# Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2020

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_LTP
_database_code_depnum_ccdc_archive 'CCDC 2023264'
loop_
_audit_author_name
_audit_author_address
'Chao Shi'
;Jiangxi University of Science and Technology
China
;
_audit_update_record             
;
2020-08-14 deposited with the CCDC.	2020-10-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Eu N8 O24 Rb, 4(C7 H12 N O)'
_chemical_formula_sum            'C28 H48 Eu N12 O28 Rb'
_chemical_formula_weight         1238.22

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.8880(3)
_cell_length_b                   9.9339(3)
_cell_length_c                   12.5623(5)
_cell_angle_alpha                67.454(4)
_cell_angle_beta                 88.996(3)
_cell_angle_gamma                89.379(3)
_cell_volume                     1139.46(7)
_cell_formula_units_Z            1
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    14935
_cell_measurement_theta_min      2.060
_cell_measurement_theta_max      30.877

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.804
_exptl_crystal_F_000             624
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.20
_exptl_absorpt_coefficient_mu    2.545
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  Rigaku
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            14935
_diffrn_reflns_av_unetI/netI     0.0226
_diffrn_reflns_av_R_equivalents  0.0202
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_theta_min         2.060
_diffrn_reflns_theta_max         30.877
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.788
_diffrn_measured_fraction_theta_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.788
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.788
_diffrn_reflns_point_group_measured_fraction_full 1.000
_reflns_number_total             7188
_reflns_number_gt                5643
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1104P)²+4.2569P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         5663
_refine_ls_number_parameters     319
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0584
_refine_ls_R_factor_gt           0.0582
_refine_ls_wR_factor_ref         0.1763
_refine_ls_wR_factor_gt          0.1759
_refine_ls_goodness_of_fit_ref   1.173
_refine_ls_restrained_S_all      1.173
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.001

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
N6 N 0.5103(8) 0.4471(7) 0.2947(7) 0.0606(17) Uani 1 1 d . . . . .
H6C H 0.5180 0.5498 0.2842 0.073 Uiso 1 1 calc R U . . .
N4 N 0.5784(6) -0.2099(7) 1.2739(5) 0.0455(12) Uani 1 1 d . . . . .
O10 O 0.4699(6) -0.2371(8) 1.2376(7) 0.0720(19) Uani 1 1 d . . . . .
C10 C 0.4850(12) 0.1838(11) 0.3258(11) 0.072(3) Uani 1 1 d . . . . .
H10 H 0.4755 0.0805 0.3390 0.086 Uiso 1 1 calc R U . . .
C14 C 0.6247(12) 0.2135(13) 0.3616(13) 0.087(4) Uani 1 1 d . . . . .
H14A H 0.6368 0.1576 0.4432 0.105 Uiso 1 1 calc R U . . .
H14B H 0.6940 0.1837 0.3194 0.105 Uiso 1 1 calc R U . . .
C13 C 0.6386(11) 0.3731(14) 0.3368(13) 0.090(4) Uani 1 1 d . . . . .
H13A H 0.6635 0.3864 0.4065 0.108 Uiso 1 1 calc R U . . .
H13B H 0.7093 0.4146 0.2793 0.108 Uiso 1 1 calc R U . . .
C2 C 0.8817(9) 0.2942(8) 0.6191(7) 0.0486(16) Uani 1 1 d . . . . .
C1 C 1.0293(11) 0.3088(9) 0.6370(9) 0.066(2) Uani 1 1 d . . . . .
H1A H 1.0764 0.3494 0.5632 0.079 Uiso 1 1 calc R U . . .
H1B H 1.0420 0.3737 0.6773 0.079 Uiso 1 1 calc R U . . .
N5 N 1.0842(7) 0.1619(7) 0.7061(6) 0.0524(14) Uani 1 1 d . . . . .
H5C H 1.1810 0.1697 0.7182 0.063 Uiso 1 1 calc R U . . .
C6 C 1.0647(9) 0.0638(10) 0.6412(9) 0.061(2) Uani 1 1 d . . . . .
H6A H 1.1105 0.1046 0.5668 0.073 Uiso 1 1 calc R U . . .
H6B H 1.1037 -0.0313 0.6840 0.073 Uiso 1 1 calc R U . . .
C7 C 0.9168(9) 0.0489(9) 0.6246(9) 0.063(2) Uani 1 1 d . . . . .
H7A H 0.8910 -0.0527 0.6618 0.075 Uiso 1 1 calc R U . . .
H7B H 0.8986 0.0804 0.5430 0.075 Uiso 1 1 calc R U . . .
C4 C 0.8601(11) 0.0878(11) 0.8014(8) 0.073(3) Uani 1 1 d . . . . .
H4A H 0.8298 -0.0121 0.8398 0.087 Uiso 1 1 calc R U . . .
H4B H 0.8098 0.1479 0.8337 0.087 Uiso 1 1 calc R U . . .
Eu1 Eu 0.0000 0.5000 1.0000 0.02157(13) Uani 1 2 d S . P . .
N1 N -0.0200(6) 0.6322(6) 0.7421(4) 0.0409(11) Uani 1 1 d . . . . .
O11 O 0.6255(9) -0.0830(7) 1.2341(6) 0.0727(19) Uani 1 1 d . . . . .
N3 N 0.2154(6) 0.7121(7) 0.9914(6) 0.0420(12) Uani 1 1 d . . . . .
O6 O 0.3006(8) 0.2195(9) 0.9576(8) 0.087(3) Uani 1 1 d . . . . .
N2 N 0.2131(6) 0.2990(6) 0.9718(5) 0.0424(12) Uani 1 1 d . . . . .
O5 O 0.1714(7) 0.2898(7) 1.0680(6) 0.0648(16) Uani 1 1 d . . . . .
O4 O 0.1558(6) 0.3921(7) 0.8850(6) 0.0638(14) Uani 1 1 d . . . . .
C3 C 0.8345(8) 0.1391(9) 0.6749(8) 0.0518(17) Uani 1 1 d . . . . .
H3 H 0.7380 0.1326 0.6610 0.062 Uiso 1 1 calc R U . . .
O2 O 0.0559(8) 0.6848(7) 0.7967(6) 0.0671(16) Uani 1 1 d . . . . .
O3 O -0.0239(8) 0.6832(8) 0.6372(5) 0.080(2) Uani 1 1 d . . . . .
