# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_shelx
_database_code_depnum_ccdc_archive 'CCDC 2000896'
loop_
_audit_author_name
_audit_author_address
'Nawal K. Al-Rasbi'
;Department of Chemistry, Sultan Qaboos University,  Al Khod
Oman
;
_audit_update_record             
;
2020-05-04 deposited with the CCDC.	2020-05-26 downloaded from the CCDC.
;
# start Validation Reply Form
_vrf_PLAT201_shelx               
;
PROBLEM: Isotropic non-H Atoms in Main Residue(s) .......          2 Report
RESPONSE: The CF3 group showed rotational disorder and the best model was obtained with two of the F atoms being treated as isotropic.
;
# Added during the CSD deposition process: Monday 04 May 2020 11:05 AM
# end Validation Reply Form


_audit_creation_method           SHELXL-2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C34 H21 Eu F9 N2 O6'
_chemical_formula_weight         876.49

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.800(2)
_cell_length_b                   11.080(2)
_cell_length_c                   17.150(3)
_cell_angle_alpha                71.70(3)
_cell_angle_beta                 80.40(3)
_cell_angle_gamma                84.60(3)
_cell_volume                     1741.5(7)
_cell_formula_units_Z            2
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    5002
_cell_measurement_theta_min      3.00
_cell_measurement_theta_max      55.00

_exptl_crystal_description       needle
_exptl_crystal_colour            colorless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_density_diffrn    1.671
_exptl_crystal_F_000             862
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.190
_exptl_crystal_size_min          0.110
_exptl_absorpt_coefficient_mu    1.895
_shelx_estimated_absorpt_T_min   0.692
_shelx_estimated_absorpt_T_max   0.819
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.96
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   Semi-empirical
_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'sealed x-ray tube'
_diffrn_measurement_device_type  'stoe ipds ii'
_diffrn_measurement_method       'w scan'
_diffrn_detector_area_resol_mean 6.67

_diffrn_reflns_number            28838
_diffrn_reflns_av_unetI/netI     0.1015
_diffrn_reflns_av_R_equivalents  0.0585
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         2.529
_diffrn_reflns_theta_max         35.015
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             15076
_reflns_number_gt                7733
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0997P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         15076
_refine_ls_number_parameters     459
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1506
_refine_ls_R_factor_gt           0.0626
_refine_ls_wR_factor_ref         0.1873
_refine_ls_wR_factor_gt          0.1496
_refine_ls_goodness_of_fit_ref   0.991
_refine_ls_restrained_S_all      0.991
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.69981(2) 0.50269(2) 0.31326(2) 0.03961(9) Uani 1 1 d . . . . .
F1 F 0.9925(6) 0.8059(6) 0.3723(4) 0.127(2) Uani 1 1 d . . . . .
F2 F 1.0943(5) 0.7667(6) 0.2637(4) 0.1184(19) Uani 1 1 d . . . . .
F3 F 0.9971(6) 0.9485(5) 0.2543(5) 0.140(3) Uani 1 1 d . . . . .
F4 F 0.4021(4) 0.5739(5) 0.0455(2) 0.0890(14) Uani 1 1 d . . . . .
F5 F 0.3091(5) 0.5604(5) 0.1679(3) 0.0995(14) Uiso 1 1 d . . . . .
F6 F 0.3869(6) 0.3953(6) 0.1356(4) 0.126(2) Uani 1 1 d . . . . .
F7 F 1.1590(5) 0.2752(10) 0.3155(5) 0.186(4) Uani 1 1 d . . . . .
F8 F 1.1104(7) 0.2630(8) 0.4381(5) 0.157(3) Uani 1 1 d . . . . .
F9 F 1.1077(7) 0.1004(7) 0.4069(5) 0.135(2) Uiso 1 1 d . . . . .
O1 O 0.8984(4) 0.3765(4) 0.3504(3) 0.0563(9) Uani 1 1 d . . . . .
O2 O 0.6388(4) 0.2890(4) 0.3613(3) 0.0579(10) Uani 1 1 d . . . . .
