# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2
_database_code_depnum_ccdc_archive 'CCDC 2009732'
loop_
_audit_author_name
_audit_author_address
'Bing Liu'
;SUST
China
;
_audit_update_record             
;
2020-06-15 deposited with the CCDC.	2020-11-03 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C22 H15 Eu O10'
_chemical_formula_weight         591.30

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1580 3.6680 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           ?
_symmetry_space_group_name_H-M   ?

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.839(3)
_cell_length_b                   10.617(3)
_cell_length_c                   10.851(3)
_cell_angle_alpha                82.065(10)
_cell_angle_beta                 86.784(10)
_cell_angle_gamma                87.139(11)
_cell_volume                     1119.9(6)
_cell_formula_units_Z            2
_cell_measurement_temperature    153(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.754
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             580
_exptl_absorpt_coefficient_mu    2.855
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      153(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            11892
_diffrn_reflns_av_R_equivalents  0.0543
_diffrn_reflns_av_sigmaI/netI    0.0571
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_theta_min         3.55
_diffrn_reflns_theta_max         25.02
_reflns_number_total             3926
_reflns_number_gt                3534
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.1035P)²+6.7288P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3926
_refine_ls_number_parameters     312
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0612
_refine_ls_R_factor_gt           0.0542
_refine_ls_wR_factor_ref         0.1526
_refine_ls_wR_factor_gt          0.1474
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_restrained_S_all      1.053
_refine_ls_shift/su_max          0.045
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.00353(4) -0.02033(3) -0.21373(3) 0.01387(18) Uani 1 1 d . . .
O1W O -0.0760(7) -0.1404(6) -0.3660(6) 0.0269(14) Uani 1 1 d . . .
H1WA H -0.0807 -0.0917 -0.4371 0.040 Uiso 1 1 d R . .
H1WB H -0.1559 -0.1695 -0.3429 0.040 Uiso 1 1 d R . .
O11 O -0.0183(7) -0.1899(6) 0.1639(6) 0.0282(14) Uani 1 1 d . . .
O12 O -0.0983(6) -0.1023(5) -0.0163(6) 0.0236(13) Uani 1 1 d . . .
O13 O -0.0690(9) -0.6484(6) 0.3073(6) 0.0411(19) Uani 1 1 d . . .
H13A H -0.0206 -0.7110 0.3381 0.062 Uiso 1 1 calc R . .
O14 O -0.1018(6) -0.7729(5) 0.1641(6) 0.0228(13) Uani 1 1 d . . .
O15 O -0.7499(6) -0.0221(7) -0.7847(6) 0.0340(16) Uani 1 1 d . . .
O16 O -0.8639(6) -0.1252(6) -0.6263(5) 0.0212(12) Uani 1 1 d . . .
O17 O -0.2488(6) -0.0082(6) -0.7885(6) 0.0248(13) Uani 1 1 d . . .
O18 O -0.1498(6) -0.0549(6) -0.6102(5) 0.0221(13) Uani 1 1 d . . .
C11 C -0.1322(8) -0.3238(7) 0.0489(7) 0.0166(16) Uani 1 1 d . . .
C12 C -0.0973(9) -0.4319(8) 0.1298(7) 0.0191(17) Uani 1 1 d . . .
H12 H -0.0389 -0.4262 0.1955 0.04(3) Uiso 1 1 d R . .
C13 C -0.1429(9) -0.5491(8) 0.1150(8) 0.0202(17) Uani 1 1 d . . .
C14 C -0.2271(8) -0.5552(8) 0.0159(8) 0.0192(17) Uani 1 1 d . . .
H14 H -0.2602 -0.6352 0.0048 0.05(3) Uiso 1 1 d R . .
C15 C -0.2699(9) -0.4476(8) -0.0631(7) 0.0193(17) Uani 1 1 d . . .
C16 C -0.2177(8) -0.3311(7) -0.0471(7) 0.0167(16) Uani 1 1 d . . .
H16 H -0.2430 -0.2568 -0.1016 0.03(2) Uiso 1 1 d R . .
C17 C -0.0786(8) -0.1965(7) 0.0664(8) 0.0174(16) Uani 1 1 d . . .
C18 C -0.1019(9) -0.6657(8) 0.2015(8) 0.0206(17) Uani 1 1 d . . .
C19 C -0.7538(9) -0.0914(8) -0.6787(8) 0.0223(18) Uani 1 1 d . . .
C20 C -0.2530(9) -0.0529(7) -0.6739(8) 0.0189(17) Uani 1 1 d . . .