O12 O 0.6502(7) -0.3106(7) 1.3371(6) 0.0685(16) Uani 1 1 d . . . . .
O9 O 0.3057(8) 0.7948(10) 0.9922(8) 0.089(3) Uani 1 1 d . . . . .
O8 O 0.0942(7) 0.7396(7) 1.0003(6) 0.0656(15) Uani 1 1 d . . . . .
O7 O 0.2442(6) 0.5915(7) 0.9827(6) 0.0660(15) Uani 1 1 d . . . . .
O13 O 0.8108(10) 0.3977(8) 0.5620(8) 0.099(3) Uani 1 1 d . . . . .
Rb1 Rb 0.5000 0.0000 1.0000 0.0386(2) Uani 1 2 d S . P . .
C5 C 1.0125(14) 0.0970(13) 0.8211(8) 0.077(3) Uani 1 1 d . . . . .
H5A H 1.0269 0.1573 0.8650 0.092 Uiso 1 1 calc R U . . .
H5B H 1.0482 0.0004 0.8644 0.092 Uiso 1 1 calc R U . . .
C9 C 0.3910(11) 0.2243(13) 0.3980(10) 0.082(3) Uani 1 1 d . . . . .
C8 C 0.3977(15) 0.3769(13) 0.3816(12) 0.098(4) Uani 1 1 d . . . . .
H8A H 0.4163 0.3856 0.4543 0.117 Uiso 1 1 calc R U . . .
H8B H 0.3122 0.4248 0.3533 0.117 Uiso 1 1 calc R U . . .
C11 C 0.4606(14) 0.2759(16) 0.2048(11) 0.094(4) Uani 1 1 d . . . . .
H11A H 0.3699 0.2593 0.1843 0.113 Uiso 1 1 calc R U . . .
H11B H 0.5244 0.2509 0.1557 0.113 Uiso 1 1 calc R U . . .
C12 C 0.4769(15) 0.4389(17) 0.1862(9) 0.101(5) Uani 1 1 d . . . . .
H12A H 0.5481 0.4828 0.1297 0.122 Uiso 1 1 calc R U . . .
H12B H 0.3933 0.4914 0.1577 0.122 Uiso 1 1 calc R U . . .
O22 O 0.3261(14) 0.1243(15) 0.4668(15) 0.181(7) Uani 1 1 d . . . . .
O1 O -0.0965(7) 0.5299(8) 0.8029(6) 0.0706(17) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
N6 C12 1.441(15) . ?
N6 C13 1.461(13) . ?
N6 C8 1.519(13) . ?
N6 H6C 0.9800 . ?
N4 O12 1.237(8) . ?
N4 O10 1.244(9) . ?
N4 O11 1.256(9) . ?
O10 Rb1 3.023(7) . ?
C10 C9 1.445(17) . ?
C10 C11 1.465(17) . ?
C10 C14 1.527(15) . ?
C10 H10 0.9800 . ?
C14 C13 1.501(17) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C2 O13 1.225(10) . ?
C2 C3 1.503(11) . ?
C2 C1 1.497(13) . ?
C1 N5 1.485(11) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
N5 C5 1.505(13) . ?
N5 C6 1.506(11) . ?
N5 H5C 0.9800 . ?
C6 C7 1.498(13) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C3 1.505(12) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C4 C3 1.496(13) . ?
C4 C5 1.540(16) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
Eu1 O2 2.565(7) 2_567 ?
Eu1 O2 2.565(7) . ?
Eu1 O5 2.563(6) 2_567 ?
Eu1 O5 2.563(6) . ?
Eu1 O7 2.565(6) . ?
Eu1 O7 2.565(6) 2_567 ?
Eu1 O8 2.567(6) . ?
Eu1 O8 2.567(6) 2_567 ?
Eu1 O1 2.578(7) . ?
Eu1 O1 2.578(7) 2_567 ?
Eu1 O4 2.585(6) 2_567 ?
Eu1 O4 2.585(6) . ?
N1 O3 1.218(7) . ?
N1 O1 1.260(9) . ?
N1 O2 1.268(9) . ?
O11 Rb1 3.019(7) . ?
N3 O8 1.239(9) . ?
N3 O9 1.222(9) . ?
N3 O7 1.273(9) . ?
O6 N2 1.221(8) . ?
O6 Rb1 2.825(6) . ?
N2 O5 1.240(9) . ?
N2 O4 1.266(8) . ?
C3 H3 0.9800 . ?
O9 Rb1 2.846(6) 1_565 ?
Rb1 O6 2.825(6) 2_657 ?
Rb1 O9 2.846(6) 1_545 ?
Rb1 O9 2.846(6) 2_667 ?
Rb1 O11 3.019(7) 2_657 ?
Rb1 O10 3.023(7) 2_657 ?
Rb1 N4 3.368(6) 2_657 ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C9 O22 1.217(14) . ?
C9 C8 1.452(16) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C11 C12 1.55(2) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C12 N6 C13 110.7(10) . . ?
C12 N6 C8 108.9(10) . . ?
C13 N6 C8 110.0(9) . . ?
C12 N6 H6C 109.1 . . ?
C13 N6 H6C 109.1 . . ?
C8 N6 H6C 109.1 . . ?
O12 N4 O10 120.1(7) . . ?
O12 N4 O11 118.7(7) . . ?
O10 N4 O11 120.4(7) . . ?
N4 O10 Rb1 95.0(4) . . ?
C9 C10 C11 109.1(10) . . ?
C9 C10 C14 104.9(10) . . ?
C11 C10 C14 110.6(11) . . ?
C9 C10 H10 110.7 . . ?
C11 C10 H10 110.7 . . ?
C14 C10 H10 110.7 . . ?
C13 C14 C10 109.7(8) . . ?
C13 C14 H14A 109.7 . . ?
C10 C14 H14A 109.7 . . ?
C13 C14 H14B 109.7 . . ?
C10 C14 H14B 109.7 . . ?
H14A C14 H14B 108.2 . . ?
N6 C13 C14 109.5(8) . . ?
N6 C13 H13A 109.8 . . ?
C14 C13 H13A 109.8 . . ?
N6 C13 H13B 109.8 . . ?
C14 C13 H13B 109.8 . . ?
H13A C13 H13B 108.2 . . ?
O13 C2 C3 125.0(9) . . ?
O13 C2 C1 122.8(9) . . ?
C3 C2 C1 112.2(7) . . ?
N5 C1 C2 108.4(7) . . ?