O3 O 0.5521(4) 0.4753(4) 0.2268(2) 0.0558(9) Uani 1 1 d . . . . .
O4 O 0.8225(4) 0.5573(4) 0.1787(2) 0.0513(8) Uani 1 1 d . . . . .
O5 O 0.5939(4) 0.7049(3) 0.2604(2) 0.0532(9) Uani 1 1 d . . . . .
O6 O 0.8426(4) 0.6550(4) 0.3236(2) 0.0560(9) Uani 1 1 d . . . . .
N1 N 0.6833(4) 0.4819(4) 0.4719(3) 0.0442(9) Uani 1 1 d . . . . .
N2 N 0.5481(4) 0.4899(4) 0.5989(2) 0.0435(8) Uani 1 1 d . . . . .
C1 C 1.0782(8) 0.2259(8) 0.3786(7) 0.093(3) Uani 1 1 d . . . . .
C2 C 0.9256(6) 0.2588(6) 0.3697(4) 0.0589(14) Uani 1 1 d . . . . .
C3 C 0.8403(6) 0.1611(6) 0.3824(5) 0.0709(18) Uani 1 1 d . . . . .
H3 H 0.877933 0.078129 0.395742 0.085 Uiso 1 1 calc R U . . .
C4 C 0.6969(6) 0.1816(5) 0.3761(4) 0.0532(12) Uani 1 1 d . . . . .
C5 C 0.6135(6) 0.0696(5) 0.3861(4) 0.0576(13) Uani 1 1 d . . . . .
C6 C 0.6484(7) -0.0513(6) 0.4326(4) 0.0675(16) Uani 1 1 d . . . . .
H6 H 0.726629 -0.066647 0.459017 0.081 Uiso 1 1 calc R U . . .
C7 C 0.5659(11) -0.1507(7) 0.4398(6) 0.093(3) Uani 1 1 d . . . . .
H7 H 0.589979 -0.233097 0.470377 0.112 Uiso 1 1 calc R U . . .
C8 C 0.4508(9) -0.1284(8) 0.4026(6) 0.090(3) Uani 1 1 d . . . . .
H8 H 0.393840 -0.194951 0.410227 0.108 Uiso 1 1 calc R U . . .
C9 C 0.4172(8) -0.0094(8) 0.3539(6) 0.087(2) Uani 1 1 d . . . . .
H9 H 0.341538 0.003959 0.325470 0.104 Uiso 1 1 calc R U . . .
C10 C 0.4966(7) 0.0912(7) 0.3473(5) 0.0704(16) Uani 1 1 d . . . . .
H10 H 0.471383 0.173323 0.316720 0.084 Uiso 1 1 calc R U . . .
C11 C 0.4122(6) 0.5132(8) 0.1235(4) 0.0689(18) Uani 1 1 d . . . . .
C12 C 0.5521(6) 0.5235(5) 0.1497(3) 0.0507(12) Uani 1 1 d . . . . .
C13 C 0.6566(6) 0.5803(6) 0.0894(3) 0.0552(13) Uani 1 1 d . . . . .
H13 H 0.638777 0.613293 0.034907 0.066 Uiso 1 1 calc R U . . .
C14 C 0.7904(5) 0.5910(5) 0.1064(3) 0.0463(10) Uani 1 1 d . . . . .
C15 C 0.9002(6) 0.6442(6) 0.0361(3) 0.0523(12) Uani 1 1 d . . . . .
C16 C 0.8960(6) 0.6426(7) -0.0434(4) 0.0634(15) Uani 1 1 d . . . . .
H16 H 0.821042 0.608464 -0.054546 0.076 Uiso 1 1 calc R U . . .
C17 C 1.0025(8) 0.6914(8) -0.1073(4) 0.079(2) Uani 1 1 d . . . . .
H17 H 0.998507 0.689310 -0.160614 0.095 Uiso 1 1 calc R U . . .