C21 C -0.3700(8) -0.4535(8) -0.1602(7) 0.0174(16) Uani 1 1 d . . .
C22 C -0.4521(9) -0.5585(9) -0.1534(9) 0.0264(19) Uani 1 1 d . . .
H22 H -0.4423 -0.6257 -0.0865 0.007(19) Uiso 1 1 d R . .
C23 C -0.5447(10) -0.5636(9) -0.2426(9) 0.029(2) Uani 1 1 d . . .
H23 H -0.5992 -0.6357 -0.2368 0.12(7) Uiso 1 1 d R . .
C24 C -0.5596(9) -0.4684(8) -0.3406(8) 0.0219(18) Uani 1 1 d . . .
H24 H -0.6239 -0.4733 -0.4017 0.04(3) Uiso 1 1 d R . .
C25 C -0.4806(8) -0.3615(8) -0.3494(8) 0.0190(17) Uani 1 1 d . . .
C26 C -0.3874(8) -0.3562(8) -0.2593(8) 0.0184(17) Uani 1 1 d . . .
H26 H -0.3329 -0.2840 -0.2651 0.03(2) Uiso 1 1 d R . .
C31 C -0.4926(8) -0.2575(8) -0.4568(7) 0.0175(16) Uani 1 1 d . . .
C32 C -0.6166(8) -0.2191(8) -0.5123(8) 0.0198(17) Uani 1 1 d . . .
H32 H -0.6976 -0.2575 -0.4772 0.04(3) Uiso 1 1 d R . .
C33 C -0.6229(8) -0.1279(8) -0.6172(8) 0.0191(17) Uani 1 1 d . . .
C34 C -0.5034(9) -0.0736(8) -0.6682(8) 0.0204(17) Uani 1 1 d . . .
H34 H -0.5068 -0.0112 -0.7399 0.04(3) Uiso 1 1 d R . .
C35 C -0.3810(8) -0.1072(7) -0.6146(8) 0.0178(16) Uani 1 1 d . . .
C36 C -0.3767(8) -0.1986(7) -0.5090(7) 0.0167(16) Uani 1 1 d . . .
H36 H -0.2921 -0.2225 -0.4723 0.03(3) Uiso 1 1 d R . .
O2W O -0.5056(16) -0.1151(11) -1.0021(12) 0.093(4) Uani 1 1 d G . .
H2WA H -0.5526 -0.1265 -0.9314 0.139 Uiso 1 1 d G . .
H2WB H -0.5154 -0.1790 -1.0426 0.139 Uiso 1 1 d G . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O12 2.357(6) . ?
Eu1 O1W 2.381(6) . ?
Eu1 O14 2.386(5) 2_545 ?
Eu1 O11 2.391(6) 2 ?
Eu1 O18 2.437(6) 2_554 ?
Eu1 O15 2.446(6) 2_454 ?
Eu1 O17 2.518(6) 2_554 ?
Eu1 O16 2.532(6) 2_454 ?
Eu1 C20 2.838(9) 2_554 ?
Eu1 C19 2.849(9) 2_454 ?
Eu1 C17 3.139(8) 2 ?
O11 C17 1.253(10) . ?
O11 Eu1 2.391(6) 2 ?
O12 C17 1.263(10) . ?
O13 C18 1.250(11) . ?
O14 C18 1.260(10) . ?
O14 Eu1 2.386(5) 2_545 ?
O15 C19 1.276(11) . ?
O15 Eu1 2.446(6) 2_454 ?
O16 C19 1.240(11) . ?
O16 Eu1 2.532(6) 2_454 ?
O17 C20 1.268(10) . ?
O17 Eu1 2.518(6) 2_554 ?
O18 C20 1.258(10) . ?
O18 Eu1 2.437(6) 2_554 ?
C11 C12 1.386(11) . ?
C11 C16 1.388(11) . ?
C11 C17 1.515(11) . ?
C12 C13 1.377(12) . ?
C13 C14 1.404(12) . ?
C13 C18 1.499(11) . ?
C14 C15 1.393(12) . ?
C15 C16 1.398(11) . ?
C15 C21 1.492(11) . ?
C17 Eu1 3.139(8) 2 ?
C19 C33 1.493(12) . ?
C19 Eu1 2.849(9) 2_454 ?
C20 C35 1.487(12) . ?
C20 Eu1 2.838(9) 2_554 ?
C21 C26 1.396(11) . ?
C21 C22 1.401(12) . ?
C22 C23 1.374(13) . ?
C23 C24 1.371(13) . ?
C24 C25 1.397(12) . ?