N5 C1 H1A 110.0 . . ?
C2 C1 H1A 110.0 . . ?
N5 C1 H1B 110.0 . . ?
C2 C1 H1B 110.0 . . ?
H1A C1 H1B 108.4 . . ?
C1 N5 C5 110.9(8) . . ?
C1 N5 C6 109.0(7) . . ?
C5 N5 C6 109.0(7) . . ?
C1 N5 H5C 109.3 . . ?
C5 N5 H5C 109.3 . . ?
C6 N5 H5C 109.3 . . ?
C7 C6 N5 109.6(6) . . ?
C7 C6 H6A 109.7 . . ?
N5 C6 H6A 109.7 . . ?
C7 C6 H6B 109.7 . . ?
N5 C6 H6B 109.7 . . ?
H6A C6 H6B 108.2 . . ?
C6 C7 C3 110.6(7) . . ?
C6 C7 H7A 109.5 . . ?
C3 C7 H7A 109.5 . . ?
C6 C7 H7B 109.5 . . ?
C3 C7 H7B 109.5 . . ?
H7A C7 H7B 108.1 . . ?
C3 C4 C5 109.5(7) . . ?
C3 C4 H4A 109.8 . . ?
C5 C4 H4A 109.8 . . ?
C3 C4 H4B 109.8 . . ?
C5 C4 H4B 109.8 . . ?
H4A C4 H4B 108.2 . . ?
O2 Eu1 O2 180.0 2_567 . ?
O2 Eu1 O5 112.2(2) 2_567 2_567 ?
O2 Eu1 O5 67.8(2) . 2_567 ?
O2 Eu1 O5 67.8(2) 2_567 . ?
O2 Eu1 O5 112.2(2) . . ?
O5 Eu1 O5 180.0 2_567 . ?
O2 Eu1 O7 111.9(2) 2_567 . ?
O2 Eu1 O7 68.1(2) . . ?
O5 Eu1 O7 112.1(2) 2_567 . ?
O5 Eu1 O7 67.9(2) . . ?
O2 Eu1 O7 68.1(2) 2_567 2_567 ?
O2 Eu1 O7 111.9(2) . 2_567 ?
O5 Eu1 O7 67.9(2) 2_567 2_567 ?
O5 Eu1 O7 112.1(2) . 2_567 ?
O7 Eu1 O7 180.0 . 2_567 ?
O2 Eu1 O8 112.7(2) 2_567 . ?
O2 Eu1 O8 67.3(2) . . ?
O5 Eu1 O8 67.0(2) 2_567 . ?
O5 Eu1 O8 113.0(2) . . ?
O7 Eu1 O8 49.4(2) . . ?
O7 Eu1 O8 130.6(2) 2_567 . ?
O2 Eu1 O8 67.3(2) 2_567 2_567 ?
O2 Eu1 O8 112.7(2) . 2_567 ?
O5 Eu1 O8 113.0(2) 2_567 2_567 ?
O5 Eu1 O8 67.0(2) . 2_567 ?
O7 Eu1 O8 130.6(2) . 2_567 ?
O7 Eu1 O8 49.4(2) 2_567 2_567 ?
O8 Eu1 O8 180.0 . 2_567 ?
O2 Eu1 O1 130.7(2) 2_567 . ?
O2 Eu1 O1 49.3(2) . . ?
O5 Eu1 O1 69.3(2) 2_567 . ?
O5 Eu1 O1 110.7(2) . . ?
O7 Eu1 O1 112.1(2) . . ?
O7 Eu1 O1 67.9(2) 2_567 . ?
O8 Eu1 O1 112.3(2) . . ?
O8 Eu1 O1 67.7(2) 2_567 . ?
O2 Eu1 O1 49.3(2) 2_567 2_567 ?
O2 Eu1 O1 130.7(2) . 2_567 ?
O5 Eu1 O1 110.7(2) 2_567 2_567 ?
O5 Eu1 O1 69.3(2) . 2_567 ?
O7 Eu1 O1 67.9(2) . 2_567 ?
O7 Eu1 O1 112.1(2) 2_567 2_567 ?
O8 Eu1 O1 67.7(2) . 2_567 ?
O8 Eu1 O1 112.3(2) 2_567 2_567 ?
O1 Eu1 O1 180.0(4) . 2_567 ?
O2 Eu1 O4 67.4(2) 2_567 2_567 ?
O2 Eu1 O4 112.6(2) . 2_567 ?
O5 Eu1 O4 49.0(2) 2_567 2_567 ?
O5 Eu1 O4 131.0(2) . 2_567 ?
O7 Eu1 O4 112.8(2) . 2_567 ?
O7 Eu1 O4 67.2(2) 2_567 2_567 ?
O8 Eu1 O4 68.5(2) . 2_567 ?
O8 Eu1 O4 111.5(2) 2_567 2_567 ?
O1 Eu1 O4 113.1(2) . 2_567 ?
O1 Eu1 O4 66.9(2) 2_567 2_567 ?
O2 Eu1 O4 112.6(2) 2_567 . ?
O2 Eu1 O4 67.4(2) . . ?
O5 Eu1 O4 131.0(2) 2_567 . ?
O5 Eu1 O4 49.0(2) . . ?
O7 Eu1 O4 67.2(2) . . ?
O7 Eu1 O4 112.8(2) 2_567 . ?
O8 Eu1 O4 111.5(2) . . ?
O8 Eu1 O4 68.5(2) 2_567 . ?
O1 Eu1 O4 66.9(2) . . ?
O1 Eu1 O4 113.1(2) 2_567 . ?
O4 Eu1 O4 180.0 2_567 . ?
O3 N1 O1 122.1(7) . . ?
O3 N1 O2 121.7(7) . . ?
O1 N1 O2 116.0(6) . . ?
N4 O11 Rb1 94.9(4) . . ?
O8 N3 O9 122.5(8) . . ?
O8 N3 O7 117.3(6) . . ?
O9 N3 O7 120.2(8) . . ?
N2 O6 Rb1 162.3(6) . . ?
O6 N2 O5 123.6(6) . . ?
O6 N2 O4 119.5(7) . . ?
O5 N2 O4 116.9(6) . . ?
N2 O5 Eu1 97.9(4) . . ?
N2 O4 Eu1 96.1(4) . . ?
C2 C3 C4 108.0(8) . . ?
C2 C3 C7 108.0(7) . . ?