C18 C 1.1106(8) 0.7415(9) -0.0921(5) 0.092(3) Uani 1 1 d . . . . .
H18 H 1.180273 0.775684 -0.135439 0.110 Uiso 1 1 calc R U . . .
C19 C 1.1203(9) 0.7432(10) -0.0136(6) 0.102(3) Uani 1 1 d . . . . .
H19 H 1.196249 0.777576 -0.003665 0.123 Uiso 1 1 calc R U . . .
C20 C 1.0145(7) 0.6927(8) 0.0515(4) 0.076(2) Uani 1 1 d . . . . .
H20 H 1.021231 0.691693 0.105108 0.091 Uiso 1 1 calc R U . . .
C21 C 0.9837(8) 0.8267(8) 0.2929(6) 0.084(2) Uani 1 1 d . . . . .
C22 C 0.8520(6) 0.7720(6) 0.2835(4) 0.0576(13) Uani 1 1 d . . . . .
C23 C 0.7668(6) 0.8512(6) 0.2328(4) 0.0631(15) Uani 1 1 d . . . . .
H23 H 0.795444 0.932399 0.202256 0.076 Uiso 1 1 calc R U . . .
C24 C 0.6352(6) 0.8149(5) 0.2244(3) 0.0491(11) Uani 1 1 d . . . . .
C25 C 0.5441(6) 0.9070(6) 0.1709(4) 0.0589(14) Uani 1 1 d . . . . .
C26 C 0.5780(10) 1.0302(8) 0.1278(7) 0.106(3) Uani 1 1 d . . . . .
H26 H 0.659277 1.061086 0.133927 0.127 Uiso 1 1 calc R U . . .
C27 C 0.4922(15) 1.1067(11) 0.0762(9) 0.159(6) Uani 1 1 d . . . . .
H27 H 0.521900 1.185543 0.041491 0.191 Uiso 1 1 calc R U . . .
C28 C 0.3664(11) 1.0716(10) 0.0741(7) 0.114(4) Uani 1 1 d . . . . .
H28 H 0.306368 1.128974 0.042432 0.136 Uiso 1 1 calc R U . . .
C29 C 0.3260(10) 0.9518(10) 0.1182(7) 0.120(4) Uani 1 1 d . . . . .
H29 H 0.239984 0.926112 0.115001 0.144 Uiso 1 1 calc R U . . .
C30 C 0.4160(8) 0.8670(8) 0.1688(5) 0.090(3) Uani 1 1 d . . . . .
H30 H 0.389209 0.785608 0.200120 0.108 Uiso 1 1 calc R U . . .
C31 C 0.7972(5) 0.4670(6) 0.5084(4) 0.0559(13) Uani 1 1 d . . . . .
H31 H 0.883098 0.457107 0.477943 0.067 Uiso 1 1 calc R U . . .
C32 C 0.7914(5) 0.4658(7) 0.5890(3) 0.0580(14) Uani 1 1 d . . . . .
H32 H 0.871329 0.456690 0.613281 0.070 Uiso 1 1 calc R U . . .
C33 C 0.6633(5) 0.4784(6) 0.6321(4) 0.0577(14) Uani 1 1 d . . . . .
H33 H 0.656707 0.479074 0.686677 0.069 Uiso 1 1 calc R U . . .
C34 C 0.5636(4) 0.4921(4) 0.5191(3) 0.0368(9) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.338(4) . ?
Eu1 O4 2.339(4) . ?
Eu1 O1 2.343(4) . ?
Eu1 O2 2.350(4) . ?
Eu1 O5 2.350(4) . ?
Eu1 O6 2.356(4) . ?
Eu1 N1 2.636(4) . ?
Eu1 N2 2.645(4) 2_666 ?
F1 C21 1.324(10) . ?
F2 C21 1.326(10) . ?
F3 C21 1.312(10) . ?
F4 C11 1.311(8) . ?
F5 C11 1.331(8) . ?
F6 C11 1.297(9) . ?
F7 C1 1.234(12) . ?
F8 C1 1.305(12) . ?