C25 C26 1.386(12) . ?
C25 C31 1.495(11) . ?
C31 C36 1.383(11) . ?
C31 C32 1.409(12) . ?
C32 C33 1.391(12) . ?
C33 C34 1.389(12) . ?
C34 C35 1.376(12) . ?
C35 C36 1.397(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O12 Eu1 O1W 109.3(2) . . ?
O12 Eu1 O14 74.1(2) . 2_545 ?
O1W Eu1 O14 75.0(2) . 2_545 ?
O12 Eu1 O11 95.2(2) . 2 ?
O1W Eu1 O11 144.5(2) . 2 ?
O14 Eu1 O11 138.2(2) 2_545 2 ?
O12 Eu1 O18 165.0(2) . 2_554 ?
O1W Eu1 O18 79.8(2) . 2_554 ?
O14 Eu1 O18 97.6(2) 2_545 2_554 ?
O11 Eu1 O18 82.7(2) 2 2_554 ?
O12 Eu1 O15 72.2(2) . 2_454 ?
O1W Eu1 O15 75.6(2) . 2_454 ?
O14 Eu1 O15 124.0(2) 2_545 2_454 ?
O11 Eu1 O15 88.4(2) 2 2_454 ?
O18 Eu1 O15 122.4(2) 2_554 2_454 ?
O12 Eu1 O17 112.4(2) . 2_554 ?
O1W Eu1 O17 116.4(2) . 2_554 ?
O14 Eu1 O17 73.0(2) 2_545 2_554 ?
O11 Eu1 O17 74.5(2) 2 2_554 ?
O18 Eu1 O17 52.69(19) 2_554 2_554 ?
O15 Eu1 O17 162.5(2) 2_454 2_554 ?
O12 Eu1 O16 123.13(19) . 2_454 ?
O1W Eu1 O16 70.7(2) . 2_454 ?
O14 Eu1 O16 145.1(2) 2_545 2_454 ?
O11 Eu1 O16 74.4(2) 2 2_454 ?
O18 Eu1 O16 70.69(19) 2_554 2_454 ?
O15 Eu1 O16 52.1(2) 2_454 2_454 ?
O17 Eu1 O16 117.59(19) 2_554 2_454 ?
O12 Eu1 C20 138.9(2) . 2_554 ?
O1W Eu1 C20 99.5(2) . 2_554 ?
O14 Eu1 C20 86.2(2) 2_545 2_554 ?
O11 Eu1 C20 75.9(2) 2 2_554 ?
O18 Eu1 C20 26.2(2) 2_554 2_554 ?
O15 Eu1 C20 145.3(2) 2_454 2_554 ?
O17 Eu1 C20 26.5(2) 2_554 2_554 ?
O16 Eu1 C20 93.5(2) 2_454 2_554 ?
O12 Eu1 C19 98.5(2) . 2_454 ?
O1W Eu1 C19 69.0(2) . 2_454 ?
O14 Eu1 C19 138.4(2) 2_545 2_454 ?
O11 Eu1 C19 82.5(2) 2 2_454 ?
O18 Eu1 C19 95.9(2) 2_554 2_454 ?
O15 Eu1 C19 26.5(2) 2_454 2_454 ?
O17 Eu1 C19 142.6(2) 2_554 2_454 ?
O16 Eu1 C19 25.8(2) 2_454 2_454 ?
C20 Eu1 C19 119.3(2) 2_554 2_454 ?
O12 Eu1 C17 82.0(2) . 2 ?
O1W Eu1 C17 165.4(2) . 2 ?
O14 Eu1 C17 118.0(2) 2_545 2 ?
O11 Eu1 C17 21.2(2) 2 2 ?
O18 Eu1 C17 91.3(2) 2_554 2 ?
O15 Eu1 C17 100.0(2) 2_454 2 ?
O17 Eu1 C17 65.0(2) 2_554 2 ?
O16 Eu1 C17 95.5(2) 2_454 2 ?
C20 Eu1 C17 76.0(2) 2_554 2 ?
C19 Eu1 C17 100.7(2) 2_454 2 ?
C17 O11 Eu1 115.4(5) . 2 ?
C17 O12 Eu1 138.3(5) . . ?
C18 O14 Eu1 138.1(5) . 2_545 ?
C19 O15 Eu1 94.7(5) . 2_454 ?
C19 O16 Eu1 91.5(5) . 2_454 ?
C20 O17 Eu1 90.9(5) . 2_554 ?
C20 O18 Eu1 95.0(5) . 2_554 ?
C12 C11 C16 120.4(7) . . ?
