
Pt1 C14 H14A 109.5 . . ?
Pt1 C14 H14B 109.5 . . ?
Pt1 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
H14D C14 H14E 109.5 . . ?
H14D C14 H14F 109.5 . . ?
H14E C14 H14F 109.5 . . ?
Pt2 C14 H14D 109.5 . . ?
Pt2 C14 H14E 109.5 . . ?
Pt2 C14 H14F 109.5 . . ?
N2 C11 C10 121.9(4) . . ?
N2 C11 H11 119.0 . . ?
C10 C11 H11 119.0 . . ?
F2 C15 S1 110.9(3) . . ?
F1 C15 S1 111.3(3) . . ?
F1 C15 F2 107.4(3) . . ?
F3 C15 S1 110.9(3) . . ?
F3 C15 F2 107.6(3) . . ?
F3 C15 F1 108.6(3) . . ?
N1 C5 H5 119.2 . . ?
N1 C5 C4 121.6(3) . . ?
C4 C5 H5 119.2 . . ?
C5 C4 H4 120.3 . . ?
C3 C4 C5 119.4(3) . . ?
C3 C4 H4 120.3 . . ?
C10 C9 H9 120.3 . . ?
C10 C9 C8 119.4(4) . . ?
C8 C9 H9 120.3 . . ?
C2 C3 H3 120.2 . . ?
C4 C3 C2 119.6(3) . . ?
C4 C3 H3 120.2 . . ?
C7 C8 C9 118.2(4) . . ?
C7 C8 H8 120.9 . . ?
C9 C8 H8 120.9 . . ?
N2 Pt2 N1 92.5(2) . . ?
N2 Pt2 C13 95.9(3) . . ?
N2 Pt2 C12 150.9(9) . . ?
N1 Pt2 C13 147.5(10) . . ?
N1 Pt2 C12 80.5(5) . . ?
C13 Pt2 C12 76.9(4) . . ?
C14 Pt2 N2 127.2(11) . . ?
C14 Pt2 N1 109.6(3) . . ?
C14 Pt2 C13 89.9(3) . . ?
C14 Pt2 C12 81.4(3) . . ?

_olex2_exptl_crystal_mounting_method loop
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.967
_oxdiff_exptl_absorpt_empirical_full_min 0.765