F9 C1 1.342(10) . ?
O1 C2 1.255(7) . ?
O2 C4 1.239(7) . ?
O3 C12 1.260(6) . ?
O4 C14 1.263(6) . ?
O5 C24 1.252(6) . ?
O6 C22 1.266(7) . ?
N1 C34 1.326(6) . ?
N1 C31 1.341(6) . ?
N2 C33 1.325(6) . ?
N2 C34 1.345(6) . ?
C1 C2 1.526(9) . ?
C2 C3 1.371(9) . ?
C3 C4 1.419(8) . ?
C3 H3 0.9300 . ?
C4 C5 1.499(8) . ?
C5 C6 1.372(9) . ?
C5 C10 1.384(9) . ?
C6 C7 1.389(10) . ?
C6 H6 0.9300 . ?
C7 C8 1.353(13) . ?
C7 H7 0.9300 . ?
C8 C9 1.364(13) . ?
C8 H8 0.9300 . ?
C9 C10 1.384(10) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C11 C12 1.537(8) . ?
C12 C13 1.369(8) . ?
C13 C14 1.413(7) . ?
C13 H13 0.9300 . ?
C14 C15 1.483(7) . ?
C15 C16 1.377(8) . ?
C15 C20 1.383(8) . ?
C16 C17 1.390(9) . ?
C16 H16 0.9300 . ?
C17 C18 1.339(11) . ?
C17 H17 0.9300 . ?
C18 C19 1.371(12) . ?
C18 H18 0.9300 . ?
C19 C20 1.402(10) . ?
C19 H19 0.9300 . ?
C20 H20 0.9300 . ?
C21 C22 1.528(9) . ?
C22 C23 1.360(9) . ?
C23 C24 1.429(8) . ?
C23 H23 0.9300 . ?
C24 C25 1.481(8) . ?
C25 C26 1.374(9) . ?
C25 C30 1.380(10) . ?
C26 C27 1.361(14) . ?
C26 H26 0.9300 . ?
C27 C28 1.337(14) . ?
C27 H27 0.9300 . ?
C28 C29 1.363(14) . ?
C28 H28 0.9300 . ?
C29 C30 1.414(11) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 C32 1.369(8) . ?
C31 H31 0.9300 . ?
C32 C33 1.366(8) . ?
C32 H32 0.9300 . ?
C33 H33 0.9300 . ?
C34 C34 1.474(9) 2_666 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O4 73.20(13) . . ?
O3 Eu1 O1 126.35(15) . . ?
O4 Eu1 O1 84.89(14) . . ?
O3 Eu1 O2 72.28(15) . . ?
O4 Eu1 O2 112.33(15) . . ?
O1 Eu1 O2 72.16(14) . . ?
O3 Eu1 O5 75.12(15) . . ?
O4 Eu1 O5 81.45(14) . . ?
O1 Eu1 O5 149.47(14) . . ?
O2 Eu1 O5 138.37(13) . . ?
O3 Eu1 O6 140.65(14) . . ?
O4 Eu1 O6 80.89(14) . . ?
O1 Eu1 O6 78.87(14) . . ?
O2 Eu1 O6 146.44(14) . . ?
O5 Eu1 O6 72.10(14) . . ?
O3 Eu1 N1 136.41(13) . . ?
O4 Eu1 N1 150.31(13) . . ?
O1 Eu1 N1 77.42(14) . . ?
O2 Eu1 N1 84.83(15) . . ?
O5 Eu1 N1 102.05(14) . . ?
O6 Eu1 N1 72.47(14) . . ?
O3 Eu1 N2 77.19(13) . 2_666 ?
O4 Eu1 N2 144.10(13) . 2_666 ?
O1 Eu1 N2 129.74(13) . 2_666 ?
O2 Eu1 N2 76.47(14) . 2_666 ?
O5 Eu1 N2 71.60(13) . 2_666 ?
O6 Eu1 N2 111.52(14) . 2_666 ?
N1 Eu1 N2 61.36(12) . 2_666 ?