C4 C3 C7 109.5(7) . . ?
C2 C3 H3 110.5 . . ?
C4 C3 H3 110.5 . . ?
C7 C3 H3 110.5 . . ?
N1 O2 Eu1 97.3(4) . . ?
N3 O9 Rb1 175.4(8) . 1_565 ?
N3 O8 Eu1 97.0(4) . . ?
N3 O7 Eu1 96.2(4) . . ?
O6 Rb1 O6 180.0 2_657 . ?
O6 Rb1 O9 88.2(3) 2_657 1_545 ?
O6 Rb1 O9 91.8(3) . 1_545 ?
O6 Rb1 O9 91.8(3) 2_657 2_667 ?
O6 Rb1 O9 88.2(3) . 2_667 ?
O9 Rb1 O9 180.0(3) 1_545 2_667 ?
O6 Rb1 O11 67.6(2) 2_657 . ?
O6 Rb1 O11 112.4(2) . . ?
O9 Rb1 O11 113.1(2) 1_545 . ?
O9 Rb1 O11 66.9(2) 2_667 . ?
O6 Rb1 O11 112.4(2) 2_657 2_657 ?
O6 Rb1 O11 67.6(2) . 2_657 ?
O9 Rb1 O11 66.9(2) 1_545 2_657 ?
O9 Rb1 O11 113.1(2) 2_667 2_657 ?
O11 Rb1 O11 180.0 . 2_657 ?
O6 Rb1 O10 67.9(2) 2_657 . ?
O6 Rb1 O10 112.1(2) . . ?
O9 Rb1 O10 71.1(3) 1_545 . ?
O9 Rb1 O10 108.9(3) 2_667 . ?
O11 Rb1 O10 42.08(19) . . ?
O11 Rb1 O10 137.92(19) 2_657 . ?
O6 Rb1 O10 112.1(2) 2_657 2_657 ?
O6 Rb1 O10 67.9(2) . 2_657 ?
O9 Rb1 O10 108.9(2) 1_545 2_657 ?
O9 Rb1 O10 71.1(3) 2_667 2_657 ?
O11 Rb1 O10 137.92(19) . 2_657 ?
O11 Rb1 O10 42.08(19) 2_657 2_657 ?
O10 Rb1 O10 180.0 . 2_657 ?
O6 Rb1 N4 119.4(2) 2_657 2_657 ?
O6 Rb1 N4 60.6(2) . 2_657 ?
O9 Rb1 N4 88.3(2) 1_545 2_657 ?
O9 Rb1 N4 91.7(2) 2_667 2_657 ?
O11 Rb1 N4 158.19(16) . 2_657 ?
O11 Rb1 N4 21.81(16) 2_657 2_657 ?
O10 Rb1 N4 158.41(16) . 2_657 ?
O10 Rb1 N4 21.59(16) 2_657 2_657 ?
N5 C5 C4 109.1(7) . . ?
N5 C5 H5A 109.9 . . ?
C4 C5 H5A 109.9 . . ?
N5 C5 H5B 109.9 . . ?
C4 C5 H5B 109.9 . . ?
H5A C5 H5B 108.3 . . ?
O22 C9 C10 115.3(14) . . ?
O22 C9 C8 130.7(14) . . ?
C10 C9 C8 113.8(8) . . ?
C9 C8 N6 108.0(8) . . ?
C9 C8 H8A 110.1 . . ?
N6 C8 H8A 110.1 . . ?
C9 C8 H8B 110.1 . . ?
N6 C8 H8B 110.1 . . ?
H8A C8 H8B 108.4 . . ?
C10 C11 C12 109.7(9) . . ?
C10 C11 H11A 109.7 . . ?
C12 C11 H11A 109.7 . . ?
C10 C11 H11B 109.7 . . ?
C12 C11 H11B 109.7 . . ?
H11A C11 H11B 108.2 . . ?
N6 C12 C11 108.6(8) . . ?
N6 C12 H12A 110.0 . . ?
C11 C12 H12A 110.0 . . ?
N6 C12 H12B 110.0 . . ?
C11 C12 H12B 110.0 . . ?
H12A C12 H12B 108.4 . . ?
N1 O1 Eu1 96.9(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O12 N4 O10 Rb1 -141.0(6) . . . . ?
O11 N4 O10 Rb1 28.7(8) . . . . ?
C9 C10 C14 C13 -62.5(14) . . . . ?
C11 C10 C14 C13 55.0(15) . . . . ?
C12 N6 C13 C14 -64.1(14) . . . . ?
C8 N6 C13 C14 56.2(15) . . . . ?
C10 C14 C13 N6 4.4(17) . . . . ?
O13 C2 C1 N5 -177.8(9) . . . . ?
C3 C2 C1 N5 -0.1(11) . . . . ?
C2 C1 N5 C5 -59.7(10) . . . . ?
C2 C1 N5 C6 60.3(10) . . . . ?
C1 N5 C6 C7 -61.8(10) . . . . ?
C5 N5 C6 C7 59.3(10) . . . . ?
N5 C6 C7 C3 1.5(11) . . . . ?
O12 N4 O11 Rb1 141.2(6) . . . . ?
O10 N4 O11 Rb1 -28.7(8) . . . . ?
Rb1 O6 N2 O5 -1(3) . . . . ?
Rb1 O6 N2 O4 -177(2) . . . . ?
O6 N2 O5 Eu1 179.4(8) . . . . ?
O4 N2 O5 Eu1 -4.1(7) . . . . ?
O6 N2 O4 Eu1 -179.3(8) . . . . ?
O5 N2 O4 Eu1 4.0(7) . . . . ?
O13 C2 C3 C4 -122.4(10) . . . . ?
C1 C2 C3 C4 59.8(10) . . . . ?
O13 C2 C3 C7 119.3(10) . . . . ?
C1 C2 C3 C7 -58.4(10) . . . . ?
C5 C4 C3 C2 -59.9(10) . . . . ?
C5 C4 C3 C7 57.4(10) . . . . ?
C6 C7 C3 C2 56.7(10) . . . . ?
C6 C7 C3 C4 -60.6(10) . . . . ?
O3 N1 O2 Eu1 -177.3(6) . . . . ?
O1 N1 O2 Eu1 6.7(7) . . . . ?
O9 N3 O8 Eu1 -177.1(9) . . . . ?
O7 N3 O8 Eu1 2.0(8) . . . . ?