C12 C11 C17 119.9(7) . . ?
C16 C11 C17 119.7(7) . . ?
C13 C12 C11 121.1(8) . . ?
C12 C13 C14 117.7(7) . . ?
C12 C13 C18 120.6(8) . . ?
C14 C13 C18 121.7(8) . . ?
C15 C14 C13 122.6(8) . . ?
C14 C15 C16 117.6(8) . . ?
C14 C15 C21 122.2(7) . . ?
C16 C15 C21 120.2(7) . . ?
C11 C16 C15 120.4(7) . . ?
O11 C17 O12 123.4(7) . . ?
O11 C17 C11 117.8(7) . . ?
O12 C17 C11 118.8(7) . . ?
O11 C17 Eu1 43.5(4) . 2 ?
O12 C17 Eu1 81.2(5) . 2 ?
C11 C17 Eu1 156.8(5) . 2 ?
O13 C18 O14 124.4(7) . . ?
O13 C18 C13 116.5(7) . . ?
O14 C18 C13 119.0(7) . . ?
O16 C19 O15 120.9(8) . . ?
O16 C19 C33 120.6(8) . . ?
O15 C19 C33 118.5(8) . . ?
O16 C19 Eu1 62.7(4) . 2_454 ?
O15 C19 Eu1 58.8(4) . 2_454 ?
C33 C19 Eu1 170.3(6) . 2_454 ?
O18 C20 O17 121.1(8) . . ?
O18 C20 C35 119.4(7) . . ?
O17 C20 C35 119.5(8) . . ?
O18 C20 Eu1 58.8(4) . 2_554 ?
O17 C20 Eu1 62.5(4) . 2_554 ?
C35 C20 Eu1 173.2(5) . 2_554 ?
C26 C21 C22 117.5(8) . . ?
C26 C21 C15 122.4(7) . . ?
C22 C21 C15 120.1(7) . . ?
C23 C22 C21 120.1(8) . . ?
C24 C23 C22 122.0(8) . . ?
C23 C24 C25 119.4(8) . . ?
C26 C25 C24 118.6(8) . . ?
C26 C25 C31 120.8(7) . . ?
C24 C25 C31 120.6(7) . . ?
C25 C26 C21 122.4(8) . . ?
C36 C31 C32 117.3(7) . . ?
C36 C31 C25 119.5(7) . . ?
C32 C31 C25 123.2(7) . . ?
C33 C32 C31 121.8(8) . . ?
C34 C33 C32 118.9(8) . . ?
C34 C33 C19 119.6(8) . . ?
C32 C33 C19 121.5(8) . . ?
C35 C34 C33 120.7(8) . . ?
C34 C35 C36 119.6(8) . . ?
C34 C35 C20 120.0(7) . . ?
C36 C35 C20 120.2(7) . . ?
C31 C36 C35 121.7(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1W Eu1 O12 C17 76.7(8) . . . . ?
O14 Eu1 O12 C17 9.4(8) 2_545 . . . ?
O11 Eu1 O12 C17 -129.5(8) 2 . . . ?
O18 Eu1 O12 C17 -48.7(13) 2_554 . . . ?
O15 Eu1 O12 C17 143.9(9) 2_454 . . . ?
O17 Eu1 O12 C17 -54.1(9) 2_554 . . . ?
O16 Eu1 O12 C17 155.7(8) 2_454 . . . ?
C20 Eu1 O12 C17 -55.1(9) 2_554 . . . ?
C19 Eu1 O12 C17 147.4(8) 2_454 . . . ?
C17 Eu1 O12 C17 -112.9(8) 2 . . . ?
C16 C11 C12 C13 1.9(13) . . . . ?
C17 C11 C12 C13 -179.0(8) . . . . ?
C11 C12 C13 C14 -0.6(13) . . . . ?
C11 C12 C13 C18 178.7(8) . . . . ?
C12 C13 C14 C15 -2.8(13) . . . . ?
C18 C13 C14 C15 177.9(7) . . . . ?
C13 C14 C15 C16 4.8(12) . . . . ?
C13 C14 C15 C21 -173.9(8) . . . . ?
C12 C11 C16 C15 0.2(12) . . . . ?
C17 C11 C16 C15 -178.9(7) . . . . ?
C14 C15 C16 C11 -3.4(12) . . . . ?
C21 C15 C16 C11 175.4(7) . . . . ?
Eu1 O11 C17 O12 16.4(10) 2 . . . ?
Eu1 O11 C17 C11 -162.5(5) 2 . . . ?