C2 O1 Eu1 133.1(4) . . ?
C4 O2 Eu1 138.6(4) . . ?
C12 O3 Eu1 130.7(3) . . ?
C14 O4 Eu1 135.4(3) . . ?
C24 O5 Eu1 135.6(4) . . ?
C22 O6 Eu1 130.4(4) . . ?
C34 N1 C31 116.1(4) . . ?
C34 N1 Eu1 122.4(3) . . ?
C31 N1 Eu1 121.4(3) . . ?
C33 N2 C34 116.4(4) . . ?
C33 N2 Eu1 121.9(3) . 2_666 ?
C34 N2 Eu1 121.6(3) . 2_666 ?
F7 C1 F8 107.0(8) . . ?
F7 C1 F9 110.4(9) . . ?
F8 C1 F9 100.7(8) . . ?
F7 C1 C2 114.1(8) . . ?
F8 C1 C2 110.3(7) . . ?
F9 C1 C2 113.4(7) . . ?
O1 C2 C3 129.7(5) . . ?
O1 C2 C1 112.1(6) . . ?
C3 C2 C1 118.2(6) . . ?
C2 C3 C4 122.6(6) . . ?
C2 C3 H3 118.7 . . ?
C4 C3 H3 118.7 . . ?
O2 C4 C3 122.3(6) . . ?
O2 C4 C5 118.9(5) . . ?
C3 C4 C5 118.8(5) . . ?
C6 C5 C10 119.7(6) . . ?
C6 C5 C4 122.4(6) . . ?
C10 C5 C4 117.9(6) . . ?
C5 C6 C7 119.4(7) . . ?
C5 C6 H6 120.3 . . ?
C7 C6 H6 120.3 . . ?
C8 C7 C6 120.5(7) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
C7 C8 C9 120.8(7) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 H8 119.6 . . ?
C8 C9 C10 119.5(8) . . ?
C8 C9 H9 120.2 . . ?
C10 C9 H9 120.2 . . ?
C9 C10 C5 120.0(7) . . ?
C9 C10 H10 120.0 . . ?
C5 C10 H10 120.0 . . ?
F6 C11 F4 106.8(6) . . ?
F6 C11 F5 107.1(6) . . ?
F4 C11 F5 106.0(6) . . ?
F6 C11 C12 111.1(6) . . ?
F4 C11 C12 114.7(5) . . ?
F5 C11 C12 110.8(5) . . ?
O3 C12 C13 129.4(5) . . ?
O3 C12 C11 112.4(5) . . ?
C13 C12 C11 118.2(5) . . ?
C12 C13 C14 122.8(5) . . ?
C12 C13 H13 118.6 . . ?
C14 C13 H13 118.6 . . ?
O4 C14 C13 123.5(5) . . ?
O4 C14 C15 117.6(5) . . ?
C13 C14 C15 118.9(5) . . ?
C16 C15 C20 118.4(6) . . ?
C16 C15 C14 122.7(5) . . ?
C20 C15 C14 118.8(5) . . ?
C15 C16 C17 120.9(6) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 H16 119.6 . . ?
C18 C17 C16 120.1(7) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C17 C18 C19 121.0(7) . . ?
C17 C18 H18 119.5 . . ?
C19 C18 H18 119.5 . . ?
C18 C19 C20 119.3(8) . . ?
C18 C19 H19 120.3 . . ?
C20 C19 H19 120.3 . . ?
C15 C20 C19 120.2(7) . . ?
C15 C20 H20 119.9 . . ?
C19 C20 H20 119.9 . . ?
F3 C21 F1 108.4(8) . . ?
F3 C21 F2 106.7(7) . . ?
F1 C21 F2 105.6(8) . . ?
F3 C21 C22 115.3(7) . . ?
F1 C21 C22 110.5(7) . . ?
F2 C21 C22 109.9(7) . . ?
O6 C22 C23 129.8(5) . . ?
O6 C22 C21 112.7(6) . . ?
C23 C22 C21 117.4(6) . . ?