O8 N3 O7 Eu1 -2.0(8) . . . . ?
O9 N3 O7 Eu1 177.1(9) . . . . ?
C1 N5 C5 C4 58.4(10) . . . . ?
C6 N5 C5 C4 -61.6(10) . . . . ?
C3 C4 C5 N5 2.8(12) . . . . ?
C11 C10 C9 O22 127.5(15) . . . . ?
C14 C10 C9 O22 -114.0(15) . . . . ?
C11 C10 C9 C8 -56.9(15) . . . . ?
C14 C10 C9 C8 61.5(14) . . . . ?
O22 C9 C8 N6 171.9(16) . . . . ?
C10 C9 C8 N6 -2.8(17) . . . . ?
C12 N6 C8 C9 62.6(14) . . . . ?
C13 N6 C8 C9 -58.9(14) . . . . ?
C9 C10 C11 C12 58.2(14) . . . . ?
C14 C10 C11 C12 -56.7(14) . . . . ?
C13 N6 C12 C11 61.7(13) . . . . ?
C8 N6 C12 C11 -59.3(13) . . . . ?
C10 C11 C12 N6 -0.3(16) . . . . ?
O3 N1 O1 Eu1 177.3(7) . . . . ?
O2 N1 O1 Eu1 -6.7(7) . . . . ?

_refine_diff_density_max         3.815
_refine_diff_density_min         -0.919
_refine_diff_density_rms         0.215


# start Validation Reply Form

_vrf_PLAT094_LTP                 
;
PROBLEM: Ratio of Maximum / Minimum Residual Density ....       4.15 Report
RESPONSE: The TWIN Refinement is meanlingless for the structure.
 Phase transition was also not found in the thermodynamic characterization.
Consequently, the model is not so perfect.
;
# end Validation Reply Form

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_HTP
_database_code_depnum_ccdc_archive 'CCDC 2023265'
loop_
_audit_author_name
_audit_author_address
'Chao Shi'
;Jiangxi University of Science and Technology
China
;
_audit_update_record             
;
2020-10-14 deposited with the CCDC.	2020-10-21 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2014/7
_shelx_SHELXL_version_number     2014/7
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'Eu N8 O24 Rb, 4(C7 H12 N O)'
_chemical_formula_sum            'C28 H48 Eu N12 O28 Rb'
_chemical_formula_weight         1238.22

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      orthorhombic
_space_group_IT_number           65
_space_group_name_H-M_alt        'C m m m'
_space_group_name_Hall           '-C 2 2'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z'

_cell_length_a                   10.0054(6)
_cell_length_b                   23.8579(15)
_cell_length_c                   9.9705(6)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2380.0(3)
_cell_formula_units_Z            2
_cell_measurement_temperature    478(2)
_cell_measurement_reflns_used    4530
_cell_measurement_theta_min      2.0980
_cell_measurement_theta_max      26.7340

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_F_000             1144
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.20
_exptl_absorpt_coefficient_mu    2.431
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      478(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  Rigaku
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            7072
_diffrn_reflns_av_unetI/netI     0.0177
_diffrn_reflns_av_R_equivalents  0.0208
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         2.043
_diffrn_reflns_theta_max         30.896
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.800
_diffrn_measured_fraction_theta_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.800
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.800
_diffrn_reflns_point_group_measured_fraction_full 0.999
_reflns_number_total             1706
_reflns_number_gt                1549
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    ?
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0675P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   .
_refine_ls_hydrogen_treatment    undef
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         1706
_refine_ls_number_parameters     148
_refine_ls_number_restraints     294
_refine_ls_R_factor_all          0.0444
_refine_ls_R_factor_gt           0.0395
_refine_ls_wR_factor_ref         0.0964
_refine_ls_wR_factor_gt          0.0945
_refine_ls_goodness_of_fit_ref   1.103
_refine_ls_restrained_S_all      1.095
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6163(8) 0.1818(5) 0.0758(9) 0.188(3) Uani 1 1 d . U . . .
C2 C 0.5000 0.1533(5) 0.1205(15) 0.190(4) Uani 1 2 d S TU P . .
C3 C 0.5000 0.0965(5) 0.080(2) 0.285(10) Uani 1 2 d S TU P . .
C4 C 0.0753(11) 0.1819(5) 0.6165(8) 0.210(4) Uani 1 1 d . U . . .
C5 C 0.1148(17) 0.1532(6) 0.5000 0.208(5) Uani 1 2 d S TU P . .
C6 C 0.074(2) 0.0980(6) 0.5000 0.301(11) Uani 1 2 d S TU P . .
Eu Eu 0.0000 1.0000 0.0000 0.06547(17) Uani 1 8 d S TU P . .
N1 N 0.2151(7) 1.0000 0.2151(7) 0.1205(16) Uani 1 2 d S TU P . .
N2 N 0.0000 0.8738(3) 0.0000 0.117(2) Uani 1 4 d S TU P . .
N3 N 0.552(5) 0.8531(10) 0.463(6) 0.266(10) Uani 0.25 1 d . U P . .
O1 O 0.2365(8) 1.0000 0.0959(9) 0.122(2) Uani 0.500(0) 2 d S TU P . .
O2 O 0.0928(10) 1.0000 0.2372(8) 0.126(2) Uani 0.500(0) 2 d S TU P . .
O4 O 0.2967(10) 1.0000 0.2981(10) 0.250(5) Uani 1 2 d S TU P . .
O5 O 0.0748(7) 0.9016(2) 0.0745(7) 0.1234(17) Uani 0.500(0) 1 d . U P . .
O6 O 0.0000 0.8244(3) 0.0000 0.221(6) Uani 1 4 d S TU P . .
O7 O 0.615(3) 0.8857(9) 0.5000 0.246(7) Uani 0.5 2 d S TU P . .
O8 O 0.5000 0.8790(9) 0.408(3) 0.252(7) Uani 0.5 2 d S TU P . .
O9 O 0.596(4) 0.8178(11) 0.422(3) 0.292(10) Uani 0.25 1 d . U P . .
O10 O 0.681(3) 0.2103(16) 0.160(3) 0.250(13) Uani 0.25 1 d . U P . .
O11 O 0.150(4) 0.209(2) 0.689(4) 0.34(2) Uani 0.25 1 d . U P . .
O3' O 0.1656(7) 1.0436(3) 0.1666(6) 0.1256(16) Uani 0.500(0) 1 d . U P . .