Eu1 O12 C17 O11 101.2(10) . . . . ?
Eu1 O12 C17 C11 -79.8(10) . . . . ?
Eu1 O12 C17 Eu1 112.6(7) . . . 2 ?
C12 C11 C17 O11 -9.2(11) . . . . ?
C16 C11 C17 O11 169.9(8) . . . . ?
C12 C11 C17 O12 171.8(8) . . . . ?
C16 C11 C17 O12 -9.1(11) . . . . ?
C12 C11 C17 Eu1 -40.9(17) . . . 2 ?
C16 C11 C17 Eu1 138.2(11) . . . 2 ?
Eu1 O14 C18 O13 -22.1(14) 2_545 . . . ?
Eu1 O14 C18 C13 157.5(6) 2_545 . . . ?
C12 C13 C18 O13 24.5(12) . . . . ?
C14 C13 C18 O13 -156.2(8) . . . . ?
C12 C13 C18 O14 -155.0(8) . . . . ?
C14 C13 C18 O14 24.3(12) . . . . ?
Eu1 O16 C19 O15 -8.7(9) 2_454 . . . ?
Eu1 O16 C19 C33 169.5(7) 2_454 . . . ?
Eu1 O15 C19 O16 9.0(9) 2_454 . . . ?
Eu1 O15 C19 C33 -169.2(6) 2_454 . . . ?
Eu1 O18 C20 O17 -5.9(8) 2_554 . . . ?
Eu1 O18 C20 C35 172.4(6) 2_554 . . . ?
Eu1 O17 C20 O18 5.7(8) 2_554 . . . ?
Eu1 O17 C20 C35 -172.6(6) 2_554 . . . ?
C14 C15 C21 C26 -163.1(8) . . . . ?
C16 C15 C21 C26 18.2(12) . . . . ?
C14 C15 C21 C22 17.6(12) . . . . ?
C16 C15 C21 C22 -161.1(8) . . . . ?
C26 C21 C22 C23 0.3(13) . . . . ?
C15 C21 C22 C23 179.7(8) . . . . ?
C21 C22 C23 C24 0.6(15) . . . . ?
C22 C23 C24 C25 -1.3(14) . . . . ?
C23 C24 C25 C26 1.1(13) . . . . ?
C23 C24 C25 C31 178.7(8) . . . . ?
C24 C25 C26 C21 -0.2(13) . . . . ?
C31 C25 C26 C21 -177.8(8) . . . . ?
C22 C21 C26 C25 -0.5(13) . . . . ?
C15 C21 C26 C25 -179.9(8) . . . . ?
C26 C25 C31 C36 36.3(12) . . . . ?
C24 C25 C31 C36 -141.2(8) . . . . ?
C26 C25 C31 C32 -146.5(8) . . . . ?
C24 C25 C31 C32 36.0(12) . . . . ?
C36 C31 C32 C33 1.6(12) . . . . ?
C25 C31 C32 C33 -175.6(8) . . . . ?
C31 C32 C33 C34 0.0(12) . . . . ?
C31 C32 C33 C19 177.4(7) . . . . ?
O16 C19 C33 C34 -170.3(8) . . . . ?
O15 C19 C33 C34 7.9(12) . . . . ?
Eu1 C19 C33 C34 -63(4) 2_454 . . . ?
O16 C19 C33 C32 12.2(12) . . . . ?
O15 C19 C33 C32 -169.5(8) . . . . ?
Eu1 C19 C33 C32 119(3) 2_454 . . . ?
C32 C33 C34 C35 -1.3(12) . . . . ?
C19 C33 C34 C35 -178.8(7) . . . . ?
C33 C34 C35 C36 1.1(12) . . . . ?
C33 C34 C35 C20 177.0(7) . . . . ?
O18 C20 C35 C34 160.6(8) . . . . ?
O17 C20 C35 C34 -21.1(12) . . . . ?
Eu1 C20 C35 C34 -126(5) 2_554 . . . ?
O18 C20 C35 C36 -23.5(12) . . . . ?
O17 C20 C35 C36 154.9(8) . . . . ?
Eu1 C20 C35 C36 50(5) 2_554 . . . ?
C32 C31 C36 C35 -1.8(12) . . . . ?
C25 C31 C36 C35 175.5(8) . . . . ?
C34 C35 C36 C31 0.6(12) . . . . ?
C20 C35 C36 C31 -175.4(7) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O18 0.87 2.92 3.090(9) 93.0 2_554

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        25.02
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         4.543
_refine_diff_density_min         -1.544
_refine_diff_density_rms         0.265