C22 C23 C24 122.8(5) . . ?
C22 C23 H23 118.6 . . ?
C24 C23 H23 118.6 . . ?
O5 C24 C23 121.7(5) . . ?
O5 C24 C25 117.8(5) . . ?
C23 C24 C25 120.4(5) . . ?
C26 C25 C30 119.3(7) . . ?
C26 C25 C24 123.4(6) . . ?
C30 C25 C24 117.1(6) . . ?
C27 C26 C25 119.8(9) . . ?
C27 C26 H26 120.1 . . ?
C25 C26 H26 120.1 . . ?
C28 C27 C26 121.7(9) . . ?
C28 C27 H27 119.2 . . ?
C26 C27 H27 119.2 . . ?
C27 C28 C29 120.2(8) . . ?
C27 C28 H28 119.9 . . ?
C29 C28 H28 119.9 . . ?
C28 C29 C30 119.4(9) . . ?
C28 C29 H29 120.3 . . ?
C30 C29 H29 120.3 . . ?
C25 C30 C29 119.0(7) . . ?
C25 C30 H30 120.5 . . ?
C29 C30 H30 120.5 . . ?
N1 C31 C32 122.2(5) . . ?
N1 C31 H31 118.9 . . ?
C32 C31 H31 118.9 . . ?
C33 C32 C31 117.2(5) . . ?
C33 C32 H32 121.4 . . ?
C31 C32 H32 121.4 . . ?
N2 C33 C32 122.4(5) . . ?
N2 C33 H33 118.8 . . ?
C32 C33 H33 118.8 . . ?
N1 C34 N2 125.6(4) . . ?
N1 C34 C34 117.5(5) . 2_666 ?
N2 C34 C34 116.9(5) . 2_666 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C2 C3 -6.4(11) . . . . ?
Eu1 O1 C2 C1 173.1(5) . . . . ?
F7 C1 C2 O1 -58.4(11) . . . . ?
F8 C1 C2 O1 62.0(10) . . . . ?
F9 C1 C2 O1 174.0(8) . . . . ?
F7 C1 C2 C3 121.1(10) . . . . ?
F8 C1 C2 C3 -118.5(8) . . . . ?
F9 C1 C2 C3 -6.5(13) . . . . ?
O1 C2 C3 C4 -1.0(13) . . . . ?
C1 C2 C3 C4 179.6(7) . . . . ?
Eu1 O2 C4 C3 14.5(11) . . . . ?
Eu1 O2 C4 C5 -164.3(4) . . . . ?
C2 C3 C4 O2 -2.4(11) . . . . ?
C2 C3 C4 C5 176.4(6) . . . . ?
O2 C4 C5 C6 -153.7(6) . . . . ?
C3 C4 C5 C6 27.4(9) . . . . ?
O2 C4 C5 C10 25.6(9) . . . . ?
C3 C4 C5 C10 -153.3(7) . . . . ?
C10 C5 C6 C7 0.2(10) . . . . ?
C4 C5 C6 C7 179.5(6) . . . . ?
C5 C6 C7 C8 -1.1(12) . . . . ?
C6 C7 C8 C9 3.3(13) . . . . ?
C7 C8 C9 C10 -4.5(13) . . . . ?
C8 C9 C10 C5 3.5(12) . . . . ?
C6 C5 C10 C9 -1.4(10) . . . . ?
C4 C5 C10 C9 179.3(6) . . . . ?
Eu1 O3 C12 C13 18.9(9) . . . . ?
Eu1 O3 C12 C11 -161.7(4) . . . . ?
F6 C11 C12 O3 -65.8(7) . . . . ?
F4 C11 C12 O3 173.0(6) . . . . ?
F5 C11 C12 O3 53.0(8) . . . . ?
F6 C11 C12 C13 113.7(7) . . . . ?
F4 C11 C12 C13 -7.5(9) . . . . ?
F5 C11 C12 C13 -127.5(6) . . . . ?
O3 C12 C13 C14 1.6(10) . . . . ?