Rb Rb 0.5000 1.0000 0.5000 0.0941(3) Uani 1 8 d S TU P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O10 1.26(3) . ?
C1 C2 1.420(10) . ?
C1 C1 1.512(17) 10 ?
C2 C3 1.415(19) . ?
C2 C1 1.420(10) 12_655 ?
C3 C3 1.59(4) 10 ?
C4 O11 1.22(3) . ?
C4 C5 1.405(11) . ?
C4 C4 1.51(2) 12 ?
C5 C6 1.38(2) . ?
C5 C4 1.405(11) 10_556 ?
C6 C6 1.48(5) 3_556 ?
Eu O2 2.541(8) 9_575 ?
Eu O2 2.541(8) 10 ?
Eu O2 2.541(8) 2_575 ?
Eu O2 2.541(8) . ?
Eu O1 2.552(8) . ?
Eu O1 2.552(8) 9_575 ?
Eu O1 2.552(8) 10 ?
Eu O1 2.552(8) 2_575 ?
Eu O3' 2.567(6) . ?
Eu O3' 2.567(6) 9_575 ?
Eu O3' 2.567(6) 11_575 ?
Eu O3' 2.567(6) 3 ?
N1 O4 1.163(10) . ?
N1 O1 1.208(11) . ?
N1 O2 1.243(12) . ?
N1 O3' 1.250(7) . ?
N1 O3' 1.250(7) 11_575 ?
N2 O6 1.178(12) . ?
N2 O5 1.246(7) 3 ?
N2 O5 1.246(7) 10 ?
N2 O5 1.246(7) 12 ?
N2 O5 1.246(7) . ?
N3 N3 0.73(12) 10_556 ?
N3 O8 0.98(5) . ?
N3 O9 1.04(4) . ?
N3 N3 1.03(9) 12_655 ?
N3 O7 1.07(4) . ?
N3 N3 1.27(10) 3_656 ?
N3 O9 1.49(5) 10_556 ?
N3 O8 1.51(5) 10_556 ?
N3 O9 1.75(5) 12_655 ?
O1 O3' 1.444(9) 11_575 ?
O2 O3' 1.452(9) 11_575 ?
O4 Rb 2.862(6) . ?
O5 O5 1.486(15) 10 ?
O5 O5 1.497(15) 12 ?
O7 N3 1.07(4) 10_556 ?
O7 O8 1.48(3) 10_556 ?
O7 O9 1.81(3) 10_556 ?
O7 Rb 2.960(19) . ?
O8 N3 0.98(5) 12_655 ?
O8 O7 1.48(3) 3_656 ?
O8 N3 1.51(5) 10_556 ?
O8 N3 1.51(5) 3_656 ?
O8 O9 1.75(3) 12_655 ?
O8 Rb 3.03(2) . ?
O9 N3 1.49(5) 10_556 ?
O9 O9 1.55(6) 10_556 ?
O9 N3 1.75(5) 12_655 ?
Rb O4 2.862(6) 9_676 ?
Rb O4 2.862(6) 10_556 ?
Rb O4 2.862(6) 2_675 ?
Rb O7 2.96(2) 11_575 ?
Rb O7 2.96(2) 3_656 ?
Rb O7 2.960(19) 9_676 ?
Rb O8 3.03(2) 9_676 ?
Rb O8 3.03(2) 2_675 ?
Rb O8 3.03(2) 10_556 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O10 C1 C2 118.1(18) . . ?
O10 C1 C1 131.8(17) . 10 ?
C2 C1 C1 108.3(8) . 10 ?
C3 C2 C1 111.7(10) . 12_655 ?
C3 C2 C1 111.7(10) . . ?
C1 C2 C1 110.1(11) 12_655 . ?
C2 C3 C3 106.6(10) . 10 ?
O11 C4 C5 125(3) . . ?
O11 C4 C4 128(2) . 12 ?
C5 C4 C4 106.4(9) . 12 ?
C6 C5 C4 112.4(12) . 10_556 ?
C6 C5 C4 112.4(12) . . ?
C4 C5 C4 111.5(13) 10_556 . ?
C5 C6 C6 107.3(12) . 3_556 ?
O2 Eu O2 42.9(5) 9_575 10 ?
O2 Eu O2 137.1(5) 9_575 2_575 ?
O2 Eu O2 180.0 10 2_575 ?
O2 Eu O2 180.0 9_575 . ?
O2 Eu O2 137.1(5) 10 . ?
O2 Eu O2 42.9(5) 2_575 . ?
O2 Eu O1 133.4(3) 9_575 . ?
O2 Eu O1 90.5(3) 10 . ?
O2 Eu O1 89.5(3) 2_575 . ?
O2 Eu O1 46.6(3) . . ?
O2 Eu O1 46.6(3) 9_575 9_575 ?
O2 Eu O1 89.5(3) 10 9_575 ?
O2 Eu O1 90.5(3) 2_575 9_575 ?
O2 Eu O1 133.4(3) . 9_575 ?
O1 Eu O1 180.0 . 9_575 ?
O2 Eu O1 89.5(3) 9_575 10 ?
O2 Eu O1 46.6(3) 10 10 ?
O2 Eu O1 133.4(3) 2_575 10 ?
O2 Eu O1 90.5(3) . 10 ?
O1 Eu O1 44.0(4) . 10 ?
O1 Eu O1 136.0(4) 9_575 10 ?
O2 Eu O1 90.5(3) 9_575 2_575 ?
O2 Eu O1 133.4(3) 10 2_575 ?
O2 Eu O1 46.6(3) 2_575 2_575 ?
O2 Eu O1 89.5(3) . 2_575 ?
O1 Eu O1 136.0(4) . 2_575 ?
O1 Eu O1 44.0(4) 9_575 2_575 ?
O1 Eu O1 180.0 10 2_575 ?
O2 Eu O3' 147.0(2) 9_575 . ?
O2 Eu O3' 111.5(3) 10 . ?
O2 Eu O3' 68.5(3) 2_575 . ?
O2 Eu O3' 33.0(2) . . ?
O1 Eu O3' 32.8(2) . . ?
O1 Eu O3' 147.2(2) 9_575 . ?
O1 Eu O3' 69.1(2) 10 . ?
O1 Eu O3' 110.9(2) 2_575 . ?
O2 Eu O3' 33.0(2) 9_575 9_575 ?
O2 Eu O3' 68.5(3) 10 9_575 ?
O2 Eu O3' 111.5(3) 2_575 9_575 ?
O2 Eu O3' 147.0(2) . 9_575 ?
O1 Eu O3' 147.2(2) . 9_575 ?
O1 Eu O3' 32.8(2) 9_575 9_575 ?
O1 Eu O3' 110.9(2) 10 9_575 ?
O1 Eu O3' 69.1(2) 2_575 9_575 ?
O3' Eu O3' 180.0 . 9_575 ?
O2 Eu O3' 147.0(2) 9_575 11_575 ?
O2 Eu O3' 111.5(3) 10 11_575 ?
O2 Eu O3' 68.5(3) 2_575 11_575 ?
O2 Eu O3' 33.0(2) . 11_575 ?
O1 Eu O3' 32.8(2) . 11_575 ?
O1 Eu O3' 147.2(2) 9_575 11_575 ?
O1 Eu O3' 69.1(2) 10 11_575 ?
O1 Eu O3' 110.9(2) 2_575 11_575 ?
O3' Eu O3' 47.8(3) . 11_575 ?
O3' Eu O3' 132.2(3) 9_575 11_575 ?
O2 Eu O3' 33.0(2) 9_575 3 ?
O2 Eu O3' 68.5(3) 10 3 ?
O2 Eu O3' 111.5(3) 2_575 3 ?
O2 Eu O3' 147.0(2) . 3 ?
O1 Eu O3' 147.2(2) . 3 ?
O1 Eu O3' 32.8(2) 9_575 3 ?
O1 Eu O3' 110.9(2) 10 3 ?
O1 Eu O3' 69.1(2) 2_575 3 ?
O3' Eu O3' 132.2(3) . 3 ?
O3' Eu O3' 47.8(3) 9_575 3 ?
O3' Eu O3' 180.0 11_575 3 ?
O4 N1 O1 125.1(11) . . ?
O4 N1 O2 124.5(11) . . ?
O1 N1 O2 110.5(7) . . ?
O4 N1 O3' 123.6(4) . . ?
O1 N1 O3' 71.9(5) . . ?
O2 N1 O3' 71.3(5) . . ?
O4 N1 O3' 123.6(4) . 11_575 ?
O1 N1 O3' 71.9(5) . 11_575 ?
O2 N1 O3' 71.3(5) . 11_575 ?
O3' N1 O3' 112.8(7) . 11_575 ?
O6 N2 O5 122.1(4) . 3 ?
O6 N2 O5 122.1(4) . 10 ?
O5 N2 O5 73.9(7) 3 10 ?
O6 N2 O5 122.1(4) . 12 ?
O5 N2 O5 73.2(7) 3 12 ?
O5 N2 O5 115.7(8) 10 12 ?
O6 N2 O5 122.1(4) . . ?
O5 N2 O5 115.7(8) 3 . ?
O5 N2 O5 73.2(7) 10 . ?
O5 N2 O5 73.9(7) 12 . ?
N3 N3 O8 124(4) 10_556 . ?
N3 N3 O9 113(4) 10_556 . ?
O8 N3 O9 121(7) . . ?
N3 N3 N3 90.000(3) 10_556 12_655 ?
O8 N3 N3 58(3) . 12_655 ?
O9 N3 N3 115(4) . 12_655 ?
N3 N3 O7 70(3) 10_556 . ?
O8 N3 O7 93(2) . . ?
O9 N3 O7 118(6) . . ?
N3 N3 O7 126(3) 12_655 . ?
N3 N3 N3 55(5) 10_556 3_656 ?
O8 N3 N3 84(5) . 3_656 ?
O9 N3 N3 125(3) . 3_656 ?
N3 N3 N3 35(5) 12_655 3_656 ?
O7 N3 N3 107(5) . 3_656 ?
N3 N3 O9 39.8(19) 10_556 10_556 ?
O8 N3 O9 162(6) . 10_556 ?
O9 N3 O9 74(4) . 10_556 ?
N3 N3 O9 107(2) 12_655 10_556 ?
O7 N3 O9 88(4) . 10_556 ?
N3 N3 O9 79(5) 3_656 10_556 ?
N3 N3 O8 32.2(15) 10_556 10_556 ?
O8 N3 O8 92(4) . 10_556 ?
O9 N3 O8 145(5) . 10_556 ?
N3 N3 O8 70(2) 12_655 10_556 ?
O7 N3 O8 67(3) . 10_556 ?
N3 N3 O8 40(3) 3_656 10_556 ?
O9 N3 O8 72(2) 10_556 10_556 ?
N3 N3 O9 104(2) 10_556 12_655 ?
O8 N3 O9 74(4) . 12_655 ?
O9 N3 O9 83(4) . 12_655 ?
N3 N3 O9 32.4(14) 12_655 12_655 ?
O7 N3 O9 159(4) . 12_655 ?
N3 N3 O9 56(3) 3_656 12_655 ?
O9 N3 O9 99(3) 10_556 12_655 ?
O8 N3 O9 96(3) 10_556 12_655 ?
N1 O1 O3' 55.4(4) . 11_575 ?
N1 O1 Eu 101.7(6) . . ?
O3' O1 Eu 74.2(4) 11_575 . ?
N1 O2 O3' 54.6(5) . 11_575 ?
N1 O2 Eu 101.2(5) . . ?
O3' O2 Eu 74.5(4) 11_575 . ?
N1 O4 Rb 179.4(11) . . ?
N2 O5 O5 53.4(4) . 10 ?
N2 O5 O5 53.1(4) . 12 ?
O5 O5 O5 90.000(1) 10 12 ?
N2 O5 Eu 97.9(4) . . ?
O5 O5 Eu 73.22(17) 10 . ?
O5 O5 Eu 73.09(17) 12 . ?
N3 O7 N3 40(6) 10_556 . ?
N3 O7 O8 41(3) 10_556 10_556 ?
N3 O7 O8 71(3) . 10_556 ?
N3 O7 O9 30(3) 10_556 10_556 ?
N3 O7 O9 55(3) . 10_556 ?
O8 O7 O9 63.6(17) 10_556 10_556 ?
N3 O7 Rb 116(3) 10_556 . ?
N3 O7 Rb 116(3) . . ?
O8 O7 Rb 78.2(13) 10_556 . ?
O9 O7 Rb 141.7(15) 10_556 . ?
N3 O8 N3 64(6) 12_655 . ?