C11 C12 C13 C14 -177.9(6) . . . . ?
Eu1 O4 C14 C13 -13.2(9) . . . . ?
Eu1 O4 C14 C15 167.0(4) . . . . ?
C12 C13 C14 O4 -5.0(9) . . . . ?
C12 C13 C14 C15 174.9(6) . . . . ?
O4 C14 C15 C16 156.5(6) . . . . ?
C13 C14 C15 C16 -23.4(9) . . . . ?
O4 C14 C15 C20 -20.7(9) . . . . ?
C13 C14 C15 C20 159.4(6) . . . . ?
C20 C15 C16 C17 -1.6(11) . . . . ?
C14 C15 C16 C17 -178.8(6) . . . . ?
C15 C16 C17 C18 -0.4(13) . . . . ?
C16 C17 C18 C19 1.4(15) . . . . ?
C17 C18 C19 C20 -0.6(17) . . . . ?
C16 C15 C20 C19 2.5(12) . . . . ?
C14 C15 C20 C19 179.8(8) . . . . ?
C18 C19 C20 C15 -1.4(15) . . . . ?
Eu1 O6 C22 C23 13.1(10) . . . . ?
Eu1 O6 C22 C21 -164.2(5) . . . . ?
F3 C21 C22 O6 -178.4(8) . . . . ?
F1 C21 C22 O6 -55.1(9) . . . . ?
F2 C21 C22 O6 61.1(9) . . . . ?
F3 C21 C22 C23 4.0(11) . . . . ?
F1 C21 C22 C23 127.3(8) . . . . ?
F2 C21 C22 C23 -116.5(8) . . . . ?
O6 C22 C23 C24 8.4(11) . . . . ?
C21 C22 C23 C24 -174.5(7) . . . . ?
Eu1 O5 C24 C23 -23.7(9) . . . . ?
Eu1 O5 C24 C25 155.2(4) . . . . ?
C22 C23 C24 O5 -3.8(10) . . . . ?
C22 C23 C24 C25 177.4(6) . . . . ?
O5 C24 C25 C26 -179.6(8) . . . . ?
C23 C24 C25 C26 -0.7(11) . . . . ?
O5 C24 C25 C30 3.9(9) . . . . ?
C23 C24 C25 C30 -177.2(7) . . . . ?
C30 C25 C26 C27 -7.5(17) . . . . ?
C24 C25 C26 C27 176.2(11) . . . . ?
C25 C26 C27 C28 9(2) . . . . ?
C26 C27 C28 C29 -6(3) . . . . ?
C27 C28 C29 C30 3(2) . . . . ?
C26 C25 C30 C29 3.7(14) . . . . ?
C24 C25 C30 C29 -179.7(9) . . . . ?
C28 C29 C30 C25 -1.3(17) . . . . ?
C34 N1 C31 C32 -1.8(9) . . . . ?
Eu1 N1 C31 C32 174.9(5) . . . . ?
N1 C31 C32 C33 1.0(10) . . . . ?
C34 N2 C33 C32 -1.9(9) . . . . ?
Eu1 N2 C33 C32 175.4(5) 2_666 . . . ?
C31 C32 C33 N2 0.9(10) . . . . ?
C31 N1 C34 N2 0.7(7) . . . . ?
Eu1 N1 C34 N2 -175.9(3) . . . . ?
C31 N1 C34 C34 -179.7(5) . . . 2_666 ?
Eu1 N1 C34 C34 3.7(7) . . . 2_666 ?
C33 N2 C34 N1 1.1(7) . . . . ?
Eu1 N2 C34 N1 -176.2(4) 2_666 . . . ?
C33 N2 C34 C34 -178.6(5) . . . 2_666 ?
Eu1 N2 C34 C34 4.2(6) 2_666 . . 2_666 ?

_refine_diff_density_max         1.776
_refine_diff_density_min         -2.771
_refine_diff_density_rms         0.147


_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: Water, ethanol'
_exptl_crystal_preparation       Luminescent