N3 O8 O7 46(3) 12_655 3_656 ?
N3 O8 O7 98(5) . 3_656 ?
N3 O8 N3 56(5) 12_655 10_556 ?
N3 O8 N3 23(5) . 10_556 ?
O7 O8 N3 78(3) 3_656 10_556 ?
N3 O8 N3 23(5) 12_655 3_656 ?
N3 O8 N3 56(5) . 3_656 ?
O7 O8 N3 41.9(18) 3_656 3_656 ?
N3 O8 N3 40(4) 10_556 3_656 ?
N3 O8 O9 30(4) 12_655 12_655 ?
N3 O8 O9 74(3) . 12_655 ?
O7 O8 O9 67.3(17) 3_656 12_655 ?
N3 O8 O9 77(2) 10_556 12_655 ?
N3 O8 O9 53.4(18) 3_656 12_655 ?
N3 O8 Rb 116(4) 12_655 . ?
N3 O8 Rb 116(4) . . ?
O7 O8 Rb 73.2(13) 3_656 . ?
N3 O8 Rb 97.7(14) 10_556 . ?
N3 O8 Rb 97.7(14) 3_656 . ?
O9 O8 Rb 140.3(14) 12_655 . ?
N3 O9 N3 27(5) . 10_556 ?
N3 O9 O9 67(4) . 10_556 ?
N3 O9 O9 39.8(19) 10_556 10_556 ?
N3 O9 N3 32(3) . 12_655 ?
N3 O9 N3 45(3) 10_556 12_655 ?
O9 O9 N3 76(2) 10_556 12_655 ?
N1 O3' Eu 99.7(4) . . ?
O4 Rb O4 180.0 . 9_676 ?
O4 Rb O4 89.4(5) . 10_556 ?
O4 Rb O4 90.6(5) 9_676 10_556 ?
O4 Rb O4 90.6(5) . 2_675 ?
O4 Rb O4 89.4(5) 9_676 2_675 ?
O4 Rb O4 180.0 10_556 2_675 ?
O4 Rb O7 106.1(4) . . ?
O4 Rb O7 73.9(4) 9_676 . ?
O4 Rb O7 106.1(4) 10_556 . ?
O4 Rb O7 73.9(4) 2_675 . ?
O4 Rb O7 106.1(4) . 11_575 ?
O4 Rb O7 73.9(4) 9_676 11_575 ?
O4 Rb O7 106.1(4) 10_556 11_575 ?
O4 Rb O7 73.9(4) 2_675 11_575 ?
O7 Rb O7 134.1(12) . 11_575 ?
O4 Rb O7 73.9(4) . 3_656 ?
O4 Rb O7 106.1(4) 9_676 3_656 ?
O4 Rb O7 73.9(4) 10_556 3_656 ?
O4 Rb O7 106.1(4) 2_675 3_656 ?
O7 Rb O7 45.9(12) . 3_656 ?
O7 Rb O7 180.0 11_575 3_656 ?
O4 Rb O7 73.9(4) . 9_676 ?
O4 Rb O7 106.1(4) 9_676 9_676 ?
O4 Rb O7 73.9(4) 10_556 9_676 ?
O4 Rb O7 106.1(4) 2_675 9_676 ?
O7 Rb O7 180.0 . 9_676 ?
O7 Rb O7 45.9(12) 11_575 9_676 ?
O7 Rb O7 134.1(12) 3_656 9_676 ?
O4 Rb O8 77.7(5) . . ?
O4 Rb O8 102.3(5) 9_676 . ?
O4 Rb O8 102.3(5) 10_556 . ?
O4 Rb O8 77.7(5) 2_675 . ?
O7 Rb O8 28.6(5) . . ?
O7 Rb O8 151.4(5) 11_575 . ?
O7 Rb O8 28.6(5) 3_656 . ?
O7 Rb O8 151.4(5) 9_676 . ?
O4 Rb O8 102.3(5) . 9_676 ?
O4 Rb O8 77.7(5) 9_676 9_676 ?
O4 Rb O8 77.7(5) 10_556 9_676 ?
O4 Rb O8 102.3(5) 2_675 9_676 ?
O7 Rb O8 151.4(5) . 9_676 ?
O7 Rb O8 28.6(5) 11_575 9_676 ?
O7 Rb O8 151.4(5) 3_656 9_676 ?
O7 Rb O8 28.6(5) 9_676 9_676 ?
O8 Rb O8 180.0 . 9_676 ?
O4 Rb O8 77.7(5) . 2_675 ?
O4 Rb O8 102.3(5) 9_676 2_675 ?
O4 Rb O8 102.3(5) 10_556 2_675 ?
O4 Rb O8 77.7(5) 2_675 2_675 ?
O7 Rb O8 151.4(5) . 2_675 ?
O7 Rb O8 28.6(5) 11_575 2_675 ?
O7 Rb O8 151.4(5) 3_656 2_675 ?
O7 Rb O8 28.6(5) 9_676 2_675 ?
O8 Rb O8 144.8(13) . 2_675 ?
O8 Rb O8 35.2(13) 9_676 2_675 ?
O4 Rb O8 102.3(5) . 10_556 ?
O4 Rb O8 77.7(5) 9_676 10_556 ?
O4 Rb O8 77.7(5) 10_556 10_556 ?
O4 Rb O8 102.3(5) 2_675 10_556 ?
O7 Rb O8 28.6(5) . 10_556 ?
O7 Rb O8 151.4(5) 11_575 10_556 ?
O7 Rb O8 28.6(5) 3_656 10_556 ?
O7 Rb O8 151.4(5) 9_676 10_556 ?
O8 Rb O8 35.2(13) . 10_556 ?
O8 Rb O8 144.8(13) 9_676 10_556 ?
O8 Rb O8 180.0(3) 2_675 10_556 ?

_refine_diff_density_max         0.695
_refine_diff_density_min         -0.451
_refine_diff_density_rms         0.083


# start Validation Reply Form

_vrf_PLAT043_HTP                 
;
PROBLEM: Calculated and Reported Mol. Weight Differ by ..     56.38 Check.  
RESPONSE: ...The disordered organic cation was not modeled as the
 chemical sense.
;
_vrf_PLAT242_HTP                 
;
PROBLEM: Low    'MainMol' Ueq as Compared to Neighbors of        Eu1 Check.  
RESPONSE: Poor crystal quality was caused by high-temperature.
;
# end Validation Reply Form




